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1

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

2

Korean oxygenates rule sparks MTBE capacity plans  

SciTech Connect (OSTI)

The Korean government`s strict standard for gasoline sold domestically is expected to have a significant impact on the methyl tert-butyl ether (MTBE) market. The mandate-requiring gasoline oxygen content of 0.5% this year, 0.75% by 1996, and 1.0% by 1998-has sparked a rush by Korean refineries to build new MTBE plants. If expansion plans are carried out, Korea`s MTBE capacity will increase from 280,000 m.t./year to 650,000 m.t./year by 1996, far surpassing predicted demand. Honam Oil, part of the Lucky Group, plans startup of a 100,000-m.t./year unit at Yeochon by early 1996. In addition, by the end of 1996 Ssangyong Oil will bring a 100,000-m.t./year unit onstream.

Kim, Hyung-Jin

1994-06-15T23:59:59.000Z

3

Oxygenates du`jour...MTBE? Ethanol? ETBE?  

SciTech Connect (OSTI)

There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

Wolfe, R.

1995-12-31T23:59:59.000Z

4

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

5

MTBE, Oxygenates, and Motor Gasoline  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997EnvironmentElectricityrgy81 §98 3.241MTBE,

6

Acute toxicity of methyl-tertiary-butyl ether (MTBE) to aquatic organisms  

SciTech Connect (OSTI)

Due to the recent amendment of the Clean Air Act, oxygenates are now being added to gasolines to boost octane and reduce air pollution from combustion in heavily populated areas. Oxygenates such as alcohols (i.e. methanol) and ethers (methyl-tertiary-butyl ether, MTBE) are commonly being used. A series of bioassay studies have been conducted with MTBE, one of the most commonly used octane-enhancing additives. Freshwater and marine studies were conducted with fish, invertebrates and algae to determine the impact of this material on the environment following accidental spills. Static-renewal studies were run to ensure maintenance of MTBE, a highly volatile material in the test containers. Chemical confirmation of exposure concentrations demonstrated the adequacy of the exposure system. Mysid shrimp were highly sensitive to MTBE, with significantly less effect observed with the other species evaluated. These data have implications for spill response, particularly since MTBE is slow to biodegrade and will rapidly move through groundwater. Comparative data for other oxygenates will also be discussed.

BenKinney, M.T.; Barbieri, J.F.; Gross, J.S.; Naro, P.A. [Stonybrook Labs. Inc., Princeton, NJ (United States)

1994-12-31T23:59:59.000Z

7

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California  

E-Print Network [OSTI]

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California Gunnar W. Schade,* Gabrielle B. Dreyfus, and Allen H. Goldstein ABSTRACT (CARB) measured MTBE in urban regions in 1995­ 1996, reporting a range of 0.4 to 13.2 ppbv in the LosMethyl tertiary butyl ether (MTBE

Cohen, Ronald C.

8

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network [OSTI]

Environmental Microbiology (2001) 3(6), 407±416 Methyl tert-butyl ether (MTBE) degradation of California, Riverside, Riverside, CA 92521, USA. Summary The widespread use of methyl tert-butyl ether (MTBE is often proposed as the most promising alter- native after treatment. However, MTBE biodegradation appears

9

Measurement of methyl-tert-butyl-ether (MTBE) in raw drinking water  

SciTech Connect (OSTI)

In order to assess the pathways for human exposure to methyl-tert-butyl-ether (MTBE) and to understand the extent of MTBE contamination in watersheds, a purge and trap gas chromatographic mass spectrometric method to measure part-per-trillion (ppt) concentrations of MTBE in environmental waters was developed. A variety of California's raw drinking waters were analyzed. No detectable MTBE was found in deep groundwater (>1000 feet). However shallow groundwater ({approx}250 feet) contained MTBE concentrations of non-detect to 1300 ppt. MTBE concentrations measured in rivers and lakes ranged from non-detect to 3500 ppt. East (San Francisco) Bay area rain water contained approximately 80 ppt MTBE.

Davisson, M L; Koester, C J; Moran, J E

1999-10-14T23:59:59.000Z

10

Canada could get three MTBE plants  

SciTech Connect (OSTI)

This article reports on the proposed development of three methyl tert-butyl ether (MTBE) plants in Canada. MTBE is used as an oxygenated fuel additive. The author discusses how demand for MTBE is increasing due to the regulation of leaded gasoline by the U.S. and Canadian governments. The exportation of MTBE from Canada to the U.S. is highlighted.

Anderson, E

1990-03-01T23:59:59.000Z

11

MTBE demand as a oxygenated fuel additive  

SciTech Connect (OSTI)

The MTBE markets are in the state of flux. In the U.S. the demand has reached a plateau while in other parts of the world, it is increasing. The various factors why MTBE is experiencing a global shift will be examined and future volumes projected.

NONE

1996-10-01T23:59:59.000Z

12

Determination of methyl tert. butyl ether (MTBE) in gasoline  

SciTech Connect (OSTI)

A GLC-acid extraction method is described for the determination of MTBE in gasolines. The method consists of a programmed GLC analysis starting at about room temperature conducted before and after extraction with cold 85% phosphoric acid. This treatment results in the preferential solubility of ethers and other oxygenated compounds while minimizing the reaction of olefins and aromatics which may be present in the gasolines. Plotting various known concentrations of MTBE in gasolines against the concentrations determined in the same samples by the authors methodology results in a straight line relationship. The concentration of MTBE in any sample of gasoline may thus be determined using their GLC-extraction procedure and the calibration line. The analysis can accommodate a wide choice of standard GLC columns and programs. 2 refs., 1 fig., 1 tab.

Feldman, J.; Orchin, M. (Univ. of Cincinnati, OH (United States))

1993-02-01T23:59:59.000Z

13

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Methyl Tert-Butyl Ether (MTBE) in Groundwater P.I. names,Methyl tert-butyl ether (MTBE) is a contaminant of concernsubsurface environments. MTBE appears to be degraded readily

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

14

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis of their pyrolyses by  

E-Print Network [OSTI]

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis 1999; accepted 20 July 1999 Abstract The pyrolysis products of neutral methyl-d3 t-butyl ether (MTBE-d3 from thermal cracking patterns. MTBE and TOME both exhibit base peaks at m/z 73 (which shifts to m/z 76

Morton, Thomas Hellman

15

Disposition, metabolism, and toxicity of methyl tertiary butyl ether, an oxygenate for reformulated gasoline  

SciTech Connect (OSTI)

Studies of the toxicology of methyl tertiary butyl ether (MTBE) were reviewed as a possible information base for evaluating the health effects of evaporative emissions from reformulated gasoline (RFG). Perirenal fat/blood MTBE concentration ratios ranged from 9.7 to 11.6 after 15 wk of intermittent exposure. During an oxyfuels program in Fairbanks, AK, blood levels of occupationally exposed workers were 0.2-31.5 {mu}g/L MTBE and 1.6 to 72.2 {mu}g/L TBA with a mean TBA:MTBE blood concentration ratio of 4.2. In patients who received MTBE by percutaneous, transhepatic puncture for the dissolution of cholesterol gallstones, concentrations of MTBE in fat tissue reached 60 and 300 {mu}g/g at a treatment time when mean blood MTBE was less than 20 {mu}g/ml. The results of laboratory and clinical studies indicate that metabolites of MTBE may contribute to the nephropathy, neoplasms, and other pathological changes associated with repeated exposure to MTBE in experimental animals. It is concluded that such studies can provide a well-defined database for quantitatitive safety comparisons and health risk-benefit analyses of MTBE and other oxygenates in RFG. 39 refs., 1 tab.

Hutcheon, D.E.; Hove, W. ten; Boyle, J. III [UMDNJ, New Jersey Medical Schook, Newark, NJ (United States)] [UMDNJ, New Jersey Medical Schook, Newark, NJ (United States); Arnold, J.D. [Arnold & Arnold, Inc., Kansas City, MO (United States)] [Arnold & Arnold, Inc., Kansas City, MO (United States)

1996-04-05T23:59:59.000Z

16

Oxidation of methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by ozone and combined ozone/hydrogen peroxide  

SciTech Connect (OSTI)

The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O[sub 3]/H[sub 2]O[sub 2]. batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH[degree]-radical with MTBE and ETBE (k[sub OH[degree]/ETBE]/k[sub OH[degree]//MTBE] = 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE an ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds. 10 refs., 10 figs., 1 tab.

Leitner, N.K.V.; Papailhou, A.L.; Croue, J.P.; Dore, M. (Univ. de Poitiers (France)); Peyrot, J. (British Petroleum, Harfleur (France))

1994-01-01T23:59:59.000Z

17

Evaluating nonmetallic materials` compatibility with MTBE and MTBE + gasoline service  

SciTech Connect (OSTI)

Methyl-tertiary-butyl-ether (MTBE) has become the leading oxygenate in use in the petroleum industry. Since its introduction several years ago there has been premature deterioration of nonmetallic materials in both neat MTBE and MTBE + gasoline. This degradation is costly in several ways: maintenance, replacement, environmental, and product-loss. Identifying nonmetallic materials compatible with MTBE and MTBE + gasoline is important to the petroleum industry -- all the way from the refinery to the retail sale. Exposure tests have been conducted with different types of nonmetallics in neat MTBE, neat MTBE vapor, and 5% MTBE + 95% gasoline. As in previously reported tests, Teflon{reg_sign} laminates were the top performers, experiencing very little change in any of the properties tested. An ester and ether-based urethane laminate also exhibited only small property changes. Most materials displayed significant deterioration of one or more of the measured properties, even in MTBE condensing vapor and the 5% MTBE + 95% gasoline. The specific effects on each material need to be individually evaluated to determine the effect on service life.

Hotaling, A.C.

1995-12-31T23:59:59.000Z

18

MTBE: Wild card in groundwater cleanup  

SciTech Connect (OSTI)

Subsurface releases of the gasoline oxygenate, methyl tertiary butyl ether (MTBE) seriously compromise the remediation and closure of properties that have ground water contaminated with BTEX and other conventional fuel hydrocarbon components. Although a manageable protocal for BTEX remediation is being set up, the MTBE problem continues to be difficult. This article discusses a new magnesium peroxide compound which could be part of the solution. Covered topics include oxygen release compound (ORC) enhance bioremediation and the role of oxygen and ORC in MTBE remediation. 1 fig.

Koenigsberg, S. [Regenesis Bioremediation Products, San Juan Capistrano, CA (United States)

1997-11-01T23:59:59.000Z

19

Manipulation of the HIFVegf pathway rescues methyl tert-butyl ether (MTBE)-induced vascular lesions  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) has been shown to be specifically anti-angiogenic in piscine and mammalian model systems at concentrations that appear non-toxic in other organ systems. The mechanism by which MTBE targets developing vascular structures is unknown. A global transcriptome analysis of zebrafish embryos developmentally exposed to 0.006255 mM MTBE suggested that hypoxia inducible factor (HIF)-regulated pathways were affected. HIF-driven angiogenesis via vascular endothelial growth factor (vegf) is essential to the developing vasculature of an embryo. Three rescue studies were designed to rescue MTBE-induced vascular lesions: pooled blood in the common cardinal vein (CCV), cranial hemorrhages (CH), and abnormal intersegmental vessels (ISV), and test the hypothesis that MTBE toxicity was HIFVegf dependent. First, zebrafish vegf-a over-expression via plasmid injection, resulted in significantly fewer CH and ISV lesions, 46 and 35% respectively, in embryos exposed to 10 mM MTBE. Then HIF degradation was inhibited in two ways. Chemical rescue by N-oxaloylglycine significantly reduced CCV and CH lesions by 30 and 32% in 10 mM exposed embryos, and ISV lesions were reduced 24% in 5 mM exposed zebrafish. Finally, a morpholino designed to knock-down ubiquitin associated von HippelLindau protein, significantly reduced CCV lesions by 35% in 10 mM exposed embryos. In addition, expression of some angiogenesis related genes altered by MTBE exposure were rescued. These studies demonstrated that MTBE vascular toxicity is mediated by a down regulation of HIFVegf driven angiogenesis. The selective toxicity of MTBE toward developing vasculature makes it a potentially useful chemical in the designing of new drugs or in elucidating roles for specific angiogenic proteins in future studies of vascular development. - Highlights: Global gene expression of MTBE exposed zebrafish suggested altered HIF1 signaling. Over expression of zebrafish vegf-a rescues MTBE-induced vascular lesions. Inhibiting PHD or knocking down VHL rescues MTBE-induced vascular lesions. HIF1-Vegf driven angiogenesis is a target for MTBE vascular toxicity.

Bonventre, Josephine A., E-mail: josephine.bonventre@oregonstate.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Oregon State University, Department of Environmental and Molecular Toxicology, 1011 Agricultural and Life Sciences Bldg, Corvallis, OR 97331 (United States); Kung, Tiffany S., E-mail: tiffany.kung@rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); White, Lori A., E-mail: lawhite@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Cooper, Keith R., E-mail: cooper@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States)

2013-12-15T23:59:59.000Z

20

MTBE still in poor health, despite the Clean Air Act  

SciTech Connect (OSTI)

After the second winter oxygenated fuels program of the 1990 Clean Air Act, producers of methyl tert-butyl ether (MTBE) are still feeling the chill of poor profitability. Despite the strong demand growth for MTBE to meet oxygen requirements in reformulated gasoline (RFG), oversupply still dogs the market. That, combined with a run-up in feedstock prices, has seen margins for MTBE markers all but evaporate. And it seems matters are likely to get worse before they get better. This week, Belvieu Environmental Fuels (BEF; Houston) expects to startup its 15,000-bbl/day MTBE plant at Mont Belvieu, TX. In late July, Texaco will start up its 15,000-bbl/day MTBE/propylene oxide (PO) plant at Port Neches, TX. In addition, a rash of refinery-based MTBE and tert-amyl methyl ether projects are nearing completion. {open_quotes}Profitability in MTBE has been extremely poor,{close_quotes} says Marvin O. Schlanger, president of Arco Chemical Americas, the largest MTBE producer. There has, however, been some recent recovery on the spot market, with MTBE moving from less than 60 cts/gal to near cash-cost levels of 70 cts/gal. But contract prices remain depressed, and strength in butane and methanol pricing have all buy wiped out any gains in MTBE.

Wood, A.

1994-05-25T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Effects of oxygenate concentration on species mole fractions in premixed n-heptane flames  

E-Print Network [OSTI]

-heptane/oxygenate mixtures were 2.7 and 3.4. Three different fuel oxygenates (i.e. MTBE, methanol, and ethanol) were tested tertiary-butyl ether (MTBE), ethyl tertiary-butyl ether (ETBE), and tertiary amyl methyl ether (TAME)) were considered as possible fuel oxygenates. MTBE and ethanol are the most common oxygenates currently used

Senkan, Selim M.

22

Rates and products of degradation for MTBE and other oxygenate fuel additives in the subsurface environment  

SciTech Connect (OSTI)

The recent realization that oxygenated fuel additives such as MTBE are becoming widely distributed groundwater contaminants has created a sudden and pressing demand for data on the processes that control their environmental fate. Explaining and predicting the subsequent environmental fate of these compounds is going to require extrapolations over long time frames that will be very sensitive to the quality of input data on each compound. To provide such data, they have initiated a systematic study of the pathways and kinetics of fuel oxygenate degradation under subsurface conditions. Batch experiments in simplified model systems are being performed to isolate specific processes that may contribute to MTBE degradation. A variety of degradation pathways can be envisioned that lead to t-butyl alcohol (TBA) as the primary or secondary product. However, experiments to date with a facultative iron reducing bacteria showed no evidence for TBA formation. Continuing experiments include mixed cultures from a range of aquifer materials representative of NAWQA study sites.

Tratnyek, P.G.; Church, C.D.; Pankow, J.F. [Oregon Graduate Inst., Portland, OR (United States). Dept. of Environmental Science and Engineering

1995-12-31T23:59:59.000Z

23

MTBE: Capacity boosts on hold amid demand concerns  

SciTech Connect (OSTI)

Uncertainty reigns in the methyl tert-butyl ether (MTBE) market. {open_quotes}We have no choice but to put our expansion plans on the back burner,{close_quotes} says one producer. {open_quotes}Because of government actions, there are no MTBE plants being built or expanded.{close_quotes} Spot MTBE prices have risen ti 82 cts- 83 cts/gal from 76 cts-78 cts/gal earlier this month as the demand for octane enhancement increases for the summer driving season. Some observers say EPA may relax different oxygen requirements for gasoline in different seasons. That would simplify production and supply for MTBE makers.

NONE

1995-05-03T23:59:59.000Z

24

Petrochem industry expands North American MTBE capacity  

SciTech Connect (OSTI)

This paper reports that petrochemical manufacturers continue to increase methyl tertiary butyl ether (MTBE) capacity in North America. The action reflects refiners' reformulation of gasoline to help reduce auto emissions. Demand for gasoline blending oxygenates such as MTBE is expected to increase as U.S. refiners reconfigure processing trains to produce fuels meeting requirements of the Clean Air Act amendments of 1990. Recent progress includes plans to build an MTBE plant in Mexico and start-ups of plants on the U.S. Gulf Coast and in Canada.

Not Available

1992-10-05T23:59:59.000Z

25

Analysis of dissolved benzene plumes and methyl tertiary butyl ether (MTBE) plumes in ground water at leaking underground fuel tank (LUFT) sites  

SciTech Connect (OSTI)

The 1990 Clean Air Act Amendments mandate the addition of oxygenates to gasoline products to abate air pollution. Currently, many areas of the country utilize oxygenated or reformulated fuel containing 15- percent and I I-percent MTBE by volume, respectively. This increased use of MTBE in gasoline products has resulted in accidental point source releases of MTBE containing gasoline products to ground water. Recent studies have shown MTBE to be frequently detected in samples of shallow ground water from urban areas throughout the United States (Squillace et al., 1995). Knowledge of the subsurface fate and transport of MTBE in ground water at leaking underground fuel tank (LUFT) sites and the spatial extent of MTBE plumes is needed to address these releases. The goal of this research is to utilize data from a large number of LUFT sites to gain insights into the fate, transport, and spatial extent of MTBE plumes. Specific goals include defining the spatial configuration of dissolved MTBE plumes, evaluating plume stability or degradation over time, evaluating the impact of point source releases of MTBE to ground water, and attempting to identify the controlling factors influencing the magnitude and extent of the MTBE plumes. We are examining the relationships between dissolved TPH, BTEX, and MTBE plumes at LUFT sites using parallel approaches of best professional judgment and a computer-aided plume model fitting procedure to determine plume parameters. Here we present our initial results comparing dissolved benzene and MTBE plumes lengths, the statistical significance of these results, and configuration of benzene and MTBE plumes at individual LUFT sites.

Happel, A.M.; Rice, D. [Lawrence Livermore National Lab., CA (United States); Beckenbach, E. [California Univ., Berkeley, CA (United States); Savalin, L.; Temko, H.; Rempel, R. [California State Water Resources Control Board, Sacramento, CA (United States); Dooher, B. [California Univ., Los Angeles, CA (United States)

1996-11-01T23:59:59.000Z

26

MTBE -- A global perspective  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is a major and familiar component of Reformulated and Oxygenated gasoline in the US. As such, it is essential to the success of the Clean Air Act programs now reaching a crescendo in major urban areas. In less than ten years, US MTBE capacity has grown from about 4,000 B/D to more than 200,000 B/D. Outside of the USA, its role is less widely understood. Although MTBE markets elsewhere are much less driven by legislation, they have seen the same spectacular growth prospects. Overall, about as much MTBE is used today overseas as in the US. To date, this has to be one of the petrochemical industry`s major success stories. Yet today, the MTBE industry stands at a crossroads, with the direction of future development uncertain at best. DeWitt`s gasoline and oxygenates team has closely observed the ups and downs of this market during most of its turbulent history. In this paper, the authors shall try to set down the major developments and prospects, with the personal familiarity of having been there when things changed. The story begins with a brief historical sketch, leading up to the identification of four critical periods in which major changes took place. The causes of today`s uncertainty lie in all of these stages, and are in a very real sense an example of the ``Law of Unintended consequences.`` Having set the stage, a cautious set of predictions will be put forth. These are neither as promising as proponents would like, nor as unpromising as some would tend to believe.

Ludlow, W.I.; Miller, K.D. Jr.; Liew, R.E. van [DeWitt and Co., Inc., Houston, TX (United States)

1995-09-01T23:59:59.000Z

27

Health studies indicate MTBE is safe gasoline additive  

SciTech Connect (OSTI)

Implementation of the oxygenated fuels program by EPA in 39 metropolitan areas, including Fairbanks and Anchorage, Alaska, in the winter of 1992, encountered some unexpected difficulties. Complaints of headaches, dizziness, nausea, and irritated eyes started in Fairbanks, jumped to Anchorage, and popped up in various locations in the lower 48 states. The suspected culprit behind these complaints was the main additive for oxygenation of gasoline is methyl tert-butyl ether (MTBE). A test program, hastily organized in response to these complaints, has indicated that MTBE is a safe gasoline additive. However, official certification of the safety of MTBE is still awaited.

Anderson, E.V.

1993-09-01T23:59:59.000Z

28

Ecological hazards of MTBE exposure: A research agenda  

SciTech Connect (OSTI)

Fuel oxygenates are used in metropolitan areas across the United States in order to reduce the amount of carbon monoxide released into the atmosphere during the winter. The most commonly used fuel oxygenate is Methyl tert-butyl ether (MTBE). Its widespread use has resulted in releases into the environment. To date there has been only minimal effort to investigate ecological impacts caused by exposure to concentrations of MTBE typically found in environmental media. Research into the potential for MTBE to adversely affect ecological receptors is essential. Acquisition of such baselines data is especially critical in light of continuing inputs and potential accumulation of MTBE in environmental media. A research Agenda is included in this report and addresses: Assessing Ecological Impacts, Potential Ecological Impacts of MTBE (aquatic organisms, terrestrial organisms), Potential Ecological Endpoints, and A Summary of Research Needs.

Carlsen, T.; Hall, L.; Rice, D.

1997-03-01T23:59:59.000Z

29

Global developments in MTBE  

SciTech Connect (OSTI)

This paper is intended to provide an overview of some of the recent developments in MTBE demand growth worldwide and the impact of these developments on MTBE demand in the future. It provides a perspective of the influence of developments in the US on the worldwide MTBE markets. The public`s outcry regarding oxygenates in gasoline, and specifically MTBE, that has been evolving in the US during the past several months is in response to a politically mandated requirement for a fuel that contains oxygen that is provided by MTBE or ethanol. This public unrest had negatively impacted the market price for MTBE at the time this paper was being prepared. However, the author believes that MTBE, because of its clean octane capabilities, will continue to be used as an octane blendstock for gasoline in increasing quantities worldwide as we move through lead phasedown in West Europe and other countries that are experiencing pollution problems relating to exhaust emissions from internal combustion engines. The objectives of this paper are as follows: review developments in MTBE demand 1990--2000; identify regions where MTBE demand growth will occur; review production growth for MTBE, both historical and forecast; examine world trade patterns during the period; assess methanol demand growth during the period; analyze MTBE`s regional price bias; and provide a forecast of future MTBE price trends.

Feller, L.W. [CMAI, Houston, TX (United States)

1995-12-31T23:59:59.000Z

30

Alveolar breath sampling and analysis to assess exposures to methyl tertiary butyl ether (MTBE) during motor vehicle refueling  

SciTech Connect (OSTI)

In this study we present a sampling and analytical methodology that can be used to assess consumers` exposures to methyl tertiary butyl ether (MTBE) that may result from routine vehicle refueling operations. The method is based on the collection of alveolar breath samples using evacuated one-liter stainless steel canisters and analysis using a gas chromatograph-mass spectrometer equipped with a patented `valveless` cryogenic preconcentrator. To demonstrate the utility of this approach, a series of breath samples was collected from two individuals (the person pumping the fuel and a nearby observer) immediately before and for 64 min after a vehicle was refueled with premium grade gasoline. Results demonstrate low levels of MTBE in both subjects` breaths before refueling, and levels that increased by a factor of 35 to 100 after the exposure. Breath elimination models fitted to the post exposure measurements indicate that the half-life of MTBE in the first physiological compartment was between 1.3 and 2.9 min. Analysis of the resulting models suggests that breath elimination of MTBE during the 64 min monitoring period was approximately 155 {mu}g for the refueling subject while it was only 30 {mu}g for the nearby observer. This analysis also shows that the post exposure breath elimination of other gasoline constituents was consistent with previously published observations. 20 refs., 3 figs., 4 tabs.

Lindstrom, A.B.; Pleil, J.D. [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

1996-07-01T23:59:59.000Z

31

A screening model for evaluating the degradation and transport of MTBE and other fuel oxygenates in the subsurface  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) has received high attention as it contributed to cleaner air and contaminated thousands of underground storage tank sites. Because MTBE is very water soluble, it is more difficult to remove from water by conventional remediation techniques. Therefore, biodegradation of MTBE has become a remediation alternative. In order to understand the transport and transformation processes, they present a closed form solution as a screening tool in this paper. The possible reaction pathways of first-order reactions are described as a reaction matrix. The singular value decomposition is conducted analytically to decouple the partial differential equations of the multi-species transport system coupled by the reaction matrix into multiple independent subsystems. Therefore, the complexity of mathematical description for the reactive transport system is significantly reduced and analytical solutions may be previously available or easily derived.

Sun, Y; Lu, X

2004-04-20T23:59:59.000Z

32

Drinking Water Problems: MTBE  

E-Print Network [OSTI]

. This compound belongs to a chemical family of fuel oxygenates that enhance gaso- line combustion by increasing oxygen available for the process. Added to gasoline, MTBE has reduced carbon monoxide and ozone emissions by promoting more complete burning.... Texas follows the EPA drinking water advisory of 20 to 40 micrograms per liter. How can MTBE be Removed from Well Water? MTBE requires a specific treatment process for removal from water. Well owners can use granular activated carbon or charcoal...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

33

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network [OSTI]

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

34

Factors influencing biological treatment of MTBE contaminated ground water  

E-Print Network [OSTI]

Methyl tertiary-butyl ether (MTBE) biodegradation in batchCometabolic degradation of MTBE by a cyclohexane-oxidizingof 49 Biological Treatment of MTBE Fortin, N. Y. , and M. A.

Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

2001-01-01T23:59:59.000Z

35

Biodegradation of methyl tertiary butyl ether (MTBE) using a granular activated carbon trickling filter  

SciTech Connect (OSTI)

A pilot scale trickling filter was constructed using granular activated carbon (GAC) as the packing medium and inoculated with a microbial culture known to degrade MTBE. The packing dimensions were 0.076 m in diameter and 0.22 m deep. The unit operated with recycling flow for two months before a biofilm was observed on the GAC. After two additional months the biofilm had visibly spread throughout the packing. A few pieces of GAC were placed in a sealed bottle with MTBE-contaminated water and nutrients. Headspace analysis performed over 14 days confirmed that MTBE degradation was occurring. The trickling filter was converted to continuous flow and operated for one month at a nominal flow rate of 0.1 L/min and a hydraulic loading rate of 32 m{sup 3}/m{sup 2}-d. Samples were collected for analysis at the spray nozzle and at the bottom of the trickling filter. Fractional removal varied with influent MTBE concentration, temperature and liquid flow rate. Percent MTBE removal was as high as 85%. A mechanical failure resulted in the trickling filter bed drying and percent removal dropping to less than 1 percent. However, the system recovered within five days.

Converse, B.M.; Schroeder, E.D.; Chang, D.P.Y.

1999-07-01T23:59:59.000Z

36

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

37

New processes to recovery methanol and remove oxygenates from Valero MTBE unit  

SciTech Connect (OSTI)

The refiner today has to evaluate every available option to increase octane in the gasoline pool to make up for the loss in octane created by lead phase down. Production of MTBE is one of the most attractive options. MTBE is produced by selectivity reacting isobutylene with methanol. Valero Refining's refinery at Corpus Christie, Texas (formerly Saber Refining) is one of the most modern refineries built in the last decade to upgrade resids. As part of the gasoline upgrading Valero had built a Butamer Unit to convert normal butane to isobutane upstream of their HF Alkylation Unit. In 1984 as an ongoing optimization of its operations, Valero Refining evaluated various processes to enable it to increase the octane output, and decided to build an MTBE unit. Valero selected the MTBE process licensed by Arco Technology, Inc. and contracted with Jacobs Engineering Group, Inc., Houston, Texas to provide detailed engineering and procurement services.

Hillen, P.; Clemmons, J.

1987-01-01T23:59:59.000Z

38

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

39

A near infrared regression model for octane measurements in gasolines which contain MTBE  

SciTech Connect (OSTI)

Near infrared (NIR) spectroscopy has emerged as a superior technique for the on-line determination of octane during the blending of gasoline. This results from the numerous advantages that NIR spectroscopy has over conventional on-line instrumentation. Methyl t-butyl ether (MTBE) is currently the oxygenated blending component of choice. MTBE is advantageous because it has a high blending octane, a low Reid vapor pressure, is relatively cheap, and does not form peroxides (1). The goal of this project was to develop a NIR regression model that could be used to predict pump octanes regardless of whether they contained MTBE.

Maggard, S.M. (Ashland Petroleum Co., KY (USA))

1990-01-01T23:59:59.000Z

40

Race to license new MTBE and TAME routes heats up  

SciTech Connect (OSTI)

With refineries and petrochemical manufacturers continuing to gear up production of oxygenates for use in reformulated fuels, new routes to methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) are clearly hot items in the licensing market. And probably nowhere has the competition become as intense as in offerings for skeletal isomerization technologies to boost ethers production from fluid catalytic cracking and steam cracking.

Rotman, D.

1993-01-06T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

US refiners choose variety of routes to MTBE  

SciTech Connect (OSTI)

This paper reports that refiners and merchant manufacturers in the U.S. are gearing up to produce the large volumes of methyl tertiary butyl ether (MTBE) needed to comply with oxygenated gasoline requirements. The 1990 U.S. Clean Air Act Amendments specify that, as of the first of this coming November, gasoline containing a minimum of 2.7 wt % oxygen must be sold in 39 CO-nonattainment cities. Refiners and others are scurrying to bring MTBE capacity on line in time to meet this requirement. Many U.S. refiners already have some operating MTBE capacity, but this will not be nearly enough to meet the looming increase in demand. As a result, additional capacity is being constructed worldwide.

Rhodes, A.K.

1992-09-07T23:59:59.000Z

42

{gamma}-aminobutyric acid{sub A} (GABA{sub A}) receptor regulates ERK1/2 phosphorylation in rat hippocampus in high doses of Methyl Tert-Butyl Ether (MTBE)-induced impairment of spatial memory  

SciTech Connect (OSTI)

Experimental and occupational exposure to Methyl Tert-Butyl Ether (MTBE) has been reported to induce neurotoxicological and neurobehavioral effects, such as headache, nausea, dizziness, and disorientation, etc. However, the molecular mechanisms involved in MTBE-induced neurotoxicity are still not well understood. In the present study, we investigated the effects of MTBE on spatial memory and the expression and function of GABA{sub A} receptor in the hippocampus. Our results demonstrated that intraventricular injection of MTBE impaired the performance of the rats in a Morris water maze task, and significantly increased the expression of GABA{sub A} receptor {alpha}1 subunit in the hippocampus. The phosphorylation of ERK1/2 decreased after the MTBE injection. Furthermore, the decreased ability of learning and the reduction of phosphorylated ERK1/2 level of the MTBE-treated rats was partly reversed by bicuculline injected 30 min before the training. These results suggested that MTBE exposure could result in impaired spatial memory. GABA{sub A} receptor may play an important role in the MTBE-induced impairment of learning and memory by regulating the phosphorylation of ERK in the hippocampus.

Zheng Gang; Zhang Wenbin [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China); Zhang Yun [465 Hospital, Jilin Medical College, Jilin 132001 (China); Chen Yaoming; Liu Mingchao; Yao Ting; Yang Yanxia; Zhao Fang [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China); Li Jingxia; Huang Chuanshu [Nelson Institute of Environmental Medicine, New York University School of Medicine, Tuxedo, New York 10987 (United States); Luo Wenjing [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China)], E-mail: luowenj@fmmu.edu.cn; Chen Jingyuan [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China)], E-mail: jy_chen@fmmu.edu.cn

2009-04-15T23:59:59.000Z

43

Meeting the challenge of MTBE biodegradation  

SciTech Connect (OSTI)

Oxygenated and reformulated gasolines have been developed in response to air pollution control regulations targeted at reducing carbon monoxide emissions and photochemical air pollution. The 1990 Clean Air Act Amendments required the addition of fuel oxygenates to gasoline in areas where the level of carbon monoxide exceeded national ambient air quality standards. In the South Coast Air Basin gasoline containing oxygenated compounds has been in use since the late 1980`s. One oxygenated fuel additive most often selected by producers to meet the requirements is methyl tert-butyl ether (MTBE). However, large production numbers associated with MTBE production, combined with the compound`s high water solubility, chemical stability, and toxicity, make it a potentially important groundwater pollutant. The County Sanitation District of Los Angeles, Joint Water Pollution Control Plant in Carson, California is one of the few wastewater treatment plants in the nation that receives refinery wastewater discharge. It has operated several pilot-scale compost-based biofilters for control of various volatile organic contaminants throughout the plant since a 1991 joint study with the University of California, Davis. After one year of operation, one of the biofilters spontaneously developed the ability to degrade MTBE. The paper describes the collaborative efforts to determine the feasibility of transferring the degrading microbial population from the solid to liquid phase, without loss of activity, and to determine some of the environmental requirements necessary for survival of the microbial culture.

Eweis, J.B.; Chang, D.P.Y.; Schroeder, E.D.; Scow, K.M. [Univ. of California, Davis, CA (United States); Morton, R.L.; Caballero, R.C. [Los Angeles County Sanitation Districts, Carson, CA (United States). Joint Water Pollution Control Plant

1997-12-31T23:59:59.000Z

44

active methyl tert-butyl: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

45

Review of the environmental behavior and fate of methyl tert-butyl ether  

SciTech Connect (OSTI)

A review of pertinent equations and current research indicates that when gasoline oxygenated with methyl tert-butyl ether (MTBE) comes into contact with water, large amounts of MTBe can dissolve. At 25 C, the water solubility of MTBE is about 5,000 mg/L for a gasoline that is 10% MTBE by weight, whereas for a nonoxygenated gasoline, the total hydrocarbon solubility in water is typically about 120 mg/L. Methyl tert-butyl ether sorbs only weakly to subsurface solids; therefore, sorption does not substantially retard the transport of MTBE by ground water. In addition, MTBE generally resists biodegradation in ground water. The half-life of MTBE in the atmosphere can be as short as 3 d in a regional airshed. In the air, MTBE tends to partition into atmospheric water, including precipitation. However, the washing out of gas-phase MTBE by precipitation will not, by itself, greatly alter the gas-phase concentration of the compound in the air. The partitioning of MTBE to precipitation can nevertheless result in concentrations as high as 3 {micro}g/L or more in urban precipitation and can contribute to the presence of MTBE in surface and ground water.

Squillace, P.J.; Zogorski, J.S. [Geological Survey, Rapid City, SD (United States); Pankow, J.F. [Oregon Graduate Inst. of Science and Technology, Beaverton, OR (United States). Dept. of Environmental Science and Engineering; Korte, N.E. [Oak Ridge National Lab., TN (United States). Environmental Science Div.

1997-09-01T23:59:59.000Z

46

Review of potential technologies for the treatment of Methyl tertiary butyl Ether (MtBE) in drinking water  

SciTech Connect (OSTI)

At present, the state of knowledge on effective treatment technologies for MtBE in drinking water, and groundwater in general, is limited. Research by others is focusing on the remediation of MtBE close to the point of release. The City of Santa Monica, MWD, Komex and USC are currently conducting research into different technologies that could be used to remove MtBE from drinking water supplies. The objectives of the research are to evaluate different treatment technologies to identify cost-effective and technically feasible alternatives for the removal of MtBE from drinking water. The evaluation is considering moderate to high water flow rates (100 to 2,000+ gpm) and low to moderate MtBE concentrations (<2,000 {mu}g/l). The research program includes four phases: (1) Literature Review; (2) Bench Scale Study; (3) Field Scale Pre-pilot Study; and (4) Summary Evaluation. This paper presents some preliminary information and findings from the first phase of this research - the literature review. The review discusses the chemical properties of MtBE and how they affect remediation and thus, an evaluation of alternative treatment technologies. The review of available literature, and the applicability and limitations of the following technologies are presented in detail.

Brown, A.; Browne, T.E. [Komex H2O Science, Huntington Beach, CA (United States); Devinny, J.S. [Univ. of Southern California, Los Angeles, CA (United States)] [and others

1997-12-31T23:59:59.000Z

47

A review of treatment technologies for MTBE  

SciTech Connect (OSTI)

Available treatment technologies for methyl tertiary butyl ether (MTBE) contamination in soil, groundwater, and recovered groundwater are reviewed and assessed. MTBE contamination is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more soluble and more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Treatment of MTBE is complicated by its Henry`s constant, which is lower than most other gasoline constituents. Furthermore, evidence of biodegradability of MTBE is mixed, and MTBE does not degrade rapidly abiotically. Groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater, often successfully because of its high aqueous solubility. Air sparging/soil vapor extraction is also successfully employed to treat MTBE, but its effectiveness is reduced by the low Henry`s constant of MTBE. Sparging and other aerobic bioremediation approaches are hampered by the poor biodegradability of MTBE. Oxidation technologies, such as ozone injection, hold promise for rapid in situ remediation of MTBE. Treatment of recovered groundwater contaminated with MTBE is also problematic. MTBE adsorbs poorly to granular activated carbon; advanced oxidation processes are effective on MTBE, but entail high capital and operating costs; bioreactors are of questionable effectiveness on MTBE. Air stripping is usually the most cost-effective treatment technology for MTBE so long as the off gas from the air stripper can be discharged without treatment. However, off gas treatment is expensive, so groundwater is sometimes heated to reduce the requirement for stripping air.

Bass, D. [Groundwater Technology, Inc., Norwood, MA (United States)

1995-12-31T23:59:59.000Z

48

Methyl tertiary butyl ether (MtBE) contamination of the City of Santa Monica drinking water supply  

SciTech Connect (OSTI)

In the summer of 1996, the City of Santa Monica ceased pumping groundwater from two Well Fields (Charnock and Arcadia) used for public drinking water supply due to persistent and increasing concentrations of MtBE in all seven municipal water supply wells. This lost production accounted for 50% of the City`s total drinking water supply. In late 1996, the City, in cooperation with State and Federal agencies, initiated an investigation of MtBE contamination at the two well fields. The objectives of the investigation were as follows: (1) Review available data on the production, use, chemical characteristics, fate and transport, toxicology, and remediation of MtBE; (2) Identify locations of potential sources of MtBE groundwater contamination at the well fields; (3) Develop an understanding of the hydrologic pathways from the potential sources to the drinking water wells; and (4) Evaluate alternative treatment technologies for the removal of MtBE from drinking water. In addition to a review of available information about MtBE, the investigation included an extensive review of literature and available data relevant to the well fields, including well field production histories, site and regional hydrogeology, all well logs and production in the groundwater basins, general groundwater quality, and the record of MtBE detection. Based upon the review of background information, conceptual hydrogeologic models were developed. A detailed review of agency files for over 45 potential source sites was conducted. The information from this review was summarized, and source site screening and ranking criteria were developed. A field program was conducted at the major well field (Charnock), including soil gas surveys, CPTs, soil borings and well installations, geophysics, and aquifer testing. The field program provided site data which allowed the conceptual hydrogeologic model to be refitted to actual site conditions.

Brown, A.; Farrow, J.R.C. [Komex H2O Science, Huntington Beach, CA (United States); Rodriguez, R.A. [City of Santa Monica, CA (United States)] [and others

1997-12-31T23:59:59.000Z

49

Economics of new MTBE design  

SciTech Connect (OSTI)

Methyl Tertiary Butyl Ether (MTBE) is produced industrially by catalytic reaction between methanol and isobutene. The catalyst that is widely used is an acidic ion exchange resin. This article explores design and economics when sulfuric acid is the catalyst. The profitability of MTBE production depends mainly on the cost of butenes and methhanol. Thus, the example shows MTBE made with a catalyst of sulfuric acid was profitable at a Saudi Arabian location, even though it was not profitable at a U.S. Gulf Coast location.

Al-Jarallah, A.M.; Lee, A.K.K.

1988-07-01T23:59:59.000Z

50

Statoil outlines MTBE development program  

SciTech Connect (OSTI)

This paper reports that Norway's state oil company Den Norkse state Oljeselskap AS has outlined plans to become one of the major European producers of methyl tertiary butyl ether in the 1990s. Statoil predicts European demand for MTBE will jump to 4.5 million metric tons/year by 2000 from 2.5 million tons in 1990. Europe currently is a net importer of MTBE, with a productive capacity of 2.2 million tons/year.

Not Available

1991-11-25T23:59:59.000Z

51

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

52

Factors influencing biological treatment of MTBE contaminated ground water  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) contamination has complicated the remediation of gasoline contaminated sites. Many sites are using biological processes for ground water treatment and would like to apply the same technology to MTBE. However, the efficiency and reliability of MTBE biological treatment is not well documented. The objective of this study was to examine the operational and environmental variables influencing MTBE biotreatment. A fluidized bed reactor was installed at a fuel transfer station and used to treat ground water contaminated with MTBE and gasoline hydrocarbons. A complete set of chemical and operational data was collected during this study and a statistical approach was used to determine what variables were influencing MTBE treatment efficiency. It was found that MTBE treatment was more sensitive to up-set than gasoline hydrocarbon treatment. Events, such as excess iron accumulation, inhibited MTBE treatment, but not hydrocarbon treatment. Multiple regression analysis identified biomass accumulation and temperature as the most important variables controlling the efficiency of MTBE treatment. The influent concentration and loading of hydrocarbons, but not MTBE, also impacted MTBE treatment efficiency. The results of this study suggest guidelines for improving MTBE treatment. Long cell retention times in the reactor are necessary for maintaining MTBE treatment. The onset of nitrification only occurs when long cell retention times have been reached and can be used as an indicator in fixed film reactors that conditions favorable to MTBE treatment exist. Conversely, if the reactor can not nitrify, it is unlikely to have stable MTBE treatment.

Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

2001-09-14T23:59:59.000Z

53

Evaluation and Optimization of MTBE Biodegradation in Aquifers, Final Report  

SciTech Connect (OSTI)

This study was focused on meeting the following objectives concerning the process of methyl tertiary butyl ether (MTBE) biodegradation, with the goal of optimizing this process in situ: 1. Assess whether intrinsic bioattenuation of MTBE is feasible under aerobic conditions across several contaminated sites. 2. Determine the effect of co-contaminants, specifically water-soluble gasoline components (most notably benzene, toluene, ethylbenzene and xylenes [BTEX]) on MTBE biodegradation. 3. Determine whether microbial and/or chemical factors contribute to different MTBE degradative activities. 4. Isolate and characterize MTBE-degrading microorganisms from sediments in which MTBE biodegradation was observed.

Legler, T; Balser, L; Koester, C; Wilson, W

2004-02-13T23:59:59.000Z

54

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network [OSTI]

UMass builds bugs to eat MTBE ByAuriaCimino STAfFWRITER An area university's process to destroy with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete in particular has suffered from MTBE contamination because of the abundance of groundwater in the state, said

Lovley, Derek

55

Saudi MTBE project revived  

SciTech Connect (OSTI)

Alujain Corp., a member of the Xenel group of Saudi Arabia, is going ahead with plans to build an 800,000-m.t./year methyl tert-butyl ether (MTBE) plant. Bechtel has been appointed project manager for the plant, which will be owned by a new company, National Fuel Additives (Tahseen). Bechtel will help evaluate proposals already submitted for the lump sum turnkey job.

NONE

1996-01-17T23:59:59.000Z

56

MTBE, methanol prices rise  

SciTech Connect (OSTI)

After several months of drifting lower in line with declining autumn gasoline prices, tabs for methyl tert-butyl ether (MTBE) have turned around. There has been no big demand surge, but consumers and traders are beginning to build up inventories in advance of a series of midwinter shutdowns and turnarounds by producers. Spot prices, which dropped as low as 75 cts/gal, have rebounded to 90 cts/gal fob. Eager for a positive glimmer, methanol producers posted a 3-cts/gal increase in contract prices this month. It marks the first upward idea since February. In that time contract prices have dropped 75% from $1.55/gal to 39 cts/gal. A hard winter has hit early in much of the US sending natural gas prices up sharply. At the same time, formaldehyde and acetic acid markets remain firm, and with MTBE rebounding, methanol producers feel entitled to a piece of the action. {open_quotes}I don`t buy into this claim that MTBE demand is up and I don`t think producers can justify even a 3-cts/gal increase,{close_quotes} says one. {open_quotes}There is nothing in the economy to warrant a run-up. Housing starts are weaker, and demand is down at least 80,000 bbl/day with the MTBE shutdown.{close_quotes}

Morris, G.D.L.; Cornitius, T.

1995-12-20T23:59:59.000Z

57

MTBE will be a boon to U. S. gas processors  

SciTech Connect (OSTI)

This paper reports that the advent of methyl tertiary butyl ether (MTBE) as the primary oxygenate blending component for oxygenated and reformulated motor fuels promises significant benefits for the U.S. gas-processing industry. Increased demand for isobutane as MTBE-plant feedstock will buoy both normal butane and isobutane pricing in U.S. gulf Coast during the 1990s. Elimination of the need to crack normal butane in U.S. olefin plants will also strengthen competitive feedstocks somewhat, including ethane and propane. And increased use of normal butane as isomerization feedstock will result in wider recognition of the premium quality of gas plant normal butane production compared to most refinery C[sub 4] production.

Otto, K.W. (Purvin and Gertz, Inc. Dallas, TX (United States))

1993-01-11T23:59:59.000Z

58

Toxicity of methyl tertiary butyl ether to Daphnia magna and photobacterium phosphoreum  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is a liquid organic compound added to gasoline to increase its oxygen content and to reduce the emission of carbon monoxide during combustion in many urban areas. In order to meet the 1990 Clean Air Act amendments, gasoline must contain 2.7% oxygen (by weight) or 15% (by volume) of MTBE in gasoline to meet the regulations for the control of carbon monoxide emissions. Health effects caused by inhalation of MTBE include headaches, dizziness, irritated eyes and nausea; MTBE is one of cancer--causing chemicals. Intracaval injection of MTBE (0.2 mg/kg) caused the highest mortality (100%) in rats. General anesthetic effect induced by MTBE was found at or above 1200 mg/kg body weight; Rosenkranz and Klopman (1991) predicted that MTBE is neither a genotoxicant nor a carcinogen. Nevertheless, the safety of using MTBE in oxygenated fuels is now being questioned from its potential as groundwater pollutant. This study measures the toxicity of MTBE to Daphnia magna and Photobacterium phosphoreum. 13 refs.

Gupta, G.; Lin, Y.J. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States)

1995-10-01T23:59:59.000Z

59

Snamprogetti signs MTBE contracts  

SciTech Connect (OSTI)

Snamprogetti (Milan) will use a Russian-developed dehydrogenation process in a world-scale methyl tert-butyl ether (MTBE) plant it is to build at Arzew, Algeria for a previously announced joint venture of Sonatrach (Algiers), Total (Paris), and Ecofuel (Milan). The 600,000-m.t./year plant will be the first in the West to use the improved Snamprogetti-Yarsintez fluidized-bed dehydrogenation (FBD) technology proven on a demonstration plant at Yaroslavl, Russia. The process has also been selected for use in Oxyfuel Corp.`s 500,000-m.t./year MTBE plant near Beaumont, TX. Although the environmental permit is already in place, final agreement for this project has not yet been signed.

Alperowicz, N.

1992-04-15T23:59:59.000Z

60

Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms  

SciTech Connect (OSTI)

Microorganisms indigenous to the stream-bed sediments at two gasoline-contaminated groundwater sites demonstrated significant mineralization of the fuel oxygenates, methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Up to 73% of [U-{sup 14}C]-MTBE and 84% of [U-{sup 14}C]-TBA were degraded to {sup 14}CO{sub 2} under mixed aerobic/anaerobic conditions. No significant mineralization was observed under strictly anaerobic conditions. The results indicate that, under the mixed aerobic/anaerobic conditions characteristic of stream-bed sediments, microbial processes may provide a significant environmental sink for MTBE and TBA delivered to surface water bodies by contaminated groundwater or by other sources.

Bradley, P.M.; Landmeyer, J.E.; Chapelle, F.H. [Geological Survey, Columbia, SC (United States)] [Geological Survey, Columbia, SC (United States)

1999-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

MTBE movements between Texas Gulf Coast plants to be enhanced  

SciTech Connect (OSTI)

This paper reports that Texas Eastern Products Pipeline Co. (Teppco), Houston, has begun construction of its shuttle pipeline, a 10-mile, 6 and 8-in. line to move methyl tertiary butyl ether (MTBE) between producers and refiners along the Houston Ship Channel. Funding for the project has been approved, rights-of-way are secured, and procurement of materials is under way, according to Teppco. The line will flow from the western edge of Shell's refinery eastward to storage facilities of Teppco's Baytown terminal. The shuttle pipeline anticipates the US requirement for oxygenated gasolines that takes effect Nov. 1. Approximately 70% of the available US merchant capacity for MTBE is located along the shuttle's path, Teppco says.

Not Available

1992-07-27T23:59:59.000Z

62

Location of MTBE and toluene in the channel system of the zeolite mordenite: Adsorption and host-guest interactions  

SciTech Connect (OSTI)

This paper reports a study of the location of Methyl Tertiary Butyl Ether (MTBE) and toluene molecules adsorbed in the pores of the organophylic zeolite mordenite from an aqueous solution. The presence of these organic molecules in the zeolite channels was revealed by structure refinement performed by the Rietveld method. About 3 molecules of MTBE and 3.6 molecules of toluene per unit cell were incorporated into the cavities of mordenite, representing 75% and 80% of the total absorption capacity of this zeolite. In both cases a water molecule was localized inside the side pocket of mordenite. The saturation capacity determined by the adsorption isotherms, obtained by batch experiments, and the weight loss given by thermogravimetric (TG) analyses were in very good agreement with these values. The interatomic distances obtained after the structural refinements suggest MTBE could be connected to the framework through a water molecule, while toluene could be bonded to framework oxygen atoms. The rapid and high adsorption of these hydrocarbons into the organophylic mordenite zeolite makes this cheap and environmental friendly material a suitable candidate for the removal of these pollutants from water. - graphical abstract: Location of MTBE (a) and toluene (b) in mordenite channels (projection along the [001] direction). Highlights: Black-Right-Pointing-Pointer We investigated the MTBE and toluene adsorption process into an organophilic zeolite mordenite. Black-Right-Pointing-Pointer The presence of MTBE and toluene in mordenite was determined by X-ray diffraction studies. Black-Right-Pointing-Pointer About 3 molecules of MTBE and 3.6 molecules of toluene per unit cell were incorporated into the zeolite cavities. Black-Right-Pointing-Pointer MTBE is connected to the framework through a water molecule. Black-Right-Pointing-Pointer Toluene is directly bonded to framework oxygen atoms.

Arletti, Rossella, E-mail: rossella.arletti@unito.it [Department of Earth Sciences, University of Torino Via Valperga Caluso 35, I-10125, Torino (Italy)] [Department of Earth Sciences, University of Torino Via Valperga Caluso 35, I-10125, Torino (Italy); Martucci, Annalisa; Alberti, Alberto [Department of Earth Sciences, University of Ferrara, Via G. Saragat 1, I-44100, Ferrara (Italy)] [Department of Earth Sciences, University of Ferrara, Via G. Saragat 1, I-44100, Ferrara (Italy); Pasti, Luisa; Nassi, Marianna [Department of Chemistry, University of Ferrara, Via L. Borsari 26, I-44100 Ferrara (Italy)] [Department of Chemistry, University of Ferrara, Via L. Borsari 26, I-44100 Ferrara (Italy); Bagatin, Roberto [Research Centre for Non-Conventional Energy-Istituto ENI Donegani, Environmental Technologies, Via Fauser 4, I-28100 Novara (Italy)] [Research Centre for Non-Conventional Energy-Istituto ENI Donegani, Environmental Technologies, Via Fauser 4, I-28100 Novara (Italy)

2012-10-15T23:59:59.000Z

63

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

64

EPA proposal sets MTBE back  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) producers were looking for a boost from the official New Year`s start of EPA`s reformulated gasoline (RFG) program. But that prospect has been dimmed by an EPA-proposal-in reaction to concerns about RFG prices-to allow states to withdraw from the program. The states that have opted to out make up 5%-6% of the total RFG pool says Arthur Zadronzy, director/government outreach for MTBE producer Arco Chemical. {open_quotes}This is not a major hit, but it is one we have felt,{close_quotes} he says. Despite the state and EPA actions, MTBE producers are not worried about long-term consequences.

Lucas, A.

1995-01-04T23:59:59.000Z

65

Observation on the biodegradation and bioremediation potential of methyl t-butyl ether  

SciTech Connect (OSTI)

There have been few reports documenting evidence for the biodegradation of the fuel oxygenate alkyl ether, methyl t-butyl ether (MTBE) in groundwater, soils, and biosludges. Partial (or complete) microbial breakdown of MTBE has been observed in an anaerobic subsoil, a river sediment under methanogenic conditions, a cyclohexane-degrading bacterial consortium and a pure culture of the methylotroph, Methylisnus trichosporium OB3b. An aerobic bacterial enrichment (BC-1) isolated from an industrial transient (non-accumulating) metabolic intermediate. The studies suggest that MTBE is cleaved by BC-1 to TBA which is then metabolized via isopropanol and acetone. There is little information on the occurrence of indigenous MTBE-degraders in groundwater, soils and activated sludges. Preliminary evidence has been obtained, however, from a marketing terminal groundwater site that naturally-occurring MTBE-degraders are present in some monitoring wells. Microcosm experiments with groundwater from this aquifer show that MTBE is aerobically degraded (no TBA formed) with a first-order decay rate (0.31/day) similar to BTEX. Also, MTBE did not inhibit the intrinsic biodegradation potential of BTEX in groundwater microcosms. In summary, the data presented indicate that MTBE biodegradation has been observed in some environmental media. Further work is needed to assess the feasibility of using indigenous or derived aerobic and anaerobic MTBE-degrading cultures for treating fuel ethers in groundwaters or wastewater with in-situ or ex-situ bioremediation technologies.

Salanitro, J.; Wisniewski, H.; McAllister, P. [Shell Development Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

66

MTBE from butadiene-rich C/sub 4/s  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE), is made by reacting methanol with isobutylene. The preferred source of isobutylene is a steam cracker C/sub 4/ cut from which butadiene has been removed. However, moving the MTBE synthesis upstream of the butadiene extraction will improve the extraction step. The following is a review of conditions imposed on the MTBE unit's design and operation when placed in this new location.

Ancillotti, F.; Pescarollo, E.; Szatmari, E.; Lazar, L.

1987-12-01T23:59:59.000Z

67

Ethanol Demand in United States Production of Oxygenate-limited Gasoline  

SciTech Connect (OSTI)

Ethanol competes with methyl tertiary butyl ether (MTBE) to satisfy oxygen, octane, and volume requirements of certain gasolines. However, MTBE has water quality problems that may create significant market opportunities for ethanol. Oak Ridge National Laboratory (ORNL) has used its Refinery Yield Model to estimate ethanol demand in gasolines with restricted use of MTBE. Reduction of the use of MTBE would increase the costs of gasoline production and possibly reduce the gasoline output of U.S. refineries. The potential gasoline supply problems of an MTBE ban could be mitigated by allowing a modest 3 vol percent MTBE in all gasoline. In the U.S. East and Gulf Coast gasoline producing regions, the 3 vol percent MTBE option results in costs that are 40 percent less than an MTBE ban. In the U.S. Midwest gasoline producing region, with already high use of ethanol, an MTBE ban has minimal effect on ethanol demand unless gasoline producers in other regions bid away the local supply of ethanol. The ethanol/MTBE issue gained momentum in March 2000 when the Clinton Administration announced that it would ask Congress to amend the Clean Air Act to provide the authority to significantly reduce or eliminate the use of MTBE; to ensure that air quality gains are not diminished as MTBE use is reduced; and to replace the existing oxygenate requirement in the Clean Air Act with a renewable fuel standard for all gasoline. Premises for the ORNL study are consistent with the Administration announcement, and the ethanol demand curve estimates of this study can be used to evaluate the impact of the Administration principles and related policy initiatives.

Hadder, G.R.

2000-08-16T23:59:59.000Z

68

Author's personal copy Automobile proximity and indoor residential concentrations of BTEX and MTBE  

E-Print Network [OSTI]

Author's personal copy Automobile proximity and indoor residential concentrations of BTEX and MTBE to indoor benzene and MTBE concentrations appeared to have been dominated by car exhaust concentrations of other BTEX components and methyl tert-butyl ether (MTBE) have been reported [5,6]. Up until

Siegel, Jeffrey

69

Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co-contaminants  

E-Print Network [OSTI]

Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co November 2005 Key words: aerobic, biodegradation, BTEX, co-contaminant, MTBE, TBA Abstract Contamination of groundwater with the gasoline additive methyl tert-butyl ether (MTBE) is often accompanied by many aromatic

70

MTBE catalyst shows increased conversion in commercial unit  

SciTech Connect (OSTI)

Rising demand for methyl tertiary butyl ether (MTBE) has spawned interest in finding a cost-effective means of increasing production from existing units. A commercial trial of an improved MTBE catalyst was conducted recently at Lyondell Petrochemical Co.'s Channelview, Tex., plant. The new catalyst called Amberlyst 35 Wet, enhanced oxygenate production in the Lyondell trial. The new catalyst changes the activity coefficients of at least one of the components of the MTBE reaction, resulting in higher equilibrium conversion relative to its first-generation counterpart. Key catalyst properties are: particle size, 0.4--1.25 mm; Apparent density, 0.82 g/ml; Surface area, 44 sq m/g; Moisture content, 56%; Concentration of acid sites, 1.9 meq/ml (5.4 meq/g); Porosity, 0.35 cc/g; and Average pore diameter, 300 [angstrom]. Suggested operating conditions are: maximum temperature, 284 F (140 C); minimum bed depth, 24 in. (0.61 m); and liquid hourly space velocity (LHSV), 1--5 hr[sup [minus]1].

Not Available

1994-10-10T23:59:59.000Z

71

MTBE still facing pressure from ethanol under latest fuel proposal  

SciTech Connect (OSTI)

The US EPA's finalized reformulated gasoline rule, part of Phase II of the 1990 Clean Air Act, signals a possible turnaround for the sluggish methyl tert-butyl ether (MTBE) market. But if a 30% renewable fuels proposal favoring ethanol passes, pressure could continue for MTBE.

Lucas, A.

1994-01-26T23:59:59.000Z

72

MTBE: The headache of cleaner air  

SciTech Connect (OSTI)

Gasoline with methyl tertiary butyl ether (MTBE) has been sold in the United States since 1979, when it was added to fuels as an octane enhancer after lead was phased out of motor fuels. Recently it has been introduced as a means of reducing carbon monoxide emissions during the winter months in targeted US cities. However, there is concern over health complaints including headaches, dizziness and nausea from residents of some areas. These reports have launched an era of assidious research by scientists and public health officials across the country to learn more about MTBE`s short-term and long-term, and possibly carcinogenic, health effects. New research should help weigh the risk of MTBE as a possible carcinogen and the effectiveness of MTBE-blended fuels in reducing carbon monoxide levels. The question is whether, in minimizing one risk, is another risk - however small - being introduced?

Kneiss, J.

1995-07-01T23:59:59.000Z

73

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

1991-01-01T23:59:59.000Z

74

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling. Revision 1  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

1991-12-01T23:59:59.000Z

75

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

1991-12-31T23:59:59.000Z

76

High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling  

SciTech Connect (OSTI)

Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

1991-12-01T23:59:59.000Z

77

Experimental Pathology Laboratories, Inc. Methyl-Tertiary-Butyl Ether  

E-Print Network [OSTI]

COORDINATOR'S REPORT FOR LIFETIME CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE-DAWLEY RATS CONDUCTED AT THE CANCER

Baker, Chris I.

78

Falling MTBE demand bursts the methanol bubble  

SciTech Connect (OSTI)

Methanol spot markets in Europe and the US have been hit hard by weakening demand from methyl tert-butyl ether (MTBE) producers. In Europe, spot prices for domestic T2 product have dropped to DM620-DM630/m.t. fob from early-January prices above DM800/m.t. and US spot prices have slipped to $1.05/gal fob from $1.35/gal. While chemical applications for methanol show sustained demand, sharp methanol hikes during 1994 have priced MTBE out of the gasoline-additive market. {open_quotes}We`ve learned an important lesson. We killed [MTBE] applications in the rest of the world,{close_quotes} says one European methanol producer. Even with methanol currently at DM620/m.t., another manufacturer points out, MTBE production costs still total $300/m.t., $30/m.t. more than MTBE spot prices. Since late 1994, Europe`s 3.3-million m.t./year MTBE production has been cut back 30%.

Wiesmann, G.; Cornitius, T.

1995-03-01T23:59:59.000Z

79

Add MTBE unit ahead of alkylation  

SciTech Connect (OSTI)

Approximately three years ago, the people at Diamond Shamrock's Sunray, Texas, refinery recognized a growing demand for high octane super premium unleaded gasoline in their regional marketing area. It was apparent that they would need to change their processing scheme to meet this growing demand. After investigating several options, they decided to install an MTBE (methyl tert-butyl ether) unit upstream of their existing sulfuric acid (H/sub 2/SO/sub 4/) aklylation unit. The new unit would process olefin feed before it entered the alkylation unit. The MTBE unit was expected to improve Diamond Shamrock's gasoline pool in two ways. First, the MTBE would be an additional high octane blending stock for the gasoline pool. Second, the MTBE unit would improve the quality of the olefin stream going to the alkylation unit. Diamond Shamrock brought their MTBE unit onstream in December, 1985. The results of the combined operation exceeded expectations, producing alkylate in excess of 98 RON (Research octane number) and MTBE of 118 RON. These components significantly upgraded the refinery's capability to produce a super premium unleaded gasoline.

Masters, K.R.; Prohaska, E.A.

1988-08-01T23:59:59.000Z

80

The MTBE solution: Octanes, technology, and refinery profitability  

SciTech Connect (OSTI)

This paper has been developed to provide refiners with business decision insight regarding the production of methyl tertiary butyl ether (MTBE) from refinery - (FCC) produced isobutylene. The driving forces making MTBE an attractive investment are examined with regard to the increasing demand for higher octane unleaded gasolines. The decision to proceed with MTBE production depends on the profitability of such an investment and the refiner's ability to meet market demands using available processing equipment, refinery produced streams and external feedstocks. The factors affecting this decision are analyzed in this paper and include: industry ability to meet rising octane demand; profit potential realized by diverting isobutylene to MTBE; availability of technology for producing MTBE; and investment and operating costs required to produce MTBE. Chemical Research and Licensing and NEOCHEM have developed a simple, low cost process to produce MTBE, reducing the excessive equipment and high operating costs that were associated with conventional MTBE designs. The economics and process benefits of installing a CRandL/NEOCHEM MTBE process are examined within the framework of a generalized medium-sized refinery configuration.

Lander, E.P.; Hubbard, J.N.; Smith, L.A.

1983-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

82

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance of anaerobes  

E-Print Network [OSTI]

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance Keywords: Methylmercury Oxygen minimum zone Arabian Sea Equatorial Eastern Pacific Mercury methylation Although a large fraction of the world's population is exposed to mercury through consumption of marine

Morel, François M. M.

83

Texas plant will use new process to coproduce propylene oxide, MTBE  

SciTech Connect (OSTI)

Texaco Chemical Co. is building a $400 + million facility to produce 1.2 billion lb/year (14,000 b/d) methyl tertiary butyl ether (MTBE) and 400 million lb/year (about 500 metric tons/day) propylene oxide (PO). The facility-under construction at Port Neches, Tex.-will utilize a newly developed Texaco process that coproduces the two chemicals. The process produces propylene oxide and tertiary butyl alcohol (TBA) from the reaction of isobutane with oxygen in one step, then in a second step with propylene. The TBA is then reacted with methanol in a one-step process that synthesizes MTBE. The paper describes the Port Neches facilities, construction schedule, feedstocks, product uses, and auxiliary equipment.

Rhodes, A.K.

1993-08-30T23:59:59.000Z

84

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

85

Veba in MTBE project, cutting aromatics  

SciTech Connect (OSTI)

The new owners of the refinery and petrochemical complex at Schwedt in eastern Germany-RWE-DEA (Hamburg), Veba Oel (Gelsenkirchen), Agip (Rome), Total (Paris), and Elf-Aquitaine (Paris)-plan to build a 60,000-m.t./year methyl tert-butyl ether (MTBE) plant at the site for 1994-1995 completion. The MTBE project forms part of the consortium`s announced DM1.5-billion ($500 million) investment program for the complex that aims to raise refinery throughput from 8 million m.t./year to 12 million m.t./year by 1994 and hike production of naphtha and benzene.

Young, I.; Roberts, M.

1992-04-15T23:59:59.000Z

86

Methanex considers methanol, MTBE in Qatar  

SciTech Connect (OSTI)

CW has learned that Methanex Corp. is considering entering one of two methanol and methyl tert-butyl ether (MTBE) projects in Qatar. Executive v.p. Michael Wilson says that part of the company`s New Zealand plant could be moved to a site in Qatar, which would lower capital costs for the possible project by $75 million-$100 million. Both Qatar General Petroleum Corp. and Qatar Fuel Additives are developing methanol and MTBE projects at Umm Said, Qatar. Methanex says its goal is to ensure low-cost feedstocks.

NONE

1995-12-13T23:59:59.000Z

87

Total to withdraw from Qatar methanol - MTBE?  

SciTech Connect (OSTI)

Total is rumored to be withdrawing from the $700-million methanol and methyl tert-butyl ether (MTBE) Qatar Fuel Additives Co., (Qafac) project. The French company has a 12.5% stake in the project. Similar equity is held by three other foreign investors: Canada`s International Octane, Taiwan`s Chinese Petroleum Corp., and Lee Change Yung Chemical Industrial Corp. Total is said to want Qafac to concentrate on methanol only. The project involves plant unit sizes of 610,000 m.t./year of MTBE and 825,000 m.t./year of methanol. Total declines to comment.

NONE

1996-05-01T23:59:59.000Z

88

he increasing frequency of detection of the widely used gasoline additive methyl tert-  

E-Print Network [OSTI]

T he increasing frequency of detection of the widely used gasoline additive methyl tert- butyl, the September 15, 1999, Report of the Blue Ribbon Panel on Oxygenates in Gasoline (1) states that between 5 with large releases (e.g., LUFTs). Unprecedented growth in use Use of MTBE as a gasoline additive began

89

Ecofuel plans MTBE plant in Italy  

SciTech Connect (OSTI)

Ecofuel (Milan), an ENI company, is evaluating construction of a new methyl tert-butyl ether (MTBE) plant in Italy, but has shelved plans for a world-scale MTBE unit in Mexico. The Italian unit is tied to ethylene expansion now under way. Later this year EniChem (Milan), a sister company, is due to complete construction of a 360,000-m.t./year cracker at Brindisi. The C{sub 4} stream available there and from the existing cracker at Priolo in Sicily should provide enough feed for a unit of up to 100,000 m.t./year of MTBE capacity. Some of the feedstock could also come from the Ravenna cracker.

Alperowicz, N.

1992-04-29T23:59:59.000Z

90

A review of the environmental behavior and fate of fuel oxygenates  

SciTech Connect (OSTI)

The ways in which fuel oxygenate compounds behave in water, soil, and air are determined by how they partition among the different media. The behavior of a gasoline oxygenate in water is affected by the oxygenate`s (1) solubility in water from gasoline: (2) partitioning between water and soil materials; and (3) partitioning between air and water. Water in equilibrium with oxygenated gasoline can contain high concentrations of the oxygenate. For example, at room temperature water solubility of methyl tert-butyl ether (MTBE) will be about 5,000 mg/L for a gasoline that is 10% MTBE by weight. In contrast, the total hydrocarbon solubility in water is typically about 120 mg/L for nonoxygenated gasoline. Fuel oxygenates sorb only weakly to soil and aquifer materials. Therefore, sorption to these materials will not significantly retard their transport by ground water. Fuel oxygenates tend to partition into atmospheric water, including precipitation. For example, washout of gas-phase MTBE by precipitation would not, by itself, greatly alter the gas-phase concentration of the compound in the atmosphere. Nevertheless, the partitioning of MTBE to precipitation is strong enough to allow for submicrogram per liter to 3 pg/L or more inputs of MTBE to ground water and surface water. Occurrence data for MTBE in water and air supports partition theoretical calculations. MTBE and other alkyl ether oxygenates have half lives in the atmosphere that range from about 1 to 14 days. These compounds are generally considered recalcitrant in ground water; whereas ethanol and methanol will readily undergo microbial degradation except where present in concentrations toxic to microorganisms.

Squillace, P.J.

1995-12-31T23:59:59.000Z

91

MTBE growth limited despite lead phasedown in gasoline  

SciTech Connect (OSTI)

This month's legislated reduction of the allowable amount of lead additives in gasoline will increase demand strongly for methyl-tert-butyl ether (MTBE) as an octane enhancer, but the economics of the refinery business and the likelihood of rapidly increasing high-octane gasoline imports probably will limit the size of the business in coming years. MTBE will be used to fill the octane gap now, but economics and imports of gasoline later on could hold down demand. The limited growth in sales of MTBE is discussed.

Storck, W.

1985-07-15T23:59:59.000Z

92

Cytotoxic and DNA-damaging effects of methyl tert-butyl ether and its metabolites on HL-60 cells in vitro  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is a widely used oxygenate in unleaded gasoline; however, few studies have been conducted on the toxicity of this compound. This study evaluates the cytotoxic and DNA-damaging effects of MTBE and its metabolites in a human haemopoietic cell line, HL-60. The metabolites of MTBE studied include tertiary butyl alcohol (TBA), {alpha}-hydroxyisobutyric acid (HIBA), and formaldehyde. Comet assay is used to assess DNA damage, and the cytotoxicity is investigated by lactate dehydrogenease (LDH) release. The results show no significant cytotoxic effects of MTBE, TBA, and HIBA over a concentration ranging from 1 to 30 mM. Formaldehyde, in contrast, causes a substantial LDH release at a concentration of 5 {mu}M. Hydrogen peroxide, a known oxidative agent, at concentrations ranging from 10 to 100 {mu}M, produces a significant dose-related increase in DNA damage, whereas a much higher concentration of MTBE (1 to 30 mM) is required to produce a similar observation. The genotoxic effects of TBA and HIBA appear to be identical to that of MTBE. Conversely, DNA damage is observed for formaldehyde at a relatively low concentration range (5 to 100 {mu}M). These findings suggest that MTBE and its metabolites, except formaldehyde, have relatively low cytotoxic and genotoxic effects. 16 refs., 4 figs.

Tang, G.H. [Xian Medical Univ. (China); Shen, Y.; Shen, H.M. [National Univ. of Singapore (Singapore)] [and others

1996-12-31T23:59:59.000Z

93

High-resolution NMR process analyzer for oxygenates in gasoline  

SciTech Connect (OSTI)

We report a high-resolution 42-MHz[sup 1]HFT-NMR instrument that is suitable for use as a process analyzer and demonstrate its use in the determination of methyl tert-butyl ether (MTBE) in a flowing stream of gasoline. This spectrometer is based on a 55-kg permanent magnet with essentially no fringe field. A spectral resolution of 3 Hz was typically obtained for spinning samples, and this performance was only slightly degraded with flowing samples. We report a procedure for magnet drift compensation using a software procedure rather than a field-frequency lock channel. This procedure allowed signal averaging without loss of resolution. Regulatory changes to be implemented in the near future have created a need for the development of methods for the determination of MTBE and other oxygenates in reformulated gasolines. Existing methods employing gas chromatography are not fast enough for process control of a gasoline blender and suffer from other limitations. This study demonstrates that process analysis NMR is well-suited to the determination of MTBE in a simulated gasoline blender. The detection limit of 0.5 vol % MTBE was obtained with a measurement time of 1 min. The absolute standard deviation of independent determinations was 0.17% when the MTBE concentration was 10%, a nominal value. Preliminary results also suggest that the method may be applicable to gasolines containing mixtures of oxygenate additives as well as the measurement of aromatic and olefinic hydrogens. 33 refs., 9 figs.

Skloss, T.W.; Kim, A.J.; Haw, J.F. (Texas A M Univ., College Station, TX (United States))

1994-02-15T23:59:59.000Z

94

MTBE, ethanol rules come under fire  

SciTech Connect (OSTI)

EPA is facing stiff challenges to the mandates for methyl tert-butyl ether (MTBE) and ethanol in its reformulated gasoline (RFG) program. Wisconsin officials are receiving hundreds of complaints about the alleged health effects and other problems with MTBE added to gasoline, and Gov. Tommy Thompson is demanding that EPA suspend the RFG program until April 1. Rep. James Sensenbrenner (R., WI) is threatening to introduce a bill to repeal the program in Wisconsin if EPA does not comply. However, EPA administrator Carol Browner says the agency will {open_quotes}defer any decision{close_quotes} on the request. EPA has sent technical experts to Milwaukee to respond to and monitor citizens` complaints.

Begley, R.

1995-03-01T23:59:59.000Z

95

Modeling the atmospheric inputs of MTBE to groundwater systems  

SciTech Connect (OSTI)

A numerical transport model was used to calculate the movement of methyl-t-butyl ether (MTBE) and several other volatile organic compounds (VOCs) from the atmosphere downward through the unsaturated zone and into shallow groundwater. Simulations were carried out for periods as long as 10 years to investigate whether a gaseous atmospheric MTBE source at typical ambient concentrations could account for the presence of MTBE in shallow groundwater at the types of low ug/L levels that have been found during the National Water Quality Assessment Program currently being conducted by the US Geological Survey. The simulations indicate that downward movement of MTBE to shallow groundwater will be very slow when there is no net downward movement of water through the vadose zone. For example, for a vadose zone composed of fine sand, and assuming tens of cm of infiltration, then only a few years will be required for water at a water table that is 5.0 m below ground surface to attain MTBE levels that correspond to saturation with respect to the atmospheric source gaseous concentration. An on/off atmospheric source, as might occur in the seasonal use of MTBE, will lead to concentrations in shallow groundwater that correspond to saturation with the time-averaging atmospheric source concentration.

Pankow, J.F.; Johnson, R.L. [Oregon Graduate Inst., Portland, OR (United States). Dept. of Environmental Science and Engineering; Thomson, N.R. [Univ. of Waterloo, Ontario (Canada). Dept. of Civil Engineering

1995-12-31T23:59:59.000Z

96

Photocatalytic reactions of oxygenates on tropospheric oxide particles  

SciTech Connect (OSTI)

Oxygenates such as ethanol and tert-butyl methyl ether (MTBE) are finding increased use as additives to fuels. The relative merits of ethanol and MTBE have become the focus of intense debate with their ultimate fate as fugitive emissions representing one aspect of this controversy. Both species are known to react homogeneously with photogenerated OH radicals. Here we show that both can also photoreact on suspended solid particulates in the atmosphere with rates comparable to those of OH reactions. Heterogeneous reactions of ethanol yield acetaldehyde and those of MTBE give isobutene and formaldehyde (carcinogenic). Experiments by spectroscopic and kinetic techniques show that the active phases in fly ash are Fe and Ti oxides. In addition, the effects of humidity and alkali addition on the activity and selectivity of these reactions are also discussed. This work appears to be the first demonstration that volatile organic compounds can react as fast by a heterogeneous mechanism as by a homogeneous one in the atmosphere.

Idriss, H.; Seebauer, E.G.; Miller, A. [Univ. of Illinois, Urbana, IL (United States)

1996-10-01T23:59:59.000Z

97

Remediation of MTBE in groundwater: A case where pump-and-treat works  

SciTech Connect (OSTI)

Two case studies are discussed in which groundwater pumping reduced levels of dissolved methyl tertiary butyl ether (MTBE) in groundwater by more than two orders of magnitude, in some cases to below detection limits. MTBE contamination in groundwater is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Since its Henry`s constant is low, in situ removal of MTBE from groundwater by air sparging is slow, and MTBE does not rapidly degrade, either biologically or abiotically. Therefore, groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater. Pumping groundwater can reduce MME levels to below detection limits within a few years, because MTBE in the subsurface is found mostly dissolved in groundwater. In contrast, the more hydrophobic gasoline hydrocarbons exist mostly in pockets of separate phase material and adsorbed to soil particles and dissolve slowly in groundwater. Hydrocarbon concentrations are rarely reduced to closure levels within a reasonable time frame by pumping. Sites in eastern Massachusetts and southern New Jersey, where groundwater was contaminated with MTBE due to releases of unleaded gasoline from underground storage tanks, are discussed. At these sites, average MTBE levels were reduced by two to three orders of magnitude, from several ppm or more to less than 10 ppb within three years by pumping groundwater at 10 to 30 gpm.

Bass, D.H.; Riley, B. [Groundwater Technology, Inc., Norwood, MA (United States); Farrell, T. [Groundwater Technology, Inc., Trenton, NJ (United States)

1994-12-31T23:59:59.000Z

98

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 2.  

E-Print Network [OSTI]

vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern MTBE treatment are discussed. Introduction The rapidly rising number of reports of groundwater con- taminated with the gasoline additive methyl tert-butyl ether (MTBE) has raised concerns about its

99

Exposure to methyl tert-butyl ether and benzene among service station attendants and operators  

SciTech Connect (OSTI)

Concerns for atmospheric pollution from auto exhaust have led to the blending of {open_quotes}oxygenates{close_quotes} with motor fuels. The most common oxygenate, methyl tert-butyl ether (MTBE) is currently required within several metropolitan areas (Denver and Phoenix) in the range of 12% of the motor fuel. Amendments to the Clean Air Act may expand this requirement to as many as 44 other areas of the United States in the near future. In consideration of the magnitude of potential uncontrolled exposures from its extensive use and a related concern involving the potential influence of MTBE blending on exposures to other constituents of gasoline (particularly benzene), an evaluation of exposures among service station attendants and operators was undertaken at the request, and in cooperation with, the American Petroleum Institute during the latter part of 1990. For application of the survey results to a broad audience, three categories or types of service stations were identified with regard to MTBE use and exposure potential: (a) service stations that do not use MTBE or use it only as an octane enhancer, (b) service stations with seasonal requirements to use 12-15% MTBE (the Denver, Colorado, and Phoenix, Arizona, metropolitan areas), and (c) service stations equipped with stage II (active) vapor recovery systems (several coastal areas, most notably Southern California). 4 refs., 4 tabs.

Hartle, R. [National Inst. for Occupational Safety and Health, Cincinnati, OH (United States)

1993-12-01T23:59:59.000Z

100

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network [OSTI]

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Determination of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Water by Solid-Phase Microextraction/Head Space Analysis in Comparison to EPA Method 5030/8260B  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is now one of the most common groundwater contaminants in the United States. Groundwater contaminated with MTBE is also likely to be contaminated with tert-butyl alcohol (TBA), because TBA is a component of commercial grade MTBE, TBA can also be used as a fuel oxygenate, and TBA is a biodegradation product of MTBE. In California, MTBE is subject to reporting at concentrations greater than 3 {micro}g/L. TBA is classified as a ''contaminant of current interest'' and has a drinking water action level of 12 {micro}g/L. In this paper, we describe the development and optimization of a simple, automated solid phase microextraction (SPME) method for the analysis of MTBE and TBA in water and demonstrate the applicability of this method for monitoring MTBE and TBA contamination in groundwater, drinking water, and surface water. In this method, the headspace (HS) of a water sample is extracted with a carboxen/polydimethylsiloxane SPME fiber, the MTBE and TBA are desorbed into a gas chromatograph (GC), and detected using mass spectrometry (MS). The method is optimized for the routine analysis of MTBE and TBA with a level of quantitation of 0.3 {micro}g/L and 4 {micro}g/L, respectively, in water. MTBE quantitation was linear for over two orders of concentration (0.3 {micro}g/L -80 {micro}g/L). TBA was found to be linear within the range of 4 {micro}g/L-7,900 {micro}g/L. The lower level of detection for MTBE is 0.03 {micro}g/L using this method. This SPME method using headspace extraction was found to be advantageous over SPME methods requiring immersion of the fiber into the water samples, because it prolonged the life of the fiber by up to 400 sample analyses. This is the first time headspace extraction SPME has been shown to be applicable to the measurement of both MTBE and TBA at concentrations below regulatory action levels. This method was compared with the certified EPA Method 5030/8260B (purge-and-trap/GC/MS) using split samples from laboratory bioreactors treating MTBE contaminated water and applied to environmental samples collected throughout the East Bay area of California. Results from the SPME-HS/GC/MS method were directly comparable to the EPA Method 5030/8260B. This method provides an simple, inexpensive, accurate, and sensitive alternative to EPA Method 5030/8260B for the analysis of MTBE and TBA in water samples.

Oh, Keun-Chan; Stringfellow, William T.

2003-10-02T23:59:59.000Z

102

The current status of the U.S. MTBE industry  

SciTech Connect (OSTI)

This paper reviews the status of the MTBE industry from its beginnings as a result of the Clean Air Act Amendments and the need for the use of oxygenates in non-attainment areas. During 1990--93 three world scale merchant plants were constructed and in 1994 two more were brought on stream. The paper tabulates reasons why MTBE gained the lion`s share of the oxygenates market. Finally the paper discusses the problems that now plague the industry and their causes.

Rose, G.M. [Global Octanes Corp., Houston, TX (United States)

1995-12-31T23:59:59.000Z

103

Intrinsic bioremediation of a BTEX and MTBE plume under mixed aerobic/denitrifying conditions  

SciTech Connect (OSTI)

A shallow Coastal Plain aquifer in rural Sampson Country, North Carolina, has been contaminated with petroleum hydrocarbon from a leaking underground storage tank containing gasoline.An extensive field characterization has been performed to define the horizontal and vertical distribution of soluble gasoline components and indicator parameters. A plume of dissolved methyl tert-butyl ether (MTBE) and the aromatic hydrocarbons benzene, toluene, ethylbenzene, and xylene isomers (BTEX) is present in the aquifer and has migrated over 600 ft from the source area. Background dissolved oxygen concentrations range from 7 to 8 mg/L, and nitrate concentrations range from 5 to 22 mg/L as N due to extensive fertilization of fields surrounding the spill. In the center of the BTEX plume, oxygen concentrations decline to less than 1 mg/L while nitrate concentrations remain high. The total mass flux of MTBE and all BTEX components decline with distance downgradient relative to a conservative tracer (chloride). At the source, the total BTEX concentration exceeds 75 mg/L while 130 ft downgradient, total BTEX concentrations are less than 4.9 mg/L, a 15-fold reduction. Toluene and ethylbenzene decline most rapidly followed by m-p-xylene, o-xylene and finally benzene. Biodegradation of TEX appears to be enhanced by the excess nitrate present in the aquifer while benzene biodegradation appears to be due to strictly aerobic processes.

Borden, R.C.; Daniel, R.A. [North Carolina State Univ., Raleigh, NC (United States). Civil Engineering Dept.

1995-09-01T23:59:59.000Z

104

Health risks associated with exposure to gasoline additives-methyl tertiary butyl ether [MTBE]. Hearing before a Subcommittee of the Committee on Appropriations, United States Senate, One Hundred Third Congress, First Session, Special Hearing  

SciTech Connect (OSTI)

This hearing focuses on an Alaskan study by the Centers for Disease Control which examines possible health risks associated with exposure to gasoline additive know as MTBE. Testimony is given by Dr. William Roper, Director, CDC.

Not Available

1993-01-01T23:59:59.000Z

105

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

106

Effect of lower feedstock prices on economics of MTBE complex  

SciTech Connect (OSTI)

Economic evaluation of the methyl tertiary butyl ether (MTBE) complex was carried out starting from n-butane and by captive production of methanol from natural gas. The processing steps consist of isomerization of n-butane to isobutane, dehydrogenation of isobutane to make isobutene, and finally, the reaction of isobutene with methanol to produce MTBE. Two different plant sizes were considered, and the effect of 30% lower feedback prices on profitability was studied. It was found that the raw materials cost is a dominant component, composing about 55% of the total production cost. An internal rate of return of 19% could be realized for 500,000 tons per annum MTBE complex based on economic data in mid-1993. The payback period estimated at this capacity was 3.8 years, and the break-even capacity was 36.6%.

Rahman, F.; Hamid, S.H.; Ali, M.A. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia)

1996-01-01T23:59:59.000Z

107

Fast photoreactions of ethanol and MTBE on tropospheric metal oxide particles  

SciTech Connect (OSTI)

Ethanol (EtOH) and tert-Butyl methyl ether (MTBE) are both finding increased use as oxygenated additives to fuels. However, the environmental fate in the troposphere of these species is unclear when they escape as fugitive emissions. In several locations there are reports of human illness in response to MTBE in particular. Volatile organic compounds (VOC`s) such as these are generally thought to react by a variety of homogeneous free-radical mechanisms, usually beginning with attack by OH radical. However, we show by laboratory kinetic studies that the heterogeneous photoreaction on solid suspended metal-oxide particulates such as fly ash proceeds with a comparable rate, especially in urban environments. EtOH reacts to form acetaldehyde, and EtOH forms isobutene, methanol, and formaldehyde. Our work appears to be the first-ever demonstration that VOC`s can react as fast by a heterogeneous mechanism as by a homogeneous one in the atmosphere. Experiments by various optical and kinetic techniques show that the active phases in fly ash are Fe oxides, which are fairly abundant in other atmospheric particulates as well.

Idriss, H.; Seebauer, E.G. [Univ. of Illinois, Urbana, IL (United States)

1995-12-31T23:59:59.000Z

108

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

109

Detections of MTBE in surficial and bedrock aquifers in New England  

SciTech Connect (OSTI)

The gasoline additive methyl tert-butyl ether (MTBE) was detected in 24% of water samples collected from surficial and bedrock aquifers in areas of New England. MTBE was the most frequently detected volatile organic compound among the 60 volatile chemicals analyzed and was present in 33 of 133 wells sampled from July 1993 through September 1995. The median MTBE concentration measured in ground-water samples was 0.45 microgram per liter and concentrations ranged from 0.2 to 5.8 microgram per liter. The network of wells sampled for MTBE consisted of 103 monitoring wells screened in surficial sand-and-gravel aquifers and 30 domestic-supply wells in fractured crystalline bedrock aquifers. Seventy-seven percent of all MTBE detections were from 26 shallow monitoring wells screened in surficial aquifers. MTBE was detected in42% of monitoring wells in urban areas. In agricultural areas, MTBE was detected i 8% (2 of 24) of wells and was not detected in undeveloped areas. Sixty-two percent of the MTBE detections in surficial aquifers were from wells within 0.25 mile of gasoline stations or underground gasoline storage tanks; all but one of these wells were in Connecticut and Massachusetts, where reformulated gasoline is used. MTBE was detected in 23% of deep domestic-supply wells that tapped fractured bedrock aquifers. MTBE was detected in bedrock wells only in Connecticut and Massachusetts; land use near the wells was suburban to rural, and none of the sampled bedrock wells were within 0.25 mile of a gasoline station.

Grady, S.J. [Geological Survey, Hartford, CT (United States)

1995-12-31T23:59:59.000Z

110

Remediation of overlapping benzene/MTBE and MTBE-only plumes: A case study  

SciTech Connect (OSTI)

Two overlapping dissolved hydrocarbon plumes were identified in the shallow water-bearing zone at a commercial vehicle service and fueling facility. Plume 1 originated from a pre-1993 gasoline product line/dispenser leak. This plume contained a relatively common mix of benzene, toluene, ethylbenzene, xylenes (BTEX), and methyl tert-butyl ether (MTBE); benzene and MTBE were identified as the Plume 1 contaminants of concern based on their detection at approximately 200 {mu}g/l each, which exceeded regulatory guidance. Plume 2, which was detected in the tank cavity during UST removal, resulted from gasoline line leaks/underground storage tank overfills. Although the majority of impacted soils in both the dispenser and tank cavity areas were removed during UST excavation, rainfall during impacted soil removal mobilized the MTBE contained in the soils to groundwater. As a result, Plume 2 contained approximately 900 {mu}g/l MTBE while BTEX compounds were non-detect. Although the impacted zone sustained an approximate yield of only 0.3 gallon per minute, Pennsylvania regulations dictate that this zone must be treated as an aquifer. The failure of remediating gasoline plumes using pump-and-treat has been predominantly due to BTEX`s tendency to adsorb onto soil, creating a residual-phase product layer which acts as a continuing source of dissolved-phase BTEX. Based on this experience, most groundwater and remediation professionals reject pump-and-treat as a viable remedial option, except in situations where controlling groundwater movement is the predominant goal.

Carpenter, P.L. [TolTest, Inc., Pittsburgh, PA (United States); Vinch, C.A. [Ryder Transportation Services, Lawrenceville, NJ (United States)

1997-12-31T23:59:59.000Z

111

Toxicological and performance aspects of oxygenated motor vehicle fuels  

SciTech Connect (OSTI)

At the request of the Environmental Protection Agency, the committee reviewed a draft of a federal report that assesses the effects of oxygenated fuels on public health, air quality, fuel economy, engine performance, and water quality. The committee determined that much of the federal report adequately represents what is known about the effects of methyl tertiary-butyl ether (MTBE) -- the most commonly used additive in the federal oxygenated-fuels program -- on health, the environment, and motor vehicles. MTBE, a chemical added to gasoline to reduce carbon monoxide pollution, appears not to pose a substantial human health risk, but more-definitive data are needed to assess short-term health effects and to determine whether this additive is effective in reducing carbon monoxide pollution in cold environments.

NONE

1996-12-31T23:59:59.000Z

112

Lyondell`s new isobutylene route could fuel an MTBE capacity boost  

SciTech Connect (OSTI)

Driven by the hot growth prospects for methyl tert-butyl ether (MTBE), Lyondell Petrochemical (Houston) has developed a route to isobutylene it claims can produce the MTBE feedstock at half the capital cost of alternative synthesis technology. If proved, the process will be used in a new 7500-10,000 bbl/day MTBE plant at Channelview, TX. Lyondell also hopes to license the technology. {open_quotes}With expanding MTBE capacity, we will have to have new routes to isobutylene,{close_quotes} says Bob G. Gower, president and CEO of Lyondell. {open_quotes}We think this is a good fit within Lyondell, but also that it is important technology.{close_quotes} Gower declines to detail its specifics, but says it is a one-step isomerization of n-butenes to isobutylene. The firm has tested the process at a pilot unit and plans a demonstration unit in 1992.

Rotman, D.; Wood, A.

1992-03-25T23:59:59.000Z

113

Synthesis of MTBE during CO hydrogenation: Reaction sites required  

SciTech Connect (OSTI)

Synthesis of methyl tert-butyl ether (MTBE) during carbon monoxide (CO) hydrogenation has been studied with the following reaction schemes: (1) the addition of isobutylene during CO hydrogenation over metal catalysts active for methanol synthesis (Pd/SiO{sub 2} and Li-Pd/SiO{sub 2}) and (2) the addition of isobutylene during CO hydrogenation over a dual bed configuration consisting of Li-Pd/SiO{sub 2} and a zeolite (H-ZSM-5 or HY). The addition of isobutylene during methanol synthesis over the supported Pd catalysts indicated that MTBE cannot be formed on metal sites from a reaction of isobutylene with methanol precursors. However, addition of isobutylene to the syngas feed over a dual bed consisting of a methanol synthesis catalyst and an acid zeolite downstream of the methanol synthesis catalyst showed that MTBE can be synthesized during CO hydrogenation provided acid sites are available. In order to get higher conversions of methanol to MTBE, optimization of the acid catalyst and/or reaction conditions would be required to minimize formation of byproduct hydrocarbons.

Kazi, A.M.; Goodwin, J.G. Jr.; Marcelin, G.; Oukaci, R. [Univ. of Pittsburgh, PA (United States). Dept. of Chemical and Petroleum Engineering

1995-03-01T23:59:59.000Z

114

Iran plans huge private sector MTBE plant  

SciTech Connect (OSTI)

An export-oriented 1-million m.t./year methyl tert-butyl ether (MTBE) plant is planned as one of Iran`s private sector investment projects. State-owned National Petrochemical Co (NPC; Tehran) and the Dubai-based Iranian businessman Abdul Wahab Galadari have signed a letter of intent allowing Galadari to develop the venture. Colt Engineering (Calgary, AL) is assisting Galadari with costs, planning and technology selection for the estimated $300-million plus venture. An important meeting with NPC is scheduled end of this month, says Galadari, and a financial package should be put together by end of March or April. The facility will most likely be wholly-owned by the Galadari family, roughly 50% by members resident in Iran and the remainder by the Dubai-based concern A.W. Galadari Sons. NPC says it may take a token shareholding in the venture.

Alperowicz, N.

1992-01-15T23:59:59.000Z

115

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network [OSTI]

and oxidation mechanisms of methyl t-butyl ether (MTBE) in a dense medium plasma (DMP) reactor utilizing gas for the removal of MTBE from an aqueous solution in the DMP reactor. Rate constants are also derived for three reactor configurations and two pin array spin rates. The oxidation products from the treatment of MTBE

Dandy, David

116

Evidence for Thiol-Dependent Production of Oxygen Radicals by 4-Methyl-5-pyrazinyl-3H-1,2-dithiole-3-thione  

E-Print Network [OSTI]

to a peroxide species that undergoes a trace metal-catalyzed, Fenton-type reaction to generate oxygen radicalsEvidence for Thiol-Dependent Production of Oxygen Radicals by 4-Methyl-5-pyrazinyl-3H-1,2-dithiole the conversion of molecular oxygen to reactive oxygen radicals. Using a plasmid-based assay that monitors DNA

Gates, Kent. S.

117

LIDEM unit for the production of methyl tert-butyl ether from butanes  

SciTech Connect (OSTI)

One of the basic problems in the production of motor fuels is how to obtain high-octane unleaded gasolines that will meet today`s ecological requirements. The term {open_quotes}reformulated gasolines{close_quotes} has come into general use throughout the world to denote fuels with a certain chemical composition. These gasolines consist of preselected components; as shown by worldwide experience, they must include oxygen-containing compounds that are distinguished by high octane numbers and low reactivities. Standards in effect in the United States, Japan, and certain Western European countries require that automotive gasolines must contain at least 2-4% by weight of oxygen-containing compounds (calculated as oxygen). In the last 15 years, in order to meet these requirements, production has been set up in various countries for the manufacture of high-octane oxygen-containing components known as oxygenates. The most common of these is methyl tert-butyl ether (MTBE), obtained by etherification of isobutene by methanol. Process technology developed by this last organization was used as the basis for constructing a unit in the Nizhnekamskneftekhim Production Association and at the Mazheikyai Petroleum Refinery in Lithuania. MTBE production has been held back mainly by a shortage of isobutene, which is obtained mainly from butane-butene cuts produced in cat crackers. In order to alleviate this shortage, it has been proposed that MTBE should be obtained from saturated C{sub 4} hydrocarbons that are recovered in processing oilfield associated gas, and also in the refinery from primary distillation units, catalytic reformers, and hydrocrackers. A working design was developed in 1991-1992 by Lengiproneftekhim for a basically new combination unit designed for the processing of saturated C{sub 4} hydrocarbons, which has been termed the LIDEM unit (Leningrad - isomerization - dehydrogenation - MTBE).

Rudin, M.G.; Zadvornov, M.A.

1994-09-01T23:59:59.000Z

118

Whole-genorne analysis of the methyl tert-butyl ether-degrading beta-proteobacterium Methylibium petroleiphilum PM1  

SciTech Connect (OSTI)

Methylibium petroleiphilum PM1 is a methylotroph distinguished by its ability to completely metabolize the fuel oxygenate methyl tert-butyl ether (MTBE). Strain PM1 also degrades aromatic (benzene, toluene, and xylene) and straight-chain (C, to C,,) hydrocarbons present in petroleum products. Whole-genome analysis of PM1 revealed an similar to 4-Mb circular chromosome and an similar to 600-kb megaplasmid, containing 3,831 and 646 genes, respectively. Aromatic hydrocarbon and alkane degradation, metal resistance, and methylotrophy are encoded on the chromosome. The megaplasmid contains an unusual t-RNA island, numerous insertion sequences, and large repeated elements, including a 40-kb region also present on the chromosome and a 29-kb tandem repeat encoding phosphonate transport and cobalamin biosynthesis. The megaplasmid also codes for alkane degradation and was shown to play an essential role in MTBE degradation through plasmid-curing experiments. Discrepancies between the insertion sequence element distribution patterns, the distributions of best BLASTP hits among major phylogenetic groups, and the G+C contents of the chromosome (69.2%) and plasmid (66%), together with comparative genome hybridization experiments, suggest that the plasmid was recently acquired and apparently carries the genetic information responsible for PM1's ability to degrade MTBE. Comparative genomic hybridization analysis with two PM1-like MTBE-degrading environmental isolates (similar to 99% identical 16S rRNA gene sequences) showed that the plasmid was highly conserved (ca. 99% identical), whereas the chromosomes were too diverse to conduct resequencing analysis. PM1's genome sequence provides a foundation for investigating MTBE biodegradation and exploring the genetic regulation of multiple biodegradation pathways in M. petroleiphilum and other MTBE-degrading beta-proteobacteria.

Kane, Staci R. [Lawrence Livermore National Laboratory (LLNL); Chakicherla, Anu Y. [Lawrence Livermore National Laboratory (LLNL); Chain, Patrick S. G. [Lawrence Livermore National Laboratory (LLNL); Schmidt, Radomir [University of California, Davis; Shin, M [U.S. Department of Energy, Joint Genome Institute; Legler, Tina C. [Lawrence Livermore National Laboratory (LLNL); Scow, Kate M. [University of California, Davis; Larimer, Frank W [ORNL; Lucas, Susan [Joint Genome Institute, Walnut Creek, California; Richardson, P M [U.S. Department of Energy, Joint Genome Institute; Hristova, Krassimira R. [University of California, Davis

2007-03-01T23:59:59.000Z

119

The Social Costs of an MTBE Ban in California  

E-Print Network [OSTI]

349 The Social Costs of an MTBE Ban in California REFERENCESD.E. Rolston. Impacts of MTBE on California Groundwater. Environmental Assessment of MTBE, Vol. 4. A. Keller et al. ,

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

120

Effects of temperature and acidic pre-treatment on Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

The effects of temperature and acidic pretreatment on Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC, derived from bituminous coal) were investigated. Limiting factors in MTBE removal in GAC include the heterogeneous distribution of amended Fe, and slow intraparticle diffusive transport of MTBE and hydrogen peroxide (H{sub 2}O{sub 2}) into the 'reactive zone'. Acid pretreatment of GAC before Fe amendment altered the surface chemistry of the GAC, lowered the pH point of zero charge, and resulted in greater penetration and more uniform distribution of Fe in GAC. This led to a condition where Fe, MTBE, and H{sub 2}O{sub 2} coexisted over a larger volume of the GAC contributing to greater MTBE oxidation and removal. H{sub 2}O{sub 2} reaction and MTBE removal in GAC increased with temperature. Modeling H{sub 2}O{sub 2} transport and reaction in GAC indicated that H{sub 2}O{sub 2} penetration was inversely proportional with temperature and tortuosity, and occurred over a larger fraction of the total volume of small GAC particles (0.3 mm diameter) relative to large particles (1.2 mm diameter). Acidic pretreatment of GAC, Fe-amendment, elevated reaction temperature, and use of small GAC particles are operational parameters that improve Fenton-driven oxidation of MTBE in GAC. 29 refs., 6 figs., 1 tab.

Kan, E.; Huling, S.G. [Robert S. Kerr Environmental Research Center, Ada, OK (United States)

2009-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Effects of Using Oxygenated Fuels on Formaldehyde and Acetaldehyde Concentrations in Denver  

E-Print Network [OSTI]

in the oxygenate added to the fuels. MTBE blended fuels were used almost exclusively during the earlypart tertiarybutyl ether (MTBE) and gasoline. The remainder of the fuel sold was a 10% by volume blend of ethanol the program, while the additive used has gradually shifted from largely MTBE to largely ethanol blended fuels2

122

energy savings by the use of mtbe to replace alkylate in automotive gasolines  

SciTech Connect (OSTI)

This paper presents data on the differences in energy consumption in the production of leaded and unleaded AI-93 gasolines with various blend components. The authors investigate as high-octane components certain products that are more effective in use and less energy-consuming in production in comparison with alkylate. In particular, methyl tert-butyl ether (MTBE) is discussed; it is not poisonous, it has a high heat of combustion, and it does not attack materials of construction. The addition of 11% MTBE to gasoline lowers the cold start temperature of engines by 10-12 degrees. Moreover, no adjustment of the carburetor is required for the changeover to gasoline with 11% MTBE.

Englin, B.A.; Emel'yanov, V.E.; Terent'ev, G.A.; Vinogradov, A.M.

1986-07-01T23:59:59.000Z

123

Removal of MTBE and other organic contaminants from water by sorption to high silica zeolites  

SciTech Connect (OSTI)

Select zeolites with high SiO{sub 2}/Al{sub 2}O{sub 3} ratios were shown to effectively remove methyl tert-butyl ether (MTBE), chloroform, and trichloroethylene (TCE) from water. In laboratory studies using batch sorption equilibria, high Si large-port mordenite and ZSM-5 (silicalite) were found to have sorption properties for MTBE and TCE superior to activated carbon. for example, at an equilibrium solution concentration of 100 {micro}g/L, high Si mordenite retained 8--12x more MTBE than either of two powdered activated carbons used as reference sorbents. Sorption results also highlight the importance of pore size and SiO{sub 2}/Al{sub 2}O{sub 3} ration on contaminant removal efficiencies by zeolites.

Anderson, M.A.

2000-02-15T23:59:59.000Z

124

The social costs of an MTBE ban in California (Condensed version)  

E-Print Network [OSTI]

in Focus: Phasing Out MTBE in Gasoline," Annual Energyand P. J. Bartholomae, "MTBE and Benzene Plume Behavior: ASoil Sediment & Groundwater MTBE Special Issue, March, 43-

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2002-01-01T23:59:59.000Z

125

Interdisciplinary investigation of subsurface contaminant transport and fate at point-source releases of gasoline containing MTBE  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is commonly found at concentrations above the current U.S. Environmental Protection Agency draft lifetime health advisory for drinking water (20 to 200 micrograms per liter) at many point-source gasoline release sites. MTBE is significantly more persistent than benzene, toluene, ethyl-benzene and xylenes (BTEX) in the subsurface. Therefore, evaluation of the implications of its presence in gasoline to monitored natural attenuation and engineered bioremediation alternatives is warranted. An interdisciplinary, field-based investigation of the subsurface transport and fate of MTBE and petroleum hydrocarbons is being conducted by the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program at the site of an underground gasoline storage-tank release near Beaufort, South Carolina. The objective of the investigation is to provide a systematic evaluation of natural attenuation of MTBE compared to BTEX. Results of the field and laboratory studies at this site will be generalized to a broader range of hydrogeochemical conditions through experiments at other sites. Furthermore, newly developed methods of analysis can be applied to sites across the Nation. This investigation of MTBE at point-source release sites is coordinated with investigations of the occurrence of MTBE in shallow ground water, surface water, precipitation, and the atmosphere being conducted by the USGS National Water-Quality Assessment Program.

Buxton, H.T.; Baehr, A.L. [Geological Survey, West Trenton, NJ (United States); Landmeyer, J.E. [Geological Survey, Columbia, SC (United States)] [and others

1997-12-31T23:59:59.000Z

126

Multiple steady states during reactive distillation of methyl tert-butyl ether  

SciTech Connect (OSTI)

This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

1993-11-01T23:59:59.000Z

127

Relationship between MTBE-blended gasoline properties and warm-up driveability  

SciTech Connect (OSTI)

The relationship between MBE-blended gasoline properties and warm-up driveability is investigated by focusing on the transient combustion air-fuel ratio that strongly relates to the combustion state of the engine. As a result, although warm-up driveability of MTBE-free gasoline has a high correlation with 50% distillation temperature (T50) and a high correlation with 100 C distillation volume (E100), the correlation is found to be low when blended with MTBE. Various formulas that improve correlation with peak excess air ratio ({lambda}) by correcting T50 and E100 for the amount of MTBE blended are examined. The formula for which the highest determination coefficient is obtained is proposed as a new driveability index (DI) that can also be applied to MTBE-blended gasoline. In addition, the effect on driveability by gasoline base materials using this new DI also is investigated. The results indicate that the new DI worsen when heavy reformate containing large amounts of aromatics or MTBE, an oxygen-containing compound, is used for the octane improver, leaving the balance of the volatility out of consideration.

Suzawa, Takumi; Yamaguchi, Kazunori; Kashiwabara, Kimito [Mitsubishi Motors Corp., Tokyo (Japan); Fujisawa, Norihiro; Matsubara, Michiro

1995-12-31T23:59:59.000Z

128

Radiation chemistry of alternative fuel oxygenates -- Substituted ethers  

SciTech Connect (OSTI)

The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

1999-11-15T23:59:59.000Z

129

Two US markets, or one? How the MTBE-gasoline relationship is evolving  

SciTech Connect (OSTI)

This issue of Energy Detente features the price sensitivity of Methyl Tertiary Butyl Ether. Data is presented for US wholesale gasoline prices vs. MTBE for the 20-month period beginning in June 1994 and ending in January 1996, and the data is discussed. Also contained in this issue is the refining netback data and the fuel price/tax data for the period ending January 5, 1996.

NONE

1996-01-26T23:59:59.000Z

130

The Social Costs of an MTBE Ban in California  

E-Print Network [OSTI]

85 MTBE is more soluble in water than BTEX, which means thatlong as BTEX plumes; and California Regional Water QualityMTBE than BTEX dissolves in a given quantity of water. This

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

131

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network [OSTI]

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

132

Iron optimization for Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) was accomplished through the addition of iron (Fe) and hydrogen peroxide (H{sub 2}O{sub 2}) (15.9 g/L; pH 3). The GAC used was URV, a bituminous-coal based carbon. The Fe concentration in GAC was incrementally varied (1020-25 660 mg/kg) by the addition of increasing concentrations of Fe solution (FeSO4{center_dot}7H{sub 2}O). MTBE degradation in Fe-amended GAC increased by an order of magnitude over Fe-unamended GAC and H{sub 2}O{sub 2} reaction was predominantly (99%) attributed to GAC-bound Fe within the porous structure of the GAC. Imaging and microanalysis of GAC particles indicated limited penetration of Fe into GAC. The optimal Fe concentration was 6710 mg/kg (1020 mg/kg background; 5690 mg/kg amended Fe) and resulted in the greatest MTBE removal and maximum Fe loading oxidation efficiency (MTBE oxidized (g)/Fe loaded to GAC(mg/Kg)). At lower Fe concentrations, the H{sub 2}O{sub 2} reaction was Fe limited. At higher Fe concentrations, the H{sub 2}O{sub 2} reaction was not entirely Fe limited, and reductions in GAC surface area, GAC pore volume, MTBE adsorption, and Fe loading oxidation efficiency were measured. Results are consistent with nonuniform distribution of Fe, pore blockage in H{sub 2}O{sub 2} transport, unavailable Fe, and limitations in H{sub 2}O{sub 2} diffusive transport, and emphasize the importance of optimal Fe loading. 22 refs., 6 figs., 2 tabs.

Scott G. Huling; Patrick K. Jones; Tony R. Lee [U.S. Environmental Protection Agency, Ada, OK (United States). Office of Research and Development, National Risk Management Research Laboratory

2007-06-01T23:59:59.000Z

133

Multivariable controller increased MTBE complex capacity  

SciTech Connect (OSTI)

Capacity increased by more than 4.6% when one dynamic matrix multivariable controller began operating in Valero Refining Company`s MTBE production complex in Corpus Christi, Texas. This was on a plant that was already running well above design capacity due to previously made process changes. A single controller was developed to cover an isobutane dehydrogenation (ID) unit and an MTBE reaction and fractionation plant with the intermediate isobutylene surge drum. The overall benefit is realized by a comprehensive constrained multivariable predictive controller that properly handles all sets of limits experienced by the complex, whether limited by the front-end ID or back-end MTBE units. The controller has 20 manipulated, 6 disturbance and 44 controlled variables, and covers widely varying dynamics with settling times ranging from twenty minutes to six hours. The controller executes each minute with a six hour time horizon. A unique achievement is intelligent surge drum level handling by the controller for higher average daily complex capacity as a whole. The ID unit often operates at simultaneous limits on reactor effluent compressor capacity, cold box temperature and hydrogen/hydrocarbon ratio, and the MTBE unit at impurity in butene column overhead as well as impurity in MTBE product. The paper discusses ether production, isobutane dehydrogenation, maximizing production, controller design, and controller performance.

Robertson, D.; Peterson, T.J.; O`Connor, D. [DMC Corp., Houston, TX (United States); Payne, D.; Adams, V. [Valero Refining Co., Corpus Christi, TX (United States)

1997-03-01T23:59:59.000Z

134

VOL. 32, No.4 UNL WATER CENTER AUGUST 2000 New Method For Detecting Trace Amounts of MTBE  

E-Print Network [OSTI]

water their use to help curb growing prob- at spill sites. lems with air pollution. MTBE is the most emis-by Steve Ress sions, are considered small. Gasoline additives that help keep our air clean can- "Most of the information available on oxygenates 10 mine the extent of their environmental impacts

Nebraska-Lincoln, University of

135

Gas phase synthesis of MTBE on triflic-acid-modified zeolites  

SciTech Connect (OSTI)

The gas phase synthesis of MTBE (methyl tert-butyl ether) was studied using three series of triflic acid (TFA)-modified zeolites, the parent materials being HY, H-mordenite, and HZSM-5. Impregnation with TFA was found to enhance MTBE synthesis activity only for the large-pore zeolite Y and only up to a certain extent of modification. A high level of TFA modification caused a reduction in activity, apparently due to blockage of the active sites by TFA molecules and extra-lattice Al formed during the modification process. The mechanism of activity enhancement by TFA modification appears to be related to the formation of extra-lattice Al rather than the direct presence of TFA. 20 refs., 6 figs., 1 tab.

Nikolopoulos, A.A.; Kogelbauer, A.; Goodwin, J.G. Jr. [Univ. of Pittsburgh, PA (United States)] [and others] [Univ. of Pittsburgh, PA (United States); and others

1996-01-01T23:59:59.000Z

136

Biodegradation of methyl tert-butyl ether by a bacterial pure culture  

SciTech Connect (OSTI)

A bacterial strain, PM1, which is able to utilize methyl tert-butyl ether (MTBE) as its sole carbon and energy source, was isolated from a mixed microbial consortium in a compost biofilter capable of degrading MTBE. Initial linear rates of MTBE degradation by 2 x 10{sup 6} cells ml{sup {minus}1} were 0.07, 1.17, and 3.56 {mu}g ml{sup {minus}1} h{sup {minus}1} for initial concentrations of 5, 50, and 500 {mu}g MTBE ml{sup {minus}1}, respectively. When incubated with 20 {mu}g of uniformly labeled [{sup 14}C]MTBE ml{sup {minus}1}, strain PM1 converted 46% to {sup 14}CO{sub 2} and 19% to {sup 14}C-labeled cells within 120 h. This yield is consistent with the measurement of protein accumulation at different MTBE concentrations from which was estimated a biomass yield of 0.18 of cells mg MTBE{sup {minus}1}. Strain PM1 was inoculated into sediment core material collected from a contaminated groundwater plume at Port Hueneme, California, in which there was no evidence of MTBE degradation. Strain PM1 readily degraded 20 {micro}g of MTBE ml{sup {minus}1} added to the core material. The rate of MTBE removal increased with additional inputs of 20 {micro}g of MTBE ml{sup {minus}1}. These results suggest that PM1 has potential for use in the remediation of MTBE-contaminated environments.

Hanson, J.R.; Ackerman, C.E.; Scow, K.M.

1999-11-01T23:59:59.000Z

137

Vapor-liquid equilibria of hydrocarbons and fuel oxygenates. 2  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data for methyl tert-butyl ether (MTBE) + 1-heptene, MTBE + four-component gasoline prototype, ethanol + four-component gasoline prototype, and separately MTBE and ethanol with the Auto/Oil Air Quality Improvement Research Gasoline Blend A are reported. Small additions of MTBE have a very small effect on the total equilibrium pressure of this gasoline blend, and at most temperatures will decrease this pressure. In contrast, small additions of ethanol to this gasoline blend result in a significant increase in the equilibrium pressure at all temperatures. Analysis shows that the vapor-liquid equilibrium data for the MTBE-containing systems are easily correlated using a modified Peng-Robinson equation of state with conventional van der Waals one-fluid mixing rules. Data for mixtures containing ethanol cannot be accurately correlated in this way.

Bennett, A.; Lamm, S.; Orbey, H.; Sandler, S.I. (Univ. of Delaware, Newark (United States))

1993-04-01T23:59:59.000Z

138

QUANTIFYING NON-POINT SOURCES OF VOLATILE ORGANIC COMPOUNDS IN STORMWATER FROM A PARKING LOT  

E-Print Network [OSTI]

-butyl ether (MTBE) on urban particles indicates a site- specific interaction between MTBE and a particulate is a possible source only for the gasoline oxygenate methyl tert-butyl ether (MTBE). Lopes and Bender (1998

139

Remediation of a fractured clay soil contaminated with gasoline containing MTBE  

SciTech Connect (OSTI)

Gasoline and other light non-aqueous phase liquids (LNAPLs) released into fractured clay soils initially move by advection of the LNAPL through the fractures. Once advective movement of the LNAPL ceases, dissolution of the gasoline components into the pore water and diffusion into the intact blocks of clay becomes an important transport process. The aqueous-phase flux of each compound in the mixture depends in large part upon its aqueous solubility. For example, a low-solubility compound like isooctane remains primarily in the fracture in the LNAPL. A high-solubility compound, like methyl-tert-butyl ether (MTBE), dissolves readily and may move almost entirely into the clay matrix. The distribution of compounds between the matrix and the fractures will have an important impact on the rate at which the gasoline contaminated soil can be remediated. In this context, the presence of soluble additives like MTBE can significantly impact the risk and remediation time for the, soil. Beginning in 1993 a field study to examine the applicability of air flushing for remediation of low-permeability soils was sponsored by API. The study focused on a variety of soil vapor extraction (SVE) and in situ air sparging (IAS) approaches for mass removal and risk reduction. The source of gasoline contamination in this study was a release of 50 liters of a mixture containing 14 gasoline hydrocarbons ranging from pentane to naphthalene, and including MTBE. The mixture was released into the shallow subsurface and allowed to redistribute for 10 months prior to air flushing startup. Numerical modeling indicated that essentially all of the MTBE should have dissolved into the matrix. In contrast, essentially all of the isooctane should have remained in the LNAPL in the fractures.

Johnson, R.L.; Grady, D.E. [Oregon Graduate Institute, Portland, OR (United States); Walden, T. [BP Oil Europe, Brussels (Belgium)

1997-12-31T23:59:59.000Z

140

Comparative Environmental Performance of Two-Diesel-Fuel Oxygenates: Dibutyl Maleate (DBM) and Triproplyene Glycol Monomethyl Ether (TGME)  

SciTech Connect (OSTI)

Many studies have shown that the addition of oxygen bearing compounds to diesel fuel can significantly reduce particulate emissions. To assist in the evaluation of the environmental performance of diesel-fuel oxygenates, we have implemented a suite of diagnostic models for simulating the transport of compounds released to air, water, and soils/groundwater as well as regional landscapes. As a means of studying the comparative performance of DBM and TGME, we conducted a series of simulations for selected environmental media. Benzene and methyl tertiary butyl ether (MTBE) were also addressed because they represent benchmark fuel-related compounds that have been the subject of extensive environmental measurements and modeling. The simulations showed that DBM and TGME are less mobile in soil because of reduced vapor-phase transport and increased retention on soil particles. The key distinction between these two oxygenates is that DBM is predicted to have a greater potential than TGME for aerobic biodegradation, based on chemical structure.

Layton, D.W.; Marchetti, A.A.

2001-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Kinetics and mechanism of the sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation in the presence of ozone  

SciTech Connect (OSTI)

The kinetics and mechanism of the sonolytic degradation of methyl tert-butyl ether (MTBE) have been investigated at an ultrasonic frequency of 205 kHz and power of 200 W L{sup {minus}1}. The observed first-order degradation rate constant for the loss of MTBE increased from 4.1 {times} 10{sup {minus}4} s{sup {minus}1} to 8.5 {times} 10{sup {minus}4} s{sup {minus}1} as the concentration of MTBE decreased from 1.0 to 0.01 mM. In the presence of O{sub 3}, the sonolytic rate of destruction of MTBE was accelerated substantially. The rate of MTBE sonolysis with ozone was enhanced by a factor of 1.5--3.9 depending on the initial concentration of MTBE. tert-Butyl formate, tert-butyl alcohol, methyl acetate, and acetone were found to be the primary intermediates and byproducts of the degradation reaction with yields of 8, 5, 3, and 12%, respectively. A reaction mechanism involving three parallel pathways that include the direct pyrolytic decomposition of MTBE, the direct reaction of MTBE with ozone, and the reaction of MTBE with hydroxyl radical is proposed.

Kang, J.W. [Yonsei Univ., Wonju (Korea, Republic of). Dept. of Industrial Environment and Health] [Yonsei Univ., Wonju (Korea, Republic of). Dept. of Industrial Environment and Health; Hoffmann, M.R. [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.] [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.

1998-10-15T23:59:59.000Z

142

Recovery of methanol in an MTBE process  

SciTech Connect (OSTI)

In a process for the manufacture of methyltertiarybutylether (MTBE) in which methanol and a mixture of C/sub 4/ hydrocarbons containing isobutylene are contacted in a reaction zone containing an ion-exchange resin catalyst under suitable conditions to effect the reaction of methanol and isobutylene to produce a reaction product containing MTBE, unreacted methanol, unreacted isobutylene and other C/sub 4/ hydrocarbons, the reaction product is introduced to a fractionation zone wherein it is separated into a bottoms product comprising essentially MTBE and an overhead product containing unreacted methanol, unreacted isobutylene, and other C/sub 4/ hydrocarbons, and the overhead product is introduced to an absorption zone wherein the methanol is absorbed; the improvement is described which comprises utilizing silica gel as adsorbent and regenerating the silica gel adsorbent in a closed loop by contacting the silica gel absorbent with a desorption gas stream at an elevated temperature for a sufficient period of time to remove absorbed methanol, cooling the effluent from the adsorption zone to condense desorbed methanol removing desorbed methanol from the system and recycling the desorption gas to the adsorption zone.

Whisenhunt, D.E.; Byers, G.L.; Hattiangadi, U.S.

1988-05-31T23:59:59.000Z

143

Eliminating MTBE in Gasoline in 2006  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96Nebraska NuclearDecade Year-08/03)1 Eliminating MTBE in

144

Feasibility of using bioaugmentation with bacterial strain PM1 for bioremediation of MTBE-contaminated vadose and groundwater environments  

E-Print Network [OSTI]

2000. "In Situ Treatment of MTBE by Biostimulation of NativeAmerican Petroleum Institute MTBE Biodegradation Workshop,Detection and Quantification of MTBE-degrading Strain PM1 by

Scow, Kate M; Hristova, Krassimira

2001-01-01T23:59:59.000Z

145

The Social Costs of an MTBE Ban in California  

E-Print Network [OSTI]

in Gasoline. Annual Energy Outlook 2000. DOE/EIA-0383,in Gaso- line. Annual Energy Outlook 2000. DOE/EIA-0383,MTBE in Gasoline, Annual Energy Outlook 2000, 2001a. Mazur,

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

146

Heterogeneous models of tubular reactors packed with ion-exchange resins: Simulation of the MTBE synthesis  

SciTech Connect (OSTI)

The study of behavior of fixed-bed reactors using ion-exchange resins as catalysts was carried out by making use of a complete bidimensional heterogeneous model for the reactor, which included the resistances inside the ion-exchange resin particles, considered with a macroreticular structure. The active sites were located inside the gel phase of the resin, represented by microspheres, and on the macropores walls. The overall efficiency of such heterogeneous catalyst particles was defined by the macroeffectiveness and microeffectiveness factors accounting for the process behavior on the macropores and inside the microspheres. The synthesis of methyl tert-butyl ether, MTBE, a liquid-phase reversible exothermic reaction between methanol and isobutene, was considered as a reference case. This system was studied in the temperature range of 313--338 K, and the effect of the thermodynamic equilibrium conditions was examined. The results predicted by the complete heterogeneous model were compared with those obtained with the simple pseudohomogeneous model, which revealed higher hot spots. Moreover, a comparison between bidimensional and unidimensional models was also performed. The orthogonal collocation method was used for the discretization of the differential equations inside the catalyst particles, which were reduced from three (corresponding to the three mass balances for the three compounds, isobutene, methanol, and MTBE) to only one differential equation, by using the concept of the generalized variable.

Quinta Ferreira, R.M.; Almeida-Costa, C.A. [Univ. of Coimbra (Portugal). Dept. of Chemical Engineering; Rodrigues, A.E. [Univ. of Porto (Portugal). Dept. of Chemical Engineering

1996-11-01T23:59:59.000Z

147

The social costs of an MTBE ban in California (Long version)  

E-Print Network [OSTI]

Ethanol, Non-oxy Case D'( p) MTBE Case D(p) U.S. Supply S(p)NO. 932 THE SOCIAL COSTS OF AN MTBE BAN IN CALIFORNIA (LONGMTBE .

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2002-01-01T23:59:59.000Z

148

Atmosphere-Water Interaction of Chloroform, Toluene, and MTBE in Small Perennial Urban Streams  

E-Print Network [OSTI]

Atmosphere-Water Interaction of Chloroform, Toluene, and MTBE in Small Perennial Urban Streams-butyl ether (MTBE) are frequently detected VOCs in the atmosphere, surface water, and ground water in urban not be the predominant source of chloroform and toluene in the two urban streams. In contrast, MTBE may be coming from

149

DME-to-oxygenates process studies  

SciTech Connect (OSTI)

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

150

Kinetics and modeling of mixture effects during complete catalytic oxidation of benzene and methyl tert-butyl ether  

SciTech Connect (OSTI)

The performance of a catalytic incinerator depends on the nature of the compounds being oxidized and cannot be predicted simply by knowing the performance of the incinerator with pure-component model compounds. Considering the importance of mixture effects, an attempt was made to develop a combined model to predict the conversion when benzene and methyl tert-butyl ether (MTBE) are simultaneously oxidized. Complete catalytic oxidation of benzene and MTBE, singly and in mixtures, was investigated over a platinum catalyst. No inhibition effects were seen with benzene, but MTBE conversion was distinctly inhibited by benzene. A Mars-van Krevelen rate model was used to explain the results. Model parameters were obtained from pure-component experiments and then incorporated into a multicomponent model without any adjustment or additional rate parameters. The multicomponent model was able to predict the conversion of benzene and MTBE oxidation in the binary mixture using the pure-component data without adjustable parameters.

Dangi, S.; Abraham, M.A. [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering] [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

151

Refinery fuel oxygenates in view of the complex model for reformulated gasline  

SciTech Connect (OSTI)

The final version of the Complex Model for reformulated gasoline (RFG) has now been issued with some surprising features that will significantly affect refinery fuel oxygenates planning. These include the following: (1) The only oxygenates included in the model are MTBE, ETBE, TAME, and Ethanol. (2) The Complex Model calculates that MTBE and TAME are significantly more effective for reduction of air toxics emissions than Ethanol and ETBE. (3) The Complex Model calculates that MTBE and TAME typically produce about equal reduction in air toxics emissions at the same RFG oxygen content. Although gasoline certification by the Complex Model is optional prior to 1998, after 1998 it will be mandatory for both reformulated and conventional gasolines. This paper considers refinery oxygenates production in view of these features of the Complex Model for RFG, basing the discussion on 2.0 weight percent oxygen content for RFG.

Crawford, C.D.; Haelsig, C.P. [Fluor Daniel, Irvine, CA (United States)

1994-12-31T23:59:59.000Z

152

Reactant adsorption and its impact upon MTBE synthesis on zeolites  

SciTech Connect (OSTI)

Zeolites show interesting properties as catalysts for MTBE synthesis from methanol and isobutene such as a high selectivity to MTBE even at a low methanol/isobutene feed ratio. In order to explain this high selectivity, the adsorption behaviors of HY and HZSM-5 zeolites and their impact on activity and selectivity for MTBE synthesis were studied. Adsorption experiments, carried out under conditions similar to those used for reaction, showed that ca. 2.5 molecules of methanol were adsorbed per acid site on HZSM-5 and HY zeolites, whereas isobutene was found to form a 1:1 adsorption complex. The excess methanol adsorbed was found to be only weakly bonded, probably via hydrogen bonds. On a commercially used resin catalyst (Amberlyst-15) equal amounts of methanol and isobutene were adsorbed. The higher methanol uptake of the zeolites was paralleled by a higher selectivity to MTBE as compared to the resin catalyst. The increased adsorption of methanol on the zeolites was concluded to play a key role in suppressing the formation of by-products due to isobutene dimerization or oligomerization by decreasing the adsorption of isobutene on the active sites and thereby keeping these sites available for reaction. 40 refs., 5 figs., 3 tabs.

Kogelbauer, A.; Nikolopoulos, A.A.; Goodwin, J.G. Jr.; Marcelin, G. [Univ. of Pittsburgh, PA (United States)] [Univ. of Pittsburgh, PA (United States)

1995-03-01T23:59:59.000Z

153

New low energy process for MTBE and TAME  

SciTech Connect (OSTI)

Considered as new bulk petrochemicals of limited feedstocks MTBE (methyltertbutylether) and TAME (tertamylmethylether) need cheap and simple, minimum-cost production processes. The problems in optimizing the etherification are set by specifications for ether products and hydrocarbon raffinates. Working up reaction products from etherification processes containing hydrocarbons, methanol and ether to secure the pure main and side products is difficult because of azeotrope formation of methanol with ethers or hydrocarbons. At EC Erdolchemie GmbH, Cologne, a semicommercial unit with a capacity of 2,500 metric t/y has now been successfully operated for nearly one year producing high purity MTBE (> 99 wt.%) and a raffinate II with methanol content of < 0.05 wt.%. The TAME process has successfully been tested in a 3,000 kg/y TAME pilot plant for almost two years. Based on the operating experience, EC has prepared the engineering for a commercial multiproduct plant, including the production of 30,000 metric t/y MTBE, 15,000 metric t/y TAME and 6,000 metric t/y methylbutenes (TAME cracking product) in the first stage. EC has made application to the authorities for a construction permit. The process for MTBE and TAME will be licensed by EC Erdolchemie GmbH, Postfach 75 20 02, 5000 Cologne 71, West Germany or by Lurgi Kohle und Mineraloltechnik GmbH, Postfach 11 12 31, 6000 Frankfurt Main 2, West Germany.

Herwig, J.; Schleppinghoff, B.; Schulwitz, S.

1984-06-01T23:59:59.000Z

154

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Aug. 2004, p. 47204726 Vol. 70, No. 8 0099-2240/04/$08.00 0 DOI: 10.1128/AEM.70.8.47204726.2004  

E-Print Network [OSTI]

contamination of surface and groundwater resources by the gasoline oxygenate methyl tert-butyl ether (MTBE) is leading to its phaseout. Ethanol, a likely candidate to substitute MTBE, is increasingly being used

Alvarez, Pedro J.

155

International Journal of Mass Spectrometry 249250 (2006) 303310 Pyrolysis of 2-methoxy-2,3,3-trimethylbutane (MTMB) monitored by  

E-Print Network [OSTI]

used fuel oxygenates MTBE and TAME), the predominance of bond homolysis at temperatures >900 K suggests homologues ­ methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) ­ present a new set of problems discussed as alternatives to MTBE and TAME, because they are expected to be much less soluble in water. More

Morton, Thomas Hellman

156

E-Print Network 3.0 - aerobic mtbe biodegradation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

27 ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT Summary: capable of MTBE biodegradation. 12;Effective treatment of a mixture...

157

CRC fuel rating program: road octane performance of oxygenates in 1982 model cars  

SciTech Connect (OSTI)

Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

Not Available

1985-07-01T23:59:59.000Z

158

The evolution of fuel: A dissertation on MTBE and elastomers  

SciTech Connect (OSTI)

This paper begins with a history of the development of the internal combustion engine and the need for a fuel octane booster that would also be non-polluting. The use of ethers as fuel additives cause a compatibility problem with valve sealing materials. The main purpose of this presentation is to address this compatibility problem. The paper makes specific recommendations for the author`s General Twin Seal, describing the seal components (slip seal, bonnet and lower plate O-rings, gland O-rings, bearing retainer O-rings, and pressure relief device seals) and which materials these components should be manufactured from to be compatible with the following fuel additives: toluene, MTBE, and various mixtures of toluene and MTBE.

Smith, G.M. [General Valve Co., Brookshire, TX (United States)

1995-12-31T23:59:59.000Z

159

Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions  

SciTech Connect (OSTI)

This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

1995-03-01T23:59:59.000Z

160

Reaction calorimetry study of the liquid-phase synthesis of tert-butyl methyl ether  

SciTech Connect (OSTI)

The liquid-phase addition of methanol to isobutene to give tert-butyl methyl ether (MTBE) on the ion-exchange resin Lewatit K2631 has been studied in a calorimetric reactor. Heat capacity of MTBE and enthalpy of the MTBE synthesis reaction in the temperature range 312--333 K have been determined. MTBE heat capacity in the liquid phase has been found to obey the equation c[sub P] (J/mol[center dot]K) = 472.34 [minus] 2.468(T/K) + 0.005071(T/K)[sup 2]. At 298 K the standard molar reaction enthalpy is [Delta]H[degree] = [minus]33.8 kJ/mol. A method to estimate apparent activation energies from heat flow rate in a given reaction has been developed and proved to be valid for the MTBE synthesis. Using this method, an apparent activation energy of 91.1--95.2 kJ/mol is calculated. A [minus]3.8 kJ/mol value has been found for the adsorption enthalpy of methanol on the ion-exchange resin Lewatit K2631 by a combination of reaction calorimetry and thermogravimetry. This allows the calculation of an activation energy on the gel phase of the resin of 91 kJ/mol.

Sola, L.; Pericas, M.A.; Cunill, F.; Iborra, M. (Univ. de Barcelona (Spain). Dept. d'Enginyeria Quimica)

1994-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

162

Pilot-scale evaluation of chemical oxidation for MTBE-contaminated soil  

SciTech Connect (OSTI)

The US Environmental Protection Agency (USEPA) has tentatively classified MTBE as a possible human carcinogen, thus further emphasizing the importance for study of fate, transport, and environmental effects of MTBE. The treatment of subsurface contaminants (e.g., MTBE) from leaking underground storage tank (LUST) sites presents many complex challenges. Many techniques have been employed for the remediation of contaminants in soil and groundwater at LUST sites. Under sponsorship of US EPA's National Risk Management Research Laboratory, IT Corporation has conducted evaluations of chemical oxidation of MTBE contaminated soil using Fenton's Reagent (hydrogen peroxide catalyzed by ferrous sulfate), simulating both ex-situ and in-situ soil remediation. Bench-scale ex-situ tests have shown up to 90% degradation of MTBE within 12 hours. Pilot-scale MTBE oxidation tests were conducted in a stainless paddle-type mixer with a 10 cubic foot mixing volume. The reactor was designed with a heavy duty mixer shaft assembly to homogenize soil and included provisions for contaminant and reagent addition, mixing, and sample acquisition. The tests were performed by placing 400 pounds of a synthetic soil matrix (consisting of a mixture of top soil, sand, gravel and clay) in the reactor, spiking with 20 ppm of MTBE, and mixing thoroughly. The variables evaluated in the pilot-scale tests included reaction time, amount of hydrogen peroxide, and amount of ferrous sulfate. After 8 hours of reaction, using 4 times the stoichiometric quantity of hydrogen peroxide and a 10:1 hydrogen peroxide: ferrous iron weight ratio, approximately 60% MTBE degradation was observed. When 10 times the stoichiometric quantity of hydrogen peroxide was used (with the same ratio of hydrogen peroxide to ferrous iron), 90% MTBE degradation was observed. When the same test was performed without any ferrous iron addition, 75% MTBE degradation was observed.

Rahman, M.; Schupp, D.A.; Krishnan, E.R.; Tafuri, A.N.; Chen, C.T.

1999-07-01T23:59:59.000Z

163

Treatment of methyl tert-butyl ether vapors in biotrickling filters. 1. Reactor startup, steady-state performance, and culture characteristics  

SciTech Connect (OSTI)

An aerobic microbial consortium able to biodegrade methyl tert-butyl ether (MTBE) was enriched in two waste air biotrickling filters after continuous operation for 6 months. After this acclimation phase, the two laboratory-scale biotrickling filters were able to degrade up to 50 g of MTBE per cubic meter of reactor per hour, a value comparable to other gasoline constituents. Such high performance could be sustained for at least 4--6 weeks. After the acclimation phase, the MTBE degrading biotrickling filters were characterized by their almost full conversion of MTBE to carbon dioxide and the absence of any degradation byproducts in either the gas or the liquid phase. They also exhibited a very high specific degradation activity per amount of biomass, and a low rate of biomass accumulation. An observed biomass yield of 0.1 g g{sup {minus}1} and a specific growth rate of 0.025 day{sup {minus}1} were determined for the biotrickling filter process culture. Further data on MTBE mass transfer and on the dynamic behavior of the biotrickling filter are presented in part 2 of this paper. Overall, the results demonstrate that MTBE can be effectively biodegraded under carefully controlled environmental conditions.

Fortin, N.Y.; Deshusses, M.A. [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering] [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering

1999-09-01T23:59:59.000Z

164

PROOF COPY [023113] 008209QEE [023113]008209QEE  

E-Print Network [OSTI]

as a replacement for the gasoline oxygenate, methyl tert-butyl ether MTBE , may lead to indirect impacts related facilitate the migration of pre-existing contamination. MTBE 25 mg/L influent was not degraded inlet by one order of magnitude relative to columns fed BTEX alone or with MTBE. However, 16S

Alvarez, Pedro J.

165

Physico-chemical and biological characterization of an aquifer polluted with Yves Benoit (1)  

E-Print Network [OSTI]

to in order to meet specific requirements. Oxygenates such as methyl tert-butyl ether (MTBE) or ethyl tert on groundwater was not estimated prior to their utilization and the actual level of MTBE and ETBE contamination of MTBE- and ETBE-biodegradation is quite poor. Two directives have been adopted in the EU to promote

Paris-Sud XI, Université de

166

Critical Reviews in Environmental Science and Technology, 00(0):000000 (2001) 1064-3389/01/$.50  

E-Print Network [OSTI]

water contamination by methyl tert-butyl ether (MTBE) have made policymakers more cognizant of the need reformulated gasoline (RFG) (2% oxygen) year-round to reduce emissions that contribute to ozone formation. MTBE-making process that lead to the widespread use of MTBE over the last decade is now quite controversial (BRP, 1999

Alvarez, Pedro J.

167

Fourier Transform Infrared Spectroscopy  

E-Print Network [OSTI]

FTIR - 1 Fourier Transform Infrared Spectroscopy FTIR DETERMINATION OF MTBE IN GASOLINE AND ETHANOL FTIR DETERMINATION OF MTBE IN GASOLINE AND ETHANOL IN VODKA AND MOUTHWASH INTRODUCTION As a part has contained MTBE (methyl tert­butyl ether) as its primary oxygenate. However, there has been

Nizkorodov, Sergey

168

Traitement biologique in situ au sein d'un aquifre de polluants de type ETBE et MTBE  

E-Print Network [OSTI]

Traitement biologique in situ au sein d'un aquifère de polluants de type ETBE et MTBE Yves Benoit Villeurbanne (6) CNRS, UMR5557, Ecologie Microbienne ­ 69100 Villeurbanne Résumé Le MtBE et l' EtBE sont des : Traçabilité, Innocuité, Efficacité: Application aux polluants pétroliers type MTBE, ETBE), financé par le pôle

Paris-Sud XI, Université de

169

Automobile proximity and indoor residential concentrations of BTEX and MTBE  

SciTech Connect (OSTI)

Attached garages have been identified as important sources of indoor residential air pollution. However, the literature lacks information on how the proximity of cars to the living area affects indoor concentrations of gasoline-related compounds, and the origin of these pollutants. We analyzed data from the Relationships of Indoor, Outdoor, and Personal Air (RIOPA) study and evaluated 114 residences with cars in an attached garage, detached garage or carport, or without cars. Results indicate that homes with cars in attached garages were affected the most. Concentrations in homes with cars in detached garages and residences without cars were similar. The contribution from gasoline-related sources to indoor benzene and MTBE concentrations appeared to be dominated by car exhaust, or a combination of tailpipe and gasoline vapor emissions. Residing in a home with an attached garage could lead to benzene exposures ten times higher than exposures from commuting in heavy traffic.

Corsi, Dr. Richard [University of Texas, Austin; Morandi, Dr. Maria [University of Texas Health Science Center, Houston; Siegel, Dr. Jeffrey [University of Texas, Austin; Hun, Diana E [ORNL

2011-01-01T23:59:59.000Z

170

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network [OSTI]

D. J. Slomczynski. 2003. BTEX/MTBE bioremediation: BionetsScow, and L. Alvarez-Cohen. MTBE and benzene biodegradationinteractions in BTEX and MTBE mixtures by an MTBE-degrading

2007-01-01T23:59:59.000Z

171

One multivariable controller increased capacity of an Oleflex{trademark}/MTBE complex  

SciTech Connect (OSTI)

Capacity increased by more than 4.6% when one dynamic matrix controller began operating in Valero Refining Company`s MTBE production complex in Corpus Christi, Texas. This was on a plant that was already running well above design capacity due to process changes previously made on the plant. A single controller was developed to cover an Oleflex{trademark} isobutane dehydrogenation unit and an MTBe reaction and fractionation plant with the intermediate isobutylene surge drum. The overall benefit is realized by a comprehensive constrained multivariable predictive controller which properly handles all sets of limits experienced by the complex, whether limited by the front-end Oleflex{trademark} or back-end MTBE unit. The controller has 20 manipulated, 6 disturbance and 44 controlled variables, and covers widely varying dynamics with settling times ranging from twenty minutes to six hours. The controller executes each minute with a six hour time horizon. A unique achievement is intelligent handling of the surge drum level by the controller for higher average daily capacity of the complex as a whole. The Oleflex{trademark} often operates at simultaneous limits on reactor effluent compressor capacity, cold box temperature and hydrogen/hydrocarbon ratio and the MTBE at impurity in butene column overhead as well as impurity in MTBE product.

Robertson, D.; Peterson, T.J.; O`Connor, D. [Dynamic Matrix Control Corp., Houston, TX (United States); Adams, V.; Payne, D. [Valero Refining Co., Corpus Christi, TX (United States)

1996-12-01T23:59:59.000Z

173

Isobaric vapor-liquid equilibria in the systems methyl 1,1-dimethylethyl ether + hexane and + heptane  

SciTech Connect (OSTI)

The vapor-liquid equilibrium at 94 kPa has been determined for the binary systems of methyl 1,1-dimethylethyl ether (MTBE) with hexane and with heptane. Both systems deviate slightly from ideal behavior, can be described as regular solutions, and do not present an azeotrope. The activity coefficients and boiling point of the solutions were correlated with its composition by the Redlich-Kister, Wohl, Wilson, UNIQUAC, NRTL, and Wisniak-Tamir equations.

Wisniak, J.; Magen, E.; Shachar, M.; Zeroni, I.; Segura, H. [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Chemical Engineering] [Ben-Gurion Univ. of the Negev, Beer-Sheva (Israel). Dept. of Chemical Engineering; Reich, R. [Univ. de Concepcion (Chile). Dept. of Chemical Engineering] [Univ. de Concepcion (Chile). Dept. of Chemical Engineering

1997-03-01T23:59:59.000Z

174

Exposure to methyl tert-butyl ether, benzene, and total hydrocarbons at the Singapore-Malaysia causeway immigration checkpoint  

SciTech Connect (OSTI)

The primary aim of this study was to determine the extent and levels of exposure to volatile organic compounds (VOCs) from automobile emissions in a group of immigration officers at a busy cross-border checkpoint. A majority (80%) of the workers monitored were exposed to benzene at levels between 0.01 and 0.5 ppm, with only 1.2% exceeding the current Occupational Safety and Health Administration occupational exposure limit of 1 ppm. The geometric mean (GM) concentrations of 8-hr time-weighted average exposure were 0.03 ppm, 0.9 ppm, and 2.46 ppm for methyl-tert-butyl ether (MTBE), benzene, and total hydrocarbons (THC), respectively. The highest time-weighted average concentrations measured were 1.05 ppm for MTBE, 2.01 ppm for benzene, and 34 ppm for THC. It was found that motorbikes emitted a more significant amount of pollutants compared with motor cars. On average, officers at the motorcycle booths were exposed to four to five times higher levels of VOCs (GMs of 0.07 ppm, 0.23 ppm, and 4.7 ppm for MTBE, benzene, and THC) than their counterparts at the motor car booths (GMs of 0.01 ppm, 0.05 ppm, and 1.5 ppm). The airborne concentrations of all three pollutants correlated with the flow of vehicle traffic. Close correlations were also noted for the concentrations in ambient air for the three pollutants measured. Benzene and MTBE had a correlation coefficient of 0.97. The overall findings showed that the concentrations of various VOCs were closely related to the traffic density, suggesting that they were from a common source, such as exhaust emissions from the vehicles. The results also indicated that although benzene, MTBE, and THC are known to be volatile, a significant amount could still be detected in the ambient environment, thus contributing to our exposure to these compounds. 4 refs., 6 figs.

Tan, C.; Ong, H.Y.; Kok, P.W. [and others

1996-12-31T23:59:59.000Z

175

Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes  

SciTech Connect (OSTI)

This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased. (author)

Boehm, H. [Physikalische Chemie I, Universitaet Bielefeld (Germany); Braun-Unkhoff, M. [Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Stuttgart (Germany)

2008-04-15T23:59:59.000Z

176

Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review  

SciTech Connect (OSTI)

This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

Not Available

1991-10-01T23:59:59.000Z

177

Gas phase synthesis of MTBE from methanol and isobutene over dealuminated zeolites  

SciTech Connect (OSTI)

Gas phase synthesis of MTBE from methanol and isobutene has been investigated over different zeolites. It is shown that bulk Si/Al ratio has a marked influence on the formation of MTBE. H-beta zeolite was found to be as active as acid Amberlyst-15 (reference catalyst), and noticeably superior to non- and dealuminated forms of H-Y, H-ZSM-5, zeolite omega, and H-mordenites. Screening test results obtained over other catalysts (SAPOs and pillared clays) are briefly commented. The contribution of the external surface of the zeolites to the reaction is discussed. In the case of H-Y zeolites, it is shown that extra framework Al species ({sup 27}Al NMR signal at 30 ppm) have a detrimental effect on the reaction. 64 refs., 12 figs., 3 tabs.

Collignon, F.; Mariani, M.; Moreno, S.; Remy, M.; Poncelet, G. [Universite Catholique de Louvain (Belgium)] [Universite Catholique de Louvain (Belgium)

1997-02-01T23:59:59.000Z

178

Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story  

E-Print Network [OSTI]

as methyl-tert-butyl ether (MTBE), lubricating oil and itsthe environment. Use of the MTBE additive in gasoline wasof gasoline laced with MTBE into groundwater resulted in

2013-01-01T23:59:59.000Z

179

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

Ethylene dichloride 1 MTBE 2 Vinylchloride 3 Ethylbenzene 1Methyl- Tertiary-Butyl-Ether (MTBE) or Ethyl-Tertiary-Butyl-Styrene Vinylchloride MTBE Benzene, Toluene, Xylene Acetone

Neelis, Maarten

2008-01-01T23:59:59.000Z

180

Cometabolic bioremediation  

E-Print Network [OSTI]

Intrinsic bioremediation of MTBE-contaminated groundwater atcontaminants, e.g. PCE, TCE, MTBE, TNT, dioxane, atrazine,Methyl tert-butyl ether (MTBE) has also been remediated

Hazen, Terry C.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

APPENDXD.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Report The Form EIA-819, "Monthly Oxygenate Report" provides production data for fuel ethanol and methyl tertiary butyl ether (MTBE). End-of-month stock data held at ethanol...

182

antioxidant butylated hydroxytoluene: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

183

alkyl tert-butyl ether: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

184

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

185

Treatment of methyl tert-butyl ether vapors in a biotrickling filters. 2. Analysis of the rate-limiting step and behavior under transient conditions  

SciTech Connect (OSTI)

Detailed experiments were performed with gas phase biotrickling filters treating vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern. A particular emphasis was placed on the analysis of the rate-limiting step, and it was found that the process was mostly limited by the biological reaction rather than by mass transfer. Further experiments involved the study of the dynamic behavior of the biotrickling filters under simulated field conditions. In all cases, the biotrickling filters adapted rapidly to the new conditions, and new steady states were obtained within hours. The relevance of the results and the implications as far as implementation of biotrickling filters for field MTBE treatment are discussed.

Fortin, N.Y.; Deshusses, M.A. [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering] [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering

1999-09-01T23:59:59.000Z

186

Oxygen analyzer  

DOE Patents [OSTI]

An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

Benner, William H. (Danville, CA)

1986-01-01T23:59:59.000Z

187

Regulatory Takings and Environmental Regulation in NAFTA's Chapter 11  

E-Print Network [OSTI]

oxygenates (ethanol and MTBE), and that it was possible forof the gasoline additive MTBE, which uses Methanol as anand regu- lations banning MTBE expropriated parts of its

Aisbett, Emma; Karp, Larry; McAusland, Carol

2006-01-01T23:59:59.000Z

188

An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion  

SciTech Connect (OSTI)

Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

2010-02-19T23:59:59.000Z

189

Oxygen analyzer  

DOE Patents [OSTI]

An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

Benner, W.H.

1984-05-08T23:59:59.000Z

190

Sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation: The role of O{sub 3}, H{sub 2}O{sub 2}, frequency, and power density  

SciTech Connect (OSTI)

The kinetics of degradation of methyl tert-butyl ether (MTBE) by ultrasonic irradiation in the presence of ozone as functions of applied frequencies and applied power are investigated. Experiments are performed over the frequency range of 205--1,078 kHz. The higher overall reaction rates are observed at 358 and 618 kHz and then at 205 and 1,078 kHz. The observed pseudo-first-order rate constant, k{sub 0}, for MTBE degradation increases with increasing power density up to 250 W L{sup {minus}1}. A linear dependence of the first-order rate constant, k{sub O{sub 3}}, for the simultaneous degradation of O{sub 3} on power density is also observed. Naturally occurring organic matter (NOM) is shown to have a negligible effect on observed reaction rates.

Kang, J.W.; Hung, H.M.; Lin, A.; Hoffmann, M.R. [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.] [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.

1999-09-15T23:59:59.000Z

191

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network [OSTI]

methyl-tertiary-butyl- ether (MTBE) and the biomass burningfrom all source categories. MTBE is a gasoline additive andwith the fuel tracer MTBE (e.g. 0.82 for MTBE/benzene).

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

192

Environmental Life Cycle Implications of Fuel Oxygenate Production from California Biomass  

SciTech Connect (OSTI)

Historically, more than 90% of the excess agricultural residue produced in California (approximately 10 million dry metric tons per year) has been disposed through open-field burning. Concerns about air quality have prompted federal, state, and local air quality agencies to tighten regulations related to this burning and to look at disposal alternatives. One use of this biomass is as an oxygenated fuel. This report focuses on quantifying and comparing the comprehensive environmental flows over the life cycles of two disposal scenarios: (1) burning the biomass, plus producing and using MTBE; and (2) converting and using ETBE.

Kadam, K. L. (National Renewable Energy Laboratory); Camobreco, V. J.; Glazebrook, B. E. (Ecobalance Inc.); Forrest, L. H.; Jacobson, W. A. (TSS Consultants); Simeroth, D. C. (California Air Resources Board); Blackburn, W. J. (California Energy Commission); Nehoda, K. C. (California Department of Forestry and Fire Protection)

1999-05-20T23:59:59.000Z

193

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network [OSTI]

-butyl ether (MTBE) in a dense medium plasma (DMP) reactor utilizing gas chromatog- raphy-massspectrometryandgaschromatography-thermal conductivity techniques. A rate law is developed for the removal of MTBE from an aqueous solution in the DMP. The oxidation products from the treatment of MTBE-contaminated water in the DMP reactor were found

Dandy, David

194

Pyrolysis of Organic Molecules Relevant to Combustion as Monitored by Photoionization Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

is observed, which is similar to MTBE in this system whichisobutene formed from MTBE, is found to occur. REFERENCES [methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (

Weber, Kevin Howard

2010-01-01T23:59:59.000Z

195

Life-cycle Environmental Inventory of Passenger Transportation in the United States  

E-Print Network [OSTI]

Methyltert?ButylEther(MTBE);http://www.atsdr.cdc.gov/MethylTertiaryButyl Ether (MTBE), which was easilyaccountingwasnotperformedonMTBEandtheresult of

Chester, Mikhail V

2008-01-01T23:59:59.000Z

196

(distillation) (Le Chatelier  

E-Print Network [OSTI]

acetate(methyl-, ethyl-, butyl-) , methanol isobutene MTBE , ethanol isobutene ETBE , methanol 2-methyl-1% MTBE 3 DMC . 2% 1990 MTBE 1999 3 2002 MTBE . [ 1-1 ] Phosgene process polycarbonate(PC) 50/ . DMC DMC MTBE / . ( : Amoco, "Review of DMC Manufacture and its

Hong, Deog Ki

197

he U.S. Geological Survey's (USGS) National Water-Quality Assess-  

E-Print Network [OSTI]

of the wells included methyl tert-butyl ether (MTBE), tetrachloroethene (PCE), dichlorodifluoromethane, 1

198

Multiple Objective Stormwater Management For the Coliseum Complex  

E-Print Network [OSTI]

methyl tertiary butyl ether (MTBE) remain in the soil around5.2 ppb xylenes, and 160 ppb MTBE remain in the groundwater

Jones, Jesse; Kraai, Rachel

2009-01-01T23:59:59.000Z

199

Effects of water chemistry on NF/RO membrane structure and performance  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE), benzene, ethylbenzene,TCE** Industrial C 2 HCl 3 MTBE** [48] Industrial C 5 H 12 O

Mo, Yibing

2013-01-01T23:59:59.000Z

200

Water Research Institute Annual Technical Report  

E-Print Network [OSTI]

Air Act mandated oxygenated gasoline containing methyl tert-butyl ether (MtBE) in certain areas percent. The State of Maine elected to use reformulated gasoline (RFG) that contained at least 11 percent and by 1995, oxygenated gasoline use was common in the northeast. Soon after the widespread use of gasoline

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network [OSTI]

methyl-tertiary butyl ether (MTBE), from gasoline by 2004.MTBE was used to meet a requirement for gasoline to containbeginning in 2002, replacing MTBE with ethanol. According to

2007-01-01T23:59:59.000Z

202

The Scientific Basis for the Regulation of Nanoparticles: Challenging Paracelsus and Pare  

E-Print Network [OSTI]

NANOTECHNOILOGY 402 (2007). 20. MTBE unquestionably causesTertiary-Butyl Ether (MTBE)-a Gasoline Additive-CausesMethyl Tertiary-butyl Ether (MTBE) in CD-I Mice and F-344

Goldstein, Bernard D.

2010-01-01T23:59:59.000Z

203

Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

204

Soil type, crop and irrigation technique affect nitrogen leaching to groundwater  

E-Print Network [OSTI]

water contamination with MTBE (methyl tertiary-butyl ether,that areas vulnerable to MTBE are also vulner- able tothat affect the movement of MTBE. If only a small amount of

Letey, John; Vaughan, Peter

2013-01-01T23:59:59.000Z

205

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) at 57 amu has been previouslyby a fragment of MTBE (62%) with minor contributions fromFortner and Knighton, 2008). MTBE also in- terfered (16%)

2011-01-01T23:59:59.000Z

206

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3and SO2  

E-Print Network [OSTI]

methyl tertiary- butyl ether (MTBE) and its effect on plasmaand three VOCs (propyne, furan, MTBE) remained below their 3Ethanol Acetone MEK MAC MVK MTBE Furan CH 3 OH C 2 H 5 OH C

2010-01-01T23:59:59.000Z

207

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network [OSTI]

methyl-tertiary butyl ether (MTBE), from gasoline by 2004.MTBE was used to meet a requirement for gasoline to containbeginning in 2002, replacing MTBE with ethanol. According to

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

208

Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

209

Assessing the Effectiveness of California's Underground Storage Tank Annual Inspection Rate Requirements  

E-Print Network [OSTI]

Methyl Tert-Butyl Ether (MTBE), a gasoline additive. Thefor the lions share of MTBE contamination, as well asIn response to the MTBE crisis, California increased the

Cutter, W. Bowman

2008-01-01T23:59:59.000Z

210

Trichloroethene Removal From Waste Gases in Anaerobic Biotrickling Filters Through Reductive Dechlorination  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) vapors into water was used.MTBE is highly soluble in water (dimensionless Henrysgas stream was laden with MTBE vapors (200-300 mg m -3 )

Popat, Sudeep Chandrakant

2010-01-01T23:59:59.000Z

211

Life-Cycle Water Impacts of U.S. Transportation Fuels  

E-Print Network [OSTI]

Drinking Water: Methyl Tertiary Butyl Ether (MTBE).http://www.epa.gov/mtbe/water.htm (11/30/10), Chiu, Y. W. ;LCFS LCI LP LPG MED MRO MSF MTBE MWD MWDOC NAICS NERC NETL

Scown, Corinne Donahue

2010-01-01T23:59:59.000Z

212

Comparison of SPME headspace analysis to U.S. EPA method5030/8260B for MTBE monitoring  

SciTech Connect (OSTI)

A novel method for analysis of methyl tert-butyl ether andtert-butyl alcohol using solid phase microextraction is described andcompared to a standard method.

Stringfellow, William T.; Oh, Kuen-Chan

2005-02-01T23:59:59.000Z

213

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

214

ACCESS Magazine Fall 2010  

E-Print Network [OSTI]

for another. The addition of MTBE as a fuel oxygenate in theuse. The decision to use MTBE to improve air quality failed

2010-01-01T23:59:59.000Z

215

Solid state oxygen sensor  

DOE Patents [OSTI]

Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

1996-01-01T23:59:59.000Z

216

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

217

Impact of the renewable oxygenate standard for reformulated gasoline on ethanol demand, energy use, and greenhouse gas emissions  

SciTech Connect (OSTI)

To assure a place for renewable oxygenates in the national reformulated gasoline (RFG) program, the US Environmental Protection Agency has promulgated the renewable oxygenate standard (ROS) for RFG. It is assumed that ethanol derived from corn will be the only broadly available renewable oxygenate during Phase I of the RFG program. This report analyzes the impact that the ROS could have on the supply of ethanol, its transported volume, and its displacement from existing markets. It also considers the energy and crude oil consumption and greenhouse gas (GHG) emissions that could result from the production and use of various RFGs that could meet the ROS requirements. The report concludes that on the basis of current and projected near-term ethanol capacity, if ethanol is the only available renewable oxygenate used to meet the requirements of the ROS, diversion of ethanol from existing use as a fuel is likely to be necessary. Year-round use of ethanol and ETBE would eliminate the need for diversion by reducing winter demand for ethanol. On an RFG-program-wide basis, using ethanol and ETBE to satisfy the ROS can be expected to slightly reduce fossil energy use, increase crude oil use, and have essentially no effect on GHG emissions or total energy use relative to using RFG oxygenated only with MTBE.

Stork, K.C.; Singh, M.K.

1995-04-01T23:59:59.000Z

218

Equilibrium thermodynamic analysis of liquid-phase ethyl tert-butylether (ETBE) synthesis  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is now the second largest volume organic chemical, only behind ethylene, produced in the U.S. This is remarkable since its commercial production began barely two decades ago. Although MTBE is currently the industry standard, it has been proposed that ethanol and other renewable additives make up to 30% of the oxygenate market. As a result, ethyl tertiary butyl ether (ETBE, or 2-ethyoxy 2-methyl propane), derived from renewable ethanol and isobutylene, has emerged as a promising new oxygenate. ETBE also has a somewhat lower blending Reid vapor pressure as well as a higher octane number than MTBE. This paper describes the thermodynamic equilibrium constant for the production of ETBE.

Jensen, K.L.; Datta, R. [Univ. of Iowa, Iowa City, IA (United States)

1994-12-31T23:59:59.000Z

219

untitled  

Gasoline and Diesel Fuel Update (EIA)

3,054 Fuel Ethanol (FE) 1,019 97 1,116 2,133 528 393 3,054 Methyl Tertiary Butyl Ether (MTBE) 561 0 561 0 0 0 0 All Other Oxygenates a 0 0 0 0 0 0 0 Motor Gasoline Blend. Comp....

220

PSA Vol 1 Tables Revised Ver 2 Print.xls  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

11,352 13 1,309 15,181 42 Fuel Ethanol (FE) 0 0 0 0 0 0 0 Methyl Tertiary Butyl Ether (MTBE) 234 928 10,251 0 21 11,434 31 Other Oxygenates 955 390 1,101 13 1,288 3,747 10 Motor...

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

untitled  

Gasoline and Diesel Fuel Update (EIA)

Fuel Ethanol (FE) 1,229 108 1,337 2,369 724 497 3,590 Methyl Tertiary Butyl Ether (MTBE) 292 0 292 0 0 0 0 All Other Oxygenates a 0 0 0 0 0 0 0 Motor Gasoline Blend. Comp....

222

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

223

Oxygen partial pressure sensor  

DOE Patents [OSTI]

A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

Dees, D.W.

1994-09-06T23:59:59.000Z

224

Health concerns fuel EPA study of ETBE and TAME  

SciTech Connect (OSTI)

Citing possible health risks associated with the use of methyl tert-butyl ether (MTBE) in winter-blend gasoline and requirements of the 1990 Clean Air Act (CAA), EPA has called for testing the health effects of ethyl tert-butyl ether (EBTE) and tert-amyl methyl ether (TAME). The program calls for toxicity testing to develop data on the health effects of ETBE and TAME. EPA may require chemical manufacturers and processors to provide the data. A public meeting will be held this week to begin working on an agreement. EPA says most of the data should be collected in 1995 and expects the program to cost approximately $3 million. In December, EPA floated a proposal to require 30% of the oxygenates used in the reformulated gasoline program to come from renewable sources such as ETBE and ethanol. Although EPA found no serious health risks associated with MTBE, questions remain, which is why EPA says it will test the use of ETBE and TAME. William Piel, business manager for oxygenated fuels at Arco Chemical (Newtown Square, PA), says testing is {open_quotes}just a formality.{close_quotes} There should be no difference in results among MTBE, ETBE, or TAME, he says. But ETBE and TAME have much lower volatility than MTBE, which would mean significantly less exposure to these oxygenates, Piel says. Arco is the biggest producer of MTBE but also has capability to make ETBE.

Lucas, A.

1994-05-11T23:59:59.000Z

225

Integrated turbomachine oxygen plant  

SciTech Connect (OSTI)

An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

2014-06-17T23:59:59.000Z

226

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

2005-07-12T23:59:59.000Z

227

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

2004-11-23T23:59:59.000Z

228

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

229

Economics for iso-olefin production using the fluid catalytic cracking unit  

SciTech Connect (OSTI)

The Clean Air Act of 1990 requires use of oxygenates in some gasolines to improve both CO and hydrocarbon auto tailpipe emissions. Various oxygenates are currently being used by the refining industry. For the fully integrated refinery having a fluid catalytic cracking unit, the most commonly used oxygenates are methyl tertiary butyl ether (MTBE) and tertiary amyl ether (TAME). The FCC unit produces the isobutylene and iso-amylases need for manufacture of both MTBE and TAME. The economics for an assumed refinery processing scheme for several FCC cases are examined giving estimates of income and investments for each case. Up to one-third of the total gasoline pool can be made in reformulated gasoline using TAME and MTBE with the FCC unit as the sole source of feedstock. This processing route is much more economical than the alternative scheme using butane isomerization/iosbutane dehydrogenation.

McClung, R.G.; Witoshkin, A.; Bogert, D.C.; Winkler, W.S. [Englehard Corp., Iselin, NJ (United States)

1993-12-31T23:59:59.000Z

230

Effect of Ethanol and Methyl-tert-Butyl Ether on Monoaromatic Hydrocarbon Biodegradation: Response Variability for Different Aquifer Materials Under Various Electron-Accepting Conditions  

SciTech Connect (OSTI)

Aquifer microcosms were used to determine how ethanol and methyl-tert-butyl ether (MtBE) affect monoaromatic hydrocarbon degradation under different electron-accepting conditions commonly found in contaminated sites experiencing natural attenuation. Response variability was investigated by using aquifer material from four sites with different exposure history. The lag phase prior to BTEX (benzene, toluene, ethylbenzene, and xylenes) and ethanol degradation was typically shorter in microcosms with previously contaminated aquifer material, although previous exposure did not always result in high degradation activity. Toluene was degraded in all aquifer materials and generally under a broader range of electron-accepting conditions compared to benzene, which was degraded only under aerobic conditions. MtBE was not degraded within 100 days under any condition, and it did not affect BTEX or ethanol degradation patterns. Ethanol was often degraded before BTEX compounds, and had a variable effect on BTEX degradation as a function of electron-accepting conditions and aquifer material source. An occasional enhancement of toluene degradation by ethanol occurred in denitrifying microcosms with unlimited nitrate; this may be attributable to the fortuitous growth of toluene-degrading bacteria during ethanol degradation. Nevertheless, experiments with flow-through aquifer columns showed that this beneficial effect could be eclipsed by an ethanol-driven depletion of electron acceptors, which significantly inhibited BTEX degradation and is probably the most important mechanism by which ethanol could hinder BTEX natural attenuation. A decrease in natural attenuation could increase the likelihood that BTEX compounds reach a receptor as well as the potential duration of exposure.

Ruiz-Aguilar, G L; Fernandez-Sanchez, J M; Kane, S R; Kim, D; Alvarez, P J

2003-10-06T23:59:59.000Z

231

Detailed chemical kinetic reaction mechanism for biodiesel components methyl stearate and methyl oleate  

E-Print Network [OSTI]

Detailed chemical kinetic reaction mechanism for biodiesel components methyl stearate and methyl are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate renewable sources, can reduce net emissions of greenhouse gases. An important class of biodiesel fuels

Paris-Sud XI, Université de

232

Process for conversion of lignin to reformulated, partially oxygenated gasoline  

DOE Patents [OSTI]

A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

2001-01-09T23:59:59.000Z

233

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

234

High Selectivity Oxygen Delignification  

SciTech Connect (OSTI)

Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

Lucian A. Lucia

2005-11-15T23:59:59.000Z

235

MTBE Production Economics  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997EnvironmentElectricityrgy81 §98 3.241

236

Detailed Chemical Kinetic Reaction Mechanism for Biodiesel Components Methyl Stearate and Methyl Oleate  

SciTech Connect (OSTI)

New chemical kinetic reaction mechanisms are developed for two of the five major components of biodiesel fuel, methyl stearate and methyl oleate. The mechanisms are produced using existing reaction classes and rules for reaction rates, with additional reaction classes to describe other reactions unique to methyl ester species. Mechanism capabilities were examined by computing fuel/air autoignition delay times and comparing the results with more conventional hydrocarbon fuels for which experimental results are available. Additional comparisons were carried out with measured results taken from jet-stirred reactor experiments for rapeseed methyl ester fuels. In both sets of computational tests, methyl oleate was found to be slightly less reactive than methyl stearate, and an explanation of this observation is made showing that the double bond in methyl oleate inhibits certain low temperature chain branching reaction pathways important in methyl stearate. The resulting detailed chemical kinetic reaction mechanism includes more approximately 3500 chemical species and more than 17,000 chemical reactions.

Naik, C; Westbrook, C K; Herbinet, O; Pitz, W J; Mehl, M

2010-01-22T23:59:59.000Z

237

alkyl-tert alkyl ethers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TREAT METHYL- TERT-BUTYL ETHER CONTAMINATED CiteSeer Summary: Methyl-tert-butyl ether (MTBE) is a commonly used gasoline additive. Leaking underground storage tank systems,...

238

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

239

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

240

Direct Observation of the Oxygenated Species during Oxygen Reduction...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

UNIVERSITY OF CALIFORNIA Santa Barbara  

E-Print Network [OSTI]

, B. Dooher, and D. Rice, Analysis of dissolved benzene plumes and methyl tertiary butyl ether (MTBE, An evaluation of MTBE impacts to California groundwater resources, pp. 68 p., Lawrence Livermore National, Temporal Analysis of Methyl Tertiary Butyl Ether (MTBE) Plumes at California Leaking Underground Fuel tank

California at Santa Barbara, University of

242

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

243

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

244

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

245

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

246

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

247

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria, J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

248

Lyondell develops one step isobutylene process  

SciTech Connect (OSTI)

This paper reports that Lyondell Petrochemical Co., Houston, has developed a one step process to convert normal butylenes to isobutylene, a key component of methyl tertiary butyl ether (MTBE). MTBE is expected to become the additive of choice among U.S. refiners to blend oxygenated gasolines required by 1990 amendments to the Clean Air Act. Lyondell Pres. and Chief Executive Officer Bob Gower the the new process could help assure adequate supplies of MTBE to meet U.S. demand for cleaner burning fuels. Lyondell estimates the capital cost of building a grassroots plant to produce isobutylene with the new process would be less than half the cost of a grassroot plant to produce isobutylene with existing technology starting with normal butane.

Not Available

1992-03-23T23:59:59.000Z

249

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

250

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

251

EINLADUNG INFOTAG 2001 Eine Forschungsanstalt  

E-Print Network [OSTI]

durch den Benzinzusatz MTBE. Methyl-tert-butylether gehört weltweit zu den meistproduzierten orga- nischen Chemikalien. Weil MTBE im Grundwasser auftritt, soll es in den USA als Benzinzusatz verboten

Wehrli, Bernhard

252

Isothermal vapor-liquid equilibria for 2-methyl-2-butanol + 2-methyl-1-butanol + 1-pentanol  

SciTech Connect (OSTI)

Vapor-liquid equilibria (VLE) for 2-methyl-2-butanol + 2-methyl-1-butanol and 2-methyl-2-butanol + 2-methyl-1-butanol + 1-pentanol have been measured at 373.15 K. The binary VLE results have been correlated by different liquid-phase activity coefficient models. The binary interaction parameters obtained from Wilson, NRTL, and UNIQUAC models in this and a previously study are used to predict the VLE data for the ternary system. Vapor-liquid equilibrium (VLE) data are necessary for the design of distillation processes.

Aucejo, A.; Burguet, M.C.; Monton, J.B.; Munoz, R.; Sanchotello, M.; Vazquez, M.I. (Univ. of Valencia (Spain). Dept. de Ingenieria Quimica)

1994-07-01T23:59:59.000Z

253

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

254

Utilization of Renewable Oxygenates as Gasoline Blending Components  

SciTech Connect (OSTI)

This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

Yanowitz, J.; Christensen, E.; McCormick, R. L.

2011-08-01T23:59:59.000Z

255

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

256

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

257

Liquefaction of cellulosic wastes. 6: Oxygen compounds in pyrolytic oil and water fractions  

SciTech Connect (OSTI)

Liquid hydrocarbon oil and water have been produced from the liquefaction of cellulosic matter present in municipal solid wastes. The produced pyrolytic oil and water fraction seemed to be contaminated with considerable amounts of oxygen compounds as compared with fuels derived from a petroleum origin. The oxygen compounds included organic acids (fatty and naphthenic acids), phenols, and carbonyl compounds. These classes of oxygen compounds were extracted selectively from the pyrolytic oils and water using chemical extraction methods. Methyl esters of fatty acids and 2,4-dinitrophenylhydrazones of carbonyl compounds were identified by gas chromatography and thin layer chromatography, respectively. It was suggested that the identified oxygen compounds could be produced from the pyrolysis of volatiles (e.g., levoglucosane, which is the primary product of cellulose depolymerization) via different mechanistic pathways.

Gharieb, H.K.; Faramawy, S.; El-Amrousi, F.A.; El-Sabagh, S.M. [Egyptian Petroleum Research Inst., Cairo (Egypt)

1998-07-01T23:59:59.000Z

258

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

259

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

260

High Selectivity Oxygen Delignification  

SciTech Connect (OSTI)

The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

Arthur J. Ragauskas

2005-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

262

Oxygen-reducing catalyst layer  

DOE Patents [OSTI]

An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

2011-03-22T23:59:59.000Z

263

Electrochemical studies of quinone oxygen  

SciTech Connect (OSTI)

Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

1990-02-01T23:59:59.000Z

264

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

265

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

266

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network [OSTI]

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

267

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

268

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

269

Study downplays health concerns  

SciTech Connect (OSTI)

A government-funded study has concluded that reformulated gasoline containing methyl tert-butyl ether (MTBE) does not increase short-term health risks when compared with gasoline that does not contain the additive. The study, performed by the Health Effects Institute (Cambridge, MA), compared data from dozens of animal, human, and epidemiological studies of health effects linked to oxygenates, including MTBE and ethanol, but did not find enough evidence to warrant an immediate reduction in oxygenate use. However, the study did recommend that additional research be conducted on possible health consequences associated with the gasoline additives, including neurotoxic effects, if oxygenates continue to be used long term. Oxygenates have been used in gasoline since 1992, when EPA mandated that several municipalities use MTBE or other oxygenates in reformulated gasoline to reduce carbon monoxide emissions and meet Clean Air Act requirements. Shortly after the program began, residents in areas where the oxygenates were used complained of nausea, headaches, and dizziness. The institute says the study--funded by EPA and the Centers for Disease Control--will be used for a broader review of gasoline oxygenates by the White House Office of Science and Technology Policy.

Stringer, J.

1996-03-13T23:59:59.000Z

270

Mixed oxygen ion/electron-conducting ceramics for oxygen separation  

SciTech Connect (OSTI)

Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

1995-05-01T23:59:59.000Z

271

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

272

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

273

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

274

Determination of Total Lipids as Fatty Acid Methyl Esters (FAME...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

will be replaced by an ester bond between the fatty acid and a methyl group, producing methyl esters of the fatty acids (FAME) and free glycerol. 1.4 The FAME are then...

275

Comparative Dynamics of Leucine Methyl Groups in FMOC-Leucine...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dynamics of Leucine Methyl Groups in FMOC-Leucine and in a ProteinHydrophobic Core Probed by Solid-State Deuteron Comparative Dynamics of Leucine Methyl Groups in FMOC-Leucine and...

276

Sub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments  

E-Print Network [OSTI]

-dependent, sphero-symmetric droplet combustion simulation that includes detailed gas phase chemical kineticsSub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments and detailed 2012 Abstract Combustion characteristics of isolated sub-millimeter sized methyl butanoate (MB

Walter, M.Todd

277

Vapor-liquid equilibria for systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data were measured for binary systems of 1-butanol with 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol at 30 and 100 kPa. The experimental data obtained in this work are thermodynamically consistent according to a point-to-point consistency test, and deviation from ideal behavior is small in all cases. They can be equally well correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations.

Aucejo, A.; Burguet, M.C.; Monton, J.B.; Munoz, R.; Sanchotello, M.; Vazquez, M.I. (Univ. de Valencia (Spain). Dept. de Ingenieria Quimica)

1994-04-01T23:59:59.000Z

278

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-11-01T23:59:59.000Z

279

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

280

E-Print Network 3.0 - amplified methylation polymorphism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 2 Infraspecific DNA Methylation Polymorphism in Cotton (Gossypium Summary: Infraspecific DNA Methylation Polymorphism in Cotton (Gossypium...

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Oxygen transfer in the implant environment  

E-Print Network [OSTI]

Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

Goor, Jared Braden

2007-01-01T23:59:59.000Z

282

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

283

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux  

E-Print Network [OSTI]

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

Mallin, Michael

284

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

285

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network [OSTI]

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

286

Extracorporeal membrane oxygenation promotes long chain fatty...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

287

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network [OSTI]

Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

Kim, Kee Chul

2010-01-01T23:59:59.000Z

288

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

289

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

for technology that can control microscale oxygen gradientstechnology is the ability to rapidly generate and alter oxygentechnology should enable numerous studies in the field of biology where oxygen

Park, Jaehyun

2010-01-01T23:59:59.000Z

290

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

2003-11-01T23:59:59.000Z

291

Environmental Toxicology and Chemistry, Vol. 21, No. 12, pp. 26312639, 2002 Printed in the USA  

E-Print Network [OSTI]

--Aquifer microcosms were used to determine how ethanol and methyl-tert-butyl ether (MtBE) affect monoaromatic compared to benzene, which was degraded only under aerobic conditions. The MtBE was not degraded within 100 to phase out MtBE as a gasoline oxy- genate is likely to significantly increase the use of ethanol

Alvarez, Pedro J.

292

90% of new cars have engines specially designed to run on hydrous ethanol. This avoids the expense of remov-  

E-Print Network [OSTI]

competes with gasoline (petrol), diesel and MTBE (methyl tert-butyl ether, added to gasoline to MTBE, however, ethanol is comparable regarding price per energy unit and has considerable environmental advantages. MTBE is added to gasoline as an octane booster, replac- ing the lead formerly used

293

Monitoring synaptic protein dynamics with higher temporal, spatial, and molecular resolution  

E-Print Network [OSTI]

Spectrometry mSOG MiniSOG MTBE Methyl tert-butyl ether mTORMethyl tert-butyl ether (MTBE, 1.4 mL) was then added for1,000 g, 5 min). The MTBE layer was collected into a 1.5-mL

Butko, Margaret

2012-01-01T23:59:59.000Z

294

I. Pt-Catalyzed Tandem Epoxide Fragmentation/Pentannulation of Propargylic Esters II. Progress Toward the Kopsia Family of Indole Alkaloids  

E-Print Network [OSTI]

methyl t-butyl ether (MTBE), a much more environmentallyPhMe, reflux POCl 3 , Et 3 N CN MTBE Scheme 3.3: OptimizedO H NH POCl 3 , Et 3 N CN MTBE 1-Isocyanocyclohex-1-ene (

Pujanauski, Brian Gerard

2010-01-01T23:59:59.000Z

295

Oxidation and methylation of dissolved elemental mercury by anaerobic bacteria  

SciTech Connect (OSTI)

Methylmercury is a neurotoxin that poses significant health risks to humans. Some anaerobic sulphate- and iron-reducing bacteria can methylate oxidized forms of mercury, generating methylmercury1-4. One strain of sulphate-reducing bacteria (Desulfovibrio desulfuricans ND132) can also methylate elemental mercury5. The prevalence of this trait among different bacterial strains and species remains unclear, however. Here, we compare the ability of two strains of the sulphate-reducing bacterium Desulfovibrio and one strain of the iron-reducing bacterium Geobacter to oxidise and methylate elemental mercury in a series of laboratory incubations. Experiments were carried out under dark, anaerobic conditions, in the presence of environmentally-relevant concentrations of elemental mercury. We report differences in the ability of these organisms to oxidise and methylate elemental mercury. In line with recent findings5, we show that Desulfovibrio desulfuricans ND132 can both oxidise and methylate elemental mercury. However, the rate of methylation of elemental mercury is only about one third the rate of methylation of oxidized mercury. We also show that Desulfovibrio alaskensis G20 can oxidise, but not methylate, elemental mercury. Geobacter sulfurreducens PCA is able to oxidise and methylate elemental mercury in the presence of cysteine. We suggest that the activity of methylating and non-methylating bacteria may together enhance the formation of methylmercury in anaerobic environments.

Hu, Haiyan [ORNL] [ORNL; Lin, Hui [ORNL] [ORNL; Zheng, Wang [ORNL] [ORNL; Tomanicek, Stephen J [ORNL] [ORNL; Johs, Alexander [ORNL] [ORNL; Feng, Xinbin [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Gu, Baohua [ORNL] [ORNL

2013-01-01T23:59:59.000Z

296

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

297

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network [OSTI]

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

298

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which can lead to public health problems. * MtBE (Methyl tert Butyl Ether), a gasoline additive, has begun to contaminate ground water supplies. * Similarly, perchlorate has...

299

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides  

E-Print Network [OSTI]

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

Paris-Sud XI, Université de

300

Oxygen uptake of benthic systems  

E-Print Network [OSTI]

mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

Priebe, William Franklin

1972-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Methyl viologen radical reactions with several oxidizing agents. [Gamma Radiation  

SciTech Connect (OSTI)

The rates of oxidation of the methyl viologen radical by peroxodisulfate and hydrogen peroxide has been investigated. The methyl viologen free radical was produced by pulse radiolysis. The reaction of the peroxodisulfate radical with the methyl viologen radical was first order in both species, and the reaction rate constant is reported. A el-radiation study revealed a chain decomposition of the peroxodisulfate radical involving the methyl viologen radical when methanol, ethanol, or 2-propanol was present. Loss of the methyl viologen radical was then no longer observed to be a simple first-order reaction. The reaction of hydrogen peroxide with the methyl viologen radical was very slow in the presence of 1 M methanol. A much faster reaction in the absence of methanol was interpreted to be a reaction of the methyl viologen radical with the peroxy radicals. Hydrogen peroxide, in contrast to the chain decomposition of peroxodisulfate radicals, does not participate in a chain reaction involving the methyl viologen radical and methanol. Rate constants for the reaction of methyl viologen radical with dichromate radical, iodate radical, and ferricyanide radical are reported.

Levey, G.; Ebbesen, T.W.

1983-01-01T23:59:59.000Z

302

Quantifying the areal extent and dissolved oxygen concentrations of Archean oxygen oases.  

E-Print Network [OSTI]

??Several lines of evidence indicate that the advent of oxygenic photosynthesis preceded the oxygenation of the atmosphereperhaps by as much as 300 million years. The (more)

Olson, Stephanie

2013-01-01T23:59:59.000Z

303

The degradation of TPX components by oxygen, elevated temperature, and ionizing radiation  

SciTech Connect (OSTI)

TPX is PMP or poly(4-methyl-1-pentene). It has several commercially important characteristics such as high optical transparency, high crystalline melting point, etc., leading to numerous applications including infrared windows, lenses, membranes, food packaging. The life components fabricated from this material may be limited by thermal oxidative and radiation-induced degradation. A preliminary review of the scientific literature was conducted to obtain relevant information on the effects of oxygen, moisture elevated temperature, and radiation on the chemical, thermodynamic, mechanical, and electrical properties of this material. Refs, figs, tabs.

Farmer, J.C.

1996-05-31T23:59:59.000Z

304

Oxygen reduction on platinum : an EIS study  

E-Print Network [OSTI]

The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

Golfinopoulos, Theodore

2009-01-01T23:59:59.000Z

305

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

306

The Role of Oxygen in Coal Gasification  

E-Print Network [OSTI]

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

307

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

308

Composite oxygen ion transport element  

SciTech Connect (OSTI)

A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

2007-06-12T23:59:59.000Z

309

Catalyst containing oxygen transport membrane  

SciTech Connect (OSTI)

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

2012-12-04T23:59:59.000Z

310

ORTH/VIM proteins that regulate DNA methylation are functional ubiquitin E3 ligases  

E-Print Network [OSTI]

ORTH/VIM proteins that regulate DNA methylation are functional ubiquitin E3 ligases Edward Kraft1 methylation status in vivo. Keywords: RING, E3 ligase, DNA methylation, ubiquitylation, ORTH/VIM, SRA

Jacobsen, Steve

311

AN ELECTRICAL OXYGEN-TEMPERATURE METER  

E-Print Network [OSTI]

426 AN ELECTRICAL OXYGEN-TEMPERATURE METER FOR FISHERY BIOLOGISTS SEP 2 1196: vuUiJo HIM. . SPECIAL and Wildlife, Daniel H. Janzen, Director AN ELECTRICAL OXYGEN-TEMPERATURE METER FOR FISHERY BIOLOGISTS -temperature meter 11 Maintenance and trouble -shooting 12 #12;AN ELECTRICAL OXYGEN-TEMPERATURE METER

312

Effects of oxygen on fracturing fluids  

SciTech Connect (OSTI)

The stability of polysaccharide gels at high temperature is limited by such factors as pH, mechanical degradation, and oxidants. Oxygen is unavoidably placed in fracturing fluids through dissolution of air. To prevent premature degradation of the fracturing fluid by this oxidant, oxygen scavengers are commonly used. In this paper, the effects of oxygen and various oxygen scavengers on gel stability will be presented. Mechanical removal of oxygen resulted in surprisingly stable fracturing gels at 275 F. However, chemical removal of oxygen gave mixed results. Test data from sodium thiosulfate, sodium sulfite, and sodium erythorbate used as oxygen scavengers/gel stabilizers showed that the efficiency of oxygen removal from gels did not directly coincide with the viscosity retention of the gel, and large excesses of additives were necessary to provide optimum gel stabilization. The inability of some oxygen scavengers to stabilize the gel was the result of products created from the interaction of oxygen with the oxygen scavenger, which in turn, produced species that degraded the gel. The ideal oxygen scavenger should provide superior gel stabilization without creating detrimental side reaction products. Of the materials tested, sodium thiosulfate appeared to be the most beneficial.

Walker, M.L.; Shuchart, C.E.; Yaritz, J.G.; Norman, L.R.

1995-11-01T23:59:59.000Z

313

Oxygen Detection via Nanoscale Optical Indicators  

E-Print Network [OSTI]

Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

Ghosh, Ruby N.

314

8, 22252248, 2008 Detection of oxygen  

E-Print Network [OSTI]

ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

Paris-Sud XI, Université de

315

The Mechanisms of Oxygen Reduction and Evolution Reactions in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

316

Oxygen consumption of bovine granulosa cells in vitro.  

E-Print Network [OSTI]

??The oxygen consumption rate of granulosa cells is considered to be a key determinant of oocyte oxygenation in follicles. The oxygen status of the oocyte (more)

Li, Dongxing

2012-01-01T23:59:59.000Z

317

Host cells and methods for producing 3-methyl-2-buten-1-ol, 3-methyl-3-buten-1-ol, and 3-methyl-butan-1-ol  

DOE Patents [OSTI]

The invention provides for a method for producing a 5-carbon alcohol in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses a first enzyme capable of catalyzing the dephosphorylation of an isopentenyl pyrophosphate (IPP) or dimethylallyl diphosphate (DMAPP), such as a Bacillus subtilis phosphatase (YhfR), under a suitable condition so that 5-carbon alcohol is 3-methyl-2-buten-1-ol and/or 3-methyl-3-buten-1-ol is produced. Optionally, the host cell may further comprise a second enzyme capable of reducing a 3-methyl-2-buten-1-ol to 3-methyl-butan-1-ol, such as a reductase.

Chou, Howard H. (Berkeley, CA); Keasling, Jay D. (Berkeley, CA)

2011-07-26T23:59:59.000Z

318

Lycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic  

E-Print Network [OSTI]

, quenching singlet oxygen generated during the water-splitting process of photo- synthesis (10, 11). VariousLycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic photosynthetic cyclase. Instead, we show that CruP aids in preventing accumulation of reactive oxygen species (ROS

Wurtzel, Eleanore

319

Experimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine Laser  

E-Print Network [OSTI]

state I. Conventionally, a two-phase (gas-liquid) chemistry singlet oxygen generator (SOG) producesExperimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine of the electric discharge iodine laser continues, the role of oxygen atoms downstream of the discharge region

Carroll, David L.

320

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as  

E-Print Network [OSTI]

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes  

E-Print Network [OSTI]

1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

Paris-Sud XI, Université de

322

E-Print Network 3.0 - arsenic methylation profiles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , urinary arsenic methylation profiles, and urothelial carcinoma susceptibility. Food Chem. Toxicol. 46, 929... and in vitro studies suggest that methylated arsenic...

323

NAME/TEAM: ______________________________________ FTIR postlab -1  

E-Print Network [OSTI]

Spectroscopy Postlab Last modified: June 17, 2014 1) Summarize your results in the following table: v/v % MTBE your value % RE 100 lit. value - = ? 4) Convert your v/v % MTBE in gasoline to units of mass % (w/w %) of oxygen in gasoline. Density of MTBE = 0.74 g/mL, Density of gasoline = 0.66 g/mL, Molar Mass of MTBE = 88

Nizkorodov, Sergey

324

OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES  

E-Print Network [OSTI]

OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

Byrn, Marianne; Calvin, Melvin

1965-01-01T23:59:59.000Z

325

Methyl bromide emissions to the atmosphere from temperate woodland ecosystems  

E-Print Network [OSTI]

The environmental importance of methyl bromide (CH3Br) arises from its contribution to stratospheric ozone loss processes and, as a consequence, its emissions from anthropogenic sources are subject to the Montreal Protocol. A better understanding...

Drewer, Julia; Heal, Kate V; Smith, Keith A; Heal, Mathew R

2008-01-01T23:59:59.000Z

326

The Genetics of de novo Methylation in Arabidopsis thaliana  

E-Print Network [OSTI]

domains akin to UHRF1 and the VIM proteins. These proteinsthe VARIANT IN METHYLATION (VIM) family. In higher orderUHRF1 in mammal or the VIM proteins in plants. UHRF1/VIM

Greenberg, Maxim Van Cleef

2012-01-01T23:59:59.000Z

327

Regulation of yeast development by mRNA methylation  

E-Print Network [OSTI]

The internal methylation of mRNA post-transcriptionally is an essential component of the mRNA editing machinery in virtually every eukaryotic system. Despite this ubiquity, little is known about the relevance, consequences ...

Agarwala, Sudeep D

2012-01-01T23:59:59.000Z

328

akap12 promoter methylation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(MEK) with hydrogen peroxide (H2O2), is widely used in industry as a radicalThermal Hazard Analysis of Methyl Ethyl Ketone Peroxide Ron-Hsin Chang, Chi-Min Shu and Po-Yin Yeh...

329

Control of mercury methylation in wetlands through iron addition  

E-Print Network [OSTI]

Mason, R. P. ; Flegal, A. R. , Mercury speciation in the SanP. ; Flegal, A. R. , Decadal mercury trends in San FranciscoP. G. ; Nelson, D. C. , Mercury methylation from unexpected

Sedlak, David L; Ulrich, Patrick D

2009-01-01T23:59:59.000Z

330

Methyl arsenic adsorption and desorption behavior on iron oxides  

E-Print Network [OSTI]

METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 2004 Major Subject: Soil Science METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to Texas A&M University...

Lafferty, Brandon James

2005-08-29T23:59:59.000Z

331

The synthesis of some N-methylated aminoalkylphosphonic acids  

E-Print Network [OSTI]

(XLIII) were o heated with diethyl hydrogenphosphonate (XVI) at approximately 100 until the evolution of dimethylarnine (XXX) ceased. The 1-dimethyl- amino 1-alkenes (XLIV) reacted exothermically with diethyl hydro- genphosphonate (XVI) once... exothermically with methyl iodide at room temperature whereas the other eaters, which contained more bulky (R) substituents, did not. Secondly, the betaine obtained m the highest yield, N, N, N-trimethyl-N-(phosphono- methyl)ammonium hydroxide, mner salt...

Eikenberry, Jon Nathan

1966-01-01T23:59:59.000Z

332

Identification of an Archean marine oxygen oasis  

SciTech Connect (OSTI)

The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

Riding, Dr Robert E [University of Tennessee (UT); Fralick, Dr Philip [Lakehead University, Canada; Liang, Liyuan [ORNL

2014-01-01T23:59:59.000Z

333

Myocardial Reloading after Extracorporeal Membrane Oxygenation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Protein Synthesis. Abstract: Extracorporeal membrane oxygenation (ECMO) unloads the heart providing a bridge to recovery in children after myocardial stunning. Mortality after...

334

Oxygen Concentration Microgradients for Cell Culture.  

E-Print Network [OSTI]

??There is a growing need for technology that can control microscale oxygen gradients onto a tissue or culture sample in vitro. This dissertation introduces the (more)

Park, Jaehyun

2010-01-01T23:59:59.000Z

335

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

Tsuo, Y. Simon (Lakewood, CO)

1991-01-01T23:59:59.000Z

336

Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system  

E-Print Network [OSTI]

Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

Low, Clarke Alan

2008-01-01T23:59:59.000Z

337

TABLES1.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

ethanol blended into finished motor gasoline and oxygenate production from merchant MTBE plants are also included. d Includes stocks located in the Strategic Petroleum Reserve....

338

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen  

E-Print Network [OSTI]

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

Sibener, Steven

339

New Oxygen-Production Technology Proving Successful  

Broader source: Energy.gov [DOE]

The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

340

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network [OSTI]

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, shielded metal arc, self-shielded metal arc, and submerged arc welding are reviewed. Calcu- lations upon heating is also discussed. Introduction Oxygen and nitrogen ~ontamination of weld metal

Eagar, Thomas W.

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates  

SciTech Connect (OSTI)

Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

Zhao, Y.; Xu, Q.; Cheah, S.

2013-01-01T23:59:59.000Z

342

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

343

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1997-01-01T23:59:59.000Z

344

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1996-01-01T23:59:59.000Z

345

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

346

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

347

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)  

E-Print Network [OSTI]

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

Levin, Lisa

348

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System  

E-Print Network [OSTI]

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

Carroll, David L.

349

Nested methylation-specific polymerase chain reaction cancer detection method  

DOE Patents [OSTI]

A molecular marker-based method for monitoring and detecting cancer in humans. Aberrant methylation of gene promoters is a marker for cancer risk in humans. A two-stage, or "nested" polymerase chain reaction method is disclosed for detecting methylated DNA sequences at sufficiently high levels of sensitivity to permit cancer screening in biological fluid samples, such as sputum, obtained non-invasively. The method is for detecting the aberrant methylation of the p16 gene, O 6-methylguanine-DNA methyltransferase gene, Death-associated protein kinase gene, RAS-associated family 1 gene, or other gene promoters. The method offers a potentially powerful approach to population-based screening for the detection of lung and other cancers.

Belinsky, Steven A. (Albuquerque, NM); Palmisano, William A. (Edgewood, NM)

2007-05-08T23:59:59.000Z

350

Characterization of an oxygen suspension used for intravenous infusion  

E-Print Network [OSTI]

Oxygenated fluid mixture can be used to treat critically ill patients suffering from asphyxia, lung injury, and cardiac arrest. This oxygenated fluid delivered intravenously re-oxygenates the bloodstream, allowing for more ...

Pea, Kristen Helen

2012-01-01T23:59:59.000Z

351

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

352

Blood oxygen transport and depletion : the key of consummate divers  

E-Print Network [OSTI]

and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

Meir, Jessica Ulrika

2009-01-01T23:59:59.000Z

353

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

354

Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF  

E-Print Network [OSTI]

neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

2010-01-01T23:59:59.000Z

355

Long-term oxygen sensor implantation in the porcine subcutaneous environment  

E-Print Network [OSTI]

Membrane-?Covered Oxygen Electrode. Analytical Microvascular and tissue oxygen distribution. vitro stability of an oxygen sensor. Anal Chem,

Kumosa, Lucas Stefan

2011-01-01T23:59:59.000Z

356

On the maximum value of the cosmic abundance of oxygen and the oxygen yield  

E-Print Network [OSTI]

We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2007-01-11T23:59:59.000Z

357

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J.

2013-01-29T23:59:59.000Z

358

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J

2013-11-26T23:59:59.000Z

359

Methods for detection of methyl-CpG dinucleotides  

DOE Patents [OSTI]

The invention provides methods for enriching methyl-CpG sequences from a DNA sample. The method makes use of conversion of cytosine residues to uracil under conditions in which methyl-cytosine residues are preserved. Additional methods of the invention enable to preservation of the context of me-CpG dinucleotides. The invention also provides a recombinant, full length and substantially pure McrA protein (rMcrA) for binding and isolation of DNA fragments containing the sequence 5'-C.sup.MeCpGG-3'. Methods for making and using the rMcrA protein, and derivatives thereof are provided.

Dunn, John J.

2012-09-11T23:59:59.000Z

360

Effects of hydration water on protein methyl group dynamics insolution  

SciTech Connect (OSTI)

Elastic and quasielastic neutron scattering experiments have been used to investigate the dynamics of methyl groups in a protein-model hydrophobic peptide in solution. The results suggest that, when the hydrophobic side chains are hydrated by a single hydration water layer, the only allowed motions are confined and attributed to librational and rotational movement associated with the methyl groups. They provide unique experimental evidence that the structural and dynamical properties of the interfacial water strongly influence the side-chain dynamics and the activation of diffusive motion.

Russo D; Hura GL; Copley JRD

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

362

Density Functional Theory Study of Oxygen Reduction Activity...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Abstract: The...

363

Selective reduction of NOx in oxygen rich environments with plasma...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

364

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

365

Oxygen detected in atmosphere of Saturn's moon Dione  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

366

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

367

Effects of Oxygen-Containing Functional Groups on Supercapacitor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular dynamics (MD)...

368

Testing Oxygen Reduction Reaction Activity with the Rotating...  

Broader source: Energy.gov (indexed) [DOE]

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

369

Isolation, Characterization of an Intermediate in an Oxygen Atom...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

370

Fractionation of Oxygen Isotopes in Phosphate during its Interactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides. Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides....

371

Direct Measurement of Oxygen Incorporation into Thin Film Oxides...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

372

Density Functional Study of the Structure, Stability and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

373

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

374

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

375

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

376

Reactive Gliosis Reactive Oxygen Species: Superoxide  

E-Print Network [OSTI]

. By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

377

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

378

Design optimization of oxygenated fluid pump  

E-Print Network [OSTI]

In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

Piazzarolo, Bruno Aiala

2012-01-01T23:59:59.000Z

379

Electron-impact excitation of neutral oxygen  

E-Print Network [OSTI]

Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

P. S. Barklem

2006-09-25T23:59:59.000Z

380

Injectable polymer for in vivo oxygen sensing  

E-Print Network [OSTI]

This thesis documents the synthesis and characterization of an elastomeric polymer that is oxygen sensitive and can be interrogated using Magnetic Resonance Imaging (MRI) or Magnetic Resonance (MR) technology to report the ...

Imaad, Syed M. (Syed Muhammad)

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Oxygen Enriched Combustion System Performance Study  

E-Print Network [OSTI]

}ched combustlon systems are technically, envlronmentally and economically feasible and offer significant energy savings and/or productivity improvement, and then to verify the performance of selected systems in research furnaces. Tests of several commercial... for 35 - 100 percent oxygen. The absolute levels of the NO x emissions also depended on the furnace temperature. INTRODUCTION Oxygen enriched combustion has been found to have significant energy saving potential in industrial furnace applications...

Chen, S. L.; Kwan, Y.; Abele, A. R.; Silver, L. S.; Kobayashi, H.

382

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

383

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

384

Magnetism in LithiumOxygen Discharge Product  

SciTech Connect (OSTI)

Nonaqueous lithiumoxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithiumoxygen batteries. We demonstrate that the major discharge product formed in the lithiumoxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

2013-05-13T23:59:59.000Z

385

Atomic Oxygen in the Comae of Comets  

E-Print Network [OSTI]

We report on the detection of atomic oxygen lines in the spectra of 8 comets. These forbidden lines are a result of the photodissociation of the parent oxygen-bearing species directly into an excited state. We used high resolution spectra obtained at the McDonald Observatory 2.7m telescope to resolve the cometary oxygen lines from the telluric oxygen lines and from other cometary emissions. We find that the relative intensities of the two red lines (6300.304 and 6363.776A) are consistent with theory. The green line (5577.339A) has an intensity which is about 10% of the sum of the intensities of the two red lines. We show that collisional quenching may be important in the inner coma. If we assume the relative excitation rates of potential parents which have appeared in the literature, then H2O would be the parent of the cometary green oxygen line. However, those rates have been questioned. We measured the width of the three oxygen lines and find that the green line is wider than either of the two red lines. The finding of a wider line could imply a different parent for the green and red lines. However, the constancy of the green to red line flux ratio suggests the parent is the same for these lines but that the exciting photons have different energies.

Anita L. Cochran

2008-07-03T23:59:59.000Z

386

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

387

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic Core at Cryogenic Temperatures by Deuteron NMR Spectroscopy. Freezing of Dynamics of a Methyl Group in a Protein...

388

Environmental and age effects on methylation changes in human brain and blood cells  

E-Print Network [OSTI]

Previous studies have shown that DNA methylation may 1 e associated with disease, aging, the rate of aging and genetics. In this thesis, age is accurately predicted from DNA methylation in brain and blood tissues using two ...

Giguzinsky, Orit

2014-01-01T23:59:59.000Z

389

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

390

The degradation of TPX components by oxygen, elevated temperature, and ionizing radiation  

SciTech Connect (OSTI)

Poly(4-methyl-l-pentene), also known as PMP or TPX, has several commercially important characteristics such as high optical transparency, high crystalline melting point, low density, low electrical conductivity, and good heat resistance. Such characteristics have lead to numerous industrial applications including infrared windows, infrared lenses, membranes, and food packaging. The life components fabricated from this material may be limited bv thermal oxidative and radiation-induced degradation. A preliminary review of the scientific literature has been conducted to obtain relevant information on the effects of oxygen, moisture elevated temperature, and radiation on the chemical, thermodynamic, mechanical, and electrical properties of this important construction material. Key information from the literature has become especially important in light of decreased budgets for defense-related research and development, and the prolonged service life of existing systems.

Farmer, J.C.

1996-09-01T23:59:59.000Z

391

Ultrafast photochemistry of methyl hydroperoxide on ice particles  

E-Print Network [OSTI]

Ultrafast photochemistry of methyl hydroperoxide on ice particles M. A. Kambouresa , S. AOOH, on water clusters produces a surprisingly wide range of products on a subpicosecond time scale | photodissociation Photoinduced processes at surfaces of water or ice are of interest in atmospheric chemistry

Nizkorodov, Sergey

392

Oxygen generator for medical applications (USIC)  

SciTech Connect (OSTI)

The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

Staiger, C. L.

2012-03-01T23:59:59.000Z

393

Phase 1 Methyl Iodide Deep-Bed Adsorption Tests  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products (FPs) and activation products including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent [Jubin 2012b]. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the first phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during Fiscal Year (FY) 2013 and early FY-2014. Testing has been performed to address questions posed in the test plan, and followed the testing outline in the test plan. Tests established detection limits, developed procedures for sample analysis with minimal analytical interferences, and confirmed earlier results that show that the methyl iodide reacts when in contact with the AgZ sorbent, and not significantly in the gas flow upstream of the sorbent. The reaction(s) enable separation of the iodine from the organic moiety, so that the iodine can chemisorb onto the sorbent. The organic moiety can form other compounds, some of which are organic compounds that are detected and can be tentatively identified using GC-FID and GCMS. Test results also show that other gas constituents (NOx and/or H2O) can affect the methyl iodide reactions. With NOx and H2O present in the gas stream, the majority of uncaptured iodine exiting iodine-laden sorbent beds is in the form of I2 or HI, species that are soluble in NaOH scrubbing solution for iodine analysis. But when NOx and H2O are not present, then the majority of the uncaptured iodine exiting iodine-laden sorbent is in the form of methyl iodide. Methyl iodide adsorption efficiencies have been high enough so that initial DFs exceed 1,000 to 10,000. The methyl iodide mass transfer zone depths are estimated at 4-8 inches, possibly deeper than mass transfer zone depths estimated for I2 adsorption on AgZ. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption under various conditions specified in the methyl iodide test plan, and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

Nick Soelberg; Tony Watson

2014-08-01T23:59:59.000Z

394

Dissecting Oxygenic Photosynthesis: The Evolution of the "Z"-Scheme  

E-Print Network [OSTI]

of the "period four oxygen clock" and the structure of the oxygen-evolving center. After a brief mention the maximum quantum yield, i.e., the number of oxygen molecules evolved per photon of light absorbed11CHAPTER Dissecting Oxygenic Photosynthesis: The Evolution of the "Z"-Scheme for Thylakoid

Govindjee

395

Oxygen Toxicity Calculations by Erik C. Baker, P.E.  

E-Print Network [OSTI]

1 Oxygen Toxicity Calculations by Erik C. Baker, P.E. Management of exposure to oxygen toxicity myself using the good ole' FORTRAN programming language, I found that incorporating oxygen toxicity for others. Background Two oxygen toxicity parameters are typically "tracked" in technical diving

Read, Charles

396

Energetic neutral atoms at Mars 4. Imaging of planetary oxygen  

E-Print Network [OSTI]

Energetic neutral atoms at Mars 4. Imaging of planetary oxygen S. Barabash and M. Holmstro of the Martian oxygen exosphere/corona results in the production of planetary oxygen ions. The newborn ions start. The oxygen ions can then charge exchange with the neutral gases (H, H2, and O) of the Martian exosphere

Lukyanov, Alex

397

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-02-01T23:59:59.000Z

398

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

399

Oxygen abundance of open cluster dwarfs  

E-Print Network [OSTI]

We present oxygen abundances of dwarfs in the young open cluster IC 4665 deduced from the OI $\\lambda$7774 triplet lines and of dwarfs in the open cluster Pleiades derived from the [OI] $\\lambda$6300 forbidden line. Stellar parameters and oxygen abundances were derived using the spectroscopic synthesis tool SME (Spectroscopy Made Easy). We find a dramatic increase in the upper boundary of the OI triplet abundances with decreasing temperature in the dwarfs of IC 4665, consistent with the trend found by Schuler et al. in the open clusters Pleiades and M 34, and to a less extent in the cool dwarfs of Hyades (Schuler et al. 2006a) and UMa (King & Schuler 2005). By contrast, oxygen abundances derived from the [OI] $\\lambda$6300 forbidden line for stars in Pleiades and Hyades (Schuler et al. 2006b) are constant within the errors. Possible mechanisms that may lead a varying oxygen triplet line abundance are examined, including systematic errors in the stellar parameter determinations, the NLTE effects, surface activities and granulation. The age-related effects stellar surface activities (especially the chromospheric activities) are suggested by our analysis to blame for the large spreads of oxygen triplet line abundances.

Z. -X. Shen; X. -W. Liu; H. -W. Zhang; B. Jones; D. N. C. Lin

2007-03-30T23:59:59.000Z

400

Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells  

E-Print Network [OSTI]

Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells Xue Xia, Justin C. Tokash, Fang Zhang, Peng Liang, Xia Huang,*, and Bruce E. Logan*,, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, P

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully influence organisms living in near  

E-Print Network [OSTI]

Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully to the winter of 2014. Their scholarly work is presented in this collection. #12;1 Oxygen: From Environment", 2013, 2014 Table of contents Page 2. Laura Lilly - Low-oxygen formation along the California current. 6

402

Interaction of light with the ZnO surface: Photon induced oxygen "breathing," oxygen vacancies, persistent photoconductivity,  

E-Print Network [OSTI]

Interaction of light with the ZnO surface: Photon induced oxygen "breathing," oxygen vacancies donation of oxygen vacancies. Our findings suggest that the observed decomposition of the ZnO lattice may. The formation of oxygen-vacancy rich surface is suggested to induce surface delta doping, causing accumulation

Shalish, Ilan

403

Photochemical Escape of Oxygen from Early Mars  

E-Print Network [OSTI]

Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

Zhao, Jinjin

2015-01-01T23:59:59.000Z

404

Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report  

SciTech Connect (OSTI)

The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

Dombek, B.D.

1996-03-01T23:59:59.000Z

405

Oxygen Transport Ceramic Membranes Quarterly Report  

E-Print Network [OSTI]

/Reaction rates in Ion 21 Transport Membranes using Isotope Tracer and Transient Kinetic Techniques CONCLUSIONS 30Oxygen Transport Ceramic Membranes Quarterly Report January 2003 ­ March 2003 Principal Authors on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane

Eagar, Thomas W.

406

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

407

Oxygen addition to sulfur of metal thiolates  

E-Print Network [OSTI]

, and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

Soma, Takako

2012-06-07T23:59:59.000Z

408

Oxygen isotope exchange between water and semiquinones  

SciTech Connect (OSTI)

A reaction is described that can be utilized to produce /sup 17/O-labeled anion radicals that yield strong well resolved ESR signals exhibiting splitting from the /sup 17/O nucleus. The oxygen anthraquinone has been studied, and the results are reported herein. 7 references, 1 figure.

Stevenson, G.R.; Wang, Z.Y.; Reiter, R.C.; Peters, S.J.

1988-09-14T23:59:59.000Z

409

Oxygen-producing inert anodes for SOM process  

DOE Patents [OSTI]

An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

Pal, Uday B

2014-02-25T23:59:59.000Z

410

Mercury Methylation in Mine Wastes Collected from Abandoned Mercury Mines in the USA  

SciTech Connect (OSTI)

Mercury mines contain highly elevated Hg contents, but more problematic environmentally are elemental Hg and soluble Hg salts produced during ore retorting that remain in wastes at mine sites. Under certain conditions, these inorganic Hg compounds convert to bioavailable, highly toxic organic Hg forms. Speciation and transformation of Hg was studied in wastes collected from abandoned Hg mines at McDermitt, NV, and Terlingua, TX, which are moderate size on an international scale and produced about 10,000 and 5,000 t of elemental Hg, respectively. In waste samples, we measured total Hg and methyl-Hg contents, identified various Hg compounds using Hg-thermo-desorption pyrolysis, and determined rates of Hg methylation and methyl-Hg demethylation using isotopic-tracer methods. Pyrolysis analysis of mine wastes showed variable amounts of cinnabar, metacinnabar, Hg salts, elemental Hg, and elemental Hg sorbed onto particulates such as clay and Fe-oxides. Mine wastes with the highest methyl-Hg contents correspond to those with elemental Hg and particulate-sorbed elemental Hg, and also produced the highest laboratory-estimated potential Hg methylation rates, as much as 4.8%/day. Samples containing dominantly cinnabar showed little or no Hg methylation. Mine wastes with high methyl-Hg contents generally showed low methyl-Hg demethylation, suggesting that Hg methylation was dominant. Both mines are located in semiarid climates, and during this study, streambeds below the mines were dry. Total Hg contents in stream sediment collected below the mines show significant dilution, and methyl-Hg contents were typically below the limit of determination. Methylation of Hg downstream from Hg mines is probably lower in arid climates due to lack of mine-water runoff and lower microbial activity. The correspondence of mine wastes containing elemental Hg and high methyl-Hg contents suggests that Hg0 oxidizes to Hg2+, which is subsequently bioavailable for microbial Hg methylation.

Gray, John E. (U.S. Geological Survey); Hines, Mark E. (Massachusetts, Univ Of); Biester, Harald (Heidelberg College); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2003-05-01T23:59:59.000Z

411

The Economics of Oxygen Enriched Air Production Via Membranes  

E-Print Network [OSTI]

Oxygen enriched air combustion is a recognized approach to energy conservation. Conventional methods of producing oxygen enriched air: Pressure Swing Adsorption and Cryogenics, are energy-intensive and expensive. In this paper the economics of using...

Gollan, A.; Kleper, M. H.

1984-01-01T23:59:59.000Z

412

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

413

OXYGEN TRANSFER IN TRICKLING FILTERS By BruceE. Logan~  

E-Print Network [OSTI]

OXYGEN TRANSFER IN TRICKLING FILTERS By BruceE. Logan~ ABSTRACT: Insufficientoxygen transfer can result in anaerobic biofilmsand odor generation during biochemicaloxygen demand (BOD) removal plastic media trickling filters occurs by diffusion of oxygen through thin fluid films, previous models

414

Design, measurement, and analysis of oxygenated fluid pump system  

E-Print Network [OSTI]

The author sought out the opportunity to design and implement a system for pumping oxygenated fluid and mixing it with saline, for the purpose of providing sufficient levels of oxygen for patients undergoing forms of ...

Mason, Alexander M., IV (Alexander Martin)

2012-01-01T23:59:59.000Z

415

Label-free oxygen-metabolic photoacoustic microscopy in vivo  

E-Print Network [OSTI]

tomography (PET) using radioactively labeled oxy- gen. Many other pathological and physiological functions of oxygen consumption instead of the static oxygen concentration.11 If the region of interest has well

Wang, Lihong

416

Optimization of Oxygen Purity for Coal Conversion Energy Reduction  

E-Print Network [OSTI]

The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

Baker, C. R.; Pike, R. A.

1982-01-01T23:59:59.000Z

417

Optical Perfusion and Oxygenation Characterization in a Liver Phantom  

E-Print Network [OSTI]

Continuous monitoring of blood perfusion and oxygenation is essential in assessing the health of a transplanted organ. Particularly, monitoring the perfusion and oxygenation of the organ during the two-week period after the transplant procedure...

King, Travis J.

2012-02-14T23:59:59.000Z

418

Methane Adsorption and Dissociation and Oxygen Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

419

Inhibitive Influence of Oxygen Vacancies for Photoactivity on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Abstract: Scanning tunneling...

420

Oxygen-induced magnetic properties and metallic behavior of a...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Abstract: In this paper, ab initio...

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

422

On the reduction of oxygen from dispersed media  

E-Print Network [OSTI]

The reduction of oxygen from an organic phase dispersed in a concentrated electrolyte is investigated. Dispersed organic phases are used to enhance oxygen transport in fermenters and artificial blood substitutes. This work ...

Roushdy, Omar H., 1977-

2007-01-01T23:59:59.000Z

423

Proton NMR analysis of octane number for motor gasoline: Part V  

SciTech Connect (OSTI)

A method to predict the octane number of automobile gasoline containing methyl tert-butyl ether (MTBE) by proton magnetic resonance (PMR) spectrometry was studied. Samples of gasoline whose octane numbers had been identified according to the ASTM standards (commercially available premium gasoline to which MTBE was added at rates of 7 vol % and 14 vol %) were used in this investigation of the effect of MTBE on the octane number. The findings were utilized to introduce a term regarding MTBE into the previously reported linear regression equation for estimating the octane number from the PMR spectrum, and the appropriateness of the linear regression equation was assessed. As a result the MTBE contents in the sample were determined with satisfactory accuracy by using a standard addition method, and a linear regression equation reflecting the effect of MTBE was obtained. These achievements are reported. 11 refs., 3 figs., 5 tabs.

Ichikawa, M.; Nonaka, N.; Amano, H.; Takada, I.; Ishimori, S. [Suzuki Motor Corp., Hamamatsu (Japan); Andoh, H.; Kumamoto, K. [Showa Shell Sikiyu Tokyo (Japan)

1992-10-01T23:59:59.000Z

424

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-10-01T23:59:59.000Z

425

Electrical insulator assembly with oxygen permeation barrier  

DOE Patents [OSTI]

A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

Van Der Beck, R.R.; Bond, J.A.

1994-03-29T23:59:59.000Z

426

A miniature inexpensive, oxygen sensing element  

SciTech Connect (OSTI)

An exhaustive study was conducted to determine the feasibility of Nernst-type oxygen sensors based on ceramics containing Bi{sub 2}O{sub 3}. The basic sensor design consisted of a ceramic sensing module sealed into a metal tube. The module accommodated an internal heater and thermocouple. Thermal-expansion-matched metals, adhesives, and seals were researched and developed, consistent with sequential firings during sensor assembly. Significant effort was devoted to heater design/testing and to materials' compatibility with Pt electrodes. A systematic approach was taken to develop all sensor components which led to several design modifications. Prototype sensors were constructed and exhaustively tested. It is concluded that development of Nerst-type oxygen sensors based on Bi{sub 2}O{sub 3} will require much further effort and application of specialized technologies. However, during the course of this 3-year program much progress was reported in the literature on amperometric-type oxygen sensors, and a minor effort was devoted here to this type of sensor based on Bi{sub 2}O{sub 3}. These studies were made on Bi{sub 2}O{sub 3}-based ceramic samples in a multilayer-capacitor-type geometry and amperometric-type oxygen sensing was demonstrated at very low temperatures ({approximately} 160{degree}C). A central advantage here is that these types of sensors can be mass-produced very inexpensively ({approximately} 20--50 cents per unit). Research is needed, however, to develop an optimum diffusion-limiting barrier coating. In summary, the original goals of this program were not achieved due to unforeseen problems with Bi{sub 2}O{sub 3}-based Nernst sensors. However, a miniature amperometric sensor base on Bi{sub 2}O{sub 3} was demonstrated in this program, and it is now seen that this latter sensor is far superior to the originally proposed Nernst sensor. 6 refs., 24 figs.

Arenz, R.W.

1991-10-07T23:59:59.000Z

427

Oxygen stabilized zirconium vanadium intermetallic compound  

DOE Patents [OSTI]

An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

1982-01-01T23:59:59.000Z

428

Motor Gasoline Outlook and State MTBE Bans  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil31 E n e

429

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

430

Quasi-Reversible Oxygen Exchange of Amorphous IGZO Thin Films  

E-Print Network [OSTI]

MRSEC Quasi-Reversible Oxygen Exchange of Amorphous IGZO Thin Films NSF Grant # 1121262 A. U. Adler of varying oxygen partial pressure. Oxygen exchange was confirmed by 18O tracer diffusion (time of carrier content vs. pO2) analysis should be applicable for studying the underlying carrier generation

Shahriar, Selim

431

Oxygen Reduction DOI: 10.1002/anie.201403264  

E-Print Network [OSTI]

Oxygen Reduction DOI: 10.1002/anie.201403264 Dramatic Increase in the Oxygen Reduction Reaction solvation) is used to predict how the energies and barriers for the mechanistic steps of the oxygen. In these electro- chemical devices, H2 (generated e.g. from solar energy conversion) reacts with O2 to produce

Goddard III, William A.

432

IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS  

E-Print Network [OSTI]

1 IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS Jacek Makinia*, Scott A in a full-scale activated sludge reactor. The Activated Sludge Model No. 1 was used to describe for dissolved oxygen. KEYWORDS Activated sludge; dispersion; dissolved oxygen dynamics; mass transfer

Wells, Scott A.

433

Oceanic oxygen changes as a bellwether of climate change  

E-Print Network [OSTI]

Oceanic oxygen changes as a bellwether of climate change Term paper in Biogeochemistry@ethz.ch] Tutor: Prof. Dr. Nicholas Gruber [nicholas.gruber@env.ethz.ch] Abstract The response of oceanic oxygen of climate change. Recent publications indicate that the oceanic oxygen outgassing is substaintially larger

Fischlin, Andreas

434

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence  

E-Print Network [OSTI]

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear molybdenum chloride clusters. Measurements of the probe operating in a 0%­21% gaseous oxygen environment have

Ghosh, Ruby N.

435

THE OXYGEN REQUIREMENTS OF SHELLFISH By Philip H. Mitchell  

E-Print Network [OSTI]

THE OXYGEN REQUIREMENTS OF SHELLFISH ~ By Philip H. Mitchell 2°7 #12;Blank page retained for pagination #12;THE OXYGEN REQUIREMENTS OF SHELLFISH. By PHILIP H. MITCHELL. J1, The respiratory exchanges to temperature changes, a smaller utili- zation of oxygen in proportion to the body weight with increase in size

436

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

437

Green fluorescent protein based indicators of dynamic redox changes and reactive oxygen species  

E-Print Network [OSTI]

attached a singlet oxygen generator to the C-terminal ofencoded singlet oxygen generators, which is currentlyassays. A. Singlet oxygen generator and sensor are tethered;

Dooley, Colette

2006-01-01T23:59:59.000Z

438

E-Print Network 3.0 - acute oxygen sensing Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dissolved oxygen with global warming. In coastal regimes oxygen deficits represent acute ecosystem... Ocean oxygen minima expansions and their biological impacts Lothar Stramma...

439

Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals  

E-Print Network [OSTI]

Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

2006-01-01T23:59:59.000Z

440

OXYGEN REDUCTION WITH CARBON SUPPORTED METALLIC CLUSTER CATALYSTS IN ALKALINE ELECTROLYTE  

E-Print Network [OSTI]

be published in the Proceedings OXYGEN REDUCTION WITH CARBONof California. LBL-11891 Oxygen Reduction with Carbonof Pt interacts with both oxygen and water more strongly

Ross Jr., Philip N.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.  

E-Print Network [OSTI]

Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

Chakraborty, Subrata

2013-01-01T23:59:59.000Z

442

E-Print Network 3.0 - active oxygen control Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: active oxygen control Page: << < 1 2 3 4 5 > >> 1 Oxygen Modulation via Microfluidic Devices Oxygen...

443

E-Print Network 3.0 - acibenzolar-s-methyl para controle Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a coffee-leaf extract formulation in tomato Summary: ), acibenzolar-S-methyl (Bion) or water (control) and three days subsequently infected with the tomato pathogen... in the...

444

Durability of Poly (Methyl Methacrylate) Lenses Used in Concentrating Photovoltaics (Presentation)  

SciTech Connect (OSTI)

This presentation reports the findings of NREL's screen test to characterize the durability of poly (methyl methacrylate) lenses used in concentrated photovoltaics.

Miller, D.; Gedvilas, L.; To, B.; Kennedy, C.; Kurtz, S.

2010-10-21T23:59:59.000Z

445

E-Print Network 3.0 - anhydroecgonine methyl ester Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Idaho Collection: Environmental Sciences and Ecology 9 A Novel Post-translational Modification of Yeast Elongation Factor 1A Summary: that is released as volatile methyl groups...

446

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

447

Magnetic interaction in oxygenated alpha Fe-phthalocyanines  

SciTech Connect (OSTI)

Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mssbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mssbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mssbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltn; Horvth, Attila [Institute of Chemistry, Etvs Lornd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsr, Zoltn [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

2014-10-27T23:59:59.000Z

448

Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters the water by diffusion from air, as a by-product of photosynthesis and  

E-Print Network [OSTI]

Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters and rapids. There is an inverse relationship between temperature and DO, i.e. colder water holds more oxygen it supplies oxygen to aquatic organisms. Higher DO levels also give the water a better taste. Figure 2. During

Tyler, Christy

449

FORMATION OF MOLECULAR OXYGEN AND OZONE ON AMORPHOUS SILICATES  

SciTech Connect (OSTI)

Oxygen in the interstellar medium is seen in the gas phase, in ices (incorporated in H{sub 2}O, CO, and CO{sub 2}), and in grains such as (Mg{sub x} Fe{sub 1-x} )SiO{sub 3} or (Mg{sub x} Fe{sub 1-x} ){sub 2}SiO{sub 4}, 0 < x < 1. In this investigation, we study the diffusion of oxygen atoms and the formation of oxygen molecules and ozone on the surface of an amorphous silicate film. We find that ozone is formed at low temperature (<30 K), and molecular oxygen forms when the diffusion of oxygen atoms becomes significant, at around 60 K. This experiment, besides being the first determination of the diffusion energy barrier (1785 {+-} 35 K) for oxygen atoms on a silicate surface, suggests bare silicates as a possible storage place for oxygen atoms in low-A{sub v} environments.

Jing Dapeng; He Jiao; Vidali, Gianfranco [Physics Department, Syracuse University, Syracuse, NY 13244 (United States); Brucato, John Robert; Tozzetti, Lorenzo [Osservatorio Astrofisico di Arcetri, INAF, I-50125 Florence (Italy); De Sio, Antonio [Department of Physics and Astronomy, University of Florence, I-50125 Florence (Italy)

2012-09-01T23:59:59.000Z

450

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network [OSTI]

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

451

The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries  

SciTech Connect (OSTI)

The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

2014-09-30T23:59:59.000Z

452

How Plants Do It: Light, Oxygen, Action!  

SciTech Connect (OSTI)

Plants have been doing it with ease for millions of years, and yet science has yet to fully comprehend how: Photosynthesis. It's a fundamental process of all plant life on Earth, using the simple and abundant ingredients of water and light to create food and enrich the planet's atmosphere with life-giving oxygen. In this talk, Professor Yachandra discusses how understanding the process of photosynthesis holds the key to a whole new level of mastery of how energy is produced, with enormous implications for the economy and the environment.

Yachandra, Vittal (University of California, Berkeley) [University of California, Berkeley

2008-08-26T23:59:59.000Z

453

SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION  

SciTech Connect (OSTI)

Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

Timothy L. Ward

2000-06-30T23:59:59.000Z

454

Oxygen stabilized zirconium-vanadium-iron alloy  

DOE Patents [OSTI]

An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

1982-01-01T23:59:59.000Z

455

Jupiter Oxygen Corporation | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429 Throttled (botOpen6 Climate ZoneJeromeCounty isJupiter Oxygen Corporation

456

Characterization of the Deltaproteobacteria in contaminated and uncontaminated stream sediments and identification of potential mercury methylators  

SciTech Connect (OSTI)

Microbial communities were examined in surface stream sediments at 5 contaminated sites and 1 control site near Oak Ridge, TN, USA, to identify bacteria that could be contributing to mercury (Hg) methylation. The phylogenetic composition of the sediment bacterial community was examined over 3 quarterly sampling periods (36 samples) using 16S rRNA gene pyrosequencing. Only 3064 sequences (0.85% of the total community) were identified as Deltaproteobacteria, the only group known to methylate Hg, using the Ribosomal Database Project classifier at the 99% confidence threshold. Constrained ordination techniques indicated statistically significant positive linear correlations between Desulfobulbus spp., Desulfonema spp. and Desulfobacca spp. and methyl-Hg concentrations at the Hg-contaminated sites. In contrast, the distribution of organisms related to Byssovorax spp. was significantly correlated to inorganic carbon, nitrate and uranium concentrations but not to Hg or methyl-Hg. Overall, the abundance and richness of Deltaproteobacteria sequences were higher in uncontaminated sediments, while the majority of the members present at the contaminated sites were either known potential metal-reducers/methylators or metal tolerant species. Given the abundance relative to other known Hg methylators and the association with methyl-Hg, Desulfobulbus spp. is considered a prime candidate for involvement in Hg methylation in these streams.

Mosher, Jennifer [ORNL; Vishnivetskaya, Tatiana A [ORNL; Elias, Dwayne A [ORNL; Podar, Mircea [ORNL; Brooks, Scott C [ORNL; Brown, Steven D [ORNL; Brandt, Craig C [ORNL; Palumbo, Anthony Vito [ORNL

2012-01-01T23:59:59.000Z

457

Arsenic Methylation and Bladder Cancer Risk in CaseControl Studies in Argentina and the  

E-Print Network [OSTI]

Arsenic Methylation and Bladder Cancer Risk in Case­Control Studies in Argentina and the United's susceptibility to bladder cancer. Methods: Urinary methylation products were measured in subjects from Argentina (114 cases and 114 controls) and the United States (23 cases and 49 controls). Results: In Argentina

California at Berkeley, University of

458

et al. (2008) identified several additional methylation sites on FOXO1 that ap-  

E-Print Network [OSTI]

, it remains to be deter- mined how methylation alters the activity and posttranslational regulation. In this light, methylation could, therefore, play a very general role in the regulation of FOXO1 activity serve as a link between aging and age-related diseases such as diabe- tes and cancer. FOXO dysregulation

Hertel, Klemens J.

459

Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants  

SciTech Connect (OSTI)

Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

Manohar S. Sohal; J. Stephen Herring

2008-07-01T23:59:59.000Z

460

Oxygen Abundance Measurements of SHIELD Galaxies  

E-Print Network [OSTI]

We have derived oxygen abundances for 8 galaxies from the Survey of HI in Extremely Low-mass Dwarfs (SHIELD). The SHIELD survey is an ongoing study of very low-mass galaxies, with M$_{\\rm HI}$ between 10$^{6.5}$ and 10$^{7.5}$ M$_{\\odot}$, that were detected by the Arecibo Legacy Fast ALFA (ALFALFA) survey. H$\\alpha$ images from the WIYN 3.5m telescope show that these 8 SHIELD galaxies each possess one or two active star-forming regions which were targeted with long-slit spectral observations using the Mayall 4m telescope at KPNO. We obtained a direct measurement of the electron temperature by detection of the weak [O III] $\\lambda$4363 line in 2 of the HII regions. Oxygen abundances for the other HII regions were estimated using a strong-line method. When the SHIELD galaxies are plotted on a B-band luminosity-metallicity diagram they appear to suggest a slightly shallower slope to the relationship than normally seen. However, that offset is systematically reduced when the near-infrared luminosity is used ins...

Haurberg, Nathalie C; Cannon, John M; Marshall, Melissa V

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

OXYGEN DEPLETION IN THE INTERSTELLAR MEDIUM: IMPLICATIONS FOR GRAIN MODELS AND THE DISTRIBUTION OF ELEMENTAL OXYGEN  

SciTech Connect (OSTI)

This paper assesses the implications of a recent discovery that atomic oxygen is being depleted from diffuse interstellar gas at a rate that cannot be accounted for by its presence in silicate and metallic oxide particles. To place this discovery in context, the uptake of elemental O into dust is considered over a wide range of environments, from the tenuous intercloud gas and diffuse clouds sampled by the depletion observations to dense clouds where ice mantles and gaseous CO become important reservoirs of O. The distribution of O in these contrasting regions is quantified in terms of a common parameter, the mean number density of hydrogen (n{sub H}). At the interface between diffuse and dense phases (just before the onset of ice-mantle growth) as much as {approx}160 ppm of the O abundance is unaccounted for. If this reservoir of depleted oxygen persists to higher densities it has implications for the oxygen budget in molecular clouds, where a shortfall of the same order is observed. Of various potential carriers, the most plausible appears to be a form of O-bearing carbonaceous matter similar to the organics found in cometary particles returned by the Stardust mission. The 'organic refractory' model for interstellar dust is re-examined in the light of these findings, and it is concluded that further observations and laboratory work are needed to determine whether this class of material is present in quantities sufficient to account for a significant fraction of the unidentified depleted oxygen.

Whittet, D. C. B. [New York Center for Astrobiology, and Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, NY 12180 (United States)

2010-02-20T23:59:59.000Z

462

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

463

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

464

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

465

Electrochemical oxygen pumps. Final CRADA report.  

SciTech Connect (OSTI)

All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

Carter, J. D.

2009-10-01T23:59:59.000Z

466

Methyl-CpG island-associated genome signature tags  

DOE Patents [OSTI]

Disclosed is a method for analyzing the organismic complexity of a sample through analysis of the nucleic acid in the sample. In the disclosed method, through a series of steps, including digestion with a type II restriction enzyme, ligation of capture adapters and linkers and digestion with a type IIS restriction enzyme, genome signature tags are produced. The sequences of a statistically significant number of the signature tags are determined and the sequences are used to identify and quantify the organisms in the sample. Various embodiments of the invention described herein include methods for using single point genome signature tags to analyze the related families present in a sample, methods for analyzing sequences associated with hyper- and hypo-methylated CpG islands, methods for visualizing organismic complexity change in a sampling location over time and methods for generating the genome signature tag profile of a sample of fragmented DNA.

Dunn, John J

2014-05-20T23:59:59.000Z

467

THE JOURNAL OF CHEMICAL PHYSICS 138, 054301 (2013) Photodissociation dynamics of the methyl perthiyl radical at 248 nm  

E-Print Network [OSTI]

the photodissociation of the methyl perthiyl radical CH3SS at 248 nm. The radical was produced by flash pyrolysis

Neumark, Daniel M.

468

Optical measurements of methyl group tunneling in molecular crystals: Temperature dependence of the nuclear spin conversion rate  

E-Print Network [OSTI]

) The tunneling methyl groups in dimethyl-s-tetrazine (DMST) doped single crystals of durene were investigated

469

An Exocyclic Methylene Group Acts As a Bioisostere of the 2?-Oxygen Atom in LNA  

SciTech Connect (OSTI)

We show for the first time that it is possible to obtain LNA-like (Locked Nucleic Acid 1) binding affinity and biological activity with carbocyclic LNA (cLNA) analogs by replacing the 2{prime}-oxygen atom in LNA with an exocyclic methylene group. Synthesis of the methylene-cLNA nucleoside was accomplished by an intramolecular cyclization reaction between a radical at the 2{prime}-position and a propynyl group at the C-4{prime} position. Only methylene-cLNA modified oligonucleotides showed similar thermal stability and mismatch discrimination properties for complementary nucleic acids as LNA. In contrast, the close structurally related methyl-cLNA analogs showed diminished hybridization properties. Analysis of crystal structures of cLNA modified self-complementary DNA decamer duplexes revealed that the methylene group participates in a tight interaction with a 2{prime}-deoxyribose residue of the 5{prime}-terminal G of a neighboring duplex, resulting in the formation of a CH...O type hydrogen bond. This indicates that the methylene group retains a negative polarization at the edge of the minor groove in the absence of a hydrophilic 2{prime}-substituent and provides a rationale for the superior thermal stability of this modification. In animal experiments, methylene-cLNA antisense oligonucleotides (ASOs) showed similar in vivo activity but reduced toxicity as compared to LNA ASOs. Our work highlights the interchangeable role of oxygen and unsaturated moieties in nucleic acid structure and emphasizes greater use of this bioisostere to improve the properties of nucleic acids for therapeutic and diagnostic applications.

Seth, Punit P.; Allerson, Charles R.; Berdeja, Andres; Siwkowski, Andrew; Pallan, Pradeep S.; Gaus, Hans; Prakash, Thazha P.; Watt, Andrew T.; Egli, Martin; Swayze, Eric E. (Isis Pharm.); (Vanderbilt)

2010-12-07T23:59:59.000Z

470

Modelling Study of the Low-Temperature Oxidation of Large Methyl Esters J. Biet, V. Warth, O. Herbinet*  

E-Print Network [OSTI]

-decane / methyl palmitate mixture in a jet-stirred reactor. This paper also presents the construction and a comparison of models for methyl esters from C7 up to C17 in terms of conversion in a jet-stirred reactor, the development of renewable energy is more vital than ever [1,2]. The production of biofuels such as methyl

Paris-Sud XI, Université de

471

The effect of monomolecular films on oxygen transfer across an air-water interface  

E-Print Network [OSTI]

Rate 8. Effect of Aquasave Monolayer on Oxygen Uptake Rate 9. Effect of Isopropyl Alcohol on Oxygen Uptake Rate 10. Effect of Isopropyl Alcohol on Oxygen Uptake Rate 11. Effect of Isopropyl Alcohol on Oxygen Uptake Rate 12. Effect of Kerosene... on Oxygen Uptake Rate 13. Effect of Kerosene on Oxygen Uptake Rate 14. Effect of n-Pentanol on Oxygen Uptake Rate 15. Effect of n-Pentanol on Oxygen Uptake Rate 16. Effect of Hexane on Oxygen Uptake Rate 17. Effect of Hexane on Oxygen Uptake Rate 18...

Mahmoud, Tariq Ahmad

1967-01-01T23:59:59.000Z

472

Oxygen-Enriched Combustion for Military Diesel Engine Generators...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak...

473

Palladium-Cobalt Particles As Oxygen-Reduction Electrocatalysts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Palladium-Cobalt Particles As Oxygen-Reduction Electrocatalysts Brookhaven National Laboratory...

474

Catalytic reduction system for oxygen-rich exhaust  

DOE Patents [OSTI]

Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

1999-04-13T23:59:59.000Z

475

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the efficiency of solid oxide fuel cells can be improved. Citation: Edmondson PD, WJ Weber, F Namavar, and Y Zhang.2011."Lattice Distortions and Oxygen Vacancies Produced in...

476

active oxygen probe: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CERN Preprints Summary: I present here the results of the first principles studies of the adsorption energetics of the intermediates of the oxygen electro-reduction reaction (ORR)...

477

Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence  

E-Print Network [OSTI]

in oxygen atmospheres 0%­21% were obtained with a signal to noise ratio better than 150. Photobleaching physical principles, electrochemistry or luminescence. Electrochemical devices result in analyte

Ghosh, Ruby N.

478

Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

- - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

479

Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...  

Gasoline and Diesel Fuel Update (EIA)

Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

480

Microbial metatranscriptomics in a permanent marine oxygen minimum zone  

E-Print Network [OSTI]

Simultaneous characterization of taxonomic composition, metabolic gene content and gene expression in marine oxygen minimum zones (OMZs) has potential to broaden perspectives on the microbial and biogeochemical dynamics ...

Stewart, Frank J.

Note: This page contains sample records for the topic "oxygenates mtbe methyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

482

Modeling Oxygen Transport in Three-Dimensional Capillary Networks.  

E-Print Network [OSTI]

??The purpose of this thesis was to examine how the use of real 3-dimensional (3D) capillary network geometries affect models of oxygen transport to tissue. (more)

Fraser, Graham M

2012-01-01T23:59:59.000Z

483

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Precursor Transport Through the Hydrogen Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the Hydrogen...

484

Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Abstract: In a recent work, we have shown that chemically synthesized...