National Library of Energy BETA

Sample records for ozone carbon monoxide

  1. Carbon Monoxide Environmental Public

    E-Print Network [OSTI]

    The National Workgroup on Carbon Monoxide Surveillance Formed in April 2005 Membership: EPHT grantees Academic

  2. What is carbon monoxide? Carbon monoxide (CO) is a poisonous,

    E-Print Network [OSTI]

    Johnson, Eric E.

    other material containing carbon such as gasoline, kerosene, oil, propane, coal, or wood. Forges, blast is the internal combustion engine. How does CO harm you? Carbon monoxide is harmful when breathed because

  3. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  4. Carbon monoxide in collapsing interstellar clouds

    E-Print Network [OSTI]

    De Jong, T.; Chu, Shih-I; Dalgarno, A.

    1975-07-01

    Calculations are made for the energy loss rates, brightness temperatures, and line profiles of carbon monoxide in collapsing interstellar clouds. The most recent data for the H2-CO collision rates have been used in the calculations; a useful...

  5. Carbon Monoxide Poisoning Avoided Through Weatherization | Department...

    Broader source: Energy.gov (indexed) [DOE]

    usual, it probably would've put me to sleep and left me there -- it was just too much carbon monoxide coming out in the house," says Mark Pickartz, of Van Buren, Ark. Pickartz's...

  6. Impact of Emissions, Chemistry, and Climate on Atmospheric Carbon Monoxide: 100-year Predictions from a Global Chemistry-Climate Model

    E-Print Network [OSTI]

    of methane and the production of CO2, ozone, and sulfate aerosols and thus affects climate, while, producing formaldehyde (CH2O) and then carbon monoxide. This methane reaction, in combination with R1

  7. Method and apparatus for selective removal of carbon monoxide

    DOE Patents [OSTI]

    Borup, Rodney L. (East Rochester, NY); Skala, Glenn W. (Churchville, NY); Brundage, Mark A. (Pittsford, NY); LaBarge, William J. (Bay City, MI)

    2000-01-01

    There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.

  8. Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter

    E-Print Network [OSTI]

    Apte, Michael G.

    2010-01-01

    Passive Colorimetric Dosimeter Tubes for Carbon Monoxide."Passive Colorimetric Dosimeter Tubes for Ammonia, CarbonPassive Badges, and Dosimeter Tubes." In: Air Sampling

  9. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    E-Print Network [OSTI]

    Joo, Sang Hoon

    2011-01-01

    sensitivity The catalytic oxidation of carbon monoxide (CO)stabilizer. The catalytic activity of CO oxidation overintriguing catalytic behavior for CO oxidation 5-15 ; while

  10. ILENR/RE-AQ-ON-ROAD CARBON MONOXIDE AND HYDROCARBON

    E-Print Network [OSTI]

    Denver, University of

    #12;ILENR/RE-AQ- Printed: Contract: Project: ON-ROAD CARBON MONOXIDE AND HYDROCARBON REMOTE SENSING. Repeat Measurements of the Same Vehicle. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 F

  11. CO (Carbon Monoxide Mixing Ratio System) Handbook

    SciTech Connect (OSTI)

    Biraud, S

    2011-02-23

    The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

  12. A global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission Spectrometer (TES)

    E-Print Network [OSTI]

    and anthropogenic incomplete combustion processes. In the presence of nitrogen oxides, carbon monoxide (COA global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission compare carbon monoxide (CO) products from the Measurements of Pollution in the Troposphere (MOPITT

  13. Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3)

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2 monoxide (CO), carbon dioxide (CO2), and molecular oxygen (O2) with varying carbon-to-oxygen ratios from 1 and destruction pathways of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3

  14. Search of medical literature for indoor carbon monoxide exposure

    SciTech Connect (OSTI)

    Brennan, T.; Ivanovich, M.

    1995-12-01

    This report documents a literature search on carbon monoxide. The search was limited to the medical and toxicological databases at the National Library of Medicine (MEDLARS). The databases searched were Medline, Toxline and TOXNET. Searches were performed using a variety of strategies. Combinations of the following keywords were used: carbon, monoxide, accidental, residential, occult, diagnosis, misdiagnosis, heating, furnace, and indoor. The literature was searched from 1966 to the present. Over 1000 references were identified and summarized using the following abbreviations: The major findings of the search are: (1) Acute and subacute carbon monoxide exposures result in a large number of symptoms affecting the brain, kidneys, respiratory system, retina, and motor functions. (2) Acute and subacute carbon monoxide (CO) poisonings have been misdiagnosed on many occasions. (3) Very few systematic investigations have been made into the frequency and consequences of carbon monoxide poisonings.

  15. Carbon monoxide sensor and method of use thereof

    DOE Patents [OSTI]

    McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

    2007-09-04

    Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

  16. A role for nickel-iron cofactors in biological carbon monoxide and carbon dioxide utilization

    E-Print Network [OSTI]

    Kung, Yan

    Ni–Fe containing enzymes are involved in the biological utilization of carbon monoxide, carbon dioxide, and hydrogen. Interest in these enzymes has increased in recent years due to hydrogen fuel initiatives and concerns ...

  17. Carbon Dioxide in Exoplanetary Atmospheres: Rarely Dominant Compared to Carbon Monoxide and Water

    E-Print Network [OSTI]

    Heng, Kevin

    2015-01-01

    We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres. We construct analytical models of systems in chemical equilibrium that include carbon monoxide, carbon dioxide, water, methane and acetylene and relate the equilibrium constants of the chemical reactions to temperature and pressure via the tabulated Gibbs free energies. We prove that such chemical systems may be described by a quintic equation for the mixing ratio of methane. By examining the abundances of these molecules across a broad range of temperatures (spanning equilibrium temperatures from 600 to 2500 K), pressures (via temperature-pressure profiles that explore albedo and opacity variations) and carbon-to-oxygen ratios (from 0.1 to 100), we conclude that carbon dioxide is subdominant compared to carbon monoxide and water. Atmospheric mixing does not alter this conclusion if carbon dioxide is subdominant everywhere in the atmosphere. Carbon dioxide and carbon monoxide may attain comparable abundances if th...

  18. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  19. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  20. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01

    carbon filters for the control of ozone, sulfur dioxide, andMendell (2008). "Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  1. Carbon Monoxide Sensor - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from thecarbon capture faqsCarbon

  2. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  3. Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice analog samples

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice O and 13 C18 O), carbon dioxide (12 C16 O2, 12 C18 O16 O, 12 C18 O2, 13 C16 O2, 13 C18 O16 O, and 13 and of carbon dioxide were extracted and fit to derive reaction mechanisms and information on the decomposition

  4. Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter

    E-Print Network [OSTI]

    Apte, Michael G.

    2010-01-01

    In. - Patty's Industrial Hygiene and Toxicology, Vol. 3A,Monoxide Detection. Industrial Hygiene Journal Match-April,Monoxide." Applied Industrial Hygiene, 4,119-125. Jabara, J.

  5. Inverting for emissions of carbon monoxide from Asia using aircraft observations over the western Pacific

    E-Print Network [OSTI]

    Palmer, Paul

    Inverting for emissions of carbon monoxide from Asia using aircraft observations over the western 2001), in combination with an optimal estimation inverse model, to improve emission estimates of carbon monoxide (CO) from Asia. A priori emissions and their errors are from a customized bottom-up Asian emission

  6. Quantifying the impact of model errors on topdown estimates of carbon monoxide emissions using satellite observations

    E-Print Network [OSTI]

    Heald, Colette L.

    Quantifying the impact of model errors on topdown estimates of carbon monoxide emissions using use of inverse modeling to better quantify regional surface emissions of carbon monoxide (CO), which to or larger than the combustion source, optimizing the CO from NMVOC emissions on larger spatial scales than

  7. Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: Signature of mountain venting?

    E-Print Network [OSTI]

    Jones, Dylan

    Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: Signature of mountain- posphere (MOPITT) satellite instrument. Enhanced CO is observed over the Zagros mountains of Iran), Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: Signature of mountain venting

  8. First principles study of carbon monoxide adsorption on zirconia-supported copper

    E-Print Network [OSTI]

    Rappe, Andrew M.

    First principles study of carbon monoxide adsorption on zirconia-supported copper Eric J. Walter a of carbon monoxide on a monolayer of copper adsorbed on the (1 1 1) face of cubic zirconia. For the bulk, oxidized and reduced (1 1 1) surfaces of cubic zirconia (c-ZrO2). For adsorption of copper

  9. Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b

    E-Print Network [OSTI]

    Zheng, Yufeng

    diameter of 30 nm and 20 layers. Nickel was observed in the tips of the nanotubes and played a crucial roleCarbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b , Y.F. Zheng a , C.S. Lee a , N was used to synthesize carbon nanotubes (CNTs) in a hot-®lament chemical vapor deposition (HFCVD) system

  10. Top-down estimate of a large source of atmospheric carbon monoxide associated with fuel combustion in Asia

    E-Print Network [OSTI]

    Palmer, Paul

    Top-down estimate of a large source of atmospheric carbon monoxide associated with fuel combustion modeling methodology, we find that the source of carbon monoxide from fossil-fuel and biofuel combustion source of atmospheric carbon monoxide associated with fuel combustion in Asia, Geophys. Res. Lett., 29

  11. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  12. Cyclic process for producing methane from carbon monoxide with heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

    1982-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  13. Production of carbon monoxide-free hydrogen and helium from a high-purity source

    DOE Patents [OSTI]

    Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

    2008-11-18

    The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

  14. NAST-I remote sensing and carbon monoxide Daniel K. Zhoua

    E-Print Network [OSTI]

    Li, Jun

    of methane (CH4), carbon monoxide (CO), and formaldehyde (CH2O), with those of the hydroxyl radical (OH) often show elevated CO and O3, the latter resulting from photochemical production.2 The importance

  15. SWNT Synthesis by Carbon Monoxide Catalytic Thermal CVD (COCCVD) Method Toshiaki NISHII1,2

    E-Print Network [OSTI]

    Maruyama, Shigeo

    plants. Furthermore, carbon dioxide gas is exhausted from most industrial plants as one of Greenhouse. (2) R. Saito, G. Dresselhaus, M. S. Dresselhaus, Physical Properties of Carbon Nanotubes, (1988 CVD SWNT Synthesis by Carbon Monoxide Catalytic Thermal CVD (COCCVD) Method * Toshiaki

  16. Carbon monoxide inhalation increases microparticles causing vascular and CNS dysfunction

    SciTech Connect (OSTI)

    Xu, Jiajun; Yang, Ming; Kosterin, Paul; Salzberg, Brian M.; Milovanova, Tatyana N.; Bhopale, Veena M.; Thom, Stephen R.

    2013-12-01

    We hypothesized that circulating microparticles (MPs) play a role in pro-inflammatory effects associated with carbon monoxide (CO) inhalation. Mice exposed for 1 h to 100 ppm CO or more exhibit increases in circulating MPs derived from a variety of vascular cells as well as neutrophil activation. Tissue injury was quantified as 2000 kDa dextran leakage from vessels and as neutrophil sequestration in the brain and skeletal muscle; and central nervous system nerve dysfunction was documented as broadening of the neurohypophysial action potential (AP). Indices of injury occurred following exposures to 1000 ppm for 1 h or to 1000 ppm for 40 min followed by 3000 ppm for 20 min. MPs were implicated in causing injuries because infusing the surfactant MP lytic agent, polyethylene glycol telomere B (PEGtB) abrogated elevations in MPs, vascular leak, neutrophil sequestration and AP prolongation. These manifestations of tissue injury also did not occur in mice lacking myeloperoxidase. Vascular leakage and AP prolongation were produced in naïve mice infused with MPs that had been obtained from CO poisoned mice, but this did not occur with MPs obtained from control mice. We conclude that CO poisoning triggers elevations of MPs that activate neutrophils which subsequently cause tissue injuries. - Highlights: • Circulating microparticles (MPs) increase in mice exposed to 100 ppm CO or more. • MPs are lysed by infusing the surfactant polyethylene glycol telomere B. • CO-induced MPs cause neutrophil activation, vascular leak and CNS dysfunction. • Similar tissue injuries do not arise with MPs obtained from air-exposed, control mice.

  17. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  18. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, A.; Jiang, Z.

    1996-05-28

    The compound, [Pd(Me-DUPHOS)(MeCN){sub 2}](BF{sub 4}){sub 2}, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic {alpha}-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone).

  19. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, Ayusman (State College, PA); Jiang, Zhaozhong (State College, PA)

    1996-01-01

    The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)

  20. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  1. Constraints on Carbon Monoxide Emissions Based on Tall Tower Measurements in the U.S. Upper Midwest

    E-Print Network [OSTI]

    Minnesota, University of

    Constraints on Carbon Monoxide Emissions Based on Tall Tower Measurements in the U.S. Upper Midwest-up emission estimates in response to top-down constraints. 1. INTRODUCTION Carbon monoxide (CO) is a precursor is emitted during the combustion of biomass and fossil fuel and produced photochemically from the oxidation

  2. The isotopic record of Northern Hemisphere atmospheric carbon monoxide1 since 1950; implications for the CO budget Supplementary Material2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 The isotopic record of Northern Hemisphere atmospheric carbon monoxide1 since 1950 as a supplement to `The isotopic record of Northern Hemisphere23 atmospheric carbon monoxide since 1950 combustion, methane oxidation, NMHC oxidation, biofuel burning, biomass burning, direct57 biogenic

  3. Poster Session 08: Bystander and other Low Dose Effect Exogenous carbon monoxide suppresses adaptive response induced

    E-Print Network [OSTI]

    Yu, Peter K.N.

    Poster Session 08: Bystander and other Low Dose Effect Exogenous carbon monoxide suppresses; adaptive response; zebrafish embryos Journal of Radiation Research, 2014, 55, i115 Supplement doi: 10 prepared medium with the chemical at different time points after the application of the priming dose. Our

  4. Effects of exogenous carbon monoxide on radiation-induced bystander effect in zebrafish embryos in vivo

    E-Print Network [OSTI]

    Yu, Peter K.N.

    that the dose-response of radiation in the low-dose regime deviated from the LNT model. A notable example radiation are linearly proportional to the absorbed dose, evidence accumulated in the past decades showed as a pharmaceutical agent to release a low dose of exogenous carbon monoxide (CO) to attenuate the effect on bystander

  5. Carbon monoxide sensor for PEM fuel cell systems Christopher T. Holta,*

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    monoxide can lead to poisoning of platinum electrocatalysts used in the fuel cells [1,2]. The reforming are converted to hydrogen and carbon mon- oxide by reactions with air (partial oxidation), with water (steam. In the third step, the gas mixture is reacted with air over a preferential oxidation (PROX) catalyst, so

  6. Crystallization and mutational studies of carbon monoxide dehydrogenase from moorella thermoacetica 

    E-Print Network [OSTI]

    Kim, Eun Jin

    2004-09-30

    Carbon Monoxide Dehydrogenase (CODH), also known as Acetyl-CoA synthase (ACS), is one of seven known Ni containing enzymes. CODH/ACS is a bifunctional enzyme which oxidizes CO to CO2 reversibly and synthesizes acetyl-CoA. Recently, X-ray crystal...

  7. Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase 

    E-Print Network [OSTI]

    Feng, Jian

    2005-08-29

    The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

  8. Stochastic resonance in surface catalytic oxidation of carbon monoxide Lingfa Yang, Zhonghuai Hou, and Houwen Xina)

    E-Print Network [OSTI]

    Yang, Lingfa

    Stochastic resonance in surface catalytic oxidation of carbon monoxide Lingfa Yang, Zhonghuai Hou: catalytic oxidation on a single sur- face, by analysis of the behavior of a set of ordinary differ- ential help researchers to find SR in this system experimentally. II. REACTION MODEL The catalytic oxidation

  9. Elevated levels of carbon monoxide in the patient compartment of ambulances

    SciTech Connect (OSTI)

    Iglewicz, R.; Rosenman, K.D.; Iglewicz, B.; O'Leary, K.; Hockemeier, R.

    1984-05-01

    Six hundred and ninety New Jersey ambulances were monitored for carbon monoxide (CO); 27 per cent had CO levels of 10 ppm or more greater than ambient air in the breathing zone of the patient. Twenty-nine of these ambulances had levels of at least 35 ppm greater than ambient air. Results indicate that a CO exposure problem exists in ambulances.

  10. Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I of surface temperature and oxygen coverage. Both the velocity and angular distributions are bimodal without first accommodating on the surface, the velocity, angular, and internal state distributions may

  11. PREFERENTIAL OXIDATION OF CARBON MONOXIDE IN A THIN-FILM CATALYTIC MICROREACTOR: ADVANTAGES AND LIMITATIONS

    E-Print Network [OSTI]

    Besser, Ronald S.

    PREFERENTIAL OXIDATION OF CARBON MONOXIDE IN A THIN-FILM CATALYTIC MICROREACTOR: ADVANTAGES stream after hydrocarbon fuel reforming and water-gas-shift reactions. This process, referred to as CO intermediate, which enhances the catalytic activity at temperatures below 200°C. With the same catalyst system

  12. Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications

    E-Print Network [OSTI]

    Cao, Guozhong

    Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications-grown and the O2-annealed TNT array electrodes. The improved biosensor properties of the TiO2 nanotube arrays were, particularly TiO2 nanotubes (TNT), which possess large surface areas, have been widely used as chemical sensors

  13. Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE

    E-Print Network [OSTI]

    Nychka, Douglas

    . Atmospheric Carbon Monoxide (CO) is an impor- tant trace gas in the atmosphere. It is produced by both natural emissions and human activities and is formed primarily through natural atmospheric oxidation processes fields of CO on short time scales. An observing framework for atmospheric composition that is analogous

  14. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  15. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  16. Name __________________ Lab 8. Air pollution: carbon monoxide & dioxide lab

    E-Print Network [OSTI]

    Perfect, Ed

    and other particles become embedded in the lungs and leads to chronic coughing and lung damage. Carbon

  17. Impact of emissions, chemistry, and climate on atmospheric carbon monoxide : 100-year predictions from a global chemistry-climate model

    E-Print Network [OSTI]

    Wang, Chien.; Prinn, Ronald G.

    The possible trends for atmospheric carbon monoxide in the next 100 yr have been illustrated using a coupled atmospheric chemistry and climate model driven by emissions predicted by a global economic development model. ...

  18. Effects on carbon monoxide levels in mobile homes using unvented kerosene heaters for residential heating

    SciTech Connect (OSTI)

    Williams, R.; Walsh, D.; White, J.; Jackson, M.; Mumford, J.

    1992-01-01

    Carbon monoxide (CO) emission levels were continuously monitored in 8 mobile trailer homes less than 10 years old. These homes were monitored in an US EPA study on indoor air quality as affected by unvented portable kerosene heaters. Respondents were asked to operate their heaters in a normal fashion. CO, air exchange and temperature values were measured during the study in each home. Results indicate that consumers using unvented kerosene heaters may be unknowingly exposed to high CO levels without taking proper precautions.

  19. Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides

    SciTech Connect (OSTI)

    Haas, P.A.; Lee, D.D.; Mailen, J.C.

    1991-11-01

    The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

  20. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2001-01-01

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  1. Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading and a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from thecarbon capture faqsCarbonProcess for its

  2. Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux measurements

    E-Print Network [OSTI]

    Goldstein, Allen

    Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux Abstract High ground-level ozone concentrations are typical of Mediterranean climates. Plant exposure to this oxidant is known to reduce carbon assimilation. Ozone damage has been traditionally measured through

  3. Process for producing hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a heteropolyanionic metal complex catalyst

    SciTech Connect (OSTI)

    Kuch, Ph. L.

    1984-12-18

    Hydrogen and carbonyl sulfide are produced by a process comprising contracting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a heteropolymolybdate or tungstate complex. Use of these catalysts reduce the amount of by-product carbon dioxide and methane formation and thus enhance the make of hydrogen and carbonyl sulfide.

  4. Solar Carbon Monoxide, Thermal Profiling, and the Abundances of C, O, and their Isotopes

    E-Print Network [OSTI]

    Thomas R. Ayres; Claude Plymate; Christoph U. Keller

    2006-06-07

    A solar photospheric "thermal profiling" analysis is presented, exploiting the infrared rovibrational bands of carbon monoxide (CO) as observed with the McMath-Pierce Fourier transform spectrometer (FTS) at Kitt Peak, and from above the Earth's atmosphere by the Shuttle-borne ATMOS experiment. Visible continuum intensities and center-limb behavior constrained the temperature profile of the deep photosphere, while CO center-limb behavior defined the thermal structure at higher altitudes. The oxygen abundance was self consistently determined from weak CO absorptions. Our analysis was meant to complement recent studies based on 3-D convection models which, among other things, have revised the historical solar oxygen (and carbon) abundance downward by a factor of nearly two; although in fact our conclusions do not support such a revision. Based on various considerations, an oxygen abundance of 700+/-100 ppm (parts per million relative to hydrogen) is recommended; the large uncertainty reflects the model sensitivity of CO. New solar isotopic ratios also are reported for 13C, 17O, and 18O.

  5. Effects of solar radiation on organic matter cycling: Formation of carbon monoxide and carbonyl sulfide (Chapter 11). Book chapter

    SciTech Connect (OSTI)

    Zepp, R.G.

    1994-01-01

    The effects of photoinduced processes on carbon cycling and the biospheric emission of two important trace carbon gases--carbon monoxide and carbonyl sulfide--are examined. Both of these gases are likely to play an important role in the biospheric feedbacks that may reinforce or attenuate future changes in climate. Evidence is presented to support the hypothesis that a significant fraction of the global sources of both of these gases derives from the photochemical fragmentation of decayed plant materials and other biogenic organic matter in terrestrial and marine environments.

  6. The Fourth Positive System of Carbon Monoxide in the Hubble Space Telescope Spectra of Comets

    E-Print Network [OSTI]

    Roxana E. Lupu; Paul D. Feldman; Harold A. Weaver; Gian-Paolo Tozzi

    2007-08-22

    The rich structure of the Fourth Positive System (A-X) of carbon monoxide accounts for many of the spectral features seen in long slit HST-STIS observations of comets 153P/Ikeya-Zhang, C/2001 Q4 (NEAT), and C/2000 WM1 (LINEAR), as well as in the HST-GHRS spectrum of comet C/1996 B2 Hyakutake. A detailed CO fluorescence model is developed to derive the CO abundances in these comets by simultaneously fitting all of the observed A-X bands. The model includes the latest values for the oscillator strengths and state parameters, and accounts for optical depth effects due to line overlap and self-absorption. The model fits yield radial profiles of CO column density that are consistent with a predominantly native source for all the comets observed by STIS. The derived CO abundances relative to water in these comets span a wide range, from 0.44% for C/2000 WM1 (LINEAR), 7.2% for 153P/Ikeya-Zhang, 8.8% for C/2001 Q4 (NEAT) to 20.9% for C/1996 B2 (Hyakutake). The subtraction of the CO spectral features using this model leads to the first identification of a molecular hydrogen line pumped by solar HI Lyman-beta longward of 1200A in the spectrum of comet 153P/Ikeya-Zhang. (Abridged)

  7. Simultaneous Detection of Water, Methane and Carbon Monoxide in the Atmosphere of Exoplanet HR8799b

    E-Print Network [OSTI]

    Barman, Travis S; Macintosh, Bruce; Marois, Christian

    2015-01-01

    Absorption lines from water, methane and carbon monoxide are detected in the atmosphere of exoplanet HR8799b. A medium-resolution spectrum presented here shows well-resolved and easily identified spectral features from all three molecules across the K band. The majority of the lines are produced by CO and H2O, but several lines clearly belong to CH4. Comparisons between these data and atmosphere models covering a range of temperatures and gravities yield log mole fractions of H2O between -3.09 and -3.91, CO between -3.30 and -3.72 and CH4 between -5.06 and -5.85. More precise mole fractions are obtained for each temperature and gravity studied. A reanalysis of H-band data, previously obtained at similar spectral resolution, results in a nearly identical water abundance as determined from the K-band spectrum. The methane abundance is shown to be sensitive to vertical mixing and indicates an eddy diffusion coefficient in the range of 10^6 to 10^8 cm^2 s^-1, comparable to mixing in the deep troposphere of Jupite...

  8. Relationship of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide yield of cigarettes

    SciTech Connect (OSTI)

    Krzyzanowski, M.; Sherrill, D.L.; Paoletti, P.; Lebowitz, M.D. )

    1991-02-01

    The data from consecutive surveys of the Tucson Epidemiologic Study (1981-1988) were used to evaluate the relationship in cigarette smokers of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide (CO) yields of the cigarette. There were 690 subjects who reported smoking regularly in at least one survey, over age 15. After adjustment for intensity and duration of smoking and for depth of inhalation, the risk of chronic phlegm, cough, and dyspnea were not related to the tar and nicotine yields. In 414 subjects with pulmonary function tested in at least one of the three surveys the spirometric indices used were significantly related to the daily dose of tar, nicotine, and CO (product of the cigarette yield and daily number of cigarettes smoked). The effects were more pronounced for past than for current doses. However, the differentiation of pulmonary function due to various yields of cigarettes was small in comparison to the difference in pulmonary function between smokers and nonsmokers.

  9. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  10. Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

  11. One-dimensional turbulence model simulations of autoignition of hydrogen/carbon monoxide fuel mixtures in a turbulent jet

    SciTech Connect (OSTI)

    Gupta, Kamlesh G.; Echekki, Tarek [Department of Mechanical and Aerospace Engineering, North Carolina State University, NC (United States)

    2011-02-15

    The autoignition of hydrogen/carbon monoxide in a turbulent jet with preheated co-flow air is studied using the one-dimensional turbulence (ODT) model. The simulations are performed at atmospheric pressure based on varying the jet Reynolds number and the oxidizer preheat temperature for two compositions corresponding to varying the ratios of H{sub 2} and CO in the fuel stream. Moreover, simulations for homogeneous autoignition are implemented for similar mixture conditions for comparison with the turbulent jet results. The results identify the key effects of differential diffusion and turbulence on the onset and eventual progress of autoignition in the turbulent jets. The differential diffusion of hydrogen fuels results in a reduction of the ignition delay relative to similar conditions of homogeneous autoignition. Turbulence may play an important role in delaying ignition at high-turbulence conditions, a process countered by the differential diffusion of hydrogen relative to carbon monoxide; however, when ignition is established, turbulence enhances the overall rates of combustion of the non-premixed flame downstream of the ignition point. (author)

  12. Line Broadening and Temperature Dependence in the 0 --> 3 Overtone Band of Carbon Monoxide Cyril Hnatovsky , Adriana Predoi-Cross , Kimberly Strong , James R. Drummond , and D. Chris Benner1 1 1 1 2

    E-Print Network [OSTI]

    Strong, Kimberly

    Line Broadening and Temperature Dependence in the 0 --> 3 Overtone Band of Carbon Monoxide Cyril. Introduction Carbon monoxide (CO) is a trace constituent present in the Earth's atmosphere. It is produced, and the incomplete combustion of fossil fuels and biomass. The lifetime of an atmospheric CO molecule is relatively

  13. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst

    SciTech Connect (OSTI)

    McGuiggan, M.F.; Kuch, P.L.

    1984-05-08

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

  14. Contribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide levels in two areas of the United States

    E-Print Network [OSTI]

    Dabdub, Donald

    - house gas, but also the hydroperoxide radical (HO2). HO2 converts nitric oxide to nitrogen dioxideContribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide. Chen, K. Carmody, S. Vutukuru, and D. Dabdub (2007), Contribution of gas phase oxidation of volatile

  15. Potentiometric CO titrations of carbon monoxide dehydrogenase and CO-inhibition of the NI-removing reaction with 1,10--phenanthroline 

    E-Print Network [OSTI]

    Russell, William Kent

    1996-01-01

    Carbon monoxide dehydrogenase from Clostridium thermoaceticum catalyzes two reactions involving redox chemistry (the reversible oxidation Of CO to C02, and the synthesis of acetyl-CoA) using three types of Ni and Fe-S structures called the A-, B...

  16. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 106, NO. D22, PAGES28,481-28,495, NOVEMBER 27, 2001 Source analysis of carbon monoxide

    E-Print Network [OSTI]

    Laat, Jos de

    Source analysis of carbon monoxide pollution during INDOEX 1999 A.T.J. de Laat, J. Lelieveld, G and higher hydrocarbons, and is directly emitted by combustion processes. Fossil fuel combustion pollution. However, the large number of possible sources in combination with the long photochemical lifetime

  17. Will Monetized Carbon Emission Reductions Buy Enhanced Building Operations? 

    E-Print Network [OSTI]

    Millhone, J.

    2007-01-01

    transportation arteries and thus are capable of measuring impacts from mobile sources as well as stationary sources. Monitoring is performed to measure the criteria pollutants (sulfur dioxide, carbon monoxide, oxides of nitrogen, lead, particulate matter.... Monitoring is performed to measure the criteria pollutants (sulfur dioxide, carbon monoxide, oxides of nitrogen, lead, particulate matter, and ozone) as well as meteorological parameters (wind speed, wind direction, wind direction variance, temperature, net...

  18. Past and Future Effects of Ozone on Net Primary Production and Carbon Sequestration Using a Global Biogeochemical Model

    E-Print Network [OSTI]

    Felzer, Benjamin Seth.

    Exposure of plants to ozone inhibits photosynthesis and therefore reduces vegetation production and carbon sequestration. Simulations with the Terrestrial Ecosystem Model (TEM) for the historical period (1860-1995) show ...

  19. Ozone effects on net primary production and carbon sequestration in the conterminous United States using a biogeochemistry model

    E-Print Network [OSTI]

    Felzer, Benjamin Seth.; Kicklighter, David W.; Melillo, Jerry M.; Wang, Chien.; Zhuang, Qianlai.; Prinn, Ronald G.

    The effects of air pollution on vegetation may provide an important control on the carbon cycle that has not yet been widely considered. Prolonged exposure to high levels of ozone, in particular, has been observed to inhibit ...

  20. Application of an all-solid-state diode-laser-based sensor for carbon monoxide detection by optical absorption in the 4.4 ? 4.8 µm spectral region 

    E-Print Network [OSTI]

    Rodolfo, Barron Jimenez

    2005-02-17

    An all-solid-state continuous-wave (cw) laser system for mid-infrared absorption measurements of the carbon monoxide (CO) molecule has been developed and demonstrated. The single-mode, tunable output of an external-cavity ...

  1. Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce lower emissions it is essential

    E-Print Network [OSTI]

    Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce

  2. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  3. An experimental investigation of the ignition properties of hydrogen and carbon monoxide

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    dioxide (CO2) were performed using a rapid compression facility. Experiments were conducted using pressure for near zero pollutant emissions, including greenhouse gases such as carbon dioxide (CO2). In particular], complicating turbine operation and design. The high-temperatures associated with the hydro- gen kinetics can

  4. Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3]) have the poten-

    E-Print Network [OSTI]

    Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3 gases (greenhouse gases) altered by human activities (IPCC 2007), only carbon dioxide (CO2 vegeta- tion properties affect local and regional climate, as well as how atmospheric forcing

  5. Catalysts for the production of hydrocarbons from carbon monoxide and water

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

    1985-11-06

    A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

  6. Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway

    SciTech Connect (OSTI)

    Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min; Xing, Mingyou; Liu, Liegang; Yao, Ping

    2013-11-15

    Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 ?mol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: • CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. • CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. • The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

  7. VOLUME 87, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 5 NOVEMBER 2001 Distinct Reaction Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110)

    E-Print Network [OSTI]

    Hla, Saw-Wai

    Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110): Scanning Tunneling Microscopy for catalytic oxidation of hydrogen on a platinum surface [3]. In the latter case, the two different mechanisms calculations, we identify the reaction mechanism for the oxidation of carbon monoxide to carbon dioxide

  8. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a multi-metal oxide/sulfide catalyst

    SciTech Connect (OSTI)

    Jevnikar, M. G.; Kuch, Ph. L.

    1985-02-19

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a catalytic composition containing an oxide and/or sulfide of at least one of molybdenum, tungsten, iron, chromium and vanadium in combination with at least one promoter metal, e.g. a catalyst of the formula Cs Cu /SUB 0.2/ Zn /SUB 0.5/ Mn /SUB 0.5/ Sn /SUB 2.4/ Mo O /SUB x/ S /SUB y/ .

  9. Carbon Monoxide Safety Tips 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Garcia, Monica L.

    1999-07-26

    problems can stem from a number of common sources?automo- biles, furnaces, water heaters, fireplaces, wood stoves, charcoal grills, gas ranges, space heaters and portable generators. Serious problems can develop when these appliances are not in good working... from one type to another without proper knowledge, skills and tools. 3 Never use a gas range, oven or clothes dryer for heating your home. 3 Never operate unvented gas-burning appli- ances, such as kerosene or natural gas space heaters, in a closed room...

  10. Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615

    SciTech Connect (OSTI)

    Wayland, B.B.

    2009-08-31

    Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

  11. Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W.J. Dawson, and P.K. Dutta

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    Research has been conducted to develop a novel sensor for the detection of carbon monoxide in the presence of hydrogen and nitrogen. The automotive fuel cell application requires a sensor to detect low levels will protect the PEM fuel cell stack; detection of CO is extremely important because too much CO will poison

  12. Near-ambient X-ray photoemission spectroscopy and kinetic approach to the mechanism of carbon monoxide oxidation over lanthanum substituted cobaltites

    SciTech Connect (OSTI)

    Hueso, J. L.; Martinez-Martinez, D.; Cabalerro, Alfonso; Gonzalez-Elipe, Agustin Rodriguez; Mun, Bongjin Simon; Salmeron, Miquel

    2009-07-31

    We have studied the oxidation of carbon monoxide over a lanthanum substituted perovskite (La0.5Sr0.5CoO3-d) catalyst prepared by spray pyrolysis. Under the assumption of a first-order kinetics mechanism for CO, it has been found that the activation energy barrier of the reaction changes from 80 to 40 kJ mol-1 at a threshold temperature of ca. 320 oC. In situ XPS near-ambient pressure ( 0.2 torr) shows that the gas phase oxygen concentration over the sample decreases sharply at ca. 300 oC. These two observations suggest that the oxidation of CO undergoes a change of mechanism at temperatures higher than 300 oC.

  13. Spring leaf flush in aspen (Populus tremuloides) clones is altered by long-term growth at elevated carbon dioxide and elevated ozone concentration

    E-Print Network [OSTI]

    carbon dioxide and elevated ozone concentration Justin M. McGrath a , David F. Karnosky b , Elizabeth A. In this study, we investigated spring leaf flush and how long-term growth at elevated carbon dioxide growth and produc- tivity are increasing atmospheric carbon dioxide concentration ([CO2]) and increasing

  14. The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters 

    E-Print Network [OSTI]

    Buys, Ronald Earl

    1980-01-01

    time of 30 days. 34 10 Correlation between measured and calculated nonadsorbable COD values for bio-oxidized samples. 37 Correlation between measured and calculated nonadsorbable COD values for bio-oxidized plus ozonated samples. 12 Effect... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

  15. Design and implementation of Carbon Monoxide and Oxygen emissions measurement in swirl-stabilized oxy-fuel combustion

    E-Print Network [OSTI]

    Sommer, Andrew (Andrew Zhang)

    2013-01-01

    Oxy-fuel combustion in natural gas power generation is a technology of growing interest as it provides the most efficient means of carbon capture. Since all the emissions from these power plants are sequestered, there are ...

  16. Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor

    SciTech Connect (OSTI)

    Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

    2010-08-31

    Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

  17. Ozone and carbon dioxide effects on spider mites in white clover and peanut

    SciTech Connect (OSTI)

    Heagle, A.S.; Brandenburg, R.L.; Burns, J.C.; Miller, J.E. [North Carolina State Univ., Raleigh, NC (United States)

    1994-11-01

    Effects of O{sub 3} and/or elevated CO{sub 2} on two-spotted spider mites (Tetranychus urticae Koch) grown on an O{sub 3}-sensitive and an O{sub 3}-resistant clone of white clover (Trifolium repens L.) were measured in greenhouse and field experiments. Peanut (Arachis hypogeae L.) {open_quote}NC-9{close_quote} was used in one greenhouse study with O{sub 3}. In field studies, O{sub 3} treatments were charcoal filtered air (CF), nonfiltered air (NF), and two NF treatments with O{sub 3} added for 12 h d{sup {minus}1} at proportions of {approx} 1.25 and 1.50 times the ambient O{sub 3} concentration. In greenhouse studies, constant amounts of O{sub 3} were added to CF for 6 h d{sup {minus}1} to achieve mean concentrations ranging from 5 to 100 nL L{sup {minus}1}. For the greenhouse O{sub 3} x CO{sub 2} experiment, CO{sub 2} concentrations were ambient and approximately twice-ambient for 24 h d{sup {minus}1}. Plants were exposed to O{sub 3} and/or CO{sub 2} for {approx} 7 d before infestation with mites; daily exposures continued for 14 to 28 d to allow reproduction for at least two generations. Leaves were sampled to count eggs, larvae, nymphs, and adults. Ozone caused more chlorosis and necrosis on the O{sub 3}-sensitive clover clone (NC-S) than on the O{sub 3}-resistant clone (NC-R). Carbon dioxide enrichment increased shoot growth of both clones by {approx}33%. Statistical analyses indicated significant O{sub 3} effects in some experiments and nonsignificant O{sub 3} effects in others. A trend toward increased mite populations with increased O{sub 3} occurred, however, on NC-S in all trials. No consistent trends occurred with NC-R. With peanut, a significant linear increase in mite population occurred with increased O{sub 3}. Carbon dioxide enrichment increased the rate of population increase on both clover clones, but more so on NC-R. 47 refs., 2 figs., 7 tabs.

  18. Kinetics of the Reduction of Wüstite by Hydrogen and Carbon Monoxide for the Chemical Looping Production of Hydrogen

    E-Print Network [OSTI]

    Liu, Wen; Lim, Jin Yang; Saucedo, Marco A.; Hayhurst, Allan N.; Scott, Stuart A.; Dennis, J. S.

    2014-08-13

    , carbon capture storage; CSTR, continuous stirred tank reactor; I.D, internal diameter; PEMFC, proton exchange membrane fuel cell; PFR, plug flow reactor; SEM, scanning electron microscopy n Corresponding author. E-mail address: wl247@cam.ac.uk (W. Liu... of unsupported wüstite, the complicating effects of supporting materials on the kinetics can be excluded. W. Liu et al. / Chemical Engineering Science 120 (2014) 149–166150 2. Experimental 2.1. Materials preparation The method of wet-granulation (Bohn et al...

  19. Formation of ketene (H{sub 2}CCO) in interstellar analogous methane (CH{sub 4})-carbon monoxide (CO) ices: A combined FTIR and reflectron time-of-flight mass spectroscopic study

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I.; Jones, Brant M.

    2014-07-01

    The formation of ketene (H{sub 2}CCO) in methane-carbon monoxide (CH{sub 4}-CO) ices was investigated upon its exposure to ionizing radiation in the form of energetic electrons at 5.5 K. The radiation-induced nonthermal equilibrium processing of these ices was monitored online and in situ via infrared spectroscopy complimented with post-irradiation temperature programmed desorption studies exploiting highly sensitive reflectron time-of-flight mass spectrometry (ReTOF) coupled with single photon fragment-free photo ionization (PI) at 10.49 eV. The detection of ketene in irradiated (isotopically labeled) methane-carbon monoxide ices was confirmed via the ?{sub 2} infrared absorption band and substantiated during the warm-up phase based on sublimation profiles obtained from the ReTOF-PI spectra of the corresponding isotopic masses. The experiments conducted with the mixed isotopic ices of {sup 12}CD{sub 4}-{sup 13}CO provide clear evidence of the formation of at least two ketene isotopomers (D{sub 2} {sup 12}C{sup 13}CO and D{sub 2} {sup 13}C{sup 13}CO), allowing for the derivation of two competing formation pathways. We have also proposed underlying reaction mechanisms to the formation of ketene based on kinetic fitting of the temporal evolution of the ketene isotopomers.

  20. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex

    SciTech Connect (OSTI)

    Thoi, VanSara; Kornienko, Nick; Margarit, C; Yang, Peidong; Chang, Christopher

    2013-06-07

    The solar-driven reduction of carbon dioxide to value-added chemical fuels is a longstanding challenge in the fields of catalysis, energy science, and green chemistry. In order to develop effective CO2 fixation, several key considerations must be balanced, including (1) catalyst selectivity for promoting CO2 reduction over competing hydrogen generation from proton reduction, (2) visible-light harvesting that matches the solar spectrum, and (3) the use of cheap and earth-abundant catalytic components. In this report, we present the synthesis and characterization of a new family of earth-abundant nickel complexes supported by N-heterocyclic carbene amine ligands that exhibit high selectivity and activity for the electrocatalytic and photocatalytic conversion of CO2 to CO. Systematic changes in the carbene and amine donors of the ligand have been surveyed, and [Ni(Prbimiq1)]2+ (1c, where Prbimiq1 = bis(3-(imidazolyl)isoquinolinyl)propane) emerges as a catalyst for electrochemical reduction of CO2 with the lowest cathodic onset potential (Ecat = 1.2 V vs SCE). Using this earth-abundant catalyst with Ir(ppy)3 (where ppy = 2-phenylpyridine) and an electron donor, we have developed a visible-light photoredox system for the catalytic conversion of CO2 to CO that proceeds with high selectivity and activity and achieves turnover numbers and turnover frequencies reaching 98,000 and 3.9 s1, respectively. Further studies reveal that the overall efficiency of this solar-to-fuel cycle may be limited by the formation of the active Ni catalyst and/or the chemical reduction of CO2 to CO at the reduced nickel center and provide a starting point for improved photoredox systems for sustainable carbon-neutral energy conversion.

  1. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

    1999-01-01

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  2. A DFT Study of Interaction of Carbon Monoxide with Carbonaceous Materials Juan F. Espinal, Alejandro Montoya, Fanor Mondragon,*, and Thanh N. Truong*,

    E-Print Network [OSTI]

    Truong, Thanh N.

    it is a clean and efficient alternative to the use of coal instead of combustion. The gasification process are important in carbon gasification processes as well as in carbon single-wall nanotubes formation from CO disproportionation reaction. In the case of gasification, adsorption of CO blocks the active sites

  3. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  4. Chemical Composition of Gas-Phase Organic Carbon Emissions from Motor Vehicles and Implications for Ozone Production

    E-Print Network [OSTI]

    Goldstein, Allen

    Chemical Composition of Gas-Phase Organic Carbon Emissions from Motor Vehicles and Implications gasoline and diesel vehicles via two methods. First we use speciated measurements of exhaust emissions from-based, single vehicle dynamometer testing, and on-road measurements in roadway tunnels.3-12 Emission factors

  5. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  6. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01

    Global and zonal total ozone variations estimated fromon multidecadal total ozone simulations, J. Geophys. Res. ,and J. A. Logan (2007), Ozone climatolo- gical profiles for

  7. Quantifying the contributions to stratospheric ozone changes from ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Quantifying the contributions to stratospheric ozone changes from ozone depleting substances., Reader, M. C. and Jonsson, A. I. (2010) Quantifying the contributions to stratospheric ozone changes from ozone depleting substances and greenhouse gases. Atmospheric Chemistry and Physics, 10. pp. 8803

  8. Nuclear conflict and ozone depletion Quick summary

    E-Print Network [OSTI]

    Toohey, Darin W.

    Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

  9. The Ozone Hole Some perspective

    E-Print Network [OSTI]

    Toohey, Darin W.

    The Ozone Hole · Some perspective · The British Antarctic Survey · The "Ozone Hole" · International of the predicted ozone losses! This was quite a controversy. Ultimately, ozone losses started appearing in the late 1980s (see Figure below), but by then, there was already a credibility issue for ozone scientists. #12

  10. Midlatitude Ozone: Loss and Trends

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 17 Midlatitude Ozone: Loss and Trends ATOC/CHEM 5151 #12;2 Importance of midlatitude ozone · Covers most of the world's populated areas · Provides protection from UV #12;3 Ozone loss picture, c. 1988 #12;4 Lower vs. Upper stratosphere #12;5 Ozone loss, post 1988 · Discovery of ozone hole

  11. Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: Algorithm description and validation

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment October 2005. [1] Ozone profiles are derived from back scattered radiance spectra in the ultraviolet (289­339 nm) measured by the Global Ozone Monitoring Experiment (GOME) using the optimal estimation technique

  12. 6, 74277469, 2006 Linear ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 7427­7469, 2006 Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Chemistry and Physics Discussions Evaluation of linear ozone photochemistry parametrizations Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Abstract Introduction

  13. Combined Crossed Molecular Beam and ab Initio Investigation of the Multichannel Reaction of Boron Monoxide (BO; X2

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    in conventional carbon based jet fuel systems. The combustion of hydrocarbon based fuels can reach temperatures monoxide (11 BO; X2 + ) radical with unsaturated hydrocarbons are of importance in understanding the formation of small boron-oxygen bearing hydrocarbons in boron combustion processes. Over recent decades

  14. Public Health in East and Southeast Asia: Challenges and Opportunities in the Twenty-First Century

    E-Print Network [OSTI]

    Detels, Roger; Sullivan, Sheena G.; Tan, Chorh Chuan

    2012-01-01

    Fuel or tobacco combustion Carbon monoxide (CO) RemodelingCarbon monoxide (CO) Reactions of NOx and other volatile organic compounds in the atmosphere ­ Ozone (O ) Fossil fuel combustion

  15. Validation of operational ozone profiles from the Ozone Monitoring Instrument

    E-Print Network [OSTI]

    Validation of operational ozone profiles from the Ozone Monitoring Instrument M. Kroon,1 J. F. de we present the validation results of the operational vertical ozone profiles retrieved from the nadir observations by the Ozone Monitoring Instrument (OMI) aboard the NASA Earth Observing System (EOS) Aura

  16. NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY

    E-Print Network [OSTI]

    vi NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY Prepared as a NARSTO initiative, this tropospheric O3 in the accompanying Textbox, the NARSTO Ozone Assessment contains two product components. The first of these is a set aspects of tropospheric ozone pollution. The second component, the NARSTO Ozone Assessment Document

  17. Artificial ozone holes

    E-Print Network [OSTI]

    S. N. Dolya

    2014-10-18

    This article considers an opportunity of disinfecting a part of the Earth surface, occupying a large area of ten thousand square kilometers. The sunlight will cause dissociation of molecular bromine into atoms; each bromine atom kills thirty thousand molecules of ozone. Each bromine plate has a mass of forty milligrams grams and destroys ozone in the area of hundred square meters. Thus, to form the ozone hole over the area of ten thousand square kilometers, it is required to have the total mass of bromine equal to the following four tons.

  18. Search for the electric dipole moment of the electron with thorium monoxide

    E-Print Network [OSTI]

    2010-01-01

    moment of the electron with thorium monoxide A C Vutha, W Cmoment of the electron with thorium monoxide A C Vutha 1 , WeEDM, using a cold beam of thorium monoxide (ThO) molecules.

  19. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  20. Control of carbon balance in a silicon smelting furnace

    DOE Patents [OSTI]

    Dosaj, V.D.; Haines, C.M.; May, J.B.; Oleson, J.D.

    1992-12-29

    The present invention is a process for the carbothermic reduction of silicon dioxide to form elemental silicon. Carbon balance of the process is assessed by measuring the amount of carbon monoxide evolved in offgas exiting the furnace. A ratio of the amount of carbon monoxide evolved and the amount of silicon dioxide added to the furnace is determined. Based on this ratio, the carbon balance of the furnace can be determined and carbon feed can be adjusted to maintain the furnace in carbon balance.

  1. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01

    models include a nearly complete set of chemical species and reactions that affect ozone, but are costly to Earth System

  2. Tropospheric carbon monoxide: satellite observations and their applications 

    E-Print Network [OSTI]

    MacCallum, Stuart Neil

    2008-01-01

    of greenhouse gases such as CH4 and O3. Consequently, CO has an atmospheric lifetime of 1-3 months, making it a good tracer for studying the long range transport of pollution. Satellite observations present a valuable tool to investigate tropospheric CO...

  3. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions

    Broader source: Energy.gov [DOE]

    Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  4. Kinetics of the carbon monoxide oxidation reaction under microwave heating

    SciTech Connect (OSTI)

    Perry, W.L.; Katz, J.D.; Rees, D.; Paffett, M.T. [Los Alamos National Lab., NM (United States); Datye, A. [Univ. of New Mexico, Albuquerque, NM (United States)

    1996-06-01

    915 MHz microwave heating has been used to drive the CO oxidation reaction over Pd/Al{sub 2}O{sub 3} with out significantly affecting the reaction kinetics. As compared to an identical conventionally heated system, the activation energy, pre-exponential factor, and reaction order with respect to CO were unchanged. Temperature was measured using a thermocouple extrapolation technique. Microwave-induced thermal gradients were found to play a significant role in kinetic observations. The authors chose the CO oxidation reaction over a supported metal catalyst because the reaction kinetics are well known, and because of the diverse dielectric properties of the various elements in the system: CO is a polar molecule, O{sub 2} and CO{sub 2} are non-polar, Al{sub 2}O{sub 3} is a dielectric, and Pt and Pd are conductors.

  5. CARBON MONOXIDE IN THE COLD DEBRIS OF SUPERNOVA 1987A

    SciTech Connect (OSTI)

    Kamenetzky, J.; McCray, R.; Glenn, J. [Department of Astrophysical and Planetary Sciences, University of Colorado at Boulder, UCB 391, Boulder, CO 80309 (United States); Indebetouw, R. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22903 (United States); Barlow, M. J.; Matsuura, M. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Baes, M. [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281 S9, B-9000 Gent (Belgium); Blommaert, J. A. D. L.; Decin, L. [Instituut voor Sterrenkunde, KU Leuven, Celestijnenlaan 200D BUS 2401, B-2001 Leuven (Belgium); Bolatto, A. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Dunne, L. [Department of Physics and Astronomy, University of Canterbury, Private Bag 4800, Christchurch 8410 (New Zealand); Fransson, C. [Department of Astronomy, Oskar Klein Centre, Stockholm University, AlbaNova, SE-106 91 Stockholm (Sweden); Gomez, H. L. [School of Physics and Astronomy, Cardiff University, The Parade, Cardiff CF24 3AA (United Kingdom); Groenewegen, M. A. T. [Royal Observatory of Belgium, Ringlaan 3, B-1180 Brussels (Belgium); Hopwood, R. [Physics Department, Imperial College London, London SW7 2AZ (United Kingdom); Kirshner, R. P. [Harvard College Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Lakicevic, M. [Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG (United Kingdom); Marcaide, J. [Universidad de Valencia, C/Dr. Moliner 50, E-46100 Burjassot (Spain); Marti-Vidal, I. [Onsala Space Observatory, SE-439 92 Onsala (Sweden); Meixner, M. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); and others

    2013-08-20

    We report spectroscopic and imaging observations of rotational transitions of cold CO and SiO in the ejecta of SN1987A, the first such emission detected in a supernova remnant. In addition to line luminosities for the CO J = 1-0, 2-1, 6-5, and 7-6 transitions, we present upper limits for all other transitions up to J = 13-12, collectively measured from the Atacama Large Millimeter Array, the Atacama Pathfinder EXperiment, and the Herschel Spectral and Photometric Imaging REceiver. Simple models show the lines are emitted from at least 0.01 M{sub Sun} of CO at a temperature >14 K, confined within at most 35% of a spherical volume expanding at {approx}2000 km s{sup -1}. Moreover, we locate the emission within 1'' of the central debris. These observations, along with a partial observation of SiO, confirm the presence of cold molecular gas within supernova remnants and provide insight into the physical conditions and chemical processes in the ejecta. Furthermore, we demonstrate the powerful new window into supernova ejecta offered by submillimeter observations.

  6. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Fuel Distributor, Nonprofit, General PublicConsumer, Transportation Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) This...

  7. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ambient air quality standards for particulate matter, sulfur dioxide, carbon monoxide, ozone, lead and nitrogen dioxide. Eligibility: Agricultural, Commercial, Construction, Fed....

  8. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    standards for ambient air quality standards for particulate matter, sulfur dioxide, carbon monoxide, ozone, lead and nitrogen dioxide. Eligibility: Agricultural, Commercial,...

  9. 5, 59575985, 2005 European ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract Introduction explain the trends in European ozone levels? J. E. Jonson 1 , D. Simpson 1 , H. Fagerli 1 , and S. Solberg License. 5957 #12;ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract

  10. 6, 56715709, 2006 Hemispheric ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page Chemistry and Physics Discussions Hemispheric ozone variability indices derived from satellite observations.erbertseder@dlr.de) 5671 #12;ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page

  11. 4, 32853332, 2004 Tropospheric ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 3285­3332, 2004 Tropospheric ozone over Equatorial Africa B. Sauvage et al. Title Page and Physics Discussions Tropospheric ozone over Equatorial Africa: regional aspects from the MOZAIC data B Correspondence to: B. Sauvage (saub@aero.obs-mip.fr) 3285 #12;ACPD 4, 3285­3332, 2004 Tropospheric ozone over

  12. 2, 339356, 2002 Surface ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 339­356, 2002 Surface ozone depletion episodes D. W. Tarasick and J. W. Bottenheim Title ozone depletion episodes in the Arctic and Antarctic from historical ozonesonde records D. W. Tarasick.tarasick@ec.gc.ca) 339 #12;ACPD 2, 339­356, 2002 Surface ozone depletion episodes D. W. Tarasick and J. W. Bottenheim

  13. 5, 38113845, 2005 Antarctic ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al. Title Page Discussions Indicators of Antarctic ozone depletion G. E. Bodeker 1 , H. Shiona 1 , and H. Eskes 2 1 National Commons License. 3811 #12;ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al

  14. Assimilation of Aura ozone data

    E-Print Network [OSTI]

    Assimilation of Aura ozone data I. Stajner, H. Hayashi, K. Wargan, L.-P. Chang, and S. Pawson Global Modeling and Assimilation Office (GMAO) NASA/Goddard AGU Fall meeting December 2004 #12;2 Ozone assimilation at GMAO · Total ozone columns and stratospheric profiles from SBUV/2 instrument are assimilated

  15. 2, 921942, 2002 Global ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 921­942, 2002 Global ozone forecasting H. J. Eskes et al. Title Page Abstract Introduction Geophysical Society 2002 Atmospheric Chemistry and Physics Discussions Global ozone forecasting based on ERS-2 July 2002 Correspondence to: H. J. Eskes (eskes@knmi.nl) 921 #12;ACPD 2, 921­942, 2002 Global ozone

  16. 6, 51375162, 2006 Oceanic ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W. Fairall et al. Title Page Abstract Discussions Water-side turbulence enhancement of ozone deposition to the ocean C. W. Fairall1 , D. Helmig2 , L. Fairall (chris.fairall@noaa.gov) 5137 #12;ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W

  17. Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter

    E-Print Network [OSTI]

    Apte, Michael G.

    2010-01-01

    continue testing and evaluation of sensors, in collaborationCharacteristics General evaluation of sensor Standard MD-1on the CO sampler sensors. Evaluation ofsampler materials

  18. Ozone decomposition in water solutions 

    E-Print Network [OSTI]

    Hewes, Cecil Grayson

    1969-01-01

    OF LITERATUR 1V Vi ~ V111 III ~ EXPERIMENTAL SYSTEM AND ITS OPERATION 14 IV. DISCUSS10N OF RESULTS AND COiJCLUSION. . . 24 i~JOMENCLATUHE. BIBLIOGRAPIFY APPENDIX I. WASTE WATER REGENERATION BY OZONATION. II. AMINE REMOVAL BY OZONATION...ATER SOLUTIONS OF pH 8. XIII. REACTION RATE CONSTANTS FOR THE D'COMPOSITION OF OZONE IN INTER SOLUTIONS OF pH 8. XIV COD REMOVAL BY OZONE XV. OZONIZATION OF MATER CONTAINIiNG RESIDUAL AMINE. 57 60 LIST OF FIGURES FIGURE 1. FIOW DIAGRAM OF THZ...

  19. A new photocatalytic material was synthesized to investigate its performance for the photoreduction of carbon dioxide (CO2) in the presence of water vapor (H2O) to valuable products

    E-Print Network [OSTI]

    of carbon dioxide (CO2) in the presence of water vapor (H2O) to valuable products such as carbon monoxide-TiO2 nano-composite for the reduction of carbon dioxide in the presence of water vapor

  20. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Perry, William L. (Jemez Springs, NM); Chen, Chun-Ku (Albuquerque, NM)

    2006-02-14

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  1. Multi-model assessment of stratospheric ozone return dates and ozone recovery in

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models. (2010) Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models Chemistry and Physics Multi-model assessment of stratospheric ozone return dates and ozone recovery

  2. Solving the Tulsa ozone problem

    SciTech Connect (OSTI)

    Wagner, K.K. [Atmospheric Information Systems, Norman, OK (United States); Wilson, J.D. [Wilson Consulting Group, Tulsa, OK (United States); Gibeau, E. [Aeromet Inc., Tulsa, OK (United States)

    1998-12-31

    Local governments and interested parties in Tulsa, Oklahoma are planning actions to keep Tulsa in compliance with the ozone ambient air quality standard. Based on recent data Tulsa exceeds the new eight hour average national ambient air quality standard for ozone and occasionally exceeds the previous one hour standard. Currently, Tulsa is in attainment of the former one-hour ozone standard. The first planning step is to integrate the existing information about Tulsa`s ozone problem. Prior studies of Tulsa ozone are reviewed. Tulsa`s recent air quality and meteorological monitoring are evaluated. Emission inventory estimates are assessed. Factors identified with Tulsa`s ozone problem are the transport of ozone and precursor gases, a possible role for biogenic emissions, and a simplistic ozone forecasting method. The integration of information found that current air quality and meteorological monitoring is meager. Observations of volatile organic compounds and NO{sub y} are absent. Prior intensive studies in 1977 and 1985 are more than ten years old and lack relevance to today`s problem. Emission inventory estimates are scarce and uncertain. The current knowledge base was judged inadequate to properly characterize the present ozone problem. Actions are recommended to enlarge the information base to address Tulsa`s ozone problem.

  3. ROLE OF THE LAND PLUME IN THE TRANSPORT OF OZONE OVER THE OCEAN DURING INDOEX (1999)

    E-Print Network [OSTI]

    Raman, Sethu

    1999-01-01

    from India to the North Indian Ocean (Satheesh, 1998). High concentrations of non-sea salt aerosols by agricultural burning and bio-fuel use that have greatly increased carbon monoxide concentrations over based on a comprehensive set of observations during the field phase of INDOEX in 1999. In addition

  4. Plasmachemical Synthesis of Carbon Suboxide 

    E-Print Network [OSTI]

    Geiger, Robert

    2012-12-11

    (DBD) containing pure carbon monoxide. Optical emission spectroscopy was used to analyze the plasma and models of the emission spectra were created to determine the plasma temperatures. Deposition rates were determined to be on the order of 0.2 mg...

  5. 6, 66276694, 2006 linearized ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al. Title Chemistry and Physics Discussions CHEM2D-OPP: A new linearized gas-phase ozone photochemistry.mccormack@nrl.navy.mil) 6627 #12;ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al

  6. ontinuing the legacy of Dr. Charles D. Keeling in monitoring carbon dioxide, NOAA's Office

    E-Print Network [OSTI]

    C ontinuing the legacy of Dr. Charles D. Keeling in monitoring carbon dioxide, NOAA's Office provides funding to Charles D. Keeling to begin monitoring carbon dioxide (CO2) at the South Pole and Mauna-seasonal data on carbon dioxide, methane, carbon monoxide, and other gases in a region where rapid climate

  7. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  8. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  9. Oceanic alkyl nitrates as a natural source of tropospheric ozone

    E-Print Network [OSTI]

    Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

    2008-01-01

    Chemical transport model ozone simulations for spring 2001ozonesondes, and Total Ozone Mapping Spectrometer columns,behaviour of tropospheric ozone precursors in a global 3-D

  10. Global tropospheric ozone modeling: Quantifying errors due to grid resolution

    E-Print Network [OSTI]

    Wild, Oliver; Prather, Michael J

    2006-01-01

    by and influencing ozone in unpolluted tropospheric air,R. C. , et al. (2004), Ozone production in transpacificplumes and implications for ozone air quality in California,

  11. Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

    E-Print Network [OSTI]

    2011-01-01

    Part I: NO x , PAN and Ozone Relationships, J. Atmos.Bromine measurements in ozone depleted air over the Arcticto springtime tropospheric ozone maxima using TOPSE measure-

  12. Post-treatment of fly ash by ozone in a fixed bed reactor

    SciTech Connect (OSTI)

    Kim Hougaard Pedersen; Merc Casanovas Meli; Anker Degn Jensen; Kim Dam-Johansen

    2009-01-15

    The residual carbon in fly ash produced from pulverized coal combustion can adsorb the air-entraining admixtures (AEAs) added to enhance air entrainment in concrete. This behavior of the ash can be suppressed by exposing the fly ash to oxidizing species, which oxidizes the carbon surface and thus prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O{sub 3}/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data. 28 refs., 7 figs., 3 tabs.

  13. ~A four carbon alcohol. It has double the amount of carbon of ethanol, which equates to a substantial increase in harvestable energy (Btu's).

    E-Print Network [OSTI]

    Toohey, Darin W.

    when consumed in an internal combustion engine yields no SOX, NOX or carbon monoxide allButanol ~A four carbon alcohol. It has double the amount of carbon of ethanol, which equates environmentally harmful byproducts of combustion. CO2 is the combustion byproduct of butanol, and is considered

  14. Ozone Conference II: Abstract Proceedings

    SciTech Connect (OSTI)

    None

    1999-11-01

    Ozone Conference II: Pre- and Post-Harvest Applications Two Years After Gras, was held September 27-28, 1999 in Tulare, California. This conference, sponsored by EPRI's Agricultural Technology Alliance and Southern California Edison's AgTAC facility, was coordinated and organized by the on-site ATA-AgTAC Regional Center. Approximately 175 people attended the day-and-a-half conference at AgTAC. During the Conference twenty-two presentations were given on ozone food processing and agricultural applications. Included in the presentations were topics on: (1) Ozone fumigation; (2) Ozone generation techniques; (3) System and design applications; (4) Prewater treatment requirements; (5) Poultry water reuse; (6) Soil treatments with ozone gas; and (7) Post-harvest aqueous and gaseous ozone research results. A live videoconference between Tulare and Washington, D.C. was held to discuss the regulators' view from inside the beltway. Attendees participated in two Roundtable Question and Answer sessions and visited fifteen exhibits and demonstrations. The attendees included university and governmental researchers, regulators, consultants and industry experts, technology developers and providers, and corporate and individual end-users. This report is comprised of the Abstracts of each presentation, biographical sketches for each speaker and a registration/attendees list.

  15. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, Jerome W. (Lockport, IL); Klingler, Robert J. (Westmount, IL)

    1993-01-01

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  16. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.

    1993-03-30

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  17. Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles.

    E-Print Network [OSTI]

    Schofield, Jeremy

    via catalytic cycle: Under cold conditions, dimers ClO OCl form which are unstable in light. #3; Once concentration of ozone drops, reservoir reactions dominate and HCl and ClONO 2 reformed. #3; In antarctic spring

  18. Atmos. Chem. Phys., 9, 93159327, 2009 www.atmos-chem-phys.net/9/9315/2009/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    airborne measurements of carbon dioxide (CO2), carbon monoxide (CO), ozone (O3), equiv- alent black carbon Siberian forest fires are known to be a major extratropical source of carbon monoxide (CO), as well in Yakutsk where measure- ments in fresh smoke could be made during the descent. We estimate a combustion

  19. ATOC 3500/CHEM 3151 Spring 2014 Stratospheric Ozone Destruction in the "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC 3500/CHEM 3151 Spring 2014 Problem 15 Stratospheric Ozone Destruction in the "Ozone Hole" The figure below shows typical observations of the total amount of ozone in a layer of air 8 km thick between 12 and 20 km over the South Pole (recall that we like to express the `thickness of ozone

  20. N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone"

    E-Print Network [OSTI]

    Heller, Barbara

    N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone" Search done of Ozone by G. C. Carnahan and O. A. DeCelle; Chemical Engineering program, 1914 Call No. Thesis 543.2 C22 Press releases issued by Illinois Institute of Technology, 1940-1968 that include the word "ozone

  1. Climatology of UTLS ozone and the ratio of ozone and potential vorticity over northern Europe

    E-Print Network [OSTI]

    Kirkwood, Sheila

    Climatology of UTLS ozone and the ratio of ozone and potential vorticity over northern Europe T variations of ozone in the upper troposphere and lower stratosphere (UTLS) region have been studied using of ozone exhibits a prominent annual cycle in the UTLS region. The observed change in the phase

  2. Carbon dioxide capture process with regenerable sorbents

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

    2002-05-14

    A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

  3. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097­10129, 2007 Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Page Abstract Introduction

  4. 5, 243286, 2005 Retrieval of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 243­286, 2005 Retrieval of ozone column content during SOLVE II J. M. Livingston et al and Physics Discussions Retrieval of ozone column content from airborne Sun photometer measurements during Aerospace Center), Oberpfaffenhofen, Wessling, Germany 243 #12;ACPD 5, 243­286, 2005 Retrieval of ozone

  5. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  6. 6, 43254340, 2006 Scaling in ozone and

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title Chemistry and Physics Discussions Long-memory processes in global ozone and temperature variations C #12;ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title

  7. 7, 22492274, 2007 Vertical ozone over

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean and Central Europe P. D a Creative Commons License. Atmospheric Chemistry and Physics Discussions Vertical ozone measurements (kalabokas pavlos@yahoo.gr) 2249 #12;ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean

  8. 8, 31433162, 2008 Total ozone over

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 3143­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Chemistry and Physics Discussions Total column ozone variations over oceanic region around Indian sub­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Abstract Introduction

  9. 8, 50075060, 2008 Evaluation of ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 5007­5060, 2008 Evaluation of ozone trends from g-b FTIR observations C. Vigouroux et al.0 License. Atmospheric Chemistry and Physics Discussions Evaluation of tropospheric and stratospheric ozone Publications on behalf of the European Geosciences Union. 5007 #12;ACPD 8, 5007­5060, 2008 Evaluation of ozone

  10. 8, 49114947, 2008 NOx-induced ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract Chemistry and Physics Discussions Model simulations of stratospheric ozone loss caused by enhanced on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

  11. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  12. 6, 84578483, 2006 Low ozone over the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 8457­8483, 2006 Low ozone over the UK M. Keil et al. Title Page Abstract Introduction Discussions The January 2006 low ozone event over the UK M. Keil, D. R. Jackson, and M. C. Hort Met Office 2006 Correspondence to: M. Keil (mike.keil@metoffice.gov.uk) 8457 #12;ACPD 6, 8457­8483, 2006 Low ozone

  13. 5, 96419668, 2005 The origin of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 9641­9668, 2005 The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions-5-9641 European Geosciences Union Atmospheric Chemistry and Physics Discussions The origin of ozone V. Grewe The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions References Tables Figures Back

  14. 6, 39133943, 2006 Svalbard total ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 3913­3943, 2006 Svalbard total ozone C. Vogler et al. Title Page Abstract Introduction Discussions Re-evaluation of the 1950­1962 total ozone record from Longyearbyen, Svalbard C. Vogler 1 , S. Br total ozone C. Vogler et al. Title Page Abstract Introduction Conclusions References Tables Figures Back

  15. 3, 187223, 2003 TOMS cloudy ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 3, 187­223, 2003 TOMS cloudy ozone anomaly X. Liu et al. Title Page Abstract Introduction Geosciences Union 2003 Atmospheric Chemistry and Physics Discussions Occurrence of ozone anomalies over cloudy 2003 Correspondence to: X. Liu (xliu@nsstc.uah.edu) 187 #12;ACPD 3, 187­223, 2003 TOMS cloudy ozone

  16. 3, 10811107, 2003 Mid-latitude ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 3, 1081­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page-dimensional model study of long-term mid-high latitude lower stratosphere ozone changes M. P. Chipperfield School­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page Abstract Introduction

  17. 4, 21672238, 2004 Ozone loss and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 2167­2238, 2004 Ozone loss and chlorine activation in the Arctic winters 1991­2003 S Union 2004 Atmospheric Chemistry and Physics Discussions Ozone loss and chlorine activation Correspondence to: S. Tilmes (simone.tilmes@t-online.de) 2167 #12;ACPD 4, 2167­2238, 2004 Ozone loss and chlorine

  18. Ozone: Integrating Structured and Semistructured Data ?

    E-Print Network [OSTI]

    Abiteboul, Serge

    Ozone: Integrating Structured and Semistructured Data ? Tirthankar Lahiri 1 , Serge Abiteboul 2 language, and we implement our extensions in a system called Ozone. In our approach, structured data may full knowledge of structure. Ozone also enhances both ODMG/OQL and OEM/Lorel by virtue

  19. Seasonal persistence of midlatitude total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of midlatitude total ozone anomalies Article Published Version Fioletov, V. E. and Shepherd, T. G. (2003) Seasonal persistence of midlatitude total ozone anomalies. Geophysical Research persistence of midlatitude total ozone anomalies Vitali E. Fioletov Meteorological Service of Canada, Toronto

  20. Black Carbon Emissions by Rocket Engines Types of rocket engines Emissions

    E-Print Network [OSTI]

    Toohey, Darin W.

    Black Carbon Emissions by Rocket Engines Types of rocket engines Emissions Liquid Hydrogen. Note: Black carbon does not deplete ozone. What happens is the black carbon emissions from the rocket. Other black carbon emissions: The number one contributor to black carbon is burning biomass. Also

  1. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01

    Palazzotto MC, Mann KR (1990) Electrochemistry and infraredPalazotto MC, Mann KR (1991) Electrochemistry and InfraredJ (2006) Analytical Electrochemistry (John Wiley & Sons,

  2. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01

    collected on a Bruker Equinox 55 spectrometer. Microanalysesacquired using the Bruker Equinox 55 spectrometer mentionedacquired using a Bruker Equinox 55 spectrometer. For the CO

  3. Hydroxyl, water, ammonia, carbon monoxide and neutral carbon towards the Sgr A complex

    E-Print Network [OSTI]

    Karlsson, Roland; Hjalmarson, Åke; Winnberg, Anders; Fathi, Kambiz; Frisk, Urban; Olberg, Michael

    2013-01-01

    We observed OH, H$_2$O, HN$_3$, C$^{18}$O, and C$_I$ towards the +50 km/s cloud (M-0.02-0.07), the CND and the +20 km/s (M-0.13-0.08) cloud in the Sgr A complex with the VLA, Odin and SEST. Strong OH absorption, H$_2$O emission and absorption lines were seen at all three positions. Strong C$^{18}$O emissions were seen towards the +50 and +20 km/s clouds. The CND is rich in H$_2$O and OH, and these abundances are considerably higher than in the surrounding clouds, indicating that shocks, star formation and clump collisions prevail in those objects. A comparison with the literature reveals that it is likely that PDR chemistry including grain surface reactions, and perhaps also the influences of shocks has led to the observed abundances of the observed molecular species studied here. In the redward high-velocity line wings of both the +50 and +20 km/s clouds and the CND, the very high H$_2$O abundances are suggested to be caused by the combined action of shock desorption from icy grain mantles and high-temperatu...

  4. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01

    are on the decline of the peak oil production curve, and thedue to the impending peak in oil production and the threatoil production curves for those countries that have passed peak

  5. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01

    Kubiak, C. P. “Artificial photosynthesis of CO: Kinetic andJM, et al. (2012) Artificial photosynthesis of CO: Kineticentitled “Artificial photosynthesis of CO: Kinetic and

  6. Comparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane

    E-Print Network [OSTI]

    Jacobson, Mark

    of the world econ- omy and demand for aviation and its emissions are expected to increase in the future from aviation (mainly carbon dioxide (CO2), water vapor (H2O), nitrogen oxides (NOx = NO + NO2), VOCsComparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane

  7. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  8. The mitigation and conversion of carbon dioxide (CO2) to more useful carbon chemicals is a research topic that is at the forefront of current engineering and sustainability applications. Direct

    E-Print Network [OSTI]

    The mitigation and conversion of carbon dioxide (CO2) to more useful carbon chemicals is a research studies indicate that titanium dioxide (TiO2) containing materials serve as the best photocatalyst for CO2O2 materials allows one to increase the yield of certain products such as carbon monoxide (CO

  9. Long-Term Trends in Motor Vehicle Emissions in U.S. Urban Areas Brian C. McDonald and Drew R. Gentner

    E-Print Network [OSTI]

    Goldstein, Allen

    to estimate long- term trends (1990-2010) in carbon monoxide (CO) emissions from motor vehicles. Non), nitrogen oxides (NOx = NO + NO2), and carbon monoxide (CO) are coemitted with carbon dioxide (CO2) during combustion. These pollutants are important to tropospheric ozone (O3) and secondary organic aerosol (SOA

  10. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine 

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01

    Ozone, a phytotoxic air pollutant, is formed from photochemical reactions of hydrocarbons and nitrogen oxides in the troposphere. Ozone is taken into the plant through the stomata, and quickly broken down into hydroxyl radicals. These hydroxyl...

  11. Improving ozone profile retrieval from spaceborne UV backscatter

    E-Print Network [OSTI]

    Haak, Hein

    Chapter 2 Improving ozone profile retrieval from spaceborne UV backscatter spectrometers using convergence behaviour diagnostics Abstract The Ozone Profile Algorithm (OPERA), developed at KNMI, retrieves the vertical ozone distribution from nadir spectral satellite measurements of back scattered sunlight

  12. oZONE Faculty and Staff Enrolling Students

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Enrolling Students Log in to ozone.ou.edu. Click the Advising tab. Please lecture schedule CRN ­ Course Reference Number In oZONE the Registration Add Errors will display one

  13. Controls over ozone deposition to a high elevation subalpine forest

    E-Print Network [OSTI]

    Turnipseed, AA; Burns, SP; Moore, DJP; Hu, J; Guenther, AB; Monson, RK

    2009-01-01

    D.L. , Fehsenfeld, F.C. , 1986b. Background ozone andanthropogenic ozone enhancement at Niwot Ridge, Colorado.Day-time variations of ozone eddy ?uxes to maize. Boundary-

  14. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01

    particles produced by ozone/limonene reactions in indoor airgas-phase reactions of ozone with organic compounds underNazaroff, W.W. , 2008. Ozone levels in passenger cabins of

  15. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    Jan de Leeuw; Shuojun Wang

    2011-01-01

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  16. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    de Leeuw, Jan; Wang, Shuojun

    2007-01-01

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  17. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  18. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  19. 17 October 2014 Antarctic Ozone Bulletin

    E-Print Network [OSTI]

    Toohey, Darin W.

    17 October 2014 Antarctic Ozone Bulletin No 4/2014 Global Atmosphere Watch 0 5 10 0 5 10 15 20 25 30 -80 -60 -40 -20 0 Ushuaia 2014-10-10 Total ozone = 180 DU 14-21 km column = 39 DU 12-20 km column = 53 DU Ozone Temperature ECMWF analysis of PV at 475 K on 2014-10-10 at 12h -65.0 -59.5 -54.0 -48

  20. A fast stratospheric ozone chemistry schemeA fast stratospheric ozone chemistry scheme Michel Bourqui1

    E-Print Network [OSTI]

    Bourqui, Michel

    A fast stratospheric ozone chemistry schemeA fast stratospheric ozone chemistry scheme Michel a computationally efficient chemical scheme, the FAst STratospheric Ozone Chemistry (FASTOC) scheme, which has advantages over many existing fast methods, as it does not rely on relaxation to assumed conditions, does

  1. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  2. Tropospheric Ozone Pollution and Personal Exposure

    E-Print Network [OSTI]

    Toohey, Darin W.

    ://www.nctcog.org/trans/air/ozone/formation.gif #12;Health Effects · Chest pain, coughing, throat irritation, and congestion · Wheezing and difficulty

  3. The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination

    E-Print Network [OSTI]

    Thompson, Anne

    iii ABSTRACT The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination with other instruments tropospheric ozone residual (TOR) can be derived. In this study, the trajectory

  4. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

  5. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01

    to determine deposition velocity, reaction probability, orOzone level, deposition velocity, reaction probability wereOzone level, deposition velocity, reaction probability were

  6. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Energy Savers [EERE]

    More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

  7. Molecular dynamics simulation of formation process of single-walled carbon nanotubes by CCVD method

    E-Print Network [OSTI]

    Maruyama, Shigeo

    chemical vapor deposition (CCVD) method [4-7] has been contrived for a scalable, large-scale production of SWNTs, with various carbon-source molecules tested such as carbon monoxide [4, 7], methane [5 simulations [10, 11] with the Brenner potential [12] or tight-binding molecular dynamics (TBMD) simulation [13

  8. Aerosol Observing Systems (AOS), New Capabilities for ASR Researchers Stephen R. Springston (srs@bnl.gov)

    E-Print Network [OSTI]

    Gases PTRMS Carbon Monoxide Ozone Ozone Ozone Sulfur Dioxide Speciated Odd Nitrogen (NO, NO NO ) o Lab of remote access over the internet allows mentors complete control over AOS infrastructure components/off all subsystems allowing both remote and autonomous restart and shutdown of unit in graded steps o

  9. Speeding up Ozone Profile Retrieval using Machine Learning Techniques

    E-Print Network [OSTI]

    Emmerich, Michael

    Speeding up Ozone Profile Retrieval using Machine Learning Techniques L.M. Strijbosch April 25 to the process of ozone profile retrieval, a method for retrieving a global ozone distribution from satellite Machines are selected to replace the forward model, which is the slowest part of ozone profile retrieval

  10. Effects of stratospheretroposphere chemistry coupling on tropospheric ozone

    E-Print Network [OSTI]

    Effects of stratospheretroposphere chemistry coupling on tropospheric ozone Wenshou Tian,1,2 Martyn in both the troposphere and stratosphere. The modeled total column ozone agrees well with Total Ozone Mapping Spectrometer observations. Modeled ozone profiles in the upper troposphere and lower stratosphere

  11. Atmospheric ozone and colors of the Antarctic twilight sky

    E-Print Network [OSTI]

    Lee Jr., Raymond L.

    Atmospheric ozone and colors of the Antarctic twilight sky Raymond L. Lee, Jr.,1, * Wolfgang Meyer absorption at longer wavelengths by ozone's Chappuis bands. Because stratospheric ozone is greatly depleted correlations between ozone concentration and twilight colors. We also used a spectroradiometer at a midlatitude

  12. Part III Research Project Stratosphere-Troposphere Exchange of Ozone

    E-Print Network [OSTI]

    Withers, Paul

    Part III Research Project Stratosphere-Troposphere Exchange of Ozone Observed by Data Assimilation Stratosphere-Troposphere exchange of ozone at tropopause folds is an important process in the atmosphere. Reconstruction of the evolution of ozone at a tropopause fold by conventional means requires synoptic ozone

  13. Tropospheric Ozone Satellite Retrievals in the Pacific Northwest

    E-Print Network [OSTI]

    Collins, Gary S.

    Tropospheric Ozone Satellite Retrievals in the Pacific Northwest Jacqueline Costello1, Farren: Tropospheric ozone is difficult to retrieve from satellites because of the abundance of ozone in the stratosphere. Tropospheric ozone has become a significant environmental issue and can be exacerbated by UT

  14. Ozone Depletion 2. O 3 generation and depletion

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion Outline: 1. O 3 , O 2 evolution 2. O 3 generation and depletion 3. Antarctic ozone 2 converted to ozone via: O 2 h#23; ! 2O #3; O #3; +O 2 ! O 3 + heat #15; O 3 absorbs near #21;#1;l #15; Decreasing l increases transmittance Imagine all ozone in atmosphere forming a thin layer

  15. ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE

    SciTech Connect (OSTI)

    Ketusky, E.; Subramanian, K.

    2012-02-29

    At the Savannah River Site (SRS), oxalic acid is currently considered the preferred agent for chemically cleaning the large underground Liquid Radioactive Waste Tanks. It is applied only in the final stages of emptying a tank when generally less than 5,000 kg of waste solids remain, and slurrying based removal methods are no-longer effective. The use of oxalic acid is preferred because of its combined dissolution and chelating properties, as well as the fact that corrosion to the carbon steel tank walls can be controlled. Although oxalic acid is the preferred agent, there are significant potential downstream impacts. Impacts include: (1) Degraded evaporator operation; (2) Resultant oxalate precipitates taking away critically needed operating volume; and (3) Eventual creation of significant volumes of additional feed to salt processing. As an alternative to dealing with the downstream impacts, oxalate decomposition using variations of ozone based Advanced Oxidation Process (AOP) were investigated. In general AOPs use ozone or peroxide and a catalyst to create hydroxyl radicals. Hydroxyl radicals have among the highest oxidation potentials, and are commonly used to decompose organics. Although oxalate is considered among the most difficult organic to decompose, the ability of hydroxyl radicals to decompose oxalate is considered to be well demonstrated. In addition, as AOPs are considered to be 'green' their use enables any net chemical additions to the waste to be minimized. In order to test the ability to decompose the oxalate and determine the decomposition rates, a test rig was designed, where 10 vol% ozone would be educted into a spent oxalic acid decomposition loop, with the loop maintained at 70 C and recirculated at 40L/min. Each of the spent oxalic acid streams would be created from three oxalic acid strikes of an F-area simulant (i.e., Purex = high Fe/Al concentration) and H-area simulant (i.e., H area modified Purex = high Al/Fe concentration) after nearing dissolution equilibrium, and then decomposed to {le} 100 Parts per Million (ppm) oxalate. Since AOP technology largely originated on using ultraviolet (UV) light as a primary catalyst, decomposition of the spent oxalic acid, well exposed to a medium pressure mercury vapor light was considered the benchmark. However, with multi-valent metals already contained in the feed, and maintenance of the UV light a concern; testing was conducted to evaluate the impact from removing the UV light. Using current AOP terminology, the test without the UV light would likely be considered an ozone based, dark, ferrioxalate type, decomposition process. Specifically, as part of the testing, the impacts from the following were investigated: (1) Importance of the UV light on the decomposition rates when decomposing 1 wt% spent oxalic acid; (2) Impact of increasing the oxalic acid strength from 1 to 2.5 wt% on the decomposition rates; and (3) For F-area testing, the advantage of increasing the spent oxalic acid flowrate from 40 L/min (liters/minute) to 50 L/min during decomposition of the 2.5 wt% spent oxalic acid. The results showed that removal of the UV light (from 1 wt% testing) slowed the decomposition rates in both the F & H testing. Specifically, for F-Area Strike 1, the time increased from about 6 hours to 8 hours. In H-Area, the impact was not as significant, with the time required for Strike 1 to be decomposed to less than 100 ppm increasing slightly, from 5.4 to 6.4 hours. For the spent 2.5 wt% oxalic acid decomposition tests (all) without the UV light, the F-area decompositions required approx. 10 to 13 hours, while the corresponding required H-Area decompositions times ranged from 10 to 21 hours. For the 2.5 wt% F-Area sludge, the increased availability of iron likely caused the increased decomposition rates compared to the 1 wt% oxalic acid based tests. In addition, for the F-testing, increasing the recirculation flow rates from 40 liter/minute to 50 liter/minute resulted in an increased decomposition rate, suggesting a better use of ozone.

  16. Tree and forest effects on air quality and human health in the United David J. Nowak a, *

    E-Print Network [OSTI]

    ). These pollutants are: carbon monoxide (CO), nitrogen dioxide (NO2), ozone (O3), lead (Pb), sulfur dioxide (SO2 by intercepting particles, emitting particles (e.g., pollen) and resuspension of particles captured on the plant

  17. griculture is in the spotlight as a

    E-Print Network [OSTI]

    Mukhtar, Saqib

    . These "crite- ria pollutants" are ozone (O3), carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2 to a particle of water. Equivalent spherical diameter (ESD) -- A term that categorizes the properties

  18. Ozone Climatologies Figure 1: Ozone climatology for control run in kg/m(a), percentage change in

    E-Print Network [OSTI]

    Feigon, Brooke

    Ozone Climatologies (a) (b) (c) Figure 1: Ozone climatology for control run in kg/m³(a), percentage change in ozone for the perturbed runs; tropopause region (b), whole stratosphere (c). Determining the impact of lower stratospheric ozone depletion on Southern Hemisphere climate Sarah P.E. Keeley and Nathan

  19. Effects of 20002050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone

    E-Print Network [OSTI]

    Wu, Shiliang

    Effects of 2000­2050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone in the United States Shiliang Wu,1 Loretta J. Mickley,1 Daniel J. Jacob,1 David Rind) on the global tropospheric ozone budget and on the policy-relevant background (PRB) ozone in the United States

  20. Microarray-based analysis of survival of soil microbial community during ozonation

    E-Print Network [OSTI]

    Wang, Jian

    2010-01-01

    3 ] in Ozonation time (h) Ozone BTC TSEM content was used to1. Ozone breakthrough curve (BTC) and TSEM removal during

  1. Exposure to Particulate Matter and Ozone of Outdoor Origin in Singapore

    E-Print Network [OSTI]

    Gall, Elliott T; Chen, Ailu; Chang, Victor; Nazaroff, William W

    2015-01-01

    ulate matter (PM) or ozone, at concentration increments of ~SL, Samet JM, Dominici F. Ozone and short-term mortality inthe penetration of ambient ozone into residential buildings.

  2. LARGE MULTICONFIGURATION SELF-CONSISTENT-FIELD WAVEFUNCTIONS FOR THE OZONE MOLECULE

    E-Print Network [OSTI]

    Schaefer III., Henry F.

    2013-01-01

    theory comparable to that employed here for ozone. HoweverB (cyclopentadiyl) > B (ozone) > B (methylene), based onfor the its state of ozone near geometry. Coefficients of

  3. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01

    of healthy young volunteers to ozone causes cardiovasculareffects of five common ozone-initiated terpene reactiondecay rates, and removal of ozone and their relation to

  4. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01

    2008. Learning about ozone depletion. Climatic Change 89(1–and Physics of Stratospheric Ozone. San Diego, CA: AcademicPhotochemical behavior of the ozone layer. Report Number

  5. Ozone photochemical production in urban Shanghai, China: Analysis based on ground level observations

    E-Print Network [OSTI]

    2009-01-01

    of aerosols on surface ozone concentration in Tianjin,W. P. L. (1994), Development of ozone reactivity scales forand M. M. Fox (1953), Ozone formation in photochemical

  6. oZONE Faculty and Staff Exporting and Importing Grades

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Exporting and Importing Grades Exporting/Importing Grades in oZONE The new - Log in to ozone.ou.edu using your OU Net ID (4+4) as you would in any other OU system. Click Importing Grades from a Exported oZONE template If you exported a course template from the oZONE grading

  7. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L.; Koss, T.C.

    1992-10-01

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  8. Carbonyl sulfide/carbon chemistry: Interim report, July 1, 1985-February 28, 1986

    SciTech Connect (OSTI)

    Hinckley, C.C.; Shiley, R.H.

    1986-05-01

    This interim report describes work performed during the first eight months of a continuing project, including descriptions of sample preparations and analyses. The objective of the study is to determine the effects of carbonyl sulfide, a product of the carbon monoxide/ethanol desulfurization process, on coal. A coal is first treated with carbon monoxide to reduce pyrite, and is then reacted with OCS and N/sub 2/ under various conditions. OCS is a potent resulfurization agent and appears to affect the formation of mesophase in chars derived from the coal. 8 refs., 1 fig., 8 tabs.

  9. Reducing a Companies Carbon Footprint through Energy Saving Best Practices at a Dairy Manufacturing Facility

    E-Print Network [OSTI]

    Kortan, Michael J.

    2010-12-17

    these companies with increased sales. These global warming gasses are made up of both naturally occurring and non-naturally occurring gasses. Naturally occurring gasses are carbon dioxide (CO2 ), methane, nitrous oxide, and ozone gasses while non...

  10. Purification of carbon nanotubes by dynamic oxidation in air Nikolay Dementev,a

    E-Print Network [OSTI]

    Borguet, Eric

    ) are nanometre-wide hollow carbon structures with exceptional mechanical and elec- tronic properties.1 such as oxygen, carbon dioxide, water vapor or ozone. A detailed overview of existing purification techniquesPurification of carbon nanotubes by dynamic oxidation in air Nikolay Dementev,a Sebastian Osswald

  11. DOI: 10.1002/cphc.200600390 Identification of the D3h Isomer of Carbon

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    -bearing molecules such as ozone or carbon dioxide, ionizing radiation from the solar wind can liberate oxygen atoms enrichment of stratospheric carbon dioxide.[1­4] In view of radiation-induced degradation of oxygen.[17] However, despite the importance of the carbon trioxide isomers in atmospheric chemistry, to date

  12. 5, 90039038, 2005 Ozone in Europe

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    that extensive forest fires on the Iberian Peninsula, resulting from the drought and heat, contributed to the peak ozone values observed in15 North Europe in August. Additionally, forest fires in Siberia probably

  13. Ozone determination in different copying centers 

    E-Print Network [OSTI]

    Lai, Chen-Fu

    1993-01-01

    Photocopying machines have been in existence for forty years: however, few people recognize their potential to create a human health hazard by ozone emission. This study was designed to determine the photocopier's emission rate and evaluate tile...

  14. Activated, coal-based carbon foam

    DOE Patents [OSTI]

    Rogers, Darren Kenneth; Plucinski, Janusz Wladyslaw

    2004-12-21

    An ablation resistant, monolithic, activated, carbon foam produced by the activation of a coal-based carbon foam through the action of carbon dioxide, ozone or some similar oxidative agent that pits and/or partially oxidizes the carbon foam skeleton, thereby significantly increasing its overall surface area and concurrently increasing its filtering ability. Such activated carbon foams are suitable for application in virtually all areas where particulate or gel form activated carbon materials have been used. Such an activated carbon foam can be fabricated, i.e. sawed, machined and otherwise shaped to fit virtually any required filtering location by simple insertion and without the need for handling the "dirty" and friable particulate activated carbon foam materials of the prior art.

  15. Increasing global agricultural production by reducing ozone damages via methane emission controls and ozone-

    E-Print Network [OSTI]

    Mauzerall, Denise

    Increasing global agricultural production by reducing ozone damages via methane emission controls demonstrate the significant potential to sustainably improve global agricultural production by decreasing O3 degradation poses a major challenge for agricultural production. Because surface ozone (O3) has a significant

  16. This journal is c the Owner Societies 2011 Phys. Chem. Chem. Phys., 2011, 13, 94699482 9469 Cite this: Phys. Chem. Chem. Phys., 2011, 13, 94699482

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Carbon dioxide absorptions are detected remotely by space- borne spectroscopic facilities molecular oxygen (O2) and carbon dioxide (CO2) ices with 5 keV H+ and He+ ions was investigated ice; and ozone, carbon monoxide (CO), and cyclic carbon trioxide (c-CO3) in irradiated carbon dioxide

  17. Quantum yield for carbon monoxide production in the 248 nm photodissociation of carbonyl sulfide (OCS)

    SciTech Connect (OSTI)

    Zhao, Z.; Stickel, R.E.; Wine, P.H. [Georgia Institute of Technology, Atlanta, GA (United States)] [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-03-01

    Tunable diode laser absorption spectroscopy has been coupled with excimer laser flash photolysis to measure the quantum yield for CO production from 248 nm photodissociation of carbonyl sulfide (OCS) relative to the well known quantum yield for CO production from 248 nm photolysis of phosgene (Cl{sub 2}CO). The temporal resolution of the experiments was sufficient to distinguish CO formed directly by photodissociation from that formed by subsequent S({sup 3}P{sub j}) reaction with OCS. Under the experimental conditions employed, CO formation via the fast S({sup 1}D{sub 2})+OCS reaction was minimal. Measurements at 297K and total pressures from 4 to 100 Torr N{sub 2}+N{sub 2}O show the CO yield to be greater than 0.95 and most likely unity. This result suggests that the contribution of OCS as a precursor to the lower stratospheric sulfate aerosol layer is somewhat larger than previously thought. 25 refs., 1 fig., 2 tabs.

  18. Carbon Monoxide Dehydrogenases and Acetyl-CoA Synthases: Light at the End of the Tunnel?

    SciTech Connect (OSTI)

    Paul A. Lindahl

    2002-02-19

    OAK-B135 Metalloenzymes seem to ''come of age'' when their structures are known at atomic resolution, spectroscopic and catalytic properties are basically understood, and genetic expression systems are available. Such foundations allow detailed mechanistic and spectroscopic properties to be probed and correlated to structure. The objective of this article is to summarize what is known about the title group of enzymes, and show that, to a large degree, they have come of age.

  19. Effect of Sodium Sulfide on Ni-Containing Carbon Monoxide Dehydrogenases

    SciTech Connect (OSTI)

    Jian Feng; Paul A. Lindahl

    2004-07-28

    OAK-B135 The structure of the active-site C-cluster in CO dehydrogenase from Carboxythermus hydrogenoformans includes a {mu}{sup 2}-sulfide ion bridged to the Ni and unique Fe, while the same cluster in enzymes from Rhodospirillum rubrum (CODH{sub Rr}) and Moorella thermoacetica (CODH{sub Mt}) lack this ion. This difference was investigated by exploring the effects of sodium sulfide on activity and spectral properties. Sulfide partially inhibited the CO oxidation activity of CODH{sub Rr} and generated a lag prior to steady-state. CODH{sub Mt} was inhibited similarly but without a lag. Adding sulfide to CODH{sub Mt} in the C{sub red1} state caused the g{sub av} = 1.82 EPR signal to decline and new features to appear, including one with g = 1.95, 1.85 and (1.70 or 1.62). Removing sulfide caused the g{sub av} = 1.82 signal to reappear and activity to recover. Sulfide did not affect the g{sub av} = 1.86 signal from the C{sub red2} state. A model was developed in which sulfide binds reversibly to C{sub red1}, inhibiting catalysis. Reducing this adduct causes sulfide to dissociate, C{sub red2} to develop, and activity to recover. Using this model, apparent K{sub I} values are 40 {+-} 10 nM for CODH{sub Rr} and 60 {+-} 30 {micro}M for CODH{sub Mt}. Effects of sulfide are analogous to those of other anions, including the substrate hydroxyl group, suggesting that these ions also bridge the Ni and unique Fe. This proposed arrangement raises the possibility that CO binding labilizes the bridging hydroxyl and increases its nucleophilic tendency towards attacking Ni-bound carbonyl.

  20. INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE

    E-Print Network [OSTI]

    Bailey, Robert Brian

    2011-01-01

    is proportional to the outgassing rate of the warm metalat temperature 1.6 K, outgassing ceases, and the only source

  1. Methane, carbon monoxide, and ammonia in brown dwarfs and self-luminous giant planets

    SciTech Connect (OSTI)

    Zahnle, Kevin J.; Marley, Mark S. E-mail: Mark.S.Marley@NASA.gov

    2014-12-10

    We address disequilibrium abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based one-dimensional atmospheric chemistry model. Our approach is to use the full kinetics model to survey the parameter space with effective temperatures between 500 K and 1100 K. In all of these worlds, equilibrium chemistry favors CH{sub 4} over CO in the parts of the atmosphere that can be seen from Earth, but in most disequilibrium favors CO. The small surface gravity of a planet strongly discriminates against CH{sub 4} when compared to an otherwise comparable brown dwarf. If vertical mixing is like Jupiter's, the transition from methane to CO occurs at 500 K in a planet. Sluggish vertical mixing can raise this to 600 K, but clouds or more vigorous vertical mixing could lower this to 400 K. The comparable thresholds in brown dwarfs are 1100 ± 100 K. Ammonia is also sensitive to gravity, but, unlike CH{sub 4}/CO, the NH{sub 3}/N{sub 2} ratio is insensitive to mixing, which makes NH{sub 3} a potential proxy for gravity. HCN may become interesting in high-gravity brown dwarfs with very strong vertical mixing. Detailed analysis of the CO-CH{sub 4} reaction network reveals that the bottleneck to CO hydrogenation goes through methanol, in partial agreement with previous work. Simple, easy to use quenching relations are derived by fitting to the complete chemistry of the full ensemble of models. These relations are valid for determining CO, CH{sub 4}, NH{sub 3}, HCN, and CO{sub 2} abundances in the range of self-luminous worlds we have studied, but may not apply if atmospheres are strongly heated at high altitudes by processes not considered here (e.g., wave breaking).

  2. Multimodel simulations of carbon monoxide: Comparison with observations and projected near-future changes

    E-Print Network [OSTI]

    2006-01-01

    1997), The ASAD atmospheric chemistry integration packageet al. (2001), Atmospheric chemistry and greenhouse gases,J. -F. Lamarque, Atmospheric Chemistry Division, National

  3. Delivering carbon monoxide froma prorous material with an entrapped photoactive manganese carbonyl

    E-Print Network [OSTI]

    Han, Il Gu

    2013-01-01

    conducted. The control group of CBA mice with BALB/c heartsc mice were transplanted into CBA mice after treatment with

  4. A Micro-Computer-Based Fuel Optimization System Utilizing In-Situ Measurement of Carbon Monoxide 

    E-Print Network [OSTI]

    DeVivo, D. G.

    1980-01-01

    A microcomputer-based control system utilizing a distributed intelligence architecture has been developed to control combustion in hydrocarbon fuel-fired boilers and heaters to significantly reduce fuel usage. The system incorporates a unique flue...

  5. TES carbon monoxide validation with DACOM aircraft measurements during INTEX-B 2006

    E-Print Network [OSTI]

    , consistent with known features in the tracer fields due to transpacific transport of polluted air parcels in the Houston area. The comparisons of TES and DACOM CO profiles near Hawaii and Anchorage in April to May 2006, and Intercontinental Chemical Transport Experiment (INTEX)-B in March to May 2006 near Houston, TX, Hawaii, HI

  6. Multimodel simulations of carbon monoxide: Comparison with observations and projected near-future changes

    E-Print Network [OSTI]

    2006-01-01

    forcing from aircraft NOx emissions: Mechanisms and seasonaland its response to NOx emission controls, J. Atmos. Chem. ,Inversion of CO and NOx emissions using the adjoint of the

  7. Carbon Monoxide Pollution Promotes Cardiac Remodeling and Ventricular Arrhythmia in Healthy Rats

    E-Print Network [OSTI]

    Boyer, Edmond

    worldwide by outdoor air pollution caused by vehicles and industrial emissions (http://www.who.int; http:// www.infoforhealth.org). Notably, air pollution increases the risk of mortality from cardiovascular investigating the effects of urban air pollution in humans are mainly restricted to epide- miological studies

  8. Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring and autumn

    E-Print Network [OSTI]

    Vincent, Warwick F.

    and autumn Huixiang Xie1 Institut des sciences de la mer de Rimouski, Universite´ du Que´bec a` Rimouski, Rimouski, Que´bec G5L 3A1, Canada Simon Be´langer De´partement de biologie, chimie et ge´ographie, Universite´ du Que´bec a` Rimouski, Rimouski, Que´bec G5L 3A1, Canada Serge Demers Institut des sciences de

  9. Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane

    E-Print Network [OSTI]

    Weidner, John W.

    - based fuels is known to degrade the performance of a proton ex- change membrane fuel cell PEMFC effects of CO on the performance of a PEMFC, researchers have explored ways to modify fuel cell opera

  10. Technology development for iron Fischer-Tropsch catalysis. [Pretreatment of catalyst in carbon monoxide

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The present study shows that activation of a high surface area Fe{sub 2}O{sub 3} catalyst in CO in a (CSTR), continuously stirred tank reactor using tetralin as solvent results in an activated that is three times of material that is activated in H{sub 2} or directly in the syngas.

  11. Continuous Measurement of Carbon Monoxide Improves Combustion Efficiency of CO Boilers 

    E-Print Network [OSTI]

    Gilmour, W. A.; Pregler, D. N.; Branham, R. L.; Prichard, J. J.

    1981-01-01

    The paper describes the application of in-situ flue gas CO measurement in the operation of CO Boilers and details the steps needed to optimize combustion efficiency....

  12. Nitric oxide and carbon monoxide in cigarette smoke in the development of cardiorespiratory disease in smokers

    E-Print Network [OSTI]

    Borland, Colin David Ross

    1988-10-18

    in the Department of Respiratory Physiology, Addenbrooke's Hospital, Hills Road, Cambridge CB2 2QQ. 2) The practical work was all performed by me excepting as follows. In Chapter 6 Karen Harmes ESc p~rformed the methaemoglobin analyses. In Chapter 5(2) Rachel... as to atmospheric po llution (Reid and Fletcher 1971) . Genetic susceptibility to obstructive lung disease, e.g. a 1 antitrypsin defic iency (Kueppers and Black 1974) is well recognised but it affects only a s mall proportion of s mokers. The relat ionshi p...

  13. PAST RESEARCH SUMMARY REDUCTION OF CARBON MONOXIDE DOE/ER/04949--1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access toOctoberConsumptionPoweredE Contract No.No. 330

  14. Concentration of ozone in surface air over greater Boston

    E-Print Network [OSTI]

    Widen, Donald Allen

    1966-01-01

    Surface ozone concentrations were measured in the Greater Boston area from November, 1964 to December, 1965. Ozone was monitored continuosly using a Mast microcoulombmetric sensor. A chromium trioxide filter was fitted to ...

  15. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. 2005 Diesel Engine Emissions...

  16. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01

    in the air upstream and downstream of the filters.were also measured upstream and downstream of a “reference”in the air upstream and downstream of the filters. For

  17. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01

    removing particulate matter. ANSI/ASHRAE standard 52.1-1992efficiency by particle size. ANSI/ASHRAE Standard 52.2-1999.GA, ASHRAE. ASHRAE (2007). ANSI/ASHRAE Standard 62.1.

  18. What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found in the strato-

    E-Print Network [OSTI]

    What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found it represents only a tiny fraction of the atmosphere, ozone is crucial for life on Earth. Ozone--acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. With- out ozone, the Sun

  19. Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong-Hoo Park a

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong Received in revised form 26 May 2010 Accepted 2 June 2010 Keywords: Ozone fluxes Citrus Tropospheric ozone climates. In the summer, orchards in California experience high levels of tropospheric ozone, formed

  20. Theoretical studies on hydrogen ignition and droplet combustion

    E-Print Network [OSTI]

    Del Álamo, Gonzalo

    2006-01-01

    the combustion of hydrogen and carbon monoxide. Combustionfor carbon-monoxide hydrogen oxygen kinetics. Combustion

  1. Seasonal ozone variations in the upper mesosphere

    SciTech Connect (OSTI)

    Thomas, R.J. (Univ. of Colorado, Boulder (United States))

    1990-05-20

    The global daytime ozone was measured by the Solar Mesosphere Explorer satellite (SME) for 5 years. The measurements extend through the mesosphere, covering from 50 km to over 90 km. The ozone in the upper mesosphere varies annually by up to a factor of 3. The observed seasonal variations may be summarized in several different ways. From year to year there is a great deal of repeatability of these variations. This repeatability occurs in most of the upper mesosphere outside the tropics. Near 0.01 mbar (80 km) the mid- and high-latitude mixing ratio peaks each year in mid-April. A secondary maximum in the altitude profile of ozone density usually occurs near 85 km. Changes in this structure are directly related to the April maximum and other seasonal changes seen at 0.01 mbar. The changing seasonal structure produces a bump at the ozone mixing ratio minimum that is largest just after spring equinox. This perturbation to the mixing ratio profile seems to move upward during the first half of the year. The seasonal changes of ozone were analyzed in terms of annual and semiannual structure. The variations generally have both an annual and semiannual component depending on altitude and latitude. The phases of the variations change quickly with both altitude and latitude. The semiannual component peaks in April, over most of the upper mesosphere.

  2. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  3. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2000 tropical ozone climatology 2; published 31 January 2003. [1] The first view of stratospheric and tropospheric ozone variability in the Southern Hemisphere tropics is provided by a 3-year record of ozone soundings from the Southern Hemisphere

  4. Ozone climatology using interactive chemistry: results from the Canadian

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone climatology using interactive chemistry: results from the Canadian Middle Atmosphere Model., Medvedev, A. S. and Shepherd, T. G. (2000) Ozone climatology using interactive chemistry: results from RESEARCH, VOL. 105,NO. D21, PAGES 26,475-26,491,NOVEMBER 16, 2000 Ozone climatology using interactive

  5. Chemistry climate model simulations of1 spring Antarctic ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Chemistry climate model simulations of1 spring Antarctic ozone Article Published Version Austin, J. (2010) Chemistry climate model simulations of spring Antarctic1 ozone. Journal of Geophysical Research ozone John Austin,1,2 H. Struthers,3 J. Scinocca,4 D. A. Plummer,5 H. Akiyoshi,6 A. J. G. Baumgaertner,7

  6. Assigning vibrational polyads using relative equilibria. Application to ozone

    E-Print Network [OSTI]

    Sadovskií, Dmitrií

    Assigning vibrational polyads using relative equilibria. Application to ozone I. N. Kozin a,1 , D equilibria. We use the ozone molecule as a concrete example where n­polyads or ``hyperpolyads'' should structure of the vibrational levels of ozone. We consider the classical mechanical analogue

  7. Using transport diagnostics to understand chemistry climate model ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Using transport diagnostics to understand chemistry climate model ozone simulations Article chemistry climate model ozone simulations. Journal of Geophysical Research - Atmospheres, 116 (D17). D17302 transport diagnostics to understand chemistry climate model ozone simulations S. E. Strahan,1 A. R. Douglass

  8. A comparison study of data assimilation algorithms for ozone forecasts

    E-Print Network [OSTI]

    Mallet, Vivien

    A comparison study of data assimilation algorithms for ozone forecasts Lin Wu,1,2 V. Mallet,1,2 M assimilation schemes with the aim of designing suitable assimilation algorithms for short- range ozone but stable systems with high uncertainties (e.g., over 20% for ozone daily peaks (Hanna et al., 1998; Mallet

  9. On the statistical modeling of persistence in total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    On the statistical modeling of persistence in total ozone anomalies Article Published Version in total ozone anomalies. Journal of Geophysical Research, 115. D16306. ISSN 0148-0227 doi: 10.1029/2009JD the statistical modeling of persistence in total ozone anomalies D. I. Vyushin,1 T. G. Shepherd,1 and V. E

  10. Ozone Chemistry in the High-Latitude Boundary Layer

    E-Print Network [OSTI]

    Toohey, Darin W.

    Ozone Chemistry in the High-Latitude Boundary Layer Linnea Avallone Department of Atmospheric layer ozone loss phenomenon · In situ observations of BrO at Arctic sites · Preliminary results from Antarctic experiments in 2002 and 2004 #12;Brief History · Springtime ozone loss observed at many sites

  11. Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E for their species effectiveness in reducing ozone concentrations in a simulated indoor environment. Continuously supply system were used to simulate an indoor environment in which ozone concentrations could be measured

  12. Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer

    E-Print Network [OSTI]

    Oppenheimer, Michael

    Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 ozone depletion has been much studied as a case history in the interaction between environmental science the photochemistry of ozone in order to illustrate how scientific learning has the potential to mislead policy makers

  13. A global picture of the seasonal persistence of stratospheric ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    A global picture of the seasonal persistence of stratospheric ozone anomalies Article Published persistence of stratospheric ozone anomalies. Journal of Geophysical Research, 115. D18119. ISSN 0148-0227 doi global picture of the seasonal persistence of stratospheric ozone anomalies S. Tegtmeier,1,2 V. E

  14. Ozone Treatments of Fresh Atlantic Cod, Gadus morhua

    E-Print Network [OSTI]

    Ozone Treatments of Fresh Atlantic Cod, Gadus morhua ELINOR M. RAVESI, JOSEPH J. L1CCIARDELLO and LINDA D. RACICOT Introduction The strong oxidizing nature of ozone, known since its discovery in 1840 (1977) cited in a review article numerous reports of the successful use of ozone to I) control microbial

  15. Relative importance of radical families The "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    · Relative importance of radical families · The "Ozone Hole" · Introduction to heterogeneous chemistry Tuesday, March 8, 2011 #12;Review of important points so far Stratospheric ozone is only produced with these parameters Sir Sydney Chapman nearly got it right. He could account for the formation of the ozone layer

  16. oZONE Faculty and Staff Course Overrides

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Course Overrides and the Registration Add Errors They Resolve Departments of the overrides within the registration component of oZONE. We have, however, retained a few instances where some. There is also a link to this document on the Student Training and Instructions page in the oZONE info site

  17. Quantum origin of an anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Quantum origin of an anomalous isotope effect in ozone formation D. Babikov *, B.K. Kendrick, R mechanical calculations of the ðJ ¼ 0Þ energies and lifetimes of the metastable states of ozone on a new effect in the reaction that forms ozone because of their role in the energy transfer mechanism, in which

  18. The Ozone Layer in the 21st Lead Authors

    E-Print Network [OSTI]

    Robock, Alan

    CHAPTER 6 The Ozone Layer in the 21st Century Lead Authors: G.E. Bodeker D.W. Waugh Coauthors: H;#12;CHAPTER 6 THE OZONE LAYER IN THE 21ST CENTURY Contents SCIENTIFIC SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.5 6.2 A FRAMEWORK FOR EVALUATING CHANGES IN OZONE ABUNDANCES

  19. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982004 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2004 tropical ozone climatology: 3 more than 3000 ozone profiles from 14 tropical and subtropical sites using balloon- borne technique might cause small station-to-station biases in the total ozone measurement. We present further

  20. Summertime total ozone variations over middle and polar latitudes

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Summertime total ozone variations over middle and polar latitudes Article Published Version Fioletov, V. E. and Shepherd, T. G. (2005) Summertime total ozone variations over middle and polar's research outputs online #12;Summertime total ozone variations over middle and polar latitudes Vitali E

  1. Arctic ozone loss and climate sensitivity: Updated threedimensional model study

    E-Print Network [OSTI]

    Feng, Wuhu

    Arctic ozone loss and climate sensitivity: Updated three­dimensional model study Chipperfield winter­spring chemical ozone loss from 1991 2003, its observed correlation with low temperatures. CTM throughout studied. The model reproduces large column winters also captures shape of ozone loss profile

  2. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2000 tropical ozone climatology 1. Comparison with Total Ozone Mapping Spectrometer (TOMS) and ground-based measurements Anne M. Thompson,1 Additional Ozonesondes (SHADOZ) project and established from operational sites, provided over 1000 ozone

  3. Corona method and apparatus for altering carbon containing compounds

    DOE Patents [OSTI]

    Sharma, Amit K. (Richland, WA); Camaioni, Donald M. (Richland, WA); Josephson, Gary B. (Richland, WA)

    1999-01-01

    The present invention is a method and apparatus for altering a carbon containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

  4. Corona Method And Apparatus For Altering Carbon Containing Compounds

    DOE Patents [OSTI]

    Sharma, Amit K. (Plainsboro, NJ); Camaioni, Donald M. (Richland, WA); Josephson; Gary B. (Richland, WA)

    2004-05-04

    The present invention is a method and apparatus for altering a carbon-containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon-containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

  5. Analysis of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions and photochemistry

    E-Print Network [OSTI]

    Dickerson, Russell R.

    fossil fuel use and 40 Tg yrÀ1 from biomass burning. With the addition of isoprene oxidation, the total. In India, the preponderance of motorcycles with small, two-stroke engines and the practice of adulterating CO emissions were 67 Tg yrÀ1 from India and 87 Tg(CO) yrÀ1 from all of South Asia. These values

  6. The Effects of Gaseous Ozone and Nitric Acid Deposition on two Crustose Lichen Species From Joshua Tree National Park

    E-Print Network [OSTI]

    Hessom, Elizabeth Curie

    2012-01-01

    photosynthetic rate responses to ozone in some foliose andof gaseous nitric acid and ozone on lichens. Dissertations &with nitric acid and ozone. Environmental Pollution, In

  7. Tropospheric column ozone: matching individual profiles from Aura OMI and TES with a chemistry-transport model

    E-Print Network [OSTI]

    Tang, Q.; Prather, M. J

    2012-01-01

    Science Objectives of the Ozone Monitoring In- strument,G. J. , and Logan, J. A. : Ozone climatolog- ical profilestroposphere ex- change ozone flux related to deep

  8. Megacity impacts on regional ozone formation: observations and WRF-Chem modeling for the MIRAGE-Shanghai field campaign

    E-Print Network [OSTI]

    2013-01-01

    Tie, X. : Analysis of ozone and VOCs measured in Shanghai: AMegacity impacts on regional ozone formation terminations inand Tie, X. : Study of ozone “weekend effect” in Shanghai,

  9. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  10. High Performance Silicon Monoxide (SiO) Electrode for Next Generation Lithium Ion Batteries

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2015-02-27

    Berkeley Lab’s High Performance Silicon Monoxide Electrode has a capacity retention of more than 90% after ~500 cycles, which translates into a ~20% improvement over the limited energy density of conventional graphite anode-based lithium-ion batteries, enabling next-generation mobile electronics and electric/plug-in vehicles....

  11. Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation

    SciTech Connect (OSTI)

    Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

    2013-08-15

    The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

  12. Ozone Reductions using Residential Building Envelopes

    E-Print Network [OSTI]

    for Energy Efficiency and Renewable Energy, Building Technologies Program, of the U.S. Department of Energy Residential Building Envelopes Prepared For: California Energy Commission Public Interest Energy ResearchOzone Reductions using Residential Building Envelopes I.S. Walker, M.H. Sherman and W.W. Nazaroff

  13. Growth, physiology, and [delta] 13C of loblolly and shortleaf pine as affected by ozone and soil water deficit 

    E-Print Network [OSTI]

    Elsik, Christine Golemboski

    1992-01-01

    balance be altered as a result of stomatal closure, because of decreased in transpirational cooling (Winner and Atkinson 1986). Biomass and Carbon Allocation Although a reduction in photosynthesis due to 0, . through a decrease in both photosynthetic... photosynthesis was linearly related to 0, in loblolly pine, and was accompanied by decreased foliar chlorophyll concenuation and decreased stomatal conductance, Decreased transpiration was attributable to 0, in both species. Ozone increased 5"Cms of loblolly...

  14. Relations between isoprene and nitric oxide in exhaled breath and the potential influence of outdoor ozone: a pilot study

    E-Print Network [OSTI]

    Khan, Alya; Staimer, Norbert; Tjoa, Thomas; Galassetti, Pietro; Blake, Donald R.; Delfino, Ralph J.

    2013-01-01

    2-day 3-day 5-day a 12.7 ppb ozone b Adjusted for splines ofoutput after exposure to ozone. J Appl Physiol. 1996; 80:apparatus against ozone damage, quenches ozone products, and

  15. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean 

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31

    Despite the known reactivity of ozone (O_(3)) in water and ozone’s environmental importance in the atmosphere, there are relatively few studies published examining the chemistry of O_(3) in seawater. This study focused on ...

  16. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    E-Print Network [OSTI]

    Jin, Ling

    2010-01-01

    Vertical distribution of ozone at four sites in the UnitedAltshuler, S. ; Franco, G. Ozone formation in California'sSeinfeld, J. H. Analysis of ozone in the San Joaquin Valley

  17. Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy

    E-Print Network [OSTI]

    Brown, Matthew A.

    2008-01-01

    J. C. , Reactivity of ozone on solid potassium iodide.and mechanisms of aqueous ozone reactions with bromide,for Dry Deposition of Ozone to Seawater Surfaces. Journal of

  18. Ground-level ozone influenced by circadian control of isoprene emissions

    E-Print Network [OSTI]

    2011-01-01

    S. The relation between ozone, NO x and hydrocarbons inAmerican emissions on surface ozone in the US. Atmos. Chem.10.1038/NGEO1271 Ground-level ozone influenced by circadian

  19. OZONE INDUCED CONDUCTANCE INCREASES ASSAYED WITH LIPID IMPREGNATED FILTER MEMBRANES-EFFECT OF VITAMIN E

    E-Print Network [OSTI]

    Sheih, P.K

    2011-01-01

    29-44. R. L. Heath (1975) Ozone, in Response of Plants toSince it is possible that ozone absorption "is incompleteof the filter. After the ozone treatment was stopped the

  20. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    E-Print Network [OSTI]

    Destaillats, Hugo

    2012-01-01

    used in LBNL, exposed to 150 ppb ozone at two different flowMendell, 2008. Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  1. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D7, PAGES 9873-9887, JULY 20, 1989 The Sensitivity of Total Ozone and Ozone Perturbation Scenarios

    E-Print Network [OSTI]

    Jackman, Charles H.

    of Total Ozone and Ozone Perturbation Scenarios in a Two-Dimensional Model Due to Dynamical Inputs CHARLESTland The sensitivity of the total ozone distribution in our two-dimensional photochemical model to dynamical inputs has average total ozone varies by up to 10%. dependingon the various dynamical inputs, and the seasonaland

  2. Ozone treatment in a closed culture system for Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Yamaguchi, Ryoji

    1978-01-01

    periodically and analyzed for total ammonia nitrogen and nitrate nitrogen concentrations using the Direct Nessleriza- tion Method and the Cadmium Reduction Method, respectively (APHA, 1976) . 2. Chemical oxygen demand (COD) and ozonation: The solutions... level. 29 7. Tests of the homogeneity of variance and oneway analysis of variance for the effects of ozonation on two levels of nitrite nitrogen concentration with 95X confidence limit. . . . 31 8. Effects of ozone on ammonia, nitrite, nitrate, COD...

  3. Tropospheric Ozone ATOC/CHEM 5151

    E-Print Network [OSTI]

    Toohey, Darin W.

    ) ( production! #12;18 Ozone production CO + OH CO2 + H loss · Photolysis (1.4 x 1011 cm-2 s-1) · Oxidation of CO (3.5 x 1011 cm-2 s-1) 4. Chemical production #12;23 Formaldehyde chemistry CH2O + h H + HCO H + O2 + M HO2 + M HCO + O2 CO + HO2 2x [HO2

  4. Fundamental differences between Arctic and Antarctic ozone depletion

    E-Print Network [OSTI]

    Solomon, Susan

    Antarctic ozone depletion is associated with enhanced chlorine from anthropogenic chlorofluorocarbons and heterogeneous chemistry under cold conditions. The deep Antarctic “hole” contrasts with the generally weaker depletions ...

  5. Estimating changes in urban ozone concentrations due to life cycle emissions from hydrogen transportation systems

    E-Print Network [OSTI]

    Wang, Guihua; Ogden, Joan M; Chang, Daniel P.Y.

    2007-01-01

    of natural gas to hydrogen pathways on urban air quality.Natural gas (NG); Hydrogen pathways; Ozone formation; Ozone air quality

  6. Ozone depletion, developing countries, and human rights: Seeking better ground on which to fight for protection of the ozone layer

    SciTech Connect (OSTI)

    Williams, V.

    1995-12-31

    I urge you not to take a complacent view of the situation. The state of depletion of the ozone layer continues to be alarming... In February, 1993, the ozone levels over North America and most of Europe were 20 percent below normal... Even now, millions of tons of CFC [chlorofluorocarbon] products are en route to their fatal stratospheric rendezvous... This exponential increase calls for increased reflection on the state of the ozone layer and calls for bold decisions.

  7. Carbon sequestration

    E-Print Network [OSTI]

    Carbon sequestration is the process of capture and long-term storage of atmospheric carbon dioxide (CO 2).[1] Carbon sequestration describes long-term storage of carbon dioxide or other forms of carbon to either mitigate or defer global warming and avoid ...

  8. Reactive uptake of ozone at simulated leaf surfaces: implications for "non-stomatal" ozone flux 

    E-Print Network [OSTI]

    Cape, J Neil; Hamilton, Richard P; Heal, Mathew R

    2009-01-01

    The reaction of ozone (O3) with ?-pinene has been studied as a function of temperature and relative humidity and in the presence of wax surfaces that simulate a leaf surface. The objective was to determine whether the presence of a wax surface...

  9. Observed relationships of ozone air pollution with temperature and emissions

    E-Print Network [OSTI]

    Stehr, Jeffrey

    Observed relationships of ozone air pollution with temperature and emissions Bryan J. Bloomer,1, and R. R. Dickerson (2009), Observed relationships of ozone air pollution with temperature and emissions decreased by 43% for the time period 1995 to 2002 compared with 2003 to 2006 as a result of air pollution

  10. URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA

    E-Print Network [OSTI]

    Boyer, Edmond

    Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

  11. ORIGINAL CONTRIBUTION Ozone and Short-term Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    . With the National Morbidity, Mortality, and Air Pollution Study (NMMAPS), we have developed na- tional approaches Ambient Air Qual- ity Standard (NAAQS) for ozone, adding a daily maximum 8-hour stan- dard of 80 ppb.19 Because of the relevance of epidemiologic evi- dence to the NAAQS for ozone and other pollutants

  12. Light emission from an argon discharge containing an admixture of carbon G. Bekefi, P. Avivi, F. DothanDeutsch, L. Friedland, J. L. Hirshfield, and H. Keren

    E-Print Network [OSTI]

    Friedland, Lazar

    Light emission from an argon discharge containing an admixture of carbon monoxide G. Bekefi, P Publishing Articles you may be interested in Light Emission of Argon Discharges: Importance of Heavy Particle Processes AIP Conf. Proc. 740, 353 (2004); 10.1063/1.1843519 Kinetic pathways to visible emission from

  13. Modeling Transport E ects on Ground-Level Ozone Using a

    E-Print Network [OSTI]

    Huang, Su-Yun

    Modeling Transport E ects on Ground-Level Ozone Using a Non-Stationary Space-Time Model Hsin on Ground-Level Ozone 1 #12;Summary This article presents a novel autoregressive space-time model for ground-level ozone data, which models not only spatio-temporal dynamics of hourly ozone con- centrations, but also

  14. Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Aakash C. Rai1

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Dynamics2 3 10 Ozone is a major pollutant of indoor air. Many studies have demonstrated the adverse health effect of11 ozone and the byproducts generated as a result of ozone-initiated reactive chemistry

  15. Improving total column ozone retrievals by using cloud pressures derived from Raman scattering in the UV

    E-Print Network [OSTI]

    Joiner, Joanna

    Improving total column ozone retrievals by using cloud pressures derived from Raman scattering resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals. By default, the TOMS

  16. Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A) Austin, TX 78758, USA ABSTRACT Most ozone exposure occurs indoors even though some surfaces consume ozone and reduce its concentration relative to outdoors. Ozone consumption often results in emissions of secondary

  17. Why are there large differences between models in global budgets of tropospheric ozone?

    E-Print Network [OSTI]

    Wu, Shiliang

    Why are there large differences between models in global budgets of tropospheric ozone? Shiliang Wu for tropospheric ozone. The ozone production rate in the troposphere, P(Ox), varies from 2300 to 5300 Tg yrÀ1 compounds (NMVOCs, mostly biogenic isoprene), and ozone influx from stratosphere-troposphere exchange (STE

  18. An intramolecular theory of the mass-independent isotope effect for ozone. I.

    E-Print Network [OSTI]

    Hathorn, Bryan C.

    An intramolecular theory of the mass-independent isotope effect for ozone. I. B. C. Hathorn and R-independent isotope effect for ozone formation and dissociation is described. The experiments include the enrichment and asymmetric ozone isotopomers, the enrichment of ozone formed from heavily enriched oxygen isotopes

  19. A cohesive total ozone data set from the SBUV(/2) satellite system A. J. Miller,1

    E-Print Network [OSTI]

    Jackman, Charles H.

    A cohesive total ozone data set from the SBUV(/2) satellite system A. J. Miller,1 R. M. Nagatani,1 of total ozone estimates from the Solar Backscatter Ultraviolet Ozone Sensors (SBUVand SBUV/2) began of individual instruments are good, they give total ozone accuracies of approximately 2%. However, without

  20. Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1

    E-Print Network [OSTI]

    Son, Seok-Woo

    Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1 Neil F. Tandon,2 Lorenzo M cooling resulting from ozone depletion has only recently been examined and a comprehensive picture on the stratospheric ozone forcing used, we here show that stratospheric ozone affects the entire atmospheric

  1. PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure

    E-Print Network [OSTI]

    in industrial processes is increasing. Applications for ozone include treatment of waste water, water

  2. A Survey and Critical Review of the Literature on Indoor Air Quality, Ventilation and Health Symptoms in Schools

    E-Print Network [OSTI]

    Daisey, Joan M.

    2010-01-01

    Carbon monoxide originates from incomplete combustion ofcarbon monoxide poisoning caused by faulty combustion

  3. Experimental and Computational Studies of the Combustion of Classical and Alternative Fuels

    E-Print Network [OSTI]

    Niemann, Ulrich

    the combustion of hydrogen and carbon monoxide. Combustionthe combustion of hydrogen and carbon monoxide. Combustionpects of combustion of hydrogen [29], carbon monoxide [29],

  4. Computational Studies of Flame Structures

    E-Print Network [OSTI]

    Amin, Vaishali

    2015-01-01

    equation for combustion of carbon monoxide with oxygen isof combustion of hydrogen [19], carbon monoxide [19],and carbon monoxide is necessary to design combustion

  5. Numerical and experimental studies of ethanol flames and autoignition theory for higher alkanes

    E-Print Network [OSTI]

    Saxena, Priyank

    2007-01-01

    of hydrogen and carbon monoxide”, Combustion and Flame, 145,of Hydrogen and Carbon Monoxide”, Combustion and Flame, 145,hydrogen and carbon monoxide”, Combustion and Flame , 145,

  6. UV-Vis, infrared, and mass spectroscopy of electron irradiated frozen oxygen and carbon dioxide mixtures with water

    SciTech Connect (OSTI)

    Jones, Brant M.; Kaiser, Ralf I.; Strazzulla, Giovanni

    2014-02-01

    Ozone has been detected on the surface of Ganymede via observation of the Hartley band through the use of ultraviolet spectroscopy and is largely agreed upon to be formed by radiolytic processing via interaction of magnetospheric energetic ions and/or electrons with oxygen-bearing ices on Ganymede's surface. Interestingly, a clearly distinct band near 300 nm within the shoulder of the UV-Vis spectrum of Ganymede was also observed, but currently lacks an acceptable physical or chemical explanation. Consequently, the primary motivation behind this work was the collection of UV-Vis absorption spectroscopy of ozone formation by energetic electron bombardment of a variety of oxygen-bearing ices (oxygen, carbon dioxide, water) relevant to this moon as well as other solar system. Ozone was indeed synthesized in pure ices of molecular oxygen, carbon dioxide and a mixture of water and oxygen, in agreement with previous studies. The Hartley band of the ozone synthesized in these ice mixtures was observed in the UV-Vis spectra and compared with the spectrum of Ganymede. In addition, a solid state ozone absorption cross section of 6.0 ± 0.6 × 10{sup –17} cm{sup 2} molecule{sup –1} was obtained from the UV-Vis spectral data. Ozone was not produced in the irradiated carbon dioxide-water mixtures; however, a spectrally 'red' UV continuum is observed and appears to reproduce well what is observed in a large number of icy moons such as Europa.

  7. Essays on the Impact of Climate Change and Building Codes on Energy Consumption and the Impact of Ozone on Crop Yield

    E-Print Network [OSTI]

    Aroonruengsawat, Anin

    2010-01-01

    14 Impact of ozone on crop yield15 Data 15.1 OzoneEstimated effect of mean ozone on crop yields. . . . . . .

  8. Ti{sub 5}O{sub 5} superstructures of cubic titanium monoxide

    SciTech Connect (OSTI)

    Gusev, A. I.

    2013-08-15

    A cubic model is proposed for the Ti{sub 5}O{sub 5} (Ti{sub 5} Black-Small-Square O{sub 5}{open_square} {identical_to} Ti{sub 90} Black-Small-Square {sub 18}O{sub 90}{open_square}{sub 18}) superstructure of nonstoichiometric titanium monoxide Ti{sub x}O{sub z} with double imperfection. The unit cell of the cubic Ti{sub 5}O{sub 5} superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti{sub x}O{sub z} monoxide and belongs to space group Pm 3-bar m . The channel of the disorder-order transition, i.e., Ti{sub x}O{sub z} (space group Fm 3-bar m)-Ti{sub 5}O{sub 5} (space group Pm 3-bar m), includes 75 superstructure vectors of seven stars (k{sub 10}), (k{sub 7}), (k{sub 6(1)}), (k{sub 6(2)}), (k{sub 4(1)}), (k{sub 4(2)}), and (k{sub 1}). The distribution functions of Ti and O atoms over the sites of the cubic Ti{sub 5}O{sub 5} superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO{sub 1.087} monoxide with the theoretical simulation results supports the existence of the cubic Ti{sub 5}O{sub 5} superstructure. The cubic (space group Pm 3-bar m) Ti{sub 5}O{sub 5} superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.

  9. Carbon Smackdown: Carbon Capture

    SciTech Connect (OSTI)

    Jeffrey Long

    2010-07-12

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  10. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  11. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  12. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, M.; Grohse, E.W.

    1995-06-27

    A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

  13. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

    1995-01-01

    A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

  14. On the photoelectron velocity-map imaging of lutetium monoxide anion LuO{sup ?}

    SciTech Connect (OSTI)

    Liu, Zhiling; Xie, Hua; Qin, Zhengbo; Cong, Ran; Wu, Xia; Tang, Zichao, E-mail: zctang@dicp.ac.cn; Fan, Hongjun, E-mail: fanhj@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China); Li, Quanjiang [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-01-21

    We report a combined photoelectron velocity-map imaging spectroscopy and density functional theory investigation on lutetium monoxide anion. Transition between the X {sup 1}?{sup +} anion electronic ground state and the neutral X {sup 2}?{sup +} electronic ground state is observed. Vibrationally resolved spectra were obtained at four different photon energies, providing a wealth of spectroscopic information for the electronic ground states of the anionic lutetium monoxide and corresponding neutral species. Franck-Condon simulations of the ground-state transition are performed to assign vibrational structure in the spectra and to assist in identifying the observed spectral bands. The electronic ground state of LuO{sup ?} is found to have a vibrational frequency of 743 ± 10 cm{sup ?1} and an equilibrium bond length of 1.841 Å. The electron affinity of LuO is measured to be 1.624 ± 0.002 eV. The fundamental frequency of ground-state LuO is estimated to be 839 ± 10 cm{sup ?1}.

  15. Ozone-forming potential of a series of oxygenated organic compounds

    SciTech Connect (OSTI)

    Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. )

    1991-03-01

    An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

  16. Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2,

    E-Print Network [OSTI]

    Jackman, Charles H.

    Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2, CF2ClBr, and CF2BrCF2Br Dimitrios K. Papanastasiou,1,2,5 Nabilah. [1] The contribution of Halons, bromine-containing haloalkanes, to stratospheric ozone depletion

  17. Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects

    E-Print Network [OSTI]

    Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects on photosynthesis to a complex canopy architecture§ M.J. Martina, *, G.E. Hosta; accepted 17 July 2001 ``Capsule'': A process model is described that predicts the relative effects of ozone

  18. Global Health and Economic Impacts of Future Ozone Pollution

    E-Print Network [OSTI]

    Webster, Mort D.

    We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the ...

  19. Assessing Global Terrestrial Sources of Methyl Halides - Ozone Regulating Gases 

    E-Print Network [OSTI]

    Gancarczyk, Maciej

    2010-11-24

    Methyl bromide (CH3Br) and methyl chloride (CH3Cl) play significant roles in the depletion of the stratospheric ozone layer. The vast portion of methyl halide sources and sinks sources and sinks are natural in origin. The ...

  20. Foliar ozone injury and gas exchange among black cherry genotypes

    SciTech Connect (OSTI)

    Kouterick, K.B.; Skelly, J.M.; Fredericksen, T.S.; Kolb, T.E.; Savage, J.E.; Snyder, K.R. (Penn State Univ., University Park, PA (United States))

    1994-06-01

    The effect of differing ozone exposures on seedlings of black cherry genotypes was investigated in northcentral Pennsylvania. Ozone exclusion treatments were administrated to half-sib families R12 and MO-7, and wild-type (WT) grown in open-top chambers. Over the 1993 growing season, left gas exchange and stem volume were related to percentage of foliar ozone injury observed as adaxial stipple. Ozone symptoms decreased significantly with increasing ozone filtration. R12 exhibited the most severe foliar injury, while WT seedlings showed slightly less symptoms. MO-7 had the least amount of foliar injury. No clear trends in stomatal conductance or net photosynthesis were observed until August. During August, foliar injury was positively related to stomatal conductance. Stomatal conductance values were greatest in R12, followed by WT and MO-7. Photosynthesis followed the same pattern at stomatal conductance. Dark respiration rates were variable across treatments for the entire growing season. Differing ozone exposures did not affect stem volume, but stem volume of seedlings of all families in the open plot were significantly lower than seedlings within chambers. Overall, R12 had higher stem volume than MO-7 and WT seedlings.

  1. A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells

    SciTech Connect (OSTI)

    Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

    2013-01-01

    The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

  2. Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause-Based Climatology and Optimal Estimation Approach

    E-Print Network [OSTI]

    Pan, Laura

    Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause for retrieving atmospheric ozone profile information from advanced satellite infrared sounders, this study investigates various methods to optimize ozone retrievals. A set of retrieval experiments has been performed

  3. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    E-Print Network [OSTI]

    2015-01-01

    VOC reactivity and its effect on ozone production during theand HONO chemistry on ozone A. , Molina, L. T. , Nenes, A. ,15/4357/2015/ emissions on ozone concentration during summer

  4. Predict carbonation rate on iron Fischer-Tropsch catalyst

    SciTech Connect (OSTI)

    Dry, M.E.

    1980-02-01

    An experimental study of the coking rate in 5 cm ID fluidized-bed reactors, in which the feed gas composition, the total pressure, and the fresh feed/recycle gas ratios were varied over wide ranges, showed a strong correlation between the carbon deposition rate and the ratio of carbon monoxide partial pressure to the square of the hydrogen partial pressure at the reactor inlet over a wide gas-composition range. At a given fresh gas composition, the combination rate varied inversely with the total pressure of the system. Coking decreased as the moles of CO + CO/sub 2/ converted to hydrocarbon increased. A Fischer-Tropsch reaction scheme is proposed and is used to derive a rate expression for catalyst carbonation that was approximately confirmed.

  5. Revised and Updated Thermochemical Properties of the Gases Mercapto ,,HS..., Disulfur Monoxide ,,S2O..., Thiazyl ,,NS...,

    E-Print Network [OSTI]

    Fegley Jr., Bruce

    in the 4th edition of the NIST-JANAF Thermochemical Tables. Updated enthalpies of formation were includedRevised and Updated Thermochemical Properties of the Gases Mercapto ,,HS..., Disulfur Monoxide ,,S2 to compute the thermochemical tables for four ideal gases: mercapto HS , disulfur monox- ide (S2O), thiazyl

  6. Projections of Future Summertime Ozone over the U.S.

    SciTech Connect (OSTI)

    Pfister, G. G.; Walters, Stacy; Lamarque, J. F.; Fast, Jerome D.; Barth, Mary; Wong, John; Done, James; Holland, Greg; Bruyere, Cindy

    2014-05-05

    This study uses a regional fully coupled chemistry-transport model to assess changes in surface ozone over the summertime U.S. between present and a 2050 future time period at high spatial resolution (12 km grid spacing) under the SRES A2 climate and RCP8.5 anthropogenic pre-cursor emission scenario. The impact of predicted changes in climate and global background ozone is estimated to increase surface ozone over most of the U.S; the 5th - 95th percentile range for daily 8-hour maximum surface ozone increases from 31-79 ppbV to 30-87 ppbV between the present and future time periods. The analysis of a set of meteorological drivers suggests that these mostly will add to increasing ozone, but the set of simulations conducted does not allow to separate this effect from that through enhanced global background ozone. Statistically the most robust positive feedbacks are through increased temperature, biogenic emissions and solar radiation. Stringent emission controls can counteract these feedbacks and if considered, we estimate large reductions in surface ozone with the 5th-95th percentile reduced to 27-55 ppbV. A comparison of the high-resolution projections to global model projections shows that even though the global model is biased high in surface ozone compared to the regional model and compared to observations, both the global and the regional model predict similar changes in ozone between the present and future time periods. However, on smaller spatial scales, the regional predictions show more pronounced changes between urban and rural regimes that cannot be resolved at the coarse resolution of global model. In addition, the sign of the changes in overall ozone mixing ratios can be different between the global and the regional predictions in certain regions, such as the Western U.S. This study confirms the key role of emission control strategies in future air quality predictions and demonstrates the need for considering degradation of air quality with future climate change in emission policy making. It also illustrates the need for high resolution modeling when the objective is to address regional and local air quality or establish links to human health and society.

  7. Morphological basis of tolerance to ozone

    SciTech Connect (OSTI)

    Evans, M.J.; Dekker, N.P.; Cabral-Anderson, L.J.; Shami, S.G.

    1985-06-01

    The purpose of this research was to study Type 1 epithelial cells in the ozone (O/sub 3/)-tolerant lung epithelium. Rats were made tolerant by exposure to 0.5 ppm O/sub 3/ for 2 days and allowed to recover in air. Reexposure to a lethal concentration of O/sub 3/ (6 ppm) at 3, 7, and 15 days of recovery revealed that tolerance was present at 3 days but almost absent at 7 and 15 days of recovery. Using Type 2 cell proliferation as a means of quantitating Type 1 cell injury, it was observed that when the preexposed rats were reexposed to 0.5 ppm at 3, 7, and 15 days, very little Type 1 cell injury occurred at 3 days. However, at 7 and 15 days the amount of Type 1 cell injury was the same as that associated with the original exposure. To determine whether there was any change in the alveolar epithelial cell populations between the periods of tolerance (3 days) and its decline (7 and 15 days), the percentage of tritiated thymidine (( /sup 3/H)TdR-labeled Type 1 and 2 cells at these times were determined. There was a significant decrease in (/sup 3/H)TdR-labeled Type 1 and 2 cells between the third and fifteenth days of recovery as excess cells were sloughed off and the tissue returned to normal. Using electron microscopic morphometry, Type 1 and 2 cells were then studied during the decline of tolerance. No change was found in the morphology of Type 2 cells; however, the morphology of Type 1 cells revealed a 58% decrease in surface area and a 25% increase in the arithmetic mean thickness when tolerance was present at 3 days. As tolerance declined (7 and 15 days), Type 1 cell morphology returned to normal. It was concluded that tolerance exists when the surface area of a cell exposed to a particular concentration of ozone is small enough so that the existing antioxidant mechanism contained within that cell volume can protect it from damage.

  8. Effect of Organic Capping Layers over Monodisperse Platinum Nanoparticles upon Activity for Ethylene Hydrogenation and Carbon Monoxide Oxidation

    E-Print Network [OSTI]

    Kuhn, John N.

    2010-01-01

    CO) oxidation (Figure 6) and the catalytic activity wascatalytic properties for ethylene hydrogenation and CO oxidation,catalytic properties using ethylene hydrogenation and CO oxidation,

  9. Comparison of adjoint and analytical Bayesian inversion methods for constraining Asian sources of carbon monoxide using satellite

    E-Print Network [OSTI]

    Jacob, Daniel J.

    satellite fire data. Citation: Kopacz, M., D. J. Jacob, D. K. Henze, C. L. Heald, D. G. Streets, and Q of Gaussian errors [Rodgers, 2000]. The cost function describes the error- weighted mismatch between

  10. Detection of Far-Infrared Water Vapor, Hydroxyl, and Carbon Monoxide Emissions from the Supernova Remnant 3C 391

    E-Print Network [OSTI]

    William T. Reach; Jeonghee Rho

    1998-09-01

    We report the detection of shock-excited far-infrared emission of H2O, OH, and CO from the supernova remnant 3C 391, using the ISO Long-Wavelength Spectrometer. This is the first detection of thermal H2O and OH emission from a supernova remnant. For two other remnants, W~28 and W~44, CO emission was detected but OH was only detected in absorption. The observed H2O and OH emission lines arise from levels within ~400 K of the ground state, consistent with collisional excitation in warm, dense gas created after the passage of the shock front through the dense clumps in the pre-shock cloud. The post-shock gas we observe has a density ~2x10^5 cm^{-3} and temperature 100-1000 K, and the relative abundances of CO:OH:H2O in the emitting region are 100:1:7 for a temperature of 200 K. The presence of a significant column of warm H2O suggests that the chemistry has been significantly changed by the shock. The existence of significant column densities of both OH and H2O, which is at odds with models for non-dissociative shocks into dense gas, could be due to photodissociation of H2O or a mix of fast and slow shocks through regions with different pre-shock density.

  11. Effect of Organic Capping Layers over Monodisperse Platinum Nanoparticles upon Activity for Ethylene Hydrogenation and Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Kuhn, John N.; Tsung, Chia-Kuang; Huang, Wenyu; Somorjai, Gabor A.

    2009-03-24

    The influence of oleylamine (OA), trimethyl tetradecyl ammonium bromide (TTAB), and polyvinlypyrrolidone (PVP) capping agents upon the catalytic properties of Pt/silica catalysts was evaluated. Pt nanoparticles that were 1.5 nm in size were synthesized by the same procedure (ethylene glycol reduction under basic conditions) with the various capping agents added afterward for stabilization. Before examining catalytic properties for ethylene hydrogenation and CO oxidation, the Pt NPs were deposited onto mesoporous silica (SBA-15) supports and characterized by transmission electron microscopy (TEM), H{sub 2} chemisorption, and elemental analysis (ICP-MS). PVP- and TTAB-capped Pt yielded mass-normalized reaction rates that decreased with increasing pretreatment temperature, and this trend was attributed to the partial coverage of the Pt surface with decomposition products from the organic capping agent. Once normalized to the Pt surface area, similar intrinsic activities were obtained regardless of the pretreatment temperature, which indicated no influence on the nature of the active sites. Consequently, a chemical probe technique using intrinsic activity for ethylene hydrogenation was demonstrated as an acceptable method for estimating the metallic surface areas of Pt. Amine (OA) capping exhibited a detrimental influence on the catalytic properties as severe deactivation and low activity were observed for ethylene hydrogenation and CO oxidation, respectively. These results were consistent with amine groups being strong poisons for Pt surfaces, and revealed the need to consider the effects of capping agents on the catalytic properties.

  12. Constraints on Carbon Monoxide Emissions Based on Tall Tower Measurements in the U.S. Upper Midwest

    E-Print Network [OSTI]

    Mlllet, Dylan B.

    Harvard University, Cambridge, MA 02138, USA * Correspondence to: Dylan B. Millet (dbm@umn.edu) Supporting. Turbulence is simulated by a Markov chain process. The evolution of particles backwards in time maps I(xr, tr

  13. Structural Changes in Self-Catalyzed Adsorption of Carbon Monoxide on 1,4-Phenylene Diisocyanide Modified Au(111)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kestell, John; Boscoboinik, J. Anibal; Cheng, Lanxia; Garvey, Michael; Bennett, Dennis W.; Tysoe, Wilfred T.

    2015-07-23

    The self-accelerated adsorption of CO on 1,4-phenylene diisocyanide (PDI)-derived oligomers on Au(111) is explored by reflection–absorption infrared spectroscopy and scanning tunneling microscopy. PDI incorporates gold adatoms from the Au(111) surface to form one-dimensional —(Au–PDI)n— chains that can also connect between gold nanoparticles on mica to form a conductive pathway between them. CO adsorption occurs in two stages; it first adsorbs adjacent to the oligomers that move to optimize CO adsorption. Further CO exposure induces PDI decoordination to form Au–PDI adatom complexes thereby causing the conductivity of a PDI-linked gold nanoparticle array on mica to decrease to act as a chemicallymore »drive molecular switch. This simple system enables the adsorption process to be explored in detail. DFT calculations reveal that both the —(Au–PDI)n— oligomer chain and the Au–PDI adatom complex are stabilized by coadsorbed CO. A kinetic “foot-in-the-door” model is proposed in which fluctuations in PDI coordination allow CO to diffuse into the gap between gold adatoms to prevent the PDI from reattaching, thereby allowing additional CO to adsorb, to provide kinetic model for allosteric CO adsorption on PDI-covered gold.« less

  14. Controlled synthesis of concave tetrahedral palladium nanocrystals by reducing Pd(acac){sub 2} with carbon monoxide

    SciTech Connect (OSTI)

    Zhu, Hai; Chi, Quan; Zhao, Yanxi; Li, Chunya; Tang, Heqing; Li, Jinlin; Huang, Tao; Liu, Hanfan; Institute of Chemistry, Chinese Academy of Science, Beijing 100080

    2012-11-15

    Graphical abstract: By using CO as a reducing agent, uniform and well-defined concave tetrahedral Pd nanocrystals were successfully synthesized. CO flow rate was the most essential for the formation of the concave tetrahedral nanostructures. The morphologies and sizes of the final products can be well controlled by adjusting the flow rate of CO. Highlights: ? By using CO as a reducing agent, concave tetrahedral Pd nanocrystals were obtained. ? CO flow rate is critical to the formation of concave tetrahedral Pd nanocrystals. ? The selective adsorption of CO on (1 1 0) facets is essential to concave Pd tetrahedra. -- Abstract: CO reducing strategy to control the morphologies of palladium nanocrystals was investigated. By using CO as a reducing agent, uniform and well-defined concave tetrahedral Pd nanocrystals with a mean size of about 55 ± 2 nm were readily synthesized with Pd(acac){sub 2} as a precursor and PVP as a stabilizer. The structures of the as-prepared Pd nanocrystals were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), ultraviolet–visible (UV–vis) absorption spectroscopy and electrochemical measurements. The results demonstrated that CO was the most essential for the formation of the concave tetrahedral Pd nanostructures. The morphologies and sizes of the final products can be well controlled by adjusting the flow rate of CO. The most appropriate CO flow rate, temperature and time for the formation of the ideal concave tetrahedral Pd nanocrystals was 0.033 mL s{sup ?1}, 100 °C and 3 h, respectively.

  15. Adsorption and Co-adsorption of Ethylene and Carbon Monoxide on Silica-Supported Monodisperse Pt Nanoparticles: Volumetric

    E-Print Network [OSTI]

    Yang, Peidong

    on the poisoning of the heterogeneously catalyzed conversion of hydrocarbons. 1. Introduction Lateral interactions conventional theory, such as Langmuir-Hinshelwood hetero- geneous kinetics.1,2 Interactions between adsorbates roughness (nano- particle size) on adsorbate-adsorbate interactions is important. Conventional theories

  16. Zirconia-based potentiometric sensor using a pair of oxide electrodes for selective detection of carbon monoxide

    SciTech Connect (OSTI)

    Miura, Norio; Raisen, Takahisa; Lu, Geyu; Yamazoe, Noboru

    1997-07-01

    A high-performance solid-state compact gas sensor to detect CO has been needed for monitoring and controlling the combustion condition of gas appliances. By using a pair of oxide electrodes, a stabilized-zirconia-based sensor was developed for selective detection of CO at high temperature. Among the oxide pair examined, the combination of CdO and SnO{sub 2} was best suited for the electrode couple, giving quick and selective response to CO in air at 600 C. The 90% response and the 90% recovery times of the sensor to 200 ppm CO was as short as ca. 8 and 10 s, respectively, at 600 C. The EMF value was linearly related with the logarithm of CO concentration in the range of 20 to 4,000 ppm. Moreover, the cross-sensitivities to other gases, such as H{sub 2}, NO, NO{sub 2}, CO{sub 2}, O{sub 2}, and H{sub 2}O, were small or insignificant.

  17. GALLIUM NITRIDE INTEGRATED GAS/TEMPERATURE SENSORS FOR FUEL CELL SYSTEM MONITORING FOR HYDROGEN AND CARBON MONOXIDE

    E-Print Network [OSTI]

    GALLIUM NITRIDE INTEGRATED GAS/TEMPERATURE SENSORS FOR FUEL CELL SYSTEM MONITORING FOR HYDROGEN on field effect devices using catalytic metal gates on silicon carbide substrates has been reviewed (Spetz) and prototype silicon carbide (SiC) FET based sensors show enhanced sensitivity at high temperature

  18. Carbon monoxide oxidation on bare and Pt-modified Ru(1010) and Ru(0001) single crystal electrodes

    E-Print Network [OSTI]

    Brankovic, Stanko R.

    1010-01-01

    S.R. Brankovic a , N.S. Marinkovic b , J.X. Wang a , R.R. Adzic´ a, * a Materials Science Department

  19. Design and Development of a Mid-Infrared Carbon Monoxide Sensor for a High-Pressure Combustor Rig 

    E-Print Network [OSTI]

    Camou, Alejandro

    2014-05-03

    concentration can be reduced by eliminating condensation within the gas lines. The sensor also proved to capture the fuel flow variations while showing room for improvement in the broadening behavior. These tests using direct absorption spectroscopy (DAS...

  20. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  1. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    combustion thus increase emissions of carbon monoxide andand carbon monoxide may also be generated from combustion and

  2. The Cost of Crop Damage Caused by Ozone Air Pollution From Motor Vehicles

    E-Print Network [OSTI]

    Murphy, James; Delucchi, Mark; McCubbin, Donald; Kim, H.J.

    1999-01-01

    Effects of Motor-Vehicle Air Pollution. UCD-ITS-RR-96-3 (by Ozone Air Pollution from Motor-Vehicles. UCD- ITS-RR-96-by ozone air pollution from motor vehicles J. J. Murphy†?,

  3. Past changes in the vertical distribution of ozone – Part 3: Analysis and interpretation of trends

    E-Print Network [OSTI]

    Harris, N. R. P.; Hassler, B.; Tummon, F.; Bodeker, G. E.; Hubert, D.; Petropavlovskikh, I.; Steinbrecht, W.; Anderson, J.; Bhartia, P. K.; Boone, C. D.; Bourassa, A.; Davis, S. M.; Degenstein, D.; Delcloo, A.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Jones, N.; Kurylo, M. J.; Kyrölä, E.; Laine, M.; Leblanc, S. T.; Lambert, J.-C.; Liley, B.; Mahieu, E.; Maycock, A.; de Mazière, M.; Parrish, A.; Querel, R.; Rosenlof, K. H.; Roth, C.; Sioris, C.; Staehelin, J.; Stolarski, R. S.; Stübi, R.; Tamminen, J.; Vigouroux, C.; Walker, K.; Wang, H. J.; Wild, J.; Zawodny, J. M.

    2015-03-23

    Trends in the vertical distribution of ozone are reported and compared for a number of new and recently revised datasets. The amount of ozone-depleting compounds in the stratosphere (as measured by Equivalent Effective Stratospheric Chlorine – EESC...

  4. Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films...

    Office of Scientific and Technical Information (OSTI)

    Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Citation Details In-Document Search Title: Ozone-Based Atomic Layer...

  5. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01

    C. Ozone deposition velocities, reaction probabilities andreaction phenomena described by a single parameter, the ozone deposition velocity,velocity, v t (m h ?1 ), a characteristic of the ?uid mechanics of a space, and the reaction

  6. Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...

    Energy Savers [EERE]

    Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

  7. A global inventory of ecosystem sources of methyl bromide, an ozone destroying gas 

    E-Print Network [OSTI]

    Fenney, Gareth

    2008-12-11

    Stratospheric ozone depletion is affected by halogen radicals, such as bromine, which is 40 times more effective at depleting ozone than chlorine. Methyl bromide, the largest contributor of bromine to the stratosphere is ...

  8. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F.

    2007-05-15

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  9. Effects of ozone cooling in the tropical lower stratosphere and upper troposphere

    E-Print Network [OSTI]

    Effects of ozone cooling in the tropical lower stratosphere and upper troposphere Piers M. Forster lower stratosphere and upper troposphere and elucidate the key role of ozone changes in driving of tropical ozone decreases at 70 hPa and lower pressures can lead to significant cooling not only

  10. THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING BAYESIAN MODELS

    E-Print Network [OSTI]

    West, Mike

    THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING University. The authors thank Alex Guenther for supplying the high frequency ozone concentration measurements a multiscale Bayesian model for separating ozone (O 3 ) concentration turbulent fluctuations from such inherent

  11. EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH

    E-Print Network [OSTI]

    McKendry, Ian

    EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH, hourly average ozone concentrations were mea- sured at three sites of differing elevation (188, 588. Sites experienced ozone concentrations ranging from 0 to 88 ppb in 2001, and 0 to 96 ppb in 2002. Daily

  12. Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend

    E-Print Network [OSTI]

    Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend W. J. Collins, R of circulation changes in a changed climate on the exchange of ozone between the stratosphere and the troposphere. We have identified an increase in the net transport of ozone into the troposphere in the future

  13. The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation

    E-Print Network [OSTI]

    Waugh, Darryn W.

    The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation Luke D impact on tropospheric circulation causes significant changes to the distribution of ozone. Here we derive the lower tropospheric to lower stratospheric ozone response to ENSO from observations

  14. How Bromate and Ozone Concentrations can be Modelled at Full Scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 How Bromate and Ozone Concentrations can be Modelled at Full Scale based on Lab-Scale Experiments ­ A Case Study Running head title How to model bromate & ozone at full scale based on lab tests Pierre-scale modelling study of an industrial ozonation unit for practical application. The modelling framework combines

  15. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  16. Technical note Barriers and opportunities for passive removal of indoor ozone

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Technical note Barriers and opportunities for passive removal of indoor ozone Elliott T. Gall presents a Monte Carlo simulation to assess passive removal materials (PRMs) that remove ozone of homes in Houston, Texas, were taken from the literature and combined with back- ground ozone removal

  17. Ground-level ozone in the 21st century: future trends,

    E-Print Network [OSTI]

    Ground-level ozone in the 21st century: future trends, impacts and policy implications October 2008. Courtesy of Dr Mhairi Coyle, CEH Edinburgh. #12;Ground-level ozone in the 21st century: future trends Limited #12;Ground-level ozone in the 21st century I October 2008 I iiiThe Royal Society Ground

  18. Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone

    E-Print Network [OSTI]

    Barthelat, Francois

    Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated) to investigate the sludge reduction potential of partially ozonating sludge return activated sludge (RAS

  19. 1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.

    E-Print Network [OSTI]

    Crambes, Christophe

    Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

  20. Separating the Influence of Halogen and Climate Changes on Ozone Recovery in the Upper Stratosphere

    E-Print Network [OSTI]

    causes ozone destruction by enhancing production of water vapor via methane oxidation. Additionally. Including potential climate-induced stratospheric water vapor increases, the ozone change relative to 1980 depletion chemistry, and therefore indirectly leading to more ozone. Increases in methane directly affect

  1. Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a)

    E-Print Network [OSTI]

    Reid, Scott A.

    Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a) Brian K for an anomalous isotope effect in ozone formation is given in terms of the energy transfer mechanism, where the metastable states of ozone are formed first, and then stabilized by collisions with other atoms. Unusual

  2. A review of statistical methods for the meteorological adjustment of tropospheric ozone

    E-Print Network [OSTI]

    Washington at Seattle, University of

    A review of statistical methods for the meteorological adjustment of tropospheric ozone Mary Lou adjustment of tropospheric ozone Mary Lou Thompson1 Joel Reynolds1 Lawrence H. Cox2 Peter Guttorp1 Paul D.larry@epamail.epa.gov ABSTRACT: A variety of statistical methods for meteorological adjustment of ozone have been proposed

  3. Ozone deposition to an orange orchard: Partitioning between stomatal and non-stomatal sinks

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone deposition to an orange orchard: Partitioning between stomatal and non-stomatal sinks Silvano January 2012 Keywords: Orange plants Ozone flux Stomatal deposition Non-stomatal deposition BVOC a b s t r a c t Orange trees are widely cultivated in regions with high concentrations of tropospheric ozone

  4. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. , NO. , PAGES 1?? , Analysis of 19701995 Trends in Tropospheric Ozone at

    E-Print Network [OSTI]

    Jacob, Daniel J.

    in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS­CHEM Model Andrew C. Fusco Department. The causes of trends in tropospheric ozone at Northern Hemisphere mid­ latitudes from 1970 to 1995 to investigate the sensitivity of tropospheric ozone with respect to (1) changes in the anthropogenic emission

  5. Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery Article Published.G. and Ravishankara, A.R. (2009) Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery's research outputs online #12;Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery J. F

  6. A Comparison of Bayesian and Conditional Density Models in Probabilistic Ozone Forecasting

    E-Print Network [OSTI]

    Hsieh, William

    A Comparison of Bayesian and Conditional Density Models in Probabilistic Ozone Forecasting Song Cai to provide predictive distributions of daily maximum surface level ozone concentrations. Five forecast models forecasts for extreme events, namely poor air quality events defined as having ozone concentration 82 ppb

  7. Projections of UV radiation changes in the 21st century: impact of ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Projections of UV radiation changes in the 21st century: impact of ozone recovery and cloud effects radiation changes in the 21st century: impact of ozone recovery and cloud effects. Atmospheric Chemistry Chemistry and Physics Projections of UV radiation changes in the 21st century: impact of ozone recovery

  8. ATOC/CHEM 5151 Problem 10 Energetics of the Photolysis of Ozone

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC/CHEM 5151 ­ Problem 10 Energetics of the Photolysis of Ozone Answers will be posted Thursday, October 9, 2014 Photolysis of ozone is important in the formation of the OH radical throughout much standard enthalpy tables to determine the bond strength of ozone (i.e., heat of reaction O + O2 O3) 105 k

  9. Quantifying stratospheric ozone response to changes in methane and nitrous oxide

    E-Print Network [OSTI]

    Bourqui, Michel

    Quantifying stratospheric ozone response to changes in methane and nitrous oxide concentrations of Ozone destruction and creation at different altitudes and concentrations of CH4 and N2O #12;Contents levels have varying conditions and are governed by different chemical regimes We will simulate ozone

  10. Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002

    E-Print Network [OSTI]

    Thompson, Anne

    Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002 R. D the characteristic Southern Hemisphere springtime tropospheric ozone maximum, but its seasonal features are modulated anticyclonic gyre over southern Africa permit the buildup of relatively high springtime midtropospheric ozone

  11. Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun

    E-Print Network [OSTI]

    Folkins, Ian

    Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun Department] The climatological ozone profile in the tropics is shaped like an ``S,'' with a minimum at the surface, a maximum. These features can be reproduced by a very simple model whose only free parameter is the mean ozone mixing ratio

  12. PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on

    E-Print Network [OSTI]

    PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone. Kelly*1 The corrosion of Ag in an atmosphere of ozone and humidity with or without irradiation corrosion product to chloride in the reduction solution. The presence of both ozone and UV radiation

  13. Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone treatment

    E-Print Network [OSTI]

    Parikh, Atul N.

    Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone (structure code: MFI) following a previously published procedure. The films were illuminated using an ozone. Results presented here indicate that the UV/ozone treatment under nominally room temperature conditions

  14. Evaluating Ozone Air Pollution Effects on Pines in the Western United States

    E-Print Network [OSTI]

    Evaluating Ozone Air Pollution Effects on Pines in the Western United States United States. Evaluating ozone air pollution effects on pines in the western United States. Gen. Tech. Rep. PSW­GTR­155. Historical and technical background is provided about ozone air pollution effects on ponderosa (Pinus

  15. Ensemble-based air quality forecasts: A multimodel approach applied to ozone

    E-Print Network [OSTI]

    Mallet, Vivien

    Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1 21 September 2006. [1] The potential of ensemble techniques to improve ozone forecasts ozone-monitoring networks. We found that several linear combinations of models have the potential

  16. The potential to narrow uncertainty in projections of stratospheric ozone over the

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    The potential to narrow uncertainty in projections of stratospheric ozone over the 21st century of stratospheric ozone over the 21st century. Atmospheric Chemistry and Physics, 10 (19). pp. 9473-9486. ISSN 1680 of stratospheric ozone over the 21st century A. J. Charlton-Perez1, E. Hawkins1, V. Eyring2, I. Cionni2, G. E

  17. Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY

    E-Print Network [OSTI]

    Jackman, Charles H.

    Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY G; revised 4 May 2005; accepted 13 May 2005; published 20 August 2005. [1] We use atmospheric ozone density profiles between 35 and 65 km altitude derived from SCIAMACHY limb measurements to quantify the ozone

  18. Ozone database in support of CMIP5 simulations: results and corresponding

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing Article., Bodeker, G.E., Shepherd, T.G., Shindell, D.T. and Waugh, D.W. (2011) Ozone database in support of CMIP5 and Physics Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing I

  19. Smoothing Parameter Selection When Errors are Correlated and Application to Ozone Data

    E-Print Network [OSTI]

    Heckman, Nancy E.

    Smoothing Parameter Selection When Errors are Correlated and Application to Ozone Data by Robert Jr trend of daily and monthly ground ozone levels in southern Ontario. iii #12; Contents Abstract ii.2 Air Pollution Data . . . . . . . . . . . . . . . . . . . . . . . . 79 5.2.1 Daily Ozone Data . . . . . . . . . . . . . . . . . . .

  20. Nighttime secondary ozone layer during major stratospheric sudden warmings in specified-dynamics WACCM

    E-Print Network [OSTI]

    Limpasuvan, Varavut

    Nighttime secondary ozone layer during major stratospheric sudden warmings in specified to the thermosphere. Currently, the role of atmospheric dynamics on polar ozone in the mesosphere-lower thermosphere "secondary" (90­105 km) ozone maximum by examining the dynamics and distribution of key species (like H and O

  1. Impact of Antarctic Ozone Depletion and Recovery on Southern Hemisphere Precipitation, Evaporation, and Extreme Changes

    E-Print Network [OSTI]

    Son, Seok-Woo

    Impact of Antarctic Ozone Depletion and Recovery on Southern Hemisphere Precipitation, Evaporation) ABSTRACT The possible impact of Antarctic ozone depletion and recovery on Southern Hemisphere (SH) mean- tercomparison Project 3 (CMIP3). By grouping models into four sets, those with and without ozone depletion

  2. Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations

    E-Print Network [OSTI]

    Liu, Hongyu

    Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations ozone over the Asian Pacific Rim in different seasons are quantified by analysis of Hong Kong at midlatitudes from fall at low latitudes due to monsoonal influence. The UT ozone minimum and high variability

  3. Analytica Chimica Acta 573574 (2006) 913 Metal oxide thin films as sensing layers for ozone detection

    E-Print Network [OSTI]

    2006-01-01

    Analytica Chimica Acta 573­574 (2006) 9­13 Metal oxide thin films as sensing layers for ozone. Their structural, electrical and ozone sensing properties were analyzed. Structural investigations carried out with ultraviolet light and subsequent oxidation in ozone atmosphere at room temperature. © 2006 Elsevier B.V. All

  4. Low ozone concentrations over Macquarie Island during 1997. Part I: trajectory analysis

    E-Print Network [OSTI]

    Cordero, Eugene

    Low ozone concentrations over Macquarie Island during 1997. Part I: trajectory analysis by Eugene C instruments show record low ozone column densities between 20°S and 60°S throughout 1997. The monthly averaged record from the Total Ozone Mapping Spectrometer (TOMS) indicates that measurements from 1997 are lower

  5. Ozone ensemble forecast with machine learning Vivien Mallet,1,2

    E-Print Network [OSTI]

    Mallet, Vivien

    Ozone ensemble forecast with machine learning algorithms Vivien Mallet,1,2 Gilles Stoltz,3; published 13 March 2009. [1] We apply machine learning algorithms to perform sequential aggregation of ozone forecasts. The latter rely on a multimodel ensemble built for ozone forecasting with the modeling system

  6. Efficient quantum-classical method for computing thermal rate constant of recombination: Application to ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    : Application to ozone formation Mikhail V. Ivanov and Dmitri Babikov Citation: J. Chem. Phys. 136, 184304 (2012 for computing thermal rate constant of recombination: Application to ozone formation Mikhail V. Ivanov of ozone. Comparison of the predicted rate vs. experimental result is presented. © 2012 American Institute

  7. Conditional quantiles when the covariates are curves : an application to Ozone pollution

    E-Print Network [OSTI]

    Bercu, Bernard

    Conditional quantiles when the covariates are curves : an application to Ozone pollution forecasting Summary This work deals with the study of pollution data with the aim of forecas- ting the Ozone of the maximum of Ozone one day kno- wing one or several of these functional variables the day before. To do this

  8. Semiclassical wave packet study of anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Semiclassical wave packet study of anomalous isotope effect in ozone formation Evgeny Vetoshkin represent the metastable O3 * species and play a central role in the process of ozone formation.1063/1.2778432 I. INTRODUCTION Ozone O3 is formed in the stratosphere as a product of the following recombination

  9. Seedling insensitivity to ozone for three conifer species native to Great Smoky Mountains National Park$

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seedling insensitivity to ozone for three conifer species native to Great Smoky Mountains National concentrations of ozone had little eect on seedlings of three species of conifers commonly found in Great Smoky Mountains National Park. Abstract Field symptoms typical of ozone injury have been observed on several

  10. Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air Purifiers

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air ozone (O3) during operation, either in- tentionally or as a byproduct of air ionization standards. Sev- eral types of air purifiers were tested for their ability to produce ozone in various indoor

  11. The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest

    E-Print Network [OSTI]

    Collins, Gary S.

    The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest also acts as an antioxidant within a plant, reacting and neutralizing ozone and peroxides, though , and reacts photochemically in the presence of NOx to produce tropospheric ozone. The Model of Emissions

  12. Seasonal persistence of northern low-and middle-latitude anomalies of ozone and

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases) Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases outputs online #12;Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other

  13. Impact of long-range correlations on trend detection in total ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of long-range correlations on trend detection in total ozone Article Published Version detection in total ozone. Journal of Geophysical Research, 112. D14307. ISSN 0148-0227 doi: 10.1029/2006JD of long-range correlations on trend detection in total ozone Dmitry I. Vyushin,1 Vitali E. Fioletov,2

  14. Semiclassical molecular dynamics simulations of ultrafast photodissociation dynamics associated with the Chappuis band of ozone

    E-Print Network [OSTI]

    Miller, William H.

    with the Chappuis band of ozone Victor S. Batista and William H. Millera) Department of Chemistry, University A ) of ozone following photoexcitation of the molecule in the gas phase with visible light. Our algorithm and recurrence events, as well as an interpretation of experimental studies of the Chappuis band of ozone

  15. LOT-G3: Plasma Lamp, Ozonator and CW transmitter

    E-Print Network [OSTI]

    Gobato, Ricardo; Gobato, Alekssander

    2015-01-01

    The LOT-G3 is designed to be a versatile equipment that perform several simple experiments for use in helping the physics classes for high school. Easy construction, low cost, using easily accessible materials. Its construction involves simple practices and knowledge of electromagnetism. It has the function of a plasma globe to demonstrate the ionization of a low pressure gas, as well as the formation of magnetic field. Can be used as sanitizer closed environments such as automotive vehicles in ozonator function, demonstrating the ionization of oxygen in the atmosphere, producing ozone, essential to life on earth. And as a sparks transmitter, low power, low frequency modulated continuous wave in (CW), for signals in Morse code. Therefore the equipment here called LOT-G3, has three functions: a plasma lamp, ozonator and CW transmitter.

  16. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V.; Gordon, C.J.; Jarema, K.A.; MacPhail, R.C.; Cascio, W.E.; Phillips, P.M.; Ledbetter, A.D.; Schladweiler, M.C.; Andrews, D.; Miller, D.; Doerfler, D.L.; Kodavanti, U.P.

    2013-12-15

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  17. The HIPPO (HIAPER Pole-to-Pole Observations) study of the carbon cycle and greenhouse gases measured meteorology, atmospheric chemistry, and aerosol constituents along transects from approximately pole-to-pole

    E-Print Network [OSTI]

    .) · Ancillary flight information, field catalogs, data quality reports, software, and documentation · Pole products and user documentation. Files are in ASCII text format. Products include: · A comprehensive merged structure data: 1) greenhouse gases and carbon cycle gases, 2) ozone and water vapor, 3) black carbon

  18. Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a,*, Daniel J. Jacob a,b

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a Accepted 23 May 2011 Keywords: Air quality Ozone Kalman filter Assimilation Remote sensing a b s t r a c satellite measurements of ozone in different spectral regions to constrain surface ozone concentrations

  19. Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great by symptoms of foliar ozone injury. Abstract The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts

  20. Combined Crossed Molecular Beam and Ab Initio Investigation of the Reaction of Boron Monoxide (BO; X2

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    ; X2 + ) with 1,3-Butadiene (CH2CHCHCH2; X1 Ag) and Its Deuterated Counterparts Surajit Maity, Beni B Information ABSTRACT: The reactions of the boron monoxide (11 BO; X2 + ) radical with 1,3- butadiene (CH2CHCHCH2; X1 Ag) and its partially deuterated counterparts, 1,3- butadiene-d2 (CH2CDCDCH2; X1 Ag) and 1

  1. Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch

    SciTech Connect (OSTI)

    A. Blutke; B.C. Stratton; D.R. Mikkelsen; J. Vavruska; R. Knight

    1998-01-01

    The technical feasibility of using an induction-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz and ~11 kVA with an argon/oxygen mixture as the plasma-forming gas. A gaseous oxygen quench formed ozone by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in the reaction chamber was measured by Fourier Transform infrared (FTIR) spectroscopy over a wide range of experimental configurations. The geometry of the quench gas flow, the quench flow velocity, and the quench flow rate played important roles in determining the ozone concentration. The ozone concentration was sensitive to the torch RF power, but was insensitive to the torch gas flow rates. These observations are interpreted within the framework of a simple model of ozone synthesis.

  2. Massive global ozone loss predicted following regional nuclear conflict

    E-Print Network [OSTI]

    Robock, Alan

    that nuclear war could be winnable, and preceded the first significant reductions in nuclear weapons stockpiles, the proliferation of nuclear weapons has produced greater risks of a regional nuclear conflict. At the same timeMassive global ozone loss predicted following regional nuclear conflict Michael J. Mills* , Owen B

  3. Design and Usage of an Ozone Mapping App Ilyas Uyanik

    E-Print Network [OSTI]

    design, pollution visualiza- tion, air quality monitoring, ozone, user studies Permission to make digital-time, quantitative, and localized pollutant information has become available for a few big cities. Several mobile to conventional weather report- ing systems that provide a qualitative and static description of pollutant levels

  4. Tropospheric ozone over the North Pacific from ozonesonde observations

    E-Print Network [OSTI]

    Liu, Hongyu

    of urban air pollution. At sites in the mid and eastern Pacific the signature of transport of polluted air, Tsukuba, and Sapporo, Japan), a site in the central Pacific (Hilo, Hawaii), and a site on the west coast very high mixing ratios of ozone were observed that result from pollution transport from China

  5. EARTH OBSERVATION 400M Indians Endangered By Ozone

    E-Print Network [OSTI]

    Singh, Ramesh P.

    has been linked to increases in skin cancer rates. All rights reserved. © 2004 United Press using satellite and limited ground observations, the Press Trust of India reported Tuesday. The rate the reasons for the depletion, th e report states. Ozone is an important atmospheric trace gas that blocks

  6. Validation of satellite ozone profile retrievals using Beijing ozonesonde data

    E-Print Network [OSTI]

    Pan, Laura

    , the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua satellite and the Microwave Limb Sounder (MLS in the stratosphere and troposphere. Stratospheric ozone forms a protective layer that absorbs enough solar) on the NASA Aqua satellite [Aumann et al., 2003] and the Microwave Limb Sounder (MLS) on the NASA Aura

  7. Search for the electric dipole moment of the electron with thorium monoxide

    E-Print Network [OSTI]

    Amar C. Vutha; Wesley C. Campbell; Yulia V. Gurevich; Nicholas R. Hutzler; Maxwell Parsons; David Patterson; Elizabeth Petrik; Benjamin Spaun; John M. Doyle; Gerald Gabrielse; David DeMille

    2010-11-06

    The electric dipole moment of the electron (eEDM) is a signature of CP-violating physics beyond the Standard Model. We describe an ongoing experiment to measure or set improved limits to the eEDM, using a cold beam of thorium monoxide (ThO) molecules. The metastable $H {}^3\\Delta_1$ state in ThO has important advantages for such an experiment. We argue that the statistical uncertainty of an eEDM measurement could be improved by as much as 3 orders of magnitude compared to the current experimental limit, in a first-generation apparatus using a cold ThO beam. We describe our measurements of the $H$ state lifetime and the production of ThO molecules in a beam, which provide crucial data for the eEDM sensitivity estimate. ThO also has ideal properties for the rejection of a number of known systematic errors; these properties and their implications are described.

  8. TES Observations duringTES Observations during Texas Air Quality Study IITexas Air Quality Study II

    E-Print Network [OSTI]

    mb ofthe surface to .01 mb of temperature, water, ozone,temperature, water, ozone, carbon monoxide Spectral Radiance)Radiance) 2B1 filter: 700 nW/cm2B1 filter: 700 nW/cm22 /sr/cm/sr/cm--11 1B2 filter: 2001B2 filter: 200 2A1 filter: 1502A1 filter: 150 1A1 filter: 1001A1 filter: 100 Nadir NEDT @290KNadir

  9. The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone

    E-Print Network [OSTI]

    Dominici, Francesca

    and applied several statistical models to data on air pollution, weather, and mortality for 98 U.S. urban mortality. Interventions to further reduce ozone pollution would benefit public health, even in regions pollutant linked to numerous harmful health effects, including reduced lung function, increased frequency

  10. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  11. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  12. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  13. Atmos. Chem. Phys., 9, 80498060, 2009 www.atmos-chem-phys.net/9/8049/2009/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ) and particulate mercury (HgP ) along with carbon monoxide (CO), ozone (O3), aerosols, and meteorological variables. The mean mercury concentrations were 1.6 ng m-3 (GEM), 20 pg m-3 (RGM) and 9 pg m-3 (HgP ). We observed chloride) denuders, and particulate-bound mercury (HgP ) which are trapped by quartz-fiber filters. RGM

  14. WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos

    E-Print Network [OSTI]

    Paulos, Eric

    and health from people who are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide

  15. WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos

    E-Print Network [OSTI]

    Chen, Yiling

    are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

  16. DiscussionPaper|DiscussionPaper|DiscussionPaper|DiscussionPaper| Atmos. Chem. Phys. Discuss., 11, 681744, 2011

    E-Print Network [OSTI]

    zonal gradients in mean MBL sub-micron aerosol particle size and composition, carbon10 monoxide, ozone and sulphur dioxide were seen over the campaign, with a generally more variable and polluted coastal layer airmasses having been in recent contact with the local land surface and remote maritime airmasses

  17. Modeling Air Quality Near Freeways Using a Three Dimensional Eulerian Model 

    E-Print Network [OSTI]

    Kota, Sri Harsha

    2010-10-12

    experiment, conducted at Michigan in 1976. Sensitivity of the model to meteorology and traffic-related parameters are studied in detail. In the second case, the spatial distribution of ozone, carbon monoxide, NOx and 1,3-Butadiene near a simulated 8-lane...

  18. Atmos. Chem. Phys., 12, 815828, 2012 www.atmos-chem-phys.net/12/815/2012/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Abstract. Carbon monoxide (CO) and ozone (O3) have been measured in the Western Pacific (43 N to 35 S) dur fossil fuel combustion in Asia is the dominant source. European and North American fossil fuel combustion biomass burning and fossil fuel combustion are dominant; African biomass burning has a significant impact

  19. Atmos. Chem. Phys., 9, 35473562, 2009 www.atmos-chem-phys.net/9/3547/2009/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    and transport). 1 Introduction Atmospheric carbon monoxide (CO) is a product of incom- plete combustion as well reac- tion with OH. Atmospheric CO is a precursor of tropospheric ozone (O3) and, as a combustion product, provides a useful proxy for combustion-related emissions of other precursors of tropospheric O3

  20. CitiSense Adaptive Services for Community-Driven Behavioral and Environmental Monitoring to Induce

    E-Print Network [OSTI]

    Simunic, Tajana

    times nor at equal risk for asthma or other harmful consequences of air pollution. What if everyday RI³FLWL]HQ LQIUDVWUXFWXUH´ for the monitoring of pollution and environmental conditions that users by users, data about pollutants such as ozone and carbon monoxide is collected and used to provide real

  1. Page 2 of 4 TREE Cookies Etc. Trees & Air-continued

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    #12;Page 2 of 4 TREE Cookies Etc. Trees & Air- continued pollutants include ozone, sulfur dioxide of trees on air pollution. The research on trees and air pollution is rather new and still ongoing, nitrogen dioxide, and carbon monoxide. These are taken out of the air by trees primarily through leaf

  2. Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies Rula A. Deeb1 ; Jonathan with Federal Clean Air Act requirements for carbon monoxide and ozone attainment, ethanol is being considered as a replacement for MTBE. The objective of this study is to evaluate the potential impact of ethanol on benzene

  3. Sum frequency generation and catalytic reaction studies of the removal of the organic capping agents from Pt nanoparticles by UV-ozone treatment

    E-Print Network [OSTI]

    Aliaga, Cesar

    2010-01-01

    and (b) after 2 hours of UV/ozone treatment. (a) 50nm (b)a) before and (b) after UV/ozone treatment for 270 minutes.from Pt nanoparticles by UV-ozone treatment Cesar Aliaga, †

  4. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 91, NO. D1, PAGES 1103-1116, JANUARY 20, 1986 Two-Dimensional Monthly Average Ozone BalanceFrom

    E-Print Network [OSTI]

    Jackman, Charles H.

    -Dimensional Monthly Average Ozone BalanceFrom Limb Infrared Monitor of the Stratosphereand Stratosphericand consistency.We computethe diurnal averagephotochemicalproductionand lossterms of ozone usingmonthly ozone,whichisthelossrate by thechlorinefamily,iscalculatedfroma two

  5. Carbon particles

    DOE Patents [OSTI]

    Hunt, Arlon J. (Oakland, CA)

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  6. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  7. Meeting the New Ozone Standard: Challenges and Opportunities

    Broader source: Energy.gov [DOE]

    This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

  8. The Cost of Crop Damage Caused by Ozone Air Pollution From Motor Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark A.; Murphy, James; Kim, Jin; McCubbin, Donald R.

    1996-01-01

    without motor-vehicle related pollution. This diagram is forBY OZONE AIR POLLUTION FROM MOTOR VEHICLES Report #12 in thePOLLUTION FROM MOTOR VEHICLES

  9. Seasonal and Diurnal Variations of Ozone near the Mesopause from Observations of the 11.072-GHz Line

    E-Print Network [OSTI]

    Pratap, P.

    Ground-based observations of the 11.072-GHz line of ozone were made from January 2008 through January 2009. These observations provide an estimate of the diurnal and seasonal variations of ozone in the mesopause region. ...

  10. Predicted Abundances of Carbon Compounds in Volcanic Gases on Io

    E-Print Network [OSTI]

    Laura Schaefer; Bruce Fegley Jr

    2004-09-17

    We use chemical equilibrium calculations to model the speciation of carbon in volcanic gases on Io. The calculations cover wide temperature (500-2000 K), pressure (10^-8 to 10^+2 bars), and composition ranges (bulk O/S atomic ratios \\~0 to 3), which overlap the nominal conditions at Pele (1760 K, 0.01 bar, O/S ~ 1.5). Bulk C/S atomic ratios ranging from 10^-6 to 10^-1 in volcanic gases are used with a nominal value of 10^-3 based upon upper limits from Voyager for carbon in the Loki plume on Io. Carbon monoxide and CO2 are the two major carbon gases under all conditions studied. Carbonyl sulfide and CS2 are orders of magnitude less abundant. Consideration of different loss processes (photolysis, condensation, kinetic reactions in the plume) indicates that photolysis is probably the major loss process for all gases. Both CO and CO2 should be observable in volcanic plumes and in Io's atmosphere at abundances of several hundred parts per million by volume for a bulk C/S ratio of 10^-3.

  11. Observational constraints on the global atmospheric budget of ethanol

    E-Print Network [OSTI]

    2010-01-01

    relative to carbon monoxide (CO) for combustion of differentcarbon monoxide emissions (Poulopou- los et al. , 2001), their combustion

  12. Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region, induced by dynamic processes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region September 1998 / Revised: 25 January 1999 / Accepted: 26 January 1999 Abstract. The total ozone distribution before. A spatial pattern correlation between the zonally asymmetric part of total ozone

  13. Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2

    E-Print Network [OSTI]

    Wu, Shiliang

    1 Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2 3 the effect on China's ozone air quality from 2000-2050 global15 changes in climate and anthropogenic emissions of ozone precursors. The climate and16 emission effect in combination will increase afternoon mean

  14. LA RPARTITION DE L'OZONE ATMOSPHRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER.

    E-Print Network [OSTI]

    Boyer, Edmond

    LA RÉPARTITION DE L'OZONE ATMOSPHÉRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER. Observatoire observations en déter- minant la distribution de l'ozone par une série de Charlier du type A. En général on ne peut déterminer que la quantité totale d'ozone et la hauteur moyenne de la distribution, ces quantités

  15. Photodissociation of Ozone from 321 to 329 nm: The Relative Yields P2) with O2(X 3

    E-Print Network [OSTI]

    Houston, Paul L.

    Photodissociation of Ozone from 321 to 329 nm: The Relative Yields of O(3 P2) with O2(X 3 g - ), O2 Supporting Information ABSTRACT: Product imaging of O(3 P2) following dissociation of ozone has been used to determine the relative yields of the product channels O(3 P2) + O2(X 3 g - ) of ozone. All three channels

  16. Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH*. Nicolas MOSER**, Caroline CHARPENTIER*, Alexis MOQUET*,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH, Switzerland E-mail : Isabelle.Zdanevitch(a),iner is.fr (corresponding author) ABSTRACT Ozone is actually one by continuous monitors but a better information on ozone levels would be given by a denser monitoring network

  17. Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace

    E-Print Network [OSTI]

    Collins, Gary S.

    Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace been done to determine vertical ozone profiles, especially in environments such as the northern mixed forest where this field campaign is being run. What past research that has been done has shown that ozone

  18. Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis) in Great Smoky Mountains

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis ``Capsule'': Ground-level ozone causes deleterious effects to cutleaf coneflower and crown-beard in Great Smoky Mountains National Park. Abstract Incidence and severity of visible foliar ozone injury on cutleaf

  19. The Huggins band of ozone: Unambiguous electronic and vibrational Zheng-Wang Qu, Hui Zhu, Motomichi Tashiro, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: Unambiguous electronic and vibrational assignment Zheng-Wang Qu, Hui Zhu 12 February 2004; accepted 2 March 2004 The Huggins band of ozone is investigated by means of exact.1063/1.1711589 Because of the importance of ozone for the shielding of harmful UV light, its photophysics has been

  20. Rapid formation of molecular bromine from deliquesced NaBr aerosol in the presence of ozone and UV light

    E-Print Network [OSTI]

    Dabdub, Donald

    Rapid formation of molecular bromine from deliquesced NaBr aerosol in the presence of ozone and UV deliquesced NaBr aerosols in the presence of OH radicals produced by ozone irradiated by UV light, depending on the availability of ozone and bromide in the system. Interface reactions, an important source

  1. The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov; accepted 16 September 2004 The Huggins band of ozone is investigated by means of dynamics calculations American Institute of Physics. DOI: 10.1063/1.1814098 I. INTRODUCTION Because of the importance of ozone

  2. The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations on an accurate potential energy surface

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations present an ab initio potential energy surface for the ground electronic state of ozone. It is global, i. All bound states of nonrotating ozone up to more than 99% of the dissociation energy are calculated

  3. Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA

    E-Print Network [OSTI]

    Pan, Laura

    Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA) are used to examine the quality of the Atmospheric Infrared Sounder (AIRS) v4 vertical ozone profile range), AIRS ozone mixing ratios are larger than ozonesonde measurements, and at higher altitudes ($100

  4. Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core-Shell Morphologies

    E-Print Network [OSTI]

    Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core of oleic acid aerosol particles with ozone are studied below 1% relative humidity. The particles have inert of the organic layer is monitored with increasing ozone exposure by using an aerosol mass spectrometer

  5. 3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1

    E-Print Network [OSTI]

    3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1 Abstract Plants react biochemically to ozone in three phases: with constitutive chemicals in the apoplastic, plant reactions with ozone result in constitutive molecules such as the ozonolysis of ethylene

  6. A New Application of UV-Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin

    E-Print Network [OSTI]

    Parikh, Atul N.

    A New Application of UV-Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin room temperature photochemical method, simply employing ultraviolet light- (187-254 nm) generated ozone. The structures and compositions of the thin film mesophases before and after exposure to UV/ozone were determined

  7. Carbon investment funds

    SciTech Connect (OSTI)

    2007-01-15

    The report is a study of the development of funds to invest in the purchase of carbon credits. It takes a look at the growing market for carbon credits, the rise of carbon investment funds, and the current state of carbon investing. Topics covered in the report include: Overview of climate change, greenhouse gases, and the Kyoto Protocols. Analysis of the alternatives for reducing carbon emissions including nitrous oxide reduction, coal mine methane capture and carbon capture and storage; Discussion of the different types of carbon credits; Discussion of the basics of carbon trading; Evaluation of the current status of carbon investing; and Profiles of 37 major carbon investment funds worldwide.

  8. A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani

    E-Print Network [OSTI]

    Corani, Giorgio

    A neural emission-receptor model for ozone reduction planning S.Barazzetta, G. Corani , G- ulated areas. Ozone is produced by a series of photochemical reactions, activated by the emissions concen- trations are equally complex and cannot be directly used to optimize emission reduction policies

  9. Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution

    E-Print Network [OSTI]

    Thompson, Anne

    Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution Anne M of the southern African burning region were taken at Lusaka, Zambia (15.5S, 28E) in early September 2000. Maximum from trans- boundary recirculation. Starting out over Zambia, Angola, and Namibia, ozone-rich air

  10. White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure

    E-Print Network [OSTI]

    Collins, Gary S.

    White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure Daniel M on a large scale in forests. Monoterpene and sesquiterpene emissions from trees significantly contribute investigates the effect of an abiotic stress, specifically acute ozone exposure, on the terpene emissions

  11. Intercontinental source attribution of ozone pollution at western U.S. sites using an adjoint method

    E-Print Network [OSTI]

    Jacob, Daniel J.

    the history of air parcels reaching the site. MBO experiences distinct Asian ozone pollution episodes; most stringent air quality standards [Task Force on Hemispheric Transport of Air Pollution, 2007]. Ozone previously to pollutant transport to Hawaii [Vukic´evic´ and Hess, 2000; Hess and Vukic´evic´, 2003

  12. Thesis proposal CSF Brazil 2014 treatment of open pit mines wastewater by a coupled ozone technique

    E-Print Network [OSTI]

    Bordenave, Charles

    /or hydroxides such as MnO2 or Fe(OH)3. The disinfection power of ozone is also well known. Thus the efficiency of University of São Paulo (USP). It has more than 2000 installations in Brazil, Argentina and Peru, treating of new application of ozone permitting to support his growth. Powered by TCPDF (www.tcpdf.org) #12;

  13. Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations

    E-Print Network [OSTI]

    Jacob, Daniel J.

    1 Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations contributing to tropospheric ozone over the Asian Pacific Rim in different seasons are quantified by analysis influence along the Pacific Rim occurs in summer, reflecting rapid convective transport of surface pollution

  14. Formaldehyde columns from the Ozone Monitoring Instrument: Urban versus background levels and evaluation using aircraft

    E-Print Network [OSTI]

    Mlllet, Dylan B.

    Formaldehyde columns from the Ozone Monitoring Instrument: Urban versus background levels formaldehyde column (WHCHO) retrievals from the Ozone Monitoring Instrument (OMI) and assess the information (20­200 km) near many urban areas. Citation: Boeke, N. L., et al. (2011), Formaldehyde columns from

  15. Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2

    E-Print Network [OSTI]

    Weber, Rodney

    1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 and Chemistry EAS 6790 Fall 2006 Home Work Assignment No. 4, Ozone Chemistry Problems 11.8 and 11.9 (sub-part 1 and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

  16. The impact of large scale biomass production on ozone air pollution in Joost B. Beltman a

    E-Print Network [OSTI]

    Utrecht, Universiteit

    The impact of large scale biomass production on ozone air pollution in Europe Joost B. Beltman by up to 25% and 40%. Air pollution mitigation strategies should consider land use management. a r t i Poplar a b s t r a c t Tropospheric ozone contributes to the removal of air pollutants from

  17. Response of different-aged black cherry trees to ambient ozone exposure

    SciTech Connect (OSTI)

    Fredericksen, T.S.; Joyce, B.J.; Kouterick, K.B.; Kolb, T.E.; Skelly, J.M.; Steiner, K.C.; Savage, J.E.; Snyder, K.R. (Pennyslvania State Univ., Univ. Park, PA (United States))

    1994-06-01

    Black cherry (Prunus serotina Ehrh.) is a valuable commercial timber species which is also highly sensitive to ozone relative to other eastern deciduous tree species. Studies of ozone effects on forest trees have been restricted mostly to experiments using small seedlings under controlled conditions. Yet, mature trees may differ from seedlings in physiology, morphology, and exposure to air pollutants. An experiment was conducted in 1993 to determine differences in ozone uptake and foliar injury symptoms between open-ground seedlings, forest saplings, and mature forest trees of black cherry in northcentral Pennsylvania. Seedlings grew under the highest ozone concentrations and also had greater seasonal ozone uptake due to higher rates of stomatal conductance. However, because of their indeterminate growth habit, seedlings had lower cumulative ozone uptake per leaf lifespan than saplings or mature trees, both of which had determinate shoot growth. Although greater initially for seedlings, foliar injury was nearly identical between size classes by the end of the growing season. Leaves in the lower crown of larger trees had lower ozone uptake than leaves in the upper crown, but exhibited more foliar injury symptoms. Lower crown leaves received more effective exposure to ozone because of their thinner leaves and had less available photosynthate for repair or replacement of damaged tissue.

  18. Distinguishing the impacts of ozone-depleting substances and well-mixed greenhouse gases on Arctic stratospheric ozone and temperature trends

    E-Print Network [OSTI]

    Rieder, Harald E.

    Whether stratospheric cooling due to increases in well-mixed greenhouse gases (WMGHG) could increase the depletion of Arctic stratospheric ozone has been the subject of scientific and public attention for decades. Here we ...

  19. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P

    2012-09-18

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  20. Physical and Chemical Characterization of Particulate and Gas phase Emissions from Biomass Burning

    E-Print Network [OSTI]

    Hosseini, Seyedehsan

    2012-01-01

    carbon monoxide, and particulate emissions from the combustioncombustion of biomass is dominated by emissions of carbon dioxide (CO 2 ), carbon monoxide (carbon monoxide; EC/TC ratio is proposed as a better surrogate of combustion

  1. Indoor Air Quality in 24 California Residences Designed as High Performance Green Homes

    E-Print Network [OSTI]

    Less, Brennan

    2012-01-01

    incomplete combustion of carbon-based fuels. Carbon monoxideCombustion Appliance Zone California Energy Commission Central Fan Integrated Supply Cubic Feet per Minute Carbon Monoxide

  2. Maximizing Power Output in Homogeneous Charge Compression Ignition (HCCI) Engines and Enabling Effective Control of Combustion Timing

    E-Print Network [OSTI]

    Saxena, Samveg

    2011-01-01

    cylinder mode Carbon Monoxide (ppm) Combustion Timing,combustion timing, higher emission of hydrocarbons and carbon monoxideand carbon monoxide emissions increase with delays in combustion

  3. Pre-clinical Measures of Eye Damage (Lens Opacity), Case-control Study of Tuberculosis, and Indicators of Indoor Air Pollution from Biomass Smoke

    E-Print Network [OSTI]

    Pokhrel, Amod Kumar

    2010-01-01

    kerosene combustion include carbon monoxide, carbon dioxide,combustion releases a complex mixture of organic and inorganic compounds, such as fine particulates (PM2.5), carbon monoxide (

  4. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01

    Li, M. Daskin. 2009. Carbon Footprint and the Management ofThe Importance of Carbon Footprint Estimation Boundaries.Carbon accounting and carbon footprint - more than just

  5. Public Review Draft: A Method for Assessing Carbon Stocks, Carbon

    E-Print Network [OSTI]

    Public Review Draft: A Method for Assessing Carbon Stocks, Carbon Sequestration, and Greenhouse, and Zhu, Zhiliang, 2010, Public review draft; A method for assessing carbon stocks, carbon sequestration

  6. Carbon Fiber Consortium | Partnerships | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Fiber Consortium SHARE Carbon Fiber Consortium Oak Ridge Carbon Fiber Composites Consortium The Oak Ridge Carbon Fiber Composites Consortium was established in 2011 to...

  7. Material Safety Data Sheet According to 93/112/EC

    E-Print Network [OSTI]

    Wikswo, John

    Hazardous Combustion Products Thermal decomposition may emit carbon monoxide and carbon dioxide. Upper

  8. Rev. Date: 25-Aug-11 Art: 715023-00D Material Safety Data Sheet

    E-Print Network [OSTI]

    Wikswo, John

    Combustion Products Thermal decomposition may emit carbon monoxide and carbon dioxide. Upper Explosion Limit

  9. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  10. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    SciTech Connect (OSTI)

    Jin, Ling; Tonse, Shaheen; Cohan, Daniel S.; Mao, Xiaoling; Harley, Robert A.; Brown, Nancy J.

    2009-05-15

    CMAQ-HDDM is used to determine spatial and temporal variations in ozone limiting reagents and local vs upwind source contributions for an air pollution episode in Central California. We developed a first- and second- order sensitivity analysis approach with the Decoupled Direct Method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a five-day ozone episode (29th July-3rd Aug, 2000). Despite considerable spatial variations, nitrogen oxides (NO{sub x}) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8-hr ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1-hr ozone standard. Inter-basin source contributions of NO{sub x} emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NO{sub x} and AVOC, and the rate coefficient of the OH + NO{sub 2} termination reaction, have the greatest effect on first-order ozone responses to changes in NO{sub x} emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

  11. THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, Carol [Savannah River Site (SRS), Aiken, SC (United States). Savannah River Remediation, LLC; Osterberg, Paul [Fauske and Associates, LLC, Burr Ridge, IL (United States); Johnson, Tom [Fauske and Associates, LLC, Burr Ridge, IL (United States); Frawely, Thomas [Fauske and Associates, LLC, Burr Ridge, IL (United States)

    2013-01-23

    The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

  12. Photophysics of carbon nanotubes

    E-Print Network [OSTI]

    Samsonidze, Georgii G

    2007-01-01

    This thesis reviews the recent advances made in optical studies of single-wall carbon nanotubes. Studying the electronic and vibrational properties of carbon nanotubes, we find that carbon nanotubes less than 1 nm in ...

  13. Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production

    E-Print Network [OSTI]

    Narasayya, Vivek

    #12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

  14. TOC Total organic carbon MBC Microbial biomass carbon

    E-Print Network [OSTI]

    Virginia Tech

    C Carbon TOC Total organic carbon MBC Microbial biomass carbon Active C Pool Indicated by Light, the relationship between carbon dynamics including total organic carbon (TOC) storage, microbial biomass carbon and microbial biomass carbon in subsoil 4 years after rehabilitation · Microbial biomass carbon had a positive

  15. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

    1993-01-01

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  16. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  17. Air-Quality Data from NARSTO (North American Research Strategy for Tropospheric Ozone)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    NARSTO is a public/private partnership dedicated to improving management of air quality in North America. It was established on February 13, 1995 when representatives of Canada, the United States, and Mexico signed the NARSTO Charter in a ceremony at the White House. The Department of Energy is one of the charter members providing funding. The central programmatic goal of NARSTO is to provide data and information for use in the determination of workable, efficient, and effective strategies for local and regional ozone and fine particle management. Since its founding, NARSTO has completed three major scientific Assessments of critical air quality management issues. NARSTO maintains the Quality Systems Science Center and the NARSTO Data Archive for storing data from NARSTO Affiliated Research Activities and making these data available to the scientific community. NARSTO also facilitates activities, such as the Reactivity Research Working Group, which provide critical reviews of the state of the science in areas of interest to air quality policy makers. In January 1997, the U.S. Department of Energy's Environmental Sciences Division announced their sponsorship of the NARSTO Quality Systems Science Center (QSSC). The QSSC is located at the Oak Ridge National Laboratory within the Carbon Dioxide Information Analysis Center (CDIAC). Quality Assurance and Data Management assistance and guidelines are provided by the QSCC, along with access to data files. The permanent data archive is maintained by the NASA EOSDIS Distributed Active Archive Center at the Langley Research Center. The archived data can be reached by a link from the QSSC.(Specialized Interface) See also the NARSTO web site at http://www.narsto.org/

  18. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  19. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  20. Methanol Decomposition over Palladium Particles Supported on Silica: Role of Particle Size and Co-Feeding Carbon Dioxide on the Catalytic Properties

    SciTech Connect (OSTI)

    Hokenek, Selma; Kuhn, John N. (USF)

    2012-10-23

    Monodisperse palladium particles of six distinct and controlled sizes between 4-16 nm were synthesized in a one-pot polyol process by varying the molar ratios of the two palladium precursors used, which contained palladium in different oxidation states. This difference permitted size control by regulation of the nucleation rate because low oxidation state metals ions nucleate quickly relative to high oxidation state ions. After immobilization of the Pd particles on silica by mild sonication, the catalysts were characterized by X-ray absorption spectroscopy and applied toward catalytic methanol decomposition. This reaction was determined as structure sensitive with the intrinsic activity (turnover frequency) increasing with increasing particle size. Moreover, observed catalytic deactivation was linked to product (carbon monoxide) poisoning. Co-feeding carbon dioxide caused the activity and the amount of deactivation to decrease substantially. A reaction mechanism based on the formation of the {pi}-bond between carbon and oxygen as the rate-limiting step is in agreement with antipathetic structure sensitivity and product poisoning by carbon monoxide.