National Library of Energy BETA

Sample records for ozone osha occupational

  1. OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational

    Energy Savers [EERE]

    Safety and Health Programs and Related Matters; 29 CFR 1960 | Department of Energy OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 November 26, 2004 Federal Register copy of OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health

  2. OSHA's Final Rule on Occupational Exposure to Respirable Crystalline

    Office of Environmental Management (EM)

    Safety and Health Programs and Related Matters; 29 CFR 1960 | Department of Energy OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 November 26, 2004 Federal Register copy of OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health

  3. OSHA's approach to risk assessment for setting a revised occupational exposure standard for 1,3-butadiene

    SciTech Connect (OSTI)

    Grossman, E.A.; Martonik, J. )

    1990-06-01

    In its 1980 benzene decision (Industrial Union Department, ALF-CIO v. American Petroleum Institute, 448 U.S. 607 (1980)), the Supreme Court ruled that before he can promulgate any permanent health or safety standard, the Secretary (of Labor) is required to make a threshold finding that a place of employment is unsafe--in the sense that significant risks are present and can be lessened by a change in practices (448 U.S. at 642). The Occupational Safety and Health Administration (OSHA) has interpreted this to mean that whenever possible, it must quantify the risk associated with occupational exposure to a toxic substance at the current permissible exposure limit (PEL). If OSHA determines that there is significant risk to workers' health at its current standard, then it must quantify the risk associated with a variety of alternative standards to determine at what level, if any, occupational exposure to a substance no longer poses a significant risk. For rulemaking on occupational exposure to 1,3-butadiene, there are two studies that are suitable for quantitative risk assessment. One is a mouse inhalation bioassay conducted by the National Toxicology Program (NTP), and the other is a rat inhalation bioassay conducted by Hazelton Laboratories Europe. Of the four risk assessments that have been submitted to OSHA, all four have used the mouse and/or rat data with a variety of models to quantify the risk associated with occupational exposure to 1,3-butadiene. In addition, OSHA has performed its own risk assessment using the female mouse and female rat data and the one-hit and multistage models.

  4. OSHA Rulemaking on Basic Program Elements for Federal Employee...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 OSHA Rulemaking on Basic Program Elements ...

  5. OSHA`s process safety management standard

    SciTech Connect (OSTI)

    Morelli, J.A.

    1994-12-31

    On February 24, 1992, OSHA published the final rule for its Process Safety Management Standard (PSM) mandated by the Clean Air Act Amendments of 1990. (see Federal Register 57 FR 6356-6417). This standard imposes several responsibilities upon employers whose processes can cause large accident releases that could result in processes can cause large accident releases that could result in catastrophes. In contrast to OSHA`s Hazard Communication standard which focuses on routine daily exposures to hazardous materials, the PSM Standard is concerned with processes whereby the use, storage, manufacturing, handling or on-site movement of highly hazardous chemicals which exceed threshold quantities, provides potential for a catastrophic release. The PSM Standard requires: a written program, plans, training, hazard analysis and compliance auditing. This paper outlines the provisions under this Standard pursuant to OSHA regulation 29 Code of Federal Regulation 1910.119.

  6. Controlling OSHA PSM documentation

    SciTech Connect (OSTI)

    Person, J.S. [Warren-Forthought, Inc., Angleton, TX (United States)

    1997-06-01

    At present, most companies in the hazardous materials process industries are knowledgeable in the requirements of the OSHA Process Safety Management (PSM) standard (29 CFR 1910.119), issued in May of 1992. The current question facing many of these companies is no longer ``How does one comply?`` but rather, ``What does one do with all the documentation generated from the OSHA PSM Standard?``. Using an Electronic Performance Support System (EPSS) for delivering and controlling OSHA PSM documentation will be discussed. This paper will address the important components of an EPSS and successful case studies.

  7. Current DOE and OSHA VPP Sites

    Broader source: Energy.gov [DOE]

    Need to know which sites are current DOE-VPP or OSHA VPP Sites? The link, below, will take you to a Voluntary Protection Programs Participant's Association web page where you may search for current...

  8. Exemptions from OSHA`s PSM rule oil and gas field production

    SciTech Connect (OSTI)

    West, H.H. [Shawnee Engineers, Houston, TX (United States); Landes, S. [SH Landes, Houston, TX (United States)

    1995-12-31

    The OSHA Process Safety Management (PSM) regulation, OSHA 1910.119, contains a number of exemptions which are specifically directed to the low hazard situations typically found in the field production facilities of the oil and gas industry. Each relevant PSM exemption is discussed with particular regard to the requirements of hydrocarbon production facilities.

  9. WAP Memorandum 013: Updated OSHA Requirements for Confined Spaces

    Broader source: Energy.gov [DOE]

    Standard (29 CFR 1926 Subpart AA) took effect August 3, 2015. OSHA has issued a 60-day extension to the enforcement of this rule via a memorandum titled “Temporary Enforcement Policy for Construction Work in Confined Spaces,” which moves the effective enforcement date to Oct. 2, 2015.

  10. Occupational safety and health law handbook

    SciTech Connect (OSTI)

    Sarvadi, D.G.; Keller; Heckman

    1999-09-01

    This book reviews the regulations and standards governing the protection of employees in the workplace and provides insight into dealing with pertinent regulations and regulatory authorities. Written for safety professionals, industrial hygienists, human resource professionals, attorneys, and students, this companion to Government Institutes' best-selling ``Environmental Law Handbook'' offers the legal fundamentals behind occupational safety and health laws in one concise and authoritative volume. In 19 chapters, the authoring law firm of Keller and Heckman cover the OSHAct and its development; OSHA, NIOSH, and OSHRC; the roles played by other regulatory agencies; the OSHA rulemaking process; OSHA Standards and the General Duty Clause; record keeping and reporting; employers' and employees' rights; inspections; violations, penalties, and how to contest them; criminal prosecutions; state plans; industry-specific issues; OSHA reform; and international regulations and standards. This book references approximately 400 seminal OSHA legal decisions from the approximately 1,300 cases on record and includes coverage of Canadian and European Community regulations, making it the first comprehensive global overview of occupational safety and health law.

  11. A review of OSHA PSM citations relating to mechanical integrity of process piping

    SciTech Connect (OSTI)

    Casada, M.L.; Remson, A.C.; Yerger, C.M. [JBF Associates, Inc., Knoxville, TN (United States)

    1996-07-01

    OSHA`s process safety management (PSM) regulation has been in effect for more than three years. The regulation poses challenges for facilities in documenting the integrity of process piping systems. This paper summarizes the results of a project sponsored by the Materials Technology Institute (MTI) to compile PSM enforcement information relating to mechanical integrity W and process safety information (PSI) relating to equipment. This paper provides an analysis of how OSHA is citing violations of the PSM regulation as it relates to process piping. This information should be helpful to engineers and maintenance personnel who need guidance on how to ``OSHA-proof`` their mechanical integrity compliance for process piping systems.

  12. Using OSHA`s requirement for the revalidation of PHA`s to comply with EPA`s proposed risk management rule

    SciTech Connect (OSTI)

    Him, M.S.; Mannan, M. [RMT/Jones and Neuse, Inc., Austin, TX (United States)

    1996-11-01

    OSHA`s Process Safety Management rule not only requires the performance of process hazards analyses (PHA`s) of covered areas, but the revalidation of these PHA`s every 5 years. With the May 26, 1997 deadline for the completion of initial PHA`s nearing and the pending approval on or before March 1996 of EPA`s Risk Management Programs (RMP) for Chemical Accidental Release Prevention ({section}40 CFR 68), PSM-covered facilities must start developing plans for compliance with one or more of the requirements of these regulations. This paper discusses some of the strategies that companies falling under Tier 3 of EPA`s RMP rule may use to comply with OSHA`s revalidation of PHA`s and the upcoming EPA rule. The paper also provides details on the use of other PSM elements for PHA revalidation (such as compliance audits and management of change), the development of schedules for PHA revalidation, preparation time, the revalidation process, and the documentation/identification of RMP hazard scenarios.

  13. Using OSHA`s requirement for the revalidation of PHA`STo comply with EPA`s proposed risk management rule

    SciTech Connect (OSTI)

    Him, M.S.; Mannan, M. [RMT/Jones & Neuse, Inc., Austin, TX (United States)

    1996-08-01

    OSHA`s Process Safety Management rule not only requires the performance of process hazards analyses (PHA`s) of covered areas, but the revalidation of these PHA`s every 5 years. With the May 26, 1997 deadline for the completion of initial PHA`s nearing and the pending approval on or before March 1996 of EPA`s Risk Management Programs (RMP) for Chemical Accidental Release Prevention ({section}40 CFR 68), PSM-covered facilities must start developing plans for compliance with one or more of the requirements of these regulations. This paper discusses some of the strategies that companies falling under Tier 3 of EPA`s RMP rule may use to comply with OSHA`s revalidation of PHA`s and the upcoming EPA rule. The paper also provides details on the use of other PSM elements for PHA revalidation (such as compliance audits and management of change), the development of schedules for PHA revalidation, preparation time, the revalidation process, and the documentation/identification of RMP hazard scenarios.

  14. OSHA safety regulation calls for step-by-step approach

    SciTech Connect (OSTI)

    Bellomo, P.J. (Arthur D. Little Inc., Houston, TX (US))

    1992-06-01

    The U.S. Occupational Safety and Health Administration's long-awaited process safety management (PSM) regulation mandates the implementation of a PSM program at facilities handling highly hazardous materials, including oil refineries and petrochemical plants. This article presents a step-by-step PSM program compliance strategy, delineated and explored through practical examples.

  15. The OSHA and EPA programs on preventing chemical accidents and potential applications in the photovoltaic industry

    SciTech Connect (OSTI)

    Fthenakis, V.M.

    1996-08-01

    OSHA issued in 1992, the Process Safety Management (PSM) of Highly Hazardous Substances. This rule requires owners/operators of facilities that handle hazardous chemicals in quantities greater than the listed thresholds to establish all the elements of a PSM. EPA has issued in June 1996, the rules for a Risk Management Program which also refers to specific substances and threshold quantities. These rules are applicable to all the facilities that use or store any of 139 regulated substances at quantities ranging from 100 lb to 10,000 lb. The RMP rule covers off-site hazards, while the OSHA Process Safety Management (PSM) rule covers worker safety issues within the plant boundary. Some of the listed substances may be found in photovoltaic manufacturing facilities. This brief report presents the basic elements of these two rules and discusses their potential applicability in the photovoltaic industry.

  16. Preparing for CAAA risk management plans: The lessons of OSHA PSM process safety management

    SciTech Connect (OSTI)

    Gillespie, D.P. [Control Systems Consultants, Inc., Ashland, KY (United States)

    1994-12-31

    29 CFR 1910.119 OSHA Process Safety Management (PSM) became law in 1992, presenting covered facilities with extraordinarily comprehensive and demanding requirements for information management. This paper reports an approach adopted by petrochemical plants that have pioneered automated, integrated compliance with PSM information requirements. The approach is worthy of consideration by the many additional plants that will be covered by 40 CFR Part 67 Risk Management Programs for Chemical Accidental Release Prevention (RNT), which closely parallels PSM`s information requirements.

  17. Process safety management (OSHA) and process risk management (CAA) application. Application to a coke plant

    SciTech Connect (OSTI)

    Graeser, W.C.; Mentzer, W.P.

    1995-12-01

    Risk Management Programs for Chemical Accidental Release Prevention is the name of the proposed rule for the RMP Risk Management Program. The RMP was written in response to several catastrophic releases of hazardous substances. The rule is applicable to facilities that store, process or use greater than threshold quantities of 62 listed flammable chemicals and another 100 listed toxic substances. Additionally, a Risk Management Plan is registered with the EPA, Chemical Safety and Hazardous Investigation Board, state governments and the local emergency planning commission. The Clean Air Act Amendments of 1990 (specifically Section 112r) required the EPA to develop a three phase Risk Management Plan for industry: prevention program; hazard assessment; and emergency response program. The Prevention Program closely follows the OSHA`s Process Safety Management Standard. The Hazard Assessment section requires facilities to develop plans for a worst case scenario. The Emergency Response section defines the steps the facility and each employee will take if a release occurs. This section also needs to be coordinated with the Local Emergency Planning Commission. These regulations are described using Clairton Works as an example of compliance.

  18. Statistical Analysis of Occupational Safety Data of Voluntary Protection Program (VPP) and Non-VPP Sites

    Broader source: Energy.gov [DOE]

    The Voluntary Protection Program (VPP) was originally developed by Occupational Safety and Health Administration (OSHA) in 1982 to foster greater ownership of safety and health in the workplace. The Department of Energy (DOE) adopted VPP in 1992; currently 23 sites across the DOE complex participate in the program. As its name implies, it is a voluntary program; i.e. not required by laws or regulations.

  19. An OSHA based approach to safety analysis for nonradiological hazardous materials

    SciTech Connect (OSTI)

    Yurconic, M.

    1992-08-01

    The PNL method for chemical hazard classification defines major hazards by means of a list of hazardous substances (or chemical groups) with associated trigger quantities. In addition, the functional characteristics of the facility being classified is also be factored into the classification. In this way, installations defined as major hazard will only be those which have the potential for causing very serious incidents both on and off site. Because of the diversity of operations involving chemicals, it may not be possible to restrict major hazard facilities to certain types of operations. However, this hazard classification method recognizes that in the industrial sector major hazards are most commonly associated with activities involving very large quantities of chemicals and inherently energetic processes. These include operations like petrochemical plants, chemical production, LPG storage, explosives manufacturing, and facilities which use chlorine, ammonia, or other highly toxic gases in bulk quantities. The basis for this methodology is derived from concepts used by OSHA in its proposed chemical process safety standard, the Dow Fire and Explosion Index Hazard Classification Guide, and the International Labor Office`s program on chemical safety. For the purpose of identifying major hazard facilities, this method uses two sorting criteria, (1) facility function and processes and (2) quantity of substances to identify facilities requiringclassification. Then, a measure of chemical energy potential (material factor) is used to identify high hazard class facilities.

  20. An OSHA based approach to safety analysis for nonradiological hazardous materials

    SciTech Connect (OSTI)

    Yurconic, M.

    1992-08-01

    The PNL method for chemical hazard classification defines major hazards by means of a list of hazardous substances (or chemical groups) with associated trigger quantities. In addition, the functional characteristics of the facility being classified is also be factored into the classification. In this way, installations defined as major hazard will only be those which have the potential for causing very serious incidents both on and off site. Because of the diversity of operations involving chemicals, it may not be possible to restrict major hazard facilities to certain types of operations. However, this hazard classification method recognizes that in the industrial sector major hazards are most commonly associated with activities involving very large quantities of chemicals and inherently energetic processes. These include operations like petrochemical plants, chemical production, LPG storage, explosives manufacturing, and facilities which use chlorine, ammonia, or other highly toxic gases in bulk quantities. The basis for this methodology is derived from concepts used by OSHA in its proposed chemical process safety standard, the Dow Fire and Explosion Index Hazard Classification Guide, and the International Labor Office's program on chemical safety. For the purpose of identifying major hazard facilities, this method uses two sorting criteria, (1) facility function and processes and (2) quantity of substances to identify facilities requiringclassification. Then, a measure of chemical energy potential (material factor) is used to identify high hazard class facilities.

  1. ARM - Measurement - Ozone Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Ozone Concentration The atmospheric concentration or volume mixing ratio (mole fraction) of Ozone Categories Atmospheric State Instruments The above measurement is...

  2. Supervisors` orientation to occupational safety in DOE

    SciTech Connect (OSTI)

    1993-10-01

    This document presents OSHA regulations, safety and health guidelines pertinent to DOE and the first-line supervisor.

  3. ARM - Measurement - Ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ozone Ozone measurements are given in Dobson units and are integers with 3...

  4. ARM - Campaign Instrument - ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsozone Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Ozone Monitor (OZONE) Instrument...

  5. Occupational Medicine Variance Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory | Department of Energy Medical Surveillance System (OMSS) PIA, Idaho National Laboratory Occupational Medical Surveillance System (OMSS) PIA, Idaho National Laboratory Occupational Medical Surveillance System (OMSS) PIA, Idaho National Laboratory PDF icon Occupational Medical Surveillance System (OMSS) PIA, Idaho National Laboratory More Documents & Publications Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Injury & Illness System

  6. PIA - Richland Occupational Medicine Contract | Department of...

    Energy Savers [EERE]

    PIA - Richland Occupational Medicine Contract PIA - Richland Occupational Medicine Contract PIA - Richland Occupational Medicine Contract PDF icon PIA - Richland Occupational...

  7. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  8. PRIVACY IMPACT ASSESSMENT: OCCUPATIONAL MEDICINE- INL OCCUPATIONAL

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OCCUPATIONAL MEDICINE- INL OCCUPATIONAL MEDICAL SUVEILLANCE SYSTEM (OMSS) PIA Template Version 3 - May, 2009 Department of Energy Privacy Impact Assessment (PIA) Guidance is provided in the template. See DOE Order 206.1, Department of Energy Privacy Program, Appendix A, Privacy Impact Assessments, for requirements and additional guidance for conducting a PIA: http://www.directives.doe.gov/pdfs/doe/doetextlneword/206/o2061.pdf Please complete electronically: no hand-written submissions will be

  9. PRIVACY IMPACT ASSESSMENT: Occupational Safety Health Occupational

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Occupational Safety & Health - Occupational Injury & Illness System PIA Template Version 3 - May, 2009 Department of Energy Privacy Impact Assessment (PIA) Guidance is provided in the template. See DOE Order 206.1 J Department of Energy Privacy Program, Appendix A, Privacy Impact Assessments, for requirements and additional guidance for conducting a PIA: http://www.directives.doe.gov/pdfs/doe/doetextlneword/206/o2061.pdf Please complete electronically: no hand-written submissions will be

  10. Tropospheric ozone in east Asia

    SciTech Connect (OSTI)

    Phadnis, M.J.

    1996-12-31

    An analysis of the observed data for the tropospheric ozone at mid latitudes in east Asia is done. There are three ways by which the tropospheric ozone is calculated, namely: (1) Ozonesonde measurements, (2) Fishman`s method of Residual Ozone and (3) TOMS measurements - an indirect method of calculating tropospheric ozone. In addition the surface ozone values at the network sites in Japan is also considered. The analysis of data is carried out for a period of twelve years from 1979 to 1991. In general it is observed that the tropospheric ozone is more in summer than winter, obviously because of the larger tropopause height in summer. On an average for the period of the analysis, the ozone values are at a high of about 60 DU (dobson units). While in winter the values go down to around 30 DU. Also a time series analysis shows an increasing trend in the values over the years. The ozonesonde values are correlated more to the TOMS tropospheric ozone values. For the stations analyzed in Japan, the TOMS tropospheric ozone values are generally greater than the ozonesonde values. The analysis of the average monthly surface ozone in Japan shows highs in spring and lows in summer. This can be attributed to movement of pollutant laden fronts towards Japan during spring. The highs for surface ozone are about 50 DU while the lows are around 20 DU.

  11. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F.; Brown, John D.; Whinnery, Jr., LeRoy L.

    1999-01-01

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  12. Occupant Safety Assessment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Occupant Emergency Plans Occupant Emergency Plans On this page is the collection of Emergency Procedures documents for the Department of Energy, Headquarters buildings, in the Washington, DC, metropolitan area. Emergency Procedures Pamphlets Building Evacuation Routes Occupant Emergency Plans (OEP's) All of these documents are only available to computers attached to the DOE Network. They are for use only by DOE Headquarters employees. Any computer not on the DOE Network will get an error message

  13. Occupational Medicine - Assistant PIA, Idaho National Laboratory...

    Energy Savers [EERE]

    Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Medicine - Assistant PIA, Idaho...

  14. Ozone Risk Assessment Utilities

    Energy Science and Technology Software Center (OSTI)

    1999-08-10

    ORAMUS is a user-friendly, menu-driven software system that calculates and displays user-selected risk estimates for health effects attributable to short-term exposure to tropospheric ozone. Inputs to the risk assessment are estimates of exposure to ozone and exposure-response relationships to produce overall risk estimates in the form of probability distributions. Three fundamental models are included: headcount risk, benchmark risk, and hospital admissions. Exposure-response relationships are based on results of controlled human exposure studies. Exposure estimates aremore » based on the EPA''s probabilistic national ambient air quality standards (NAAQS) exposure model, pNEM/Osub3, which simulates air quality associated with attainment of alternative NAAQS. Using ORAMUS, risk results for 27 air quality scenarios, air quality in 9 urban areas, 33 health endpoints, and 4 chronic health endpoints can be calculated.« less

  15. Ozone transport commission developments

    SciTech Connect (OSTI)

    Joyce, K.M.

    1995-08-01

    On September 27, 1994, the states of the Ozone Transport Commission (OTC) signed an important memorandum of understanding (MOU) agreeing to develop a regional strategy for controlling stationary sources of nitrogen oxide emissions. Specifically, the states of the Ozone Transport Region, OTR, agreed to propose regulations for the control of NOx emissions from boilers and other indirect heat exchangers with a maximum gross heat input rate of at least 250 million BTU per hour. The Ozone Transport Region was divided into Inner, Outer and Northern Zones. States in the Outer Zone agreed to reduce NOx emissions by 55%. States in the Inner Zone agreed to reduce NOx emissions 65%. Facilities in both zones have the option to emit NOx at a rate no greater than 0.2 pounds per million Btu by May 1, 1999. This option provides fairness for the gas-fired plants which already have relatively low NOx emissions. Additionally, States in the Inner and Outer Zones agreed to reduce their NOx emissions by 75% or to emit NOx at a rate no greater than 0.15 pounds per million BTU by May 1, 2003. The Northern Zone States agree to reduce their rate of NOx emissions by 55% from base year levels by May 1, 2003, or to emit NOx at a rate no greater than 0.2 pounds per million BTU. As part of this MOU, States also agreed to develop a regionwide trading mechanism to provide a cost-effective mechanism for implementing the reductions.

  16. Nonaqueous ozonation of vulcanized rubber

    DOE Patents [OSTI]

    Serkiz, Steven M.

    1999-01-01

    A process and resulting product is provided in which a solid particulate, such as vulcanized crumb rubber, has the surface functional groups oxidized by ozonation using a nonpolar solvent. The ozonation process renders the treated crumb rubber more suitable for use in new rubber formulations. As a result, larger loading levels of the treated crumb rubber can be used in new rubber mixtures.

  17. Occupational Safety Performance

    Office of Environmental Management (EM)

    Direct Data Entry Coding Guide August 2014 Table of Contents Chapter A - Occupation Codes ................................................................................................... A-1 Chapter B - Body Part Codes ...................................................................................................... B-1 Chapter C - Nature of Injury/Illness Codes ................................................................................. C-1 Chapter D - Source, Target, and Other

  18. Promising Technology: Ozone Laundry System for Multiload Clothes Washers

    Broader source: Energy.gov [DOE]

    These laundry systems use ozone as the chemical cleaning agent. The system generates ozone by electrifying oxygen in the air, and then dissolves the ozone in water.

  19. PIA - Richland Occupational Medicine Contract | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medicine Contract PIA - Richland Occupational Medicine Contract PIA - Richland Occupational Medicine Contract PDF icon PIA - Richland Occupational Medicine Contract More Documents ...

  20. Annual DOE Occupational Radiation Exposure Reports | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual DOE Occupational Radiation Exposure Reports Annual DOE Occupational Radiation Exposure Reports November 17, 2015 Annual DOE Occupational Radiation Exposure | 2014 Report The...

  1. ARM - Measurement - Ozone Column Abundance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Column Abundance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ozone Column Abundance The vertically integrated amount of ozone (commonly measured in Dobson Unit, 1 DU = 134 mmol/m^2) Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  2. Impact of the revised OSHA exposure standard on evaluation and control of benzene and other volatile organic chemicals in the liquid petroleum pipeline industry

    SciTech Connect (OSTI)

    Mercer, D.O.

    1989-01-01

    The primary purpose of this study was to determine the benzene exposure potential of workers in the liquid petroleum pipeline industry and to assess the impact of compliance with the revised standard on this industry. In addition, exposure to ethylene dibromide (EDB), and ethylene dichloride (EDC), which have toxicological profiles similar to that of benzene and are routinely found in this industry, were evaluated and appropriate control protocols were recommended. Exposure potential to benzene in excess of the 0.5 ppm (8-hour TWA) OSHA action level was shown to be limited to three free product handling operations, and that this increased exposure potential was dependent on the length of time necessary to perform the operations. The incidence and magnitude of benzene overexposure was not severe and control could be accomplished with engineering methods, along with work practice controls and personal protective equipment. Through application of a risk assessment model it was shown that 14 excess leukemia deaths per one thousand workers could be expected in the employee population that routinely performs those operation having maximum benzene exposure potential. This compares to less than on excess leukemia death per one thousand workers in the total work population. The evaluation of EDB and EDC indicated that exposure potential to EDB was of greatest concern. Even though exposure could be limited through application of standard industrial hygiene methods, any control protocol short of total elimination of EDB from the product stream may be not sufficient to reduce exposure to accepted levels.

  3. Energy Employees' Occupational Illness Compensation Program Act...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Database, INL Energy Employees' Occupational Illness Compensation Program Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database, INL ...

  4. Occupational Medicine - Assistant PIA, Idaho National Laboratory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medicine - Assistant PIA, Idaho National Laboratory Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Medicine - Assistant PIA, Idaho National ...

  5. 29 CFR 1910 Occupational Safety and Health Standards

    National Nuclear Security Administration (NNSA)

    ... XVII (7-1-07 Edition) 1910.7 which will be available on the OSHA web site. APPENDIX A ... tion), and synthetic web (nylon, poly- ester, and polypropylene). (b) Definitions. ...

  6. Relation between Atmospheric Ozone and Geomagnetic Disturbances...

    Office of Scientific and Technical Information (OSTI)

    This involves a decrease of ozone in the 50 to 65 deg N region and an increase south of 50 deg N. Two or three days after the storm, the ozone amount increases in the 50 to 65 deg ...

  7. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  8. Occupational Medicine | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    state regulations. The Occupational Medicine office enhances the efficiency of existing safety and health programs and assists in the reduction of workplace injuries and illnesses....

  9. DOE HQ Occupational Safety and Health Program | Department of...

    Energy Savers [EERE]

    DOE HQ Occupational Safety and Health Program DOE HQ Occupational Safety and Health Program HQ Occupational Safety and Health Program Procedures PDF icon DOE HQ Occupational Safety...

  10. Occupational Medical Program

    Energy Science and Technology Software Center (OSTI)

    1993-12-08

    The Occupational Medical Program (OMP) oversees all Idaho National Engineering Laboratory (INEL) health care, and provides services to all managing and operating (M&O) contractors at the INEL and for the Department of Energy Idaho Office (DOE-ID). The evolution of the automated OMP at the INEL is guided by the U.S. Department of Energy (DOE) directives and regulations. The OMP is developing a multiyear plan for the computerization of patient and demographics, epidemiology, medical records, andmore » surveillance. This plan will require the following six development phases: Employee Demographic Phase, Patient Surveillance Certification and Restrictions Phase, Electronic Notification Phase, Epidemiology-Industrial Hygiene/Radiation Exposure/OMP Integration Phase, Medical Scheduling Phase, and Medical Records Phase.« less

  11. DOE 2012 occupational radiation exposure

    SciTech Connect (OSTI)

    none,

    2013-10-01

    The U.S. Department of Energy (DOE) Office of Analysis within the Office of Health, Safety and Security (HSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE (including the National Nuclear Security Administration [NNSA]). The DOE 2012 Occupational Radiation Exposure Report provides an evaluation of DOE-wide performance regarding compliance with Title 10, Code of Federal Regulations (C.F.R.), Part 835, Occupational Radiation Protection dose limits and as low as reasonably achievable (ALARA) process requirements. In addition, the report provides data to DOE organizations responsible for developing policies for protection of individuals from the adverse health effects of radiation. The report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. Over the past 5-year period, the occupational radiation exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site.

  12. DOE 2011 occupational radiation exposure

    SciTech Connect (OSTI)

    none,

    2012-12-01

    The U.S. Department of Energy (DOE) Office of Analysis within the Office of Health, Safety and Security (HSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE (including the National Nuclear Security Administration [NNSA]). The DOE 2011 Occupational Radiation Exposure Report provides an evaluation of DOE-wide performance regarding compliance with Title 10, Code of Federal Regulations (C.F.R.), Part 835, Occupational Radiation Protection dose limits and as low as reasonably achievable (ALARA) process requirements. In addition, the report provides data to DOE organizations responsible for developing policies for protection of individuals from the adverse health effects of radiation. The report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. The occupational radiation exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site over the past five years.

  13. Image-based occupancy sensor

    DOE Patents [OSTI]

    Polese, Luigi Gentile; Brackney, Larry

    2015-05-19

    An image-based occupancy sensor includes a motion detection module that receives and processes an image signal to generate a motion detection signal, a people detection module that receives the image signal and processes the image signal to generate a people detection signal, a face detection module that receives the image signal and processes the image signal to generate a face detection signal, and a sensor integration module that receives the motion detection signal from the motion detection module, receives the people detection signal from the people detection module, receives the face detection signal from the face detection module, and generates an occupancy signal using the motion detection signal, the people detection signal, and the face detection signal, with the occupancy signal indicating vacancy or occupancy, with an occupancy indication specifying that one or more people are detected within the monitored volume.

  14. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru

    2000-01-01

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  15. Annual DOE Occupational Radiation Exposure | 2003 Report

    Broader source: Energy.gov [DOE]

    The DOE 2003 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2003.

  16. ORO Energy Employees Occupational Illness Compensation Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Occupational Illness Compensation Program(EEOICPA)PIA, Oak Ridge Operations Office ORO Energy Employees Occupational Illness Compensation Program(EEOICPA)PIA, Oak Ridge...

  17. Annual DOE Occupational Radiation Exposure | 2014 Report

    Broader source: Energy.gov [DOE]

    The DOE 2014 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2014.

  18. Annual DOE Occupational Radiation Exposure | 2004 Report

    Broader source: Energy.gov [DOE]

    The DOE 2004 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2004.

  19. Safety & Occupational Health Specialist | Department of Energy

    Energy Savers [EERE]

    & Occupational Health Specialist Safety & Occupational Health Specialist Submitted by admin on Sat, 2015-10-17 00:14 Job Summary Organization Name Department Of Energy Agency...

  20. Annual DOE Occupational Radiation Exposure | 2001 Report

    Broader source: Energy.gov [DOE]

    The DOE 2001 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2001.

  1. Annual DOE Occupational Radiation Exposure | 1995 Report

    Broader source: Energy.gov [DOE]

    The DOE Occupational Radiation Exposure Report, 1995 reports occupational radiation exposures incurred by individuals at U.S. Department of Energy (DOE) facilities during the calendar year 1995.

  2. Annual DOE Occupational Radiation Exposure | 2010 Report

    Broader source: Energy.gov [DOE]

    The DOE 2010 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2010.

  3. Annual DOE Occupational Radiation Exposure | 2008 Report

    Broader source: Energy.gov [DOE]

    The DOE 2008 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2008.

  4. Annual DOE Occupational Radiation Exposure | 1996 Report

    Broader source: Energy.gov [DOE]

    The DOE Occupational Radiation Exposure Report, 1996 reports occupational radiation exposures incurred by individuals at U.S. Department of Energy (DOE) facilities during the calendar year 1996.

  5. DOE 2013 occupational radiation exposure (Technical Report) ...

    Office of Scientific and Technical Information (OSTI)

    DOE 2013 occupational radiation exposure Citation Details In-Document Search Title: DOE 2013 occupational radiation exposure The Office of Analysis within the U.S. Department of ...

  6. Nevada Department of Transportation - Occupancy Permits | Open...

    Open Energy Info (EERE)

    Occupancy Permits Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Nevada Department of Transportation - Occupancy Permits Abstract This website gives...

  7. Annual DOE Occupational Radiation Exposure | 2002 Report

    Broader source: Energy.gov [DOE]

    The DOE 2002 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2002.

  8. Annual DOE Occupational Radiation Exposure | 2007 Report

    Broader source: Energy.gov [DOE]

    The DOE 2007 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2007.

  9. Annual DOE Occupational Radiation Exposure | 2009 Report

    Broader source: Energy.gov [DOE]

    The DOE 2009 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2009.

  10. Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion

    Office of Scientific and Technical Information (OSTI)

    Prize-winning Research, Massachusetts Institute of Technology (MIT) The Science and Policies of the Ozone Layer -- A Historical Perspective, IDEaS - Nobel Laureate Mario J....

  11. Ozone contactor hydraulic considerations in meeting CT disinfection...

    Office of Scientific and Technical Information (OSTI)

    Optimization of ozone dose and contact time for CT calculations was performed in the pilot plant. Operational guidelines for the application of ozone in Union Hills pilot plant ...

  12. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment

  13. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment 2003 DEER Conference ...

  14. Reformulated Gasoline Use Under the 8-Hour Ozone Rule

    Reports and Publications (EIA)

    2002-01-01

    This paper focuses on the impact on gasoline price and supply when additional ozone non-attainment areas come under the new 8-hour ozone standard.

  15. Effect of Ventilation Strategies on Residential Ozone Levels...

    Office of Scientific and Technical Information (OSTI)

    Effect of Ventilation Strategies on Residential Ozone Levels Citation Details In-Document Search Title: Effect of Ventilation Strategies on Residential Ozone Levels You are...

  16. Effect of Ventilation Strategies on Residential Ozone Levels...

    Office of Scientific and Technical Information (OSTI)

    Effect of Ventilation Strategies on Residential Ozone Levels Citation Details In-Document Search Title: Effect of Ventilation Strategies on Residential Ozone Levels Authors:...

  17. Reactivity of Ozone with Solid Potassium Iodide Investigated...

    Office of Scientific and Technical Information (OSTI)

    Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy Citation Details In-Document Search Title: Reactivity of Ozone with Solid Potassium...

  18. DOE 2010 occupational radiation exposure

    SciTech Connect (OSTI)

    none,

    2011-11-01

    The U.S. Department of Energy (DOE) Office of Analysis within the Office of Health, Safety and Security (HSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE.* The DOE 2010 Occupational Radiation Exposure Report provides an evaluation of DOE-wide performance regarding compliance with DOE Part 835 dose limits and as low as reasonably achievable (ALARA) process requirements. In addition, the report provides data to DOE organizations responsible for developing policies for protection of individuals from the effects of radiation. The report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. The occupational radiation exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site over the past 5 years.

  19. Occupational Medicine Workshops and Webinars

    Broader source: Energy.gov [DOE]

    The DOE Annual Occupational Medicine Workshop & Webinar (OMWW) is a valuable training opportunity established by the Office of Health, Safety, and Security in support of hundreds of medical and allied health professionals located at over four dozen locations across the Department. Their vital work in the field of Occupational Medicine encompasses medical qualification examinations, injury and illness management, disability management, workers’ compensation, and much more.

  20. Occupational Radiation Exposure | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Occupational Radiation Exposure Occupational Radiation Exposure Welcome The Occupational Radiation Exposure Information page on this web page is intended to provide the latest available information on radiation exposure to the workforce at DOE facilities. In addition, this page is intended to serve as a central location for the dissemination of information concerning the recording and reporting requirements for occupational radiation exposure at DOE facilities. Only "occupationally"

  1. DOE 2013 occupational radiation exposure

    SciTech Connect (OSTI)

    none,

    2014-11-01

    The Office of Analysis within the U.S. Department of Energy (DOE) Office of Environment, Health, Safety and Security (EHSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE (including the National Nuclear Security Administration [NNSA]). The DOE 2013 Occupational Radiation Exposure Report provides an evaluation of DOE-wide performance regarding compliance with Title 10, Code of Federal Regulations (C.F.R.), Part 835, Occupational Radiation Protection dose limits and as low as reasonably achievable (ALARA) process requirements. In addition, the report provides data to DOE organizations responsible for developing policies for protection of individuals from the adverse health effects of radiation. The report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. Over the past five-year period, the occupational radiation exposure information has been analyzed in terms of aggregate data, dose to individuals, and dose by site.

  2. Operating Experience Level 3, DOE Occupational Radiation Exposures...

    Energy Savers [EERE]

    DOE Occupational Radiation Exposures for 2013 Operating Experience Level 3, DOE Occupational Radiation Exposures for 2013 January 29, 2015 OE-3 2015-01: DOE Occupational Radiation...

  3. Occupational Health Manager PIA, Carlsbad Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Occupational Health Manager PIA, Carlsbad Field Office PDF icon Occupational Health Manager PIA, Carlsbad Field Office More Documents & Publications Occupational Medicine - ...

  4. Thermo Scientific Ozone Analyzer Instrument Handbook (Technical...

    Office of Scientific and Technical Information (OSTI)

    The primary measurement output from the Thermo Scientific Ozone Analyzer is the concentration of the analyte (O3) reported at 1-s resolution in units of ppbv in ambient air. Note ...

  5. Headquarters Occupational Health Clinics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Headquarters Occupational Health Clinics Headquarters Occupational Health Clinics The Department of Energy recognizes the importance of maintaining a healthy and fit Federal workforce. To that end, our occupational health care professionals at the Headquarters Occupational Health Clinics in Forrestal and Germantown provide the following services: Walk-in care. Assessment, nursing care and follow-up for minor illnesses and injuries on a walk-in basis. First-response. Emergency treatment to any

  6. Image Processing Occupancy Sensor - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Building Energy Efficiency Find More Like This Return to Search Image Processing Occupancy Sensor National Renewable Energy Laboratory Contact NREL About This Technology Publications: PDF Document Publication IPOS Fact Sheet (485 KB) Occupancy detection--stationary and active Occupancy detection--stationary and active Multiple independent lighting and ventilation controls Multiple independent lighting and ventilation controls Technology Marketing Summary Lighting

  7. Occupational Injury & Illness System (01&15) PIA, Idaho National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database, INL Energy Employees' Occupational Illness Compensation ...

  8. Pantex Occupational Health System (OHS), National Nuclear Security...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pantex Occupational Health System (OHS), National Nuclear Security Administration Pantex Site Office Pantex Occupational Health System (OHS), National Nuclear Security ...

  9. Occupational Medical Surveillance System (OMSS) PIA, Idaho National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (OMSS) PIA, Idaho National Laboratory More Documents & Publications Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Injury & Illness System ...

  10. Pantex Occupational Health System (OHS), National Nuclear Security...

    Energy Savers [EERE]

    Pantex Occupational Health System (OHS), National Nuclear Security Administration Pantex Site Office Pantex Occupational Health System (OHS), National Nuclear Security...

  11. Occupational Medical Surveillance System (OMSS) PIA, Idaho National...

    Energy Savers [EERE]

    (OMSS) PIA, Idaho National Laboratory More Documents & Publications Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Injury & Illness System...

  12. Energy Employees' Occupational Illness Compensation Program Act (EEOICPA)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracking Database, INL Energy Employees' Occupational Illness Compensation Program | Department of Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database, INL Energy Employees' Occupational Illness Compensation Program Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database, INL Energy Employees' Occupational Illness Compensation Program Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking

  13. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Broader source: Energy.gov (indexed) [DOE]

    Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S.

  14. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Iron Catalysis in Oxidations by Ozone Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Ozone is used commercially for treatment of potable and non-potable water, and as an industrial oxidant. ISU and Ames Laboratory researchers have developed a method for using iron in ozone oxidation that significantly improves the speed of oxidation reactions. Description Ozone is recognized as potent and effective oxidizing agent, and has a

  15. Relation between Atmospheric Ozone and Geomagnetic Disturbances (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Relation between Atmospheric Ozone and Geomagnetic Disturbances Citation Details In-Document Search Title: Relation between Atmospheric Ozone and Geomagnetic Disturbances Results are given for a study of the behavior of the mean meridional distribution of total ozone over 15 European stations (38 to 78 deg N) during severe magnetic storms. The storms studied were 14 severe geomagnetic disturbance; in 1957, 1958, and 1959, and the ozone distributions were studied

  16. Microsoft Word - Sept 2010.MeetingMinutes.FINAL

    Office of Environmental Management (EM)

    ... River Protection OSHA - Occupational Safety & Health Administration PARS - Project ... Moab remedial actions; Idaho cleanup project; Carlsbad carrier services and ...

  17. Occupant Emergency Plans | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Occupant Emergency Plans Occupant Emergency Plans On this page is the collection of Emergency Procedures documents for the Department of Energy, Headquarters buildings, in the Washington, DC, metropolitan area. Emergency Procedures Pamphlets Building Evacuation Routes Occupant Emergency Plans (OEP's) All of these documents are only available to computers attached to the DOE Network. They are for use only by DOE Headquarters employees. Any computer not on the DOE Network will get an error message

  18. Annual DOE Occupational Radiation Exposure Reports | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    employees during 1985. May 19, 2006 Annual DOE Occupational Radiation Exposure | 1984 Report The Seventeenth Annual Report of Radiation Exposures for DOE & DOE Contractor...

  19. Annual DOE Occupational Radiation Exposure | 1974 Report

    Broader source: Energy.gov [DOE]

    The Seventh Annual Report of Radiation Exposures for AEC & AEC Contractor Employees analyzes occupational radiation exposures at the Atomic Energy Commission (AEC) and its contractor employees during 1974.

  20. RSF Workshop Session IV: Occupant Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Design Decisions and Occupant...

  1. Energy Employees Occupational Illness Compensation Program Act...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Act (EEOICPA) Tracking System PIA, Office of Business Operations Energy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System PIA, Office of ...

  2. Enenrgy Employees Occupational Illness Compensation Program Act...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracking System, PIA, Savannah River Operations Office Enenrgy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System, PIA, Savannah River Operations ...

  3. Deputy Secretary Memo Regarding Energy Employees Occupational...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    These records serve as the basis for DOL and NIOSH to make informed decisions regarding claim adjudication. PDF icon Energy Employees Occupational Illness Compensation Program Act ...

  4. Real-Time Occupancy Change Analyzer

    Energy Science and Technology Software Center (OSTI)

    2005-03-30

    The Real-Time Occupancy Change Analyzer (ROCA) produces an occupancy grid map of an environment around the robot, scans the environment to generate a current obstacle map relative to a current robot position, and converts the current obstacle map to a current occupancy grid map. Changes in the occupancy grid can be reported in real time to support a number of tracking capabilities. The benefit of ROCA is that rather than only providing a vector tomore » the detected change, it provides the actual x,y position of the change.« less

  5. The 1986 residential occupant survey

    SciTech Connect (OSTI)

    Ivey, D.L.; Alley, P.K.

    1987-04-01

    In 1986, Pacific Northwest Laboratory developed the Residential Occupant Survey-Spring '86, which was implemented. The overall purpose of the study was to collect demographic, attitudinal, and behavioral data related to the use and conservation of electricity in dwellings participating in the Bonneville Power Administration's End-Use Load and Conservation Assessment Program (ELCAP). Information was collected on the respondents' perceptions of the energy efficiency of their dwelling, temperature the dwelling was kept when people were at home and awake during the last heating season, which rooms, if any, were not heated during the last heating season, number of times the dwelling was unoccupied for at least one week, number of times pets were let out of the dwelling per day, attitudes toward energy use and conservation and several socio-demographic variables such as age, sex, and total household income. The results of the data analyses showed age to be an important factor for reported indoor temperature and perceived energy efficiency of the dwelling. The results also showed that almost 60% of the ELCAP occupants do not heat one or more rooms during the heating season, and almost 45% of the ELCAP dwellings were unoccupied for at least one week during the reporting period. In terms of the reported allocation of household income for household energy expenses, the results showed that the reported dollar amount spent for the expenses remained relatively constant over income levels.

  6. DOE HQ Occupational Safety and Health Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Occupational Safety and Health Program DOE HQ Occupational Safety and Health Program HQ Occupational Safety and Health Program Procedures PDF icon DOE HQ Occupational Safety and Health Program More Documents & Publications HQ Confined Space Program, Policy 2010-001 Independent Oversight Review, Department of Energy Contractor - August 2000 FAQS Qualification Card - Occupational Safety

  7. Occupational Medical Surveillance System (OMSS) PIA, Idaho National

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory | Department of Energy Medical Surveillance System (OMSS) PIA, Idaho National Laboratory Occupational Medical Surveillance System (OMSS) PIA, Idaho National Laboratory Occupational Medical Surveillance System (OMSS) PIA, Idaho National Laboratory PDF icon Occupational Medical Surveillance System (OMSS) PIA, Idaho National Laboratory More Documents & Publications Occupational Medicine - Assistant PIA, Idaho National Laboratory Occupational Injury & Illness System

  8. Promising Technology: Wireless Lighting Occupancy Sensors

    Broader source: Energy.gov [DOE]

    Occupancy sensors and controls detect human presence, and modulate light settings accordingly. When there is no human presence detected, the system can dim or turn off lights. This technology ensures that lights are not used when there are no occupants present, which can lead to significant energy savings.

  9. Occupancy change detection system and method

    DOE Patents [OSTI]

    Bruemmer, David J. [Idaho Falls, ID; Few, Douglas A. [Idaho Falls, ID

    2009-09-01

    A robot platform includes perceptors, locomotors, and a system controller. The system controller executes instructions for producing an occupancy grid map of an environment around the robot, scanning the environment to generate a current obstacle map relative to a current robot position, and converting the current obstacle map to a current occupancy grid map. The instructions also include processing each grid cell in the occupancy grid map. Within the processing of each grid cell, the instructions include comparing each grid cell in the occupancy grid map to a corresponding grid cell in the current occupancy grid map. For grid cells with a difference, the instructions include defining a change vector for each changed grid cell, wherein the change vector includes a direction from the robot to the changed grid cell and a range from the robot to the changed grid cell.

  10. A Basic Overview of Occupational Radiation Exposure Monitoring...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting September ...

  11. Pamphlet, A Basic Overview of Occupational Radiation Exposure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pamphlet, A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting Pamphlet, A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & ...

  12. CBEI: Improving Code Compliance with Change of Occupancy Retrofits...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Code Compliance with Change of Occupancy Retrofits - 2015 Peer Review CBEI: Improving Code Compliance with Change of Occupancy Retrofits - 2015 Peer Review Presenter: Jennifer ...

  13. Wireless Occupancy Sensors for Lighting Controls: An Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wireless Occupancy Sensors for Lighting Controls: An Applications Guide for Federal ... of the energy savings potential of wireless lighting occupancy sensors for room ...

  14. Occupational Injury & Illness System (01&15) PIA, Idaho National...

    Energy Savers [EERE]

    Tracking Database, INL Energy Employees' Occupational Illness Compensation Program Occupational Medicine - Assistant PIA, Idaho National Laboratory VisitDosimBadgeTrckg-PIA.pdf...

  15. Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle Applications Potential of Thermoelectrics forOccupant Comfort and Fuel Efficiency Gains in Vehicle ...

  16. Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion

    Office of Scientific and Technical Information (OSTI)

    Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion Resources with Additional Information In 1973 Mario Molina ... was a postdoctoral researcher working in the laboratory of F. Sherwood Rowland at the University of California at Irvine ... when he made an unsettling discovery. He had been investigating a class of compounds called chlorofluorocarbons, or CFCs. CFCs were used as refrigerants, aerosol sprays, and in making plastic foams. Molina wondered what happened to them once they

  17. Ozone contactor hydraulic considerations in meeting CT disinfection

    Office of Scientific and Technical Information (OSTI)

    requirements (Journal Article) | SciTech Connect Ozone contactor hydraulic considerations in meeting CT disinfection requirements Citation Details In-Document Search Title: Ozone contactor hydraulic considerations in meeting CT disinfection requirements Tracer studies were performed in bench and pilot scale ozone diffusion contactors to determine actual contact times for the bench and pilot scale units and to characterize the flow pattern through these reactors. It was recognized that the

  18. DOE SC ARM TR 179 Thermo Scientific Ozone Analyzer Instrument...

    Office of Scientific and Technical Information (OSTI)

    ... data increment. Ozone - Mixing volume of O3 in ambient air (no water vapor correction). ... However, the supplied pressure regulator only supplies consistent gauge pressure, not ...

  19. Ozone Removal by Filters Containing Activated Carbon: A Pilot...

    Office of Scientific and Technical Information (OSTI)

    in a commercial building heating, ventilating, and air conditioning (HVAC) system. ... measurements of ozone concentrations in the air upstream and downstream of the filters. ...

  20. Cal/OSHA process safety standard update

    SciTech Connect (OSTI)

    Pourmehraban, I.

    1995-12-31

    Process Safety Management (PSM) regulation applies mainly to chemical and oil companies, plus other industries such as food processing, and paper production. It covers plants that deal with any of about 130 toxic chemicals in quantities above thresholds limits in Appendix A of PSM standard or flammable liquids and gases in quantities greater than 10,000 pounds. The State Consultation PSM teams (North and South) use a detailed audit checklist featuring above elements for audit of facilities requesting PSM assistance. The audit focuses on three generic activities: records, onsite conditions, and interviews. Records include written programs that outline the requirements and documentation of completion. Onsite conditions are implementation of activities specified in written programs. Interviews are for evaluation of transferred information to the workers that are already developed in written programs and training programs.

  1. Ozone depletion, developing countries, and human rights: Seeking better ground on which to fight for protection of the ozone layer

    SciTech Connect (OSTI)

    Williams, V.

    1995-12-31

    I urge you not to take a complacent view of the situation. The state of depletion of the ozone layer continues to be alarming... In February, 1993, the ozone levels over North America and most of Europe were 20 percent below normal... Even now, millions of tons of CFC [chlorofluorocarbon] products are en route to their fatal stratospheric rendezvous... This exponential increase calls for increased reflection on the state of the ozone layer and calls for bold decisions.

  2. Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. ...

  3. Annual DOE Occupational Radiation Exposure | 1975 Report

    Broader source: Energy.gov [DOE]

    The Eighth Annual Report of Radiation Exposures for ERDA & ERDA Contractor Employees analyzes occupational radiation exposures at the Energy Research and Development Administration (ERDA) and its contractor employees during 1975.

  4. Annual DOE Occupational Radiation Exposure | 1978 Report

    Broader source: Energy.gov [DOE]

    The Eleventh Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1978.

  5. Annual DOE Occupational Radiation Exposure | 1977 Report

    Broader source: Energy.gov [DOE]

    The Tenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1977.

  6. Annual DOE Occupational Radiation Exposure | 1976 Report

    Broader source: Energy.gov [DOE]

    The Ninth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1976.

  7. Annual DOE Occupational Radiation Exposure | 1985 Report

    Broader source: Energy.gov [DOE]

    The Eighteenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1985.

  8. DOE 2010 Occupational Radiation Exposure November 2011

    SciTech Connect (OSTI)

    U.S. Department of Energy, Office of Health, Safety and Security, Office of Analysis

    2011-11-11

    This report discusses radiation protection and dose reporting requirements, presents the 2010 occupational radiation dose data trended over the past 5 years, and includes instructions to submit successful ALARA projects.

  9. FAQS Reference Guide – Occupational Safety

    Broader source: Energy.gov [DOE]

    This reference guide has been developed to address the competency statements in the July 2011 version of DOE-STD-1160-2011, Occupational Safety Functional Area Qualification Standard.

  10. Annual DOE Occupational Radiation Exposure | 1988 Report

    Broader source: Energy.gov [DOE]

    The Twenty-first Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1988.

  11. Annual DOE Occupational Radiation Exposure | 1984 Report

    Broader source: Energy.gov [DOE]

    The Seventeenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1984.

  12. Annual DOE Occupational Radiation Exposure | 1986 Report

    Broader source: Energy.gov [DOE]

    The Nineteenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1986.

  13. Annual DOE Occupational Radiation Exposure | 1987 Report

    Broader source: Energy.gov [DOE]

    The Twentieth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1987.

  14. Annual DOE Occupational Radiation Exposure | 1991 Report

    Broader source: Energy.gov [DOE]

    The Twenty-fourth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1991.

  15. Annual DOE Occupational Radiation Exposure | 1980 Report

    Broader source: Energy.gov [DOE]

    The Thirteenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1980.

  16. Annual DOE Occupational Radiation Exposure | 1982 Report

    Broader source: Energy.gov [DOE]

    The Fifteenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1982.

  17. Annual DOE Occupational Radiation Exposure | 1979 Report

    Broader source: Energy.gov [DOE]

    The Twelfth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1979.

  18. Annual DOE Occupational Radiation Exposure | 1981 Report

    Broader source: Energy.gov [DOE]

    The Fourteenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1981.

  19. Annual DOE Occupational Radiation Exposure | 1983 Report

    Broader source: Energy.gov [DOE]

    The Sixteenth Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1983.

  20. Occupational Radiation Protection Program (10 CFR 835)

    Broader source: Energy.gov [DOE]

    The occupational radiation protection program is governed by the Rule, specified as 10 CFR 835. The requirements given in 10 CFR 835 are matters of law, punishable by civil and criminal penalties.

  1. 2014 DOE Occupational Radiation Exposure Report Appendices

    Energy Savers [EERE]

    Labor Category Occupation Code Occupation Name 562 Groundskeepers 570 Forest Workers 580 Misc. Agriculture 610 Mechanics/Repairers 641 Masons 642 Carpenters 643 Electricians 644 Painters 645 Pipe Fitter 650 Miners/Drillers 660 Misc. Repair/Construction Laborers 850 Handlers/Laborers/Helpers 110 Manager - Adminstrator 400 Sales 450 Admin. Support and Clerical 910 Military 990 Miscellaneous 681 Machinists 682 Sheet Metal Workers 690 Operators, Plant/System/Utility 710 Machine Setup/Operators 771

  2. Energy Employees Occupational Illness Compensation Program Act (EEOICPA)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracking System PIA, Office of Business Operations | Department of Energy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System PIA, Office of Business Operations Energy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System PIA, Office of Business Operations Energy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System PIA, Office of Business Operations PDF icon Energy Employees Occupational Illness

  3. PIA - Savannah River Nuclear Solution (SRNS) Energy Employees Occupational

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Illness Compensation Program Act (EEOICPA) | Department of Energy Energy Employees Occupational Illness Compensation Program Act (EEOICPA) PIA - Savannah River Nuclear Solution (SRNS) Energy Employees Occupational Illness Compensation Program Act (EEOICPA) PIA - Savannah River Nuclear Solution (SRNS) Energy Employees Occupational Illness Compensation Program Act (EEOICPA) PDF icon PIA - Savannah River Nuclear Solution (SRNS) Energy Employees Occupational Illness Compensation Program Act

  4. Pantex Occupational Health System (OHS), National Nuclear Security

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Administration Pantex Site Office | Department of Energy Pantex Occupational Health System (OHS), National Nuclear Security Administration Pantex Site Office Pantex Occupational Health System (OHS), National Nuclear Security Administration Pantex Site Office Pantex Occupational Health System (OHS), National Nuclear Security Administration Pantex Site Office PDF icon Pantex Occupational Health System (OHS), National Nuclear Security Administration Pantex Site Office More Documents &

  5. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  6. DOE Occupational Radiation Exposure, 2001 report

    SciTech Connect (OSTI)

    None, None

    2001-12-31

    The goal of the U.S. Department of Energy (DOE) is to conduct its operations, including radiological, to ensure the safety and health of all DOE employees, contractors, and subcontractors. The DOE strives to maintain radiation exposures to its workers below administrative control levels and DOE limits and to further reduce these exposures to levels that are “As Low As Reasonably Achievable” (ALARA). The 2001 DOE Occupational Radiation Exposure Report provides a summary and analysis of the occupational radiation exposure received by individuals associated with DOE activities. The DOE mission includes stewardship of the nuclear weapons stockpile and the associated facilities, environmental restoration of DOE, and energy research.

  7. Annual DOE Occupational Radiation Exposure | 1992- 1994 Report

    Broader source: Energy.gov [DOE]

    The DOE Occupational Radiation Exposure Report, 1992-1994 reports occupational radiation exposures incurred by individuals at U.S. Department of Energy (DOE) facilities from 1992 through 1994.

  8. ARM - Field Campaign - 1999 Northeast Corridor Ozone & Particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : 1999 Northeast Corridor Ozone & Particulate Study 1999.07.23 - 1999.08.11 Lead...

  9. Code of Federal Regulations OCCUPATIONAL RADIATION PROTECTION | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy OCCUPATIONAL RADIATION PROTECTION Code of Federal Regulations OCCUPATIONAL RADIATION PROTECTION The rules in this part establish radiation protection standards, limits, and program requirements for protecting individuals from ionizing radiation resulting from the conduct of DOE activities. PDF icon Code of Federal Regulations OCCUPATIONAL RADIATION PROTECTION More Documents & Publications Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION PROTECTION Subpart A - General

  10. Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION PROTECTION |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy PART 835-OCCUPATIONAL RADIATION PROTECTION Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION PROTECTION General. The rules in this part establish radiation protection standards, limits, and program requirements for protecting individuals from ionizing radiation resulting from the conduct of DOE activities. PDF icon Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION PROTECTION More Documents & Publications Order Module--NNSA OCCUPATIONAL RADIATION

  11. Federal Employee Occupational Safety And Health (FEOSH) Program Overview |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Federal Employee Occupational Safety And Health (FEOSH) Program Overview Federal Employee Occupational Safety And Health (FEOSH) Program Overview Congress established Public Law 91-596, The Occupational Safety and Health Act of 1970 (OSH Act) "to ensure so far as possible every working man and woman in the Nation safe and healthful working conditions and to preserve our human resources." PDF icon Federal Employee Occupational Safety And Health (FEOSH) Program

  12. Annual DOE Occupational Radiation Exposure | 1997 Report | Department of

    Energy Savers [EERE]

    Energy 7 Report Annual DOE Occupational Radiation Exposure | 1997 Report The DOE Occupational Radiation Exposure Report, 1997 reports occupational radiation exposures incurred by individuals at U.S. Department of Energy (DOE) facilities during the calendar year 1997. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. This information is analyzed and trended over time to provide a measure of DOE's performance in

  13. Annual DOE Occupational Radiation Exposure | 2005 Report | Department of

    Energy Savers [EERE]

    Energy 5 Report Annual DOE Occupational Radiation Exposure | 2005 Report The DOE 2005 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2005. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. The 101 DOE organizations submitting radiation exposure reports for 2005 have been grouped into 26 geographic sites across the complex.

  14. Annual DOE Occupational Radiation Exposure | 2011 Report | Department of

    Energy Savers [EERE]

    Energy 1 Report Annual DOE Occupational Radiation Exposure | 2011 Report The DOE 2011 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2011. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. The 107 DOE organizations submitting radiation exposure reports for 2011 have been grouped into 32 sites. This information has been

  15. Annual DOE Occupational Radiation Exposure | 2012 Report | Department of

    Energy Savers [EERE]

    Energy 2 Report Annual DOE Occupational Radiation Exposure | 2012 Report The DOE 2012 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2012. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. The 94 DOE organizations submitting radiation exposure reports for 2012 have been grouped into 32 sites. This information has been analyzed

  16. Annual DOE Occupational Radiation Exposure | 2013 Report | Department of

    Energy Savers [EERE]

    Energy 3 Report Annual DOE Occupational Radiation Exposure | 2013 Report The DOE 2013 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2013. This report includes occupational radiation exposure information for all DOE employees, contractors, and subcontractors, as well as members of the public in controlled areas that are monitored for exposure to radiation. The 105 DOE organizations submitting radiation

  17. 2015 DOE Annual Occupational Medicine Workshop & Webinar (OMWW) - March

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    16-17, 2015 | Department of Energy DOE Annual Occupational Medicine Workshop & Webinar (OMWW) - March 16-17, 2015 2015 DOE Annual Occupational Medicine Workshop & Webinar (OMWW) - March 16-17, 2015 December 18, 2014 - 3:13pm Addthis 2015 DOE Annual Occupational Medicine Workshop & Webinar (OMWW) - March 16-17, 2015 The DOE Annual Occupational Medicine Workshop & Webinar (OMWW) is a valuable training opportunity established by the Office of Health, Safety, and Security in

  18. Annual DOE Occupational Radiation Exposure | 2006 Report | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 06 Report Annual DOE Occupational Radiation Exposure | 2006 Report The DOE 2006 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2006. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. The 95 DOE organizations submitting radiation exposure reports for 2006 have been grouped into 34 sites across the complex. This

  19. CRAD, Occupational Radiation Protection Program- December 4, 2012

    Broader source: Energy.gov [DOE]

    Occupational Radiation Protection Program Inspection Criteria, Approach, and Lines of Inquiry (HSS CRAD 45-35, Rev. 1)

  20. ORO Energy Employees Occupational Illness Compensation Program(EEOICPA)PIA,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oak Ridge Operations Office | Department of Energy Energy Employees Occupational Illness Compensation Program(EEOICPA)PIA, Oak Ridge Operations Office ORO Energy Employees Occupational Illness Compensation Program(EEOICPA)PIA, Oak Ridge Operations Office ORO Energy Employees Occupational Illness Compensation Program(EEOICPA)PIA, Oak Ridge Operations Office PDF icon ORO Energy Employees Occupational Illness Compensation Program(EEOICPA)PIA, Oak Ridge Operations Office More Documents &

  1. A Review of High Occupancy Vehicle (HOV) Lane Performance and...

    Open Energy Info (EERE)

    URI: cleanenergysolutions.orgcontentreview-high-occupancy-vehicle-hov-lan Language: English Policies: Deployment Programs DeploymentPrograms: Demonstration & Implementation This...

  2. Occupational Health Manager PIA, Carlsbad Field Office | Department...

    Energy Savers [EERE]

    Health Manager PIA, Carlsbad Field Office More Documents & Publications Occupational Medicine - Assistant PIA, Idaho National Laboratory Integrated Safety Management Workshop...

  3. Annual DOE Occupational Radiation Exposure | 2000 Report | Department of

    Office of Environmental Management (EM)

    Energy 0 Report Annual DOE Occupational Radiation Exposure | 2000 Report The DOE 2000 Occupational Radiation Exposure Report analyzes occupational radiation exposures at U.S. Department of Energy (DOE) facilities during 2000. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. The 104 DOE organizations submitting radiation exposure reports for 2000 have been grouped into 28 geographic sites across the complex.

  4. Process-scale modeling of elevated wintertime ozone in Wyoming.

    SciTech Connect (OSTI)

    Kotamarthi, V. R.; Holdridge, D. J.; Environmental Science Division

    2007-12-31

    Measurements of meteorological variables and trace gas concentrations, provided by the Wyoming Department of Environmental Quality for Daniel, Jonah, and Boulder Counties in the state of Wyoming, were analyzed for this project. The data indicate that highest ozone concentrations were observed at temperatures of -10 C to 0 C, at low wind speeds of about 5 mph. The median values for nitrogen oxides (NOx) during these episodes ranged between 10 ppbv and 20 ppbv (parts per billion by volume). Measurements of volatile organic compounds (VOCs) during these periods were insufficient for quantitative analysis. The few available VOCs measurements indicated unusually high levels of alkanes and aromatics and low levels of alkenes. In addition, the column ozone concentration during one of the high-ozone episodes was low, on the order of 250 DU (Dobson unit) as compared to a normal column ozone concentration of approximately 300-325 DU during spring for this region. Analysis of this observation was outside the scope of this project. The data analysis reported here was used to establish criteria for making a large number of sensitivity calculations through use of a box photochemical model. Two different VOCs lumping schemes, RACM and SAPRC-98, were used for the calculations. Calculations based on this data analysis indicated that the ozone mixing ratios are sensitive to (a) surface albedo, (b) column ozone, (c) NOx mixing ratios, and (d) available terminal olefins. The RACM model showed a large response to an increase in lumped species containing propane that was not reproduced by the SAPRC scheme, which models propane as a nearly independent species. The rest of the VOCs produced similar changes in ozone in both schemes. In general, if one assumes that measured VOCs are fairly representative of the conditions at these locations, sufficient precursors might be available to produce ozone in the range of 60-80 ppbv under the conditions modeled.

  5. FAQS Gap Analysis Qualification Card - Occupational Safety | Department

    Energy Savers [EERE]

    of Energy Occupational Safety FAQS Gap Analysis Qualification Card - Occupational Safety Functional Area Qualification Standard Gap Analysis Qualification Cards outline the differences between the last and latest version of the FAQ Standard. File Occupational Safety Gap Analysis Qualification Card More Documents & Publications FAQS Gap Analysis Qualification Card - Environmental Restoration FAQS Gap Analysis Qualification Card - Waste Management FAQS Gap Analysis Qualification Card -

  6. Enenrgy Employees Occupational Illness Compensation Program Act (EEOICPA)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tracking System, PIA, Savannah River Operations Office | Department of Energy Enenrgy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System, PIA, Savannah River Operations Office Enenrgy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System, PIA, Savannah River Operations Office Enenrgy Employees Occupational Illness Compensation Program Act (EEOICPA) Tracking System, PIA, Savannah River Operations Office PDF icon Enenrgy Employees

  7. ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE

    SciTech Connect (OSTI)

    Ketusky, E.; Subramanian, K.

    2012-02-29

    At the Savannah River Site (SRS), oxalic acid is currently considered the preferred agent for chemically cleaning the large underground Liquid Radioactive Waste Tanks. It is applied only in the final stages of emptying a tank when generally less than 5,000 kg of waste solids remain, and slurrying based removal methods are no-longer effective. The use of oxalic acid is preferred because of its combined dissolution and chelating properties, as well as the fact that corrosion to the carbon steel tank walls can be controlled. Although oxalic acid is the preferred agent, there are significant potential downstream impacts. Impacts include: (1) Degraded evaporator operation; (2) Resultant oxalate precipitates taking away critically needed operating volume; and (3) Eventual creation of significant volumes of additional feed to salt processing. As an alternative to dealing with the downstream impacts, oxalate decomposition using variations of ozone based Advanced Oxidation Process (AOP) were investigated. In general AOPs use ozone or peroxide and a catalyst to create hydroxyl radicals. Hydroxyl radicals have among the highest oxidation potentials, and are commonly used to decompose organics. Although oxalate is considered among the most difficult organic to decompose, the ability of hydroxyl radicals to decompose oxalate is considered to be well demonstrated. In addition, as AOPs are considered to be 'green' their use enables any net chemical additions to the waste to be minimized. In order to test the ability to decompose the oxalate and determine the decomposition rates, a test rig was designed, where 10 vol% ozone would be educted into a spent oxalic acid decomposition loop, with the loop maintained at 70 C and recirculated at 40L/min. Each of the spent oxalic acid streams would be created from three oxalic acid strikes of an F-area simulant (i.e., Purex = high Fe/Al concentration) and H-area simulant (i.e., H area modified Purex = high Al/Fe concentration) after nearing dissolution equilibrium, and then decomposed to {le} 100 Parts per Million (ppm) oxalate. Since AOP technology largely originated on using ultraviolet (UV) light as a primary catalyst, decomposition of the spent oxalic acid, well exposed to a medium pressure mercury vapor light was considered the benchmark. However, with multi-valent metals already contained in the feed, and maintenance of the UV light a concern; testing was conducted to evaluate the impact from removing the UV light. Using current AOP terminology, the test without the UV light would likely be considered an ozone based, dark, ferrioxalate type, decomposition process. Specifically, as part of the testing, the impacts from the following were investigated: (1) Importance of the UV light on the decomposition rates when decomposing 1 wt% spent oxalic acid; (2) Impact of increasing the oxalic acid strength from 1 to 2.5 wt% on the decomposition rates; and (3) For F-area testing, the advantage of increasing the spent oxalic acid flowrate from 40 L/min (liters/minute) to 50 L/min during decomposition of the 2.5 wt% spent oxalic acid. The results showed that removal of the UV light (from 1 wt% testing) slowed the decomposition rates in both the F & H testing. Specifically, for F-Area Strike 1, the time increased from about 6 hours to 8 hours. In H-Area, the impact was not as significant, with the time required for Strike 1 to be decomposed to less than 100 ppm increasing slightly, from 5.4 to 6.4 hours. For the spent 2.5 wt% oxalic acid decomposition tests (all) without the UV light, the F-area decompositions required approx. 10 to 13 hours, while the corresponding required H-Area decompositions times ranged from 10 to 21 hours. For the 2.5 wt% F-Area sludge, the increased availability of iron likely caused the increased decomposition rates compared to the 1 wt% oxalic acid based tests. In addition, for the F-testing, increasing the recirculation flow rates from 40 liter/minute to 50 liter/minute resulted in an increased decomposition rate, suggesting a better use of ozone.

  8. Projections of Future Summertime Ozone over the U.S.

    SciTech Connect (OSTI)

    Pfister, G. G.; Walters, Stacy; Lamarque, J. F.; Fast, Jerome D.; Barth, Mary; Wong, John; Done, James; Holland, Greg; Bruyere, Cindy

    2014-05-05

    This study uses a regional fully coupled chemistry-transport model to assess changes in surface ozone over the summertime U.S. between present and a 2050 future time period at high spatial resolution (12 km grid spacing) under the SRES A2 climate and RCP8.5 anthropogenic pre-cursor emission scenario. The impact of predicted changes in climate and global background ozone is estimated to increase surface ozone over most of the U.S; the 5th - 95th percentile range for daily 8-hour maximum surface ozone increases from 31-79 ppbV to 30-87 ppbV between the present and future time periods. The analysis of a set of meteorological drivers suggests that these mostly will add to increasing ozone, but the set of simulations conducted does not allow to separate this effect from that through enhanced global background ozone. Statistically the most robust positive feedbacks are through increased temperature, biogenic emissions and solar radiation. Stringent emission controls can counteract these feedbacks and if considered, we estimate large reductions in surface ozone with the 5th-95th percentile reduced to 27-55 ppbV. A comparison of the high-resolution projections to global model projections shows that even though the global model is biased high in surface ozone compared to the regional model and compared to observations, both the global and the regional model predict similar changes in ozone between the present and future time periods. However, on smaller spatial scales, the regional predictions show more pronounced changes between urban and rural regimes that cannot be resolved at the coarse resolution of global model. In addition, the sign of the changes in overall ozone mixing ratios can be different between the global and the regional predictions in certain regions, such as the Western U.S. This study confirms the key role of emission control strategies in future air quality predictions and demonstrates the need for considering degradation of air quality with future climate change in emission policy making. It also illustrates the need for high resolution modeling when the objective is to address regional and local air quality or establish links to human health and society.

  9. DOE occupational radiation exposure 2000 report

    SciTech Connect (OSTI)

    none,

    2000-12-31

    The U.S. Department of Energy (DOE) Office of Safety and Health publishes the annual DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE and DOE contractor managers in managing radiological safety programs and to assist them in prioritizing resources. We appreciate the efforts and contributions from the various stakeholders within and outside DOE in making this report most useful to them. This report includes occupational radiation exposure information for all monitored DOE employees, contractors, subcontractors, and visitors. The exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  10. DOE occupational radiation exposure 1998 report

    SciTech Connect (OSTI)

    none,

    1998-12-31

    The U.S. Department of Energy (DOE) Office of Environment, Safety and Health with support from Environment Safety and Health Technical Information Services publishes the DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE/DOE contractor managers in managing radiological safety programs and to assist them in prioritizing resources. We appreciate the efforts and contributions from the various stakeholders within and outside DOE and hope we have succeeded in making the report more useful. This report includes occupational radiation exposure information for all monitored DOE employees, contractors, subcontractors, and visitors. The exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  11. DOE occupational radiation exposure 1997 report

    SciTech Connect (OSTI)

    none,

    1997-12-31

    The U.S. Department of Energy (DOE) Office of Environment, Safety and Health publishes the DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE/DOE contractor managers in managing radiological safety programs and to assist them in prioritizing resources. We appreciate the efforts and contributions from the various stakeholders within and outside DOE and hope we have succeeded in making the report more useful. This report includes occupational radiation exposure information for all monitored DOE employees, contractors, subcontractors, and visitors. The exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  12. DOE occupational radiation exposure 1996 report

    SciTech Connect (OSTI)

    none,

    1996-12-31

    The U.S. Department of Energy (DOE) Office of Environment, Safety and Health publishes the DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE/DOE contractor managers in their management of radiological safety programs and to assist them in the prioritization of resources. We appreciate the efforts and contributions from the various stakeholders within and outside the DOE and hope we have succeeded in making the report more useful. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. The exposure information is analyzed in terms of collective data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  13. DOE occupational radiation exposure 2004 report

    SciTech Connect (OSTI)

    none,

    2004-12-31

    The U.S. Department of Energy (DOE) Office of Corporate Performance Assessment (EH-3) publishes the annual DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE and DOE contractor managers and workers in managing radiological safety programs and to assist them in prioritizing resources. We appreciate the efforts and contributions from the various stakeholders within and outside DOE to make the report most useful. This report includes occupational radiation exposure information for all monitored DOE employees, contractors, and subcontractors, as well as members of the public. DOE is defined to include the National Nuclear Security Administration sites. The exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  14. DOE occupational radiation exposure 2002 report

    SciTech Connect (OSTI)

    none,

    2002-12-31

    The U.S. Department of Energy (DOE) Office of Corporate Performance Assessment (EH-3) publishes the annual DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE and DOE contractor managers and workers in managing radiological safety programs and to assist them in prioritizing resources. We appreciate the efforts and contributions from the various stakeholders within and outside DOE to make the report most useful. This report includes occupational radiation exposure information for all monitored DOE employees, contractors, subcontractors, and members of the public. The exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  15. DOE occupational radiation exposure 2003 report

    SciTech Connect (OSTI)

    none,

    2003-12-31

    The U.S. Department of Energy (DOE) Office of Corporate Performance Assessment (EH-3) publishes the annual DOE Occupational Radiation Exposure Report. This report is intended to be a valuable tool for DOE and DOE contractor managers and workers in managing radiological safety programs and to assist them in prioritizing resources. We appreciate the efforts and contributions from the various stakeholders within and outside DOE to make the report most useful. This report includes occupational radiation exposure information for all monitored DOE employees, contractors, subcontractors, and members of the public. DOE is defined to include the National Nuclear Security Administration sites. The exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. For the purposes of examining trends, data for the past 5 years are included in the analysis.

  16. Morphological basis of tolerance to ozone

    SciTech Connect (OSTI)

    Evans, M.J.; Dekker, N.P.; Cabral-Anderson, L.J.; Shami, S.G.

    1985-06-01

    The purpose of this research was to study Type 1 epithelial cells in the ozone (O/sub 3/)-tolerant lung epithelium. Rats were made tolerant by exposure to 0.5 ppm O/sub 3/ for 2 days and allowed to recover in air. Reexposure to a lethal concentration of O/sub 3/ (6 ppm) at 3, 7, and 15 days of recovery revealed that tolerance was present at 3 days but almost absent at 7 and 15 days of recovery. Using Type 2 cell proliferation as a means of quantitating Type 1 cell injury, it was observed that when the preexposed rats were reexposed to 0.5 ppm at 3, 7, and 15 days, very little Type 1 cell injury occurred at 3 days. However, at 7 and 15 days the amount of Type 1 cell injury was the same as that associated with the original exposure. To determine whether there was any change in the alveolar epithelial cell populations between the periods of tolerance (3 days) and its decline (7 and 15 days), the percentage of tritiated thymidine (( /sup 3/H)TdR-labeled Type 1 and 2 cells at these times were determined. There was a significant decrease in (/sup 3/H)TdR-labeled Type 1 and 2 cells between the third and fifteenth days of recovery as excess cells were sloughed off and the tissue returned to normal. Using electron microscopic morphometry, Type 1 and 2 cells were then studied during the decline of tolerance. No change was found in the morphology of Type 2 cells; however, the morphology of Type 1 cells revealed a 58% decrease in surface area and a 25% increase in the arithmetic mean thickness when tolerance was present at 3 days. As tolerance declined (7 and 15 days), Type 1 cell morphology returned to normal. It was concluded that tolerance exists when the surface area of a cell exposed to a particular concentration of ozone is small enough so that the existing antioxidant mechanism contained within that cell volume can protect it from damage.

  17. PRIVACY IMPACT ASSESSMENT: INL Energy Employees' Occupational

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * PRIVACY IMPACT ASSESSMENT: INL Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database PIA Template Version 3 - May, 2009 Department of Energy Privacy Impact Assessment (PIA) Guidance Is provided In the template. See DOE Order 206.1, Department of Energy Privacy Program, Appendix A, Privacy Impact Assessments, for requirements and additional guidance for conducting a PIA: http://www.directives.doe.gov/pdfs/doe/doetextlneword/206/o2061.pdf Please complete

  18. Job Seekers - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Job Seekers About HPMC OMS Contact Us Directions Event Calendar Hours of Operation How We Compare Job Seekers Notice of Privacy Practices Patient Rights & Responsibilities Frequently Asked Questions Job Seekers Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size Search the links below for positions available to interested candidates. Candidates selected for positions with HPMC Occupational Medical Services are hired and employed by either HPM Corporation or

  19. Headquarters Occupational Safety and Health Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-11-03

    To implement the Occupational Safety and Health Program for Department of Energy (DOE) Headquarters employees as an element of the DOE Integrated Safety Management System. Cancels: HQ 3790.2A. Canceled by DOE O 251.91. This directive was reviewed and certified as current and necessary by Bruce M. Carnes, Director, Office of Management, Budget and Evaluation/Chief Financial Officer, 9/18/02. Canceled by DOE N 251.91.

  20. Revealing Occupancy Patterns in Office Buildings Through the use of Annual Occupancy Sensor Data

    SciTech Connect (OSTI)

    Carlos Duarte; Kevin Van Den Wymelenberg; Craig Rieger

    2013-06-01

    Energy simulation programs like DOE-2 and EnergyPlus are tools that have been proven to aid with energy calculations to predict energy use in buildings. Some inputs to energy simulation models are relatively easy to find, including building size, orientation, construction materials, and HVAC system size and type. Others vary with time (e.g. weather and occupancy) and some can be a challenge to estimate in order to create an accurate simulation. In this paper, the analysis of occupancy sensor data for a large commercial, multi-tenant office building is presented. It details occupancy diversity factors for private offices and summarizes the same for open offices, hallways, conference rooms, break rooms, and restrooms in order to better inform energy simulation parameters. Long-term data were collected allowing results to be presented to show variations of occupancy diversity factors in private offices for time of day, day of the week, holidays, and month of the year. The diversity factors presented differ as much as 46% from those currently published in ASHRAE 90.1 2004 energy cost method guidelines, a document referenced by energy modelers regarding occupancy diversity factors for simulations. This may result in misleading simulation results and may introduce inefficiencies in the final equipment and systems design.

  1. Real-World Studies of Ambient Ozone Formation as a Function of...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California ...

  2. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F.

    2007-05-15

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  3. Occupational ALARA Program Guide for Use with Title 10, CFR, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-03-17

    This Guide provides an acceptable methodology for establishing and operating an occupational "as low as is reasonably achievable" (ALARA) program that will comply with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection (DOE 1998a), hereinafter referred to as 10 CFR 835. For completeness, this Guide also references detailed guidance provided in the DOE-STD-1098-99, RADIOLOGICAL CONTROL (DOE 1999a), hereinafter referred to as the RCS.

  4. Impact of heterogeneous chemistry on model predictions of ozone changes

    SciTech Connect (OSTI)

    Granier, C.; Brasseur, G. )

    1992-11-20

    A two-dimensional chemical/transport model of the middle atmosphere is used to assess the importance of chemical heterogeneous processes in the polar regions (on polar stratospheric clouds (PSCs)) and at other latitudes (on sulfate aerosols). When conversion on type I and type II PSCs of N[sub 2]O[sub 5] into HNO[sub 3] and of CIONO[sub 2] into reactive forms of chlorine is taken into account, enhanced CIO concentrations lead to the formation of a springtime ozone hole over the Antarctic continent; no such major reduction in the ozone column is found in the Arctic region. When conversion of nitrogen and chlorine compounds is assumed to occur on sulfate particles in the lower stratosphere, significant perturbations in the chemistry are also found. For background aerosol conditions, the concentration of nitric acid is enhanced and agrees with observed values, while that of nitrogen oxides is reduced and agrees less than if heterogeneous processes are ignored in the calculations. The concentration of the OH radical is significantly increased. Ozone number density appears to become larger between 16 and 30 km but smaller below 16 km, especially at high latitudes. The ozone column is only slightly modified, except at high latitudes where it is substantially reduced if the CIONO[sub 2] conversion into reactive chlorine is considered. After a large volcanic eruption these changes are further exacerbated. The ozone budget in the lower stratrosphere becomes less affected by nitrogen oxides but is largely controlled by the CIO[sub x] and HO[sub x] chemistries. A substantial decrease in the ozone column is predicted as a result of the Pinatubo volcanic eruption, mostly in winter at middle and high latitudes. 62 refs., 18 figs., 3 tabs.

  5. Systems and methods for sensing occupancy

    DOE Patents [OSTI]

    Dasu, Aravind; Mathias, Dean; Liu, Chenguang; Christensen, Randy; Christensen, Bruce

    2014-09-09

    A computer implemented method for sensing occupancy of a workspace includes creating a difference image that represents luminance differences of pixels in past and current images of the workspace resulting from motion in the workspace, determining motion occurring in regions of the workspace based on the difference image, and altering a workspace environment based at least in part on the determined motion. The method also includes determining which pixels in the difference image represent persistent motion that can be ignored and determining which pixels representing motion in the difference image are invalid because the pixels are isolated from other pixels representing motion.

  6. DOE 2008 Occupational Radiation Exposure October 2009

    SciTech Connect (OSTI)

    U.S. Department of Energy, Office of Health, Safety and Security

    2009-10-01

    A major priority of the U.S. Department of Energy (DOE) is to ensure the health, safety, and security of DOE employees, contractors, and subcontractors. The Office of Health, Safety and Security (HSS) provides the corporate-level leadership and strategic vision necessary to better coordinate and integrate health, safety, environment, security, enforcement, and independent oversight programs. One function that supports this mission is the DOE Corporate Operating Experience Program that provides collection, analysis, and dissemination of performance indicators, such as occupational radiation exposure information. This analysis supports corporate decision-making and synthesizes operational information to support continuous environment, safety, and health improvement across the DOE complex.

  7. Occupational Safety Review of High Technology Facilities

    SciTech Connect (OSTI)

    Lee Cadwallader

    2005-01-31

    This report contains reviews of operating experiences, selected accident events, and industrial safety performance indicators that document the performance of the major US DOE magnetic fusion experiments and particle accelerators. These data are useful to form a basis for the occupational safety level at matured research facilities with known sets of safety rules and regulations. Some of the issues discussed are radiation safety, electromagnetic energy exposure events, and some of the more widespread issues of working at height, equipment fires, confined space work, electrical work, and other industrial hazards. Nuclear power plant industrial safety data are also included for comparison.

  8. CBEI: Improving Code Compliance with Change of Occupancy Retrofits - 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Review | Department of Energy Improving Code Compliance with Change of Occupancy Retrofits - 2015 Peer Review CBEI: Improving Code Compliance with Change of Occupancy Retrofits - 2015 Peer Review Presenter: Jennifer Senick, Rutgers View the Presentation PDF icon CBEI: Improving Code Compliance with Change of Occupancy Retrofits - 2015 Peer Review More Documents & Publications Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of

  9. Wireless Occupancy Sensors for Lighting Controls: An Applications Guide for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal Facility Managers | Department of Energy Occupancy Sensors for Lighting Controls: An Applications Guide for Federal Facility Managers Wireless Occupancy Sensors for Lighting Controls: An Applications Guide for Federal Facility Managers This fact sheet provides federal facility managers with an overview of the energy savings potential of wireless lighting occupancy sensors for room types, cost considerations, key steps to successful installation of wireless sensors, pros and cons of

  10. A Basic Overview of the Energy Employees Occupational Illness Compensation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program | Department of Energy Policy, Guidance & Reports » Worker Health & Safety » A Basic Overview of the Energy Employees Occupational Illness Compensation Program A Basic Overview of the Energy Employees Occupational Illness Compensation Program January 2015 A Basic Overview of the Energy Employees Occupational Illness Compensation Program This pamphlet is developed by the Department of Energy (DOE) as an outreach and awareness tool to assist former and current DOE Federal,

  11. 2015 DOE Annual Occupational Medicine Workshop and Webinar (OMWW) |

    Energy Savers [EERE]

    Department of Energy 15 DOE Annual Occupational Medicine Workshop and Webinar (OMWW) 2015 DOE Annual Occupational Medicine Workshop and Webinar (OMWW) March 16-17, 2015 DOE Annual Occupational Medicine Workshop and Webinar (OMWW): Registration, Directions, Lodging, and Access REGISTRATION AND CONFERENCE SYSTEM The 2015 DOE Annual OMWW will be held March 16-17 in the Small Auditorium on the ground floor of the DOE Headquarters Forrestal Building in Washington, DC. Registration for the 2015

  12. Annual DOE Occupational Radiation Exposure | 1989 Report | Department of

    Energy Savers [EERE]

    Energy 89 Report Annual DOE Occupational Radiation Exposure | 1989 Report The Twenty-second Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1989. This report includes occupational radiation exposure information for all DOE employees and contractors that are monitored for exposure to radiation. This information has been analyzed and trends over time

  13. Annual DOE Occupational Radiation Exposure | 1990 Report | Department of

    Energy Savers [EERE]

    Energy 90 Report Annual DOE Occupational Radiation Exposure | 1990 Report The Twenty-third Annual Report of Radiation Exposures for DOE & DOE Contractor Employees analyzes occupational radiation exposures at the U.S. Department of Energy (DOE) and its contractor employees during 1990. This report includes occupational radiation exposure information for all DOE employees and contractors that are monitored for exposure to radiation. This information has been analyzed and trends over time

  14. Energy Employees Occupational Illness Compensation Program | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Energy Employees Occupational Illness Compensation Program Energy Employees Occupational Illness Compensation Program The Energy Employees Occupational Illness Compensation Program Act (EEOICPA) was enacted to provide compensation and medical benefits to employees who worked at certain Department of Energy (DOE) facilities, including contractors and subcontractors at those locations, and certain of its vendors. Adjudication of issues pertaining to all claims for benefits under the

  15. Energy Employees Occupational Illness Compensation Program | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Energy Employees Occupational Illness Compensation Program Energy Employees Occupational Illness Compensation Program The Energy Employees Occupational Illness Compensation Program Act (EEOICPA) was enacted to provide compensation and medical benefits to employees who worked at certain Department of Energy (DOE) facilities, including contractors and subcontractors at those locations, and certain of its vendors. Adjudication of issues pertaining to all claims for benefits under the

  16. LM Records Handling System (LMRHS01) - Energy Employees Occupational

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Illness Compensation Program Act, Office of Legacy Management | Department of Energy Energy Employees Occupational Illness Compensation Program Act, Office of Legacy Management LM Records Handling System (LMRHS01) - Energy Employees Occupational Illness Compensation Program Act, Office of Legacy Management LM Records Handling System (LMRHS01) - Energy Employees Occupational Illness Compensation Program Act, Office of Legacy Management PDF icon LM Records Handling System (LMRHS01) - Energy

  17. Occupational Radiation Exposures at the Department of Energy | Department

    Energy Savers [EERE]

    of Energy Occupational Radiation Exposures at the Department of Energy Occupational Radiation Exposures at the Department of Energy Nimi Rao*, U.S. Department of Energy ; Derek Hagemeyer, Oak Ridge Institute for Science and Education Abstract: The DOE Radiation Exposure Monitoring System (REMS) project began in 1969 under the AEC and has undergone significant evolutions since inception. The system serves as the central repository for occupational radiation exposure records for all

  18. FAQS Job Task Analyses - Occupational Safety | Department of Energy

    Energy Savers [EERE]

    Occupational Safety FAQS Job Task Analyses - Occupational Safety FAQS Job Task Analyses are performed on the Function Area Qualification Standards. The FAQS Job Task Analyses consists of: Developing a comprehensive list of tasks that define the job such as the duties and responsibilities which include determining their levels of importance and frequency. Identifying and evaluating competencies. Last step is evaluating linkage between job tasks and competencies. PDF icon FAQS JTA - Occupational

  19. Order Module--NNSA OCCUPATIONAL RADIATION PROTECTION | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NNSA OCCUPATIONAL RADIATION PROTECTION Order Module--NNSA OCCUPATIONAL RADIATION PROTECTION The familiar level of this module is designed to provide the basic information to meet the requirements that are related to 10 CFR 835, "Occupational Radiation Protection," in the following DOE Functional Area Qualification Standards: DOE-STD-1177-2004, Emergency Management DOE-STD-1151-2002, Facility Representative DOE-STD-1146-2007, General Technical Base DOE-STD-1138-2007, Industrial Hygiene

  20. Code of Federal Regulations Occupational Radiation Protection; Final Rule |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Occupational Radiation Protection; Final Rule Code of Federal Regulations Occupational Radiation Protection; Final Rule The Department of Energy (DOE) is amending its primary standards for occupational radiation protection. This final rule is the culmination of a systematic analysis to identify the elements of a comprehensive radiation protection program and determine those elements of such a program that should be codified as DOE continues its transition from a system

  1. Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION PROTECTION

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Subpart A - General Provisions | Department of Energy PART 835-OCCUPATIONAL RADIATION PROTECTION Subpart A - General Provisions Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION PROTECTION Subpart A - General Provisions The rules in this part establish radiation protection standards, limits, and program requirements for protecting individuals from ionizing radiation resulting from the conduct of DOE activities. PDF icon Code of Federal Regulations PART 835-OCCUPATIONAL RADIATION

  2. Energy Employees Occupational Illness Compensation Program Act (EEOICPA)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program | Department of Energy Energy Employees Occupational Illness Compensation Program Act (EEOICPA) Program Energy Employees Occupational Illness Compensation Program Act (EEOICPA) Program EEOICPA Program The U.S. Department of Labor (DOL) administers the EEOICPA Program. For information on how to submit an EEOICPA claim, please go to: U.S. Department of Labor, Division of Energy Employees Occupational Illness Compensation DOE's role is to provide requested record information to DOL.

  3. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V.; Gordon, C.J.; Jarema, K.A.; MacPhail, R.C.; Cascio, W.E.; Phillips, P.M.; Ledbetter, A.D.; Schladweiler, M.C.; Andrews, D.; Miller, D.; Doerfler, D.L.; Kodavanti, U.P.

    2013-12-15

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: Air pollutants have been associated with increased diabetes in humans. Acute ozone exposure produces profound metabolic alterations in rats. Age influences metabolic risk factors in aging BN rats. Acute metabolic effects are reversible and repeated exposure reduces these effects. Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  4. Coordinated NO{sub x} control strategies: Phase II Title IV, ozone transport region and ozone transport assessment group

    SciTech Connect (OSTI)

    Frazier, W.F.; Dunn, R.M.; Baublis, D.C.

    1998-12-31

    Many electric utilities are faced with future nitrogen oxides (NO{sub x}) reduction requirements. In some instances, these utilities will be affected by multiple regulatory programs. For example, numerous fossil fired plants must comply with Phase II of Title IV of the Clean Air Act Amendments of 1990 (CAAA), state NO{sub x} rules as a result of the recommendations of the Ozone Transport Commission (OTC) and future requirements of the Proposed Rule for Reducing Regional Transport of Ground-Level Ozone (Ozone Transport SIP Rulemaking). This paper provides an overview of NO{sub x} regulatory programs, NO{sub x} compliance planning concepts, and NO{sub x} control technology options that could be components of an optimized compliance strategy.

  5. Wireless Occupancy Sensors for Lighting Controls: An Applications...

    Office of Scientific and Technical Information (OSTI)

    for Lighting Controls: An Applications Guide for Federal Facility Managers Citation Details In-Document Search Title: Wireless Occupancy Sensors for Lighting Controls: An ...

  6. Hawaii Clean Energy Iniative Use and Occupancy Permit | Open...

    Open Energy Info (EERE)

    Reference LibraryAdd to library PermittingRegulatory Guidance - Instructions: Hawaii Clean Energy Iniative Use and Occupancy PermitPermittingRegulatory GuidanceInstructions...

  7. CRAD, Occupational Safety & Health - Los Alamos National Laboratory...

    Office of Environmental Management (EM)

    & Health - Los Alamos National Laboratory TA 55 SST Facility CRAD, Occupational Safety & Health - Los Alamos National Laboratory TA 55 SST Facility A section of Appendix C to DOE...

  8. PIA - Richland Occupational Injury and Illness | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injury and Illness More Documents & Publications Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory PIA - Bonneville Power Adminstration Ethics Helpline

  9. Fiscal Year 2013 Department of Energy Annual Occupational Safety...

    Office of Environmental Management (EM)

    Fiscal Year 2013 Department of Energy Annual Occupational Safety and Health Report for Federal Employees to the Secretary of Labor Fiscal Year 2013 Department of Energy Annual ...

  10. PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational...

    Energy Savers [EERE]

    PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational Health and Safety Medical System (OHS) (Includes the Drug and Alcohol Testing System (Assistant)) PIA - Savannah...

  11. PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Alcohol Testing System (Assistant)) PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational Health and Safety Medical System (OHS) (Includes the Drug and Alcohol ...

  12. DOE occupational radiation exposure 1996 report

    SciTech Connect (OSTI)

    1996-12-31

    The goal of the US Department of Energy (DOE) is to conduct its radiological operations to ensure the health and safety of all DOE employees including contractors and subcontractors. The DOE strives to maintain radiation exposures to its workers below administrative control levels and DOE limits and to further reduce these exposures and releases to levels that are ``As Low As Reasonably Achievable`` (ALARA). The DOE Occupational Radiation Exposure Report, 1996 provides summary and analysis of the occupational radiation exposure received by individuals associated with DOE activities. The DOE mission includes stewardship of the nuclear weapons stockpile and the associated facilities, environmental restoration of DOE and precursor agency sites, and energy research. Collective exposure at DOE has declined by 80% over the past decade due to a cessation in opportunities for exposure during the transition in DOE mission from weapons production to cleanup, deactivation and decommissioning, and changes in reporting requirements and dose calculation methodology. In 1996, the collective dose decreased by 10% from the 1995 value due to decreased doses at five of the seven highest-dose DOE sites. For 1996, these sites attributed the reduction in collective dose to the completion of several decontamination and decommissioning projects, reduced spent fuel storage activities, and effective ALARA practices. This report is intended to be a valuable tool for managers in their management of radiological safety programs and commitment of resources.

  13. Occupant radon exposure in houses with basements

    SciTech Connect (OSTI)

    Franklin, E.M.; Fuoss, S.

    1995-12-31

    This study compares basement and main-level radon exposure based on bi-level week-long radon measurements, occupancy and activity data collected in normal use during heating and non-heating seasons in a geographically-stratified random sample of about 600 Minnesota homes, in response to critiques of radon measurement protocol. Basement radon (RN1) (M=4.5, SD=4.5) and main level (Rn2)(M=2.9, SD=3.4) correlation was 0.8 (p=.00), including seasonal variation. In a 101-house subsample where Rn1 >=4.0 pCi/L and Rn2 <=3.9 pCi/L, maximum household exposure in basements was 1162 pCiHrs (M=120, Sd=207), main-level 2486 pCiHrs (M-434, SD=421). In same households, persons with most basement-time maxed 100 hrs (M=13,SD=23), persons with most main-level time maxed 160 hrs (M=79, SD=39). Basement activities show two patterns, (1) member used it for personal domain, e.g. sleeping, and (2) household used it for general activities, e.g. TV or children`s play. Basement occupancy justifies measurement of radon in the lowest livable housing level.

  14. Occupancy Simulation in Three Residential Research Houses

    SciTech Connect (OSTI)

    Boudreaux, Philip R; Gehl, Anthony C; Christian, Jeffrey E

    2012-01-01

    Three houses of similar floor plan are being compared for energy consumption. The first house is a typical builder house of 2400 ft2 (223 m2) in east Tennessee. The second house contains retrofits available to a home owner such as energy efficient appliances, windows and HVAC, as well as an insulated attic which contains HVAC duct work. The third house was built using optimum-value framing construction with photovoltaic modules and solar water heating. To consume energy researchers have set up appliances, lights, and plug loads to turn on and off automatically according to a schedule based on the Building America Research Benchmark Definition. As energy efficiency continues to be a focus for protecting the environment and conserving resources, experiments involving whole house energy consumption will be done. In these cases it is important to understand how to simulate occupancy so that data represents only house performance and not human behavior. The process for achieving automated occupancy simulation will be discussed. Data comparing the energy use of each house will be presented and it will be shown that the third house used 66% less and the second house used 36% less energy than the control house in 2010. The authors will discuss how energy prudent living habits can further reduce energy use in the third house by 23% over the average American family living in the same house.

  15. Fall Protection Can Prevent Serious Injuries

    Broader source: Energy.gov (indexed) [DOE]

    protection requirements were not followed. According to the Occupational Safety and Health Administration (OSHA), falls from elevations, including into holes in floors, are the...

  16. DOE-HDBK-1101-2004; Process Safety Management for Highly Hazardous...

    Office of Environmental Management (EM)

    The Occupational Safety and Health Administration (OSHA) staff provided assistance. Mobil Chemical, General Electric, and Dow Chemical graciously shared their process safety ...

  17. DOE 2012 Occupational Radiation Exposure October 2013

    SciTech Connect (OSTI)

    2012-02-02

    The U.S. Department of Energy (DOE) Office of Analysis within the Office of Health, Safety and Security (HSS) publishes the annual DOE Occupational Radiation Exposure Report to provide an overview of the status of radiation protection practices at DOE (including the National Nuclear Security Administration [NNSA]). The DOE 2012 Occupational Radiation Exposure Report provides an evaluation of DOE-wide performance regarding compliance with Title 10, Code of Federal Regulations (C.F.R.), Part 835, Occupational Radiation Protection dose limits and as low as reasonably achievable (ALARA) process requirements. In addition, the report provides data to DOE organizations responsible for developing policies for protection of individuals from the adverse health effects of radiation. The report provides a summary and an analysis of occupational radiation exposure information from the monitoring of individuals involved in DOE activities. Over the past 5-year period, the occupational radiation exposure information is analyzed in terms of aggregate data, dose to individuals, and dose by site. As an indicator of the overall amount of radiation dose received during the conduct of operations at DOE, the report includes information on collective total effective dose (TED). The TED is comprised of the effective dose (ED) from external sources, which includes neutron and photon radiation, and the internal committed effective dose (CED), which results from the intake of radioactive material into the body. The collective ED from photon exposure decreased by 23% between 2011 and 2012, while the neutron dose increased by 5%. The internal dose components of the collective TED decreased by 7%. Over the past 5-year period, 99.99% of the individuals receiving measurable TED have received doses below the 2 roentgen equivalent in man (rems) (20 millisievert [mSv]) TED administrative control level (ACL), which is well below the DOE regulatory limit of 5 rems (50 mSv) TED annually. The occupational radiation exposure records show that in 2012, DOE facilities continued to comply with DOE dose limits and ACLs and worked to minimize exposure to individuals. The DOE collective TED decreased 17.1% from 2011 to 2012. The collective TED decreased at three of the five sites with the largest collective TED. u Idaho Site – Collective dose reductions were achieved as a result of continuing improvements at the Advanced Mixed Waste Treatment Project (AMWTP) through the planning of drum movements that reduced the number of times a container is handled; placement of waste containers that created highradiation areas in a centralized location; and increased worker awareness of high-dose rate areas. In addition, Idaho had the largest decrease in the total number of workers with measurable TED (1,143 fewer workers). u Hanford Site (Hanford) – An overall reduction of decontamination and decommissioning (D&D) activities at the Plutonium Finishing Plant (PFP) and Transuranic (TRU) retrieval activities resulted in collective dose reductions. u Savannah River Site (SRS) – Reductions were achieved through ALARA initiatives employed site wide. The Solid Waste Management Facility used extended specialty tools, cameras and lead shield walls to facilitate removal of drums. These tools and techniques reduce exposure time through improved efficiency, increase distance from the source of radiation by remote monitoring, shield the workers to lower the dose rate, and reduce the potential for contamination and release of material through repacking of waste. Overall, from 2011 to 2012, there was a 19% decrease in the number of workers with measurable dose. Furthermore, due to a slight decrease in both the DOE workforce (7%) and monitored workers (10%), the ratio of workers with measurable doses to monitored workers decreased to 13%. Another primary indicator of the level of radiation exposure covered in this report is the average measurable dose, which normalizes the collective dose over the population of workers who actually received a measurable dose. The average measurable TED increased by 3% from 2011 to 2012. Additional analyses show that the dose distribution in 2012 was similar to the distribution in 2011. In 2012, 13% of the monitored workers received a measurable TED and the average measurable TED, 0.069 rem, was less than 2% of the DOE limit. From 2011 to 2012, the collective TED and the number of individuals with measurable TED decreased 17.1% and 19%, respectively. These decreases were mainly due to an overall reduction of D&D activities at the PFP and TRU retrieval activities at Hanford; a 78% decrease in the number of targeted waste drums that were processed at the Idaho Site’s Accelerated Retrieval Project (ARP) from 5,566 drums in 2011 to a total of 1,211 drums processed in 2012; and ALARA initiatives employed site wide at SRS. In addition, the decreases were the result of decreased American Recovery and Reinvestment Act (ARRA) activities and continuing D&D, particularly at the DOE sites that comprise the majority of DOE collective dose. Over the past 5 years, the size of the monitored workforce has remained at a fairly stable level (within 12%), while the collective dose has varied up to 37%. No reported doses exceeded the DOE occupational limit of 5 rems TED in 2012 and no reported doses exceeded the DOE ACL of 2 rems TED.

  18. Occupancy schedules learning process through a data mining framework

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    D'Oca, Simona; Hong, Tianzhen

    2014-12-17

    Building occupancy is a paramount factor in building energy simulations. Specifically, lighting, plug loads, HVAC equipment utilization, fresh air requirements and internal heat gain or loss greatly depends on the level of occupancy within a building. Developing the appropriate methodologies to describe and reproduce the intricate network responsible for human-building interactions are needed. Extrapolation of patterns from big data streams is a powerful analysis technique which will allow for a better understanding of energy usage in buildings. A three-step data mining framework is applied to discover occupancy patterns in office spaces. First, a data set of 16 offices with 10more » minute interval occupancy data, over a two year period is mined through a decision tree model which predicts the occupancy presence. Then a rule induction algorithm is used to learn a pruned set of rules on the results from the decision tree model. Finally, a cluster analysis is employed in order to obtain consistent patterns of occupancy schedules. Furthermore, the identified occupancy rules and schedules are representative as four archetypal working profiles that can be used as input to current building energy modeling programs, such as EnergyPlus or IDA-ICE, to investigate impact of occupant presence on design, operation and energy use in office buildings.« less

  19. Employee Job Task Analysis (EJTA) - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Occupational Health Services > Employee Job Task Analysis (EJTA) Occupational Health Services Behavioral Health Services Beryllium Beryllium-Associated Worker Registry Emergency Preparedness Employee Job Task Analysis (EJTA) Environmental Management System (EMS) Epidemiology/Health Data Analysis Human Reliability Program (HRP) Industrial Rehabilitation & Ergonomics Infection Control & Immunizations Influenza Immunization Program Medical Exam Scheduling Medical Exams Return to Work

  20. Software for the occupational health and safety integrated management system

    SciTech Connect (OSTI)

    Vătăsescu, Mihaela

    2015-03-10

    This paper intends to present the design and the production of a software for the Occupational Health and Safety Integrated Management System with the view to a rapid drawing up of the system documents in the field of occupational health and safety.

  1. Occupancy schedules learning process through a data mining framework

    SciTech Connect (OSTI)

    D'Oca, Simona; Hong, Tianzhen

    2014-12-17

    Building occupancy is a paramount factor in building energy simulations. Specifically, lighting, plug loads, HVAC equipment utilization, fresh air requirements and internal heat gain or loss greatly depends on the level of occupancy within a building. Developing the appropriate methodologies to describe and reproduce the intricate network responsible for human-building interactions are needed. Extrapolation of patterns from big data streams is a powerful analysis technique which will allow for a better understanding of energy usage in buildings. A three-step data mining framework is applied to discover occupancy patterns in office spaces. First, a data set of 16 offices with 10 minute interval occupancy data, over a two year period is mined through a decision tree model which predicts the occupancy presence. Then a rule induction algorithm is used to learn a pruned set of rules on the results from the decision tree model. Finally, a cluster analysis is employed in order to obtain consistent patterns of occupancy schedules. Furthermore, the identified occupancy rules and schedules are representative as four archetypal working profiles that can be used as input to current building energy modeling programs, such as EnergyPlus or IDA-ICE, to investigate impact of occupant presence on design, operation and energy use in office buildings.

  2. On-Line User Survey Form to provide feedback for the DOE Occupational...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    User Survey Form to provide feedback for the DOE Occupational Radiation Exposure Report On-Line User Survey Form to provide feedback for the DOE Occupational Radiation Exposure...

  3. DOE Awards Hanford Site Occupational Medical Services Contract | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Hanford Site Occupational Medical Services Contract DOE Awards Hanford Site Occupational Medical Services Contract June 8, 2012 - 12:00pm Addthis Media Contact Cameron Hardy 509-308-4947 Cameron.hardy@rl.gov Cincinnati - The U.S. Department of Energy (DOE) announced today that HPM Corporation, of Kennewick, Washington has been awarded an estimated $99 million contract to provide Occupational Medical Services at the DOE Hanford Site. HPM is a certified minority-owned, women-owned

  4. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  5. Meeting the New Ozone Standard: Challenges and Opportunities

    Broader source: Energy.gov [DOE]

    This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

  6. DOE Occupational Radiation Exposure, 1998 Report

    Office of Environmental Management (EM)

    OCCUPATIONAL RADIATION EXPOSURE D E P A R T M E N T O F E N E R G Y U N I T E D S T A T E S O F A M E R I C A DOE/EH-0608 E T A * S H I E L D * A L A R A * N E U T R O N * AEDE * E L E C T R O N * T E D E * I N T E R N A L * C E D E * G A M M A * B E T A * S H I E L D * A L A R A * N E U T R ON * AED E * E L E C T R O N * T E D E * I N T E R N A L * C E D E * G A M M A * B E 1998 Report http://rems.eh.doe.gov This report has been reproduced directly from the best available copy. Available to DOE

  7. Age-dependent inhibition of pentobarbital sleeping time by ozone in mice and rats

    SciTech Connect (OSTI)

    Canada, A.T.; Calabrese, E.J.; Leonard, D.

    1986-09-01

    The effect of age on the metabolism of pentobarbital in mice and rats was investigated following exposure to 0.3 ppm of ozone for 3.75 hr. Young animals were 2.5 months of age and the mature were 18 months. The pentobarbital sleeping time was significantly prolonged following the ozone exposure in both the mice and rats when compared with an air control. No ozone effect on sleeping time was found in the young animals. The results indicate that there may be an age-related sensitivity to the occurrence of ozone-related inhibition of pentobarbital metabolism.

  8. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Controlling superconductivity in La2-xSrxCuO4+ by ozone and vacuum annealing Citation Details In-Document Search Title: Controlling superconductivity in ...

  9. Wireless Occupancy Sensors for Lighting Controls: An Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...09%20Sustainability%20Committee %20Final%20Report%20with%20Attachments%5B1%5D.pdf. 4. Steiner, JP. 2014. Estimating the Battery Life of a Wireless Occupancy Sensor. http:...

  10. NAC 408.429 - Applicants for Occupancy Permits | Open Energy...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: NAC 408.429 - Applicants for Occupancy PermitsLegal Abstract This regulation governs...

  11. DOE occupational radiation exposure. Report 1992--1994

    SciTech Connect (OSTI)

    1997-05-01

    The DOE Occupational Radiation Exposure Report, 1992-1994 reports occupational radiation exposures incurred by individuals at US Department of Energy (DOE) facilities from 1992 through 1994. This report includes occupational radiation exposure information for all DOE employees, contractors, subcontractors, and visitors. This information is analyzed and trended over time to provide a measure of the DOE`s performance in protecting its workers from radiation. Occupational radiation exposure at DOE has been decreasing over the past 5 years. In particular, doses in the higher dose ranges are decreasing, including the number of doses in excess of the DOE limits and doses in excess of the 2 rem Administrative Control Level (ACL). This is an indication of greater attention being given to protecting these individuals from radiation in the workplace.

  12. Federal Employee Occupational Safety And Health (FEOSH) Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Congress established Public Law 91-596, The Occupational Safety and Health Act of 1970 (OSH Act) "to ensure so far as possible every working man and woman in the Nation safe and ...

  13. Operating Experience Level 3, DOE Occupational Radiation Exposures for 2013

    Broader source: Energy.gov [DOE]

    This Operating Experience Level 3 (OE-3) document provides an overview summary of radiation doses from occupational exposures at the Department of Energy (DOE), including the National Nuclear Security Administration for the year 2013.

  14. FAQS Qualification Card - Occupational Safety | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Qualification Card - Occupational Safety FAQS Qualification Card - Occupational Safety A key element for the Department's Technical Qualification Programs is a set of common Functional Area Qualification Standards (FAQS) and associated Job Task Analyses (JTA). These standards are developed for various functional areas of responsibility in the Department, including oversight of safety management programs identified as hazard controls in Documented Safety Analyses (DSA). For each functional area,

  15. Reporting Occupational Radiation Exposure Data | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reporting Occupational Radiation Exposure Data Reporting Occupational Radiation Exposure Data IMPORTANT NOTICE: Due to increasing security concerns for the protection of Personnally Identifiable Information (PII), AU-23 has issued a policy statement regarding the submission of radiation exposure records to REMS. This policy should be implemented immediately by all organizations reporting radiation exposure records to REMS in accordance with the REMS Reporting Guide. DOE sites are required to

  16. Safety and Occupational Health Specialist | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Safety and Occupational Health Specialist Safety and Occupational Health Specialist Submitted by admin on Tue, 2016-05-10 18:01 Job Summary Organization Name Department Of Energy Agency SubElement Department of Energy Locations Freeport, Texas Announcement Number DOE-SE-16-SP-00072-DE Job Summary This position is located in the Office of the Assistant Project Manager for Maintenance and Operations, Site Operations and Maintenance Division, Bryan Mound Site, located in Freeport, Texas. The

  17. Safety & Occupational Health Manager | Department of Energy

    Office of Environmental Management (EM)

    Safety & Occupational Health Manager Safety & Occupational Health Manager Submitted by admin on Sat, 2016-05-21 00:15 Job Summary Organization Name Department Of Energy Agency SubElement Western Area Power Administration Locations Bismarck, North Dakota Huron, South Dakota Announcement Number WAPA-16-DE-165 Job Summary (See Frequently Asked Questions for more information). Where would I be working? Western Area Power Administration, Upper Great Plains Region, Safety Office (B0700). One

  18. Occupational Safety and Health Administration and Department of Energy Voluntary Protection Program MOU

    Broader source: Energy.gov [DOE]

    Occupational Safety and Health Administration and Department of Energy Voluntary Protection Program MOU

  19. Ventilation and occupant behavior in two apartment buildings

    SciTech Connect (OSTI)

    Diamond, R.C.; Modera, M.P.; Feustel, H.E.

    1986-10-01

    In this paper we approach the subject of ventilation and occupant behavior in multifamily buildings by asking three questions: (1) why and how do occupants interact with ventilation in an apartment building, (2) how does the physical environment (i.e., building characteristics and climate) affect the ventilation in an apartment, and (3) what methods can be used to answer the first two questions. To investigate these and related questions, two apartment buildings in Chicago were monitored during the 1985-1986 heating season. In addition to collecting data on energy consumption, outdoor temperature, wind speed, and indoor apartment temperatures, we conducted diagnostic measurements and occupant surveys in both buildings. The diagnostic tests measured leakage areas of the individual apartments, both through the exterior envelope and to other apartments. The measured leakage areas are used in conjunction with a multizone air flow model to simulate infiltration and internal air flows under different weather conditions. The occupants were questioned about their attitudes and behavior regarding the comfort, air quality, ventilation, and energy use of their apartments. This paper describes each of the research methods utilized, the results of these efforts, and conclusions that can be drawn about ventilation-occupant interactions in these apartment buildings. We found that there was minimal window opening during the winter, widespread use of auxiliary heating to control thermal comfort, and that the simulations show little outside air entry in the top-floor apartments during periods of low wind speeds. The major conclusion of this work is that a multi-disciplinary approach is required to understand or predict occupant-ventilation interactions. Such an approach must take into account the physical characteristics of the building and the climate, as well as the preferences and available options of the occupants.

  20. Classical and alternative macrophage activation in the lung following ozone-induced oxidative stress

    SciTech Connect (OSTI)

    Sunil, Vasanthi R.; Patel-Vayas, Kinal; Shen, Jianliang; Laskin, Jeffrey D.; Laskin, Debra L.

    2012-09-01

    Ozone is a pulmonary irritant known to cause oxidative stress, inflammation and tissue injury. Evidence suggests that macrophages play a role in the pathogenic response; however, their contribution depends on the mediators they encounter in the lung which dictate their function. In these studies we analyzed the effects of ozone-induced oxidative stress on the phenotype of alveolar macrophages (AM). Exposure of rats to ozone (2 ppm, 3 h) resulted in increased expression of 8-hydroxy-2?-deoxyguanosine (8-OHdG), as well as heme oxygenase-1 (HO-1) in AM. Whereas 8-OHdG was maximum at 24 h, expression of HO-1 was biphasic increasing after 3 h and 4872 h. Cleaved caspase-9 and beclin-1, markers of apoptosis and autophagy, were also induced in AM 24 h post-ozone. This was associated with increased bronchoalveolar lavage protein and cells, as well as matrix metalloproteinase (MMP)-2 and MMP-9, demonstrating alveolar epithelial injury. Ozone intoxication resulted in biphasic activation of the transcription factor, NF?B. This correlated with expression of monocyte chemotactic protein?1, inducible nitric oxide synthase and cyclooxygenase?2, markers of proinflammatory macrophages. Increases in arginase-1, Ym1 and galectin-3 positive anti-inflammatory/wound repair macrophages were also observed in the lung after ozone inhalation, beginning at 24 h (arginase-1, Ym1), and persisting for 72 h (galectin-3). This was associated with increased expression of pro-surfactant protein-C, a marker of Type II cell proliferation and activation, important steps in wound repair. These data suggest that both proinflammatory/cytotoxic and anti-inflammatory/wound repair macrophages are activated early in the response to ozone-induced oxidative stress and tissue injury. -- Highlights: ? Lung macrophages are highly sensitive to ozone induced oxidative stress. ? Ozone induces autophagy and apoptosis in lung macrophages. ? Proinflammatory and wound repair macrophages are activated early after ozone. ? Oxidative stress may contribute to regulating macrophage phenotype and function.

  1. Energy Employees Occupational Illness Compensation Program Act (EEOICPA) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    51836 A PILOT STUDY OF ENERGY EFFICIENT AIR CLEANING FOR OZONE Lara A. Gundel, Douglas P. Sullivan, Gregory Y. Katsapov and William J. Fisk Indoor Environment Department Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, CA 94720 November 28, 2002 This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Building Technologies Program of the U.S. Department of Energy under contract No. DE-AC03-76SF00098. 1 LBNL-51836 A

  2. Congress Offers OSHA Praise on VPP | Department of Energy

    Office of Environmental Management (EM)

    Goals | Department of Energy Comprehensive Energy Program at Patrick Air Force Base Set to Exceed Energy Goals Comprehensive Energy Program at Patrick Air Force Base Set to Exceed Energy Goals Federal Energy Management Program case study focuses on Patrick Air Force Base's use of a utility energy services contract to achieve its energy goals. PDF icon Download the Patrick Air Force Base case study. More Documents & Publications FPL Energy Services ESCO Qualification Sheet UESC Project

  3. Operating Experience Level 3, OSHA's Revised Hazard Communication...

    Broader source: Energy.gov (indexed) [DOE]

    Publications Hazard Communication Training - Upcoming Implementation Date for New Hazard Communication Standard Operating Experience Level 3, Safe Management of Mercury...

  4. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  5. Delocalization and occupancy effects of 5f orbitals in plutonium

    Office of Scientific and Technical Information (OSTI)

    intermetallics using L3-edge resonant X-ray emission spectroscopy (Journal Article) | SciTech Connect Journal Article: Delocalization and occupancy effects of 5f orbitals in plutonium intermetallics using L3-edge resonant X-ray emission spectroscopy Citation Details In-Document Search Title: Delocalization and occupancy effects of 5f orbitals in plutonium intermetallics using L3-edge resonant X-ray emission spectroscopy Although actinide (An) L3 -edge X-ray absorption near-edge structure

  6. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    SciTech Connect (OSTI)

    Jin, Ling; Tonse, Shaheen; Cohan, Daniel S.; Mao, Xiaoling; Harley, Robert A.; Brown, Nancy J.

    2009-05-15

    CMAQ-HDDM is used to determine spatial and temporal variations in ozone limiting reagents and local vs upwind source contributions for an air pollution episode in Central California. We developed a first- and second- order sensitivity analysis approach with the Decoupled Direct Method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a five-day ozone episode (29th July-3rd Aug, 2000). Despite considerable spatial variations, nitrogen oxides (NO{sub x}) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8-hr ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1-hr ozone standard. Inter-basin source contributions of NO{sub x} emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NO{sub x} and AVOC, and the rate coefficient of the OH + NO{sub 2} termination reaction, have the greatest effect on first-order ozone responses to changes in NO{sub x} emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

  7. THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, Carol; Osterberg, Paul; Johnson, Tom; Frawely, Thomas

    2013-01-23

    The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

  8. The role of developing countries in protecting the ozone layer: An ethical analysis

    SciTech Connect (OSTI)

    Zatz, M.N.

    1994-12-31

    In an effort to reduce the depletion of the stratospheric ozone layer, the nations of the world joined together in a landmark effort to address this most important problem. Unlike many environmental issues which are localized, ozone depletion is an environmental problem which must be addressed on a global scale. In order to successfully halt the depletion of the ozone layer, it is imperative that all countries amend their current practices and reduce their consumption of ozone-depleting substances. This necessity presents an ethical dilemma when assigning responsibility for ozone layer protection among nations. This paper will address the difficulties in dealing with ozone depletion on a global scale and will discuss the ethically correct role which should be assumed by developing countries. After presenting a brief history of the problem of ozone depletion and the measures which have been taken to halt it, this paper will describe an ethical framework in which ozone layer protection policies in developing countries should be evaluated. This framework is based on the concept of balancing morally-correct policies with economically-sound policies. It illustrates, in detail, how the environmental impacts of policies must be considered in conjunction with the impacts of such policies on the lives and well-being of the country`s citizens. The paper presents an ethical analysis of three primary policy options. These options address the phaseout of ozone-depleting substances (such as CFCs) and include: the no-phaseout option, the developed country accelerated phaseout schedule, and the delayed phaseout schedule. Each option is examined within the ethical framework presented earlier in the paper. Finally, the paper concludes by addressing the ethical responsibilities of developed countries. It discusses the various ways in which developed countries should provide aid.

  9. Ozone in sea water. Part 1: Chemistry; Part 2: Corrosion of metals

    SciTech Connect (OSTI)

    Wyllie, W.E. II; Brown, B.E.; Duquette, D.J.

    1995-12-01

    Ozonation of sea water for biofouling control is being utilized in desalination processes, heat exchange systems, as well as in salt water aquariums. The chemistry of ozone in sea water is much more complex than in fresh water due to the high concentration of easily oxidizable, ozone-demanding species and the formation of secondary oxidants. The major secondary oxidant is bromine in the form of hypobromite and hypobromous acid (BrO{sup {minus}}/HOBr) which are formed by oxidation of the bromide ion (Br{sup {minus}}), naturally found in sea water in concentrations of 65 mg/L. HOBr can react again with ozone to return Br{sup {minus}}, resulting in accelerated decomposition of ozone, or to form bromate (BrO{sub 3}{sup {minus}}) The BrO ion is known to interfere with the measurement of residual ozone in sea water, so it is important that the feed gas conditions, solution pH, and the hypobromous and bromate concentrations be reported to quantify the amount of ozone introduced into a system. In 0.5 N NaCl and sea water solutions, ozone appears to stabilize the passivity of passivating metals, but susceptibility to crevice corrosion appears to increase in the same environments. The effect of BrO{sup {minus}}/HOBr on the corrosion of metals in sea water is believed to be similar to chlorine and ozone, in that it acts as a strong oxidizer. However, it is not certain whether BrO{sup {minus}}/HOBr and BrO{sub 3}{sup {minus}} have any damaging effects on protective metal films.

  10. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  11. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum

    Office of Scientific and Technical Information (OSTI)

    annealing (Journal Article) | SciTech Connect Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing Citation Details In-Document Search Title: Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship

  12. CRAD, Occupational Safety & Health- Idaho MF-628 Drum Treatment Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2006 Commencement of Operations assessment of the Occupational Safety and Industrial Hygiene programs at the MF-628 Drum Treatment Facility at the Idaho National Laboratory Advanced Mixed Waste Treatment Project.

  13. CRAD, Occupational Safety & Health- Idaho Accelerated Retrieval Project Phase II

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2006 Commencement of Operations assessment of the Occupational Safety and Industrial Hygiene Program at the Idaho Accelerated Retrieval Project Phase II.

  14. DOE Basic Overview of Occupational Radiation Exposure_2011 pamphlet

    SciTech Connect (OSTI)

    ORAU

    2012-08-08

    This pamphlet focusses on two HSS activities that help ensure radiation exposures are accurately assessed and recorded, namely: 1) the quality and accuracy of occupational radiation exposure monitoring, and 2) the recording, reporting, analysis, and dissemination of the monitoring results. It is intended to provide a short summary of two specific HSS programs that aid in the oversight of radiation protection activities at DOE. The Department of Energy Laboratory Accreditation Program (DOELAP) is in place to ensure that radiation exposure monitoring at all DOE sites is precise and accurate, and conforms to national and international performance and quality assurance standards. The DOE Radiation Exposure Monitoring Systems (REMS) program provides for the collection, analysis, and dissemination of occupational radiation exposure information. The annual REMS report is a valuable tool for managing radiological safety programs and for developing policies to protect individuals from occupational exposure to radiation. In tandem, these programs provide DOE management and workers an assurance that occupational radiation exposures are accurately measured, analyzed, and reported.

  15. Fact #613: March 8, 2010 Vehicle Occupancy Rates

    Broader source: Energy.gov [DOE]

    The average number of persons occupying a car is 1.59 and has not changed much since 1995. The largest increases from 1995 to 2009 have been in the occupancy rates for vans – from 2.07 to 2.35 –...

  16. File:03HIDUseAndOccupancyPermit.pdf | Open Energy Information

    Open Energy Info (EERE)

    3HIDUseAndOccupancyPermit.pdf Jump to: navigation, search File File history File usage Metadata File:03HIDUseAndOccupancyPermit.pdf Size of this preview: 463 599 pixels. Other...

  17. Influence of ozone on pentobarbital pharmacokinetics in mice

    SciTech Connect (OSTI)

    Graham, J.A.; Menzel, D.B.; Mole, M.L.; Miller, F.J.; Gardner, D.E.

    1985-01-01

    It had been shown that 3- to 5-hr exposures to ambient concentrations of ozone (O/sub 3/) increase pentobarbital-induced sleeping time in female mice, hamsters, and rats without decreasing heptatic cytochrome P-450 levels or selected mixed function oxidases. To elucidate potential mechanisms involved, clearance of pentobarbital from the blood of O/sub 3/-exposed mice was examined. Pentobarbital clearance followed first-order kinetics with a one-compartment model. Mice exposed to 1960 micrograms per cu. m. (1ppm) for 5 hr had a 71% increase in the plasma half-life of pentobarbital. It therefore appears possible that pentobarbital-induced sleeping time is increased due to a decrease in hepatic metabolism of pentobarbital.

  18. Energy Savings for Occupancy-Based Control (OBC) of Variable-Air-Volume (VAV) Systems

    SciTech Connect (OSTI)

    Zhang, Jian; Lutes, Robert G.; Liu, Guopeng; Brambley, Michael R.

    2013-01-24

    This study evaluates the savings potential of occupancy based control (OBC) for large office buildings with VAV terminal boxes installed.

  19. Occupational Medical Services at Hanford B-1 PART I - THE SCHEDULE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Injury & Illness System (01&15) PIA, Idaho National Laboratory Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory PDF icon Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory More Documents & Publications Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database, INL Energy

  20. Use of Occupancy Sensors in LED Parking Lot and Garage Applications: Early Experiences

    SciTech Connect (OSTI)

    Kinzey, B. R.; Myer, M. A.; Royer, M. P.; Sullivan, G. P.

    2012-10-01

    Final GATEWAY program report on the early experiences of using occupancy sensors in LED parking lot and garage applications.

  1. Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Injury & Illness System (01&15) PIA, Idaho National Laboratory Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory PDF icon Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory More Documents & Publications Energy Employees' Occupational Illness Compensation Program Act (EEOICPA) Tracking Database, INL Energy

  2. Coal mine injury and employment experience by occupation, 1976-1980. Informational report

    SciTech Connect (OSTI)

    Larson, L.P.

    1985-01-01

    The report presents the injury and employment experience, from 1976 through 1980, of selected occupations in the coal-mining industry. Injury data from the MSHA Health and Safety Analysis Center's data base are matched with employment data for individual occupations collected through respirable dust-sampling procedures, providing fatality and injury rates for each occupation. The rates are used to establish a ranking of occupations according to their level of risk.

  3. CFTB 04/22/2010 Revisions to the 2008 Census of Fatal Occupational...

    National Nuclear Security Administration (NNSA)

    maintenance, and repair occupations 345 354 9 6.6 6.7 0.1 Transportation and material moving occupations 1,330 1,376 46 15.5 16.1 0.6 Military occupations 53 57 4 NA...

  4. Environmental Externalities in Electric Power Markets: Acid Rain, Urban Ozone, and Climate Change

    Reports and Publications (EIA)

    1995-01-01

    This article discusses the emissions resulting from the generation of electricity by utilities and their role in contributing to the environmental problems of acid rain, urban ozone, and climate change.

  5. Improved Potential Energy Surface of Ozone Constructed Using the Fitting by Permutationally Invariant Polynomial Function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ayouz, Mehdi; Babikov, Dmitri

    2012-01-01

    New global potential energy surface for the ground electronic state of ozone is constructed at the complete basis set level of the multireference configuration interaction theory. A method of fitting the data points by analytical permutationally invariant polynomial function is adopted. A small set of 500 points is preoptimized using the old surface of ozone. In this procedure the positions of points in the configuration space are chosen such that the RMS deviation of the fit is minimized. New ab initio calculations are carried out at these points and are used to build new surface. Additional points are addedmore » to the vicinity of the minimum energy path in order to improve accuracy of the fit, particularly in the region where the surface of ozone exhibits a shallow van der Waals well. New surface can be used to study formation of ozone at thermal energies and its spectroscopy near the dissociation threshold.« less

  6. Influence of Long-Period Variations of Total Ozone Content on Climate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Change in Twentieth Century Influence of Long-Period Variations of Total Ozone Content on Climate Change in Twentieth Century Zuev, V Institute of Atmospheric Optics Zueva, N. Institute of Atmospheric Optics Bondarenko, S Institute of Atmospheric Optics Category: Atmospheric State and Surface It is shown that during long-term total ozone decrease everywhere at middle and high latitudes there takes place the destruction of balance in global carbon cycle first of all due to reduction of

  7. Spatially Resolved Estimation of Ozone-related Mortality in the United

    Office of Scientific and Technical Information (OSTI)

    States under Two Representative Concentration Pathways (RCPs) and their Uncertainty (Journal Article) | SciTech Connect Spatially Resolved Estimation of Ozone-related Mortality in the United States under Two Representative Concentration Pathways (RCPs) and their Uncertainty Citation Details In-Document Search Title: Spatially Resolved Estimation of Ozone-related Mortality in the United States under Two Representative Concentration Pathways (RCPs) and their Uncertainty BACKGROUND: The spatial

  8. Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High

    Office of Scientific and Technical Information (OSTI)

    Performance Electrochemical Energy Storage (Journal Article) | SciTech Connect Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Citation Details In-Document Search Title: Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Authors: Chen, Xinyi ; Pomerantseva, Ekaterina ; Banerjee, P ; Gregorczyk, Keith ; Ghodssi, Reza ; Rubloff, Gary W Publication Date: 2012-04-10 OSTI

  9. A global analysis of the ozone deficit in the upper stratosphere and lower mesosphere

    SciTech Connect (OSTI)

    Eluszkiewicz, J.; Allen, M. )

    1993-01-20

    The global measurements of temperature, ozone, water vapor, and nitrogen dioxide acquired by the Limb Infrared Monitor of the Stratosphere (LIMS), supplemented by a precomputed distribution of chlorine monoxide, are used to test the balance between odd oxygen production and loss in the upper stratosphere and lower mesosphere. An efficient photochemical equilibrium model, validated by comparison with the results from a fully time-dependent one-dimensional model at selected latitudes, is used in the calculations. The computed ozone abundances are systematically lower than observations for May 1-7, 1979, which suggests, contrary to the conclusions of other recent studies, a problem in model simulations of stratospheric ozone. The ozone deficit' at 30[degrees]N is smaller than previous analyses of LIMS data have indicated. In the stratosphere, this reduction in the deficit is due to the fact that CIO abundances for the 1979 period utilized in this study are much lower than in earlier work, mainly as a result of lower Cl[sub y] concentrations. In the mesosphere, a correlation of the ozone deficit with the distribution of water vapor is indicated. The ozone deficit in the stratosphere can be eliminated by modifying only one model reaction rate: either by decreasing the rate of odd oxygen loss or by increasing the rate of odd oxygen production Cl[sub y] increasing the photodissociation rate of molecular oxygen primarily in the Herzberg continuum and/or invoking photolysis of vibrationally excited molecular oxygen. With the ozone abundances thus increased, a small residual deficit in the lower mesophere can be eliminated by reducing, within the recommended kinetic uncertainties, the efficiency of odd hydrogen-catalyzed odd oxygen loss. With the adjusted model, the calculated ozone abundances for the week of January 1-7. 1979, outside of winter latitudes, also agree with the LIMS observations to within 10%. 49 refs., 15 figs., 1 tab.

  10. Image-based occupancy sensor - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    36,866 Site Map Printable Version Share this resource About Search Categories (15) Advanced Materials Biomass and Biofuels Building Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual Patent Search Success Stories Find More Like This Return to Search Image-based occupancy sensor United

  11. Optimization of Occupancy Based Demand Controlled Ventilation in Residences

    SciTech Connect (OSTI)

    Mortensen, Dorthe K.; Walker, Iain S.; Sherman, Max H.

    2011-05-01

    Although it has been used for many years in commercial buildings, the application of demand controlled ventilation in residences is limited. In this study we used occupant exposure to pollutants integrated over time (referred to as 'dose') as the metric to evaluate the effectiveness and air quality implications of demand controlled ventilation in residences. We looked at air quality for two situations. The first is that typically used in ventilation standards: the exposure over a long term. The second is to look at peak exposures that are associated with time variations in ventilation rates and pollutant generation. The pollutant generation had two components: a background rate associated with the building materials and furnishings and a second component related to occupants. The demand controlled ventilation system operated at a low airflow rate when the residence was unoccupied and at a high airflow rate when occupied. We used analytical solutions to the continuity equation to determine the ventilation effectiveness and the long-term chronic dose and peak acute exposure for a representative range of occupancy periods, pollutant generation rates and airflow rates. The results of the study showed that we can optimize the demand controlled airflow rates to reduce the quantity of air used for ventilation without introducing problematic acute conditions.

  12. Occupational Radiation Protection Record-Keeping and Reporting Guide for use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-05-20

    This Guide provides an acceptable methodology for establishing and operating an occupational radiation protection record-keeping and reporting program that will comply with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection. Canceled by DOE G 441.1-1B.

  13. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-11-01

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  14. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-01-01

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  15. Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.

    SciTech Connect (OSTI)

    Whitfield, R. G.

    1999-03-04

    This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

  16. Occupational Health Services Part I Contract No. DE-AC06-04RL14383; Modification M039 Section H

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Health Manager PIA, Carlsbad Field Office Occupational Health Manager PIA, Carlsbad Field Office Occupational Health Manager PIA, Carlsbad Field Office PDF icon Occupational Health Manager PIA, Carlsbad Field Office More Documents & Publications Occupational Medicine - Assistant PIA, Idaho National Laboratory Integrated Safety Management Workshop Registration, PIA, Idaho National Laboratory Occupational Injury & Illness System (01&15) PIA, Idaho National Laboratory

    ;

  17. Post-treatment of fly ash by ozone in a fixed bed reactor

    SciTech Connect (OSTI)

    Kim Hougaard Pedersen; Merc Casanovas Meli; Anker Degn Jensen; Kim Dam-Johansen

    2009-01-15

    The residual carbon in fly ash produced from pulverized coal combustion can adsorb the air-entraining admixtures (AEAs) added to enhance air entrainment in concrete. This behavior of the ash can be suppressed by exposing the fly ash to oxidizing species, which oxidizes the carbon surface and thus prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O{sub 3}/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data. 28 refs., 7 figs., 3 tabs.

  18. Code linkages for occupant safety during roadside impact simulations

    SciTech Connect (OSTI)

    Kay, G.J.; Logan, R.

    1994-01-11

    Current code linkage developments at Lawrence Livermore National Laboratory include coupling of the nonlinear explicit finite element analysis (FEA) code DYNA3D with rigid body crash victim simulation (CVS) codes. This coupling approach takes advantage of the structural response capabilities of DYNA3D and the validated occupant response abilities of the CVS codes. Two types of coupling are described and demonstrated in this paper and a description of the equilibrium initialization method which was employed in the coupling development is also presented.

  19. A Basic Overview of the Occupational Radiation Exposure Monitoring, Analysis & Reporting

    Energy Savers [EERE]

    Occupational Radiation Exposure: Monitoring, Analysis & Reporting A Basic Overview of OCCUPATIONAL RADIATION EXPOSURE Monitoring, Analysis & Reporting Outreach & Awareness Series to Advance the DOE Mission Office of Health, Safety and Security U.S. Department of Energy September 2012 Occupational Radiation Exposure: Monitoring, Analysis & Reporting i Overview One of the priorities of the Department of Energy (DOE) is to ensure a safe and secure workplace by integrating safety and

  20. PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational Health

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Safety Medical System (OHS) (Includes the Drug and Alcohol Testing System (Assistant)) | Department of Energy MedGate Occupational Health and Safety Medical System (OHS) (Includes the Drug and Alcohol Testing System (Assistant)) PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational Health and Safety Medical System (OHS) (Includes the Drug and Alcohol Testing System (Assistant)) PIA - Savannah River Nuclear Solution (SRNS) MedGate Occupational Health and Safety Medical System

  1. Observation of stratospheric trace gases related to ozone depletion in the Antarctic spring

    SciTech Connect (OSTI)

    De Zafra, R.L.; Parrish, A.; Solomon, P.; Barrett, J.W.; Connor, B.; Jaramillo, M. )

    1987-01-01

    During the first National Ozone Expedition (NOZE I), which ran from 21 August to early November 1986 at McMurdo Station, the authors made frequent measurements of chlorine monoxide (CIO), ozone (O{sub 3}), nitrous oxide (N{sub 2}O), and occasional measurements of hydrogen cyanide. Observations were made with a ground-based millimeters wave spectrometer capable of detecting and measuring the pressure broadened rotational emission lines of these molecules in the 260-280 gigahertz frequency range. The spectral bandpass and resolution of the instrument is sufficient to recover altitude distributions over a range of approximately 20-55 kilometers and to detect emission from as low as approximately 13-15 kilometers. Results are given and discussed on the levels of chlorine monoxide, nitrous oxide, and ozone found.

  2. Water relations of differentially irrigated cotton exposed to ozone

    SciTech Connect (OSTI)

    Temple, P.J.

    1990-01-01

    The field study was conducted to test the hypothesis that plants chronically exposed to O{sub 3} may be more susceptible to drought because O{sub 3} typically inhibits root growth and increases shoot-root ratios in plants. Cotton was grown in open-top chambers on Hanford coarse sandy loam in Riverside, CA. Plants were grown under three irrigation regimes: Optimum water for lint production (OW), suboptimum or moderate drought stress (SO), and severely drought stressed (SS) and were exposed to seasonal 12 h (0800-2000) O{sub 3} centrations of 0.015, 0.074, 0.094, or 0.111/microLL. Leaf xylem pressure potentials Psi(sub 1) and soil water content Theta(sub v) were measured weekly from June to October. Mean seasonal Psi(sub 1) increased from -1.89 MPa to -1.72 MPa in low to high O{sub 3} treatments, averaged across soil water regimes. Ozone had no effect on seasonal water use of cotton, but water use efficiency was significantly reduced by O{sub 3} in OW and SO, but not in SS treatments. Drought-stressed plants extracted proportionally greater amounts of water from deeper in the soil profile than OW cotton, and O{sub 3} had no apparent effect on this redistribution of roots in the soil. Since O{sub 3} had no apparent effect on the ability of drought-stressed cotton to maintain Psi(sub 1) and to increase root growth relative to shoot growth, this suggests that O{sub 3} may have little or no effect on the potential of cotton to adapt to or tolerate drought.

  3. Abiotic ozone and oxygen in atmospheres similar to prebiotic Earth

    SciTech Connect (OSTI)

    Domagal-Goldman, Shawn D.; Segura, Antgona; Claire, Mark W.; Robinson, Tyler D.; Meadows, Victoria S.

    2014-09-10

    The search for life on planets outside our solar system will use spectroscopic identification of atmospheric biosignatures. The most robust remotely detectable potential biosignature is considered to be the detection of oxygen (O{sub 2}) or ozone (O{sub 3}) simultaneous to methane (CH{sub 4}) at levels indicating fluxes from the planetary surface in excess of those that could be produced abiotically. Here we use an altitude-dependent photochemical model with the enhanced lower boundary conditions necessary to carefully explore abiotic O{sub 2} and O{sub 3} production on lifeless planets with a wide variety of volcanic gas fluxes and stellar energy distributions. On some of these worlds, we predict limited O{sub 2} and O{sub 3} buildup, caused by fast chemical production of these gases. This results in detectable abiotic O{sub 3} and CH{sub 4} features in the UV-visible, but no detectable abiotic O{sub 2} features. Thus, simultaneous detection of O{sub 3} and CH{sub 4} by a UV-visible mission is not a strong biosignature without proper contextual information. Discrimination between biological and abiotic sources of O{sub 2} and O{sub 3} is possible through analysis of the stellar and atmospheric contextparticularly redox state and O atom inventoryof the planet in question. Specifically, understanding the spectral characteristics of the star and obtaining a broad wavelength range for planetary spectra should allow more robust identification of false positives for life. This highlights the importance of wide spectral coverage for future exoplanet characterization missions. Specifically, discrimination between true and false positives may require spectral observations that extend into infrared wavelengths and provide contextual information on the planet's atmospheric chemistry.

  4. Use of Occupancy Sensors in LED Parking Lot and Garage Applications...

    Office of Scientific and Technical Information (OSTI)

    Done correctly, occupancy sensors can substantially enhance the savings from an already efficient lighting system. However, this technology is confronted by several potential ...

  5. Occupational Health Services Part I DE-AC06-04RL14383, Modification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in that the Contractor is expected to perform all technical, operational and managerial functions necessary to provide the occupational medical services, in accordance with...

  6. 10 C.F.R. PART 835-OCCUPATIONAL RADIATION PROTECTION, Subpart...

    Energy Savers [EERE]

    ... in the environment (such as from the testing of nuclear explosive devices); (iv) Radon and its ... individual's occupational exposure history as a special entry; and (ii) Not be ...

  7. Use of Occupancy Sensors in LED Parking Lot and Garage Applications...

    Office of Scientific and Technical Information (OSTI)

    Experiences Kinzey, Bruce R.; Myer, Michael; Royer, Michael P.; Sullivan, Greg P. LED lighting; parking lot lighting; occupancy sensors LED lighting; parking lot lighting;...

  8. Impacts from a fossil fuel power plant on ozone levels in Memphis, Tennessee

    SciTech Connect (OSTI)

    Mueller, S.F.; Bailey, E.M.

    1998-12-31

    The Tennessee Valley Authority (TVA) Allen power plant is located on the Mississippi River in the southwest corner of Memphis, Tennessee. Allen has three coal-fired cyclone boilers with a rated capacity of 272 MW each. It is a Phase 2 plant under Title IV of the Clean Air Act and is the largest single source of NO{sub x} in the Memphis area. TVA plans to reduce Allen NOx emissions through a combination of burning low-sulfur coal (which has the benefit of reducing NO{sub x} emissions while also reducing SO{sub 2} emissions) and installing gas re-burn technology. A modeling study using the SAI, Inc., UAM-V photochemical model was conducted to examine the potential impacts of NO{sub x} reductions on ozone levels in the Memphis area. A series of four model simulations were made in which different Allen emissions scenarios were examined. The focus period of the photochemical modeling was 11--14 July 1995 when measurements in and near Memphis indicated peak hourly ozone levels of 135--140 ppb. This analysis primarily examined computed impacts within 50 km of Memphis. Allen was computed to contribute as much as 20--30 ppb to ground ozone levels 20-50 km downwind using its NO{sub x} emission rate before Title IV compliance. After compliance it was computed to contribute only about 10--20 ppb. At the same time, maximum daily ozone reductions due to Allen NO{sub x} titration of ozone were between 30 and 60 ppb. These benefits will be reduced by 30--50% after Title IV compliance, and are expected to occur within 30 km of the plant. More model grid cells indicated dis-benefits (net ground-level ozone increases) than benefits on three of the four episode days using the Title IV compliance emission rate. Significant ozone dis-benefits were expected because of the well-documented NO titration of ozone within plumes having a high ratio of NO to volatile organic compounds.

  9. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jrmie; Brunner, Gregory; Zhang, Jianshun; Fisk, William J.

    2011-05-01

    Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

  10. Statistical Analysis and Modeling of Occupancy Patterns in Open-Plan Offices using Measured Lighting-Switch Data

    SciTech Connect (OSTI)

    Chang, Wen-Kuei; Hong, Tianzhen

    2013-01-01

    Occupancy profile is one of the driving factors behind discrepancies between the measured and simulated energy consumption of buildings. The frequencies of occupants leaving their offices and the corresponding durations of absences have significant impact on energy use and the operational controls of buildings. This study used statistical methods to analyze the occupancy status, based on measured lighting-switch data in five-minute intervals, for a total of 200 open-plan (cubicle) offices. Five typical occupancy patterns were identified based on the average daily 24-hour profiles of the presence of occupants in their cubicles. These statistical patterns were represented by a one-square curve, a one-valley curve, a two-valley curve, a variable curve, and a flat curve. The key parameters that define the occupancy model are the average occupancy profile together with probability distributions of absence duration, and the number of times an occupant is absent from the cubicle. The statistical results also reveal that the number of absence occurrences decreases as total daily presence hours decrease, and the duration of absence from the cubicle decreases as the frequency of absence increases. The developed occupancy model captures the stochastic nature of occupants moving in and out of cubicles, and can be used to generate a more realistic occupancy schedule. This is crucial for improving the evaluation of the energy saving potential of occupancy based technologies and controls using building simulations. Finally, to demonstrate the use of the occupancy model, weekday occupant schedules were generated and discussed.

  11. The DOE Security Plan for the Energy Employees Occupational Illness Compensation Program

    Broader source: Energy.gov [DOE]

    The U.S. Congress passed the Energy Employees Occupational Illness Compensation Program Act (EEOICPA) in 2000. The purpose of EEOICPA is to compensate eligible employees and former employees of the Department of Energy (DOE), its contractors and subcontractors, or certain survivors of such individuals for occupational illness and death arising from work at a covered facility.

  12. DOE Issues Request for Proposals for Hanford Site Occupational Medical Services

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – The Department of Energy (DOE) today issued a Request for Proposals (RFP) for an Occupational Medical Services contract at the Hanford Site. The solicitation is for a small-business contractor to perform occupational medical services for the DOE Richland Operations Office and Office of River Protection.

  13. Occupational radiation Exposure at Agreement State-Licensed Materials Facilities, 1997-2010

    SciTech Connect (OSTI)

    U.S. Nuclear Regulatory Commission, Office of Nuclear Regulatory Research

    2012-07-07

    The purpose of this report is to examine occupational radiation exposures received under Agreement State licensees. As such, this report reflects the occupational radiation exposure data contained in the Radiation Exposure Information and Reporting System (REIRS) database, for 1997 through 2010, from Agreement State-licensed materials facilities.

  14. Study of air pollution: Effects of ozone on neuropeptide-mediated responses in human subjects. Final report

    SciTech Connect (OSTI)

    Boushey, H.A.

    1991-11-01

    The study examined the hypothesis that ozone inactivates the enzyme, neutral endopeptidase, responsible for limiting the effects of neuropeptides released from afferent nerve endings. Cough response of capsaicin solution delivered from a nebulizer at 2 min. intervals until two or more coughs were produced. Other endpoints measured included irritative symptoms as rated by the subjects on a nonparametric scale, spirometry, of each concentration of ozone were compared to those of filtered air in a single-blind randomized sequence. The results indicate that a 2 h. exposure to 0.4 ppm of ozone with intermittent light exercise alters the sensitivity of airway nerves that mediate the cough response to inhaled materials. This dose of ozone also caused a change in FEV1. A lower level of ozone, 0.02 ppm, caused a change in neither cough threshold nor FEV1, even when the duration of exposure was extended to three hours. The findings are consistent with the author's hypothesis that ozone may sensitize nerve endings in the airways by inactivating neutral endopeptidase, an enzyme that regulates their activity, but they do not demonstrate that directly examining an effect directly mediated by airway nerves allows detection of effects of ozone at doses below those causing effects detected by standard tests of pulmonary function.

  15. Valuing the ozone-related health benefits of methane emission controls

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarofim, Marcus C.; Waldhoff, Stephanie T.; Anenberg, Susan C.

    2015-06-29

    Methane is a greenhouse gas that oxidizes to form ground-level ozone, itself a greenhouse gas and a health-harmful air pollutant. Reducing methane emissions will both slow anthropogenic climate change and reduce ozone-related mortality. We estimate the benefits of reducing methane emissions anywhere in the world for ozone-related premature mortality globally and for eight geographic regions. Our methods are consistent with those used by the US Government to estimate the social cost of carbon (SCC). We find that the global short- and long-term premature mortality benefits due to reduced ozone production from methane mitigation are (2011) $790 and $1775 per tonnemore » methane, respectively. These correspond to approximately 70 and 150 % of the valuation of methane’s global climate impacts using the SCC after extrapolating from carbon dioxide to methane using global warming potential estimates. Results for monetized benefits are sensitive to a number of factors, particularly the choice of elasticity to income growth used when calculating the value of a statistical life. The benefits increase for emission years further in the future. Regionally, most of the global mortality benefits accrue in Asia, but 10 % accrue in the United States. As a result, this methodology can be used to assess the benefits of methane emission reductions anywhere in the world, including those achieved by national and multinational policies.« less

  16. Narrowband filter radiometer for ground-based measurements of global ultraviolet solar irradiance and total ozone

    SciTech Connect (OSTI)

    Petkov, Boyan; Vitale, Vito; Tomasi, Claudio; Bonafe, Ubaldo; Scaglione, Salvatore; Flori, Daniele; Santaguida, Riccardo; Gausa, Michael; Hansen, Georg; Colombo, Tiziano

    2006-06-20

    The ultraviolet narrowband filter radiometer (UV-RAD) designed by the authors to take ground-based measurements of UV solar irradiance, total ozone, and biological dose rate is described, together with the main characteristics of the seven blocked filters mounted on it, all of which have full widths at half maxima that range 0.67 to 0.98 nm. We have analyzed the causes of cosine response and calibration errors carefully to define the corresponding correction terms, paying particular attention to those that are due to the spectral displacements of the filter transmittance peaks from the integer wavelength values. The influence of the ozone profile on the retrieved ozone at large solar zenith angles has also been examined by means of field measurements. The opportunity of carrying out nearly monochromatic irradiance measurements offered by the UV-RAD allowed us to improve the procedure usually followed to reconstruct the solar spectrum at the surface by fitting the computed results, using radiative transfer models with field measurements of irradiance. Two long-term comparison campaigns took place, showing that a mean discrepancy of+0.3% exists between the UV-RAD total ozone values and those given by the Brewer no. 63 spectroradiometer and that mean differences of+0.3% and-0.9% exist between the erythemal dose rates determined with the UV-RAD and those obtained with the Brewer no. 63 and the Brewer no. 104 spectroradiometers, respectively.

  17. Development of pollution reduction strategies for Mexico City: Estimating cost and ozone reduction effectiveness

    SciTech Connect (OSTI)

    Thayer, G.R.; Hardie, R.W.; Barrera-Roldan, A.

    1993-12-31

    This reports on the collection and preparation of data (costs and air quality improvement) for the strategic evaluation portion of the Mexico City Air Quality Research Initiative (MARI). Reports written for the Mexico City government by various international organizations were used to identify proposed options along with estimates of cost and emission reductions. Information from appropriate options identified by SCAQMD for Southem California were also used in the analysis. A linear optimization method was used to select a group of options or a strategy to be evaluated by decision analysis. However, the reduction of ozone levels is not a linear function of the reduction of hydrocarbon and NO{sub x} emissions. Therefore, a more detailed analysis was required for ozone. An equation for a plane on an isopleth calculated with a trajectory model was obtained using two endpoints that bracket the expected total ozone precursor reductions plus the starting concentrations for hydrocarbons and NO{sub x}. The relationship between ozone levels and the hydrocarbon and NO{sub x} concentrations was assumed to lie on this plane. This relationship was used in the linear optimization program to select the options comprising a strategy.

  18. Biokinetic data and models for occupational intake of lanthanoids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leggett, Richard Wayne; Ansoborlo, Eric; Bailey, Michael; Gregoratto, Demetrio; Pacquet, Francois; Taylor, David

    2014-05-12

    The lanthanoid (or lanthanide) chemical elements comprise fifteen elements with atomic numbers 57 (lanthanum) through 71 (lutetium). This paper reviews data related to the biological behavior of these elements in the human body and proposes biokinetic models for application to occupational intake of radio-lanthanoids. Generic (element-independent) absorption rates from the respiratory and alimentary tracts to blood are proposed. The proposed systemic models are largely generic but include some element-specific parameter values to reflect regular changes with ionic radius in certain aspects of the behavior of the lanthanoids. This work was performed within the internal dosimetry task group (INDOS) of Committeemore » 2 of the International Commission on Radiological Protection (ICRP).« less

  19. Biokinetic data and models for occupational intake of lanthanoids

    SciTech Connect (OSTI)

    Leggett, Richard Wayne; Ansoborlo, Eric; Bailey, Michael; Gregoratto, Demetrio; Pacquet, Francois; Taylor, David

    2014-05-12

    The lanthanoid (or lanthanide) chemical elements comprise fifteen elements with atomic numbers 57 (lanthanum) through 71 (lutetium). This paper reviews data related to the biological behavior of these elements in the human body and proposes biokinetic models for application to occupational intake of radio-lanthanoids. Generic (element-independent) absorption rates from the respiratory and alimentary tracts to blood are proposed. The proposed systemic models are largely generic but include some element-specific parameter values to reflect regular changes with ionic radius in certain aspects of the behavior of the lanthanoids. This work was performed within the internal dosimetry task group (INDOS) of Committee 2 of the International Commission on Radiological Protection (ICRP).

  20. Biokinetic data and models for occupational intake of lanthanoids

    SciTech Connect (OSTI)

    Leggett, Richard Wayne; Ansoborlo, Eric; Bailey, Dr. Michael; Gregoratto, Demetrio; Pacquet, Dr. Francois; Taylor, Dr. David

    2014-01-01

    The lanthanoid (or lanthanide) chemical elements comprise fifteen elements with atomic numbers 57 (lanthanum) through 71 (lutetium). This paper reviews data related to the biological behavior of these elements in the human body and proposes biokinetic models for application to occupational intake of radio-lanthanoids. Generic (element-independent) absorption rates from the respiratory and alimentary tracts to blood are proposed. The proposed systemic models are largely generic but include some element-specific parameter values to reflect regular changes with ionic radius in certain aspects of the behavior of the lanthanoids. This work was performed within the internal dosimetry task group (INDOS) of Committee 2 of the International Commission on Radiological Protection (ICRP).

  1. Occupational Radiation Exposure Analysis of US ITER DCLL TBM

    SciTech Connect (OSTI)

    Merrill, Brad J; Cadwallader, Lee C; Dagher, Mohamad

    2007-08-01

    This report documents an Occupational Radiation Exposure (ORE) analysis that was performed for the US International Thermonuclear Experimental Reactor (ITER) Dual Coolant Lead Lithium (DCLL) Test Blanket Module (TBM). This analysis was performed with the QADMOD dose code for anticipated maintenance activities for this TBM concept and its ancillary systems. The QADMOD code was used to model the PbLi cooling loop of this TBM concept by specifying gamma ray source terms that simulated radioactive material within the piping, valves, heat exchanger, permeator, pump, drain tank, and cold trap of this cooling system. Estimates of the maintenance tasks that will have to be performed and the time required to perform these tasks where developed based on either expert opinion or on industrial maintenance experience for similar technologies. This report details the modeling activity and the calculated doses for the maintenance activities envisioned for the US DCLL TBM.

  2. The Impact of Emission and Climate Change on Ozone in the United States under Representative Concentration Pathways (RCPs)

    SciTech Connect (OSTI)

    Gao, Yang; Fu, Joshua S.; Drake, John B.; Lamarque, J.-F.; Liu, Yang

    2013-09-27

    Dynamical downscaling was applied in this study to link the global climate-chemistry model Community Atmosphere Model (CAM-Chem) with the regional models: Weather Research and Forecasting (WRF) Model and Community Multi-scale Air Quality (CMAQ). Two Representative Concentration Pathway (RCP) scenarios (RCP 4.5 and RCP 8.5) were used to evaluate the climate impact on ozone concentrations in 2050s. Ozone concentrations in the lower-mid troposphere (surface to ~300 hPa), from mid- to high latitudes in the Northern Hemisphere (NH), show decreasing trends in RCP 4.5 between 2000s and 2050s, with the largest decrease of 4-10 ppbv occurring in the summer and the fall; and increasing trends (2-12 ppbv) in RCP 8.5 resulting from the increased methane emissions. In RCP 8.5, methane emissions increase by ~60% by the end of 2050s, accounting for more than 90% of ozone increases in summer and fall, and 60-80% in spring and winter. Under the RCP 4.5 scenario, in the summer when photochemical reactions are the most active, the large ozone precursor emissions reduction leads to the greatest decrease of downscaled surface ozone concentrations, ranging from 6 to 10 ppbv. However, a few major cities show ozone increases of 3 to 7 ppbv due to weakened NO titration. Under the RCP 8.5 scenario, in winter, downscaled ozone concentrations increase across nearly the entire continental US in winter, ranging from 3 to 10 ppbv due to increased methane emissions and enhanced stratosphere-troposphere exchange (STE). More intense heat waves are projected to occur by the end of 2050s in RCP 8.5, leading to more than 8 ppbv of the maximum daily 8-hour daily average (MDA8) ozone during the heat wave days than other days; this indicates the dramatic impact heat waves exert on high frequency ozone events.

  3. Calendar Year 2014 Department of Energy Annual Occupational Safety and Health Report for Federal Employees to the Secretary of Labor

    Broader source: Energy.gov [DOE]

    Calendar Year 2014 Department of Energy Annual Occupational Safety and Health Report for Federal Employees to the Secretary of Labor

  4. Stochastic Modeling of Overtime Occupancy and Its Application in Building Energy Simulation and Calibration

    SciTech Connect (OSTI)

    Sun, Kaiyu; Yan , Da; Hong , Tianzhen; Guo, Siyue

    2014-02-28

    Overtime is a common phenomenon around the world. Overtime drives both internal heat gains from occupants, lighting and plug-loads, and HVAC operation during overtime periods. Overtime leads to longer occupancy hours and extended operation of building services systems beyond normal working hours, thus overtime impacts total building energy use. Current literature lacks methods to model overtime occupancy because overtime is stochastic in nature and varies by individual occupants and by time. To address this gap in the literature, this study aims to develop a new stochastic model based on the statistical analysis of measured overtime occupancy data from an office building. A binomial distribution is used to represent the total number of occupants working overtime, while an exponential distribution is used to represent the duration of overtime periods. The overtime model is used to generate overtime occupancy schedules as an input to the energy model of a second office building. The measured and simulated cooling energy use during the overtime period is compared in order to validate the overtime model. A hybrid approach to energy model calibration is proposed and tested, which combines ASHRAE Guideline 14 for the calibration of the energy model during normal working hours, and a proposed KS test for the calibration of the energy model during overtime. The developed stochastic overtime model and the hybrid calibration approach can be used in building energy simulations to improve the accuracy of results, and better understand the characteristics of overtime in office buildings.

  5. Wastewater treatment: Ozonation processes and equipment. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The bibliography contains citations concerning the use of ozone for wastewater disinfection. The citations cover system descriptions and evaluations, comparisons with the chlorination disinfection process, reaction kinetics, and the combination of ozonation with other wastewater treatment methods. The treatment of organic and inorganic compounds in wastewater and municipal water supplies is also discussed. (Contains 250 citations and includes a subject term index and title list.)

  6. Wastewater treatment: Ozonation processes and equipment. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-03-01

    The bibliography contains citations concerning the use of ozone for wastewater disinfection. The citations cover system descriptions and evaluations, comparisons with the chlorination disinfection process, reaction kinetics, and the combination of ozonation with other wastewater treatment methods. The treatment of organic and inorganic compounds in wastewater and municipal water supplies is also discussed. (Contains 250 citations and includes a subject term index and title list.)

  7. Demonstration of Advanced Technologies for Multi-Load Washers in Hospitality and Healthcare -- Ozone Based Laundry Systems

    SciTech Connect (OSTI)

    Boyd, Brian K.; Parker, Graham B.; Petersen, Joseph M.; Sullivan, Greg; Goetzler, W.; Sutherland, T. A.; Foley, K. J.

    2014-08-14

    The objective of this demonstration project was to evaluate market-ready retrofit technologies for reducing the energy and water use of multi-load washers in healthcare and hospitality facilities. Specifically, this project evaluated laundry wastewater recycling technology in the hospitality sector and ozone laundry technology in both the healthcare and hospitality sectors. This report documents the demonstration of ozone laundry system installations at the Charleston Place Hotel in Charleston, South Carolina, and the Rogerson House assisted living facility in Boston, Massachusetts.

  8. Water vapor and ozone profiles with a CO{sub 2} DIAL system in south Italy

    SciTech Connect (OSTI)

    Bellecci, C.; Caputi, G.; De Donato, F.; Gaudio, P.; Valentini, M.

    1996-12-31

    In this paper the authors present the work carried out at the University of Calabria regarding a prototype of a DIAL system. This has been realized for remote pollution monitoring. Most of the efforts have been done to perform several measurements on an horizontal path in order to scan the wide surrounding area. The concentrations of ozone and water vapor have been carried out using two different methods both related with the DIAL technique. With the integrated technique, average concentrations have been evaluated up to 5 km using topographical targets. In the range resolution technique, profiles of ozone and water vapor have been performed up to 700 m with a spatial resolution of about 30 m. Although the system needs a revision in several subsystems of its set-up, the experimentation has pointed out the performance available and the necessary improvements.

  9. Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

  10. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L.; Koss, T.C.

    1992-10-01

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  11. Tropospheric and Lower Stratospheric Ozone Profiles From AERI-X Emission Spectra

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tropospheric and Lower Stratospheric Ozone Profiles From AERI-X Emission Spectra P. F. Fogal and F. J. Murcray Department of Physics and Astronomy University of Denver Denver, Colorado Introduction The University of Denver Atmospheric Emission Radiometric Interferometer-Extended (AERI-X) has been in regular operation at the Southern Great Plains (SGP) Atmospheric Radiation Measurements (ARM) Program site, conditions permitting, since the mid-1990s. We present here the analysis of several spectra

  12. A new feature in the internal heavy isotope distribution in ozone

    SciTech Connect (OSTI)

    Bhattacharya, S. K. Liang, Mao-Chang; Savarino, Joel; Michalski, G.

    2014-10-07

    Ozone produced by discharge or photolysis of oxygen has unusually heavy isotopic composition ({sup 18}O/{sup 16}O and {sup 17}O/{sup 16}O ratio) which does not follow normal mass fractionation rule: δ{sup 17}O ∼ 0.52{sup *}δ{sup 18}O, expressed as an anomaly Δ{sup 17}O = δ{sup 17}O − 0.52{sup *}δ{sup 18}O. Ozone molecule being an open isosceles triangle can have the heavy isotope located either in its apex or symmetric (s) position or the base or asymmetric (as) position. Correspondingly, one can define positional isotopic enrichment, written as δ{sup 18}O (s) or δ{sup 18}O (as) (and similarly for δ{sup 17}O) as well as position dependent isotope anomaly Δ{sup 17}O (s) and Δ{sup 17}O (as). Marcus and co-workers have proposed a semi-empirical model based in principle on the RRKM model of uni-molecular dissociation but with slight modification (departure from statistical randomness assumption for symmetrical molecules) which explains many features of ozone isotopic enrichment. This model predicts that the bulk isotope anomaly is contained wholly in the asymmetric position and the Δ{sup 17}O (s) is zero. Consequently, Δ{sup 17}O (as) = 1.5 {sup *} Δ{sup 17}O (bulk) (named here simply as the “1.5 rule”) which has been experimentally confirmed over a range of isotopic enrichment. We now show that a critical re-analysis of the earlier experimental data demonstrates a small but significant departure from this 1.5 rule at the highest and lowest levels of enrichments. This departure provides the first experimental proof that the dynamics of ozone formation differs from a statistical model constrained only by restriction of symmetry. We speculate over some possible causes for the departure.

  13. Effects of ozone on the respiratory health, allergic sensitization, and cellular immune system in children

    SciTech Connect (OSTI)

    Zwick, H.; Popp, W.; Wagner, C.; Reiser, K.; Schmoeger, J.B.; Boeck, A.H.; Herkner, K.; Radunsky, K. )

    1991-11-01

    To investigate the lasting effects of high ozone concentrations under environmental conditions, we examined the respiratory health, pulmonary function, bronchial hyperresponsiveness to methacholine, allergic sensitization, and lymphocyte subpopulations of 10- to 14-yr-old children. A total of 218 children recruited from an area with high ozone concentrations (Group A) were tested against 281 children coming from an area with low ozone concentrations (Group B). As to subjective complaints, categorized as 'usually cough with or without phlegm,' 'breathlessness,' and 'susceptibility to chest colds,' there was no difference between the two groups. The lung function parameters were similar, but in Group A subjects' bronchial hyperresponsiveness occurred more frequently and was found to be more severe than in Group B (29.4 versus 19.9%, p less than 0.02; PD20 2,100 {plus minus} 87 versus 2,350 {plus minus} 58 micrograms, p less than 0.05). In both groups the number of children who had been suffering from allergic diseases and sensitization to aeroallergens, found by means of the skin test, was the same. Comparison of the total IgE levels showed no difference at all between the two groups. As far as the white blood cells are concerned, the total and differential cell count was the same, whereas lymphocyte subpopulations showed readily recognizable changes.

  14. Guide of Good Practices for Occupational Radiological Protection in Uranium Facilities

    Energy Savers [EERE]

    36-2009 July 2009 DOE STANDARD GUIDE OF GOOD PRACTICES FOR OCCUPATIONAL RADIOLOGICAL PROTECTION IN URANIUM FACILITIES U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. DOE-STD-1136-2009 Guide of Good Practices for Occupational Radiological Protection in Uranium Facilities i This document is available on the Department of Energy Technical Standards Program Web Site at

  15. Development of Occupational Exposure Limits for the Hanford Tank Farms

    SciTech Connect (OSTI)

    Still, Kenneth; Gardner, Donald; Snyder, Robert; Anderson, Thomas; Honeyman, James; Timchalk, Charles

    2010-04-01

    Production of plutonium for the United States nuclear weapons program from the 1940s to the 1980s generated 53 million gallons of radioactive chemical waste, which is storedin 177 underground tanks at the Hanford Site in southeastern W 18 ashington State. Recent 19 attempts to begin the retrieval and treatment of these wastes require moving the waste to 20 more modern tanks results in potential exposure of the workers to unfamiliar odors 21 emanating from headspace in the tanks. Given the unknown risks involved, workers 22 were placed on supplied air respiratory protection. CH2M HILL, the managers of the 23 Hanford Site Tank Farms, asked an Independent Toxicology Panel (ITP) to assist them in issues relating to an Industrial Hygiene and risk assessment problem. The ITP was called upon to help determine the risk of exposure to vapors from the tanks, and in general develop a strategy for solution of the problem. This paper presents the methods used to determine the chemicals of potential concern (COPC) and the resultant development of screening values and Acceptable Occupational Exposure Limits (AOELs) for these COPCs. A total of 1,826 chemicals were inventoried and evaluated. Over 1,500 chemicals were identified in the waste tanks headspaces and more than 600 of these were assigned screening values; 72 of these compounds were recommended for AOEL development. Included in this list of 72 were 57 COPCs identified by the ITP and of these 47 were subsequently assigned AOELs. An exhaustive exposure assessment strategy was developed by the CH2M HILL industrial hygiene department to evaluate these COPCs.

  16. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃

    SciTech Connect (OSTI)

    Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi; Shadike, Zulipiya; Huang, Xuan-Qi; Luo, Jun; Yang, Zhen-Zhong; Li, Hong; Gu, Lin; Yang, Xiao-Qing; Fu, Zheng-Wen

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe₂(MoO₄)₃ electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na⁺ and Li⁺, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe₂(MoO₄)₃ and the one by one Na occupation (pseudo-continuous occupation) at 8d sites in partially sodiated Fe₂(MoO₄)₃ are obtained during the discharge processes of Li/Fe₂(MoO₄)₃ and Na/Fe₂(MoO₄)₃ cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.

  17. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe?(MoO?)?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji -Li; Zhou, Yong -Ning; Shi, Si -Qi; Shadike, Zulipiya; Huang, Xuan -Qi; Luo, Jun; Yang, Zhen -Zhong; Li, Hong; Gu, Lin; Yang, Xiao -Qing; et al

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe?(MoO?)? electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na? and Li?, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe?(MoO?)? and the one by one Na occupation (pseudo-continuous occupation) at 8d sites inmorepartially sodiated Fe?(MoO?)? are obtained during the discharge processes of Li/Fe?(MoO?)? and Na/Fe?(MoO?)? cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.less

  18. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe₂(MoO₄)₃

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi; Shadike, Zulipiya; Huang, Xuan-Qi; Luo, Jun; Yang, Zhen-Zhong; Li, Hong; Gu, Lin; Yang, Xiao-Qing; et al

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe₂(MoO₄)₃ electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na⁺ and Li⁺, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe₂(MoO₄)₃ and the one by one Na occupation (pseudo-continuous occupation) at 8d sites inmore » partially sodiated Fe₂(MoO₄)₃ are obtained during the discharge processes of Li/Fe₂(MoO₄)₃ and Na/Fe₂(MoO₄)₃ cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.« less

  19. Stratospheric ozone protection: The Montreal Protocol and Title VI of the Clean Air Act Amendments of 1990

    SciTech Connect (OSTI)

    Babst, C.R. III

    1993-08-01

    The stratospheric ozone layer protects the surface of the Earth from harmful ultraviolet (UV-B) radiation, which has been causally linked to skin cancer and cataracts, suppression of the human immune system, damage to crops and aquatic organisms, the formation of ground-level zone and the rapid weathering of outdoor plastics. In recent years, scientists have observed a significant deterioration of the ozone layer, particularly over the poles, but increasingly over populated regions as well. This deterioration has been attributed to the atmospheric release of certain man-made halocarbons, including chlorofluorocarbons (CFCs), halons, methyl chloroform and carbon tetrachloride. Once used extensively as propellants for aerosol sprays (but generally banned for such purposes since 1978), CFCs are widely used today as refrigerants, foams and solvents. All of these chlorinated (CFC, methyl chloroform and carbon tetrachloride) and brominated (halon) compounds are classified for regulatory purposes as Class I substances because of their significant ozone-depleting potential. Hydrochlorofluorocarbons (HCFCs), developed as alternatives to CFCs and halons for many different applications, have been classified for regulatory purposes as Class II substances because of their relatively less destructive impact on stratospheric ozone. This paper describes the following regulations to reduce destruction of the ozone layer: the Montreal Protocol; Title VI of the Clean air Act Amendments of 1990; Accelerated Phase-out schedules developed by the countries which signed the Montreal Protocol; Use restrictions; Recycling and Emission reduction requirements; Servicing of motor vehicle air conditions; ban on nonessential products; labeling requirements; safe alternatives. 6 refs.

  20. Use of North American and European air quality networks to evaluate global chemistry-climate modeling of surface ozone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schnell, J. L.; Prather, M. J.; Josse, B.; Naik, V.; Horowitz, L. W.; Cameron-Smith, P.; Bergmann, D.; Zeng, G.; Plummer, D. A.; Sudo, K.; et al

    2015-04-16

    We test the current generation of global chemistry-climate models in their ability to simulate observed, present-day surface ozone. Models are evaluated against hourly surface ozone from 4217 stations in North America and Europe that are averaged over 1° × 1° grid cells, allowing commensurate model-measurement comparison. Models are generally biased high during all hours of the day and in all regions. Most models simulate the shape of regional summertime diurnal and annual cycles well, correctly matching the timing of hourly (~ 15:00) and monthly (mid-June) peak surface ozone abundance. The amplitude of these cycles is less successfully matched. The observedmore » summertime diurnal range (~ 25 ppb) is underestimated in all regions by about 7 ppb, and the observed seasonal range (~ 21 ppb) is underestimated by about 5 ppb except in the most polluted regions where it is overestimated by about 5 ppb. The models generally match the pattern of the observed summertime ozone enhancement, but they overestimate its magnitude in most regions. Most models capture the observed distribution of extreme episode sizes, correctly showing that about 80% of individual extreme events occur in large-scale, multi-day episodes of more than 100 grid cells. The observed linear relationship showing increases in ozone by up to 6 ppb for larger-sized episodes is also matched.« less

  1. Ozone generation by negative direct current corona discharges in dry air fed coaxial wire-cylinder reactors

    SciTech Connect (OSTI)

    Yehia, Ashraf; Mizuno, Akira

    2013-05-14

    An analytical study was made in this paper for calculating the ozone generation by negative dc corona discharges. The corona discharges were formed in a coaxial wire-cylinder reactor. The reactor was fed by dry air flowing with constant rates at atmospheric pressure and room temperature, and stressed by a negative dc voltage. The current-voltage characteristics of the negative dc corona discharges formed inside the reactor were measured in parallel with concentration of the generated ozone under different operating conditions. An empirical equation was derived from the experimental results for calculating the ozone concentration generated inside the reactor. The results, that have been recalculated by using the derived equation, have agreed with the experimental results over the whole range of the investigated parameters, except in the saturation range for the ozone concentration. Therefore, the derived equation represents a suitable criterion for expecting the ozone concentration generated by negative dc corona discharges in dry air fed coaxial wire-cylinder reactors under any operating conditions in range of the investigated parameters.

  2. Occupational Health Services Part I DE-AC06-04RL14383, Modification No. 171 Section B

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Occupational Health Services Part I DE-AC06-04RL14383, Modification No. 171 Section B Page B-2 B.1 Occupational Medical Services a. This is a performance-based, cost reimbursement service contract for the rendering of Occupational Medical Services for the U. S. Department of Energy's Hanford Site. The Contractor shall furnish all personnel, facilities, equipment, material, supplies, and services (except as expressly set forth in this contract as furnished by the Government) and otherwise do all

  3. X-RAY CONSTRAINTS ON THE LOCAL SUPERMASSIVE BLACK HOLE OCCUPATION FRACTION

    SciTech Connect (OSTI)

    Miller, Brendan P.; Gallo, Elena; Baldassare, Vivienne; Greene, Jenny E.; Kelly, Brandon C.; Treu, Tommaso; Woo, Jong-Hak

    2015-01-20

    Distinct seed formation mechanisms are imprinted upon the fraction of dwarf galaxies currently containing a central supermassive black hole. Seeding by Population III remnants is expected to produce a higher occupation fraction than is generated with direct gas collapse precursors. Chandra observations of nearby early-type galaxies can directly detect even low-level supermassive black hole activity, and the active fraction immediately provides a firm lower limit to the occupation fraction. Here, we use the volume-limited AMUSE surveys of ?200 optically selected early-type galaxies to characterize simultaneously, for the first time, the occupation fraction and the scaling of L {sub X} with M {sub star}, accounting for intrinsic scatter, measurement uncertainties, and X-ray limits. For early-type galaxies with M {sub star} < 10{sup 10} M {sub ?}, we obtain a lower limit to the occupation fraction of >20% (at 95% confidence), but full occupation cannot be excluded. The preferred dependence of log L {sub X} upon log M {sub star} has a slope of ?0.7-0.8, consistent with the ''downsizing'' trend previously identified from the AMUSE data set, and a uniform Eddington efficiency is disfavored at ?2?. We provide guidelines for the future precision with which these parameters may be refined with larger or more sensitive samples.

  4. DOE Issues Draft Request for Proposals for Hanford Site Occupational Medical Services- Agency Solicits Input from Industry, Stakeholders, and Workforce

    Broader source: Energy.gov [DOE]

    The Department of Energy today issued a Draft Request for Proposals (RFP) for an Occupational Medical Services acquisition at the Hanford Site in southeastern Washington State.

  5. Detection of ocean glint and ozone absorption using LCROSS Earth observations

    SciTech Connect (OSTI)

    Robinson, Tyler D.; Ennico, Kimberly; Meadows, Victoria S.; Sparks, William; Schwieterman, Edward W.; Bussey, D. Ben J.; Breiner, Jonathan

    2014-06-01

    The Lunar CRater Observation and Sensing Satellite (LCROSS) observed the distant Earth on three occasions in 2009. These data span a range of phase angles, including a rare crescent phase view. For each epoch, the satellite acquired near-infrared and mid-infrared full-disk images, and partial-disk spectra at 0.26-0.65 μm (λ/Δλ ∼ 500) and 1.17-2.48 μm (λ/Δλ ∼ 50). Spectra show strong absorption features due to water vapor and ozone, which is a biosignature gas. We perform a significant recalibration of the UV-visible spectra and provide the first comparison of high-resolution visible Earth spectra to the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional spectral Earth model. We find good agreement with the observations, reproducing the absolute brightness and dynamic range at all wavelengths for all observation epochs, thus validating the model to within the ∼10% data calibration uncertainty. Data-model comparisons reveal a strong ocean glint signature in the crescent phase data set, which is well matched by our model predictions throughout the observed wavelength range. This provides the first observational test of a technique that could be used to determine exoplanet habitability from disk-integrated observations at visible and near-infrared wavelengths, where the glint signal is strongest. We examine the detection of the ozone 255 nm Hartley and 400-700 nm Chappuis bands. While the Hartley band is the strongest ozone feature in Earth's spectrum, false positives for its detection could exist. Finally, we discuss the implications of these findings for future exoplanet characterization missions.

  6. Effects of ambient ozone on respiratory function and symptoms in Mexico City schoolchildren

    SciTech Connect (OSTI)

    Castillejos, M.; Gold, D.R.; Dockery, D.; Tosteson, T.; Baum, T.; Speizer, F.E. )

    1992-02-01

    The effects of ambient ozone (O3) on respiratory function and acute respiratory symptoms were evaluated in 143 7- to 9-yr-old schoolchildren followed longitudinally at 1- to 2-wk intervals over a period of 6 months at three schools in Pedregal, Mexico City. The maximum O3 level exceeded the World Health Organization guideline of 80 ppb and the U.S. standard of 120 ppb in every week. For an increase from lowest to highest in the mean O3 level during the 48 hr before spirometry (53 ppb), logistic regression estimated relative odds of 1.7 for a child reporting cough/phlegm on the day of spirometry. For the full population, the mean O3 level during the hour before spirometry, not adjusted for temperature and humidity, predicted a significant decrement in FVC but not in FEV1 or FEF25-75. In contrast, the mean O3 level during the previous 24-, 48-, and 168-h periods predicted significant decrements in FEV1 and FEF25-75 but not in FVC. Ozone was consistently associated with a greater decrement in lung function for the 15 children with chronic phlegm as compared with the children without chronic cough, chronic phlegm, or wheeze. Ozone in the previous 24-, 48-, and 168-h periods predicted decrements in FEV1 for children of mothers who were current or former smokers, but not for children of mothers who were never smokers. Many of these effects were reduced in multiple regression analyses including temperature and humidity, as temperature and O3 were highly correlated.

  7. Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region

    SciTech Connect (OSTI)

    Steiner, A. L.; Tawfik, A. B.; Shalaby, A.; Zakey, A. S.; Abdel Wahab, M. M.; Salah, Z.; Solmon, F.; Sillman, S.; Zaveri, Rahul A.

    2014-04-16

    An integrated chemistry-climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on Greater Cairo (GC) region. The densley populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjuction with natural sources such as dust and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average-ground-based NO2 observations of 40-60 ppb are substantially higher than modeled estimates (5-10 ppb), likely due to model grid resolution, improper boundary layer representation, and poor emissions inventories. Observed ozone concentrations range from 35 ppb (winter) to 80 ppb (summer). The model reproduces the seasonal cycle fairly well, but modeled summer ozone is understimated by approximately 15 ppb and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry-climate model captures the springtime peak aerosol optical depth (AOD) of 0.7-1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta, yet the model underestimates this fall observed AOD peak, as standard emissions inventories underestimate this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities are needed to improve air quality simulations in this region.

  8. Highly reproducible and reliable metal/graphene contact by ultraviolet-ozone treatment

    SciTech Connect (OSTI)

    Li, Wei [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China); Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Hacker, Christina A.; Cheng, Guangjun; Hight Walker, A. R.; Richter, Curt A.; Gundlach, David J., E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn [Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Liang, Yiran; Tian, Boyuan; Liang, Xuelei, E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn; Peng, Lianmao [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China)

    2014-03-21

    Resist residue from the device fabrication process is a significant source of contamination at the metal/graphene contact interface. Ultraviolet Ozone (UVO) treatment is proven here, by X-ray photoelectron spectroscopy and Raman measurement, to be an effective way of cleaning the metal/graphene interface. Electrical measurements of devices that were fabricated by using UVO treatment of the metal/graphene contact region show that stable and reproducible low resistance metal/graphene contacts are obtained and the electrical properties of the graphene channel remain unaffected.

  9. Systemic responses to inhaled ozone in mice: cachexia and down-regulation of liver xenobiotic metabolizing genes

    SciTech Connect (OSTI)

    Last, Jerold A. . E-mail: jalast@ucdavis.edu; Gohil, Kishorchandra; Mathrani, Vivek C.; Kenyon, Nicholas J.

    2005-10-15

    Rats or mice acutely exposed to high concentrations of ozone show an immediate and significant weight loss, even when allowed free access to food and water. The mechanisms underlying this systemic response to ozone have not been previously elucidated. We have applied the technique of global gene expression analysis to the livers of C57BL mice acutely exposed to ozone. Mice lost up to 14% of their original body weight, with a 42% decrease in total food consumption. We previously had found significant up-regulation of genes encoding proliferative enzymes, proteins related to acute phase reactions and cytoskeletal functions, and other biomarkers of a cachexia-like inflammatory state in lungs of mice exposed to ozone. These results are consistent with a general up-regulation of different gene families responsive to NF-{kappa}B in the lungs of the exposed mice. In the present study, we observed significant down-regulation of different families of mRNAs in the livers of the exposed mice, including genes related to lipid and fatty acid metabolism, and to carbohydrate metabolism in this tissue, consistent with a systemic cachexic response. Several interferon-dependent genes were down-regulated in the liver, suggesting a possible role for interferon as a signaling molecule between lung and liver. In addition, transcription of several mRNAs encoding enzymes of xenobiotic metabolism in the livers of mice exposed to ozone was decreased, suggesting cytokine-mediated suppression of cytochrome P450 expression. This finding may explain a previously controversial report from other investigators more than 20 years ago of prolongation of pentobarbital sleeping time in mice exposed to ozone.

  10. Use of North American and European air quality networks to evaluate global chemistry–climate modeling of surface ozone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schnell, J. L.; Prather, M. J.; Josse, B.; Naik, V.; Horowitz, L. W.; Cameron-Smith, P.; Bergmann, D.; Zeng, G.; Plummer, D. A.; Sudo, K.; et al

    2015-09-25

    We test the current generation of global chemistry–climate models in their ability to simulate observed, present-day surface ozone. Models are evaluated against hourly surface ozone from 4217 stations in North America and Europe that are averaged over 1° × 1° grid cells, allowing commensurate model–measurement comparison. Models are generally biased high during all hours of the day and in all regions. Most models simulate the shape of regional summertime diurnal and annual cycles well, correctly matching the timing of hourly (~ 15:00 local time (LT)) and monthly (mid-June) peak surface ozone abundance. The amplitude of these cycles is less successfullymore » matched. The observed summertime diurnal range (~ 25 ppb) is underestimated in all regions by about 7 ppb, and the observed seasonal range (~ 21 ppb) is underestimated by about 5 ppb except in the most polluted regions, where it is overestimated by about 5 ppb. The models generally match the pattern of the observed summertime ozone enhancement, but they overestimate its magnitude in most regions. Most models capture the observed distribution of extreme episode sizes, correctly showing that about 80 % of individual extreme events occur in large-scale, multi-day episodes of more than 100 grid cells. The models also match the observed linear relationship between episode size and a measure of episode intensity, which shows increases in ozone abundance by up to 6 ppb for larger-sized episodes. We conclude that the skill of the models evaluated here provides confidence in their projections of future surface ozone.« less

  11. Predicting tropospheric ozone and hydroxyl radical in a global, three-dimensional, chemistry, transport, and deposition model

    SciTech Connect (OSTI)

    Atherton, C.S.

    1995-01-05

    Two of the most important chemically reactive tropospheric gases are ozone (O{sub 3}) and the hydroxyl radical (OH). Although ozone in the stratosphere is a necessary protector against the sun`s radiation, tropospheric ozone is actually a pollutant which damages materials and vegetation, acts as a respiratory irritant, and is a greenhouse gas. One of the two main sources of ozone in the troposphere is photochemical production. The photochemistry is initiated when hydrocarbons and carbon monoxide (CO) react with nitrogen oxides (NO{sub x} = NO + NO{sub 2}) in the presence of sunlight. Reaction with the hydroxyl radical, OH, is the main sink for many tropospheric gases. The hydroxyl radical is highly reactive and has a lifetime on the order of seconds. Its formation is initiated by the photolysis of tropospheric ozone. Tropospheric chemistry involves a complex, non-linear set of chemical reactions between atmospheric species that vary substantially in time and space. To model these and other species on a global scale requires the use of a global, three-dimensional chemistry, transport, and deposition (CTD) model. In this work, I developed two such three dimensional CTD models. The first model incorporated the chemistry necessary to model tropospheric ozone production from the reactions of nitrogen oxides with carbon monoxide (CO) and methane (CH{sub 4}). The second also included longer-lived alkane species and the biogenic hydrocarbon isoprene, which is emitted by growing plants and trees. The models` ability to predict a number of key variables (including the concentration of O{sub 3}, OH, and other species) were evaluated. Then, several scenarios were simulated to understand the change in the chemistry of the troposphere since preindustrial times and the role of anthropogenic NO{sub x} on present day conditions.

  12. Use of Occupancy Sensors in LED Parking Lot and Garage Applications: Early Experiences

    SciTech Connect (OSTI)

    Kinzey, Bruce R.; Myer, Michael; Royer, Michael P.; Sullivan, Greg P.

    2012-11-07

    Occupancy sensor systems are gaining traction as an effective technological approach to reducing energy use in exterior commercial lighting applications. Done correctly, occupancy sensors can substantially enhance the savings from an already efficient lighting system. However, this technology is confronted by several potential challenges and pitfalls that can leave a significant amount of the prospective savings on the table. This report describes anecdotal experiences from field installations of occupancy sensor controlled light-emitting diode (LED) lighting at two parking structures and two parking lots. The relative levels of success at these installations reflect a marked range of potential outcomes: from an additional 76% in energy savings to virtually no additional savings. Several issues that influenced savings were encountered in these early stage installations and are detailed in the report. Ultimately, care must be taken in the design, selection, and commissioning of a sensor-controlled lighting installation, else the only guaranteed result may be its cost.

  13. Occupational safety data and casualty rates for the uranium fuel cycle. [Glossaries

    SciTech Connect (OSTI)

    O'Donnell, F.R.; Hoy, H.C.

    1981-10-01

    Occupational casualty (injuries, illnesses, fatalities, and lost workdays) and production data are presented and used to calculate occupational casualty incidence rates for technologies that make up the uranium fuel cycle, including: mining, milling, conversion, and enrichment of uranium; fabrication of reactor fuel; transportation of uranium and fuel elements; generation of electric power; and transmission of electric power. Each technology is treated in a separate chapter. All data sources are referenced. All steps used to calculate normalized occupational casualty incidence rates from the data are presented. Rates given include fatalities, serious cases, and lost workdays per 100 man-years worked, per 10/sup 12/ Btu of energy output, and per other appropriate units of output.

  14. Perspective on occupational radiation exposures at a hypothetical fusion power station

    SciTech Connect (OSTI)

    Easterly, C.E.; Cannon, J.B.

    1983-01-01

    If current technology were used, several major sources of potential occupational radiation exposure at fusion power stations would be quite similar to those at current light water reactor power stations. Based upon this similarity, crude estimates of doses received from various maintenance operations at fusion power reactors are made. The dose estimates reinforce the need for concurrent development of sophisticated remote maintenance devices and low-activation materials for fusion reactors. It is concluded that minimization of occupational doses can be best achieved by developing an overall maintenance strategy that combines the best features of remote techniques and low activation materials as opposed to developing one or the other exclusively.

  15. Genotypic variability in ponderosa pine responses to combined ozone and drought stresses

    SciTech Connect (OSTI)

    Temple, P.J.

    1995-06-01

    Five-year-old ponderosa (Pinus ponderosa Laws.) seedlings from 18 half-sib and one full-sib families obtained from the California Tree Improvement Program were harvested after 1, 2, and 3 growing seasons of exposure to three levels of ozone (O{sub 3}) and two levels of available soil water (ASW) in open-top chambers in the California Sierras. Seedlings were evaluated for O{sub 3} injury symptoms, biomass, and radial growth in response to these stresses. Ozone injury responses were highly variable across families, but family rankings for O{sub 3} injury were consistent across years. Family rankings for O{sub 3} injury were highly correlated with those for reductions in biomass and radial growth for trees in the high ASW treatment, but drought-stressed trees showed no consistent relation between foliar 03 injury and reductions in growth. After three seasons of exposure to 88 ppb O{sub 3}, foliar biomass of the three most susceptible families averaged 60% less than trees in the low-O{sub 3} control, while O{sub 3} had no effect on growth of the three most resistant families. Variability across families of growth responses to drought was significantly less than the variability in seedling responses to O{sub 3}.

  16. Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases. Final report

    SciTech Connect (OSTI)

    Prather, Michael J.; Hsu, Juno; Nicolau, Alex; Veidenbaum, Alex; Smith, Philip Cameron; Bergmann, Dan

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  17. NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games

    SciTech Connect (OSTI)

    Yang, Qing; Wang, Yuhang; Zhao, Chun; Liu, Zhen; Gustafson, William I.; Shao, Min

    2011-07-15

    We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 Sep 20, 2008). The emission reduction began in early July and was in full force by July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.

  18. Volatile organic compound emissions from usaf wastewater treatment plants in ozone nonattainment areas. Master's thesis

    SciTech Connect (OSTI)

    Ouellette, B.A.

    1994-09-01

    In accordance with the 1990 Clean Air Act Amendments (CAAA), this research conducts an evaluation of the potential emission of volatile organic compounds (VOCs) from selected Air Force wastewater treatment plants. Using a conservative mass balance analysis and process specific simulation models, volatile organic emission estimates are calculated for four individual facilities--Edwards AFB, Luke AFB, McGuire AFB, and McClellan AFB--which represent a cross section of the current inventory of USAF wastewater plants in ozone nonattainment areas. From these calculations, maximum facility emissions are determined which represent the upper limit for the potential VOC emissions from these wastewater plants. Based on the calculated emission estimates, each selected wastewater facility is evaluated as a potential major stationary source of volatile organic emissions under both Title I of the 1990 CAAA and the plant's governing Clean Air Act state implementation plan. Next, the potential impact of the specific volatile organics being emitted is discussed in terms of their relative reactivity and individual contribution to tropospheric ozone formation. Finally, a relative comparison is made between the estimated VOC emissions for the selected wastewater facilities and the total VOC emissions for their respective host installations.

  19. Ozone-forming potential of a series of oxygenated organic compounds

    SciTech Connect (OSTI)

    Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. )

    1991-03-01

    An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

  20. Not in the want ads: Finding the emerging environmental occupations within economic and social change

    SciTech Connect (OSTI)

    Palumbo, M.J.

    1995-12-01

    The transition of America`s work force is an evolving process. Environmental issues, in general, and environment occupational dynamics, in specific, are complex and involve a wide variety of private and public organizations. The paper advocates a federal government role in directly supporting sustainable development oriented environmental programs to assist in the transition of today`s labor into the skilled and growing occupations of tomorrow. The American economy and the industrial organizations which define it are changing drastically. Much of this change has been influenced by compliance to strict environmental regulation and enforcement, protective labor laws, and the increased adoption of pollution prevention processes and principles. Additional factors include: increased international competition and free trade, a global recession, and increasingly flexible capital transfer and monetary markets. As the world approaches the turn of the century, technological change dominates the economic landscape. There is no clearly drawn map or model on how American labor will integrate, prepare, and train for the new jobs created from the practice of sustainable development. The policies and commitments necessary to drive the transition of our occupational work force are clearly in their infancy. Consequently, the study will collect and synthesize existing information related to environmental occupations, job growth, and sustainable development oriented programs. The study will conclude with a discussion of common themes and policies for business and labor leaders, and environmental lists which maximize economic efficiency, protect the environment, and ensure that job creation is achieved.

  1. Student manual, Book 2: Orientation to occupational safety compliance in DOE

    SciTech Connect (OSTI)

    Colley, D.L.

    1993-10-01

    This is a student hand-book an Occupational Safety Compliance in DOE. Topics include the following: Electrical; materials handling & storage; inspection responsibilities & procedures; general environmental controls; confined space entry; lockout/tagout; office safety, ergonomics & human factors; medical & first aid, access to records; construction safety; injury/illness reporting system; and accident investigation procedures.

  2. CRAD, Occupational Safety & Health- Oak Ridge National Laboratory High Flux Isotope Reactor Contractor ORR

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February 2007 assessment of the Occupational Safety and Health Program portion of an Operational Readiness Review of the Oak Ridge National Laboratory High Flux Isotope Reactor.

  3. CRAD, Occupational Safety & Health- Los Alamos National Laboratory Waste Characterization, Reduction, and Repackaging Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Occupational and Industrial Safety and Hygiene Program portion of an Operational Readiness Review at the Los Alamos National Laboratory Waste Characterization, Reduction, and Repackaging Facility.

  4. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore » same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  5. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore »same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  6. A technical framework to describe occupant behavior for building energy simulations

    SciTech Connect (OSTI)

    Turner , William; Hong , Tianzhen

    2013-12-20

    Green buildings that fail to meet expected design performance criteria indicate that technology alone does not guarantee high performance. Human influences are quite often simplified and ignored in the design, construction, and operation of buildings. Energy-conscious human behavior has been demonstrated to be a significant positive factor for improving the indoor environment while reducing the energy use of buildings. In our study we developed a new technical framework to describe energy-related human behavior in buildings. The energy-related behavior includes accounting for individuals and groups of occupants and their interactions with building energy services systems, appliances and facilities. The technical framework consists of four key components: i. the drivers behind energy-related occupant behavior, which are biological, societal, environmental, physical, and economical in nature ii. the needs of the occupants are based on satisfying criteria that are either physical (e.g. thermal, visual and acoustic comfort) or non-physical (e.g. entertainment, privacy, and social reward) iii. the actions that building occupants perform when their needs are not fulfilled iv. the systems with which an occupant can interact to satisfy their needs The technical framework aims to provide a standardized description of a complete set of human energy-related behaviors in the form of an XML schema. For each type of behavior (e.g., occupants opening/closing windows, switching on/off lights etc.) we identify a set of common behaviors based on a literature review, survey data, and our own field study and analysis. Stochastic models are adopted or developed for each type of behavior to enable the evaluation of the impact of human behavior on energy use in buildings, during either the design or operation phase. We will also demonstrate the use of the technical framework in assessing the impact of occupancy behavior on energy saving technologies. The technical framework presented is part of our human behavior research, a 5-year program under the U.S. - China Clean Energy Research Center for Building Energy Efficiency.

  7. Occupational exposures and chronic respiratory symptoms. A population-based study

    SciTech Connect (OSTI)

    Korn, R.J.; Dockery, D.W.; Speizer, F.E.; Ware, J.H.; Ferris, B.G. Jr.

    1987-08-01

    Data from a random sample of 8515 white adults residing in 6 cities in the eastern and midwestern United States were used to examine the relationships between occupational exposures to dust or to gases and fumes and chronic respiratory symptoms; 31% of the population had a history of occupational dust exposure and 30% reported exposure to gas or fumes. After adjusting for smoking habits, age, gender, and city of residence, subjects with either occupational exposure had significantly elevated prevalences of chronic cough, chronic phlegm, persistent wheeze, and breathlessness. The adjusted relative odds of chronic respiratory symptoms for subjects exposed to dust ranged from 1.32 to 1.60. Subjects with gas or fume exposure had relative odds of symptoms between 1.27 and 1.43 when compared with unexposed subjects. Occupational dust exposure was associated with a higher prevalence of chronic obstructive pulmonary disease as defined by an FEV1/FVC ratio of less than 0.6, when comparing exposed and unexposed participants (OR = 1.53, 95% Cl = 1.17-2.08). Gas or fume exposure was associated with a small, but not significant, increase in COPD prevalence. Significant trends were noted for wheeze and phlegm with increasing duration of dust exposure. Although 36% of exposed subjects reported exposure to both dust and fumes, there was no evidence of a multiplicative interaction between the effects of the individual exposures. Smoking was a significant independent predictor of symptoms, but did not appear to modify the effect of dust or fumes on symptom reporting. These data, obtained in random samples of general populations, demonstrate that chronic respiratory symptoms and disease can be independently associated with occupational exposures.

  8. Occupational exposures and chronic respiratory symptoms: a population-based study

    SciTech Connect (OSTI)

    Korn, R.J.; Dockery, D.W.; Speizer, F.E.; Ware, J.H.; Ferris, B.G.

    1987-01-01

    Data from a random sample of 8515 white adults residing in six cities in the eastern and midwestern United States were used to examine the relationships between occupational exposures to dust or to gases and fumes and chronic respiratory symptoms. 31% of the population had a history of occupational dust exposure and 30% reported exposure to gas or to fumes. After adjusting for smoking habits, age, gender, and city of residence, subjects with either occupational exposure had significantly elevated prevalence of chronic cough, chronic phlegm, persistent wheeze, and breathlessness. The adjusted relative odds of chronic respiratory symptoms for subjects exposed to dust ranged from 1.32 to 1.60. Subjects with gas or fume exposure had relative odds of symptoms between 1.27 and 1.43 when compared to unexposed subjects. Occupational dust exposure was associated with a higher prevalence of chronic obstructive pulmonary disease (COPD) as defined by an FEV1/FVC ratio of less than 0.6, when comparing exposed and unexposed participants (OR=1.53, 95% CI=1.17-2.08). Gas or fume exposure was associated with a small, but not significant, increase in COPD prevalence. Significant trends were noted for wheeze and phlegm with increasing duration of dust exposure. Although 36% of exposed subjects reported exposure to both dust and fumes, there was no evidence of a multiplicative interaction between the effects of the individual exposures. Smoking was a significant independent predictor of symptoms, but did not appear to modify the effect of dust or fumes on symptom reporting. These data, obtained in random samples of general populations, demonstrate that chronic respiratory disease can be independently associated with occupational exposures.

  9. ARM - Ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox ...

  10. Voluntary Protection Program - Related Links | Department of Energy

    Energy Savers [EERE]

    - Related Links Voluntary Protection Program - Related Links VPPPA - The Voluntary Protection Programs Participants' Association, a non- profit organization is leading the way in safety, health, and environmental excellence through cooperative efforts among labor, management, and government. http://www.vpppa.org. OSHA VPP - The United States Department of Labor, Occupational Safety and Health Administration - Voluntary Protection Program http://www.osha.gov/dcsp/vpp/index.html State VPP Programs

  11. Ge Interface Engineering with Ozone-oxidation for Low Interface State Density

    SciTech Connect (OSTI)

    Kuzum, Duygu; Krishnamohan, T.; Pethe, Abhijit J.; Okyay, Ali, K.; Oshima, Yasuhiro; Sun, Yun; McVittie, Jim P.; Pianetta, Piero A.; McIntyre, Paul C.; Saraswat, Krishna C.; /Stanford U., CIS

    2008-06-02

    Passivation of Ge has been a critical issue for Ge MOS applications in future technology nodes. In this letter, we introduce ozone-oxidation to engineer Ge/insulator interface. Interface states (D{sub it}) values across the bandgap and close to conduction bandedge were extracted using conductance technique at low temperatures. D{sub it} dependency on growth conditions was studied. Minimum D{sub it} of 3 x 10{sup 11} cm{sup -2} V{sup -1} was demonstrated. Physical quality of the interface was investigated through Ge 3d spectra measurements. We found that the interface and D{sub it} is strongly affected by the distribution of oxidation states and quality of the suboxide.

  12. A Bayesian Machine Learning Model for Estimating Building Occupancy from Open Source Data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stewart, Robert N.; Urban, Marie L.; Duchscherer, Samantha E.; Kaufman, Jason; Morton, April M.; Thakur, Gautam; Piburn, Jesse; Moehl, Jessica

    2016-01-01

    Understanding building occupancy is critical to a wide array of applications including natural hazards loss analysis, green building technologies, and population distribution modeling. Due to the expense of directly monitoring buildings, scientists rely in addition on a wide and disparate array of ancillary and open source information including subject matter expertise, survey data, and remote sensing information. These data are fused using data harmonization methods which refer to a loose collection of formal and informal techniques for fusing data together to create viable content for building occupancy estimation. In this paper, we add to the current state of the artmore » by introducing the Population Data Tables (PDT), a Bayesian based informatics system for systematically arranging data and harmonization techniques into a consistent, transparent, knowledge learning framework that retains in the final estimation uncertainty emerging from data, expert judgment, and model parameterization. PDT probabilistically estimates ambient occupancy in units of people/1000ft2 for over 50 building types at the national and sub-national level with the goal of providing global coverage. The challenge of global coverage led to the development of an interdisciplinary geospatial informatics system tool that provides the framework for capturing, storing, and managing open source data, handling subject matter expertise, carrying out Bayesian analytics as well as visualizing and exporting occupancy estimation results. We present the PDT project, situate the work within the larger community, and report on the progress of this multi-year project.Understanding building occupancy is critical to a wide array of applications including natural hazards loss analysis, green building technologies, and population distribution modeling. Due to the expense of directly monitoring buildings, scientists rely in addition on a wide and disparate array of ancillary and open source information including subject matter expertise, survey data, and remote sensing information. These data are fused using data harmonization methods which refer to a loose collection of formal and informal techniques for fusing data together to create viable content for building occupancy estimation. In this paper, we add to the current state of the art by introducing the Population Data Tables (PDT), a Bayesian model and informatics system for systematically arranging data and harmonization techniques into a consistent, transparent, knowledge learning framework that retains in the final estimation uncertainty emerging from data, expert judgment, and model parameterization. PDT probabilistically estimates ambient occupancy in units of people/1000 ft2 for over 50 building types at the national and sub-national level with the goal of providing global coverage. The challenge of global coverage led to the development of an interdisciplinary geospatial informatics system tool that provides the framework for capturing, storing, and managing open source data, handling subject matter expertise, carrying out Bayesian analytics as well as visualizing and exporting occupancy estimation results. We present the PDT project, situate the work within the larger community, and report on the progress of this multi-year project.« less

  13. Zone Level Occupant-Responsive Building Energy Systems at the GSA

    SciTech Connect (OSTI)

    Robinson, Alastair

    2014-03-01

    The General Services Administration (GSA) partnered with the U.S. Department of Energy (DOE) to develop and implement building energy system retrofits, aiming to reduce energy consumption of at least two building systems by a total of 30 percent or more, as part of DOEs Commercial Building Partnership (CBP) Program. Lawrence Berkeley National Laboratory (LBNL) provided technical expertise in support of this DOE program, working with the GSA and a team of consultants. This case study reports expected energy savings from appropriate energy efficient design and operations modifications to lighting and heating, ventilating and air conditioning (HVAC) systems at the selected study sites. These retrofits comprised installation of new lighting systems with dimming capability and occupancy-sensor control at the individual light fixture level, and utilized lighting system occupancy sensor signals to continually readjust zone-level ventilation airflow according to the number of people present, down to minimum rates when vacant.

  14. Waste collection in developing countries - Tackling occupational safety and health hazards at their source

    SciTech Connect (OSTI)

    Bleck, Daniela; Wettberg, Wieland

    2012-11-15

    Waste management procedures in developing countries are associated with occupational safety and health risks. Gastro-intestinal infections, respiratory and skin diseases as well as muscular-skeletal problems and cutting injuries are commonly found among waste workers around the globe. In order to find efficient, sustainable solutions to reduce occupational risks of waste workers, a methodological risk assessment has to be performed and counteractive measures have to be developed according to an internationally acknowledged hierarchy. From a case study in Addis Ababa, Ethiopia suggestions for the transferral of collected household waste into roadside containers are given. With construction of ramps to dump collected household waste straight into roadside containers and an adaptation of pushcarts and collection procedures, the risk is tackled at the source.

  15. A Bayesian Machine Learning Model for Estimating Building Occupancy from Open Source Data

    SciTech Connect (OSTI)

    Stewart, Robert N.; Urban, Marie L.; Duchscherer, Samantha E.; Kaufman, Jason; Morton, April M.; Thakur, Gautam; Piburn, Jesse; Moehl, Jessica

    2016-01-01

    Understanding building occupancy is critical to a wide array of applications including natural hazards loss analysis, green building technologies, and population distribution modeling. Due to the expense of directly monitoring buildings, scientists rely in addition on a wide and disparate array of ancillary and open source information including subject matter expertise, survey data, and remote sensing information. These data are fused using data harmonization methods which refer to a loose collection of formal and informal techniques for fusing data together to create viable content for building occupancy estimation. In this paper, we add to the current state of the art by introducing the Population Data Tables (PDT), a Bayesian based informatics system for systematically arranging data and harmonization techniques into a consistent, transparent, knowledge learning framework that retains in the final estimation uncertainty emerging from data, expert judgment, and model parameterization. PDT probabilistically estimates ambient occupancy in units of people/1000ft2 for over 50 building types at the national and sub-national level with the goal of providing global coverage. The challenge of global coverage led to the development of an interdisciplinary geospatial informatics system tool that provides the framework for capturing, storing, and managing open source data, handling subject matter expertise, carrying out Bayesian analytics as well as visualizing and exporting occupancy estimation results. We present the PDT project, situate the work within the larger community, and report on the progress of this multi-year project.Understanding building occupancy is critical to a wide array of applications including natural hazards loss analysis, green building technologies, and population distribution modeling. Due to the expense of directly monitoring buildings, scientists rely in addition on a wide and disparate array of ancillary and open source information including subject matter expertise, survey data, and remote sensing information. These data are fused using data harmonization methods which refer to a loose collection of formal and informal techniques for fusing data together to create viable content for building occupancy estimation. In this paper, we add to the current state of the art by introducing the Population Data Tables (PDT), a Bayesian model and informatics system for systematically arranging data and harmonization techniques into a consistent, transparent, knowledge learning framework that retains in the final estimation uncertainty emerging from data, expert judgment, and model parameterization. PDT probabilistically estimates ambient occupancy in units of people/1000 ft2 for over 50 building types at the national and sub-national level with the goal of providing global coverage. The challenge of global coverage led to the development of an interdisciplinary geospatial informatics system tool that provides the framework for capturing, storing, and managing open source data, handling subject matter expertise, carrying out Bayesian analytics as well as visualizing and exporting occupancy estimation results. We present the PDT project, situate the work within the larger community, and report on the progress of this multi-year project.

  16. 10 C.F.R. PART 835-OCCUPATIONAL RADIATION PROTECTION, Subpart A - General Provisions

    Energy Savers [EERE]

    835-OCCUPATIONAL RADIATION PROTECTION Authority: 42 U.S.C. 2201; 7191. Source: 58 FR 65485, Dec. 14, 1993, unless otherwise noted. Subpart A-General Provisions § 835.1 Scope. (a) General. The rules in this part establish radiation protection standards, limits, and program requirements for protecting individuals from ionizing radiation resulting from the conduct of DOE activities. (b) Exclusion. The requirements in this part do not apply to: 1. Activities that are regulated through a license by

  17. Differences in serum concentrations of organochlorine compounds by occupational social class in pancreatic cancer

    SciTech Connect (OSTI)

    Porta, Miquel Bosch de Basea, Magda; Benavides, Fernando G.; Lopez, Tomas; Fernandez, Esteve; Marco, Esther; Alguacil, Juan; Grimalt, Joan O.; Puigdomenech, Elisa

    2008-11-15

    Background: The relationships between social factors and body concentrations of environmental chemical agents are unknown in many human populations. Some chemical compounds may play an etiopathogenic role in pancreatic cancer. Objective: To analyze the relationships between occupational social class and serum concentrations of seven selected organochlorine compounds (OCs) in exocrine pancreatic cancer: dichlorodiphenyltrichloroethane (p,p'-DDT), dichlorodiphenyldichloroethene (p,p'-DDE), 3 polychlorinated biphenyls (PCBs), hexachlorobenzene, and {beta}-hexachlorocyclohexane. Methods: Incident cases of exocrine pancreatic cancer were prospectively identified, and interviewed face-to-face during hospital admission (n=135). Serum concentrations of OCs were analyzed by high-resolution gas chromatography with electron-capture detection. Social class was classified according to occupation. Results: Multivariate-adjusted concentrations of all seven compounds were higher in occupational social classes IV-V (the less affluent) than in classes I-II; they were higher as well in class III than in classes I-II for four compounds. Concentrations of six OCs were higher in manual workers than in non-manual workers (p<0.05 for PCBs). Social class explained statistically between 3.7% and 5.7% of the variability in concentrations of PCBs, and 2% or less variability in the other OCs. Conclusions: Concentrations of most OCs were higher in the less affluent occupational social classes. In pancreatic cancer the putative causal role of these persistent organic pollutants may not be independent of social class. There is a need to integrate evidence on the contribution of different social processes and environmental chemical exposures to the etiology of pancreatic and other cancers.

  18. Guide of Good Practices for Occupational Radiological Protection in Plutonium Facilities

    Energy Savers [EERE]

    28-2008 December 2008 DOE STANDARD GUIDE OF GOOD PRACTICES FOR OCCUPATIONAL RADIOLOGICAL PROTECTION IN PLUTONIUM FACILITIES U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Not Measurement Sensitive DOE-STD-1128-2008 ii This document is available on the Department of Energy Technical Standards Program Web Site at http://www.hss.energy.gov/nuclearsafety/techstds/ DOE-STD-1128-2008 iii Foreword This

  19. Current practices for maintaining occupational exposures ALARA at low-level waste disposal sites

    SciTech Connect (OSTI)

    Hadlock, D.E.; Herrington, W.N.; Hooker, C.D.; Murphy, D.W.; Gilchrist, R.L.

    1983-12-01

    The United States Nuclear Regulatory Commission contracted with Pacific Northwest Laboratory (PNL) to provide technical assistance in establishing operational guidelines, with respect to radiation control programs and methods of minimizing occupational radiation exposure, at Low-Level Waste (LLW) disposal sites. The PNL, through site visits, evaluated operations at LLW disposal sites to determine the adequacy of current practices in maintaining occupational exposures as low as is reasonably achievable (ALARA). The data sought included the specifics of: ALARA programs, training programs, external exposure control, internal exposure control, respiratory protection, surveillance, radioactive waste management, facilities and equipment, and external dose analysis. The results of the study indicated the following: The Radiation Protection and ALARA programs at the three commercial LLW disposal sites were observed to be adequate in scope and content compared to similar programs at other types of nuclear facilities. However, it should be noted that there were many areas that could be improved upon to help ensure the health and safety of occupationally exposed individuals.

  20. Occupational Health Services Part I DE-AC06-04RL14383, Modification No. 139 Section B

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DE-AC06-04RL14383, Modification No. 139 Section B Page B-2 B.1 Occupational Medical Services a. This is a performance-based, cost reimbursement service contract for the rendering of Occupational Medical Services for the U. S. Department of Energy's Hanford Site. The Contractor shall furnish all personnel, facilities, equipment, material, supplies, and services (except as expressly set forth in this contract as furnished by the Government) and otherwise do all things necessary for, or incident

  1. Progress on Enabling an Interactive Conversation Between Commercial Building Occupants and Their Building To Improve Comfort and Energy Efficiency: Preprint

    SciTech Connect (OSTI)

    Schott, M.; Scheib, J.; Long, N.; Fleming, K.; Benne, K.; Brackney, L.

    2012-06-01

    Many studies have reported energy savings after installing a dashboard, but dashboards provide neither individual feedback to the occupant nor the ability to report individual comfort. The Building Agent (BA) provides an interface to engage the occupant in a conversation with the building control system and the building engineer. Preliminary outcomes of the BA-enabled feedback loop are presented, and the effectiveness of the three display modes will be compared to other dashboard studies to baseline energy savings in future research.

  2. Removal of pollutant compounds from water supplies using ozone, ultraviolet light, and a counter, current packed column. Master's thesis

    SciTech Connect (OSTI)

    Kelly, E.L.

    1991-01-01

    Many water pollutants are determined to be carcinogenic and often appear in very low concentrations and still pose a health risk. Conventional water treatment processes cannot remove these contaminants and there is a great demand for the development of alternative removal technologies. The use of ozone and ultraviolet light in a counter current packed column could prove to be an effective treatment process to remove these contaminants.

  3. Occupation Codes

    Energy Savers [EERE]

    ... from effects of high, low, or changes in air pressure. ... 0311 METHYL ALCOHOL (OR METHANOL) Carbinol Wood spirits ... Includes: Fixtures, load indicators, hooks, shackles, ...

  4. Comparison of the responses of children and adults to acute ozone exposure

    SciTech Connect (OSTI)

    McDonnell, W.F.; Chapman, R.S.; Horstman, D.H.; Leigh, M.W.; Salaam, S.A.

    1986-07-01

    The purpose of the paper is to compare the results of two studies in which the respiratory responses of children and adults to acute ozone (O/sub 3/) exposure were measured. Forty-two 18-30 year old males were exposed for 2.5 hours in a controlled environmental chamber to either 0.0 or 0.12 ppm O3 while performing intermittent heavy exercise. Twenty-two 8-11 year old males were exposed in a similar manner to both air and 0.12 ppm O3. Measures of respiratory symptoms and function were made before and after exposure. Adults experienced an increase in the symptom cough and decrements in forced vital capacity and some measures of forced expiratory flow. Children experienced similar decrements in pulmonary function, but had no increase in symptoms. The authors concluded that as measured by pulmonary function children appear to be no more responsive to O3 exposure than are adults and may experience fewer symptoms.

  5. Respiratory responses of vigorously exercising children to 0. 12 ppm ozone exposure

    SciTech Connect (OSTI)

    McDonnell, W.F. 3d.; Chapman, R.S.; Leigh, M.W.; Strope, G.L.; Collier, A.M.

    1985-10-01

    Changes in respiratory function have been suggested for children exposed to less than 0.12 ppm ozone (O3) while engaged in normal activities. Because the results of these studies have been confounded by other variables, such as temperature or the presence of other pollutants or have been questioned as to the adequacy of exposure measurements, the authors determined the acute response of children exposed to 0.12 ppm O3 in a controlled chamber environment. Twenty-three white males 8 to 11 yr of age were exposed once to clean air and once to 0.12 ppm O3 in random order. Exposures were for 2.5 h and included 2 h of intermittent heavy exercise. Measures of forced expiratory volume in one second (FEV1) and the symptom cough were determined prior to and after each exposure. A significant decline in FEV1 was found after the O3 exposure compared to the air exposure, and it appeared to persist for 16 to 20 h. No significant increase in cough was found due to O3 exposure. Forced vital capacity, specific airways resistance, respiratory frequency, tidal volume, and other symptoms were measured in a secondary exploratory analysis of this study.

  6. OZONE PRODUCTION IN THE PHILADELPHIA URBAN AREA DURING NE-OPS 99.

    SciTech Connect (OSTI)

    KLEINMAN,L.I.; DAUM,P.H.; BRECHTEL,F.; LEE,Y.N.; NUNNERMACKER,L.J.; SPRINGSTON,S.R.; WEINSTEIN-LLOYD,J.

    2001-10-01

    As part of the 1999 NARSTO Northeast Oxidant and Particulate Study (NE-OPS) field campaign, the DOE G-1 aircraft sampled trace gases and aerosols in and around the Philadelphia metropolitan area. Twenty research flights were conducted between July 25 and August 11. The overall goals of these flights were to obtain a mechanistic understanding of O{sub 3} production; to characterize the spatial and temporal behavior of photo-oxidants and aerosols; and to study the evolution of aerosol size distributions, including the process of new particle formation. Within the NE-OPS program, other groups provided additional trace gas, aerosol, and meteorological observations using aircraft, balloon, remote sensing, and surface based instruments (Phillbrick et al., 2000). In this article we provide an overview of the G-1 observations related to O{sub 3} production, focusing on the vertical distribution of pollutants. Ozone production rates are calculated using a box model that is constrained by observed trace gas concentrations. Highest O{sub 3} concentrations were observed on July 31, which we present as a case study. On that day, O{sub 3} concentrations above the 1-hour 120 ppb standard were observed downwind of Philadelphia and also in the plume of a single industrial facility located on the Delaware River south of the city.

  7. Mechanical-biological waste treatment and the associated occupational hygiene in Finland

    SciTech Connect (OSTI)

    Tolvanen, Outi K. . E-mail: outolvan@bytl.jyu.fi; Haenninen, Kari I.

    2006-07-01

    A special feature of waste management in Finland has been the emphasis on the source separation of kitchen biowaste (catering waste); more than two-thirds of the Finnish population participates in this separation. Source-separated biowaste is usually treated by composting. The biowaste of about 5% of the population is handled by mechanical-biological treatment. A waste treatment plant at Mustasaari is the only plant in Finland using digestion for kitchen biowaste. For the protection of their employees, the plant owners commissioned a study on environmental factors and occupational hygiene in the plant area. During 1998-2000 the concentrations of dust, microbes and endotoxins and noise levels were investigated to identify possible problems at the plant. Three different work areas were investigated: the pre-processing and crushing hall, the bioreactor hall and the drying hall. Employees were asked about work-related health problems. Some problems with occupational hygiene were identified: concentrations of microbes and endotoxins may increase to levels harmful to health during waste crushing and in the bioreactor hall. Because employees complained of symptoms such as dry cough and rash or itching appearing once or twice a month, it is advisable to use respirator masks (class P3) during dusty working phases. The noise level in the drying hall exceeded the Finnish threshold value of 85 dBA. Qualitatively harmful factors for the health of employees are similar in all closed waste treatment plants in Finland. Quantitatively, however, the situation at the Mustasaari treatment plant is better than at some Finnish dry waste treatment plants. Therefore is reasonable to conclude that mechanical sorting, which produces a dry waste fraction for combustion and a biowaste fraction for anaerobic treatment, is in terms of occupational hygiene better for employees than combined aerobic treatment and dry waste treatment.

  8. The Role of Occupant Behavior in Achieving Net Zero Energy: A Demonstration Project at Fort Carson

    SciTech Connect (OSTI)

    Judd, Kathleen S.; Sanquist, Thomas F.; Zalesny, Mary D.; Fernandez, Nicholas

    2013-09-30

    This study, sponsored by the U.S. General Services Administrations Office of Federal High-Performance Green Buildings, aimed to understand the potential for institutional and behavioral change to enhance the performance of buildings, through a demonstration project with the Department of Defense in five green buildings on the Fort Carson, Colorado, Army base. To approach this study, the research team identified specific occupant behaviors that had the potential to save energy in each building, defined strategies that might effectively support behavior change, and implemented a coordinated set of actions during a three-month intervention.

  9. Distribution of occupation numbers in finite Fermi systems and role of interaction in chaos and thermalization

    SciTech Connect (OSTI)

    Flambaum, V.V.; Izrailev, F.M. [School of Physics, University of New South Wales, Sydney 2052 (Australia)] [School of Physics, University of New South Wales, Sydney 2052 (Australia)

    1997-01-01

    A method is developed for calculation of single-particle occupation numbers in finite Fermi systems of interacting particles. It is more accurate than the canonical distribution method and gives the Fermi-Dirac distribution in the limit of large number of particles. It is shown that statistical effects of the interaction are absorbed by an increase of the effective temperature. Criteria for quantum chaos and statistical equilibrium are considered. All results are confirmed by numerical experiments in the two-body random interaction model. {copyright} {ital 1997} {ital The American Physical Society}

  10. Modeling analyses of the effects of changes in nitrogen oxides emissions from the electric power sector on ozone levels in the eastern United States

    SciTech Connect (OSTI)

    Edith Gego; Alice Gilliland; James Godowitch

    2008-04-15

    In this paper, we examine the changes in ambient ozone concentrations simulated by the Community Multiscale Air Quality (CMAQ) model for summer 2002 under three different nitrogen oxides (NOx) emission scenarios. Two emission scenarios represent best estimates of 2002 and 2004 emissions; they allow assessment of the impact of the NOx emissions reductions imposed on the utility sector by the NOx State Implementation Plan (SIP) Call. The third scenario represents a hypothetical rendering of what NOx emissions would have been in 2002 if no emission controls had been imposed on the utility sector. Examination of the modeled median and 95th percentile daily maximum 8-hr average ozone concentrations reveals that median ozone levels estimated for the 2004 emission scenario were less than those modeled for 2002 in the region most affected by the NOx SIP Call. Comparison of the 'no-control' with the '2002' scenario revealed that ozone concentrations would have been much higher in much of the eastern United States if the utility sector had not implemented NOx emission controls; exceptions occurred in the immediate vicinity of major point sources where increased NO titration tends to lower ozone levels. 13 refs., 8 figs., 2 tabs.

  11. Modeling regional/urban ozone and particulate matter in Beijing, China.

    SciTech Connect (OSTI)

    Fu, J.S.; Streets, D.G.; Jang, C.J.; Hao, J.; He, K.; Wang, L.; Zhang, Q.

    2009-01-15

    This paper examines Beijing air quality in the winter and summer of 2001 using an integrated air quality modeling system (Fifth Generation Mesoscale Meteorological Model (MM5)/Community Multiscale Air Quality (CMAQ)) in nested mode. The National Aeronautics and Space Administration (NASA) Transport and Chemical Evolution over the Pacific (TRACE-P) emission inventory is used in the 36- (East Asia), 12- (East China), and 4-km (greater Beijing area) domains. Furthermore, we develop a local Beijing emission inventory that is used in the 4-km domain. We also construct a corroborated mapping of chemical species between the TRACE-P inventory and the Carbon Bond IV (CB-IV) chemical mechanism before the integrated modeling system is applied to study ozone (O{sub 3}) and particulate matter (PM) in Beijing. Meteorological data for the integrated modeling runs are extracted from MM5. Model results show O{sub 3} hourly concentrations in the range of 80-159 parts per billion (ppb) during summer in the urban areas and up to 189 ppb downwind of the city. High fine PM (PM2.5) concentrations (monthly average of 75 {mu}g.m{sup -3} in summer and 150 {mu}g.m{sup -3} in winter) are simulated over the metropolitan and down-wind areas with significant secondary constituents. Major sources of particulates were biomass burning, coal combustion and industry. A comparison against available O{sub 3} and PM measurement data in Beijing is described. We recommend refinements to the developed local Beijing emission inventory to improve the simulation of Beijing's air quality. The 4-km modeling configuration is also recommended for the development of air pollution control strategies. 31 refs., 5 figs., 3 tabs.

  12. The combined effects of elevated carbon dioxide and ozone on crop systems

    SciTech Connect (OSTI)

    Miller, J.E.; Heagle, A.S.; Shafer, S.R.; Heck, W.W.

    1994-12-31

    Concentrations of carbon dioxide (CO{sub 2}) and ozone (O{sub 3}) in the troposphere have risen in the last century due to industrialization. Current levels of tropospheric O{sub 3} suppress growth of crops and other plants, and O{sub 3} concentrations may continue to rise with changes in global climate. On the other hand, projected increases in atmospheric concentrations of CO{sub 2} in the next 50 to 100 years are expected to cause significant increases in growth of most species. Since elevated concentrations of these gases will co-occur, it is important to understand their joint action. Until recently, however, the combined effects of O{sub 3} and CO{sub 2} have received little attention. Most publications on combined CO{sub 2} and O{sub 3} effects have described experiments conducted in greenhouse or controlled-environment facilities. To date, data on responses of agricultural species to the combined gases have come from experiments with radish, tomato, white clover, tobacco, or wheat. In most cases, CO{sub 2} stimulated and O{sub 3} suppressed growth of the plant tissues studied, and CO{sub 2} usually attenuated development of O{sub 3}-induced visible injury. Some data have indicated a tendency for CO{sub 2}, in concentrations up to double the current ambient level, to attenuate effects of O{sub 3} on growth, but statistical analyses of such data often have not supported such a conclusion. In this paper, the results of a recent field experiment with soybean are reported, and the results are compared to other similar research with elevated atmospheric concentrations of both O{sub 3} and CO{sub 2}.

  13. The pulmonary response of white and black adults to six concentrations of ozone

    SciTech Connect (OSTI)

    Seal, E. Jr.; McDonnell, W.F.; House, D.E.; Salaam, S.A.; Dewitt, P.J.; Butler, S.O.; Green, J.; Raggio, L. )

    1993-04-01

    Many early studies of respiratory responsiveness to ozone (O3) were done on healthy, young, white males. The purpose of this study was to determine whether gender or race differences in O3 response exist among white and black, males and females, and to develop concentration-response curves for each of the gender-race groups. Three hundred seventy-two subjects (n > 90 in each gender-race group), ages 18 to 35 yr, were exposed once for 2.33 h to 0.0 (purified air), 0.12, 0.18, 0.24, 0.30, or 0.40 ppm O3. Each exposure was preceded by baseline pulmonary function tests and a symptom questionnaire. The first 2 h of exposure included alternating 15-min periods of rest and exercise on a motorized treadmill producing a minute ventilation (VE) of 25 L/min/m2 body surface area (BSA). After exposure, subjects completed a set of pulmonary function tests and a symptom questionnaire. Lung function and symptom responses were expressed as percent change from baseline and analyzed using a nonparametric two factor analysis of variance. Three primary variables were analyzed: FEV1, specific airway resistance (SRaw), and cough. Statistical analysis demonstrated no significant differences in response to O3 among the individual gender-race groups. For the group as a whole, changes in the variables FEV1, SRaw, and cough were first noted at 0.12, 0.18, and 0.18 ppm O3, respectively. Adjusted for exercise difference, concentration-response curves for FEV1 and cough among white males were consistent with previous reports (1).

  14. Air pollution and childhood respiratory health: Exposure to sulfate and ozone in 10 Canadian Rural Communities

    SciTech Connect (OSTI)

    Stern, B.R.; Raizenne, M.E.; Burnett, R.T.; Jones, L.; Kearney, J.; Franklin, C.A. )

    1994-08-01

    This study was designed to examine differences in the respiratory health status of preadolescent school children, aged 7-11 years, who resided in 10 rural Canadian communities in areas of moderate and low exposure to regional sulfate and ozone pollution. Five of the communities were located in central Saskatchewan, a low-exposure region, and five were located in southwestern Ontario, an area with moderately elevated exposures resulting from long-range atmospheric transport of polluted air masses. In this cross-sectional study, the child's respiratory symptoms and illness history were evaluated using a parent-completed questionnaire, administered in September 1985. Respiratory function was assessed once for each child in the schools between October 1985 and March 1986, by the measurement of pulmonary function for forced vital capacity (FVC), forced expiratory volume in 1 sec (FEV[sub 1.0]), peak expiratory flow rate (PEFR), mean forced expiratory flow rate during the middle half of the FVC curve (FEF[sub 25-75]), and maximal expiratory flow at 50% of the expired vital capacity (V[sub 50]max). After controlling for the effects of age, sex, parental smoking, parental education and gas cooking, no significant regional differences were observed in rates of chronic cough or phlegm, persistent wheeze, current asthma, bronchitis in the past year, or any chest illness that kept the child at home for 3 or more consecutive days during the previous year. Children living in southwestern Ontario had statistically significant (P < 0.01) mean decrements of 1.7% in FVC and 1.3% in FEV[sub 1.0] compared with Saskatchewan children, after adjusting for age, sex, weight, standing height, parental smoking, and gas cooking. There were no statistically significant regional differences in the pulmonary flow parameters (P > 0.05). 54 refs., 1 fig., 7 tabs.

  15. Air-Quality Data from NARSTO (North American Research Strategy for Tropospheric Ozone)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    NARSTO is a public/private partnership dedicated to improving management of air quality in North America. It was established on February 13, 1995 when representatives of Canada, the United States, and Mexico signed the NARSTO Charter in a ceremony at the White House. The Department of Energy is one of the charter members providing funding. The central programmatic goal of NARSTO is to provide data and information for use in the determination of workable, efficient, and effective strategies for local and regional ozone and fine particle management. Since its founding, NARSTO has completed three major scientific Assessments of critical air quality management issues. NARSTO maintains the Quality Systems Science Center and the NARSTO Data Archive for storing data from NARSTO Affiliated Research Activities and making these data available to the scientific community. NARSTO also facilitates activities, such as the Reactivity Research Working Group, which provide critical reviews of the state of the science in areas of interest to air quality policy makers. In January 1997, the U.S. Department of Energy's Environmental Sciences Division announced their sponsorship of the NARSTO Quality Systems Science Center (QSSC). The QSSC is located at the Oak Ridge National Laboratory within the Carbon Dioxide Information Analysis Center (CDIAC). Quality Assurance and Data Management assistance and guidelines are provided by the QSCC, along with access to data files. The permanent data archive is maintained by the NASA EOSDIS Distributed Active Archive Center at the Langley Research Center. The archived data can be reached by a link from the QSSC.(Specialized Interface) See also the NARSTO web site at http://www.narsto.org/

  16. Iron(II) catalysis in oxidation of hydrocarbons with ozone in acetonitrile

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bataineh, Hajem; Pestovsky, Oleg; Bakac, Andreja

    2015-02-11

    Oxidation of alcohols, ethers, and sulfoxides by ozone in acetonitrile is catalyzed by submillimolar concentrations of Fe(CH3CN)62+. The catalyst provides both rate acceleration and greater selectivity toward the less oxidized products. For example, Fe(CH3CN)62+-catalyzed oxidation of benzyl alcohol yields benzaldehyde almost exclusively (>95%), whereas the uncatalyzed reaction generates a 1:1 mixture of benzaldehyde and benzoic acid. Similarly, aliphatic alcohols are oxidized to aldehydes/ketones, cyclobutanol to cyclobutanone, and diethyl ether to a 1:1 mixture of ethanol and acetaldehyde. The kinetics of oxidation of alcohols and diethyl ether are first-order in [Fe(CH3CN)62+] and [O3] and independent of [substrate] at concentrations greater thanmore » ~5 mM. In this regime, the rate constant for all of the alcohols is approximately the same, kcat = (8 ± 1) × 104 M–1 s–1, and that for (C2H5)2O is (5 ± 0.5) × 104 M–1 s–1. In the absence of substrate, Fe(CH3CN)62+ reacts with O3 with kFe = (9.3 ± 0.3) × 104 M–1 s–1. The similarity between the rate constants kFe and kcat strongly argues for Fe(CH3CN)62+/O3 reaction as rate-determining in catalytic oxidation. The active oxidant produced in Fe(CH3CN)62+/O3 reaction is suggested to be an Fe(IV) species in analogy with a related intermediate in aqueous solutions. As a result, this assignment is supported by the similarity in kinetic isotope effects and relative reactivities of the two species toward substrates.« less

  17. Review of Literature on Terminal Box Control, Occupancy Sensing Technology and Multi-zone Demand Control Ventilation (DCV)

    SciTech Connect (OSTI)

    Liu, Guopeng; Dasu, Aravind R.; Zhang, Jian

    2012-03-01

    This report presents an overall review of the standard requirement, the terminal box control, occupancy sensing technology and DCV. There is system-specific guidance for single-zone systems, but DCV application guidance for multi-zone variable air volume (VAV) systems is not available. No real-world implementation case studies have been found using the CO2-based DCV. The review results also show that the constant minimum air flow set point causes excessive fan power consumption and potential simultaneous heating and cooling. Occupancy-based control (OBC) is needed for the terminal box in order to achieve deep energy savings. Key to OBC is a technology for sensing the actual occupancy of the zone served in real time. Several technologies show promise, but none currently fully meets the need with adequate accuracy and sufficiently low cost.

  18. Effect of canopy structure and open-top chamber techniques on micrometeorological parameters and the gradients and transport of water vapor, carbon dioxide and ozone in the canopies of plum trees (`prunus salicina`) in the San Joaquin valley. Final report

    SciTech Connect (OSTI)

    Grantz, D.A.; Vaughn, D.L.; Metheny, P.A.; Malkus, P.; Wosnik, K.

    1995-03-15

    Plum trees (Prunus salicina cv. Casselman) were exposed to ozone in open-top chambers (OTC) or chamberless plots, and trace gas concentrations and microenvironmental conditions were monitored within tree canopies inside the outside the OTC. Concentrations of ozone, carbon dioxide and water vapor, leaf and air temperature, light intensity, and wind speed were measured at nine positions in the tree canopies. The objectives were to: (1) map the distribution of microenvironmental parameters within the canopies inside and outside the OTC; (2) determine transport parameters for gas exchange, and (3) calculate ozone flux. Significant vertical and horizontal gradients were observed; gradients were diminished and often inverted inside relative to outside the OTC due to air distribution at the bottom of the OCT. Ozone flux was readily modeled from measures of stomatal conductance, nonstomatal conductance and ozone concentration at the leaf surface.

  19. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    SciTech Connect (OSTI)

    Kim, Saewung; Kim, So-Young; Lee, Meehye; Shim, Heeyoun; Wolfe, Glenn; Guenther, Alex B.; He, Amy; Hong, Youdeog; Han, Jinseok

    2014-01-01

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Gangzhou, and Beijing are surrounded by densely forested areas and recent research has consistently demonstrated the importance of biogenic volatile organic compounds from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical concentrations, undermine our ability to assess regional photochemical air pollution problems. We present an observational dataset of CO, NOX, SO2, ozone, HONO, and VOCs (anthropogenic and biogenic) from Taehwa Research Forest (TRF) near the Seoul Metropolitan Area (SMA) in early June 2012. The data show that TRF is influenced both by aged pollution and fresh BVOC emissions. With the dataset, we diagnose HOx (OH, HO2, and RO2) distributions calculated with the University of Washington Chemical Box Model (UWCM v 2.1). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that 1) different model simulation scenarios cause systematic differences in HOX distributions especially OH levels (up to 2.5 times) and 2) radical destruction (HO2+HO2 or HO2+RO2) could be more efficient than radical recycling (HO2+NO) especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozone-VOC-NOX sensitivity and oxidation product formation rates. Overall, the VOC limited regime in ozone photochemistry is predicted but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with OVOCs production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher than expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.

  20. Enforcement Regulations and Directives - Worker Safety and Health |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Worker Safety and Health Enforcement Regulations and Directives - Worker Safety and Health Regulations 10 C.F.R. Part 851 - Worker Safety and Health Program; Final Rule 10 C.F.R. Part 850 - Chronic Beryllium Disease Prevention Program; Final Rule 29 C.F.R. Part 1910 - Occupational Safety and Health Standards (OSHA) 29 C.F.R. Part 1926 - Safety and Health Regulations for Construction (OSHA) 29 C.F.R. Part 1904 - Reporting and Reporting Occupational Injuries and Illnesses

  1. Department of Energy Construction Safety Reference Guide

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    DOE has adopted the Occupational Safety and Health Administration (OSHA) regulations Title 29 Code of Federal Regulations (CFR) 1926 ``Safety and Health Regulations for Construction,`` and related parts of 29 CFR 1910, ``Occupational Safety and Health Standards.`` This nonmandatory reference guide is based on these OSHA regulations and, where appropriate, incorporates additional standards, codes, directives, and work practices that are recognized and accepted by DOE and the construction industry. It covers excavation, scaffolding, electricity, fire, signs/barricades, cranes/hoists/conveyors, hand and power tools, concrete/masonry, stairways/ladders, welding/cutting, motor vehicles/mechanical equipment, demolition, materials, blasting, steel erection, etc.

  2. Radiation-Generating Devices Guide for Use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-04-15

    For use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection. This Guide provides an acceptable methodology for establishing and operating a sealed radioactive source accountability and control program that will comply with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection (DOE 1998a), hereinafter referred to as 10 CFR 835. In particular, this Guide provides guidance for achieving compliance with subpart M of 10 CFR 835. Canceled by DOE G 441.1-1B.

  3. Effect of the ozonization of brown coal from the Kansk-Achinsk Basin on its pyrolysis in a mixture with polyethylene

    SciTech Connect (OSTI)

    V.I. Sharypov; N.G. Beregovtsova; S.V. Baryshnikov; B.N. Kuznetsov

    2008-06-15

    It was found that the treatment of brown coal from the Kansk-Achinsk Basin with an ozone-oxygen mixture at 25-100{sup o}C for 1-8 h was accompanied by the formation of oxygen-containing structural groups in the organic matter of coal, the thermal stability of these groups was comparatively low. The preliminary ozonization of coal resulted in an increase in the degree of conversion and the yield of liquid distillation products in the course of coprocessing of coal with polyethylene.

  4. Summer outdoor temperature and occupational heat-related illnesses in Quebec (Canada)

    SciTech Connect (OSTI)

    Adam-Poupart, Ariane; Smargiassi, Audrey; Busque, Marc-Antoine; Duguay, Patrice; Fournier, Michel; Zayed, Joseph; Labrèche, France

    2014-10-15

    Background: Predicted rise in global mean temperature and intensification of heat waves associated with climate change present an increasing challenge for occupational health and safety. Although important scientific knowledge has been gathered on the health effects of heat, very few studies have focused on quantifying the association between outdoor heat and mortality or morbidity among workers. Objective: To quantify the association between occupational heat-related illnesses and exposure to summer outdoor temperatures. Methods: We modeled 259 heat-related illnesses compensated by the Workers' Compensation Board of Quebec between May and September, from 1998 to 2010, with maximum daily summer outdoor temperatures in 16 health regions of Quebec (Canada) using generalized linear models with negative binomial distributions, and estimated the pooled effect sizes for all regions combined, by sex and age groups, and for different time lags with random-effect models for meta-analyses. Results: The mean daily compensation count was 0.13 for all regions of Quebec combined. The relationship between daily counts of compensations and maximum daily temperatures was log-linear; the pooled incidence rate ratio (IRR) of daily heat-related compensations per 1 °C increase in daily maximum temperatures was 1.419 (95% CI 1.326 to 1.520). Associations were similar for men and women and by age groups. Increases in daily maximum temperatures at lags 1 and 2 and for two and three-day lag averages were also associated with increases in daily counts of compensations (IRRs of 1.206 to 1.471 for every 1 °C increase in temperature). Conclusion: This study is the first to quantify the association between occupational heat-related illnesses and exposure to summer temperatures in Canada. The model (risk function) developed in this study could be useful to improve the assessment of future impacts of predicted summer outdoor temperatures on workers and vulnerable groups, particularly in colder temperate zones. - Highlights: • 259 heat-related compensated illnesses were modeled with ambient temperature • An overall risk ratio of 1.419 (95% CI 1.326–1.520) for every 1 °C increase was found • Risk estimates were similar for men and women and by large age groups. • There were little lag effects (IRRs of 1.206 to 1.471 for every 1 °C increase)

  5. Signatures of a conical intersection in photofragment distributions and absorption spectra: Photodissociation in the Hartley band of ozone

    SciTech Connect (OSTI)

    Picconi, David; Grebenshchikov, Sergy Yu.

    2014-08-21

    Photodissociation of ozone in the near UV is studied quantum mechanically in two excited electronic states coupled at a conical intersection located outside the Franck-Condon zone. The calculations, performed using recent ab initio PESs, provide an accurate description of the photodissociation dynamics across the Hartley/Huggins absorption bands. The observed photofragment distributions are reproduced in the two electronic dissociation channels. The room temperature absorption spectrum, constructed as a Boltzmann average of many absorption spectra of rotationally excited parent ozone, agrees with experiment in terms of widths and intensities of diffuse structures. The exit channel conical intersection contributes to the coherent broadening of the absorption spectrum and directly affects the product vibrational and translational distributions. The photon energy dependences of these distributions are strikingly different for fragments created along the adiabatic and the diabatic paths through the intersection. They can be used to reverse engineer the most probable geometry of the non-adiabatic transition. The angular distributions, quantified in terms of the anisotropy parameter β, are substantially different in the two channels due to a strong anticorrelation between β and the rotational angular momentum of the fragment O{sub 2}.

  6. Occupational Radiation Exposure at Commercial Nuclear Power Reactors and Other Facilities 2008

    SciTech Connect (OSTI)

    U.S. Nuclear Regulatory Commission, Office of Nuclear Regulatory Research

    2009-12-01

    This report summarizes the occupational exposure data that are maintained in the U.S. Nuclear Regulatory Commission (NRC) Radiation Exposure Information and Reporting System (REIRS). The bulk of the information contained in the report was compiled from the 2008 annual reports submitted by five of the seven categories1 of NRC licensees subject to the reporting requirements of 10 CFR 20.2206. The annual reports submitted by these licensees consist of radiation exposure records for each monitored individual. These records are analyzed for trends and presented in this report in terms of collective dose and the distribution of dose among the monitored individuals. Because there are no geologic repositories for high-level waste currently licensed and no low-level waste disposal facilities in operation, only five categories will be considered in this report.

  7. Improving the Success Rate of Delivering Annual Occupational Dosimetry Reports to Persons Issued Temporary External Dosimeters

    SciTech Connect (OSTI)

    Mallett, Michael Wesley

    2014-09-09

    Workers who are not routinely monitored for occupational radiation exposure at LANL may be issued temporary dosimeters in the field. Per 10CFR835 and DOE O 231.1A, the Laboratory's radiation protection program is responsible for reporting these results to the worker at the end of the year. To do so, the identity of the worker and their mailing address must be recorded by the delegated person at the time the dosimeter is issued. Historically, this data has not been consistently captured. A new online application was developed to record the issue of temporary dosimeters. The process flow of the application was structured such that: 1) the worker must be uniquely identified in the Lab's HR database, and 2) the mailing address of record is verified live time via a commercial web service, for the transaction to be completed. A COPQ savings (Type B1) of $96K/year is demonstrated for the new application.

  8. Occupational and traning requirements for expanded coal production (as of October 1980). [Forecasting to 1995

    SciTech Connect (OSTI)

    Not Available

    1982-04-01

    This study was initiated because of the anticipated rapid growth in trained personnel requirements in bituminous coal mining, and because the industry had already experienced significant problems in recruiting skilled manpower in the course of its employment expansion during the 1970's. Employment in bituminous coal mining is projected to nearly double, from 234,000 in 1977 to 456,000 in 1995, as the net result of a projected threefold increase in coal output to nearly 2.0 billion in 1995 and of an expected significant improvement in overall productivity. A large proportion of current coal mining employees are in occupations which require significant amounts of training for effective work performance. Employment growth to 1955 will be most rapid in those occupations requiring the greatest training or educational preparation. The new training infrastructure which has emerged to meet these needs includes both internal, company-operated training programs and those offered by various external providers. Among the latter are: Vocational schools, community colleges, and university extension departments; public agencies, such as MSHA and state mining departments; coal industry trade associations; and vendors or training consultant groups. The Conference Board survey of coal industry training programs, conducted in late 1979, was designed to provide comprehensive data on the scope of the coal industry's own training activities and on related training issues, based on a mail questionnaire survey addressed to all companies producing 300,000 or more tons per year. The training programs are described with emphasis on time changes, regional effects and implications for a coordinated plan.

  9. Atomic layer deposition of tin oxide and zinc tin oxide using tetraethyltin and ozone

    SciTech Connect (OSTI)

    Warner, Ellis J.; Gladfelter, Wayne L.; Johnson, Forrest; Campbell, Stephen A.

    2015-03-15

    Silicon or glass substrates exposed to sequential pulses of tetraethyltin (TET) and ozone (O{sub 3}) were coated with thin films of SnO{sub 2}. Self-limiting deposition was found using 8 s pulse times, and a uniform thickness per cycle (TPC) of 0.2 nm/cycle was observed in a small, yet reproducible, temperature window from 290 to 320 °C. The as-deposited, stoichiometric SnO{sub 2} films were amorphous and transparent above 400 nm. Interspersing pulses of diethylzinc and O{sub 3} among the TET:O{sub 3} pulses resulted in deposition of zinc tin oxide films, where the fraction of tin, defined as [at. % Sn/(at. % Sn + at. % Zn)], was controlled by the ratio of TET pulses, specifically n{sub TET}:(n{sub TET} + n{sub DEZ}) where n{sub TET} and n{sub DEZ} are the number of precursor/O{sub 3} subcycles within each atomic layer deposition (ALD) supercycle. Based on film thickness and composition measurements, the TET pulse time required to reach saturation in the TPC of SnO{sub 2} on ZnO surfaces was increased to >30 s. Under these conditions, film stoichiometry as a function of the TET pulse ratio was consistent with the model devised by Elliott and Nilsen. The as-deposited zinc tin oxide (ZTO) films were amorphous and remained so even after annealing at 450 °C in air for 1 h. The optical bandgap of the transparent ZTO films increased as the tin concentration increased. Hall measurements established that the n-type ZTO carrier concentration was 3 × 10{sup 17} and 4 × 10{sup 18} cm{sup −3} for fractional tin concentrations of 0.28 and 0.63, respectively. The carrier mobility decreased as the concentration of tin increased. A broken gap pn junction was fabricated using ALD-deposited ZTO and a sputtered layer of cuprous oxide. The junction demonstrated ohmic behavior and low resistance consistent with similar junctions prepared using sputter-deposited ZTO.

  10. Iron(II) catalysis in oxidation of hydrocarbons with ozone in acetonitrile

    SciTech Connect (OSTI)

    Bataineh, Hajem; Pestovsky, Oleg; Bakac, Andreja

    2015-02-11

    Oxidation of alcohols, ethers, and sulfoxides by ozone in acetonitrile is catalyzed by submillimolar concentrations of Fe(CH3CN)62+. The catalyst provides both rate acceleration and greater selectivity toward the less oxidized products. For example, Fe(CH3CN)62+-catalyzed oxidation of benzyl alcohol yields benzaldehyde almost exclusively (>95%), whereas the uncatalyzed reaction generates a 1:1 mixture of benzaldehyde and benzoic acid. Similarly, aliphatic alcohols are oxidized to aldehydes/ketones, cyclobutanol to cyclobutanone, and diethyl ether to a 1:1 mixture of ethanol and acetaldehyde. The kinetics of oxidation of alcohols and diethyl ether are first-order in [Fe(CH3CN)62+] and [O3] and independent of [substrate] at concentrations greater than ~5 mM. In this regime, the rate constant for all of the alcohols is approximately the same, kcat = (8 ± 1) × 104 M–1 s–1, and that for (C2H5)2O is (5 ± 0.5) × 104 M–1 s–1. In the absence of substrate, Fe(CH3CN)62+ reacts with O3 with kFe = (9.3 ± 0.3) × 104 M–1 s–1. The similarity between the rate constants kFe and kcat strongly argues for Fe(CH3CN)62+/O3 reaction as rate-determining in catalytic oxidation. The active oxidant produced in Fe(CH3CN)62+/O3 reaction is suggested to be an Fe(IV) species in analogy with a related intermediate in aqueous solutions. As a result, this assignment is supported by the similarity in kinetic isotope effects and relative reactivities of the two species toward substrates.

  11. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    SciTech Connect (OSTI)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 C to 380 C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on the same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.

  12. Potential for savings in compliance costs for reducing ground-level ozone possible by instituting seasonal versus annual nitric oxide emission limits

    SciTech Connect (OSTI)

    Lookman, A.A.

    1996-12-31

    Ground-level ozone is formed in the atmosphere from its precursor emissions, namely nitric oxide (NO{sub x}) and volatile organic compounds (VOC), with its rate of formation dependent on atmospheric conditions. Since ozone levels tend to be highest during the summer months, seasonal controls of precursors have been suggested as a means of reducing the costs of decreasing ozone concentrations to acceptable levels. This paper attempts to quantify what the potential savings if seasonal control were instituted for coal-fired power plants, assuming that only commercially available NO{sub x} control technologies are used. Cost savings through seasonal control is measured by calculating the total annualized cost of NO{sub x} removal at a given amount of seasonal control for different target levels of annual control. For this study, it is assumed that trading of NO{sub x} emissions will be allowed, as has been proposed by the Ozone Transportation Commission (OTC). The problem has been posed as a binary integer linear programming problem, with decision variables being which control to use at each power plant. The results indicate that requiring annual limits which are lower than seasonal limits can substantially reduce compliance costs. These savings occur because requiring stringent compliance only on a seasonal basis allows power plants to use control methods for which the variable costs are paid for only part of the year, and through the use of gas-based controls, which are much cheaper to operate in the summer months.

  13. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    SciTech Connect (OSTI)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometer (UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.

  14. Compliance with the Clean Air Act Title VI Stratospheric Ozone Protection Program requirements at U.S. DOE Oak Ridge Reservation Facilities

    SciTech Connect (OSTI)

    Humphreys, M.P.; Atkins, E.M.

    1999-07-01

    The Title VI Stratospheric Ozone Protection Program of the Clean Air Act (CAA) requires promulgation of regulations to reduce and prevent damage to the earth's protective ozone layer. Regulations pursuant to Title VI of the CAA are promulgated in the Code of Federal Regulations (CFR) at Title 40 CFR, Part 822. The regulations include ambitious production phaseout schedules for ozone depleting substances (ODS) including chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), halons, carbon tetrachloride, and methyl chloroform under 40 CFR 82, Subpart A. The regulations also include requirements for recycling and emissions reduction during the servicing of refrigeration equipment and technician certification requirements under Subpart F; provisions for servicing of motor vehicle air conditioners under Subpart B; a ban on nonessential products containing Class 1 ODS under Subpart C; restrictions on Federal procurement of ODS under Subpart D; labeling of products using ODS under Subpart E; and the Significant New Alternatives Policy Program under Subpart G. This paper will provide details of initiatives undertaken at US Department of Energy (DOE) Oak Ridge Reservation (ORR) Facilities for implementation of requirements under the Title VI Stratospheric Ozone Protection Program. The Stratospheric Ozone Protection Plans include internal DOE requirements for: (1) maintenance of ODS inventories; (2) ODS procurement practices; (3) servicing of refrigeration and air conditioning equipment; (4) required equipment modifications or replacement; (5) technician certification training; (6) labeling of products containing ODS; (7) substitution of chlorinated solvents; and (8) replacement of halon fire protection systems. The plans also require establishment of administrative control systems which assure that compliance is achieved and maintained as the regulations continue to develop and become effective.

  15. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometermore » (UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.« less

  16. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    SciTech Connect (OSTI)

    Kim, S.; Kim, S. -Y.; Lee, M.; Shim, H.; Wolfe, G. M.; Guenther, A. B.; He, A.; Hong, Y.; Han, J.

    2015-04-29

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Guangzhou, and Beijing are surrounded by densely forested areas, and recent research has consistently demonstrated the importance of biogenic volatile organic compounds (VOCs) from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical, undermine our ability to assess regional photochemical air pollution problems. We present an observational data set of CO, NOx, SO2, ozone, HONO, and VOCs (anthropogenic and biogenic) from Taehwa research forest (TRF) near the Seoul metropolitan area in early June 2012. The data show that TRF is influenced both by aged pollution and fresh biogenic volatile organic compound emissions. With the data set, we diagnose HOx (OH, HO2, and RO2) distributions calculated using the University of Washington chemical box model (UWCM v2.1) with near-explicit VOC oxidation mechanisms from MCM v3.2 (Master Chemical Mechanism). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that (1) different model simulation scenarios cause systematic differences in HOx distributions, especially OH levels (up to 2.5 times), and (2) radical destruction (HO2 + HO2 or HO2 + RO2) could be more efficient than radical recycling (RO2 + NO), especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozoneVOCNOx sensitivity and VOC oxidation product formation rates. Overall, the NOx limited regime is assessed except for the morning hours (8 a.m. to 12 p.m. local standard time), but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with oxygenated VOCs (OVOCs) production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher-than-expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.

  17. Court decision dropping toxic substance rules stands

    SciTech Connect (OSTI)

    Bryant, C.R.

    1993-06-01

    In a somewhat surprising move, the U.S. Department of Labor has decided not to appeal a court decision essentially dropping regulations established by the Occupational Safety and Health Administration (OSHA) for about 400 hazardous substances. The decision leaves unregulated or subject to reduced standards substances that range from carbon monoxide to perchloroethylene. The Labor Department had until March 22, 1993, to appeal the court decision. On July 8, 1992, the U.S. Court of Appeals for the 11th Circuit overturned OSHA's final Air Contaminants Standard, which was promulgated in 1989. The standard established permissible exposure limits (PELs) for 428 toxic substances. In AFL-CIO vs. OSHA, the Court ruled that OSHA failed to make a separate scientific case for evaluating health risks of each chemical. Because of the decision not to appeal, PELs for more than half of the substances regulated by OSHA now are removed from the books or revert to the voluntary industry standards adopted by OSHA in 1970 and in force prior to the 1989 final rule.

  18. Multi-model Estimates of Intercontinental Source-Receptor Relationships for Ozone Pollution

    SciTech Connect (OSTI)

    Fiore, A M; Dentener, F J; Wild, O; Cuvelier, C; Schultz, M G; Hess, P; Textor, C; Schulz, M; Doherty, R; Horowitz, L W; MacKenzie, I A; Sanderson, M G; Shindell, D T; Stevenson, D S; Szopa, S; Van Dingenen, R; Zeng, G; Atherton, C; Bergmann, D; Bey, I; Carmichael, G; Collins, W J; Duncan, B N; Faluvegi, G; Folberth, G; Gauss, M; Gong, S; Hauglustaine, D; Holloway, T; Isaksen, I A; Jacob, D J; Jonson, J E; Kaminski, J W; Keating, T J; Lupu, A; Marmer, E; Montanaro, V; Park, R; Pitari, G; Pringle, K J; Pyle, J A; Schroeder, S; Vivanco, M G; Wind, P; Wojcik, G; Wu, S; Zuber, A

    2008-10-16

    Understanding the surface O{sub 3} response over a 'receptor' region to emission changes over a foreign 'source' region is key to evaluating the potential gains from an international approach to abate ozone (O{sub 3}) pollution. We apply an ensemble of 21 global and hemispheric chemical transport models to estimate the spatial average surface O{sub 3} response over East Asia (EA), Europe (EU), North America (NA) and South Asia (SA) to 20% decreases in anthropogenic emissions of the O{sub 3} precursors, NO{sub x}, NMVOC, and CO (individually and combined), from each of these regions. We find that the ensemble mean surface O{sub 3} concentrations in the base case (year 2001) simulation matches available observations throughout the year over EU but overestimates them by >10 ppb during summer and early fall over the eastern U.S. and Japan. The sum of the O{sub 3} responses to NO{sub x}, CO, and NMVOC decreases separately is approximately equal to that from a simultaneous reduction of all precursors. We define a continental-scale 'import sensitivity' as the ratio of the O{sub 3} response to the 20% reductions in foreign versus 'domestic' (i.e., over the source region itself) emissions. For example, the combined reduction of emissions from the 3 foreign regions produces an ensemble spatial mean decrease of 0.6 ppb over EU (0.4 ppb from NA), less than the 0.8 ppb from the reduction of EU emissions, leading to an import sensitivity ratio of 0.7. The ensemble mean surface O{sub 3} response to foreign emissions is largest in spring and late fall (0.7-0.9 ppb decrease in all regions from the combined precursor reductions in the 3 foreign regions), with import sensitivities ranging from 0.5 to 1.1 (responses to domestic emission reductions are 0.8-1.6 ppb). High O{sub 3} values are much more sensitive to domestic emissions than to foreign emissions, as indicated by lower import sensitivities of 0.2 to 0.3 during July in EA, EU, and NA when O{sub 3} levels are typically highest, and by the weaker relative response of annual incidences of daily maximum 8-hour average O{sub 3} above 60 ppb to emission reductions in a foreign region (<10-20% of that to domestic) as compared to the annual mean response (up to 50% of that to domestic). Applying the ensemble annual mean results to changes in anthropogenic emissions from 1996 to 2002, we estimate a Northern Hemispheric increase in background surface O{sub 3} of about 0.1 ppb yr{sup -1}, at the low end of the 0.1-0.5 ppb yr{sup -1} derived from observations. From an additional simulation in which global atmospheric methane was reduced, we infer that 20% reductions in anthropogenic methane emissions from a foreign source region would yield an O{sub 3} response in a receptor region that roughly equals that produced by combined 20% reductions of anthropogenic NO{sub x}, NMVOC and CO emissions from the foreign source region.

  19. Occupational health and environment research 1983: Health, Safety, and Environment Division. Progress report

    SciTech Connect (OSTI)

    Voelz, G.L.

    1985-05-01

    The primary responsibility of the Health, Safety, and Environment (HSE) Division at the Los Alamos National Laboratory is to provide comprehensive occupational health and safety programs, waste processing, and environmental protection. These activities are designed to protect the workers, the public, and the environment. Evaluation of respiratory protective equipment included the XM-30 and M17A1 military masks, use of MAG-1 spectacles in respirators, and eight self-contained units. The latter units were used in an evaluation of test procedures used for Bureau of Mines approval of breathing apparatuses. Analyses of air samples from field studies of a modified in situ oil shale retorting facility were performed for total cyclohexane extractables and selected polynuclear aromatic hydrocarbons. Aerosols generation and characterization of effluents from oil shale processing were continued as part of an inhalation toxicology study. Additional data on plutonium excretion in urine are presented and point up problems in using the Langham equation to predict plutonium deposition in the body from long-term excretion data. Environmental surveillance at Los Alamos during 1983 showed the highest estimated radiation dose from Laboratory operations to be about 26% of the natural background radiation dose. Several studies on radionuclides and their transport in the Los Alamos environment are described. The chemical quality of surface and ground water near the geothermal hot dry rock facility is described. Short- and long-term consequences to man from releases of radionuclides into the environment can be simulated by the BIOTRAN computer model, which is discussed brirfly.

  20. Thermally-assisted-occupation density functional theory with generalized-gradient approximations

    SciTech Connect (OSTI)

    Chai, Jeng-Da

    2014-05-14

    We extend the recently proposed thermally-assisted-occupation density functional theory (TAO-DFT) [J.-D. Chai, J. Chem. Phys. 136, 154104 (2012)] to generalized-gradient approximation (GGA) exchange-correlation density functionals. Relative to our previous TAO-LDA (i.e., the local density approximation to TAO-DFT), the resulting TAO-GGAs are significantly superior for a wide range of applications, such as thermochemistry, kinetics, and reaction energies. For noncovalent interactions, TAO-GGAs with empirical dispersion corrections are shown to yield excellent performance. Due to their computational efficiency for systems with strong static correlation effects, TAO-LDA and TAO-GGAs are applied to study the electronic properties (e.g., the singlet-triplet energy gaps, vertical ionization potentials, vertical electron affinities, fundamental gaps, and symmetrized von Neumann entropy) of acenes with different number of linearly fused benzene rings (up to 100), which is very challenging for conventional electronic structure methods. The ground states of acenes are shown to be singlets for all the chain lengths studied here. With the increase of acene length, the singlet-triplet energy gaps, vertical ionization potentials, and fundamental gaps decrease monotonically, while the vertical electron affinities and symmetrized von Neumann entropy (i.e., a measure of polyradical character) increase monotonically.

  1. Occupancy by key transcription factors is a more accurate predictor of enhancer activity than histone modifications or chromatin accessibility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dogan, Nergiz; Wu, Weisheng; Morrissey, Christapher S.; Chen, Kuan-Bei; Stonestrom, Aaron; Long, Maria; Keller, Cheryl A.; Cheng, Yong; Jain, Deepti; Visel, Axel; et al

    2015-04-23

    Regulated gene expression controls organismal development, and variation in regulatory patterns has been implicated in complex traits. Thus accurate prediction of enhancers is important for further understanding of these processes. Genome-wide measurement of epigenetic features, such as histone modifications and occupancy by transcription factors, is improving enhancer predictions, but the contribution of these features to prediction accuracy is not known. Given the importance of the hematopoietic transcription factor TAL1 for erythroid gene activation, we predicted candidate enhancers based on genomic occupancy by TAL1 and measured their activity. Contributions of multiple features to enhancer prediction were evaluated based on the resultsmore » of these and other studies. Results: TAL1-bound DNA segments were active enhancers at a high rate both in transient transfections of cultured cells (39 of 79, or 56%) and transgenic mice (43 of 66, or 65%). The level of binding signal for TAL1 or GATA1 did not help distinguish TAL1-bound DNA segments as active versus inactive enhancers, nor did the density of regulation-related histone modifications. A meta-analysis of results from this and other studies (273 tested predicted enhancers) showed that the presence of TAL1, GATA1, EP300, SMAD1, H3K4 methylation, H3K27ac, and CAGE tags at DNase hypersensitive sites gave the most accurate predictors of enhancer activity, with a success rate over 80% and a median threefold increase in activity. Chromatin accessibility assays and the histone modifications H3K4me1 and H3K27ac were sensitive for finding enhancers, but they have high false positive rates unless transcription factor occupancy is also included. Conclusions: Occupancy by key transcription factors such as TAL1, GATA1, SMAD1, and EP300, along with evidence of transcription, improves the accuracy of enhancer predictions based on epigenetic features.« less

  2. Occupancy by key transcription factors is a more accurate predictor of enhancer activity than histone modifications or chromatin accessibility

    SciTech Connect (OSTI)

    Dogan, Nergiz; Wu, Weisheng; Morrissey, Christapher S.; Chen, Kuan-Bei; Stonestrom, Aaron; Long, Maria; Keller, Cheryl A.; Cheng, Yong; Jain, Deepti; Visel, Axel; Pennacchio, Len A.; Weiss, Mitchell J.; Blobel, Gerd A.; Hardison, Ross C.

    2015-04-23

    Regulated gene expression controls organismal development, and variation in regulatory patterns has been implicated in complex traits. Thus accurate prediction of enhancers is important for further understanding of these processes. Genome-wide measurement of epigenetic features, such as histone modifications and occupancy by transcription factors, is improving enhancer predictions, but the contribution of these features to prediction accuracy is not known. Given the importance of the hematopoietic transcription factor TAL1 for erythroid gene activation, we predicted candidate enhancers based on genomic occupancy by TAL1 and measured their activity. Contributions of multiple features to enhancer prediction were evaluated based on the results of these and other studies. Results: TAL1-bound DNA segments were active enhancers at a high rate both in transient transfections of cultured cells (39 of 79, or 56%) and transgenic mice (43 of 66, or 65%). The level of binding signal for TAL1 or GATA1 did not help distinguish TAL1-bound DNA segments as active versus inactive enhancers, nor did the density of regulation-related histone modifications. A meta-analysis of results from this and other studies (273 tested predicted enhancers) showed that the presence of TAL1, GATA1, EP300, SMAD1, H3K4 methylation, H3K27ac, and CAGE tags at DNase hypersensitive sites gave the most accurate predictors of enhancer activity, with a success rate over 80% and a median threefold increase in activity. Chromatin accessibility assays and the histone modifications H3K4me1 and H3K27ac were sensitive for finding enhancers, but they have high false positive rates unless transcription factor occupancy is also included. Conclusions: Occupancy by key transcription factors such as TAL1, GATA1, SMAD1, and EP300, along with evidence of transcription, improves the accuracy of enhancer predictions based on epigenetic features.

  3. Deputy Secretary Memo Regarding Energy Employees Occupational Illness Compensation Program Act Interviews of Current and Former Workers

    Broader source: Energy.gov [DOE]

    The Department embraces its responsibility for and commitment to the health and well-being of the Department of Energy's (DOE) current and former workers, both Federal and contractor employees. Two key programs that advance DO E's commitment to its former and current workers are the Department of Labor (DOL) managed Energy Employees Occupational Illness Compensation Program (EEOICP) and the Former Worker Medical Screening Program.

  4. Radiation Safety Training Guide for Use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-03-17

    This Guide provides an acceptable methodology for establishing and operating a radiation safety training program that will comply with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection (DOE 1998a), hereinafter referred to as 10 CFR 835. In particular, this Guide provides guidance for achieving compliance with subpart J of 10 CFR 835. Canceled by DOE G 441.1-1B.

  5. Determination of solute site occupancies within γ' precipitates in nickel-base superalloys via orientation-specific atom probe tomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meher, Subhashish; Rojhirunsakool, Tanaporn; Nandwana, Peeyush; Tiley, Jamie; Banerjee, Rajarshi

    2015-04-28

    In this study, the analytical limitations in atom probe tomography such as resolving a desired set of atomic planes, for solving complex materials science problems, have been overcome by employing a well-developed unique and reproducible crystallographic technique, involving synergetic coupling of orientation microscopy with atom probe tomography. The crystallographic information in atom probe reconstructions has been utilized to determine the solute site occupancies in Ni-Al-Cr based superalloys accurately. The structural information in atom probe reveals that both Al and Cr occupy the same sub-lattice within the L12-ordered g precipitates to form Ni3(Al,Cr) precipitates in a Ni-14Al-7Cr(at.%) alloy. Interestingly, the additionmore » of Co, which is a solid solution strengthener, to a Ni-14Al-7Cr alloy results in the partial reversal of Al site occupancy within g precipitates to form (Ni,Al)3(Al,Cr,Co) precipitates. This unique evidence of reversal of Al site occupancy, resulting from the introduction of other solutes within the ordered structures, gives insights into the relative energetics of different sub-lattice sites when occupied by different solutes.« less

  6. Occupant-in-Place Energy Efficiency Retrofit in a Group Home for 30% Energy Savings in Climate Zone 4

    SciTech Connect (OSTI)

    Moore, Mike

    2013-08-01

    Energy efficiency retrofits (EERs) face many challenges on the path to scalability. Limited budgets, cost effectiveness, risk factors, and accessibility impact the type and the extent of measures that can be implemented feasibly to achieve energy savings goals. Group home retrofits can face additional challenges than those in single family homes – such as reduced access (occupant-in-place restrictions) and lack of incentives for occupant behavioral change. This project studies the specification, implementation, and energy savings from an EER in a group home, with an energy savings goal of 30%. This short term test report chronicles the retrofit measures specified, their projected cost effectiveness using building energy simulations, and the short term test results that were used to characterize pre-retrofit and post-retrofit conditions. Additionally, the final report for the project will include analysis of pre- and post-retrofit performance data on whole building energy use, and an assessment of the energy impact of occupant interface with the building (i.e., window operation). Ultimately, the study’s results will be used to identify cost-effective EER measures that can be implemented in group homes, given constraints that are characteristic of these buildings. Results will also point towards opportunities for future energy savings.

  7. Occupant-in-Place Energy Efficiency Retrofit in a Group Home for 30% Energy Savings in Climate Zone 4

    SciTech Connect (OSTI)

    Moore, M.

    2013-08-01

    Energy efficiency retrofits (EERs) face many challenges on the path to scalability. Limited budgets, cost effectiveness, risk factors, and accessibility impact the type and the extent of measures that can be implemented feasibly to achieve energy savings goals. Group home retrofits can face additional challenges than those in single family homes - such as reduced access (occupant-in-place restrictions) and lack of incentives for occupant behavioral change. This project studies the specification, implementation, and energy savings from an EER in a group home, with an energy savings goal of 30%. This short term test report chronicles the retrofit measures specified, their projected cost-effectiveness using building energy simulations, and the short term test results that were used to characterize pre-retrofit and post-retrofit conditions. Additionally, the final report for the project will include analysis of pre- and post-retrofit performance data on whole building energy use, and an assessment of the energy impact of occupant interface with the building (i.e., window operation). Ultimately, the study's results will be used to identify cost effective EER measures that can be implemented in group homes, given constraints that are characteristic of these buildings. Results will also point towards opportunities for future energy savings.

  8. DOE 2011 Occupational Radiation Exposure report, _Prepared for the U.S. Department of Energy, Office of Health, Safety and Security. December 2012

    SciTech Connect (OSTI)

    Derek Hagemeyer, Yolanda McCormick

    2012-12-12

    This report discusses radiation protection and dose reporting requirements, presents the 2011 occupational radiation dose data along with trends over the past 5 years, and provides instructions to submit successful as low as reasonably achievable (ALARA) projects.

  9. U.S. Recordable Injury and Illness Rates and Lost Workday Rates Lowest Since BLS Began Reporting

    Broader source: Energy.gov [DOE]

    Acting Assistant Secretary for the Occupational Safety and Health Administration (OSHA), Jonathan L. Snare, told a gathering of safety and health professionals at the American Society of Safety Engineers Annual National Conference in New Orleans, LA, that the nation’s recordable injury and illness rates have declined 7.1 percent from 2002 to 2003.

  10. Sum frequency generation and catalytic reaction studies of the removal of the organic capping agents from Pt nanoparticles by UV-ozone treatment

    SciTech Connect (OSTI)

    Aliaga, Cesar; Park, Jeong Y.; Yamada, Yusuke; Lee, Hyun Sook; Tsung, Chia-Kuang; Yang, Peidong; Somorjai, Gabor A.

    2009-12-10

    We report the structure of the organic capping layers of platinum colloid nanoparticles and their removal by UV-ozone exposure. Sum frequency generation vibrational spectroscopy (SFGVS) studies identify the carbon-hydrogen stretching modes on poly(vinylpyrrolidone) (PVP) and tetradecyl tributylammonium bromide (TTAB)-capped platinum nanoparticles. We found that the UV-ozone treatment technique effectively removes the capping layer on the basis of several analytical measurements including SFGVS, X-ray photoelectron spectroscopy, and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The overall shape of the nanoparticles was preserved after the removal of capping layers, as confirmed by transmission electron microscopy (TEM). SFGVS of ethylene hydrogenation on the clean platinum nanoparticles demonstrates the existence of ethylidyne and di-{sigma}-bonded species, indicating the similarity between single-crystal and nanoparticle systems.

  11. Gender and snow crab occupational asthma in Newfoundland and Labrador, Canada

    SciTech Connect (OSTI)

    Howse, Dana; Gautrin, Denyse; Neis, Barbara . E-mail: bneis@mun.ca; Cartier, Andre; Horth-Susin, Lise; Jong, Michael; Swanson, Mark C.

    2006-06-15

    Fish and shellfish processing employs many thousands of people globally, with shellfish processing becoming more important in recent years. Shellfish processing is associated with multiple occupational health and safety (OHS) risks. Snow crab occupational asthma (OA) is work-related asthma associated with processing snow crab. We present a gender analysis of findings from a 3-year multifaceted study of snow crab OA in Newfoundland and Labrador, Canada. The study was carried out in four snow crab processing communities between 2001 and 2004. An anonymous survey questionnaire on knowledge, beliefs, and concerns related to processing snow crab administered to 158 workers attending community meetings at the start of the research found that women were significantly more likely than men to associate certain health problems, especially chest tightness, difficulty breathing, and cough, with crab processing (P<0.001). Worker health assessments carried out with 215 processing workers (187 current/28 former; 120 female/95 male) found that female participants were more likely to be diagnosed as almost certain/highly probable snow crab OA and allergy (P=0.001) and to be sensitized to snow crab (P=0.01) than male participants. Work histories from the health assessments were used to classify processing jobs as male or female. Allergen sampling (211 allergen samples: 115 area, 96 personal breathing zone) indicated that the plant areas where these male jobs were concentrated were associated with lower levels of aerosolized crab allergens (the agents responsible for OA to snow crab) than areas associated with female jobs. This difference was statistically significant in the two plants with poor ventilation (p<0.001 and P=0.017 for these plants). A gender analysis of work history data showed that female health assessment participants were likely to have worked longer processing snow crab than males (5 years versus 3.5 years, respectively). Cross-referencing of work history results with allergen sampling data for male and female job areas showed a gender difference in median cumulative exposures (duration of exposurexlevel of exposures) for health assessment participants. Health assessment participants with estimated higher median cumulative exposures were more likely to receive a diagnosis of almost certain/highly probable OA and allergy. Semistructured interviews with 27 health assessment participants (24 female/ 3 male) with a diagnosis of almost certain/highly probable or possible snow crab OA indicated that these workers can experience substantial quality of life impacts while working and that they seek to reduce the economic impact of their illness by remaining at their jobs as long as possible. Indications of selection bias and other study limitations point to the need for more research exploring the relationship between the gender division of labor and knowledge, beliefs, and concerns about snow crab processing, as well as gender differences in prevalence, quality of life, and socioeconomic impact.

  12. Statistical Methods and Software for the Analysis of Occupational Exposure Data with Non-detectable Values

    SciTech Connect (OSTI)

    Frome, EL

    2005-09-20

    Environmental exposure measurements are, in general, positive and may be subject to left censoring; i.e,. the measured value is less than a ''detection limit''. In occupational monitoring, strategies for assessing workplace exposures typically focus on the mean exposure level or the probability that any measurement exceeds a limit. Parametric methods used to determine acceptable levels of exposure, are often based on a two parameter lognormal distribution. The mean exposure level, an upper percentile, and the exceedance fraction are used to characterize exposure levels, and confidence limits are used to describe the uncertainty in these estimates. Statistical methods for random samples (without non-detects) from the lognormal distribution are well known for each of these situations. In this report, methods for estimating these quantities based on the maximum likelihood method for randomly left censored lognormal data are described and graphical methods are used to evaluate the lognormal assumption. If the lognormal model is in doubt and an alternative distribution for the exposure profile of a similar exposure group is not available, then nonparametric methods for left censored data are used. The mean exposure level, along with the upper confidence limit, is obtained using the product limit estimate, and the upper confidence limit on an upper percentile (i.e., the upper tolerance limit) is obtained using a nonparametric approach. All of these methods are well known but computational complexity has limited their use in routine data analysis with left censored data. The recent development of the R environment for statistical data analysis and graphics has greatly enhanced the availability of high-quality nonproprietary (open source) software that serves as the basis for implementing the methods in this paper.

  13. Controlling intake of uranium in the workplace: Applications of biokinetic modeling and occupational monitoring data

    SciTech Connect (OSTI)

    Leggett, Richard Wayne; Eckerman, Keith F; McGinn, Wilson; Meck, Dr. Robert A.

    2012-01-01

    This report provides methods for interpreting and applying occupational uranium monitoring data. The methods are based on current international radiation protection guidance, current information on the chemical toxicity of uranium, and best available biokinetic models for uranium. Emphasis is on air monitoring data and three types of bioassay data: the concentration of uranium in urine; the concentration of uranium in feces; and the externally measured content of uranium in the chest. Primary Reference guidance levels for prevention of chemical effects and limitation of radiation effects are selected based on a review of current scientific data and regulatory principles for setting standards. Generic investigation levels and immediate action levels are then defined in terms of these primary guidance levels. The generic investigation and immediate actions levels are stated in terms of radiation dose and concentration of uranium in the kidneys. These are not directly measurable quantities, but models can be used to relate the generic levels to the concentration of uranium in air, urine, or feces, or the total uranium activity in the chest. Default investigation and immediate action levels for uranium in air, urine, feces, and chest are recommended for situations in which there is little information on the form of uranium taken into the body. Methods are prescribed also for deriving case-specific investigation and immediate action levels for uranium in air, urine, feces, and chest when there is sufficient information on the form of uranium to narrow the range of predictions of accumulation of uranium in the main target organs for uranium: kidneys for chemical effects and lungs for radiological effects. In addition, methods for using the information herein for alternative guidance levels, different from the ones selected for this report, are described.

  14. DOE interpretations Guide to OSH standards. Update to the Guide

    SciTech Connect (OSTI)

    Not Available

    1994-03-31

    Reflecting Secretary O`Leary`s focus on occupational safety and health, the Office of Occupational Safety is pleased to provide you with the latest update to the DOE Interpretations Guide to OSH Standards. This Guide was developed in cooperation with the Occupational Safety and Health Administration, which continued its support during this last revision by facilitating access to the interpretations found on the OSHA Computerized Information System (OCIS). This March 31, 1994 update contains 123 formal interpretation letters written OSHA. As a result of the unique requests received by the 1-800 Response Line, this update also contains 38 interpretations developed by DOE. This new occupational safety and health information adds still more important guidance to the four volume reference set that you presently have in your possession.

  15. DOE interpretations Guide to OSH standards. Update to the Guide

    SciTech Connect (OSTI)

    Not Available

    1994-03-31

    Reflecting Secretary O`Leary`s focus on occupational safety and health, the Office of Occupational Safety is pleased to provide you with the latest update to the DOE Interpretations Guide to OSH Standards. This Guide was developed in cooperation with the Occupational Safety and Health Administration, which continued it`s support during this last revision by facilitating access to the interpretations found on the OSHA Computerized Information System (OCIS). This March 31, 1994 update contains 123 formal in letter written by OSHA. As a result of the unique requests received by the 1-800 Response Line, this update also contains 38 interpretations developed by DOE. This new occupational safety and health information adds still more important guidance to the four volume reference set that you presently have in your possession.

  16. DOE interpretations Guide to OSH standards. Update to the Guide

    SciTech Connect (OSTI)

    Not Available

    1994-03-31

    Reflecting Secretary O`Leary`s focus on occupational safety and health, the Office of Occupational Safety is pleased to provide you with the latest update to the DOE Interpretations Guide to OSH Standards. This Guide was developed in cooperation with the Occupational Safety and Health Administration, which continued its support during this last revision by facilitating access to the interpretations found on the OSHA Computerized Information System (OCIS). This March 31, 1994 update contains 123 formal interpretation letters written by OSHA. As a result of the unique requests received by the 1-800 Response Line, this update also contains 38 interpretations developed by DOE. This new occupational safety and health information adds still more important guidance to the four volume reference set that you presently have in your possession.

  17. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, S.; Kim, S. -Y.; Lee, M.; Shim, H.; Wolfe, G. M.; Guenther, A. B.; He, A.; Hong, Y.; Han, J.

    2015-04-29

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Guangzhou, and Beijing are surrounded by densely forested areas, and recent research has consistently demonstrated the importance of biogenic volatile organic compounds (VOCs) from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical, undermine our ability to assess regional photochemical air pollution problems. We present an observational data set of CO, NOx, SO2, ozone, HONO,more » and VOCs (anthropogenic and biogenic) from Taehwa research forest (TRF) near the Seoul metropolitan area in early June 2012. The data show that TRF is influenced both by aged pollution and fresh biogenic volatile organic compound emissions. With the data set, we diagnose HOx (OH, HO2, and RO2) distributions calculated using the University of Washington chemical box model (UWCM v2.1) with near-explicit VOC oxidation mechanisms from MCM v3.2 (Master Chemical Mechanism). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that (1) different model simulation scenarios cause systematic differences in HOx distributions, especially OH levels (up to 2.5 times), and (2) radical destruction (HO2 + HO2 or HO2 + RO2) could be more efficient than radical recycling (RO2 + NO), especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozone–VOC–NOx sensitivity and VOC oxidation product formation rates. Overall, the NOx limited regime is assessed except for the morning hours (8 a.m. to 12 p.m. local standard time), but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with oxygenated VOCs (OVOCs) production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher-than-expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.« less

  18. Clean Cities ozone air quality attainment and maintenance strategies that employ alternative fuel vehicles, with special emphasis on natural gas and propane

    SciTech Connect (OSTI)

    Santini, D.J.; Saricks, C.L.

    1998-08-04

    Air quality administrators across the nation are coming under greater pressure to find new strategies for further reducing automotive generated non-methane hydrocarbon (NMHC) and nitrogen oxide (NOx) emissions. The US Environmental Protection Agency (EPA) has established stringent emission reduction requirements for ozone non-attainment areas that have driven the vehicle industry to engineer vehicles meeting dramatically tightened standards. This paper describes an interim method for including alternative-fueled vehicles (AFVs) in the mix of strategies to achieve local and regional improvements in ozone air quality. This method could be used until EPA can develop the Mobile series of emissions estimation models to include AFVs and until such time that detailed work on AFV emissions totals by air quality planners and emissions inventory builders is warranted. The paper first describes the challenges confronting almost every effort to include AFVs in targeted emissions reduction programs, but points out that within these challenges resides an opportunity. Next, it discusses some basic relationships in the formation of ambient ozone from precursor emissions. It then describes several of the salient provisions of EPA`s new voluntary emissions initiative, which is called the Voluntary Mobile Source Emissions Reduction Program (VMEP). Recent emissions test data comparing gaseous-fuel light-duty AFVs with their gasoline-fueled counterparts is examined to estimate percent emissions reductions achievable with CNG and LPG vehicles. Examples of calculated MOBILE5b emission rates that would be used for summer ozone season planning purposes by an individual Air Quality Control Region (AQCR) are provided. A method is suggested for employing these data to compute appropriate voluntary emission reduction credits where such (lighter) AFVs would be acquired. It also points out, but does not quantify, the substantial reduction credits potentially achievable by substituting gaseous-fueled for gasoline-fueled heavy-duty vehicles. Finally, it raises and expands on the relevance of AFVs and their deployment to some other provisions embedded in EPA`s current guidance for implementing 1-hour NAAQS--standards which currently remain in effect--as tools to provide immediate reductions in ozone, without waiting for promised future clean technologies.

  19. Re-Assessing Green Building Performance: A Post Occupancy Evaluation of 22 GSA Buildings

    SciTech Connect (OSTI)

    Fowler, Kimberly M.; Rauch, Emily M.; Henderson, Jordan W.; Kora, Angela R.

    2010-06-01

    2nd report on the performance of GSA's sustainably designed buildings. The purpose of this study was to provide an overview of measured whole building performance as it compares to GSA and industry baselines. The PNNL research team found the data analysis illuminated strengths and weaknesses of individual buildings as well as the portfolio of buildings. This section includes summary data, observations that cross multiple performance metrics, discussion of lessons learned from this research, and opportunities for future research. The summary of annual data for each of the performance metrics is provided in Table 25. The data represent 1 year of measurements and are not associated with any specific design features or strategies. Where available, multiple years of data were examined and there were minimal significant differences between the years. Individually focused post occupancy evaluation (POEs) would allow for more detailed analysis of the buildings. Examining building performance over multiple years could potentially offer a useful diagnostic tool for identifying building operations that are in need of operational changes. Investigating what the connection is between the building performance and the design intent would offer potential design guidance and possible insight into building operation strategies. The 'aggregate operating cost' metric used in this study represents the costs that were available for developing a comparative industry baseline for office buildings. The costs include water utilities, energy utilities, general maintenance, grounds maintenance, waste and recycling, and janitorial costs. Three of the buildings that cost more than the baseline in Figure 45 have higher maintenance costs than the baseline, and one has higher energy costs. Given the volume of data collected and analyzed for this study, the inevitable request is for a simple answer with respect to sustainably designed building performance. As previously stated, compiling the individual building values into single metrics is not statistically valid given the small number of buildings, but it has been done to provide a cursory view of this portfolio of sustainably designed buildings. For all metrics except recycling cost per rentable square foot and CBE survey response rate, the averaged building performance was better than the baseline for the GSA buildings in this study.

  20. Iron site occupancies in magnetite-ulvospinel solid solution: A new approach using XMCD

    SciTech Connect (OSTI)

    Pearce, C. I.; Henderson, C. M. B.; Telling, N. D.; Pattrick, R. A.D.; Vaughan, D. J.; Charnock, J. M.; Arenholz, E.; Tuna, F.; Coker, V.S.; Laan, G. van der

    2009-06-22

    Ordering of Fe{sup 3+} and Fe{sup 2+} between octahedral (Oh) and tetrahedral (Td) sites in synthetic members of the magnetite (Fe{sub 3}O{sub 4}) - ulvoespinel (Fe{sub 2}TiO{sub 4}) solid-solution series was determined using Fe L{sub 2,3}-edge X-ray magnetic circular dichroism (XMCD) coupled with electron microprobe and chemical analysis, Ti L-edge spectroscopy, Fe K-edge EXAFS and XANES, Fe{sub 57} Moessbauer spectroscopy, and unit cell parameters. Microprobe analysis, cell edges and chemical FeO determinations showed that the bulk compositions of the samples were stoichiometric magnetite-ulvoespinel solid-solutions. Surface sensitive XMCD showed that the surfaces of these oxide minerals were more sensitive to redox conditions and some samples required re-equilibration with suitable solid-solid buffers. Detailed site-occupancy analysis of these samples gave XMCD-Fe{sup 2+}/Fe{sup 3+} ratios very close to stoichiometric values. L{sub 2,3}-edge spectroscopy showed that Ti{sup 4+} was restricted to Oh sites. XMCD results showed that significant Fe{sup 2+} only entered Td when the Ti content was > 0.40 apfu while Fe{sup 2+} in Oh increased from 1 a.p.f.u in magnetite to a maximum of {approx}1.4 apfu in USP45. As the Ti content increased from this point, the steady increase in Fe{sup 2+} in Td sites was clearly observable in the XMCD spectra, concurrent with a slow decrease in Fe{sup 2+} in Oh sites. Calculated magnetic moments showed a steady decrease from magnetite (4.06 {mu}{sub B}) to USP45 (1.5 {mu}{sub B}) and then a slower decrease towards the value for ulvoespinel (0 {mu}{sub B}). Two of the synthesized samples were also partially maghemitized by re-equilibrating with an oxidizing Ni-NiO buffer and XMCD showed that Fe{sup 2+} oxidation only occurred at Oh sites, with concomitant vacancy formation restricted to this site. This study shows the advantage of using XMCD as a direct measurement of Fe oxidation state in these complex magnetic spinels. These results can be used to rationalize the magnetic properties of titanomagnetites, and their oxidized titanomaghemitized analogues, in Earth's crustal rocks.

  1. 38th Symposium on Biotechnology for Fuels and Chemicals | Department of

    Energy Savers [EERE]

    | Department of Energy nd Annual National Safety Awareness Event to Prevent Falls in Construction 2nd Annual National Safety Awareness Event to Prevent Falls in Construction April 27, 2015 - 8:08am Addthis 2nd Annual National Safety Awareness Event to Prevent Falls in Construction As part of a Fall Prevention Campaign launched 3 years ago by the Occupational Safety and Health Administration (OSHA), the National Institute for Occupational Safety and Health, and the Center for Construction

  2. 3-D Model for Deactivation & Decommissioning

    Office of Environmental Management (EM)

    | Department of Energy nd Annual National Safety Awareness Event to Prevent Falls in Construction 2nd Annual National Safety Awareness Event to Prevent Falls in Construction April 27, 2015 - 8:08am Addthis 2nd Annual National Safety Awareness Event to Prevent Falls in Construction As part of a Fall Prevention Campaign launched 3 years ago by the Occupational Safety and Health Administration (OSHA), the National Institute for Occupational Safety and Health, and the Center for Construction

  3. VPP Interagency Agreement Between DOE and DOL

    Broader source: Energy.gov [DOE]

    The purpose of thia agreement ie for the U. S. Department Of Labor's (DOL) Occupational Safety and Health Administration (OSHA) Directorate of Federal-State Operation8 (FSO) to provide aeeistance to the U. S. Department of Energy’s (DOE) Office of Occupational safety (EH-31) in the development bf the DOE Voluntary Protection Program (DOE-WP) at Government-~ned-or-LeaBed Contractor-Operated (GOCO) facilities.

  4. 2nd Annual National Safety Awareness Event to Prevent Falls in Construction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy nd Annual National Safety Awareness Event to Prevent Falls in Construction 2nd Annual National Safety Awareness Event to Prevent Falls in Construction April 27, 2015 - 8:08am Addthis 2nd Annual National Safety Awareness Event to Prevent Falls in Construction As part of a Fall Prevention Campaign launched 3 years ago by the Occupational Safety and Health Administration (OSHA), the National Institute for Occupational Safety and Health, and the Center for Construction

  5. GP-8 LAWS AND REGULATIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    40-DOP (5-2011) Supersedes (7-2010) issue DECLARATION of OCCUPATIONAL MEDICINE PROVIDER GENERAL INFORMATION PURPOSE All Contractors and their lower-tier subcontractors must comply with the Department of Energy's Worker Safety and Health Program regulation, 10 CFR 851, "Worker Safety and Health Program (WSHP). The WSHP enforces worker safety and health requirements including, but not limited to, standards of the Occupational Safety and Health Administration (OSHA), American National

  6. The Department of Energy Respiratory Acceptance Program for Supplied-Air Suits

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2004-02-04

    The supplied-air suits that protect DOE contractor and federal employees from exposure to harmful atmospheres and radioactive contaminants are not included in the National Institute for Occupational Safety and Health (NIOSH) certification process for respiratory protective devices. Therefore, with the awareness and acknowledgement of NIOSH and the Occupational Safety and Health Administration (OSHA), the Department established a system for acceptance testing of supplied-air suits.

  7. Spatial and temporal variations in indoor environmental conditions, human occupancy, and operational characteristics in a new hospital building

    SciTech Connect (OSTI)

    Ramos, Tiffanie; Dedesko, Sandra; Siegel, Jeffrey A.; Gilbert, Jack A.; Stephens, Brent

    2015-03-02

    The dynamics of indoor environmental conditions, human occupancy, and operational characteristics of buildings influence human comfort and indoor environmental quality, including the survival and progression of microbial communities. A suite of continuous, long-term environmental and operational parameters were measured in ten patient rooms and two nurse stations in a new hospital building in Chicago, IL to characterize the indoor environment in which microbial samples were taken for the Hospital Microbiome Project. Measurements included environmental conditions (indoor dry-bulb temperature, relative humidity, humidity ratio, and illuminance) in the patient rooms and nurse stations; differential pressure between the patient rooms and hallways; surrogate measures for human occupancy and activity in the patient rooms using both indoor air CO₂ concentrations and infrared doorway beam-break counters; and outdoor air fractions in the heating, ventilating, and air-conditioning systems serving the sampled spaces. Measurements were made at 5-minute intervals over consecutive days for nearly one year, providing a total of ~8×10⁶ data points. Indoor temperature, illuminance, and human occupancy/activity were all weakly correlated between rooms, while relative humidity, humidity ratio, and outdoor air fractions showed strong temporal (seasonal) patterns and strong spatial correlations between rooms. Differential pressure measurements confirmed that all patient rooms were operated at neutral pressure. The patient rooms averaged about 100 combined entrances and exits per day, which suggests they were relatively lightly occupied compared to higher traffic environments (e.g., retail buildings) and more similar to lower traffic office environments. There were also clear differences in several environmental parameters before and after the hospital was occupied with patients and staff. Characterizing and understanding factors that influence these building dynamics is vital for hospital environments, where they can impact patient health and the survival and spread of healthcare associated infections.

  8. Occupational hygiene in terms of volatile organic compounds (VOCs) and bioaerosols at two solid waste management plants in Finland

    SciTech Connect (OSTI)

    Lehtinen, Jenni; Tolvanen, Outi; Nivukoski, Ulla; Veijanen, Anja; Hnninen, Kari

    2013-04-15

    Highlights: ? Odorous VOCs: acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene. ? VOC concentrations did not exceed occupational exposure limit concentrations. ? 2,3-Butanedione as the health effecting compound is discussed. ? Endotoxin concentrations may cause health problems in waste treatment. - Abstract: Factors affecting occupational hygiene were measured at the solid waste transferring plant at Hyvink and at the optic separation plant in Hmeenlinna. Measurements consisted of volatile organic compounds (VOCs) and bioaerosols including microbes, dust and endotoxins. The most abundant compounds in both of the plants were aliphatic and aromatic hydrocarbons, esters of carboxylic acids, ketones and terpenes. In terms of odour generation, the most important emissions were acetic acid, 2,3-butanedione, ethyl acetate, alpha-pinene and limonene due to their low threshold odour concentrations. At the optic waste separation plant, limonene occurred at the highest concentration of all single compounds of identified VOCs. The concentration of any single volatile organic compound did not exceed the occupational exposure limit (OEL) concentration. However, 2,3-butanedione as a health risk compound is discussed based on recent scientific findings linking it to lung disease. Microbe and dust concentrations were low at the waste transferring plant. Only endotoxin concentrations may cause health problems; the average concentration inside the plant was 425 EU/m{sup 3} which clearly exceeded the threshold value of 90 EU/m{sup 3}. In the wheel loader cabin the endotoxin concentrations were below 1 EU/m{sup 3}. High microbial and endotoxin concentrations were measured in the processing hall at the optic waste separation plant. The average concentration of endotoxins was found to be 10,980 EU/m{sup 3}, a concentration which may cause health risks. Concentrations of viable fungi were quite high in few measurements in the control room. The most problematic factor was endotoxins whose average measured concentrations was 4853 EU/m{sup 3}.

  9. Spatial and temporal variations in indoor environmental conditions, human occupancy, and operational characteristics in a new hospital building

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ramos, Tiffanie; Dedesko, Sandra; Siegel, Jeffrey A.; Gilbert, Jack A.; Stephens, Brent

    2015-03-02

    The dynamics of indoor environmental conditions, human occupancy, and operational characteristics of buildings influence human comfort and indoor environmental quality, including the survival and progression of microbial communities. A suite of continuous, long-term environmental and operational parameters were measured in ten patient rooms and two nurse stations in a new hospital building in Chicago, IL to characterize the indoor environment in which microbial samples were taken for the Hospital Microbiome Project. Measurements included environmental conditions (indoor dry-bulb temperature, relative humidity, humidity ratio, and illuminance) in the patient rooms and nurse stations; differential pressure between the patient rooms and hallways; surrogatemore » measures for human occupancy and activity in the patient rooms using both indoor air CO₂ concentrations and infrared doorway beam-break counters; and outdoor air fractions in the heating, ventilating, and air-conditioning systems serving the sampled spaces. Measurements were made at 5-minute intervals over consecutive days for nearly one year, providing a total of ~8×10⁶ data points. Indoor temperature, illuminance, and human occupancy/activity were all weakly correlated between rooms, while relative humidity, humidity ratio, and outdoor air fractions showed strong temporal (seasonal) patterns and strong spatial correlations between rooms. Differential pressure measurements confirmed that all patient rooms were operated at neutral pressure. The patient rooms averaged about 100 combined entrances and exits per day, which suggests they were relatively lightly occupied compared to higher traffic environments (e.g., retail buildings) and more similar to lower traffic office environments. There were also clear differences in several environmental parameters before and after the hospital was occupied with patients and staff. Characterizing and understanding factors that influence these building dynamics is vital for hospital environments, where they can impact patient health and the survival and spread of healthcare associated infections.« less

  10. Pulmonary function and symptom responses after 6. 6-hour exposure to 0. 12-ppm ozone with moderate exercise (journal version)

    SciTech Connect (OSTI)

    Folinsbee, L.J.; Horstman, D.H.; McDonnell, W.F.

    1988-01-01

    Episodes occasionally occur when ambient ozone (O/sub 3/) levels remain at or near 0.12 ppm for more than 6 h. The hypothesis that prolonged exposure to 0.12 ppm O/sub 3/ would result in progressively larger changes in respiratory function and symptoms over time was tested. Ten nonsmoking males (18-35 yr) were exposed once to clear air (CA) and once to 0.12 pp, O/sub 3/ for 6.75 h. Exposures consisted of six 50-min exercise periods, each followed by 10-min rest and measurement; a 45-min lunch period followed the third exercise period. Exercise ventilation averaged approximately 40 1/min. Forced expiratory and inspiratory spirometry and respiratory symptoms were measured prior to exposure and after each exercise. Increases in the symptom ratings of cough and pain on deep inspiration were observed with O/sub 3/ exposure but not with CA. Airway reactivity to methacholine was approximately doubled following O/sub 3/ exposure. Spirometry results indicate that prolonged exposure to 0.12 ppm O/sub 3/ results in a marked increase in non-specific airway reactivity and progressive changes in respiratory function.

  11. The role of EPA`s Acid Rain Division in the Ozone Transport Commission`s NOx budget program

    SciTech Connect (OSTI)

    Schary, C.; Culligan, K.

    1997-12-31

    The Ozone Transport Commission`s (OTC) Nitrogen Oxides (NO{sub x}) Budget Program will implement the emissions reduction goal of the 1994 Memorandum of Understanding between its twelve member states and the District of Columbia. The program will achieve its significant NO{sub x} reductions from electric utilities and industrial boilers using a {open_quotes}cap-and-trade{close_quotes} approach modeled after the US Environmental Protection Agency`s sulfur dioxide emissions trading under the Acid Rain Program. The similarity of the two programs has led to the development of an important partnership between the OTC states and EPA`s Acid Rain Division, Over the past two years, Acid Rain Program staff have shared their technical expertise and assisted extensively in the development of the program`s rules. Leveraging the investment EPA made in the systems used to run the Acid Rain Program, the OTC states have asked the Acid Rain Division to administer the data systems for them, and together are working to expand its existing Emissions Tracking System and to modify a clone of the sulfur dioxide Allowance Tracking System, to fulfill the unique requirements of the NO{sub x} Budget Program. This partnership is an important example of the new type of cooperation and sharing of expertise and resources that should develop between EPA and states as they launch multi-state programs to address regional pollution problems that defy a single-state solution.

  12. Occupational Health Services Part III Contract No. DE-AC06-04RL14383, Modification 142 Section J

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    III Contract No. DE-AC06-04RL14383, Modification 142 Section J Page J-11 J.3 Health Care Center Description There is a Health Care Center located in the 200 West Area of the Hanford Site, that is staffed by the Occupational Medical Contractor to provide first aid services to workers in the adjacent areas. The 200 West Facility is Government-Furnished. The Health Care Center consists of office space, examination/treatment rooms, storage rooms, etc. as shown on the floor plan in Figure J.3- 1,

  13. Impact of fuel cladding failure events on occupational radiation exposures at nuclear power plants. Case study: PWR during routine operations

    SciTech Connect (OSTI)

    Moeller, M.P.; Martin, G.F.; Haggard, D.L.

    1986-01-01

    The purpose of this report is to present data in support of evaluating the impact of fuel cladding failure events on occupational radiation exposure. To determine quantitatively whether fuel cladding failure contributes significantly to occupational radiation exposure, radiation exposure measurements were taken at comparable locations in two mirror-image pressurized-water reactors (PWRs) and their common auxiliary building. One reactor, Unit B, was experiencing degraded fuel characterized as 0.125% fuel pin-hole leakers and was operating at approximately 55% of the reactor's licensed maximum core power, while the other reactor, Unit A, was operating under normal conditions with less than 0.01% fuel pin-hole leakers at 100% of the reactor's licensed maximum core power. Measurements consisted of gamma spectral analyses, radiation exposure rates and airborne radionuclide concentrations. In addition, data from primary coolant sample results for the previous 20 months on both reactor coolant systems were analyzed. The results of the measurements and coolant sample analyses suggest that a 3560-megawatt-thermal (1100 MWe) PWR operating at full power with 0.125% failed fuel can experience an increase of 540% in radiation exposure rates as compared to a PWR operating with normal fuel. In specific plant areas, the degraded fuel may elevate radiation exposure rates even more.

  14. Understanding the chemical properties of macerals and minerals in coal and its potential application for occupational lung disease prevention

    SciTech Connect (OSTI)

    Huang, X.; Finkelman, R.B.

    2008-07-01

    The objective of this review was to assess whether some chemical parameters in coal play a role in producing environmental health problems. Basic properties of coal - such as chemical forms of the organic materials, structure, compositions of minerals - vary from one coal mine region to another as well as from coals of different ranks. Most importantly, changes in chemical properties of coals due to exposure to air and humidity after mining - a dynamic process - significantly affect toxicity attributed to coal and environmental fate. Although coal is an extremely complex and heterogeneous material, the fundamental properties of coal responsible for environmental and adverse health problems are probably related to the same inducing components of coal. For instance, oxidation of pyrite (FeS{sub 2}) in the coal forms iron sulfate and sulfuric acid, which produces occupational lung diseases (e.g., pneumoconiosis) and other environmental problems (e.g., acid mine drainage and acid rain). Calcite (CaCO{sub 3}) contained in certain coals alters the end products of pyrite oxidation, which may make these coals less toxic to human inhalation and less hazardous to environmental pollution. Finally, knowledge gained on understanding of the chemical properties of coals is illustrated to apply for prediction of toxicity due to coal possibly before large-scale mining and prevention of occupational lung disease during mining.

  15. A Radiocarbon Chronology of Hunter-Gatherer Occupation from Bodega Bay, California, USA

    SciTech Connect (OSTI)

    Kennedy, M A; Russell, A D; Guilderson, T P

    2005-04-27

    The evolution of hunter-gatherer maritime adaptations in western North America has been a prominent topic of discussion among archaeologists in recent years (e.g. Arnold 1992; Erlandson and Colten 1991; Erlandson and Glassow 1997; Lightfoot 1993). Although vast coastal regions of the northeastern Pacific (for example, southern California) have been investigated in detail, our understanding of hunter-gatherer developments along the coast of northern California is limited. Previous research indicates that humans have exploited marine mammals, fish and shellfish along the northern California shoreline since the early Holocene (Schwaderer 1992). By the end of the late Holocene, some groups remained year-round on the coast subsisting primarily on marine resources (e.g. Gould 1975; Hildebrandt and Levulett 2002). However, a paucity of well-dated cultural deposits has hindered our understanding of these developments, particularly during the early and middle Holocene. The lack of a long and reliable chronological sequence has restricted our interpretations of behavioral change, including the adaptive strategies (such as foraging, mobility and settlement) used by human foragers to colonize and inhabit the coastal areas of this region. These shortcomings have also hindered comparative interpretations with other coastal and inland regions in western North America. Here we present a Holocene radiocarbon chronology of hunter-gatherer occupation based on contemporaneous samples of charcoal and Mytilus californianus (California sea mussel) shell recovered from seven archaeological sites near Bodega Bay, California. A series of 127 {sup 14}C ages reveal a chronological sequence that spans from ca. 8940-110 cal BP (1{sigma}) (7890-160 {sup 14}C yr BP = charcoal; 8934-101 {sup 14}C yr BP = shell). As part of this sequence, we report new {sup 14}C dates from the stratified cave and open-air midden deposits at Duncan's Landing (CA-SON-348/H). In addition, we present {sup 14}C ages from three middle Holocene sites located in the Bodega Dunes, and from three late Holocene sites, including Kili (CASON-299), the oldest known village site in the region. Bodega Bay (38 degrees 19 minutes N, 123 degrees 03 minutes W) is situated about 90 km north of San Francisco Bay, California (Figure 1). The Pacific, in conjunction with prominent geomorphological features, has given rise to a series of coastal habitats (e.g. semi-protected and protected shorelines) around Bodega Bay that are rather unique for the unprotected, surf swept rocky shores of northern California. This stretch of coastline also lies within a zone of particularly strong seasonal upwelling between Point Reyes Peninsula and Cape Mendocino; a region characterized by high Ekman transport (Huyer 1983), and high coastal concentrations of the nutrients silica and phosphate (van Geen and Husby 1996). The interaction between land and sea results in a productive marine ecosystem that has attracted hunter-gatherers for much of the Holocene.

  16. Accidental release prevention requirement: Risk management programs under Clean Air Act section 112(r)(7)

    SciTech Connect (OSTI)

    Hahn, J. [Integrated Waste Services Association, Fairfield, NJ (United States)

    1997-12-01

    The Occupational Safety and Health Administration promulgates and enforces regulations that govern the health and safety of workers. OSHA rules often are considered to govern what happens {open_quotes}inside the fence line,{close_quotes} or within the physical boundaries of the facility. In some ways, the U.S. Environmental Protection Agency takes over where OSHA leaves off. The U.S. EPA is responsible for environmental programs {open_quotes}outside the fence line.{close_quotes} The concept is as simple as drawing a line, or is it? Anyone developing and implementing compliance programs, whether for OSHA or EPA, will tell you nothing is that simple. EPA`s recent promulgation of rules pertaining to risk management programs is a case in point. A new EPA rule is intended to compliment OSHA requirements under the Process Safety Management (PSM) rule. Under the OSHA rule, plant operators developed programs that ensure safe measures are in use when handling certain chemicals. During the past three years, waste-to-energy facilities faced difficult decisions when complying with the PSM requirements. Earlier this year, the US EPA promulgated its 112(r)(7) rule that is intended to `complement` OSHA`s PSM requirements. This is not always the case. Unfortunately, these new Clean Air Act requirements do not always complement, but may instead confuse plant operators. For example, EPA`s 112(r) rule may force plant operators to change, once again, their decisions on the use of selected chemicals. The US EPA estimates that approximately 66,000 facilities, including the 114 waste-to-energy facilities nationwide, may be affected by the list and risk management planning rules. The facilities include chemical and many other manufacturers, cold storage facilities with ammonia refrigeration systems, public water treatment systems, wholesalers and distributors of these chemicals, propane retailers, utilities, and federal facilities.

  17. Pulmonary function and symptom responses after 6. 6-hour exposure to 0. 12 ppm ozone with moderate exercise

    SciTech Connect (OSTI)

    Folinsbee, L.J.; McDonnell, W.F.; Horstman, D.H.

    1988-01-01

    Episodes occasionally occur when ambient ozone (O/sub 3/) levels remain at or near 0.12 ppm for more than 6 h. Small decrements in lung function have been reported following 2-h exposures to 0.12 ppm O/sub 3/. For short exposures to higher O/sub 3/ concentrations, lung function decrements are a function of exposure duration. Thus, we investigated the hypothesis that prolonged exposure to 0.12 ppm O/sub 3/ would result in progressively larger changes in respiratory function and symptoms over time. Ten nonsmoking males were exposed once to clean air and once to 0.12 ppm O/sub 3/ for 6.6 h. Exposures consisted of six 50-min exercise periods, each followed by 10-min rest and measurement; a 35-min lunch period followed by the third exercise period. Exercise ventilation averaged approximately 40 L/min. Forced expiratory and inspiratory spirometry and respiratory symptoms were measured prior to exposure and after each exercise. Airway reactivity to methacholine was determined after each exposure. After correcting for the air exposures, FEV 1.0 was found to decrease linearly during the O/sub 3/ exposure and was decreased by an average of 13.0 percent at the end of exposure. Decreases in FVC and FEF24-75% were also linear and averaged 8.3 and 17.4 percent, respectively, at the end of exposure. On forced inspiratory tests, the FIVC and FIV05 were decreased 12.6 and 20.7 percent, respectively. Increases in the symptom ratings of cough and pain on deep inspiration were observed with O/sub 3/ exposure but not with clean air. Airway reactivity to methacholine was approximately doubled following O/sub 3/ exposure.

  18. U.S. NO2 trends (2005-2013): EPA Air Quality System (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI)

    Office of Scientific and Technical Information (OSTI)

    Atmospheric Environment 110 (2015) 130-143 Contents lists available at ScienceDirect Atmospheric Environment journal homepage: www.elsevier.com/locate/atmosenv U.S. NO2 trends (2005-2013): EPA Air Quality System (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI) CrossMark Lok N. Lamsal a b *, Bryan N. Duncan b, Yasuko Yoshida c'b, Nickolay A. Krotkov b, Kenneth E. Pickering b, David G. Streets d, Zifeng Lu d a Goddard Earth Sciences Technology and Research,

  19. THE EFFECT OF THE PRESENCE OF OZONE ON THE LOWER FLAMMABILITY LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, C.

    2012-01-12

    The Enhanced Chemical Cleaning (ECC) process uses ozone to effect the oxidation of metal oxalates produced during the dissolution of sludge in the Savannah River Site (SRS) waste tanks. The ozone reacts with the metal oxalates to form metal oxide and hydroxide precipitants, and the CO{sub 2}, O{sub 2}, H{sub 2}O and any unreacted O{sub 3} gases are discharged into the vapor space. In addition to the non-radioactive metals in the waste, however, the SRS radioactive waste also contains a variety of radionuclides, hence, hydrogen gas is also present in the vapor space of the ECC system. Because hydrogen is flammable, the impact of this resultant gas stream on the Lower Flammability Limit (LFL) of hydrogen must be understood for all possible operating scenarios of both normal and off-normal situations, with particular emphasis at the elevated temperatures and pressures of the typical ECC operating conditions. Oxygen is a known accelerant in combustion reactions, but while there are data associated with the behavior of hydrogen/oxygen environments, recent, relevant studies addressing the effect of ozone on the flammability limit of hydrogen proved scarce. Further, discussions with industry experts verified the absence of data in this area and indicated that laboratory testing, specific to defined operating parameters, was needed to comprehensively address the issue. Testing was thus designed and commissioned to provide the data necessary to support safety related considerations for the ECC process. A test matrix was developed to envelope the bounding conditions considered credible during ECC processing. Each test consists of combining a gas stream of high purity hydrogen with a gas stream comprised of a specified mixture of ozone and oxygen in a temperature and pressure regulated chamber such that the relative compositions of the two streams are controlled. The gases are then stirred to obtain a homogeneous mixture and ignition attempted by applying 10J of energy to a fuse wire. A gas combination is considered flammable when a pressure rise of 7% of the initial absolute pressure is observed. The specified testing methodology is consistent with guidelines established in ASTM E-918-83 (2005) 'Standard Practices for Determining Limits of Flammability of Chemicals at Elevated Temperature and Pressure'.

  20. Analysis of road pricing, metering and the priority treatment of high occupancy vehicles using system dynamics. Master's thesis

    SciTech Connect (OSTI)

    Castillo, W.

    1992-01-01

    Transportation Systems Management (TSM) employs various techniques such as road pricing, metering and the priority treatment of high occupancy vehicles (HOVs) in an effort to make more efficient use of existing transportation facilities. Efficiency is improved in terms of moving more people through the facility while simultaneously reducing the number of vehicles using the facility. This report uses a hypothetical toll facility and examines four computer modeling approaches to determine which of the approaches are valid in terms of predicting the behavior of trip makers seeking to use the facility in response to various combinations of TSM techniques. Once an approach has been determined to be valid, seven different combination of TSM techniques, or strategies, are compared to a base strategy to determine what strategy or strategies are most affective in achieving the goals of TSM.

  1. Changes in the peripheral blood transcriptome associated with occupational benzene exposure identified by cross-comparison on two microarray platforms

    SciTech Connect (OSTI)

    McHale, Cliona M.; Zhang, Luoping; Lan, Qing; Li, Guilan; Hubbard, Alan E.; Forrest, Matthew S.; Vermeulen, Roel; Chen, Jinsong; Shen, Min; Rappaport, Stephen M.; Yin, Songnian; Smith, Martyn T.; Rothman, Nathaniel

    2009-03-01

    Benzene is an established cause of leukemia and a possible cause of lymphoma in humans but the molecular pathways underlying this remain largely undetermined. This study sought to determine if the use of two different microarray platforms could identify robust global gene expression and pathway changes associated with occupational benzene exposure in the peripheral blood mononuclear cell (PBMC) gene expression of a population of shoe-factory workers with well-characterized occupational exposures to benzene. Microarray data was analyzed by a robust t-test using a Quantile Transformation (QT) approach. Differential expression of 2692 genes using the Affymetrix platform and 1828 genes using the Illumina platform was found. While the overall concordance in genes identified as significantly associated with benzene exposure between the two platforms was 26% (475 genes), the most significant genes identified by either array were more likely to be ranked as significant by the other platform (Illumina = 64%, Affymetrix = 58%). Expression ratios were similar among the concordant genes (mean difference in expression ratio = 0.04, standard deviation = 0.17). Four genes (CXCL16, ZNF331, JUN and PF4), which we previously identified by microarray and confirmed by real-time PCR, were identified by both platforms in the current study and were among the top 100 genes. Gene Ontology analysis showed over representation of genes involved in apoptosis among the concordant genes while Ingenuity{reg_sign} Pathway Analysis (IPA) identified pathways related to lipid metabolism. Using a two-platform approach allows for robust changes in the PBMC transcriptome of benzene-exposed individuals to be identified.

  2. Growth behavior and properties of atomic layer deposited tin oxide on silicon from novel tin(II)acetylacetonate precursor and ozone

    SciTech Connect (OSTI)

    Kannan Selvaraj, Sathees; Feinerman, Alan; Takoudis, Christos G.

    2014-01-15

    In this work, a novel liquid tin(II) precursor, tin(II)acetylacetonate [Sn(acac){sub 2}], was used to deposit tin oxide films on Si(100) substrate, using a custom-built hot wall atomic layer deposition (ALD) reactor. Three different oxidizers, water, oxygen, and ozone, were tried. Resulting growth rates were studied as a function of precursor dosage, oxidizer dosage, reactor temperature, and number of ALD cycles. The film growth rate was found to be 0.1??0.01?nm/cycle within the wide ALD temperature window of 175300?C using ozone; no film growth was observed with water or oxygen. Characterization methods were used to study the composition, interface quality, crystallinity, microstructure, refractive index, surface morphology, and resistivity of the resulting films. X-ray photoelectron spectra showed the formation of a clean SnO{sub x}Si interface. The resistivity of the SnO{sub x} films was calculated to be 0.3?? cm. Results of this work demonstrate the possibility of introducing Sn(acac){sub 2} as tin precursor to deposit conducting ALD SnO{sub x} thin films on a silicon surface, with clean interface and no formation of undesired SiO{sub 2} or other interfacial reaction products, for transparent conducting oxide applications.

  3. Three-Dimensional Mapping of Ozone-Induced Injury in the Nasal Airways of Monkeys Using Magnetic Resonance Imaging and Morphometric Techniques

    SciTech Connect (OSTI)

    Carey, Stephen A.; Minard, Kevin R.; Trease, Lynn L.; Wagner, James G.; Garcia, Guilherme M.; Ballinger, Carol A.; Kimbell, Julia; Plopper, Charles G.; Corley, Rick A.; Postlewait, Ed; Harkema, Jack R.

    2007-03-01

    ABSTRACT Age-related changes in gross and microscopic structure of the nasal cavity can alter local tissue susceptibility as well as the dose of inhaled toxicant delivered to susceptible sites. This article describes a novel method for the use of magnetic resonance imaging, 3-dimensional airway modeling, and morphometric techniques to characterize the distribution and magnitude of ozone-induced nasal injury in infant monkeys. Using this method, we are able to generate age-specific, 3-dimensional, epithelial maps of the nasal airways of infant Rhesus macaques. The principal nasal lesions observed in this primate model of ozone-induced nasal toxicology were neutrophilic rhinitis, along with necrosis and exfoliation of the epithelium lining the anterior maxilloturbinate. These lesions, induced by acute or cyclic (episodic) exposures, were examined by light microscopy, quantified by morphometric techniques, and mapped on 3-dimensional models of the nasal airways. Here, we describe the histopathologic, imaging, and computational biology methods developed to efficiently characterize, localize, quantify, and map these nasal lesions. By combining these techniques, the location and severity of the nasal epithelial injury were correlated with epithelial type, nasal airway geometry, and local biochemical and molecular changes on an individual animal basis. These correlations are critical for accurate predictive modeling of exposure-dose-response relationships in the nasal airways, and subsequent extrapolation of nasal findings in animals to humans for developing risk assessment.

  4. Evaluation and Control of Radiation Dose to the Embryo/Fetus Guide for Use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-04-29

    This Guide provides an acceptable methodology for establishing and operating a program to control fetal exposure to ionizing radiation and evaluate the resultant dose that will comply with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection (DOE 1998), hereinafter referred to as 10 CFR 835.

  5. Posting and Labeling for Radiological Control Guide for use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-05-24

    This Guide provides an acceptable methodology for establishing and operating a radiological hazard posting and labeling program that will comply with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection Canceled by DOE G 441.1-1B.

  6. Management and Administration of Radiation Protection Programs Guide for use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2003-10-20

    This Guide discusses acceptable methods for ensuring that radiological activities will be managed and administered in accordance with a documented radiation protection program that complies with U.S. DOE requirements specified in Title 10 CFR Part 835, Occupational Radiation Protection. Cancels DOE G 441.1-1. Canceled by DOE G 441.1-1B.

  7. Occupational Health Services - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exercise physiology and work conditioning, monitored care and case management, fitness for duty evaluations, health education and wellness promotion, infection control,...

  8. ARM - Instrument - ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ship Ronald H. Brown; AMF2 MAG M1 Browse Data Browse Plots Los Angeles, CA to Honolulu, HI - container ship Horizon Spirit; AMF2 retired MAO S1 Browse Data Browse Plots...

  9. Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005-2014

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Z.; Streets, D. G.; de Foy, B.; Lamsal, L. N.; Duncan, B. N.; Xing, J.

    2015-05-28

    Satellite remote sensing of tropospheric nitrogen dioxide (NO2) can provide valuable information for estimating surface nitrogen oxides (NOx) emissions. Using an exponentially-modified Gaussian (EMG) method and taking into account the effect of wind on observed NO2 distributions, we estimate three-year moving-average emissions of summertime NOx from 35 US urban areas directly from NO2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following the conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NOx emissions from each urban area by applying the EMG method to OMI data with windmore » speeds greater than 3–5 m s-1. Meanwhile, we find that OMI NO2 observations under weak-wind conditions (i.e., < 3 m s-1) are qualitatively better correlated with the surface NOx source strength in comparison to all-wind OMI maps; and therefore we use them to calculate the satellite-observed NO2 burdens of urban areas and compare with NOx emission estimates. The EMG results show that OMI-derived NOx emissions are highly correlated (R > 0.93) with weak-wind OMI NO2 burdens as well as bottom-up NOx emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous, EMG-obtained, effective NO2 lifetimes (~3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO2 chemical lifetimes. In general, isolated urban areas with NOx emission intensities greater than ~ 2 Mg h-1 produce statistically significant weak-wind signals in three-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NOx emissions over all selected US urban areas decreased by 49%, consistent with reductions of 43, 47, 49, and 44% in the total bottom-up NOx emissions, the sum of weak-wind OMI NO2 columns, the total weak-wind OMI NO2 burdens, and the averaged NO2 concentrations, respectively, reflecting the success of NOx control programs for both mobile sources and power plants. The decrease rates of these NOx-related quantities are found to be faster (i.e., -6.8 to -9.3% yr-1) before 2010 and slower (i.e., -3.4 to -4.9% yr-1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NOx emissions, the weak-wind OMI NO2 burdens, and ground-based NO2 measurements; and high correlations are found for all urban areas (median R = 0.8), particularly large ones (R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NOx emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.« less

  10. Reconstruction and Prediction of Variations of Total Ozone and Associated Variations of UV-B Solar Radiation for Subarctic Regions Based of Dendrochronologic Data

    SciTech Connect (OSTI)

    Zuev, V.V.; Bondarenko, S.L.

    2005-03-18

    Variations of dendrochronologic parameters, especially annual ring density, significantly reflect the physiological tree response to systematic variations of solar UV-B radiation, taking place on monthly and longer timescales during growing season. Such variations of UV-B radiation are totally governed by variations of total ozone (TO). Thus, in any dendrochronologic signal, especially for coniferous trees, there is also a recorded response to TO variations, characterizing variations of UV-B radiation. Because a monitoring of global TO distribution is regularly performed since 1979 using TOMS satellite instrumentation, there appears a possibility to reconstruct TO behavior in the past practically at any point of dendrochronologic monitoring network. The reconstruction is performed by the method of linear regression, based on significant correlation of annual ring density of coniferous trees and TO for coordinates of denrochronologic signal. The present report considers the Subarctic latitudes, which are characterized by considerable TO variations in the second half of twentieth century.

  11. Risk Level Based Management System: a control banding model for occupational health and safety risk management in a highly regulated environment

    SciTech Connect (OSTI)

    Zalk, D; Kamerzell, R; Paik, S; Kapp, J; Harrington, D; Swuste, P

    2009-05-27

    The Risk Level Based Management System (RLBMS) is an occupational risk management (ORM) model that focuses occupational safety, hygeiene, and health (OSHH) resources on the highest risk procedures at work. This article demonstrates the model's simplicity through an implementation within a heavily regulated research institution. The model utilizes control banding strategies with a stratification of four risk levels (RLs) for many commonly performed maintenance and support activities, characterizing risk consistently for comparable tasks. RLBMS creates an auditable tracking of activities, maximizes OSHH professional field time, and standardizes documentation and control commensurate to a given task's RL. Validation of RLs and their exposure control effectiveness is collected in a traditional quantitative collection regime for regulatory auditing. However, qualitative risk assessment methods are also used within this validation process. Participatory approaches are used throughout the RLBMS process. Workers are involved in all phases of building, maintaining, and improving this model. This work participation also improves the implementation of established controls.

  12. Management and Administration of Radiation Protection Programs Guide for Use with Title 10, Code of Federal Regulations, Part 835, Occupational Radiation Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-03-17

    This Guide discusses acceptable methods for ensuring that radiological activities will be managed and administered in accordance with a documented radiation protection program (RPP) that complies with U.S. Department of Energy (DOE) requirements specified in Title 10 of the Code of Federal Regulations (CFR), Part 835, Occupational Radiation Protection (DOE 1998a), hereinafter referred to as 10 CFR 835. Canceled by DOE G 441.1-1A.

  13. Evaluation of P-101 course ``Orientation to Occupational Safety Compliance in DOE`` taught in Richland, Washington, June 16--June 26, 1992

    SciTech Connect (OSTI)

    Colley, D.L.

    1993-03-01

    This report summarizes trainee evaluations for the Safety Training Section course, ``Orientation to Occupational Safety in DOE``, (P-101) which was conducted June 16 to 26, 1992 at Hanford, in Richland, Washington. Sections 1.1 and 1.2 of this report summarize the quantitative course evaluations that trainees provided upon completion of the course. Appendix A provides a transcript of the trainees` written comments.

  14. Evaluation of P-101 course Orientation to Occupational Safety Compliance in DOE'' taught in Richland, Washington, June 16--June 26, 1992

    SciTech Connect (OSTI)

    Colley, D.L.

    1993-03-01

    This report summarizes trainee evaluations for the Safety Training Section course, Orientation to Occupational Safety in DOE'', (P-101) which was conducted June 16 to 26, 1992 at Hanford, in Richland, Washington. Sections 1.1 and 1.2 of this report summarize the quantitative course evaluations that trainees provided upon completion of the course. Appendix A provides a transcript of the trainees' written comments.

  15. The Department of Energy`s Rocky Flats Plant: A guide to record series useful for health-related research. Volume VII. Employee occupational exposure and health

    SciTech Connect (OSTI)

    1995-08-01

    This is the seventh in a series of seven volumes which constitute a guide to records of the Rocky Flats Plant useful for conducting health-related research. The primary purpose of Volume VII is to describe record series pertaining to employee occupational exposure and health at the Department of Energy`s (DOE) Rocky Flats Plant, now named the Rocky Flats Environmental Technology Site, near Denver, Colorado. History Associates Incorporated (HAI) prepared this guide as part of its work as the support services contractor for DOE`s Epidemiologic Records Inventory Project. This introduction briefly describes the Epidemiologic Records Inventory Project and HAI`s role in the project, provides a history of occupational exposure monitoring and health practices at Rocky Flats, and identifies organizations contributing to occupational exposure monitoring and health policies and activities. Other topics include the scope and arrangement of the guide and the organization to contact for access to these records. Comprehensive introductory and background information is available in Volume 1. Other volumes in the guide pertain to administrative and general subjects, facilities and equipment, production and materials handling, environmental and workplace monitoring, and waste management. In addition, HAI has produced a subject-specific guide, titled The September 1957 Rocky Flats Fire: A Guide to Record Series of the Department of Energy and Its Contractors, which researchers should consult for further information about records related to this incident.

  16. Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005-2014

    SciTech Connect (OSTI)

    Lu, Z.; Streets, D. G.; de Foy, B.; Lamsal, L. N.; Duncan, B. N.; Xing, J.

    2015-05-28

    Satellite remote sensing of tropospheric nitrogen dioxide (NO2) can provide valuable information for estimating surface nitrogen oxides (NOx) emissions. Using an exponentially-modified Gaussian (EMG) method and taking into account the effect of wind on observed NO2 distributions, we estimate three-year moving-average emissions of summertime NOx from 35 US urban areas directly from NO2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following the conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NOx emissions from each urban area by applying the EMG method to OMI data with wind speeds greater than 3–5 m s-1. Meanwhile, we find that OMI NO2 observations under weak-wind conditions (i.e., < 3 m s-1) are qualitatively better correlated with the surface NOx source strength in comparison to all-wind OMI maps; and therefore we use them to calculate the satellite-observed NO2 burdens of urban areas and compare with NOx emission estimates. The EMG results show that OMI-derived NOx emissions are highly correlated (R > 0.93) with weak-wind OMI NO2 burdens as well as bottom-up NOx emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous, EMG-obtained, effective NO2 lifetimes (~3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO2 chemical lifetimes. In general, isolated urban areas with NOx emission intensities greater than ~ 2 Mg h-1 produce statistically significant weak-wind signals in three-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NOx emissions over all selected US urban areas decreased by 49%, consistent with reductions of 43, 47, 49, and 44% in the total bottom-up NOx emissions, the sum of weak-wind OMI NO2 columns, the total weak-wind OMI NO2 burdens, and the averaged NO2 concentrations, respectively, reflecting the success of NOx control programs for both mobile sources and power plants. The decrease rates of these NOx-related quantities are found to be faster (i.e., -6.8 to -9.3% yr-1) before 2010 and slower (i.e., -3.4 to -4.9% yr-1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NOx emissions, the weak-wind OMI NO2 burdens, and ground-based NO2 measurements; and high correlations are found for all urban areas (median R = 0.8), particularly large ones (R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NOx emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.

  17. Occupational radiation exposure at commercial nuclear power reactors and other facilities 1994. Twenty-seventh annual report

    SciTech Connect (OSTI)

    Thomas, M.L.; Hagemeyer, D.

    1996-01-01

    This report summarizes the occupational exposure data that are maintained in the U.S. Nuclear Regulatory Commission`s (NRC) Radiation Exposure Information and Reporting System (REIRS). Annual reports for 1994 were received from a total of 303 NRC licensees, of which 109 were operators of nuclear power reactors in commercial operation. Compilations of the reports submitted by the 303 licensees indicated that 152,028 individuals were monitored, 79,780 of whom received a measurable dose. The collective dose incurred by these individuals was 24,740 person-cSv (person-rem){sup 2} which represents a 15% decrease from the 1993 value. The number of workers receiving a measurable dose also decreased, resulting in the average measurable dose of 0.31 cSv (rem) for 1994. The average measurable dose is defined to be the total collective dose (TEDE) divided by the number of workers receiving a measurable dose. These figures have been adjusted to account for transient reactor workers. In 1994, the annual collective dose per reactor for light water reactor licensees (LWRs) was 198 person-cSv (person-rem). This represents a 18% decrease from the 1993 value of 242 person-cSv (person-rem). The annual collective dose per reactor for boiling water reactors (BWRs) was 327 person-cSv (person-rem) and, for pressurized water reactors (PWRs), it was 131 person-cSv (person-rem). Analyses of transient worker data indicate that 18,178 individuals completed work assignments at two or more licensees during the monitoring year. The dose distributions are adjusted each year to account for the duplicate reporting of transient workers by multiple licensees. In 1994, the average measurable dose calculated from reported data was 0.28 cSv (rem). The corrected dose distribution resulted in an average measurable dose of 0.31 cSv (rem).

  18. A population-based exposure assessment methodology for carbon monoxide: Development of a carbon monoxide passive sampler and occupational dosimeter

    SciTech Connect (OSTI)

    Apte, M.G.

    1997-09-01

    Two devices, an occupational carbon monoxide (CO) dosimeter (LOCD), and an indoor air quality (IAQ) passive sampler were developed for use in population-based CO exposure assessment studies. CO exposure is a serious public health problem in the U.S., causing both morbidity and mortality (lifetime mortality risk approximately 10{sup -4}). Sparse data from population-based CO exposure assessments indicate that approximately 10% of the U.S. population is exposed to CO above the national ambient air quality standard. No CO exposure measurement technology is presently available for affordable population-based CO exposure assessment studies. The LOCD and IAQ Passive Sampler were tested in the laboratory and field. The palladium-molybdenum based CO sensor was designed into a compact diffusion tube sampler that can be worn. Time-weighted-average (TWA) CO exposure of the device is quantified by a simple spectrophotometric measurement. The LOCD and IAQ Passive Sampler were tested over an exposure range of 40 to 700 ppm-hours and 200 to 4200 ppm-hours, respectively. Both devices were capable of measuring precisely (relative standard deviation <20%), with low bias (<10%). The LOCD was screened for interferences by temperature, humidity, and organic and inorganic gases. Temperature effects were small in the range of 10{degrees}C to 30{degrees}C. Humidity effects were low between 20% and 90% RH. Ethylene (200 ppm) caused a positive interference and nitric oxide (50 ppm) caused a negative response without the presence of CO but not with CO.

  19. OSH technical reference manual

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    In an evaluation of the Department of Energy (DOE) Occupational Safety and Health programs for government-owned contractor-operated (GOCO) activities, the Department of Labor`s Occupational Safety and Health Administration (OSHA) recommended a technical information exchange program. The intent was to share written safety and health programs, plans, training manuals, and materials within the entire DOE community. The OSH Technical Reference (OTR) helps support the secretary`s response to the OSHA finding by providing a one-stop resource and referral for technical information that relates to safe operations and practice. It also serves as a technical information exchange tool to reference DOE-wide materials pertinent to specific safety topics and, with some modification, as a training aid. The OTR bridges the gap between general safety documents and very specific requirements documents. It is tailored to the DOE community and incorporates DOE field experience.

  20. A Few Simple Steps for Better Gas Mileage | Department of Energy

    Energy Savers [EERE]

    6 MEISPP Flyer 2016 MEISPP Flyer PDF icon 2016 MEISPP Flyer.pdf More Documents & Publications 2015 Student Employment Brochure

    National Fall Prevention Campaign 2016 National Fall Prevention Campaign March 17, 2016 - 9:07am Addthis 2016 National Fall Prevention Campaign As part of a Fall Prevention event initiated by the Occupational Safety and Health Administration (OSHA), the 3rd Annual National Fall Prevention Campaign will take place on May 2-6. This event is a nationwide voluntary

  1. 2016 Strategic Plan Chief of Nuclear Safety | Department of Energy

    Office of Environmental Management (EM)

    National Fall Prevention Campaign 2016 National Fall Prevention Campaign March 17, 2016 - 9:07am Addthis 2016 National Fall Prevention Campaign As part of a Fall Prevention event initiated by the Occupational Safety and Health Administration (OSHA), the 3rd Annual National Fall Prevention Campaign will take place on May 2-6. This event is a nationwide voluntary effort to remind and educate employers and workers in the construction industry of the serious dangers regarding falls from elevated

  2. Operating Experience Level 3, Fall Protection Can Prevent Serious Injuries

    Broader source: Energy.gov [DOE]

    2015-05: This Operating Experience Level 3 (OE-3) document provides information about a safety concern related to incidents at Department of Energy (DOE) facilities in which fall protection requirements were not followed. According to the Occupational Safety and Health Administration (OSHA), falls from elevations, including into holes in floors, are the leading cause of worker fatalities in the U.S. construction industry.

  3. DOE/RL-92-36, Hanford Site Hoisting and Rigging Manual APPENDIX B, Users Guide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    APPENDIX B, Users Guide November 18, 2014 Rev 1 Page 1 INTRODUCTION This chapter is a user's guide to good practices. Its use and application does not absolve the user of responsibilities to comply with the requirements of this manual and referenced Department of Energy (DOE), Occupational Safety and Health Administration (OSHA), and American Society of Mechanical Engineers (ASME) standards. Permission for the use of The Complete Rigger's Reference Handbook in this manual does not allow

  4. 2016 National Fall Prevention Campaign | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Fall Prevention Campaign 2016 National Fall Prevention Campaign March 17, 2016 - 9:07am Addthis 2016 National Fall Prevention Campaign As part of a Fall Prevention event initiated by the Occupational Safety and Health Administration (OSHA), the 3rd Annual National Fall Prevention Campaign will take place on May 2-6. This event is a nationwide voluntary effort to remind and educate employers and workers in the construction industry of the serious dangers regarding falls from elevated

  5. Fire Protection Related Sites | Department of Energy

    Energy Savers [EERE]

    Related Sites Fire Protection Related Sites DOE-Related Fire Safety Web Sites EFCOG - Fire Protection Working Group Headquarter's Office of Science Brookhaven National Laboratory Hanford Fire Department Non-DOE Government-Related Web Sites Consumer Product Safety Commission (CPSC) Occupational Safety & Health Administration (OSHA) U.S. Nuclear Regulatory Commission (NRC) U.S. Environmental Protection Agency EPA Federal Emergency Management Agency (FEMA) National Fire Academy Other Related

  6. Occupational Safety Performance Trends

    Broader source: Energy.gov [DOE]

    DOE Quarterly TRC and DART Case Rates EM Quarterly TRC and DART Case Rates NNSA Quarterly TRC and DART Case Rates SC Quarterly TRC and DART Case Rates

  7. Council's Occupational Excellence Achievement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... waste-reducing radiological exposure, and improving safety and stormwater compliance. ... The Secondary Pathways Project reduced mercury infiltration into the ground and stormwater ...

  8. HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 EXPO EAT Featured Presentation April InsideOut WorkFit Training Patient Satisfaction Event Calendar Weight Loss Convoy Class--Second Quarter May 17, 2016 Weight Loss Convoy Class--Second Quarter May 24, 2016 Weight Loss Convoy Class--Second Quarter May 31, 2016 Convoy Alumni Meeting June 1, 2016 Site-Wide Health Fairs: PLAY June 2, 2016 Weight Loss Convoy Class--Second Quarter June 7, 2016 News and Information April 18, 2016 Update on Zika Virus from the Centers for Disease Control and

  9. PRELIMINARY EVALUATION OF POTENTIAL OCCUPATIONAL AND PUBLIC HEALTH IMPACTS OF SEDIMENT DECONTAMINATION FACILITIES FOR NEW YORK/NEW JERSEY HARBOR

    SciTech Connect (OSTI)

    ROWE,M.D.; KLEIN,R.C.; JONES,K.W.

    1999-07-31

    Sediment is accumulating in New York/New Jersey Harbor, and shipping channels are rapidly becoming too shallow for large ships. The Port Authority of New York/New Jersey has determined that dredging of the ship channels is essential to keep them navigable. About five million cubic yards of sediment must be removed per year to keep the channels open. Without dredging, the channels will soon become unusable, and the shoreside shipping and warehousing businesses that depend on them will fade away. The economic loss to the area would be devastating. But the deeper layers of sediment in the Harbor contain a broad range of pollutants that are hazardous to humans and the environment-a legacy of past discharges that are no longer permitted. These include heavy metals, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), chlorinated pesticides, and dioxins. As a result, there are several million cubic yards of sediments to be dredged per year that do not meet applicable criteria for ocean disposal and must be dealt with in some other way. A possible solution to the problem is to treat the dredged material to immobilize or destroy the contaminants and make the treated sediments suitable for disposal in the ocean or on land at acceptable cost. A variety of technologies can be used to achieve this goal. The simplest approach is to make manufactured soil from untreated sediment. The most complex approaches involve high-temperature destruction of organic contaminants and immobilization of inorganic contaminants. When any of these technologies are used, there is potential for risks to human health from process wastes and from the treated materials themselves. Also, disposal or beneficial use of treated materials may generate other risks to human health or the environment. A description of some of the technologies considered is given in Table 1. Success in removing or immobilizing the contaminants, which varies significantly among technologies, is reported elsewhere. This report provides a preliminary evaluation, or ``screening assessment,'' of potential occupational, public, and environmental health risks from dredging, transporting, and treating contaminated harbor sediments with thermal treatment methods to render them suitable for disposal or beneficial use. The assessment was done in stages as the project advanced and data became available from other tasks on characteristics of sediments and treatment processes.

  10. Program desk manual for occupational safety and health -- U.S. Department of Energy Richland Operations, Office of Environment Safety and Health

    SciTech Connect (OSTI)

    Musen, L.G.

    1998-08-27

    The format of this manual is designed to make this valuable information easily accessible to the user as well as enjoyable to read. Each chapter contains common information such as Purpose, Scope, Policy and References, as well as information unique to the topic at hand. This manual can also be provided on a CD or Hanford Internet. Major topics include: Organization and program for operational safety; Occupational medicine; Construction and demolition; Material handling and storage; Hoisting and rigging; Explosives; Chemical hazards; Gas cylinders; Electrical; Boiler and pressure vessels; Industrial fire protection; Industrial hygiene; and Safety inspection checklist.

  11. Spatially Resolved Estimation of Ozone-related Mortality in the United States under Two Representative Concentration Pathways (RCPs) and their Uncertainty

    SciTech Connect (OSTI)

    Kim, Young-Min; Zhou, Ying; Gao, Yang; Fu, Joshua S.; Johnson, Brent; Huang, Cheng; Liu, Yang

    2015-01-01

    BACKGROUND: The spatial pattern of the uncertainty in climate air pollution health impact has rarely been studied due to the lack of high-resolution model simulations, especially under the latest Representative Concentration Pathways (RCPs). OBJECTIVES: We estimated county-level ozone (O3) and PM2.5 related excess mortality (EM) and evaluated the associated uncertainties in the continental United States in the 2050s under RCP4.5 and RCP8.5. METHODS: Using dynamically downscaled climate model simulations, we calculated changes in O3 and PM2.5 levels at 12 km resolution between the future (2057-2059) and present (2001-2004) under two RCP scenarios. Using concentration-response relationships in the literature and projected future populations, we estimated EM attributable to the changes in O3 and PM2.5. We finally analyzed the contribution of input variables to the uncertainty in the county-level EM estimation using Monte Carlo simulation. RESULTS: O3-related premature deaths in the continental U.S. were estimated to be 1,082 deaths/year under RCP8.5 (95% confidence interval (CI): -288 to 2,453), and -5,229 deaths/year under RCP4.5 (-7,212 to -3,246). Simulated PM2.5 changes resulted in a significant decrease in EM under the two RCPs. The uncertainty of O3-related EM estimates was mainly caused by RCP scenarios, whereas that of PM2.5-related EMs was mainly from concentration-response functions. CONCLUSION: EM estimates attributable to climate change-induced air pollution change as well as the associated uncertainties vary substantially in space, and so are the most influential input variables. Spatially resolved data is crucial to develop effective mitigation and adaptation policy.

  12. Lead-based paint and lead-containing materials: The impact of recent EPA and OSHA regulations on maintenance and construction

    SciTech Connect (OSTI)

    Staker, R.D.; Scheffius, F.R.

    1998-07-01

    Over the past several years a number of new federal environmental, health, and safety regulations have been established which address various types of lead containing materials such as lead used in solder and lead-based paint. The regulations pertain to the use, removal, disposal, and handling of lead-containing materials during maintenance activities, renovation activities, and new construction. This paper will present a review of these new regulations, the impact on and applicability to maintenance and construction activities, and the risks to human health and environment. Examples will be used to illustrate the concepts discussed. This paper should be of particular interest to electric power senior managers, plant managers, environmental managers, and environmental staff.

  13. A Post-Occupancy Monitored Evaluation of the Dimmable Lighting, Automated Shading, and Underfloor Air Distribution System in The New York Times Building

    SciTech Connect (OSTI)

    Lee, E. S.; Fernandes, L. L.; Coffey, B.; McNeil, A.; Clear, R.; Webster, T.; Bauman, F.; Dickerhoff, D.; Heinzerling, D.; Hoyt, T.

    2013-01-01

    With aggressive goals to reduce national energy use and carbon emissions, the U.S. Department of Energy (DOE) will be looking to exemplary buildings that have already invested in new approaches to achieving the energy performance goals now needed at a national level. The New York Times Building, in New York, New York, incorporates a number of innovative technologies, systems and processes and could become model for widespread replication in new and existing buildings. A year-long monitored study was conducted to verify energy performance, assess occupant comfort and satisfaction with the indoor environment, and evaluate impact on maintenance and operations. Lessons learned were derived from the analysis; these lessons could help identify and shape policy, financial, or supporting strategies to accelerate diffusion in the commercial building market.

  14. The impact of fuel cladding failure events on occupational radiation exposures at nuclear power plants: Case study, PWR (pressurized-water reactor) during an outage

    SciTech Connect (OSTI)

    Moeller, M.P.; Martin, G.F.; Kenoyer, J.L.

    1987-08-01

    This report is the second in a series of case studies designed to evaluate the magnitude of increase in occupational radiation exposures at commercial US nuclear power plants resulting from small incidents or abnormal events. The event evaluated is fuel cladding failure, which can result in elevated primary coolant activity and increased radiation exposure rates within a plant. For this case study, radiation measurements were made at a pressurized-water reactor (PWR) during a maintenance and refueling outage. The PWR had been operating for 22 months with fuel cladding failure characterized as 105 pin-hole leakers, the equivalent of 0.21% failed fuel. Gamma spectroscopy measurements, radiation exposure rate determinations, thermoluminescent dosimeter (TLD) assessments, and air sample analyses were made in the plant's radwaste, pipe penetration, and containment buildings. Based on the data collected, evaluations indicate that the relative contributions of activation products and fission products to the total exposure rates were constant over the duration of the outage. This constancy is due to the significant contribution from the longer-lived isotopes of cesium (a fission product) and cobalt (an activation product). For this reason, fuel cladding failure events remain as significant to occupational radiation exposure during an outage as during routine operations. As documented in the previous case study (NUREG/CR-4485 Vol. 1), fuel cladding failure events increased radiation exposure rates an estimated 540% at some locations of the plant during routine operations. Consequently, such events can result in significantly greater radiation exposure rates in many areas of the plant during the maintenance and refueling outages than would have been present under normal fuel conditions.

  15. Determinants of residential electricity consumption: Using smart meter data to examine the effect of climate, building characteristics, appliance stock, and occupants' behavior

    SciTech Connect (OSTI)

    Kavousian, A; Rajagopal, R; Fischer, M

    2013-06-15

    We propose a method to examine structural and behavioral determinants of residential electricity consumption, by developing separate models for daily maximum (peak) and minimum (idle) consumption. We apply our method on a data set of 1628 households' electricity consumption. The results show that weather, location and floor area are among the most important determinants of residential electricity consumption. In addition to these variables, number of refrigerators and entertainment devices (e.g., VCRs) are among the most important determinants of daily minimum consumption, while number of occupants and high-consumption appliances such as electric water heaters are the most significant determinants of daily maximum consumption. Installing double-pane windows and energy-efficient lights helped to reduce consumption, as did the energy-conscious use of electric heater. Acknowledging climate change as a motivation to save energy showed correlation with lower electricity consumption. Households with individuals over 55 or between 19 and 35 years old recorded lower electricity consumption, while pet owners showed higher consumption. Contrary to some previous studies, we observed no significant correlation between electricity consumption and income level, home ownership, or building age. Some otherwise energy-efficient features such as energy-efficient appliances, programmable thermostats, and insulation were correlated with slight increase in electricity consumption. (C) 2013 Elsevier Ltd. All rights reserved.

  16. Measured Performance and Analysis of Ground Source Heat Pumps for Space Conditioning and for Water Heating in a Low-Energy Test House Operated under Simulated Occupancy Conditions

    SciTech Connect (OSTI)

    Ally, Moonis Raza [ORNL] [ORNL; Munk, Jeffrey D [ORNL] [ORNL; Baxter, Van D [ORNL] [ORNL; Gehl, Anthony C [ORNL] [ORNL

    2012-01-01

    In this paper we present measured performance and efficiency metrics of Ground Source Heat Pumps (GSHPs) for space conditioning and for water heating connected to a horizontal ground heat exchanger (GHX) loop. The units were installed in a 345m2 (3700ft2) high-efficiency test house built with structural insulated panels (SIPs), operated under simulated occupancy conditions, and located in Oak Ridge, Tennessee (USA) in US Climate Zone 4 . The paper describes distinctive features of the building envelope, ground loop, and equipment, and provides detailed monthly performance of the GSHP system. Space conditioning needs of the house were completely satisfied by a nominal 2-ton (7.0 kW) water-to-air GSHP (WA-GSHP) unit with almost no auxiliary heat usage. Recommendations for further improvement through engineering design changes are identified. The comprehensive set of data and analyses demonstrate the feasibility and practicality of GSHPs in residential applications and their potential to help achieve source energy and greenhouse gas emission reduction targets set under the IECC 2012 Standard.

  17. Data, exergy, and energy analysis of a vertical-bore, ground-source heat pump to for domestic water heating under simulated occupancy conditions

    SciTech Connect (OSTI)

    Ally, Moonis Raza; Munk, Jeffrey D.; Baxter, Van D.; Gehl, Anthony C.

    2015-05-27

    Evidence is provided to support the view that greater than two-thirds of energy required to produce domestic hot water may be extracted from the ground which serves as renewable energy resource. The case refers to a 345 m2 research house located in Oak Ridge, Tennessee, 36.01 N 84.26 W in a mixed-humid climate with HDD of 2218 C-days (3993 F-days) and CDD of 723 C-days (1301 F-days). The house is operated under simulated occupancy conditions in which the hot water use protocol is based on the Building America Research Benchmark Definition (Hendron 2008; Hendron and Engebrecht 2010) which captures the water consumption lifestyles of the average family in the United States. The 5.275 (1.5-ton) water-to-water ground source heat pump (WW-GSHP) shared the same vertical bore with a 7.56 KW water-to-air ground source heat pump for space conditioning the same house. Energy and exergy analysis of data collected continuously over a twelve month period provide performance metrics and sources of inherent systemic inefficiencies. Data and analyses are vital to better understand how WW-GSHPs may be further improved to enable the ground to be used as a renewable energy resource.

  18. Data, exergy, and energy analysis of a vertical-bore, ground-source heat pump to for domestic water heating under simulated occupancy conditions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ally, Moonis Raza; Munk, Jeffrey D.; Baxter, Van D.; Gehl, Anthony C.

    2015-05-27

    Evidence is provided to support the view that greater than two-thirds of energy required to produce domestic hot water may be extracted from the ground which serves as renewable energy resource. The case refers to a 345 m2 research house located in Oak Ridge, Tennessee, 36.01 N 84.26 W in a mixed-humid climate with HDD of 2218 C-days (3993 F-days) and CDD of 723 C-days (1301 F-days). The house is operated under simulated occupancy conditions in which the hot water use protocol is based on the Building America Research Benchmark Definition (Hendron 2008; Hendron and Engebrecht 2010) which captures themore » water consumption lifestyles of the average family in the United States. The 5.275 (1.5-ton) water-to-water ground source heat pump (WW-GSHP) shared the same vertical bore with a 7.56 KW water-to-air ground source heat pump for space conditioning the same house. Energy and exergy analysis of data collected continuously over a twelve month period provide performance metrics and sources of inherent systemic inefficiencies. Data and analyses are vital to better understand how WW-GSHPs may be further improved to enable the ground to be used as a renewable energy resource.« less

  19. Risk Factors in Heating, Ventilating, and Air-Conditioning Systemsfor Occupant Symptoms in U.S. Office Buildings: the EPA BASE Study

    SciTech Connect (OSTI)

    Mendell, M.J.; Lei-Gomez, Q.; Mirer, A.; Seppanen, O.; Brunner, G.

    2006-10-01

    Nonspecific building-related symptoms among occupants of modern office buildings worldwide are common and may be associated with important reductions in work performance, but their etiology remains uncertain. Characteristics of heating, ventilating, and air-conditioning (HVAC) systems in office buildings that increase risk of indoor contaminants or reduce effectiveness of ventilation may cause adverse exposures and subsequent increase in these symptoms among occupants. We analyzed data collected by the U.S. EPA from a representative sample of 100 large U.S. office buildings--the Building Assessment and Survey Evaluation (BASE) study--using multivariate logistic regression models with generalized estimating equations adjusted for potential personal and building confounders. We estimated odds ratios (ORs) and 95% confidence intervals (CIs) for associations between seven building-related symptom outcomes and selected HVAC system characteristics. Among factors of HVAC design or configuration: Outdoor air intakes less than 60 m above the ground were associated with approximately doubled odds of most symptoms assessed. Sealed (non-operable) windows were associated with increases in skin and eye symptoms (ORs= 1.9, 1.3, respectively). Outdoor air intake without an intake fan was associated with an increase in eye symptoms (OR=1.7). Local cooling coils were associated with increased headache (OR=1.5). Among factors of HVAC condition, maintenance, or operation: the presence of humidification systems in good condition was associated with an increase in headache (OR=1.4), whereas the presence of humidification systems in poor condition was associated with increases in fatigue/difficulty concentrating, as well as upper respiratory symptoms (ORs=1.8, 1.5). No regularly scheduled inspections for HVAC components was associated with increased eye symptoms, cough and upper respiratory symptoms (ORs=2.2, 1.6, 1.5). Less frequent cleaning of cooling coils or drip pans was associated with increased headache (OR=1.6). Fair or poor condition of duct liner was associated with increased upper respiratory symptoms (OR=1.4). Most of the many potential risk factors assessed here had not been investigated previously, and associations found with single symptoms may have been by chance, including several associations that were the reverse of expected. Risk factors newly identified in these analyses that deserve attention include outdoor air intakes less than 60 m above the ground, lack of operable windows, poorly maintained humidification systems, and lack of scheduled inspection for HVAC systems. Infrequent cleaning of cooling coils and drain pans were associated with increases in several symptoms in these as well as prior analyses of BASE data. Replication of these findings is needed, using more objective measurements of both exposure and health response. Confirmation of the specific HVAC factors responsible for increased symptoms in buildings, and development of prevention strategies could have major public health and economic benefits worldwide.

  20. Contaminants in Buildings and Occupied Spaces as Risk Factors forOccupant Symptoms in U.S. Office Buildings: Findings from the U.S. EPABASE Study

    SciTech Connect (OSTI)

    Mendell, M.J.; Mirer, A.; Lei-Gomez, Q.

    2007-08-01

    Nonspecific building-related symptoms among occupants of modern office buildings worldwide are common and may be associated with important reductions in work performance, but their etiology remains uncertain. Most reported research into environmental risk factors for these symptoms has focused on ventilation system-related factors, dampness, and particle removal through filtration and cleaning, with relatively few studies of other potential sources of indoor contaminants. We analyzed data collected by the U.S. Environmental Protection Agency (EPA) from a representative sample of 100 large U.S. office buildings--the Building Assessment and Survey Evaluation (BASE) study--using multivariate-adjusted logistic regression models with generalized estimating equations. We estimated odds ratios (ORs) and 95% confidence intervals (CIs) for associations between seven building-related symptom outcomes and a diverse set of potential indoor and outdoor sources for indoor pollutants. Although most of the investigated risk factors showed no apparent association with building-related symptoms, some interesting associations resulted. Increased prevalence of symptoms was associated with carpets older than one year (lower respiratory symptoms), non-carpeted floors (upper and lower respiratory symptoms), older furniture (eye and skin symptoms), infrequent vacuuming (upper respiratory, eye, and skin symptoms and headache), and masonry exterior walls (cough, eye symptoms, and fatigue/concentration difficulty). For the many potential risk factors assessed, almost none had been investigated previously, and many associations found here may have been by chance. Additional confirmatory research focused on risk factors initially identified here is needed, using more objective measures of health outcomes and risk factors or exposures.

  1. Association of genetic polymorphisms in GADD45A, MDM2, and p14{sup ARF} with the risk of chronic benzene poisoning in a Chinese occupational population

    SciTech Connect (OSTI)

    Sun Pin; Zhang Zhongbin; Wan Junxiang; Zhao Naiqing; Jin Xipeng; Xia Zhaolin

    2009-10-01

    Benzene reactive metabolites can lead to DNA damage and trigger the p53-dependent defense responses to maintain genomic stability. We hypothesized that the p53-dependent genes may play a role in the development of chronic benzene poisoning (CBP). In a case-control study of 303 patients with benzene poisoning and 295 workers occupationally exposed to benzene in south China, we investigated associations between the risk of CBP and polymorphisms in three p53-dependent genes. Potential interactions of these polymorphisms with lifestyle factors were also explored. We found p14{sup ARF} rs3731245 polymorphism was associated with risk of CBP (P = 0.014). Compared with those carrying the GG genotype, individuals carrying p14{sup ARF} rs3731245 GA+AA genotypes had a reduced risk of CBP ([adjusted odds ratio (OR{sub adj}) = 0.57, 95%CI = 0.36-0.89]. Further analysis showed p14{sup ARF} TGA/TAG diplotype was associated with an increased risk of CBP (P = 0.0006), whereas p14{sup ARF} TGG/TAA diplotype was associated with a decreased risk of CBP (P = 0.0000001). In addition, we found individuals carrying both MDM2 Del1518 WW genotype and p14{sup ARF} rs3731245 GA+AA genotypes had a lower risk of CBP (OR{sub adj} = 0.25; 95%CI = 0.10-0.62; P = 0.003). Although these results require confirmation and extension, our findings suggest that genetic polymorphisms in p14{sup ARF} may have an impact on the risk of CBP in the study population.

  2. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=Li–Cs;B=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, C.  M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer themore » B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.« less

  3. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=Li–Cs;B=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, C.  M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer themore »B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.« less

  4. A review of the accidental release analysis procedure for the Clean Air Act Section 112(r)

    SciTech Connect (OSTI)

    Sung, H.M.; Liles, R. [Trinity Consultants, Inc., Dallas, TX (United States)

    1995-12-31

    As a result of the 1990 Clean Air Act Amendment, the US Environmental Protection Agency (EPA) is in the process of developing a chemical accident prevention program, which is covered under Section 112(r)(7). The EPA finalized the threshold quantities for the compounds listed in the 112(r)(7)(A) in January 1994. The proposed risk management program (RMP), 112(r)(7)(B), received over 1,000 comments from industries and the general public. The RMP rule proposed by the EPA is fundamentally based on the Process Safety Management (PSM) standard implemented by the Occupational Safety Health Administration (OSHA). The PSM was promulgated in May 1992. Many of the facilities subject to the OSHA PSM standard have developed certain programs to comply with the rule. The major difference between the EPA RMP and the OSHA PSM is the off-site hazard risk assessment (consequence analysis) required by EPA. As a result of this additional requirement, most of the comments received by the EPA for the proposed RMP rule concern the worst case release scenario defined for the hazard risk assessment, which may have a significant impact on the operations and future planning for all the facilities subject to this rule. This paper reviews major concerns involved in the consequence analysis of accidental releases. Several well-established models are reviewed in terms of their applicability for different release scenarios.

  5. NNSA Occupancy Agreement.pdf

    National Nuclear Security Administration (NNSA)

  6. Video occupant detection and classification

    DOE Patents [OSTI]

    Krumm, John C.

    1999-01-01

    A system for determining when it is not safe to arm a vehicle airbag by storing representations of known situations as observed by a camera at a passenger seat; and comparing a representation of a camera output of the current situation to the stored representations to determine the known situation most closely represented by the current situation. In the preferred embodiment, the stored representations include the presence or absence of a person or infant seat in the front passenger seat of an automobile.

  7. Safety and Occupational Health Manager

    Broader source: Energy.gov [DOE]

    The Office of Science manages fundamental research programs in basic energy sciences, biological and environmental sciences, and computational science. In addition, the Office of Science is the...

  8. Beryllium - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (HRP) Industrial Rehabilitation & Ergonomics Infection Control & Immunizations Influenza Immunization Program Medical Exam Scheduling Medical Exams Return to Work Risk...

  9. Environmental, safety, and health engineering

    SciTech Connect (OSTI)

    Woodside, G.; Kocurek, D.

    1997-12-31

    A complete guide to environmental, safety, and health engineering, including an overview of EPA and OSHA regulations; principles of environmental engineering, including pollution prevention, waste and wastewater treatment and disposal, environmental statistics, air emissions and abatement engineering, and hazardous waste storage and containment; principles of safety engineering, including safety management, equipment safety, fire and life safety, process and system safety, confined space safety, and construction safety; and principles of industrial hygiene/occupational health engineering including chemical hazard assessment, personal protective equipment, industrial ventilation, ionizing and nonionizing radiation, noise, and ergonomics.

  10. Microsoft Word - 2050p.dot

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    50-P (3-2008) Supersedes (3-2006) issue UCI (WHEN COMPLETED) UCI (WHEN COMPLETED) 1 Sandia National Laboratories REPORT OF OCCUPATIONAL INJURY/ILLNESS (Based on the OSHA definitions and requirements which may or may not be consistent with various state compensation laws) NOTICE OF INCIDENT (Pursuant to Chapter 52, NMSA 1978 section 52-1-29) Instructions: All personnel are required to complete pages 1 and 2 of this form (e.g., employees at remote sites, contractors). Page 3 pertains only to

  11. GS-PO-0010-001.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LSU/CAMD Policy Doc. ID: GS-PO-0010-001.doc Forklift Use Date: 2001/01/30 1. Introduction: OHSA regulations state that all forklift operators must be trained. This training should consist of both classroom and hands-on training and should include a test before an individual should be permitted to operate a powered industrial truck. Although Louisiana State University does not fall under the jurisdiction of the Occupational Health and Safety Administration (OSHA), it is the policy of LSU and the

  12. Occupational Radiation Exposure at Commercial Nuclear Power Reactors and Other Facilities 2010, Prepared for the Nuclear Regulatory Commission, Office of Nuclear Regulatory Research, May 2012

    SciTech Connect (OSTI)

    D. E. Lewis D. A. Hagemeyer Y. U. McCormick

    2012-07-07

    This report summarizes the occupational exposure data that are maintained in the U.S. Nuclear Regulatory Commission’s (NRC) Radiation Exposure Information and Reporting System (REIRS). The bulk of the information contained in the report was compiled from the 2010 annual reports submitted by five of the seven categories of NRC licensees subject to the reporting requirements of 10 CFR 20.2206. Because there are no geologic repositories for high-level waste currently licensed and no NRC-licensed low-level waste disposal facilities currently in operation, only five categories will be considered in this report. The annual reports submitted by these licensees consist of radiation exposure records for each monitored individual. These records are analyzed for trends and presented in this report in terms of collective dose and the distribution of dose among the monitored individuals. Annual reports for 2010 were received from a total of 190 NRC licensees. The summation of reports submitted by the 190 licensees indicated that 192,424 individuals were monitored, 81,961 of whom received a measurable dose. When adjusted for transient workers who worked at more than one licensee during the year, there were actually 142,471 monitored individuals and 62,782 who received a measurable dose. The collective dose incurred by these individuals was 10,617 person-rem, which represents a 12% decrease from the 2009 value. This decrease was primarily due to the decrease in collective dose at commercial nuclear power reactors, as well as a decrease in the collective dose for most of the other categories of NRC licensees. The number of individuals receiving a measurable dose also decreased, resulting in an average measurable dose of 0.13 rem for 2010. The average measurable dose is defined as the total effective dose equivalent (TEDE) divided by the number of individuals receiving a measurable dose. In calendar year 2010, the average annual collective dose per reactor for light water reactor (LWR) licensees was 83 person-rem. This represents a 14% decrease from the value reported for 2009 (96 person-rem). The decrease in collective dose for commercial nuclear power reactors was due to an 11% decrease in total outage hours in 2010. During outages, activities involving increased radiation exposure such as refueling and maintenance are performed while the reactor is not in operation. The average annual collective dose per reactor for boiling water reactors (BWRs) was 137 personrem for 35 BWRs, and 55 person-rem for 69 pressurized water reactors (PWRs). Analyses of transient individual data indicate that 29,333 individuals completed work assignments at two or more licensees during the monitoring year. The dose distributions are adjusted each year to account for the duplicate reporting of transient individuals by multiple licensees. The adjustment to account for transient individuals has been specifically noted in footnotes in the figures and tables for commercial nuclear power reactors. In 2010, the average measurable dose per individual for all licensees calculated from reported data was 0.13 rem. Although the average measurable dose per individual from data submitted by licensees was 0.13 rem, a corrected dose distribution resulted in an average measurable dose per individual of 0.17 rem.

  13. Balancing energy conservation and occupant needs in ventilation rate standards for Big Box stores and other commercial buildings in California. Issues related to the ASHRAE 62.1 Indoor Air Quality Procedure

    SciTech Connect (OSTI)

    Mendell, Mark J.; Apte, Mike G.

    2010-10-31

    This report considers the question of whether the California Energy Commission should incorporate the ASHRAE 62.1 ventilation standard into the Title 24 ventilation rate (VR) standards, thus allowing buildings to follow the Indoor Air Quality Procedure. This, in contrast to the current prescriptive standard, allows the option of using ventilation rate as one of several strategies, which might include source reduction and air cleaning, to meet specified targets of indoor air concentrations and occupant acceptability. The research findings reviewed in this report suggest that a revised approach to a ventilation standard for commercial buildings is necessary, because the current prescriptive ASHRAE 62.1 Ventilation Rate Procedure (VRP) apparently does not provide occupants with either sufficiently acceptable or sufficiently healthprotective air quality. One possible solution would be a dramatic increase in the minimum ventilation rates (VRs) prescribed by a VRP. This solution, however, is not feasible for at least three reasons: the current need to reduce energy use rather than increase it further, the problem of polluted outdoor air in many cities, and the apparent limited ability of increasing VRs to reduce all indoor airborne contaminants of concern (per Hodgson (2003)). Any feasible solution is thus likely to include methods of pollutant reduction other than increased outdoor air ventilation; e.g., source reduction or air cleaning. The alternative 62.1 Indoor Air Quality Procedure (IAQP) offers multiple possible benefits in this direction over the VRP, but seems too limited by insufficient specifications and inadequate available data to provide adequate protection for occupants. Ventilation system designers rarely choose to use it, finding it too arbitrary and requiring use of much non-engineering judgment and information that is not readily available. This report suggests strategies to revise the current ASHRAE IAQP to reduce its current limitations. These strategies, however, would make it more complex and more prescriptive, and would require substantial research. One practical intermediate strategy to save energy would be an alternate VRP, allowing VRs lower than currently prescribed, as long as indoor VOC concentrations were no higher than with VRs prescribed under the current VRP. This kind of hybrid, with source reduction and use of air cleaning optional but permitted, could eventually evolve, as data, materials, and air-cleaning technology allowed gradual lowering of allowable concentrations, into a fully developed IAQP. Ultimately, it seems that VR standards must evolve to resemble the IAQP, especially in California, where buildings must achieve zero net energy use within 20 years.

  14. Pacific Northwest Laboratory annual report for 1981 to the DOE Office of the Assistant Secretary for Environmental Protection, Safety and Emergency Preparedness. Part 5. Environmental and occupational protection, assessment, and engineering

    SciTech Connect (OSTI)

    Glass, W.A.

    1982-02-01

    This report describes research in environment, health, and safety conducted during fiscal year 1981. The five parts of the report are oriented to particular segments of the program. Parts 1 to 4 report on research performed for the DOE Office of Health and Environmental Research in the Office of Energy Research. Part 5 reports progress on all research performed for the Office of the Assistant Secretary for Environmental Protection, Safety and Emergency Preparedness. The parts are: Part 1: Biomedical Sciences under Program Manager, H. Drucker; Part 2: Ecological Sciences, under Program Manager, B.E. Vaughan; Part 3: Atmospheric Sciences under Program Manager, C.E. Elderkin; Part 4: Physical Sciences under Program Manager, J.M. Nielsen; and Part 5: Environmental and Occupational Protection, Assessment, and Engineering under Program Managers, D.L. Hessel, S. Marks, and W.A. Glass.

  15. The transition from the open minimum to the ring minimum on the ground state and on the lowest excited state of like symmetry in ozone: A configuration interaction study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Theis, Daniel; Ivanic, Joseph; Windus, Theresa L.; Ruedenberg, Klaus

    2016-03-10

    The metastable ring structure of the ozone 11A1 ground state, which theoretical calculations have shown to exist, has so far eluded experimental detection. An accurate prediction for the energy difference between this isomer and the lower open structure is therefore of interest, as is a prediction for the isomerization barrier between them, which results from interactions between the lowest two 1A1 states. In the present work, valence correlated energies of the 11A1 state and the 21A1 state were calculated at the 11A1 open minimum, the 11A1 ring minimum, the transition state between these two minima, the minimum of the 21A1more » state, and the conical intersection between the two states. The geometries were determined at the full-valence multi-configuration self-consistent-field level. Configuration interaction (CI) expansions up to quadruple excitations were calculated with triple-zeta atomic basis sets. The CI expansions based on eight different reference configuration spaces were explored. To obtain some of the quadruple excitation energies, the method of CorrelationEnergy Extrapolation by Intrinsic Scaling was generalized to the simultaneous extrapolation for two states. This extrapolation method was shown to be very accurate. On the other hand, none of the CI expansions were found to have converged to millihartree (mh) accuracy at the quadruple excitation level. The data suggest that convergence to mh accuracy is probably attained at the sextuple excitation level. On the 11A1 state, the present calculations yield the estimates of (ring minimum—open minimum) ~45–50 mh and (transition state—open minimum) ~85–90 mh. For the (21A1–1A1) excitation energy, the estimate of ~130–170 mh is found at the open minimum and 270–310 mh at the ring minimum. At the transition state, the difference (21A1–1A1) is found to be between 1 and 10 mh. The geometry of the transition state on the 11A1 surface and that of the minimum on the 21A1 surface nearly coincide. More accurate predictions of the energydifferences also require CI expansions to at least sextuple excitations with respect to the valence space. Furthermore, for every wave function considered, the omission of the correlations of the 2s oxygen orbitals, which is a widely used approximation, was found to cause errors of about ±10 mh with respect to the energy differences.« less

  16. Ozone response relationships in healthy nonsmokers

    SciTech Connect (OSTI)

    Kulle, T.J.; Sauder, L.R.; Hebel, J.R.; Chatham, M.D.

    1985-07-01

    Significant concentration responses were observed in FVC, FEV1, FEF25-75, SGaw, IC, and TLC in 20 healthy, nonsmoking volunteers exposed randomly to 0.00, 0.10, 0.15, 0.20, and 0.25 ppm O/sub 3/. In addition, significant response changes for FVC, FEV1, and FEF25-75 were shown with time over the 2-h exposure. Intermittent, heavy exercise (VE, 68 L/min) lasting 14 min was employed every 30 min during exposure. Inspection of the concentration and time response curves suggests that the threshold for the group response is at or below 0.15 ppm O/sub 3/. Six subjects experienced decreases greater than 5% in FEV1 or greater than 15% in SGaw at 0.15 ppm. This concentration is only slightly higher than the 1-h O/sub 3/ National Ambient Air Quality Standard. A dose-related response was also seen for cough, nose and throat irritation, and chest discomfort. The work load, length of exposure, and individual sensitivity must be considered for establishing a safe O/sub 3/ exposure level.

  17. Ozone-response relationships in healthy nonsmokers

    SciTech Connect (OSTI)

    Kulle, T.J.; Sauder, L.R.; Hebel, J.R.; Chatham, M.D.

    1985-01-01

    Significant concentration responses were observed in FVC1 FEV1, FEF 25-75, SGaw, IC, and TLC in 20 healthy, nonsmoking volunteers exposed randomly to 0.00, 0.10, 0.15, 0.20, and 0.25 ppm O3. In addition, significant response changes for FVC1 FEV1, FEF25-75 were shown with time over the 2-h exposure. Intermittent, heavy exercise (VE1 68L/min) lasting 14 min was employed every 30 min during exposure. Inspection of the concentration and time-response curves suggests that the threshold for the group response is at or below 0.15 ppm O/sub 3/. Six subjects experienced decreases > 5% in SGaw at 0.15 ppm. The concentration is only slightly higher than the 1-h O/sub 3/ National Ambient Air Quality Standard. A dose-related response was also seen for cough, nose and throat irritation, and chest discomfort. The work load, length of exposure, and individual sensitivity must be considered for establishing a safe O/sub 3/ exposure level.

  18. Health hazard evaluation report HETA 85-030-1693, Fruehauf Corporation - Parts Plant, Delphos, Ohio

    SciTech Connect (OSTI)

    Gorman, R.; Ehrenberg, R.; Hunninen, K.

    1986-06-01

    A request was received from union and management at the Fruehauf Corporations Parts Facility in Delphos, Ohio to evaluate possible exposures to total welding fume, metals, carbon-monoxide, oxides of nitrogen, and ozone during welding operations. Total welding fume concentrations in 32 personal breathing zone samples ranged from 1.5 to 23.4 milligrams per cubic meter (mg/m/sup 3/). Nine area samples ranged from 0.4 to 3.7mg/m/sup 3/. Three sample results exceeded OSHA standard of 15mg/m/sup 3/. Iron was the predominant metal found. Measurable quantities of aluminum, chromium, copper, magnesium, manganese, molybdenum, nickel, lead, tin, and vanadium were found. Results of a questionnaire, given to 33 of the 92 welders, indicated a relatively high prevalence of reported symptoms of mucous membrane and respiratory tract irritation, including eye irritation, sinus/nasal congestion, headaches, throat irritation and cough.

  19. Example process hazard analysis of a Department of Energy water chlorination process

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    On February 24, 1992, the Occupational Safety and Health Administration (OSHA) released a revised version of Section 29 Code of Federal Regulations CFR Part 1910 that added Section 1910.119, entitled ``Process Safety Management of Highly Hazardous Chemicals`` (the PSM Rule). Because US Department of Energy (DOE) Orders 5480.4 and 5483.1A prescribe OSHA 29 CFR 1910 as a standard in DOE, the PSM Rule is mandatory in the DOE complex. A major element in the PSM Rule is the process hazard analysis (PrHA), which is required for all chemical processes covered by the PSM Rule. The PrHA element of the PSM Rule requires the selection and application of appropriate hazard analysis methods to systematically identify hazards and potential accident scenarios associated with processes involving highly hazardous chemicals (HHCs). The analysis in this report is an example PrHA performed to meet the requirements of the PSM Rule. The PrHA method used in this example is the hazard and operability (HAZOP) study, and the process studied is the new Hanford 300-Area Water Treatment Facility chlorination process, which is currently in the design stage. The HAZOP study was conducted on May 18--21, 1993, by a team from the Westinghouse Hanford Company (WHC), Battelle-Columbus, the DOE, and Pacific Northwest Laboratory (PNL). The chlorination process was chosen as the example process because it is common to many DOE sites, and because quantities of chlorine at those sites generally exceed the OSHA threshold quantities (TQs).

  20. Revised analyses of decommissioning for the reference pressurized Water Reactor Power Station. Volume 2, Effects of current regulatory and other considerations on the financial assurance requirements of the decommissioning rule and on estimates of occupational radiation exposure: Appendices, Final report

    SciTech Connect (OSTI)

    Konzek, G.J.; Smith, R.I.; Bierschbach, M.C.; McDuffie, P.N.

    1995-11-01

    With the issuance of the final Decommissioning Rule (July 27, 1998), owners and operators of licensed nuclear power plants are required to prepare, and submit to the US Nuclear Regulatory Commission (NRC) for review, decommissioning plans and cost estimates. The NRC staff is in need of bases documentation that will assist them in assessing the adequacy of the licensee submittals, from the viewpoint of both the planned actions, including occupational radiation exposure, and the probable costs. The purpose of this reevaluation study is to provide some of the needed bases documentation. This report contains the results of a review and reevaluation of the 1978 PNL decommissioning study of the Trojan nuclear power plant (NUREG/CR-0130), including all identifiable factors and cost assumptions which contribute significantly to the total cost of decommissioning the nuclear power plant for the DECON, SAFSTOR, and ENTOMB decommissioning alternatives. These alternatives now include an initial 5--7 year period during which time the spent fuel is stored in the spent fuel pool, prior to beginning major disassembly or extended safe storage of the plant. Included for information (but not presently part of the license termination cost) is an estimate of the cost to demolish the decontaminated and clean structures on the site and to restore the site to a ``green field`` condition. This report also includes consideration of the NRC requirement that decontamination and decommissioning activities leading to termination of the nuclear license be completed within 60 years of final reactor shutdown, consideration of packaging and disposal requirements for materials whose radionuclide concentrations exceed the limits for Class C low-level waste (i.e., Greater-Than-Class C), and reflects 1993 costs for labor, materials, transport, and disposal activities.