National Library of Energy BETA

Sample records for radon thoron isotopic

  1. Portable apparatus for the measurement of environmental radon and thoron

    DOE Patents [OSTI]

    Negro, Vincent C.

    2001-01-01

    The radometer is a portable instrument for the measurement of the concentration of atmospheric radon/thoron in a test area. A constant velocity pump pulls the air from the outside at a constant flow rate. If the air is too moist, some or all of the sample is passed through a desiccant filter prior to encountering an electrostatic filter. The electrostatic filter prevents any charged particles from entering the sampling chamber. Once the sample has entered the chamber, the progeny of the decay of radon/thoron are collected on a detector and measured. The measured data is compiled by a computer and displayed.

  2. Multi-parametric approach towards the assessment of radon and thoron progeny exposures

    SciTech Connect (OSTI)

    Mishra, Rosaline E-mail: rosaline.mishra@gmail.com; Sapra, B. K.; Mayya, Y. S.

    2014-02-15

    Conventionally, the dosimetry is carried out using radon and thoron gas concentration measurements and doses have been assigned using assumed equilibrium factors for the progeny species, which is inadequate pertaining to the variations in equilibrium factors and possibly due to significant thoron. In fact, since the true exposures depend upon the intricate mechanisms of progeny deposition in the lung, therefore an integrated approach for the assessment of progeny is essential. In this context, the recently developed deposition based progeny concentration measurement techniques (DTPS: Direct Thoron progeny sensors and DRPS: Direct Radon progeny sensors) appear to be best suited for radiological risk assessments both among occupational workers and general study populations. DTPS and DRPS consist of aluminized mylar mounted LR115 type passive detectors, which essentially detects the alpha particles emitted from the deposited progeny atoms on the detector surface. It gives direct measure of progeny activity concentrations in air. DTPS has a lower limit of detection limit of 0.1?Bq/m{sup 3} whereas that for DRPS is 1 Bq/m{sup 3}, hence are perfectly suitable for indoor environments. These DTPS and DRPS can be capped with 200-mesh type wire-screen to measure the coarse fraction of the progeny concentration and the corresponding coarse fraction deposition velocities as well as the time integrated fine fraction. DTPS and DRPS can also be lodged in an integrated sampler wherein the wire-mesh and filter-paper are arranged in an array in flow-mode, to measure the fine and coarse fraction concentration separately and simultaneously. The details are further discussed in the paper.

  3. Invited Article: In situ comparison of passive radon-thoron discriminative monitors at subsurface workplaces in Hungary

    SciTech Connect (OSTI)

    Kvsi, Norbert; Social Organization for Radioecological Cleanliness, Veszprm ; Vigh, Tams; Manganese Mining Process Ltd., rkt ; Nmeth, Csaba; University of Pannonia, Veszprm ; Ishikawa, Tetsuo; Omori, Yasutaka; Janik, Miroslaw; Yonehara, Hidenori

    2014-02-15

    During a one-year long measurement period, radon and thoron data obtained by two different passive radon-thoron discriminative monitors were compared at subsurface workplaces in Hungary, such as mines (bauxite and manganese ore) and caves (medical and touristic). These workplaces have special environmental conditions, such as, stable and high relative humidity (100%), relatively stable temperature (12C21C), low or high wind speed (max. 2.4 ms{sup ?1}) and low or elevated aerosol concentration (13060000 particles m{sup ?3}). The measured radon and thoron concentrations fluctuated in a wide range among the different workplaces. The respective annual average radon concentrations and their standard deviations (in brackets) measured by the passive radon-thoron discriminative monitor with cellulose filter (CF) and the passive radon-thoron discriminative monitor with sponge filter (SF) were: 350(321) Bqm{sup ?3} and 550(497) Bqm{sup ?3} in the bauxite mine; 887(604) Bqm{sup ?3} and 1258(788) Bqm{sup ?3} in the manganese ore mine; 2510(2341) Bqm{sup ?3} and 3403(3075) Bqm{sup ?3} in the medical cave (Hospital Cave of Tapolca); and 6239(2057) Bq m{sup ?3} and 8512(1955) Bqm{sup ?3} in the touristic cave (Lake Cave of Tapolca). The respective average thoron concentrations and their standard deviation (in brackets) measured by CF and SF monitors were: 154(210) Bqm{sup ?3} and 161(148) Bqm{sup ?3} in the bauxite mine; 187(191) Bqm{sup ?3} and 117(147) Bqm{sup ?3} in the manganese-ore mine; 360(524) Bqm{sup ?3} and 371(789) Bqm{sup ?3} in the medical cave (Hospital Cave of Tapolca); and 1420(1184) Bq m{sup ?3} and 1462(3655) Bqm{sup ?3} in the touristic cave (Lake Cave of Tapolca). Under these circumstances, comparison of the radon data for the SF and CF monitors showed the former were consistently 51% higher in the bauxite mine, 38% higher in the manganese ore mine, and 34% higher in the caves. Consequently, correction is required on previously obtained radon data acquired by CF monitors at subsurface workplaces to gain comparable data for SF monitors. In the case of thoron, the data were unreliable and no significant tendency was seen during the comparison therefore comparison of previously obtained thoron data acquired by either CF or SF is doubtful. There was probable influence by relative humidity on the detection response; however, the effects of the high wind speed and elevated aerosol concentration could not be excluded. The results of this study call attention to the importance of calibration under extreme environmental conditions and the need for using reliable radon-thoron monitors for subsurface workplaces.

  4. Method of and apparatus for measuring the mean concentration of thoron and/or radon in a gas mixture

    DOE Patents [OSTI]

    Lucas, Henry

    1990-01-01

    A method of and an apparatus for detecting and accurately measuring the mean concentrations of .sup.222 Rn and .sup.220 Tn in a gas mixture, such as the ambient atmosphere in a mine, is provided. The apparatus includes an alpha target member which defines at least one operative target surface and which is preferably fabricated from a single piece of an alpha particle sensitive material. At least one portion of the operative target surface is covered with an alpha particle filter. The uncovered and filter covered operative surface is exposed to the gas mixture containing the .sup.222 Rn and .sup.220 Tn. In the radioactive decay series of these isotopes the maximum kinetic energy emitted by the alpha decay of .sup.222 Rn is about 1.1 MeV less than the maximum kinetic energy emitted by the alpha decay of a .sup.220 Tn. The alpha particle filter has a predetermined mass per unit area of the covered portion of the operative target surface that prevents penetration of alpha particles which originate from .sup.222 Rn decay, but which allows passage therethrough of the maximum kinetic energy alpha particles from .sup.220 Tn decay. Thus, a count of the alpha particle tracks in the uncovered portion of the target member is proportional to the mean concentration of sum of .sup.222 Rn and .sup.220 Tn in the gas mixture, while the count of alpha tracks in the target member under the filter is proportional to the concentration of only the .sup.220 Tn in the gas mixture.

  5. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Science Nuclear Physics Isotopes Isotopes Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. ...

  6. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Science » Nuclear Physics » Isotopes Isotopes Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Get Expertise Eva Birnbaum (505) 665-7167 Email Wolfgang Runde (505) 667-3350 Email Isotope Production and Applications isotopes Isotopes produced at IPF are critical for medical diagnosis and disease treatment. These positron emission tomography images were made possible using isotopes produced at LANL.

  7. Radon detection

    DOE Patents [OSTI]

    MacArthur, D.W.; Allander, K.S.; Bounds, J.A.

    1994-01-25

    A detector for atmospheric radon using a long range alpha detector as its sensing element is described. An electrostatic filter removes ions from ambient air, while allowing radon atoms to pass into a decay cavity. Here, radon atoms are allowed to decay, creating air ions. These air ions are drawn by a fan through a second electrostatic filter which can be activated or deactivated, and into the long range alpha detector. With the second electrostatic filter activated, no air ions are allowed to pass, and the signal output from the long range alpha detector consists of only the electronic background. With the second electrostatic filter deactivated, air ions and cosmic rays will be detected. The cosmic ray contribution can be minimized by shielding. 3 figures.

  8. Radon detection

    DOE Patents [OSTI]

    MacArthur, Duncan W.; Allander, Krag S.; Bounds, John A.

    1994-01-01

    A detector for atmospheric radon using a long range alpha detector as its sensing element. An electrostatic filter removes ions from ambient air, while allowing radon atoms to pass into a decay cavity. Here, radon atoms are allowed to decay, creating air ions. These air ions are drawn by a fan through a second electrostatic filter which can be activated or deactivated, and into the long range alpha detector. With the second electrostatic filter activated, no air ions are allowed to pass, and the signal output from the long range alpha detector consists of only the electronic background. With the second electrostatic filter deactivated, air ions and cosmic rays will be detected. The cosmic ray contribution can be minimized by shielding.

  9. Fernald radon stack monitor user`s guide

    SciTech Connect (OSTI)

    Whitley, C.R.

    1997-01-01

    The stack monitor uses long-range alpha detection (LRAD) technology for the measurement of radon levels in the stack emissions. The basic principle behind LRAD is the collection of ions created in air through the energy loss mechanisms of decay alphas. This is accomplished by establishing an electric field in the region where alpha decays will occur, and directing the ions via the field onto a biased plate. Accumulation of charge on the plate results in a current in the biasing circuit which can be read with a sensitive electrometer. In electrostatic LRAD designs, the linearity of the measured current with gross alpha activity is well-established. In order to determine radon-222 levels in the presence of other radon isotopes, it is necessary to perform some type of isotopic analysis on the stack samples. In the present case, other radon isotopes of possible concern are radon-219, which occurs in the decay chain of uranium-235, and radon-220, found in the decay chain of thorium-232. Radon-219, with a half-life of four seconds, presents no difficulty for the situation in which emanations from the vitrification process undergo as little as one minute of delay before release into the stack. For example, an initial concentration of 200,000 pCi/l of radon-219 decays to 5 pCi/l in one minute. Radon-220, however, has a half-life of about 55 seconds. If initially present in a substantial ratio to radon-222, a radon gross-alpha measurement on stack emissions would have a significant error if used as a measure for radon-222, even with many minutes of processing delay before the sample was taken.

  10. ARM - Campaign Instrument - radon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsradon Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Radon (RADON) Instrument Categories...

  11. Radon Dose Determination for Cave Guides in Czech Republic

    SciTech Connect (OSTI)

    Thinova, Lenka; Rovenska, Katerina

    2008-08-07

    According to recommended approach there are six (from total of twelve) open-to-public caves in Czech Republic, reaching near to an effective lung-dose of 6mSv/year. A conservative approach for estimating the potential effective lung-dose in caves (or underground) is based on two season's measurements, using solid state alpha track detector (Kodak in plastic diffusion chamber). The obtained dataset is converted into an annual effective dose, in agreement with the ICRP65 recommendation, using the 'cave factor' 1.5. The value of 'cave factor' which depends on the spectrum of aerosol particles, or on the proportional representation of the unattached/attached ratio (6.5 : 93.5 for residential places, 13.6 : 86.4 for caves due to lower concentration of free aerosols) and on the equilibrium factor. Thus conversion factor is 1.5 times higher in comparison with ICRP 65. Is this correct? Because a more precisely determined dose value would have a significant impact on radon remedies, or on restricting the time workers stay underground, a series of measurement was initiated in 2003 with the aim to specify input data, computation and errors in effective dose assessment in each one of the evaluated caves separately. The enhancement of personal dosimetry for underground work places includes a study of the given questions, from the following points of view in each cave: continual radon measurement; regular measurements of radon and its daughters to estimate the equilibrium factor and the presence of free {sup 218}Po; regular indoor air flow measurements to study the location of the radon supply and its transfer among individual areas of the cave; natural radioactive element content evaluation in subsoil and in water inside/outside, a study of the radon sources in the cave; determination of the free fraction from continual unattached and attached fraction measurement (grid and filter); thoron measurement. Air flow measurements provide very interesting information about the origin of 'radon pockets' with very high radon concentration, and enable study of the location of the radon supply and its transfer among individual areas of the cave. Most of the results show the equilibrium factor around F = 0.2-0.7 and the unattached fraction around 2%-30%. One of the most important question remains: how accurately was the unattached fraction measured? Part of this project was to verify the influence of etched track detector position in the cave.

  12. Laboratory studies on the removal of radon-born lead from KamLAND׳s organic liquid scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Keefer, G.; Grant, C.; Piepke, A.; Ebihara, T.; Ikeda, H.; Kishimoto, Y.; Kibe, Y.; Koseki, Y.; Ogawa, M.; Shirai, J.; et al

    2014-09-28

    We studied the removal of radioactivity from liquid scintillator in preparation of a low background phase of KamLAND. We describe the methods and techniques developed to measure and efficiently extract radon decay products from liquid scintillator. Lastly, we report the radio-isotope reduction factors obtained when applying various extraction methods. During this study, distillation was identified as the most efficient method for removing radon daughters from liquid scintillator.

  13. Automatically processed alpha-track radon monitor

    DOE Patents [OSTI]

    Langner, G.H. Jr.

    1993-01-12

    An automatically processed alpha-track radon monitor is provided which includes a housing having an aperture allowing radon entry, and a filter that excludes the entry of radon daughters into the housing. A flexible track registration material is located within the housing that records alpha-particle emissions from the decay of radon and radon daughters inside the housing. The flexible track registration material is capable of being spliced such that the registration material from a plurality of monitors can be spliced into a single strip to facilitate automatic processing of the registration material from the plurality of monitors. A process for the automatic counting of radon registered by a radon monitor is also provided.

  14. Use of a Radon Stripping Algorithm for Retrospective Assessment...

    Office of Scientific and Technical Information (OSTI)

    and beta spectroscopy system employing a passive implanted planar silicon (PIPS) detector. ... MODIFICATIONS; PROGENY; RADON; SILICON air monitoring, radon, algorithm, PIPS, ...

  15. Problems Found Using a Radon Stripping Algorithm for Retrospective...

    Office of Scientific and Technical Information (OSTI)

    and beta spectroscopy system employing a passive implanted planar silicon (PIPS) detector. ... MODIFICATIONS; PROGENY; RADON; SILICON air monitoring, radon, algorithm, PIPS, ...

  16. Low-Cost Radon Reduction Pilot Study

    SciTech Connect (OSTI)

    Rose, William B.; Francisco, Paul W.; Merrin, Zachary

    2015-09-01

    The aim of the research was to conduct a primary scoping study on the impact of air sealing between the foundation and the living space on radon transport reduction across the foundation-living space floor assembly. Fifteen homes in the Champaign, Illinois area participated in the study. These homes were instrumented for hourly continuous radon measurements and simultaneous temperature and humidity the foundation was improved. However, this improved isolation did not lead to significant reductions in radon concentration in the living space. Other factors such as outdoor temperature were shown to have an impact on radon concentration.

  17. Radon and radon daughter measurements at and near the former Middlesex Sampling Plant, Middlesex, New Jersey

    SciTech Connect (OSTI)

    Haywood, F.F.; Perdue, P.T.; Christian, D.J.; Leggett, R.W.; Dickson, H.W.; Myrick, T.E.

    1980-03-01

    The results of the radon and radon daughter measurements made to date (1978) at the Middlesex Sampling Plant in Middlesex, New Jersey, are presented in this report. These measurements were one portion of a more comprehensive radiological survey conducted at this site and the surrounding area from 1976 to 1978. The surveyed property served as a uranium ore sampling plant during the 1940's and early 1950's and as a result contains elevated levels of surface an subsurface contamination. On-site indoor radon daughter and radon concentrations exceeded both the US Surgeon General Guidelines and the Nuclear Regulatory Commission's maximum permissible concentration limits for radon (10 CFR Part 20) in all structures surveyed. Off-site structures showed concentrations of radon and radon daughters at or only slightly above background levels, except for one site where the radon levels were found to be above the 10 CFR Part 20 guidelines. Outdoor radon ad radon daughter concentrations, measured both on and off the site, were well below the guidelines, and the data give no indication of significant radon transport from the site.

  18. Isotope Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science and Production 35 years of experience in isotope production, processing, and applications. Llllll Committed to the safe and reliable production of radioisotopes, products, and services. Contact: Kevin John LANL Isotope Program Manager kjohn@lanl.gov 505-667-3602 Sponsored by the Department of Energy National Isotope Program http://www.nuclear.energy.gov/isotopes/nelsotopes2a.html Isotopes for Environmental Science Isotopes produced at Los Alamos National Laboratory are used as

  19. Evaluation of experiences in long-term radon and radon-daughter measurements

    SciTech Connect (OSTI)

    Young, J.A.; Jackson, P.O.; Thomas, V.W.

    1982-12-01

    Pacific Northwest Laboratory (PNL) is performing side-by-side measurements of radon and radon daughter concentrations using several instruments and techniques, and is comparing these measurements with side-by-side measurements made by other investigators at other locations. The standard deviation of the differences between the (natural) logarithms of the Terradex Track Etch radon concentrations and the logarithms of the Radon Progency Integrating Sampling Units (RPISU) radon daughter concentrations (S.D.-ln) measured in 50 buildings in Edgemont, South Dakota, was 0.37. Using this S.D.-ln, it can be calculated that if the Track Etch radon daughter concentration is 0.010 WL there should be only a 14% probability that the RPISU average would be greater than 0.015 WL, and only a 3% probability tht the RPISU average would be greater than 0.020 WL. If buildings had been cleared from remedial action when the Track Etch averages were less than 0.10 WL, then about 61% of the buildings would have been cleared from remedial action, and only a few percent of these buildings would have actually had average RPISU concentrations greater than 0.015 WL. The S.D.-ln between the Track Etch radon measurements and the RPISU radon daughter measurements made by ALARA at Grand Junction, the PERM radon measurements and the MOD-225 radon daughter measurements made by Mound Facility at Canonsburg and Middlesex, and the PERM and Track Etch radon measurements made by Mound Facility at Salt Lake City were similar to the S.D.-ln between the Track Etch radon measurements and the RPISU radon daughter measurements at Edgemont.

  20. Radiological risk assessment of environmental radon

    SciTech Connect (OSTI)

    Khalid, Norafatin; Majid, Amran Ab; Yahaya, Redzuwan; Yasir, Muhammad Samudi

    2013-11-27

    Measurements of radon gas ({sup 222}Rn) in the environmental are important to assess indoor air quality and to study the potential risk to human health. Generally known that exposure to radon is considered the second leading cause of lung cancer after smoking. The environmental radon concentration depends on the {sup 226}Ra concentration, indoor atmosphere, cracking on rocks and building materials. This study was carried out to determine the indoor radon concentration from selected samples of tin tailings (amang) and building materials in an airtight sealed homemade radon chamber. The radiological risk assessment for radon gas was also calculated based on the annual exposure dose, effective dose equivalent, radon exhalation rates and fatal cancer risk. The continuous radon monitor Sun Nuclear model 1029 was used to measure the radon concentration emanates from selected samples for 96 hours. Five types of tin tailings collected from Kampar, Perak and four samples of building materials commonly used in Malaysia dwellings or building constructions were analysed for radon concentration. The indoor radon concentration determined in ilmenite, monazite, struverite, xenotime and zircon samples varies from 219.6 76.8 Bq m{sup ?3} to 571.1 251.4 Bq m{sup ?3}, 101.0 41.0 Bq m{sup ?3} to 245.3 100.2 Bq m{sup ?3}, 53.1 7.5 Bq m{sup ?3} to 181.8 9.7 Bq m{sup ?3}, 256.1 59.3 Bq m{sup ?3} to 652.2 222.2 Bq m{sup ?3} and 164.5 75.9 Bq m{sup ?3} to 653.3 240.0 Bq m{sup ?3}, respectively. Whereas, in the building materials, the radon concentration from cement brick, red-clay brick, gravel aggregate and cement showed 396.3 194.3 Bq m{sup ?3}, 192.1 75.4 Bq m{sup ?3}, 176.1 85.9 Bq m{sup ?3} and 28.4 5.7 Bq m{sup ?3}, respectively. The radon concentration in tin tailings and building materials were found to be much higher in xenotime and cement brick samples than others. All samples in tin tailings were exceeded the action level for radon gas of 148 Bq m{sup ?3} proposed by EPA except monazite 0.15 kg, struverite 0.15 kg and 0.25 kg. Whereas, all building material samples have exceeded the radon concentration in concrete and building materials of 3 to 7 Bq m{sup ?3} estimated by ICRP. The annual effective dose, effective dose equivalent, and radon exhalation rates in tin tailings were calculated to be in the range of 2.47 to 11.46 mSv, 5.94 to 1090.56 mSv y{sup ?1}, and 0.23 to 1.18 mBq kg{sup ?1} h{sup ?1}. For building materials, the calculated risk assessment of the annual effective dose, effective dose equivalent, radon exhalation rates and fatal cancer risk were 0.72 to 10.00 mSv, 1.73 to 24.00 mSv y{sup ?1}, 0.010 to 0.06 mBq kg{sup ?1} h{sup ?1} and 40 to 550 chances of persons will suffer the cancer per million (1 10{sup 6}), respectively.

  1. Radon measurements at the FEMP

    SciTech Connect (OSTI)

    Tomczak, L.M.; Daniels, R.D.; Dennis, C.; Glassey, H.G.; Lohner, W.G.; Ray, E.C.; Selasky, J.A.; Spitz, H.B.; Roush, K.

    1993-08-01

    Environmental radon monitoring activities at the DOE Fernald Environmental Management Project (FEMP) have been conducted extensively since the early 1980`s. Monitoring has been conducted at ambient concentration levels (< 1 pCi/L Rn-222), inside buildings, and at significantly elevated levels (hundreds of thousands pCi/L Rn-222) within the K-65 silo that store concentrated radium bearing wastes. The purpose of this paper/presentation is to present and discuss some of the difficulties encountered/solutions (e.g. reliability, detection limits, affects of environmental factors, data transfer, etc.) that have been discovered while taking measurements using both alpha track-etch passive integrating detectors and alpha scintillation real-time detectors. A short summary and conclusion section is provided following each topic presented.

  2. National radon database documentation. Volume 4. The EPA/state residential radon surveys: Year 4. Final report 1986-1992

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The National Radon Database has been developed by the U.S. Environmental Protection Agency (EPA) to distribute information collected in two recently completed radon surveys: the EPA/State Residential Radon Surveys, Years 1 to 6; and The National Residential Radon Survey. The goals of the state radon surveys were twofold. Some measure of the distribution of radon levels among residences was desired for major geographic areas within each state and for each state as a whole. In addition, it was desired that each state survey would be able to identify areas of potentially high residential radon concentrations (hot spots) in the state, enabling the state to focus its attention on areas where indoor radon concentrations might pose a greater health threat. The document discusses year 4, 1989-90. The areas surveyed are: California; Hawaii; Idaho; Louisiana; Nebraska; Billings, MT IHS Area; Nevada; North Carolina; Oklahoma; South Carolina; and Navajo Nation.

  3. Occupant radon exposure in houses with basements

    SciTech Connect (OSTI)

    Franklin, E.M.; Fuoss, S.

    1995-12-31

    This study compares basement and main-level radon exposure based on bi-level week-long radon measurements, occupancy and activity data collected in normal use during heating and non-heating seasons in a geographically-stratified random sample of about 600 Minnesota homes, in response to critiques of radon measurement protocol. Basement radon (RN1) (M=4.5, SD=4.5) and main level (Rn2)(M=2.9, SD=3.4) correlation was 0.8 (p=.00), including seasonal variation. In a 101-house subsample where Rn1 >=4.0 pCi/L and Rn2 <=3.9 pCi/L, maximum household exposure in basements was 1162 pCiHrs (M=120, Sd=207), main-level 2486 pCiHrs (M-434, SD=421). In same households, persons with most basement-time maxed 100 hrs (M=13,SD=23), persons with most main-level time maxed 160 hrs (M=79, SD=39). Basement activities show two patterns, (1) member used it for personal domain, e.g. sleeping, and (2) household used it for general activities, e.g. TV or children`s play. Basement occupancy justifies measurement of radon in the lowest livable housing level.

  4. Indoor radon and decay products: Concentrations, causes, and control strategies

    SciTech Connect (OSTI)

    Nero, A.V.; Gadgil, A.J.; Nazaroff, W.W.; Revzan, K.L.

    1990-11-01

    This report is another in the on going technical report series that addresses various aspects of the DOE Radon Research Program. It provides an overview of what is known about the behavior of radon and its decay products in the indoor environment and examines the manner in which several important classes of factors -- structural, geological, and meteorological -- affect indoor radon concentrations. Information on US indoor radon concentrations, currently available monitoring methods and novel radon control strategies are also explored. 238 refs., 22 figs., 9 tabs.

  5. The relation of seismic activity and radon concentration

    SciTech Connect (OSTI)

    Kulali, Feride E-mail: iskender@fef.sdu.edu.tr; Akkurt, ?skender E-mail: iskender@fef.sdu.edu.tr; Vogiannis, Efstratios

    2014-10-06

    Radon, which is the largest source of natural ionizing radiation, reaches to surface as gas or dissolved form in the ground water. Emanation of radon can has a profile is disposed to increasing or decreasing depending on the effects of meteorological events or crust movements. In this work, the radon concentration in soil gas, which is transported from soil to AlphaGUARD, is continuously measured in Mytilene (Greece). A graph of radon concentration is prepared for comparison with simultaneous earthquake data. As a consequence of comparison, we determined that the radon concentration indicates anomalies before the earthquakes.

  6. Low Radioactive Techniques in SuperNEMO: Status of the Radon R and D

    SciTech Connect (OSTI)

    Perrot, F. [Universite de Bordeaux, Centre d'Etudes Nucleaires de Bordeaux Gradignan, UMR 5797, Chemin du Solarium, Le Haut-Vigneau, BP120, F-33175 Gradignan (France); CNRS/IN2P3, Centre d'Etudes Nucleaires de Bordeaux Gradignan, UMR 5797, Chemin du Solarium, Le Haut-Vigneau, BP120, F-33175 Gradignan (France)

    2011-04-27

    Radon is a well-known source of background with respect to the search for neutrinoless double beta decay (0{nu}{beta}{beta}), due to the high Q{sub {beta}} value of one of its daughter nucleus {sup 214}Bi. Radon has been observed and reduced down to 6.5 mBq/m{sup 3} in the NEMO-3 experiment which is looking for the 0{nu}{beta}{beta} process in {sup 100}Mo and in six other isotopes. The SuperNEMO project, a next-generation double beta decay experiment which will also use a tracko-calorimeter technique, has been in an R and D phase since 2006. The goal is to reach a sensitivity of T{sub 1/2}(0{nu})>10{sup 26} y corresponding to an effective Majorana neutrino mass of 0.05-0.1 eV with 100 kg of {sup 82}Se. Such a sensitivity requires in particular to improve the radon radiopurity down to 0.1 mBq/m{sup 3} in the tracking chamber.

  7. Isotope separation

    DOE Patents [OSTI]

    Bartlett, Rodney J.; Morrey, John R.

    1978-01-01

    A method and apparatus is described for separating gas molecules containing one isotope of an element from gas molecules containing other isotopes of the same element in which all of the molecules of the gas are at the same electronic state in their ground state. Gas molecules in a gas stream containing one of the isotopes are selectively excited to a different electronic state while leaving the other gas molecules in their original ground state. Gas molecules containing one of the isotopes are then deflected from the other gas molecules in the stream and thus physically separated.

  8. Radon free storage container and method

    DOE Patents [OSTI]

    Langner, Jr., G. Harold (Mack, CO); Rangel, Mark J. (Austin, CO)

    1991-01-01

    A radon free containment environment for either short or long term storage of radon gas detectors can be provided as active, passive, or combined active and passive embodiments. A passive embodiment includes a resealable vessel containing a basket capable of holding and storing detectors and an activated charcoal adsorbing liner between the basket and the containment vessel wall. An active embodiment includes the resealable vessel of the passive embodiment, and also includes an external activated charcoal filter that circulates the gas inside the vessel through the activated charcoal filter. An embodiment combining the active and passive embodiments is also provided.

  9. Isotope geochemistry

    SciTech Connect (OSTI)

    Cole, D.R.; Curtis, D.B.; DePaolo, D.J.; Gerlach, T.M.; Laul, J.C.; Shaw, H.; Smith, B.M.; Sturchio, N.C.

    1990-09-01

    This document represents the consensus of members of the ad hoc Committee on Isotope Geochemistry in the US Department of Energy; the committee is composed of researchers in isotope geochemistry from seven of the national laboratories. Information included in this document was presented at workshops at Lawrence Berkeley Laboratory (April 1989) and at Los Alamos National Laboratory (August 1989).

  10. Low-cost Radon Reduction Pilot Study

    SciTech Connect (OSTI)

    Rose, William B.; Francisco, Paul W.; Merrin, Zachary

    2015-09-01

    The U.S. Department of Energy's Building America research team Partnership for Advanced Residential Retrofits conducted a primary scoping study on the impact of air sealing between the foundation and the living space on radon transport reduction across the foundation and living space floor assembly. Fifteen homes in the Champaign, Illinois, area participated in the study. These homes were instrumented for hourly continuous radon measurements and simultaneous temperature and humidity measurements. Blower door and zone pressure diagnostics were conducted at each house. The treatments consisted of using air-sealing foams at the underside of the floor that separated the living space from the foundation and providing duct sealing on the ductwork that is situated in the foundation area. The hypothesis was that air sealing the floor system that separated the foundation from the living space should better isolate the living space from the foundation; this isolation should lead to less radon entering the living space from the foundation. If the hypothesis had been proven, retrofit energy-efficiency programs may have chosen to adopt these isolation methods for enhanced radon protection to the living space.

  11. Isotopes Products

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes Products Isotopes Products Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Products stress and rest Stress and rest Rb-82 PET images in a patient with dipyridamole stress-inducible lateral wall and apical ischemia. (http://www.fac.org.ar/scvc/llave/image/machac/machaci.htm#f2,3,4) Strontium-82 is supplied to our customers for use in Sr-82/Rb-82 generator technologies. The generators in turn are supplied to

  12. A radon progeny deposition model (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    by the long half life (22 y) of sup 210Pb on sensitive locations of a detector. ... RADIATION; CLEAN ROOMS; DEPOSITION; HALF-LIFE; PROGENY; RADIATION DETECTORS; RADON; ...

  13. A radon progeny deposition model (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    However, existing models have not explored the impact of some environmental factors important for low background experiments. A test stand has been constructed to deposit radon ...

  14. ISOTOPE SEPARATORS

    DOE Patents [OSTI]

    Bacon, C.G.

    1958-08-26

    An improvement is presented in the structure of an isotope separation apparatus and, in particular, is concerned with a magnetically operated shutter associated with a window which is provided for the purpose of enabling the operator to view the processes going on within the interior of the apparatus. The shutier is mounted to close under the force of gravity in the absence of any other force. By closing an electrical circuit to a coil mouated on the shutter the magnetic field of the isotope separating apparatus coacts with the magnetic field of the coil to force the shutter to the open position.

  15. Radon diffusion through multilayer earthen covers: models and simulations

    SciTech Connect (OSTI)

    Mayer, D.W.; Oster, C.A.; Nelson, R.W.; Gee, G.W.

    1981-09-01

    A capability to model and analyze the fundamental interactions that influence the diffusion of radon gas through uranium mill tailings and cover systems has been investigated. The purpose of this study is to develop the theoretical basis for modeling radon diffusion and to develop an understanding of the fundamental interactions that influence radon diffusion. This study develops the theoretical basis for modeling radon diffusion in one, two and three dimensions. The theory has been incorporated into three computer models that are used to analyze several tailings and cover configurations. This report contains a discussion of the theoretical basis for modeling radon diffusion, a discussion of the computer models used to analyze uranium mill tailings and multilayered cover systems, and presents the results that have been obtained.

  16. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final...

    Office of Scientific and Technical Information (OSTI)

    Radon-222 (222Rn) is a valuable tracer for measuring atmospheric mixing because it is emitted from the land surface and has a short enough half-life (3.8 days) to allow ...

  17. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final...

    Office of Scientific and Technical Information (OSTI)

    The radioisotope radon-222 (222Rn) is a valuable tracer for measuring atmospheric mixing because it is emitted from the land surface and has a short enough half-life (3.8 days) to ...

  18. Residential radon and lung cancer incidence in a Danish cohort

    SciTech Connect (OSTI)

    Braeuner, Elvira V.; Andersen, Claus E.; Sorensen, Mette; Jovanovic Andersen, Zorana; Center for Epidemiology Screening, Department of Public Health, University of Copenhagen ; Gravesen, Peter; Ulbak, Kaare; Hertel, Ole; Pedersen, Camilla; Overvad, Kim; Tjonneland, Anne; Raaschou-Nielsen, Ole

    2012-10-15

    High-level occupational radon exposure is an established risk factor for lung cancer. We assessed the long-term association between residential radon and lung cancer risk using a prospective Danish cohort using 57,053 persons recruited during 1993-1997. We followed each cohort member for cancer occurrence until 27 June 2006, identifying 589 lung cancer cases. We traced residential addresses from 1 January 1971 until 27 June 2006 and calculated radon at each of these addresses using information from central databases regarding geology and house construction. Cox proportional hazards models were used to estimate incidence rate ratios (IRR) and 95% confidence intervals (CI) for lung cancer risk associated with residential radon exposure with and without adjustment for sex, smoking variables, education, socio-economic status, occupation, body mass index, air pollution and consumption of fruit and alcohol. Potential effect modification by sex, traffic-related air pollution and environmental tobacco smoke was assessed. Median estimated radon was 35.8 Bq/m{sup 3}. The adjusted IRR for lung cancer was 1.04 (95% CI: 0.69-1.56) in association with a 100 Bq/m{sup 3} higher radon concentration and 1.67 (95% CI: 0.69-4.04) among non-smokers. We found no evidence of effect modification. We find a positive association between radon and lung cancer risk consistent with previous studies but the role of chance cannot be excluded as these associations were not statistically significant. Our results provide valuable information at the low-level radon dose range.

  19. Radon in energy-efficient earth-sheltered structures

    SciTech Connect (OSTI)

    Nero, A.V.

    1983-05-01

    Exposure o the radioactive-decay products of radon 222 that are present in indoor air constitutes the most-significant radiation dose received by the general population in most countries. Indoor concentrations vary from one building to another, ranging from insignificant to very high levels that cause radiation doses higher than those experienced by uranium miners. This wide range of concentrations is attributable to variability in the rate at which radon enters buildings, and differences in the ventilation rate. Earth-sheltered dwellings, because they are more completely surrounded by earth material than other structures, have an as yet unquantified potential for having radon entry rates that are higher than typical for other houses in the region. Moreover, measures that save energy by reducing ventilation rates (for example by reducing infiltration) can also raise indoor radon concentrations. For these reasons a significant effort is needed to determine the potential for ventilation-reducing measures and earth sheltering to increase radon concentrations, especially in regions where they are already high. Where necessary, proper attention to specific design features that affect radon entry rates or residence time indoors should be adequate to avoid undue risk to the public.

  20. Radon in multi-story residential buildings. Final report

    SciTech Connect (OSTI)

    Mardis, H.M.; MacWaters, J.; Oswald, J.

    1991-12-01

    In September 1989, HUD signed an Interagency Agreement with the Environmental Protection Agency (EPA) requesting EPA to measure radon levels and distribution patterns in several multi-story residential buildings. This study was conducted in two phases. The Phase 1 included walk-through investigations of each of the four test buildings. These preliminary investigations were focused on identifying site-specific characteristics that might influence radon entry and distribution. The results of these investigations were used to design and implement short-term screening measurements (diffusion barrier charcoal canisters) of each building's radon potential. Phase 2 consisted of long-term radon measurements with alpha track detectors (approximately 6 months) and investigations of the characteristics of each building. These measurements were made to address the possibility that long-term radon levels might be higher on upper floors than indicated by the short-term basement and ground-level screening tests. The report describes the investigations that were conducted, the data that were gathered for each building, and general observations and discussions about patterns of radon distribution in these specific buildings.

  1. HEALTH PHYSICS SOCIETY - ENVIRONMENTAL/RADON SECTION ANNOUNCEMENT OF SPONSORED SCHOLARSHIP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HEALTH PHYSICS SOCIETY - ENVIRONMENTAL/RADON SECTION ANNOUNCEMENT OF SPONSORED SCHOLARSHIP Tim Jannik, Environmental/Radon Section President The HPS Environmental/Radon Section is dedicated to promoting students within our discipline. To this end, the Environmental/Radon section is proud to announce the F. Ward Whicker Scholarship. This scholarship will provide $2,000 per year ($1,000 for the first semester and $1,000 for the second semester-dependent on successful completion of the first

  2. Method for separating isotopes

    DOE Patents [OSTI]

    Jepson, B.E.

    1975-10-21

    Isotopes are separated by contacting a feed solution containing the isotopes with a cyclic polyether wherein a complex of one isotope is formed with the cyclic polyether, the cyclic polyether complex is extracted from the feed solution, and the isotope is thereafter separated from the cyclic polyether.

  3. Stable isotope studies

    SciTech Connect (OSTI)

    Ishida, T.

    1992-01-01

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  4. Modeling surface backgrounds from radon progeny plate-out

    SciTech Connect (OSTI)

    Perumpilly, G.; Guiseppe, V. E.; Snyder, N. [University of South Dakota, Vermillion, South Dakota 57069 (United States)] [University of South Dakota, Vermillion, South Dakota 57069 (United States)

    2013-08-08

    The next generation low-background detectors operating deep underground aim for unprecedented low levels of radioactive backgrounds. The surface deposition and subsequent implantation of radon progeny in detector materials will be a source of energetic background events. We investigate Monte Carlo and model-based simulations to understand the surface implantation profile of radon progeny. Depending on the material and region of interest of a rare event search, these partial energy depositions can be problematic. Motivated by the use of Ge crystals for the detection of neutrinoless double-beta decay, we wish to understand the detector response of surface backgrounds from radon progeny. We look at the simulation of surface decays using a validated implantation distribution based on nuclear recoils and a realistic surface texture. Results of the simulations and measured ? spectra are presented.

  5. ARM - Measurement - Isotope ratio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Isotope ratio Ratio of stable isotope concentrations. Categories Atmospheric...

  6. Radon monitoring and early low background counting at the Sanford Underground Laboratory

    SciTech Connect (OSTI)

    Thomas, K.J.; Mei, D.M.; Heise, J.; Durben, D.; Salve, R.

    2010-09-01

    Radon detectors have been deployed underground at the Sanford Underground Laboratory at the site of the former Homestake Mine in Lead, SD. Currently, no radon mitigation measures are in place in the underground environment, and the continuing evolution of the facility ventilation systems has led to significant variations in early airborne radon concentrations. The average radon concentration measured near the primary ventilation intake for the 4850-ft level (Yates shaft) is 391 Bq/m{sup 3}, based on approximately 146 days of data. The corresponding average radon concentration near the other main ventilation intake for the 4850-ft level (Ross shaft) is 440 Bq/m{sup 3} based on approximately 350 days of data. Measurements have also been collected near the 1250-ft level Ross shaft, with average radon concentrations at 180 Bq/m{sup 3}. Secondary factors that may increase the baseline radon level underground include the presence of iron oxide and moisture, which are known to enhance radon emanation. The results of the current radon monitoring program will be used for the planning of future measurements and any potential optimization of ventilation parameters for the reduction of radon in relevant areas underground.

  7. Recommended Procedures for Measuring Radon Fluxes from Disposal Sites of Residual Radioactive Materials

    SciTech Connect (OSTI)

    Young,, J. A.; Thomas, V. W.; Jackson, P. 0.

    1983-03-01

    This report recornmenrls instrumentation and methods suitable for measuring radon fluxes emanating from covered disposal sites of residual radioactive materials such as uranium mill tailings. Problems of spatial and temporal variations in radon flux are discussed and the advantages and disadvantages of several instruments are examined. A year-long measurement program and a two rnonth measurement rnethodology are then presented based on the inherent difficulties of measuring average radon flux over a cover using the recommended instrumentation.

  8. HYDROGEN ISOTOPE TARGETS

    DOE Patents [OSTI]

    Ashley, R.W.

    1958-08-12

    The design of targets for use in the investigation of nuclear reactions of hydrogen isotopes by bombardment with accelerated particles is described. The target con struction eomprises a backing disc of a metal selected from the group consisting of molybdenunn and tungsten, a eoating of condensed titaniunn on the dise, and a hydrogen isotope selected from the group consisting of deuterium and tritium absorbed in the coatiag. The proeess for preparing these hydrogen isotope targets is described.

  9. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, Jakob

    1991-01-01

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus.

  10. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus. 2 figures.

  11. PRINCIPAL ISOTOPE SELECTION REPORT

    SciTech Connect (OSTI)

    K. D. Wright

    1998-08-28

    Utilizing nuclear fuel to produce power in commercial reactors results in the production of hundreds of fission product and transuranic isotopes in the spent nuclear fuel (SNF). When the SNF is disposed of in a repository, the criticality analyses could consider all of the isotopes, some principal isotopes affecting criticality, or none of the isotopes, other than the initial loading. The selected set of principal isotopes will be the ones used in criticality analyses of the SNF to evaluate the reactivity of the fuel/waste package composition and configuration. This technical document discusses the process used to select the principal isotopes and the possible affect that these isotopes could have on criticality in the SNF. The objective of this technical document is to discuss the process used to select the principal isotopes for disposal criticality evaluations with commercial SNF. The principal isotopes will be used as supporting information in the ''Disposal Criticality Analysis Methodology Topical Report'' which will be presented to the United States Nuclear Regulatory Commission (NRC) when approved by the United States Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM).

  12. Stable isotope enrichment

    SciTech Connect (OSTI)

    Egle, Brian

    2014-07-14

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  13. Stable isotope enrichment

    ScienceCinema (OSTI)

    Egle, Brian

    2014-07-15

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  14. Radon induced surface contaminations in low background experiments

    SciTech Connect (OSTI)

    Pattavina, L. [INFN - Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy)] [INFN - Laboratori Nazionali del Gran Sasso, I-67010 Assergi (AQ) (Italy)

    2013-08-08

    In neutrinoless double-beta decay and dark matter searches, one of the main issues is to increase the experimental sensitivity through careful material selection and production, minimizing the background contributions. In order to achieve the required, extremely low, counting rates, very stringent requirements must be fulfilled in terms of bulk material radiopurity. As the experimental sensitivity increases, the bulk impurities in the detector components decrease, and surface contaminations start to play an increasingly significant role In fully active detectors, like cryogenic particle detectors, surface contaminations are a critical issue (as shown by the CUORICINO experiment). {sup 222}Rn is by far the most intense source of airborne radioactivity, and if a radio-pure material is exposed to environment where the Radon concentration is not minimized, {sup 210}Pb and {sup 210}Po contaminations can occur. The mechanisms and the dynamics of Radon-induced surface contaminations are reviewed, and specific solutions to prevent and to reject the induced background are presented.

  15. Price Quotes and Isotope Ordering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ordering Price Quotes and Isotope Ordering Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Isotope...

  16. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  17. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul; Jensen, Reed J.; Cotter, Theodore P.; Greiner, Norman R.; Boyer, Keith

    1987-01-01

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  18. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Reed, J.J.; Cotter, T.P.; Boyer, K.; Greiner, N.R.

    1975-11-26

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light is described. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  19. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul; Jensen, Reed J.; Cotter, Theodore P.; Boyer, Keith; Greiner, Norman R.

    1988-01-01

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  20. Indoor Radon and Its Decay Products: Concentrations, Causes, and Control Strategies

    SciTech Connect (OSTI)

    Nero, A.V.; Gadgil, A.J.; Nazaroff, W.W.; Revzan, K.L.

    1990-01-01

    This report is an introduction to the behavior of radon 222 and its decay products in indoor air. This includes review of basic characteristics of radon and its decay products and of features of the indoor environment itself, all of which factors affect behavior in indoor air. The experimental and theoretical evidence on behavior of radon and its decay products is examined, providing a basis for understanding the influence of geological, structural, and meteorological factors on indoor concentrations, as well as the effectiveness of control techniques. We go on to examine three important issues concerning indoor radon. We thus include (1) an appraisal of the concentration distribution in homes, (2) an examination of the utility and limitations of popular monitoring techniques and protocols, and (3) an assessment of the key elements of strategies for controlling radon levels in homes.

  1. Construction and measurements of a vacuum-swing-adsorption radon-mitigation system

    SciTech Connect (OSTI)

    Schnee, R. W.; Bunker, R.; Ghulam, G.; Jardin, D.; Kos, M.; Tenney, A. S. [Department of Physics, Syracuse University, Syracuse, NY 13244 (United States)] [Department of Physics, Syracuse University, Syracuse, NY 13244 (United States)

    2013-08-08

    Long-lived alpha and beta emitters in the {sup 222}Rn decay chain on (and near) detector surfaces may be the limiting background in many experiments attempting to detect dark matter or neutrinoless double beta decay, and in screening detectors. In order to reduce backgrounds from radon-daughter plate-out onto the wires of the Beta Cage during its assembly, an ultra-low-radon cleanroom is being commissioned at Syracuse University using a vacuum-swing-adsorption radon-mitigation system. The radon filter shows ?20 reduction at its output, from 7.470.56 to 0.370.12 Bq/m{sup 3}, and the cleanroom radon activity meets project requirements, with a lowest achieved value consistent with that of the filter, and levels consistently < 2 Bq/m{sup 3}.

  2. Characterization of the radon source in North-Central Florida. Final report part 1 -- Final project report; Final report part 2 -- Technical report

    SciTech Connect (OSTI)

    1997-12-01

    This report contains two separate parts: Characterization of the Radon Source in North-Central Florida (final report part 1 -- final project report); and Characterization of the Radon Source in North-Central Florida (technical report). The objectives were to characterize the radon 222 source in a region having a demonstrated elevated indoor radon potential and having geology, lithology, and climate that are different from those in other regions of the U.S. where radon is being studied. Radon availability and transport in this region were described. Approaches for predicting the radon potential of lands in this region were developed.

  3. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  4. Plasma isotope separation methods

    SciTech Connect (OSTI)

    Grossman, M.W. ); Shepp, T.A. )

    1991-12-01

    Isotope separation has many important industrial, medical, and research applications. Large-scale processes have typically utilized complex cascade systems; for example, the gas centrifuge. Alternatively, high single-stage enrichment processes (as in the case of the calutron) are very energy intensive. Plasma-based methods being developed for the past 15 to 20 years have attempted to overcome these two drawbacks. In this review, six major types of isotope separation methods which involve plasma phenomena are discussed. These methods are: plasma centrifuge, AVLIS (atomic vapor laser isotope separation), ion wave, ICR (ion-cyclotron resonance), calutron, and gas discharge. The emphasis of this paper is to describe the plasma phenomena in these major categories. An attempt was made to include enough references so that more detailed study or evaluation of a particular method could readily be pursued. A brief discussion of isotope separation using mass balance concepts is also carried out.

  5. RADON PROGENY AS AN EXPERIMENTAL TOOL FOR DOSIMETRY OF NANOAEROSOLS

    SciTech Connect (OSTI)

    Ruzer, Lev; Ruzer, Lev S.; Apte, Michael G.

    2008-02-25

    The study of aerosol exposure and dosimetry measurements and related quantitation of health effects are important to the understanding of the consequences of air pollution, and are discussed widely in the scientific literature. During the last 10 years the need to correlate aerosol exposure and biological effects has become especially important due to rapid development of a new, revolutionary industry ?-- nanotechnology. Nanoproduct commerce is predicted to top $1 trillion by 2015. Quantitative assessment of aerosol particle behavior in air and in lung deposition, and dosimetry in different parts of the lung, particularly for nanoaerosols, remains poor despite several decades of study. Direct measurements on humans are still needed in order to validate the hollow cast, animal studies, and lung deposition modeling. We discuss here the use of nanoscale radon decay products as an experimental tool in the study of local deposition and lung dosimetry for nanoaerosols. The issue of the safe use of radon progeny in such measurements is discussed based on a comparison of measured exposure in 3 settings: general population, miners, and in a human experiment conducted at the Paul Scherer Institute (PSI) in Switzerland. One of the properties of radon progeny is that they consist partly of 1 nm radioactive particles called unattached activity; having extremely small size and high diffusion coefficients, these particles can be potentially useful as radioactive tracers in the study of nanometer-sized aerosols. We present a theoretical and experimental study of the correlation between the unattached activity and aerosol particle surface area, together with a description of its calibration and method for measurement of the unattached fraction.

  6. A generic biokinetic model for noble gases with application to radon

    SciTech Connect (OSTI)

    Leggett, Richard Wayne; Marsh, James; Gregoratto, Demetrio; Blanchardon, Eric

    2013-01-01

    The International Commission for Radiological Protection (ICRP) currently uses a dose conversion coefficient to calculate effective dose per unit exposure to radon and its progeny. The coefficient is derived by dividing the detriment associated with unit exposure to radon, as estimated from epidemiological studies, by the detriment per unit effective dose, as estimated mainly from atomic bomb survivor data and animal studies. In a recent statement the ICRP indicated that future guidance on exposure to radon and its progeny will be developed in the same way as guidance for any other radionuclide. That is, intake of radon and progeny will be limited on the basis of effective dose coefficients derived from biokinetic and dosimetric models. This paper proposes a biokinetic model for systemic (absorbed) radon for use in the calculation of dose coefficients for inhaled or ingested radon. The model is based largely on physical laws governing transfer of a non-reactive and soluble gas between materials. Model predictions are shown to be consistent with results of controlled studies of the fate of internally deposited radon in human subjects.

  7. The Effect of Steady Winds on Radon-222 Entry from soil into houses

    SciTech Connect (OSTI)

    Riley, W.J.; Gadgil, A.J.; Bonnefous, Y.C.; Nazaroff, W.W.

    1994-10-01

    Wind affects the radon-222 entry rate from soil into buildings and the resulting indoor concentrations. To investigate this phenomenon, we employ a previously tested three-dimensional numerical model of soil-gas Bow around houses, a commercial computational fluid dynamics code, an established model for determining ventilation rates in the presence of wind, and new wind tunnel results for the ground-surface pressure field caused by wind. These tools and data, applied under steady-state conditions to a prototypical residential building, allow us (1) to determine the complex soil-gas flow patterns that result from the presence of wind-generated ground-surface pressures, (2) to evaluate the effect of these flows on the radon concentration in the soil, and (3) to calculate the effect of wind on the radon entry rate and indoor concentration. For a broad range of soil permeabilities, two wind speeds, and two wind directions, we quantify the"flushing" effect of wind on the radon in the soil surrounding a house, and the consequent sharp decrease in radon entry rates. Experimental measurements of the time-dependent radon concentration in soil gas beneath houses confirm the existence of wind-induced flushing. Comparisons are made to modeling predictions obtained while ignoring the effect of the wind-generated ground-surface pressures. These investigations lead to the conclusion that wind-generated ground-surface pressures play a significant role in determining radon entry rates into residential buildings. [References: 26

  8. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  9. Transportation of medical isotopes

    SciTech Connect (OSTI)

    Nielsen, D.L.

    1997-11-19

    A Draft Technical Information Document (HNF-1855) is being prepared to evaluate proposed interim tritium and medical isotope production at the Fast Flux Test Facility (FFTF). This assessment examines the potential health and safety impacts of transportation operations associated with the production of medical isotopes. Incident-free and accidental impacts are assessed using bounding source terms for the shipment of nonradiological target materials to the Hanford Site, the shipment of irradiated targets from the FFTF to the 325 Building, and the shipment of medical isotope products from the 325 Building to medical distributors. The health and safety consequences to workers and the public from the incident-free transportation of targets and isotope products would be within acceptable levels. For transportation accidents, risks to works and the public also would be within acceptable levels. This assessment is based on best information available at this time. As the medical isotope program matures, this analysis will be revised, if necessary, to support development of a final revision to the Technical Information Document.

  10. Isotope separation apparatus

    DOE Patents [OSTI]

    Arnush, Donald (Rancho Palos Verdes, CA); MacKenzie, Kenneth R. (Pacific Palisades, CA); Wuerker, Ralph F. (Palos Verdes Estates, CA)

    1980-01-01

    Isotope separation apparatus consisting of a plurality of cells disposed adjacent to each other in an evacuated container. A common magnetic field is established extending through all of the cells. A source of energetic electrons at one end of the container generates electrons which pass through the cells along the magnetic field lines. Each cell includes an array of collector plates arranged in parallel or in tandem within a common magnetic field. Sets of collector plates are disposed adjacent to each other in each cell. Means are provided for differentially energizing ions of a desired isotope by applying energy at the cyclotron resonant frequency of the desired isotope. As a result, the energized desired ions are preferentially collected by the collector plates.

  11. Radon and helium in soil gases in the Phlegraean Fields, central Italy

    SciTech Connect (OSTI)

    Lombardi, S. ); Reimer, G.M. )

    1990-05-01

    The distribution and migration of radon and helium soil-gas concentrations in the Phlegraean Fields, Italy, are controlled by the tectonic features of the area. Radon is supplied from surficial sources and helium has both surficial and deep origins. There is no direct correlation between the two noble gases on a point-to-point basis but the areal distribution of both gases is similar, suggesting that the distribution is controlled primarily by fractures and movement of geothermal fluids.

  12. Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign

    Office of Scientific and Technical Information (OSTI)

    Summary (Program Document) | SciTech Connect Program Document: Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary Citation Details In-Document Search Title: Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary Uncertainty in vertical mixing between the surface layer, boundary layer, and free troposphere leads to large uncertainty in "top-down" estimates of regional land-atmosphere carbon exchange (i.e., estimates based on

  13. Variation in the annual average radon concentration measured in homes in Mesa County, Colorado

    SciTech Connect (OSTI)

    Rood, A.S.; George, J.L.; Langner, G.H. Jr.

    1990-04-01

    The purpose of this study is to examine the variability in the annual average indoor radon concentration. The TMC has been collecting annual average radon data for the past 5 years in 33 residential structures in Mesa County, Colorado. This report is an interim report that presents the data collected up to the present. Currently, the plans are to continue this study in the future. 62 refs., 3 figs., 12 tabs.

  14. Wind-induced contaminant transport in near-surface soils with application to radon entry into buildings

    SciTech Connect (OSTI)

    Riley, W J

    1996-05-01

    Indoor air exposures to gaseous contaminants originating in soil can cause large human health risks. To predict and control these exposures, the mechanisms that affect vapor transport in near-surface soils need to be understood. In particular, radon exposure is a concern since average indoor radon concentrations lead to much higher risks than are generally accepted for exposure to other environmental contaminants. This dissertation examines an important component of the indoor radon problem: the impacts of wind on soil-gas and radon transport and entry into buildings. The research includes experimental and modeling studies of wind`s interactions with a building`s superstructure and the resulting soil-gas and radon flows in the surrounding soil. In addition to exploring the effects of steady winds, a novel modeling technique is developed to examine the impacts of fluctuating winds on soil-gas and radon transport.

  15. Integration of Nontraditional Isotopic Systems Into Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemistry on Reservoir Sustainability Integration of Nontraditional Isotopic Systems Into ... Chemistry on Reservoir Sustainability Integration of Nontraditional Isotopic Systems Into ...

  16. DEEP WATER ISOTOPIC CURRENT ANALYZER

    DOE Patents [OSTI]

    Johnston, W.H.

    1964-04-21

    A deepwater isotopic current analyzer, which employs radioactive isotopes for measurement of ocean currents at various levels beneath the sea, is described. The apparatus, which can determine the direction and velocity of liquid currents, comprises a shaft having a plurality of radiation detectors extending equidistant radially therefrom, means for releasing radioactive isotopes from the shaft, and means for determining the time required for the isotope to reach a particular detector. (AEC)

  17. Industrial Technology of Decontamination of Liquid Radioactive Waste in SUE MosSIA 'Radon' - 12371

    SciTech Connect (OSTI)

    Adamovich, Dmitry V.; Neveykin, Petr P.; Karlin, Yuri V.; Savkin, Alexander E. [SUE MosSIA 'Radon', 7th Rostovsky lane 2/14, Moscow 119121 (Russian Federation)

    2012-07-01

    SUE MosSIA 'RADON' - this enterprise was created more than 50 years ago, which deals with the recycling of radioactive waste and conditioning of spent sources of radiation in stationary and mobile systems in the own factory and operating organizations. Here is represented the experience SUE MosSIA 'Radon' in the field of the management with liquid radioactive waste. It's shown, that the activity of SUE MosSIA 'RADON' is developing in three directions - improvement of technical facilities for treatment of radioactive waters into SUE MosSIA 'RADON' development of mobile equipment for the decontamination of radioactive waters in other organizations, development of new technologies for decontamination of liquid radioactive wastes as part of various domestic Russian and international projects including those related to the operation of nuclear power and nuclear submarines. SUE MosSIA 'RADON' has processed more than 270 thousand m{sup 3} of radioactive water, at that more than 7000 m{sup 3} in other organizations for more than 50 years. It is shown that a number of directions, particularly, the development of mobile modular units for decontamination of liquid radioactive waste, SUE MosSIA 'RADON' is a leader in the world. (authors)

  18. The ORNL Indoor Air Quality Study: Re-cap, Context, and Assessment on Radon

    SciTech Connect (OSTI)

    Tonn, Bruce Edward; Rose, Erin M.; Ternes, Mark P.

    2015-10-01

    As part of the retrospective evaluation of the U.S. Department of Energy s low-income Weatherization Assistance Program that was led by Oak Ridge National Laboratory (ORNL), an assessment of the impacts of weatherization on indoor air quality (IAQ) was conducted. This assessment included nearly 500 treatment and control homes across the country. Homes were monitored for carbon monoxide, radon, formaldehyde, temperature and humidity pre- and post-weatherization. This report focuses on the topic of radon and addresses issues not thoroughly discussed in the original IAQ report. The size, scope and rigor of the radon component of the IAQ study are compared to previous studies that assessed the impacts of weatherization on indoor radon levels. It is found that the ORNL study is by far the most extensive study conducted to date, though the ORNL results are consistent with the findings of the other studies. However, the study does have limitations related to its reliance on short-term measurements of radon and inability to attribute changes in radon levels in homes post-weatherization to specific weatherization measures individually or in combination.

  19. Method for separating boron isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D.

    1978-01-01

    A method of separating boron isotopes .sup.10 B and .sup.11 B by laser-induced selective excitation and photodissociation of BCl.sub.3 molecules containing a particular boron isotope. The photodissociation products react with an appropriate chemical scavenger and the reaction products may readily be separated from undissociated BCl.sub.3, thus effecting the desired separation of the boron isotopes.

  20. Radon-related backgrounds in the LUX dark matter search

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bradley, A.; Akerib, D. S.; Araújo, H. M.; Bai, X.; Bailey, A. J.; Balajthy, J.; Bernard, E.; Bernstein, A.; Byram, D.; Cahn, S. B.; et al

    2015-01-01

    The LUX detector is currently in operation at the Davis Campus at the 4850’ level of the Sanford Underground Research Facility (SURF) in Lead, SD to directly search for WIMP dark matter. Knowing the type and rate of backgrounds is critical in a rare, low energy event search, and LUX was designed, constructed, and deployed to mitigate backgrounds, both internal and external. An important internal background are decays of radon and its daughters. These consist of alpha decays, which are easily tagged and are a tracer of certain backgrounds, and beta decays, some of which are not as readily taggedmore » and present a background for the WIMP search. We report on studies of alpha decay and discuss implications for the WIMP search.« less

  1. Radon-related backgrounds in the LUX dark matter search

    SciTech Connect (OSTI)

    Bradley, A. [Case Western Reserve Univ., Cleveland, OH (United States); Akerib, D. S. [Case Western Reserve Univ., Cleveland, OH (United States); Arajo, H. M. [Imperial College London, London (United Kingdom); Bai, X. [South Dakota School of Mines and Technology, Rapid City, SD (United States); Bailey, A. J. [Imperial College London, London (United Kingdom); Balajthy, J. [Univ. of Maryland, College Park, MD (United States); Bernard, E. [Yale Univ., New Haven, CT (United States); Bernstein, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Byram, D. [Univ. of South Dakota, Vermillion, SD (United States); Cahn, S. B. [Yale Univ., New Haven, CT (United States); Carmona-Benitez, M. C. [Univ. of California Santa Barbara, Santa Barbara, CA (United States); Chan, C. [Brown Univ., Providence, RI (United States); Chapman, J. J. [Brown Univ., Providence, RI (United States); Chiller, A. A. [Univ. of South Dakota, Vermillion, SD (United States); Chiller, C. [Univ. of South Dakota, Vermillion, SD (United States); Coffey, T. [Case Western Reserve Univ., Cleveland, OH (United States); Currie, A. [Imperial College London, London (United Kingdom); de Viveiros, L. [Univ. of Coimbra, Coimbra (Portugal); Dobi, A. [Univ. of Maryland, College Park, MD (United States); Dobson, J. [Univ. of Edingburg, Edinburg (United Kingdom); Druszkiewicz, E. [Univ. of Rochester, Rochester, NY (United States); Edwards, B. [Yale Univ., New Haven, CT (United States); Faham, C. H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fiorucci, S. [Brown Univ., Providence, RI (United States); Flores, C. [Univ. of California, Davis, Davis, CA (United States); Gaitskell, R. J. [Brown Univ., Providence, RI (United States); Gehman, V. M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ghag, C. [Univ. College London, London (United Kingdom); Gibson, K. R. [Case Western Reserve Univ., Cleveland, OH (United States); Gilchriese, M. G.D. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hall, C. [Univ. of Maryland, College Park, MD (United States); Hertel, S. A. [Yale Univ., New Haven, CT (United States); Horn, M. [Yale Univ., New Haven, CT (United States); Huang, D. Q. [Brown Univ., Providence, RI (United States); Ihm, M. [Univ. of California Berkeley, Berkeley, CA (United States); Jacobsen, R. G. [Univ. of California Berkeley, Berkeley, CA (United States); Kazkaz, K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Knoche, R. [Univ. of Maryland, College Park, MD (United States); Larsen, N. A. [Yale Univ., New Haven, CT (United States); Lee, C. [Case Western Reserve Univ., Cleveland, OH (United States); Lindote, A. [Univ. of Coimbra, Coimbra (Portugal); Lopes, M. I. [Univ. of Coimbra, Coimbra (Portugal); Malling, D. C. [Brown Univ., Providence, RI (United States); Mannino, R. [Texas A & M Univ., College Station, TX (United States); McKinsey, D. N. [Yale Univ., New Haven, CT (United States); Mei, D. -M. [Univ. of South Dakota, Vermillion, SD (United States); Mock, J. [Univ. of California, Davis, Davis, CA (United States); Moongweluwan, M. [Univ. of Rochester, Rochester, NY (United States); Morad, J. [Univ. of California, Davis, Davis, CA (United States); Murphy, A. St.J. [Univ. of Edingburg, Edinburg (United Kingdom); Nehrkorn, C. [Univ. of California Santa Barbara, Santa Barbara, CA (United States); Nelson, H. [Univ. of California Santa Barbara, Santa Barbara, CA (United States); Neves, F. [Univ. of Coimbra, Coimbra (Portugal); Ott, R. A. [Univ. of California, Davis, Davis, CA (United States); Pangilinan, M. [Brown Univ., Providence, RI (United States); Parker, P. D. [Yale Univ., New Haven, CT (United States); Pease, E. K. [Yale Univ., New Haven, CT (United States); Pech, K. [Case Western Reserve Univ., Cleveland, OH (United States); Phelps, P. [Case Western Reserve Univ., Cleveland, OH (United States); Reichhart, L. [Univ. College London, London (United Kingdom); Shutt, T. [Case Western Reserve Univ., Cleveland, OH (United States); Silva, C. [Univ. of Coimbra, Coimbra (Portugal)

    2015-01-01

    The LUX detector is currently in operation at the Davis Campus at the 4850 level of the Sanford Underground Research Facility (SURF) in Lead, SD to directly search for WIMP dark matter. Knowing the type and rate of backgrounds is critical in a rare, low energy event search, and LUX was designed, constructed, and deployed to mitigate backgrounds, both internal and external. An important internal background are decays of radon and its daughters. These consist of alpha decays, which are easily tagged and are a tracer of certain backgrounds, and beta decays, some of which are not as readily tagged and present a background for the WIMP search. We report on studies of alpha decay and discuss implications for the WIMP search.

  2. Effects of finite sampling and additive noise on image reconstruction from Radon transform

    SciTech Connect (OSTI)

    Tsujimoto, E.M. (California Univ., Davis, CA (USA))

    1988-12-01

    The Radon transform arises naturally in the problem of reconstructing an image or cross section from line integral measurements through a specified object. Each line integral or ray is a sample of the Radon transform of the object and the set of all samples at a particular angle is called a projection or view. Consequently, the set of all possible samples at all possible projections in a particular plane constitutes the two-dimensional Radon transform. Of course, it is impossible to acquire an infinite number of data points for the purpose of image reconstruction. However, with a sufficient set of Radon transform samples, an images can be determined through various Radon transform inversion techniques. From this statement, however, arises the question of just what constitutes a sufficient set of Radon transform samples. Acquiring an insufficient number of samples results in various artifacts in the reconstructed image. On the other hand, taking too many samples utilizes the data inefficiently. Thus, the problem of interest is to determine the optimum number of projections and the optimum number of samples per projection required to adequately represent the Radon transform such that the image can be accurately reconstructed. The problem of image reconstruction is further complicated if noise is introduced in the projection domain. Noise may be caused by round-off error in the sampled projection data or by various other factors inherent in data acquisition processes. However, several filtering techniques can be implemented to suppress the effects of noise. Therefore, a second problem of interest is to study the effectiveness of different filtering techniques in noise suppression.

  3. Manus Water Isotope Investigation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Manus Water Isotope Investigation Field Campaign Report JL Conroy D Noone KM Cobb March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not

  4. Manus Water Isotope Investigation

    Office of Scientific and Technical Information (OSTI)

    ENERGY Office of Science DOE/SC-ARM-15-079 Manus Water Isotope Investigation Field Campaign Report JL Conroy D Noone KM Cobb March 2016 CLIMATE RESEARCH FACILITY DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus,

  5. ISOTOPE SEPARATING APPARATUS CONTROL

    DOE Patents [OSTI]

    Barnes, S.W.

    1959-08-25

    An improved isotope separating apparatus of the electromagnetic type, commonly referred to as a calutron, is described. Improvements in detecting and maintaining optimum position and focus of the ion beam are given. The calutron collector is provided with an additional electrode insulated from and positioned between the collecting pockets. The ion beams are properly positioned and focused until the deionizing current which flows from ground to this additional electrode ts a minimum.

  6. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, Christopher A.; Worden, Earl F.

    1995-01-01

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  7. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, C.A.; Worden, E.F.

    1995-08-22

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  8. Study on the influence of CR-39 detector size on radon progeny detection in indoor environments

    SciTech Connect (OSTI)

    Pereira, L. A.; Hadler, J. C.; Lixandro F, A. L.; Guedes, S.; Takizawa, R. H.

    2014-11-11

    It is well known that radon daughters up to {sup 214}Po are the real contaminants to be considered in case of indoor radon contamination. Assemblies consisting of 6 circular bare sheets of CR-39, a nuclear track detector, with radius varying from 0.15 to 1.2 cm were exposed far from any material surface for periods of approximately 6 months in 13 different indoor rooms (7 workplaces and 6 dwellings), where ventilation was moderate or poor. It was observed that track density was as greater as smaller was the detector radius. Track density data were fitted using an equation deduced based on the assumption that the behavior of radon and its progeny in the air was described by Fick's Law, i.e., when the main mechanism of transport of radon progeny in the air is diffusion. As many people spend great part of their time in closed or poorly ventilated environments, the confirmation they present equilibrium between radon and its progeny is an interesting start for dosimetric calculations concerning this contamination.

  9. Potential increases in natural radon emissions due to heating of the Yucca Mountain rock mass

    SciTech Connect (OSTI)

    Pescatore, C.; Sullivan, T.M.

    1992-02-01

    Heating of the rock mass by the spent fuel in the proposed repository at Yucca Mountain will cause extra amounts of natural radon to diffuse into the fracture system and to migrate faster to the accessible environment. Indeed, free-convection currents due to heating will act to shorten the radon travel times and will cause larger releases than would be possible under undistributed conditions. To estimate the amount of additional radon released due to heating of the Yucca Mountain rock mass, we obtain an expression for the release enhancement factor, E. This factor is defined as the ratio between the total flux of radon at the surface of the mountain before and after closure of the repository assuming the only cause of disturbance to be the heating of the rock mass. With appropriate approximations and using a heat load representative of that expected at Yucca Mountain, the present calculations indicate that the average enhancement factor over the first 10,000 years will be 4.5 as a minimum. These calculations are based on the assumption that barometric pumping does not significantly influence radon release. The latter assumption will need to be substantiated.

  10. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1988-02-01

    This report contains a listing of electromagnetically separated stable isotopes which are available at the Oak Ridge National Laboratory for distribution for nondestructive research use on a loan basis. This inventory includes all samples of stable isotopes in the Research Materials Collection and does not designate whether a sample is out on loan or is in reprocessing. For some of the high-abundance, naturally occurring isotopes, larger amounts can be made available; for example, Ca-40 and Fe-56.

  11. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    This report contains a listing of electromagnetically separated stable isotopes which are available for distribution within the United States for nondestructive research use from the Oak Ridge National Laboratory on a loan basis. This inventory includes all samples of stable isotopes in the Material Research Collection and does not designate whether a sample is out on loan or in reprocessing. For some of the high abundance naturally occurring isotopes, larger amounts can be made available; for example, Ca-40 and Fe-56.

  12. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1984-03-01

    This report contains a listing of electromagnetically separated stable isotopes which are available at the Oak Ridge National Laboratory for distribution for nondestructive research use on a loan basis. This inventory includes all samples of stable isotopes in the Research Materials Collection and does not designate whether a sample is out on loan or is in reprocessing. For some of the high abundance naturally occurring isotopes, larger amounts can be made available; for example, Ca-40 and Fe-56.

  13. Isotopically labeled compositions and method

    DOE Patents [OSTI]

    Schmidt, Jurgen G.; Kimball, David B.; Alvarez, Marc A.; Williams, Robert F.; Martinez, Rudolfo A.

    2011-07-12

    Compounds having stable isotopes .sup.13C and/or .sup.2H were synthesized from precursor compositions having solid phase supports or affinity tags.

  14. Advanced isotope separation

    SciTech Connect (OSTI)

    Not Available

    1982-05-04

    The Study Group briefly reviewed the technical status of the three Advanced Isotope Separation (AIS) processes. It also reviewed the evaluation work that has been carried out by DOE's Process Evaluation Board (PEB) and the Union Carbide Corporation-Nuclear Division (UCCND). The Study Group briefly reviewed a recent draft assessment made for DOE staff of the nonproliferation implications of the AIS technologies. The staff also very briefly summarized the status of GCEP and Advanced Centrifuge development. The Study Group concluded that: (1) there has not been sufficient progress to provide a firm scientific, technical or economic basis on which to select one of the three competing AIS processes for full-scale engineering development at this time; and (2) however, should budgetary restraints or other factors force such a selection, we believe that the evaluation process that is being carried out by the PEB provides the best basis available for making a decision. The Study Group recommended that: (1) any decisions on AIS processes should include a comparison with gas centrifuge processes, and should not be made independently from the plutonium isotope program; (2) in evaluating the various enrichment processes, all applicable costs (including R and D and sales overhead) and an appropriate discounting approach should be included in order to make comparisons on a private industry basis; (3) if the three AIS programs continue with limited resources, the work should be reoriented to focus only on the most pressing technical problems; and (4) if a decision is made to develop the Atomic Vapor Laser Isotope Separation process, the solid collector option should be pursued in parallel to alleviate the potential program impact of liquid collector thermal control problems.

  15. ISOTOPE FRACTIONATION PROCESS

    DOE Patents [OSTI]

    Clewett, G.H.; Lee, DeW.A.

    1958-05-20

    A new method is described for isotopic enrichment of uranium. It has been found that when an aqueous acidic solution of ionic tetravalent uraniunn is contacted with chelate complexed tetravalent uranium, the U/sup 238/ preferentially concentrates in the complexed phase while U/sup 235/ concentrates in the ionic phase. The effect is enhanced when the chelate compound is water insoluble and is dissolved in a water-immiscible organic solvent. Cupferron is one of a number of sultable complexing agents, and chloroform is a suitable organic solvent.

  16. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, F.T.

    Intermetallic compounds with the CaCu/sub 5/ type of crystal structure, particularly LaNiCo/sub 4/ and CaNi/sub 5/, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation column. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale multi-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen cn produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  17. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T.

    1981-01-01

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  18. Asphalt emulsion radon barrier systems for uranium mill tailings: an overview of the technology

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.; Freeman, H.D.; Gates, T.E.; Nelson, D.A.; Dunning, R.L.

    1984-03-01

    Pacific Northwest Laboratory (PNL), under contract to the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) office, has developed an asphalt emulsion cover system to reduce the release of radon from uranium mill tailings. The system has been field tested at Grand Junction, Colorado. Results from laboratory and field tests indicate that this system is effective in reducing radon release to near-background levels (<2.5 pCi m/sup -2/s/sup -1/) and has the properties required for long-term effectiveness and stability. Engineering specifications have been developed, and analysis indicates that asphalt emulsion covers are cost-competitive with other cover systems. This report summarizes the technology for asphalt emulsion radon barrier systems. 59 references, 45 figures, 36 tables.

  19. Radon in HUD assisted multifamily housing: Policy recommendations to the Congress

    SciTech Connect (OSTI)

    Not Available

    1991-04-01

    The report complies with Section 1091 of the Stewart B. McKinney Homeless Assistance Amendments Act of 1988 which requires that the HUD Secretary report to the Congress on a recommended policy for addressing radon contamination in specified housing. The housing specified in the Act is virtually all rental housing predominantly for low-income and moderate-income households. Almost all of it is multifamily housing: row houses, walk-up apartment buildings, or high-rise buildings. There is inadequate information on the extent to which excessive concentrations of radon occur above the first floor of multistory buildings and on the variation in radon concentrations in attached houses in the same row. HUD's recommended policy is in the four topic areas specified in the Act: research, education, testing, and mitigation.

  20. National Radon Database. Volume 4. The EPA/state residential radon surveys: CA, HI, ID, LA, NE, NV, NC, OK, SC, the Navajo Nation, and the Billings, MT IHS Area 1989-1990 (5 1/4 inch, 1. 2mb) (for microcomputers). Data file

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The National Radon Database (NRDB) was developed by the United States Environmental Protection Agency (USEPA) to distribute information in two recent radon surveys: the EPA/State Residential Radon Surveys and the National Residential Radon Survey. The National Residential Radon Surveys collected annual average radon measurements on all levels of approximately 5,700 homes nationwide. Information collected during survey includes a detailed questionnaire on house characteristics, as well as radon measurements. The radon survey data for Volume 6 is contained on two diskettes. The data diskettes are accompanied by comprehensive documentation on the design and implementation of the survey, the development and use of sampling weights, a summary of survey results, and information concerning the household questionnaire.

  1. National Radon Database. Volume 4. The EPA/state residential radon survey: CA, HI, ID, LA, NE, NV, NC, OK, SC, the Navajo Nation, and the Billings, MT IHS Area 1989-1990 (3 1/2 inch, 1. 44mb) (for microcomputers). Data file

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The National Radon Database (NRDB) was developed by the United States Environmental Protection Agency (USEPA) to distribute information in two recent radon surveys: the EPA/State Residential Radon Surveys and the National Residential Radon Survey. The National Residential Radon Surveys collected annual average radon measurements on all levels of approximately 5,700 homes nationwide. Information collected during survey includes a detailed questionnaire on house characteristics, as well as radon measurements. The radon survey data for Volume 6 is contained on two diskettes. The data diskettes are accompanied by comprehensive documentation on the design and implementation of the survey, the development and use of sampling weights, a summary of survey results, and information concerning the household questionnaire.

  2. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    This report contains a listing of electromagnetically separated stable isotopes which are available for distribution within the United States for non-destructive research use from the Oak Ridge National Laboratory on a loan basis. This inventory includes all samples of stable isotopes in the Materials Research Collection and does not designate whether a sample is out on loan or in reprocessing.

  3. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, Reed J.; Thorne, James M.; Cluff, Coran L.; Hayes, John K.

    1984-01-01

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)dichloroborane as the feed material. The photolysis can readily be achieved with CO.sub.2 laser radiation and using fluences significantly below those required to dissociate BCl.sub.3.

  4. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, R.J.; Thorne, J.M.; Cluff, C.L.

    1981-01-23

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)-dichloroborane as the feed material. The photolysis can readily by achieved with CO/sub 2/ laser radiation and using fluences significantly below those required to dissociate BCl/sub 3/.

  5. Heavy Isotopes Lead Materials Management Organization (LMMO)...

    Office of Scientific and Technical Information (OSTI)

    Heavy Isotopes Lead Materials Management Organization (LMMO) Update Citation Details In-Document Search Title: Heavy Isotopes Lead Materials Management Organization (LMMO) Update ...

  6. Isotopic Trends in Production of Superheavies

    SciTech Connect (OSTI)

    Antonenko, N.V.; Adamian, G.G.; Zubov, A.S.; Scheid, W.

    2005-11-21

    The isotopic trends are discussed for cold and hot fusion reactions leading to superheavies. The possibilities of production of new isotopes in incomplete fusion reactions are treated.

  7. Isotope separation by laser means

    DOE Patents [OSTI]

    Robinson, C. Paul; Jensen, Reed J.; Cotter, Theodore P.; Greiner, Norman R.; Boyer, Keith

    1982-06-15

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  8. Cost of radon-barrier systems for uranium mill tailings

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.

    1982-08-01

    This report deals specifically with the cost of three types of radon barrier systems, earthen covers, asphalt emulsion covers, and multilayer covers, which could meet standards proposed by the Environmental Protection Agency to stabilize uranium mill tailings located primarily in the western US. In addition, the report includes a sensitivity analysis of various factors which significantly effect the overall cost of the three systems. These analyses were based on a generic disposal site. Four different 3m thick earthen covers were tested and cost an average of $27/m/sup 2/. The least expensive earthen cover cost was about $21/m/sup 2/. The asphalt cover system (6 to 7 cm of asphalt topped with 0.6m of overburden) cost about $28/m/sup 2/. The four multilayer covers averaged $57/m/sup 2/, but materials handling problems encountered during the test inflated this cost above what was anticipated and significant cost reductions should be possible. The least expensive multilayer cover cost $43/m/sup 2/. Based on the results of the Grand Junction field test we estimated the cost of covering the tailings from three high priority sites, Durango, Shiprock, and Salt Lake City (Vitro). The cost of a 3m earthen cover ranged from $18 to 33/m/sup 2/ for the seven disposal sites (two or three at each location) studied. The cost of asphalt cover systems were $23 to 28/m/sup 2/ and the multilayer cover costs were between $31 to 36/m/sup 2/. The earthen cover costs are less than the Grand Junction field test cost primarily because cover material is available at or near most of the disposal sites selected. Earthen material was imported from 6 to 10 miles for the field test. Assuming more efficienct utilization of materials significantly reduced the cost of the multilayer covers.

  9. Container for hydrogen isotopes

    DOE Patents [OSTI]

    Solomon, David E.

    1977-01-01

    A container for the storage, shipping and dispensing of hydrogen isotopes such as hydrogen, deuterium, tritium, or mixtures of the same which has compactness, which is safe against fracture or accident, and which is reusable. The container consists of an outer housing with suitable inlet and outlet openings and electrical feed elements, the housing containing an activated sorber material in the form, for example, of titanium sponge or an activated zirconium aluminate cartridge. The gas to be stored is introduced into the chamber under conditions of heat and vacuum and will be retained in the sorber material. Subsequently, it may be released by heating the unit to drive off the stored gas at desired rates.

  10. Laser separation of medical isotopes

    SciTech Connect (OSTI)

    Eerkens, J.W.; Puglishi, D.A.; Miller, W.H.

    1996-12-31

    There is an increasing demand for different separated isotopes as feed material for reactor and cyclotron-produced radioisotopes used by a fast-growing radiopharmaceutical industry. One new technology that may meet future demands for medical isotopes is molecular laser isotope separation (MLIS). This method was investigated for the enrichment of uranium in the 1970`s and 1980s by Los Alamos National Laboratory, Isotope Technologies, and others around the world. While South Africa and Japan have continued the development of MLIS for uranium and are testing pilot units, around 1985 the United States dropped the LANL MLIS program in favor of AVLIS (atomic vapor LIS), which uses electron-beam-heated uranium metal vapor. AVLIS appears difficult and expensive to apply to most isotopes of medical interest, however, whereas MLIS technology, which is based on cooled hexafluorides or other gaseous molecules, can be adapted more readily. The attraction of MLIS for radiopharmaceutical firms is that it allows them to operate their own dedicated separators for small-quantity productions of critical medical isotopes, rather than having to depend on large enrichment complexes run by governments, which are only optimal for large-quantity productions. At the University of Missouri, the authors are investigating LIS of molybdenum isotopes using MoF{sub 6}, which behaves in a way similar to UF{sub 6}, studied in the past.

  11. AIR AND RADON PATHWAY MODELING FOR THE F AREA TANK FARM

    SciTech Connect (OSTI)

    Dixon, K.; Phifer, M.

    2010-07-30

    An air and radon pathways analysis was conducted for the F-Area Tank Farm (FTF) to estimate the flux of volatile radionuclides and radon at the ground surface due to residual waste remaining in the tanks following closure. This analysis was used as the basis to estimate the dose to the maximally exposed individual (MEI) for the air pathway per Curie (Ci) of each radionuclide remaining in the combined FTF waste tanks. For the air pathway analysis, several gaseous radionuclides were considered. These included carbon-14 (C-14), chlorine-36 (Cl-36), iodine-129 (I-129), selenium-79 (Se-79), antimony-125 (Sb-125), tin-126 (Sn-126), tritium (H-3), and technetium-99 (Tc-99). The dose to the MEI was estimated at the SRS Boundary during the 100 year institutional control period. For the 10,000 year post closure compliance period, the dose to the MEI was estimated at the 100 m compliance point. Additionally, the dose to the MEI was estimated at a seepage outcrop located 1600 m from the facility. For the radon pathway analysis, five parent radionuclides and their progeny were analyzed. These parent radionuclides included uranium-238 (U-238), plutonium-238 (Pu-238), uranium-234 (U-234), thorium-230 (Th-230), and radium-226 (Ra-226). The peak flux of radon-222 due to each parent radionuclide was estimated for the simulation period of 10,100 years.

  12. Four Years of Practical Arrangements between IAEA and Moscow SIA 'Radon': Preliminary Results - 13061

    SciTech Connect (OSTI)

    Batyukhnova, O.G.; Karlina, O.K.; Neveikin, P.P. [SUE SIA 'Radon', The 7-th Rostovsky Lane 2/14, Moscow, 119121 (Russian Federation)] [SUE SIA 'Radon', The 7-th Rostovsky Lane 2/14, Moscow, 119121 (Russian Federation)

    2013-07-01

    The International Education Training Centre (IETC) at Moscow State Unitary Enterprise Scientific and Industrial Association 'Radon' (SIA 'Radon'), in co-operation with the International Atomic Energy Agency (IAEA), has developed expertise and provided training to waste management personnel for the last 15 years. Since 1997, the educational system of the enterprise with the support of the IAEA has acquired an international character: more than 470 experts from 35 countries- IAEA Member States completed the professional development. Training is conducted at various thematic courses or fellowships for individual programs and seminars on IAEA technical projects. In June 2008 a direct agreement (Practical Arrangements) was signed between SIA 'Radon' and the IAEA on cooperation in the field of development of new technologies, expert's advice to IAEA Member States, and, in particular, the training of personnel in the field of radioactive waste management (RWM), which opens up new perspectives for fruitful cooperation of industry professionals. The paper summarizes the current experience of the SIA 'Radon' in the organization and implementation of the IAEA sponsored training and others events and outlines some of strategic educational elements, which IETC will continue to pursue in the coming years. (authors)

  13. Filter for on-line air monitor unaffected by radon progeny and method of using same

    DOE Patents [OSTI]

    Phillips, Terrance D.; Edwards, Howard D.

    1999-01-01

    An apparatus for testing air having contaminants and radon progeny therein. The apparatus includes a sampling box having an inlet for receiving the air and an outlet for discharging the air. The sampling box includes a filter made of a plate of sintered stainless steel. The filter traps the contaminants, yet allows at least a portion of the radon progeny to pass therethrough. A method of testing air having contaminants and radon progeny therein. The method includes providing a testing apparatus that has a sampling box with an inlet for receiving the air and an outlet for discharging the air, and has a sintered stainless steel filter disposed within said sampling box; drawing air from a source into the sampling box using a vacuum pump; passing the air through the filter; monitoring the contaminants trapped by the filter; and providing an alarm when a selected level of contaminants is reached. The filter traps the contaminants, yet allows at least a portion of the radon progeny to pass therethrough.

  14. Compelling Research Opportunities using Isotopes

    SciTech Connect (OSTI)

    2009-04-23

    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1) medicine, pharmaceuticals, and biology, (2) physical sciences and engineering, and (3) national security and other applications. In each area, compelling research opportunities were considered and the subcommittee as a whole determined the final priorities for research opportunities as the foundations for the recommendations. While it was challenging to prioritize across disciplines, our order of recommendations reflect the compelling research prioritization along with consideration of time urgency for action as well as various geopolitical market issues. Common observations to all areas of research include the needs for domestic availability of crucial stable and radioactive isotopes and the education of the skilled workforce that will develop new advances using isotopes in the future. The six recommendations of NSACI reflect these concerns and the compelling research opportunities for potential new discoveries. The science case for each of the recommendations is elaborated in the respective chapters.

  15. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This report contains a listing of electromagnetically separated stable isotopes which are available for distribution within the United States for non-destructive research use from the Oak Ridge National Laboratory on a loan basis. This inventory includes all samples of stable isotopes in the Materials Research Collection and does not designate whether a sample is out on loan or in reprocessing. For some of the high abundance naturally occurring isotopes, larger amounts can be made available; for example, Ca-40 and Fe-56.

  16. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1983-03-01

    This report contains a listing of electromagnetically separated stable isotopes which are available for distribution within the United States for non-destructive research use from the Oak Ridge National Laboratory on a loan basis. This inventory includes all samples of stable isotopes in the Materials Research Collection and does not designate whether a sample is out on loan or in reprocessing. For some of the high abundance naturally occurring isotopes, larger amounts can be made available; for example, Ca-40 and Fe-56.

  17. Method for laser induced isotope enrichment

    DOE Patents [OSTI]

    Pronko, Peter P.; Vanrompay, Paul A.; Zhang, Zhiyu

    2004-09-07

    Methods for separating isotopes or chemical species of an element and causing enrichment of a desired isotope or chemical species of an element utilizing laser ablation plasmas to modify or fabricate a material containing such isotopes or chemical species are provided. This invention may be used for a wide variety of materials which contain elements having different isotopes or chemical species.

  18. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  19. Raman scattering method and apparatus for measuring isotope ratios and isotopic abundances

    DOE Patents [OSTI]

    Harney, Robert C.; Bloom, Stewart D.

    1978-01-01

    Raman scattering is used to measure isotope ratios and/or isotopic abundances. A beam of quasi-monochromatic photons is directed onto the sample to be analyzed, and the resulting Raman-scattered photons are detected and counted for each isotopic species of interest. These photon counts are treated mathematically to yield the desired isotope ratios or isotopic abundances.

  20. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1985-02-01

    This report contains a listing of electromagnetically separated stable isotopes which are available at the Oak Ridge National Laboratory for distribution for non-destructive research use on a loan basis. This inventory includes all samples of stable isotopes in the Research Materials Collection and does not designate whether a sample is out on loan or is in reprocessing. For some of the high abundance naturally occurring isotopes, larger amounts can be made available; for example, /sup 40/Ca and /sup 56/Fe. All request for the loan of samples should be submitted with a summary of the purpose of the loan to: Isotope Distribution Office, Oak Ridge National Laboratory, P.O. Box X, Oak Ridge, Tennessee 37831. Requests from non-DOE contractors and from foreign institutions require DOE approval.

  1. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means. 3 figures.

  2. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, Jakob

    1991-01-01

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means.

  3. National Weatherization Assistance Program Impact Evaluation: Impact of Exhaust-Only Ventilation on Radon and Indoor Humidity - A Field Investigation

    SciTech Connect (OSTI)

    Pigg, Scott

    2014-09-01

    The study described here sought to assess the impact of exhaust-only ventilation on indoor radon and humidity in single-family homes that had been treated by the Weatherization Assistance Program (WAP).

  4. Isotope separation apparatus and method

    DOE Patents [OSTI]

    Feldman, Barry J.

    1985-01-01

    The invention relates to an improved method and apparatus for laser isotope separation by photodeflection. A molecular beam comprising at least two isotopes to be separated intersects, preferably substantially perpendicular to one broad side of the molecular beam, with a laser beam traveling in a first direction. The laser beam is reflected back through the molecular beam, preferably in a second direction essentially opposite to the first direction. Because the molecules in the beam occupy various degenerate energy levels, if the laser beam comprises chirped pulses comprising selected wavelengths, the laser beam will very efficiently excite substantially all unexcited molecules and will cause stimulated emission of substantially all excited molecules of a selected one of the isotopes in the beam which such pulses encounter. Excitation caused by first direction chirped pulses moves molecules of the isotope excited thereby in the first direction. Stimulated emission of excited molecules of the isotope is brought about by returning chirped pulses traveling in the second direction. Stimulated emission moves emitting molecules in a direction opposite to the photon emitted. Because emitted photons travel in the second direction, emitting molecules move in the first direction. Substantial molecular movement of essentially all the molecules containing the one isotope is accomplished by a large number of chirped pulse-molecule interactions. A beam corer collects the molecules in the resulting enriched divergent portions of the beam.

  5. Atomic line emission analyzer for hydrogen isotopes (Patent)...

    Office of Scientific and Technical Information (OSTI)

    Atomic line emission analyzer for hydrogen isotopes Title: Atomic line emission analyzer for hydrogen isotopes Apparatus for isotopic analysis of hydrogen comprises a low pressure ...

  6. Department of Energy's Isotope Development and Production for...

    Energy Savers [EERE]

    STATES DEPARTMENT OF ENERGY ISOTOPE DEVELOPMENT AND ... Program Overview The primary goal of the Isotope ... sources of research isotopes at more affordable prices. ...

  7. Isotope separation apparatus and method

    DOE Patents [OSTI]

    Cotter, Theodore P.

    1982-12-28

    The invention relates to a method and apparatus for laser isotope separation by photodeflection. A molecular beam comprising at least two isotopes to be separated intersects, preferable substantially perpendicular to one broad side of the molecular beam, with a laser beam traveling in a first direction. The laser beam is reflected back through the molecular beam, preferably in a second direction essentially opposite to the first direction. The laser beam comprises .pi.-pulses of a selected wavelength which excite unexcited molecules, or cause stimulated emission of excited molecules of one of the isotopes. Excitation caused by first direction .pi.-pulses moves molecules of the isotope excited thereby in the first direction. Stimulated emission of excited molecules of the isotope is brought about by returning .pi.-pulses traveling in the second direction. Stimulated emission moves emitting molecules in a direction opposite to the photon emitted. Because emitted photons travel in the second direction, emitting molecules move in the first direction. Substantial molecular movement is accomplished by a large number of .pi.-pulse-molecule interactions. A beam corer collects the molecules in the resulting enriched divergent portions of the beam.

  8. Isotope specific arbitrary material sorter

    DOE Patents [OSTI]

    Barty, Christopher P.J.

    2015-12-08

    A laser-based mono-energetic gamma-ray source is used to provide a rapid and unique, isotope specific method for sorting materials. The objects to be sorted are passed on a conveyor in front of a MEGa-ray beam which has been tuned to the nuclear resonance fluorescence transition of the desired material. As the material containing the desired isotope traverses the beam, a reduction in the transmitted MEGa-ray beam occurs. Alternately, the laser-based mono-energetic gamma-ray source is used to provide non-destructive and non-intrusive, quantitative determination of the absolute amount of a specific isotope contained within pipe as part of a moving fluid or quasi-fluid material stream.

  9. Stable isotope research pool inventory

    SciTech Connect (OSTI)

    Not Available

    1986-08-01

    This report contains a listing of electromagnetically separated stable isotopes which are available at the Oak Ridge National Laboratory for distribution for nondestructive research use on a loan basis. This inventory includes all samples of stable isotopes in the Research Materials Collection and does not designate whether a sample is out on loan or is in reprocessing. For some of the high-abundance, naturally occurring isotopes, larger amounts can be made available; for example, Ca-40 and Fe-56. All requests for the loan of samples should be submitted with a summary of the purpose of the loan to: Iotope Distribution Office, Oak Ridge National Laboratory, P.O. Box X, Oak Ridge, Tennessee 37831. Requests from non-DOE contractors and from foreign institutions require DOE approval.

  10. DOE/SC-ARM-15-027 Radon Measurements of Atmospheric Mixing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Radon Measurements of Atmospheric Mixing (RAMIX) 2006-2014 Final Campaign Summary ML Fischer SC Biraud A Hirsch May 2015 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

  11. Isotope geochronology of metamorphic processes

    SciTech Connect (OSTI)

    Ovchinnikov, L.N.; Voronovskiy, S.N.; Ovchinnikova, L.V.

    1986-05-01

    The long history of the earth and its crust is a history of uninterrupted and continuing transformation, making metamorphism the most common and most extensive geological process on this planet. Metamorphism has occurred in all epochs and is a factor in all endogenic processes: geodynamics, magmatism, and the action of intratelluric fluids. But it varies in scale, type, and mechanism, and is always combined with metasomatism - the chemical and mineral transformation of material. This paper discusses methodological principles of isotope dating, laws characterizing changes in indicator minerals, internal stability of isotopic systems, and interesting geological problems. 13 references.

  12. AVLIS enrichment of medical isotopes

    SciTech Connect (OSTI)

    Haynam, C.A.; Scheibner, K.F.; Stern, R.C.; Worden, E.F.

    1996-12-31

    Under the Sponsorship of the United states Enrichment Corporation (USEC), we are currently investigating the large scale separation of several isotopes of medical interest using atomic vapor isotope separation (AVLIS). This work includes analysis and experiments in the enrichment of thallium 203 as a precursor to the production of thallium 201 used in cardiac imaging following heart attacks, on the stripping of strontium 84 from natural strontium as precursor to the production of strontium 89, and on the stripping of lead 210 from lead used in integrated circuits to reduce the number of alpha particle induced logic errors.

  13. Radon exhalation rate from coal ashes and building materials in Italy

    SciTech Connect (OSTI)

    Battaglia, A.; Capra, D.; Queirazza, G.

    1992-12-31

    The Italian National Electricity Board, in cooperation with Centro Informazioni Stubi Esperienze (CISE) has a program to assess the hazards connected with using fly ash in civil applications as partial substitutes for cement and other building materials. We investigated the natural radioactivity levels of more than 200 building materials. The survey involved materials available in Italy, categorized by geographical location and type of production. We also examined approximately 100 samples of fly ash from United States and South African coal, obtained from Italian power plants. Exhalation rates from about 40 powdered materials were determined by continuously measuring radon concentration growth in closed containers. Measurements were also performed on whole bricks, slabs, and titles. Details about the high-sensitivity measuring devices are presented. The influence of fly ash on exhalation rates was investigated by accurately measuring radon emanation from slabs with various ash/cement ratios and with slabs of inert materials having various radium concentrations. We will discuss results of forecasting indoor radon concentrations under different ventilation conditions. Two identical test rooms are being built, one with conventional and one with fly-ash building materials, to compare theoretical calculations with experimental data. Specifications for instruments to control and to measure the most important parameters are also discussed.

  14. Radon emanation from giant landslides of Koefels (Tyrol, Austria) and Langtang Himal (Nepal)

    SciTech Connect (OSTI)

    Purtscheller, F.; Pirchl, T.; Sieder, G.

    1995-07-01

    The identification of extremely high indoor radon concentrations in the village Umhausen (Tyrol, Austria) initiated a scientific program to get information about the source and distribution of this noble gas. The high concentrations can not be related to U anomalies or large-scale fault zones. The nearby giant landslide of Koefels, with its highly fractured and crushed orthogneisses, are the only possible source of radon, despite the fact that the U and Ra content of the rocks is by no means exceptional. The reasons for the high emanation rates from the landslide are discussed and compared to results gained from a similar examination of the giant landslide of Langtang Himal (Nepal). The exceptional geologic situation in both cases, as well as the spatial distribution of different concentration levels, indicate that both landslides must be considered as the production sites of radon. Independent of the U and Ra contents of the rocks, the most important factors producing high emanation rates are the production of a high active surface area in circulation pathways for Rn-enriched soil air by brittle deformation due to the impact of the landslidemass. 37 refs., 4 figs., 1 tab.

  15. U.S. Postal Service radon assessment and mitigation program. Progress report, September 1993--November 1994

    SciTech Connect (OSTI)

    Velazquez, L.E.; Petty, J.L. Jr.

    1994-12-31

    In 1992, the US Postal Service (USPS) entered into an Interagency Agreement with the Department of Energy (DOE) whereby DOE would provide technical assistance in support of the USPS Radon Assessment and Mitigation Program. To aid in this effort, DOE tasked the Hazardous Waste Remedial Actions Program (HAZWRAP), which is managed by Martin Marietta Energy Systems, Inc., for DOE under contract AC05-84OR21400. Since that time, HAZWRAP has developed and finalized the sampling protocol, mitigation diagnostic protocol, and the quality assurance and quality control procedures. These procedures were validated during the Protocol Validation (1992-1993) and Pilot Study (1993-1994) phases of the program. To date, HAZWRAP has performed approximately 16,000 radon measurements in 250 USPS buildings. Mitigation diagnostics have been performed in 27 buildings. Thus far, 13% of the measurements have been above the Environmental Protection Agency action level of 4 pCi/L. This report summarizes the pilot program radon testing data and mitigation diagnostic data for 22 sites and contains recommendations for mitigation diagnostics.

  16. Analysis of electret ion chamber radon detector response to {sup 222}Rn and interference from background gamma radiation

    SciTech Connect (OSTI)

    Usman, S.; Spitz, H.; Lee, S.

    1999-01-01

    Environmental radon ({sup 222}Rn) monitors that incorporate electret detectors are confounded by background gamma radiation, which may cause the electret to discharge by as much as 7.5 volts per mR. Although background gamma corrections were formerly made by multiplying the known background gamma exposure rate with a constant conversion factor, this research demonstrates that doing so introduces an error ranging up to about 20%, especially in high gamma background areas. A new, more accurate method of background gamma correction has been developed that uses an average, voltage-dependent discharge factor, D{sub {gamma}} (V Kg C{sup {minus}1}). This factor and its coefficients were experimentally determined by separately exposing groups of electret radon detectors to photons from {sup 60}Co and {sup 137}Cs. Statistical analysis shows that D{sub {gamma}} is independent of the orientation of the electret during irradiation but that some dependency on dose rate or energy of the irradiating photons may be expected. The discharge of the electret due only to gamma irradiation, V{sub {gamma}}, is determined by multiplying the total integrated gamma exposure by D{sub {gamma}}. The discharge of the electret during a radon measurement can then be corrected for background gamma radiation by subtracting V{sub {gamma}} from the total discharge of the electret resulting in a net discharge due solely to radon. A new equation has also been developed in this study for the radon discharge factor, D{sub Rn} (V m{sup 3}Bq{sup {minus}1} s{sup {minus}1}), that is entirely consistent with the gamma discharge radon detectors to known concentrations of radon.

  17. Isotope separation by photochromatography (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    The method is particularly applicable to the separation of hydrogen isotopes. Authors: ... particularly; applicable; separation; hydrogen; isotopes; excited molecules; hydrogen ...

  18. Online Catalog of Isotope Products from DOE's National Isotope Development Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. The Isotope subprogram supports the production, and the development of production techniques of radioactive and stable isotopes that are in short supply for research and applications. Isotopes are high-priority commodities of strategic importance for the Nation and are essential for energy, medical, and national security applications and for basic research; a goal of the program is to make critical isotopes more readily available to meet domestic U.S. needs. This subprogram is steward of the Isotope Production Facility (IPF) at Los Alamos National Laboratory (LANL), the Brookhaven Linear Isotope Producer (BLIP) facility at BNL, and hot cell facilities for processing isotopes at ORNL, BNL and LANL. The subprogram also coordinates and supports isotope production at a suite of university, national laboratory, and commercial accelerator and reactor facilities throughout the Nation to promote a reliable supply of domestic isotopes. The National Isotope Development Center (NIDC) at ORNL coordinates isotope production across the many facilities and manages the business operations of the sale and distribution of isotopes.

  19. Isotopes for cancer and cardiac care

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes for cancer Isotopes for cancer and cardiac care Eva Birnbaum is interviewed on KSFR radio on the Lab's Isotope Program February 4, 2016 hot cell facility A worker uses remote manipulator arms to handle a highly radioactive target inside the Lab's radiochemistry hot cell facility. Isotopes from Los Alamos are used for the diagnosis of cardiac disease, for the calibration of PET scanners which in turn diagnose cancer, neurological disease, inflammatory diseases, trauma, and other

  20. Science with Beams of Radioactive Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pacifichem 2015 Pacifichem 2015 The International Chemical Congress of Pacific Basin Societies Science with Beams of Radioactive Isotopes (# 340) Honolulu, Hawaii, USA December 15-20, 2015 Science with Beams of Radioactive Isotopes (# 340) All of the elements that make up the periodic chart have been created from nuclear reactions. Many of the stable nuclei in the universe are daughters of unstable isotopes, and their true origin lies in the stellar reactions of these radioactive isotopes. Thus

  1. Dry phase reactor for generating medical isotopes

    DOE Patents [OSTI]

    Mackie, Thomas Rockwell; Heltemes, Thad Alexander

    2016-05-03

    An apparatus for generating medical isotopes provides for the irradiation of dry-phase, granular uranium compounds which are then dissolved in a solvent for separation of the medical isotope from the irradiated compound. Once the medical isotope is removed, the dissolved compound may be reconstituted in dry granular form for repeated irradiation.

  2. Isotope Cancer Treatment Research at LANL

    ScienceCinema (OSTI)

    Weidner, John; Nortier, Meiring

    2014-06-02

    Los Alamos National Laboratory has produced medical isotopes for diagnostic and imaging purposes for more than 30 years. Now LANL researchers have branched out into isotope cancer treatment studies. New results show that an accelerator-based approach can produce clinical trial quantities of actinium-225, an isotope that has promise as a way to kill tumors without damaging surrounding healthy cells.

  3. Assessment of inhalation and ingestion doses from exposure to radon gas using passive and active detecting techniques

    SciTech Connect (OSTI)

    Ismail, A. H.; Jafaar, M. S.

    2011-07-01

    The aim of this study was to assess an environmental hazard of radon exhalation rate from the samples of soil and drinking water in selected locations in Iraqi Kurdistan, passive (CR-39NTDs) and active (RAD7) detecting techniques has been employed. Long and short term measurements of emitted radon concentrations were estimated for 124 houses. High and lower radon concentration in soil samples was in the cities of Hajyawa and Er. Tyrawa, respectively. Moreover, for drinking water, high and low radon concentration was in the cities of Similan and Kelak, respectively. A comparison between our results with that mentioned in international reports had been done. Average annual dose equivalent to the bronchial epithelium, stomach and whole body in the cities of Kelak and Similan are estimated, and it was varied from 0.04{+-}0.01 mSv to 0.547{+-}0.018 mSv, (2.832{+-}0.22)x10{sup -5} to (11.972{+-}2.09)x10{sup -5} mSv, and (0.056 {+-}0.01) x10{sup -5} to (0.239{+-}0.01)x10{sup -5} mSv, respectively. This indicated that the effects of dissolved radon on the bronchial epithelium are much than on the stomach and whole body. (authors)

  4. S. 2844: A Bill to provide for radon testing. Introduced in the Senate of the United States, One Hundredth Congress, Second Session, September 29, 1988

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    Bill S. 2844 provides for radon testing and is cited as the Department of Housing and Urban Development Policy Act. The bill provides the Department of Housing and Urban Development (HUD) with a mandate to establish a departmental radon policy and program. The department will be required to use its programs to assist the Environmental Protection Agency (EPA) address radon contamination. The bill also requires HUD, in coordination with the EPA, to develop a radon assessment and mitigation program which utilizes EPA recommended guidelines and standards to ensure that occupants of housing covered under this act are not exposed to elevated levels of radon. The entire contents of the bill are presented in eight sections entitled: Short Title, findings, Purpose, Definitions, Program, Information, Cooperation with Environmental Protection Agency, and Authorization. The bill was referred to the Committee on Banking, Housing and Urban Affairs.

  5. Measuring SNM Isotopic Distributions using FRAM

    SciTech Connect (OSTI)

    Geist, William H.

    2015-12-02

    The first group of slides provides background information on the isotopic composition of plutonium. It is shown that 240Pu is the critical isotope in neutron coincidence/multiplicity counting. Next, response function analysis to determine isotopic composition is discussed. The isotopic composition can be determined by measuring the net peak counts from each isotope and then taking the ratio of the counts for each isotope relative to the total counts for the element. Then FRAM (Fixed energy Response function Analysis with Multiple efficiencies) is explained. FRAM can control data acquisition, automatically analyze newly acquired data, analyze previously acquired data, provide information on the quality of the analysis, and facilitate analysis in unusual situations (non-standard energy calibrations, gamma rays from non-SNM isotopes, poor spectra (within limits)).

  6. Isotope hydrology of catchment basins: lithogenic and cosmogenic isotopic systems

    SciTech Connect (OSTI)

    Nimz, G. J., LLNL

    1998-06-01

    A variety of physical processes affect solute concentrations within catchment waters. The isotopic compositions of the solutes can indicate which processes have determined the observed concentrations. These processes together constitute the physical history of the water. Many solutes in natural waters are derived from the interaction between the water and the rock and/or soil within the system - these are termed `lithogenic` solutes. The isotopic compositions of these solutes provide information regarding rock-water interactions. Many other solutes have their isotopic compositions determined both within and outside of the catchment - i.e., in addition to being derived from catchment rock and soil, they are solutes that are also transported into the catchment. Important members of this group include solutes that have isotopic compositions produced by atomic particle interactions with other nuclides. The source of the atomic particles can be cosmic radiation (producing `cosmogenic` nuclides in the atmosphere and land surface), anthropogenic nuclear reactions (producing `thermonuclear` nuclides), or radioactive and fission decay of naturally-occurring elements, principally {sup 238}U (producing `in-situ` lithogenic nuclides in the deep subsurface). Current language usage often combines all of the atomic particle-produced nuclides under the heading `cosmogenic nuclides`, and for simplicity we will often follow that usage here, although always indicating which variety is being discussed. This paper addresses the processes that affect the lithogenic and cosmogenic solute concentrations in catchment waters, and how the isotopic compositions of the solutes can be used in integrative ways to identify these processes, thereby revealing the physical history of the water within a catchment system. The concept of a `system` is important in catchment hydrology. A catchment is the smallest landscape unit that can both participate in all of the aspects of the hydrologic cycle and also be treated as a mostly closed system for mass balance considerations. It is the near closure of the system that permits well- constrained chemical mass balance calculations to be made. These calculations generally focus of lithogenic solutes, and therefore in our discussions of lithogenic nuclides in the paper, the concept of chemical mass balance in a nearly dosed system will play an important role. Examination of the isotopic compositions of solutes provides a better understanding of the variety of processes controlling mass balance. It is with this approach that we examined the variety of processes occurring within the catchment system, such as weathering and soil production, generation of stormflow and streamflow (hydrograph separation), movement of soil pore water, groundwater flow, and the overall processes involved with basinal water balance. In this paper, the term `nuclide` will be used when referring to a nuclear species that contains a particular number of protons and neutrons. The term is not specific to any element. The term `isotope` will be used to distinguish nuclear species of a given element (atoms with the same number of protons). That is to say, there are many nuclides in nature - for example, {sup 36}Cl, {sup 87}Sr, {sup 238}U; the element has four naturally-occurring isotopes - {sup 87}Sr, and {sup 88}Sr. This paper will first discuss the general principles that underlie the study of lithogenic and cosmogenic nuclides in hydrology, and provide references to some of the more important studies applying these principles and nuclides. We then turn in the second section to a discussion of their specific applications in catchment- scale systems. The final section of this paper discusses new directions in the application of lithogenic and cosmogenic nuclides to catchment hydrology, with some thoughts concerning possible applications that still remain unexplored.

  7. Laser ablation molecular isotopic spectrometry of carbon isotopes

    SciTech Connect (OSTI)

    Bol'shakov, Alexander A.; Jain, Jinesh; Russo, Richard E.; McIntyre, Dustin; Mao, Xianglei

    2015-08-28

    Quantitative determination of carbon isotopes using Laser Ablation Molecular Isotopic Spectrometry (LAMIS) is described. Optical emission of diatomic molecules CN and C2 is used in these measurements. Two quantification approaches are presented:empirical calibration of spectra using a set of reference standards and numerical fitting of a simulated spectrum to the experimental one. Formation mechanisms of C2 and CN in laser ablation plasma are briefly reviewed to provide insights for implementation of LAMIS measurements. A simulated spectrum of the 12C2 Swan system was synthesized using four constituents within 473.5–476.5 nm. Simulation included three branches of 12C2 (1-0), branches R(0-0) and R(1-1), and branch P(9-8) of 12C2. Spectral positions of the tail lines in R(0-0) and R(1-1) were experimentally measured, since they were not accurately known before. The Swan band (1-0) of the isotopologue 13C12C was also simulated. Fitting to the experimental spectrumyielded the ratio 13C/12C = 1.08% in a good agreement with measurements by isotope ratio mass spectrometry. LAMIS promises to be useful in coal, oil and shale exploration, carbon sequestration monitoring, and agronomy studies

  8. Determination of radon concentration in water using RAD7 with RAD H{sub 2}O accessories

    SciTech Connect (OSTI)

    Malik, M. F. I.; Rabaiee, N. A.; Jaafar, M. S.

    2015-04-24

    In the last decade, the radon issue has become one of the major problems of radiation protection. Radon exposure occurs when using water for showering, washing dishes, cooking and drinking water. RAD7 and Rad H20 accessories were used in order to measure radon concentration in water sample. In this study, four types of water were concerns which are reverse osmosis (drinking water), mineral water, tap water and well water. Reverse osmosis (drinking water) and mineral water were bought from the nearest supermarket while tap water and well water were taken from selected areas of Pulau Pinang and Kedah. Total 20 samples were taken with 5 samples for each type of water. The measured radon concentration ranged from 2.9±2.9 to 79.5±17 pCi/L, 2.9±2.9 to 67.8±16 pCi/L, 15.97±7 to 144.25±24 pCi/L and 374.89±37 to 6409.03±130 pCi/L in reverse osmosis (drinking water), mineral water, tap water and well water. Well water has the highest radon compared to others. It was due to their geological element such as granite. Results for all types of water are presented and compared with maximum contamination limit (MCL) recommended by United State Environmental Protection Agency (USEPA) which is 300pCi/L. Reverse osmosis water, mineral water and tap water were fall below MCL. However, well water was exceeded maximum level that was recommended. Thus, these findings were suggested that an action should be taken to reduce radon concentration level in well water as well as reduce a health risk towards the public.

  9. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel

    1994-01-01

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  10. AIR AND RADON PATHWAY MODELING FOR THE F-AREA TANK FARM

    SciTech Connect (OSTI)

    Dixon, K; Mark Phifer, M

    2007-09-17

    The F-Area Tank Farm (FTF) is located within F-Area in the General Separations Area (GSA) of the Savannah River Site (SRS) as seen in Figure 1. The GSA contains the F and H Area Separations Facilities, the S-Area Defense Waste Processing Facility, the Z-Area Saltstone Facility, and the E-Area Low-Level Waste Disposal Facilities. The FTF is a nearly rectangular shaped area and comprises approximately 20 acres, which is bounded by SRS coordinates N 76,604.5 to N 77,560.0 and E 52,435.0 to E 53,369.0. SRS is in the process of preparing a Performance Assessment (PA) to support FTF closure. As part of the PA process, an analysis was conducted to evaluate the potential magnitude of gaseous release of radionuclides from the FTF over the 100-year institutional control period and 10,000-year post-closure compliance period. Specifically, an air and radon pathways analysis has been conducted to estimate the flux of volatile radionuclides and radon at the ground surface due to residual waste remaining in the tanks following closure. This analysis was used as the basis to estimate the dose to the maximally exposed individual (MEI) for the air pathway per Curie (Ci) of each radionuclide remaining in the combined FTF waste tanks. For the air pathway analysis, several gaseous radionuclides were considered. These included carbon-14 (C-14), chlorine-36 (Cl-36), iodine-129 (I-129), selenium-79 (Se-79), antimony-125 (Sb-125), tin-126 (Sn-126), tritium (H-3), and technetium-99 (Tc-99). The dose to the MEI was estimated at the SRS Boundary during the 100 year institutional control period. For the 10,000 year post closure compliance period, the dose to the MEI was estimated at the 100 m compliance point. For the radon pathway analysis, five parent radionuclides and their progeny were analyzed. These parent radionuclides included uranium-238 (U-238), plutonium-238 (Pu-238), uranium-234 (U-234), thorium-230 (Th-230), and radium-226 (Ra-226). The peak flux of radon-222 due to each parent radionuclide was estimated for the simulation period of 10,100 years.

  11. Evaluation of radon progeny from Mount St. Helens eruptions. Final report

    SciTech Connect (OSTI)

    Lepel, E.A.; Olsen, K.B.; Thomas, V.W.; Eichner, F.N.

    1982-09-01

    A network of twelve monitoring sites around Mount St. Helens was established to evaluate possible short-lived radioactivity in the fallen ash. Seven sites were located near major population centers of Washington and Oregon, and five sites were located within 80 km of the volcano. Each site monitored the radioactivity present by the use of thermoluminescent dosimeters which recorded the total exposure to radioactivity over the exposure period. Eruptions occurring on July 22, August 7, and October 16 to 18, 1980 were monitored. No statistically significant quantities of measurable radon daughters were observed.

  12. Stable Isotope Enrichment Capabilities at ORNL

    SciTech Connect (OSTI)

    Egle, Brian; Aaron, W Scott; Hart, Kevin J

    2013-01-01

    The Oak Ridge National Laboratory (ORNL) and the US Department of Energy Nuclear Physics Program have built a high-resolution Electromagnetic Isotope Separator (EMIS) as a prototype for reestablishing a US based enrichment capability for stable isotopes. ORNL has over 60 years of experience providing enriched stable isotopes and related technical services to the international accelerator target community, as well as medical, research, industrial, national security, and other communities. ORNL is investigating the combined use of electromagnetic and gas centrifuge isotope separation technologies to provide research quantities (milligram to several kilograms) of enriched stable isotopes. In preparation for implementing a larger scale production facility, a 10 mA high-resolution EMIS prototype has been built and tested. Initial testing of the device has simultaneously collected greater than 98% enriched samples of all the molybdenum isotopes from natural abundance feedstock.

  13. METHOD AND APPARATUS FOR COLLECTING ISOTOPES

    DOE Patents [OSTI]

    Leyshon, W.E.

    1957-08-01

    A method and apparatus for collecting isotopes having a high vapor pressure, such as isotopes of mercury, in a calutron are described. Heretofore, the collected material would vaporize and escape from the ion receiver as fast as it was received. By making the receiver of pure silver, the mercury isotopes form a nonvolatile amalgam with the silver at the water cooled temperature of the receiver, and the mercury is thus retained.

  14. EIS-0249: Medical Isotopes Production Project

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impacts of a proposal to establish a production capability for molybdenum-99 (Mo-99) and related medical isotopes.

  15. Categorical Exclusion 4577: Lithium Isotope Separation & Enrichment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Isotope Separation & Enrichment Technologies (4577) Program or Field Office: Y-12 Site Office Location(s) (CityCountyState): Oak Ridge, Anderson County, Tennessee...

  16. Isotope production agreement benefits medical patients | National...

    National Nuclear Security Administration (NNSA)

    Francis Tsang of Global Medical Isotope Systems (GMIS), Dr. Chris Deeney of National Security Technologies (NSTec), and Zane Wilson, Chief Executive Officer of GMIS, observe the ...

  17. Nitrogen concentration and isotope dataset for environmental...

    Office of Scientific and Technical Information (OSTI)

    (BER) Country of Publication: United States Availability: ORNL Language: English Subject: 54 Environmental Sciences ngee; ngee-arctic; nitrate concentrations; nitrate isotopes; ...

  18. Method for isotope enrichment by photoinduced chemiionization

    DOE Patents [OSTI]

    Dubrin, James W.

    1985-01-01

    Isotope enrichment, particularly .sup.235 U enrichment, is achieved by irradiating an isotopically mixed vapor feed with radiant energy at a wavelength or wavelengths chosen to selectively excite the species containing a desired isotope to a predetermined energy level. The vapor feed if simultaneously reacted with an atomic or molecular reactant species capable of preferentially transforming the excited species into an ionic product by a chemiionization reaction. The ionic product, enriched in the desired isotope, is electrostatically or electromagnetically extracted from the reaction system.

  19. Uranium isotopes fingerprint biotic reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U),more » i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.« less

  20. Uranium isotopes fingerprint biotic reduction

    SciTech Connect (OSTI)

    Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J.; Weyer, Stefan; Bernier-Latmani, Rizlan

    2015-04-20

    Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U), i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.

  1. Nationwide occurrence of radon and other natural radioactivity in public water supplies

    SciTech Connect (OSTI)

    Horton, T. R.

    1985-10-01

    The nationwide study, which began in November of 1980, was designed to systematically sample water supplies in all 48 contiguous states. The results of the study will be used, in cooperation with EPA's Office of Drinking Water, to estimate population exposures nationwide and to support possible future standards for radon, uranium, and other natural radioactivity in public water supplies. Samples from more than 2500 public water supplies representing 35 states were collected. Although we sampled only about five percent of the total number of groundwater supplies in the 48 contiguous states of the US, those samples represent nearly 45 percent of the water consumed by US groundwater users in the 48 contiguous states. Sample results are summarized by arithmetic mean, geometric mean, and population weighted arithmetic mean for each state and the entire US. Results include radon, gross alpha, gross beta, Ra-226, Ra-228, total Ra, U-234, U-238, total U, and U-234/U-238 ratios. Individual public water supply results are found in the appendices. 24 refs., 91 figs., 51 tabs.

  2. Control of contamination of radon-daughters in the DEAP-3600 acrylic vessel

    SciTech Connect (OSTI)

    Jillings, Chris; Collaboration: DEAP Collaboration; and others

    2013-08-08

    DEAP-3600 is a 3600kg single-phase liquid-argon dark matter detector under construction at SNOLAB with a sensitivity of 10{sup ?46}cm{sup 2} for a 100 GeV WIMP. The argon is held an an acrylic vessel coated with wavelength-shifting 1,1,4,4-tetraphenyl-1,3-butadiene (TPB). Acrylic was chosen because it is optically transparent at the shifted wavelength of 420 nm; an effective neutron shield; and physically strong. With perfect cleaning of the acrylic surface before data taking the irreducible background is that from bulk {sup 210}Pb activity that is near the surface. To achieve a background rate of 0.01 events in the 1000-kg fiducial volume per year of exposure, the allowed limit of Pb-210 in the bulk acrylic is 31 mBq/tonne (= 1.2 10{sup ?20}g/g). We discuss how pure acrylic was procured and manufactured into a complete vessel paying particular attention to exposure to radon during all processes. In particular field work at the acrylic panel manufacturer, RPT Asia, and acrylic monomer supplier, Thai MMA Co. Ltd, in Thailand is described. The increased diffusion of radon during annealing the acrylic at 90C as well as techniques to mitigate against this are described.

  3. Hydrogen-isotope permeation barrier

    DOE Patents [OSTI]

    Maroni, Victor A.; Van Deventer, Erven H.

    1977-01-01

    A composite including a plurality of metal layers has a Cu-Al-Fe bronze layer and at least one outer layer of a heat and corrosion resistant metal alloy. The bronze layer is ordinarily intermediate two outer layers of metal such as austenitic stainless steel, nickel alloys or alloys of the refractory metals. The composite provides a barrier to hydrogen isotopes, particularly tritium that can reduce permeation by at least about 30 fold and possibly more below permeation through equal thicknesses of the outer layer material.

  4. Spatial periphery of lithium isotopes

    SciTech Connect (OSTI)

    Galanina, L. I. Zelenskaja, N. S.

    2013-12-15

    The spatial structure of lithium isotopes is studied with the aid of the charge-exchange and (t, p) reactions on lithium nuclei. It is shown that an excited isobaric-analog state of {sup 6}Li (0{sup +}, 3.56MeV) has a halo structure formed by a proton and a neutron, that, in the {sup 9}Li nucleus, there is virtually no neutron halo, and that {sup 11}Li is a Borromean nucleus formed by a {sup 9}Li core and a two-neutron halo manifesting itself in cigar-like and dineutron configurations.

  5. Uranium molecular laser isotope separation

    SciTech Connect (OSTI)

    Jensen, R.J.; Sullivan, A.

    1982-01-01

    The Molecular Laser Isotope Separation program is moving into the engineering phase, and it is possible to determine in some detail the plant cost terms involved in the process economics. A brief description of the MLIS process physics is given as a motivation to the engineering and economics discussion. Much of the plant cost arises from lasers and the overall optical system. In the paper, the authors discuss lasers as operating units and systems, along with temporal multiplexing and Raman shifting. Estimates of plant laser costs are given.

  6. Study of the atmospheric chemistry of radon progeny in laboratory and real indoor atmospheres. Final project report

    SciTech Connect (OSTI)

    Hopke, P.K.

    1996-09-01

    This report completes Clarkson University`s study of the chemical and physical behavior of the {sup 218}Po atom immediately following its formation by the alpha decay of radon. Because small changes in size for activity in the sub-10 nm size range result in large changes in the delivered dose per unit exposure, this behavior must be understood if the exposure to radon progeny and it dose to the cells in the respiratory tract are to be fully assessed. In order to pursue this general goal, two areas of radon progeny behavior are being pursued; laboratory studies under controlled conditions to better understand the fundamental physical and chemical processes that affect the progeny`s atmospheric behavior and studies in actual indoor environments to develop a better assessment of the exposure of the occupants of that space to the size and concentration of the indoor radioactive aerosol. Thus, two sets of specific goals have been established for this project. The specific tasks of the controlled laboratory studies are (1) Determine the formation rates of {circ}OH radicals formed by the radiolysis of air following radon decay; (2) Examine the formation of particles by the radiolytic oxidation of substances like SO{sub 2}, ethylene, and H{sub 2}S to lower vapor pressure compounds and determine the role of gas phase additives such as H{sub 2}O and NH{sub 3} in determining the particle size; (3) Measure the rate of ion-induced nucleation using a thermal diffusion cloud chamber, and (4) Measure the neutralization rate of {sup 218}PoO{sub x}{sup +} in O{sub 2} at low radon concentrations.

  7. Final Report, NEAC Subcommittee for Isotope Research & Production Planning

    Energy Savers [EERE]

    | Department of Energy Final Report, NEAC Subcommittee for Isotope Research & Production Planning Final Report, NEAC Subcommittee for Isotope Research & Production Planning Isotopes, including both radioactive and stable isotopes, make important contributions to research, medicine, and industry in the United States and throughout the world. For nearly fifty years, the Department of Energy (DOE) has actively promoted the use of isotopes by funding (a) production of isotopes at a

  8. Isotope separation by selective photodissociation of glyoxal

    DOE Patents [OSTI]

    Marling, John B.

    1976-01-01

    Dissociation products, mainly formaldehyde and carbon monoxide, enriched in a desired isotope of carbon, oxygen, or hydrogen are obtained by the selective photodissociation of glyoxal wherein glyoxal is subjected to electromagnetic radiation of a predetermined wavelength such that photon absorption excites and induces dissociation of only those molecules of glyoxal containing the desired isotope.

  9. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    SciTech Connect (OSTI)

    Chastagner, P.

    2001-08-01

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  10. Efficient palladium isotope chromatograph for hydrogen (EPIC)

    SciTech Connect (OSTI)

    Embury, M.C.; Ellefson, R.E.; Melke, H.B. )

    1992-03-01

    The Efficient Palladium Isotope Chromatograph (EPIC) is a rapid cycling, computer-operated displacement chromatograph for the separation of hydrogen isotopes. EPIC incorporates several features that optimize product throughput and purity. This paper describes this palladium displacement chromatograph, the operations with protium and deuterium, and the design modifications for operation with tritium.

  11. Permeation of Multiple Isotopes in the Transition Between Surface...

    Office of Environmental Management (EM)

    Permeation of Multiple Isotopes in the Transition Between Surface- and Diffusion-Limited Regimes Permeation of Multiple Isotopes in the Transition Between Surface- and...

  12. Isotopic Analysis At Fenton Hill Hdr Geothermal Area (Goff, Et...

    Open Energy Info (EERE)

    Isotopic Analysis At Fenton Hill Hdr Geothermal Area (Goff, Et Al., 1981) Redirect page Jump to: navigation, search REDIRECT Isotopic Analysis- Fluid At Fenton Hill Hdr Geothermal...

  13. Manus Water Isotope Investigation Field Campaign Report (Program...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Program Document: Manus Water Isotope Investigation Field Campaign Report Citation Details In-Document Search Title: Manus Water Isotope ...

  14. Plutonium Isotopes in the Terrestrial Environment at the Savannah...

    Office of Scientific and Technical Information (OSTI)

    Plutonium Isotopes in the Terrestrial Environment at the Savannah River Site, USA. A Long-Term Study Citation Details In-Document Search Title: Plutonium Isotopes in the ...

  15. Advances in Hydrogen Isotope Separation Using Thermal Cycling...

    Office of Environmental Management (EM)

    Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Presentation...

  16. Selected Isotopes for Optimized Fuel Assembly Tags

    SciTech Connect (OSTI)

    Gerlach, David C.; Mitchell, Mark R.; Reid, Bruce D.; Gesh, Christopher J.; Hurley, David E.

    2008-10-01

    In support of our ongoing signatures project we present information on 3 isotopes selected for possible application in optimized tags that could be applied to fuel assemblies to provide an objective measure of burnup. 1. Important factors for an optimized tag are compatibility with the reactor environment (corrosion resistance), low radioactive activation, at least 2 stable isotopes, moderate neutron absorption cross-section, which gives significant changes in isotope ratios over typical fuel assembly irradiation levels, and ease of measurement in the SIMS machine 2. From the candidate isotopes presented in the 3rd FY 08 Quarterly Report, the most promising appear to be Titanium, Hafnium, and Platinum. The other candidate isotopes (Iron, Tungsten, exhibited inadequate corrosion resistance and/or had neutron capture cross-sections either too high or too low for the burnup range of interest.

  17. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D.; Sander, Robert K.

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  18. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, K.F.; Haynam, C.A.; Johnson, M.A.; Worden, E.F.

    1999-08-31

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207. 5 figs.

  19. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, Karl F.; Haynam, Christopher A.; Johnson, Michael A.; Worden, Earl F.

    1999-01-01

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207.

  20. Apparatus for storing hydrogen isotopes

    DOE Patents [OSTI]

    McMullen, John W.; Wheeler, Michael G.; Cullingford, Hatice S.; Sherman, Robert H.

    1985-01-01

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas(es) is (are) stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forming at a significantly lower temperature).

  1. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  2. Isotope separation by photoselective dissociative electron capture

    DOE Patents [OSTI]

    Stevens, Charles G. [Pleasanton, CA

    1978-08-29

    A method of separating isotopes based on photoselective electron capture dissociation of molecules having an electron capture cross section dependence on the vibrational state of the molecule. A molecular isotope source material is irradiated to selectively excite those molecules containing a desired isotope to a predetermined vibrational state having associated therewith an electron capture energy region substantially non-overlapping with the electron capture energy ranges associated with the lowest vibration states of the molecules. The isotope source is also subjected to electrons having an energy corresponding to the non-overlapping electron capture region whereby the selectively excited molecules preferentially capture electrons and dissociate into negative ions and neutrals. The desired isotope may be in the negative ion product or in the neutral product depending upon the mechanism of dissociation of the particular isotope source used. The dissociation product enriched in the desired isotope is then separated from the reaction system by conventional means. Specifically, .sup.235 UF.sub.6 is separated from a UF.sub.6 mixture by selective excitation followed by dissociative electron capture into .sup.235 UF.sub.5 - and F.

  3. Isotope separation by photoselective dissociative electron capture

    DOE Patents [OSTI]

    Stevens, C.G.

    1978-08-29

    Disclosed is a method of separating isotopes based on photoselective electron capture dissociation of molecules having an electron capture cross section dependence on the vibrational state of the molecule. A molecular isotope source material is irradiated to selectively excite those molecules containing a desired isotope to a predetermined vibrational state having associated therewith an electron capture energy region substantially non-overlapping with the electron capture energy ranges associated with the lowest vibration states of the molecules. The isotope source is also subjected to electrons having an energy corresponding to the non-overlapping electron capture region whereby the selectively excited molecules preferentially capture electrons and dissociate into negative ions and neutrals. The desired isotope may be in the negative ion product or in the neutral product depending upon the mechanism of dissociation of the particular isotope source used. The dissociation product enriched in the desired isotope is then separated from the reaction system by conventional means. Specifically, [sup 235]UF[sub 6] is separated from a UF[sub 6] mixture by selective excitation followed by dissociative electron capture into [sup 235]UF[sub 5]- and F. 2 figs.

  4. Isotope effects on desorption kinetics of hydrogen isotopes implanted into stainless steel by glow discharge

    SciTech Connect (OSTI)

    Matsuyama, M.; Kondo, M.; Noda, N.; Tanaka, M.; Nishimura, K.

    2015-03-15

    In a fusion device the control of fuel particles implies to know the desorption rate of hydrogen isotopes by the plasma-facing materials. In this paper desorption kinetics of hydrogen isotopes implanted into type 316L stainless steel by glow discharge have been studied by experiment and numerical calculation. The temperature of a maximum desorption rate depends on glow discharge time and heating rate. Desorption spectra observed under various experimental conditions have been successfully reproduced by numerical simulations that are based on a diffusion-limited process. It is suggested, therefore, that desorption rate of a hydrogen isotope implanted into the stainless steel is limited by a diffusion process of hydrogen isotope atoms in bulk. Furthermore, small isotope effects were observed for the diffusion process of hydrogen isotope atoms. (authors)

  5. Y-12 begins to separate lithium isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    begins to separate lithium isotopes During the years from 1946 through the early 1950s, Y-12 continued to expand as needed to meet the demand for a growing primary mission of...

  6. Atomic vapor laser isotope separation process

    DOE Patents [OSTI]

    Wyeth, R.W.; Paisner, J.A.; Story, T.

    1990-08-21

    A laser spectroscopy system is utilized in an atomic vapor laser isotope separation process. The system determines spectral components of an atomic vapor utilizing a laser heterodyne technique. 23 figs.

  7. Isotope separation by photochromatography (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Isotope separation by photochromatography Citation Details In-Document Search Title: Isotope separation by photochromatography An isotope separation method which comprises physically adsorbing an isotopically mixed molecular species on an adsorptive surface and irradiating the adsorbed molecules with radiation of a predetermined wavelength which will selectively excite a desired isotopic species. Sufficient energy is transferred to the excited molecules to desorb them from the surface

  8. Environmental assessment: special isotope separation process selection

    SciTech Connect (OSTI)

    Not Available

    1986-04-01

    This Environmental Assessment (EA) evaluates the differences in potential environmental impacts between two plutonium Special Isotope Separation (SIS) technologies: Atomic Vapor Laser Isotope Separation (AVLIS) and Molecular Laser Isotope Separation (MLIS). Both SIS technologies use PuO/sub 2/ as feed; AVLIS converts feed to plutonium metal and MLIS converts feed to PuF/sub 6/. The AVLIS process uses laser energy to selectively photoionize and electrostatically separate plutonium isotopes from an atomic vapor stream. The MLIS process uses laser energy to selectively disassociate specific isotopes of plutonium in the form of PuF/sub 6/ molecules to create PuF/sub 5/ for collection and further processing. Both processes produce plutonium metal as their product. An evaluation of differences in potential environmental impacts attributed to the construction of an SIS facility, based on either technology, included a comparison of construction materials, land areas required, and the size of the design and construction workforce. The differences in potential environmental impacts from operating an SIS facility were also compared. No large differences in potential environmental impacts would be expected from the use of process chemicals. An AVLIS or an MLIS facility would produce operating effluents that would meet all applicable radiation, chemical, and hazardous waste standards and would be constructed to protect workers, the public and the environment. This EA has not revealed any significant differences in the potential environmental impacts that could occur as a result of deploying either the AVLIS or the MLIS Special Isotope Separation technology.

  9. THE ATTENUATED RADON TRANSFORM: APPLICATION TO SINGLE-PHOTON EMISSION COMPUTED TOMOGRAPHY IN THE PRESENCE OF A VARIABLE ATTENUATING MEDIUM

    SciTech Connect (OSTI)

    Gullberg, Grant T.

    1980-03-01

    The properties of the attenuated Radon transform and its application to single-photon emission computed tomography (ECT) are analyzed in detail. In nuclear medicine and biological research, the objective of ECT is to describe quantitatively the position and strengths of internal sources of injected radiopharmaceuticals and radionuclides where the attenuation between the sources and detector is unknown. The problem is mathematically and practically quite different from well-known methods in transmission computed tomography (TCT) where only the attenuation is unknown. A mathematical structure using function theory and the theory of linear operators on Hilbert spaces is developed to better understand the spectral properties of the attenuated Radon transform. The continuous attenuated Radon transform is reduced to a matrix operator for discrete angular and lateral sampling, and the reconstruction problem reduces to a system of linear equations. For variable attenuation coefficients frequently found in imaging internal organs, the numerical methods developed in this paper involve iterative techniques of performing the generalized inverse. Its application to nuclear medicine is demonstrated by reconstructions of transverse sections of the brain, heart, and liver.

  10. TRIFID (TRansuranic Isotopic Fraction Interrogation Device): A second generation plutonium isotopic analysis system

    SciTech Connect (OSTI)

    Fleissner, J G; Coressel, T W; Freier, D A; Macklin, L L

    1989-01-01

    The TRIFID (Transuranic Isotopic Fraction Interrogation Device) system is a second generation plutonium isotopic analysis system which incorporates many new and unique features in the area of isotopic data acquisition and isotopic analysis instrument consisting of a Canberra Series 95-MCA interfaced to a Compaq 386 computer. The entire TRIFID software package, including MCA communications and isotopic analysis routines, was developed using the C programming language. Extensive use has been made of user friendly screens and menus for ease of operation and training and to facilitate use by technical level operators. Automated TRIFID features provide for MCA/ADC setup and acquisition, spectral storage, isotopic analysis, and report generation. One unique feature of the TRIFID system design allows it to be pre-programed for an entire day's counting. The isotopic analysis module (EPICS) contains an expert system formalism which is used to detect and assay for spectral interferences, and to automatically adjust peak fitting constraints based on spectral intensity variations. A TRIFID system has been in operation in a production laboratory at the Rocky Flats Plant since September 1988. Marked decreases in training and hands-on operation time have been achieved in comparison to the older, preceding isotopic systems. 2 refs., 3 figs.

  11. Laser Isotope Separation Employing Condensation Repression

    SciTech Connect (OSTI)

    Eerkens, Jeff W.; Miller, William H.

    2004-09-15

    Molecular laser isotope separation (MLIS) techniques using condensation repression (CR) harvesting are reviewed and compared with atomic vapor laser isotope separation (AVLIS), gaseous diffusion (DIF), ultracentrifuges (UCF), and electromagnetic separations (EMS). Two different CR-MLIS or CRISLA (Condensation Repression Isotope Separation by Laser Activation) approaches have been under investigation at the University of Missouri (MU), one involving supersonic super-cooled free jets and dimer formation, and the other subsonic cold-wall condensation. Both employ mixtures of an isotopomer (e.g. {sup i}QF{sub 6}) and a carrier gas, operated at low temperatures and pressures. Present theories of VT relaxation, dimerization, and condensation are found to be unsatisfactory to explain/predict experimental CRISLA results. They were replaced by fundamentally new models that allow ab-initio calculation of isotope enrichments and predictions of condensation parameters for laser-excited and non-excited vapors which are in good agreement with experiment. Because of supersonic speeds, throughputs for free-jet CRISLA are a thousand times higher than cold-wall CRISLA schemes, and thus preferred for large-quantity Uranium enrichments. For small-quantity separations of (radioactive) medical isotopes, the simpler coldwall CRISLA method may be adequate.

  12. Diffusion in silicon isotope heterostructures

    SciTech Connect (OSTI)

    Silvestri, Hughes Howland

    2004-05-14

    The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded diffusion profiles enabled the modeling of the coupled dopant and self-diffusion. From the modeling of the simultaneous diffusion, the dopant diffusion mechanisms, the native defect charge states, and the self- and dopant diffusion coefficients can be determined. This information is necessary to enhance the physical modeling of dopant diffusion in Si. It is of particular interest to the modeling of future electronic Si devices, where the nanometer-scale features have created the need for precise physical models of atomic diffusion in Si. The modeling of the experimental profiles of simultaneous diffusion of B and Si under p-type extrinsic conditions revealed that both species are mediated by neutral and singly, positively charged Si self-interstitials. The diffusion of As and Si under extrinsic n-type conditions yielded a model consisting of the interstitialcy and vacancy mechanisms of diffusion via singly negatively charged self-interstitials and neutral vacancies. The simultaneous diffusion of P and Si has been modeled on the basis of neutral and singly negatively charged self-interstitials and neutral and singly positively charged P species. Additionally, the temperature dependence of the diffusion coefficient of Si in Ge was measured over the temperature range of 550 C to 900 C using a buried Si layer in an epitaxially grown Ge layer.

  13. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

  14. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-03-30

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  15. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, James W.

    1993-01-01

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  16. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K.

    1994-01-01

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  17. An investigation of radon release and mobility in the subsurface environment. Final project report

    SciTech Connect (OSTI)

    Thomas, D.

    1997-06-01

    Processes affecting transport of volatile species in the shallow soil column have recently been recognized as having a substantial impact on a broad array of real world problems. Investigations of volatile transport have ranged from studies of probable health impacts of radon infiltration into homes to pesticide and volatile organic contaminant mobility in the soil column. The objectives of many of these studies has been the development of numerical models of vapor phase (and solute) transport in shallow soils. An early model, LEACHM, developed by Hutson and Wagenent was recently modified enabling it to describe both solute and vapor phase transport of volatile chemicals in the soil. Subsequent tests of the latter model, named LEACHV, showed that use outside of a very restricted range of soil conditions resulted in large mass balance errors and unreasonable values for soil gas concentrations and vapor flux. The present research was undertaken in an effort to identify and correct the subroutines responsible for the problems and to allow the model to describe vapor phase transport in a much broader range of soil conditions.

  18. Environmental factors affecting long-term stabilization of radon suppression covers for uranium mill tailings

    SciTech Connect (OSTI)

    Young, J.K.; Long, L.W.; Reis, J.W.

    1982-04-01

    Pacific Northwest Laboratory is investigating the use of a rock armoring blanket (riprap) to mitigate wind and water erosion of an earthen radon suppression cover applied to uranium mill tailings. To help determine design stresses for the tailings piles, environmental parameters are characterized for the five active uranium-producing regions on a site-specific basis. Only conventional uranium mills that are currently operating or that are scheduled to open in the mid 1980s are considered. Available data indicate that flooding has the most potential for disrupting a tailings pile. The arid regions of the Wyoming Basins and the Colorado Plateau are subject to brief storms of high intensity. The Texas Gulf Coast has the highest potential for extreme precipitation from hurricane-related storms. Wind data indicate average wind speeds from 3 to 6 m/sec for the sites, but extremes of 40 m/sec can be expected. Tornado risks range from low to moderate. The Colorado Plateau has the highest seismic potential, with maximum acceleration caused by earthquakes ranging from 0.2 to 0.4 g. Any direct effect from volcanic eruption is negligible, as all mills are located 90 km or more from an igneous or hydrothermal system.

  19. Overview of the U.S. Department of Energy's Isotope Programs

    SciTech Connect (OSTI)

    Carty, J.

    2004-10-05

    This presentation provides an overview of the U.S. Department of Energy's Isotopes Program. The charter of the Isotope Programs covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials, and related isotope services.

  20. Principles of isotope geology. Second edition

    SciTech Connect (OSTI)

    Faure, G.

    1986-01-01

    This is a text in isotope geology/geoscience that integrates material taught in various courses into a unified picture of the earth sciences. It presents an exposition of the principles used in the interpretation of isotopic data and shows how such interpretations apply to the solution of geological problems. References up to 1985 are included with chapters in this edition. New chapters on Sm-Nd, Lu-Hf Re-Os, and K-Ca decay schemes and cosmogenic radionuclides have been added. Data summaries and references have been expanded.

  1. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  2. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

    1987-04-07

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

  3. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul; Rockwood, Stephen D.; Jensen, Reed J.; Lyman, John L.; Aldridge, III, Jack P.

    1987-01-01

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  4. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul; Rockwood, Stephen D.; Jensen, Reed J.; Lyman, John L.; Aldridge, III, Jack P.

    1977-01-01

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, in the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  5. Ion laser isotope enrichment by photo-predissociation of formaldehyde

    DOE Patents [OSTI]

    Marling, John B.

    1977-06-17

    Enrichment of carbon, hydrogen and/or oxygen isotopes by means of isotopically selective photo-predissociation of formaldehyde is achieved by irradiation with a fixed frequency ion laser, specifically, a neon, cadmium, or xenon ion laser.

  6. Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility...

    Office of Environmental Management (EM)

    Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility Building 9204-3 Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility Building 9204-3 The ...

  7. Method for production of an isotopically enriched compound

    DOE Patents [OSTI]

    Watrous, Matthew G.

    2012-12-11

    A method is presented for producing and isolating an isotopically enriched compound of a desired isotope from a parent radionuclide. The method includes forming, or placing, a precipitate containing a parent radionuclide of the desired daughter isotope in a first reaction zone and allowing sufficient time for the parent to decay into the desired gaseous daughter radioisotope. The method further contemplates collecting the desired daughter isotope as a solid in a second reaction zone through the application of temperatures below the freezing point of the desired isotope to a second reaction zone that is connected to the first reaction zone. Specifically, a method is presented for producing isotopically enriched compounds of xenon, including the radioactive isotope Xe-131m and the stable isotope Xe-131.

  8. Isotopic Analysis- Rock At Coso Geothermal Area (1984) | Open...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis- Rock At Coso Geothermal Area (1984) Exploration Activity Details Location Coso Geothermal Area Exploration Technique...

  9. Mapping quadrupole collectivity in the Cd isotopes: The breakdown...

    Office of Scientific and Technical Information (OSTI)

    ... LIFETIME; MEV RANGE; NUCLEAR POTENTIAL; SILVER 112; SPHERICAL CONFIGURATION; SPIN; ... PROPERTIES; POTENTIALS; RADIOISOTOPES; SILVER ISOTOPES; SPECTROSCOPY Word Cloud More ...

  10. Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes

    SciTech Connect (OSTI)

    Kathawa, J.; Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15

    Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  11. Laser Isotope Enrichment for Medical and Industrial Applications

    SciTech Connect (OSTI)

    Leonard Bond

    2006-07-01

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ”calutrons” (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation repression. In this scheme a gas, of the selected isotopes for enrichment, is irradiated with a laser at a particular wavelength that would excite only one of the isotopes. The entire gas is subject to low temperatures sufficient to cause condensation on a cold surface. Those molecules in the gas that the laser excited are not as likely to condense as are the unexcited molecules. Hence the gas drawn out of the system will be enriched in the isotope that was excited by the laser. We have evaluated the relative energy required in this process if applied on a commercial scale. We estimate the energy required for laser isotope enrichment is about 20% of that required in centrifuge separations, and 2% of that required by use of "calutrons".

  12. Strontium-isotope stratigraphy of Enewetak Atoll

    SciTech Connect (OSTI)

    Ludwig, K.R.; Halley, R.B.; Simmons, K.R.; Peterman, Z.E.

    1988-02-01

    /sup 87/Sr//sup 86/Sr ratios determined for samples from a 350 m core of Neogene lagoonal, shallow-water limestones from Enewetak Atoll display a remarkably informative trend. Like the recently published data for Deep Sea Drilling Project (DSDP) carbonates, /sup 87/Sr//sup 86/Sr at Enewetak increases monotonically but not smoothly from the early Miocene to the Pleistocene. The data show intervals of little or no change in /sup 87/Sr//sup 86/Sr, punctuated by sharp transitions to lower values toward greater core depths. The sharp transitions correlate with observed solution disconformities caused by periods of subaerial erosion, whereas the intervals of little or no change in /sup 87/Sr//sup 86/Sr correspond to intervals of rapid accumulation of shallow-water carbonate sediments. When converted to numerical ages using the published DSDP 590B trend, the best-resolved time breaks are at 282 m (12.3 to 18.2 Ma missing) and 121.6 m (3.0 to 5.3 Ma missing) below the lagoon floor. At Enewetak, Sr isotopes offer a stratigraphic resolution for these shallow-marine Neogene carbonates comparable to that of nannofossil zonation in deep-sea carbonates (0.3-3 m.y.). In addition, the correlation of times of Sr-isotope breaks at Enewetak with times of rapid Sr-isotope change in the DSDP 590B samples confirms the importance of sea-level changes in the evolution of global-marine Sr isotopes and shows that the Sr-isotope response to sea-level falls is rapid.

  13. Method of enhancing selective isotope desorption from metals

    DOE Patents [OSTI]

    Knize, Randall J. (Plainsboro, NJ); Cecchi, Joseph L. (Lawrenceville, NJ)

    1984-01-01

    A method of enhancing the thermal desorption of a first isotope of a diatomic gas from a metal comprises the steps of (a) establishing a partial pressure of a second isotope of the diatomic gas in vicinity of the metal; heating the metal to a temperature such that the first isotope is desorbed from the metal; and reducing the partial pressure of the desorbed first isotope while maintaining the partial pressure of the second isotope substantially constant. The method is especially useful for enhancing the desorption of tritium from the Zr-Al getter in a plasma confinement device.

  14. Enriching stable isotopes: Alternative use for Urenco technology

    SciTech Connect (OSTI)

    Rakhorst, H.; de Jong, P.G.T.; Dawson, P.D.

    1996-12-31

    The International Urenco Group utilizes a technologically advanced centrifuge process to enrich uranium in the fissionable isotope {sup 235}U. The group operates plants in the United Kingdom, the Netherlands, and Germany and currently holds a 10% share of the multibillion dollar world enrichment market. In the early 1990s, Urenco embarked on a strategy of building on the company`s uniquely advanced centrifuge process and laser isotope separation (LIS) experience to enrich nonradioactive isotopes colloquially known as stable isotopes. This paper summarizes the present status of Urenco`s stable isotopes business.

  15. Method of preparing mercury with an arbitrary isotopic distribution

    DOE Patents [OSTI]

    Grossman, Mark W.; George, William A.

    1986-01-01

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg.sub.2 Cl.sub.2, corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H.sub.2 O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H.sub.2 O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered.

  16. Method of preparing mercury with an arbitrary isotopic distribution

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1986-12-16

    This invention provides for a process for preparing mercury with a predetermined, arbitrary, isotopic distribution. In one embodiment, different isotopic types of Hg[sub 2]Cl[sub 2], corresponding to the predetermined isotopic distribution of Hg desired, are placed in an electrolyte solution of HCl and H[sub 2]O. The resulting mercurous ions are then electrolytically plated onto a cathode wire producing mercury containing the predetermined isotopic distribution. In a similar fashion, Hg with a predetermined isotopic distribution is obtained from different isotopic types of HgO. In this embodiment, the HgO is dissolved in an electrolytic solution of glacial acetic acid and H[sub 2]O. The isotopic specific Hg is then electrolytically plated onto a cathode and then recovered. 1 fig.

  17. Computer program for the sensitivity calculation of a CR-39 detector in a diffusion chamber for radon measurements

    SciTech Connect (OSTI)

    Nikezic, D. Stajic, J. M.; Yu, K. N.

    2014-02-15

    Computer software for calculation of the sensitivity of a CR-39 detector closed in a diffusion chamber to radon is described in this work. The software consists of two programs, both written in the standard Fortran 90 programming language. The physical background and a numerical example are given. Presented software is intended for numerous researches in radon measurement community. Previously published computer programs TRACK-TEST.F90 and TRACK-VISION.F90 [D. Nikezic and K. N. Yu, Comput. Phys. Commun. 174, 160 (2006); D. Nikezic and K. N. Yu, Comput. Phys. Commun. 178, 591 (2008)] are used here as subroutines to calculate the track parameters and to determine whether the track is visible or not, based on the incident angle, impact energy, etching conditions, gray level, and visibility criterion. The results obtained by the software, using five different V functions, were compared with the experimental data found in the literature. Application of two functions in this software reproduced experimental data very well, while other three gave lower sensitivity than experiment.

  18. Regioselective synthesis using the deuterium isotope effect

    SciTech Connect (OSTI)

    Miyano, M.

    1981-04-24

    Dehydration of 1a by various procedures invariably produced more exo olefin 2a than endo olefin 3a. This could be reversed by introduction of deuterium in the Me-21 group of the starting material. Thus, dehydration of 1b could afford more endo olefin 3b than exo olefin 2b due to the deuterium isotope effect. A regioselective synthesis of 18-oxoprogesterone (15a) from 3..beta..-hydroxypregn-5-en-20-one (5a) was carried out taking advantage of the deuterium isotope effect as depicted in Scheme I. The key steps were dehydration of 7b to predominantly endo olefin 9b and removal of the deuteriums from 18-oxoprogesterone-17..cap alpha..,21,21,21-d/sub 4/ (15b) to give 15a.

  19. Hydrogen isotopic exchange over palladium metal

    SciTech Connect (OSTI)

    Carstens, D.H.W.; Encinias, P.D.

    1990-01-01

    We have recently developed the laser-Raman technique as a means of unambiguously measuring the partial pressures of all possible hydrogen isotopes in the gas phase. Using this technique we have investigated the hydrogen-deuterium exchange in a number of metals. This report presents detailed data for isotopic exchange in the palladium hydride system over the temperature range 26{degree}C to -100{degree}C at a pressure of 7 atm. First order kinetic rate constants and activation energies are summarized for the forward (hydride to deuteride) and reverse (deuteride to hydride) exchange processes. In addition, we have found that small amounts (100 ppm) of impurities in the exchange gases considerably slow the exchange kinetics with the effect increasing down the series CH{sub 4}, CO{sub 2}, H{sub 2}O, and CO. 9 refs., 4 figs., 1 tab.

  20. Quantifying uncertainty in stable isotope mixing models

    SciTech Connect (OSTI)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (?15N and ?18O) but all methods tested are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.

  1. Separation of uranium isotopes by chemical exchange

    DOE Patents [OSTI]

    Ogle, P.R. Jr.

    1974-02-26

    A chemical exchange method is provided for separating /sup 235/U from / sup 238/U comprising contacting a first phase containing UF/sub 6/ with a second phase containing a compound selected from the group consisting of NOUF/sub 6/, NOUF/sub 7/, and NO/sub 2/UF/sub 7/ until the U Fsub 6/ in the first phase becomes enriched in the /sup 235/U isotope. (Official Gazette)

  2. Concerning the Facility for Rare Isotope Beams

    ScienceCinema (OSTI)

    Symons, James

    2013-05-29

    James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

  3. Quantifying uncertainty in stable isotope mixing models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davis, Paul; Syme, James; Heikoop, Jeffrey; Fessenden-Rahn, Julianna; Perkins, George; Newman, Brent; Chrystal, Abbey E.; Hagerty, Shannon B.

    2015-05-19

    Mixing models are powerful tools for identifying biogeochemical sources and determining mixing fractions in a sample. However, identification of actual source contributors is often not simple, and source compositions typically vary or even overlap, significantly increasing model uncertainty in calculated mixing fractions. This study compares three probabilistic methods, SIAR [Parnell et al., 2010] a pure Monte Carlo technique (PMC), and Stable Isotope Reference Source (SIRS) mixing model, a new technique that estimates mixing in systems with more than three sources and/or uncertain source compositions. In this paper, we use nitrate stable isotope examples (δ15N and δ18O) but all methods testedmore » are applicable to other tracers. In Phase I of a three-phase blind test, we compared methods for a set of six-source nitrate problems. PMC was unable to find solutions for two of the target water samples. The Bayesian method, SIAR, experienced anchoring problems, and SIRS calculated mixing fractions that most closely approximated the known mixing fractions. For that reason, SIRS was the only approach used in the next phase of testing. In Phase II, the problem was broadened where any subset of the six sources could be a possible solution to the mixing problem. Results showed a high rate of Type I errors where solutions included sources that were not contributing to the sample. In Phase III some sources were eliminated based on assumed site knowledge and assumed nitrate concentrations, substantially reduced mixing fraction uncertainties and lowered the Type I error rate. These results demonstrate that valuable insights into stable isotope mixing problems result from probabilistic mixing model approaches like SIRS. The results also emphasize the importance of identifying a minimal set of potential sources and quantifying uncertainties in source isotopic composition as well as demonstrating the value of additional information in reducing the uncertainty in calculated mixing fractions.« less

  4. Optically pumped isotopic ammonia laser system

    DOE Patents [OSTI]

    Buchwald, Melvin I.; Jones, Claude R.; Nelson, Leonard Y.

    1982-01-01

    An optically pumped isotopic ammonia laser system which is capable of producing a plurality of frequencies in the middle infrared spectral region. Two optical pumping mechanisms are disclosed, i.e., pumping on R(J) and lasing on P(J) in response to enhancement of rotational cascade lasing including stimulated Raman effects, and, pumping on R(J) and lasing on P(J+2). The disclosed apparatus for optical pumping include a hole coupled cavity and a grating coupled cavity.

  5. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  6. First AID (Atom counting for Isotopic Determination).

    SciTech Connect (OSTI)

    Roach, J. L. (Jeffrey L.); Israel, K. M. (Kimberly M.); Steiner, R. E. (Robert E.); Duffy, C. J. (Clarence J.); Roench, F. R. (Fred R.)

    2002-01-01

    Los Alamos National Laboratory (LANL) has established an in vitro bioassay monitoring program in compliance with the requirements in the Code of Federal Regulations, 10 CFR 835, Occupational Radiation Protection. One aspect of this program involves monitoring plutonium levels in at-risk workers. High-risk workers are monitored using the ultra-sensitive Therrnal Ionization Mass Spectrometry (TIMS) technique to ensure compliance with DOE standards. TIMS is used to measure atom ratios of 239Pua nd 240Puw ith respect to a tracer isotope ('Pu). These ratios are then used to calculate the amount of 239Pu and 240Pup resent. This low-level atom counting technique allows the calculation of the concentration levels of 239Pu and 240Pu in urine for at risk workers. From these concentration levels, dose assessments can be made and worker exposure levels can be monitored. Detection limits for TIMS analysis are on the order of millions of atoms, which translates to activity levels of 150 aCi 239Pua nd 500 aCi for 240Pu. pCi for Our poster presentation will discuss the ultra-sensitive, low-level analytical technique used to measure plutonium isotopes and the data verification methods used for validating isotopic measurements.

  7. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  8. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  9. FILTR: Flash Isotope Library and Training Resource

    SciTech Connect (OSTI)

    Campbell, D; Trombino, D

    2007-07-26

    The subject of radiation detection is replete with complex concepts and challenging nomenclature. Furthermore, a daunting variety of radioactive isotopes may be encountered during the routine operation of a radiation detector. Individuals tasked with searching for illicit sources of radiation must remain vigilant while navigating through more frequently encountered mundane and legitimate radioactive sources. The Flash Isotope Library and Training Resource (FILTR) is being developed as an easily accessible and intuitive reference tool to manage the high volume of complex information required for this task. FILTR is an extended version of the Primary Utility for Nuclear Terminology (PUNT) software developed by the Counter Measures Test Beds group at Lawrence Livermore National Laboratory for the United States Secret Service. Authored in the Flash multimedia development environment, FILTR contains detailed information on potentially encountered isotopes as well as training on radiation and operational procedures. Reference material is organized to present critical information quickly while facilitating more in-depth investigation through an intuitive interface and engaging content. FILTR is being developed for a diverse audience of law enforcement organizations and government agencies and a wide range of skill sets from expert analysts to officers whose primary role is not radiation detection. Additionally, the wide compatibility of Flash content will allow FILTR to be readily accessible through the growing number of multi-media enabled electronic devices, including PDAs and cellular phones.

  10. U.S. Department of Energy Isotope Program

    SciTech Connect (OSTI)

    2015-06-23

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. PNNL’s Isotope Program operates in a multi-program category-2 nuclear facility, the Radiochemical Processing Laboratory (RPL), that contains 16 hot cells and 20 gloveboxes. As part of the DOE Isotope Program, the Pacific Northwest National Laboratory dispenses strontium-90, neptunium-237, radium-223, and thorium-227. PNNL’s Isotope Program uses a dedicated hot-cell for strontium-90 dispensing and a dedicated glovebox for radium-223 and thorium-227 dispensing. PNNL’s Isotope Program has access to state of the art analytical equipment in the RPL to support their research and production activities. DOE Isotope Program funded research at PNNL has advanced the application of automated radiochemistry for isotope such as zirconium-89 and astatine-211 in partnership with the University of Washington.

  11. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  12. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-07

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ²⁰⁶⁻²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D₁ and D₂ transitions, of sufficient precision to differentiate between ab initio calculations.

  13. Nitrogen concentration and isotope dataset for environmental samples from

    Office of Scientific and Technical Information (OSTI)

    2012 and 2013, Barrow, Alaska (Dataset) | Data Explorer Data Explorer Search Results Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska Title: Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska Dataset includes nitrate concentrations for polygonal active layer samples, snowmelt; ammonium concentrations for active layer samples; nitrate isotopes for active layer samples, snowmelt,

  14. Expert Panel: Forecast Future Demand for Medical Isotopes | Department of

    Energy Savers [EERE]

    Energy Expert Panel: Forecast Future Demand for Medical Isotopes Expert Panel: Forecast Future Demand for Medical Isotopes The Expert Panel has concluded that the Department of Energy and National Institutes of Health must develop the capability to produce a diverse supply of radioisotopes for medical use in quantities sufficient to support research and clinical activities. Such a capability would prevent shortages of isotopes, reduce American dependence on foreign radionuclide sources and

  15. Physicist wins early-career award for isotope work

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    May » Physicist wins early-career award for isotope work Physicist wins early-career award for isotope work Jonathan Ward Engle, is among 49 winners, of the US Department of Energy's Early Career Research Program awards for 2016. May 12, 2016 Jonathan Ward Engle Jonathan Ward Engle Contact Nancy Ambrosiano Communications Office (505) 667-0471 Email "Jonathan's work brings distinctive mission and science together, connecting the strong history of Los Alamos research in isotopes with

  16. COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technical Challenges | Princeton Plasma Physics Lab February 4, 2015, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and Technical Challenges Dr. Georg Bollen Michigan State University - The Facility for Rare Isotope Beams Wednesday Colloquium, February 4, 2015, "Facility for Rare Isotope Beams - Scientific Opportunities and Technial Chanllenges", Dr. Georg Bollen Colloquium Committee: The Princeton Plasma Physics

  17. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Security Administration Isotope production agreement benefits medical patients Thursday, March 19, 2015 - 12:24pm Medical patients, both locally and potentially nationwide, should be the beneficiaries of the first-ever public-private partnership agreement between National Security Technologies, LLC (NSTec), and Henderson, Nevada-based Global Medical Isotope Systems, LLC (GMIS). The agreement on research and development aims to enable production of an essential radioactive isotope used in

  18. Mapping quadrupole collectivity in the Cd isotopes: The breakdown of

    Office of Scientific and Technical Information (OSTI)

    harmonic vibrational motion (Journal Article) | SciTech Connect Mapping quadrupole collectivity in the Cd isotopes: The breakdown of harmonic vibrational motion Citation Details In-Document Search Title: Mapping quadrupole collectivity in the Cd isotopes: The breakdown of harmonic vibrational motion The stable Cd isotopes have long been used as paradigms for spherical vibrational motion. Extensive investigations with in-beam {gamma} spectroscopy have resulted in very-well-established level

  19. Fact Sheet: Facility For Rare Isotope Beams (FRIB) Applicant Selection |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Facility For Rare Isotope Beams (FRIB) Applicant Selection Fact Sheet: Facility For Rare Isotope Beams (FRIB) Applicant Selection December 11, 2008 - 8:51am Addthis Based on the analyses and recommendations over the last decade, the U.S. Department of Energy (DOE) Office of Science determined that the establishment of a Facility for Rare Isotope Beams (FRIB) is a high priority for the future of U.S. nuclear science research. This determination and supporting rationale

  20. System and method for high precision isotope ratio destructive analysis

    DOE Patents [OSTI]

    Bushaw, Bruce A; Anheier, Norman C; Phillips, Jon R

    2013-07-02

    A system and process are disclosed that provide high accuracy and high precision destructive analysis measurements for isotope ratio determination of relative isotope abundance distributions in liquids, solids, and particulate samples. The invention utilizes a collinear probe beam to interrogate a laser ablated plume. This invention provides enhanced single-shot detection sensitivity approaching the femtogram range, and isotope ratios that can be determined at approximately 1% or better precision and accuracy (relative standard deviation).

  1. A modeling study of the effect of depth of burial of depleted uranium and thorium on radon gas flux at a dry desert alluvial soil radioactive waste management site (RWMS)

    SciTech Connect (OSTI)

    Lindstrom, F.T.; Cawlfield, D.E.; Emer, D.F.; Shott, G.J.

    1993-08-01

    An integral part of designing low-level waste (LLW) disposal pits and their associated closure covers in very dry desert alluvium is the use of a radon gas transport and fate model. Radon-222 has the potential to be a real heath hazard. The production of radon-222 results from the radioactive decay (a particle emission) of radium-226 in the uranium-235 and 238 Bateman chains. It is also produced in the thorium-230 series. Both long lived radionuclides have been proposed for disposal in the shallow land burial pits in Area 5 RWMS compound of Nevada Test Site (NTS). The constructed physics based model includes diffusion and barometric pressure-induced advection of an M-chain of radionuclides. The usual Bateman decay mechanics are included for each radionuclide. Both linear reversible and linear irreversible first order sorption kinetics are assumed for each radionuclide. This report presents the details of using the noble gas transport model, CASCADR9, in an engineering design study mode. Given data on the low-level waste stream, which constitutes the ultimate source of radon-222 in the RWMS, CASCADR9 is used to generate the surface flux (pCi/cm{sup 2}-sec) of radon-222 under the realistic atmospheric and alluvial soil conditions found in the RWMS at Area 5, of the NTS. Specifically, this study examines the surface flux of radon-222 as a function of the depth of burial below the land surface.

  2. Isotopic Analysis- Fluid At Rose Valley Geothermal Area (1990...

    Open Energy Info (EERE)

    Rose Valley Geothermal Area (1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Rose Valley Geothermal Area (1990)...

  3. Isotopic Analysis-Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Estimate deep reservoir temperature Notes The oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes have been tested. Methods are...

  4. Isotopic Analysis-Fluid At Yellowstone Caldera Geothermal Region...

    Open Energy Info (EERE)

    Estimate deep reservoir temperature Notes The oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes have been tested. Methods are...

  5. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Exploration Activity: Isotopic Analysis At Valles Caldera - Redondo Geothermal Area (Phillips, 2004) Exploration Activity Details Location Valles Caldera - Redondo Geothermal Area...

  6. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    Phillips, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area...

  7. Isotopic Analysis-Fluid At Raft River Geothermal Area (1982)...

    Open Energy Info (EERE)

    GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis-Fluid At Raft River Geothermal Area (1982) Exploration Activity Details Location Raft River...

  8. Isotopic Analysis-Fluid At Raft River Geothermal Area (1977)...

    Open Energy Info (EERE)

    GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis-Fluid At Raft River Geothermal Area (1977) Exploration Activity Details Location Raft River...

  9. Helium isotopes in geothermal systems- Iceland, The Geysers,...

    Open Energy Info (EERE)

    isotopes in geothermal systems- Iceland, The Geysers, Raft River and Steamboat Springs Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium...

  10. Establishment of the Heavy Isotopes Lead Materials Management...

    Office of Scientific and Technical Information (OSTI)

    Lead Materials Management Organization (LMMO) Citation Details In-Document Search Title: Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) ...

  11. Isotopic Analysis At Nw Basin & Range Region (Laney, 2005) |...

    Open Energy Info (EERE)

    Location Northwest Basin and Range Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  12. Isotopic Analysis At Central Nevada Seismic Zone Region (Laney...

    Open Energy Info (EERE)

    Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  13. Isotopic Analysis- Fluid At Coso Geothermal Area (1990) | Open...

    Open Energy Info (EERE)

    Exploration Activity Details Location Coso Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  14. Isotopic Analysis At Clear Lake Area (Thompson, Et Al., 1992...

    Open Energy Info (EERE)

    Exploration Activity Details Location Clear Lake Area Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness useful DOE-funding Unknown Notes Deuterium and...

  15. Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal...

    Open Energy Info (EERE)

    Details Location Indian Valley Hot Springs Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  16. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    Details Location Valles Caldera - Sulphur Springs Area Exploration Technique Isotopic Analysis- Rock Activity Date Usefulness not indicated DOE-funding Unknown References...

  17. Isotopic Analysis At Northern Basin & Range Region (Laney, 2005...

    Open Energy Info (EERE)

    Location Northern Basin and Range Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  18. Isotopic Analysis- Fluid At Sierra Valley Geothermal Area (1990...

    Open Energy Info (EERE)

    Activity Details Location Sierra Valley Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1990 Usefulness not indicated DOE-funding Unknown...

  19. Isotopic Analysis At Buffalo Valley Hot Springs Area (Laney,...

    Open Energy Info (EERE)

    Activity Details Location Buffalo Valley Hot Springs Area Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  20. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Long Valley Caldera Geothermal Area (Taylor & Gerlach, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long...

  1. Isotopic Analysis- Gas At Chena Geothermal Area (Kolker, Et Al...

    Open Energy Info (EERE)

    Date 2007 - 2007 Usefulness useful DOE-funding Unknown Exploration Basis Lawrence Berkeley National Laboratory sampling and analysis of He isotopes from Chena Hot Springs....

  2. Temperature effects on the behavior of liquid hydrogen isotopes...

    Office of Scientific and Technical Information (OSTI)

    liquid hydrogen isotopes inside a spherical-shell directly driven inertial confinement fusion target Kim, K.; Mok, L.S. 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; LASER TARGETS;...

  3. Isotopic Analysis At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date...

  4. Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 2000...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 2000) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  5. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Goff, Et Al., 1982) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Valles Caldera - Redondo Geothermal Area (Goff, Et Al.,...

  6. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    WoldeGabriel & Goff, 1992) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

  7. Isotopic Analysis- Fluid At Valles Caldera - Redondo Area (Rao...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  8. Isotopic Analysis At Yellowstone Region (Goff & Janik, 2002)...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Yellowstone Region (Goff & Janik, 2002) Exploration...

  9. Isotopic Analysis At Jemez Springs Area (Rao, Et Al., 1996) ...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  10. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  11. Isotopic Analysis- Fluid At Fenton Hill HDR Geothermal Area ...

    Open Energy Info (EERE)

    analyzed for their hydrogen and oxygen isotope contents as a part of previous studies (Goff & Grigsby, 1982; Vuataz & Goff, 1986). The present study focuses on the interpretation...

  12. Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 1995...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 1995) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  13. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1982) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  14. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1985) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  15. Isotopic Analysis At Jemez Springs Area (Goff & Janik, 2002)...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Jemez Springs Area (Goff & Janik, 2002) Exploration...

  16. Cancer-fighting treatment gets boost from Isotope Production...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Medical Isotope Work Moves Cancer Treatment Agent Forward - Los Alamos scientist Meiring Nortier holds a thorium foil test target for the proof-of-concept production experiments. ...

  17. Isotopic Analysis At San Juan Volcanic Field Area (Larson & Jr...

    Open Energy Info (EERE)

    San Juan Volcanic Field Area (Larson & Jr, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At San Juan Volcanic Field...

  18. Isotopic Analysis At Yellowstone Region (Sturchio, Et Al., 1990...

    Open Energy Info (EERE)

    Yellowstone Caldera Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness could be useful with more improvements DOE-funding Unknown Notes...

  19. Isotopic Analysis- Fluid At Coso Geothermal Area (1982) | Open...

    Open Energy Info (EERE)

    Details Location Coso Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1982 Usefulness not indicated DOE-funding Unknown Exploration Basis...

  20. Isotopic Analysis At Long Valley Caldera Geothermal Area (Smith...

    Open Energy Info (EERE)

    Smith & Suemnicht, 1991) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Long Valley Caldera Geothermal Area (Smith &...

  1. Strontium Isotopes Test Long-Term Zonal Isolation of Injected...

    Office of Scientific and Technical Information (OSTI)

    Water after Hydraulic Fracturing Citation Details In-Document Search Title: Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus Formation Water after ...

  2. Small-Scale Reactor for the Production of Medical Isotopes -...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    shortage of medical isotopes-specifically Molybdenum 99 (Mo-99) which is essential in cancer treatment, diagnostics, and medical imaging. The US is completely dependent on foreign...

  3. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  4. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Through 30 September Activity T. Winnett, Cathy J. Janik (1986) Isotopic Composition of Carbon in Fluids from the Long Valley Geothermal System, California, In- Proceedings of...

  5. Isotopic Analysis At Newberry Caldera Area (Goles & Lambert,...

    Open Energy Info (EERE)

    Rock Activity Date Usefulness not indicated DOE-funding Unknown References Gordon G. Goles, Richard St J. Lambert (1990) A Strontium Isotopic Study Of Newberry Volcano,...

  6. Unusual superconducting isotope effect in the presence of a quantum...

    Office of Scientific and Technical Information (OSTI)

    Title: Unusual superconducting isotope effect in the presence of a quantum criticality Authors: Kedem, Yaron ; Zhu, Jian-Xin ; Balatsky, Alexander V. Publication Date: 2016-05-23 ...

  7. Isotopic Analysis At Northern Basin & Range Region (Cole, 1983...

    Open Energy Info (EERE)

    Cole, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Northern Basin & Range Region (Cole, 1983) Exploration Activity...

  8. Isotopic Analysis- Fluid At Roosevelt Hot Springs Geothermal...

    Open Energy Info (EERE)

    Unknown Exploration Basis Faulder 1991 Conceptual Geological Model compilation and literature review of the Roosevelt Hot Springs Geothermal Area. Notes Stable isotope analysis...

  9. Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans, Et Al., 2002) Exploration Activity Details...

  10. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    western United States. Limited analyses of spring and borehole fluids and existing experimental rate studies suggest that dissolved sulfate and water are probably in isotopic...

  11. Isotopic Analysis At Lassen Volcanic National Park Area (Janik...

    Open Energy Info (EERE)

    Park Area (Janik & Mclaren, 2010) Exploration Activity Details Location Lassen Volcanic National Park Area Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness...

  12. Method of isotope separation by chemi-ionization

    DOE Patents [OSTI]

    Wexler, Sol; Young, Charles E.

    1977-05-17

    A method for separating specific isotopes present in an isotopic mixture by aerodynamically accelerating a gaseous compound to form a jet of molecules, and passing the jet through a stream of electron donor atoms whereby an electron transfer takes place, thus forming negative ions of the molecules. The molecular ions are then passed through a radiofrequency quadrupole mass filter to separate the specific isotopes. This method may be used for any compounds having a sufficiently high electron affinity to permit negative ion formation, and is especially useful for the separation of plutonium and uranium isotopes.

  13. Isotopic Analysis- Fluid At Salt Wells Area (Shevenell & Garside...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 2002 -...

  14. John De Laeter Centre For Isotope Research | Open Energy Information

    Open Energy Info (EERE)

    2013 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for John De Laeter Centre For Isotope Research Citation Curtin University. John...

  15. Hydrogeological And Isotopic Survey Of Geothermal Fields In The...

    Open Energy Info (EERE)

    Hydrogeological And Isotopic Survey Of Geothermal Fields In The Buyuk Menderes Graben, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  16. Hydrogen Isotope Separation From Noble Gasses in Plasma Exhausts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Isotope Separation From Noble Gasses in Plasma Exhausts and Other Gas Streams --- Inventors Thomas A. Kozub, William R. Blanchard and Charles A. Gentile The objective of...

  17. {open_quotes}Radon{close_quotes} - the system of Soviet designed regional waste management facilities

    SciTech Connect (OSTI)

    Horak, W.C.; Reisman, A.; Purvis, E.E. III

    1997-07-01

    The Soviet Union established a system of specialized regional facilities to dispose of radioactive waste generated by sources other than the nuclear fuel cycle. The system had 16 facilities in Russia, 5 in Ukraine, one in each of the other CIS states, and one in each of the Baltic Republics. These facilities are still being used. The major generators of radioactive waste they process these are research and industrial organizations, medical and agricultural institution and other activities not related to nuclear power. Waste handled by these facilities is mainly beta- and gamma-emitting nuclides with half lives of less than 30 years. The long-lived and alpha-emitting isotopic content is insignificant. Most of the radwaste has low and medium radioactivity levels. The facilities also handle spent radiation sources, which are highly radioactive and contain 95-98 percent of the activity of all the radwaste buried at these facilities.

  18. Laser-assisted isotope separation of tritium

    DOE Patents [OSTI]

    Herman, Irving P. (Castro Valley, CA); Marling, Jack B. (Livermore, CA)

    1983-01-01

    Methods for laser-assisted isotope separation of tritium, using infrared multiple photon dissociation of tritium-bearing products in the gas phase. One such process involves the steps of (1) catalytic exchange of a deuterium-bearing molecule XYD with tritiated water DTO from sources such as a heavy water fission reactor, to produce the tritium-bearing working molecules XYT and (2) photoselective dissociation of XYT to form a tritium-rich product. By an analogous procedure, tritium is separated from tritium-bearing materials that contain predominately hydrogen such as a light water coolant from fission or fusion reactors.

  19. Measurement of Plutonium Isotopic Composition - MGA

    SciTech Connect (OSTI)

    Vo, Duc Ta

    2015-08-21

    In this module, we will use the Canberra InSpector-2000 Multichannel Analyzer with a high-purity germanium detector (HPGe) and the MGA isotopic anlysis software to assay a variety of plutonium samples. The module provides an understanding of the MGA method, its attributes and limitations. You will assess the system performance by measuring a range of materials similar to those you may assay in your work. During the final verification exercise, the results from MGA will be combined with the 240Pueff results from neutron coincidence or multiplicity counters so that measurements of the plutonium mass can be compared with the operator-declared (certified) values.

  20. CONTROL SYSTEM FOR ISOTOPE SEPARATING APPARATUS

    DOE Patents [OSTI]

    Barnes, S.W.

    1960-01-26

    A method is described for controlling the position of the ion beams in a calutron used for isotope separation. The U/sup 238/ beams is centered over the U/sup 235/ receiving pocket, the operator monitoring the beam until a maximum reading is achieved on the meter connected to that pocket. Then both beams are simultaneously shifted by a preselected amount to move the U/sup 235/ beam over the U/sup 235/ pocket. A slotted door is placed over the entrance to that pocket during the U/sup 238/ beam centering to reduce the contamination to the pocket, while allowing enough beam to pass for monitoring purposes.

  1. Apparatus for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W.; George, William A.; Marcucci, Rudolph V.

    1988-01-01

    An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

  2. Global Security, Medical Isotopes, and Nuclear Science

    SciTech Connect (OSTI)

    Ahle, L E

    2007-09-17

    Over the past century basic nuclear science research has led to the use of radioactive isotopes into a wide variety of applications that touch our lives everyday. Some are obvious, such as isotopes for medical diagnostics and treatment. Others are less so, such as National/Global security issues. And some we take for granted, like the small amount of 241Am that is in every smoke detector. At the beginning of this century, we are in a position where the prevalence and importance of some applications of nuclear science are pushing the basic nuclear science community for improved models and nuclear data. Yet, at the same time, the push by the basic nuclear science community to study nuclei that are farther and farther away from stability also offer new opportunities for many applications. This talk will look at several global security applications of nuclear science, summarizing current R&D and need for improved nuclear data It will also look at how applications of nuclear science, such as to medicine, will benefit from the push for more and more powerful radioactive ion beam facilities.

  3. Global Security, Medical Isotopes, and Nuclear Science

    SciTech Connect (OSTI)

    Ahle, Larry

    2007-10-26

    Over the past century basic nuclear science research has led to the use of radioactive isotopes into a wide variety of applications that touch our lives everyday. Some are obvious, such as isotopes for medical diagnostics and treatment. Others are less so, such as National/Global security issues. And some we take for granted, like the small amount of 241 Am that is in every smoke detector. At the beginning of this century, we are in a position where the prevalence and importance of some applications of nuclear science are pushing the basic nuclear science community for improved models and nuclear data. Yet, at the same time, the push by the basic nuclear science community to study nuclei that are farther and farther away from stability also offer new opportunities for many applications. This talk will look at several global security applications of nuclear science, summarizing current R and D and need for improved nuclear data It will also look at how applications of nuclear science, such as to medicine, will benefit from the push for more and more powerful radioactive ion beam facilities.

  4. Sandia National Laboratories Medical Isotope Reactor concept.

    SciTech Connect (OSTI)

    Coats, Richard Lee; Dahl, James J.; Parma, Edward J., Jr.

    2010-04-01

    This report describes the Sandia National Laboratories Medical Isotope Reactor and hot cell facility concepts. The reactor proposed is designed to be capable of producing 100% of the U.S. demand for the medical isotope {sup 99}Mo. The concept is novel in that the fuel for the reactor and the targets for the {sup 99}Mo production are the same. There is no driver core required. The fuel pins that are in the reactor core are processed on a 7 to 21 day irradiation cycle. The fuel is low enriched uranium oxide enriched to less than 20% {sup 235}U. The fuel pins are approximately 1 cm in diameter and 30 to 40 cm in height, clad with Zircaloy (zirconium alloy). Approximately 90 to 150 fuel pins are arranged in the core in a water pool {approx}30 ft deep. The reactor power level is 1 to 2 MW. The reactor concept is a simple design that is passively safe and maintains negative reactivity coefficients. The total radionuclide inventory in the reactor core is minimized since the fuel/target pins are removed and processed after 7 to 21 days. The fuel fabrication, reactor design and operation, and {sup 99}Mo production processing use well-developed technologies that minimize the technological and licensing risks. There are no impediments that prevent this type of reactor, along with its collocated hot cell facility, from being designed, fabricated, and licensed today.

  5. Plutonium Isotopic Gamma-Ray Analysis

    Energy Science and Technology Software Center (OSTI)

    1992-01-08

    The MGA8 (Multiple Group Analysis) program determines the relative abundances of plutonium and other actinide isotopes in different materials. The program analyzes spectra taken of such samples using a 4096-channel germanium (Ge) gamma-ray spectrometer. The code can be run in a one or two detector mode. The first spectrum, which is required and must be taken at a gain of 0.075 Kev/channel with a high resolution planar detector, contains the 0-300 Kev energy region. Themore » second spectrum, which is optional, must be taken at a gain of 0.25 Kev/channel; it becomes important when analyzing high burnup samples (concentration of Pu241 greater than one percent). Isotopic analysis precisions of one percent or better can be obtained, and no calibrations are required. The system also measures the abundances of U235, U238, Np237, and Am241. A special calibration option is available to perform a one-time peak-shape characterization when first using a new detector system.« less

  6. Plutonium Isotopic Gamma-Ray Analysis

    Energy Science and Technology Software Center (OSTI)

    1992-01-08

    The MGA8 (Multiple Group Analysis) program determines the relative abundances of plutonium and other actinide isotopes in different materials. The program analyzes spectra taken of such samples using a 4096-channel germanium (Ge) gamma-ray spectrometer. The code can be run in a one or two detector mode. The first spectrum, which is required and must be taken at a gain of 0.075 Kev/channel with a high resolution planar detector, contains the 0-300 Kev energy region. Themore »second spectrum, which is optional, must be taken at a gain of 0.25 Kev/channel; it becomes important when analyzing high burnup samples (concentration of Pu241 greater than one percent). Isotopic analysis precisions of one percent or better can be obtained, and no calibrations are required. The system also measures the abundances of U235, U238, Np237, and Am241. A special calibration option is available to perform a one-time peak-shape characterization when first using a new detector system.« less

  7. Supported palladium materials for isotope separation

    SciTech Connect (OSTI)

    Rutherford, W.M.; Ellis, R.E.; Abell, G.C.

    1988-01-21

    Several palladium packing materials were investigated for their suitability for use in the separation of hydrogen isotopes by displacement chromatography. The materials included palladium on Chromosorb and several formulations of palladium on commercially available alpha-alumina-based catalyst supports. All materials showed some degradation upon being subjected to repeated hydriding-dehydriding cycles; however, the degradation did not lead to unacceptably low permeability to gas flow. Dynamic performance of the packings was evaluated by displacement of deuterium with protium at several temperatures and flow rates. Isotopic exchange was generally rapid. However, high surface area packings (greater than 4 m/sup 2//g) yielded transition zones that were initially sharp, but had long ''tails'' at deuterium concentrations below 5%. Best results were obtained with a packing containing 48.2% palladium on Norton catalyst support No. SA5*21 (surface area = 0.33 m/sup 2//g). Improved performance was observed as the displacement temperature was increased to 80/sup 0/C from 22/sup 0/C. The slight decrease in equilibrium separation was more than offset by improved kinetics at the higher temperature. 19 figs., 6 tabs.

  8. Use of Stable Isotopes in Forensic Analysis of Microorganisms

    SciTech Connect (OSTI)

    Kreuzer-Martin, Helen W.; Hegg, Eric L.

    2012-01-18

    The use of isotopic signatures for forensic analysis of biological materials is well-established, and the same general principles that apply to interpretation of stable isotope content of C, N, O, and H apply to the analysis of microorganisms. Heterotrophic microorganisms derive their isotopic content from their growth substrates, which are largely plant and animal products, and the water in their culture medium. Thus the isotope signatures of microbes are tied to their growth environment. The C, N, O, and H isotope ratios of spores have been demonstrated to constitute highly discriminating signatures for sample matching. They can rule out specific samples of media and/or water as possible production media, and can predict isotope ratio ranges of the culture media and water used to produce a given sample. These applications have been developed and tested through analyses of approximately 250 samples of Bacillus subtilis spores and over 500 samples of culture media, providing a strong statistical basis for data interpretation. A Bayesian statistical framework for integrating stable isotope data with other types of signatures derived from microorganisms has been able to characterize the culture medium used to produce spores of various Bacillus species, leveraging isotopic differences in different medium types and demonstrating the power of data integration for forensic investigations.

  9. Isoscalar and neutron modes in the E 1 spectra of Ni isotopes...

    Office of Scientific and Technical Information (OSTI)

    Ni isotopes and the relevance of shell effects and the continuum Citation Details ... Ni isotopes and the relevance of shell effects and the continuum Authors: ...

  10. Isotopic fractionation associated with [NiFe]- and [FeFe]-hydrogenases...

    Office of Scientific and Technical Information (OSTI)

    Isotopic fractionation associated with NiFe- and FeFe-hydrogenases Citation Details In-Document Search Title: Isotopic fractionation associated with NiFe- and ...

  11. Process for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J.; Todd, Terry A.; Lewis, Leroy C.; Henscheid, Joseph P.

    2005-10-04

    The invention includes a method of separating isotopes from a mixture containing at least two isotopes in a solution. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the precipitate. The precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. The invention also includes a system for producing an actinium-225/bismuth-213 product.

  12. Isotope separation by photodissociation of Van der Waal's molecules

    DOE Patents [OSTI]

    Lee, Yuan T.

    1977-01-01

    A method of separating isotopes based on the dissociation of a Van der Waal's complex. A beam of molecules of a Van der Waal's complex containing, as one partner of the complex, a molecular species in which an element is present in a plurality of isotopes is subjected to radiation from a source tuned to a frequency which will selectively excite vibrational motion by a vibrational transition or through electronic transition of those complexed molecules of the molecular species which contain a desired isotope. Since the Van der Waal's binding energy is much smaller than the excitational energy of vibrational motion, the thus excited Van der Waal's complex dissociate into molecular components enriched in the desired isotope. The recoil velocity associated with vibrational to translational and rotational relaxation will send the separated molecules away from the beam whereupon the product enriched in the desired isotope can be separated from the constituents of the beam.

  13. Special isotope separation at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Hendrickson, P.D.

    1989-02-03

    The SIS facilities will include a Plutonium Processing Facility (PPF), a Laser Support Facility (LSF), and all associated equipment required for isotope separation. The SIS Plant will process fuel-grade plutonium into weapons-grade plutonium using Atomic Vapor Laser Isotope Separation (AVLIS) and supporting chemical processes. The AVLIS process uses precisely tuned visible laser light to selectively ionize or excite specific plutonium isotopes in a vapor stream. The ionized plutonium isotopes (Pu 240, Pu 238 and Pu 241) are then separated from the plutonium isotope of interest (Pu 239). Chemical processes are required to (1) prepare the AVLIS plutonium feed for processing, remove americium-241, and cast plutonium metal into forms that meet AVLIS processing requirements; (2) recover and, if required, purify the AVLIS plutonium product; and (3) recover and process the AVLIS separated by-products. This presentation describes the production facility and some of the plutonium processes.

  14. Helium isotopes and tectonics in southern Italy

    SciTech Connect (OSTI)

    Sano, Yuji; Wakita, Hiroshi ); Nuccio, M.P. ); Italiano, F.

    1989-06-01

    Geodynamic evolution of southern Italy can be understood within the framework of the Mediterranean-Alpine System. Subduction of a plate along the Sicily-Calabrian forearc under the Tyrrhenian Sea has been suggested by many geophysicists, although it is not yet confirmed and remains somewhat controversial. Helium isotope ratios provide useful information on the geotectonic structure of the region. The authors report here the {sup 3}H/{sup 4}He ratios of terrestrial gas samples from southern Italy. The observed {sup 3}He/{sup 4}He ratios are relatively high in the Eolian volcanic arc region and low in the other areas. Dichotomous explanations are presented. Firstly, volcanic arc-forearc hypothesis suggests the subduction along the Sicily-Calabrian forearc. Secondly, horizontal transport hypothesis is described based on the relationship between the ratios and radial distance from the recent spreading basin in Southern Tyrrhenian Sea.

  15. Penning trap mass measurements on nobelium isotopes

    SciTech Connect (OSTI)

    Dworschak, M.; Block, M.; Ackermann, D.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Vorobyev, G. K.; Audi, G.; Blaum, K.; Droese, C.; Marx, G.; Schweikhard, L.; Eliseev, S.; Ketter, J.; Fleckenstein, T.; Haettner, E.; Plass, W. R.; Scheidenberger, C.; Ketelaer, J.; Kluge, H.-J.

    2010-06-15

    The Penning trap mass spectrometer SHIPTRAP at GSI Darmstadt allows accurate mass measurements of radionuclides, produced in fusion-evaporation reactions and separated by the velocity filter SHIP from the primary beam. Recently, the masses of the three nobelium isotopes {sup 252-254}No were determined. These are the first direct mass measurements of transuranium elements, which provide new anchor points in this region. The heavy nuclides were produced in cold-fusion reactions by irradiating a PbS target with a {sup 48}Ca beam, resulting in production rates of the nuclei of interest of about one atom per second. In combination with data from decay spectroscopy our results are used to perform a new atomic-mass evaluation in this region.

  16. Compact hydrogen/helium isotope mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O.; McComas, David J.; Scime, Earl E.

    1996-01-01

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  17. Absolute photoneutron cross sections of Sm isotopes

    SciTech Connect (OSTI)

    Gheorghe, I.; Glodariu, T.; Utsunomiya, H.; Filipescu, D.; Nyhus, H.-T.; Renstrom, T.; Tesileanu, O.; Shima, T.; Takahisa, K.; Miyamoto, S.

    2015-02-24

    Photoneutron cross sections for seven samarium isotopes, {sup 144}Sm, {sup 147}Sm, {sup 148}Sm, {sup 149}Sm, {sup 150}Sm, {sup 152}Sm and {sup 154}Sm, have been investigated near neutron emission threshold using quasimonochromatic laser-Compton scattering γ-rays produced at the synchrotron radiation facility NewSUBARU. The results are important for nuclear astrophysics calculations and also for probing γ-ray strength functions in the vicinity of neutron threshold. Here we describe the neutron detection system and we discuss the related data analysis and the necessary method improvements for adapting the current experimental method to the working parameters of the future Gamma Beam System of Extreme Light Infrastructure - Nuclear Physics facility.

  18. Photolytic separation of isotopes in cryogenic solution

    DOE Patents [OSTI]

    Freund, Samuel M.; Maier, II, William B.; Holland, Redus F.; Beattie, Willard H.

    1985-01-01

    Separation of carbon isotopes by photolysis of CS.sub.2 in cryogenic solutions of nitrogen, krypton and argon with 206 nm light from an iodine resonance lamp is reported. The spectral distribution of the ultraviolet absorption depends on solvent. Thus, in liquid nitrogen the photolytic decomposition rate of .sup.13 CS.sub.2 is greater than that of .sup.12 CS.sub.2 (because the absorption of 206 nm radiation is greater for .sup.13 CS.sub.2), whereas in liquid krypton and liquid argon the reverse is true. The shift in ultraviolet spectrum is a general phenomenon readily characterized as a function of solvent polarizability, and exhibits behavior similar to that for vibrational transitions occurring in the infrared.

  19. Photolytic separation of isotopes in cryogenic solution

    DOE Patents [OSTI]

    Freund, S.M.; Maier, W.B. II; Holland, R.F.; Battie, W.H.

    Separation of carbon isotopes by photolysis of CS/sub 2/ in cryogenic solutions of nitrogen, krypton and argon with 206 nm light from an iodine resonance lamp is reported. The spectral distributionn of the ultraviolet absorption depends on solvent. Thus, in liquid nitrogen the photolytic decomposition rate of /sup 13/CS/sub 2/ is greater than that of /sup 12/CS/sub 2/ (because the absorption of 206 nm radiation is greater for /sup 13/CS/sub 2/), whereas in liquid krypton and liquid argon the reverse is true. The shift in ultraviolet spectrum is a general phenomenon readily characterized as a function of solvent polarizability, and exhibits behavior similar to that for vibrational transitions occurring in the infrared.

  20. Laser-isotope-separation technology. [Review; economics

    SciTech Connect (OSTI)

    Jensen, R.J.; Blair, L.S.

    1981-01-01

    The Molecular Laser Isotope Separation (MLIS) process currently under development is discussed as an operative example of the use of lasers for material processing. The MLIS process, which uses infrared and ultraviolet lasers to process uranium hexafluoride (UF/sub 6/) resulting in enriched uranium fuel to be used in electrical-power-producing nuclear reactor, is reviewed. The economics of the MLIS enrichment process is compared with conventional enrichment technique, and the projected availability of MLIS enrichment capability is related to estimated demands for U.S. enrichment service. The lasers required in the Los Alamos MLIS program are discussed in detail, and their performance and operational characteristics are summarized. Finally, the timely development of low-cost, highly efficient ultraviolet and infrared lasers is shownd to be the critical element controlling the ultimate deployment of MLIS uranium enrichment. 8 figures, 7 tables.

  1. Hydrogen Isotope Exchange Properties of Porous Solids Containing Hydrogen

    SciTech Connect (OSTI)

    HEUNG, LEUNGK.

    2004-08-18

    Porous solids such as activated alumina, silica and molecular sieves generally contain significant amounts of hydrogen atoms in the form of H2O or OH even at high temperature and low humidity environment. A significant amount of this hydrogen is available for reversible isotopic exchange. This exchange reaction is slow under normal conditions and does not render itself to practical applications. But if the exchange kinetics is improved this reaction has the potential to be used for tritium removal from gas streams or for hydrogen isotopic separation.The use of catalysts to improve the exchange kinetics between hydrogen isotope in the gas phase and that in the solid phase was investigated. Granules of alumina, silica and molecular sieve were coated with platinum or palladium as the catalyst. The granules were packed in a 2-cm diameter column for isotope exchange tests. Gas streams containing different concentrations of deuterium in nitrogen or argon were fed through the protium saturated column. Isotope concentration in column effluent was monitored to generate isotope break-through curves. The curves were analyzed to produce information on the kinetics and capacity of the material. The results showed that all materials tested provided some extent of isotope exchange but some were superior both in kinetics and capacity. This paper will present the test results.

  2. Direct analysis of air filter samples for alpha emitting isotopes

    SciTech Connect (OSTI)

    Mohagheghi, A.H.; Ghanbari, F.; Ebara, S.B.; Enghauser, M.E. [Sandia National Labs., Albuquerque, NM (United States); Bakhtiar, S.N. [Westinghouse WIPP, Carlsbad, NM (United States)

    1997-04-01

    The traditional method for determination of alpha emitting isotopes on air filters has been to process the samples by radiochemical methods. However, this method is too slow for cases of incidents involving radioactive materials where the determination of personnel received dose is urgent. A method is developed to directly analyze the air filters taken from personal and area air monitors. The site knowledge is used in combination with alpha spectral information to identify isotopes. A mathematical function is developed to estimate the activity for each isotope. The strengths and weaknesses of the method are discussed.

  3. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A.

    1984-05-01

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  4. Method for isotopic analysis of chlorinated organic compounds

    DOE Patents [OSTI]

    Holt, B.D.; Sturchio, N.C.

    1999-08-24

    The present invention provides a method for preparing a VOC sample for carbon and chlorine isotope ratio analysis by mass spectrometer. A VOC sample is placed in a combustion tube and reacted with CuO to form CO{sub 2} and CuCl. The CO{sub 2} is then extracted and analyzed for the carbon isotope ratio. The CuCl is separated from the excess CuO and reacted with CH{sub 3}I to form CH{sub 3}Cl, extracted and analyzed for chlorine isotope ratio. 9 figs.

  5. Shape coexistence and phase transitions in the platinum isotopes

    SciTech Connect (OSTI)

    Morales, Irving O.; Frank, Alejandro; Vargas, Carlos E.; Isacker, P. Van

    2008-08-15

    The matrix coherent-state approach of the interacting boson model with configuration mixing is used to study the geometry of the platinum isotopes. With a parameter set determined in previous studies, it is found that the absolute minimum of the potential for the Pt isotopes evolves from spherical to oblate and finally to prolate shapes when the neutron number decreases from N=126 (semi-magic) to N=104 (mid-shell). Shape coexistence is found in the isotopes {sup 182,184,186,188}Pt. A phase diagram is constructed that shows the coexistence region as a function of the number of bosons and the strength of the mixing parameter.

  6. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2007-06-25

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  7. Cost Estimate for Laser Isotope Separation for RIA

    SciTech Connect (OSTI)

    Scheibner, K

    2004-11-01

    Isotope enrichment of some elements is required in support of the Rare Isotope Accelerator (RIA) in order to obtain the beam intensities, source efficiencies and/or source lifetime required by RIA. The economics of using Atomic Vapor Laser Isotope Separation (AVLIS) technology as well as ElectroMagnetic (EM) separation technology has been evaluated. It is concluded that such an AVLIS would be about 10 times less expensive than a facility based on electromagnetic separation - $17 M versus $170 M. In addition, the AVLIS facility footprint would be about 10 times smaller, and operations would require about 4 years (including 2 years of startup) versus about 11 years for an EM facility.

  8. VELOCITY SELECTOR METHOD FOR THE SEPARATION OF ISOTOPES

    DOE Patents [OSTI]

    Britten, R.J.

    1957-12-31

    A velocity selector apparatus is described for separating and collecting an enriched fraction of the isotope of a particular element. The invention has the advantage over conventional mass spectrometers in that a magnetic field is not used, doing away with the attendant problems of magnetic field variation. The apparatus separates the isotopes by selectively accelerating the ionized constituents present in a beam of the polyisotopic substance that are of uniform kinetic energy, the acceleration being applied intermittently and at spaced points along the beam and in a direction normal to the direction of the propagation of the uniform energy beam whereby a transverse displacement of the isotopic constituents of different mass is obtained.

  9. Plutonium isotopic assay from alpha spectroscopy: A progress report

    SciTech Connect (OSTI)

    Baran, D.T.

    1995-12-31

    The Non-Destructive Assay (NDA) group at New Brunswick Laboratory (NBL) continues to develop and refine a computer program ALPHAFIT, a sophisticated peak-fitting routine for use in determining the isotopic abundances of Pu and U samples. The program uses up to seven parameters per peak fit and up to 12 peaks per region of interest to de-convolute typical complicated Pu a spectra. Preliminary results show decent fits for major peaks in the spectrum and calculated isotopic abundances of the major isotopes to {+-} 4%.

  10. Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility

    Office of Environmental Management (EM)

    Building 9204-3 | Department of Energy Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility Building 9204-3 Report of Survey of Oak Ridge Isotope Enrichment (Calutron) Facility Building 9204-3 The purpose of this document is to report the results of a survey conducted at the Isotope Enrichment Facility (IEF, Calutron, Building 9204-3) on the Y-12 Plant property at the Oak Ridge Site. The survey was conducted during the week of November 29, 1999. The primary purpose of the

  11. Scoping assessment on medical isotope production at the Fast Flux Test Facility

    SciTech Connect (OSTI)

    Scott, S.W.

    1997-08-29

    The Scoping Assessment addresses the need for medical isotope production and the capability of the Fast Flux Test Facility to provide such isotopes. Included in the discussion are types of isotopes used in radiopharmaceuticals, which types of cancers are targets, and in what way isotopes provide treatment and/or pain relief for patients.

  12. Stable isotope studies. Final report, March 1, 1972--February 29, 1992

    SciTech Connect (OSTI)

    Ishida, T.

    1992-10-01

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  13. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Silicates In The Larderello Geothermal Field, Italy Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The...

  14. Chemical and light-stable isotope characteristics of waters from...

    Open Energy Info (EERE)

    light-stable isotope characteristics of waters from the raft river geothermal area and environs, Cassia County, Idaho, Box Elder county, Utah Jump to: navigation, search OpenEI...

  15. Y-12 plant prepares to separate lithium isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plant prepares to separate lithium isotopes The Y-12 National Security Complex is one of three major Manhattan Project sites in Oak Ridge. Y-12 is the nation's sole storage...

  16. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR ...

  17. Isotope Transport and Exchange within the Coso Geothermal System...

    Open Energy Info (EERE)

    and the nearby Coso Hot Springs using finite element models of single-phase, variable-density fluid flow, conductive- convective heat transfer, fluid-rock isotope exchange, and...

  18. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    isotope ratios in gases of thirty hot springs and geothermal wells and of five natural gas wells in the western United States show no relationship to regional conductive heat...

  19. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    of 36Cl- as a tracer isotope in geothermal systems. References F.M. Phillips, Fraser E. Goff, Francois D. Vuataz, H.W. Bentley, H.E. Gove (1984) 36Cl as a tracer in geothermal...

  20. RESOLUTION OF URANIUM ISOTOPES WITH KINETIC PHOSPHORESCENCE ANALYSIS

    SciTech Connect (OSTI)

    Miley, Sarah M.; Hylden, Anne T.; Friese, Judah I.

    2013-04-01

    This study was conducted to test the ability of the Chemchek Kinetic Phosphorescence Analyzer Model KPA-11 with an auto-sampler to resolve the difference in phosphorescent decay rates of several different uranium isotopes, and therefore identify the uranium isotope ratios present in a sample. Kinetic phosphorescence analysis (KPA) is a technique that provides rapid, accurate, and precise determination of uranium concentration in aqueous solutions. Utilizing a pulsed-laser source to excite an aqueous solution of uranium, this technique measures the phosphorescent emission intensity over time to determine the phosphorescence decay profile. The phosphorescence intensity at the onset of decay is proportional to the uranium concentration in the sample. Calibration with uranium standards results in the accurate determination of actual concentration of the sample. Different isotopes of uranium, however, have unique properties which should result in different phosphorescence decay rates seen via KPA. Results show that a KPA is capable of resolving uranium isotopes.

  1. Enforcement Letter, International Isotopes Idaho Inc- August 20, 1999

    Broader source: Energy.gov [DOE]

    Issued to International Isotopes Idaho, Inc. related to the Relocation of an Irradiated Pellet at the Test Reactor Area Hot Cell Facility at the Idaho National Engineering and Environmental Laboratory

  2. Isotopic Analysis At Separation Creek Area (Van Soest, Et Al...

    Open Energy Info (EERE)

    Usefulness useful DOE-funding Unknown References M. C. van Soest, B. M. Kennedy, W. C. Evans, R. H. Mariner (2002) Mantle Helium And Carbon Isotopes In Separation Creek...

  3. FY09 PROGRESS: MULTI-ISOTOPE PROCESS (MIP) MONITOR

    SciTech Connect (OSTI)

    Schwantes, Jon M.; Orton, Christopher R.; Fraga, Carlos G.; Christensen, Richard; Laspe, Amy R.; Ward, Rebecca M.

    2009-10-18

    Model and experimental estimates of the Multi-Isotope Process Monitor performance for determining burnup after dissolution and acid concentration during solvent extraction steps during reprocessing of spent nuclear fuel are presented.

  4. An isotopic study of the Coso, California, geothermal area |...

    Open Energy Info (EERE)

    and vicinity and were analyzed for major chemical constituents and deltaD and delta18O. Non-thermal ground waters from the Coso Range were found to be isotopically heavier...

  5. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G.; Roberts, George W.

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  6. A Method to Distill Hydrogen Isotopes from Lithium | Princeton...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Distill Hydrogen Isotopes from Lithium This white paper outlines a method for the removal of tritium and deuterium from liquid lithium. The method is based on rapid or flash ...

  7. Uranium accountancy in Atomic Vapor Laser Isotope Separation

    SciTech Connect (OSTI)

    Carver, R.D.

    1986-01-01

    The AVLIS program pioneers the large scale industrial application of lasers to produce low cost enriched uranium fuel for light water reactors. In the process developed at Lawrence Livermore National Laboratory, normal uranium is vaporized by an electron beam, and a precisely tuned laser beam selectively photo-ionizes the uranium-235 isotopes. These ions are moved in an electromagnetic field to be condensed on the product collector. All other uranium isotopes remain uncharged and pass through the collector section to condense as tails. Tracking the three types of uranium through the process presents special problems in accountancy. After demonstration runs, the uranium on the collector was analyzed for isotopic content by Battelle Pacific Northwest Laboratory. Their results were checked at LLNL by analysis of parallel samples. The differences in isotopic composition as reported by the two laboratories were not significant.

  8. Research and Medical Isotope Reactor Supply | Y-12 National Security...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research and Medical ... Research and Medical Isotope Reactor Supply Our goal is to fuel research and test reactors with low-enriched uranium. Y-12 tops the short list of the...

  9. Isotopic Analysis- Fluid At Dixie Valley Geothermal Area (Kennedy...

    Open Energy Info (EERE)

    suggest that helium isotopes are the best and possibly the only indication of deep permeability where high temperature fluids are masked beneath a cold reservoir. Notes 3He4He...

  10. Method for the simultaneous preparation of radon-211, xenon-125, xenon-123, astatine-211, iodine-125 and iodine-123

    DOE Patents [OSTI]

    Mirzadeh, S.; Lambrecht, R.M.

    1985-07-01

    The invention relates to a practical method for commercially producing radiopharmaceutical activities and, more particularly, relates to a method for the preparation of about equal amount of Radon-211 (/sup 211/Rn) and Xenon-125 (/sup 125/Xe) including a one-step chemical procedure following an irradiation procedure in which a selected target of Thorium (/sup 232/Th) or Uranium (/sup 238/U) is irradiated. The disclosed method is also effective for the preparation in a one-step chemical procedure of substantially equal amounts of high purity /sup 123/I and /sup 211/At. In one preferred arrangement of the invention almost equal quantities of /sup 211/Rn and /sup 125/Xe are prepared using a onestep chemical procedure in which a suitably irradiated fertile target material, such as thorium-232 or uranium-238, is treated to extract those radionuclides from it. In the same one-step chemical procedure about equal quantities of /sup 211/At and /sup 123/I are prepared and stored for subsequent use. In a modified arrangement of the method of the invention, it is practiced to separate and store about equal amounts of only /sup 211/Rn and /sup 125/Xe, while preventing the extraction or storage of the radionuclides /sup 211/At and /sup 123/I.

  11. Isotope Production at the Hanford Site in Richland, Washington

    SciTech Connect (OSTI)

    Ammoniums

    1999-06-01

    This report was prepared in response to a request from the Nuclear Energy Research Advisory Committee (NERAC) subcommittee on ''Long-Term Isotope Research and Production Plans.'' The NERAC subcommittee has asked for a reply to a number of questions regarding (1) ''How well does the Department of Energy (DOE) infrastructure sme the need for commercial and medical isotopes?'' and (2) ''What should be the long-term role of the federal government in providing commercial and medical isotopes?' Our report addresses the questions raised by the NERAC subcommittee, and especially the 10 issues that were raised under the first of the above questions (see Appendix). These issues are related to the isotope products offered by the DOE Isotope Production Sites, the capabilities and condition of the facilities used to produce these products, the management of the isotope production programs at DOE laboratories, and the customer service record of the DOE Isotope Production sites. An important component of our report is a description of the Fast Flux Test Facility (FFTF) reactor at the Hbford Site and the future plans for its utilization as a source of radioisotopes needed by nuclear medicine physicians, by researchers, and by customers in the commercial sector. In response to the second question raised by the NERAC subcommittee, it is our firm belief that the supply of isotopes provided by DOE for medical, industrial, and research applications must be strengthened in the near future. Many of the radioisotopes currently used for medical diagnosis and therapy of cancer and other diseases are imported from Canada, Europe, and Asia. This situation places the control of isotope availability, quality, and pricing in the hands of non-U.S. suppliers. It is our opinion that the needs of the U.S. customers for isotopes and isotope products are not being adequately served, and that the DOE infrastructure and facilities devoted to the supply of these products must be improved This perception forms one of the fundamental bases for our proposal that the FFTF, which is currently in a standby condition, be reactivated to supply nuclear services and products such as radioisotopes needed by the U.S. medical, industrial, and research communities.

  12. Research and Medical Isotope Reactor Supply | Y-12 National Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complex Research and Medical ... Research and Medical Isotope Reactor Supply Our goal is to fuel research and test reactors with low-enriched uranium. Y-12 tops the short list of the world's most secure, reliable uranium feedstock suppliers for dozens of research and test reactors on six continents. These reactors can be used to test materials, irradiate new reactor fuel designs and produce medical isotopes for diagnostic and therapeutic purposes, as examples. The LEU is used to fabricate

  13. Heavy neodymium isotopes in the interacting boson (IBA-2) model

    SciTech Connect (OSTI)

    Giannatiempo, A.

    2011-08-15

    The N>82 even neodymium isotopes were studied in the framework of the IBA-2 model. The analysis was performed by using a very schematic Hamiltonian, particularly suited to investigate the U(5) {yields} SU(3) transition. The evolution of the excitation energy patterns and of the spectroscopic properties along the isotopic chain can be correctly reproduced when the role played by states of mixed symmetry character is also taken into account.

  14. Establishment of the Heavy Isotopes Lead Materials Management Organization

    Office of Scientific and Technical Information (OSTI)

    (LMMO) (Conference) | SciTech Connect Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) Citation Details In-Document Search Title: Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) Authors: Patton, Bradley D [1] ; Robinson, Sharon M [1] ; Sherman, Steven R [1] + Show Author Affiliations ORNL [ORNL Publication Date: 2013-01-01 OSTI Identifier: 1110926 DOE Contract Number: DE-AC05-00OR22725 Resource Type: Conference Resource

  15. Heavy Isotopes Lead Materials Management Organization (LMMO) Update

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Heavy Isotopes Lead Materials Management Organization (LMMO) Update Citation Details In-Document Search Title: Heavy Isotopes Lead Materials Management Organization (LMMO) Update Authors: Patton, Bradley D [1] ; Robinson, Sharon M [1] ; Sherman, Steven R [1] ; Bone, Sherri [2] + Show Author Affiliations ORNL U.S. Department of Energy, NA Publication Date: 2014-01-01 OSTI Identifier: 1156744

  16. Separation of the isotopes of boron by chemical exchange reactions

    DOE Patents [OSTI]

    McCandless, Frank P.; Herbst, Ronald S.

    1995-01-01

    The isotopes of boron, .sup.10 B and .sup.11 B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF.sub.3 and a liquid BF.sub.3 . donor molecular addition complex formed between BF.sub.3 gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone.

  17. Isotopic evidence for a martian regolith component in martian meteorites.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Isotopic evidence for a martian regolith component in martian meteorites. Citation Details In-Document Search Title: Isotopic evidence for a martian regolith component in martian meteorites. No abstract prepared. Authors: Rao, M.N. ; Nyquist, L.E. ; Bogard, D.D. ; Garrison, D.H. ; Sutton, S. [1] ; UC) [2] + Show Author Affiliations (NASA JSC) ( Publication Date: 2009-03-23 OSTI Identifier: 1009059 Resource Type: Conference Resource Relation: Conference: Lunar

  18. Ab Initio Calculations of Even Oxygen Isotopes with Chiral

    Office of Scientific and Technical Information (OSTI)

    Two-Plus-Three-Nucleon Interactions (Journal Article) | SciTech Connect Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Citation Details In-Document Search Title: Ab Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Authors: Hergert, H. ; Binder, S. ; Calci, A. ; Langhammer, J. ; Roth, R. Publication Date: 2013-06-10 OSTI Identifier: 1102833 Type: Publisher's Accepted Manuscript Journal Name: Physical

  19. Separation of the isotopes of boron by chemical exchange reactions

    DOE Patents [OSTI]

    McCandless, F.P.; Herbst, R.S.

    1995-05-30

    The isotopes of boron, {sup 10}B and {sup 11}B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF{sub 3} and a liquid BF{sub 3} donor molecular addition complex formed between BF{sub 3} gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone. 1 Fig.

  20. GUM Analysis for TIMS and SIMS Isotopic Ratios in Graphite

    SciTech Connect (OSTI)

    Heasler, Patrick G.; Gerlach, David C.; Cliff, John B.; Petersen, Steven L.

    2007-04-01

    This report describes GUM calculations for TIMS and SIMS isotopic ratio measurements of reactor graphite samples. These isotopic ratios are used to estimate reactor burn-up, and currently consist of various ratios of U, Pu, and Boron impurities in the graphite samples. The GUM calculation is a propagation of error methodology that assigns uncertainties (in the form of standard error and confidence bound) to the final estimates.

  1. HEU Minimization and the Reliable Supply of Medical Isotopes Nuclear

    National Nuclear Security Administration (NNSA)

    Security Summit: Fact Sheet | National Nuclear Security Administration HEU Minimization and the Reliable Supply of Medical Isotopes Nuclear Security Summit: Fact Sheet March 26, 2012 Molybdenum-99 (Mo-99) is used to produce technetium-99m (Tc-99m), a medical isotope that is used in about 100,000 diagnostic medical procedures globally every day. Today, Mo-99 is produced at aging facilities in Europe, Canada and South Africa primarily using highly-enriched uranium (HEU) - a weapons-usable

  2. Unusual superconducting isotope effect in the presence of a quantum

    Office of Scientific and Technical Information (OSTI)

    criticality (Journal Article) | SciTech Connect Unusual superconducting isotope effect in the presence of a quantum criticality Citation Details In-Document Search This content will become publicly available on May 23, 2017 Title: Unusual superconducting isotope effect in the presence of a quantum criticality Authors: Kedem, Yaron ; Zhu, Jian-Xin ; Balatsky, Alexander V. Publication Date: 2016-05-23 OSTI Identifier: 1254211 Type: Publisher's Accepted Manuscript Journal Name: Physical Review

  3. Isotopic discontinuities in ground water beneath Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Stuckless, J.S.; Whelan, J.F.; Steinkampf, W.C.

    1991-05-01

    Analytical data for stable isotopes in ground water from beneath Yucca Mountain, when examined in map view, show areal patterns of heterogeneity that can be interpreted in terms of mixing of at least three end members. One end member must be isotopically heavy in terms of hydrogen and oxygen and have a young apparent {sup 14}C age such as water found at the north end of Yucca Mountain beneath Fortymile Wash. A second end member must contain isotopically heavy carbon and have an old apparent {sup 14}C age such as water from the Paleozoic aquifer. The third end member cannot be tightly defined. It must be isotopically lighter than the first with respect of hydrogen and oxygen and be intermediate to the first and second end members with respect to both apparent {sup 14}C age and {delta}{sup 13}C. The variable isotopic compositions of hydrogen and oxygen indicate that two of the end members are waters, but the variable carbon isotopic composition could represent either a third water end member or reaction of water with a carbon-bearing solids such as calcite. 15 refs., 4 figs., 1 tab.

  4. The Atomic Vapor Laser Isotope Separation Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management`s position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  5. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation, and plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the elective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to form an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of dvelopment, cost, advantages and drawbacks of the five processes, (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  6. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the selective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to from an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of development, cost, advantages and drawbacks of the five processes (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  7. IUPAC Periodic Table of Isotopes for the Educational Community

    SciTech Connect (OSTI)

    Holden N. E.; Holden,N.E.; Coplen,T.B.

    2012-07-15

    John Dalton first proposed the concept of atomic weights of the elements in the first decade of the nineteenth century. These atomic weights of the chemical elements were thought of as constants of nature, similar to the speed of light. Dmitri Mendeleev arranged the atomic weights of the elements in ascending order of value and used the systematic variation of their chemical properties to produce his Periodic Table of the Elements in 1869. Measurement of atomic weight values became an important chemical activity for a century and a half. Theodore Richards received a Noble Prize for his work in this area. In 1913, Fredrick Soddy found a species of radium, which had an atomic weight value of 228, compared to the familiar radium gas value of 226. Soddy coined the term 'isotope' (Greek for 'in the same place') to account for this second atomic weight value in the radium position of the Periodic Table. Both of these isotopes of radium are radioactive. Radioactive isotopes are energetically unstable and will decay (disintegrate) over time. The time it takes for one half of a sample of a given radioactive isotope to decay is the half-life of that isotope. In addition to having different atomic weight values, radium-226 and radium-228 also have different half-life values. Around the same time as Soddy's work, J.J. Thomson (discoverer of the electron) identified two stable (non-radioactive) isotopes of the same element, neon. Over the next 40 years, the majority of the known chemical elements were found to have two or more stable (or long-lived radioactive isotopes that contribute significantly to the determination of the atomic weights of the elements).

  8. Boosting Production of Radioisotopes for Diagnostics and Therapeutics: Upgrades to Brookhaven Lab's isotope production and research facility increase the yield of key medical isotopes

    Broader source: Energy.gov [DOE]

    The DOE Office of Science’s Nuclear Physics Isotope Development and Production for Research and Applications program (DOE Isotope Program) seeks to make critical isotopes more readily available for energy, medical, and national security applications and for basic research. Under this program, scientists, engineers, and technicians at DOE’s Brookhaven National Laboratory recently completed the installation of a beam raster (or scanning) system designed to increase the yield of critical isotopes produced at the Brookhaven Linac Isotope Producer (BLIP), the Lab’s radioisotope production and research facility, in operation since 1972.

  9. Kinetic Isotopic Fractionation During Diffusion of Ionic Speciesin Water

    SciTech Connect (OSTI)

    Richter, Frank M.; Mendybaev, Ruslan A.; Christensen, John; Hutcheon, Ian D.; Williams, Ross W.; Sturchio, Neil C.; Beloso Jr.,Abelardo D.

    2005-06-09

    Experiments specifically designed to measure the ratio of the diffusivities of ions dissolved in water were used to determine D{sub Li}/D{sub K}, D{sub 7{sub Li}}/D{sub 6{sub Li}}, D{sub 25{sub Mg}}/D{sub 24{sub Mg}}, D{sub 26{sub Mg}}/D{sub 25{sub Mg}}, and D{sub 37{sub Cl}}/D{sub 35{sub Cl}}. The measured ratio of the diffusion coefficients for Li and K in water (D{sub Li}/D{sub K} = 0.6) is in good agreement with published data, providing evidence that the experimental design being used resolves the relative mobility of ions with adequate precision to also be used for determining the fractionation of isotopes by diffusion in water. In the case of Li we found measurable isotopic fractionation associated with the diffusion of dissolved LiCl (D{sub 7{sub Li}}/D{sub 6{sub Li}} = 0.99772 {+-} 0.00026). This difference in the diffusion coefficient of {sup 7}Li compared to {sup 6}Li is significantly less than reported in an earlier study, a difference we attribute to the fact that in the earlier study Li diffused through a membrane separating the water reservoirs. Our experiments involving Mg diffusing in water found no measurable isotopic fractionation (D{sub 25{sub Mg}}/D{sub 24{sub Mg}} = 1.00003 {+-} 0.00006). Cl isotopes were fractionated during diffusion in water (D{sub 37{sub Cl}}/D{sub 35{sub Cl}} = 0.99857 {+-} 0.00080) whether or not the co-diffuser (Li or Mg) was isotopically fractionated. The isotopic fractionation associated with the diffusion of ions in water is much smaller than values we found previously for the isotopic fractionation of Li and Ca isotopes by diffusion in molten silicate liquids. A major distinction between water and silicate liquids is that water, being a polar liquid, surrounds dissolved ions with hydration shells, which very likely play an important but still poorly understood role in reducing isotopic fractionation associated with diffusion.

  10. ORNL-5489 Radon and Radon Daughter

    Office of Legacy Management (LM)

    ... in resolution when helium is used as a chamber fill gas. ... Department of Energy, 376 Hudson Street, New York, NY 10014 Jack Healy, Office of Environmental Policy Analysis, Los ...

  11. A New Bench-Top Approach to Isotopic Purification of 244Pu

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liezers, Martin; Farmer, Orville T.; Thomas, Linda MP; Hager, George J.; Eiden, Gregory C.

    2016-03-01

    A new approach to isotopic purification has been developed and applied to the production of a small quantity of 244Pu with an isotopic purity >99.996 %, as compared against the standard 244Pu available that displays an isotopic purity of 97.87 %. The presence of Pu isotopes 239Pu, 240Pu, 241Pu and 242Pu have been greatly reduced, allowing for higher spiking levels of the isotopically purified 244Pu tracer. Details of the isotopic purification process will be described along with the effect this improved Pu tracer could have on analytical Pu mass spectrometry measurements.

  12. System for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J. [Idaho Falls, ID; Todd, Terry A. [Aberdeen, ID; Lewis, Leroy C. [Idaho Falls, ID; Henscheid, Joseph P. [Idaho Falls, ID

    2009-08-04

    A method of separating isotopes from a mixture containing at least two isotopes in a solution is disclosed. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material containing thorium-229 and thorium-232, and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the thorium iodate precipitate. The thorium iodate precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid, which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. A system for producing an actinium-225/bismuth-213 product is also disclosed.

  13. Natural mercury isotope variation in coal deposits and organic soils

    SciTech Connect (OSTI)

    Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie

    2008-11-15

    There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

  14. The use of carbon stable isotope ratios in drugs characterization

    SciTech Connect (OSTI)

    Magdas, D. A. Cristea, G. Bot, A. Mirel, V.

    2013-11-13

    Isotopic Ratio Mass Spectrometry (IRMS) is an effective toll to be used for drug product authentication. The isotopic composition could be used to assist in the differentiation between batches of drugs and assist in the identification of counterfeit materials on the market. Only two factors affect the isotopic ratios in pharmaceutical components: the isotopic composition of the raw materials and the synthetic processes performed upon them. Counterfeiting of pharmaceutical drugs threatens consumer confidence in drug products companies' economical well-being. In this preliminary study, the analyzed samples consist in two types of commercially available analgesics, which were purchases from Romanian pharmacies. Differences in δ{sup 13}C between batches from −29.7 to −31.6% were observed, demonstrating that this method can be used to differentiate among individual drug batches and subsequently identify counterfeits on the market. On the other hand, carbon isotopic ratios differences among producers were recorded, the variations being between −31.3 to −34.9% for the same type of analgesic, but from different manufactures.

  15. Medical Isotope Production Analyses In KIPT Neutron Source Facility

    SciTech Connect (OSTI)

    Talamo, Alberto; Gohar, Yousry

    2016-01-01

    Medical isotope production analyses in Kharkov Institute of Physics and Technology (KIPT) neutron source facility were performed to include the details of the irradiation cassette and the self-shielding effect. An updated detailed model of the facility was used for the analyses. The facility consists of an accelerator-driven system (ADS), which has a subcritical assembly using low-enriched uranium fuel elements with a beryllium-graphite reflector. The beryllium assemblies of the reflector have the same outer geometry as the fuel elements, which permits loading the subcritical assembly with different number of fuel elements without impacting the reflector performance. The subcritical assembly is driven by an external neutron source generated from the interaction of 100-kW electron beam with a tungsten target. The facility construction was completed at the end of 2015, and it is planned to start the operation during the year of 2016. It is the first ADS in the world, which has a coolant system for removing the generated fission power. Argonne National Laboratory has developed the design concept and performed extensive design analyses for the facility including its utilization for the production of different radioactive medical isotopes. 99Mo is the parent isotope of 99mTc, which is the most commonly used medical radioactive isotope. Detailed analyses were performed to define the optimal sample irradiation location and the generated activity, for several radioactive medical isotopes, as a function of the irradiation time.

  16. Isotopically Enriched Films and Nanostructures by Ultrafast Pulsed Laser Deposition

    SciTech Connect (OSTI)

    Peter Pronko

    2004-12-13

    This project involved a systematic study to apply newly discovered isotopic enrichment effects in laser ablation plumes to the fabrication of isotopically engineered thin films, superlattices, and nanostructures. The approach to this program involved using ultrafast lasers as a method for generating ablated plasmas that have preferentially structured isotopic content in the body of the ablation plasma plumes. In examining these results we have attempted to interpret the observations in terms of a plasma centrifuge process that is driven by the internal electro-magnetic fields of the plasma itself. The research plan involved studying the following phenomena in regard to the ablation plume and the isotopic mass distribution within it: (1) Test basic equations of steady state centrifugal motion in the ablation plasma. (2) Investigate angular distribution of ions in the ablation plasmas. (3) Examine interactions of plasma ions with self-generated magnetic fields. (3) Investigate ion to neutral ratios in the ablation plasmas. (5) Test concepts of plasma pumping. (6) Fabricate isotopically enriched nanostructures.

  17. Isotope Production and Distribution Program`s Fiscal Year 1997 financial statement audit

    SciTech Connect (OSTI)

    1998-03-27

    The Department of Energy Isotope Production and Distribution Program mission is to serve the national need for a reliable supply of isotope products and services for medicine, industry and research. The program produces and sells hundreds of stable and radioactive isotopes that are widely utilized by domestic and international customers. Isotopes are produced only where there is no U.S. private sector capability or other production capacity is insufficient to meet U.S. needs. The Department encourages private sector investment in new isotope production ventures and will sell or lease its existing facilities and inventories for commercial purposes. The Isotope Program reports to the Director of the Office of Nuclear Energy, Science and Technology. The Isotope Program operates under a revolving fund established by the Fiscal Year (FY) 1990 Energy and Water Appropriations Act and maintains financial viability by earning revenues from the sale of isotopes and services and through annual appropriations. The FY 1995 Energy and Water Appropriations Act modified predecessor acts to allow prices charged for Isotope Program products and services to be based on production costs, market value, the needs of the research community, and other factors. Although the Isotope Program functions as a business, prices set for small-volume, high-cost isotopes that are needed for research purposes may not achieve full-cost recovery. As a result, isotopes produced by the Isotope Program for research and development are priced to provide a reasonable return to the U.S. Government without discouraging their use. Commercial isotopes are sold on a cost-recovery basis. Because of its pricing structure, when selecting isotopes for production, the Isotope Program must constantly balance current isotope demand, market conditions, and societal benefits with its determination to operate at the lowest possible cost to U.S. taxpayers. Thus, this report provides a financial analysis of this situation.

  18. Simple, rapid method for the preparation of isotopically labeled formaldehyde

    DOE Patents [OSTI]

    Hooker, Jacob Matthew; Schonberger, Matthias; Schieferstein, Hanno; Fowler, Joanna S.

    2011-10-04

    Isotopically labeled formaldehyde (*C.sup..sctn.H.sub.2O) is prepared from labeled methyl iodide (*C.sup..sctn.H.sub.3I) by reaction with an oxygen nucleophile having a pendant leaving group. The mild and efficient reaction conditions result in good yields of *C.sup..sctn.H.sub.2O with little or no *C isotopic dilution. The simple, efficient production of .sup.11CH.sub.2O is described. The use of the .sup.11CH.sub.2O for the formation of positron emission tomography tracer compounds is described. The reaction can be incorporated into automated equipment available to radiochemistry laboratories. The isotopically labeled formaldehyde can be used in a variety of reactions to provide radiotracer compounds for imaging studies as well as for scintillation counting and autoradiography.

  19. Rare Isotopes in Cosmic Explosions and Accelerators on Earth

    ScienceCinema (OSTI)

    Schatz, Hendrick [Michigan State University, East Lansing, Michigan, United States

    2010-01-08

    Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

  20. METHOD TO TEST ISOTOPIC SEPARATION EFFICIENCY OF PALLADIUM PACKED COLUMNS

    SciTech Connect (OSTI)

    Heung, L; Gregory Staack, G; James Klein, J; William Jacobs, W

    2007-06-27

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam use, were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages using the test results. The effects of column diameter, metal foam and gas flow rate were identified.

  1. Tests of isotopic separation efficiency of palladium packed columns

    SciTech Connect (OSTI)

    Heung, L. K.; Staack, G. C.; Klein, J. E.; Jacobs, W. D.

    2008-07-15

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam presence were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages based on the test results. The effects of column diameter, metal foam presence and gas flow rate were identified. (authors)

  2. Evaluation of repeated measurements of radon-222 concentrations in well water sampled from bedrock aquifers of the Piedmont near Richmond, Virginia, USA: Effects of lithology and well characteristics

    SciTech Connect (OSTI)

    Harris, Shelley A. . E-mail: saharris@vcu.edu; Billmeyer, Ernest R.; Robinson, Michael A.

    2006-07-15

    Radon ({sup 222}Rn) concentrations in 26 ground water wells of two distinct lithologies in the Piedmont of Virginia were measured to assess variation in ground water radon concentrations (GWRC), to evaluate differences in concentrations related to well characteristics, lithology, and spatial distributions, and to assess the feasibility of predicting GWRC. Wells were sampled in accordance with American Public Health Association Method 7500 Rn-B, with modifications to include a well shaft profile analysis that determined the minimum purge time sufficient to remove the equivalent of one column of water from each well. Statistically significant differences in GWRC were found in the Trssu (1482{+-}1711 pCi/L) and Mpg (7750{+-}5188 pCi/L) lithologies, however, no significant differences were found among GWRC at each well over time. Using multiple regression, 86% of the variability (R {sup 2}) in the GWRC was explained by the lithology, latitudinal class, and water table elevation of the wells. The GWRC in a majority of the wells studied exceed US Environmental Protection Agency designated maximum contaminant level and AMCL. Results support modifications to sampling procedures and indicate that, in previous studies, variations in GWRC concentrations over time may have been due in part to differences in sampling procedures and not in source water.

  3. Lesson 3 - Atoms and Isotopes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 - Atoms and Isotopes Lesson 3 - Atoms and Isotopes You've probably heard people refer to nuclear energy as "atomic energy." Why? Nuclear energy is the energy that is stored in the bonds of atoms, inside the nucleus. Nuclear power plants are designed to capture this energy as heat and convert it to electricity. This lesson looks closely at what atoms are and how atoms store energy. This lesson covers the following topics: Matter Molecules Elements Chemical reaction Periodic table The

  4. Interactions of Hydrogen Isotopes and Oxides with Metal Tubes

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2008-08-01

    Understanding and accounting for interaction of hydrogen isotopes and their oxides with metal surfaces is important for persons working with tritium systems. Reported data from several investigators have shown that the processes of oxidation, adsorption, absorption, and permeation are all coupled and interactive. A computer model has been developed for predicting the interaction of hydrogen isotopes and their corresponding oxides in a flowing carrier gas stream with the walls of a metallic tube, particularly at low hydrogen concentrations. An experiment has been constructed to validate the predictive model. Predictions from modeling lead to unexpected experiment results.

  5. Equations of state and phase diagrams of hydrogen isotopes

    SciTech Connect (OSTI)

    Urlin, V. D.

    2013-11-15

    A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.

  6. Atomic vapor laser isotope separation using resonance ionization

    SciTech Connect (OSTI)

    Comaskey, B.; Crane, J.; Erbert, G.; Haynam, C.; Johnson, M.; Morris, J.; Paisner, J.; Solarz, R.; Worden, E.

    1986-09-01

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power-reactor fuel has been under development for over 10 years. In June 1985, the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for enriched uranium. Resonance photoionization is the heart of the AVLIS process. We discuss those fundamental atomic parameters that are necessary for describing isotope-selective resonant multistep photoionization along with the measurement techniques that we use. We illustrate the methodology adopted with examples of other elements that are under study in our program.

  7. Isotope Effects and Helium Retention Behavior in Vanadium Tritide

    SciTech Connect (OSTI)

    Bowman, Jr., R. C.; Attalla, A.; Craft, B. D.

    1985-04-01

    The relaxation times of the H, T, and 3He nuclei have been measured in vanadium hydride and tritide samples. Substantial isotope effects in both the phase transition temperatures and diffusion parameters have been found. When compared to hydrides, the tritide samples have lower transition temperatures and faster mobilities. The differences in the occupancies of the interstitial sites are largely responsible for these isotope effects. Most of the helium atoms generated by tritium decay remain trapped in microscopic bubbles formed with the VTx lattice. Evidence is presented for the gradual growth of the helium bubbles over periods of hundreds of days.

  8. Third minima in thorium and uranium isotopes in a self-consistent...

    Office of Scientific and Technical Information (OSTI)

    Third minima in thorium and uranium isotopes in a self-consistent theory Title: Third minima in thorium and uranium isotopes in a self-consistent theory Authors: McDonnell, J. D. ; ...

  9. Isotope enrichment by frequency-tripled temperature tuned neodymium laser photolysis of formaldehyde

    DOE Patents [OSTI]

    Marling, John B.

    1977-01-01

    Enrichment of carbon, hydrogen and/or oxygen isotopes by means of isotopically selective photo-predissociation of formaldehyde is achieved by irradiation provided by a frequency-tripled, temperature tuned neodymium laser.

  10. Dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources

    DOE Patents [OSTI]

    Barty, Christopher P.J.

    2013-02-05

    A dual isotope notch observer for isotope identification, assay and imaging with mono-energetic gamma-ray sources includes a detector arrangement consists of three detectors downstream from the object under observation. The latter detector, which operates as a beam monitor, is an integrating detector that monitors the total beam power arriving at its surface. The first detector and the middle detector each include an integrating detector surrounding a foil. The foils of these two detectors are made of the same atomic material, but each foil is a different isotope, e.g., the first foil may comprise U235 and second foil may comprise U238. The integrating detectors surrounding these pieces of foil measure the total power scattered from the foil and can be similar in composition to the final beam monitor. Non-resonant photons will, after calibration, scatter equally from both foils.

  11. Method for enriching a middle isotope using vibration-vibration pumping

    DOE Patents [OSTI]

    Rich, Joseph W.; Homicz, Gregory F.; Bergman, Richard C.

    1989-01-01

    Method for producing isotopically enriched material by vibration-vibration excitation of gaseous molecules wherein a middle mass isotope of an isotopic mixture including lighter and heavier mass isotopes preferentially populates a higher vibrational mode and chemically reacts to provide a product in which it is enriched. The method can be used for vibration-vibration enrichment of .sup.17 O in a CO reactant mixture.

  12. Isotopic Generation and Confirmation of the PWR Application Model 

    SciTech Connect (OSTI)

    L.B. Wimmer

    2003-11-10

    The objective of this calculation is to establish an isotopic database to represent commercial spent nuclear fuel (CSNF) from pressurized water reactors (PWRs) in criticality analyses performed for the proposed Monitored Geologic Repository at Yucca Mountain, Nevada. Confirmation of the conservatism with respect to criticality in the isotopic concentration values represented by this isotopic database is performed as described in Section 3.5.3.1.2 of the ''Disposal Criticality Analysis Methodology Topical Report'' (YMP 2000). The isotopic database consists of the set of 14 actinides and 15 fission products presented in Section 3.5.2.1.1 of YMP 2000 for use in CSNF burnup credit. This set of 29 isotopes is referred to as the principal isotopes. The oxygen isotope from the UO{sub 2} fuel is also included in the database. The isotopic database covers enrichments of {sup 235}U ranging from 1.5 to 5.5 weight percent (wt%) and burnups ranging from approximately zero to 75 GWd per metric ton of uranium (mtU). The choice of fuel assembly and operating history values used in generating the isotopic database are provided is Section 5. Tables of isotopic concentrations for the 29 principal isotopes (plus oxygen) as a function of enrichment and burnup are provided in Section 6.1. Results of the confirmation of the conservatism with respect to criticality in the isotopic concentration values are provided in Section 6.2.

  13. Using phylogenetic probes for quantification of stable isotope labeling and microbial community analysis

    DOE Patents [OSTI]

    Brodie, Eoin L; DeSantis, Todd Z; Karaoz, Ulas; Andersen, Gary L

    2014-12-09

    Herein is described methods for a high-sensitivity means to measure the incorporation of stable isotope labeled substrates into RNA following stable isotope probing experiments (SIP). RNA is hybridized to a set of probes such as phylogenetic microarrays and isotope incorporation is quantified such as by secondary ion mass spectrometer imaging (NanoSIMS).

  14. Nitrogen concentration and isotope dataset for environmental samples from 2012 and 2013, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jeff Heikoop; Heather Throckmorton

    2015-05-15

    Dataset includes nitrate concentrations for polygonal active layer samples, snowmelt; ammonium concentrations for active layer samples; nitrate isotopes for active layer samples, snowmelt, permafrost; ammonium isotopes for active layer samples; and nitrogen isotopes for soils and dissolved organic nitrogen extracted from soil pore waters.

  15. Shape coexistence in the neutron-deficient Pt isotopes in the configuration-mixed IBM

    SciTech Connect (OSTI)

    Vargas, Carlos E.; Campuzano, Cuauhtemoc; Morales, Irving O.; Frank, Alejandro; Van Isacker, Piet

    2008-05-12

    The matrix-coherent state approach in the IBM with configuration mixing is used to describe the geometry of neutron-deficient Pt isotopes. Employing a parameter set for all isotopes determined previously, it is found that the lowest minimum goes from spherical to oblate and finally acquires a prolate shape when approaching the mid-shell Pt isotopes.

  16. CRAD, Maintenance- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Maintenance Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  17. CRAD, Engineering- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Engineering Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  18. Method of enhancing selective isotope desorption from metals

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1983-07-26

    This invention relates generally to the field of gas desorption from metals; and, more particularly, to a method of enhancing the selective desorption of a particular isotope of a gas from metals. Enhanced selective desorption is especially useful in the operation of fusion devices.

  19. Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes

    SciTech Connect (OSTI)

    Draayer, Jerry P.

    2014-09-28

    We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

  20. CRAD, Management- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Management in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  1. CRAD, Training- Oak Ridge National Laboratory High Flux Isotope Reactor

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Training Program in preparation for restart of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  2. Cascades for hydrogen isotope separation using metal hydrides

    SciTech Connect (OSTI)

    Hill, F.B.; Grzetic, V.

    1982-01-01

    Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.

  3. Rare Isotope Beams for the 21st Century

    ScienceCinema (OSTI)

    James Symons

    2010-01-08

    In a scientific keynote address on Friday, June 12 at Michigan State University (MSU) in East Lansing, James Symons, Director of Berkeley Labs Nuclear Science Division (NSD), discussed the exciting research prospects of the new Facility for Rare Isotope Beams (FRIB) to be built at MSUs National Superconducting Cyclotron Laboratory.

  4. Revision of HFIR (High Flux Isotope Reactor) operating procedures

    SciTech Connect (OSTI)

    McGinty, D.M.

    1987-01-23

    This report documents modifications to the facility and changes in some operating procedures for the High Flux Isotope Reactor (HFIR). The topics covered include: Reactor Operation, Reactor Start-up, Reactor Safety Systems, Reactor Control Systems, Reporting Requirements, and Administrative Procedures. (FI)

  5. RECTIFIED ABSORPTION METHOD FOR THE SEPARATION OF HYDROGEN ISOTOPES

    DOE Patents [OSTI]

    Hunt, C.D.; Hanson, D.N.

    1961-10-17

    A method is described for separating and recovering heavy hydrogen isotopes from gaseous mixtures by multiple stage cyclic absorption and rectification from an approximate solvent. In particular, it is useful for recovering such isoteoes from ammonia feedstock streams containing nitrogen solvent. Modifications of the process ranging from isobaric to isothermal are provided. Certain impurities are tolerated, giving advantages over conventional fractional distillation processes. (AEC)

  6. Apparatus and method for monitoring of gas having stable isotopes

    SciTech Connect (OSTI)

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  7. Alternative applications of atomic vapor laser isotope separation technology

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This report was commissioned by the Secretary of Energy. It summarizes the main features of atomic vapor laser isotope separation (AVLIS) technology and subsystems; evaluates applications, beyond those of uranium enrichment, suggested by Lawrence Livermore National Laboratory (LLNL) and a wide range of US industries and individuals; recommends further work on several applications; recommends the provision of facilities for evaluating potential new applications; and recommends the full involvement of end users from the very beginning in the development of any application. Specifically excluded from this report is an evaluation of the main AVLIS missions, uranium enrichment and purification of plutonium for weapons. In evaluating many of the alternative applications, it became clear that industry should play a greater and earlier role in the definition and development of technologies with the Department of Energy (DOE) if the nation is to derive significant commercial benefit. Applications of AVLIS to the separation of alternate (nonuranium) isotopes were considered. The use of {sup 157}Gd as burnable poison in the nuclear fuel cycle, the use {sup 12}C for isotopically pure diamond, and the use of plutonium isotopes for several nonweapons applications are examples of commercially useful products that might be produced at a cost less than the product value. Separations of other isotopes such as the elemental constituents of semiconductors were suggested; it is recommended that proposed applications be tested by using existing supplies to establish their value before more efficient enrichment processes are developed. Some applications are clear, but their production costs are too high, the window of opportunity in the market has passed, or societal constraints (e.g., on reprocessing of reactor fuel) discourage implementation.

  8. The Atomic Vapor Laser Isotope Separation Program. [Atomic Vapor Laser Isotope Separation (AVLIS) Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management's position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  9. Laser-induced separation of hydrogen isotopes in the liquid phase

    DOE Patents [OSTI]

    Freund, Samuel M.; Maier, II, William B.; Beattie, Willard H.; Holland, Redus F.

    1980-01-01

    Hydrogen isotope separation is achieved by either (a) dissolving a hydrogen-bearing feedstock compound in a liquid solvent, or (b) liquefying a hydrogen-bearing feedstock compound, the liquid phase thus resulting being kept at a temperature at which spectral features of the feedstock relating to a particular hydrogen isotope are resolved, i.e., a clear-cut isotope shift is delineated, irradiating the liquid phase with monochromatic radiation of a wavelength which at least preferentially excites those molecules of the feedstock containing a first hydrogen isotope, inducing photochemical reaction in the excited molecules, and separating the reaction product containing the first isotope from the liquid phase.

  10. Salt effects on isotope partitioning and their geochemical implications: An overview

    SciTech Connect (OSTI)

    Horita, J.; Cole, D.R.; Fortier, S.M.

    1996-01-01

    Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500{degree}C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.

  11. Reactor Fuel Isotopics and Code Validation for Nuclear Applications

    SciTech Connect (OSTI)

    Francis, Matthew W.; Weber, Charles F.; Pigni, Marco T.; Gauld, Ian C.

    2015-02-01

    Experimentally measured isotopic concentrations of well characterized spent nuclear fuel (SNF) samples have been collected and analyzed by previous researchers. These sets of experimental data have been used extensively to validate the accuracy of depletion code predictions for given sets of burnups, initial enrichments, and varying power histories for different reactor types. The purpose of this report is to present the diversity of data in a concise manner and summarize the current accuracy of depletion modeling. All calculations performed for this report were done using the Oak Ridge Isotope GENeration (ORIGEN) code, an internationally used irradiation and decay code solver within the SCALE comprehensive modeling and simulation code. The diversity of data given in this report includes key actinides, stable fission products, and radioactive fission products. In general, when using the current ENDF/B-VII.0 nuclear data libraries in SCALE, the major actinides are predicted to within 5% of the measured values. Large improvements were seen for several of the curium isotopes when using improved cross section data found in evaluated nuclear data file ENDF/B-VII.0 as compared to ENDF/B-V-based results. The impact of the flux spectrum on the plutonium isotope concentrations as a function of burnup was also shown. The general accuracy noted for the actinide samples for reactor types with burnups greater than 5,000 MWd/MTU was not observed for the low-burnup Hanford B samples. More work is needed in understanding these large discrepancies. The stable neodymium and samarium isotopes were predicted to within a few percent of the measured values. Large improvements were seen in prediction for a few of the samarium isotopes when using the ENDF/B-VII.0 libraries compared to results obtained with ENDF/B-V libraries. Very accurate predictions were obtained for 133Cs and 153Eu. However, the predicted values for the stable ruthenium and rhodium isotopes varied as much as 10% of the measured values, and 109Ag was consistently over-predicted by as much as 170%. In general, there is a larger uncertainty for modeling radioactive fission products when compared to either the actinides or the stable fission products in SNF. The relative C/E ratios ranged from a few percent for 137Cs up to 60% and 100% for 106Ru and 125Sb, respectively. Limited or no radioactive fission products data exist in the current data sets for reactor types other than PWRs and BWRs. More work is needed in obtaining a greater diversity of radioactive fission product data. While performing this survey, issues leading to inconsistencies in nuclear fission yield data were discovered that specifically impacted the fission product noble gases. Emphasis was given to this legacy data, and corrective actions were taken as described in this report. After the fission yield data were corrected, the stable xenon and krypton fission products were predicted to within 5% of their measurements. However, preliminary results not explicitly given in this report indicate that the relative C/E ratio for the radioactive isotope 85Kr varied as much as 10%. Due to the complex migration and the difficulty in measuring noble gases in the fuel, a more thorough investigation is needed to understand how accurately depletion codes can calculate these gas concentrations.

  12. Dual pressure-dual temperature isotope exchange process

    DOE Patents [OSTI]

    Babcock, D.F.

    1974-02-12

    A liquid and a gas stream, each containing a desired isotope, flow countercurrently through two liquid-gas contacting towers maintained at different temperatures and pressures. The liquid is enriched in the isotope in one tower while the gas is enriched within the other and a portion of at least one of the enriched streams is withdrawn from the system for use or further enrichment. The tower operated at the lower temperature is also maintained at the lower pressure to prevent formation of solid solvates. Gas flow between the towers passes through an expander-compressor apparatas to recover work from the expansion of gas to the lower pressure and thereby compress the gas returning to the tower of higher pressure. (Official Gazette)

  13. Isotopic prediction of eruption volume at continental volcanoes

    SciTech Connect (OSTI)

    Perry, F.V.; Valentine, G.A.; Crowe, B.M.

    1997-10-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The objective of this project was to determine whether isotopic techniques can be used to assess the eruption potential and eruption volume of continental stratovolcanoes. Large-volume eruptions from stratovolcanoes pose significant hazards to population and infrastructure in many parts of the world. We are testing whether this technique will allow a short- to medium-term (decades to millennia) probabilistic hazard assessment of large-volume eruptions. If successful, the technique will be useful to countries or regions that must consider medium to long-term volcanic (e.g., nuclear waste facilities). We have begun sample acquisition and isotopic measurements at two stratovolcanoes, Pico de Orizaba in eastern Mexico and Daisen in western Japan.

  14. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  15. Stable Isotope Characterization of TICs/TIMs: Analytical Progress Report

    SciTech Connect (OSTI)

    Volpe, A M; Singleton, M J

    2009-06-05

    We measured twelve alkali cyanide samples that were also sent to ORNL and PNNL collaborators. While results indicate distinct {delta}{sup 13}C and {delta}{sup 15}N values that would be useful to signature studies, the alkali cyanides, especially NaCN, show chemical breakdown during storage that will influence forensic analysis. Carbon and nitrogen stable isotopic compositions of raw materials used to synthesis TETS were measured. Results indicate wide ranges in {delta}{sup 13}C and {delta}{sup 15}N values. Using these raw materials, LLNL scientists synthesized three batches of TETS following published procedures. Stable isotopic measurements of TETS synthesis products indicates nitrogen ({var_epsilon} {sup 15}N = -1.7 to -0.8) and carbon ({var_epsilon} {sup 13}C = -1.0 to -0.1) fractionation during production.

  16. Hydrogen isotope MicroChemLab FY15.

    SciTech Connect (OSTI)

    Robinson, David; Luo, Weifang; Stewart, Kenneth D.

    2015-09-01

    We have developed a new method to measure the composition of gaseous mixtures of any two hydrogen isotopes, as well as an inert gas component. When tritium is one of those hydrogen isotopes, there is usually some helium present, because the tritium decays to form helium at a rate of about 1% every 2 months. The usual way of measuring composition of these mixtures involves mass spectrometry, which involves bulky, energy-intensive, expensive instruments, including vacuum pumps that can quite undesirably disperse tritium. Our approach uses calorimetry of a small quantity of hydrogen-absorbing material to determine gas composition without consuming or dispersing the analytes. Our work was a proof of principle using a rather large and slow benchtop calorimeter. Incorporation of microfabricated calorimeters, such as those that have been developed in Sandias MicroChemLab program or that are now commercially available, would allow for faster measurements and a smaller instrument footprint.

  17. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  18. Descriptions of carbon isotopes within the energy density functional theory

    SciTech Connect (OSTI)

    Ismail, Atef; Cheong, Lee Yen; Yahya, Noorhana; Tammam, M.

    2014-10-24

    Within the energy density functional (EDF) theory, the structure properties of Carbon isotopes are systematically studied. The shell model calculations are done for both even-A and odd-A nuclei, to study the structure of rich-neutron Carbon isotopes. The EDF theory indicates the single-neutron halo structures in {sup 15}C, {sup 17}C and {sup 19}C, and the two-neutron halo structures in {sup 16}C and {sup 22}C nuclei. It is also found that close to the neutron drip-line, there exist amazing increase in the neutron radii and decrease on the binding energies BE, which are tightly related with the blocking effect and correspondingly the blocking effect plays a significant role in the shell model configurations.

  19. NOVEL CONCEPTS FOR ISOTOPIC SEPARATION OF 3HE/4HE

    SciTech Connect (OSTI)

    Roy, L.; Nigg, H.; Watson, H.

    2012-09-04

    The research outlined below established theoretical proof-of-concept using ab initio calculations that {sup 3}He can be separated from {sup 4}He by taking advantage of weak van der Waals interactions with other higher molecular weight rare gases such as xenon. To the best of our knowledge, this is the only suggested method that exploits the physical differences of the isotopes using a chemical interaction.

  20. MAGNESIUM ISOTOPE RATIOS IN {omega} CENTAURI RED GIANTS

    SciTech Connect (OSTI)

    Da Costa, G. S.; Norris, John E.; Yong, David

    2013-05-20

    We have used the high-resolution observations obtained at the Anglo-Australian Telescope with Ultra-High Resolution Facility (R {approx} 100,000) and at Gemini-S with b-HROS (R {approx} 150,000) to determine magnesium isotope ratios for seven {omega} Cen red giants that cover a range in iron abundance from [Fe/H] = -1.78 to -0.78 dex, and for two red giants in M4 (NGC 6121). The {omega} Cen stars sample both the ''primordial'' (i.e., O-rich, Na- and Al-poor) and the ''extreme'' (O-depleted, Na- and Al-rich) populations in the cluster. The primordial population stars in both {omega} Cen and M4 show ({sup 25}Mg, {sup 26}Mg)/{sup 24}Mg isotopic ratios that are consistent with those found for the primordial population in other globular clusters with similar [Fe/H] values. The isotopic ratios for the {omega} Cen extreme stars are also consistent with those for extreme population stars in other clusters. The results for the extreme population stars studied indicate that the {sup 26}Mg/{sup 24}Mg ratio is highest at intermediate metallicities ([Fe/H] < -1.4 dex), and for the highest [Al/Fe] values. Further, the relative abundance of {sup 26}Mg in the extreme population stars is notably higher than that of {sup 25}Mg, in contrast to model predictions. The {sup 25}Mg/{sup 24}Mg isotopic ratio in fact does not show any obvious dependence on either [Fe/H] or [Al/Fe] nor, intriguingly, any obvious difference between the primordial and extreme population stars.

  1. FUEL CYCLE ISOTOPE EVOLUTION BY TRANSMUTATION DYNAMICS OVER MULTIPLE RECYCLES

    SciTech Connect (OSTI)

    Samuel Bays; Steven Piet; Amaury Dumontier

    2010-06-01

    Because all actinides have the ability to fission appreciably in a fast neutron spectrum, these types of reactor systems are usually not associated with the buildup of higher mass actinides: curium, berkelium and californium. These higher actinides have high specific decay heat power, gamma and neutron source strengths, and are usually considered as a complication to the fuel manufacturing and transportation of fresh recycled transuranic fuel. This buildup issue has been studied widely for thermal reactor fuels. However, recent studies have shown that the transmutation physics associated with "gateway isotopes" dictates Cm-Bk-Cf buildup, even in fast burner reactors. Assuming a symbiotic fuel relationship with light water reactors (LWR), Pu-242 and Am-243 are formed in the LWRs and then are externally fed to the fast reactor as part of its overall transuranic fuel supply. These isotopes are created much more readily in a thermal than in fast spectrum systems due to the differences in the fast fission (i.e., above the fission threshold for non-fissile actinides) contribution. In a strictly breeding fast reactor this dependency on LWR transuranics would not exist, and thus avoids the introduction of LWR derived gateway isotopes into the fast reactor system. However in a transuranic burning fast reactor, the external supply of these gateway isotopes behaves as an external driving force towards the creation and build-up of Cm-Bk-Cf in the fuel cycle. It was found that though the Cm-Bk-Cf concentration in the equilibrium fuel cycle is dictated by the fast neutron spectrum, the time required to reach that equilibrium concentration is dictated by recycle, transmutation and decay storage dynamics.

  2. Integration of Nontraditional Isotopic Systems Into Reaction-Transport

    Broader source: Energy.gov (indexed) [DOE]

    Models of EGS For Exploration, Evaluation of Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir Sustainability | Department of Energy Nontraditional Isotopic Systems Into Reaction-Transport Models of EGS For Exploration, Evaluation of Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir Sustainability presentation at the April 2013 peer review meeting held in Denver, Colorado. PDF icon sonnenthal_foa_peer2013.pdf More Documents & Publications track 4:

  3. METHOD FOR PRODUCING ISOTOPIC METHANES AND PARTIALLY HALOGENATED DERIVATIVES THEROF

    DOE Patents [OSTI]

    Frazer, J.W.

    1959-08-18

    A method is given for producing isotopic methanes and/ or partially halogenated derivatives. Lithium hydride, deuteride, or tritide is reacted with a halogenated methane or with a halogenated methane in combination with free halogen. The process is conveniently carried out by passing a halogenated methane preferably at low pressures or in an admixture with an inert gas through a fixed bed of finely divided lithium hydride heated initially to temperatures of 100 to 200 deg C depending upon the halogenated methane used.

  4. Generalized Modeling of Enrichment Cascades That Include Minor Isotopes

    SciTech Connect (OSTI)

    Weber, Charles F

    2012-01-01

    The monitoring of enrichment operations may require innovative analysis to allow for imperfect or missing data. The presence of minor isotopes may help or hurt - they can complicate a calculation or provide additional data to corroborate a calculation. However, they must be considered in a rigorous analysis, especially in cases involving reuse. This study considers matched-abundanceratio cascades that involve at least three isotopes and allows generalized input that does not require all feed assays or the enrichment factor to be specified. Calculations are based on the equations developed for the MSTAR code but are generalized to allow input of various combinations of assays, flows, and other cascade properties. Traditional cascade models have required specification of the enrichment factor, all feed assays, and the product and waste assays of the primary enriched component. The calculation would then produce the numbers of stages in the enriching and stripping sections and the remaining assays in waste and product streams. In cases where the enrichment factor or feed assays were not known, analysis was difficult or impossible. However, if other quantities are known (e.g., additional assays in waste or product streams), a reliable calculation is still possible with the new code, but such nonstandard input may introduce additional numerical difficulties into the calculation. Thus, the minimum input requirements for a stable solution are discussed, and a sample problem with a non-unique solution is described. Both heuristic and mathematically required guidelines are given to assist the application of cascade modeling to situations involving such non-standard input. As a result, this work provides both a calculational tool and specific guidance for evaluation of enrichment cascades in which traditional input data are either flawed or unknown. It is useful for cases involving minor isotopes, especially if the minor isotope assays are desired (or required) to be important contributors to the overall analysis.

  5. Isotope Development & Production for Research and Applications (IDPRA) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. DOE Office of Science (SC) Research » Isotope Development & Production for Research and Applications (IDPRA) Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information »

  6. An overview of copper-laser development for isotope separation

    SciTech Connect (OSTI)

    Warner, B.E.

    1987-03-13

    We have developed a copper-laser pumped dye-laser system that addresses all of the requirements for atomic vapor laser isotope separation. The requirement for high average power for the laser system has led to the development of copper-laser chains with injection-locked oscillators and multihundred-watt amplifiers. By continuously operating the Laser Demonstration Facility, we gain valuable data for further upgrade and optimization.

  7. DOE Isotope Program Announces Availability of Radionuclide Generators for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Medical Research | U.S. DOE Office of Science (SC) DOE Isotope Program Announces Availability of Radionuclide Generators for Medical Research Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email

  8. Flask Samplers for Carbon Cycle Gases and Isotopes (FLASK) Handbook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Flask Samplers for Carbon Cycle Gases and Isotopes (FLASK) Handbook S Biraud March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not

  9. Process for preparing a chemical compound enriched in isotope content

    DOE Patents [OSTI]

    Michaels, Edward D.

    1982-01-01

    A process to prepare a chemical enriched in isotope content which includes: (a) A chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; (b) the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; (c) the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; (d) the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products.

  10. Hanford Isotope Project strategic business analysis Cesium-137 (Cs-137)

    SciTech Connect (OSTI)

    1995-10-01

    The purpose of this business analysis is to address the beneficial reuse of Cesium 137 (Cs-137) in order to utilize a valuable national asset and possibly save millions of tax dollars. Food irradiation is the front runner application along with other uses. This business analysis supports the objectives of the Department of Energy National Isotope Strategy distributed in August 1994 which describes the DOE plans for the production and distribution of isotope products and services. As part of the Department`s mission as stated in that document. ``The Department of Energy will also continue to produce and distribute other radioisotopes and enriched stable isotopes for medical diagnostics and therapeutics, industrial, agricultural, and other useful applications on a businesslike basis. This is consistent with the goals and objectives of the National Performance Review. The Department will endeavor to look at opportunities for private sector to co-fund or invest in new ventures. Also, the Department will seek to divest from ventures that can more profitably or reliably be operated by the private sector.``

  11. Isotope production and distribution Programs Fiscal Year (FY) 1995 Financial Statement Audit (ER-FC-96-01)

    SciTech Connect (OSTI)

    1996-02-12

    The charter of the Department of Energy (DOE) Isotope Production and Distribution Program (Isotope Program) covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials such as lithium and deuterium, and related isotope services. Services provided include, but are not limited to, irradiation services, target preparation and processing, source encapsulation and other special preparations, analyses, chemical separations, and leasing of stable isotopes for research purposes. Isotope Program products and services are sold worldwide for use in a wide variety of research, development, biomedical, and industrial applications. The Isotope Program reports to the Director of the Office of Nuclear Energy, Science and Technology. The Isotope Program operates under a revolving fund, as established by the Fiscal Year 1990 Energy and Water Appropriations Act (Public Law 101-101). The Fiscal Year 1995 Appropriations Act (Public Law 103-316) modified predecessor acts to allow prices charged for Isotope Program products and services to be based on production costs, market value, the needs of the research community, and other factors. Prices set for small-volume, high-cost isotopes that are needed for research may not achieve full-cost recovery. Isotope Program costs are financed by revenues from the sale of isotopes and associated services and through payments from the isotope support decision unit, which was established in the DOE fiscal year 1995 Energy, Supply, Research, and Development appropriation. The isotope decision unit finances the production and processing of unprofitable isotopes that are vital to the national interest.

  12. Development of the laser isotope separation method (AVLIS) for obtaining weight amounts of highly enriched {sup 150}Nd isotope

    SciTech Connect (OSTI)

    Babichev, A P; Grigoriev, Igor' S; Grigoriev, A I; Dorovskii, A P; D'yachkov, Aleksei B; Kovalevich, S K; Kochetov, V A; Kuznetsov, V A; Labozin, Valerii P; Matrakhov, A V; Mironov, Sergei M; Nikulin, Sergei A; Pesnya, A V; Timofeev, N I; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G

    2005-10-31

    Results obtained at the first stage of development of the experimental technique for obtaining weight amounts of the highly enriched {sup 150}Nd isotope by laser photoionisation are presented. The vaporiser and the laser are designed, and various methods of irradiation of neodymium vapour and extraction of photoions are tested. The product yield {approx}40 mg h{sup -1} for the {approx}60% enrichment and 25 mg h{sup -1} for the {approx}65% enrichment is achieved for a vaporiser of length 27 cm. The cost of constructing the facility for preparing 50 kg of the {sup 150}Nd isotope, intended for determining the neutrino mass, is estimated. This estimate shows that the cost of production can be lowered by a factor of 5-7 compared to the electromagnetic method. (invited paper)

  13. A simulation of the transport and fate of radon-222 derived from thorium-230 low-level waste in the near-surface zone of the Radioactive Waste Management Site in Area 5 of the Nevada Test Site

    SciTech Connect (OSTI)

    Lindstrom, F.T.; Cawlfield, D.E.; Donahue, M.E.; Emer, D.F.; Shott, G.J.

    1993-12-01

    US Department of Energy (DOE) Order 5820.2A (DOE, 1988) requires performance assessments on all new and existing low-level radioactive waste (LLW) disposal sites. An integral part of performance assessment is estimating the fluxes of radioactive gases such as radon-220 and radon-222. Data needs pointed out by mathematical models drive site characterization. They provide a logical means of performing the required flux estimations. Thorium-230 waste, consisting largely of thorium hydroxide and thorium oxides, has been approved for disposal in shallow trenches and pits at the LLW Radioactive Waste Management Site in Area 5 of the Nevada Test Site. A sophisticated gas transport model, CASCADR8 (Lindstrom et al., 1992b), was used to simulate the transport and fate of radon-222 from its source of origin, nine feet below a closure cap of native soil, through the dry alluvial earth, to its point of release into the atmosphere. CASCADR8 is an M-chain gas-phase radionuclide transport and fate model. It has been tailored to the site-specific needs of the dry desert environment of southern Nevada. It is based on the mass balance principle for each radionuclide and uses gas-phase diffusion as well as barometric pressure-induced advection as its main modes of transport. CASCADR8 uses both reversible and irreversible sorption kinetic rules as well as the usual classical Bateman (1910) M-chain decay rules for its kinetic processes. Worst case radon-222 gas-phase concentrations, as well as surface fluxes, were estimated over 40 days. The maximum flux was then used in an exposure assessment model to estimate the total annual dose equivalent received by a person residing in a standard 2500-square-foot house with 10-foot walls. Results are described.

  14. Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data

    SciTech Connect (OSTI)

    Thomas, James; Decker, David; Patterson, Gary; Peterman, Zell; Mihevc, Todd; Larsen, Jessica; Hershey, Ronald

    2007-06-25

    Groundwater samples in the Yucca Mountain area were collected for chemical and isotopic analyses and measurements of water temperature, pH, specific conductivity, and alkalinity were obtained at the well or spring at the time of sampling. For this project, groundwater samples were analyzed for major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). The U.S. Geological Survey (USGS) performed all the fieldwork on this project including measurement of water chemistry field parameters and sample collection. The major ions dissolved in the groundwater, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) were analyzed by the USGS. All preparation and processing of samples for DOC carbon isotopic analyses and geochemical modeling were performed by the Desert Research Institute (DRI). Analysis of the DOC carbon dioxide gas produced at DRI to obtain carbon-13 and carbon-14 values was conducted at the University of Arizona Accelerator Facility (a NSHE Yucca Mountain project QA qualified contract facility). The major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of DIC were used in geochemical modeling (NETPATH) to determine groundwater sources, flow paths, mixing, and ages. The carbon isotopes of DOC were used to calculate groundwater ages that are independent of DIC model corrected carbon-14 ages. The DIC model corrected carbon-14 calculated ages were used to evaluate groundwater travel times for mixtures of water including water beneath Yucca Mountain. When possible, groundwater travel times were calculated for groundwater flow from beneath Yucca Mountain to down gradient sample sites. DOC carbon-14 groundwater ages were also calculated for groundwaters in the Yucca Mountain area. When possible, groundwater travel times were estimated for groundwater flow from beneath Yucca Mountain to down gradient groundwater sample sites using the DOC calculated groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by the USGS, is the best geochemical program for correcting carbon-14 activities for geochemical r

  15. Optimization of Depletion Modeling and Simulation for the High Flux Isotope

    Office of Scientific and Technical Information (OSTI)

    Reactor (Conference) | SciTech Connect Optimization of Depletion Modeling and Simulation for the High Flux Isotope Reactor Citation Details In-Document Search Title: Optimization of Depletion Modeling and Simulation for the High Flux Isotope Reactor Monte Carlo based depletion tools used for the high-fidelity modeling and simulation of the High Flux Isotope Reactor (HFIR) come at a great computational cost; finding sufficient approximations is necessary to make the use of these tools

  16. High Flux Isotope Reactor (HFIR) | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Facilities » High Flux Isotope Reactor (HFIR) Scientific User Facilities (SUF) Division SUF Home About User Facilities X-Ray Light Sources Neutron Scattering Facilities Spallation Neutron Source (SNS) High Flux Isotope Reactor (HFIR) Nanoscale Science Research Centers (NSRCs) Projects Accelerator & Detector Research Science Highlights Principal Investigators' Meetings BES Home Neutron Scattering Facilities High Flux Isotope Reactor (HFIR) Print Text Size: A A A FeedbackShare Page Quick

  17. Efficient and selective isotopic labeling of hemes to facilitate the study

    Office of Scientific and Technical Information (OSTI)

    of multiheme proteins (Journal Article) | SciTech Connect Efficient and selective isotopic labeling of hemes to facilitate the study of multiheme proteins Citation Details In-Document Search Title: Efficient and selective isotopic labeling of hemes to facilitate the study of multiheme proteins Specific isotopic labeling of hemes provides a unique opportunity to characterize the structure and function of heme-proteins. Unfortunately, present day methods do not allow efficient labeling in high

  18. Shape coexistence in the neutron-deficient Pt isotopes in a configuration mixing IBM

    SciTech Connect (OSTI)

    Morales, Irving O.; Vargas, Carlos E.; Frank, Alejandro

    2004-09-13

    The recently proposed matrix-coherent state approach for configuration mixing IBM is used to describe the evolving geometry of the neutron deficient Pt isotopes. It is found that the Potential Energy Surface (PES) of the Platinum isotopes evolves, when the number of neutrons decreases, from spherical to oblate and then to prolate shapes, in agreement with experimental measurements. Oblate-Prolate shape coexistence is observed in 194,192Pt isotopes.

  19. Application of Environmental Isotopes to the Evaluation of the Origin of

    Energy Savers [EERE]

    Contamination in a Desert Arroyo: Many Devils Wash, Shiprock, New Mexico | Department of Energy Application of Environmental Isotopes to the Evaluation of the Origin of Contamination in a Desert Arroyo: Many Devils Wash, Shiprock, New Mexico Application of Environmental Isotopes to the Evaluation of the Origin of Contamination in a Desert Arroyo: Many Devils Wash, Shiprock, New Mexico Application of Environmental Isotopes to the Evaluation of the Origin of Contamination in a Desert Arroyo:

  20. Preliminary Notice of Violation, MAC Isotopes, LLC- EA- 1998-05

    Broader source: Energy.gov [DOE]

    Issued to MAC Isotopes, LLC, related to a Radioactive Material Release at the Idaho National Engineering and Environmental Laboratory, (1998-05)

  1. A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrotherm...

    Open Energy Info (EERE)

    through the isotopically lighter volcanic rocks of the caldera fill. Authors Fraser Goff, Harold A. Wollenberg, D. C. Brookins and Ronald W. Kistler Published Journal Journal...

  2. Isotope Production and Distribution Program. Financial statements, September 30, 1994 and 1993

    SciTech Connect (OSTI)

    Marwick, P.

    1994-11-30

    The attached report presents the results of the independent certified public accountants` audit of the Isotope Production and Distribution (IP&D) Program`s financial statements as of September 30, 1994. The auditors have expressed an unqualified opinion on IP&D`s 1994 statements. Their reports on IP&D`s internal control structure and on compliance with laws,and regulations are also provided. The charter of the Isotope Program covers the production and sale of radioactive and stable isotopes, byproducts, and related isotope services. Prior to October 1, 1989, the Program was subsidized by the Department of Energy through a combination of appropriated funds and isotope sales revenue. The Fiscal Year 1990 Appropriations Act, Public Law 101-101, authorized a separate Isotope Revolving Fund account for the Program, which was to support itself solely from the proceeds of isotope sales. The initial capitalization was about $16 million plus the value of the isotope assets in inventory or on loan for research and the unexpended appropriation available at the close of FY 1989. During late FY 1994, Public Law 103--316 restructured the Program to provide for supplemental appropriations to cover costs which are impractical to incorporate into the selling price of isotopes. Additional information about the Program is provided in the notes to the financial statements.

  3. Isotopic Analysis At Seven Mile Hole Area (Larson, Et Al., 2009...

    Open Energy Info (EERE)

    Seven Mile Hole Area (Larson, Et Al., 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Seven Mile Hole Area (Larson, Et...

  4. Isotope Related Reports | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    of the Biological and Environmental Research Advisory Committee, April 2004. Expert Panel: Forecast Future Demand for Medical Isotopes, .pdf file (109KB)March 1999. Medical ...

  5. Separation of carbon and nitrogen isotopes by selective photodissociation azo or diazo compounds

    DOE Patents [OSTI]

    Chen, Hao-Lin [Walnut Creek, CA

    1977-12-20

    Separation of isotopes, particularly of carbon or nitrogen, is achieved by the selective photodissociation of an azo compound or a diazoalkane, particularly azomethane or diazomethane.

  6. Stable isotopes of authigenic minerals in variably-saturated fractured tuff

    SciTech Connect (OSTI)

    Weber, D.S.; Evans, D.D.

    1988-11-01

    Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to result from near-surface isotopic enrichment due to evaporation rather than the effects of rock-water interaction. Oxygen isotope ratios of rock matrix opal samples exhibited an isotopic gradient believed to result from, leaching and reprecipitation of silica at depth. Methods and results can be used to further define primary flowpaths and the movement of water in variably-saturated fractured rock. 71 refs., 23 figs., 3 tabs.

  7. Isotope fractionation in surface ionization ion source of alkaline-earth iodides

    SciTech Connect (OSTI)

    Suzuki, T.; Kanzaki, C.; Nomura, M.; Fujii, Y.

    2012-02-15

    The relationship between the isotope fractionation of alkaline-earth elements in the surface ionization ion source and the evaporation filament current, i.e., filament temperature, was studied. It was confirmed that the isotope fractionation depends on the evaporation filament temperature; the isotope fractionation in the case of higher temperature of filament becomes larger. The ionization and evaporation process in the surface ionization ion source was discussed, and it was concluded that the isotope fractionation is suppressed by setting at the lower temperature of evaporation filament because the dissociations are inhibited on the evaporation filament.

  8. Utilizing Isotopic Uranium Ratios in Groundwater Evaluations at FUSRAP Sites

    SciTech Connect (OSTI)

    Frederick, W.T.; Keil, K.G.; Rhodes, M.C.; Peterson, J.M.; MacDonell, M.M.

    2007-07-01

    The U.S. Army Corps of Engineers Buffalo District is evaluating environmental radioactive contamination at several Formerly Utilized Sites Remedial Action Program (FUSRAP) sites throughout New York, Pennsylvania, Ohio, and Indiana. The investigations follow the process defined in the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA). Groundwater data from the Niagara Falls Storage Site (NFSS) in Lewiston, New York were evaluated for isotopic uranium ratios, specifically uranium-234 versus uranium-238 (U- 234 and U-238, respectively), and the results were presented at Waste Management 2006. Since uranium naturally occurs in all groundwater, it can be difficult to distinguish where low-concentration impacts from past releases differ from the high end of a site-specific natural background range. In natural groundwater, the ratio of U-234 to U-238 exceeds 1 (unity) due to the alpha particle recoil effect, in which U-234 is preferentially mobilized to groundwater from adjacent rock or soil. This process is very slow and may take hundreds to thousands of years before a measurable increase is seen in the natural isotopic ratio. If site releases are the source of uranium being measured in groundwater, the U-234 to U-238 ratio is commonly closer to 1, which normally reflects FUSRAP-related, uranium-contaminated wastes and soils. This lower ratio occurs because not enough residence time has elapsed since the 1940's and 1950's for the alpha particle recoil effect to have significantly altered the contamination-derived ratio. An evaluation of NFSS-specific and regional groundwater data indicate that an isotopic ratio of 1.2 has been identified as a signature value to help distinguish natural groundwater, which may have a broad background range, from zones impacted by past releases. (authors)

  9. SPECTROSCOPY OF TRANSFERMIUM ISOTOPES AT DUBNA: RESULTS AND PLANS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPECTROSCOPY OF TRANSFERMIUM ISOTOPES AT DUBNA: RESULTS AND PLANS eremin@jinr.ru Yu. Ts. Oganessian , A.V. Yeremin, O.N. Malyshev, A.G. Popeko, A. Lopes-Martens, K. Hauschild and O. Dorvaux Super Heavy Nuclei International Symposium Texas A & M University, College Station TX, USA March 31 - April 02, 2015 * Introduction. Types of the spectroscopy experiments * Experimental set up at FLNR JINR. Past, present and future. * Experiments at FLNR JINR. Results and plans. Main goal of our activity:

  10. Tunable dye laser amplifier chain for laser isotope separation

    SciTech Connect (OSTI)

    Grigoriev, Igor' S; D'yachkov, Aleksei B; Labozin, Valerii P; Mironov, Sergei M; Nikulin, Sergei A; Firsov, Valerii A

    2004-05-31

    A tunable dye laser amplifier chain developed for experiments on atomic vapour laser isotope separation (AVLIS) is described. The system, pumped by copper vapour lasers, consists of a master oscillator and an amplifier stage including a preamplifier and three main amplifiers working in the saturation mode. The master oscillator of the stage is a dye laser with a grazing incidence diffraction grating. Longitudinal pumping of the amplifiers is used. The efficiency of the main amplifiers is 50 % - 55 %. The average power of laser radiation at the output of the last amplifier is 100 W. (lasers. amplifiers)

  11. Consistency test of neutrinoless double beta decay with one isotope

    SciTech Connect (OSTI)

    Duerr, Michael; Lindner, Manfred [Max-Planck-Institut fuer Kernphysik, Postfach 10 39 80, 69029 Heidelberg (Germany); Zuber, Kai [Technical University Dresden, Institut fuer Kern- und Teilchenphysik, 01069 Dresden (Germany)

    2011-11-01

    We discuss a consistency test which makes it possible to discriminate unknown nuclear background lines from neutrinoless double beta decay with only one isotope. By considering both the transition to the ground state and to the first excited 0{sup +} state, a sufficiently large detector can reveal if neutrinoless double beta decay or some other nuclear physics process is at work. Such a detector could therefore simultaneously provide a consistency test for a certain range of Majorana masses and be sensitive to lower values of the effective Majorana mass .

  12. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    SciTech Connect (OSTI)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  13. Reaction cross sections of carbon isotopes incident on a proton

    SciTech Connect (OSTI)

    Abu-Ibrahim, B.; Horiuchi, W.; Kohama, A.; Suzuki, Y.

    2008-03-15

    We systematically study total reaction cross sections of carbon isotopes with N=6-16 on a proton target for wide range of incident energies. An emphasis is put on the difference from the case of a carbon target. The calculations include the reaction cross sections of {sup 19,20,22}C at 40A MeV, the data of which have recently been measured at RIKEN. The Glauber theory is used to calculate the reaction cross sections. To describe the intrinsic structure of the carbon isotopes, we use a Slater determinant generated from a phenomenological mean-field potential, and construct the density distributions. To go beyond the simple mean-field model, we adopt two types of dynamical models: One is a core+n model for odd-neutron nuclei, and the other is a core+n+n model for {sup 16}C and {sup 22}C. We propose empirical formulas which are useful in predicting unknown cross sections.

  14. Natural thorium isotopes in marine sediment core off Labuan port

    SciTech Connect (OSTI)

    Hafidz, B. Y.; Asnor, A. S.; Terence, R. C.; Mohamed, C. A. R.

    2014-02-12

    Sediment core was collected from Labuan port and analyzed to determine the radioactivity of thorium (Th) isotopes. The objectives of this study are to determine the possible sources of Th isotopes at Labuan port and estimates the sedimentation rate based on {sup 228}Th/{sup 232}Th model. The results suggest the {sup 230}Th and {sup 232}Th might be originated from terrestrial sedimentary rock while {sup 228}Th originated by authigenic origin. High ratio value of {sup 230}Th/{sup 232}Th detected at the top surface sediment indicates the increasing of {sup 230}Th at the recent years which might be contributed from the anthropogenic sources. The sedimentation rate of core sediment from Labuan Port was successfully estimated by using {sup 228}Th/{sup 232}Th model. The result show high sedimentation rate with 4.67 cm/year indicates rapid deposition occurred at this study area due to the high physical activity at the Labuan port. By assume the constant sedimentation rate at this area; we estimated the age of 142 cm core sediment obtained from Labuan port is 32 years started from 1981 to 2012. This chronology will be used in forthcoming research to investigate the historical profile of anthropogenic activities affecting the Labuan port.

  15. Utilization of Kinetic Isotope Effects for the Concentration of Tritium

    SciTech Connect (OSTI)

    Brown, Gilbert M.; Meyer, Thomas J.; Moyer, Bruce A.

    2000-06-01

    Work is in progress to develop methods for concentrating tritium in water based on large primary isotope effects in catalytic redox processes. Basic research is being conducted to develop the chemistry of a complete cyclic process. The process will remove tritium from H2O by concentrating it with respect to protio-water. This research involves developing chemical cycles that produce high concentration factors for HTO based on the discrimination of CH and C-T bonds in oxidation reactions. Several steps are required in a cyclic process for the concentration of tritium in water. In the first step, the tritium is incorporated in an organic compound. H-T discrimination occurs as the tritium containing compound is oxidized in a step involving a Ru(IV) oxo complex. Strong primary kinetic isotope effects lead to the oxidation of C-H bonds in preference to C-T bonds, and this reaction leads to concentration of tritium in the organic compound. The reduced form of the ruthenium compound can be reoxidized so that the oxidation step can be made catalytic.

  16. Stable isotope, site-specific mass tagging for protein identification

    DOE Patents [OSTI]

    Chen, Xian

    2006-10-24

    Proteolytic peptide mass mapping as measured by mass spectrometry provides an important method for the identification of proteins, which are usually identified by matching the measured and calculated m/z values of the proteolytic peptides. A unique identification is, however, heavily dependent upon the mass accuracy and sequence coverage of the fragment ions generated by peptide ionization. The present invention describes a method for increasing the specificity, accuracy and efficiency of the assignments of particular proteolytic peptides and consequent protein identification, by the incorporation of selected amino acid residue(s) enriched with stable isotope(s) into the protein sequence without the need for ultrahigh instrumental accuracy. Selected amino acid(s) are labeled with .sup.13C/.sup.15N/.sup.2H and incorporated into proteins in a sequence-specific manner during cell culturing. Each of these labeled amino acids carries a defined mass change encoded in its monoisotopic distribution pattern. Through their characteristic patterns, the peptides with mass tag(s) can then be readily distinguished from other peptides in mass spectra. The present method of identifying unique proteins can also be extended to protein complexes and will significantly increase data search specificity, efficiency and accuracy for protein identifications.

  17. Isotope-enriched protein standards for computational amide I spectroscopy

    SciTech Connect (OSTI)

    Reppert, Mike; Roy, Anish R.; Tokmakoff, Andrei

    2015-03-28

    We present a systematic isotope labeling study of the protein G mutant NuG2b as a step toward the production of reliable, structurally stable, experimental standards for amide I infrared spectroscopic simulations. By introducing isotope enriched amino acids into a minimal growth medium during bacterial expression, we induce uniform labeling of the amide bonds following specific amino acids, avoiding the need for chemical peptide synthesis. We use experimental data to test several common amide I frequency maps and explore the influence of various factors on map performance. Comparison of the predicted absorption frequencies for the four maps tested with empirical assignments to our experimental spectra yields a root-mean-square error of 6-12 cm{sup −1}, with outliers of at least 12 cm{sup −1} in all models. This means that the predictions may be useful for predicting general trends such as changes in hydrogen bonding configuration; however, for finer structural constraints or absolute frequency assignments, the models are unreliable. The results indicate the need for careful testing of existing literature maps and shed light on possible next steps for the development of quantitative spectral maps.

  18. Couplings between dipole and quadrupole vibrations in tin isotopes

    SciTech Connect (OSTI)

    Simenel, C.; Chomaz, Ph.

    2009-12-15

    We study the couplings between collective vibrations such as the isovector giant dipole and isoscalar giant quadrupole resonances in tin isotopes in the framework of the time-dependent Hartree-Fock theory with a Skyrme energy density functional. These couplings are a source of anharmonicity in the multiphonon spectrum. In particular, the residual interaction is known to couple the isovector giant dipole resonance with the isoscalar giant quadrupole resonance built on top of it, inducing a nonlinear evolution of the quadrupole moment after a dipole boost. This coupling also affects the dipole motion in a nucleus with a static or dynamical deformation induced by a quadrupole constraint or boost, respectively. Three methods associated with these different manifestations of the coupling are proposed to extract the corresponding matrix elements of the residual interaction. Numerical applications of the different methods to {sup 132}Sn are in good agreement with each other. Finally, several tin isotopes are considered to investigate the role of isospin and mass number on this coupling. A simple 1/A dependence of the residual matrix elements is found with no noticeable contribution from the isospin. This result is interpreted within the Goldhaber-Teller model.

  19. Chemical and isotopic data for groundwater in southern Nevada

    SciTech Connect (OSTI)

    Rose, T. P., LLNL

    1997-07-01

    This document presents a compilation of chemical and isotopic data for groundwater samples analyzed by Lawrence Livermore National Laboratory (LLNL) in support of the Hydrology and Radionuclide Migration Program (HRMP) and the Underground Test Area Program (UGTA) for the U.S. Department of Energy, Nevada Operations Office. Included are data for 107 samples collected from wells and springs located on and around the Nevada Test Site (NTS), within an area approximately bounded by latitudes 36{sup o} to 38{sup o}15'N and longitudes 115{sup o} to 117{sup o}15'W. The samples were collected during the time period 1992 to early 1997. The data represents one of the largest internally consistent geochemical data sets to be gathered for groundwater in southern Nevada. This database is available in electronic or hardcopy formats to interested parties upon request. In addition to the LLNL data we have included a table of selected isotopic data summarized from a larger database compiled by GeoTrans, Inc. (1994). This data is included for comparative purposes as a means of placing the LLNL data in the context of other data for the same geographic region.

  20. An efficient palladium isotope chromatograph (EPIC) for hydrogen

    SciTech Connect (OSTI)

    Rutherford, W.M.

    1989-06-20

    The efficient palladium isotope chromatography (EPIC) system is based on a palladium displacement chromatograph developed and tested for the preparative scale separation of the isotopes of hydrogen. Rapid cycling and high efficiency are obtained by use of high-performance packing operating at an elevated temperature (80/degree/C) and elevated pressure (1.5 atm). The process, which was tested with a 50/50 mixture of hydrogen and deuterium, depends on the exploitation of thermally driven pressure differences to recover and recycle the mixed transition zone between the bands of the pure components and also to recover and recycle the hydrogen gas used as the displacing agent. The purity of the product is significantly enhanced by partially backfilling the column with pure deuterium at the beginning of each displacement cycle. The computer-controlled system operates continuously, and it is capable of separating 2.2 std L/hr of feed at product assays of 99.86 at. % hydrogen and 99.992 at. % deuterium. 11 refs., 5 figs., 1 tab.

  1. High Specific Activity Sn-117m by Post Irradiation Isotope Separation

    SciTech Connect (OSTI)

    DAuria, John

    2015-04-16

    ElectroMagnetic Isotope Separation (EMIS) is used in the production of enriched stable isotopes. We demonstrated the feasibility of using EMIS to produce medium Specific Activity 117mSm using high purity 116Sn target material irradiated in a high flux reactor.

  2. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  3. EIS-0136: Special Isotope Separation Project Idaho National Engineering Laboratory, Idaho Falls, Idaho

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this EIS to provide environmental input to the decision to construct the Special Isotope Separation Project, which would allow for the processing of existing fuel-grade plutonium into weapons-grade plutonium using the Atomic Laser Isotope Separation process.

  4. Liquid-phase thermal diffusion isotope separation apparatus and method having tapered column

    DOE Patents [OSTI]

    Rutherford, W.M.

    1985-12-04

    A thermal diffusion counterflow method and apparatus for separating isotopes in solution in which the solution is confined in a long, narrow, vertical slit which tapers from bottom to top. The variation in the width of the slit permits maintenance of a stable concentration distribution with relatively long columns, thus permitting isotopic separation superior to that obtained in the prior art.

  5. Liquid-phase thermal diffusion isotope separation apparatus and method having tapered column

    DOE Patents [OSTI]

    Rutherford, William M.

    1988-05-24

    A thermal diffusion counterflow method and apparatus for separating isotopes in solution in which the solution is confined in a long, narrow, vertical slit which tapers from bottom to top. The variation in the width of the slit permits maintenance of a stable concentration distribution with relatively long columns, thus permitting isotopic separation superior to that obtainable in the prior art.

  6. Forensic Applications of Light-Element Stable Isotope Ratios of Ricinus communis Seeds and Ricin Preparations

    SciTech Connect (OSTI)

    Kreuzer, Helen W.; West, Jason B.; Ehleringer, James

    2013-01-01

    Seeds of the castor plant Ricinus communis, also known as castor beans, are of forensic interest because they are the source of the poison ricin. We have tested whether stable isotope ratios of castor seeds and ricin prepared by various methods can be used as a forensic signature. We collected over 300 castor seed samples from locations around the world and measured the C, N, O, and H stable isotope ratios of the whole seeds, oil, and three types of ricin preparations. Our results demonstrate that N isotope ratios can be used to correlate ricin prepared by any of these methods to source seeds. Further, stable isotope ratios distinguished >99% of crude and purified ricin protein samples in pair-wise comparison tests. Stable isotope ratios therefore constitute a valuable forensic signature for ricin preparations.

  7. Significance of Isotopically Labile Organic Hydrogen in Thermal Maturation of Organic Matter

    SciTech Connect (OSTI)

    Arndt Schimmelmann; Maria Mastalerz

    2010-03-30

    Isotopically labile organic hydrogen in fossil fuels occupies chemical positions that participate in isotopic exchange and in chemical reactions during thermal maturation from kerogen to bitumen, oil and gas. Carbon-bound organic hydrogen is isotopically far less exchangeable than hydrogen bound to nitrogen, oxygen, or sulfur. We explore why organic hydrogen isotope ratios express a relationship with organic nitrogen isotope ratios in kerogen at low to moderate maturity. We develop and apply new techniques to utilize organic D/H ratios in organic matter fractions and on a molecular level as tools for exploration for fossil fuels and for paleoenvironmental research. The scope of our samples includes naturally and artificially matured substrates, such as coal, shale, oil and gas.

  8. Pending indoor air quality and radon abatement legislation. Hearing before the Subcommittee on Clean Air and Nuclear Regulation of the Committee on Environment and Public Works, United States Senate, One Hundred Third Congress, First Session on S. 656 and S. 657, May 25, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This hearing on pending indoor air quality and radon abatement legislation includes testimony from individuals and representatives of the following groups: Business Council on Indoor Air; American Lung Association; Consumer Federation of America; Radiation Protection Programs, NJ; School of Hygiene and Public Health, Johns Hopkins University; AFL-CIO; EPA; National Parent Teacher Association. Additional material includes statements from: American Lung Assoc.; Alliance for Radon Reduction; Alliance to Save Energy; American Industrial Hygiene Assoc.; Bowser Morner, Inc.; Building Owners and Managers Assoc. International; Chemical Specialties Manufacturers Assoc.; Council for American Private Education; National Assoc. of Home Builders; National Assoc. of Realtors; National School Boards Assoc.; Sheet Metal and Air Conditioning Contractors National Assoc.

  9. Isotopic generator for bismuth-212 and lead-212 from radium

    DOE Patents [OSTI]

    Atcher, Robert W.; Friedman, Arnold M.; Hines, John

    1987-01-01

    A method and apparatus for providing radionuclides of bismuth-212 and lead-212. Thorium-228 and carrier solution starting material is input to a radiologically contained portion of an isotopic generator system, and radium-224 is separated from thorium-228 which is retained by a strongly basic anion exchange column. The separated radium-224 is transferred to an accessible, strongly acidic cationic exchange column. The cationic column retains the radium-224, and natural radioactive decay generates bismuth-212 and lead-212. The cationic exchange column can also be separated from the contained portion of the system and utilized without the extraordinary safety measures necessary in the contained portion. Furthermore, the cationic exchange column provides over a relatively long time period the short lived lead-212 and bismuth-212 radionuclides which are useful for a variety of medical therapies.

  10. Cryogenic distribution for the Facility for Rare Isotope Beams

    SciTech Connect (OSTI)

    S. Jones, Dana Arenius, Adam Fila, P. Geutschow, Helmut Laumer, Matt Johnson, Cory S. Waltz, J. G. Weisend II

    2012-06-01

    The Facility for Rare Isotope Beams (FRIB) is a new National User Facility for nuclear science funded by the Department of Energy Office of Science and operated by Michigan State University. The FRIB accelerator linac consists of superconducting radio-frequency (SCRF) cavities operating at 2 K and SC magnets operating at 4.5 K all cooled by a large scale cryogenic refrigeration system. A major subsystem of the cryogenic system will be the distribution system whose primary components will include a distribution box, the transfer lines and the interconnect valve boxes at each cryogenic device. An overview of the conceptual design of the distribution system including engineering details, capabilities and schedule is described.

  11. Utilizing Isotopic Uranium Ratios in Groundwater Evaluations at NFSS

    SciTech Connect (OSTI)

    Rhodes, M.C.; Keil, K.G.; Frederick, W.T.; Papura, T.R.; Leithner, J.S.; Peterson, J.M.; MacDonell, M.M.

    2006-07-01

    The U.S. Army Corps of Engineers (USACE) Buffalo District is currently evaluating environmental contamination at the Niagara Falls Storage Site (NFSS) under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as part of its Formerly Utilized Sites Remedial Action Program (FUSRAP). The NFSS is located in the Town of Lewiston in western New York and has been used to store uranium-contaminated materials since 1944. Most of the radioactive materials are currently contained in an on-site structure, but past contamination remains in soil and groundwater. As a naturally occurring radionuclide, uranium is present in all groundwater. Because contamination levels at the site are quite low, it can be difficult to distinguish zones that have been impacted by the past releases from those at the high end of the natural background range. The differences in the isotopic ratio of uranium-234 (U-234) to uranium-238 (U-238) between natural groundwater systems and affected areas are being used in an innovative way to better define the nature and extent of groundwater contamination at NFSS. In natural groundwater, the ratio of U-234 to U-238 exceeds 1 due to the alpha particle recoil effect, in which U-234 is preferentially mobilized to groundwater from adjacent rock or soil. This process is very slow, and it can be hundreds to thousands of years before a measurable impact is seen in the isotopic ratio. Thus, as a result of the recoil effect, the ratio of U-234 to U-238 will be higher in natural groundwater than in contaminated groundwater. This means that if site releases were the source of the uranium being measured in groundwater at NFSS, the ratio of U-234 to U-238 would be expected to be very close to 1 (the same ratio that exists in wastes and soil at the site), because not enough time has elapsed for the alpha particle recoil effect to have significantly altered that ratio. From an evaluation of site and regional groundwater data, an isotopic ratio of 1.2 has been identified as a site-specific signature to help distinguish natural groundwater (e.g., at the high end of the background range) from zones impacted by past releases. This information is crucial for focusing the ongoing CERCLA evaluation and decision making process. This signature value is not applied as a bright line, e.g., to define samples with ratios of U-234 to U-238 above 1.2 as representing background and those with ratios below 1.2 as being affected by site releases. Rather, this ratio serves as a weight of evidence for use in conjunction with other site information, including historical activities, to form science-based decisions regarding contaminated groundwater. This novel approach for developing a groundwater signature from the isotopic uranium ratio has proven to be a very useful tool for NFSS, and it is now being considered for broader application. (authors)

  12. Intruder states in odd-mass Ag isotopes

    SciTech Connect (OSTI)

    Rogowski, J.; Alstad, J.; Brant, S.; Daniels, W.R.; De Frenne, D.; Heyde, K.; Jacobs, E.; Kaffrell, N.; Paar, V.; Skarnemark, G.; Trautmann, N. (Institut fuer Kernchemie, Universitaet Mainz, D-6500 Mainz (Federal Republic of Germany) Department of Chemistry, University of Oslo, N-0315 Oslo (Norway) Prirodoslovno-matematicki fakultet, University of Zagreb, 41000 Zagreb (Yugoslavia) Los Alamos National Laboratory, Los Alamos, NM (USA) Laboratorium voor Kernfysica, Proeftuinstraat 86, B-9000 Gent (Belgium) Department of Nuclear Chemistry, Chalmers University of Technology, S-41296 Goeteborg (Sweden))

    1990-12-01

    The information on the coexistence of deformed intruder states and normal spherical hole-core coupled states in odd-mass Ag nuclei has been extended to the neutron-rich isotopes {sup 113}Ag{sub 66} and {sup 115}Ag{sub 68}. Data have been obtained from an investigation of the {gamma} rays following the {beta}{sup {minus}} decay of the {sup 113,115}Pd precursors. A minimum for the excitation energy of the intruder states occurs in {sup 113}Ag{sub 66}, exactly at neutron midshell. The properties of the intruder states in {sup 109,111,113,115}Ag are discussed and a description in the framework of the interacting-boson-fermion model is presented.

  13. An EBIS system for rare isotope science project in Korea

    SciTech Connect (OSTI)

    Kim, Jongwon E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Han, Jae-Eun E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Son, Hyock-Jun E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Yi, Kun-Hui E-mail: jehan@ibs.re.kr E-mail: khyi@ibs.re.kr; Zhao, Liangji E-mail: kim@far-tech.com; Kim, Jin-Soo E-mail: kim@far-tech.com

    2015-01-09

    An EBIS system has been designed to be used as a charge breeder for the post accelerator of an ISOL system. An electron gun, which is designed to produce a maximum current of 3 A at the beam energy of 20 kV, will be acquired from the Budker Institute, Novosibirsk. Electron beam optics calculations of the EBIS system as well as of the gun assembly have been performed using PBGUNS and TRAK. A superconducting solenoid with a maximum field of 6 T is to be used to compress the electron beam. A test stand, which includes the gun assembly and a high-power electron beam collector, is being designed and will be ready for the gun test in the end of this year. Charge breeding simulation using EBIS0D and CBSIM has been performed for a few key isotopes.

  14. Performance and safety parameters for the high flux isotope reactor

    SciTech Connect (OSTI)

    Ilas, G. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831-6172 (United States); Primm III, T. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831-6172 (United States); Primm Consulting, LLC, 945 Laurel Hill Road, Knoxville, TN 37923 (United States)

    2012-07-01

    A Monte Carlo depletion model for the High Flux Isotope Reactor (HFIR) Cycle 400 and its use in calculating parameters of relevance to the reactor performance and safety during the reactor cycle are presented in this paper. This depletion model was developed to serve as a reference for the design of a low-enriched uranium (LEU) fuel for an ongoing study to convert HFIR from high-enriched uranium (HEU) to LEU fuel; both HEU and LEU depletion models use the same methodology and ENDF/B-VII nuclear data as discussed in this paper. The calculated HFIR Cycle 400 parameters, which are compared with measurement data from critical experiments performed at HFIR, data included in the HFIR Safety Analysis Report (SAR), or data reported by previous calculations, provide a basis for verification or updating of the corresponding SAR data. (authors)

  15. Performance and Safety Parameters for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Ilas, Germina [ORNL; Primm, Trent [Primm Consulting, LLC

    2012-01-01

    A Monte Carlo depletion model for the High Flux Isotope Reactor (HFIR) Cycle 400 and its use in calculating parameters of relevance to the reactor performance and safety during the reactor cycle are presented in this paper. This depletion model was developed to serve as a reference for the design of a low-enriched uranium (LEU) fuel for an ongoing study to convert HFIR from high-enriched uranium (HEU) to LEU fuel; both HEU and LEU depletion models use the same methodology and ENDV/B-VII nuclear data as discussed in this paper. The calculated HFIR Cycle 400 parameters, which are compared when available with measurement data from critical experiments performed at HFIR, data included in the HFIR Safety Analysis Report (SAR), or data reported by previous calculations, provide a basis for verification or updating of the corresponding SAR data.

  16. Methods for separating medical isotopes using ionic liquids

    DOE Patents [OSTI]

    Luo, Huimin; Boll, Rose Ann; Bell, Jason Richard; Dai, Sheng

    2014-10-21

    A method for extracting a radioisotope from an aqueous solution, the method comprising: a) intimately mixing a non-chelating ionic liquid with the aqueous solution to transfer at least a portion of said radioisotope to said non-chelating ionic liquid; and b) separating the non-chelating ionic liquid from the aqueous solution. In preferred embodiments, the method achieves an extraction efficiency of at least 80%, or a separation factor of at least 1.times.10.sup.4 when more than one radioisotope is included in the aqueous solution. In particular embodiments, the method is applied to the separation of medical isotopes pairs, such as Th from Ac (Th-229/Ac-225, Ac-227/Th-227), or Ra from Ac (Ac-225 and Ra-225, Ac-227 and Ra-223), or Ra from Th (Th-227 and Ra-223, Th-229 and Ra-225).

  17. CRYOGENIC ADSORPTION OF HYDROGEN ISOTOPES OVER NANO-STRUCTURED MATERIALS

    SciTech Connect (OSTI)

    Xiao, S.; Heung, L.

    2010-10-07

    Porous materials such as zeolites, activated carbon, silica gels, alumina and a number of industrial catalysts are compared and ranked for hydrogen and deuterium adsorption at liquid nitrogen temperature. All samples show higher D{sub 2} adsorption than that of H{sub 2}, in which a HY sample has the greatest isotopic effect while 13X has the highest hydrogen uptake capacity. Material's moisture content has significant impact to its hydrogen uptake. A material without adequate drying could result in complete loss of its adsorption capacity. Even though some materials present higher H{sub 2} adsorption capacity at full pressure, their adsorption at low vapor pressure may not be as good as others. Adsorption capacity in a dynamic system is much less than in a static system. A sharp desorption is also expected in case of temperature upset.

  18. NEST-GENERATION TCAP HYDROGEN ISOTOPE SEPARATION PROCESS

    SciTech Connect (OSTI)

    Heung, L; Henry Sessions, H; Anita Poore, A; William Jacobs, W; Christopher Williams, C

    2007-08-07

    A thermal cycling absorption process (TCAP) for hydrogen isotope separation has been in operation at Savannah River Site since 1994. The process uses a hot/cold nitrogen system to cycle the temperature of the separation column. The hot/cold nitrogen system requires the use of large compressors, heat exchanges, valves and piping that is bulky and maintenance intensive. A new compact thermal cycling (CTC) design has recently been developed. This new design uses liquid nitrogen tubes and electric heaters to heat and cool the column directly so that the bulky hot/cold nitrogen system can be eliminated. This CTC design is simple and is easy to implement, and will be the next generation TCAP system at SRS. A twelve-meter column has been fabricated and installed in the laboratory to demonstrate its performance. The design of the system and its test results to date is discussed.

  19. Ion extraction and charge exchange in laser isotope separation

    SciTech Connect (OSTI)

    Hostein, D.; Doneddu, F.

    1996-02-01

    In the atomic vapor laser isotope separation (AVLIS) process, a vapor is ionized by pulsed laser beams, and the ions are extracted by negatively biased collectors. The authors compute the unsteady dynamics of the photoplasma using a two-dimensional (2-D) particle-in-cell (PIC) code. Collisions between ions and neutral species are simulated by a Monte Carlo technique. The plasma dynamics is visualized by snapshots of particle positions showing the directions of their velocities. The three kinds of particles (electrons, photo-ions, and ions created by charge exchange) are marked by different colors. The graphic outputs illustrate the motion of the electrons toward the anodes, the vertical drift of the plasma, its erosion by the transient ion sheath, and nonselective ionization by charge exchange.

  20. Beta-decay measurements of neutron-deficient cesium isotopes

    SciTech Connect (OSTI)

    Parry, R.F.

    1983-03-01

    Beta decay endpoint energy measurements of the neutron deficient cesium isotopes were done using an energy spectrum shape fitting technique. This was a departure from the typical method of endpoint energy analysis, the Fermi-Kurie plot. A discussion of the shape fitting procedure and its improved features are discussed. These beta endpoint measurements have led to total decay energies (Q/sub EC/) of the neutron deficient /sup 119/ /sup 123/Cs isotopes. The total decay energies of /sup 122m/Cs (Q/sub EC/ = 6.95 +- 0.25 MeV) and /sup 119/Cs (Q/sub EC/ = 6.26 +- 0.29 MeV) were new measurements. The total decay energies of /sup 123/Cs (Q/sub EC/ = 4.05 +- 0.18 MeV), /sup 122g/Cs (Q/sub EC/ = 7.05 +- 0.18 MeV), /sup 121/Cs (Q/sub EC/ = 5.21 +- 0.22 MeV), and /sup 120/Cs (Q/sub EC/ = 7.38 +- 0.23 MeV) were measurements with significantly improved uncertainties as compared to the literature. Further, a combination of the energy levels derived from previous literature gamma-gamma coincident measurements and the experimental beta-coincident gamma decay energies has supported an improved level scheme for /sup 121/Xe and the proposal of three new energy levels in /sup 119/Xe. Comparison of the experimental cesium mass excesses (determined with our Q/sub EC/ values and known xenon mass excesses) with both the literature and theoretical predicted values showed general agreement except for /sup 120/Cs. Possible explanations for this deviation are discussed.

  1. Utilization of Kinetic Isotope Effects for the Concentration of Tritium

    SciTech Connect (OSTI)

    Brown, Gilbert M.; Meyer, Thomas j.; Moyer, Bruce A.

    1999-06-01

    The objective of this research program is to develop methods for concentrating tritium in water based on large primary isotope effects in catalytic redox processes. Basic research is being conducted to develop the chemistry of a complete cyclic process. Because tritium (generally present as HTO) is in a rapidly established equilibrium with protio-water, it moves with groundwater and separation from water cannot be achieved by the usual pump-and-treat methods using sorbants. The general methodology developed in this work will be applicable to a number of DOE waste streams, and as a consequence of the process tritium will be incorporated into an organic compound that will not readily exchange the tritium with groundwater. The process to be developed will remove tritium from H2O by concentrating it with respect to protio-water. This research involves developing chemical cycles that produce high concentration factors for HTO and T2O based on the discrimination of C-H and C-T bonds in oxidation reactions. Several steps are required in a cyclic process for the concentration of tritium in water. In the first step the tritium is incorporated in an organic compound. H-T discrimination occurs as the tritium containing compound is oxidized in a step involving a Ru(IV) oxo complex. Strong primary kinetic isotope effects lead to the oxidation of C-H bonds in preference to C-T bonds, and this reaction leads to concentration of tritium in the organic compound. The reduced form of the ruthenium compound can be reoxidized so that the oxidation step can be made catalytic.

  2. Hanford isotope project strategic business analysis yttrium-90 (Y-90)

    SciTech Connect (OSTI)

    1995-10-01

    The purpose of this analysis is to address the short-term direction for the Hanford yttrium-90 (Y-90) project. Hanford is the sole DOE producer of Y-90, and is the largest repository for its source in this country. The production of Y-90 is part of the DOE Isotope Production and Distribution (IP and D) mission. The Y-90 is ``milked`` from strontium-90 (Sr-90), a byproduct of the previous Hanford missions. The use of Sr-90 to produce Y-90 could help reduce the amount of waste material processed and the related costs incurred by the clean-up mission, while providing medical and economic benefits. The cost of producing Y-90 is being subsidized by DOE-IP and D due to its use for research, and resultant low production level. It is possible that the sales of Y-90 could produce full cost recovery within two to three years, at two curies per week. Preliminary projections place the demand at between 20,000 and 50,000 curies per year within the next ten years, assuming FDA approval of one or more of the current therapies now in clinical trials. This level of production would incentivize private firms to commercialize the operation, and allow the government to recover some of its sunk costs. There are a number of potential barriers to the success of the Y-90 project, outside the control of the Hanford Site. The key issues include: efficacy, Food and Drug Administration (FDA) approval and medical community acceptance. There are at least three other sources for Y-90 available to the US users, but they appear to have limited resources to produce the isotope. Several companies have communicated interest in entering into agreements with Hanford for the processing and distribution of Y-90, including some of the major pharmaceutical firms in this country.

  3. Small Stirling dynamic isotope power system for robotic space missions

    SciTech Connect (OSTI)

    Bents, D.J.

    1992-08-01

    The design of a multihundred-watt Dynamic Isotope Power System (DIPS), based on the US Department of Energy (DOE) General Purpose Heat Source (GPHS) and small (multihundred-watt) free-piston Stirling engine (FPSE), is being pursued as a potential lower cost alternative to radioisotope thermoelectric generators (RTG's). The design is targeted at the power needs of future unmanned deep space and planetary surface exploration missions ranging from scientific probes to Space Exploration Initiative precursor missions. Power level for these missions is less than a kilowatt. The incentive for any dynamic system is that it can save fuel and reduce costs and radiological hazard. Unlike DIPS based on turbomachinery conversion (e.g. Brayton), this small Stirling DIPS can be advantageously scaled to multihundred-watt unit size while preserving size and mass competitiveness with RTG's. Stirling conversion extends the competitive range for dynamic systems down to a few hundred watts--a power level not previously considered for dynamic systems. The challenge for Stirling conversion will be to demonstrate reliability and life similar to RTG experience. Since the competitive potential of FPSE as an isotope converter was first identified, work has focused on feasibility of directly integrating GPHS with the Stirling heater head. Thermal modeling of various radiatively coupled heat source/heater head geometries has been performed using data furnished by the developers of FPSE and GPHS. The analysis indicates that, for the 1050 K heater head configurations considered, GPHS fuel clad temperatures remain within acceptable operating limits. Based on these results, preliminary characterizations of multihundred-watt units have been established.

  4. Innovative lasers for uranium isotope separation. [Progress report

    SciTech Connect (OSTI)

    Brake, M.L.; Gilgenbach, R.M.

    1991-06-01

    Copper vapor lasers have important applications to uranium atomic vapor laser isotope separation (AVLIS). The authors have spent the first two years of their project investigating two innovative methods of exciting/pumping copper vapor lasers which have the potential to improve the efficiency and scaling of large laser systems used in uranium isotope separation. Experimental research has focused on the laser discharge kinetics of (1) microwave, and (2) electron beam excitation/pumping of large-volume copper vapor lasers. During the first year, the experiments have been designed and constructed and initial data has been taken. During the second year these experiments have been diagnosed. Highlights of some of the second year results as well as plans for the future include the following: Microwave resonant cavity produced copper vapor plasmas at 2.45 GHz, have been investigated. A CW (0--500 W) signal heats and vaporizes the copper chloride to provide the atomic copper vapor. A pulsed (5 kW, 0.5--5kHz) signal is added to the incoming CW signal via a hybrid mixer to excite the copper states to the laser levels. An enhancement of the visible radiation has been observed during the pulsed pardon of the signal. Electrical probe measurements have been implemented on the system to verify the results of the electromagnetic model formulated last year. Laser gain measurements have been initiated with the use of a commercial copper vapor laser. Measurements of the spatial profile of the emission are also currently being made. The authors plan to increase the amount of pulsed microwave power to the system by implementing a high power magnetron. A laser cavity will be designed and added to this system.

  5. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  6. Chromium Isotope Fractionation During Reduction of Cr(VI) Under Saturated Flow Conditions

    SciTech Connect (OSTI)

    Jamieson-Hanes, Julia H.; Gibson, Blair D.; Lindsay, Matthew B.J.; Kim, Yeongkyoo; Ptacek, Carol J.; Blowes, David W.

    2012-10-25

    Chromium isotopes are potentially useful indicators of Cr(VI) reduction reactions in groundwater flow systems; however, the influence of transport on Cr isotope fractionation has not been fully examined. Laboratory batch and column experiments were conducted to evaluate isotopic fractionation of Cr during Cr(VI) reduction under both static and controlled flow conditions. Organic carbon was used to reduce Cr(VI) in simulated groundwater containing 20 mg L{sup -1} Cr(VI) in both batch and column experiments. Isotope measurements were performed on dissolved Cr on samples from the batch experiments, and on effluent and profile samples from the column experiment. Analysis of the residual solid-phase materials by scanning electron microscopy (SEM) and by X-ray absorption near edge structure (XANES) spectroscopy confirmed association of Cr(III) with organic carbon in the column solids. Decreases in dissolved Cr(VI) concentrations were coupled with increases in {delta}{sup 53}Cr, indicating that Cr isotope enrichment occurred during reduction of Cr(VI). The {delta}{sup 53}Cr data from the column experiment was fit by linear regression yielding a fractionation factor ({alpha}) of 0.9979, whereas the batch experiments exhibited Rayleigh-type isotope fractionation ({alpha} = 0.9965). The linear characteristic of the column {delta}{sup 53}Cr data may reflect the contribution of transport on Cr isotope fractionation.

  7. Simple interpretation of shape evolution in Pt isotopes without intruder states

    SciTech Connect (OSTI)

    McCutchan, E.A.; Casten, R.F.; Zamfir, N.V.

    2005-06-01

    The most commonly accepted interpretation of the light Pt isotopes invokes the coexistence and mixing with proton intruder states from above the Z = 82 shell gap. Using an alternative description, interacting boson model (IBA) calculations are performed for the Pt isotopes with a simple, single configuration, two-parameter Hamiltonian. Excellent agreement is obtained for energies and electromagnetic transition strengths over the entire isotopic chain, spanning a wide variety of structures, and suggesting that these nuclei can be described more simply without the introduction of an intruder configuration. The Pt nuclei close to midshell are found to lie close to a region of phase/shape coexistence.

  8. Capillary absorption spectrometer and process for isotopic analysis of small samples

    DOE Patents [OSTI]

    Alexander, M. Lizabeth; Kelly, James F.; Sams, Robert L.; Moran, James J.; Newburn, Matthew K.; Blake, Thomas A.

    2016-03-29

    A capillary absorption spectrometer and process are described that provide highly sensitive and accurate stable absorption measurements of analytes in a sample gas that may include isotopologues of carbon and oxygen obtained from gas and biological samples. It further provides isotopic images of microbial communities that allow tracking of nutrients at the single cell level. It further targets naturally occurring variations in carbon and oxygen isotopes that avoids need for expensive isotopically labeled mixtures which allows study of samples taken from the field without modification. The method also permits sampling in vivo permitting real-time ambient studies of microbial communities.

  9. Isotope and Nuclear Chemistry Division annual report FY 1986, October 1985-September 1986

    SciTech Connect (OSTI)

    Heiken, J.H.

    1987-06-01

    This report describes progress in the major research and development programs carried out in FY 1986 by the Isotope and Nuclear Chemistry Division. The report includes articles on radiochemical diagnostics and weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production and separation; chemical biology and nuclear medicine; element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced concepts and technology; and atmospheric chemistry.

  10. Application of the Isotope Ratio Method to a Boiling Water Reactor

    SciTech Connect (OSTI)

    Frank, Douglas P.; Gerlach, David C.; Gesh, Christopher J.; Hurley, David E.; Meriwether, George H.; Mitchell, Mark R.; Reid, Bruce D.

    2010-08-11

    The isotope ratio method is a technique for estimating the energy or plutonium production in a fission reactor by measuring isotope ratios in non-fuel reactor components. The isotope ratios in these components can then be directly related to the cumulative energy production with standard reactor modeling methods. All reactor materials contain trace elemental impurities at parts per million levels, and the isotopes of these elements are transmuted by neutron irradiation in a predictable manner. While measuring the change in a particular isotopes concentration is possible, it is difficult to correlate to energy production because the initial concentration of that element may not be accurately known. However, if the ratio of two isotopes of the same element can be measured, the energy production can then be determined without knowing the absolute concentration of that impurity since the initial natural ratio is known. This is the fundamental principle underlying the isotope ratio method. Extremely sensitive mass-spectrometric methods are currently available that allow accurate measurements of the impurity isotope ratios in samples. Additionally, indicator elements with stable activation products have been identified so that their post-irradiation isotope ratios remain constant. This method has been successfully demonstrated on graphite-moderated reactors. Graphite reactors are particularly well-suited to such analyses since the graphite moderator is resident in the fueled region of the core for the entire period of operation. Applying this method to other reactor types is more difficult since the resident portions of the reactor available for sampling are either outside the fueled region of the core or structural components of individual fuel assemblies. The goal of this research is to show that the isotope ratio method can produce meaningful results for light water-moderated power reactors. In this work, we use the isotope ratio method to estimate the energy production in a boiling water reactor fuel bundle based on measurements taken from the corresponding fuel assembly channel. Our preliminary results are in good agreement with the actual operating history of the reactor during the cycle that the fuel bundle was resident in the core.

  11. Modeling and Simulations for the High Flux Isotope Reactor Cycle 400

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Modeling and Simulations for the High Flux Isotope Reactor Cycle 400 Citation Details In-Document Search Title: Modeling and Simulations for the High Flux Isotope Reactor Cycle 400 A concerted effort over the past few years has been focused on enhancing the core model for the High Flux Isotope Reactor (HFIR), as part of a comprehensive study for HFIR conversion from high-enriched uranium (HEU) to low-enriched uranium (LEU) fuel. At this time, the core

  12. Motivation for New Measurements on 241, 242, 243Am Isotopes (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Motivation for New Measurements on 241, 242, 243Am Isotopes Citation Details In-Document Search Title: Motivation for New Measurements on 241, 242, 243Am Isotopes The initial objective of this work was an updated review on the Am isotopes data since the next official release (3.1) of the JEFF3 evaluated data file is foreseen around June 2005. Alternatively, this work searches for the possible reasons of the observed discrepancies between differential and integral

  13. Age and isotopic relationships among the angrites Lewis Cliff 86010 and Angra dos Reis

    SciTech Connect (OSTI)

    Lugmair, G.W. ); Galer, S.J.G. Max-Planck-Inst. fuer Chemie, Mainz )

    1992-04-01

    Results of a wide-ranging isotopic investigation of the unique Antarctican angrite LEW-86010 (LEW) are presented, together with a reassessment of the type angrite Angra dos Reis (ADOR). The principal objectives of this study are to obtain precise radiometric ages, initial Sr isotopic compositions, and to search for the erstwhile presence of the short-lived nuclei {sup 146}Sm and {sup 26}Al via their daughter products. The isotopic compositions of Sm, U, Ca, and Ti were also measured. This allows a detailed appraisal to be made of the relations between, and the genealogy of, these two angrites.

  14. Integrated safeguards and security for the INEL Special Isotope Separation Plant

    SciTech Connect (OSTI)

    Warner, G.F.; Zack, N.R.

    1990-06-12

    This paper describes the approach that was taken in developing safeguards and security design criteria to be used for the Special Isotope Separation (SIS) Production Plant. The US Department of Energy has postponed the construction of the SIS Production Plant that was to be built at the Idaho National Engineering Laboratory (INEL) site located near Idaho Falls, Idaho. The SIS Plant planned to isotopically enrich plutonium utilizing the Atomic Vapor Laser Isotope Separation (AVLIS) process developed at the Lawrence Livermore National Laboratory. Westinghouse Idaho Nuclear Co., Inc. as a prime contractor to the DOE Idaho Operations Office, was to operate the Plant.

  15. Preliminary Notice of Violation, International Isotopes Idaho, Inc.- EA-2000-04

    Broader source: Energy.gov [DOE]

    Issued to International Isotopes Idaho, Inc., related to Work Planning and Control Deficiencies associated with Replacement of Exhaust Ventilation Filters at the Test Reactor Area Hot Cell Facility at the Idaho National Engineering and Environmental Laboratory, May 19, 2000

  16. EA-1211: Relocation and Storage of Isotopic Heat Sources, Hanford Site, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal for relocation and storage of the isotopic heat sources at the U.S. Department of Energy Hanford Site in Richland, Washington.

  17. Facility for Rare Isotope Beams: The Journey Has Begun on DOE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... At the heart of the Facility for Rare Isotope Beams will be a state of the art ... more familiar with and by studying their creation, scientists are able to explore and more ...

  18. Understanding H isotope adsorption and absorption of Al-alloys using modeling and experiments (LDRD: #165724)

    SciTech Connect (OSTI)

    Ward, Donald K.; Zhou, Xiaowang; Karnesky, Richard A.; Kolasinski, Robert; Foster, Michael E.; Thurmer, Konrad; Chao, Paul; Epperly, Ethan Nicholas; Zimmerman, Jonathan A.; Wong, Bryan M.; Sills, Ryan B.

    2015-09-01

    Current austenitic stainless steel storage reservoirs for hydrogen isotopes (e.g. deuterium and tritium) have performance and operational life-limiting interactions (e.g. embrittlement) with H-isotopes. Aluminum alloys (e.g.AA2219), alternatively, have very low H-isotope solubilities, suggesting high resistance towards aging vulnerabilities. This report summarizes the work performed during the life of the Lab Directed Research and Development in the Nuclear Weapons investment area (165724), and provides invaluable modeling and experimental insights into the interactions of H isotopes with surfaces and bulk AlCu-alloys. The modeling work establishes and builds a multi-scale framework which includes: a density functional theory informed bond-order potential for classical molecular dynamics (MD), and subsequent use of MD simulations to inform defect level dislocation dynamics models. Furthermore, low energy ion scattering and thermal desorption spectroscopy experiments are performed to validate these models and add greater physical understanding to them.

  19. Isotopic identification of soil and permafrost nitrate sources in an Arctic tundra ecosystem

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Heikoop, Jeffrey M.; Throckmorton, Heather M.; Newman, Brent D.; Perkins, George B.; Iversen, Colleen M.; Chowdhury, Taniya Roy; Romanovsky, Vladimir; Graham, David E.; Norby, Richard J.; Wilson, Cathy J.; et al

    2015-05-13

    The nitrate (NO3–) dual isotope approach was applied to snowmelt, tundra active layer pore waters, and underlying permafrost in Barrow, Alaska, USA, to distinguish between NO3– derived from atmospheric deposition versus that derived from microbial nitrification.

  20. Quantum fluctuations and isotope effects in ab initio descriptions of water

    SciTech Connect (OSTI)

    Wang, Lu; Markland, Thomas E.; Ceriotti, Michele

    2014-09-14

    Isotope substitution is extensively used to investigate the microscopic behavior of hydrogen bonded systems such as liquid water. The changes in structure and stability of these systems upon isotope substitution arise entirely from the quantum mechanical nature of the nuclei. Here, we provide a fully ab initio determination of the isotope exchange free energy and fractionation ratio of hydrogen and deuterium in water treating exactly nuclear quantum effects and explicitly modeling the quantum nature of the electrons. This allows us to assess how quantum effects in water manifest as isotope effects, and unravel how the interplay between electronic exchange and correlation and nuclear quantum fluctuations determine the structure of the hydrogen bond in water.