National Library of Energy BETA

Sample records for queries compound queries

  1. compound queries | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  2. Multicolor Maps from Compound Queries | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  3. Query | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Query Query Query Query_1.pdf Query (104.29 KB) More Documents & Publications DOE Retrospective Review Plan and Burden Reduction Report July 29, 2013 DOE EO 13563 January 2014 Update Report and Burden Reduction Efforts DOE Retrospective Review Plan and Burden Reduction Report - December 18, 2012

  4. ask queries | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  5. Query

    Energy Savers [EERE]

    DOEIN CIA 12182006 12172008 Executive Office of the President, Council on Dixon, Robert K. DOEEE Environmental Quality (CEQ) 10232007 2232009 Dumaine, Carol CIA DOEIN ...

  6. SPARQL Query Form | OpenEI

    Open Energy Info (EERE)

    where a ?Concept LIMIT 100 Display Results As: Auto HTML Spreadsheet XML JSON Javascript NTriples RDFXML Rigorous check of the query Execution timeout, in milliseconds,...

  7. Oregon Certified Water Right Examiners Query Webpage | Open Energy...

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Oregon Certified Water Right Examiners Query Webpage Citation State of...

  8. Increasing ask query limit | OpenEI Community

    Open Energy Info (EERE)

    via json. For example, this query only returns two entries: http:en.openei.orgservicesrestutilityrates?versionlatest&formatjsonplain&offset9998&limit30&detailb...

  9. Query-Driven Visualization and Analysis

    SciTech Connect (OSTI)

    Ruebel, Oliver; Bethel, E. Wes; Prabhat, Mr.; Wu, Kesheng

    2012-11-01

    This report focuses on an approach to high performance visualization and analysis, termed query-driven visualization and analysis (QDV). QDV aims to reduce the amount of data that needs to be processed by the visualization, analysis, and rendering pipelines. The goal of the data reduction process is to separate out data that is "scientifically interesting'' and to focus visualization, analysis, and rendering on that interesting subset. The premise is that for any given visualization or analysis task, the data subset of interest is much smaller than the larger, complete data set. This strategy---extracting smaller data subsets of interest and focusing of the visualization processing on these subsets---is complementary to the approach of increasing the capacity of the visualization, analysis, and rendering pipelines through parallelism. This report discusses the fundamental concepts in QDV, their relationship to different stages in the visualization and analysis pipelines, and presents QDV's application to problems in diverse areas, ranging from forensic cybersecurity to high energy physics.

  10. HDF5-FastQuery: An API for Simplifying Access to Data Storage,Retrieval, Indexing and Querying

    SciTech Connect (OSTI)

    Bethel, E. Wes; Gosink, Luke; Shalf, John; Stockinger, Kurt; Wu,Kesheng

    2006-06-15

    This work focuses on research and development activities that bridge a gap between fundamental data management technology index, query, storage and retrieval and use of such technology in computational and computer science algorithms and applications. The work has resulted in a streamlined applications programming interface (API) that simplifies data storage and retrieval using the HDF5 data I/O library, and eases use of the FastBit compressed bitmap indexing software for data indexing/querying. The API, which we call HDF5-FastQuery, will have broad applications in domain sciences as well as associated data analysis and visualization applications.

  11. T-703: Cisco Unified Communications Manager Open Query Interface Lets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remote Users Obtain Database Contents | Department of Energy 703: Cisco Unified Communications Manager Open Query Interface Lets Remote Users Obtain Database Contents T-703: Cisco Unified Communications Manager Open Query Interface Lets Remote Users Obtain Database Contents August 26, 2011 - 3:45pm Addthis PROBLEM: A vulnerability was reported in Cisco Unified Communications Manager. A remote user can obtain database contents PLATFORM: Cisco Unified Communications Manager 6.x, 7.x, 8.0, 8.5

  12. Parallel Index and Query for Large Scale Data Analysis

    SciTech Connect (OSTI)

    Chou, Jerry; Wu, Kesheng; Ruebel, Oliver; Howison, Mark; Qiang, Ji; Prabhat,; Austin, Brian; Bethel, E. Wes; Ryne, Rob D.; Shoshani, Arie

    2011-07-18

    Modern scientific datasets present numerous data management and analysis challenges. State-of-the-art index and query technologies are critical for facilitating interactive exploration of large datasets, but numerous challenges remain in terms of designing a system for process- ing general scientific datasets. The system needs to be able to run on distributed multi-core platforms, efficiently utilize underlying I/O infrastructure, and scale to massive datasets. We present FastQuery, a novel software framework that address these challenges. FastQuery utilizes a state-of-the-art index and query technology (FastBit) and is designed to process mas- sive datasets on modern supercomputing platforms. We apply FastQuery to processing of a massive 50TB dataset generated by a large scale accelerator modeling code. We demonstrate the scalability of the tool to 11,520 cores. Motivated by the scientific need to search for inter- esting particles in this dataset, we use our framework to reduce search time from hours to tens of seconds.

  13. Secure quantum private information retrieval using phase-encoded queries

    SciTech Connect (OSTI)

    Olejnik, Lukasz

    2011-08-15

    We propose a quantum solution to the classical private information retrieval (PIR) problem, which allows one to query a database in a private manner. The protocol offers privacy thresholds and allows the user to obtain information from a database in a way that offers the potential adversary, in this model the database owner, no possibility of deterministically establishing the query contents. This protocol may also be viewed as a solution to the symmetrically private information retrieval problem in that it can offer database security (inability for a querying user to steal its contents). Compared to classical solutions, the protocol offers substantial improvement in terms of communication complexity. In comparison with the recent quantum private queries [Phys. Rev. Lett. 100, 230502 (2008)] protocol, it is more efficient in terms of communication complexity and the number of rounds, while offering a clear privacy parameter. We discuss the security of the protocol and analyze its strengths and conclude that using this technique makes it challenging to obtain the unconditional (in the information-theoretic sense) privacy degree; nevertheless, in addition to being simple, the protocol still offers a privacy level. The oracle used in the protocol is inspired both by the classical computational PIR solutions as well as the Deutsch-Jozsa oracle.

  14. Query optimization for graph analytics on linked data using SPARQL

    SciTech Connect (OSTI)

    Hong, Seokyong; Lee, Sangkeun; Lim, Seung -Hwan; Sukumar, Sreenivas R.; Vatsavai, Ranga Raju

    2015-07-01

    Triplestores that support query languages such as SPARQL are emerging as the preferred and scalable solution to represent data and meta-data as massive heterogeneous graphs using Semantic Web standards. With increasing adoption, the desire to conduct graph-theoretic mining and exploratory analysis has also increased. Addressing that desire, this paper presents a solution that is the marriage of Graph Theory and the Semantic Web. We present software that can analyze Linked Data using graph operations such as counting triangles, finding eccentricity, testing connectedness, and computing PageRank directly on triple stores via the SPARQL interface. We describe the process of optimizing performance of the SPARQL-based implementation of such popular graph algorithms by reducing the space-overhead, simplifying iterative complexity and removing redundant computations by understanding query plans. Our optimized approach shows significant performance gains on triplestores hosted on stand-alone workstations as well as hardware-optimized scalable supercomputers such as the Cray XMT.

  15. Large-Scale Continuous Subgraph Queries on Streams

    SciTech Connect (OSTI)

    Choudhury, Sutanay; Holder, Larry; Chin, George; Feo, John T.

    2011-11-30

    Graph pattern matching involves finding exact or approximate matches for a query subgraph in a larger graph. It has been studied extensively and has strong applications in domains such as computer vision, computational biology, social networks, security and finance. The problem of exact graph pattern matching is often described in terms of subgraph isomorphism which is NP-complete. The exponential growth in streaming data from online social networks, news and video streams and the continual need for situational awareness motivates a solution for finding patterns in streaming updates. This is also the prime driver for the real-time analytics market. Development of incremental algorithms for graph pattern matching on streaming inputs to a continually evolving graph is a nascent area of research. Some of the challenges associated with this problem are the same as found in continuous query (CQ) evaluation on streaming databases. This paper reviews some of the representative work from the exhaustively researched field of CQ systems and identifies important semantics, constraints and architectural features that are also appropriate for HPC systems performing real-time graph analytics. For each of these features we present a brief discussion of the challenge encountered in the database realm, the approach to the solution and state their relevance in a high-performance, streaming graph processing framework.

  16. Towards Optimal Multi-Dimensional Query Processing with BitmapIndices

    SciTech Connect (OSTI)

    Rotem, Doron; Stockinger, Kurt; Wu, Kesheng

    2005-09-30

    Bitmap indices have been widely used in scientific applications and commercial systems for processing complex, multi-dimensional queries where traditional tree-based indices would not work efficiently. This paper studies strategies for minimizing the access costs for processing multi-dimensional queries using bitmap indices with binning. Innovative features of our algorithm include (a) optimally placing the bin boundaries and (b) dynamically reordering the evaluation of the query terms. In addition, we derive several analytical results concerning optimal bin allocation for a probabilistic query model. Our experimental evaluation with real life data shows an average I/O cost improvement of at least a factor of 10 for multi-dimensional queries on datasets from two different applications. Our experiments also indicate that the speedup increases with the number of query dimensions.

  17. V-204: A specially crafted query can cause BIND to terminate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    affected source distributions may crash with assertion failures triggered in the same fashion. IMPACT: A specially crafted DNS query could cause the DNS service to terminate...

  18. Minimizing I/O Costs of Multi-Dimensional Queries with BitmapIndices

    SciTech Connect (OSTI)

    Rotem, Doron; Stockinger, Kurt; Wu, Kesheng

    2006-03-30

    Bitmap indices have been widely used in scientific applications and commercial systems for processing complex,multi-dimensional queries where traditional tree-based indices would not work efficiently. A common approach for reducing the size of a bitmap index for high cardinality attributes is to group ranges of values of an attribute into bins and then build a bitmap for each bin rather than a bitmap for each value of the attribute. Binning reduces storage costs,however, results of queries based on bins often require additional filtering for discarding it false positives, i.e., records in the result that do not satisfy the query constraints. This additional filtering,also known as ''candidate checking,'' requires access to the base data on disk and involves significant I/O costs. This paper studies strategies for minimizing the I/O costs for ''candidate checking'' for multi-dimensional queries. This is done by determining the number of bins allocated for each dimension and then placing bin boundaries in optimal locations. Our algorithms use knowledge of data distribution and query workload. We derive several analytical results concerning optimal bin allocation for a probabilistic query model. Our experimental evaluation with real life data shows an average I/O cost improvement of at least a factor of 10 for multi-dimensional queries on datasets from two different applications. Our experiments also indicate that the speedup increases with the number of query dimensions.

  19. Cyber Graph Queries for Geographically Distributed Data Centers

    SciTech Connect (OSTI)

    Berry, Jonathan W.; Collins, Michael; Kearns, Aaron; Phillips, Cynthia A.; Saia, Jared

    2015-05-01

    We present new algorithms for a distributed model for graph computations motivated by limited information sharing we first discussed in [20]. Two or more independent entities have collected large social graphs. They wish to compute the result of running graph algorithms on the entire set of relationships. Because the information is sensitive or economically valuable, they do not wish to simply combine the information in a single location. We consider two models for computing the solution to graph algorithms in this setting: 1) limited-sharing: the two entities can share only a polylogarithmic size subgraph; 2) low-trust: the entities must not reveal any information beyond the query answer, assuming they are all honest but curious. We believe this model captures realistic constraints on cooperating autonomous data centers. We have algorithms in both setting for s - t connectivity in both models. We also give an algorithm in the low-communication model for finding a planted clique. This is an anomaly- detection problem, finding a subgraph that is larger and denser than expected. For both the low- communication algorithms, we exploit structural properties of social networks to prove perfor- mance bounds better than what is possible for general graphs. For s - t connectivity, we use known properties. For planted clique, we propose a new property: bounded number of triangles per node. This property is based upon evidence from the social science literature. We found that classic examples of social networks do not have the bounded-triangles property. This is because many social networks contain elements that are non-human, such as accounts for a business, or other automated accounts. We describe some initial attempts to distinguish human nodes from automated nodes in social networks based only on topological properties.

  20. Practical private database queries based on a quantum-key-distribution protocol

    SciTech Connect (OSTI)

    Jakobi, Markus; Simon, Christoph; Gisin, Nicolas; Bancal, Jean-Daniel; Branciard, Cyril; Walenta, Nino; Zbinden, Hugo

    2011-02-15

    Private queries allow a user, Alice, to learn an element of a database held by a provider, Bob, without revealing which element she is interested in, while limiting her information about the other elements. We propose to implement private queries based on a quantum-key-distribution protocol, with changes only in the classical postprocessing of the key. This approach makes our scheme both easy to implement and loss tolerant. While unconditionally secure private queries are known to be impossible, we argue that an interesting degree of security can be achieved by relying on fundamental physical principles instead of unverifiable security assumptions in order to protect both the user and the database. We think that the scope exists for such practical private queries to become another remarkable application of quantum information in the footsteps of quantum key distribution.

  1. U-038: BIND 9 Resolver crashes after logging an error in query.c

    Broader source: Energy.gov [DOE]

    A remote server can cause the target connected client to crash. Organizations across the Internet are reporting crashes interrupting service on BIND 9 nameservers performing recursive queries. Affected servers crash after logging an error in query.c with the following message: "INSIST(! dns_rdataset_isassociated(sigrdataset))" Multiple versions are reported as being affected, including all currently supported release versions of ISC BIND 9. ISC is actively investigating the root cause and working to produce patches which avoid the crash.

  2. U-039: ISC Update: BIND 9 Resolver crashes after logging an error in query.c

    Broader source: Energy.gov [DOE]

    A remote server can cause the target connected client to crash. Organizations across the Internet are reporting crashes interrupting service on BIND 9 nameservers performing recursive queries. Affected servers crash after logging an error in query.c with the following message: "INSIST(! dns_rdataset_isassociated(sigrdataset))" Multiple versions are reported as being affected, including all currently supported release versions of ISC BIND 9. ISC is actively investigating the root cause and working to produce patches which avoid the crash.

  3. An Application of Multivariate Statistical Analysis for Query-Driven Visualization

    SciTech Connect (OSTI)

    Gosink, Luke J.; Garth, Christoph; Anderson, John C.; Bethel, E. Wes; Joy, Kenneth I.

    2010-03-01

    Abstract?Driven by the ability to generate ever-larger, increasingly complex data, there is an urgent need in the scientific community for scalable analysis methods that can rapidly identify salient trends in scientific data. Query-Driven Visualization (QDV) strategies are among the small subset of techniques that can address both large and highly complex datasets. This paper extends the utility of QDV strategies with a statistics-based framework that integrates non-parametric distribution estimation techniques with a new segmentation strategy to visually identify statistically significant trends and features within the solution space of a query. In this framework, query distribution estimates help users to interactively explore their query's solution and visually identify the regions where the combined behavior of constrained variables is most important, statistically, to their inquiry. Our new segmentation strategy extends the distribution estimation analysis by visually conveying the individual importance of each variable to these regions of high statistical significance. We demonstrate the analysis benefits these two strategies provide and show how they may be used to facilitate the refinement of constraints over variables expressed in a user's query. We apply our method to datasets from two different scientific domains to demonstrate its broad applicability.

  4. How can I query data on OpenEI and generate a map? | OpenEI Community

    Open Energy Info (EERE)

    How can I query data on OpenEI and generate a map? Home > Groups > Developer I'd like to have an Ask or SPARQL query display as a map in the OpenEI wiki section. What are the...

  5. Tool For Editing Structured Query Language Text Within ORACLE Forms Applications

    Energy Science and Technology Software Center (OSTI)

    1991-02-01

    SQTTEXT is an ORACLE SQL*Forms application that allows a programmer to view and edit all the Structured Query Language (SQL) text for a given application on one screen. This application is an outgrowth of the prototyping of an on-line system dictionary for the Worldwide Household Goods Information system for Transportation-Modernization decision support system being prototyped by the Oak Ridge National Laboratory, but it can be applied to all SQL*Forms software development, debugging, and maintenance.

  6. Computer systems and methods for the query and visualization of multidimensional databases

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L.; Hanrahan, Patrick

    2006-08-08

    A method and system for producing graphics. A hierarchical structure of a database is determined. A visual table, comprising a plurality of panes, is constructed by providing a specification that is in a language based on the hierarchical structure of the database. In some cases, this language can include fields that are in the database schema. The database is queried to retrieve a set of tuples in accordance with the specification. A subset of the set of tuples is associated with a pane in the plurality of panes.

  7. Computer systems and methods for the query and visualization of multidimensional database

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L.; Hanrahan, Patrick

    2010-05-11

    A method and system for producing graphics. A hierarchical structure of a database is determined. A visual table, comprising a plurality of panes, is constructed by providing a specification that is in a language based on the hierarchical structure of the database. In some cases, this language can include fields that are in the database schema. The database is queried to retrieve a set of tuples in accordance with the specification. A subset of the set of tuples is associated with a pane in the plurality of panes.

  8. A METHOD FOR ESTIMATING GAS PRESSURE IN 3013 CONTAINERS USING AN ISP DATABASE QUERY

    SciTech Connect (OSTI)

    Friday, G; L. G. Peppers, L; D. K. Veirs, D

    2008-07-31

    The U.S. Department of Energy's Integrated Surveillance Program (ISP) is responsible for the storage and surveillance of plutonium-bearing material. During storage, plutonium-bearing material has the potential to generate hydrogen gas from the radiolysis of adsorbed water. The generation of hydrogen gas is a safety concern, especially when a container is breached within a glove box during destructive evaluation. To address this issue, the DOE established a standard (DOE, 2004) that sets the criteria for the stabilization and packaging of material for up to 50 years. The DOE has now packaged most of its excess plutonium for long-term storage in compliance with this standard. As part of this process, it is desirable to know within reasonable certainty the total maximum pressure of hydrogen and other gases within the 3013 container if safety issues and compliance with the DOE standards are to be attained. The principal goal of this investigation is to document the method and query used to estimate total (i.e. hydrogen and other gases) gas pressure within a 3013 container based on the material properties and estimated moisture content contained in the ISP database. Initial attempts to estimate hydrogen gas pressure in 3013 containers was based on G-values (hydrogen gas generation per energy input) derived from small scale samples. These maximum G-values were used to calculate worst case pressures based on container material weight, assay, wattage, moisture content, container age, and container volume. This paper documents a revised hydrogen pressure calculation that incorporates new surveillance results and includes a component for gases other than hydrogen. The calculation is produced by executing a query of the ISP database. An example of manual mathematical computations from the pressure equation is compared and evaluated with results from the query. Based on the destructive evaluation of 17 containers, the estimated mean absolute pressure was significantly higher

  9. ISABELA-QA: query-driven analytics with ISABELA-compressed extreme-scale

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scientific data | Argonne Leadership Computing Facility ISABELA-QA: query-driven analytics with ISABELA-compressed extreme-scale scientific data Authors: Lakshminarasimhan,S., Jenkins, J., Latham,R., Samatova, N.F., Arkatkar, I., Gong, Z., Kolla, H., Chen, J., Ku, S.H. Chang, C.S., Ethier, S., Klasky, S. Efficient analytics of scientific data from extreme-scale simulations is quickly becoming a top-notch priority. The increasing simulation output data sizes demand for a paradigm shift in how

  10. Query and Visualization of extremely large network datasets over the web using Quadtree based KML Regional Network Links

    SciTech Connect (OSTI)

    Dadi, Upendra; Liu, Cheng; Vatsavai, Raju

    2009-01-01

    Geographic data sets are often very large in size. Interactive visualization of such data at all scales is not easy because of the limited resolution of the monitors and inability of visualization applications to handle the volume of data. This is especially true for large vector datasets. The end user s experience is frequently unsatisfactory when exploring such data over the web using a naive application. Network bandwidth is another contributing factor to the low performance. In this paper, a Quadtree based technique to visualize extremely large spatial network datasets over the web is described. It involves using custom developed algorithms leveraging a PostGIS database as the data source and Google Earth as the visualization client. This methodology supports both point and range queries along with non-spatial queries. This methodology is demonstrated using a network dataset consisting of several million links. The methodology is based on using some of the powerful features of KML (Keyhole Markup Language). Keyhole Markup Language (KML) is an Open Geospatial Consortium (OGC) standard for displaying geospatial data on Earth browsers. One of the features of KML is the notion of Network Links. Using network links, a wide range of geospatial data sources such as geodatabases, static files and geospatial data services can be simultaneously accessed and visualized seamlessly. Using the network links combined with Level of Detail principle, view based rendering and intelligent server and client-side caching, scalability in visualizing extremely large spatial datasets can be achieved.

  11. HDF5-FastQuery: Accelerating Complex Queries

    Office of Scientific and Technical Information (OSTI)

    ... On the Performance of Bitmap Indices for High Cardinality Attributes. In International Conference on Very Large Data Bases (VLDB), Toronto, Canada, August 31 - September 3, 2004, ...

  12. HDF5-FastQuery: Accelerating Complex Queries

    Office of Scientific and Technical Information (OSTI)

    ... These groups act as a container of various metadata which in our approach is ... is based on the HDF5 indexing function H5INquery, and takes three arrays as function input. ...

  13. Complex Queries | Open Energy Information

    Open Energy Info (EERE)

    Electricity Markets Afghanistan-NREL Mission Afghanistan-NREL Resource Maps and Toolkits China-NREL Cooperation Dominica Island-NREL Cooperation Egypt-NREL Energy Activities...

  14. Example Queries | Open Energy Information

    Open Energy Info (EERE)

    Avoca, New York Avoca, Pennsylvania Avoca, Wisconsin Avocado Heights, California Avon Lake, Ohio Avon Park, Florida Avon, Alabama Avon, Colorado Avon, Connecticut Avon,...

  15. Table Name query? | OpenEI Community

    Open Energy Info (EERE)

    - 06:39 Groups Menu You must login in order to post into this group. Recent content Hello-Sorry for the delay in... Use of DynamicAggregationProcessor I submitted a pull...

  16. Natural Gas Annual Respondent Query System

    Gasoline and Diesel Fuel Update (EIA)

    (Volumes in Thousand Cubic Feet, Prices in Dollars per Thousand Cubic Feet) Form EIA-176 * User Guide * Definitions, Sources, & Notes Natural Gas Deliveries (2011 - 2014)...

  17. Querying Allocations Using cbank | Argonne Leadership Computing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    20130101 -b 20130131 charges on all projects for a particular user cbank charges -u username -a 20130401 get specifics on a single charge cbank detail charge NNNNN list ...

  18. Image subregion querying using color correlograms

    DOE Patents [OSTI]

    Huang, Jing; Kumar, Shanmugasundaram Ravi; Mitra, Mandar; Zhu, Wei-Jing

    2002-01-01

    A color correlogram (10) is a representation expressing the spatial correlation of color and distance between pixels in a stored image. The color correlogram (10) may be used to distinguish objects in an image as well as between images in a plurality of images. By intersecting a color correlogram of an image object with correlograms of images to be searched, those images which contain the objects are identified by the intersection correlogram.

  19. HDF5-FastQuery: Accelerating Complex Queries on HDF Datasets...

    Office of Scientific and Technical Information (OSTI)

    the scientific user community since they provide multi-dimensional storage and retrieval. ... Subject: 99 GENERAL AND MISCELLANEOUSMATHEMATICS, COMPUTING, AND INFORMATION SCIENCE; ...

  20. Developer | OpenEI Community

    Open Energy Info (EERE)

    compound queries Type Term Title Author Replies Last Post sort icon Blog entry compound queries Multicolor Maps from Compound Queries Jweers 16 May 2013 - 14:22...

  1. Developer | OpenEI Community

    Open Energy Info (EERE)

    ask queries Type Term Title Author Replies Last Post sort icon Blog entry ask queries Multicolor Maps from Compound Queries Jweers 16 May 2013 - 14:22...

  2. T-703: Cisco Unified Communications Manager Open Query Interface...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A remote user can obtain database contents, including authentication credentials. ... This may include authentication credentials, configuration details, and other sensitive ...

  3. Improving Estimation Accuracy of Aggregate Queries on Data Cubes

    SciTech Connect (OSTI)

    Pourabbas, Elaheh; Shoshani, Arie

    2008-08-15

    In this paper, we investigate the problem of estimation of a target database from summary databases derived from a base data cube. We show that such estimates can be derived by choosing a primary database which uses a proxy database to estimate the results. This technique is common in statistics, but an important issue we are addressing is the accuracy of these estimates. Specifically, given multiple primary and multiple proxy databases, that share the same summary measure, the problem is how to select the primary and proxy databases that will generate the most accurate target database estimation possible. We propose an algorithmic approach for determining the steps to select or compute the source databases from multiple summary databases, which makes use of the principles of information entropy. We show that the source databases with the largest number of cells in common provide the more accurate estimates. We prove that this is consistent with maximizing the entropy. We provide some experimental results on the accuracy of the target database estimation in order to verify our results.

  4. Category:Query Results Templates | Open Energy Information

    Open Energy Info (EERE)

    The following 4 pages are in this category, out of 4 total. D Template:DefineVariables L Template:LabelActivities Template:LabelValuePair S Template:SubPageListHelper Retrieved...

  5. All | OpenEI Community

    Open Energy Info (EERE)

    All Home > All By term Q & A Term: ask queries Type Term Title Author Replies Last Post sort icon Blog entry ask queries Multicolor Maps from Compound Queries Jweers 16 May 2013 -...

  6. Geothermal Prospector: Supporting Geothermal Analysis Through Spatial Data Visualization and Querying Tools

    SciTech Connect (OSTI)

    Getman, Daniel; Anderson, Arlene; Augustine, Chad

    2015-09-02

    Determining opportunities for geothermal energy can involve a significant investment in data collection and analysis. Analysts within a variety of industry and research domains collect and use these data; however, determining the existence and availability of data needed for a specific analysis activity can be challenging and represents one of the initial barriers to geothermal development [2]. This paper describes the motivating factors involved in designing and building the Geothermal Prospector application, how it can be used to reduce risks and costs related to geothermal exploration, and where it fits within the larger collection of tools that is the National Geothermal Data System (NGDS) [5].

  7. Computer systems and methods for the query and visualization of multidimensional databases

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L.; Hanrahan, Patrick

    2012-03-20

    In response to a user request, a computer generates a graphical user interface on a computer display. A schema information region of the graphical user interface includes multiple operand names, each operand name associated with one or more fields of a multi-dimensional database. A data visualization region of the graphical user interface includes multiple shelves. Upon detecting a user selection of the operand names and a user request to associate each user-selected operand name with a respective shelf in the data visualization region, the computer generates a visual table in the data visualization region in accordance with the associations between the operand names and the corresponding shelves. The visual table includes a plurality of panes, each pane having at least one axis defined based on data for the fields associated with a respective operand name.

  8. Computer systems and methods for the query and visualization of multidimensional databases

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L; Hanrahan, Patrick

    2015-03-03

    A computer displays a graphical user interface on its display. The graphical user interface includes a schema information region and a data visualization region. The schema information region includes multiple operand names, each operand corresponding to one or more fields of a multi-dimensional database that includes at least one data hierarchy. The data visualization region includes a columns shelf and a rows shelf. The computer detects user actions to associate one or more first operands with the columns shelf and to associate one or more second operands with the rows shelf. The computer generates a visual table in the data visualization region in accordance with the user actions. The visual table includes one or more panes. Each pane has an x-axis defined based on data for the one or more first operands, and each pane has a y-axis defined based on data for the one or more second operands.

  9. Computer systems and methods for the query and visualization of multidimensional databases

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L.; Hanrahan, Patrick

    2015-11-10

    A computer displays a graphical user interface on its display. The graphical user interface includes a schema information region and a data visualization region. The schema information region includes a plurality of fields of a multi-dimensional database that includes at least one data hierarchy. The data visualization region includes a columns shelf and a rows shelf. The computer detects user actions to associate one or more first fields with the columns shelf and to associate one or more second fields with the rows shelf. The computer generates a visual table in the data visualization region in accordance with the user actions. The visual table includes one or more panes. Each pane has an x-axis defined based on data for the one or more first fields, and each pane has a y-axis defined based on data for the one or more second fields.

  10. Computer systems and methods for the query and visualization of multidimensional databases

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L; Hanrahan, Patrick

    2014-04-29

    In response to a user request, a computer generates a graphical user interface on a computer display. A schema information region of the graphical user interface includes multiple operand names, each operand name associated with one or more fields of a multi-dimensional database. A data visualization region of the graphical user interface includes multiple shelves. Upon detecting a user selection of the operand names and a user request to associate each user-selected operand name with a respective shelf in the data visualization region, the computer generates a visual table in the data visualization region in accordance with the associations between the operand names and the corresponding shelves. The visual table includes a plurality of panes, each pane having at least one axis defined based on data for the fields associated with a respective operand name.

  11. Computer systems and methods for the query and visualization of multidimensional databases

    DOE Patents [OSTI]

    Stolte, Chris; Tang, Diane L.; Hanrahan, Patrick

    2011-02-01

    In response to a user request, a computer generates a graphical user interface on a computer display. A schema information region of the graphical user interface includes multiple operand names, each operand name associated with one or more fields of a multi-dimensional database. A data visualization region of the graphical user interface includes multiple shelves. Upon detecting a user selection of the operand names and a user request to associate each user-selected operand name with a respective shelf in the data visualization region, the computer generates a visual table in the data visualization region in accordance with the associations between the operand names and the corresponding shelves. The visual table includes a plurality of panes, each pane having at least one axis defined based on data for the fields associated with a respective operand name.

  12. Geospatial | OpenEI Community

    Open Energy Info (EERE)

    Geospatial > Posts by term Content Group Activity By term Q & A Feeds ask queries (1) compound queries (1) data (1) developer (1) geospatial data (1) GIS (1) GIS data (1) Global...

  13. Polybenzimidazole compounds

    DOE Patents [OSTI]

    Klaehn, John R.; Peterson, Eric S.; Wertsching, Alan K.; Orme, Christopher J.; Luther, Thomas A.; Jones, Michael G.

    2010-08-10

    A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

  14. Polybenzimidazole compounds

    DOE Patents [OSTI]

    Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Jones, Michael G. (Chubbuck, ID); Wertsching, Alan K. (Idaho Falls, ID); Luther, Thomas A. (Idaho Falls, ID); Trowbridge, Tammy L. (Idaho Falls, ID)

    2011-11-22

    A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO--, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

  15. User:Jayhuggins/Test | Open Energy Information

    Open Energy Info (EERE)

    6 Compound Queries 7 Pipe Escape 8 Parser Functions 9 Maps 10 Math 11 Loops 12 External Data 13 Dynamic Functions 14 Category Test 15 Array 16 Number Format 17 UUID 18 InputBox...

  16. maps | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  17. multicolor | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  18. Google maps | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  19. results | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  20. Semantic Mediawiki | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  1. result formats | OpenEI Community

    Open Energy Info (EERE)

    queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or...

  2. OpenEI Community Central | OpenEI Community

    Open Energy Info (EERE)

    OpenEI Community Central Home > OpenEI Community Central > Posts by term > OpenEI Community Central Content Group Activity By term Q & A Feeds Term: compound queries Type Term...

  3. Bismaleimide compounds

    DOE Patents [OSTI]

    Adams, J.E.; Jamieson, D.R.

    1986-01-14

    Bismaleimides of the formula shown in the diagram wherein R[sub 1] and R[sub 2] each independently is H, C[sub 1-4]-alkyl, C[sub 1-4]-alkoxy, Cl or Br, or R[sub 1] and R[sub 2] together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R[sub 1] and R[sub 2] are not t-butyl or t-butoxy; X is O, S or Se; n is 1--3; and the alkylene bridging group, optionally, is substituted by 1--3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

  4. Bismaleimide compounds

    DOE Patents [OSTI]

    Adams, Johnnie E.; Jamieson, Donald R.

    1986-01-14

    Bismaleimides of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C1 or Br, or R.sub.1 and R.sub.2 together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R.sub.1 and R.sub.2 are not t-butyl or t-butoxy; X is O, S or Se; n is 1-3; and the alkylene bridging group, optionally, is substituted by 1-3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

  5. Energy Information, Data, and other Resources | OpenEI

    Open Energy Info (EERE)

    provides inline queries in the form of an Ask query, which can also be modified into a web service (see OpenEI REST services documentation). Ask queries can be executed here and...

  6. SAPLE: Sandia Advanced Personnel Locator Engine.

    SciTech Connect (OSTI)

    Procopio, Michael J.

    2010-04-01

    We present the Sandia Advanced Personnel Locator Engine (SAPLE) web application, a directory search application for use by Sandia National Laboratories personnel. SAPLE's purpose is to return Sandia personnel 'results' as a function of user search queries, with its mission to make it easier and faster to find people at Sandia. To accomplish this, SAPLE breaks from more traditional directory application approaches by aiming to return the correct set of results while placing minimal constraints on the user's query. Two key features form the core of SAPLE: advanced search query interpretation and inexact string matching. SAPLE's query interpretation permits the user to perform compound queries when typing into a single search field; where able, SAPLE infers the type of field that the user intends to search on based on the value of the search term. SAPLE's inexact string matching feature yields a high-quality ranking of personnel search results even when there are no exact matches to the user's query. This paper explores these two key features, describing in detail the architecture and operation of SAPLE. Finally, an extensive analysis on logged search query data taken from an 11-week sample period is presented.

  7. Sounding Board V.1.0

    Energy Science and Technology Software Center (OSTI)

    2006-10-10

    Sounding Board allows users to query multiple models simultaneously, finding relevant experts, related terms, and historical text related to one's query.

  8. XAFS Model Compound Library

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Newville, Matthew

    The XAFS Model Compound Library contains XAFS data on model compounds. The term "model" compounds refers to compounds of homogeneous and well-known crystallographic or molecular structure. Each data file in this library has an associated atoms.inp file that can be converted to a feff.inp file using the program ATOMS. (See the related Searchable Atoms.inp Archive at http://cars9.uchicago.edu/~newville/adb/) This Library exists because XAFS data on model compounds is useful for several reasons, including comparing to unknown data for "fingerprinting" and testing calculations and analysis methods. The collection here is currently limited, but is growing. The focus to date has been on inorganic compounds and minerals of interest to the geochemical community. [Copied, with editing, from http://cars9.uchicago.edu/~newville/ModelLib/

  9. Preparation of uranium compounds

    DOE Patents [OSTI]

    Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

    2013-02-19

    UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

  10. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, Richard A.; Lambrecht, Richard M.; Bloomer, William D.

    1989-05-02

    Methods and kits for incorporating a radioactive astatine isotope (particularly .sup.211 At) into an organic compound by electrophilic astatodestannylation of organostannanes.

  11. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, R.A.; Lambrecht, R.M.; Bloomer, W.D.

    1989-05-02

    Methods and kits for incorporating a radioactive astatine isotope (particularly [sup 211]At) into an organic compound by electrophilic astatodestannylation of organostannanes. 3 figs.

  12. Partially fluorinated ionic compounds

    DOE Patents [OSTI]

    Han, legal representative, Amy Qi; Yang, Zhen-Yu

    2008-11-25

    Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

  13. Nitrodifluoraminoterphenyl compounds and processes

    DOE Patents [OSTI]

    Lerom, M.W.; Peters, H.M.

    1975-07-08

    This patent relates to the nitrodifluoraminoterphenyl compounds: 3,3''-bis (difluoramino)-2,2'' 4,4', 4'',6,6',6''-octanitro-m-terphenyl (DDONT) and 3,3''-bis(difluoramino)-2,2',2''4,4',4'',6,6',6''-nonanitro-m-terphenyl (DDNONA). Procedures are described wherein diamino precursors of the indicated compounds are prepared and the final compounds are obtained by a fluorination operation. The compounds are highly energetic and suitable for use as explosives and particularly in exploding bridge wire (EBW) detonators. (auth)

  14. Heart testing compound

    DOE Patents [OSTI]

    Knapp, Jr., Furn F.; Goodman, Mark M.

    1985-01-01

    The compound 15-(p-[.sup.125 I]-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

  15. Heart testing compound

    DOE Patents [OSTI]

    Knapp, F.F. Jr.; Goodman, M.M.

    1983-06-29

    The compound 15-(p-(/sup 125/I)-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

  16. Charge Density Wave Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fisher Research Group Layered Chalcogenides 29 February 2008 Controlling the Wave by Brad Plummer, SLAC Communications Stanford University researchers working in part at SSRL have discovered a novel set of properties pertaining to a compound of materials called tritellurides. These compounds, composed of three atoms of tellurium and a single atom of one of the rare earth elements, demonstrate unique electronic properties that can be controlled by altering the temperature of the material. The

  17. Microoptical compound lens

    DOE Patents [OSTI]

    Sweatt, William C.; Gill, David D.

    2007-10-23

    An apposition microoptical compound lens comprises a plurality of lenslets arrayed around a segment of a hollow, three-dimensional optical shell. The lenslets collect light from an object and focus the light rays onto the concentric, curved front surface of a coherent fiber bundle. The fiber bundle transports the light rays to a planar detector, forming a plurality of sub-images that can be reconstructed as a full image. The microoptical compound lens can have a small size (millimeters), wide field of view (up to 180.degree.), and adequate resolution for object recognition and tracking.

  18. Aminopropyl thiophene compounds

    DOE Patents [OSTI]

    Goodman, Mark M.; Knapp, Jr., Furn F.

    1990-01-01

    Radiopharmaceuticals useful in brain imaging comprising radiohalogenated thienylethylamine derivatives. The compounds are 5-halo-thiophene-2-isopropyl amines able to cross the blood-brain barrier and be retained for a sufficient length of time to allow the evaluation of regional blood flow by radioimaging of the brain.

  19. Compound floating pivot micromechanisms

    DOE Patents [OSTI]

    Garcia, Ernest J.

    2001-04-24

    A new class of tilting micromechanical mechanisms have been developed. These new mechanisms use compound floating pivot structures to attain far greater tilt angles than are practical using other micromechanical techniques. The new mechanisms are also capable of bi-directional tilt about multiple axes.

  20. 8-fluoropurine compounds

    DOE Patents [OSTI]

    Barrio, Jorge R.; Satyamurthy, Nagichettiar; Namavari, Mohammad; Phelps, Michael E.

    2001-01-01

    An efficient, regiocontrolled approach to the synthesis of 8-fluoropurines by direct fluorination of purines with dilute elemental fluorine, or acetyl hypofluorite, is provided. In a preferred embodiment, a purine compound is dissolved in a polar solvent and reacted with a dilute mixture of F.sub.2 in He or other inert gas.

  1. Multicylinder compound engine

    SciTech Connect (OSTI)

    Paul, M.A.; Paul, A.

    1990-10-23

    This patent describes a compound, rotary-reciprocal engine. It comprises: a two-cycle reciprocator having cylinders, each cylinder having at least one piston arranged for reciprocation in the cylinder in a cycled operation with a timed air input to the cylinder and a timed exhaust from the cylinder; a compressed air intake and combustion gas exit in each cylinder of the reciprocator; fuel injection means for injecting fuel into the cylinders at appropriate times in the cycled operation; and, a rotocharger.

  2. Titanium alkoxide compound

    DOE Patents [OSTI]

    Boyle, Timothy J.

    2007-08-14

    A titanium alkoxide composition is provided, as represented by the chemical formula (OC.sub.6H.sub.5N).sub.2Ti(OC.sub.6H.sub.5NH.sub.2).sub.2. As prepared, the compound is a crystalline substance with a hexavalent titanium atom bonded to two OC.sub.6H.sub.5NH.sub.2 groups and two OC.sub.6H.sub.5N groups with a theoretical molecular weight of 480.38, comprising 60.01% C, 5.04% H and 11.66% N.

  3. Boronated porphyrin compounds

    DOE Patents [OSTI]

    Kahl, S.B.; Koo, M.S.

    1992-09-22

    A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

  4. Boronated porphyrin compounds

    DOE Patents [OSTI]

    Kahl, Stephen B.; Koo, Myoung-Seo

    1992-01-01

    A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

  5. ARM - Measurement - Volatile organic compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsVolatile organic compounds ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Volatile organic compounds The quantity or concentration measure of volatile organic compounds including both man-made and naturally occurring chemical compounds (this is inclusive of hydrocarbons). Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following

  6. Microsoft Word - NG_ResQrySys_UsersGuide_Sept2015-FINAL.docx

    Gasoline and Diesel Fuel Update (EIA)

    ... the Query System is a web-based system, no download or installation is necessary. All that is needed to run the Query System is a PC with up-to-date web-browsing software (such ...

  7. Energy Information, Data, and other Resources | OpenEI

    Open Energy Info (EERE)

    SPARQL SPARQL OpenEI's SPARQL endpoint is accessible at sparql Sample SPARQL queries are available at resource...

  8. Sqlog

    Energy Science and Technology Software Center (OSTI)

    2007-08-22

    The sqlog software implements a system for creation, query, and maintenance of database for SLURM job history.

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    in ITER. less Full Text Available April 2013, Physical Review Letters (Novembe r2012) Prev Next SOLR Query Details...

  10. Method of preparing metallocene compounds

    DOE Patents [OSTI]

    Rosenblum, Myron; Matchett, Stephen A.

    1992-01-01

    This invention describes a novel method of preparing metallocene compounds. The invention is based on synthesis of novel bis cyclopentadienides that, under appropriate conditions, will either encapsulate a transition metal to produce a metallocene such as ferrocene, or ferrocene derivative, or will yield a polymeric metallocene. Compounds produced by this process are useful as catalysts in propulsion systems, or as anti-knock compounds in gasolines.

  11. Method of producing cyclohexasilane compounds

    DOE Patents [OSTI]

    Elangovan, Arumugasamy; Anderson, Kenneth; Boudjouk, Philip R; Schulz, Douglas L

    2015-03-10

    A method of preparing a cyclohexasilane compound from trichlorosilane is provided. The method includes contacting trichlorosilane with a reagent composition to produce a compound containing a tetradecahalocyclohexasilane dianion, such as a tetradecachlorocyclohexasilane dianion. The reagent composition typically includes (a) tertiary polyamine ligand; and (b) a deprotonating reagent, such as a tertiary amine having a pKa of at least about 10.5. Methods of converting the tetradecahalocyclohexasilane dianion-containing compound to cyclohexasilane or a dodecaorganocyclohexasilane are also provided.

  12. METHOD OF REDUCING PLUTONIUM COMPOUNDS

    DOE Patents [OSTI]

    Johns, I.B.

    1958-06-01

    A method is described for reducing plutonium compounds in aqueous solution from a higher to a lower valence state. This reduction of valence is achieved by treating the aqueous solution of higher valence plutonium compounds with hydrogen in contact with an activated platinum catalyst.

  13. Devices for collecting chemical compounds

    DOE Patents [OSTI]

    Scott, Jill R; Groenewold, Gary S

    2013-12-24

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  14. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, Michael S.

    1995-01-01

    A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

  15. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1995-08-22

    A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired. 5 figs.

  16. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1993-01-01

    A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

  17. Detection of chlorinated aromatic compounds

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1996-02-06

    A method for making a composition for measuring the concentration of chlorinated aromatic compounds in aqueous fluids, and an optical probe for use with the method are disclosed. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis. 5 figs.

  18. Detection of chlorinated aromatic compounds

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1996-01-01

    A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

  19. Crystallographic properties of fertilizer compounds

    SciTech Connect (OSTI)

    Frazier, A.W.; Dillard, E.F.; Thrasher, R.D.; Waerstad, K.R.; Hunter, S.R.; Kohler, J.J.; Scheib, R.M.

    1991-02-01

    This bulletin is a compilation of crystallographic data collected at NFERC on 450 fertilizer-related compounds. In TVA's fertilizer R and D program, petrographic examination, XRD, and infrared spectroscopy are combined with conventional chemical analysis methods in identifying the individual compounds that occur in fertilizer materials. This handbook brings together the results of these characterization studies and supplemental crystallographic data from the literature. It is in one-compound-per-page, loose-leaf format, ordered alphabetically by IUPAC name. Indexes provided include IUPAC name, formula, group, alternate formula, synonyms, x-ray data, optical data. Tables are given for solids, compounds in commercial MAP and DAP, and matrix materials in phosphate rock.

  20. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1991-01-01

    This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

  1. Photochemical dimerization of organic compounds

    DOE Patents [OSTI]

    Crabtree, Robert H.; Brown, Stephen H.; Muedas, Cesar A.; Ferguson, Richard R.

    1992-01-01

    At least one of selectivity and reaction rate of photosensitized vapor phase dimerizations, including dehydrodimerizations, hydrodimerizations and cross-dimerizations of saturated and unsaturated organic compounds is improved by conducting the dimerization in the presence of hydrogen or nitrous oxide.

  2. Aza compounds as anion receptors

    DOE Patents [OSTI]

    Lee, Hung Sui; Yang, Xiao-Qing; McBreen, James

    1998-01-06

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li.sup.+ ion in alkali metal batteries.

  3. Aza compounds as anion receptors

    DOE Patents [OSTI]

    Lee, H.S.; Yang, X.Q.; McBreen, J.

    1998-01-06

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li{sup +} ion in alkali metal batteries. 3 figs.

  4. Method for purifying bidentate organophosphorus compounds

    DOE Patents [OSTI]

    Schulz, Wallace W.

    1977-01-01

    Bidentate organophosphorus compounds useful for extracting actinide elements from acidic nuclear waste solutions are purified of undesirable acidic impurities by contacting the compounds with ethylene glycol which preferentially extracts the impurities found in technical grade bidentate compounds.

  5. Host compounds for red phosphorescent OLEDs

    SciTech Connect (OSTI)

    Xia, Chuanjun; Cheon, Kwang -Ohk

    2015-08-25

    Novel compounds containing a triphenylene moiety linked to an .alpha..beta. connected binaphthyl ring system are provided. These compounds have surprisingly good solubility in organic solvents and are useful as host compounds in red phosphorescent OLEDs.

  6. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron...

  7. Cyanobacterium sp. for production of compounds

    DOE Patents [OSTI]

    Piven, Irina; Friedrich, Alexandra; Duhring, Ulf; Uliczka, Frank; Baier, Kerstin; Inaba, Masami; Shi, Tuo; Wang, Kui; Enke, Heike; Kramer, Dan

    2015-10-13

    A genetically enhanced cyanobacterial host cell, Cyanobacterium sp. ABICyano1, is disclosed. The enhanced Cyanobacterium sp. ABICyano1 produces a compound or compounds of interest.

  8. Process for production of a borohydride compound

    DOE Patents [OSTI]

    Chin, Arthur Achhing; Jain, Puja; Linehan, Suzanne; Lipiecki, Francis Joseph; Maroldo, Stephen Gerard; November, Samuel J; Yamamoto, John Hiroshi

    2013-02-19

    A process for production of a borohydride compound. The process comprises combining a compound comprising boron and oxygen with an adduct of alane.

  9. Estimating Missing Features to Improve Multimedia Information Retrieval

    SciTech Connect (OSTI)

    Bagherjeiran, A; Love, N S; Kamath, C

    2006-09-28

    Retrieval in a multimedia database usually involves combining information from different modalities of data, such as text and images. However, all modalities of the data may not be available to form the query. The retrieval results from such a partial query are often less than satisfactory. In this paper, we present an approach to complete a partial query by estimating the missing features in the query. Our experiments with a database of images and their associated captions show that, with an initial text-only query, our completion method has similar performance to a full query with both image and text features. In addition, when we use relevance feedback, our approach outperforms the results obtained using a full query.

  10. Superconductivity in graphite intercalation compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Robert P.; Weller, Thomas E.; Howard, Christopher A.; Dean, Mark P. M.; Rahnejat, Kaveh C.; Saxena, Siddharth S.; Ellerby, Mark

    2015-02-26

    This study examines the field of superconductivity in the class of materials known as graphite intercalation compounds which has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC₆ and YbC₆ in 2005. In what follows, we outline the crystal structure and electronic structure of these and related compounds. We go on to experiments addressing the superconducting energy gap, lattice dynamics, pressure dependence, and how this relates to theoretical studies. The bulk of the evidence strongly supports a BCS superconducting state. However, important questions remain regarding which electronic statesmore » and phonon modes are most important for superconductivity and whether current theoretical techniques can fully describe the dependence of the superconducting transition temperature on pressure and chemical composition.« less

  11. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1994-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  12. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1993-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  13. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.

    1989-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  14. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1994-06-14

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  15. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-09-07

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

  16. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1989-07-18

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  17. Compound semiconductor optical waveguide switch

    DOE Patents [OSTI]

    Spahn, Olga B.; Sullivan, Charles T.; Garcia, Ernest J.

    2003-06-10

    An optical waveguide switch is disclosed which is formed from III-V compound semiconductors and which has a moveable optical waveguide with a cantilevered portion that can be bent laterally by an integral electrostatic actuator to route an optical signal (i.e. light) between the moveable optical waveguide and one of a plurality of fixed optical waveguides. A plurality of optical waveguide switches can be formed on a common substrate and interconnected to form an optical switching network.

  18. Hyperpolarizable compounds and devices fabricated therefrom

    DOE Patents [OSTI]

    Therien, M.J.; DiMagno, S.G.

    1998-07-21

    Substituted compounds having relatively large molecular first order hyperpolarizabilities are provided, along with devices and materials containing them. In general, the compounds bear electron-donating and electron-withdrawing chemical substituents on a polyheterocyclic core. 13 figs.

  19. Hyperpolarizable compounds and devices fabricated therefrom

    DOE Patents [OSTI]

    Therien, Michael J.; DiMagno, Stephen G.

    1998-01-01

    Substituted compounds having relatively large molecular first order hyperpolarizabilities are provided, along with devices and materials containing them. In general, the compounds bear electron-donating and electron-withdrawing chemical substituents on a polyheterocyclic core.

  20. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.; Bomstad, Theresa M.; Sorini-Wong, Susan S.

    2009-02-10

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  1. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.; Bomstad, Theresa M.; Sorini-Wong, Susan S.; Wong, Gregory K.

    2011-03-01

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  2. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Towards Heavy Fermions in Europium Intermetallic Compounds Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in

  3. Semiconducting compounds and devices incorporating same

    DOE Patents [OSTI]

    Marks, Tobin J.; Facchetti, Antonio; Boudreault, Pierre-Luc; Miyauchi, Hiroyuki

    2016-01-19

    Disclosed are molecular and polymeric compounds having desirable properties as semiconducting materials. Such compounds can exhibit desirable electronic properties and possess processing advantages including solution-processability and/or good stability. Organic transistor and photovoltaic devices incorporating the present compounds as the active layer exhibit good device performance.

  4. Thin films of mixed metal compounds

    SciTech Connect (OSTI)

    Mickelsen, Reid A.; Chen, Wen S.

    1985-01-01

    A compositionally uniform thin film of a mixed metal compound is formed by simultaneously evaporating a first metal compound and a second metal compound from independent sources. The mean free path between the vapor particles is reduced by a gas and the mixed vapors are deposited uniformly. The invention finds particular utility in forming thin film heterojunction solar cells.

  5. Thin films of mixed metal compounds

    DOE Patents [OSTI]

    Mickelsen, R.A.; Chen, W.S.

    1985-06-11

    Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

  6. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1993-01-01

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  7. METHOD OF RECOVERING URANIUM COMPOUNDS

    DOE Patents [OSTI]

    Poirier, R.H.

    1957-10-29

    S>The recovery of uranium compounds which have been adsorbed on anion exchange resins is discussed. The uranium and thorium-containing residues from monazite processed by alkali hydroxide are separated from solution, and leached with an alkali metal carbonate solution, whereby the uranium and thorium hydrorides are dissolved. The carbonate solution is then passed over an anion exchange resin causing the uranium to be adsorbed while the thorium remains in solution. The uranium may be recovered by contacting the uranium-holding resin with an aqueous ammonium carbonate solution whereby the uranium values are eluted from the resin and then heating the eluate whereby carbon dioxide and ammonia are given off, the pH value of the solution is lowered, and the uranium is precipitated.

  8. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, Gregory D.; Moore, Glenn A.; Stone, Mark L.; Reagen, William K.

    1995-01-01

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

  9. Volatile organic compound sensing devices

    DOE Patents [OSTI]

    Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

    1995-08-29

    Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

  10. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  11. Organic electronic devices using phthalimide compounds

    DOE Patents [OSTI]

    Hassan, Azad M.; Thompson, Mark E.

    2010-09-07

    Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

  12. Organic electronic devices using phthalimide compounds

    DOE Patents [OSTI]

    Hassan, Azad M.; Thompson, Mark E.

    2012-10-23

    Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

  13. Organic electronic devices using phthalimide compounds

    DOE Patents [OSTI]

    Hassan, Azad M.; Thompson, Mark E.

    2013-03-19

    Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

  14. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  15. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  16. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  17. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  18. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  19. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  20. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  1. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H.; Gruen, Dieter M.

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  2. Complex fragment emission from hot compound nuclei

    SciTech Connect (OSTI)

    Moretto, L.G.

    1986-03-01

    The experimental evidence for compound nucleus emission of complex fragments at low energies is used to interpret the emission of the same fragments at higher energies. The resulting experimental picture is that of highly excited compound nuclei formed in incomplete fusion processes which decay statistically. In particular, complex fragments appear to be produced mostly through compound nucleus decay. In the appendix a geometric-kinematic theory for incomplete fusion and the associated momentum transfer is outlined. 10 refs., 19 figs.

  3. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron...

  4. Hydrodesulfurization catalysis by Chevrel phase compounds

    DOE Patents [OSTI]

    McCarty, Kevin F.; Schrader, Glenn L.

    1985-12-24

    A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M.sub.x Mo.sub.6 S.sub.8, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS.sub.2 catalysts. The most active catalysts were the "large" cation compounds (Ho, Pb, Sn), and the least active catalysts were the "small" cation compounds (Cu, Fe, Ni, Co.).

  5. Hydrodesulfurization catalyst by Chevrel phase compounds

    DOE Patents [OSTI]

    McCarty, K.F.; Schrader, G.L.

    1985-05-20

    A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M/sub x/Mo/sub 6/S/sub 8/, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS/sub 2/ catalysts. The most active catalysts were the ''large'' cation compounds (Ho, Pb, Sn), and the least active catalysts were the ''small'' cation compounds (Cu, Fe, Ni, Co.).

  6. Compound and Elemental Analysis | Open Energy Information

    Open Energy Info (EERE)

    gases usually include: carbon dioxide (CO2) hydrogen sulfide (H2S) ammonia (NH4) methane (CH4) Related Techniques Lab Analysis Techniques Fluid Lab Analysis Compound and...

  7. Compound hybrid geothermal-fossil power plants: thermodynamic...

    Office of Scientific and Technical Information (OSTI)

    SUPERHEATING; THERMODYNAMICS; WELL TEMPERATURE; WELLHEADS; WESTERN REGION; HEATING; HYDROGEN COMPOUNDS; NORTH AMERICA; OXYGEN COMPOUNDS; POWER PLANTS; RESERVOIR TEMPERATURE;...

  8. Methods of making organic compounds by metathesis

    DOE Patents [OSTI]

    Abraham, Timothy W.; Kaido, Hiroki; Lee, Choon Woo; Pederson, Richard L.; Schrodi, Yann; Tupy, Michael John

    2015-09-01

    Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.

  9. SWNVF: database contents

    National Nuclear Security Administration (NNSA)

    Nevada Test Site (NTS). The database complies with protocols of Structured Query Language (SQL), allowing construction of relationships among these data, from...

  10. Electric Power Annual 2014 - U.S. Energy Information Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview Data Electricity Data Browser (interactive query tool with charting & mapping) Summary Sales (consumption), ... to ultimate customers by end-use sector XLS Table 2.5. ...

  11. Electric Power Monthly - U.S. Energy Information Administration

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Overview Data Electricity Data Browser (interactive query tool with charting & mapping) Summary Sales (consumption), ... Customers: Total by End-Use Sector 5.2 Revenue from ...

  12. Electricity Monthly Update - Energy Information Administration

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Overview Data Electricity Data Browser (interactive query tool with charting & mapping) Summary Sales (consumption), ... demand levels that occurred towards the end of the month. ...

  13. Gateway:ECOWAS Clean Energy Gateway | Open Energy Information

    Open Energy Info (EERE)

    Policy Organizations (3) add West African Companies (4) add West African Programs (76The part "|Programs and Projects" of the query was not understood. Results might not...

  14. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... factors as well as explain some mutational effects. less August 2012 , American Chemical Society (ACS) Prev Next Switch to Detail View for this search SOLR Query Details

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Thomas C. ; Petsko, Gregory A. ; Ringe, Dagmar ; Brandeis) April 2016 , American Chemical Society (ACS) Prev Next Switch to Detail View for this search SOLR Query Details

  16. Prueba 3 | Open Energy Information

    Open Energy Info (EERE)

    de Redes (98) add Empresas de Energas Renovables (12) add Programas y Proyectos (1157The part "|Programs and Projects" of the query was not understood....

  17. OSTI, US Dept of Energy, Office of Scientific and Technical Informatio...

    Office of Scientific and Technical Information (OSTI)

    Using web-crawling technology, the search capability allows users to enter a single query for a technology transfer term; the search feature returns a consolidated, ...

  18. OSTI, US Dept of Energy Office of Scientific and Technical Information...

    Office of Scientific and Technical Information (OSTI)

    Web "mashups" combine multiple productsservices into a single application for the purpose ... one-stop simultaneous searching of multiple networked data resources via a single query. ...

  19. OSTI, US Dept of Energy Office of Scientific and Technical Information...

    Office of Scientific and Technical Information (OSTI)

    ... The NLEBeta employs two highly effective web tools - federated search, the simultaneous search of multiple web pages and databases in real time via a single query, and relevancy ...

  20. A Proactive Learning Framework for Non-Intrusive Load Monitoring...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NILM systems perform analysis on whole-building data taken at the main power panel to ... learning, an advanced machine learning method that interactively queries the user for ...

  1. Load flow analysis: Base cases, data, diagrams, and results ...

    Office of Scientific and Technical Information (OSTI)

    The report summarizes the load flow model construction, simulation, and validation and describes the general capabilities of an information query system designed to access load ...

  2. T-617: BIND RPZ Processing Flaw Lets Remote Users Deny Service

    Broader source: Energy.gov [DOE]

    When a name server is configured with a response policy zone (RPZ), queries for type RRSIG can trigger a server crash.

  3. T-559: Stack-based buffer overflow in oninit in IBM Informix...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    exploit this vulnerability. The specific flaw exists within the oninit process bound to TCP port 9088 when processing the arguments to the USELASTCOMMITTED option in a SQL query....

  4. Template:UnderDevelopment | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  5. Allocations | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Allocation Management Determining Allocation Requirements Querying Allocations Using cbank MiraCetusVesta Cooley Policies Documentation Feedback Please provide feedback to help...

  6. Search for: All records | DOE Data Explorer

    Office of Scientific and Technical Information (OSTI)

    Save Results Excel (limit 2000) CSV (limit 5000) XML (limit 5000) Have feedback or suggestions for a way to improve these results? Prev Next SOLR Query Details Close...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Barbeau, P.S. ; Stanford U., Phys. Dept. ; Beauchamp, E. ; Laurentian U. ; Belov, V. ; Moscow, ITEP ; et al Full Text Available March 2013 Prev Next SOLR Query Details...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    L. ; Winiarz, Jeffrey G. ; Kaiser, Helmut ; Taub, Haskell ; Veith, Gabriel M. December 2015 , Elsevier Prev Next Switch to Detail View for this search SOLR Query Details

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    and one where protein globules cause inter-aggregate clustering. less December 2015 , Elsevier Prev Next Switch to Detail View for this search SOLR Query Details

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Xiao Mei ; Du, Zehui ; Schuh, Christopher A. ; Tamura, Nobumichi ; Gan, Chee Lip April 2016 , Elsevier Prev Next Switch to Detail View for this search SOLR Query Details

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ; Liang, Shuquan ; Liu, Jun ; Wang, Wenjun ; Lei, Ming ; Tang, Shasha ; Yang, Qian March 2015 , Elsevier Prev Next Switch to Detail View for this search SOLR Query Details

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... retrieval algorithm for aerosol optical depth (AOD) in the presence of clouds using ... Richland, WA Prev Next Switch to Detail View for this search SOLR Query Details

  13. Template:TATNav | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  14. Template:ResourceLibraryTabs | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  15. Widget:CSC-CSS | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Widget Edit History...

  16. Template:LEDSLACNavs | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  17. Template:LEDSGPFooter | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  18. Template:WebServiceGraphic | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  19. Template:WFSPNav | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  20. Form:RAPID-BestPractices | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Form Edit History...

  1. Template:Organization | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  2. Widget:ContactFinder | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Widget Edit History...

  3. Widget:MailChimp | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Widget Edit History...

  4. Template:RAPID-Nav | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  5. Form:GeothermalResourceArea | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Form Edit History...

  6. Template:WindCover | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  7. Template:NEPA CX | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  8. Montana/Wind Resources | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Montana...

  9. Template:RegulatoryToolkitTabs | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  10. Template:Reflist | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Template Edit History...

  11. Cultural Resources | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Cultural...

  12. Widget:UtilityRateFinder | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Widget Edit History...

  13. Form:RRSection | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Form Edit History...

  14. Arizona/Wind Resources | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Arizona...

  15. OSTI, US Dept of Energy Office of Scientific and Technical Information...

    Office of Scientific and Technical Information (OSTI)

    Rather than relying on search algorithms that identify a specific query term, semantic search uses more complex contextual relationships among people, places and things. It is an ...

  16. OSTIblog Articles in the STI reports Topic | OSTI, US Dept of...

    Office of Scientific and Technical Information (OSTI)

    Rather than relying on search algorithms that identify a specific query term, semantic search uses more complex contextual relationships among people, places and things. It is an ...

  17. NREL: Energy Analysis - Nick Langle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HTML CSS Javascript jQuery UI UX Responsive Web Design Semantic MediaWiki SEO Primary research interests Web Design & Usability Data Visualization & Analytics Geospatial ...

  18. In-Situ Microphysics from the RACORO IOP (Dataset) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    We highly recommend that anyone wishing to use these files do so in a collaborative endeavor and we welcome queries and opportunities for collaboration. There are caveats ...

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    is discussed. Full Text Available April 2014 , Institute of Electrical and Electronics Engineers (IEEE) Prev Next Switch to Detail View for this search SOLR Query Details

  20. OCIO Technology Summit: Data Analytics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at the Energy Information Administration demonstrated the Electricity Data Browser influence on creating the visualization of data, bringing together maps, query tools, and...

  1. File:02SiteConsiderations (1).pdf | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search File Edit History...

  2. Energy Events | Open Energy Information

    Open Energy Info (EERE)

    Events Jump to: navigation, search Upcoming Events You need to have JavaScript enabled to view the interactive timeline. Further results for this query.WEEKMONTHYEAREvent:Preparing...

  3. Category:Tech Potential Properties | Open Energy Information

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Category Edit History...

  4. User:GregZiebold/Sector test | Open Energy Information

    Open Energy Info (EERE)

    search Query all sector types for Companies: Bioenergy Biofuels Biomass Buildings Carbon Efficiency Geothermal energy Hydro Hydrogen Marine and Hydrokinetic Ocean Renewable Energy...

  5. developer | OpenEI Community

    Open Energy Info (EERE)

    apps, lod, sparql and community will continue to function normally. Additionally, web services that rely on Ask queries (utility rate database API) may have some downtime...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    potential applications in high density nonvolatile storage in the future. less October 2015 , Wiley Prev Next Switch to Detail View for this search SOLR Query Details

  7. Form:Marine and Hydrokinetic Technology Project Milestone | Open...

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Form Edit History...

  8. Form:Marine and Hydrokinetic Technology Project | Open Energy...

    Open Energy Info (EERE)

    source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Form Edit History...

  9. Contact DMSE | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact DMSE Division of Materials Sciences and Engineering Director Business Manager General Inquiries Web Queries Matthew Kramer Susan Elsner Julie Dredla Sarah Wiley 125 Metals...

  10. Properties | Open Energy Information

    Open Energy Info (EERE)

    View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Special page Properties Jump to:...

  11. Inline_System

    Energy Science and Technology Software Center (OSTI)

    2010-02-01

    Inline_System replaces a small subset of file query and manipulation commands, on computing platforms that do not offer a complete standard POSIX environment.

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    rhombohedral structure in TbMn2. Full Text Available January 2015 , Royal Society of Chemistry Prev Next Switch to Detail View for this search SOLR Query Details

  13. Coal Markets

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Glossary FAQS Overview Data Coal Data Browser (interactive query tool with charting and mapping) Summary Prices Reserves Consumption Production Stocks Imports, exports ...

  14. User:Woodjr/Sandbox/GoogleEarth | Open Energy Information

    Open Energy Info (EERE)

    < User:Woodjr | Sandbox Jump to: navigation, search Demonstration of an experimental "GoogleEarth" result format for ask queries. Based on the Thematic Mapping API....

  15. Collegiate Wind Competition | Open Energy Information

    Open Energy Info (EERE)

    Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Collegiate Wind Competition Jump to: navigation, search Wind competition.jpg The...

  16. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compound EuNi2P2 might suggest to some the strings of a musical instrument, as in the harp and its player shown at the right. The red "bumps" do not correspond to badly plucked...

  17. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R.W.; Ellis, T.W.; Dennis, K.W.; Hofer, R.J.; Branagan, D.J.

    1997-11-25

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g., a transition metal and optional boron), and a carbide-forming element (e.g., a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g., Nd{sub 2}Fe{sub 14}B or LaNi{sub 5}) and a carbide of the carbide-forming element are formed.

  18. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R. William; Ellis, Timothy W.; Dennis, Kevin W.; Hofer, Robert J.; Branagan, Daniel J.

    1997-11-25

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

  19. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    state in EuNi2P2. The angle-resolved photoemission spectroscopy (ARPES) data for the localized europium 4f6 final states in the rare-earth intermetallic compound EuNi2P2 might...

  20. SEPARATION PROCESS FOR PROTACTINIUM AND COMPOUNDS THEREOF

    DOE Patents [OSTI]

    Van Winkle, A.

    1959-07-21

    The separation of protactinium from aqueous solutions from its mixtures with thorium, uranium and fission products is described. The process for the separation comprises preparing an ion nitric acid solution containing protactinium in the pentavalent state and contacting the solution with a fluorinated beta diketone, such as trifluoroacetylacetone, either alone or as an organic solvent solution to form a pentavalent protactinium chelate compound. When the organic solvent is present the chelate compound is extracted; otherwise it is separated by filtration.

  1. Aza crown ether compounds as anion receptors

    DOE Patents [OSTI]

    Lee, Hung Sui; Yang, Xiao-Oing; McBreen, James

    1998-08-04

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

  2. Aza crown ether compounds as anion receptors

    DOE Patents [OSTI]

    Lee, H.S.; Yang, X.O.; McBreen, J.

    1998-08-04

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

  3. Polymers containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E; Eastwood, Eric A

    2013-04-23

    Polymers comprising residues of cage compound monomers having at least one polyalkoxy silyl substituent are provided. The cage compound monomers are selected from borane cage compound monomers comprising at least 7 cage atoms and/or carborane cage compound monomers comprising 7 to 11 cage compound monomers. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Articles of manufacture comprising such polymers are also disclosed.

  4. Process for production of a borohydride compound

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-19

    A process for production of a borohydride compound M(BH.sub.4).sub.y. The process has three steps. The first step combines a compound of formula (R.sup.1O).sub.yM with aluminum, hydrogen and a metallic catalyst containing at least one metal selected from the group consisting of titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group; M is an alkali metal, Be or Mg; and y is one or two; wherein the catalyst is present at a level of at least 200 ppm based on weight of aluminum. The second step combines the compound of formula M(AlH.sub.3OR.sup.1).sub.y with a borate, boroxine or borazine compound to produce M(BH.sub.4).sub.y and a byproduct mixture containing alkali metal and aluminum aryloxides. The third step separates M(BH.sub.4).sub.y from the byproduct mixture.

  5. Basics and prospective of magnetic Heusler compounds

    SciTech Connect (OSTI)

    Felser, Claudia Wollmann, Lukas; Chadov, Stanislav; Fecher, Gerhard H.; Parkin, Stuart S. P.

    2015-04-01

    Heusler compounds are a remarkable class of materials with more than 1000 members and a wide range of extraordinary multi-functionalities including halfmetallic high-temperature ferri- and ferromagnets, multi-ferroics, shape memory alloys, and tunable topological insulators with a high potential for spintronics, energy technologies, and magneto-caloric applications. The tunability of this class of materials is exceptional and nearly every functionality can be designed. Co{sub 2}-Heusler compounds show high spin polarization in tunnel junction devices and spin-resolved photoemission. Manganese-rich Heusler compounds attract much interest in the context of spin transfer torque, spin Hall effect, and rare earth free hard magnets. Most Mn{sub 2}-Heusler compounds crystallize in the inverse structure and are characterized by antiparallel coupling of magnetic moments on Mn atoms; the ferrimagnetic order and the lack of inversion symmetry lead to the emergence of new properties that are absent in ferromagnetic centrosymmetric Heusler structures, such as non-collinear magnetism, topological Hall effect, and skyrmions. Tetragonal Heusler compounds with large magneto crystalline anisotropy can be easily designed by positioning the Fermi energy at the van Hove singularity in one of the spin channels. Here, we give a comprehensive overview and a prospective on the magnetic properties of Heusler materials.

  6. Raman Spectroscopy for Analysis of Thorium Compounds (Conference...

    Office of Scientific and Technical Information (OSTI)

    Conference: Raman Spectroscopy for Analysis of Thorium Compounds Citation Details In-Document Search Title: Raman Spectroscopy for Analysis of Thorium Compounds The thorium fuel ...

  7. Compound and Elemental Analysis At Maui Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Maui Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Maui...

  8. SEPARATION PROCESS FOR ZIRCONIUM AND COMPOUNDS THEREOF

    DOE Patents [OSTI]

    Crandall, H.W.; Thomas, J.R.

    1959-06-30

    The separation of zirconium from columbium, rare earths, yttrium and the alkaline earth metals, such mixtures of elements occurring in zirconium ores or neutron irradiated uranium is described. According to the invention a suitable separation of zirconium from a one normal acidic aqueous solution containing salts, nitrates for example, of tetravalent zirconium, pentavalent columbium, yttrium, rare earths in the trivalent state and alkaline earths can be obtained by contacting the aqueous solution with a fluorinated beta diketonc alone or in an organic solvent solution, such as benzene, to form a zirconium chelate compound. When the organic solvent is present the zirconium chelate compound is directly extracted; otherwise it is separated by filtration. The zirconium may be recovered from contacting the organic solvent solution containing the chelated compound by back extraction with either an aqueous hydrofluoric acid or an oxalic acid solution.

  9. Beta cell device using icosahedral boride compounds

    DOE Patents [OSTI]

    Aselage, Terrence L.; Emin, David

    2002-01-01

    A beta cell for converting beta-particle energies into electrical energy having a semiconductor junction that incorporates an icosahedral boride compound selected from B.sub.12 As.sub.2, B.sub.12 P.sub.2, elemental boron having an .alpha.-rhombohedral structure, elemental boron having a .beta.-rhombohedral structure, and boron carbides of the chemical formula B.sub.12-x C.sub.3-x, where 0.15compound self-heals, resisting degradation from radiation damage.

  10. Organic photosensitive devices using subphthalocyanine compounds

    DOE Patents [OSTI]

    Rand, Barry; Forrest, Stephen R.; Mutolo, Kristin L.; Mayo, Elizabeth; Thompson, Mark E.

    2011-07-05

    An organic photosensitive optoelectronic device, having a donor-acceptor heterojunction of a donor-like material and an acceptor-like material and methods of making such devices is provided. At least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound; and/or the device optionally has at least one of a blocking layer or a charge transport layer, where the blocking layer and/or the charge transport layer includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound.

  11. Dry etching method for compound semiconductors

    DOE Patents [OSTI]

    Shul, R.J.; Constantine, C.

    1997-04-29

    A dry etching method is disclosed. According to the present invention, a gaseous plasma comprising, at least in part, boron trichloride, methane, and hydrogen may be used for dry etching of a compound semiconductor material containing layers including aluminum, or indium, or both. Material layers of a compound semiconductor alloy such as AlGaInP or the like may be anisotropically etched for forming electronic devices including field-effect transistors and heterojunction bipolar transistors and for forming photonic devices including vertical-cavity surface-emitting lasers, edge-emitting lasers, and reflectance modulators. 1 fig.

  12. Dry etching method for compound semiconductors

    DOE Patents [OSTI]

    Shul, Randy J.; Constantine, Christopher

    1997-01-01

    A dry etching method. According to the present invention, a gaseous plasma comprising, at least in part, boron trichloride, methane, and hydrogen may be used for dry etching of a compound semiconductor material containing layers including aluminum, or indium, or both. Material layers of a compound semiconductor alloy such as AlGaInP or the like may be anisotropically etched for forming electronic devices including field-effect transistors and heterojunction bipolar transistors and for forming photonic devices including vertical-cavity surface-emitting lasers, edge-emitting lasers, and reflectance modulators.

  13. Process for producing phenolic compounds from lignins

    DOE Patents [OSTI]

    Agblevor, Foster A. (Lakewood, CO)

    1998-01-01

    A process for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400.degree. C. to about 600.degree. C. at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1-3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof.

  14. Process for producing phenolic compounds from lignins

    DOE Patents [OSTI]

    Agblevor, F.A.

    1998-09-15

    A process is described for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400 C to about 600 C at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1--3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof. 16 figs.

  15. PRODUCTION OF URANIUM AND THORIUM COMPOUNDS

    DOE Patents [OSTI]

    Arden, T.V.; Burstall, F.H.; Linstead, R.P.; Wells, R.A.

    1955-12-27

    Compounds of Th and U are extracted with an organic solvent in the presence of an adsorbent substance which has greater retentivity for impurities present than for the uranium and/or thorium. The preferred adsorbent material is noted as being cellulose. The uranium and thoriumcontaining substances treated are preferably in the form of dissolved nitrates, and the preferred organic solvent is diethyl ether.

  16. Arrays of stacked metal coordination compounds

    DOE Patents [OSTI]

    Bulkowski, John E. (Newark, DE)

    1986-01-01

    A process is disclosed for preparing novel arrays of metal coordination compounds characterized by arrangement of the metal ions, separated by a linking agent, in stacked order one above the other. The process permits great flexibility in the design of the array. For example, layers of different composition can be added to the array at will.

  17. Arrays of stacked metal coordination compounds

    DOE Patents [OSTI]

    Bulkowski, J.E.

    1986-10-21

    A process is disclosed for preparing novel arrays of metal coordination compounds characterized by arrangement of the metal ions, separated by a linking agent, in stacked order one above the other. The process permits great flexibility in the design of the array. For example, layers of different composition can be added to the array at will. 3 figs.

  18. Stable surface passivation process for compound semiconductors

    DOE Patents [OSTI]

    Ashby, Carol I. H.

    2001-01-01

    A passivation process for a previously sulfided, selenided or tellurated III-V compound semiconductor surface. The concentration of undesired mid-gap surface states on a compound semiconductor surface is reduced by the formation of a near-monolayer of metal-(sulfur and/or selenium and/or tellurium)-semiconductor that is effective for long term passivation of the underlying semiconductor surface. Starting with the III-V compound semiconductor surface, any oxidation present thereon is substantially removed and the surface is then treated with sulfur, selenium or tellurium to form a near-monolayer of chalcogen-semiconductor of the surface in an oxygen-free atmosphere. This chalcogenated surface is then contacted with a solution of a metal that will form a low solubility chalcogenide to form a near-monolayer of metal-chalcogen-semiconductor. The resulting passivating layer provides long term protection for the underlying surface at or above the level achieved by a freshly chalcogenated compound semiconductor surface in an oxygen free atmosphere.

  19. Boron-containing amino carboxylic acid compounds and uses thereof

    DOE Patents [OSTI]

    Kabalka, George W.; Srivastava, Rajiv R.

    2000-03-14

    Novel compounds which are useful for boron neutron capture therapy (BNCT) are disclosed. The compounds comprise a stable boron-containing group and an aminocycloalkane carboxylic acid group or a boronated acyclic hydrocarbon-linked amino carboxylic acid. Methods for synthesis of the compounds and for use of the compounds in BNCT are disclosed.

  20. Tritium labeling of organic compounds deposited on porous structures

    DOE Patents [OSTI]

    Ehrenkaufer, Richard L. E.; Wolf, Alfred P.; Hembree, Wylie C.

    1979-01-01

    An improved process for labeling organic compounds with tritium is carried out by depositing the selected compound on the extensive surface of a porous structure such as a membrane filter and exposing the membrane containing the compound to tritium gas activated by the microwave discharge technique. The labeled compound is then recovered from the porous structure.

  1. Process for preparing a deuterated or tritiated compound

    DOE Patents [OSTI]

    Bergman, Robert C.; Klei, Steven R.

    2004-09-21

    A process for labeling organic compounds with deuterium and tritium is described using specific catalysts.

  2. Process for preparing a deuterated or tritiated compound

    DOE Patents [OSTI]

    Bergman, Robert C.; Klei, Steven R.

    2006-05-16

    A process for labeling organic compounds with deuterium and tritium is described using specific catalysts.

  3. Process for preparing a deuterated or tritiated compound

    DOE Patents [OSTI]

    Klei, Steven R.; Bergman, Robert C.

    2006-06-06

    A process for labeling organic compounds with deuterium and tritium is described using specific catalysts.

  4. Method for halogenating or radiohalogenating a chemical compound

    DOE Patents [OSTI]

    Kabalka, George W.

    2006-05-09

    A method for obtaining a halogenated organic compound, whereby an organotrifluoroborate compound is reacted with a halide ion in the presence of an oxidizing agent to produce the corresponding halogenated organic compound. The method may be used for producing radiohalogenated organic compounds.

  5. Compositions containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E; Eastwood, Eric A

    2014-11-11

    Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

  6. Compositions containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E.; Eastwood, Eric A.

    2015-09-15

    Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

  7. Compositions containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E; Eastwood, Eric A

    2013-05-28

    Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

  8. Dielectric insulating polyolefin compounds and conductor products insulated therewith

    DOE Patents [OSTI]

    MacKenzie, Jr., Burton T.; Prober, Maurice; Kiersztyn, Stanley E.

    1979-01-01

    Polyolefin compounds containing nitrile polysiloxane fluid which have improved electrical properties, and electrical conductors insulated therewith.

  9. Efficient Data Management for Knowledge Discovery in Large-Scale Geospatial Imagery Collections

    SciTech Connect (OSTI)

    Baldwin, C; Abdulla, G

    2006-01-24

    We describe the results of our investigation on supporting ad-hoc and continuous queries over data streams. The major problem we address here is how to identify and utilize metadata for smart caching and to support queries over streaming and archived or historical data.

  10. Climatepipes: User-friendly data access, data manipulation, data analysis and visualization of community climate models Phase II

    SciTech Connect (OSTI)

    Chaudhary, Aashish

    2015-09-02

    In Phase I, we successfully developed a web-based tool that provides workflow and form-based interfaces for accessing, querying, and visualizing interesting datasets from one or more sources. For Phase II of the project, we have implemented mechanisms for supporting more elaborate and relevant queries.

  11. QQACCT

    Energy Science and Technology Software Center (OSTI)

    2015-01-01

    batchacct provides convenient library and command-line access to batch system accounting data for GridEngine and SLURM schedulers. It can be used to perform queries useful for data analysis of the accounting data alone or for integrative analysis in the context of a larger query.

  12. Multidimensional structured data visualization method and apparatus, text visualization method and apparatus, method and apparatus for visualizing and graphically navigating the world wide web, method and apparatus for visualizing hierarchies

    DOE Patents [OSTI]

    Risch, John S.; Dowson, Scott T.

    2012-03-06

    A method of displaying correlations among information objects includes receiving a query against a database; obtaining a query result set; and generating a visualization representing the components of the result set, the visualization including one of a plane and line to represent a data field, nodes representing data values, and links showing correlations among fields and values. Other visualization methods and apparatus are disclosed.

  13. Multidimensional structured data visualization method and apparatus, text visualization method and apparatus, method and apparatus for visualizing and graphically navigating the world wide web, method and apparatus for visualizing hierarchies

    DOE Patents [OSTI]

    Risch, John S.; Dowson, Scott T.; Hart, Michelle L.; Hatley, Wes L.

    2008-05-13

    A method of displaying correlations among information objects comprises receiving a query against a database; obtaining a query result set; and generating a visualization representing the components of the result set, the visualization including one of a plane and line to represent a data field, nodes representing data values, and links showing correlations among fields and values. Other visualization methods and apparatus are disclosed.

  14. Direct synthesis of catalyzed hydride compounds

    DOE Patents [OSTI]

    Gross, Karl J.; Majzoub, Eric

    2004-09-21

    A method is disclosed for directly preparing alkali metal aluminum hydrides such as NaAlH.sub.4 and Na.sub.3 AlH.sub.6 from either the alkali metal or its hydride, and aluminum. The hydride thus prepared is doped with a small portion of a transition metal catalyst compound, such as TiCl.sub.3, TiF.sub.3, or a mixture of these materials, in order to render them reversibly hydridable. The process provides for mechanically mixing the dry reagents under an inert atmosphere followed by charging the mixed materials with high pressure hydrogen while heating the mixture to about 125.degree. C. The method is relatively simple and inexpensive and provides reversible hydride compounds which are free of the usual contamination introduced by prior art wet chemical methods.

  15. Modification of silica gel by organotitanium compounds

    SciTech Connect (OSTI)

    Khrustaleva, E.A.; Abramova, V.I.; Suvorov, A.L.; Fridman, L.I.

    1988-05-10

    The study of the modification of silica gels by various organotitanium compounds (OTC) is of interest in connection with their possible use as specific adsorbents, catalysts in the preparation of filled polymeric materials. The authors studied the modification of silica gel by OTC of different types in order to obtain reactive functional organic groups bound to titanium atoms on its surface. During treatment of silica gel with organotitanium compounds of different types in an organic solvent, these react chemically with the hydroxylic groups of silica gel to form Si-O-Ti groups on the surface, containing organic radicals bound to the titanium atom. In the case of coordinatively unsaturated OTC, increase in the time of interaction of the components on heating and excess OTC lead to partial splitting of the Si-O-Ti bonds, which is not observed for coordinatively saturated OTC.

  16. Compound refractive X-ray lens

    DOE Patents [OSTI]

    Nygren, David R.; Cahn, Robert; Cederstrom, Bjorn; Danielsson, Mats; Vestlund, Jonas

    2000-01-01

    An apparatus and method for focusing X-rays. In one embodiment, his invention is a commercial-grade compound refractive X-ray lens. The commercial-grade compound refractive X-ray lens includes a volume of low-Z material. The volume of low-Z material has a first surface which is adapted to receive X-rays of commercially-applicable power emitted from a commercial-grade X-ray source. The volume of low-Z material also has a second surface from which emerge the X-rays of commercially-applicable power which were received at the first surface. Additionally, the commercial-grade compound refractive X-ray lens includes a plurality of openings which are disposed between the first surface and the second surface. The plurality of openings are oriented such that the X-rays of commercially-applicable power which are received at the first surface, pass through the volume of low-Z material and through the plurality openings. In so doing, the X-rays which emerge from the second surface are refracted to a focal point.

  17. Hydromechanical transmission with compound planetary assembly

    DOE Patents [OSTI]

    Orshansky, Jr., deceased, Elias; Weseloh, William E.

    1980-01-01

    A power transmission having three distinct ranges: (1) hydrostatic, (2) simple power-split hydromechanical, and (3) compound power-split hydromechanical. A single compound planetary assembly has two sun gears, two ring gears, and a single carrier with two sets of elongated planet gears. The two sun gears may be identical in size, and the two ring gears may be identical in size. A speed-varying module in driving relationship to the first sun gear is clutchable, in turn, to (1) the input shaft and (2) the second sun gear. The speed-varying means may comprise a pair of hydraulic units hydraulically interconnected so that one serves as a pump while the other serves as a motor and vice versa, one of the units having a variable stroke and being the one clutchable to either the input shaft or to the second sun gear. The other unit, which may have a fixed stroke, is connected in driving relation to the first sun gear. A brake grounds the carrier in the first range and in reverse and causes drive to be delivered to the output shaft through the first ring gear in a hydrostatic mode, the first ring gear being rigidly connected to the output shaft. The input shaft is also clutchable to the second ring gear of the compound planetary assembly.

  18. Intercalation compounds and electrodes for batteries

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young-Il; Huang, Biyan

    2004-09-07

    This invention concerns intercalation compounds and in particular lithium intercalation compounds which have improved properties for use in batteries. Compositions of the invention include particulate metal oxide material having particles of multicomponent metal oxide, each including an oxide core of at least first and second metals in a first ratio, and each including a surface coating of metal oxide or hydroxide that does not include the first and second metals in the first ratio formed by segregation of at least one of the first and second metals from the core. The core may preferably comprise Li.sub.x M.sub.y N.sub.z O.sub.2 wherein M and N are metal atom or main group elements, x, y and z are numbers from about 0 to about 1 and y and z are such that a formal charge on M.sub.y N.sub.z portion of the compound is (4-x), and having a charging voltage of at least about 2.5V. The invention may also be characterized as a multicomponent oxide microstructure usable as a lithium intercalation material including a multiphase oxide core and a surface layer of one material, which is a component of the multiphase oxide core, that protects the underlying intercalation material from chemical dissolution or reaction. In a particular preferred example the multicomponent oxide may be an aluminum-doped lithium manganese oxide composition. Such aluminum-doped lithium manganese oxide compositions, having an orthorhombic structure, also form a part of the invention. In addition, the invention includes articles, particularly electrodes, for batteries formed from the compositions of the invention, and batteries including such electrodes. The invention further relates to a composite intercalation material comprising at least two compounds in which at least one compound has an orthorhombic structure Li.sub.x Al.sub.y Mn.sub.1-y O.sub.2, where y is nonzero, or a mixture of orthorhombic and monoclinic Li.sub.x Al.sub.y Mn.sub.1-y O.sub.2.

  19. Hydroxyalkyl phosphine compounds for use as diagnostic and therapeutic pharmaceuticals

    DOE Patents [OSTI]

    Katti, Kattesh V.; Singh, Prahlad R.; Reddy, V. Sreenivasa; Katti, Kavita K.; Volkert, Wynn A.; Ketring, Alan R.

    1999-01-01

    A compound and method of making a compound for use as a diagnostic or therapeutic pharmaceutical comprises a functionalized hydroxyalkyl phosphine ligand and a metal combined with the ligand.

  20. Surface passivation process of compound semiconductor material using UV photosulfidation

    DOE Patents [OSTI]

    Ashby, Carol I. H.

    1995-01-01

    A method for passivating compound semiconductor surfaces by photolytically disrupting molecular sulfur vapor with ultraviolet radiation to form reactive sulfur which then reacts with and passivates the surface of compound semiconductors.

  1. Hydroxyalkyl phosphine compounds for use as diagnostic and therapeutic pharmaceuticals

    DOE Patents [OSTI]

    Katti, K.V.; Singh, P.R.; Reddy, V.S.; Katti, K.K.; Volkert, W.A.; Ketring, A.R.

    1999-03-02

    This research discloses a compound and method of making a compound for use as a diagnostic or therapeutic pharmaceutical comprises a functionalized hydroxyalkyl phosphine ligand and a metal combined with the ligand. 16 figs.

  2. Palladium catalyzed hydrogenation of bio-oils and organic compounds

    DOE Patents [OSTI]

    Elliott, Douglas C [Kennewick, WA; Hu, Jianli [Richland, WA; Hart,; Todd, R [Kennewick, WA; Neuenschwander, Gary G [Burbank, WA

    2011-06-07

    The invention provides palladium-catalyzed hydrogenations of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydrogenations of organic compounds typically found in bio-oils.

  3. Palladium catalyzed hydrogenation of bio-oils and organic compounds

    DOE Patents [OSTI]

    Elliott, Douglas C.; Hu, Jianli; Hart, Todd R.; Neuenschwander, Gary G.

    2008-09-16

    The invention provides palladium-catalyzed hydrogenations of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydrogenations of organic compounds typically found in bio-oils.

  4. Ternary compound electrode for lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Godshall, N.A.; Huggins, R.A.

    1980-07-30

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

  5. Ternary compound electrode for lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D.; Godshall, Ned A.; Huggins, Robert A.

    1982-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

  6. Radiological Control Programs for Special Tritium Compounds

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    84-2004 SEPTEMBER 2004 CHANGE NOTICE NO. 1 Date June 2006 DOE HANDBOOK RADIOLOGICAL CONTROL PROGRAMS FOR SPECIAL TRITIUM COMPOUNDS U.S. Department of Energy AREA OCSH Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. NOT MEASUREMENT SENSITIVE ii Table of Changes Page Change 67 (near bottom) In row 1, column 2 of the table titled "dosimetric properties" 6 mrem was changed to 6 x 10 -2 mrem Available on the Department of Energy

  7. Radiological Control Programs for Special Tritium Compounds

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE.F 1325.8 (08-93) United States Government Department of Energy memorandum DATE: May 11, 2006 REPLY TO EH-52:JRabovsky:3-2 135 ATTN OF: APPROVAL OF CHANGE NOTICE 1 TO DEPARTMENT OF ENERGY (DOE) SUBJECT. HANDBOOK 1184-2004, RADIOLOGICAL CONTROL PROGRAMS FOR SPECIAL TRITIUM COMPOUNDS TO: Dennis Kubicki, EH-24 Technical Standards Manager This memorandum forwards the subject Change Notice 1 to DOE Handbook, DOE- HDBK- 1184-2004, which has approved for publication and distribution. The change to

  8. Method for conversion of .beta.-hydroxy carbonyl compounds

    DOE Patents [OSTI]

    Lilga, Michael A. (Richland, WA); White, James F. (Richland, WA); Holladay, Johnathan E. (Kennewick, WA); Zacher, Alan H. (Kennewick, WA); Muzatko, Danielle S. (Kennewick, WA); Orth, Rick J. (Kennewick, WA)

    2010-03-30

    A process is disclosed for conversion of salts of .beta.-hydroxy carbonyl compounds forming useful conversion products including, e.g., .alpha.,.beta.-unsaturated carbonyl compounds and/or salts of .alpha.,.beta.-unsaturated carbonyl compounds. Conversion products find use, e.g., as feedstock and/or end-use chemicals.

  9. Novel amine-based presursor compounds and composite membranes thereof

    DOE Patents [OSTI]

    Lee, Eric K. L.; Tuttle, Mark E.

    1989-01-01

    Novel amine-based precursor compounds comprising the condensation products of dialkylenetriamine and alpha, beta-unsaturated acid halides are disclosed, as well as composite membranes containing such compounds, the membranes being useful in RO-type processes for desalination and the removal of low molecular weight organic compounds such as phenols and carboxylic acids.

  10. Boron containing amino acid compounds and methods for their use

    DOE Patents [OSTI]

    Glass, John D.; Coderre, Jeffrey A.

    2000-01-01

    The present invention provides new boron containing amino acid compounds and methods for making these compounds by contacting melphalan or another nitrogen mustard derivative and sodium borocaptate. The present invention also provides a method of treating a mammal having a tumor by administering to the mammal a therapeutically effective amount of the new boron containing amino acid compounds.

  11. Method of digesting an explosive nitro compound

    DOE Patents [OSTI]

    Shah, Manish M.

    2000-01-01

    The present invention is a process wherein bleaching oxidants are used to digest explosive nitro compounds. The process has an excellent reaction rate for digesting explosives and operates under multivariate conditions. Reaction solutions may be aqueous, non-aqueous or a combination thereof, and can also be any pH, but preferably have a pH between 2 and 9. The temperature may be ambient as well as any temperature above which freezing of the solution would occur and below which any degradation of the bleaching oxidant would occur or below which any explosive reaction would be initiated. The pressure may be any pressure, but is preferably ambient or atmospheric, or a pressure above a vapor pressure of the aqueous solution to avoid boiling of the solution. Because the bleaching oxidant molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The bleaching oxidants generate reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro compound.

  12. Compound Refractive Lenses for Thermal Neutron Applications

    SciTech Connect (OSTI)

    Gary, Charles K.

    2013-11-12

    This project designed and built compound refractive lenses (CRLs) that are able to focus, collimate and image using thermal neutrons. Neutrons are difficult to manipulate compared to visible light or even x rays; however, CRLs can provide a powerful tool for focusing, collimating and imaging neutrons. Previous neutron CRLs were limited to long focal lengths, small fields of view and poor resolution due to the materials available and manufacturing techniques. By demonstrating a fabrication method that can produce accurate, small features, we have already dramatically improved the focal length of thermal neutron CRLs, and the manufacture of Fresnel lens CRLs that greatly increases the collection area, and thus efficiency, of neutron CRLs. Unlike a single lens, a compound lens is a row of N lenslets that combine to produce an N-fold increase in the refraction of neutrons. While CRLs can be made from a variety of materials, we have chosen to mold Teflon lenses. Teflon has excellent neutron refraction, yet can be molded into nearly arbitrary shapes. We designed, fabricated and tested Teflon CRLs for neutrons. We demonstrated imaging at wavelengths as short as 1.26 ? with large fields of view and achieved resolution finer than 250 μm which is better than has been previously shown. We have also determined designs for Fresnel CRLs that will greatly improve performance.

  13. Compound And Rotational Damping In Warm Nuclei

    SciTech Connect (OSTI)

    Leoni, S.; Bracco, A.; Benzoni, G.; Blasi, N.; Camera, F.; Grassi, C.; Million, B.; Paleni, A.; Pignanelli, M.; Vigezzi, E.; Wieland, O.; Matsuo, M.; Doessing, T.; Herskind, B.; Hagemann, G.B.; Wilson, J.; Maj, A.; Kmiecik, M.; LoBianco, G.; Petrache, C.M.

    2005-04-05

    The {gamma}-decay from excited nuclei is used to study the interplay between rotational motion and compound nucleus formation in deformed nuclei. A new analysis technique is presented which allows for the first time to directly measure the rotational and compound damping widths {gamma}rot and {gamma}{mu} from {gamma}-coincidence spectra. The method is first tested on simulated spectra and then applied to high-statistics EUROBALL data on the nucleus 163Er. Experimental values of {approx_equal}200 and 20 keV are obtained for {gamma}rot and {gamma}{mu}, respectively, in the spin region I {approx_equal} 30-40 ({Dirac_h}/2{pi}), in good agreement with microscopic cranked shell model calculations for the specific nucleus. A dependence of rotational damping on the K-quantum number of the nuclear states is also observed, both in experiment and theory, resulting in a {approx_equal}30% reduction of {gamma}rot for high-K states. This points to a delayed onset of rotational damping in high-K configurations.

  14. Materials Chemistry and Performance of Silicone-Based Replicating Compounds.

    SciTech Connect (OSTI)

    Brumbach, Michael T.; Mirabal, Alex James; Kalan, Michael; Trujillo, Ana B; Hale, Kevin

    2014-11-01

    Replicating compounds are used to cast reproductions of surface features on a variety of materials. Replicas allow for quantitative measurements and recordkeeping on parts that may otherwise be difficult to measure or maintain. In this study, the chemistry and replicating capability of several replicating compounds was investigated. Additionally, the residue remaining on material surfaces upon removal of replicas was quantified. Cleaning practices were tested for several different replicating compounds. For all replicating compounds investigated, a thin silicone residue was left by the replica. For some compounds, additional inorganic species could be identified in the residue. Simple solvent cleaning could remove some residue.

  15. Unconventional superconductivity in heavy-fermion compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    White, B. D.; Thompson, J. D.; Maple, M. B.

    2015-02-27

    Over the past 35 years, research on unconventional superconductivity in heavy-fermion systems has evolved from the surprising observations of unprecedented superconducting properties in compounds that convention dictated should not superconduct at all to performing explorations of rich phase spaces in which the delicate interplay between competing ground states appears to support emergent superconducting states. In this article, we review the current understanding of superconductivity in heavy-fermion com- pounds and identify a set of characteristics that is common to their unconventional superconducting states. These core properties are compared with those of other classes of unconventional superconductors such as the cuprates andmore » iron-based superconductors. Lastly, we conclude by speculating on the prospects for future research in this field and how new advances might contribute towards resolving the long-standing mystery of how unconventional superconductivity works.« less

  16. Clathrate compounds and method of manufacturing

    DOE Patents [OSTI]

    Nolas, George S.; Witanachchi, Sarath; Mukherjee, Pritish

    2009-05-19

    The present invention comprises new materials, material structures, and processes of fabrication of such that may be used in technologies involving the conversion of light to electricity and/or heat to electricity, and in optoelectronics technologies. The present invention provide for the fabrication of a clathrate compound comprising a type II clathrate lattice with atoms of silicon and germanium as a main framework forming lattice spacings within the framework, wherein the clathrate lattice follows the general formula Si.sub.136-yGe.sub.y, where y indicates the number of Ge atoms present in the main framework and 136-y indicates the number of Si atoms present in the main framework, and wherein y>0.

  17. Reactive codoping of GaAlInP compound semiconductors

    DOE Patents [OSTI]

    Hanna, Mark Cooper; Reedy, Robert

    2008-02-12

    A GaAlInP compound semiconductor and a method of producing a GaAlInP compound semiconductor are provided. The apparatus and method comprises a GaAs crystal substrate in a metal organic vapor deposition reactor. Al, Ga, In vapors are prepared by thermally decomposing organometallic compounds. P vapors are prepared by thermally decomposing phospine gas, group II vapors are prepared by thermally decomposing an organometallic group IIA or IIB compound. Group VIB vapors are prepared by thermally decomposing a gaseous compound of group VIB. The Al, Ga, In, P, group II, and group VIB vapors grow a GaAlInP crystal doped with group IIA or IIB and group VIB elements on the substrate wherein the group IIA or IIB and a group VIB vapors produced a codoped GaAlInP compound semiconductor with a group IIA or IIB element serving as a p-type dopant having low group II atomic diffusion.

  18. Flash vacuum pyrolysis of lignin model compounds

    SciTech Connect (OSTI)

    Cooney, M.J.; Britt, P.F.; Buchanan, A.C. III

    1997-03-01

    Despite the extensive research into the pyrolysis of lignin, the underlying chemical reactions that lead to product formation are poorly understood. Detailed mechanistic studies on the pyrolysis of biomass and lignin under conditions relevant to current process conditions could provide insight into utilizing this renewable resource for the production of chemicals and fuel. Currently, flash or fast pyrolysis is the most promising process to maximize the yields of liquid products (up to 80 wt %) from biomass by rapidly heating the substrate to moderate temperatures, typically 500{degrees}C, for short residence times, typically less than two seconds. To provide mechanistic insight into the primary reaction pathways under process relevant conditions, we are investigating the flash vacuum pyrolysis (FVP) of lignin model compounds that contain a {beta}-ether. linkage and {alpha}- or {gamma}-alcohol, which are key structural elements in lignin. The dominant products from the FVP of PhCH{sub 2}CH{sub 2}OPh (PPE), PhC(OH)HCH{sub 2}OPh, and PhCH{sub 2}CH(CH{sub 2}OH)OPh at 500{degrees}C can be attributed to homolysis of the weakest bond in the molecule (C-O bond) or 1,2-elimination. Surprisingly, the hydroxy-substituent dramatically increases the decomposition of PPE. It is proposed that internal hydrogen bonding is accelerating the reaction.

  19. Internal combustion engine with compound air compression

    SciTech Connect (OSTI)

    Paul, M.A.; Paul, A.

    1991-10-15

    This patent describes an internal combustion engine in combination with a compound air compression system. It comprises: a reciprocator with at least one cylinder, at least one piston reciprocal in the cylinder and a combustion chamber formed in substantial part by portions of the piston and cylinder, the reciprocator having a drive shaft; a rotary compressor having a drive shaft mechanically coupled to the drive shaft of the reciprocator, the rotary compressor having a Wankel-type, three-lobe, epitrochiodal configuration sides having a conduit conjected to the reciprocator for supplying compressed air to the reciprocator; a turbocharged with a gas turbine and a turbocompressor, the turbocompressor having an air conduit connected to the expander side of the rotary compressor; and a bypass conduit with a valve means connecting the turbocharger to the reciprocator for supplying compressed air directly to the reciprocator wherein the drive shaft of the reciprocator and the drive shaft of the compressor have connecting means for transmitting mechanical energy to the reciprocator at mid to high operating speeds of the engine when the turbocharge supplies compressed air to the rotary compressor and, at least in part, drives the rotary compressor.

  20. Fission Barriers of Compound Superheavy Nuclei

    SciTech Connect (OSTI)

    Pei, Junchen; Nazarewicz, Witold; Sheikh, J. A.; Kerman, A. K.

    2009-01-01

    The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. We study the temperature-dependent fission barriers by means of the self-consistent nuclear density functional theory. The equivalence of isothermal and isentropic descriptions is demonstrated. The effect of the particle gas is found to be negligible in the range of temperatures studied. Calculations have been carried out for ^{264}Fm, ^{272}Ds, ^{278}112, ^{292}114, and ^{312}124. For nuclei around ^{278}112 produced in "cold fusion" reactions, we predict a more rapid decrease of fission barriers with temperature as compared to the nuclei around ^{292}114 synthesized in "hot fusion" experiments. This is explained in terms of the difference between the ground-state and fission-barrier temperatures. Our calculations are consistent with the long survival probabilities of the superheavy elements produced in Dubna with the ^{48}Ca beam.

  1. Sandia National Labs: PCNSC: Research: Compound Semiconductor Science and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Compound Semiconductor Science and Technology Thrust The Physical, Chemical, and Nano Sciences Center's vision for Compound Semiconductors is to develop the science of compound semiconductors that will enable us to invent integrated nano-technologies for the microsystems of the future. We will achieve this by advancing the frontiers of semiconductor research in areas such as quantum phenomena, defect physics, materials and device modeling, heteroepitaxy, and by discovering new

  2. Boron compounds as anion binding agents for nonaqueous battery electrolytes

    DOE Patents [OSTI]

    Lee, Hung Sui; Yang, Xia-Oing; McBreen, James; Xiang, Caili

    2000-02-08

    Novel fluorinated boron-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boron-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boron-based anion receptors include borane and borate compounds bearing different fluorinated alkyl and aryl groups.

  3. Evaluation of Sulfur Spinel Compounds for Multivalent Battery Cathode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications - Joint Center for Energy Storage Research August 17, 2016, Research Highlights Evaluation of Sulfur Spinel Compounds for Multivalent Battery Cathode Applications A group of 3d transition-metal sulfur-spinel compounds were systematically assessed for MV cathode applications, based on their electrochemical and thermodynamic properties . Cr2S4, Ti2S4 and Mn2S4 spinel compounds exhibit superior Mg2+ mobility, and hence, emerge as the top three candidates. Scientific Achievement

  4. Model Compound Studies of Fuel Cell Membrane Degradation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Model Compound Studies of Fuel Cell Membrane Degradation Model Compound Studies of Fuel Cell Membrane Degradation Presentation on Model Compound Studies of Fuel Cell Membrane Degradation to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005. htmwg05_schiraldi.pdf (549.62 KB) More Documents & Publications Some durability considerations for proton exchange membranes Processing-Performance Relationships for Perfluorosulfonate Ionomer Membrane

  5. Recovery of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, Mark W.; George, William A.

    1988-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  6. Recovery of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, Mark W.; George, William A.

    1991-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  7. Recovery of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, Mark W.; George, William A.

    1989-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  8. Process for synthesizing compounds from elemental powders and product

    DOE Patents [OSTI]

    Rabin, Barry H.; Wright, Richard N.

    1993-01-01

    A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe.sub.3 Al and FeAl.

  9. Compound and Elemental Analysis At Snake River Plain Region ...

    Open Energy Info (EERE)

    | Sign Up Search Page Edit with form History Compound and Elemental Analysis At Snake River Plain Region (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  10. Compound and Elemental Analysis At Fish Lake Valley Area (DOE...

    Open Energy Info (EERE)

    ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Fish Lake Valley Area (DOE GTP) Exploration Activity Details Location Fish Lake Valley Area...

  11. Compound and Elemental Analysis At Fish Lake Valley Area (Deymonaz...

    Open Energy Info (EERE)

    ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Fish Lake Valley Area (Deymonaz, Et Al., 2008) Exploration Activity Details Location Fish...

  12. Compound and Elemental Analysis At International Geothermal Area...

    Open Energy Info (EERE)

    Geothermal Area Indonesia Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Improving Exploration Models of...

  13. Interplay between compound and fragments aspects of nuclear fission...

    Office of Scientific and Technical Information (OSTI)

    aspects of nuclear fission and heavy-ion reaction Citation Details In-Document Search Title: Interplay between compound and fragments aspects of nuclear fission and ...

  14. Compound and Elemental Analysis At Salt Wells Area (Shevenell...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Compound and Elemental Analysis Activity Date...

  15. Compound and Elemental Analysis At Lightning Dock Area (Norman...

    Open Energy Info (EERE)

    Area (Norman & Moore, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Lightning Dock Area (Norman &...

  16. Compound and Elemental Analysis At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Compound and Elemental Analysis...

  17. Compound and Elemental Analysis At Clear Lake Area (Thompson...

    Open Energy Info (EERE)

    Details Location Clear Lake Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness useful DOE-funding Unknown Notes Based on the above discussion,...

  18. Compound and Elemental Analysis At Wister Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    Wister Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Wister Area (DOE GTP) Exploration...

  19. Compound and Elemental Analysis At Alum Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    Alum Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Alum Area (DOE GTP) Exploration Activity...

  20. Compound and Elemental Analysis At Lightning Dock Geothermal...

    Open Energy Info (EERE)

    Area (Dellechaie, 1977) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Lightning Dock Geothermal Area...

  1. Recovery of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1989-11-07

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figs.

  2. Recovery of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1991-06-18

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figures.

  3. Compound and Elemental Analysis At Little Valley Area (Wood,...

    Open Energy Info (EERE)

    Little Valley Area (Wood, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Little Valley Area (Wood,...

  4. Compound and Elemental Analysis At Mcgee Mountain Area (DOE GTP...

    Open Energy Info (EERE)

    Mcgee Mountain Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Mcgee Mountain Area (DOE GTP)...

  5. Structural and property studies on metal-organic compounds with...

    Office of Scientific and Technical Information (OSTI)

    with 3-D supramolecular network Citation Details In-Document Search Title: Structural and property studies on metal-organic compounds with 3-D supramolecular network Two ...

  6. Compound and Elemental Analysis At Fenton Hill HDR Geothermal...

    Open Energy Info (EERE)

    In Hot Dry Rock Geothermal Systems- Field Investigations Of In Situ Geochemical Behavior Additional References Retrieved from "http:en.openei.orgwindex.php?titleCompound...

  7. Compound and Elemental Analysis At Raft River Geothermal Area...

    Open Energy Info (EERE)

    Raft River Geothermal Area (1981) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Raft River Geothermal Area...

  8. Process for preparing a chemical compound enriched in isotope content

    DOE Patents [OSTI]

    Michaels, Edward D.

    1982-01-01

    A process to prepare a chemical enriched in isotope content which includes: (a) A chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; (b) the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; (c) the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; (d) the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products.

  9. Prediction of New Hydrogen Storage Compounds and Mixtures

    Broader source: Energy.gov [DOE]

    Presentation on the Prediction of New Hydrogen Storage Compounds and Mixtures given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  10. Novel Compounds for Enhancing Electrolyte Stability and Safety...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Lithium-ion Cells Novel Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review...

  11. Compound and Elemental Analysis At Long Valley Caldera Geothermal...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Long Valley Caldera Geothermal Area (Evans, Et Al., 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  12. Compound and Elemental Analysis At Seven Mile Hole Area (Larson...

    Open Energy Info (EERE)

    Seven Mile Hole Area (Larson, Et Al., 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Seven Mile Hole...

  13. Compound and Elemental Analysis At Central Nevada Seismic Zone...

    Open Energy Info (EERE)

    Nevada Seismic Zone Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  14. Compound and Elemental Analysis At Nw Basin & Range Region (Laney...

    Open Energy Info (EERE)

    Northwest Basin and Range Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  15. Compound and Elemental Analysis At Northern Basin & Range Region...

    Open Energy Info (EERE)

    Northern Basin and Range Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  16. Compound and Elemental Analysis At Lassen Volcanic National Park...

    Open Energy Info (EERE)

    Location Lassen Volcanic National Park Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown References J. Michael...

  17. Compound and Elemental Analysis At Buffalo Valley Hot Springs...

    Open Energy Info (EERE)

    Location Buffalo Valley Hot Springs Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  18. Structural Basis of Prion Inhibition by Phenothiazine Compounds...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Structural Basis of Prion Inhibition by Phenothiazine Compounds Citation Details In-Document Search Title: Structural Basis of Prion ...

  19. Compound and Elemental Analysis At Kilauea Southwest Rift And...

    Open Energy Info (EERE)

    Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown References Michelle L. Coombs, Thomas W. Sisson, Peter W. Lipman...

  20. Compound and Elemental Analysis At Kilauea East Rift Area (Coombs...

    Open Energy Info (EERE)

    Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown References Michelle L. Coombs, Thomas W. Sisson, Peter W. Lipman...

  1. Compound and Elemental Analysis At Mt St Helens Area (Shevenell...

    Open Energy Info (EERE)

    Exploration Activity: Compound and Elemental Analysis At Mt St Helens Area (Shevenell & Goff, 2000) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  2. Compound and Elemental Analysis At Fenton Hill HDR Geothermal...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Fenton Hill HDR Geothermal Area (Goff &...

  3. Compound and Elemental Analysis At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Goff, Et Al., 1982) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Valles Caldera - Sulphur Springs...

  4. Compound and Elemental Analysis At Yellowstone Region (Goff ...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Yellowstone Region (Goff & Janik, 2002)...

  5. Compound and Elemental Analysis At Jemez Springs Area (Goff ...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Jemez Springs Area (Goff & Janik, 2002)...

  6. Compound and Elemental Analysis At Valles Caldera - Redondo Geothermal...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Valles Caldera - Redondo Geothermal Area (Goff, Et Al., 1982) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  7. Compound and Elemental Analysis At Mt St Helens Area (Shevenell...

    Open Energy Info (EERE)

    Exploration Activity: Compound and Elemental Analysis At Mt St Helens Area (Shevenell & Goff, 1995) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  8. Compound and Elemental Analysis At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Valles Caldera - Sulphur Springs Geothermal Area (Goff, Et Al., 1985) Exploration Activity Details Location Valles Caldera - Sulphur Springs...

  9. Massive-scale RDF Processing Using Compressed Bitmap Indexes

    SciTech Connect (OSTI)

    Madduri, Kamesh; Wu, Kesheng

    2011-05-26

    The Resource Description Framework (RDF) is a popular data model for representing linked data sets arising from the web, as well as large scienti#12;c data repositories such as UniProt. RDF data intrinsically represents a labeled and directed multi-graph. SPARQL is a query language for RDF that expresses subgraph pattern-#12;nding queries on this implicit multigraph in a SQL- like syntax. SPARQL queries generate complex intermediate join queries; to compute these joins e#14;ciently, we propose a new strategy based on bitmap indexes. We store the RDF data in column-oriented structures as compressed bitmaps along with two dictionaries. This paper makes three new contributions. (i) We present an e#14;cient parallel strategy for parsing the raw RDF data, building dictionaries of unique entities, and creating compressed bitmap indexes of the data. (ii) We utilize the constructed bitmap indexes to e#14;ciently answer SPARQL queries, simplifying the join evaluations. (iii) To quantify the performance impact of using bitmap indexes, we compare our approach to the state-of-the-art triple-store RDF-3X. We #12;nd that our bitmap index-based approach to answering queries is up to an order of magnitude faster for a variety of SPARQL queries, on gigascale RDF data sets.

  10. Process for reducing aromatic compounds in ethylenediamine with calcium

    DOE Patents [OSTI]

    Benkeser, Robert A.; Laugal, James A.; Rappa, Angela

    1985-01-01

    Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

  11. Method for selective dehalogenation of halogenated polyaromatic compounds

    DOE Patents [OSTI]

    Farcasiu, Malvina; Petrosius, Steven C.

    1994-01-01

    A method for dehalogenating halogenated polyaromatic compounds is provided wherein the polyaromatic compounds are mixed with a hydrogen donor solvent and a carbon catalyst in predetermined proportions, the mixture is maintained at a predetermined pressure, and the mixture is heated to a predetermined temperature and for a predetermined time.

  12. Method and reaction pathway for selectively oxidizing organic compounds

    DOE Patents [OSTI]

    Camaioni, Donald M.; Lilga, Michael A.

    1998-01-01

    A method of selectively oxidizing an organic compound in a single vessel comprises: a) combining an organic compound, an acid solution in which the organic compound is soluble, a compound containing two oxygen atoms bonded to one another, and a metal ion reducing agent capable of reducing one of such oxygen atoms, and thereby forming a mixture; b) reducing the compound containing the two oxygen atoms by reducing one of such oxygen atoms with the metal ion reducing agent to, 1) oxidize the metal ion reducing agent to a higher valence state, and 2) produce an oxygen containing intermediate capable of oxidizing the organic compound; c) reacting the oxygen containing intermediate with the organic compound to oxidize the organic compound into an oxidized organic intermediate, the oxidized organic intermediate having an oxidized carbon atom; d) reacting the oxidized organic intermediate with the acid counter ion and higher valence state metal ion to bond the acid counter ion to the oxidized carbon atom and thereby produce a quantity of an ester incorporating the organic intermediate and acid counter ion; and e) reacting the oxidized organic intermediate with the higher valence state metal ion and water to produce a quantity of alcohol which is less than the quantity of ester, the acid counter ion incorporated in the ester rendering the carbon atom bonded to the counter ion less reactive with the oxygen containing intermediate in the mixture than is the alcohol with the oxygen containing intermediate.

  13. Polymers containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E.; Eastwood, Eric A.

    2012-06-05

    Polymers comprising residues of borane and/or carborane cage compound monomers having at least one polyalkoxy silyl substituent. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Methods of making and applications for using such polymers are also disclosed.

  14. Process for reducing aromatic compounds in ethylenediamine with calcium

    DOE Patents [OSTI]

    Benkeser, R.A.; Laugal, J.A.; Rappa, A.

    1985-08-06

    Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

  15. Method for converting asbestos to non-carcinogenic compounds

    DOE Patents [OSTI]

    Selby, Thomas W.

    1996-01-01

    Hazardous and carcinogenic asbestos waste characterized by a crystalline fibrous structure is transformed into non-carcinogenic, relatively nonhazardous, and non-crystalline solid compounds and gaseous compounds which have commercial utilization. The asbestos waste is so transformed by the complete fluorination of the crystalline fibrous silicate mineral defining the asbestos.

  16. Method for converting asbestos to non-carcinogenic compounds

    DOE Patents [OSTI]

    Selby, T.W.

    1996-08-06

    Hazardous and carcinogenic asbestos waste characterized by a crystalline fibrous structure is transformed into non-carcinogenic, relatively nonhazardous, and non-crystalline solid compounds and gaseous compounds which have commercial utilization. The asbestos waste is so transformed by the complete fluorination of the crystalline fibrous silicate mineral defining the asbestos. 7 figs.

  17. Preparation of high nitrogen compound and materials therefrom

    DOE Patents [OSTI]

    Huynh, My Hang V.; Hiskey, Michael A.

    2006-10-10

    The high-nitrogen compound of the formula ##STR00001## was prepared. Pyrolysis of the compound yields carbon nitrides C.sub.2N.sub.3 and C.sub.3N.sub.5. The carbon nitrides vary in their density, texture, and morphology.

  18. Spinel Compounds as Multivalent Battery Cathodes: A Systematic Evaluation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Based on ab initio Calculations - Joint Center for Energy Storage Research December 16, 2014, Research Highlights Spinel Compounds as Multivalent Battery Cathodes: A Systematic Evaluation Based on ab initio Calculations Evaluation of multivalent spinel compounds based on multiple performance characteristics such as voltage, specific energy, thermodynamic stability, thermal stability and intercalant mobility. The favorable (unfavorable) properties are represented with light (dark) color

  19. Redox chromophore compounds and electrodes of metal containing substituted bipyridines

    DOE Patents [OSTI]

    Elliott, Cecil M.; Redepenning, Jody G.

    1986-01-01

    Chromophoric compounds, each having a wide range of distinct color changes in response to changes in the oxidation states thereof, are provided in the form of polymerizable monomers, and polymers thereof, of certain metal containing, and electron group substituted, 2,2'-bipyridine compounds.

  20. Process for forming a metal compound coating on a substrate

    DOE Patents [OSTI]

    Sharp, Donald J.; Vernon, Milton E.; Wright, Steven A.

    1991-01-01

    A method of coating a substrate with a thin layer of a metal compound by forming a dispersion of an electrophoretically active organic colloid and a precursor of the metal compound in an electrolytic cell in which the substrate is an electrode. Upon application of an electric potential, the electrode is coated with a mixture of the organic colloid and the precursor to the metal compound, and the coated substrate is then heated in the presence of an atmosphere or vacuum to decompose the organic colloid and form a coating of either a combination of metal compound and carbon, or optionally forming a porous metal compound coating by heating to a temperature high enough to chemically react the carbon.

  1. Process for forming a metal compound coating on a substrate

    DOE Patents [OSTI]

    Sharp, D.J.; Vernon, M.E.; Wright, S.A.

    1988-06-29

    A method of coating a substrate with a thin layer of a metal compound by forming a dispersion of an electrophoretically active organic colloid and a precursor of the metal compound in an electrolytic cell in which the substrate is an electrode. Upon application of an electric potential, the electrode is coated with a mixture of the organic colloid and the precursor to the metal compound, and the coated substrate is then heated in the presence of an atmosphere or vacuum to decompose the organic colloid and form a coating of either a combination of metal compound and carbon, or optionally forming a porous metal compound coating by heating to a temperature high enough to chemically react the carbon.

  2. Corona Method And Apparatus For Altering Carbon Containing Compounds

    DOE Patents [OSTI]

    Sharma, Amit K.; Camaioni, Donald M.; Josephson; Gary B.

    2004-05-04

    The present invention is a method and apparatus for altering a carbon-containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon-containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

  3. Corona method and apparatus for altering carbon containing compounds

    DOE Patents [OSTI]

    Sharma, Amit K.; Camaioni, Donald M.; Josephson, Gary B.

    1999-01-01

    The present invention is a method and apparatus for altering a carbon containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

  4. Device for collecting chemical compounds and related methods

    DOE Patents [OSTI]

    Scott, Jill R.; Groenewold, Gary S.; Rae, Catherine

    2013-01-01

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from the fixed surfaces so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  5. FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Theresa M. Bomstad

    2003-07-01

    Western Research Institute (WRI) is continuing work toward the development of new screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of halogens. In prior work, the devices were tested for response to carbon tetrachloride, heptane, toluene, and water vapors. In the current work, sensor response was evaluated with sixteen halogenated VOCs relative to carbon tetrachloride. The results show that the response of the various chlorinated VOCs is within an order of magnitude of the response to carbon tetrachloride for each of the sensors. Thus, for field screening a single response factor can be used. Both types of leak detectors are being further modified to provide an on-board LCD signal readout, which is related to VOC concentration. The units will be fully portable and will operate with 115-V line or battery power. Signal background, noise level, and response data on the Bacharach heated diode detector and the TIF corona discharge detector show that when the response curves are plotted against the log of concentration, the plot is linear to the upper limit for the particular unit, with some curvature at lower levels. When response is plotted directly against concentration, the response is linear at the low end and is curved at the high end. The dynamic ranges for carbon tetrachloride of the two devices from the lower detection limit (S/N=2) to signal saturation are 4-850 vapor parts per million (vppm) for the corona discharge unit and 0.01-70 vppm for the heated diode unit. Additional circuit modifications are being made to lower the detection limit and increase the dynamic response range of the corona discharge unit. The results indicate that both devices show potential utility for future analytical method development work toward

  6. Compound cast product and method for producing a compound cast product

    DOE Patents [OSTI]

    Meyer, Thomas N.; Viswanathan, Srinath

    2002-09-17

    A compound cast product is formed in a casting mold (14) having a mold cavity (16) sized and shaped to form the cast product. A plurality of injectors (24) is supported from a bottom side (26) of the casting mold (14). The injectors (24) are in fluid communication with the mold cavity (16) through the bottom side (26) of the casting mold (14). A molten material holder furnace (12) is located beneath the casting mold (14). The holder furnace (12) defines molten material receiving chambers (36) configured to separately contain supplies of two different molten materials (37, 38). The holder furnace (12) is positioned such that the injectors (24) extend downward into the receiving chamber (36). The receiving chamber (36) is separated into at least two different flow circuits (51, 52). A first molten material (37) is received in a first flow circuit (51), and a second molten material (38) is received into a second flow circuit (52). The first and second molten materials (37, 38) are injected into the mold cavity (16) by the injectors (24) acting against the force of gravity. The injectors (24) are positioned such that the first and second molten materials (37, 38) are injected into different areas of the mold cavity (16). The molten materials (37, 38) are allowed to solidify and the resulting compound cast product is removed from the mold cavity (16).

  7. EIA Open Data - Doc - U.S. Energy Information Administration (EIA)

    Gasoline and Diesel Fuel Update (EIA)

    API Commands EIA's API uses a modified RESTful architecture, where a separate URI is used for each query command with query string variables, both required and optional, providing input parameters. Two such query string input parameters apply to all commands: api_key: Required. A valid API key is required and may be obtained from Registration out: Optional. Valid values are "xml" or "json". If missing or any other value, the API call will return JSON formatted output. API

  8. Oxygen-stabilized zirconium-vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1981-10-06

    An oxygen stabilized intermetallic compound having the formula Zr/sub x/OV/sub y/ where x = 0.7 to 2.0 and y = 0.18 to 0.33 is described. The compound is capable of reversibly sorbing hydrogen at temperatures from - 196/sup 0/C to 450/sup 0/C at pressures down to 10/sup -6/ Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO/sub 2/.

  9. Mixed anion materials and compounds for novel proton conducting membranes

    DOE Patents [OSTI]

    Poling, Steven Andrew; Nelson, Carly R.; Martin, Steve W.

    2006-09-05

    The present invention provides new amorphous or partially crystalline mixed anion chalcogenide compounds for use in proton exchange membranes which are able to operate over a wide variety of temperature ranges, including in the intermediate temperature range of about 100 .degree. C. to 300.degree. C., and new uses for crystalline mixed anion chalcogenide compounds in such proton exchange membranes. In one embodiment, the proton conductivity of the compounds is between about 10.sup.-8 S/cm and 10.sup.-1 S/cm within a temperature range of between about -60 and 300.degree. C. and a relative humidity of less than about 12%..

  10. SEPARATION OF URANIUM HEXAFLUORIDE FROM ORGANIC FLUORO COMPOUNDS

    DOE Patents [OSTI]

    Libby, W.F.

    1958-10-01

    A method is presented for removing perfiuoroorganic compounds such as C/ sub 7/F/sub 16/ from UF/sub 6/. The physical and chemical properties of the perfluoro compounds are such as to render their removal from UF/sub 6/ difficulty by conventional techniques. The mixture containing UF/sub 6/ and the perfluoro compounds is pyrolyzed in an inert container at high temperature and pressure. The properties of the products obtained by pyrolysis differ from the properties of UF/sub 6/ to a sufficient degree to render their separation possible by ordinary methods.

  11. Process and apparatus for formation of photovoltaic compounds

    DOE Patents [OSTI]

    Hall, Robert B.; Rocheleau, Richard E.

    1985-01-01

    The invention relates to a process and apparatus for formation and deposition of thin films on a substrate, in a vacuum, by evaporation of the elements to form a Zn.sub.x Cd.sub.1-x S compound having a preselected fixed ratio of cadmium to zinc, characterized by the evaporation of cadmium and zinc at a rate the ratio of which is proportional to the stoichiometric ratio of those elements in the intended compound and evaporation of sulfur at a rate at least twice the combined rates of cadmium and zinc, and at least twice that required by the stoichiometry of the intended compound.

  12. Aqueous phase removal of nitrogen from nitrogen compounds

    DOE Patents [OSTI]

    Fassbender, Alex G.

    1993-01-01

    A method is disclosed for denitrification of compounds containing nitrogen present in aqueous waste streams. The method comprises the steps of (1) identifying the types of nitrogen compounds present in a waste stream, (2) determining the concentrations of nitrogen compounds, (3) balancing oxidized and reduced form of nitrogen by adding a reactant, and (4) heating the mixture to a predetermined reaction temperature from about 300.degree. C. to about 600.degree. C., thereby resulting in less harmful nitrogen and oxygen gas, hydroxides, alcohols, and hydrocarbons.

  13. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1987-07-14

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

  14. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, Tuan

    1987-01-01

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique.

  15. Methods and compounds for chemical ligation (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Methods and compounds for chemical ligation Citation Details In-Document Search Title: ... DOE Contract Number: FG02-02ER63445 Resource Type: Patent Research Org: Harvard College ...

  16. Compound Solar Technology CompSolar | Open Energy Information

    Open Energy Info (EERE)

    Solar Technology CompSolar Jump to: navigation, search Name: Compound Solar Technology (CompSolar) Place: Jhunan, Taiwan Zip: 350 Sector: Solar Product: Producer of glass-based...

  17. Process for synthesizing compounds from elemental powders and product

    DOE Patents [OSTI]

    Rabin, B.H.; Wright, R.N.

    1993-12-14

    A process for synthesizing intermetallic compounds from elemental powders is described. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe[sub 3] Al and FeAl. 25 figures.

  18. Removal of basic nitrogen compounds from hydrocarbon liquids

    DOE Patents [OSTI]

    Givens, Edwin N.; Hoover, David S.

    1985-01-01

    A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

  19. Process for reducing organic compounds with calcium, amine, and alcohol

    DOE Patents [OSTI]

    Benkeser, Robert A.; Laugal, James A.; Rappa, Angela

    1985-01-01

    Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

  20. Anion receptor compounds for non-aqueous electrolytes

    DOE Patents [OSTI]

    Lee, Hung Sui; Yang, Xiao-Oing; McBreen, James

    2000-09-19

    A new family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

  1. Process for reducing organic compounds with calcium, amine, and alcohol

    DOE Patents [OSTI]

    Benkeser, R.A.; Laugal, J.A.; Rappa, A.

    1985-08-06

    Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about [minus]10 C to about 30 C or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

  2. Chromium (V) compounds as cathode material in electrochemical power sources

    DOE Patents [OSTI]

    Delnick, F.M.; Guidotti, R.A.; McCarthy, D.K.

    A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca/sub 5/(CrO/sub 4/)/sub 3/Cl, Ca/sub 5/(CrO/sub 4/)OH, and Cr/sub 2/O/sub 5/. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

  3. Chromium (V) compounds as cathode material in electrochemical power sources

    DOE Patents [OSTI]

    Delnick, Frank M.; Guidotti, Ronald A.; McCarthy, David K.

    1985-01-01

    A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca.sub.5 (CrO.sub.4).sub.3 Cl, Ca.sub.5 (CrO.sub.4).sub.3 OH, and Cr.sub.2 O.sub.5. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

  4. Technologies for Extracting Valuable Metals and Compounds from Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluids | Department of Energy Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Demonstrate geothermal mineral extraction; Demonstrate technical and economic feasibility; Produce products for market development; Generate operational data and scale up data so a commercial scale plant can be designed and built.

  5. Device for aqueous detection of nitro-aromatic compounds

    DOE Patents [OSTI]

    Reagen, W.K.; Schulz, A.L.; Ingram, J.C.; Lancaster, G.D.; Grey, A.E.

    1994-04-26

    This invention relates to a compact and portable detection apparatus for nitro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound. 4 figures.

  6. Device for aqueous detection of nitro-aromatic compounds

    DOE Patents [OSTI]

    Reagen, William K.; Schulz, Amber L.; Ingram, Jani C.; Lancaster, Gregory D.; Grey, Alan E.

    1994-01-01

    This invention relates to a compact and portable detection apparatus for ro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound.

  7. Selective Conversion of Lignin into Simple Aromatic Compounds - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Selective Conversion of Lignin into Simple Aromatic Compounds Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Lignin is a major component of non-edible biomass (15-30 percent by weight; 40 percent by energy). It is a cheap byproduct of pulp and biofuel production and is one of the few naturally occurring sources of high-volume aromatic compounds. Converting lignin's complex biopolymer structure into simple organic

  8. Chromium (V) compounds as cathode material in electrochemical power sources

    SciTech Connect (OSTI)

    Delnick, F. M.; Guidotti, R. A.; McCarthy, D. K.

    1985-04-02

    A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca/sub 5/(CrO/sub 4/)/sub 3/Cp, Ca/sub 5/(CrO/sub 4/)/sub 3/OH, and Cr/sub 2/O/sub 5/. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

  9. Lattice thermal expansion for normal tetrahedral compound semiconductors

    SciTech Connect (OSTI)

    Omar, M.S. . E-mail: dr_m_s_omar@yahoo.com

    2007-02-15

    The cubic root of the deviation of the lattice thermal expansion from that of the expected value of diamond for group IV semiconductors, binary compounds of III-V and II-VI, as well as several ternary compounds from groups I-III-VI{sub 2}, II-IV-V{sub 2} and I-IV{sub 2}V{sub 3} semiconductors versus their bonding length are given straight lines. Their slopes were found to be 0.0256, 0.0210, 0.0170, 0.0259, 0.0196, and 0.02840 for the groups above, respectively. Depending on the valence electrons of the elements forming these groups, a formula was found to correlate all the values of the slopes mentioned above to that of group IV. This new formula which depends on the melting point and the bonding length as well as the number of valence electrons for the elements forming the compounds, will gives best calculated values for lattice thermal expansion for all compounds forming the groups mentioned above. An empirical relation is also found between the mean ionicity of the compounds forming the groups and their slopes mentioned above and that gave the mean ionicity for the compound CuGe{sub 2}P{sub 3} in the range of 0.442.

  10. Reactive codoping of GaAlInP compound semiconductors (Patent...

    Office of Scientific and Technical Information (OSTI)

    Patent: Reactive codoping of GaAlInP compound semiconductors Citation Details In-Document Search Title: Reactive codoping of GaAlInP compound semiconductors A GaAlInP compound ...

  11. Developer | OpenEI Community

    Open Energy Info (EERE)

    Q & A Feeds American Clean Skies Foundation (1) API (3) APIs (1) Apps (1) ask queries (1) Big Data (1) bug (2) challenge (1) citation (1) citing (1) clean energy (1) cleanweb (2)...

  12. Utility Rate API v2 | OpenEI Community

    Open Energy Info (EERE)

    Hi, I am running into one issue with the API and that is using an ask query to get the data in the embedded multiple instance template fields. This is the last big problem that...

  13. OpenEI Community Central | OpenEI Community

    Open Energy Info (EERE)

    (1) acres (1) adoption (1) American Clean Skies Foundation (1) Apps (1) ask queries (1) Big Data (1) biofuel art (1) building (1) building load (1) building load data (1) car (1)...

  14. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Switch to Detail View for this search SciTech Connect Search Results Page 1 of 1 Search ... October 1972 Prev Next Switch to Detail View for this search SOLR Query ...

  15. PowerPoint Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...w.gsaelibrary.gsa.govElibMainsinDetails.do?executeQueryYES&scheduleNumber84&fl ag&filter&specialItemNumber246+53 Become a GSA Schedule 84, SIN 246-53 vendor (2 steps) ...

  16. OSTI, US Dept of Energy, Office of Scientific and Technical Informatio...

    Office of Scientific and Technical Information (OSTI)

    ... Is an offset needed? Does the site's query script need to incorporate parameters that will block old, pre-Harvesting records from coming into OSTI's system again? Who at the site ...

  17. Sulphur Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  18. Lake City Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  19. Maazama Well Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  20. Virgin Islands Wtr&Pwr Auth | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  1. Graph Mining Meets the Semantic Web

    SciTech Connect (OSTI)

    Lee, Sangkeun; Sukumar, Sreenivas R; Lim, Seung-Hwan

    2015-01-01

    The Resource Description Framework (RDF) and SPARQL Protocol and RDF Query Language (SPARQL) were introduced about a decade ago to enable flexible schema-free data interchange on the Semantic Web. Today, data scientists use the framework as a scalable graph representation for integrating, querying, exploring and analyzing data sets hosted at different sources. With increasing adoption, the need for graph mining capabilities for the Semantic Web has emerged. We address that need through implementation of three popular iterative Graph Mining algorithms (Triangle count, Connected component analysis, and PageRank). We implement these algorithms as SPARQL queries, wrapped within Python scripts. We evaluate the performance of our implementation on 6 real world data sets and show graph mining algorithms (that have a linear-algebra formulation) can indeed be unleashed on data represented as RDF graphs using the SPARQL query interface.

  2. In-situ sampling of a large-scale particle simulation for interactive...

    Office of Scientific and Technical Information (OSTI)

    The limiting technology in this situation is analogous to the problem in many population surveys: there aren't enough human resources to query a large population. To cope with the ...

  3. Help:SubObjects | Open Energy Information

    Open Energy Info (EERE)

    except the subobject is listed too. If this is not included, it might actually be OK, but it's working with it in - so there you have it. You'll notice an ask query is in...

  4. OpenEI Community - Utility+Utility Access Map

    Open Energy Info (EERE)

    the Special Ask page, in the query box enter the following:

    &91;&91;Category:Utility...

  5. Finding Utility Companies Under a Given Utility ID | OpenEI Community

    Open Energy Info (EERE)

    utility company pages under a given utility id. From the Special Ask page, in the query box enter the following: Category:Utility CompaniesEiaUtilityId::15248 substituting...

  6. Utility+Utility Access Map | OpenEI Community

    Open Energy Info (EERE)

    utility company pages under a given utility id. From the Special Ask page, in the query box enter the following: Category:Utility CompaniesEiaUtilityId::15248 substituting...

  7. Solar Power In China | Open Energy Information

    Open Energy Info (EERE)

    Solar Power In China Jump to: navigation, search This article is a stub. You can help OpenEI by expanding it. Working on ask query to display all Chinese solar companies TODO:...

  8. Title 43 CFR 3201 Available Lands | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  9. Title 25 USC 323 Rights-of-way for all purposes across any Indian...

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  10. Alaska - AS 42.45.045 - Renewable Energy Grant Fund and Recommendation...

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  11. Title 10, Chapter 49 Protection of Navigable Waters and Shorelands...

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  12. How can an external application get access to OpenEI images and...

    Open Energy Info (EERE)

    How can an external application get access to OpenEI images and thumbnails? Home > Groups > Developer I'm building an external application in Simile Exhibit. Through an Ask query...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    which are of great significance to the in-depth understanding of the phase transformation ... March 2016 , Elsevier Prev Next Switch to Detail View for this search SOLR Query ...

  14. Kanuti Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  15. HCP Handbook | Open Energy Information

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  16. OSTI, US Dept of Energy Office of Scientific and Technical Information...

    Office of Scientific and Technical Information (OSTI)

    Federated search, for those of you new to the term, is the simultaneous search of multiple online databases or web resources from a single query. The Wikipedia article on federated ...

  17. OSTIblog Articles in the milestones Topic | OSTI, US Dept of...

    Office of Scientific and Technical Information (OSTI)

    Federated search, for those of you new to the term, is the simultaneous search of multiple online databases or web resources from a single query. The Wikipedia article on federated ...

  18. Microsoft Word - Plain Language Compliance Report 2016.doc

    Energy Savers [EERE]

    For example, visitors can enter a search term and find that information on Energy.gov; ... found most user search queries consist of terms that are simple and in Plain Language. ...

  19. DOE - NNSA/NFO -- Search

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. DOENNSA - Nevada Field Office Search this Website To enter a query, type in a few descriptive ... of the page Return results where my terms occur Sort Sort by relevance Sort by ...

  20. Template:LabelValuePair | Open Energy Information

    Open Energy Info (EERE)

    is typically used to display the results of an ask or sparql query in a simple label: value format. It is used by many pages, including the sub pages for country profiles, and is...

  1. OSTI Employees Cited for Central Roles in Science.gov | OSTI...

    Office of Scientific and Technical Information (OSTI)

    in the creation and ongoing development of Science.gov, a federal science Web portal. ... for ranking science queries across 30 deep Web scientific databases and 1,800 Web sites. ...

  2. Microsoft Word - rhubc2_DOE-SC-ARM-0901_final_rev3.24.09.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... This query led us to meet with Dr. Michel Cure at the University of Valparaiso. Dr. Cure is starting a project to forecast water vapor amounts over the Atacama Astronomical Park, ...

  3. Thermo Scientific Sulfur Dioxide Analyzer Instrument Handbook...

    Office of Scientific and Technical Information (OSTI)

    in National Instruments LabView that both controls the Model 43i-TLE Analyzer AND queries the unit for all measurement and housekeeping data. The LabView vi (the software program ...

  4. November-December | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    ... To test the hypotheses of brain structure, dynamics and function, the team built a ... This is why being able to test the speed of the query execution on the Dash compute system ...

  5. Polls | OpenEI Community

    Open Energy Info (EERE)

    May 2012 - 13:48 by Rmckeel * The Utility Rate web service * The Incentive web service * Web services to query by geographic location or shape * Mediawiki Ask examples & tutorials...

  6. ScienceLab | OSTI, US Dept of Energy, Office of Scientific and...

    Office of Scientific and Technical Information (OSTI)

    For single-query access to an array of federal science education resources, intended for ... Innovative, state-of-the-art audio indexing and speech recognition technology is used to ...

  7. User:Nlangle/Timeline Test | Open Energy Information

    Open Energy Info (EERE)

    enabled to view the interactive timeline. Further results for this query.DECADEFederal Oil and Gas Royalty Simplification and Fairness Act of 19961996-01-010Year: 1996 Federal...

  8. User:Woodjr/Sandbox/GeoMap | Open Energy Information

    Open Energy Info (EERE)

    GeoMap < User:Woodjr | Sandbox Jump to: navigation, search Demonstration of an experimental "GeoMap" result format for ask queries. Based on Google's GeoMap Visualization API....

  9. Direct-Current Resistivity At Cove Fort Area - Liquid (Combs...

    Open Energy Info (EERE)

    form View source History View New Pages Recent Changes All Special Pages Semantic SearchQuerying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with...

  10. NREL: Energy Analysis - Jon Weers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Senior Web Applications Engineer On staff since March 2010 Phone number: 303-275-3701 E-mail: jon.weers@nrel.gov Areas of expertise Interactive web applications (PHP, jQuery, ...

  11. Publications about OSTI | OSTI, US Dept of Energy Office of Scientific...

    Office of Scientific and Technical Information (OSTI)

    and WorldWideScience.org, the patron gains access to multiple, geographically dispersed deep web databases and can search all of the constituent sources with a single query. ...

  12. OSTI, US Dept of Energy Office of Scientific and Technical Information...

    Office of Scientific and Technical Information (OSTI)

    In 2005, the idea of creating a global science gateway for the web was conceived at OSTI. ... a single query, and it would be available at no cost to anyone anywhere with web access. ...

  13. Science.gov 3.0 Launched | Department of Energy

    Energy Savers [EERE]

    early viewing of results while the database and Web site searches continue in real time. ... A single query searches across 30 databases and 1,800 Web sites. Science.gov allows users ...

  14. OSTI, US Dept of Energy Office of Scientific and Technical Information...

    Office of Scientific and Technical Information (OSTI)

    the simultaneous search of multiple online databases or web resources from a single query. ... be developed as part of many scientific research projects in today's Web 2.0 environment. ...

  15. Science.gov 3.0 Launched; Offers Increased Precision Searches...

    Office of Science (SC) Website

    early viewing of results while the database and Web site searches continue in real time. ... A single query searches across 30 databases and 1,800 Web sites. Science.gov allows users ...

  16. OSTIblog Articles in the milestones Topic | OSTI, US Dept of...

    Office of Scientific and Technical Information (OSTI)

    the simultaneous search of multiple online databases or web resources from a single query. ... Today it is the Internet transformation, especially the Web. As a leader in making the Web ...

  17. Web Support

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Web Support We want to be able to respond promptly to your queries. To expedite our response, please check the specific website or page in question for the name of the appropriate ...

  18. Survey of electrochemical production of inorganic compounds. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

  19. Low work function, stable compound clusters and generation process

    DOE Patents [OSTI]

    Dinh, Long N.; Balooch, Mehdi; Schildbach, Marcus A.; Hamza, Alex V.; McLean, II, William

    2000-01-01

    Low work function, stable compound clusters are generated by co-evaporation of a solid semiconductor (i.e., Si) and alkali metal (i.e., Cs) elements in an oxygen environment. The compound clusters are easily patterned during deposition on substrate surfaces using a conventional photo-resist technique. The cluster size distribution is narrow, with a peak range of angstroms to nanometers depending on the oxygen pressure and the Si source temperature. Tests have shown that compound clusters when deposited on a carbon substrate contain the desired low work function property and are stable up to 600.degree. C. Using the patterned cluster containing plate as a cathode baseplate and a faceplate covered with phosphor as an anode, one can apply a positive bias to the faceplate to easily extract electrons and obtain illumination.

  20. Method for digesting a nitro-bearing explosive compound

    DOE Patents [OSTI]

    Shah, Manish M.

    2000-01-01

    The present invention is a process wherein superoxide radicals from superoxide salt are used to break down the explosive compounds. The process has an excellent reaction rate for degrading explosives, and operates at ambient temperature and atmospheric pressure in aqueous or non-aqueous conditions. Because the superoxide molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The superoxide salt generates reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro-bearing compound.

  1. LANL researchers improve path to producing uranium compounds, candidates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for advanced nuclear fuels Researchers improve path to producing uranium compounds LANL researchers improve path to producing uranium compounds, candidates for advanced nuclear fuels Enhance the ability to develop advanced nuclear fuels in a safer, simpler manner. April 7, 2011 This illustration shows the structures of UI4(1,4-dioxane)2 (left) and the UI3(1,4-dioxane)1.5 complexes. This illustration shows the structures of UI4(1,4-dioxane)2 (left) and the UI3(1,4-dioxane)1.5 complexes.

  2. Interplay between compound and fragments aspects of nuclear fission and

    Office of Scientific and Technical Information (OSTI)

    heavy-ion reaction (Conference) | SciTech Connect Conference: Interplay between compound and fragments aspects of nuclear fission and heavy-ion reaction Citation Details In-Document Search Title: Interplay between compound and fragments aspects of nuclear fission and heavy-ion reaction The scission point in nuclear fission plays a special role where one-body system changes to two-body system. Inverse of this situation is realized in heavy-ion fusion reaction where two-body system changes to

  3. SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF

    DOE Patents [OSTI]

    Magnusson, L.B.

    1958-04-01

    A process is described for the separation of neptunium, from aqueous solutions of neptunium, plutonium, uraniunn, and fission prcducts. This separation from an acidic aqueous solution of a tetravalent neptuniunn can be made by contacting the solution with a certain type of chelating,; agent, preferably dissolved in an organic solvent, to form a neptunium chelate compound. When the organic solvent is present, the neptunium chelate compound is extracted; otherwise, it precipitates from the aqueous solution and is separated by any suitable means. The chelating agent is a fluorinated BETA -diketone. such as trifluoroacetyl acetone.

  4. Porotomo Subtask 3.9 Build FEM Configuration

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Tabrez Ali

    mesh.vtk: Self contained VTK file that contains mesh information and can be directly visualized in Paraview/Visit mesh.png: Image of mesh as visualized in Paraview nodes.csv: Nodal coordinates of the mesh in UTM coordinates (m). nodes_rotated.csv: Nodal coordinates of the mesh in rotated (X/Y/Z) coordinates (m). cells.csv: Connectivity data query_points.csv: List of points (centroid of cells) that will be used to query the geologic database

  5. LANL Contacts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab Contacts Lab Contacts Addresses and phone numbers for general information, journalistic queries, business needs, community programs and employee resources. General Employee directory Emergency communication Communications Office (505) 667-7000 Ethics & Audits Internal Audit: (505) 665-3104 Ethics Office: (505) 667-7506 Fax: (505) 665-3664 ethics@lanl.gov Journalist queries Communications Office (505) 667-7000 Media contacts Lab mailing address Los Alamos National Laboratory P.O. Box 1663

  6. Buildings Energy Data Book

    Buildings Energy Data Book [EERE]

    Explore Survey Data from the Energy Information Administration Follow the links below to two easy-to-use query tools, developed exclusively for this website. With these tools you can explore results from the Commercial Buildings Energy Consumption Survey (CBECS) and the Residential Energy Consumption Survey (RECS). Commercial Buildings Energy Index Use this custom query tool to analyze micro data from CBECS 2003. Residential Buildings Energy Index Use this custom Microsoft Excel pivot table to

  7. Geometric Algorithms for Modeling, Motion, and Animation (GAMMA): Collision Detection Videos from the University of North Carolina GAMMA Research Group

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Physically based modeling simulations depend highly on the physical interaction between objects in a scene. Complex physics engines require fast, accurate, and robust proximity queries to maintain a realistic simulation at interactive rates. We couple our proximity query research with physically based modeling to ensure that our packages provide the capabilities of today's physics engines.[Copied from http://www.cs.unc.edu/~geom/collide/index.shtml

  8. Department of Energy (DOE) OpenNet documents

    Office of Scientific and Technical Information (OSTI)

    Help The Search Help section provides assistance in the following areas: Search features Field definitions Query examples Adjacency This database allows you to search for exact character strings or phrases. This is known as a literal search and provides the same functionality as an adjacency operator. To search, use double quotes around the phrase entered in the query box. For example, using the Basic Search on the Home Page, or the Full-Text and field on the Advanced Search page, enter:

  9. Porotomo Subtask 3.9 Build FEM Configuration

    SciTech Connect (OSTI)

    Tabrez Ali

    2015-06-30

    mesh.vtk: Self contained VTK file that contains mesh information and can be directly visualized in Paraview/Visit mesh.png: Image of mesh as visualized in Paraview nodes.csv: Nodal coordinates of the mesh in UTM coordinates (m). nodes_rotated.csv: Nodal coordinates of the mesh in rotated (X/Y/Z) coordinates (m). cells.csv: Connectivity data query_points.csv: List of points (centroid of cells) that will be used to query the geologic database

  10. Volatilization of organotin compounds from estuarine and coastal environments

    SciTech Connect (OSTI)

    Amouroux, D.; Tessier, E.; Donard, O.F.X.

    2000-03-15

    The occurrence and speciation of volatile tin compounds (Sn) have been investigated in a contaminated area of the Arcachon Bay (SW France) and in the water column of the Scheldt (Belgium/Netherlands) and Gironde (SW France) estuaries. This paper describes the application of a multi-isotope analytical method, using gas chromatography and inductively coupled plasma-mass spectrometry. Analytes were collected by cryogenic trapping of the gaseous species. This trapping has allowed the authors to probe volatile tin compounds by detecting both {sup 118}Sn and {sup 120}Sn isotopes. Volatile organic tin compounds have been determined in both sediment and water. They could result from both natural methylation and hybridization processes of inorganic tin and from anthropogenic butyltin derivatives released from ship antifouling paintings which have accumulated in sediments. The most ubiquitous species were found to be the methylated forms of butyltin derivatives. These results suggest that biological and/or chemical methylation mechanisms are likely to occur in sediments and to lead to remobilization of tin species into the water column and subsequently to the atmosphere. Finally, sediment-water and water-atmosphere fluxes have been calculated to assess the potential impact of these processes on the fate of organotin compounds in coastal environments.

  11. Polymerizable 2(2-hydroxynaphthyl)2H-benzotriazole compounds

    DOE Patents [OSTI]

    Gomez, P.M.; Neidlinger, H.H.

    1991-07-16

    Benzotriazole compounds having the formula: ##STR1## wherein R.sub.1 is H, Cl, or OCH.sub.3 ; R.sub.2 is a hydroxynaphthyl group; and R.sub.3 is a vinyl unsaturated polymerizable group. Homopolymers or copolymers thereof are effective as UV light stabilizers and absorbers.

  12. Thermoelectric materials ternary penta telluride and selenide compounds

    DOE Patents [OSTI]

    Sharp, Jeffrey W.

    2001-01-01

    Ternary tellurium compounds and ternary selenium compounds may be used in fabricating thermoelectric devices with a thermoelectric figure of merit (ZT) of 1.5 or greater. Examples of such compounds include Tl.sub.2 SnTe.sub.5, Tl.sub.2 GeTe.sub.5, K.sub.2 SnTe.sub.5 and Rb.sub.2 SnTe.sub.5. These compounds have similar types of crystal lattice structures which include a first substructure with a (Sn, Ge) Te.sub.5 composition and a second substructure with chains of selected cation atoms. The second substructure includes selected cation atoms which interact with selected anion atoms to maintain a desired separation between the chains of the first substructure. The cation atoms which maintain the desired separation between the chains occupy relatively large electropositive sites in the resulting crystal lattice structure which results in a relatively low value for the lattice component of thermal conductivity (.kappa..sub.g). The first substructure of anion chains indicates significant anisotropy in the thermoelectric characteristics of the resulting semiconductor materials.

  13. Thermoelectric materials: ternary penta telluride and selenide compounds

    DOE Patents [OSTI]

    Sharp, Jeffrey W.

    2002-06-04

    Ternary tellurium compounds and ternary selenium compounds may be used in fabricating thermoelectric devices with a thermoelectric figure of merit (ZT) of 1.5 or greater. Examples of such compounds include Tl.sub.2 SnTe.sub.5, Tl.sub.2 GeTe.sub.5, K.sub.2 SnTe.sub.5 and Rb.sub.2 SnTe.sub.5. These compounds have similar types of crystal lattice structures which include a first substructure with a (Sn, Ge) Te.sub.5 composition and a second substructure with chains of selected cation atoms. The second substructure includes selected cation atoms which interact with selected anion atoms to maintain a desired separation between the chains of the first substructure. The cation atoms which maintain the desired separation between the chains occupy relatively large electropositive sites in the resulting crystal lattice structure which results in a relatively low value for the lattice component of thermal conductivity (.kappa..sub.g). The first substructure of anion chains indicates significant anisotropy in the thermoelectric characteristics of the resulting semiconductor materials.

  14. Method and apparatus for measuring properties of a compound

    DOE Patents [OSTI]

    Meng, Ling Jian

    2013-10-22

    A system that incorporates teachings of the present disclosure may include, for example, an apparatus having a collimator having at least one aperture and a fluorescence detector. The collimator can be positioned next to a compound. The compound can emit fluorescence X-rays when impacted by an X-ray beam generated by an X-ray source. The collimator can absorb at least a first portion of the fluorescence X-rays emitted by the compound and release at least a second portion of the fluorescence X-rays at the at least one aperture. The second portion of the fluorescence X-rays released by the at least one aperture have known directional information based on a position of the collimator. The fluorescence detector can detect the second portion of the fluorescence X-rays released by the at least one aperture. A three-dimensional (3-D) rendering of an elemental distribution of the compound can be determined from the fluorescence X-rays detected and the directional information. Additional embodiments are disclosed.

  15. Preparation and synthetic application of {alpha}-phenylthioethylsamarium compound

    SciTech Connect (OSTI)

    Kasuga, Y.; Matsubara, S.; Utimoto, K. [Kyoto Univ. (Japan)

    1995-12-31

    Although samarium(II) iodide-mediated reaction of organohalides with carbonyl compounds has been applied to various organic syntheses, intermediary organosamarium species could be detected only when HMPA exists in the reaction system. The authors now report the detection of {alpha}-phenylthioethylsamarium compound in the absence of HMPA and application to diastereoselective reaction with aldehydes. A treatment of the organosamarium reagent, prepared from 1-chloroethyl phenyl sulfide and samarium(II) iodide, with D{sub 2}O afforded 1-deuterioethyl phenyl sulfide in 53% yield (82% D). The reagent reacted with aldehyde containing a stereogenic center at {alpha}-position to give {beta}-hydroxysulfide with high diastereoselectivity. Reaction using Barbier type procedure afforded the same results. These results suggest that {alpha}-phenylthioethylsamarium species is also generated in the Barbier type reaction. Configurational stability of {alpha}-thiosubstituted alkylmetal compounds seems to depend on the applied metal. Hoffmann Test indicated that the configuration of {alpha}-phenylthloethylsamarium compound is unchanged during the reaction with aldehyde, while that of {alpha}-alkylthioalkyllithium is unstable.

  16. RADIOLYSIS OF ORGANIC COMPOUNDS IN THE ADSORBED STATE

    DOE Patents [OSTI]

    Sutherland, J.W.; Allen, A.O.

    1961-10-01

    >A method of forming branch chained hydrocarbons by means of energetic penetrating radiation is described. A solid zeolite substrate is admixed with a cobalt ion and is irradiated with a hydrocarbon adsorbed therein. Upon irradiation with gamma rays, there is an increased yield of branched and lower molecular straight chain compounds. (AEC)

  17. Polymerizable 2(2-hydroxynaphthyl)2H-benzotriazole compounds

    DOE Patents [OSTI]

    Gomez, Peter M.; Neidlinger, Hermann H.

    1991-01-01

    Benzotriazole compounds having the formula: ##STR1## wherein R.sub.1 is H, Cl, or OCH.sub.3 ; R.sub.2 is a hydroxynaphthyl group; and R.sub.3 is a vinyl unsaturated polymerizable group. Homopolymers or copolymers thereof are effective as UV light stabilizers and absorbers.

  18. Biodegradation and Biotransformation of Mixed Wastes Containing Metals and Chlorinated Xenobiotic Compounds By Microbial

    SciTech Connect (OSTI)

    Crqwford, D. L.; Kamashwaran, S. R.

    2001-07-01

    OAK 270 - Biodegradation and biotransformation of mixed Wastes Containing metals and chlorinated Xenobiotic compounds by microbial.

  19. Quantitative method of determining beryllium or a compound thereof in a sample

    DOE Patents [OSTI]

    McCleskey, T. Mark; Ehler, Deborah S.; John, Kevin D.; Burrell, Anthony K.; Collis, Gavin E.; Minogue, Edel M.; Warner, Benjamin P.

    2006-10-31

    A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.

  20. Quantitative method of determining beryllium or a compound thereof in a sample

    DOE Patents [OSTI]

    McCleskey, T. Mark; Ehler, Deborah S.; John, Kevin D.; Burrell, Anthony K.; Collis, Gavin E.; Minogue, Edel M.; Warner, Benjamin P.

    2010-08-24

    A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.

  1. Fate of hazardous waste derived organic compounds in Lake Ontario

    SciTech Connect (OSTI)

    Jaffe, R.; Hites, R.A.

    1986-03-01

    Dated sediment cores from Lake Ontario's four sedimentation basins and sedentary fish from tributaries and embayments were analyzed by gas chromatographic, methane-enhanced, negative ion mass spectrometry for a group of fluorinated aromatic compounds. The historical record of these chemicals in Lake Ontario sediments agrees well with the use of the Hyde Park dump in the city of Niagara Falls, NY. These compounds first appeared in sediments in 1958 and rapidly increased until 1970. These dates coincide with the onset of dumping at Hyde Park and remedial action undertaken when this dump was closed, respectively. Chemicals introduced into Lake Ontario by the Niagara River distribute throughout the lake rapidly and uniformly and accumulate in sedentary fish taken from remote locations in the lake. 24 references, 9 figures, 4 tables.

  2. Method for production of an isotopically enriched compound

    DOE Patents [OSTI]

    Watrous, Matthew G.

    2012-12-11

    A method is presented for producing and isolating an isotopically enriched compound of a desired isotope from a parent radionuclide. The method includes forming, or placing, a precipitate containing a parent radionuclide of the desired daughter isotope in a first reaction zone and allowing sufficient time for the parent to decay into the desired gaseous daughter radioisotope. The method further contemplates collecting the desired daughter isotope as a solid in a second reaction zone through the application of temperatures below the freezing point of the desired isotope to a second reaction zone that is connected to the first reaction zone. Specifically, a method is presented for producing isotopically enriched compounds of xenon, including the radioactive isotope Xe-131m and the stable isotope Xe-131.

  3. Method of plasma etching Ga-based compound semiconductors

    SciTech Connect (OSTI)

    Qiu, Weibin; Goddard, Lynford L.

    2012-12-25

    A method of plasma etching Ga-based compound semiconductors includes providing a process chamber and a source electrode adjacent to the process chamber. The process chamber contains a sample comprising a Ga-based compound semiconductor. The sample is in contact with a platen which is electrically connected to a first power supply, and the source electrode is electrically connected to a second power supply. The method includes flowing SiCl.sub.4 gas into the chamber, flowing Ar gas into the chamber, and flowing H.sub.2 gas into the chamber. RF power is supplied independently to the source electrode and the platen. A plasma is generated based on the gases in the process chamber, and regions of a surface of the sample adjacent to one or more masked portions of the surface are etched to create a substantially smooth etched surface including features having substantially vertical walls beneath the masked portions.

  4. Structural investigation of a new antimicrobial thiazolidine compound

    SciTech Connect (OSTI)

    Cozar, I. B.; Pîrnău, A.; Vedeanu, N.; Nastasă, C.

    2013-11-13

    Thiazoles and their derivatives have attracted the interest over the last decades because of their varied biological activities: antibacterial, antiviral, antifungal, inflammation or in the treatment of allergies. A new synthesized compound 3-[2-(4-Methyl-2-phenyl-thiazol-5-yl)-2-oxo-ethyl]-thazolidine-2,4-dione was investigated by FT-IR, FT-Raman, {sup 1}H, {sup 13}C NMR spectroscopies and also by DFT calculations at B3LYP/6-31G(d) level of theory. The very good correlation found between the experimental and theoretical data shows that the optimized molecular structure is very close to reality. Also the NMR spectra show a monomeric behaviour of this compound in solutions.

  5. Method of plasma etching GA-based compound semiconductors

    DOE Patents [OSTI]

    Qiu, Weibin; Goddard, Lynford L.

    2013-01-01

    A method of plasma etching Ga-based compound semiconductors includes providing a process chamber and a source electrode adjacent thereto. The chamber contains a Ga-based compound semiconductor sample in contact with a platen which is electrically connected to a first power supply, and the source electrode is electrically connected to a second power supply. SiCl.sub.4 and Ar gases are flowed into the chamber. RF power is supplied to the platen at a first power level, and RF power is supplied to the source electrode. A plasma is generated. Then, RF power is supplied to the platen at a second power level lower than the first power level and no greater than about 30 W. Regions of a surface of the sample adjacent to one or more masked portions of the surface are etched at a rate of no more than about 25 nm/min to create a substantially smooth etched surface.

  6. Amination of electrophilic aromatic compounds by vicarious nucleophilic substitution

    DOE Patents [OSTI]

    Mitchell, Alexander R.; Pagoria, Philip F.; Schmidt, Robert D.

    2000-01-01

    The present invention relates to a process to aminate electrophilic aromatic compounds by vicarious nucleophilic substitution of hydrogen using quaternary hydrazinium salts. The use of trialkylhydrazinium halide, e.g., trimethylhydrazinium iodide, as well as hydroxylamine, alkoxylamines, and 4-amino-1,2,4-triazole to produce aminated aromatic structures, such as 1,3-diamino-2,4,6-trinitrobenzene (DATB), 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) and 3,5-diamino-2,4,6-trinitrotoluene (DATNT), is described. DATB and TATB are useful insensitive high explosives. TATB is also used for the preparation of benzenehexamine, a starting material for the synthesis of novel materials (optical imaging devices, liquid crystals, ferromagnetic compounds).

  7. Method of recovering adsorbed liquid compounds from molecular sieve columns

    DOE Patents [OSTI]

    Burkholder, H.R.; Fanslow, G.E.

    1983-12-20

    Molecularly adsorbed volatile liquid compounds are recovered from molecular sieve adsorbent columns by directionally applying microwave energy to the bed of the adsorbent to produce a mixed liquid-gas effluent. The gas portion of the effluent generates pressure within the bed to promote the discharge of the effluent from the column bottoms. Preferably the discharged liquid-gas effluent is collected in two to three separate fractions, the second or intermediate fraction having a substantially higher concentration of the desorbed compound than the first or third fractions. The desorption does not need to be assisted by passing a carrier gas through the bed or by applying reduced pressure to the outlet from the bed. 8 figs.

  8. Identification of a potential superhard compound ReCN

    SciTech Connect (OSTI)

    Fan, Xiaofeng; Li, M. M.; Singh, David J.; Jiang, Qing; Zheng, W. T.

    2015-01-24

    Here, we identify a new ternary compound, ReCN and characterize its properties including structural stability and indicators of hardness using first principles calculations. Furthermore, we find that there are two stable structures with space groups P63mc (HI) and P3m1 (HII), in which there are no C–C and N–N bonds. Both structures, H1 and III are elastically and dynamically stable. The electronic structures show that ReCN is a semiconductor, although the parent compounds, ReC2 and ReN2 are both metallic. ReCN is found to possess the outstanding mechanical properties with the large bulk modulus, shear modulus and excellent ideal strengths. Additionally, ReCN may perhaps be synthesized relatively easily because it becomes thermodynamic stable with respect to decomposition at very low pressures.

  9. Identification of a potential superhard compound ReCN

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fan, Xiaofeng; Li, M. M.; Singh, David J.; Jiang, Qing; Zheng, W. T.

    2015-01-24

    Here, we identify a new ternary compound, ReCN and characterize its properties including structural stability and indicators of hardness using first principles calculations. Furthermore, we find that there are two stable structures with space groups P63mc (HI) and P3m1 (HII), in which there are no C–C and N–N bonds. Both structures, H1 and III are elastically and dynamically stable. The electronic structures show that ReCN is a semiconductor, although the parent compounds, ReC2 and ReN2 are both metallic. ReCN is found to possess the outstanding mechanical properties with the large bulk modulus, shear modulus and excellent ideal strengths. Additionally, ReCNmore » may perhaps be synthesized relatively easily because it becomes thermodynamic stable with respect to decomposition at very low pressures.« less

  10. Method of recovering adsorbed liquid compounds from molecular sieve columns

    DOE Patents [OSTI]

    Burkholder, Harvey R.; Fanslow, Glenn E.

    1983-01-01

    Molecularly adsorbed volatile liquid compounds are recovered from molecular sieve adsorbent columns by directionally applying microwave energy to the bed of the adsorbent to produce a mixed liquid-gas effluent. The gas portion of the effluent generates pressure within the bed to promote the discharge of the effluent from the column bottoms. Preferably the discharged liquid-gas effluent is collected in two to three separate fractions, the second or intermediate fraction having a substantially higher concentration of the desorbed compound than the first or third fractions. The desorption does not need to be assisted by passing a carrier gas through the bed or by applying reduced pressure to the outlet from the bed.

  11. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  12. Conversion of radioactive ferrocyanide compounds to immobile glasses

    DOE Patents [OSTI]

    Schulz, Wallace W.; Dressen, A. Louise

    1977-04-26

    Complex radioactive ferrocyanide compounds result from the scavenging of cesium from waste products produced in the chemical reprocessing of nuclear fuel. These ferrocyanides, in accordance with this process, are converted to an immobile glass, resistant to leaching by water, by fusion together with sodium carbonate and a mixture of (a) basalt and boron trioxide (B.sub.2 O.sub.3) or (b) silica (SiO.sub.2) and lime (CaO).

  13. Process for production of an aluminum hydride compound

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Miller, Dean Michael; Molzahn, David Craig

    2013-08-06

    A compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl substituted by at least one of: (i) an alkoxy group having from one to six carbon atoms; and (ii) an alkyl group having from three to twelve carbon atoms; wherein M is an alkali metal, Be or Mg; and y is one or two.

  14. Misfit layer compounds and ferecrystals: Model systems for thermoelectric nanocomposites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Merrill, Devin R.; Moore, Daniel B.; Bauers, Sage R.; Falmbigl, Matthias; Johnson, David C.

    2015-04-22

    A basic summary of thermoelectric principles is presented in a historical context, following the evolution of the field from initial discovery to modern day high-zT materials. A specific focus is placed on nanocomposite materials as a means to solve the challenges presented by the contradictory material requirements necessary for efficient thermal energy harvest. Misfit layer compounds are highlighted as an example of a highly ordered anisotropic nanocomposite system. Their layered structure provides the opportunity to use multiple constituents for improved thermoelectric performance, through both enhanced phonon scattering at interfaces and through electronic interactions between the constituents. Recently, a class ofmore » metastable, turbostratically-disordered misfit layer compounds has been synthesized using a kinetically controlled approach with low reaction temperatures. The kinetically stabilized structures can be prepared with a variety of constituent ratios and layering schemes, providing an avenue to systematically understand structure-function relationships not possible in the thermodynamic compounds. We summarize the work that has been done to date on these materials. The observed turbostratic disorder has been shown to result in extremely low cross plane thermal conductivity and in plane thermal conductivities that are also very small, suggesting the structural motif could be attractive as thermoelectric materials if the power factor could be improved. The first 10 compounds in the [(PbSe)1+δ]m(TiSe₂)n family (m, n ≤ 3) are reported as a case study. As n increases, the magnitude of the Seebeck coefficient is significantly increased without a simultaneous decrease in the in-plane electrical conductivity, resulting in an improved thermoelectric power factor.« less

  15. Structural and Electronic Investigations of Complex Intermetallic Compounds

    SciTech Connect (OSTI)

    Hyunjin Ko

    2008-08-18

    In solid state chemistry, numerous investigations have been attempted to address the relationships between chemical structure and physical properties. Such questions include: (1) How can we understand the driving forces of the atomic arrangements in complex solids that exhibit interesting chemical and physical properties? (2) How do different elements distribute themselves in a solid-state structure? (3) Can we develop a chemical understanding to predict the effects of valence electron concentration on the structures and magnetic ordering of systems by both experimental and theoretical means? Although these issues are relevant to various compound classes, intermetallic compounds are especially interesting and well suited for a joint experimental and theoretical effort. For intermetallic compounds, the questions listed above are difficult to answer since many of the constituent atoms simply do not crystallize in the same manner as in their separate, elemental structures. Also, theoretical studies suggest that the energy differences between various structural alternatives are small. For example, Al and Ga both belong in the same group on the Periodic Table of Elements and share many similar chemical properties. Al crystallizes in the fcc lattice with 4 atoms per unit cell and Ga crystallizes in an orthorhombic unit cell lattice with 8 atoms per unit cell, which are both fairly simple structures (Figure 1). However, when combined with Mn, which itself has a very complex cubic crystal structure with 58 atoms per unit cell, the resulting intermetallic compounds crystallize in a completely different fashion. At the 1:1 stoichiometry, MnAl forms a very simple tetragonal lattice with two atoms per primitive unit cell, while MnGa crystallizes in a complicated rhombohedral unit cell with 26 atoms within the primitive unit cell. The mechanisms influencing the arrangements of atoms in numerous crystal structures have been studied theoretically by calculating electronic

  16. Incorporation of Catalytic Compounds in the Porosity of SiC Wall...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples Incorporation of Catalytic Compounds in the Porosity ...

  17. Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration

    SciTech Connect (OSTI)

    Farha, Omar K.; Hupp, Joseph T.

    2012-09-11

    Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

  18. Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration

    SciTech Connect (OSTI)

    Farha, Omar K; Hupp, Joseph T

    2013-06-25

    Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

  19. Methods of producing sulfate salts of cations from heteroatomic compounds and dialkyl sulfates and uses thereof

    DOE Patents [OSTI]

    Friesen, Cody A.; Wolfe, Derek; Johnson, Paul Bryan

    2015-09-29

    Methods of preparing sulfate salts of heteroatomic compounds using dialkyl sulfates as a primary reactant are disclosed. Also disclosed are methods of making ionic liquids from the sulfate salts of the heteroatomic compound, and electrochemical cells comprising the ionic liquids.

  20. Branched peptide amphiphiles, related epitope compounds and self assembled structures thereof

    DOE Patents [OSTI]

    Stupp, Samuel I.; Guler, Mustafa O.

    2008-11-18

    Branched peptide amphiphilic compounds incorporating one or residues providing a pendant amino group for coupling one or more epitope sequences thereto, such compounds and related compositions for enhanced epitope presentation.

  1. Magnetic properties of Er1-xDyxAl2 (0 ≤ x ≤ 1) compounds...

    Office of Scientific and Technical Information (OSTI)

    Er1-xDyxAl2 (0 x 1) compounds in low applied fields Citation Details In-Document Search Title: Magnetic properties of Er1-xDyxAl2 (0 x 1) compounds in low applied ...

  2. Spin-Glass Behavior in a Giant Unit Cell Compound Tb117Fe52Ge113...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Spin-Glass Behavior in a Giant Unit Cell Compound Tb117Fe52Ge113.8(1) Citation Details In-Document Search Title: Spin-Glass Behavior in a Giant Unit Cell Compound ...

  3. Spin-Glass Behavior in a Giant Unit Cell Compound Tb117Fe52Ge113...

    Office of Scientific and Technical Information (OSTI)

    Spin-Glass Behavior in a Giant Unit Cell Compound Tb117Fe52Ge113.8(1) Citation Details In-Document Search Title: Spin-Glass Behavior in a Giant Unit Cell Compound ...

  4. Reactive codoping of GaAlInP compound semiconductors (Patent...

    Office of Scientific and Technical Information (OSTI)

    This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and ... A GaAlInP compound semiconductor and a method of producing a GaAlInP compound ...

  5. Hydroxymethyl phosphine compounds for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, Kattesh V.; Karra, Srinivasa Rao; Berning, Douglas E.; Smith, C. Jeffrey; Volkert, Wynn A.; Ketring, Alan R.

    2000-01-01

    A compound and method of making a compound for use as a diagnostic or therapeutic pharmaceutical comprises at least one functionalized hydroxyalkyl phosphine donor group and one or more sulfur or nitrogen donor and a metal combined with the ligand.

  6. Hydroxymethyl phosphine compounds for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, Kattesh V.; Karra, Srinivasa Rao; Berning, Douglas E.; Smith, C. Jeffrey; Volkert, Wynn A.; Ketring, Alan R.

    1999-01-01

    A compound and method of making a compound for use as a diagnostic or therapeutic pharmaceutical comprises at least one functionalized hydroxyalkyl phosphine donor group and one or more sulfur or nitrogen donor and a metal combined with the ligand.

  7. 1-/sup 11/C-D-glucose and related compounds

    SciTech Connect (OSTI)

    Shiue, C.Y.; Wolf, A.P.

    1982-01-26

    The novel compounds 1-/sup 11/C-D-glucose, 1-/sup 11/C-D-mannose, 1-/sup 11/C-D-galactose, 2-/sup 11/C-D-glucose, 2-/sup 11/C-D-mannose and 2-/sup 11/C-D-galactose which can be used in nuclear medicine to monitor the metabolism of glucose and galactose can be rapidly prepared by reaction of the appropriate aldose substrate with an alkali metal /sup 11/C-labeled cyanide followed by reduction with a Raney alloy in formic acid.

  8. Low temperature properties of some Er-rich intermetallic compounds

    SciTech Connect (OSTI)

    K.A. Gshneidner,jr; A.O. Pecharsky; L.Hale; V.K. Pecharsky

    2004-09-30

    The low temperature volumetric heat capacity ({approx}3.5 to 350 K) and magnetic susceptibility ({approx}4 to 320 K) of Er{sub 3}Rh, Er{sub 3}Ir, Er{sub 3}Pt, Er{sub 2}Al, and Er{sub 2}Sn have been measured. All of the compounds order antiferromagnetically (or ferrimagnetically), and most exhibit more than one magnetic ordering transition. The volumetric heat capacities in general are smaller than those of the prototype magnetic regenerator materials, except for Er{sub 3}Ir in the 12 to 14 K temperature range.

  9. Electrolytic photodissociation of chemical compounds by iron oxide photochemical diodes

    DOE Patents [OSTI]

    Somorjai, Gabor A.; Leygraf, Christofer H.

    1985-01-01

    Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor photochemical diode having visible light as its sole source of energy. The photochemical diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

  10. 1-.sup.11 C-D-Glucose and related compounds

    DOE Patents [OSTI]

    Shiue, Chyng-Yann; Wolf, Alfred P.

    1984-03-27

    The novel compounds 1-.sup.11 C-D-glucose, 1-.sup.11 C-D-mannose, 1-.sup.11 C-D-galactose, 2-.sup.11 C-D-glucose, 2-.sup.11 C-D-mannose and 2-.sup.11 C-D-galactose which can be used in nuclear medicine to monitor the metabolism of glucose and galactose can be rapidly prepared by reaction of the appropriate aldose substrate with an alkali metal .sup.11 C-labeled cyanide followed by reduction with a Raney alloy in formic acid.

  11. The integrated compound parabolic concentrator: From development to demonstration

    SciTech Connect (OSTI)

    Winston, R.; O`Gallagher, J.J.; Duff, W.S.; Cavallaro, A.

    1997-12-31

    The authors describe the fabrication, testing and application of the Integrated Compound Parabolic Concentrator (ICPC) to solar cooling. The cooling technology is a double effect absorption cycle chiller operating at 165 C. The design parameters are optimized for this temperature range. The optical and mechanical design of the solar collector is chosen for compatibility with mass production. A project to employ approximately 350 of these collector tubes to drive a 20 ton commercial double effect chiller on an office building in Sacramento, CA has started. The authors expect the system to be operational this year.

  12. Prediction of New Hydrogen Storage Compounds and Mixtures

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8, 2006 DOE Theory Focus Session on Hydrogen Storage Materials Prediction of New Hydrogen Storage Compounds and Mixtures Vidvuds Ozoliņš UCLA Research supported by DOE grants No. DE-FG02-05ER46253 and DE-FC36-04GO14013 May 18, 2006 DOE Theory Focus Session on Hydrogen Storage Materials DOE BES: Theory and Modeling of Materials for Hydrogen Storage PIs: Gerbrand Ceder (MIT), Nicola Marzari (MIT), Vidvuds Ozoliņš (UCLA) Discovery of Novel Complex Metal Hydrides for Hydrogen Storage Through

  13. Process for removing an organic compound from water

    DOE Patents [OSTI]

    Baker, Richard W.; Kaschemekat, Jurgen; Wijmans, Johannes G.; Kamaruddin, Henky D.

    1993-12-28

    A process for removing organic compounds from water is disclosed. The process involves gas stripping followed by membrane separation treatment of the stripping gas. The stripping step can be carried out using one or multiple gas strippers and using air or any other gas as stripping gas. The membrane separation step can be carried out using a single-stage membrane unit or a multistage unit. Apparatus for carrying out the process is also disclosed. The process is particularly suited for treatment of contaminated groundwater or industrial wastewater.

  14. Complex-compound low-temperature TES system

    SciTech Connect (OSTI)

    Rockenfeller, U.

    1989-03-01

    Development of a complex-compound low-temperature TES system is described herein from basic chemical principles through current bench scale system development. Important application engineering issues and an economic outlook are addressed as well. The system described uses adsorption reactions between solid metal inorganic salts and ammonia refrigerant. It is the coordinative nature of these reactions that allows for storage of ammonia refrigerant within the solid salt crystals that function as a chemical compressor during on peak periods (substituting the mechanical compressor) and release ammonia during off peak periods while a mechanical vapor compression system provides the necessary reactor pressure and heat.

  15. Statistical methods of spin assignment in compound nuclear reactions

    SciTech Connect (OSTI)

    Mach, H.; Johns, M.W.

    1985-01-15

    Spin assignment to nuclear levels can be obtained from standard in-beam gamma-ray spectroscopy techniques and in the case of compound nuclear reactions can be complemented by statistical methods. These are based on a correlation pattern between level spin and gamma-ray intensities feeding low-lying levels. Three types of intensity and level spin correlations are found suitable for spin assignment: shapes of the excitation functions, ratio of intensity at two beam energies or populated in two different reactions, and feeding distributions. Various empirical attempts are examined and the range of applicability of these methods as well as the limitations associated with them are given.

  16. SEPARATION PROCESS FOR TRANSURANIC ELEMENT AND COMPOUNDS THEREOF

    DOE Patents [OSTI]

    Calvin, M.

    1958-10-14

    S> A process is presented for the separation of pluto nium from uranium and fission products in an aqueous acidic solution by use of a chelating agent. The plutonium is maintained in the tetravalent state and the uranium in the hexavalent state, and the acidic concentration is adjusted to about 1 N bar. The aqueous solution is then contacted with a water-immiscible organic solvent solution and the chelating agent. The chelating agents covered by this invention comprise a group of compounds characterized as fluorinated beta-diketones.

  17. Turbo Compounding: A Technology Whose Time Has Come | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turbo Compounding: A Technology Whose Time Has Come Turbo Compounding: A Technology Whose Time Has Come 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_vuk.pdf (977.84 KB) More Documents & Publications Electric Turbo Compounding Technology Update Electric Turbo Compounding...A Technology Who's Time Has Come Design and Development of e-Turbo for SUV and Light Truck Applications

  18. Organic solid state switches incorporating porphyrin compounds and method for producing organic solid state optical switches

    DOE Patents [OSTI]

    Wasielewski, M.R.; Gaines, G.L.; Niemczyk, M.P.; Johnson, D.G.; Gosztola, D.J.; O`Neil, M.P.

    1996-07-23

    A light-intensity dependent molecular switch comprised of a compound which shuttles an electron or a plurality of electrons from a plurality of electron donors to an electron acceptor upon being stimulated with light of predetermined wavelengths, said donors selected from porphyrins and other compounds, and a method for making said compound are disclosed. 4 figs.

  19. Organic solid state switches incorporating porphyrin compounds and method for producing organic solid state optical switches

    DOE Patents [OSTI]

    Wasielewski, Michael R.; Gaines, George L.; Niemczyk, Mark P.; Johnson, Douglas G.; Gosztola, David J.; O'Neil, Michael P.

    1996-01-01

    A light-intensity dependent molecular switch comprised of a compound which shuttles an electron or a plurality of electrons from a plurality of electron donors to an electron acceptor upon being stimulated with light of predetermined wavelengths, said donors selected from porphyrins and other compounds, and a method for making said compound.

  20. Gas chromatograph-mass spectrometer (GC/MS) system for quantitative analysis of reactive chemical compounds

    DOE Patents [OSTI]

    Grindstaff, Quirinus G.

    1992-01-01

    Described is a new gas chromatograph-mass spectrometer (GC/MS) system and method for quantitative analysis of reactive chemical compounds. All components of such a GC/MS system external to the oven of the gas chromatograph are programmably temperature controlled to operate at a volatilization temperature specific to the compound(s) sought to be separated and measured.

  1. Method of coating a substrate with a calcium phosphate compound

    DOE Patents [OSTI]

    Gao, Yufei; Campbell, Allison A.

    2000-01-01

    The present invention is a method of coating a substrate with a calcium phosphate compound using plasma enhanced MOCVD. The substrate is a solid material that may be porous or non-porous, including but not limited to metal, ceramic, glass and combinations thereof. The coated substrate is preferably used as an implant, including but not limited to orthopaedic, dental and combinations thereof. Calcium phosphate compound includes but is not limited to tricalcium phosphate (TCP), hydroxyapatite (HA) and combinations thereof. TCP is preferred on a titanium implant when implant resorbability is desired. HA is preferred when the bone bonding of new bone tissue into the structure of the implant is desired. Either or both of TCP and/or HA coated implants may be placed into a solution with an agent selected from the group of protein, antibiotic, antimicrobial, growth factor and combinations thereof that can be adsorbed into the coating before implantation. Once implanted, the release of TCP will also release the agent to improve growth of new bone tissues and/or to prevent infection.

  2. Evaluation of rice husk ash as filler in tread compounds

    SciTech Connect (OSTI)

    Fernandes, M. R. S.; Furtado, C. R. G. E-mail: ana.furtado.sousa@gmail.com; Sousa, A. M. F. de E-mail: ana.furtado.sousa@gmail.com

    2014-05-15

    Rice which is one of the largest agriculture crops produces around 22% of rice rusk during its milling process. This material is mainly used as fuel for energy generation, which results in an ash, which disposal represents an environmental issue. The rice husk ash (RHA) contains over than 70% of silica in an amorphous form and a lot of applications is being developed for it all over the world. The use of silica as a filler in the tire industry is growing since it contributes significantly to the reduction of fuel consumption of the automobiles, allowing at the same time better traction (safety). This paper presents an evaluation of the use of RHA as filler in rubber tread compounds prepared in lab scale and compares its performance with compounds prepared with commercial silica and carbon black, the fillers normally used in tire industry. Mechanical and rheological properties are evaluated, with emphasis for tan delta as an indicator of tread performance related with rolling resistance (fuel consumption) and wet grip/traction (safety)

  3. Magneto-optic properties of uranium-based compounds

    SciTech Connect (OSTI)

    Kirby, R.D.; Shen, J.X.; Woollam, J.A.; Sellmyer, D.J. )

    1991-04-15

    Uranium-based compounds often show interesting magnetic properties and large polar Kerr rotations. Because of this, the wavelength and temperature dependencies of the polar Kerr rotation in several uranium-based compounds, including UMn{sub 2}Ge{sub 2}, UFe{sub 2}, and UGa{sub 2}, have been investigated. The Mn moments order ferromagnetically in UMn{sub 2}Ge{sub 2} below 380 K, and while the U moments do not order ferromagnetically until the temperature is below 150 K. The measurements presented here show that the size of the Kerr rotation increases from 0.05{degree} at room temperature to 0.15{degree} when the U moments are ordered. The wavelength dependence of the Kerr rotation between 500 and 1000 nm is rather weak. UGa{sub 2} orders ferromagnetically at 130 K, and a Kerr rotation of 0.2{degree} at 85 K and 632.8 nm can be measured, with the rotation increasing to 0.4{degree} at 1000 nm. UFe{sub 2} orders ferromagnetically at 180 K, and the Kerr rotation (85 K, 632.8 nm) is 0.17{degree}. These magnetic and optical properties are discussed in terms of the electronic states of uranium.

  4. Hexagonal phase transformation in the engineered scavenger compound lithium titanate

    SciTech Connect (OSTI)

    Collins, W.K.; Riley, W.D.; Jong, B.W.

    1993-01-01

    Engineered scavenger compounds (ESC's) developed by the US Bureau of Mines are a novel class of compounds that selectively can recover a desired element from a solid or molten alloy. Lithium titanate (Li[sub 2]Ti[sub 3]O[sub 7] or Li[sub 2]O [center dot] 3TiO[sub 2]) is used as an ESC to recover lithium (Li) from aluminum-lithium (Al-Li) alloys. X-ray diffraction measurements have shown that Li[sub 2]Ti[sub 3]O[sub 7] undergoes a phase change during scavenging from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of lithium in the matrix of the material and the effect of temperature. Although both phases are metastable, the hexagonal phase that forms during the scavenging of lithium from Al-Li alloys appears to be the more stable phase. Recovering lithium from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. The orthorhombic and the hexagonal structures of Li[sub 2]Ti[sub 3]O[sub 7] have similar scavenging capacities for lithium. This report proposes a new mechanism for the phase transformation.

  5. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  6. Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

    SciTech Connect (OSTI)

    Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

    2008-02-18

    The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ≥ 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ≥ 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space

  7. Compounds for novel proton conducting membranes and methods of making same

    DOE Patents [OSTI]

    Poling, Steven A.; Martin, Steve W.; Sutherland, Jacob T.

    2006-03-28

    The present invention provides new compounds for use in proton exchange membranes which are able to operate in a wide variety of temperature ranges, including in the intermediate temperature range of about 100.degree. C. to 700.degree. C., and new and improved methods of making these compounds. The present invention also provides new and improved methods for making chalcogenide compounds, including, but not limited to, non-protonated sulfide, selenide and telluride compounds. In one embodiment, the proton conductivity of the compounds is between about 10.sup.-8 S/cm and 10.sup.-1 S/cm within a temperature range of between about -50 and 500.degree. C.

  8. Direct vapor/solid synthesis of mercuric iodide using compounds of mercury and iodine

    DOE Patents [OSTI]

    Skinner, Nathan L.

    1990-01-01

    A process is disclosed for producing high purity mercuric iodide by passing a gaseous source of a mercuric compound through a particulate bed of a low vapor pressure iodide compound which is maintained at an elevated temperature which is the lower of either: (a) just below the melting or volatilization temperature of the iodide compound (which ever is lower); or (b) just below the volatilization point of the other reaction product formed during the reaction; to cause the mercuric compound to react with the iodide compound to form mercuric iodide which then passes as a vapor out of the bed into a cooler condensation region.

  9. Synthesis, characterisation, electrical and optical properties of copper borate compounds

    SciTech Connect (OSTI)

    Kipcak, Azmi Seyhun; Senberber, Fatma Tugce; Aydin Yuksel, Sureyya; Derun, Emek Moroydor; Piskin, Sabriye

    2015-10-15

    Highlights: • Cu(BO{sub 2}){sub 2} was synthesized at the form of with pdf number of “00-001-0472”. • Particle sizes were found between 162.72 and 56.44 nm and 195.76 and 75.73 nm at CuSNaH. • Reaction yields were 90.4 ± 0.84, 96.9 ± 0.78 and 78.9 ± 0.76% for CuST, CuSB and CuSNaH. • The resistivity of CuST, CuSB and CuSNaH are 1.10 × 10{sup 7}, 7.02 × 10{sup 6} and 8.62 × 10{sup 5} Ωm. • The optical energy gap was 3.76 eV. - Abstract: The hydrothermal synthesis of copper borate compounds [Cu(BO{sub 2}){sub 2}] was studied, and several parameters were found to affect the synthesis. Raw materials, including CuSO{sub 4}·5H{sub 2}O, Na{sub 2}B{sub 4}O{sub 7}·5H{sub 2}O, Na{sub 2}B{sub 4}O{sub 7}·10H{sub 2}O, NaOH and H{sub 3}BO{sub 3}, were used. Reaction temperatures and reaction times between 40 °C and 100 °C and 15 and 240 min, respectively, were used. The as-synthesised copper borate was analysed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The yields of the reactions were also calculated. Single-phase, nanoparticulate copper borate compounds (Cu(BO{sub 2}){sub 2}) possessing high XRD crystal scores were obtained; the reactions used to obtain these materials were highly efficient. Electrical resistivity and optical absorbance measurements were carried out on the compounds obtained from the highest yielding reactions. The results of this study showed that even using a reaction time of 15 min, copper borate formation was successfully achieved.

  10. Generation of low work function, stable compound thin films by laser ablation

    DOE Patents [OSTI]

    Dinh, Long N.; McLean, II, William; Balooch, Mehdi; Fehring, Jr., Edward J.; Schildbach, Marcus A.

    2001-01-01

    Generation of low work function, stable compound thin films by laser ablation. Compound thin films with low work function can be synthesized by simultaneously laser ablating silicon, for example, and thermal evaporating an alkali metal into an oxygen environment. For example, the compound thin film may be composed of Si/Cs/O. The work functions of the thin films can be varied by changing the silicon/alkali metal/oxygen ratio. Low work functions of the compound thin films deposited on silicon substrates were confirmed by ultraviolet photoelectron spectroscopy (UPS). The compound thin films are stable up to 500.degree. C. as measured by x-ray photoelectron spectroscopy (XPS). Tests have established that for certain chemical compositions and annealing temperatures of the compound thin films, negative electron affinity (NEA) was detected. The low work function, stable compound thin films can be utilized in solar cells, field emission flat panel displays, electron guns, and cold cathode electron guns.

  11. Doping-assisted defect control in compound semiconductors

    DOE Patents [OSTI]

    Specht, Petra; Weber, Eicke R.; Weatherford, Todd Russell

    2006-07-11

    The present invention relates to the production of thin film epilayers of IIIV and other compounds with acceptor doping wherein the acceptor thermally stabilizes the epilayer, stabilize the naturally incorporated native defect population and therewith maintain the epilayer's beneficial properties upon annealing among other advantageous effects. In particular, balanced doping in which the acceptor concentration is similar to (but does not exceed) the antisite defects in the as-grown material is shown to be particularly advantageous in providing thermal stability, high resistivity and ultrashort trapping times. In particular, MBE growth of LT-GaAs epilayers with balanced Be doping is described in detail. The growth conditions greatly enhance the materials reproducibility (that is, the yield in processed devices). Such growth techniques can be transferred to other IIIV materials if the growth conditions are accurately reproduced. Materials produced herein also demonstrate advantages in reproducibility, reliability and radiation hardening.

  12. Two-Stroke Uniflow Turbo-Compound IC Engine

    Broader source: Energy.gov [DOE]

    An evaluation study of a turbo-compounded concept engine consisting of a two-stroke, uniflow, four cylinder air cooled flat-four engine has been completed The concept includes a high pressure ratio supercharger compressor that is powered by an exhaust driven turbine. Downstream of the high pressure turbine is a low pressure power turbine that is geared to the engine crankshaft. The engine cylinders have 360 degree circumferential intake ports with swirl vanes, located at the bottom of the piston stroke. A large single exhaust valve is at the top of the cylinder. The fuel is injected downstream directly into the swirling airflow near the top of the piston stroke. The fuel is ignited by a high energy sparkplug. This engine offers very low fuel consumption in a compact, light weight package, with fuel flexibility.

  13. Maximizing Information from Residential Measurements of Volatile Organic Compounds

    SciTech Connect (OSTI)

    Maddalena, Randy; Li, Na; Hodgson, Alfred; Offermann, Francis; Singer, Brett

    2013-02-01

    Continually changing materials used in home construction and finishing can introduce new chemicals or changes in the VOC profile in residential air and the trend towards tighter homes can lead to higher exposure concentrations for many indoor sources. However, the complex mixture of VOCs in residential air makes it difficult to discover emerging contaminants and/or trends in pollutant profiles. The purpose of this study is to prepare a comprehensive library of chemicals found in homes, along with a semi-quantitative approach to maximize the information gained from VOC measurements. We carefully reviewed data from 108 new California homes and identified 238 individual compounds. The majority of the identified VOCs originated indoors. Only 31% were found to have relevant health based exposure guidelines and less than 10% had a chronic reference exposure level (CREL). The finding highlights the importance of extending IAQ studies to include a wider range of VOCs

  14. Pressure induced phase transitions in ceramic compounds containing tetragonal zirconia

    SciTech Connect (OSTI)

    Sparks, R.G.; Pfeiffer, G.; Paesler, M.A.

    1988-12-01

    Stabilized tetragonal zirconia compounds exhibit a transformation toughening process in which stress applied to the material induces a crystallographic phase transition. The phase transition is accompanied by a volume expansion in the stressed region thereby dissipating stress and increasing the fracture strength of the material. The hydrostatic component of the stress required to induce the phase transition can be investigated by the use of a high pressure technique in combination with Micro-Raman spectroscopy. The intensity of Raman lines characteristic for the crystallographic phases can be used to calculate the amount of material that has undergone the transition as a function of pressure. It was found that pressures on the order of 2-5 kBar were sufficient to produce an almost complete transition from the original tetragonal to the less dense monoclinic phase; while a further increase in pressure caused a gradual reversal of the transition back to the original tetragonal structure.

  15. Doping-assisted defect control in compound semiconductors

    DOE Patents [OSTI]

    Specht, Petra; Weber, Eicke R.; Weatherford, Todd Russell

    2006-07-11

    The present invention relates to the production of thin film epilayers of III–V and other compounds with acceptor doping wherein the acceptor thermally stabilizes the epilayer, stabilize the naturally incorporated native defect population and therewith maintain the epilayer's beneficial properties upon annealing among other advantageous effects. In particular, balanced doping in which the acceptor concentration is similar to (but does not exceed) the antisite defects in the as-grown material is shown to be particularly advantageous in providing thermal stability, high resistivity and ultrashort trapping times. In particular, MBE growth of LT-GaAs epilayers with balanced Be doping is described in detail. The growth conditions greatly enhance the materials reproducibility (that is, the yield in processed devices). Such growth techniques can be transferred to other III–V materials if the growth conditions are accurately reproduced. Materials produced herein also demonstrate advantages in reproducibility, reliability and radiation hardening.

  16. Detection of volatile organic compounds using surface enhanced Raman scattering

    SciTech Connect (OSTI)

    Chang, A S; Maiti, A; Ileri, N; Bora, M; Larson, C C; Britten, J A; Bond, T C

    2012-03-22

    The authors present the detection of volatile organic compounds directly in their vapor phase by surface-enhanced Raman scattering (SERS) substrates based on lithographically-defined two-dimensional rectangular array of nanopillars. The type of nanopillars is known as the tapered pillars. For the tapered pillars, SERS enhancement arises from the nanofocusing effect due to the sharp tip on top. SERS experiments were carried out on these substrates using various concentrations of toluene vapor. The results show that SERS signal from a toluene vapor concentration of ppm level can be achieved, and the toluene vapor can be detected within minutes of exposing the SERS substrate to the vapor. A simple adsorption model is developed which gives results matching the experimental data. The results also show promising potential for the use of these substrates in environmental monitoring of gases and vapors.

  17. Laser photochemistry of gallium-containing compounds. [Trimethylgallium

    SciTech Connect (OSTI)

    Baughcum, S.L.; Oldenborg, R.C.

    1986-01-01

    The production of gas-phase gallium atoms in the photolysis of trimethylgallium has been investigated at 193 nm and at other laser wavelengths. Ground state (4 /sup 2/P/sup 0//sub 1/2) and metastable (4 /sup 2/P/sup 0//sub 3/2/) gallium atoms are detected using laser-induced fluorescence techniques. Our results indicate that gallium atoms continue to be produced at long times after the laser pulse. The observed dependence on photolysis laser fluence, trimethylgallium pressure, and buffer gas pressure are consistent with a mechanism in which highly excited gallium methyl radicals undergo unimolecular decomposition to produce gallium atoms. Since this process is observed to happen on the time scale of hundreds of microseconds, these results have important implications for studies of metal deposition and direct laser writing by laser photolysis of organometallic compounds. 31 refs., 5 figs.

  18. Methods for improved growth of group III nitride semiconductor compounds

    DOE Patents [OSTI]

    Melnik, Yuriy; Chen, Lu; Kojiri, Hidehiro

    2015-03-17

    Methods are disclosed for growing group III-nitride semiconductor compounds with advanced buffer layer technique. In an embodiment, a method includes providing a suitable substrate in a processing chamber of a hydride vapor phase epitaxy processing system. The method includes forming an AlN buffer layer by flowing an ammonia gas into a growth zone of the processing chamber, flowing an aluminum halide containing precursor to the growth zone and at the same time flowing additional hydrogen halide or halogen gas into the growth zone of the processing chamber. The additional hydrogen halide or halogen gas that is flowed into the growth zone during buffer layer deposition suppresses homogeneous AlN particle formation. The hydrogen halide or halogen gas may continue flowing for a time period while the flow of the aluminum halide containing precursor is turned off.

  19. Hydrogenated 5-carbon compound and method of making

    DOE Patents [OSTI]

    Elliott, D.C.; Frye, J.G.

    1999-03-16

    The present invention is based upon the surprising discovery that a 5-carbon compound selected from the group of 4-oxopentanoic acid, at least one lactone of 4-oxopentanoic acid, and combinations thereof, may be hydrogenated with a bimetallic catalyst of a noble metal in combination with a second metal and preserve the pendant methyl group. It was further unexpectedly discovered that the same conditions of bimetallic catalyst in the presence of hydrogen are useful for catalyzing the different intermediate reactions, for example, angelicalactone to gamma-valerolactone and gamma-valerolactone to 1,4-pentanediol. Finally, it was surprising that levulinic acid could be converted to 2-methyltetrahydrofuran with heating in the presence of the bimetallic catalyst and hydrogen in a single process vessel. The method of the present invention unexpectedly produced a fuel or fuel component having 2-methyltetrahydrofuran either in a yield greater than 4.5 mol % or in combination with alcohols. 8 figs.

  20. Hydrogenated 5-carbon compound and method of making

    DOE Patents [OSTI]

    Elliott, Douglas C.; Frye, John G.

    1999-01-01

    The present invention is based upon the surprising discovery that a 5-carbon compound selected from the group of 4-oxopentanoic acid, at least one lactone of 4-oxopentanoic acid, and combinations thereof, may be hydrogenated with a bimetallic catalyst of a noble metal in combination with a second metal and preserve the pendant methyl group. It was further unexpectedly discovered that the same conditions of bimetallic catalyst in the presence of hydrogen are useful for catalyzing the different intermediate reactions for example angelicalactone to gamma-valerolactone and gamma-valerolactone to 1,4-pentanediol. Finally, it was surprising that levulinic acid could be converted to 2-methyltetrahydrofuran with heating in the presence of the bimetallic catalyst and hydrogen in a single process vessel. The method of the present invention unexpectedly produced a fuel or fuel component having 2-methyltetrahydrofuran either in a yield greater than 4.5 mol % or in combination with alcohols.