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Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

2

Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ambient Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts DOE's Studies of WeekdayWeekend Ozone Pollution in Southern...

3

E-Print Network 3.0 - air pollutants ozone Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

1 Global Ozone Project Ozone Formation in Summary: , power plants and industry all emit air pollution that forms ground-level ozone. Ozone is a primary... Stratospheric and...

4

MICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air  

E-Print Network (OSTI)

from Waters Associates. Water used was deionized, distilled, and hydrocarbon filtered (BarnsteadMICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air to extract polycyclic aromatic hydrocarbons (PAH) from air particulate sampleswas investigated. High

Canberra, University of

5

Geophysics: Ancient Air, Ozone, and Faults  

Science Journals Connector (OSTI)

...col-leagues at he Jet Propulsion Laboratory showing that the postulated reactions do occur under Antarctic stratospheric di-iions. Whether similar reactions accelerate ozone destruion under conditions more typial of the rest of the stratosphere re-mains...

RICHARD A. KERR

1988-01-08T23:59:59.000Z

6

Proceedings: Indoor Air 2005 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON  

E-Print Network (OSTI)

Proceedings: Indoor Air 2005 2118 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON PRIMARY of reactions of ozone on building products and on their emissions in indoor air. For this purpose, 12 building products were exposed to ozone in a dedicated experimental setup. The measured ozone removal rate

Paris-Sud XI, Université de

7

Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

8

Ensemble-based air quality forecasts: A multimodel approach applied to ozone  

E-Print Network (OSTI)

Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1., and B. Sportisse (2006), Ensemble-based air quality forecasts: A multimodel approach applied to ozone, J, the uncertainty in chem- istry transport models is a major limitation of air quality forecasting. The source

Boyer, Edmond

9

Massive global ozone loss predicted following regional nuclear conflict  

Science Journals Connector (OSTI)

...particles, which in turn heat the ambient air, causing...Heterogeneous reaction of ozone with hydrocarbon flame soot . Phys Chem Chem Phys...and nonreactive uptake on hydrocarbon soot: HNO 3 , O 3 , and N 2...the reaction of ozone with combustion soot: Implications for reactivity...

Michael J. Mills; Owen B. Toon; Richard P. Turco; Douglas E. Kinnison; Rolando R. Garcia

2008-01-01T23:59:59.000Z

10

Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2  

E-Print Network (OSTI)

1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 and Chemistry EAS 6790 Fall 2006 Home Work Assignment No. 4, Ozone Chemistry Problems 11.8 and 11.9 (sub-part 1 and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

Weber, Rodney

11

Concentration of ozone in surface air over greater Boston  

E-Print Network (OSTI)

Surface ozone concentrations were measured in the Greater Boston area from November, 1964 to December, 1965. Ozone was monitored continuosly using a Mast microcoulombmetric sensor. A chromium trioxide filter was fitted to ...

Widen, Donald Allen

1966-01-01T23:59:59.000Z

12

A Laboratory Method For Measuring The Ozone Emission From In-duct Air Cleaners.  

E-Print Network (OSTI)

: Emission rate, HVAC air cleaners, electrostatic precipitators, coronas, standard test method 1 Introduction and to ozone byproducts. Currently there are standards and regulations that limit ozone emissions from portable cleaners (i.e., Viner et al., 1992), are generally exempt from standards and regulations because

Siegel, Jeffrey

13

Evaluating the Vertical Distribution of Ozone and Its Relationship to Pollution Events in Air Quality Models Using Satellite Data  

Science Journals Connector (OSTI)

Most regional scale models that are used for air quality forecasts and ozone source attribution do not adequately capture the distribution of ozone in the mid- and upper troposphere, but it is unclear how this...

Jessica L. Neu; Gregory Osterman…

2014-01-01T23:59:59.000Z

14

Ozonized water generator based on coaxial dielectric-barrier-discharge in air  

Science Journals Connector (OSTI)

A coaxial dielectric-barrier-discharge (DBD) as an ozonized water reactor system has been developed and described. It operates in the air at an atmospheric pressure. In the reactor one of the dielectric layers is flowing water. Ozone and ozonized water are generated in the same volume of the discharge. The ozone production and its dissolution in the water simultaneously occur leading to increases of the reactor efficiency. Filamentary 50 Hz DBD has been performed using up to 20 kV applied voltage. The obtained ozone concentrations correspond to the values typically suggested for the treatment of potable and wastewater. The efficiency can be further increased by addition of small amount of the oxygen in the DBD device. The periodical time dependence of the dissolved ozone concentration in Danube water is found and discussed.

Milorad M. Kuraica; Bratislav M. Obradovi?; Dragan Manojlovi?; Daliborka R. Ostoji?; Jagoš Puri?

2004-01-01T23:59:59.000Z

15

The impact of large scale biomass production on ozone air pollution in Joost B. Beltman a  

E-Print Network (OSTI)

The impact of large scale biomass production on ozone air pollution in Europe Joost B. Beltman a , Carlijn Hendriks a , Markus Tum b , Martijn Schaap a,* a TNO, Department of Climate, Air by up to 25% and 40%. Air pollution mitigation strategies should consider land use management. a r t i

Utrecht, Universiteit

16

Assessing Ozone and PM2.5 Air Quality Data for use with  

E-Print Network (OSTI)

Assessing Ozone and PM2.5 Air Quality Data for use with Asthma and Cardiovascular Disease Data of different methods of generating air quality data that could be used routinely in an EPHT Network. · The project will help us understand and improve the air quality data needed for a sustainable EPHT network

17

Does an Increase in Air Quality Models' Resolution Bring Surface Ozone Concentrations Closer to Reality?  

E-Print Network (OSTI)

Does an Increase in Air Quality Models' Resolution Bring Surface Ozone Concentrations Closer challenge for small-scale air quality modeling is the assessment of health impact and popu- lation exposure. Introduction A current trend in small-scale air quality modeling is to quantify the health impact of exposure

Menut, Laurent

18

THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING BAYESIAN MODELS  

E-Print Network (OSTI)

; Fast response (O 3 ) gas analyzers are widely used to monitor (O 3 ) concentration in air pollution is becom­ ing increasingly important in air pollution science and boundary layer meteorology. For exampleTHE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING

West, Mike

19

Ozonation of Mutagenic and Carcinogenic Polyaromatic Amines and Polyaromatic Hydrocarbons in Water  

Science Journals Connector (OSTI)

...Amines and Polyaromatic Hydrocarbons in Water 1 1 Supported by a grant...amines and polyaromatic hydrocarbons in water. | The Salmonella-microsome...g., 13 halogenated hydrocarbons were identified in the drinking water of New Orleans (13...

Gary R. Burleson; Michael J. Caulfield; and Morris Pollard

1979-06-01T23:59:59.000Z

20

Paso del Norte pilot border study of ozone precursors and air toxics  

SciTech Connect

A comprehensive monitoring program for ozone precursors and air toxics in the Paso del Norte border area is planned by the U.S. EPA for the Summer of 1996. A pilot study was carried out in October 1995 in the Paso del Norte area (El Paso, Texas, Ciudad Juarez, Chihuahua, and Sunland Park, New Mexico) to test the appropriateness of proposed sampling and analysis methods and to provide preliminary data to be used for planning the Summer 1996 study. Two monitoring sites were selected, one in Ciudad Juarez, and one in the El Paso area. Samples were collected every second day from October 21 to October 31, from 0300 to 0900 hr using stainless steel canisters (for VOC in the C{sub 2}-C{sub 12} range), Tenax-TA solid adsorbent cartridges (for C{sub 8}-C{sub 20} hydrocarbons). DNPH impregnated C{sub 18} Sep-Pack cartridges (for carbonyl compounds) and Teflon impregnated glass fiber filters followed by PUF/YAD/PUF {open_quotes}sandwich{close_quotes} cartridges (for SVOC). This paper discusses the data set obtained from the analyses of these samples. 6 refs., 7 figs.

Zielinska, B.; Sheetz, L.; Harshfield, G. [Desert Research Institute, Reno, NV (United States)] [and others

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Impact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F. Maupetit  

E-Print Network (OSTI)

indoor air quality (IAQ) since they produce secondary pollutants, mainly aldehydes which are known to document the impact on IAQ of outdoor ozone during summer air pollution episodes. For this purpose, a oneImpact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F

Boyer, Edmond

22

One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light  

Science Journals Connector (OSTI)

...nitric acid oxidation method (3). The first step is air oxidation of cyclohexane under high temperatures (125° to 165...Finlayson-Pitts B. J. Pitts J. N. Jr. , Tropospheric air pollution: Ozone, airborne toxics, polycyclic aromatic hydrocarbons...

Kuo Chu Hwang; Arunachalam Sagadevan

2014-12-19T23:59:59.000Z

23

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10 on the Prev'Air  

E-Print Network (OSTI)

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10'Air operational platform. This platform aims at forecasting maps, on a daily basis, for ozone, nitrogen dioxide models, ozone, nitrogen dioxide, particulate matter, threshold exceedance 1. Introduction1 Operational

Mallet, Vivien

24

Variability in surface ozone background over the United States: Implications for air quality policy  

E-Print Network (OSTI)

Variability in surface ozone background over the United States: Implications for air quality policy background over the United States: Implications for air quality policy, J. Geophys. Res., 108(D24), 4787, doi Agency (EPA) accounts for a background O3 level above which risk to human health is assessed. Since

Liu, Hongyu

25

Ozone production by nanoporous dielectric barrier glow discharge in atmospheric pressure air  

SciTech Connect

This study is aimed at demonstrating plasma-chemical ozone production based on low temperature atmospheric pressure glow discharge through nanoporous dielectric barriers. The 20 kHz ac driven discharge is formed in air or oxygen gas flowing in the axial direction of the cylindrical plasma reactor containing four parallel aluminum rods covered with nanoporous alumina films. The discharge utilizing nanoporous dielectric barrier is more uniform and more energy efficient in ozone generation than the discharge through smooth-surface dielectric barriers.

Cho, J. H.; Koo, I. G.; Choi, M. Y.; Lee, W. M. [Department of Chemistry and Division of Energy Systems Research, Ajou University, Suwon 443-749 (Korea, Republic of)

2008-03-10T23:59:59.000Z

26

Fiber Optic Evanescent Field Sensor for Hydrocarbon Monitoring in Air and Water applying UV Absorption  

Science Journals Connector (OSTI)

A fiber optic sensor for the monitoring of organic pollutants in air and water is presented. The UV absorption spectra of hydrocarbon soluble in special polymer fiber claddings are...

Schwotzer, G; Latka, I; Lehmann, H; Willsch, R

27

Interplay of air pollution and asthma immunopathogenesis: A focused review of diesel exhaust and ozone  

Science Journals Connector (OSTI)

Abstract Controlled human exposure experiments with diesel exhaust particles (DEPs) and ozone serve to illustrate the important role pollutants play in modulating both allergic mechanisms and immune responses to affect the immunopathogenesis of airway diseases such as asthma. For DEP, evidence is stronger for the exacerbation of existing asthma rather than for the development of new disease. To the extent that this enhancement occurs, the augmentation of Th2-type immunity seems to be a common element. For ozone, neutrophilic inflammation, altered immune cell phenotype and function and oxidative stress are all marked responses that likely contribute to underlying immune-inflammatory features of asthma. Evidence is also emerging that unique gene signatures and epigenetic control of immune and inflammatory-based genes are playing important roles in the magnitude of the impact ozone is having on respiratory health. Indeed, the interplay between air pollutants such as DEP and ozone and asthma immunopathogenesis is an ongoing concern in terms of understanding how exposure to these agents can lead to worsening of disease. To this end, asthmatics may be pre-disposed to the deleterious effects of pollutants like ozone, having constitutively modified host defense functions and gene signatures. Although this review has utilized DEP and ozone as example pollutants, more research is needed to better understand the interplay between air pollution in general and asthma immumopathogenesis.

Neil E. Alexis; Chris Carlsten

2014-01-01T23:59:59.000Z

28

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons  

E-Print Network (OSTI)

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons NOAA and CIRES here at CU went to the oil spill in an aircraft that was equipped with instruments to measure the air quality. 1/3 of the oil dissolved into the water column (methane completely, benzene and ethane almost completely) Showed

Toohey, Darin W.

29

Ozonation of Mutagenic and Carcinogenic Polyaromatic Amines and Polyaromatic Hydrocarbons in Water  

Science Journals Connector (OSTI)

...Laboratory, Department of Microbiology, University of Notre Dame...Present address: Department of Microbiology, Harvard School of Public...titration method of Saltzman and Gilbert (25). The effective ozone...Saitzman, B. E., and Gilbert, N. lodometric microdetermination...

Gary R. Burleson; Michael J. Caulfield; and Morris Pollard

1979-06-01T23:59:59.000Z

30

Detonation and deflagration characteristics of p-Xylene/gaseous hydrocarbon fuels/air mixtures  

Science Journals Connector (OSTI)

Abstract p-Xylene is an important intermediate for the production of polyethylene terephthalate, it has growing chemical industrial demand based on the statistics in the last few decades. In the process of producing p-Xylene, gaseous hydrocarbon fuels (e.g., H2, C1–C3) are usually involved, which renders p-Xylene highly possible mix with those gaseous hydrocarbon fuels as leaking occurs, this presents fire or explosion/detonation hazard at some specific conditions. To date, very limited data regarding its detonation and deflagration characteristics are available in previous literatures. In this study, experiments of measuring the overpressure and velocity of p-Xylene/gaseous hydrocarbon fuels (i.e., H2, C2H4, C3H8, CO)/air mixtures are carried out in a vertical detonation tube with an inner diameter of 200 mm and a length of 6.5 m to explore the detonation and deflagration characteristics of p-Xylene. The experimental results indicate that under the same initiation energy of 0.189 MJ m?2, pure p-Xylene/air and p-Xylene/CO/air cannot achieve detonation, only deflagrations are observed. However, under this same initiation energy, detonations occur in p-Xylene/H2/air, p-Xylene/C2H4/air and p-Xylene/C3H8/air mixtures. By comparing the combinatorial compositions of p-Xylene along with gaseous hydrocarbon fuels that within which detonation observed, the detonation sensitive of the mixtures in increasing order are obtained as following: p-Xylene/H2/air, p-Xylene/C3H8/air and p-Xylene/C2H4/air. The results also indicate the relative ease that p-Xylene/gaseous hydrocarbon fuel/air can be detonated mainly depends on the detonation sensitive of the gaseous fuel, which is supported by the critical energy of direct detonation initiation and chemical kinetic analysis.

Bo Zhang; Guangli Xiu; Jian Chen; Shaopeng Yang

2015-01-01T23:59:59.000Z

31

Hydrocarbon emissions from industrial release events in the Houston-Galveston area and their impact on ozone formation  

Science Journals Connector (OSTI)

Ambient measurements have shown that ozone formation in the Houston-Galveston area of Texas is frequently much more rapid than in other urban areas. One of the contributing factors is believed to be short-term episodic or “event” emissions from industrial facilities, particularly releases that contain significant mass fractions of highly reactive volatile organic compounds (HRVOCs). In this work, time series analyses are used to compare average annual flow rates for air pollutant emissions with those released during reported emission events. The results indicate that the magnitude and frequency of HRVOC event emissions are an important element in accurately reflecting ozone precursor emission patterns in the Houston-Galveston area, particularly in Harris, Brazoria, Galveston, and Chambers counties. More than 50% of the reported episodic (event) emissions of \\{HRVOCs\\} are ethene and approximately a third are propene; the remainders are isomers of butene and 1,3-butadiene. Most events last less than 24 h. The mass released in an event can vary from a few hundred to more than 100,000 lb, and the dominant type of industrial source is chemical manufacturers (SIC 2869). Daily emissions from a single facility can vary from annual average emissions by multiple orders of magnitude at a frequency of several times a year. Because there are so many facilities in the Houston-Galveston area, HRVOC emission variability of this magnitude can be expected daily, at some time and some location in the Houston-Galveston area. If the emission variability occurs at times and locations where atmospheric conditions are conducive to ozone formation, both ambient data and photochemical modeling indicate that industrial emission events can lead to elevated concentrations of ozone. Specifically, peak, area-wide ozone concentration can be increased by as much as 100 ppb for large HRVOC emission events.

Cynthia Folsom Murphy; David T. Allen

2005-01-01T23:59:59.000Z

32

Effects of particulate air pollution and ozone on lung function in non-asthmatic children  

Science Journals Connector (OSTI)

AbstractIntroduction Information on the long-term effects of different air pollutant levels on lung function is relatively lacking in Asia and still inconclusive in the world. Age differential effects of air pollution are not known. Objectives To assess the acute and subchronic effects of ambient air pollution on lung function and compared among children of different ages. Methods From April to May 2011, a nationwide study was conducted on schoolchildren aged 6–15 years in 44 schools of 24 districts in Taiwan. Spirograms were obtained from 1494 non-asthmatic children. Air pollution data were retrieved from air monitoring stations within one kilometre of the schools. Using three-level hierarchical linear models, individual lung function was fitted to air pollution, with adjustments for demographics, indoor exposures, outdoor activity, and districts. Results Lung function changes per inter-quartile increase of the past two-months average levels of particulate matter <2.5 ?m (PM2.5) and ozone (12 ?g/m3, 32–44 and 6.7 ppb, 32–38, respectively) were ?103 and ?142 ml on FVC, ?86 and ?131 on FEV1, and ?102 and ?188 ml/s on MMEF, respectively. Lag-1-day ozone exposure was associated with decreased MMEF. In children aged 6–10, PM2.5 was associated with decreased FEV1/FVC and MMEF/FVC ratios. Conclusions In children aged 6–15 years, sub-chronic exposure to ambient PM2.5 and ozone leads to reduced lung capacity, whereas acute exposure to ozone decreases mid-expiratory flow. In children aged 6–10 years, additional airway obstructive patterns in lung function may be associated with PM2.5 exposure.

Chi-Hsien Chen; Chang-Chuan Chan; Bing-Yu Chen; Tsun-Jen Cheng; Yue Leon Guo

2015-01-01T23:59:59.000Z

33

Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2  

E-Print Network (OSTI)

1 Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2 3 emissions of ozone precursors. The climate and16 emission effect in combination will increase afternoon mean increases18 in global (excluding China) anthropogenic emissions, 37% to Chinese emission19 increases

Wu, Shiliang

34

Methods for Determination of Hydrocarbons in Air, Soil & Water  

Science Journals Connector (OSTI)

Many environmental investigations often demand a quick indication of the nature and levels of contamination in air, soil and water. A portable GC for on-site monitoring allows the user to fast screen compounds in...

Hans Ole Andersen

1997-01-01T23:59:59.000Z

35

Photochemistry of aromatic hydrocarbons: implications for ozone and secondary organic aerosol formation  

E-Print Network (OSTI)

formation is essential to assess the urban air pollution. This dissertation consists of two parts: (1) theoretical investigation of the toluene oxidation initiated by OH radical using quantum chemical and kinetic calculations to understand the mechanism of O...

Suh, Inseon

2006-08-16T23:59:59.000Z

36

Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.  

SciTech Connect

This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

Whitfield, R. G.

1999-03-04T23:59:59.000Z

37

E-Print Network 3.0 - aromatic hydrocarbons methyl Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Renewable Energy 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

38

E-Print Network 3.0 - aromatic hydrocarbons progress Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Chemistry 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

39

66 USDA Forest Service Gen. Tech. Rep. PSW-GTR-155. 1996. Quality Assurance, Training, and Certification in Ozone Air Pollution Studies Schilling, Miller, and Takemoto  

E-Print Network (OSTI)

, and Certification in Ozone Air Pollution Studies Schilling, Miller, and Takemoto Air Resources Board. 1990 air quality standards--1990 Update. Mailout No. 90­ 68. Mobile Source Division, On­Road­Control data: summary of 1990 air quality data-- gaseous and particulate pollutants. Annual summary. Technical

Standiford, Richard B.

40

A comparison between the use of natural air and air containing ozone in conditioning farm products  

E-Print Network (OSTI)

H3 Ave, Air Volume& Otme 42EOO 52e98 45e 66 46e48 40, 65 56, 64 47, 31 48, 20 43. 65 51, 66 48. 99 48, 10 55. 98 52e98 42 00 50. 32 39EOO 41e31 41e 64 COe 65 39EOO 41, 25 41. 64 40. 63 , tatio Pressures In, H. C. ~ 4...

Wilkes, Lambert Henry

1953-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Air-Quality Data from NARSTO (North American Research Strategy for Tropospheric Ozone)  

DOE Data Explorer (OSTI)

NARSTO is a public/private partnership dedicated to improving management of air quality in North America. It was established on February 13, 1995 when representatives of Canada, the United States, and Mexico signed the NARSTO Charter in a ceremony at the White House. The Department of Energy is one of the charter members providing funding. The central programmatic goal of NARSTO is to provide data and information for use in the determination of workable, efficient, and effective strategies for local and regional ozone and fine particle management. Since its founding, NARSTO has completed three major scientific Assessments of critical air quality management issues. NARSTO maintains the Quality Systems Science Center and the NARSTO Data Archive for storing data from NARSTO Affiliated Research Activities and making these data available to the scientific community. NARSTO also facilitates activities, such as the Reactivity Research Working Group, which provide critical reviews of the state of the science in areas of interest to air quality policy makers. In January 1997, the U.S. Department of Energy's Environmental Sciences Division announced their sponsorship of the NARSTO Quality Systems Science Center (QSSC). The QSSC is located at the Oak Ridge National Laboratory within the Carbon Dioxide Information Analysis Center (CDIAC). Quality Assurance and Data Management assistance and guidelines are provided by the QSCC, along with access to data files. The permanent data archive is maintained by the NASA EOSDIS Distributed Active Archive Center at the Langley Research Center. The archived data can be reached by a link from the QSSC.(Specialized Interface) See also the NARSTO web site at http://www.narsto.org/

42

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries  

SciTech Connect

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti [Technical University of Bari, Bari (Italy). Department of Environmental Engineering and Sustainable Development

2006-03-15T23:59:59.000Z

43

Impact of HVAC filter on indoor air quality in terms of ozone removal and carbonyls generation  

Science Journals Connector (OSTI)

Abstract This study aims at detecting ozone removal rates and corresponding carbonyls generated by ozone reaction with HVAC filters from various building, i.e., shopping mall, school, and office building. Studies were conducted in a small-scale environmental chamber. By examining dust properties including organic carbon proportion and specific surface area of dusts adsorbed on filters along with ozone removal rates and carbonyls generation rate, the relationship among dust properties, ozone removal rates, and carbonyls generation was identified. The results indicate a well-defined positive correlation between ozone removal efficiency and carbonyls generation on filters, as well as a positive correlation among the mass of organic carbon on filters, ozone removal efficiency and carbonyls generations.

Chi-Chi Lin; Hsuan-Yu Chen

2014-01-01T23:59:59.000Z

44

Global warming impacts of ozone-safe refrigerants and refrigeration, heating, and air-conditioning technologies  

SciTech Connect

International agreements mandate the phase-out of many chlorine containing compounds that are used as the working fluid in refrigeration, air-conditioning, and heating equipment. Many of the chemical compounds that have been proposed, and are being used in place of the class of refrigerants eliminated by the Montreal Protocol are now being questioned because of their possible contributions to global warming. Natural refrigerants are put forth as inherently superior to manufactured refrigerants because they have very low or zero global warming potentials (GWPs). Questions are being raised about whether or not these manufactured refrigerants, primarily hydrofluorocarbons (HFCs), should be regulated and perhaps phased out in much the same manner as CFCs and HCFCs. Several of the major applications of refrigerants are examined in this paper and the results of an analysis of their contributions to greenhouse warming are presented. Supermarket refrigeration is shown to be an application where alternative technologies have the potential to reduce emissions of greenhouse gases (GHG) significantly with no clear advantage to either natural or HFC refrigerants. Mixed results are presented for automobile air conditioners with opportunities to reduce GHG emissions dependent on climate and comfort criteria. GHG emissions for hermetic and factory built systems (i.e. household refrigerators/freezers, unitary equipment, chillers) are shown to be dominated by energy use with much greater potential for reduction through efficiency improvements than by selection of refrigerant. The results for refrigerators also illustrate that hydrocarbon and carbon dioxide blown foam insulation have lower overall effects on GHG emissions than HFC blown foams at the cost of increased energy use.

Fischer, S.; Sand, J.; Baxter, V.

1997-12-01T23:59:59.000Z

45

Studying the feedback effects of aerosols on ozone and temperatures in Los Angeles with an Eulerian air pollution model  

SciTech Connect

An Eulerian air pollution model (GATOR/MMTD) was used to study the effects of aerosols on surface solar radiation, surface air temperatures, and ozone mixing ratios. Model results were also compared to data from the Southern California Air Quality Study (SCAQS) period of August 27-29, 1987. Gross errors for sulfate, sodium, light absorption, temperature, surface solar radiation, sulfur dioxide gas, formaldehyde gas, and ozone were lowest among parameters compared (1-40%). Gross errors for elemental carbon, organic carbon, total particulate mass, ammonium, ammonia gas, nitric acid gas, and light scattering, were larger (40-61%). Gross errors for particulate nitrate were largest (65-70%). Doubling of the land-based particulate emissions inventory caused gross errors of total particulate mass and elemental carbon to increase by factors of more than two. Also, setting lateral boundary inflow concentrations of particles to zero caused slight (< 1%) erosion of results for most species, large erosion (10%) for sodium and chloride, but slight improvement (< 1%) for a few species. Spinning up the meteorological model 24 hours in advance caused most gross errors to increase. Finally, model predictions for several parameters, with and without the inclusion of aerosols, were compared to data. The presence of aerosols reduced peak daytime surface solar radiation by approximately 6.4% (55 W m-2), increased night-time temperatures by about 0.77 K, decreased daytime temperatures by about 0.08 K, and increased overall temperatures (day plus night during the two day simulation period) by 0.43 K. The relatively small cooling during the day was due to heat trapping by elemental carbon-containing aerosols. The presence of aerosols also caused ozone mixing ratios to decrease by 2%.

Jacobson, M. [Stanford Univ., CA (United States)

1996-12-31T23:59:59.000Z

46

Hydrocarbon concentrations at the Alpine mountain sites Jungfraujoch and Arosa  

Science Journals Connector (OSTI)

Volatile hydrocarbons have been measured for 1 yr at Arosa (2010 m asl) to determine the contribution of European emissions to the trace gas concentrations at this remote site. Results are compared to concurrent hydrocarbon concentrations at the high Alpine background site Jungfraujoch (3580 m asl). Hydrocarbon concentrations at Arosa are generally much higher than at Jungfraujoch. The influence of the Alpine boundary layer air was studied based on the diurnal variation of hydrocarbon concentrations, i.e. rising pollutant concentrations in the morning at Arosa and in the afternoon at Jungfraujoch. Different hydrocarbon emission sources of the uplifting air were found at the two sites. At Jungfraujoch, several transatlantic events were detected from October 2001 to January 2002 based on analysis of hydrocarbon ratios and air parcel trajectories. The OH concentration during the transatlantic transport was estimated to be around 5×105 cm?3, derived from simultaneous hydrocarbon oxidation and dilution in the free troposphere. These transatlantic transport events were tracked back to warm conveyor belts, characterized by uniform dynamics and relatively uniform surface sources. In addition, ozone production in the free tropospheric transport was also documented in these events.

Yingshi Li; Mike Campana; Stefan Reimann; Daniel Schaub; Konrad Stemmler; Johannes Staehelin; Thomas Peter

2005-01-01T23:59:59.000Z

47

Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air Purifiers  

E-Print Network (OSTI)

of California, Irvine, CA ABSTRACT Indoor air purifiers are advertised as safe household prod- ucts for health. This is a serious concern, because O3 is a criteria air pollutant reg- ulated by health-related federal and state of growing air pollution problems in urban areas, indoor air purification has gained widespread popularity

Nizkorodov, Sergey

48

Exposure information in environmental health research: Current opportunities and future directions for particulate matter, ozone, and toxic air pollutants  

SciTech Connect

Understanding and quantifying outdoor and indoor sources of human exposure are essential but often not adequately addressed in health-effects studies for air pollution. Air pollution epidemiology, risk assessment, health tracking and accountability assessments are examples of health-effects studies that require but often lack adequate exposure information. Recent advances in exposure modeling along with better information on time-activity and exposure factors data provide us with unique opportunities to improve the assignment of exposures for both future and ongoing studies linking air pollution to health impacts. In September 2006, scientists from the US Environmental Protection Agency (EPA) and the Centers for Disease Control and Prevention (CDC) along with scientists from the academic community and state health departments convened a symposium on air pollution exposure and health in order to identify, evaluate, and improve current approaches for linking air pollution exposures to disease. This manuscript presents the key issues, challenges and recommendations identified by the exposure working group, who used cases studies of particulate matter, ozone, and toxic air pollutant exposure to evaluate health-effects for air pollution. One of the over-arching lessons of this workshop is that obtaining better exposure information for these different health-effects studies requires both goal-setting for what is needed and mapping out the transition pathway from current capabilities to meeting these goals. Meeting our long-term goals requires definition of incremental steps that provide useful information for the interim and move us toward our long-term goals. Another over-arching theme among the three different pollutants and the different health study approaches is the need for integration among alternate exposure assessment approaches. For example, different groups may advocate exposure indicators, biomonitoring, mapping methods (GIS), modeling, environmental media monitoring, and/or personal exposure modeling. However, emerging research reveals that the greatest progress comes from integration among two or more of these efforts.

McKone, Thomas E.; Ryan, P. Barry; Ozkaynak, Haluk

2007-02-01T23:59:59.000Z

49

E-Print Network 3.0 - aromatic hydrocarbons affect Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sciences and Ecology 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

50

E-Print Network 3.0 - aromatic hydrocarbons annual Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: releases about 5 billion kilograms of hydrocarbons...

51

E-Print Network 3.0 - aromatic hydrocarbons implications Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

52

Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two  

E-Print Network (OSTI)

polycyclic aromatic hydrocarbons; Size distribution; Atmospheric pollution; POVA (POllution des Vallées, published in "Atmospheric Environment 42, 173 (2008) 55 à 64" DOI : 10.1016/j.atmosenv.2007.10.008 #12 was determined during the intensive sampling campaigns of the POVA (POllution des Vallées Alpines) research

Boyer, Edmond

53

Chapter 28 - Air Quality Status and Trends  

Science Journals Connector (OSTI)

Abstract This chapter describes the condition of air quality, based on air pollutant concentrations, i.e. criteria pollutants, in airsheds around the world, as well as certain air toxics in urban areas and hot spots. The variability of pollutant concentrations in space and time are discussed, as well as differences in air pollution between more industrialized and economically developed regions vs developing nations. The status and trends of atmospheric concentrations of tropospheric ozone, oxides of nitrogen, oxides of sulfur, carbon monoxide, lead, and particulate matter are discussed. Examples of air toxics include benzene, polycyclic aromatic hydrocarbons, dioxins, aldehydes, and metals, e.g. mercury. Regional and global trends include acid deposition, depletion of the stratospheric ozone layer, and climate change. Indoor air quality is discussed. The chapter concludes with a description of an air quality index.

Daniel Vallero

2014-01-01T23:59:59.000Z

54

The Weekend Ozone Effect - The Weekly Ambient Emissions Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

55

Characteristics of Photosynthesis in Wheat Cultivars with Different Sensitivities to Ozone Under O3-Free Air Concentration Enrichment Conditions  

Science Journals Connector (OSTI)

With the help of the Chinese Ozone-Free Air Concentration Enrichment (O3FACE) platform, the responses of photosynthsis characteristics to elevated O3 concentration were investigated using winter wheat (Tritcium aestivum L.) cultivars Yannong 19 and Yangmai 16, which differ in sensitivities to O3. Under O3 treatment for 75 d, the net photosynthetic rate (Pn), stomtal conductance (Gs), and transpiration rate (Tr) decreased significantly in both cultivars, whereas the intercellular CO2 concentration (Ci) changed slightly. The O3-sensitive cultivar Yannong 19 had larger reductions in Pn (61.1%), Gs (68.0%), and Tr (57.4%) than Yangmai 16 (27.9%, 37.5%, and 27.9%, respectively). This indicated that the reduction of Pn mostly resulted from the nonstomatal factors in cooperation with stomal factors. In the chlorophyll fluorescence parameters, the maximal photochemical efficiency of PSII in the dark (Fv/Fm), the potential activity of PSII (Fv/Fo), the photochemical quenching (qP), and the rate of photochemical reaction (Prate) decreased in the O3 treatment, but the nonphotochemical quenching (NPQ) and the rate of thermal dissipation (Drate) showed a upward tendency. The change tendency of total soluble protein content and the amount of Rubisco was similar to that of chlorophyll fluorescence parameters and Pn. The results implied that the major nonstomal factors responsible for the Pn decrease under elevated O3 concentration were the Ribulose-1,5-bisphosphate (RuBP) carboxylation limitation and the damage of PSII. The change extents of all the parameters were larger in Yannong 19 than in Yangmai 16. The high Tr value and slow reduction of Rubisco amount in Yangmai 16 are probably crucial reasons for its high photosynthetic rate.

Ji-Ling CAO; Liang WANG; Qing ZENG; Jing LIANG; Hao-Ye TANG; Zu-Bin XIE; Gang LIU; Jian-Guo ZHU; Kazhuhiko KOBAYASHI

2009-01-01T23:59:59.000Z

56

A Prototype Passive Air Sampler for Measuring Dry Deposition of Polycyclic Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

(6, 11) The use of the Pas-DD collector to collect PAH dry deposition data at a high spatial resolution to generate deposition maps is analogous to the way that mosses, lichens, and other biomonitors are used to map spatial deposition, but overcoming some of the inconsistency and interpretation challenges associated with biomonitoring. ... Approximately 36% of the PUF disk total outer surface area is covered by the open plate and perforated support that holds the PUF disk in place; countering reduction in sampling for the Pas-DD collector is the higher wind speed through the Pas-DD collector plates that will reduce air-side mass transfer resistance and enhance chemical sampling rates. ... using models that account for particle size distribution show that the results are extremely sensitive to the mass of large particles and that large particles control dry deposition flux due to their high deposition velocities. ...

Anita Eng; Tom Harner; Karla Pozo

2013-09-19T23:59:59.000Z

57

Exposure information in environmental health research: Current opportunities and future directions for particulate matter, ozone, and toxic air pollutants  

E-Print Network (OSTI)

urban analysis of air pollution health effects, remainsderived from community air pollution health studies. Recentused to link them, in air pollution health studies including

McKone, Thomas E.

2008-01-01T23:59:59.000Z

58

E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

59

Ozone removal by HVAC filters  

Science Journals Connector (OSTI)

Residential and commercial HVAC filters that have been loaded with particles during operation in the field can remove ozone from intake or recirculated air. However, knowledge of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial buildings is incomplete. We measured the ozone removal efficiencies of clean (unused) fiberglass, clean synthetic filters, and field-loaded residential and commercial filters in a controlled laboratory setting. For most filters, the ozone removal efficiency declined rapidly but converged to a non-zero (steady-state) value. This steady-state ozone removal efficiency varied from 0% to 9% for clean filters. The mean steady-state ozone removal efficiencies for loaded residential and commercial filters were 10% and 41%, respectively. Repeated exposure of filters to ozone following a 24-h period of no exposure led to a regeneration of ozone removal efficiency. Based on a theoretical scaling analysis of mechanisms that are involved in the ozone removal process, we speculate that the steady-state ozone removal efficiency is limited by reactant diffusion out of particles, and that regeneration is due to internal diffusion of reactive species to sites available to ozone for reaction. Finally, by applying our results to a screening model for typical residential and commercial buildings, HVAC filters were estimated to contribute 22% and 95%, respectively, of total ozone removal in HVAC systems.

P. Zhao; J.A. Siegel; R.L. Corsi

2007-01-01T23:59:59.000Z

60

E-Print Network 3.0 - ambient ozone levels Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

level ozone. Lesson 2: Ozone Formation... , power plants and industry all emit air pollution that forms ... Source: Royer, Dana - Department of Earth and Environmental Sciences,...

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Ozone Reductions Using Residential Building Envelopes  

SciTech Connect

Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

Walker, Iain S.; Sherman, Max; Nazaroff, William W.

2009-02-01T23:59:59.000Z

62

11USDA Forest Service Gen. Tech. Rep. PSW-GTR-166. 1998. Urban air basin produced oxidants, notably ozone, induce a decline in productivity in plants. This loss of productivity  

E-Print Network (OSTI)

11USDA Forest Service Gen. Tech. Rep. PSW-GTR-166. 1998. Abstract Urban air basin produced oxidants, notably ozone, induce a decline in productivity in plants. This loss of productivity is manifested have been well-studied: increased production and more rapid turnover of antioxidant systems; production

Standiford, Richard B.

63

E-Print Network 3.0 - aromatic hydrocarbon exhaust Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: : Acetylenes: Aromatics: 57 15 2 26 A breakdown of 17...

64

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network (OSTI)

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates #12 Satellite observations of ozone and nitrogen dioxide: from retrievals to emission es- timates / by Bas Subject headings: satellite retrieval / nitrogen dioxide / ozone / air pollution / emis- sion estimates

Haak, Hein

65

Ozone decomposing filter  

DOE Patents (OSTI)

In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

1999-01-01T23:59:59.000Z

66

Source Contributions to VOC's to Ozone Formation in Southeast Texas Using a Source-oriented Air Quality Model  

E-Print Network (OSTI)

AQS) from August 16, 2000 to September 7, 2000. Environmental Protection Agency (EPA)?s Community Scale Air Quality Model (CMAQ) version 4.6 was used as a host model to include a revised Statewide Air Pollution Research Center (SAPRC99) photochemical...

Krishnan, Anupama

2011-08-08T23:59:59.000Z

67

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials: Preliminary Results and  

E-Print Network (OSTI)

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials air quality. #12;Proceedings of Healthy Buildings 2009 Paper 141 Removing ozone from indoor

Siegel, Jeffrey

68

Defensive Investments and the Demand for Air Quality: Evidence from the NOx Budget Program and Ozone Reductions  

E-Print Network (OSTI)

Willingness to pay for air quality is a function of health and the costly defensive investments that contribute to health, but there is little research assessing the empirical importance of defensive investments. The setting ...

Deschênes, Olivier

69

Constraining uncertainties about the sources and magnitude of ambient air exposures to polycyclic aromatic hydrocarbons (PAHs): The state of Minnesota as a case study  

SciTech Connect

Emissions data are often lacking or uncertain for many airborne contaminants. Chemicals, such as polycyclic aromatic hydrocarbons (PAHs), emitted from combustion sources, fall into this category. Currently available ambient-air emission inventories of PAHs either fail to account for population-based activities (such as residential wood combustion and motor vehicle activity) and/or report ''total PAH'' or particulate organic matter emissions instead of individual compounds. We measure the degree of overlap between predicted concentrations from estimated emissions with measured concentrations. Our analysis is, based on probabilistic analysis of measured outdoor air concentrations with those predicted from mass-balance models. Based on available information, we estimate the relative magnitude of emissions from four major sources of PAHs to outdoor air- (1) on-road motor vehicles, including light-duty gasoline vehicles and diesel-powered buses and medium and heavy duty trucks; (2) residential wood combustion; and (3) power generation from external combustion boilers. We use the CalTOX regional multimedia mass-balance model to evaluate our emissions estimates in rural and urban regions of the state of Minnesota, USA. We compare model estimates of outdoor PAH airborne concentrations with those reported by the Minnesota Children's Pesticide Exposure Study (MNCPES). With these measured concentrations we probabilistically evaluate our emissions and interpret the reliability of our emissions estimates for specific PAHs. The median estimates of our predicted outdoor air concentrations agree within an order of magnitude of measured concentrations. For four representative PAHs, we were able to obtain a reasonable degree of overlap between empirical and predicted distributions of outdoor air concentrations. Our combination of models, emissions estimates, and empirical concentration data estimate exposure in a manner that is more reliable than any of these tools alone. Thereby, we increase our confidence about our plausible ranges of emissions and predicted concentrations.

Lobscheid, Agnes B.; McKone, Thomas E.

2004-02-01T23:59:59.000Z

70

AutoGC systems for enhanced ozone monitoring network  

SciTech Connect

In response to a requirement for an on-line, automated ozone-precursor analyzer, a Perkin-Elmer Model ATD-400 Thermal Desorption System was specially adapted for the collection of whole-air samples. The C{sub 2} to n-C{sub 10} hydrocarbons were trapped using Peltier cooling on adsorbents at {minus}30 C. Multidimensional chromatography allowed the C{sub 2} to C{sub 6} fraction to be separated using a porous layer open tubular column while a methyl silicone column separated the C{sub 6} to C{sub 10} fraction. No cryogen was used in the collection or analysis. An air generator equipped for automatic restart and special software allowed the system to recover from power failures. Ozone precursor concentrations were detected over 5000 hours of continuous operation at the 0.1 ppbV level. Area repeatability was less than 10%, with retention time precision over 100 hours of approximately 1%RSD for most compounds. Remote communications allowed chromatography to be monitored and files to be downloaded to a central office. Results were converted to EPA AIRS database format using special conversion software. Data were archived using external Bernoulli disks.

Seeley, I. [Perkin-Elmer Corp., Norwalk, CT (United States)

1995-12-31T23:59:59.000Z

71

URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA  

E-Print Network (OSTI)

Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

Boyer, Edmond

72

The Solubility of Oxygen and Ozone in Liquids  

Science Journals Connector (OSTI)

This review covers the solubility of oxygen and ozone in liquids as a function of temperature and pressure. Solubility data for individual systems were critically evaluated and recommended or tentative values presented in many cases. The trend of solubilities in homologous series or related solvents is discussed. Liquids include water;seawater; aqueous salt solutions; mixed solvents; hydrocarbons; organic compounds containing oxygen halogen sulfur nitrogen or silicon; olive oil; and human blood. For ozone only its solubility in water is presented. Key words: aqueous solutions; biological fluids; gas solubility; hydrocarbons; mixed solvents; organic solvents; oxygen; ozone;seawater;water.

Rubin Battino; Timothy R. Rettich; Toshihiro Tominaga

1983-01-01T23:59:59.000Z

73

Effect of Ventilation Strategies on Residential Ozone Levels  

E-Print Network (OSTI)

provided  by  HVAC  system  filters,  it  was  assumed  filtration  from  the  HVAC  system  filters  brings  down  HVAC  system  air  leakage   and  ozone  deposition  on  HAVC  system  filters.      

Walker, Iain S.

2014-01-01T23:59:59.000Z

74

Chlorinated C$_{1}$ and C$_{2}$ Hydrocarbons in the Marine Environment [and Discussion  

Science Journals Connector (OSTI)

...the marine environment. | Journal Article | 0 Hydrocarbons, Chlorinated | Air Pollution analysis Animals Fresh Water Great Britain Hydrocarbons, Chlorinated analysis metabolism Seawater Water Pollution, Chemical analysis The Royal Society...

1975-01-01T23:59:59.000Z

75

Hole in the ozone layer?  

NLE Websites -- All DOE Office Websites (Extended Search)

Hole in the ozone layer? Hole in the ozone layer? Name: Kelley Location: N/A Country: N/A Date: N/A Question: Is there really a hole in the ozone layer? Replies: That depends on what one means by a "hole". There is a thinning of the layer that is particularly severe during certain seasons at the poles. But the ozone layer is thinning most everywhere. The thinning around the south pole of earth is particularly stunning, and has been referred to as a hole even though some ozone still exists there, it is much less concentrated. As you may know, this ozone destruction is probably due to human release of pollutants such as clorofluorocarbons (CFCs) an due to natural sources such as chemicals from volcanic eruptions. CFCs are used is cooling systems such as refrigerators and air conditioning. There is an international agreement to phase out the use of these destructive chemicals but they won't be banned entirely for years for fears of losing money. Meanwhile the ozone layer thins and we are exposed to increasingly higher doses of cancer causing radiation

76

Y-12 Plant Stratospheric Ozone Protection plan  

SciTech Connect

The Y-12 Plant staff is required by Lockheed Martin Energy Systems (Energy Systems) (formerly Martin Marietta Energy Systems) standard ESS-EP-129 to develop and implement a Stratospheric Ozone Protection Program which will minimize emissions of ozone-depleting substances to the environment and maximize the use of ozone-safe alternatives in order to comply with Title VI of the 1990 Clean Air Act (CAA) Amendments and the implementing regulations promulgated by the Environmental Protection Agency (EPA). This plan describes the requirements, initiatives, and accomplishments of the Y-12 Plant Stratospheric Ozone Protection Program.

NONE

1995-09-01T23:59:59.000Z

77

Ozone treatment in a closed culture system for Macrobrachium rosenbergii  

E-Print Network (OSTI)

constant flow of air. The Orthotoridine-Manganese Method (OTM) wss employed to measure ozone in solution (APHA, 1976) . Because of the rapid rate of decomposition of ozone in water, it was determined that the production of ozone could not be measured... by introducing into water and then sampling that water for analysis with OTM. Therefore, ozone was introduced directly into a solution of OTM reagent with subsequent changes in color of the reagent, measured on a "B & L Spectronic 70" spectrophotometer, being...

Yamaguchi, Ryoji

1978-01-01T23:59:59.000Z

78

Healthy Air Act (Maryland)  

Energy.gov (U.S. Department of Energy (DOE))

The Maryland Healthy Air Act was developed with the purpose of bringing Maryland into attainment with the National Ambient Air Quality Standards (NAAQS) for ozone and fine particulate matter by the...

79

Ozone chemistry in the smoke from the Kuwait oil fires  

SciTech Connect

Ozone depletion occurred in the core of the plume of smoke from the Kuwait oil fires within 100 km of the fires, primarily in regions where NO{sub x} concentrations were high and ultraviolet flux was near zero. Rapid conversion of NO to NO{sub 2} can explain almost all of the ozone loss. Ozone was produced in diffuse regions of the plume, where the ultraviolet flux was higher than in the core. However, due to the relatively high ratio of nonmethane hydrocarbons to NO{sub x}, ozone production was slow. Since ozone was produced in a much larger volume than it was depleted, the plume as a whole was a source of ozone on a regional scale. 27 refs., 4 figs., 1 tab.

Herring, J.A.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States)

1992-09-20T23:59:59.000Z

80

Polycyclic Aromatic Hydrocarbon Exposure in Household Air Pollution from Solid Fuel Combustion among the Female Population of Xuanwei and Fuyuan Counties, China  

Science Journals Connector (OSTI)

Exposure to polycyclic aromatic hydrocarbons (PAHs) from burning “smoky” (bituminous) coal has been implicated as a cause of the high lung cancer incidence in the counties of Xuanwei and Fuyuan, China. Little is known about variations in PAH exposure from ...

George S. Downward; Wei Hu; Nat Rothman; Boris Reiss; Guoping Wu; Fusheng Wei; Robert S. Chapman; Lutzen Portengen; Lan Qing; Roel Vermeulen

2014-11-13T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Formation of ozone and oxidation of methane in a direct current corona discharge  

E-Print Network (OSTI)

than in the positive corona when using air, while the reverse was observed with oxygen. At low currents and high gas flow rates, the ozone production rate increased linearly with corona current independent of gas flow rate. At high currents... humidity) and positive corona. Their results show: (1) a linear relation between ozone concentration and corona current; (2) an (non- linear) inverse relation between the ozone concentration and air flow; and (3) for a given corona current, the ozone...

Tangirala, Umashanker

1976-01-01T23:59:59.000Z

82

Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas  

E-Print Network (OSTI)

High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

Nam, Junsang

2007-01-01T23:59:59.000Z

83

Ozone Removal by Filters Containing Activated Carbon: A Pilot Study  

SciTech Connect

This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

2009-09-01T23:59:59.000Z

84

With harmful ozone concentrations tied to meteorological conditions, EPA investigates the U.S. air quality implications of a changing climate.  

E-Print Network (OSTI)

%, vehicle miles traveled increased 103% and energy consumption increased 30% (U.S. EPA 2008). Air pollution- port emphasized that the U.S. air quality management system must be "flexible and vigilant" to ensure

Cohen, Ronald C.

85

Clean air act and National Ambient Air Quality Standards (NAAQS)  

E-Print Network (OSTI)

Clean air act and National Ambient Air Quality Standards (NAAQS) Ozone: Sources/Environmental Effects Particulates (PM): Sources/Environmental Effects #12;National Ambient Air Quality Standards (NAAQS) The Clean Air Act requires EPA to set National Ambient Air Quality Standards for pollutants considered

Weber, Rodney

86

Air Pollution and Epigenetics: Recent Findings  

Science Journals Connector (OSTI)

The health effects of ambient air pollution are well-described, but less is known ... , microRNA, and DNA methylation; along with air pollutant keywords: air pollution, benzo[a]pyrene, nitrogen dioxide, ozone...1

Carrie V. Breton; Amy N. Marutani

2014-03-01T23:59:59.000Z

87

Atmospheric Environment 39 (2005) 13731382 A hierarchical Bayesian model to estimate and forecast ozone  

E-Print Network (OSTI)

reserved. Keywords: Statistical model; Space­time models; Air pollution; Ozone; Meteorology 1. Introduction describing the spatial­temporal behavior of ambient air pollutants such as ozone (O3) and particulate matter. Statistical space­time models are useful for illuminating relationships between different air pollutants

Irwin, Mark E.

88

Effect of Ventilation Strategies on Residential Ozone Levels  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Ventilation Strategies on Residential Ozone Levels Effect of Ventilation Strategies on Residential Ozone Levels Title Effect of Ventilation Strategies on Residential Ozone Levels Publication Type Journal Article LBNL Report Number LBNL-5889E Year of Publication 2012 Authors Walker, Iain S., and Max H. Sherman Journal Building and Environment Volume 59 Start Page 456 Pagination 456-465 Date Published 01/2013 Keywords ashrae standard 62,2, filtration, infiltration, mechanical ventilation, ozone, simulation Abstract Elevated outdoor ozone levels are associated with adverse health effects. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone of outdoor origin would lower population exposures and might also lead to a reduction in ozone---associated adverse health effects. In most buildings, indoor ozone levels are diminished with respect to outdoor levels to an extent that depends on surface reactions and on the degree to which ozone penetrates the building envelope. Ozone enters buildings from outdoors together with the airflows that are driven by natural and mechanical means, including deliberate ventilation used to reduce concentrations of indoor---generated pollutants. When assessing the effect of deliberate ventilation on occupant health one should consider not only the positive effects on removing pollutants of indoor origin but also the possibility that enhanced ventilation might increase indoor levels of pollutants originating outdoors. This study considers how changes in residential ventilation that are designed to comply with ASHRAE Standard 62.2 might influence indoor levels of ozone. Simulation results show that the building envelope can contribute significantly to filtration of ozone. Consequently, the use of exhaust ventilation systems is predicted to produce lower indoor ozone concentrations than would occur with balanced ventilation systems operating at the same air---exchange rate. We also investigated a strategy for reducing exposure to ozone that would deliberately reduce ventilation rates during times of high outdoor ozone concentration while still meeting daily average ventilation requirements.

89

Study to determine the nature and extent of ozone and ozone precursor transport in selected areas of California. Final report  

SciTech Connect

The project was designed to assess the contribution of transported pollutants to violations of the state ozone standard within the air basins covered by the report using existing data and advanced data analysis techniques. The objectives of the project were to determine the characteristics of ozone and ozone precursor transport within the California air basins covered by the report and to identify whether the contribution of transported pollutants to ozone violations in each downwind area was inconsequential, significant, or overwhelming, relative to locally-emitted pollutants. The precursor pollutants of interest were nitrogen oxides and reactive organic gases. The project evaluated transport to the following areas: The Broader Sacramento Area and the Upper Sacramento Valley; The North Central Coast Air Basin; The Southeast Desert Air Basin (SEDAB); and the Imperial County portion of the SEDAB.

Roberts, P.T.; Musarra, S.; Smith, T.B.; Lurmann, F.W.

1992-04-01T23:59:59.000Z

90

Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats  

SciTech Connect

Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

Bass, V. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Gordon, C.J.; Jarema, K.A.; MacPhail, R.C. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Cascio, W.E. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Phillips, P.M. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Ledbetter, A.D.; Schladweiler, M.C. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Andrews, D. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Miller, D. [Curriculum in Toxicology, University of North Carolina, Chapel Hill, NC (United States); Doerfler, D.L. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Kodavanti, U.P., E-mail: kodavanti.urmila@epa.gov [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

2013-12-15T23:59:59.000Z

91

Naphthenic hydrocarbons  

SciTech Connect

An important type of naphthenic hydrocarbons is the monocyclic type, (k/sub 2/, 0, 0). In this instance the number of carbon atoms, n = k/sub 2/, and a formula, C/sub n/H/sub 2n/, can be written where H/C = 2. The value n can vary from 2 to infinity. In the case of n = 2, it is ethylene (I) (2-membered cyclic ring); n = 3, cyclopropane (II) (3-membered cyclic ring); n = 4, cyclobutane (III) (4-membered cyclic ring); etc. If the monocyclic naphthenic is planar, then the bond angle theta can be expressed as theta = (1 - 2/n)..pi.. where n is the number of carbon atoms. However, the tetrahedron angle of the carbon atom being phi = cos/sup -1/ (- 1/3).

Yen, T.F.; Kuo, J.F.; Chilingarian, G.V.

1987-01-01T23:59:59.000Z

92

Li et al., Aerosol and Air Quality Research, Vol. 6, No. 4, pp. 418-429, 2006 UV-Absorption-Based Measurements of Ozone and Mercury  

E-Print Network (OSTI)

interferences. For example, CMMs based on atomic absorption spectrometry (AAS) are subject to interferences of the Hg detection technique. Atomic absorption spectrometry (AAS) is one of the major techniques appliedLi et al., Aerosol and Air Quality Research, Vol. 6, No. 4, pp. 418-429, 2006 UV-Absorption

Li, Ying

93

Auto GC system for enhanced ozone monitoring network  

SciTech Connect

A Perkin-Elmer Model ATD-400 Thermal Desorption System was specially adapted for the collection of whole-air samples. The C{sub 2} to n-C{sub 10} hydrocarbons were trapped using Peltier cooling on Carbotrap/Carbosieve adsorbents at {minus}30 C. A Deans switch allowed the C{sub 2} to C{sub 6} fraction to be separated using a porous layer open tubular column while a methyl silicone column separated the C{sub 6} to C{sub 10} fraction. No cryogen was used in the collection or analysis. Ozone precursor concentrations were detected at the 0.1 ppbV level. Area repeatability was less than 10%, with retention time precision over 100 hours of approximately 1% RSD for most compounds. Remote communications allowed chromatography to be monitored and files to be downloaded to a central office. Data in .CSV format was directly assimilated by spreadsheet software for diurnal inspection and customized reporting. Data were achieved using external Bernoulli disks.

Seeley, I.; Tipler, A. [Perkin-Elmer Corp., Norwalk, CT (United States); Broadway, G. [Perkin-Elmer Ltd., Beaconsfield (United Kingdom)

1994-12-31T23:59:59.000Z

94

WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos  

E-Print Network (OSTI)

are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

Mankoff, Jennifer

95

On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California  

E-Print Network (OSTI)

The San Joaquin Valley (SJV) experiences some of the worst ozone air quality in the US, frequently exceeding the California 8 h standard of 70.4 ppb. To improve our understanding of trends in the number of ozone violations ...

Pusede, S. E.

96

Primary zone air proportioner  

DOE Patents (OSTI)

An air proportioner is provided for a liquid hydrocarbon fueled gas turbine of the type which is convertible to oil gas fuel and to coal gas fuel. The turbine includes a shell for enclosing the turbine, an air duct for venting air in said shell to a gasifier, and a fuel injector for injecting gasified fuel into the turbine. The air proportioner comprises a second air duct for venting air from the air duct for mixing with fuel from the gasifier. The air can be directly injected into the gas combustion basket along with the fuel from the injector or premixed with fuel from the gasifier prior to injection by the fuel injector.

Cleary, Edward N. G. (San Diego, CA)

1982-10-12T23:59:59.000Z

97

A 700 year sediment record of black carbon and polycyclic aromatic hydrocarbons near the EMEP air monitoring station in Aspvreten, Sweden  

SciTech Connect

In view of poor constraints on historical combustion emissions, past environmental loadings of black carbon (BC) and polycyclic aromatic hydrocarbon (PAH) were reconstructed from dated lake sediment cores collected 70 km south of Stockholm, Sweden. Compared to several dramatic variations over the recent 150 years, the preindustrial loadings were steady within {+-}50% through the entire medieval with BC fluxes of 0.071 g m{sup -2} yr{sup -1} and PAH fluxes of 6 g m{sup -2} yr{sup -1}. In the wood-burning dominated century leading up to the industrial revolution around 1850, increasing BC fluxes were leading PAH fluxes. BC fluxes reached their millennial-scale maximum around 1920, whereas PAH fluxes increased exponentially to its record maximum around 1960, 50-fold above preindustrial values. For 1920-1950, BC fluxes consistently decreased as PAH fluxes kept increasing. Coal and coke represented >50% of the Swedish energy market in the 1930s. Combined with sharply decreasing (1,7-)/(1,7{+-}2,6-dimethylphenanthrene), indicative of diminishing wood combustion, and decreasing methylphenanthrenes/phenanthrene, indicative of higher-temperature combustion (coal instead of wood), the sediment archive suggests that the relative BC/PAH emission factors thus are lower for coal than for wood combustion. For the first time, both BC and PAH fluxes decreased after 1960. This trend break is a testament to the positive effects of decreasing reliance on petroleum fuels and a number of legislative actions aimed at curbing emissions and by 1990, the loading of BC was back at preindustrial levels, whereas that of PAH were the lowest since the 1910s. However, for the most recent period (1990-2004) the BC and PAH fluxes are no longer decreasing. 55 refs., 3 figs.

Marie Elmquist; Zdenek Zencak; Oerjan Gustafsson [Stockholm University, Stockholm (Sweden). Department of Applied Environmental Science

2007-10-15T23:59:59.000Z

98

Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction  

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Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction with HVAC Filters Title Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction with HVAC Filters Publication Type Conference Proceedings Year of Publication 2009 Authors Destaillats, Hugo, Wenhao Chen, Michael G. Apte, Nuan Li, Michael Spears, Jérémie Almosni, Jianshun Zheng, and William J. Fisk Conference Name Proceedings of the Healthy Buildings 2009 Conference Conference Location Syracuse, NY Keywords building-related symptoms, hvac filter, ozone, ptr-ms, secondary pollutants Abstract We used Proton Transfer Reaction - Mass Spectrometry (PTR-MS) and conventional sampling methods to monitor and identify trace level organic pollutants formed in heterogeneous reactions between ozone and HVAC filters in real time. Experiments were carried out using a bench-scale flow tube reactor operating with dry air and humidified air (50% RH), at realistically high ozone concentrations (150 ppbv). We explored different filter media (i.e., fiberglass and cotton/polyester blends) and different particle loadings (i.e., clean filter and filters loaded with particles for 3 months at the Lawrence Berkeley National Laboratory and the Port of Oakland, CA). Detailed emission dynamics of very low levels of certain organic pollutants from filter media upon ozone exposure in the presence of moisture have been obtained and analyzed.

99

Characterization of hydrocarbons found in the arctic aquatic environment near the Ekati diamond mine.  

E-Print Network (OSTI)

??Polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment of the Ekati Diamond Mine were evaluated in snow, sediment, air and water (via passive membrane samplers).… (more)

Nabess, Stephanie Ann

2014-01-01T23:59:59.000Z

100

Combustion of viscous hydrocarbons  

SciTech Connect

A method is described for utilizing viscous hydrocarbons as combustible fuels comprising: (A) forming a hydrocarbosol using a surfactant package in a proportion of about 1:100 to about 1:20,000 by weight based on hydrocarbon, (1) the surfactant package comprising (a) at least one water-soluble surfactant, an effective amount of which surfactant promotes emulsification of a hydrocarbon with API gravity of about 20/sup 0//sup o/ API or less; and (b) at least one water-soluble bioemulsifier, being a microboally-derived substance which predominantly resides at hydrocarbon/water interfaces to substantially surround hydrocarbon droplets in hydrocarbon-in-water emulsions; (2) the hydrocarbosol (a) comprising a hydrocarbon characterized by an API gravity of about 20/sup 0//sup o/ API or less; (b) having a hydrocarbon:water ratio of about 70:30 by volume; and (B) burning the resultant hydrocarbosol.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III

1986-10-21T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Ozone generation by rock fracture: Earthquake early warning?  

SciTech Connect

We report the production of up to 10 ppm ozone during crushing and grinding of typical terrestrial crust rocks in air, O{sub 2} and CO{sub 2} at atmospheric pressure, but not in helium or nitrogen. Ozone is formed by exoelectrons emitted by high electric fields, resulting from charge separation during fracture. The results suggest that ground level ozone produced by rock fracture, besides its potential health hazard, can be used for early warning in earthquakes and other catastrophes, such as landslides or land shifts in excavation tunnels and underground mines.

Baragiola, Raul A.; Dukes, Catherine A.; Hedges, Dawn [Engineering Physics, University of Virginia, Charlottesville, Virginia 22904 (United States)

2011-11-14T23:59:59.000Z

102

DNA Damage from Polycyclic Aromatic Hydrocarbons Measured by Benzo[a]pyrene-DNA Adducts in Mothers and Newborns from Northern Manhattan, The World Trade Center Area, Poland, and China  

Science Journals Connector (OSTI)

...exposure to polycyclic aromatic hydrocarbons may disproportionately increase...adducts|polycyclic aromatic hydrocarbons|cancer|susceptibility...Introduction Polycyclic aromatic hydrocarbons (PAH) are common environmental...air, food, and drinking water from incomplete combustion...

Frederica Perera; Deliang Tang; Robin Whyatt; Sally Ann Lederman; and Wieslaw Jedrychowski

2005-03-01T23:59:59.000Z

103

Chapter 3 - Hydrocarbons from Petroleum  

Science Journals Connector (OSTI)

Publisher Summary Petroleum products (in contrast to petrochemicals) are those hydrocarbon fractions that are derived from petroleum and have commercial value as a bulk product. A major group of hydrocarbon products from petroleum (petrochemicals) are the basis of a major industry. They are, in the strictest sense, different to petroleum products insofar as the petrochemicals are the basic building blocks of the chemical industry. The specific gravity of product gases, including liquefied petroleum gas, may be determined conveniently by a number of methods and a variety of instruments. The heat value of gases is generally determined at constant pressure in a flow calorimeter in which the heat released by the combustion of a definite quantity of gas is absorbed by a measured quantity of water or air. A continuous recording calorimeter is available for measuring heat values of natural gases.

James G. Speight

2011-01-01T23:59:59.000Z

104

Sensitivity Analysis of Ozone Formation and Transport for a Central  

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Sensitivity Analysis of Ozone Formation and Transport for a Central Sensitivity Analysis of Ozone Formation and Transport for a Central California Air Pollution Episode Title Sensitivity Analysis of Ozone Formation and Transport for a Central California Air Pollution Episode Publication Type Journal Article Year of Publication 2008 Authors Jin, Ling, Shaheen R. Tonse, Daniel S. Cohan, Xianglei Mao, Robert A. Harley, and Nancy J. Brown Journal Environmental Science & Technology Volume 42 Start Page 3683 Issue 10 Pagination 3683-3689 Date Published 05/2008 Abstract We developed a first- and second-order sensitivity analysis approach with the decoupled direct method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a 5 day ozone episode (Jul 29th to Aug 3rd, 2000). Despite considerable spatial variations, nitrogen oxides (NOx) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8 h ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1 h ozone standard. Interbasin source contributions of NOx emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NOx and AVOC, and the rate coefficient of the OH + NO2 termination reaction, have the greatest effect on first-order ozone responses to changes in NOx emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

105

E-Print Network 3.0 - air pollution lessons Sample Search Results  

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lessons Search Powered by Explorit Topic List Advanced Search Sample search results for: air pollution lessons Page: << < 1 2 3 4 5 > >> 1 Global Ozone Project Ozone Formation in...

106

Method of treating emissions of a hybrid vehicle with a hydrocarbon absorber and a catalyst bypass system  

DOE Patents (OSTI)

A method of treating emissions from an internal combustion engine of a hybrid vehicle includes directing a flow of air created by the internal combustion engine when the internal combustion engine is spinning but not being fueled through a hydrocarbon absorber to collect hydrocarbons within the flow of air. When the hydrocarbon absorber is full and unable to collect additional hydrocarbons, the flow of air is directed through an electrically heated catalyst to treat the flow of air and remove the hydrocarbons. When the hydrocarbon absorber is not full and able to collect additional hydrocarbons, the flow of air is directed through a bypass path that bypasses the electrically heated catalyst to conserve the thermal energy stored within the electrically heated catalyst.

Roos, Bryan Nathaniel; Gonze, Eugene V; Santoso, Halim G; Spohn, Brian L

2014-01-14T23:59:59.000Z

107

Surface ozone background in the United States: Canadian and Mexican pollution influences  

E-Print Network (OSTI)

of anthropogenic emissions from Canada, Mexico, and outside North America on daily maximum 8-hour average ozone Surface ozone Air quality standard Chemical transport model Global model a b s t r a c t We use a global chemical transport model (GEOS-Chem) with 1 Ã? 1 horizontal resolution to quantify the effects

Park, Rokjin

108

Experimental study of reactions between ozone and building products M. Nicolas, O. Ramalho, F. Maupetit*  

E-Print Network (OSTI)

ozone and building products and document their potential impact on indoor air quality. PreliminaryExperimental study of reactions between ozone and building products M. Nicolas, O. Ramalho, F experiments were conducted on four building products: two carpets, a gypsum board and a pine wood board

Paris-Sud XI, Université de

109

Tropospheric ozone trends at Mauna Loa Observatory tied to decadal climate variability  

E-Print Network (OSTI)

measurements at Mauna Loa Observatory in Hawaii reveal little change in tropospheric ozone levels during spring a suite of chemistry­climate model simulations. We show that the flow of ozone-rich air from Eurasia towards Hawaii during spring weakened in the 2000s as a result of La-Niña-like decadal cooling

110

Regional air pollution study: effects of airborne sulfur pollutants on materials. Final report  

SciTech Connect

Samples of galvanized steel, weathering steel, A1 2014 and 7079 stress samples, silver, marble, nylon and two types of house paint were exposed at nine sites of the Regional Air Monitoring System in the St. Louis area. Wind speed and direction, temperature, dew point, total sulfur, SO2, H2S, O3, NOx, total hydrocarbons, total suspended particulate matter, sulfate and nitrate were recorded. For galvanized steel a pronounced effect of time of first exposure was observed. The corrosion behavior of weathering steel was not seasonally dependent. House paint showed discontinuous erosive behavior. Exposure to the south was more erosive than exposure to the north. Rates for latex paint were higher than for oil based paint. The erosion rate of marble decreased with time. At some sites 50% reflectance loss of silver occurred after 3 months exposure. All samples of A1 7079 at 25 Ksi failed in less than 255 days, while complete failure at 15 Ksi occurred between 277 and 630 days. For A1 2014 more scatter was observed. The pollution levels in St. Louis were found to be rather low. Ozone showed similar seasonal changes as the temperature. Sites close to the center of St. Louis had lower ozone but higher NOx and total hydrocarbon levels. Sulfate was about twice as high in summer as in winter. A first attempt at multiple regression analysis was made. Apparent inconsistencies in the estimated effects are believed to be due to multicollinearity.

Mansfeld, F.

1980-01-01T23:59:59.000Z

111

Ozone in Michigan's Environment 1876–1880  

Science Journals Connector (OSTI)

Atmospheric ozone was monitored in Michigan during the late 1880's using Schoenbein's test paper. A conversion chart was constructed to relate the Schoenbein ozone scale at various relative humidifies to ozone levels indicated by a Dasibi ozone ...

Dale E. Linvill; W. J. Hooker; Brian Olson

1980-11-01T23:59:59.000Z

112

Combustion of viscous hydrocarbons  

SciTech Connect

A method is described for utilizing viscous hydrocarbons as combustible pre-atomized fuels, comprising: (A) forming a hydrocarbon-in-water emulsion using an effective amount of a surfactant package comprising at least one water-soluble surfactant, the hydrocarbon-in-water emulsion (1) comprising a hydrocarbon characterized by API gravity of about 20/sup 0/ API or less, viscosity of about 1000 centipoise or greater at 212/sup 0/F., a paraffin content of about 50% by weight or less and, an aromatic content of about 15% by weight or greater, and (2) having a hydrocarbon water ratio from about 60:40 to about 90:10 by volume; and (B) burning the resultant hydrocarbon-in-water emulsion.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III; Bolden, P.L. Jr.

1987-08-04T23:59:59.000Z

113

Air Pollution  

Science Journals Connector (OSTI)

Ozone.... A gaseous form of oxygen with three atoms per molecule. Ozone is a bluish gas that is harmful to breathe. Nearly 90 % of the Earth’s ozone is in the stratosphere and is referred to as t...

Annmarie Eldering

2014-01-01T23:59:59.000Z

114

Removal of phenol and chlorophenols from water by new ozone generator  

Science Journals Connector (OSTI)

Presence of phenol in river water occasionally disturbs the production of drinking water. Phenol often originated from coal power plants or pesticides. New ozone generator [Kuraica et al., Vacuum, 73 (2004) 705] was used for removal of phenol and chlorophenols from water. The ozone generator was based on coaxial dielectricbarrier-discharge and operated in the air at an atmospheric pressure. Flowing water was one of dielectric layers. Ozone and ozonized water were generated in the same volume of the discharge. This type of ozone generator has considerable advantages in comparison with the classical ones. In this paper five experiments were described, three with bidistilled water and two with different water samples from river Danube. In all cases, 5L of water containing 6mg/L of corresponding phenol was passed once through the ozonizer. The concentration of dissolved ozone in water was 7–40mg/L. The ozonization lasted 1 h, but the total contact time was up to 94 h. In all cases, before and after the treatment of water with ozone, the concentration of corresponding phenol [Standard Methods for Examination of Water and Wastewater, method 510 B, Chloroform Extraction Method, American Public Health Association, Washington, 1985, p. 558], dissolved and residual ozone [Standard Methods for Examination of Water and Wastewater, Methods 2-41, 2-42 (dissolved ozone) Iodometric Method; method 4-104 (ozone residual) Indigo Colorimetric Method, American Public Health Association, Washington, 1995] were determined by standard methods. In experiments with distilled water most of the phenol was removed during ozonization (89.5%). After 24 and 96 h the percentage of removed phenol increased to 93.3 and 98.9%, respectively. With 4-chlorophenol and 2,4-dichlorophenol, 99.8 and 98.9% of corresponding phenols were removed. In experiments with two different water samples from Danube, the phenol was also mostly removed during ozonization, 76.7 and 80.0%, respectively.

D. Manojlovic; D.R. Ostojic; B.M. Obradovic; M.M. Kuraica; V.D. Krsmanovic; J. Puric

2007-01-01T23:59:59.000Z

115

E-Print Network 3.0 - air station whidbey Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

inputAtmospheric input Puget Sound air arrives... from the Pacific - veryg y clean Air pollution within PS basin can be an important pathway to deliver... ). Hydrocarbons...

116

Real-World Studies of Ambient Ozone Formation as a Function of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

-- Washington D.C. ace29lawson.pdf More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Health Impacts Program DOE's...

117

Hydrocarbon Potential of Deep Water  

Science Journals Connector (OSTI)

...research-article Hydrocarbon Potential of Deep Water H. R. Warman In...the geology and hydrocarbon potential of the Earth's deeper water areas, an attempt...United Kingdom 1981 Hydrocarbon potential of deep water Warman H. R. Author...

1978-01-01T23:59:59.000Z

118

Urban and Regional Air Quality  

NLE Websites -- All DOE Office Websites (Extended Search)

equipment equipment Urban and Regional Air Quality Research in this area is concerned with regional air quality issues such as: Controlling nitrogen oxides (NOx) and volatile organic compounds, to manage tropospheric ozone pollution. Hazardous air pollutants: using science to base standards on rigorously studied risks. Air quality and climate: how does climate influence air quality at a regional or local level? Current modeling practices often do not capture variations in pollutants such as ozone-they represent a limited sample of the diverse meteorology and human behavior that affect air pollution. Improved modeling of regional air quality will help understand variability, reveal patterns of behavior, and pollutant transport issues. Controlled experiments in lab and field can help validate improved models.

119

Air quality during the 2008 Beijing Olympics: secondary pollutants and regional impact  

E-Print Network (OSTI)

B. Y. , and Yu, C. : Air quality during the 2008 BeijingNielsen, C. P. : Ozone air quality during the 2008 Beijingobservations of changes in air quality during the 2008

2010-01-01T23:59:59.000Z

120

Experimental Studies of Hydroxyl Radical Initiated Tropospheric Oxidation of Unsaturated Hydrocarbons  

E-Print Network (OSTI)

radical, followed by chain propagating radical reactions. Their oxidation is the major source for ground level ozone formation in both rural and urban area and understanding their chemistry is essential for regional air quality modeling. Until recently...

Ghosh, Buddhadeb

2011-10-21T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Recovering hydrocarbons from hydrocarbon-containing vapors  

DOE Patents (OSTI)

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

1980-09-30T23:59:59.000Z

122

7, 97959828, 2007 Tropospheric ozone  

E-Print Network (OSTI)

ACPD 7, 9795­9828, 2007 Tropospheric ozone climatology over Beijing A. J. Ding et al. Title Page Chemistry and Physics Discussions Tropospheric ozone climatology over Beijing: analysis of aircraft data;ACPD 7, 9795­9828, 2007 Tropospheric ozone climatology over Beijing A. J. Ding et al. Title Page

Paris-Sud XI, Université de

123

8, 1106311101, 2008 Tropospheric Ozone  

E-Print Network (OSTI)

ACPD 8, 11063­11101, 2008 Tropospheric Ozone climatology in the southern subtropics G. Clain et al.0 License. Atmospheric Chemistry and Physics Discussions Tropospheric ozone climatology at two southern Tropospheric Ozone climatology in the southern subtropics G. Clain et al. Title Page Abstract Introduction

Paris-Sud XI, Université de

124

Wastewater Ozonation Catalyzed by Iron  

Science Journals Connector (OSTI)

Another attempt to improve ozonation removal efficiency is the use of metals or their oxides to catalyze ozonation. ... The waveforms were generated by a potentiostat BAS model Epsilon-2. ... Sreethawong, T.; Chavadej, S.Color removal of distillery wastewater by ozonation in the absence and presence of immobilized iron oxide catalyst J. Hazard. ...

Anaid Cano Quiroz; Carlos Barrera-Di?az; Gabriela Roa-Morales; Patricia Balderas Herna?ndez; Rubi? Romero; Reyna Natividad

2010-09-23T23:59:59.000Z

125

556 2010 ASHRAE Chemical reactions between ozone and terpenoids can  

E-Print Network (OSTI)

, and air-conditioning (HVAC) system. This investigation models the influence of HVAC systems on SOA influential HVAC parameters are the flow rates through the system,particlefiltrationefficiency,andindoortemperature for the residential and commercial models, as well as ozone removal on used filters for the commercial model

Siegel, Jeffrey

126

One-Step Production of Superhydrophobic Coatings on Flat Substrates via Atmospheric Rf Plasma Process Using Non-Fluorinated Hydrocarbons  

Science Journals Connector (OSTI)

One-Step Production of Superhydrophobic Coatings on Flat Substrates via Atmospheric Rf Plasma Process Using Non-Fluorinated Hydrocarbons ... This paper describes the direct deposition of hydrocarbon coatings with a static water contact angle higher than 150 using simple C6 hydrocarbons as a reactive gas in helium plasma generated in ambient air without any preroughening of the silicon (100) substrate. ...

Seul Hee Lee; Zachary R. Dilworth; Erik Hsiao; Anna L. Barnette; Matthew Marino; Jeong Hoon Kim; Jung-Gu Kang; Tae-Hwan Jung; Seong H. Kim

2011-01-31T23:59:59.000Z

127

Bioremediation of soil contaminated with hydrocarbons and heavy metals  

SciTech Connect

This investigation showed that a soil contaminated with petroleum hydrocarbons and heavy metals had sufficient indigenous microbial activity for hydrocarbon biodegradation under nonlimiting conditions. Nutrient supplementation with nitrogen and phosphate, together with aeration, seemed to be the most important factors for enhancing biodegradation. Hydrocarbon biodegradation occurred to a much greater extent under aerobic than under anaerobic conditions. Biodegradation did, however, induce low pH conditions and thus caused high heavy-metal concentrations in the leachate. Anaerobic conditions inhibited hydrocarbon biodegradation with no subsequent drop in pH and low heavy-metal concentrations in the leachate. Thus, anaerobic conditions were shown to facilitate less metal mobility than low pH conditions. Air sparging did not cause a significant increase in biodegradation. Adsorption of heavy-fraction hydrocarbons (> C{sub 20}) to microorganisms and colloidal material in the leachate was suspected of facilitating mobility of these fractions and thus their subsequent detection in the leachate.

Plessis, C.A. du; Phaal, C.B.; Senior, E. [Univ. of Natal, Scottsville (South Africa)

1995-12-31T23:59:59.000Z

128

Meeting the New Ozone Standard: Challenges and Opportunities  

Energy.gov (U.S. Department of Energy (DOE))

This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

129

Plasma Processing Of Hydrocarbon  

SciTech Connect

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

130

E-Print Network 3.0 - air quality trends Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Engineering Current Research Projects Summary: , to quantify the effect of transboundary pollution on air quality. Ozone trends and interannual variability... Research's Community...

131

E-Print Network 3.0 - air quality quantified Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Engineering Current Research Projects Summary: , to quantify the effect of transboundary pollution on air quality. Ozone trends and interannual variability... Research's Community...

132

Ozone concentrations in El Paso, Texas  

SciTech Connect

El Paso, Texas may have a problem in meeting ambient air standards due to influx of pollutants from foreign sources. Cd. Juarez, Chihuahua, and Fort Bliss abut the city and are areas over which the Texas Air Control Board (TACB) has little or no jurisdiction. The Board maintains two Continuous Air Monitoring Stations (CAM) in El Paso. Ozone, nitric oxide, and nitrogen dioxide data were obtained from these stations. If the EPA Empirical Kinetic Model is used for El Paso, reducing NMHC concentrations may increase rather than decrease O/sub 3/ concentrations. The Texas State Implementation Plan, while not based on Empirical Kinetic Modeling, calls for a reduction of 18% in NMHC. However, 31% of all NMHC in El Paso arise from sources over which Texas had little (a federal military reservation) or no (Cd. Juarez) jurisdiction. It appears the TACB is correct in believing the SIP for O/sub 3/ may not bring El Paso into compliance. (JMT)

Crocker, J.E. (Texas Air Control Board, Austin); Applegate, H.G.

1983-02-01T23:59:59.000Z

133

Response: Stratospheric Ozone  

Science Journals Connector (OSTI)

...Stratospheric Ozone The Upper Atmosphere Research Pro-gram...not coincide with true atmospheric change. A major review...report "Spacelab-2 plasma depletion experiments...correct figure 5 is printed below. N 2.5 OMS...360 MHz0 o 1.704 MHz'(a O, 2.108 MHz...

KENNETH P. BOWMAN

1988-02-19T23:59:59.000Z

134

Stratospheric ozone depletion  

Science Journals Connector (OSTI)

...atmospheric lifetimes. The water solubility of the CFCs is very...surface back into the gas phase, where they...sufficient additional water molecules can accumulate...stratospheric ozone by nitrogen oxide catalysts from...Gille, J.C1986The water vapor budget of the...

2006-01-01T23:59:59.000Z

135

Ozone and ethylene stress  

Science Journals Connector (OSTI)

... SIRá"In a recent News and Views article1 "Adding ethylene to injury", M. Unsworth discussed the results of Mehlhorn and Wellburn2, who reported ... M. Unsworth discussed the results of Mehlhorn and Wellburn2, who reported that both endogenous ethylene (a stress-hormone) and exogenous ozone are cooperating prerequisites for injury to pea plants ...

E. F. ELSTNER

1987-08-06T23:59:59.000Z

136

Potential benefits of oxygen-enriched intake air in a vehicle powered by a spark-ignition engine  

SciTech Connect

A production vehicle powered by a spark-ignition engine (3.1-L Chevrolet Lumina, model year 1990) was tested. The test used oxygen-enriched intake air containing 25 and 28% oxygen by volume to determine (1) if the vehicle would run without difficulties and (2) if emissions benefits would result. Standard Federal Test Procedure (FTP) emissions test cycles were run satisfactorily. Test results of catalytic converter-out emissions (emissions out of the converter) showed that both carbon monoxide and hydrocarbons were reduced significantly in all three phases of the emissions test cycle. Test results of engine-out emissions (emissions straight out of the engine, with the converter removed) showed that carbon monoxide was significantly reduced in the cold phase. All emission test results were compared with those for normal air (21% oxygen). The catalytic converter also had an improved carbon monoxide conversion efficiency under the oxygen-enriched-air conditions. Detailed results of hydrocarbon speciation indicated large reductions in 1,3-butadiene, formaldehyde, acetaldehyde, and benzene from the engine with the oxygen-enriched air. Catalytic converter-out ozone was reduced by 60% with 25%-oxygen-content air. Although NO{sub x} emissions increased significantly, both for engine-out and catalytic converter-out emissions, we anticipate that they can be ameliorated in the near future with new control technologies. The automotive industry currently is developing exhaust-gas control technologies for an oxidizing environment; these technologies should reduce NO{sub x} emissions more efficiently in vehicles that use oxygen-enriched intake air. On the basis of estimates made from current data, several production vehicles that had low NO{sub x} emissions could meet the 2004 Tier II emissions standards with 25%-oxygen-content air.

Ng, H.K.; Sekar, R.R.

1994-04-01T23:59:59.000Z

137

OZONE PRECURSORS, SOURCE REGIONS, AND O(3) FORMATION DURING THE TEXAQS 2000 STUDY.  

SciTech Connect

The DOE G-1 aircraft made flights on 14 days during the TexAQS 2000 study. On 7 of those days, the aircraft encountered highly localized plumes exhibiting O{sub 3} concentrations in excess of 150 ppb; on some days, peak O{sub 3} concentrations were in excess of 200 ppb. These ozone plumes were rapidly formed with an efficiency (O{sub 3} per NO{sub x} molecule consumed) much higher (7-20) than observed in other urban areas (3-4), and were frequently associated with high concentrations (>20 ppb) of secondary hydrocarbon species such as formaldehyde. Back trajectory analysis showed that the plumes were invariably associated with emissions from one or more of the large industrial complexes clustered about the Houston Ship Channel and Galveston Bay. Very high hydrocarbon reactivities were found in the vicinity of these facilities during morning flights. These hydrocarbon reactivities, in combination with local NO{sub x} emissions, were large enough to support instantaneous O{sub 3} production rates as high as 200 ppb/h. It is hypothesized that the combination of nitrogen oxides and hydrocarbon emissions emanating from this complex of industries provided a potent mixture of chemicals that caused the rapid formation of very high concentrations of ozone which, depending on the prevailing meteorology, could cause exceedance of the NAAQS ozone standard anywhere in the Houston metropolitan area.

DAUM,P.H.; KLEINMAN,L.I.; BRECHTEL,F.; LEE,Y.N.; NUNNERMACKER,L.J.; SPRINGSTON,S.R.; WEINSTEIN-LLOYD,J.

2001-10-01T23:59:59.000Z

138

Ozone Depletion and Global Warming.  

E-Print Network (OSTI)

??Abstract This thesis examines global warming and the possible contribution that ozone depletion provides to this warming. An examination is performed to determine the extent… (more)

Fow, Alista John

2006-01-01T23:59:59.000Z

139

Annual and Seasonal Global Variation in Total Ozone and Layer-Mean Ozone,  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Ozone » Total Ozone and Layer-Mean Ozone Atmospheric Trace Gases » Ozone » Total Ozone and Layer-Mean Ozone Annual and Seasonal Global Variation in Total Ozone and Layer-Mean Ozone, 1958-1987 (1991) DOI: 10.3334/CDIAC/atg.ndp023 data Data Investigators J. K. Angell, J. Korshover, and W. G. Planet Description For 1958 through 1987, this data base presents total ozone variations and layer mean ozone variations expressed as percent deviations from the 1958 to 1977 mean. The total ozone variations were derived from mean monthly ozone values published in Ozone Data for the World by the Atmospheric Environment Service in cooperation with the World Meteorological Organization. The layer mean ozone variations are derived from ozonesonde and Umkehr observations. The data records include year, seasonal and annual

140

Probing into regional ozone and particulate matter pollution in the United States  

E-Print Network (OSTI)

) and fine particulate matter (PM2.5) air pollution and associated health effects have been one of the majorProbing into regional ozone and particulate matter pollution in the United States: 1. A 1 year CMAQ-term simulations using the Community Multiscale Air Quality (CMAQ) modeling system and subsequent process analyses

Jacobson, Mark

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani  

E-Print Network (OSTI)

in air pollution studies because of their impact on human health and agricultural crops and forests. High,guariso@elet.polimi.it Abstract: Ground level ozone pollution is a complex phenomenon heavily affecting industrialized and pop problem that determines the least cost alternatives to obtain a given air quality standard. The decision

Corani, Giorgio

142

Dispersant solutions for dispersing hydrocarbons  

DOE Patents (OSTI)

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, R.L.

1997-03-11T23:59:59.000Z

143

Modelling the Impact of Energy Transitions on Air Quality and Source Receptor Relations  

Science Journals Connector (OSTI)

Air pollution is associated with adverse effects on human health through exposure to PM and ozone. To design effective air pollution mitigation strategies it is essential to quantify the effect of pollutant emiss...

C. Hendriks; J. Kuenen; R. Kranenburg…

2014-01-01T23:59:59.000Z

144

Carbon neutral hydrocarbons  

Science Journals Connector (OSTI)

...depends on a source of primary energy to drive the required chemical...synthetic hydrocarbons are an energy carrier produced from a primary energy source such as wind, nuclear...Gustavsson et al. 2007), using a conversion value of $1.00=0.72...

2008-01-01T23:59:59.000Z

145

Optrode for sensing hydrocarbons  

DOE Patents (OSTI)

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1987-01-01T23:59:59.000Z

146

Optrode for sensing hydrocarbons  

DOE Patents (OSTI)

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 5 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1988-09-13T23:59:59.000Z

147

Optrode for sensing hydrocarbons  

DOE Patents (OSTI)

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 6 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1987-05-19T23:59:59.000Z

148

Optrode for sensing hydrocarbons  

DOE Patents (OSTI)

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1988-01-01T23:59:59.000Z

149

Air Quality Standards & ATOC/CHEM 5151  

E-Print Network (OSTI)

1 Lecture 22 Air Quality Standards & Control ATOC/CHEM 5151 #12;2 Primary Pollutants Things to reduce air pollution emissions ­ Latest version ­ 1990 (original, 1963) ­ What is an "air pollutant that are directly emitted Nitrogen Oxides (NOx) Hydrocarbons (VOCs) Carbon Monoxide (CO) #12;3 Secondary Pollutants

Toohey, Darin W.

150

6, 39133943, 2006 Svalbard total ozone  

E-Print Network (OSTI)

(Farman et al., 1985) and25 global ozone layer reduction, the chemical and dynamical processes causing

Boyer, Edmond

151

Enhancement of Local Air Pollution by Urban CO2 Domes  

Science Journals Connector (OSTI)

For this study, the nested global-through-urban 3-D model, GATOR-GCMOM (13-17) was used to examine the effects of locally emitted CO2 on local climate and air pollution. ... Jacobson, M. Z. GATOR-GCMM: 2. A study of day- and nighttime ozone layers aloft, ozone in national parks, and weather during the SARMAP Field Campaign J. Geophys. ... GATOR-GCMM 2. A study of daytime and nighttime ozone layers aloft, ozone in national parks, and weather during the SARMAP field campaign ...

Mark Z. Jacobson

2010-03-10T23:59:59.000Z

152

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network (OSTI)

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

153

Investigation of formaldehyde and acetaldehyde sampling rate and ozone  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigation of formaldehyde and acetaldehyde sampling rate and ozone Investigation of formaldehyde and acetaldehyde sampling rate and ozone interference for passive deployment of Waters Sep-Pak XPoSure samplers Title Investigation of formaldehyde and acetaldehyde sampling rate and ozone interference for passive deployment of Waters Sep-Pak XPoSure samplers Publication Type Journal Article Year of Publication 2013 Authors Mullen, Nasim A., Marion L. Russell, Melissa M. Lunden, and Brett C. Singer Journal Atmospheric Environment Volume 80 Pagination 184-189 Date Published 12/2013 Keywords aldehyde; exposure; indoor air quality; passive sampler; residential Abstract This study investigated formaldehyde and acetaldehyde passive sampling rates and ozone interference for the DNPH-based Waters Sep-Pak XPoSure sampler. Previous studies have shown that ozone interferes with active sampling by this cartridge. Our study included one laboratory and six field experiments conducted in Northern California homes. Passive sampling rates of 1.10 ± 0.09 and 0.86 ± 0.10 mL/min determined for formaldehyde and acetaldehyde are lower than previously reported. In a controlled laboratory experiment there were small, statistically insignificant impacts of subsequent ozone exposure on formaldehyde and acetaldehyde mass passively collected on the samplers. This sampler is inexpensive, easy to deploy and to transport by mail, and has a high sampling capacity when used passively; it is suitable for a wide-range of monitoring applications. However, the passive sampling rate remains in question given the internally consistent, but different results obtained in our study and the previous study.

154

Pulsed ozone generation in oxygen  

SciTech Connect

Ozone is a powerful oxidant and bactericide which is increasingly replacing chlorine in applications such as potable water treatment, swimming pool water sterilisation and bleaching. Ozone can be produced in a number of ways but the conventional method (1) is by producing an AC barrier discharge in a uniform-field arrangement containing a thin dielectric barrier. The process is highly inefficient with most of the energy supplied being converted to unwanted heat. Thus ozone treatment, although environmentally {open_quotes}friendly{close_quotes}, tends to be more costly and so there is a compelling argument for investigating ways of increasing the efficiency.

Chalmers, I.D.; Zanella, L.; MacGregor, S.J. [Univ. of Strathclyde, Glasgow (Germany)] [and others

1995-12-31T23:59:59.000Z

155

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

SciTech Connect

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

156

Radical scavengers from heavy hydrocarbons  

SciTech Connect

The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

Kubo, Junichi [Nippon Oil Co. Ltd. (Japan)

1996-10-01T23:59:59.000Z

157

Urban Form and Air Pollution in US Urban Areas!  

E-Print Network (OSTI)

of Minnesota Grant No. 0853467 #12;Air Pollution Impacts on Health 2 EPA, 2010 Ozone PM2.5 PM10 Lead NitrogenUrban Form and Air Pollution in US Urban Areas! Center for Transportation Studies Research #12;Purpose and Research Questions 4 Purpose: Explore relationship between air pollution and urban

Minnesota, University of

158

Predictability of European air quality: Assessment of 3 years of operational forecasts and analyses by the PREV'AIR system  

E-Print Network (OSTI)

- ments are still needed to manage and control the impacts of air pollution on health. [3] Facing, is proved to improve ozone forecasts, especially when photochemical pollution episodes occur. The PREV'AIR and laws regarding the pollutants of utmost importance in relation to human health, air pollution is still

Menut, Laurent

159

Continuous air agglomeration method for high carbon fly ash beneficiation  

DOE Patents (OSTI)

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahon L. (Pittsburgh, PA); Champagne, Kenneth J. (Monongahela, PA); Finseth, Dennis H. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

160

Continuous air Agglomeration Method for high Carbon fly ash Beneficiation  

SciTech Connect

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carbon-free mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

Gray, McMahan L.; Champagne, Kenneth J.; Finseth, Dennis H.

1998-09-29T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Evaluation and selection of an efficient fuel/air initiation strategy for pulse detonation engines .  

E-Print Network (OSTI)

??Rapid and efficient initiation of hydrocarbon/air mixtures has been identified as one of the critical and enabling technologies for Pulse Detonation Engines (PDEs). Although the… (more)

Channell, Brent T.

2005-01-01T23:59:59.000Z

162

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network (OSTI)

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

163

The Utilization of Certain Hydrocarbons by Microorganisms  

Science Journals Connector (OSTI)

...UTILIZATION OF CERTAIN HYDROCARBONS BY MICROORGANISMS...1940 INTRODUCTION Hydrocarbons, as a class, represent...obtained by comparing the heat of combustion of some six carbon...biological utilization of hydrocarbons as sources of energy...

L. D. Bushnell; H. F. Haas

1941-05-01T23:59:59.000Z

164

Interaction between Carcinogenic Hydrocarbons and Nucleosides  

Science Journals Connector (OSTI)

...addition, the findings that hydrocarbons inhibit DNA syn thesis...for these carcinogens. Hydrocarbon-nucleic acid interaction...and the interactions of water molecules. Indeed, carcinogenic hydrocarbons tend to form 1 This investigation...

Ronald G. Harvey and Marilyn Halonen

1968-11-01T23:59:59.000Z

165

Enhanced liquid hydrocarbon recovery process  

SciTech Connect

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

166

Hydrocarbon sensors and materials therefor  

DOE Patents (OSTI)

An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

2000-01-01T23:59:59.000Z

167

Page 2 of 4 TREE Cookies Etc. Trees & Air-continued  

E-Print Network (OSTI)

#12;Page 2 of 4 TREE Cookies Etc. Trees & Air- continued pollutants include ozone, sulfur dioxide of trees on air pollution. The research on trees and air pollution is rather new and still ongoing, nitrogen dioxide, and carbon monoxide. These are taken out of the air by trees primarily through leaf

Liskiewicz, Maciej

168

Process for recovering hydrocarbons from a hydrocarbon-bearing formation  

SciTech Connect

A method is described for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

Alston, R.B.; Braden, W.B.; Flournoy, K.H.

1980-03-11T23:59:59.000Z

169

Examination of U.S. Environmental Regulatory Criteria for Ozone from a Statistical Perspective  

E-Print Network (OSTI)

quality remediation plan aimed at achieving compliance with the standard, typically a lengthy and costly and O'Hagan, 1997; Cox et al. 1999). In the United States, recent review of National Ambient Air Quality Standards led to revision of the U.S. regulatory criteria for ambient ozone and particulate matter

Washington at Seattle, University of

170

Isotope Evidence for Ozone Formation on Surfaces  

Science Journals Connector (OSTI)

Remarkably, the gas-phase recombination or association reaction of ozone has an unusually large (?10%) isotope effect and shows almost equal enrichments of the ozone molecules containing two different oxygen isotopes. ... For a better understanding of the pressure and temperature dependence of ozone isotopic composition in oxygen discharges, we developed a relatively simple isotope kinetic model that accounts for the processes of (i) heterogeneous ozone formation at the reactor walls, (ii) isotope exchange of oxygen atoms with O2 molecules, and (iii) ozone formation in the gas phase. ...

Christof Janssen; Béla Tuzson

2010-05-06T23:59:59.000Z

171

Carbon neutral hydrocarbons  

Science Journals Connector (OSTI)

...than gasoline-powered cars (Tesla Motors 2008...system based on nuclear power. Prog. Nucl. Energy...Farrell2003Rethinking hydrogen cars. Science. 301, 315-316...methanol from air and water using controlled thermonuclear reactor power I-technology and energy...

2008-01-01T23:59:59.000Z

172

Ozone decomposition in water solutions  

E-Print Network (OSTI)

. Hewes, III; B. S. , Texas ASH University Directed by Dr. R. R. Davison The rate of the decomposition of ozone in water solutions at various pH's and temperatures were ob- tained by an iodometrical method. The orders of the reactions and the reaction...

Hewes, Cecil Grayson

1969-01-01T23:59:59.000Z

173

6, 74277469, 2006 Linear ozone  

E-Print Network (OSTI)

from biases in the schemes' climatology coefficients. Cariolle v2.1 analyses showed biases of up to 20 and Kelder (1998) ozone climatology into the scheme. Chem2D-OPP v2.1 analyses showed biases up to 20 analysed temperatures and the temperature climatology supplied with the scheme. Future developments should

Boyer, Edmond

174

Seasonal versus Episodic Performance Evaluation for an Eulerian Photochemical Air Quality Model  

SciTech Connect

This study presents detailed evaluation of the seasonal and episodic performance of the Community Multiscale Air Quality (CMAQ) modeling system applied to simulate air quality at a fine grid spacing (4 km horizontal resolution) in central California, where ozone air pollution problems are severe. A rich aerometric database collected during the summer 2000 Central California Ozone Study (CCOS) is used to prepare model inputs and to evaluate meteorological simulations and chemical outputs. We examine both temporal and spatial behaviors of ozone predictions. We highlight synoptically driven high-ozone events (exemplified by the four intensive operating periods (IOPs)) for evaluating both meteorological inputs and chemical outputs (ozone and its precursors) and compare them to the summer average. For most of the summer days, cross-domain normalized gross errors are less than 25% for modeled hourly ozone, and normalized biases are between {+-}15% for both hourly and peak (1 h and 8 h) ozone. The domain-wide aggregated metrics indicate similar performance between the IOPs and the whole summer with respect to predicted ozone and its precursors. Episode-to-episode differences in ozone predictions are more pronounced at a subregional level. The model performs consistently better in the San Joaquin Valley than other air basins, and episodic ozone predictions there are similar to the summer average. Poorer model performance (normalized peak ozone biases <-15% or >15%) is found in the Sacramento Valley and the Bay Area and is most noticeable in episodes that are subject to the largest uncertainties in meteorological fields (wind directions in the Sacramento Valley and timing and strength of onshore flow in the Bay Area) within the boundary layer.

Jin, Ling; Brown, Nancy J.; Harley, Robert A.; Bao, Jian-Wen; Michelson, Sara A; Wilczak, James M

2010-04-16T23:59:59.000Z

175

Improving Regional Air Quality with Wind Power  

Wind Powering America (EERE)

Improving Regional Air Quality with Improving Regional Air Quality with Wind Power National Renewable Energy Laboratory Improving Regional Air Quality with Wind Power National Renewable Energy Laboratory * Clean Air Act (CAA) framework * Air quality challenges * CAA policies as market drivers * Met. Wash. Council of Governments (MWCOG) case study * Environmental Protection Agency (EPA) guidance on State Implementation Plan (SIP) credit for EERE * Model SIP documentation for wind purchases * Related marketing innovations Overview Overview * CAA requires regional air quality plans (SIPs) * "Window of opportunity" - Revised SIPs required by 2006/2007 to meet new 8-hour ozone and PM standards - August 2004 EPA guidance and NREL model SIP documentation for wind purchases Clean Air Act Framework Clean Air Act Framework

176

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

177

A new technology for producing synthetic liquid hydrocarbons from gaseous hydrocarbons  

Science Journals Connector (OSTI)

Conventional technologies of synthetic liquid fuels (SLF) production from gaseous hydrocarbons by producing synthesis ... liquid hydrocarbons are examined. A high-efficiency SLF production technology that allows ...

D. L. Astanovskii; L. Z. Astanovskii; A. L. Lapidus

2012-09-01T23:59:59.000Z

178

Anthocyanins and tannins: is the urban air pollution an elicitor factor?  

Science Journals Connector (OSTI)

(Anthocyanins and tannins: is the urban air pollution an elicitor factor?) In order to...Psidium guajava cv. Paluma (guava), which is described as an efficient bio-indicator of tropospheric ozone, by displaying t...

Adriana Afonso Sandre; Juliana Moreno Pina…

2014-03-01T23:59:59.000Z

179

An integrated assessment of air pollutant abatement opportunities in a computable general equilibrium framework  

E-Print Network (OSTI)

Air pollution and anthropogenic greenhouse gas emission reduction policies are desirable to reduce smog, tropospheric concentrations of ozone precursors, acid rain, and other adverse effects on human health, the environment, ...

Waugh, C. (Caleb Joseph)

2012-01-01T23:59:59.000Z

180

Investigation of Methods of Disinfection in an All-air System  

E-Print Network (OSTI)

The experiment of removing bacteria and indoor air particulates by a bag ventilation filter with synthetic media and an electrostatic filter was carried out, and the effect of killing bacteria by ozone application was also tested. The results show...

Wang, J.; Yan, Z.

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Assessing the regional impacts of Mexico City emissions on air quality and chemistry  

E-Print Network (OSTI)

The impact of Mexico City (MCMA) emissions is examined by studying its effects on air quality, photochemistry, and on ozone production regimes by combining model products and aircraft observations from the MILAGRO experiment ...

Mena-Carrasco, Marcelo

182

E-Print Network 3.0 - air transport division Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

29--2010 TRANSPORTATION ENERGY DATA BOOK: EDITION 29--2010 Summary: in areas with ozone-air pollution problems. 12;C-8 TRANSPORTATION ENERGY DATA BOOK: EDITION 29--2010 12;......

183

Project Title: Air Quality Monitoring in the Coastal Environment of Miami Professor's name: Xinrong Ren________________________________________ ______ _  

E-Print Network (OSTI)

on the campus of the Rosenstiel School of Marine and Atmospheric Science. Atmospheric pollutants include ozone in this project will learn basic knowledge of atmospheric science and air pollution, operate some environmental Ren________________________________________ ______ _ Department: Marine and Atmospheric Chemistry

Miami, University of

184

Air Conditioning  

Science Journals Connector (OSTI)

Air Conditioning ... CHEMISTS and engineers use air conditioning as a valuable tool in more than two hundred industries. ... Air conditioning is a tool with many facets. ...

MARGARET INGELS

1938-02-10T23:59:59.000Z

185

Discharge cell for ozone generator  

DOE Patents (OSTI)

A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

Nakatsuka, Suguru (Amagasaki, JP)

2000-01-01T23:59:59.000Z

186

Ozone bleaching of recycled paper  

SciTech Connect

Chlorinated bleaching chemicals, notably chlorine and hypochlorite, are still being used to bleach deinked, woodfree pulps. Increasing environmental concern about the use of these chemicals--coupled with the industry's efforts to increase the use of recycled fibers--highlight the need to develop better techniques for producing high-quality deinked pulp. Results presented in this report suggest that deinked fibers can be treated with ozone followed by a peroxide bleaching stage to produce a high-quality pulp.

Muguet, M.; Kogan, J. (American Air Liquide, Countryside, IL (United States))

1993-11-01T23:59:59.000Z

187

DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

188

Proceedings: Indoor Air 2005 A PRELIMINARY FIELD STUDY OF INDOOR CHEMISTRY  

E-Print Network (OSTI)

is to assess the impact of outdoor ozone on indoor air quality (IAQ) during photochemical pollution episodes). Based on the Paris area outdoor air pollution monitoring network (AIRPARIF) daily forecast, specificProceedings: Indoor Air 2005 1739 A PRELIMINARY FIELD STUDY OF INDOOR CHEMISTRY M Nicolas, O

Boyer, Edmond

189

Air Pollution Impacts in the Mixed Conifer Forests of Southern California1  

E-Print Network (OSTI)

in a forest ecosystem. Key words: air pollution, forest health, nitrogen deposition, ozone, San BernardinoAir Pollution Impacts in the Mixed Conifer Forests of Southern California1 Patrick J. Temple, Andrzej Bytnerowicz, Mark E. Fenn, and Mark A. Poth2 Abstract Air pollution, principally in the form

Standiford, Richard B.

190

The Effects of Climate and Electricity Emissions on Air Quality in the United States  

E-Print Network (OSTI)

The Effects of Climate and Electricity Emissions on Air Quality in the United States by Steven D and Motivation 1 A. Background ­ Ozone and Fine Particulate Matter 2 B. The National Ambient Air Quality Standards 4 C. Improving Future Air Quality 6 D. Research Overview 8 Figures 10 References 15 Chapter 2

Wisconsin at Madison, University of

191

Clean Air Act | Open Energy Information  

Open Energy Info (EERE)

Clean Air Act Clean Air Act Jump to: navigation, search Statute Name Clean Air Act Year 1970 Url CAA.jpg Description Congress passed the CAA in 1970 in order to combat air pollution in the United States and protect the health and general welfare of United States citizens against air pollutants. References CAA[1] Federal Oil and Gas[2] Contents 1 Introduction 2 Title I Air Pollution Prevention 3 Title II Emission Standards for Moving Sources 4 Title III General Provisions 5 Title IV Acid Deposition Control 6 Title V Permits 7 Title VI Stratospheric Ozone Protection 8 References Introduction The Clean Air Act was enacted by congress in 1990. Since then only minor changes have been made. The act is just a law ensuring that the EPA will follow certain guidelines and definitions for protecting and improving the

192

Enrichment of light hydrocarbon mixture  

DOE Patents (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

193

Federal Environmental Regulations Impacting Hydrocarbon Exploration, Drilling, and Production Operations  

SciTech Connect

Waste handling and disposal from hydrocarbon exploration, drilling, and production are regulated by the US Environmental Protection Agency (EPA) through federal and state regulations and/or through implementation of federal regulations. Some wastes generated in these operations are exempt under the Resource Conservation and Recovery Act (RCRA) but are not exempt under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act (SARA), and other federal environmental laws. Exempt wastes remain exempt only if they are not mixed with hazardous wastes or hazardous substances. Once mixture occurs, the waste must be disposed as a hazardous material in an approved hazardous waste disposal facility. Before the Clean Air Act as amended in 1990, air emissions from production, storage, steam generation, and compression facilities associated with hydrocarbon exploration, drilling, and production industry were not regulated. A critical proposed regulatory change which will significantly effect Class II injection wells for disposal of produced brine and injection for enhanced oil recovery is imminent. Federal regulations affecting hydrocarbon exploration, drilling and production, proposed EPA regulatory changes, and a recent significant US Court of Appeals decision are covered in this report. It appears that this industry will, in the future, fall under more stringent environmental regulations leading to increased costs for operators.

Carroll, Herbert B.; Johnson, William I.

1999-04-27T23:59:59.000Z

194

Biological enhancement of hydrocarbon extraction  

DOE Patents (OSTI)

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

195

Fluorescence Detection of Hydrocarbons in Harbour Water  

Science Journals Connector (OSTI)

In harbor water, the hydrocarbons pollution identification represents an important issue. Hydrocarbon presence derives from oil spills, for instance in bilge water, or it may come from industrial discharge ... Fl...

A. Catini; F. Dini; D. Polese; S. Petrocco; M. De Luca…

2011-01-01T23:59:59.000Z

196

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...  

NLE Websites -- All DOE Office Websites (Extended Search)

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

197

Extracting hydrocarbons from water using a centrifuge  

Science Journals Connector (OSTI)

An original method for the solid-phase microextraction of hydrocarbons from water using a centrifuge is proposed. Comparative results...

A. Yu. Ryabov; A. A. Ilyina; A. V. Chuikin…

2014-09-01T23:59:59.000Z

198

Photo-oxides of Carcinogenic Hydrocarbons  

Science Journals Connector (OSTI)

... are involved in the biological action of carcinogenic hydrocarbons, we have attempted to isolate the photo-oxides of some of these hydrocarbons. Such ... -oxides of some of these hydrocarbons. Such photo-oxides would naturally be insoluble in water and hence would represent merely one stage in ...

J. W. COOK; R. MARTIN; E. M. F. ROE

1939-06-17T23:59:59.000Z

199

Failure of ozone and nitrogen dioxide to enhance lung tumor development in hamsters  

SciTech Connect

We tested the hypothesis that the two common oxidant air pollutants, ozone and nitrogen dioxide, modulate the development of respiratory tract tumors in Syrian golden hamsters. The animals received subcutaneous injections of the carcinogen diethylnitrosamine (20 mg/kg) twice a week while being exposed continuously to an atmosphere of 0.8 parts per million (ppm)* of ozone or 15 ppm of nitrogen dioxide. Animals were killed 16 weeks or 24 to 32 weeks after the beginning of the treatment. Ozone delayed the appearance of tracheal tumors and reduced the incidence of tumors in the lung periphery. A suspected neuroendocrine differentiation of those lung tumors could not be established by immunocytochemistry due to overfixation of tissues. On the other hand, ozone seemed to mitigate development of hepatotoxic lesions mediated by diethylnitrosamine. In animals treated with diethylnitrosamine and exposed to nitrogen dioxide, fewer tracheal tumors and no lung tumors were found. Only a few lung tumors were produced in animals treated with diethylnitrosamine and kept in an atmosphere of 65% oxygen. The previously observed neuroendocrine nature of tumors induced by simultaneous exposure to diethylnitrosamine and hyperoxia could not be established because the long fixation of tissues precluded immunocytochemical stains. Animals treated with diethylnitrosamine and kept in filtered air while being housed in wire-mesh cages developed fewer lung tumors than animals given the same treatment and kept on conventional bedding in shoebox cages. Although all inhalants tested are known to produce substantial cell proliferation in the respiratory tract, it was not possible to document whether this would enhance lung tumor development. The role of the two common air pollutants, ozone and nitrogen dioxide, as possible additional risks in the pathogenesis of lung cancer in animals continues to remain uncertain.

Witschi, H.; Breider, M.A.; Schuller, H.M. (Univ. of California, Davis, CA (United States))

1993-09-01T23:59:59.000Z

200

Ozone and life on the Archaean Earth  

Science Journals Connector (OSTI)

...John Raven Ozone and life on the Archaean Earth Charles S Cockell 1 * John A Raven 2...cockell@open.ac.uk ) 1 Centre for Earth, Planetary, Space and Astronomical Research...column abundance. On the anoxic Archaean Earth, such an ozone screen would not have existed...

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Catalytic steam reforming of hydrocarbons  

SciTech Connect

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

202

The effect of marine isoprene emissions on secondary organic aerosol and ozone formation in the coastal United States  

E-Print Network (OSTI)

The effect of marine isoprene emissions on secondary organic aerosol and ozone formation) in the coastal areas of the continental United States is studied using the U.S. Environmental Protection Agency regional-scale Community Multiscale Air Quality (CMAQ) modeling system. Marine isoprene emission rates

Zhang, Yang

203

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

Energy.gov (U.S. Department of Energy (DOE))

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

204

Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives  

SciTech Connect

Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Brunner, Gregory; Zhang, Jianshun (Jensen); Fisk, William J.

2011-05-01T23:59:59.000Z

205

Evaluation of open pit incineration for the disposal of hydrocarbon wastes  

E-Print Network (OSTI)

of hydrocarbon wastes using an open pit air curtain destructor (ACD) type incinerator was investigated. A prototype experi- mental incinerator was designed and constructed, and experiments were performed with it to determine the relationships among various... design and operational parameters (such as incinerator configuration, fuel flow- rate, and smoke emissions) and to further improve the design. The investigation was conducted in three phases. First air flow studies were performed using a full scale...

Bell, Stuart Ray

1981-01-01T23:59:59.000Z

206

NETL: IEP - Air Quality Research: Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

Regulatory Drivers Regulatory Drivers DOE/NETLÂ’s Air Quality Research Program is in direct response to the need to ensure that fossil-fuel-fired power systems continue to meet current and future environmental requirements. Specific environmental regulatory requirements driving this research are briefly summarized below: I. Clean Air Act (Including 1990 Amendments) Title I - Air Pollution Prevention and Control Part A - Air Quality and Emission Limitations Sect. 109 - National Ambient Air Quality Standards In July 1997 EPA promulgated new standards for particulate matter finer than 2.5 micrometers (PM2.5) and revised the ambient ozone standards. Sect. 111 - Standards of Performance for New Stationary Sources Part C - Prevention of Significant Deterioration of Air Quality

207

AIR POLLUTION: Diesel Fuel Culprits  

Science Journals Connector (OSTI)

AIR POLLUTION: Diesel Fuel Culprits ... Low-molecular-weight components aren't necessarily the true culprits of diesel fuel pollution, although they do contribute to it, according to Hertha Skala, assistant director of research, and her coworkers F. G. Padrta and P. C. Samson at Universal Oil Products. ... At the first national symposium on heterogeneous catalysis for control of air pollution, sponsored by Philadelphia's Franklin Institute, Mrs. Skala identified five different classes of oxygenated hydrocarbons found over the full molecular-weight range of diesel fuel components. ...

1968-12-02T23:59:59.000Z

208

Comparisons of air quality impacts of fleet electrification and increased use of  

Science Journals Connector (OSTI)

The air quality impacts of the partial electrification of the transportation fleet and the use of biofuels (E85) were modeled for the Austin Metropolitan Statistical Area, based on a 2030 vision of regional development. Changes in ozone precursor emissions and predicted ozone, carbon monoxide and aldehyde concentrations were estimated for multiple electrification and biofuel scenarios. Maximum changes in hourly ozone concentration from the use of plug-in hybrid electric vehicles (PHEVs) for 17% of the vehicle miles traveled ranged from ? 8.5 to 2.2 ppb, relative to a base case with no electrification and minimal biofuel use, depending on time of day and location. Differences in daily maximum 1 h ozone concentration ranged from ? 2.3 to 0.004 ppb. Replacement of all gasoline fuels with E85 had a smaller effect than PHEVs on maximum daily ozone concentrations. Maximum ozone changes for this scenario ranged from ? 2.1 to 2.8 ppb and the difference in daily maximum 1 h ozone concentrations ranged from ? 1.53 to 0 ppb relative to the base case. The smaller improvements in maximum ozone concentrations associated with extensive (100%) use of biofuels, compared to a smaller (17%) penetration of PHEVs, suggests that higher levels of PHEV penetration may lead to even greater improvements; however, the higher penetration would require expansion of the electrical grid capacity. The air quality impacts of the PHEVs would then depend on the emissions associated with the added generation.

Nawaf S Alhajeri; Elena C McDonald-Buller; David T Allen

2011-01-01T23:59:59.000Z

209

Effects of Plug-In Hybrid Electric Vehicles on Ozone Concentrations in Colorado  

Science Journals Connector (OSTI)

Effects of Plug-In Hybrid Electric Vehicles on Ozone Concentrations in Colorado ... Changes in PM10 and PM2.5 concentrations in Colorado (and most areas of the western U.S. outside California) were negligible. ... The biogenic, area, and mobile source inventories were provided by the National Park Service (17) based on an updated version of the Western Regional Air Partnership (WRAP) inventories from 2002 used for the Rocky Mountain Atmospheric Nitrogen and Sulfur (RoMANS) study. ...

Gregory L. Brinkman; Paul Denholm; Michael P. Hannigan; Jana B. Milford

2010-07-15T23:59:59.000Z

210

OZONE TREATMENT OF SOLUBLE ORGANICS IN PRODUCED WATER (FEAC307)  

SciTech Connect

Oil production is shifting from ''shallow'' wells (0-650 ft water depth) to off-shore, deep-water operations (>2,600 ft.). Production from these operations is now approaching 20%. By 2007, it is projected that as much as 70% of the U.S. oil production will be from deep-water operations. The crude oil from these deep wells is more polar, thus increasing the amount of dissolved hydrocarbons in the produced water. Early data from Gulf of Mexico (GOM) wells indicate that the problem with soluble organics will increase significantly as deep-water production increases. Existing physical/chemical treatment technologies used to remove dispersed oil from produced water will not remove dissolved organics. GOM operations are rapidly moving toward design of high-capacity platforms that will require compact, low-cost, efficient treatment processes to comply with current and future water quality regulations. This project is an extension of previous research to improve the applicability of ozonation and will help address the petroleum industry-wide problem of treating water containing soluble organics. The goal of this project is to maximize oxidation of water-soluble organics during a single-pass operation. The project investigates: (1) oxidant production by electrochemical and sonochemical methods, (2) increasing the mass transfer rate in the reactor by forming microbubbles during ozone injection into the produced water, and (3) using ultraviolet irradiation to enhance the reaction if needed. Industrial collaborators include Chevron, Shell, Phillips, BP Amoco, Statoil, and Marathon Oil through a joint project with the Petroleum Environmental Research Forum (PERF). The research and demonstration program consists of three phases: (1) Laboratory testing in batch reactors to compare effectiveness of organics destruction using corona discharge ozone generation methods with hydrogen peroxide generated sonochemically and to evaluate the enhancement of destruction by UV light and micro-bubble spraying. (2) Continuous-flow studies to determine the efficacy of various contactors, the dependency of organics destruction on process variables, and scale-up issues. (3) Field testing of a prototype system in close collaboration with an industrial partner to generate performance data suitable for scale-up and economic evaluation.

Klasson, KT

2001-03-20T23:59:59.000Z

211

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

212

Enhanced liquid hydrocarbon recovery process  

SciTech Connect

This patent describes a process for the recovery of liquid hydrocarbons from a subterranean hydrocarbon-bearing formation. It comprises injecting natural gas into the formation via a well in fluid communication with the formation, the natural gas being at a temperature which is insufficient to significantly mobilize light density oil in the formation and at a pressure such that the natural gas is immiscible with the light density oil in the formation, the natural gas being injected in a volume sufficient to contact light density oil in the formation within a radius from the well of about 50 meters; shutting in the well for a period of time of about 1 to about 100 days which is sufficient to render the contacted light density oil mobile; and producing the light density oil which has been mobilized by solution of the natural gas from the well.

Haines, H.K.; Monger, T.G.; Kenyon, D.E.; Galvin, L.J.

1991-06-25T23:59:59.000Z

213

Dry reforming of hydrocarbon feedstocks  

SciTech Connect

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

214

Discharge produces hydrocarbons from coal  

Science Journals Connector (OSTI)

Discharge produces hydrocarbons from coal ... Studies of the reactions of coal in electric discharges by two chemists at the U.S. Bureau of Mines' Pittsburgh Coal Research Center may lead to improved ways of producing acetylene and other useful chemicals from coal. ... Other workers have produced high yields of acetylene from coal by extremely rapid pyrolysis using energy sources such as plasma jets, laser beams, arc-image reactors, and flash heaters. ...

1968-01-22T23:59:59.000Z

215

Deep desulfurization of hydrocarbon fuels  

DOE Patents (OSTI)

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

216

A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine  

E-Print Network (OSTI)

to prevent injury from other pollutants (Manning, 1992). It has been widely reported that ethylenediurea protects plants from ozone foliar injury (Bennett et al. , 1978; Lee et al. , 198 la; Clarke et al. , 1990', Whitaker et al. , 1990; Kostka-Rick... & Manning, 1991; 1992) as well as early senescence due to ozone damage (Temple & Bisessar, 1979; Lee et al. , 1981a; Kostka-Rick et al. , 1991). Ozone pretnaturely ages the leaf, and EDU counteracts these effects by enhancing cellular carbohydrates...

Posey, Karen Lashea

1995-01-01T23:59:59.000Z

217

Compressed Air  

NLE Websites -- All DOE Office Websites (Extended Search)

BPA Utility Reimbursement Programs for Compressed Air Projects Customer Proposal Template Measurement & Verification Plan for Compressed Air CA 2006-15 A template for utilities to...

218

Low severity hydrocarbon steam reforming process  

SciTech Connect

A process is described for producing ammonia which comprises: (a) primary catalytically reforming at super atmospheric pressure in a direct-fired primary reforming zone, a hydrocarbon feedstock with steam to produce a gas containing carbon oxides, hydrogen and methane; (b) secondary catalytically reforming the gas from step (a) by introducing air and bringing the mixture towards equilibrium thereby producing a secondary reformer effluent gas containing nitrogen, carbon oxides, hydrogen and a decreased quantity of methane; (c) converting carbon monoxide catalytically with steam to carbon dioxide and hydrogen; (d) removing carbon oxides to give an ammonia synthesis gas comprising nitrogen and hydrogen and compressing the gas to ammonia synthesis pressure; (e) reacting the synthesis gas in an ammonia synthesis zone to produce ammonia and recovering ammonia from the reacted gas to produce an ammonia-depleted gas stream; (f) recycling at least a portion of the ammonia-depleted gas stream to the ammonia synthesis zone; and (g) treating a sidestream of the ammonia-depleted gas to separate a stream enriched in hydrogen and an inerts-enriched gas stream, and returning the enriched hydrogen stream to the ammonia synthesis zone.

Osman, R.M.; Byington, R.G.

1986-06-03T23:59:59.000Z

219

INFLUENCE OF ELEVATED OZONE AND CARBON DIOXIDE ON INSECT DENSITIES.  

SciTech Connect

The combustion of fossil fuels is profoundly altering the chemical composition of the atmosphere. Beginning with the Industrial Revolution, the concentration of carbon dioxide in the atmosphere has increased from approximately 280 to 370 {micro}l l{sup -1} in 2004, and it is expected to exceed 550 {micro}l l{sup -1} by 2050. Tropospheric ozone has risen even more rapidly than CO{sub 2} and average summer concentrations in the Northern Hemisphere are expected to continue to increase by 0.5-2.5% per year over the next 30 years. Although elevated CO{sub 2} stimulates photosynthesis and productivity of terrestrial ecosystems, ozone (O{sub 3}) is deleterious. In addition to directly affecting the physiology and productivity of crops, increased concentrations of tropospheric CO{sub 2} and O{sub 3} are predicted to lower the nutritional quality of leaves, which has the potential to increase herbivory as insects eat more to meet their nutritional demands. We tested the hypothesis that changes in tropospheric chemistry affect the relationship between plants and insect herbivores by changing leaf quality. The susceptibility to herbivory of soybean grown in elevated CO{sub 2} or O{sub 3} was examined using free air gas concentration enrichment (SoyFACE). FACE technology has the advantage that plants are cultivated under realistic field conditions with no unwanted alteration of microclimate or artificial constraints on the insect community.

DELUCIA, E.; DERMODY, O.; O'NEILL, B.; ALDEA, M.; HAMILTON, J.; ZANGERL, A.; ROGER, A.; BERENBAUM, M.

2005-01-05T23:59:59.000Z

220

Ozone treatment of biomass to enhance digestibility  

E-Print Network (OSTI)

is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

Almendarez, Maria Elena

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations  

Science Journals Connector (OSTI)

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations ... The environmental implications of offshore oil and gas activities ... The environmental implications of offshore oil and gas activities ...

Theodor C. Sauer

1981-08-01T23:59:59.000Z

222

High-energy-density solid and liquid hydrocarbon fuels. Final report, July 1987-December 1988  

SciTech Connect

The development of new high-energy hydrocarbon fuels for use in air-breathing missiles has been the objective of a number of investigations which have received support during the past decade through programs sponsored by the Air Force Systems Command and/or the Naval Air Systems Command. The key characteristics which must be met by potential cruise missile fuels have been described by Burdette and coworkers. A primary requirement in this regard is that candidate fuels must possess high net volumetric heat of combustion (preferably greater than 160,000 BTU/gallon). In order to meet the primary requirement of high net volumetric heat of combustion, hydrocarbon systems have been sought which maximize the ratio of carbon-atom to hydrogen-atom content have been sought that maximize the ratio n/m.(JES)

Marchand, A.P.

1989-02-01T23:59:59.000Z

223

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

224

Hydrocarbon Separations in Metal–Organic Frameworks  

Science Journals Connector (OSTI)

Given the large differences in the physical properties of methane and C2 hydrocarbons, both size selective effects and metal–hydrocarbon interactions can be tuned to achieve a high selectivity within a metal–organic framework. ... Polycyclic aromatic hydrocarbons, or PAHs, are carcinogenic byproducts of incomplete combustion of organic matter such as fossil fuels. ... data and the heats of adsorption were found to fit well to a small group of mol. ...

Zoey R. Herm; Eric D. Bloch; Jeffrey R. Long

2013-11-22T23:59:59.000Z

225

Surface Combustion Microengines Based on Photocatalytic Oxidations of Hydrocarbons at Room Temperature  

Science Journals Connector (OSTI)

Surface Combustion Microengines Based on Photocatalytic Oxidations of Hydrocarbons at Room Temperature ... For instance internal combustion engines depend on an exothermic combustion of a mixture of hydrocarbon fuel or hydrogen and air, inside a sealed cylinder equipped with a movable piston.1 Once ignited using an electrical or compression heating system, the combustion products have more available energy than the original mixture, and this energy can be translated into work by driving the piston. ... One possible explanation for the lack of data is that the temperature increase of surface or suspended colloids is hard to measure due to fast heat dissipation through solid bond vibrations or solvent molecules in continuous UV radiation. ...

Ming Su; Vinayak P. Dravid

2005-09-22T23:59:59.000Z

226

Intercomparison of ozone measurements over Antarctica  

SciTech Connect

Measurements of the abundances of ozone over Antarctic in August and September 1987 obtained during the Airborne Antarctic Ozone Experiment are intercompared. These measurements of ozone concentrations and total column abundance were obtained by three satellite instruments, two IR and one UV column-measuring instruments aboard the DC-8, one in situ DC-8, and two in situ ER-2 instruments, an upward looking lidar aboard the DC-8, and ozonesondes from four sites in Antarctica. Given the natural variability of ozone in the Antarctic and the fact that the data were not truly coincident spatially and temporally, this intercomparison is suitable only for identifying gross disparities among the techniques, rather than confirming the accuracies as rigorously as is normally done in an intercomparison. This paper presents a summary of the ozone data, using the data and accuracies given by the individual investigators in the individual papers in this issue, without any attempt to critically review or evaluate the data. In general, very good agreement (within about 10-20%, limited by natural variability) among the various techniques was found, with no systematic biases detected. These observations confirm the low ozone amounts reported in the Antarctic stratosphere.

Margitan, J.J.; Farmer, C.B.; Toon, G.C. (California Inst. of Tech., Pasadena (United States)); Brothers, G.A. (Chemal, Inc., Wallops Island, VA (United States)); Browell, E.V.; Gregory, G.L.; Hypes, W.; Larsen, J.C.; McCormick, M.P. (NASA Langley Research Center, Hampton, VA (United States)); Cariolle, D. (Centre National de la Recherches Meteorologiques, Toulouse (France)); Coffey, M.T.; Mankin, W. (National Center for Atmospheric Research, Boulder, CO (United States)); Farman, J.C. (British Antarctic Survey, Cambridge (United Kingdom)); Harder, J.W.; Mount, G.H.; Ravishankara, A.R.; Schemeltekopf, A.L.; Tuck, A.F. (NOAA Aeronomy Lab., Boulder, CO (United States)); Hofmann, D.J. (Univ. of Wyoming, Laramie (United States)); Ismail, S.; Kooi, S. (ST Systems, Inc., Hampton, VA (United States)); Jakoubek, R.O.; Proffitt, M.H.; Wahner, A.; Watterson, I. (NOAA Aeronomy Lab., Boulder, CO (United States) Univ. of Colorado, Boulder (United States)); Komhyr, W. (NOAA Air Resources La

1989-11-30T23:59:59.000Z

227

The Determination of Organic Volatiles In Air Pollution Studies: Characterization of Profiles  

Science Journals Connector (OSTI)

......such as aromatic hydrocarbon or halogenated compounds...suitable. Low MW hydrocarbons in air pollutants...23), once these data have been determined...matter, by direct heat desorption. Collection...nature. Since the data are continuously...process in internal combustion engines leaves many......

Wolfgang Bertsch; Ray C. Chang; Albert Zlatkis

1974-04-01T23:59:59.000Z

228

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

229

catalytic_upgrading_sugars_to_hydrocarbons  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

phase reforming into hydrocarbons for fuels and co-product commodities. Process Block Diagram Next Steps Additional modeling is necessary to quantify baseline costs associated...

230

Application of advanced hydrocarbon characterization and its...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

advanced hydrocarbon characterization and its consequences on future fuel properties and advanced combustion research Rafal Gieleciak, Craig Fairbridge and Darcy Hager Poster...

231

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents (OSTI)

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

232

Ability of Catalytic Converters to Reduce Air Pollution  

E-Print Network (OSTI)

of gasoline (hydrocarbons, CxHy) in air: CxHy + O2 CO2 + H2O + heat (1) When there is the correct balance of O2 and hydrocarbons in the combustion chamber (i.e., under "lean" conditions), complete combustion when the combustion temperature is high: O2 + heat 2 O� (2) O� + N2 NO� + N� (3) N� + O2 NO� + O� (4

Nizkorodov, Sergey

233

Indoor air quality implications of using ion generators in residences Michael S. Waring*  

E-Print Network (OSTI)

Indoor air quality implications of using ion generators in residences Michael S. Waring characterizes the indoor air quality implications of an ion generator in a 27 m3 residential room, with a matrix exposure and health professionals to make justified recommendations about the use of these ozone

Siegel, Jeffrey

234

Assimilation of wind profiler observations and its impact on three-dimensional transport of ozone over the Southeast Korean Peninsula  

Science Journals Connector (OSTI)

Abstract In order to investigate the impact of data assimilation on the assessment of ozone concentration in inland regions in the eastern area of the Korean Peninsula, several numerical experiments have been carried out using the Weather Research and Forecasting (WRF) model to estimate atmospheric circulations and the Community Multiscale Air Quality (CMAQ) model to assess air quality. Observations of wind that are assimilated into the modeling system are obtained from a wind profiler located at Changwon (CW), which is an urbanized coastal region in the Korean Peninsula. The simulated wind and temperature that is related to a well-developed sea breeze circulation are more consistent with observations in the experiment with dada assimilation than that without the assimilation. The ozone concentrations at both the coastal area of CW and the inland region of DG are well reproduced in the simulation with application of profiler data assimilation. Results from experiments without data assimilation are less realistic than that from the experiment with data assimilation. However, the improvement in simulation of meteorological variables and ozone concentration due to data assimilation is greater in the inland area than in the coastal area, where the wind profiler is located. The ozone concentration in CW changes only over a limited area and below the altitude of 1 km with a maximum change of 25 ppb. In contrast, the simulated ozone concentration in DG has been improved from the ground to upper levels of the planetary boundary layer (PBL), despite the fact that the observations are collected and assimilated into the model at the coastal region. Based on the results of process analysis, we find that the horizontal and vertical transportation of ozone related to the sea-breeze is more important than the local contribution of chemical production in determining the ozone concentration over the inland area. Therefore, observations of wind profiles in the coastal area and assimilation of these observations into the modeling system are important in our modeling study to assess the ozone concentration in inland areas. The assimilation of observations can greatly improve the model performance in both circulation simulation and ozone concentration simulation.

Soon-Young Park; Soon-Hwan Lee; Hwa Woon Lee

2014-01-01T23:59:59.000Z

235

Ambient Air Quality Standards (New Jersey) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ambient Air Quality Standards (New Jersey) Ambient Air Quality Standards (New Jersey) Ambient Air Quality Standards (New Jersey) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Program Info State New Jersey Program Type Siting and Permitting Provider State of New Jersey Department of Environmental Protection This article lists specific standards for ambient air quality standards for particulate matter, sulfur dioxide, carbon monoxide, ozone, lead and

236

Air Quality  

NLE Websites -- All DOE Office Websites (Extended Search)

What We Monitor & Why » What We Monitor & Why » Air Quality Air Quality To preserve our existing wilderness-area air quality, LANL implements a conscientious program of air monitoring. April 12, 2012 Real-time data monitoring for particulate matter An air monitoring field team member tests one of LANL's tapered element oscillating microbalance samplers, which collects real-time particulate matter data. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email LANL monitors air quality 24 hours a day, 365 days a year. Why we monitor air LANL monitors many different pathways in order to assess their impact on workers, the public, animals, and plants. We monitor the air around the Laboratory to ensure our operations are not affecting the air of nearby

237

Biodegradation of Aromatic Hydrocarbons in an Extremely Acidic Environment  

Science Journals Connector (OSTI)

...biodegradation of aromatic hydrocarbons can occur in environments...Polycyclic aromatic hydrocarbons (PAHs) occur as common...formed by incomplete combustion of fossil fuels...enrichments with aromatic hydrocarbons, mineralization assays...lysis was initiated by heat and sodium dodecyl...

Raymond D. Stapleton; Dwayne C. Savage; Gary S. Sayler; Gary Stacey

1998-11-01T23:59:59.000Z

238

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons| Introduction Esophageal...polycyclic aromatic hydrocarbon (PAH) content. PAHs...usually exposed to combustion products from burning...SRM 2260a Aromatic Hydrocarbons in Toluene, SRM 2269...dichloromethane; heat: preheat cell at 100C...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

239

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...polycyclic aromatic hydrocarbons| Introduction...mechanism. However, data on the association...polycyclic aromatic hydrocarbon (PAH) content...usually exposed to combustion products from burning...dichloromethane; heat: preheat cell...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

240

Metabolism of Polycyclic Aromatic Hydrocarbons in Cell Cultures  

Science Journals Connector (OSTI)

...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...cytotoxicity and conversion of hydrocarbons to water-soluble products (Chart...

Eliezer Huberman; James K. Selkirk; and Charles Heidelberger

1971-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...80C) or cold (5C) water. Measurements were...polycyclic aromatic hydrocarbons in mate drinks. | Drinking...polycyclic aromatic hydrocarbons (PAH), including...cold (5 degrees C) water. Measurements were...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

242

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...versus shallow-water environments...A (1999) Hydrocarbons in rift basins...Facies and hydrocarbon potential The...availability of water. This can either...form seals for hydrocarbons. The shallow-water environ- ments...

1999-01-01T23:59:59.000Z

243

Learning and discrimination of cuticular hydrocarbons in a social insect  

Science Journals Connector (OSTI)

...colony members. Cuticular hydrocarbons (CHCs) play a central...CHC profile with synthetic hydrocarbons [4-6] reveal that some hydrocarbons elicit aggression. However...non-volatile, insoluble in water and therefore difficult...

2012-01-01T23:59:59.000Z

244

Tensile Effective Stresses in Hydrocarbon Storage Caverns  

E-Print Network (OSTI)

Tensile Effective Stresses in Hydrocarbon Storage Caverns Hippolyte Djizanne and Pierre Bérest LMS, Germany,1-2 October 2012 TENSILE EFFECTIVE STRESSES IN HYDROCARBON STORAGE CAVERNS Hippolyte Djizanne1 that effective tensile stresses can be generated at a cavern wall after a rapid increase or decrease in pressure

Paris-Sud XI, Université de

245

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

246

Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons  

DOE Patents (OSTI)

A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

Muradov, Nazim Z. (Melbourne, FL)

2011-08-23T23:59:59.000Z

247

The Effects of Two Isomeric Benzoflavones on Aryl Hydrocarbon Hydroxylase and the Toxicity and Carcinogenicity of Polycyclic Hydrocarbons  

Science Journals Connector (OSTI)

...recrystallized from alcohol : water. For tissue culture experiments the hydrocarbons and benzoflavones...metabolism of the hydrocarbons to water-soluble derivatives...chloroform:methanol. Hydrocarbon-3 H metabolized to water-soluble derivatives...

Leila Diamond; Rosemary McFall; Joel Miller; and Harry V. Gelboin

1972-04-01T23:59:59.000Z

248

Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology  

E-Print Network (OSTI)

ozone record from Paramaribo, Surinam (6°N, 55°W) (also in SHADOZ) shows a marked contrast to southern tropical ozone because Surinam is often north of the Intertropical Convergence Zone (ITCZ). A more

Thompson, Anne

249

Open-path ozone detection by quantum-cascade laser  

Science Journals Connector (OSTI)

Open-path ozone measurements performed by mid-IR differential absorption spectroscopy are reported. Ozone spectrum was taken by fast repetitive sweeping of a quantum-cascade laser wavelength over a spectral featu...

M. Taslakov; V. Simeonov; M. Froidevaux; H. van den Bergh

2006-03-01T23:59:59.000Z

250

Hydrocarbon fouling of SCR during Premixed Charge Compression...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion...

251

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Algal Lipid Extraction and Upgrading to Hydrocarbons...

252

DOE Perspectives on Advanced Hydrocarbon-based Biofuels | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Perspectives on Advanced Hydrocarbon-based Biofuels DOE Perspectives on Advanced Hydrocarbon-based Biofuels Zia Haq, DPA Coordinator, presentation on DOE Perspectives on...

253

Commercialization of IH2® Biomass Direct-to-Hydrocarbon Fuel...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

254

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

255

Chemistry climate model simulations of1 spring Antarctic ozone  

E-Print Network (OSTI)

013577. 1. Introduction [2] Since its discovery [Farman et al., 1985], the Antarctic ozone hole has been

Wirosoetisno, Djoko

256

Attribution of the Arctic ozone column deficit in March 2011  

E-Print Network (OSTI)

Toronto, Ont. , Canada. Farman, J. C. , B. G. Gardiner, andthe Antarctic ozone hole [Farman et al. , 1985]. [ 13

2012-01-01T23:59:59.000Z

257

Operation of a Joint Utility/Industry Ambient Air Monitoring Program in the Houston Area  

E-Print Network (OSTI)

for achieving compliance of the NAAQS for ozone in Houston have largely heen directed at controlling photochemically reactive volatile hydrocarbon emissions from industrial stationary and fugitive sources. Evidence gathered by the monitoring network and from... suggest that the most cost-effective emission controls for both stationary and fugitive emissions sources in Harris County have been implemented. It is estimated that a reduction of an additional 10,000 to 20,000 tons of Volatile Organic...

Kush, J. A.

258

Texas Air Quality Status and the Texas Emission Reduction Plan  

E-Print Network (OSTI)

1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 Millionsppb Eight-Hour Ozone Design Values and Population in Texas Population BPA CC DFW HGB ARR ELP SAN NET VIC BB LRG LAR 1997 Eight-Hour Ozone NAAQS... Ton - $5,202 Clean Air Through Energy Efficiency Conference ? Galveston, Texas ? October 10, 2012 TERP Grant Amount by Area AUS Austin Area BPA Beaumont- Port Arthur CC Corpus Christi DFW Dallas-Fort Worth ELP El Paso HGB Houston...

Hildebrand, S.

2012-01-01T23:59:59.000Z

259

Preparation of synthetic hydrocarbon lubricants  

SciTech Connect

A process is described for preparing synthetic lubricating materials which process comprises: (a) reacting (i) at least a portion of a reaction product of the liquid phase oligomerization of propylene, butylene or mixtures thereof containing a C/sub 6/ olefin component, (ii) a linear olefin reactant having an average carbon number ranging from about 10 to about 18 in the presence of a catalyst, (b) separating from the reaction mixture of (a) hydrocarbons which distill at a temperature above about 660/sup 0/ F. (316/sup 0/ C.), and (c) hydrogenating the reaction product of (b) by contact with hydrogen with or without a catalyst at a temperature ranging from about 25/sup 0/ C. to about 300/sup 0/ C.

Johnson, T.H.

1986-10-07T23:59:59.000Z

260

Effects of pulp consistency and mixing intensity on ozone bleaching  

SciTech Connect

Conventional wisdom holds that ozone bleaching is feasible only at low or high pulp consistencies. However, recent research suggests that ozone bleaching at medium consistency is possible under conditions of high-intensity mixing. This article presents experimental results for softwood and hardwood pulps that were ozone-bleached over a range of consistencies (3-40%) and mixing conditions. Ozone was pressurized and delivered by a proprietary automated system. Results indicate that ozone bleaching at medium consistency can be as effective as bleaching at high consistency. Medium-consistency bleaching has the advantage of greater selectivity, resulting in higher pulp viscosity.

Hurst, M.M. (Quantum Technologies, Inc., Twinsburg, OH (United States))

1993-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Envlron. Sci. Technol. 1993, 27, 1885-1891 On-Road Hydrocarbon Remote Sensing in the Denver Area  

E-Print Network (OSTI)

), oxides of nitrogen (NO,), and other toxic air pollutants. These emissions play important roles in all emission control technology. Introduction Automobile emissionsoriginate from fuelrich-burning, misfiring or nonfunctional emission control system can produce high emission rates for carbon monoxide (CO), hydrocarbon (HC

Denver, University of

262

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

263

Removal of trace olefins from aromatic hydrocarbons  

SciTech Connect

A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

Sachtler, J.W.A.; Barger, P.T.

1989-01-03T23:59:59.000Z

264

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the Fischer–Tropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

265

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network (OSTI)

Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble...

Kanga, Shahrukh

2012-06-07T23:59:59.000Z

266

NASA reports drop in stratospheric ozone  

Science Journals Connector (OSTI)

NASA reports drop in stratospheric ozone ... "I believe I have that evidence," asserts NASA's Heath, adding: "It's not the proof—that will take much more work. ... Public release of the NASA data analysis is somewhat premature, he says, because the paper has not yet been published. ...

1981-08-24T23:59:59.000Z

267

Nuclear conflict and ozone depletion Quick summary  

E-Print Network (OSTI)

Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

Toohey, Darin W.

268

Chapter 21 Air Quality  

NLE Websites -- All DOE Office Websites (Extended Search)

for which the airsheds are "in attainment or unclassified" are carbon monoxide, nitrogen dioxide, ozone, sulfur dioxide, lead, and particulate matter (PM) including PM...

269

Methanol conversion to higher hydrocarbons  

SciTech Connect

Several indirect options exist for producing chemicals and transportation fuels from coal, natural gas, or biomass. All involve an initial conversion step to synthesis gas (CO and H{sub 2}). Presently, there are two commercial technologies for converting syngas to liquids: Fischer-Tropsch, which yields a range of aliphatic hydrocarbons with molecular weights determined by Schulz-Flory kinetics, and methanol synthesis. Mobil`s diversity of technology for methanol conversion gives the methanol synthesis route flexibility for production of either gasoline, distillate or chemicals. Mobil`s ZSM-5 catalyst is the key in several processes for producing chemicals and transportation fuels from methanol: MTO for light olefins, MTG for gasoline, MOGD for distillates. The MTG process has been commercialized in New Zealand since 1985, producing one-third of the country`s gasoline supply, while MTO and MOGD have been developed and demonstrated at greater than 100 BPD scale. This paper will discuss recent work in understanding methanol conversion chemistry and the various options for its use.

Tabak, S.A. [Mobil Research and Development Corp., Princeton, NJ (United States). Central Research Lab.

1994-12-31T23:59:59.000Z

270

International Symposium Transport and Air Pollution Session 6: Biofuels 2  

E-Print Network (OSTI)

1Sth International Symposium Transport and Air Pollution Session 6: Biofuels 2 Determination of VOC components in the exhaust of light vehicles fuelled with different biofuels F. Gazier 1,4*, A. De/bende 1 of the emissions shows changes with the composition of the biofuel in the levels of hydrocarbons, aromatic

Paris-Sud XI, Université de

271

AirUCI Summer 2007 Schedule Monday, June 25th  

E-Print Network (OSTI)

: Composition and Effects on Global Warming (p. 107, & 203­206) - PAH (p. 393­402) - Combustion reactions) - Global Circulation Models and Predictions (p. 212, 213 & 220 ­ 226) 11 am to 12 pm: Lunch with Air and pollutant formation - Fuels: Hydrocarbons, Aromatics, H2 (p. 283), Coal (p. 228 & 229), Petroleum

Nizkorodov, Sergey

272

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III (SAGE III)  

E-Print Network (OSTI)

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas extinction. We retrieve ozone and nitrogen dioxide number densities and aerosol extinction from transmission), Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III

273

Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.  

E-Print Network (OSTI)

Ozone Reaction with HVAC Filters Hugo Destaillats, WenhaoOzone Reaction with HVAC Filters Hugo Destaillats 1,3,* ,Ozone Reaction with HVAC Filters Hugo Destaillats 1,3,* ,

Destaillats, Hugo

2012-01-01T23:59:59.000Z

274

Air Pollution  

Science Journals Connector (OSTI)

Both natural processes and human activities contribute to air pollution, with the combustion of fossil fuels being the largest anthropogenic source of air pollutants. Adverse health effects (above all respiratory and cardiovascular complications), damage to crops, natural vegetation and materials, reduced visibility and changed radiation balance of the atmosphere are the major consequences of high concentrations of air pollutants. Technical fixes can sharply reduce emissions from large stationary sources and lower the rates of automotive emissions, but the rising number of vehicles and longer time spent on the road will call for more radical solutions to traffic-generated photochemical smog now present in all major urban areas.

V. Smil

2001-01-01T23:59:59.000Z

275

International aspects of restrictions of ozone-depleting substances  

SciTech Connect

This report summarizes international efforts to protect stratospheric ozone. Also included in this report is a discussion of activities in other countries to meet restrictions in the production and use of ozone-depleting substances. Finally, there is a brief presentation of trade and international competitiveness issues relating to the transition to alternatives for the regulated chlorofluorocarbons (CFCs) and halons. The stratosphere knows no international borders. Just as the impact of reduced stratospheric ozone will be felt internationally, so protection of the ozone layer is properly an international effort. Unilateral action, even by a country that produces and used large quantities of ozone-depleting substances, will not remedy the problem of ozone depletion if other countries do not follow suit. 32 refs., 7 tabs.

McDonald, S.C.

1989-10-01T23:59:59.000Z

276

Bos > AIR  

E-Print Network (OSTI)

The advent of air travel has produced a building typology completely new to the 20th century. The outdated planning of regions for airports render most existing airports as isolated, autonomous instances in the urban ...

Lee, Kevin Young

2014-01-01T23:59:59.000Z

277

Ozone heating and the destabilization of traveling waves during summer  

SciTech Connect

The effects of ozone heating on the linear stability of lower stratospheric traveling waves of the summertime, extratropical circulation are examined. Based on coupled equations for the quasigeostrophic potential vorticity and ozone volume mixing ratio, it is shown that the diabatic heating arising from ozone advection can offset the damping due to Newtonian cooling, leading to wave amplification and significant changes in the structure and zonally rectified fluxes of the wave fields in both the lower stratosphere and troposphere. The vertical profile of the zonal mean wind plays a crucial role in determining whether the ozone heating destabilizes eastward and/or westward traveling disturbances.

Nathan, T.R.; Cordero, E.C.; Li, L. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States)

1994-07-01T23:59:59.000Z

278

E-Print Network 3.0 - arctic ozone depletion Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

1 Introduction Stratospheric ozone depletion has been one... (Chubachi, 1984; Farman et al., 1985), winter ozone ... Source: Ecole Polytechnique, Centre de mathmatiques...

279

E-Print Network 3.0 - antarctic ozone experiment Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

in the 1980s of anomalously low ozone column abundances over the Antarctic by Farman et al. (1985... ), ozone abundances in the Antarctic ... Source: Ecole Polytechnique,...

280

E-Print Network 3.0 - airborne antarctic ozone Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

in the 1980s of anomalously low ozone column abundances over the Antarctic by Farman et al. (1985... ), ozone abundances in the Antarctic ... Source: Ecole Polytechnique,...

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Inc Hydrocarbon Inc Jump to: navigation, search Name Gulf Hydrocarbon Inc Address 2016 Main St Place Houston, Texas Zip 77002 Sector Biofuels Product Wholesale marketing of biodiesel and ethanol to refiners, blenders and petroleum distributors Website http://www.gulfhydrocarbon.com Coordinates 29.749227°, -95.371693° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.749227,"lon":-95.371693,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

282

George A. Olah, Carbocation and Hydrocarbon Chemistry  

Office of Scientific and Technical Information (OSTI)

George A. Olah, Carbocation and Hydrocarbon Chemistry George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information · Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations are stable and their physical properties ... can be observed, thus allowing details of their structures to be determined. Besides trivalent ions ... Olah demonstrated the existence of higher coordinate carbocations ... . These species do not violate the octet rule, but involve 2-electron 3-center bonding. '1

283

Using supercritical fluids to refine hydrocarbons  

DOE Patents (OSTI)

This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

Yarbro, Stephen Lee

2014-11-25T23:59:59.000Z

284

Gamma radiolysis of chlorinated hydrocarbons  

SciTech Connect

This program is the Idaho National Engineering Laboratory (INEL) component of a joint collarborative effort with Lawrence Livermore National Laboratory (LLNL). The purpose of this effort is to demonstrate a viable process for breaking down hazardous halogenated organic wastes to simpler, non-hazardous waste using high energy ionizing radiation. The INEL effort focuses on the use of spent reactor fuel gamma radiation sources to decompose complex wastes such as PCBs. At LLNL, halogenated solvents such as carbon tetrachloride and trichloroethylene are being studied using accelerator radiation sources. The INEL irradiation experiments concentrated on a single PCB congener so that a limited set of decomposition reactions could be studied. The congener 2,2{prime}, 3,3{prime},4,5{prime},6,6{prime} - octachlorobiphenyl was examined following exposure to various gamma doses at the Advanced Test Reactor (AIR) spent fuel pool. The decomposition rates and products in several solvents are discussed. 3 refs.

Arbon, R.E.; Mincher, B.J.; Meikrantz, D.H.

1992-01-01T23:59:59.000Z

285

Gamma radiolysis of chlorinated hydrocarbons  

SciTech Connect

This program is the Idaho National Engineering Laboratory (INEL) component of a joint collarborative effort with Lawrence Livermore National Laboratory (LLNL). The purpose of this effort is to demonstrate a viable process for breaking down hazardous halogenated organic wastes to simpler, non-hazardous waste using high energy ionizing radiation. The INEL effort focuses on the use of spent reactor fuel gamma radiation sources to decompose complex wastes such as PCBs. At LLNL, halogenated solvents such as carbon tetrachloride and trichloroethylene are being studied using accelerator radiation sources. The INEL irradiation experiments concentrated on a single PCB congener so that a limited set of decomposition reactions could be studied. The congener 2,2{prime}, 3,3{prime},4,5{prime},6,6{prime} - octachlorobiphenyl was examined following exposure to various gamma doses at the Advanced Test Reactor (AIR) spent fuel pool. The decomposition rates and products in several solvents are discussed. 3 refs.

Arbon, R.E.; Mincher, B.J.; Meikrantz, D.H.

1992-08-01T23:59:59.000Z

286

E-Print Network 3.0 - aromatic hydrocarbons evaluated Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

287

E-Print Network 3.0 - aromatic hydrocarbons part Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

288

Sexual selection on cuticular hydrocarbons of male sagebrush crickets in the wild  

Science Journals Connector (OSTI)

...association between cuticular hydrocarbon composition and desiccation...temperature on cuticular lipids and water balance in a desert Drosophila...interactions for cuticular hydrocarbon expression in Drosophila simulans...evolutionary roles of cuticular hydrocarbons in Diptera. In Insect hydrocarbons...

2013-01-01T23:59:59.000Z

289

Sustainable treatment of hydrocarbon-contaminated industrial land   

E-Print Network (OSTI)

Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

Cunningham, Colin John

2012-06-25T23:59:59.000Z

290

Chemical nature of high-molecular hydrocarbons of gaseous condensates  

SciTech Connect

Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

1987-01-01T23:59:59.000Z

291

Chapter 9 - Chemical and Physical Properties of Hydrocarbons  

Science Journals Connector (OSTI)

Publisher Summary Hydrocarbons are the simplest organic compounds and contain only carbon and hydrogen but they can be straight chain or branched chain with the same empirical formula but showing differences in properties. Chemical change results in the hydrocarbon yielding a product that may be entirely different in composition to the starting hydrocarbon—the exception is the isomerization reaction where a straight-chain hydrocarbon is converted to a branched-chain hydrocarbon. Chemical properties of hydrocarbons describe the potential of hydrocarbons to undergo chemical change or reaction by virtue of the hydrocarbon structure. Physical properties can be observed or measured without changing the composition of matter. Physical properties are used to observe and describe matter. Physical properties that are of interest in the current context include: boiling point, melting point, density, vapor density, flash point, ignition temperature, and dew point.

James G. Speight

2011-01-01T23:59:59.000Z

292

DOE Hydrogen Analysis Repository: AirCRED Model  

NLE Websites -- All DOE Office Websites (Extended Search)

AirCRED Model AirCRED Model Project Summary Full Title: AirCRED Model Project ID: 119 Principal Investigator: Andy Burnham Brief Description: The AirCRED model calculates the emissions reductions achieved through deployment of alternative fuel vehicles. Purpose To assist the U.S. Department of Energy's (DOE's) Clean Cities coalitions in estimating the ozone precursor and winter season carbon monoxide (CO) emission reduction credits earned by acquiring original equipment manufacturer (OEM) alternative fuel vehicles (AFVs), Argonne National Laboratory has developed a graphical user interface (GUI)-based calculation model called AirCRED. Performer Principal Investigator: Andy Burnham Organization: Argonne National Laboratory (ANL) Address: 9700 S. Cass Ave. Argonne, IL 60439

293

E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

294

E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

295

E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

296

E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

297

E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

298

E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

299

E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

300

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

NLE Websites -- All DOE Office Websites (Extended Search)

Enzymes Acid + Caustic Wastewater Treatment Process Heat and Power Integration Biogas + Sludge Fuel Finishing (hydroprocessing, as needed) Electricity Hydrogen Hydrocarbon...

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

THE ELECTRON MICROSCOPY OF HYDROCARBON PRODUCTION IN PARTHENIUM ARGENTATUM (GUAYULE)  

E-Print Network (OSTI)

conversion of solar energy is the production of hydrocarbonsproduction of hydrocarbons. Mankind's use of biologically converted solar energy

Bauer, T.E.

2010-01-01T23:59:59.000Z

302

aromatic hydrocarbons coated: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

303

Air Resources: Prevention and Control of Air Contamination and Air  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Resources: Prevention and Control of Air Contamination and Air Air Resources: Prevention and Control of Air Contamination and Air Pollution, Air Quality Classifications and Standards, and Air Quality Area Classifications (New York) Air Resources: Prevention and Control of Air Contamination and Air Pollution, Air Quality Classifications and Standards, and Air Quality Area Classifications (New York) < Back Eligibility Agricultural Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Multi-Family Residential Municipal/Public Utility Nonprofit Rural Electric Cooperative Schools State/Provincial Govt Transportation Tribal Government Utility Program Info State New York Program Type Environmental Regulations Provider NY Department of Environmental Conservation These regulations establish emissions limits and permitting and operational

304

Atmospheric Environment 42 (2008) 37513764 Modeling the effects of ship emissions on coastal air quality  

E-Print Network (OSTI)

Atmospheric Environment 42 (2008) 3751­3764 Modeling the effects of ship emissions on coastal air emissions, they could have important environmental effects on coastal areas near ports with heavy ship-going ships on ozone and particulate matter concentrations is quantified using UCI- CIT model for the South

Dabdub, Donald

305

Maps depicting nonattainment areas pursuant to Section 107 of the Clean Air Act - 1985  

SciTech Connect

The report is a detailed mapping of the United States depicting those areas nonattaining the National Ambient Air Quality Standards for carbon monoxide, nitrogen dioxide, ozone, sulfur dioxide, and total suspended particulates. It includes nonattainment area maps and supporting lists from Federal Register publications for final actions through September 1, 1985.

Yarn, J.; Beal, W.; Tate, C.

1985-09-01T23:59:59.000Z

306

Maps depicting nonattainment areas pursuant to Section 107 of the Clean Air Act - 1982  

SciTech Connect

This report is a detailed mapping of the United States depicting those areas not attaining the National Ambient Air Quality Standards for carbon monoxide, nitrogen dioxide, ozone, sulfur dioxide and total suspended particulates. It includes nonattainment area maps and supporting lists from Federal Register publications for final actions through February 1, 1982.

Pearson, J.; Beal, W.; Duggan, G.

1982-02-01T23:59:59.000Z

307

Maps depicting nonattainment areas pursuant to Section 107 of the Clean Air Act - 1983  

SciTech Connect

This report is a detailed mapping of the United States Depicting those areas not attaining the National Ambient Air Quality Standards for carbon monoxide, nitrogen dioxide, ozone, sulfur dioxide and total suspended particulates. It includes nonattainment area maps and supporting lists from Federal Register publications for final actions through February 1, 1983.

Duggan, G.; Pearson, J.; Beal, W.

1983-02-01T23:59:59.000Z

308

Maps depicting nonattainment areas pursuant to Section 107 of the Clean Air Act - 1984  

SciTech Connect

This report is a detailed mapping of the United States depicting those areas not attaining the National Ambient Air Quality Standards for carbon monoxide, nitrogen dioxide, ozone, sulfur dioxide and total suspended particulates. It includes non-attainment area maps and supporting lists from Federal Register publications for final actions through July 1, 1984.

Yarn, J.; Beal, W.; Tate, C.

1984-07-01T23:59:59.000Z

309

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents (OSTI)

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

310

Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons  

Science Journals Connector (OSTI)

... in the flask's headspace. This procedure produced negligible amounts of contaminating hydrocarbons. The geothermal hydrocarbons were separated and combusted, and the carbon dioxide product purified and measured using ... of the pyrolysis and spark discharge experiments, b, Isotopic abundance of hydrocarbons from four geothermal localities as follows: D, Cerro Prieto, well M-5, sampled January 1979; ...

David J. Des Marais; Jason H. Donchin; Nancy L. Nehring; Alfred H. Truesdell

1981-08-27T23:59:59.000Z

311

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

312

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

313

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

314

Nonlinear dependence of the solubility of water in hydrocarbons on the molar volume of the hydrocarbon  

Science Journals Connector (OSTI)

The solubility of water in fifty hydrocarbon solvents at 20°C is estimated by ... in nonspecific cohesion forces, and assuming that water is primarily monomeric in solution, the prediction ... breaking of the H-b...

Paul Ruelle; Ulrich W. Kesselring

1996-07-01T23:59:59.000Z

315

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network (OSTI)

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

316

Quantifying Denitrification and Its Effect on Ozone Recovery  

Science Journals Connector (OSTI)

...Effect on Ozone Recovery 10.1126...USA. 3 Atmospheric and Environmental...effects on ozone recovery in a colder and possibly...below the condensation point of...37) [or water vapor (38...5 ppm for water vapor. The atmospheric concentrations...

A. Tabazadeh; M. L. Santee; M. Y. Danilin; H. C. Pumphrey; P. A. Newman; P. J. Hamill; J. L. Mergenthaler

2000-05-26T23:59:59.000Z

317

Atmospheric Environment 41 (2007) 31513160 Ozone removal by HVAC filters  

E-Print Network (OSTI)

Atmospheric Environment 41 (2007) 3151­3160 Ozone removal by HVAC filters P. Zhao, J.A. Siegel�, R May 2006; accepted 14 June 2006 Abstract Residential and commercial HVAC filters that have been loaded of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial

Siegel, Jeffrey

318

Multimedia fate of petroleum hydrocarbons in the soil: Oil matrix of constructed biopiles  

Science Journals Connector (OSTI)

A dynamic multimedia fugacity model was used to evaluate the partitioning and fate of petroleum hydrocarbon fractions and aromatic indicator compounds within the soil: oil matrix of three biopiles. Each biopile was characterised by four compartments: air, water, soil solids and non-aqueous phase liquid (NAPL). Equilibrium partitioning in biopile A and B suggested that most fractions resided in the NAPL, with the exception of the aromatic fraction with an equivalent carbon number from 5 to 7 (EC5?7). In Biopile C, which had the highest soil organic carbon content (13%), the soil solids were the most important compartment for both light aliphatic fractions (EC5?6 and EC6?8) and aromatic fractions, excluding the EC16?21 and EC21?35. Our starting hypothesis was that hydrocarbons do not degrade within the NAPL. This was supported by the agreement between predicted and measured hydrocarbon concentrations in Biopile B when the degradation rate constant in NAPL was set to zero. In all scenarios, biodegradation in soil was predicted as the dominant removal process for all fractions, except for the aliphatic EC5?6 which was predominantly lost via volatilization. The absence of an explicit NAPL phase in the model yielded a similar prediction of total petroleum hydrocarbon (TPH) behaviour; however the predicted concentrations in the air and water phases were significantly increased with consequent changes in potential mobility. Further comparisons between predictions and measured data, particularly concentrations in the soil mobile phases, are required to ascertain the true value of including an explicit NAPL in models of this kind.

Frédéric Coulon; Michael J. Whelan; Graeme I. Paton; Kirk T. Semple; Raffaella Villa; Simon J.T. Pollard

2010-01-01T23:59:59.000Z

319

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...WI 53706 The aryl hydrocarbon receptor (AHR) is...The mammalian aryl hydrocarbon receptor (AHR) is...complex with the 90-kDa heat shock protein (HSP90) and...polycyclic aromatic hydrocarbons such as {beta...cigarette smoking and other combustion processes, initiate...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

320

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...mammalian aryl hydrocarbon receptor...the 90-kDa heat shock protein (HSP90...polycyclic aromatic hydrocarbons such as {beta...smoking and other combustion processes...we searched data from the...Helminth HSP90 Heat-Shock Proteins...Molecular Sequence Data Protein Binding...Receptors, Aryl Hydrocarbon genetics metabolism...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Clean Air Interstate Rule (released in AEO2009)  

Reports and Publications (EIA)

Clean Air Interstate Rule (CAIR) is a cap-and-trade program promulgated by the Environmental Protection Agency in 2005, covering 28 eastern U.S. states and the District of Columbia. It was designed to reduce sulfur dioxide (SO2) and nitrogen oxide (NOx) emissions in order to help states meet their National Ambient Air Quality Standards (NAAQS) for ozone and particulate matter (PM2.5) and to further emissions reductions already achieved through the Acid Rain Program and the NOx State Implementation Plan call program. The rule was set to commence in 2009 for seasonal and annual NOx emissions and in 2010 for SO2 emissions.

2009-01-01T23:59:59.000Z

322

Hydrocarbon composition of crude oils near the Caspian depression  

SciTech Connect

The structural-group composition of hydrocarbons of Mesozoic crude oils near the Caspian depression was investigated by mass-spectrometry, followed by the analysis of the mass-spectra using a computer. The distribution of naphthenic hydrocarbons, according to the number of rings and of aromatic hydrocarbons, according to the degree of hydrogen unsaturation is similar for all the crude oils examined. The hydrocarbon composition of Mesozoic crude oils is characterized by a reduction in the content of aliphatic hydrocarbons and alkyl benzenes.

Botneva, T.A.; Khramova, E.V.; Nekhamkina, L.G.; Polyakova, A.A.

1983-01-01T23:59:59.000Z

323

Composition of paraffinic and naphthenic hydrocarbons in petroleum asphalts  

SciTech Connect

Uses a combination of chromatographic, chemical, and spectroscopic methods to determine the composition of the paraffinic and naphthenic hydrocarbons recovered from asphalts. Monitors the completeness of separation of the hydrocarbons from the aromatics on the basis of UV spectra. Finds that in the mixture of adduct-forming hydrocarbons, along with the n-paraffins there were admixtures of isoparaffins and longchain alkylnaphthenes. Concludes that a comparison of the structural-group composition of the asphalt fractions from the different crudes shows that there are only slight differences in the structure of the paraffinic/naphthenic hydrocarbons present in these asphalts, particularly with regard to those hydrocarbons that do not react with urea.

Botvin'eva, A.M.; Dubkova, R.V.; Shkredova, N.A.

1982-11-01T23:59:59.000Z

324

Effects of 20002050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone  

E-Print Network (OSTI)

) project major changes in anthro- pogenic emissions of greenhouse gases and ozone precur- sors over the 2Effects of 2000­2050 changes in climate and emissions on global tropospheric ozone and the policy; published 27 September 2008. [1] We use a global chemical transport model (GEOS-Chem) driven by a general

Mickley, Loretta J.

325

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents (OSTI)

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

326

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

SciTech Connect

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

327

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents (OSTI)

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

328

High Energy Efficiency Air Conditioning  

SciTech Connect

This project determined the performance of a new high efficiency refrigerant, Ikon B, in a residential air conditioner designed to use R-22. The refrigerant R-22, used in residential and small commercial air conditioners, is being phased out of production in developed countries beginning this year because of concerns regarding its ozone depletion potential. Although a replacement refrigerant, R-410A, is available, it operates at much higher pressure than R-22 and requires new equipment. R-22 air conditioners will continue to be in use for many years to come. Air conditioning is a large part of expensive summer peak power use in many parts of the U.S. Previous testing and computer simulations of Ikon B indicated that it would have 20 - 25% higher coefficient of performance (COP, the amount of cooling obtained per energy used) than R-22 in an air-cooled air conditioner. In this project, a typical new R-22 residential air conditioner was obtained, installed in a large environmental chamber, instrumented, and run both with its original charge of R-22 and then with Ikon B. In the environmental chamber, controlled temperature and humidity could be maintained to obtain repeatable and comparable energy use results. Tests with Ikon B included runs with and without a power controller, and an extended run for several months with subsequent analyses to check compatibility of Ikon B with the air conditioner materials and lubricant. Baseline energy use of the air conditioner with its original R-22 charge was measured at 90 deg F and 100 deg F. After changeover to Ikon B and a larger expansion orifice, energy use was measured at 90 deg F and 100 deg F. Ikon B proved to have about 19% higher COP at 90 deg F and about 26% higher COP at 100 deg F versus R-22. Ikon B had about 20% lower cooling capacity at 90 deg F and about 17% lower cooling capacity at 100 deg F versus R-22 in this system. All results over multiple runs were within 1% relative standard deviation (RSD). All of these values agree well with previous results and computer simulations of Ikon B performance versus R-22. The lower cooling capacity of Ikon B is not a concern unless a particular air conditioner is near its maximum cooling capacity in application. Typically, oversized A/C systems are installed by contractors to cover contingencies. In the extended run with Ikon B, which lasted about 4.5 months at 100 deg F ambient temperature and 68% compressor on time, the air conditioner performed well with no significant loss of energy efficiency. Post-run analysis of the refrigerant, compressor lubricant oil, compressor, compressor outlet tubing, and the filter/dryer showed minor effects but nothing that was considered significant. The project was very successful. All objectives were achieved, and the performance of Ikon B indicates that it can easily be retrofitted into R-22 air conditioners to give 15 - 20% energy savings and a 1 - 3 year payback of retrofit costs depending on location and use. Ikon B has the potential to be a successful commercial product.

Edward McCullough; Patrick Dhooge; Jonathan Nimitz

2003-12-31T23:59:59.000Z

329

Quantifying the Air Pollution Exposure Consequences of Distributed  

NLE Websites -- All DOE Office Websites (Extended Search)

Quantifying the Air Pollution Exposure Consequences of Distributed Quantifying the Air Pollution Exposure Consequences of Distributed Electricity Generation Speaker(s): Garvin Heath Date: November 8, 2005 - 12:00pm Location: Bldg. 90 This talk will highlight my research investigating differences in potential for human inhalation exposure to air pollutants emitted by distributed electricity generation (DG) technologies and existing central station power plants in California. The most sophisticated research on environmental impacts of DG has focused on evaluating spatially and temporally resolved air pollutant concentrations (e.g., ozone) that result from scenarios of future deployment of DG technologies (Samuelsen at al., 2003 and collaborations amongst Tonse, van Buskirk and Heath, unpublished). I extend this research to consider the relationship between where pollutants are

330

Sources and Deposition of Polycyclic Aromatic Hydrocarbons to Western U.S. National Parks  

Science Journals Connector (OSTI)

Sources and Deposition of Polycyclic Aromatic Hydrocarbons to Western U.S. National Parks ... Department of Chemistry and Department of Environmental & Molecular Toxicology, Oregon State University, Corvallis, Oregon 97331, Department of Chemistry, University of Otago, Dunedin 9014 New Zealand, United States Department of Agriculture - Forest Service, Pacific Northwest Region Air Program, Corvallis, Oregon 97330, US Geological Survey - Water Resources Division, Denver Federal Center, Lakewood, Colorado, Environmental Radioactivity Research Centre, University of Liverpool, Liverpool L69 3BX, U.K., United States Environmental Protection Agency - Western Ecology Division, Corvallis, Oregon 97333 ...

Sascha Usenko; Staci L. Massey Simonich; Kimberly J. Hageman; Jill E. Schrlau; Linda Geiser; Don H. Campbell; Peter G. Appleby; Dixon H. Landers

2010-05-14T23:59:59.000Z

331

Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application  

SciTech Connect

A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

Sapienza, R.S.; Sansone, M.J.; Slegeir, W.A.R.

1981-08-14T23:59:59.000Z

332

Stopping Cross Sections of Some Hydrocarbon Gases for 40-200-keV Helium Ions  

Science Journals Connector (OSTI)

The stopping cross sections of air, CH4, C2H2, C2H4, C3H8, (CH2)3, and C3H6 have been measured for incident helium ions in the energy range 40 to 200 keV. The data are in good agreement with previous experiment work, and have standard deviations between 2 and 6%. They obey an energy dependence ?=?E12 in accord with the calculation of Lindhard and Scharff. It has been shown that while there is probably an effect due to chemical binding on the helium-ion stopping cross sections of hydrocarbons, this effect is small.

John T. Park

1965-05-31T23:59:59.000Z

333

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

SciTech Connect

We have suggested that certain plants rich in hydrocarbon-like materials might be cultivated for renewable photosynthetic products. Two species were selected for experimental plantations: Euphorbia lathyris, an annual from seed and Euphorbia tirucalli, a perennial from cuttings, The yield from each species is over 10 barrels of oil/acre/year without genetic or agronomic improvement. In addition to plants, there are trees, such as species of Copaifera in Brazil and other tropical areas, which produce a diesel-like oil upon tapping. Each tree produces approximately 40 liters of hydrocarbon per year, and this material can be used directly by a diesel-powered car. Further efforts to develop plants as alternate energy sources are underway, as well as a continuing search for additional plant species throughout the world which have a similar capability.

Calvin, Melvin

1980-05-01T23:59:59.000Z

334

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents (OSTI)

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

335

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents (OSTI)

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

Hsu, Wen Ling

1987-10-14T23:59:59.000Z

336

Air pollution, avoidance behaviour and children's respiratory health: Evidence from England  

Science Journals Connector (OSTI)

Abstract Despite progress in air pollution control, concerns remain over the health impact of poor air quality. Governments increasingly issue air quality information to enable vulnerable groups to avoid exposure. Avoidance behaviour potentially biases estimates of the health effects of air pollutants. But avoidance behaviour imposes a cost on individuals and therefore may not be taken in all circumstances. This paper exploits panel data at the English local authority level to estimate the relationship between children's daily hospital emergency admissions for respiratory diseases and common air pollutants, while allowing for avoidance behaviour in response to air pollution warnings. A 1% increase in nitrogen dioxide or ozone concentrations increases hospital admissions by 0.1%. For the subset of asthma admissions – where avoidance is less costly – there is evidence of avoidance behaviour. Ignoring avoidance behaviour, however, does not result in statistically significant underestimation of the health effect of air pollution.

Katharina Janke

2014-01-01T23:59:59.000Z

337

The effect of ozone on nicotine desorption from model surfaces:evidence for heterogeneous chemistry  

SciTech Connect

Assessment of secondhand tobacco smoke exposure using nicotine as a tracer or biomarker is affected by sorption of the alkaloid to indoor surfaces and by its long-term re-emission into the gas phase. However, surface chemical interactions of nicotine have not been sufficiently characterized. Here, the reaction of ozone with nicotine sorbed to Teflon and cotton surfaces was investigated in an environmental chamber by monitoring nicotine desorption over a week following equilibration in dry or humid air (65-70 % RH). The Teflon and cotton surfaces had N{sub 2}-BET surface areas of 0.19 and 1.17 m{sup 2} g{sup -1}, and water mass uptakes (at 70 % RH) of 0 and 7.1 % respectively. Compared with dry air baseline levels in the absence of O{sub 3}, gas phase nicotine concentrations decrease, by 2 orders of magnitude for Teflon after 50 h at 20-45 ppb O{sub 3}, and by a factor of 10 for cotton after 100 h with 13-15 ppb O{sub 3}. The ratios of pseudo first-order rate constants for surface reaction (r) to long-term desorption (k) were r/k = 3.5 and 2.0 for Teflon and cotton surfaces, respectively. These results show that surface oxidation was competitive with desorption. Hence, oxidative losses could significantly reduce long-term re-emissions of nicotine from indoor surfaces. Formaldehyde, N-methylformamide, nicotinaldehyde and cotinine were identified as oxidation products, indicating that the pyrrolidinic N was the site of electrophilic attack by O{sub 3}. The presence of water vapor had no effect on the nicotine-O{sub 3} reaction on Teflon surfaces. By contrast, nicotine desorption from cotton in humid air was unaffected by the presence of ozone. These observations are consistent with complete inhibition of ozone-nicotine surface reactions in an aqueous surface film present in cotton but not in Teflon surfaces.

Destaillats, Hugo; Singer, Brett C.; Lee, Sharon K.; Gundel, LaraA.

2005-05-01T23:59:59.000Z

338

Regressing Gas/Particle Partitioning Data for Polycyclic Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

Regressing Gas/Particle Partitioning Data for Polycyclic Aromatic Hydrocarbons ... Although PAHs can be emitted to the environment as a result of natural combustion processes (e.g., forest fires and volcanoes), human activities are believed to dominate global PAH emissions, because high atmospheric concentrations of PAHs are usually observed in urban and industrial areas where vehicle traffic, aluminum smelting, residential heating, and other activities emit PAHs into the atmosphere (4, 5). ... One of the earliest approaches to describing the G/P partitioning equilibrium of PAHs, known as the Junge?Pankow model, relates ? to PL using the following: The parameter A in this equation is sometimes interpreted as the product of two terms c and ?. ? is the surface area of particles in a unit volume of air (cm2·cm-3) and c (Pa·cm) is a substance-specific factor depending on ambient temper ature, compound, sorption sites, and the heats of desorption from surface and vaporization from the liquid compound (7, 10, 14). ...

Yushan Su; Ying Duan Lei; Frank Wania; Mahiba Shoeib; Tom Harner

2006-04-22T23:59:59.000Z

339

Emergency action -- Hydrocarbon spill MCB Camp Pendleton, California  

SciTech Connect

On 10 April 1991, the Camp Pendleton Natural Resources Management Office received notice that a diesel fuel pipeline located at the Naval Regional Medical Center near Lake O`Neill had leaked on 5 April 1991. The leakage occurred from an exposed, ruptured fuel line that was used to transfer fuel between 12 underground storage tanks at a fuel farm and two large underground day tanks next to the hospital boiler building. The loss consisted of approximately 8,000 gallons of diesel {number_sign}2 fuel oil. The spill saturated the soil around the pipeline as well as overflowing into downslope utility conduits and vaults with termination upon a river terrace approximately 0.5 miles downslope of the spill area, and within 500 feet of the Santa Margarita River Channel, an aquifer recharge area. Because local groundwater is the primary freshwater resource for Camp Pendleton, the concern that this spill could immediately contaminate the local groundwater supply initiated an on-site emergency task order that consisted of emergency containment, neutralization, assessment, remediation and restoration of the hydrocarbon spill. The emergency action included containment and removal of free product in electrical conduits and vaults, neutralization of existing utility containment sources, removal and assessment of contaminated soils using excavation equipment, hollow-stem auger/dual percussion/and air rotary drilling rigs, and the creation of a bioremediation treatment cell adjacent to the spill site.

O`Connor, D. [IT Corp., San Diego, CA (United States)

1994-12-31T23:59:59.000Z

340

Ozone-forming potential of a series of oxygenated organic compounds  

SciTech Connect

An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

342

The Ozone Dilemma: a reference handbook (Contemporary World Issues Series)  

E-Print Network (OSTI)

Dilemma: a reference handbook By David E. Newton Reviewed byDilemma: a reference handbook (Contemporary World IssuesThe Ozone Dilemma: a reference handbook is targeted at both

Li, Haipeng

1997-01-01T23:59:59.000Z

343

Spatial variations and chronologies of aliphatic hydrocarbons in Lake Michigan sediments.  

SciTech Connect

Four sediment cores were collected in fine-grained depositional areas of the southern basin of Lake Michigan. Spatial variations of aliphatic hydrocarbons in surficial sediments were consistent with a lakeward movement of riverine sediments in a series of resuspension-settling cycles in which an unresolved complex mixture (UCM) of hydrocarbons associated with dense sediments is deposited in nearshore areas, fine-grained sediments of terrestrial origin accumulate in the deep basin, and planktonic hydrocarbons are depleted by microbial degradation during transport to the deep basin. The rate of accumulation of the UCM (a marker of petroleum residues) in deep basin sediments has increased by more than an order of magnitude since 1880, from 60 {mu}g m{sup -2}{center_dot}a{sup -1} to approximately 960 {mu}g m{sup -2}{center_dot}a{sup -1} in 1980. Crude estimates of the atmospheric loading of the UCM (1100 {mu}g m{sup -2}{center_dot}a{sup -1}) indicate that accumulations in deep-basin sediments might be supported by atmospheric deposition. Agreement was poor between the atmospheric flux of the terrestrial n-alkanes ({Sigma}C{sub 25}, C{sub 27}, C{sub 29}, C{sub 31}) to the deep basin (3200 {mu}g m{sup -2}{center_dot}a{sup -1}) and the sediment accumulation rate (660 {mu}g m{sup -2}{center_dot}a{sup -1}). Understanding of atmospheric fluxes, estimated from the very few available data, would be improved by more frequent measurement of the levels of aliphatic hydrocarbons in air and precipitation and a better knowledge of the particle deposition velocities and precipitation scavenging coefficients.

Doskey, P. V.; Environmental Research

2001-01-15T23:59:59.000Z

344

The role of ozone in tracheal cell transformation  

SciTech Connect

This project examined the potential role of ozone as a respiratory carcinogen by characterizing its ability to induce or modulate the preneoplastic transformation of rat tracheal epithelial cells. The chemical reactivity of ozone and the types of damage it can cause suggest that it may have a role in environmental carcinogenesis. Few other studies have examined the direct cytotoxic or transforming effects of ozone after in vivo or in vitro exposure of cells, and no studies have been reported on the comparative effects of ozone on respiratory cells exposed in vivo or in vitro. The induction of early preneoplastic changes in populations of rat tracheal epithelial cells by carcinogens can be detected and quantified in vitro after exposures in vivo or in vitro of tracheal epithelial cells. This cell culture and transformation system was used to characterize the transforming potency of ozone. Tracheal epithelial cells were isolated from Fischer-344/N rats that had been exposed for six hours per day, five days per week for one, two, or four weeks to 0, 0.12, 0.5, or 1.0 parts per million (ppm)* ozone (sea-level equivalents). Cell populations were examined in culture for increases in the frequency of preneoplastic variants. Rats exposed to ozone did not exhibit an increase in the frequency of preneoplastic tracheal cells, although exposed tracheas did exhibit dose-dependent morphological changes. Rat tracheal epithelial cells were given single, 40-minute in vitro exposures to concentrations of ozone that did not result in any detectable decrease in colony-forming efficiency.

Thomassen, D.G.; Harkema, J.R.; Sun, J.D.; Stephens, N.D.; Griffith, W.C. (Inhalation Toxicology Research Institute, Lovelace Biomedical and Environmental Research Institute, Albuquerque, NM (United States))

1992-04-01T23:59:59.000Z

345

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

NLE Websites -- All DOE Office Websites (Extended Search)

Fractionation Hydrogen Acid, Caustic, Enzymes Wastewater Treatment Insoluble solids Biogas + Sludge Process Heat and Power Integration Corn Stover Hydrocarbon Biofuels (i.e....

346

Biological Conversion of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with...

347

CSIA of Petroleum Hydrocarbons: Forensic Fingerprinting and Oil Spill Characterisation.  

E-Print Network (OSTI)

??This thesis has identified a suite of hydrocarbon diagnostic indices to be applied in the forensic fingerprinting of diesel oil characterisation and source identification using… (more)

Muhammad, Syahidah Akmal binti

2012-01-01T23:59:59.000Z

348

The mobility of petroleum hydrocarbons in Athabasca oil sands tailings.  

E-Print Network (OSTI)

??Several oil sands tailings from Suncor Energy Inc. were analysed with respect to the mobility and solubility of the petroleum hydrocarbon (PHC) contaminants. At sites… (more)

Brickner, Heather

2014-01-01T23:59:59.000Z

349

Process for making unsaturated hydrocarbons using microchannel process technology  

DOE Patents (OSTI)

The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

2011-04-12T23:59:59.000Z

350

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents (OSTI)

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

351

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents (OSTI)

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

352

Selective aerobic oxidation of hydrocarbons over supported gold catalysts.  

E-Print Network (OSTI)

??The selective oxidation of hydrocarbons is of vital importance for the production of valuable chemicals from crude oil and natural gas resources. Unfortunately, when using… (more)

Hereijgers, B.P.C.

2011-01-01T23:59:59.000Z

353

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

354

Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst  

Energy.gov (U.S. Department of Energy (DOE))

Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance

355

Electrical dispersion of water drops suspended in hydrocarbons  

Science Journals Connector (OSTI)

The effects of alternating (50 Hz) and direct current fields on drops of distilled water in a nonpolar hydrocarbon medium were examined.

G. M. Panchenkov; V. V. Papko; V. Ya. Baranov

1968-10-01T23:59:59.000Z

356

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents (OSTI)

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

357

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

358

Implementation and Application of SAPRC07 and MCM Mechanisms in the Multi-scale Community Air Quality Model  

E-Print Network (OSTI)

mechanism. In this study, two state-of-the-science photochemical mechanisms, SAPRC07 and Master Chemical Mechanism (MCM) v3.1, were implemented in the Community Multi-scale Air Quality Model (CMAQ) version 4.6 developed by the US EPA to study a high ozone (O...

Li, Jingyi

2012-02-14T23:59:59.000Z

359

Exposure-Relevant Ozone Chemistry in Occupied Spaces  

E-Print Network (OSTI)

C.J. , 2004. Cleaning products and air fresheners: Exposurepollutants from cleaning product and air freshener use in2006b. Cleaning products and air fresheners: emissions and

Coleman, Beverly Kaye

2009-01-01T23:59:59.000Z

360

Update on State Air Emission Regulations That Affect Electric Power Producers (released in AEO2005)  

Reports and Publications (EIA)

Several states have recently enacted air emission regulations that will affect the electricity generation sector. The regulations are intended to improve air quality in the states and assist them in complying with the revised 1997 National Ambient Air Quality Standards (NAAQS) for ground-level ozone and fine particulates. The affected states include Connecticut, Massachusetts, Maine, Missouri, New Hampshire, New Jersey, New York, North Carolina, Oregon, Texas, and Washington. The regulations govern emissions of NOx, SO2, CO2, and mercury from power plants.

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Catalytic ozonation of phenol in water with natural brucite and magnesia  

Science Journals Connector (OSTI)

Natural brucite and magnesia were applied as catalysts in catalytic ozonation of phenol in this work. It was found that both brucite and magnesia had remarkable accelerations on degradation of phenol and removal of COD in water. On this basis, effective and feasible routes for catalytic ozonation of phenol in water were proposed. The influence of initial pH value, radical scavengers and reaction temperature were investigated. The results revealed that there were different ozonation mechanisms in two systems: molecular ozone direct oxidation mechanism was proved in catalytic ozonation with brucite, and hydroxyl radical mechanism was demonstrated to play a main role in catalytic ozonation with magnesia.

Kun He; Yu Ming Dong; Zhen Li; Lin Yin; Ai Min Zhang; Yi Chun Zheng

2008-01-01T23:59:59.000Z

362

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

363

Assessing air quality in Hong Kong: A proposed, revised air pollution index (API)  

Science Journals Connector (OSTI)

The Environment Protection Department of Hong Kong has been using an air pollution index (API) to report the status of ambient air quality since 1995. Such an index system was first developed by the USA Environmental Protection Authority. The API compares five main air pollutants, i.e. sulfur dioxide (SO2), respirable suspended particulates (RSP), nitrogen dioxide (NO2), carbon monoxide (CO) and Ozone (O3) as sub-indexes, which are calculated separately from a segmented linear function that transforms ambient pollutants concentrations into a normalized scale extending from 0 to 500. The resultant pollution level is described by the maximal value of these five sub-indexes. The limitation of this API system is that it considers only one pollutant with the maximum value at a time but reflects other pollutants concurrently. In this study, a revised air quality index (RAPI) is proposed based on the entropy function, which combines the effect of all pollutants on public health. The design of the revised index is based on database of air pollutants collected at two air quality monitoring stations in Hong Kong, i.e. a roadside station in Mong Kok and a general station in Sha Tin. Compared with the existing API, values of RAPI (calculated from data collected for API) at both stations are at higher levels and provide more information of levels of all pollutants. Therefore, RAPI should be representatively and widely used to provide the public with a better indicator of air quality. In addition, variations and oscillations of pollutants concentrations were also examined and the results show that RSP and NO2 contribute more to the overall pollution level than other components. It is suggested that more abatement strategies be focused on these pollutants to improve air quality in the future.

Wei-Zhen Lu; Hong-di He; Andrew Y.T. Leung

2011-01-01T23:59:59.000Z

364

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

365

Air Leakage of Furnaces and Air Handlers  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Leakage of Furnaces and Air Handlers Air Leakage of Furnaces and Air Handlers Title Air Leakage of Furnaces and Air Handlers Publication Type Journal Article LBNL Report Number LBNL-5553E Year of Publication 2010 Authors Walker, Iain S., Mile Lubliner, Darryl J. Dickerhoff, and William W. Delp Journal 2010 ACEEE Summer Study on Energy Efficiency in Buildings The Climate for efficiency is now Date Published 08/2010 Abstract In recent years, great strides have been made in reducing air leakage in residential and to a lesser extent small commercial forced air duct systems. Several authorities have introduced low leakage limits for thermal distribution systems; for example, the State of California Energy Code for Buildings gives credit for systems that leak less than 6% of the total air flow at 25 Pa.

366

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons were quantitatively...polycyclic aromatic hydrocarbon constituent in a kerosene...polycyclic aromatic hydrocarbon fraction in terms of...formed by the incomplete combustion of organic material...and sediments (1), heat and power generation...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

367

E-Print Network 3.0 - aromatic hydrocarbon investigation Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

368

E-Print Network 3.0 - aromatic hydrocarbons investigated Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

369

E-Print Network 3.0 - aromatic hydrocarbon components Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

370

E-Print Network 3.0 - aromatic hydrocarbon molecules Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

371

E-Print Network 3.0 - aromatic hydrocarbons molecules Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

372

E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

373

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

...research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion...mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...Carcinogens 0 Epoxy Compounds 0 Fuel Oils 0 Hydrocarbons 0 Naphthalenes...

1975-01-01T23:59:59.000Z

374

Determination of hydrocarbons in water – interlaboratory method validation before routine monitoring  

Science Journals Connector (OSTI)

The clarification of hydrocarbon input into the Baltic sea via rivers ... of a new method for the determination of hydrocarbons by solvent extraction and gas chromatography. Surrogate oil solutions with known hydrocarbon

P. Woitke; Reinhard Kreßner; Peter Lepom

2001-04-01T23:59:59.000Z

375

Process for using preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream, wherein a need exists for recovering to any selected degree and at extremely high recoveries a selected hydrocarbon component and heavier hydrocarbons. The hydrocarbons are within the group consisting of ethane, propane, butane, and pentane without the need simultaneously to recover hydrocarbons lighter than the selected hydrocarbon component from the hydrocarbon gas stream, The improvement of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent is described here. The method provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100%.

Mehra, Y.R.

1986-10-14T23:59:59.000Z

376

Metal-Air Batteries  

SciTech Connect

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

377

Hydrocarbon steam reforming using series steam superheaters  

SciTech Connect

In a process for steam reforming of a hydrocarbon gas feedstream wherein: the hydrocarbon gas feedstream is partially reformed at elevated temperatures in indirect heat exchange with hot combustion gases in a direct fired primary reforming furnace provided with a convection section for recovery of excess heat from said combustion gases; and the partially reformed feedstream is then further reformed in the presence of an oxygen-containing gas and steam in a secondary reformer to form a secondary reformer gaseous effluent; the improvement which comprises recovering waste heat from said secondary reformer effluent gas and from said primary reforming combustion products by heating a high pressure saturated steam in a first steam superheating zone by indirect heat exchange with at least a portion of said secondary reformer effluent gas to form a first superheated steam stream; and further heating said first superheated steam in a second steam superheating zone by indirect heat exchange with at least a portion of said primary reformer hot combustion gases for form a second superheated steam stream.

Osman, R. M.

1985-10-08T23:59:59.000Z

378

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

Energy.gov (U.S. Department of Energy (DOE))

This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

379

Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants  

E-Print Network (OSTI)

1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

Paris-Sud XI, Université de

380

Contemplation on the heats of combustion of isomeric hydrocarbons  

Science Journals Connector (OSTI)

Within the Hückel molecular orbital theory, the heats of combustion of isomeric hydrocarbons are related to some topological factors. The standard heats of combustion values of alternant hydrocarbons, expressed as kcal/g, seem to be related to a4 coefficient of their secular polynomials.

Lemi Türker

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network (OSTI)

aromatic hydrocarbons PAHs up to 788 amu (C64H20) were detected in the combustion gases. Only the most applications including heating systems and gas turbines for electric power generation.62­64 The combustionFormation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss

Sattler, Klaus

382

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

383

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Energy.gov (U.S. Department of Energy (DOE))

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

384

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

385

High levels of carcinogenic polycyclic aromatic hydrocarbons in mate drinks  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mate drinks Farin Kamangar...exposure to polycyclic aromatic hydrocarbons (PAHs), including known...80 oC) or cold (4 oC) water and two commonly used brands...Infusions were made by adding water to the leaves, steeping for...

Farin Kamangar; Michele Schantz; Christian Abnet; Renato Fagundes; and Sanford Dawsey

2008-05-01T23:59:59.000Z

386

Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids  

E-Print Network (OSTI)

O H H Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids O O t-BuO3C Br O O Br Br Ph PhPh Ph PhPh Ph Ph COOH HOOC Total Synthesis of Convex Polyhedral Hydrocarbons The Five Matter Icosahedron Water · Polyhedron: a closed surface made up of polygonal regions. · Regular

Stoltz, Brian M.

387

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings  

Science Journals Connector (OSTI)

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings ... Relation between Bioavailability and Fuel Oil Hydrocarbon Composition in Contaminated Soils ...

Claude-Henri. ChaIneau; Jean-Louis. Morel; Jean. Oudot

1995-06-01T23:59:59.000Z

388

E-Print Network 3.0 - aromatic hydrocarbon exposure Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and...

389

E-Print Network 3.0 - aromatic hydrocarbon contamination Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs). PAHs are...

390

E-Print Network 3.0 - aromatic hydrocarbon receptor Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

aromatic hydrocarbons... the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

391

E-Print Network 3.0 - aromatic hydrocarbons extracted Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs)....

392

E-Print Network 3.0 - aromatic hydrocarbon metabolism Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

hydrocarbon is introduced into the ocean via oil spillage, offshore drilling leaks, industrial... hydrocarbons have been attributed to inhibition of ... Source: National...

393

E-Print Network 3.0 - aromatic hydrocarbon-degrading bacteria...  

NLE Websites -- All DOE Office Websites (Extended Search)

ydrocarbonDegradation It was hypothesized... aromatic hydrocarbon degradation. Hypothesis Test Result Groundwater stimulates Fe(lll) reduction Cell... Hydrocarbon Degradation At...

394

A generalized viscosity equation for pure heavy hydrocarbons  

SciTech Connect

This paper presents a method for the correlation and prediction of the viscosity of pure heavy hydrocarbons listed in API Research Project 42. The 273 heavy hydrocarbons in the database include branched/unbranched paraffins and olefins together with a variety of complex nonfused/fused aromatic and naphthenic compounds. A generalized one-parameter viscosity-temperature equation, log ({mu} + 0.8) = 100(0.01T){sup b}, is proposed (overall AAD {lt} 7-10%) for all heavy hydrocarbons in the database. For each hydrocarbon, an optimum value of parameter b is provided. It is shown that parameter b varies linearly with the logarithm of molar mass as well as the inverse of boiling temperature (at 10 mmHg). This important observation leads to the development of a predictive method for the liquid-phase viscosity of pure heavy hydrocarbons.

Mehrotra, A.K. (Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta T2N 1N4 (CA))

1991-02-01T23:59:59.000Z

395

Cogeneration systems and processes for treating hydrocarbon containing formations  

DOE Patents (OSTI)

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

396

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents (OSTI)

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

397

Remote Sensing of Mobile Source Air Pollutant Emissions: Variability and Uncertainty in On-Road Emissions  

E-Print Network (OSTI)

-Road Emissions Estimates of Carbon Monoxide and Hydrocarbons for School and Transit Buses Report No. FHWY/NC/97Remote Sensing of Mobile Source Air Pollutant Emissions: Variability and Uncertainty in On.0 INTRODUCTION 1 1.1 Mobile Source Emissions 2 1.2 Emission Regulations 2 1.3 Emissions Contributions of "Non

Frey, H. Christopher

398

E-Print Network 3.0 - atmospheric ozone depletion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

H. U., The ozone distributionin the atmosphere,Can. J. Chem., 52, 1491-1504, 1974. Farman, J. C... , Quasi-biennial modulation of the Antarctic ozone ... Source: Bowman,...

399

E-Print Network 3.0 - arctic ozone hole Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

The discovery of the ozone hole in the Southern Hemi- sphere... (Chubachi, 1984; Farman et al., 1985), winter ozone losses over the Arctic (e.g. Brune et al., 1991... .,...

400

E-Print Network 3.0 - antarctic ozone depletion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

-B and Biosphere." Oecologia 128(1-2): 1-296. (1997). Ozone depletion FAQ Part IV: UV radiation and its effects... -B radiation due to stratospheric ozone depletion on global...

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

E-Print Network 3.0 - acute ozone-induced change Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract Predicting ozone-induced reduction of carbon... a leaf-level model to the whole tree, it is possible to investigate whether the ozone-induced ... Source: Michigan...

402

Interannual Variations of Total Ozone at Northern Midlatitudes Correlated with Stratospheric EP Flux and Potential Vorticity  

Science Journals Connector (OSTI)

At northern midlatitudes over the 1979–2002 time period, column ozone trends are observed to have maximum negative amplitudes in February and March. Here, the portion of the observed ozone interannual variability and trends during these months ...

L. L. Hood; B. E. Soukharev

2005-10-01T23:59:59.000Z

403

Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone  

E-Print Network (OSTI)

Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated

Barthelat, Francois

404

E-Print Network 3.0 - acid regulates ozone-induced Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

ozone-induced Search Powered by Explorit Topic List Advanced Search Sample search results for: acid regulates ozone-induced Page: << < 1 2 3 4 5 > >> 1 Plant Molecular Biology 51:...

405

A delayed effect of ozone fumigation on photosynthesis of Norway spruce  

E-Print Network (OSTI)

A delayed effect of ozone fumigation on photosynthesis of Norway spruce D. Eamus1 A.W. Davis J into the long-lastincl effects of ozone fumiga- tion upon photosynthesis of Norway spruce. Measurements were

Paris-Sud XI, Université de

406

Air Pollution Control  

Science Journals Connector (OSTI)

Petroleum and chemical processes are responsible for many emissions both into the air. Most relevant emissions into the air are nitrous oxides (NOx), sulfur oxides ... compounds (VOC).The major cause of all air pollution

Alireza Bahadori

2014-01-01T23:59:59.000Z

407

Hickam Air Force Base  

Energy.gov (U.S. Department of Energy (DOE))

Hickam Air Force Base spans 2,850 acres in Honolulu, Hawaii. The military base is home to the 15th Airlift Wing, the Hawaii Air National Guard, and the Pacific Air Forces headquarters.

408

OLYMPIC AIR QUALITY QUESTIONABLE  

Science Journals Connector (OSTI)

OLYMPIC AIR QUALITY QUESTIONABLE ... Athletes GOING FOR GOLD worry about Beijing’s air ... Atmospheric chemists say the air quality during the Beijing Games literally rests on which direction the winds blow. ...

RACHEL PETKEWICH

2008-07-28T23:59:59.000Z

409

Air Quality and Pollution  

Science Journals Connector (OSTI)

Air quality refers to the physical, chemical, and biological characteristics of air, both in outside space and in enclosed ... other non?industrial working places, and residencies. Air pollution is the abnormal ...

Zoran Marmut

2008-01-01T23:59:59.000Z

410

Atmospheric Environment 38 (2004) 14251436 A development of ozone abatement strategies for the Grenoble  

E-Print Network (OSTI)

with the time evolution of the ozone isopleths at the maximums locations (south and north west valleys). r 2003

411

Dispersion modeling of selected \\{PAHs\\} in urban air: A new approach combining dispersion model with GIS and passive air sampling  

Science Journals Connector (OSTI)

Abstract This study introduces a new combined air concentration measurement and modeling approach that we propose can be useful in medium and long term air quality assessment. A dispersion study was carried out for four high molecular weight polycyclic aromatic hydrocarbons (PAHs) in an urban area with industrial, traffic and domestic heating sources. A geographic information system (GIS) was used both for processing of input data as well as visualization of the modeling results. The outcomes of the dispersion model were compared to the results of passive air sampling (PAS). Despite discrepancies between measured and modeled concentrations, an approach combining the two techniques is promising for future air quality assessment. Differences between measured and modeled concentrations, in particular when measured values exceed the modeled concentrations, are indicative of undocumented, sporadic pollutant sources. Thus, these differences can also be useful for assessing and refining emission inventories.

Ond?ej Sá?ka; Lisa Melymuk; Pavel ?upr; Alice Dvorská; Jana Klánová

2014-01-01T23:59:59.000Z

412

Meteorological Simulations of Ozone Episode Case Days during the 1996 Paso del Norte Ozone Study  

SciTech Connect

Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13,1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were petiormed using the HOTMAC mesoscale meteorological model using a 1,2,4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11-13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawirisonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. We found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

1999-02-01T23:59:59.000Z

413

Yields of Secondary Organic Aerosol from Reactions between Ozone and Surface-Adsorbed d-Limonene  

E-Print Network (OSTI)

Yields of Secondary Organic Aerosol from Reactions between Ozone and Surface-Adsorbed d, terpenes can adsorb onto building materials, and Springs et al. (2011) determined that ozone did, in fact, react with terpenes adsorbed to surfaces. The purpose of this work was to determine the yield of ozone

Siegel, Jeffrey

414

PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure  

E-Print Network (OSTI)

-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up1 PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch B.C. Stratton1, R. Knight2, and D.R. Mikkelsen1, A. Blutke3, and J

415

1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.  

E-Print Network (OSTI)

Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

Crambes, Christophe

416

Process for steam reforming of hydrocarbons  

SciTech Connect

A process is provided for the steam reforming of normally liquid hydrocarbons to produce carbon monoxide and hydrogen, which does not promote the deposition of carbonacious materials upon catalytic surfaces. The catalyst consists of nickel promoted with the oxides of iron and manganese within a specific manganese to iron ratio, said metal and metal oxides being supported upon a refractory support. The support is preferably aluminum oxide in its alpha phase having a surface area of more than 0.5 m2/gm but no more than 10 m2/gm. The metallic constituents are impregnated onto said refractory low surface area support as salts and are calcined at sufficiently high temperature to convert the salts to the oxide but at a sufficiently low temperature that they do not chemically react with the support.

Broughton, D.R.; Russ, K.J.

1980-11-11T23:59:59.000Z

417

Method and apparatus for detecting halogenated hydrocarbons  

DOE Patents (OSTI)

A halogenated hydrocarbon (HHC) detector is formed from a silent discharge (also called a dielectric barrier discharge) plasma generator. A silent discharge plasma device receives a gas sample that may contain one or more HHCs and produces free radicals and excited electrons for oxidizing the HHCs in the gas sample to produce water, carbon dioxide, and an acid including halogens in the HHCs. A detector is used to sensitively detect the presence of the acid. A conductivity cell detector combines the oxidation products with a solvent where dissociation of the acid increases the conductivity of the solvent. The conductivity cell output signal is then functionally related to the presence of HHCs in the gas sample. Other detectors include electrochemical cells, infrared spectrometers, and negative ion mobility spectrometers.

Monagle, Matthew (Los Alamos, NM); Coogan, John J. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

418

Atmospheric distribution of polycyclic aromatic hydrocarbons and deposition to Galveston Bay, Texas, USA  

Science Journals Connector (OSTI)

Estimates of the atmospheric deposition to Galveston Bay of polycyclic aromatic hydrocarbons (PAHs) are made using precipitation and meteorological data that were collected continuously from 2 February 1995 to 6 August 1996 at Seabrook, TX, USA. Particulate and vapor phase \\{PAHs\\} in ambient air and particulate and dissolved phases in rain samples were collected and analyzed. More than 95% of atmospheric \\{PAHs\\} were in the vapor phase and about 73% of \\{PAHs\\} in the rain were in the dissolved phase. Phenanthrene and napthalene were the dominant compounds in air vapor and rain dissolved phases, respectively, while 5 and 6 ring PAH were predominant in the particulate phase of both air and rain samples. Total PAH concentrations ranged from 4 to 161 ng m?3 in air samples and from 50 to 312 ng l?1 in rain samples. Temporal variability in total PAH air concentrations were observed, with lower concentrations in the spring and fall (4–34 ng m ?3) compared to the summer and winter (37–161 ng m?3). \\{PAHs\\} in the air near Galveston Bay are derived from both combustion and petroleum vaporization. Gas exchange from the atmosphere to the surface water is estimated to be the major deposition process for \\{PAHs\\} (1211 ?g m? 2 yr? 1), relative to wet deposition (130 ?g m?2 yr? 1) and dry deposition (99 ?g m?2 yr? 1). Annual deposition of \\{PAHs\\} directly to Galveston Bay from the atmosphere is estimated as 2  t yr?1.

June-Soo Park; Terry L. Wade; Stephen Sweet

2001-01-01T23:59:59.000Z

419

Secondary pollutants from ozone reactions with ventilation filters and  

NLE Websites -- All DOE Office Websites (Extended Search)

Secondary pollutants from ozone reactions with ventilation filters and Secondary pollutants from ozone reactions with ventilation filters and degradation of filter media additives Title Secondary pollutants from ozone reactions with ventilation filters and degradation of filter media additives Publication Type Journal Article Year of Publication 2011 Authors Destaillats, Hugo, Wenhao Chen, Michael G. Apte, Nuan Li, Michael Spears, Jérémie Almosni, Gregory Brunner, Jianshun(Jensen) Zhang, and William J. Fisk Journal Atmospheric Environment Volume 45 Start Page 3561 Issue 21 Pagination 3561-3568 Keywords commercial building ventilation & indoor environmental quality group, commercial building ventilation and indoor environmental quality group, energy analysis and environmental impacts department, indoor environment department, indoor environment group

420

Biofouling control with ozone at the Bergen Generating Station  

SciTech Connect

The results of a study designed to evaluate the effectiveness of ozone as an alternative to chlorine for condenser biofouling control in a once-through cooling system are reported. Tests were conducted at PSE and G's Bergen Generating Station using a pilot-scale condenser system to simulate plant condenser operations. Three model condensers were operated under identical conditions with only the biocide treatment differing. Comparisons of ozone and chlorine were made and the minimum effective levels of each were determined by daily measurements of the heat transfer coefficient across the model condenser tubes and/or the water side pressure drop. Final evaluation was based on the mass of biofouling material collected from the tubewalls. Test results indicate that chlorine is capable of effective biofouling control when applied for 2 hours/day at a level as low as 0.1 mg/l. Ozone, applied on the same schedule, requires 0.5 mg/l for effective control. The results of this study are representative of only the Bergen site. Water quality at each particular site will influence the development of the biofouling organisms, the chemical reactions of the biocides, and therefore, the effectiveness of the treatment methodology. The results suggest that further examination of ozonation for biofouling control is warranted. Although much more costly than chlorine, its effects on indigenous ecosystems may prove ozone to be better suited for application at selected power plants. It must be emphasized, however, that much more information is necessary before ozone can be recommended as an environmentally acceptable alternative to chlorine.

Sugam, R.; Guerra, C.R.; DelMonaco, J.L.; Singletary, J.H.; Sandvik, W.A.

1980-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

422

Analysis, anaerobic treatment and ozonation of wool scouring wastewater  

SciTech Connect

Wool scouring effluents (WSE) were analyzed by high-resolution gas chromatography-mass spectrometry (HRGC-MS), and then exposed to anaerobic biological treatment using laboratory scale fixed-bed filters. This resulted in a nearly 50% reduction in chemical oxygen demand (COD). Ozonation of the effluent from the biological step led to an even further decrease in total organic carbon (TOC). The fatty acid content of the WSE was affected by both biological treatment and ozonation. Finally, steroids in the WSE underwent reduction reactions when exposed to the anaerobic biological treatment.

Monteverdi, A.; Rindone, B.; Sorlini, C. (Univ. di Milano (Italy)); Andreoni, V. (Univ. di Torino (Italy)); Rozzi, A. (Inst. di Ingegneria Sanitaria del Politechnico di Milano (Italy))

1992-01-01T23:59:59.000Z

423

Iraq`s significant hydrocarbon potential remains relatively undeveloped  

SciTech Connect

Iraq is probably one of the least explored countries in the Middle East, despite the fact that it possesses one of the richest hydrocarbon basins in the world almost on a par to Saudi Arabia`s potential, if not more. The aim of this article is to state the facts about Iraq and focus on the huge but untapped and undeveloped hydrocarbon resources to the international oil community. Perhaps it is best to start by describing briefly the sedimentary and tectonic elements responsible for accumulating such large hydrocarbon resources. The paper describes the basin, tectonic elements, structural anomalies, deep drilling, source rocks, reservoir rocks, characteristics, and new reserves.

AL-Gailani, M. [GeoDesign Ltd., Kingston-upon-Thames (United Kingdom)

1996-07-29T23:59:59.000Z

424

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents (OSTI)

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

1999-07-27T23:59:59.000Z

425

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents (OSTI)

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

1999-01-01T23:59:59.000Z

426

Air Pollution Spring 2010  

E-Print Network (OSTI)

and control. 6. Examine regional and global air pollution issues. Prerequisite: CHEM 113 and (MATH 261 or MATHATS 555 Air Pollution Spring 2010 T Th 11:00 ­ 12:15, NESB 101 Instructor: Prof. Sonia Kreidenweis an understanding of types and sources of air pollution. 2. Examine concentrations of air pollutants

427

The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters  

E-Print Network (OSTI)

and biochemical oxygen demands were measured before and after ozaontion as well as the amount of ozone consumed. Non-adsorbable COD was measured and a comparison of ozonized and unozonized wastewater made. BOD concentration rose after ozonation, but decreased... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

Buys, Ronald Earl

2012-06-07T23:59:59.000Z

428

Exploring the consequences of climate change for indoor air quality  

Science Journals Connector (OSTI)

Climate change will affect the concentrations of air pollutants in buildings. The resulting shifts in human exposure may influence public health. Changes can be anticipated because of altered outdoor pollution and also owing to changes in buildings effected in response to changing climate. Three classes of factors govern indoor pollutant levels in occupied spaces: (a) properties of pollutants; (b) building factors, such as the ventilation rate; and (c) occupant behavior. Diversity of indoor conditions influences the public health significance of climate change. Potentially vulnerable subpopulations include not only the young and the infirm but also those who lack resources to respond effectively to changing conditions. Indoor air pollutant levels reflect the sum of contributions from indoor sources and from outdoor pollutants that enter with ventilation air. Pollutant classes with important indoor sources include the byproducts of combustion, radon, and volatile and semivolatile organic compounds. Outdoor pollutants of special concern include particulate matter and ozone. To ensure good indoor air quality it is important first to avoid high indoor emission rates for all pollutants and second to ensure adequate ventilation. A third factor is the use of air filtration or air cleaning to achieve further improvements where warranted.

William W Nazaroff

2013-01-01T23:59:59.000Z

429

E-Print Network 3.0 - aromatic hydrocarbon emission Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

emission Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic hydrocarbon emission...

430

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network (OSTI)

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

431

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents (OSTI)

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

432

Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch  

SciTech Connect

The technical feasibility of using an induction-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz and ~11 kVA with an argon/oxygen mixture as the plasma-forming gas. A gaseous oxygen quench formed ozone by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in the reaction chamber was measured by Fourier Transform infrared (FTIR) spectroscopy over a wide range of experimental configurations. The geometry of the quench gas flow, the quench flow velocity, and the quench flow rate played important roles in determining the ozone concentration. The ozone concentration was sensitive to the torch RF power, but was insensitive to the torch gas flow rates. These observations are interpreted within the framework of a simple model of ozone synthesis.

A. Blutke; B.C. Stratton; D.R. Mikkelsen; J. Vavruska; R. Knight

1998-01-01T23:59:59.000Z

433

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

434

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

435

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN'  

E-Print Network (OSTI)

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN' OSpemnenr Of C%sITIkby. M k I. A biographyand photograph of Kenneth D. Jordan appear In previous paper in this issue. far outweighsthat

Simons, Jack

436

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

Desai, Anuradha M.

2007-04-25T23:59:59.000Z

437

Experiments on Hydrocarbon Gas Hydrates in Unconsolidated Sand  

Science Journals Connector (OSTI)

Experiments were carried out to observe the formation and decomposition of hydrocarbon gas hydrates in an unconsolidated sand pack 4.4 cm in diameter and ... 43 bars and 5 to 10°C; gas used was 90% methane and 10...

P. E. Baker

1974-01-01T23:59:59.000Z

438

Filtration Combustion in Hydrocarbon Desorption from a Porous Medium  

Science Journals Connector (OSTI)

We have investigated theoretically and experimentally the process of filtration combustion with hydrocarbon desorption from a porous skeleton realized, in particular, in heat cleaning of porous media out of resid...

S. I. Fut'ko; K. V. Dobrego; E. S. Shmelev…

2003-11-01T23:59:59.000Z

439

Fireball during combustion of hydrocarbon fueld releases II. Thermal radiation  

Science Journals Connector (OSTI)

The processes of radiative heat transfer in a fireball which develops upon ignition of a cloud of hydrocarbon fuel near the Earth’s surface are simulated numerically. The emissive characteristics of combustion pr...

G. M. Makhviladze; J. P. Roberts; S. E. Yakush

440

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network (OSTI)

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Effect of the Composition of Hydrocarbon Streams on HCCI Performance  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of hydrocarbon samples and can be treated as compositional variables which could describe bulk properties of the samples Sample fingerprint STEP 1: Data receiving Q(2d)RPR How...

442

Hydrocarbon pollution control and remediation of groundwater: a brief review  

Science Journals Connector (OSTI)

...oil-contaminated sediments. There are two main remediation techniques: soil washing and bio- remediation. With soil washing, contaminated soil is leached with water containing a surfactant to assist in hydrocarbon removal. In situ washing is undertaken...

L. Clark

443

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE.  

Science Journals Connector (OSTI)

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE. ... Citation data is made available by participants in CrossRef's Cited-by Linking service. ... Experimental methods included adiabatic heat-capacity calorimetry (5 K to 420 K), comparative ... ...

Theodore W. Richards; Frederick Barry

1915-01-01T23:59:59.000Z

444

Measurements of dissolved nonmethane hydrocarbons in sea water  

Science Journals Connector (OSTI)

An automated stripping technique for the measurement of dissolved hydrocarbons in sea water is presented together with some results obtained ... cruise from Europe to Brazil. The sea water concentrations of NMHC ...

C. Plass; R. Koppmann; J. Rudolph

445

Hygienic rating of hydrocarbons in bottom deposits of water ecosystems  

Science Journals Connector (OSTI)

The authors of this article draw the reader’s attention to the topical problem of the contamination of bottom deposits of water ecosystems by hydrocarbons, such as oil and gas condensate,...

Rauf Valievich Galiulin…

2014-05-01T23:59:59.000Z

446

Are Ventilation Filters Degrading Indoor Air Quality in California Classrooms?  

E-Print Network (OSTI)

2007) “Ozone Removal by HVAC Filters. ” Atmos.  Environ.  HVAC filters  ozone deposition in  HVAC filters and byproduct formation, 

Fisk, Michael G. Apte and William J.

2009-01-01T23:59:59.000Z

447

Transport Modeling of Membrane Extraction of Chlorinated Hydrocarbon from Water for Ion Mobility Spectrometry  

SciTech Connect

Membrane-extraction Ion Mobility Spectrometry (ME-IMS) is a feasible technique for the continuous monitoring of chlorinated hydrocarbons in water. This work studies theoretically the time-dependent characteristics of sampling and detection of trichloroethylene (TCE). The sampling is configured so that aqueous contaminants permeate through a hollow polydimethylsiloxane (PDMS) membrane and are carried away by a transport gas flowing through the membrane tube into IMS analyzer. The theoretical study is based on a two-dimensional transient fluid flow and mass transport model. The model describes the TCE mixing in the water, permeation through the membrane layer, and convective diffusion in the air flow inside membrane tube. The effect of various transport gas flow rates on temporal profiles of IMS signal intensity is investigated. The results show that fast time response and high transport yield can be achieved for ME-IMS by controlling the flow rate in the extraction membrane tube. These modeled time-response profiles are important for determining duty cycles of field-deployable sensors for monitoring chlorinated hydrocarbons in water.

Zhang, Wei [ORNL; Du, Yongzhai [ORNL; Feng, Zhili [ORNL; Xu, Jun [ORNL

2010-01-01T23:59:59.000Z

448

Volatile tritiated organic acids in stack effluents and in air surrounding contaminated materials  

SciTech Connect

A small fraction of the tritium released into the atmosphere from tritium-handling or solid waste storage facilities was shown to be in the form of volatile organic acids. The same compounds were also found, but at a much higher proportion, in the tritium evolved at room temperature from highly contaminated materials placed under air atmospheres. This might be due to the oxidation and labeling of hydrocarbon(s) by mechanisms that are presumably of a radiolytic nature. The new forms could have an impact on operational requirements and waste management strategies within a tritium facility and a fusion reactor hall. Further data are needed to assess the related doses.

Belot, Y.; Camus, H.; Marini, T.; Raviart, S. (Institut de Protection et de Surete Nucleaire (France))

1993-06-01T23:59:59.000Z

449

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents (OSTI)

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

450

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network (OSTI)

CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 2000 Major Subject: Chemical Engineering CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Alkhawaldeh, Ammar

2012-06-07T23:59:59.000Z

451

Exploring relationships between outdoor air particulate-associated  

NLE Websites -- All DOE Office Websites (Extended Search)

Exploring relationships between outdoor air particulate-associated Exploring relationships between outdoor air particulate-associated polycyclic aromatic hydrocarbon and PM2.5: A case study of benzo(a)pyrene in California metropolitan regions Title Exploring relationships between outdoor air particulate-associated polycyclic aromatic hydrocarbon and PM2.5: A case study of benzo(a)pyrene in California metropolitan regions Publication Type Journal Article LBNL Report Number LBNL-514E Year of Publication 2008 Authors Lobscheid, Agnes B., Thomas E. McKone, and D. A. Valleroc Journal Atmospheric Environment Volume 41 Start Page Chapter Pagination 5659-5672 Abstract Polycyclic aromatic hydrocarbons (PAHs) and particulate matter (PM) are co-pollutants emitted as by-products of combustion processes. Convincing evidence exists for PAHs as a primary toxic component of fine PM (PM2.5). Because PM2.5 is listed by the US EPA as a "Criteria Pollutant," it is monitored regularly at sites nationwide. In contrast, very limited data is available on measured ambient air concentrations of PAHs. However, between 1999-2001, ambient air concentrations of PM2.5 and benzo(a)pyrene (BaP) are available for California locations. We use multivariate linear regression models (MLRMs) to predict ambient air levels of BaP in four air basins based on reported PM2.5 concentrations and spatial, temporal and meteorological variables as variates. We obtain an R2 ranging from 0.57-0.72 among these basins. Significant variables (p<0.05) include the average daily PM2.5 concentration, wind speed, temperature and relative humidity, and the coastal distance as well as season, and holiday or weekend. Combining the data from all sites and using only these variables to estimate ambient BaP levels, we obtain an R2 of 0.55. These R2-values, combined with analysis of the residual error and cross validation using the PRESS-statistic, demonstrate the potential of our method to estimate reported outdoor air PAH exposure levels in metropolitan regions. These MLRMs provide a first step towards relating outdoor ambient PM2.5 and PAH concentrations for epidemiological studies when PAH measurements are unavailable, or limited in spatial coverage, based on publicly available meteorological and PM2.5 data

452

Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer  

E-Print Network (OSTI)

Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 Mainz, Germany M. Oppenheimer (*) Department of Geosciences, Princeton University, Princeton, NJ 08544, USA e-mail: omichael@princeton.edu M. Oppenheimer Woodrow Wilson School of Public and International

Oppenheimer, Michael

453

Investigation of the Atmospheric Ozone Impacts of Methyl Iodide  

E-Print Network (OSTI)

J. R. Holmes (1977): “Nitrogen Dioxide Photolysis in the LosO3 Ozone NO Nitric Oxide NO2 Nitrogen Dioxide NO3 NitrateNitrogen Pentoxide HONO Nitrous Acid HNO3 Nitric Acid HNO4 Peroxynitric Acid HO2H Hydrogen Peroxide CO Carbon Monoxide SO2 Sulfur Dioxide

Carter, W P L

2007-01-01T23:59:59.000Z

454

International Gathering Plans Ways To Safeguard Atmospheric Ozone  

Science Journals Connector (OSTI)

International Gathering Plans Ways To Safeguard Atmospheric Ozone ... Everyone's for it, as was evidenced in Helsinki recently where senior government officials from more than 80 countries, together with delegates representing many interested groups and organizations, attended a week-long meeting to seek ways of safeguarding it. ...

DERMOT A. O'SULLIVAN

1989-06-26T23:59:59.000Z

455

Ozone Treatments of Fresh Atlantic Cod, Gadus morhua  

E-Print Network (OSTI)

, has made it a useful agent for seawater disin fection (Blogoslawski et aI., 1975; Blogoslawski, 1977 to extend the storage life of many perishable foods by slowing decomposi tion caused by microorganisms. These studies were reviewed by Farquhar and Rice (1982). Storage life extension of fish using ozone was first

456

Massive global ozone loss predicted following regional nuclear conflict  

Science Journals Connector (OSTI)

...The magnitude and duration of the predicted ozone reductions are greater than those calculated in the 1980's for global thermonuclear war scenarios involving yields that exceed the ones we considered by factors of >1000. At the time, global models had...

Michael J. Mills; Owen B. Toon; Richard P. Turco; Douglas E. Kinnison; Rolando R. Garcia

2008-01-01T23:59:59.000Z

457

Emission of polycyclic aromatic hydrocarbons in China  

SciTech Connect

Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-02-01T23:59:59.000Z

458

Rock types, pore types, and hydrocarbon exploration  

SciTech Connect

A proposed exploration-oriented method of classifying porosity in sedimentary rocks is based on microscopic examination cores or cuttings. Factors include geometry, size, abundance, and connectivity of the pores. The porosity classification is predictive of key petrophysical characteristics: porosity-permeability relationships, capillary pressures, and (less certainly) relative permeabilities. For instance, intercrystalline macroporosity typically is associated with high permeability for a given porosity, low capillarity, and favorable relative permeabilities. This is found to be true whether this porosity type occurs in a sucrosic dolomite or in a sandstone with pervasive quartz overgrowths. This predictive method was applied in three Rocky Mountain oil plays. Subtle pore throat traps could be recognized in the J sandstone (Cretaceous) in the Denver basin of Colorado by means of porosity permeability plotting. Variations in hydrocarbon productivity from a Teapot Formation (Cretaceous) field in the Powder River basin of Wyoming were related to porosity types and microfacies; the relationships were applied to exploration. Rock and porosity typing in the Red River Formation (Ordovician) reconciled apparent inconsistencies between drill-stem test, log, and mud-log data from a Williston basin wildcat. The well was reevaluated and completed successfully, resulting in a new field discovery. In each of these three examples, petrophysics was fundamental for proper evaluation of wildcat wells and exploration plays.

Coalson, E.B.; Hartmann, D.J.; Thomas, J.B.

1985-05-01T23:59:59.000Z

459

A preliminary evaluation model for reservoir hydrocarbon-generating potential established based on dissolved hydrocarbons in oilfield water  

Science Journals Connector (OSTI)

A large number of oilfield water samples were analyzed in this work. Research ... relationship between the concentrations and distribution of dissolved hydrocarbons suggested that the contents and composition of ...

Hongjing Zhao; Weilin Sun; Baotian He; Bowen Mei…

2006-01-01T23:59:59.000Z

460

Method and apparatus for reducing cold-phase emissions by utilizing oxygen-enriched intake air  

DOE Patents (OSTI)

An oxygen-enriched air intake control system for an internal combustion engine includes air directing apparatus to control the air flow into the intake of the engine. During normal operation of the engine, ambient air flowing from an air filter of the engine flows through the air directing apparatus into the intake of the engine. In order to decrease the amount of carbon monoxide (CO) and hydrocarbon (HC) emissions that tend to be produced by the engine during a short period of time after the engine is started, the air directing apparatus diverts for a short period of time following the start up of the engine at least a portion of the ambient air from the air filter through a secondary path. The secondary path includes a selectively permeable membrane through which the diverted portion of the ambient air flows. The selectively permeable membrane separates nitrogen and oxygen from the diverted air so that oxygen enriched air containing from about 23% to 25% oxygen by volume is supplied to the intake of the engine.

Poola, Ramesh B. (Woodridge, IL); Sekar, Ramanujam R. (Naperville, IL); Stork, Kevin C. (Chicago, IL)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Responses measured in the exhaled breath of human volunteers acutely exposed to ozone and diesel exhaust  

Science Journals Connector (OSTI)

Exhaled breath collection is used to identify and monitor inflammatory or oxidative components in breath. Exhaled breath sample collection is noninvasive and would greatly benefit human pollutant exposure research. We demonstrate the efficacy of exhaled breath collection and analysis in two human exposure studies to ozone (O3) and diesel exhaust, respectively. O3 study: we collected exhaled breath (gas phase) from healthy human volunteers (age 18–35 years, 12 subjects) immediately before and after exposure to filtered air or 0.4 ppm O3 for 2 h with and without intermittent exercise. Six subjects received antioxidant supplementation for 2 weeks before their O3 exposure, while the remaining six subjects received placebo treatments. We demonstrate increased amounts of non-polar carbonyls exhaled immediately post O3 exposure. The O3-induced increase in exhaled carbonyl concentrations was attenuated in the group receiving antioxidants. Our data demonstrate that exhaled exposure biomarkers can be measured in the breath gas phase in humans exposed to O3. Diesel study: we collected exhaled breath condensate (EBC; liquid phase) from healthy human volunteers (age 18–40 years; 10 subjects) immediately before, immediately after and 20 h post filtered air or diesel exhaust (106 ± 9 µg m?3) exposure. Clean air and diesel exposures were separated by 3 weeks to 6 months. We obtained reproducible intra-subject EBC volumes and total protein concentrations across our six collection time points. Diesel exposure did not affect either EBC volume or total protein concentrations. Our data demonstrated EBC volume and total protein reproducibility over several months. Volume and total protein concentration may serve as normalizing factors for other EBC constituents.

K Sawyer; J M Samet; A J Ghio; J D Pleil; M C Madden

2008-01-01T23:59:59.000Z

462

Minorities and air quality non-attainment areas: A preliminary geo-demographic analysis  

SciTech Connect

A major section of the Clean Air Act Amendments (CAAA) focuses on reducing air pollution through extending and modifying the provisions for states and localities with US Environmental Protection Agency (EPA)-designated non-attainment areas. Specifically, Title 1 of the CAAA is concerned with non-attainment areas, as defined relative to the National Ambient Air Quality Standards for atmospheric ozone, carbon monoxide, and particulate matter; Title 2 is concerned with mobile sources or air pollution, which produce carbon monoxide, contribute to ozone concentrations, and in the past have been a major source of airborne lead; and Title 4 is concerned with acid deposition, mainly due to sulfur dioxide emissions. This paper has its origin in the question of the potential benefits for minorities--relative to the majority non-Black, non-Hispanic population--of reductions in air pollution that may result from these amendments. It is part of a larger effort to identify and assess the costs and benefits of the CAAA for minorities, relative to the majority population. The focus of this paper centers on comparing Black and Hispanic populations to White, non-Hispanic populations living in EPA-designated non-attainment area counties in the contiguous United States, which excludes Alaska and Hawaii. Subsequent comparisons of majority populations with Native Americans and Asian-Americans will include these two states.

Wernette, D.; Nieves, L.

1991-06-01T23:59:59.000Z

463

on man, nature & air pollution  

E-Print Network (OSTI)

converted to form more nitrogen dioxide (this is where theillustrate the nitrogen dioxide-ozone connection. Aroundnitrogen di- oxide ( no 2)–as well as particles, organ- ic compounds, and sulfur dioxide (

Finlayson-Pitts, Barbara J

2008-01-01T23:59:59.000Z

464

An Automated System for the Measurement of Nitrogen Oxides and Ozone Concentrations from a Passenger Aircraft:? Instrumentation and First Results of the NOXAR Project  

Science Journals Connector (OSTI)

Exhaust gas from the analyzer is drawn through a thermal ozone scrubber (ECO PHYSICS) and into the vacuum pump (P1 in Figures 1 and 3). ... The individual capacity of each one of the 110 W fans (2100 m3/h in free air) is sufficient to ensure that the rack will not overheat even if the other should malfunction. ... Photolysis rates were calculated for clear-sky conditions from all daytime NO and O3 measurements at solar zenith angles <85° using the STAR (system for transfer of atmospheric radiation) model (27). ...

Peter Dias-Lalcaca; Dominik Brunner; Walter Imfeld; Werner Moser; Johannes Staehelin

1998-09-04T23:59:59.000Z

465

Air and Water Pollution  

Science Journals Connector (OSTI)

Air Pollution.... Many pollutants enter our bodies through the air we breathe at 13,000 l/day ... to quantitatively understand the basic environmental physics of pollution. This chapter covers the foll...

David Hafemeister

2014-01-01T23:59:59.000Z

466

Aesculap, Inc. Air Products  

E-Print Network (OSTI)

Aesculap, Inc. Air Products Air Products Foundation Alaric Compliance Services, LLC Alvin H. Butz & Herger, Inc. Sodexo Campus Services Sodexo Inc. and Affiliates Stupp Bros., Inc. Sugarbush Products, Inc

Napier, Terrence

467

Characterizing the Spatial Variation of Air Pollutants and the Contributions of High Emitting Vehicles in Pittsburgh, PA  

Science Journals Connector (OSTI)

We used a mobile measurement platform to characterize a suite of air pollutants (black carbon (BC), particle-bound polycyclic aromatic hydrocarbons (PB–PAH), benzene, and toluene) in the city of Pittsburgh and surrounding areas. More than 270 h of data ...

Yi Tan; Eric M. Lipsky; Rawad Saleh; Allen L. Robinson; Albert A. Presto

2014-11-13T23:59:59.000Z

468

Kidney cancer and hydrocarbon exposures among petroleum refinery workers  

SciTech Connect

To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

Poole, C.; Dreyer, N.A.; Satterfield, M.H. [Epidemiology Resources Inc., Newton Lower Falls, MA (United States); Levin, L. [Drexel Univ., Philadelphia, PA (United States)

1993-12-01T23:59:59.000Z

469

Minimize Compressed Air Leaks  

Energy.gov (U.S. Department of Energy (DOE))

This tip sheet outlines a strategy for compressed air leak detection and provides a formula for cost savings calculations.

470

Air Products effective way  

E-Print Network (OSTI)

PE O A e s a b O T A O ENNST Overview Air Products effective way standard me Departm Shipping has recently y of shipping eans. Air Pro ontainer that es of this pro onduct mark eep accelera eep the cost tilize widely a earch and m m visited Air er needs wer model was cr m approache ms

Demirel, Melik C.

471

In Situ Hydrocarbon Degradation by Indigenous Nearshore Bacterial Populations  

SciTech Connect

Potential episodic hydrocarbon inputs associated with oil mining and transportation together with chronic introduction of hydrocarbons via urban runoff into the relatively pristine coastal Florida waters poses a significant threat to Florida's fragile marine environment. It is therefore important to understand the extent to which indigenous bacterial populations are able to degrade hydrocarbon compounds and also determine factors that could potentially control and promote the rate at which these compounds are broken down in situ. Previous controlled laboratory experiments carried out by our research group demonstrated that separately both photo-oxidation and cometabolism stimulate bacterial hydrocarbon degradation by natural bacterial assemblages collected from a chronically petroleum contaminated site in Bayboro Bay, Florida. Additionally, we also demonstrated that stable carbon and radiocarbon abundances of respired CO{sub 2} could be used to trace in situ hydrocarbon degradation by indigenous bacterial populations at this same site. This current proposal had two main objectives: (a) to evaluate the cumulative impact of cometabolism and photo-oxidation on hydrocarbon degradation by natural bacterial assemblages collected the same site in Bayboro Bay, Florida and (b) to determine if in situ hydrocarbon degradation by indigenous bacterial populations this site could be traced using natural radiocarbon and stable carbon abundances of assimilated bacterial carbon. Funds were used for 2 years of full support for one ESI Ph.D. student, April Croxton. To address our first objective a series of closed system bacterial incubations were carried out using photo-oxidized petroleum and pinfish (i.e. cometabolite). Bacterial production of CO{sub 2} was used as the indicator of hydrocarbon degradation and {delta}{sup 13}C analysis of the resultant CO{sub 2} was used to evaluate the source of the respired CO{sub 2} (i.e. petroleum hydrocarbons or the pinfish cometabolite). Results from these time series experiments demonstrated that short-term exposure of petroleum to UV light enhanced hydrocarbon degradation by 48% over that observed for non-photo-oxidized petroleum. Despite the greater bio-availability of the photo-oxidized over the non-photo-oxidized petroleum, an initial lag in CO{sub 2} production was observed indicating potential phototoxicity of the photo- by-products. {delta}{sup 13}C analysis and mass balance calculations reveal that co-metabolism with pinfish resulted in increased hydrocarbon degradation for both photo-oxidized and non-photo-oxidized petroleum each by over 100%. These results demonstrate the cumulative effect of photo-oxidation and co-metabolism on petroleum hydrocarbon degradation by natural bacterial populations indigenous to systems chronically impacted by hydrocarbon input. To address the second objective of this proposal bacterial concentrates were collected from Bayboro Harbor in April 2001 for nucleic acid extraction and subsequent natural radiocarbon abundance analyses. Unfortunately, however, all of these samples were lost due to a faulty compressor in our -70 freezer. The freezer was subsequently repaired and samples were again collected from Bayboro Harbor in June 2002 and again December 2002. Several attempts were made to extract the nucleic acid samples--however, the student was not able to successfully extract and an adequate amount of uncontaminated nucleic acid samples for subsequent natural radiocarbon abundance measurements of the bacterial carbon by accelerator mass spectrometry (i.e. require at least 50 {micro}g carbon for AMS measurement). Consequently, we were not able to address the second objective of this proposed work.

Cherrier, J.

2005-05-16T23:59:59.000Z

472

AIR, CLIMATE, AND ENERGY RESEARCH Background The Clean Air Act has  

E-Print Network (OSTI)

resulted in one of the most effective public health programs in American history by providing the legislation to address air quality in the United States. The legislation has led to millions of lives saved and improved health. Research at the U.S. Environmental Protection Agency has played a significant role in these health achievements. The work by EPA scientists, engineers and partners demonstrated that exposure to air pollution damages our health, causing lung and heart disease, impacts our immune, nervous and reproductive systems, and shortens our lives. Their work has linked air pollution to disease and other health problems, contributed to important risk assessments, provided new technology and scientific tools and offered new solutions to protect and manage air quality. New Challenges Despite this progress, challenges remain and new concerns have emerged. Millions of people still live in counties that do not meet air quality standards for one or more pollutants. Research has uncovered many health threats from air pollution. EPA research continues to address these threats and understand their impact on those living in highly polluted areas, other vulnerable groups and vulnerable ecosystems. Climate change represents a major challenge to the protection of human health and the environment. EPA’s research is focused on understanding the environmental impacts of climate change and how to respond to the changes and impacts with sustainable solutions. Responding to climate change also includes reducing emissions of greenhouse gases. EPA’s research in this area is focused on the environmental impacts–both positive and negative–of possible greenhouse gas reduction approaches. The energy choices we make as a society clearly influence air quality and climate change. But how do we make energy decisions that have the least negative impact and greatest benefit? Research is under way to understand the impacts of air quality as alternative energy sources emerge. The atmosphere itself has become more complex. In the past, research has focused on the health impacts of single pollutants such as ozone or particulate matter. Yet we live in a world of multiple pollutants that interact and even create new chemicals.

unknown authors

473

Preliminary assessment of hydrocarbon potential in southern Illinois  

SciTech Connect

Hydrocarbon exploration has been sparse south of the Cottage Grove fault system in southern Illinois. Over 240,000 ac in this area are within the Shawnee National Forest (SNF). Upcoming review of mineral exploration policy on SNF land and a recent amendment to the Mineral Leasing Act (1987) will result in release of portions of the SNF for competitive and potentially noncompetitive bidding for mineral exploration tracts in the near future. Preliminary assessment of hydrocarbon potential has been carried out in southern Illinois. Numerous oil shows occur in Paleozoic strata south of the Cottage Grove fault system, which, at present, describes the southern boundary of most oil production in Illinois. Only Mitchellsville oil field in southern Saline County lies south of the Cottage Grove fault system. The Upper Devonian New Albany Shale, though to be the primary source rock for Illinois basin hydrocarbons, underlies most of the area. Older potential source rocks may be present. Depositional trends of prolific oil-productive Mississippian strata in Illinois continue southward through the area. Few drill holes have tested strata older than Mississippian in the area. Complex faulting in the Rough Creek-Shawneetown fault system may have improved the potential for hydrocarbon emplacement and entrapment in this region. Preliminary assessment of hydrocarbon potential indicates that this wildcat region deserves further tests.

Crockett, J.E.; Oltz, D.F. (Illinois State Geological Survey, Champaign (USA))

1989-08-01T23:59:59.000Z

474

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

475

Determining the Right Air Quality for Your Compressed Air System  

Energy.gov (U.S. Department of Energy (DOE))

This tip sheet outlines the main factors for determining the right air quality for compressed air systems.

476

Catalytic ozonation of azo dye active brilliant red X-3B in water with natural mineral brucite  

Science Journals Connector (OSTI)

Natural mineral brucite was used directly in catalytic ozonation of dye wastewater of active brilliant red X-3B. Compared with single ozonation, degradation of X-3B increased from 47% to 89%, and removal rate of COD increased from 9% to 32.5% in catalytic ozonation for 15 min. The catalytic ozonation of X-3B followed a direct oxidization mechanism by ozone molecule, and this was actually a homogeneous catalysis of OH? due to dissolution of Mg(OH)2 from natural brucite. As a natural mineral catalyst, brucite has supplied an economical and feasible choice for catalytic ozonation of X-3B in industrial wastewater.

Yuming Dong; Kun He; Bo Zhao; Ying Yin; Lin Yin; Aimin Zhang

2007-01-01T23:59:59.000Z

477

Trade-offs between energy cost and health impact in a regional coupled energy–air quality  

Science Journals Connector (OSTI)

This letter presents a methodology for an integrated energy–air quality model in a cost and impact trade-off framework, applicable at the regional scale. ETEM (the Energy Technology Environmental Model) minimizes the energy cost at a given level of sectoral emissions. An efficient, reduced-order Eulerian air quality model (TAPOM-Lite) simulates some consecutive days where the meteorological conditions are favorable to the occurrence of an ozone episode. A health impact function has been developed to perform the feedback from ozone concentrations to the energy cost. The decomposition optimization problem is solved using an Oracle-based technique. We report on an implementation for the Grand Duchy of Luxembourg, varying the parameters of the impact function.

D S Zachary; L Drouet; U Leopold; L Aleluia Reis

2011-01-01T23:59:59.000Z

478

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

479

Thin Air Breathing  

NLE Websites -- All DOE Office Websites (Extended Search)

Thin Air Breathing Thin Air Breathing Name: Amy Location: N/A Country: N/A Date: N/A Question: Why is it hard to breathe in thin air? What health dangers do mountain climbers face at high altitudes? Replies: Among the obvious dangers of losing ones footing, the oxygen available in the air is considerable less at higher altitudes. If I recall correctly, 21% of the atmosphere at standard temperature and pressure at sea level is composed of oxygen. This is less at higher altitudes. One can lose consciousness and even die in an oxygen deficient environment with changes from oxygen content to lower than 19.5%. This can unfortunate effect can occur within minutes. Dr. Myron The air is not really thin at high altitudes. The problem is that air pressure is lower. As altitude increases, air pressure decreases. In order for your lungs to fill with air, the air pressure in your lungs has to be less than the pressure of the air outside your lungs. Air moves from areas of higher pressure to lower pressure. As your diaphragm (the muscle that separates your chest cavity from your abdominal cavity) moves downward, the size of your chest cavity increases. This decreases the pressure in your chest and air flows in. When the diaphragm is up, it puts pressure on the chest cavity and the pressure in the lungs is greater than outside the lungs. Air flows out. This is an example of Boyle's Law. The movement of the diaphragm is controlled by the brainstem. Anyway-the reason that it is harder for some people to breathe at higher altitudes is that the air pressure differences aren't as great between the inside of the lungs and outside.

480

Determination of Polycyclic Aromatic Hydrocarbons in Fresh Milk by Hollow Fiber Liquid-Phase Microextraction–Gas Chromatography Mass Spectrometry  

Science Journals Connector (OSTI)

......Polycyclic Aromatic Hydrocarbons in Fresh Milk by...polycyclic aromatic hydrocarbons (PAHs) in fresh...more volatile and heat sensitive. The...Polycyclic aromatic hydrocarbons (PAHs) are compounds...the incomplete combustion of carbon-containing...respectively. Data were collected......

Mohd Marsin Sanagi; Saw Hong Loh; Wan Aini Wan Ibrahim; Mohamed Noor Hasan; Hassan Y. Aboul Enein

2013-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "ozone hydrocarbon air" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Hepatic coenzyme Q redox balance of fishes as a potential bioindicator of environmental contamination by polycyclic aromatic hydrocarbons  

Science Journals Connector (OSTI)

...at the land-water interface are...polycyclic aromatic hydrocarbon (PAH) contamination...Markers 0 Polycyclic Hydrocarbons, Aromatic 0 Water Pollutants, Chemical...metabolism Polycyclic Hydrocarbons, Aromatic toxicity...Ubiquinone metabolism Water Pollutants, Chemical...

2011-01-01T23:59:59.000Z

482

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents (OSTI)

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

483

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents (OSTI)

A chemical reactor for oxygenating hydrocarbons includes: (a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; (b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; (c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and (d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed. 4 figs.

Kong, P.C.; Lessing, P.A.

1995-06-27T23:59:59.000Z

484

Impact of Wildfires on Ozone Exceptional Events in the Western U.S.  

Science Journals Connector (OSTI)

Impact of Wildfires on Ozone Exceptional Events in the Western U.S. ... ? National Center for Atmospheric Research, Boulder, Colorado 80307, United States ...

Daniel A. Jaffe; Nicole Wigder; Nicole Downey; Gabriele Pfister; Anne Boynard; Stephen B. Reid

2013-08-27T23:59:59.000Z

485

Establishing Policy Relevant Background (PRB) Ozone Concentrations in the United States  

Science Journals Connector (OSTI)

National Oceanic and Atmospheric Administration, Boulder, Colorado ... Processes that contribute to PRB ozone concentrations include photochemistry associated with natural emissions of volatile organic compounds (VOCs), nitrogen oxides (NOx), and carbon monoxide (CO) from sources such as biogenic emissions (not including agricultural activities), wildfires, lightning, the long-range transport of ozone and its precursors from outside of North America, and stratospheric-tropospheric exchange (STE) of ozone. ... Models generally find little ozone production in wildfire plumes for short aging times (days) because NOx emissions are low and conversion to peroxyacetylnitrate (PAN) is rapid. ...

Elena C. McDonald-Buller; David T Allen; Nancy Brown; Daniel J. Jacob; Daniel Jaffe; Charles E. Kolb; Allen S. Lefohn; Samuel Oltmans; David D. Parrish; Greg Yarwood; Lin Zhang

2011-10-10T23:59:59.000Z

486

Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives  

E-Print Network (OSTI)

2007. Ozone removal by HVAC filters. Atmospheric Environmentozone reactions on HVAC filters cannot be ignored as aof pollutants from HVAC filters may be degradation of

Destaillats, Hugo

2012-01-01T23:59:59.000Z

487

E-Print Network 3.0 - atmospheric ozone increases Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Environmental Sciences and Ecology ; Geosciences 78 Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive...

488

E-Print Network 3.0 - ameliorate ozone effects Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: students confuse the relationship between the ozone hole and the greenhouse effect, thus confusing... , and to suggest more effective teaching methods. 2....

489

Hydrocarbon composition of crude oil from Lam Bank  

SciTech Connect

The authors discuss the crude oil from a new offshore field called the Lam Bank in the Caspian Sea. A segregated commercial crude was distilled and the distillation data is shown. In order to determine the content of n-paraffins, the naphthenic-paraffinic part of the narrow cuts was subjected to adsorptive separation on CaA zeolite. Owing to the high contents of naphthenic and isoparaffinic hydrocarbons and the low content of aromatic hydrocarbons in the distillate part, this crude can be used to produce high-quality fuels and oils by the use of the dewaxing processes.

Samedova, F.I.; Agaeva, R.M.; Alieva, F.Z.; Valiev, M.A.

1987-07-01T23:59:59.000Z

490

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents (OSTI)

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

491

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents (OSTI)

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

492

Method for determining processability of a hydrocarbon containing feedstock  

SciTech Connect

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

Schabron, John F.; Rovani, Jr., Joseph F.

2013-09-10T23:59:59.000Z

493

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents (OSTI)

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

494

Isoconversional Kinetic Analysis of the Combustion of Heavy Hydrocarbons  

Science Journals Connector (OSTI)

One method to access unconventional, heavy-oil resources as well as waterflood residual oil is to apply in situ combustion (ISC) to oxidize in place a small fraction of the hydrocarbon, thereby providing heat to reduce oil viscosity and pressure that enhances recovery. ... As shown by Vyazovkin,(12) these deviations of temperature yield erroneous values of activation energy, when such a data set is used with a model that assumes linear heating. ... Estimates were made of the heat produced, and a formula was derived for computing the heat of combustion of hydrocarbons in the high-temp. ...

Murat Cinar; Louis M. Castanier; Anthony R. Kovscek

2009-07-06T23:59:59.000Z

495

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq  

E-Print Network (OSTI)

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon after the methane flames, respectively. Three-layer, feed- forward type artificial neural networks rights reserved. Keywords: Soot; Hydrocarbon flames; Artificial neural networks 1. Introduction

Senkan, Selim M.

496

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

20 May 1975 research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion] E...have been made of their fate in mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...

1975-01-01T23:59:59.000Z

497

Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels  

Energy.gov (U.S. Department of Energy (DOE))

Syngas upgrading to hydrocarbon fuels is one of eight priority pathways chosen to convert biomass into hydrocarbon fuels by the Bioenergy Technologies Office. These pathways were down-selected from an initial list of 18.

498

Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina*  

E-Print Network (OSTI)

1/28 Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina* , P of the heat transfer dynamics. Finally, the combustion mechanism is applied and validated experimentally for kerosene pyrolysis application. Keywords Regenerative cooling; Hydrocarbon pyrolysis; Supersonic Combustion

Boyer, Edmond

499

The Energies of the Atomic Linkages in the Normal Paraffin Hydrocarbons  

Science Journals Connector (OSTI)

...normal paraffin hydrocarbons, in the gaseous...values for the heats of combustion of these gases...values for the heats of combustion of the hydrocarbon gases,4'5...Jessup4 on the heats of combustion of normal heptane...

Frederick D. Rossini

1934-01-01T23:59:59.000Z

500

E-Print Network 3.0 - aromatic hydrocarbons molecular Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... ,b, Seong Gyu Seo,c and Sang-Chai Kim d a Department of Molecular Science and...