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Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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1

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

1996-04-02T23:59:59.000Z

2

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

1996-01-01T23:59:59.000Z

3

High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993  

SciTech Connect (OSTI)

The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

1993-07-01T23:59:59.000Z

4

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

5

High octane ethers from synthesis gas-derived alcohols. Final technical report, September 25, 1990--December 24, 1993  

SciTech Connect (OSTI)

The objective of the research was to develop the methodology for the catalytic synthesis of ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from alcohol mixtures that are rich in methanol and 2-methyl-1-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been previously demonstrated by us to occur over superacid catalysts to yield MIBE and smaller amounts of MTBE at moderate pressures and a mixture of methanol and isobutene at low pressures. A wide range of organic resin catalysts and inorganic oxide and zeolite catalysts have been investigated for activity and selectivity in directly coupling alcohols, principally methanol and isobutanol, to form ethers and in the dehydration of isobutanol to isobutene in the presence of methanol. All of these catalysts are strong acids, and it was found that the organic and inorganic catalysts operate in different, but overlapping, temperature ranges, i.e. mainly 60--120{degrees}C for the organic resins and 90--175{degrees}C for the inorganic catalysts. For both types of catalysts, the presence of strong acid centers is required for catalytic activity, as was demonstrated by lack of activity of fully K{sup +} ion exchanged Nafion resin and zirconia prior to being sulfated by treatment with sulfuric acid.

Klier, K.; Herman, R.G.

1994-05-01T23:59:59.000Z

6

Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers  

Science Journals Connector (OSTI)

Vapour pressures of methyl propyl, isopropyl methyl, butyl methyl, ethyl propyl, t-butyl methyl, dipropyl, di-isopropyl, di-t-butyl, and decyl methyl ethers were measured at pressures up to 205 kPa. The measured values were fitted by Antoine and by Chebyshev equations, values already published from this laboratory for three aromatic ethers were recomputed uniformly with the present results, and published values for four additional compounds were incorporated in a scheme for correlation of the vapour pressures of ethers. Estimates were made of the vapour pressures of 10 other ethers. Between 5 and 200 kPa the vapour pressures of ethers may be represented by a single equation in which carbon number or an effective carbon number is a parameter. Chebyshev equations are given for interpolation between the upper bounds of the measurements and the critical pressures of 11 ethers for which this property has been previously determined.

D Ambrose; J.H Ellender; C.H.S Sprake; R Townsend

1976-01-01T23:59:59.000Z

7

Distribution of glycerol ether lipids in the oxygen minimum zone of the Eastern Tropical North Pacific Ocean  

Science Journals Connector (OSTI)

Abstract The distributions of microbial glycerol ether lipids in suspended particulate matter in the oxygen minimum zone (OMZ) of the Eastern Tropical North Pacific Ocean (ETNP) were investigated. Nine groups of glycerol ether core lipids were detected and quantified: isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) (iso-GDGTs), isoprenoid glycerol dialkanol diethers (iso-GDDs) and hydroxylated isoprenoid \\{GDGTs\\} and \\{GDDs\\} (OH-GDGTs and OH-GDDs) of archaeal origin; branched glycerol dialkyl glycerol tetraethers (br-GDGTs) of bacterial origin and overly branched \\{GDGTs\\} (OB-GDGTs), sparsely branched \\{GDGTs\\} (SB-GDGTs), hybrid isoprenoid/branched \\{GDGTs\\} (IB-GDGTs) and a tentatively assigned H-shaped GDGT (H-1020) of unknown biological origin. The archaeal iso-GDGTs were the most abundant core lipids (89% of total), followed by iso-GDDs (4%), br-GDGTs (2%) and OH-GDGTs (1%). Archaeal intact polar \\{GDGTs\\} (IP GDGTs), including both mono- and diglycosidic iso-GDGTs, had depth profiles similar to OH-GDGTs and OH-GDDs, with a maximum concentration in the upper OMZ and secondary peaks in the mid and lower OMZ, suggesting similar but multiple planktonic sources. Core lipids of iso-GDGTs and other glycerol ethers showed deviating concentration profiles compared with IP \\{GDGTs\\} and OH-GDGTs and were most abundant in the mid OMZ. This is the first report of OH-GDDs, OB-GDGTs, SB-GDGTs, IB-GDGTs and H-1020 in the marine water column and the distribution patterns of these “orphan lipids” suggest that anaerobic planktonic microbes are their main source.

Sitan Xie; Xiao-Lei Liu; Florence Schubotz; Stuart G. Wakeham; Kai-Uwe Hinrichs

2014-01-01T23:59:59.000Z

8

Propenyl ether monomers for photopolymerization  

DOE Patents [OSTI]

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-10-22T23:59:59.000Z

9

(2/94)(2-4,9/95)(7/97)(11,12/98)(1,9,11/99) Neuman Chapter 3 Haloalkanes, Alcohols, Ethers, and Amines  

E-Print Network [OSTI]

, Ethers, and Amines from Organic Chemistry by Robert C. Neuman, Jr. Professor of Chemistry, emeritus://web.chem.ucsb.edu/~neuman/orgchembyneuman/> Chapter Outline of the Book ************************************************************************************** I. Foundations 1. Organic Molecules and Chemical Bonding 2. Alkanes and Cycloalkanes 3. Haloalkanes

Reed, Christopher A.

10

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

11

Process for making propenyl ethers and photopolymerizable compositions containing them  

DOE Patents [OSTI]

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-01-23T23:59:59.000Z

12

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

13

Oxygen and Hydroxyl Species Induce Multiple Reaction Pathways for the Partial Oxidation of Allyl Alcohol on Gold  

E-Print Network [OSTI]

, acrolein, over oxygen-precovered gold surfaces occurs via multiple reaction pathways. Utilizing temperature -dehydrogenation via interaction with an oxygen adatom or surface hydroxyl species to generate acrolein. Mediation

Henkelman, Graeme

14

Quantification of Fuel Oxygenate Ethers in Human Blood using Solid-Phase Microextraction Coupled with Gas Chromatography-High-Resolution Mass Spectrometry  

Science Journals Connector (OSTI)

......Because ofwater solubility, fuel oxygenate...toluene. When water supplies are contaminated...followed by gas chromatography-high-resolution...helium-sparged distilled water (26) to produce...blanks,and water standardsfor daily...column carrier gas for all analyses...using liquid nitrogen from Air Liq......

Lalith K. Silva; Clayton R. Wilburn; Michael A. Bonin; Mitchell M. Smith; Katherine A. Reese; David L. Ashley; Benjamin C. Blount

2008-05-01T23:59:59.000Z

15

Ozone-forming potential of a series of oxygenated organic compounds  

SciTech Connect (OSTI)

An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

16

Simultaneous liquid–liquid and vapour–liquid equilibria predictions of selected oxygenated aromatic molecules in mixtures with alkanes, alcohols, water, using the polar GC-PC-SAFT  

Science Journals Connector (OSTI)

Abstract Phase equilibria of oxygen-bearing aromatic compounds, hydrocarbons and water mixtures are of essential interest in many processes using feeds originating from biomass. The strong non-ideal thermodynamic behavior of these systems sometimes results in immiscibility with both water and alkanes. To address this problem, the GC-PPC-SAFT equation of state [Tamouza et al., 2004; Nguyen-Huynh et al., 2008a] is extended to some selected components: phenol, alkyl-phenols, alkyl-benzoates, benzaldehyde and anisole. However, as in these multifunctional compounds, the proximity of polar functional groups may result in a lack of transferability of the parameters from the monofunctional homologous species, some parameters have been adapted in view of physical arguments. Next, liquid–vapour and liquid–liquid equilibria of mixtures with n-alkanes were evaluated, using a predictive method for the binary interaction parameters (kij) [Nguyen-Huynh et al., 2008b]. Finally, mixtures with other associating compounds, as alcohols and water have also been considered. In all cases, both correlations and predictions are qualitatively and quantitatively satisfactory. The relative deviations obtained on bubble pressure of vapor–liquid equilibria are 4–8%, that is comparable to those obtained on previously investigated systems.

Nguyen-Huynh Dong; de Hemptinne Jean-Charles; Lugo Rafael; Passarello Jean-Philippe; Tobaly Pascal

2014-01-01T23:59:59.000Z

17

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect (OSTI)

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

18

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network [OSTI]

Sato, and N. Kato. 2003. Propane monooxygenase and NAD + -alcohol dehydrogenase in propane metabolism by Gordonia sp.tert-butyl ether by propane-grown Mycobacterium vaccae JOB5.

2007-01-01T23:59:59.000Z

19

Crown Ethers in Nonaqueous Electrolytes for Lithium/Air Batteries  

SciTech Connect (OSTI)

The effects of three crown ethers, 12-crown-4, 15-crown-5, and 18-crown-6, as additives and co-solvents in non-aqueous electrolytes on the cell performance of primary Li/air batteries operated in a dry air environment were investigated. Crown ethers have large effects on the discharge performance of non-aqueous electrolytes in Li/air batteries. A small amount (normally less than 10% by weight or volume in electrolytes) of 12-Crown-4 and 15-crown-5 reduces the battery performance and a minimum discharge capacity appears at the crown ether content of ca. 5% in the electrolytes. However, when the content increases to about 15%, both crown ethers improve the capacity of Li/air cells by about 28% and 16%, respectively. 15-Crown-5 based electrolytes even show a maximum discharge capacity in the crown ether content range from 10% to 15%. On the other hand, the increase of 18-crown-6 amount in the electrolytes continuously lowers of the cell performance. The different battery performances of these three crown ethers in electrolytes are explained by the combined effects from the electrolytes’ contact angle, oxygen solubility, viscosity, ionic conductivity, and the stability of complexes formed between crown ether molecules and lithium ions.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-02-04T23:59:59.000Z

20

Process for producing high purity isoolefins and dimers thereof by dissociation of ethers  

DOE Patents [OSTI]

Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150 to 250 F at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C[sub 3] to C[sub 6] and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom. 2 figs.

Smith, L.A. Jr.; Jones, E.M. Jr.; Hearn, D.

1984-05-08T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

CRC fuel rating program: road octane performance of oxygenates in 1982 model cars  

SciTech Connect (OSTI)

Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

Not Available

1985-07-01T23:59:59.000Z

22

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO2(111) Model Catalysts  

SciTech Connect (OSTI)

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

F Calaza; T Chen; D Mullins; S Overbury

2011-12-31T23:59:59.000Z

23

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO(2)(111) Model Catalysts  

SciTech Connect (OSTI)

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

Calaza, Florencia C [ORNL; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Overbury, Steven {Steve} H [ORNL

2011-01-01T23:59:59.000Z

24

Reaction Pathways and Energetics of Etheric C?O Bond Cleavage Catalyzed by Lanthanide Triflates  

SciTech Connect (OSTI)

Efficient and selective cleavage of etheric C?O bonds is crucial for converting biomass into platform chemicals and liquid transportation fuels. In this contribution, computational methods at the DFT B3LYP level of theory are employed to understand the efficacy of lanthanide triflate catalysts (Ln(OTf)3, Ln = La, Ce, Sm, Gd, Yb, and Lu) in cleaving etheric C?O bonds. In agreement with experiment, the calculations indicate that the reaction pathway for C?O cleavage occurs via a C?H ? O?H proton transfer in concert with weakening of the C?O bond of the coordinated ether substrate to ultimately yield a coordinated alkenol. The activation energy for this process falls as the lanthanide ionic radius decreases, reflecting enhanced metal ion electrophilicity. Details of the reaction mechanism for Yb(OTf)3-catalyzed ring opening are explored in depth, and for 1-methyl-d3-butyl phenyl ether, the computed primary kinetic isotope effect of 2.4 is in excellent agreement with experiment (2.7), confirming that etheric ring-opening pathway involves proton transfer from the methyl group alpha to the etheric oxygen atom, which is activated by the electrophilic lanthanide ion. Calculations of the catalytic pathway using eight different ether substrates indicate that the more rapid cleavage of acyclic versus cyclic ethers is largely due to entropic effects, with the former C?O bond scission processes increasing the degrees of freedom/particles as the transition state is approached.

Assary, Rajeev S.; Atesin, Abdurrahman C.; Li, Zhi; Curtiss, Larry A.; Marks, Tobin J.

2013-07-15T23:59:59.000Z

25

Alcohol Consumption  

Science Journals Connector (OSTI)

Different forms of alcohol have different functions: as part of cleaners, fuel, medicine, etc. Worldwide the substance is well known as a component of different alcoholic beverages. These beverages differ no...

Gundula Barsch

2008-01-01T23:59:59.000Z

26

The influence of propylene glycol ethers on base diesel properties and emissions from a diesel engine  

Science Journals Connector (OSTI)

Abstract The oxygenated additives propylene glycol methyl ether (PGME), propylene glycol ethyl ether (PGEE), dipropylene glycol methyl ether (DPGME) were studied to determine their influence on both the base diesel fuel properties and the exhaust emissions from a diesel engine (CO, NOx, unburnt hydrocarbons and smoke). For diesel blends with low oxygen content (?4.0 wt.%), the addition of these compounds to base diesel fuel decreases aromatic content, kinematic viscosity, cold filter plugging point and Conradson carbon residue. Also, each compound modifies the distillation curve at temperatures below the corresponding oxygenated compound boiling point, the distillate percentage being increased. The blend cetane number depends on the type of propylene glycol ether added, its molecular weight, and the oxygen content of the fuel. The addition of PGME decreased slightly diesel fuel cetane number, while PGEE and DPGME increased it. Base diesel fuel-propylene glycol ether blends with 1.0 and 2.5 wt.% oxygen contents were used in order to determine the performance of the diesel engine and its emissions at both full and medium loads and different engine speeds (1000, 2500 and 4000 rpm). In general, at full load and in comparison with base diesel fuel, the blends show a slight reduction of oxygen-free specific fuel consumption. CO emissions are reduced appreciably for 2.5 wt.% of oxygen blends, mainly for PGEE and DPGME. \\{NOx\\} emissions are reduced slightly, but not the smoke. Unburnt hydrocarbon emissions decrease at 1000 and 2500 rpm, but not at 4000 rpm. At medium load, the effect of the additives is much less significant, due to the fact that the ratio oxygen from additive/oxygen from air is much lower.

F. Gómez-Cuenca; M. Gómez-Marín; M.B. Folgueras-Díaz

2013-01-01T23:59:59.000Z

27

Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oxygen vacancy defects. For alcohols, it is well-established that their dissociation on bridge-bonded oxygen vacancies (BBOV’s) of a prototypical TiO2(110) surface proceeds...

28

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

29

Ab initio calculations of various protonation sites in perfluorodiethyl ether: Models for high temperature lubricant decomposition?  

SciTech Connect (OSTI)

Although perfluoropolyether (PFPE) lubricants have found successful application in spacecraft mechanisms and computer hard drives, there eventual breakdown is irksome, and the mechanism of decomposition is the subject of much scrutiny. However, very little notice is taken of the monomer ethers on which the polymer lubricants are based. Recently, concerted studies of the Lewis base properties of various fluorinated ethers have been performed, both from an experimental and a theoretical viewpoint. As an extension of the theoretical work, this study presents ab initio theoretical consideration of the multiple potential basic sites within perfluorodiethyl ether, (CF{sub 3}CF{sub 2}){sub 2}O, by way of the proton affinity of the molecule at various possible protonation sites (i.e., oxygen and fluorine atoms). The results indicate that although protonation at the oxygen is more energetically favored, protonation at the fluorine is not much higher in energy and provides for formation of an excellent leaving group, HF.

Ball, D.W. [Cleveland State Univ., OH (United States). Dept. of Chemistry

1995-04-01T23:59:59.000Z

30

Alcohol synthesis from CO or CO.sub.2  

DOE Patents [OSTI]

Methods for producing alcohols from CO or CO.sub.2 and H.sub.2 utilizing a palladium-zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C.sub.2+ oxygenates can produced utilizing Rh--Mn or a Fisher-Tropsch catalyst.

Hu, Jianli [Kennewick, WA; Dagle, Robert A [Richland, WA; Holladay, Jamelyn D [Kennewick, WA; Cao, Chunshe [Houston, TX; Wang, Yong [Richland, WA; White, James F [Richland, WA; Elliott, Douglas C [Richland, WA; Stevens, Don J [Richland, WA

2010-12-28T23:59:59.000Z

31

The interactions of water and perfluorodiethyl ether on Ru(100)  

SciTech Connect (OSTI)

We have studied the interactions of water and perfluorodiethyl ether on Ru(100) in order to model the effects of surface structure and humidity on the bonding and decomposition of perfluoroalkyl ether lubricants with metal surfaces. In order to understand the interactions on Ru(100), we have first investigated the interactions of each of these adsorbates alone on the clean surface. The interactions of water with Ru(100) have been studied using both thermal desorption spectroscopy (TDS) and electron energy loss spectroscopy (EELS). From these studies we conclude that a small amount of water dissociates on this surface (5--10% of a monolayer), but water is adsorbed in a predominantly molecular form on this surface with an increasing degree of hydrogen-bonding with increasing coverage. The effects of hydrogen and oxygen coadsorption on the interactions of water with this surface have also been studied using TDS. Finally, the interactions of coadsorbed water and perfluorodiethyl ether on Ru(100) have been investigated using TDS.

Leavitt, P.

1990-09-21T23:59:59.000Z

32

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

33

Atmospheric and combustion chemistry of dimethyl ether  

SciTech Connect (OSTI)

It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J. [Risoe National Lab., Roskilde (Denmark); Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States)

1997-12-31T23:59:59.000Z

34

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl ether)s  

E-Print Network [OSTI]

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl etherVed October 21, 2005 The synthesis and near-infrared electrochromic properties of pentacenediquinone-infrared electrochromic properties of pentacenediquinone-containing poly(aryl ether)s were studied

Wan, Xin-hua

35

Crown Ethers in Graphene Bring Strong, Selective Binding | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Characterization Crown Ethers in Graphene Bring Strong, Selective Binding November 14, 2014 Schematic showing a graphene sheet containing an array of ideal crown ethers....

36

Ethers have good gasoline-blending attributes  

SciTech Connect (OSTI)

Because of their compatibility with hydrocarbon gasoline-blending components, their high octane blending values, and their low volatility blending values, ethers will grow in use as gasoline blending components. This article discusses the properties of ethers as blending components, and environmental questions.

Unzelman, G.H.

1989-04-10T23:59:59.000Z

37

Purification of aqueous cellulose ethers  

SciTech Connect (OSTI)

Manufacture of cellulose ethers usually involves high amounts of salt by-products. For application of the product, salt must be removed. In this work, we have studied the injection of high-pressure CO{sub 2} into an aqueous polymer-salt solution; we find that upon addition of isopropanol in addition to CO{sub 2}, the solution separates into two phases. One phase is rich in polymer and water, and the other phase contains mostly isopropanol, water and CO{sub 2}. The salt distributes between the two phases, thereby offering interesting possibilities for development of a new purification process for water-soluble polymers. This work presents experimental phase-equilibrium data for hydroxyethyl cellulose and sodium carboxymethyl cellulose with sodium acetate and potassium sulfate, respectively, in the region 40{degree}C and 30 to 80 bar. Based on these data, we suggest a process for the manufacture and purification of water-soluble cellulose ethers. 15 refs., 14 figs., 9 tabs.

Bartscherer, K.A.; de Pablo, J.J.; Bonnin, M.C.; Prausnitz, J.M.

1990-07-01T23:59:59.000Z

38

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures  

SciTech Connect (OSTI)

Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

Waller, F.J.

1997-11-01T23:59:59.000Z

39

Kinetic measurements of the gas-phase reactions of OH radicals with hydroxy ethers, hydroxy ketones, and keto ethers  

SciTech Connect (OSTI)

Absolute rate constants were determined for the gas-phase reactions of hydroxyl radicals with a series of hydroxy ethers as well as the simplest hydroxy ketone and keto ether with use of the flash photolysis resonance fluorescence technique. At 298 K, the measured rate constants were as follows (in units of 10{sup {minus}12} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}): 2-methoxyethanol, 12.5 {plus minus} 0.7; 2-ethoxyethanol, 18.7 {plus minus} 2.0; 2-butoxyethanol, 23.1 {plus minus} 0.9; 3-ethoxy-1-propanol, 22.0 {plus minus} 1.3; 3-methoxy-l-butanol, 23.6 {plus minus} 1.6; acetol, 3.0 {plus minus} 0.3; and methoxyacetone, 6.8 {plus minus} 0.6. The kinetic data for 2-methoxyethanol obtained between 240 and 440 K were used to derive the following Arrhenius expression: k{sub 1} = (4.5 {plus minus} 1.4) {times} 10{sup {minus}12} exp((325 {plus minus} 100)/T) (cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}). The results for all seven reactants are discussed in terms of the prediction of OH rate constants for oxygenated organic compounds.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1989-11-16T23:59:59.000Z

40

The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol  

Science Journals Connector (OSTI)

...The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol G. R. Freeman The two modes of decomposition of ethanol at 525 degrees C, namely dehydration and dehydrogenation, are affected...

1958-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames  

SciTech Connect (OSTI)

The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

2000-12-15T23:59:59.000Z

42

The Effect of Chronic Ethanol Consumption on the Rate of Whole Animal and Perfused Liver Oxygen Consumption  

Science Journals Connector (OSTI)

In order to assess the thyroid state of rats chronically treated with an alcohol containing diet, the rate of minimal oxygen consumption, the level of serum thyroid hormones and the rate of perfused liver oxygen

Walter T. Schaffer; W. Donner Denckla…

1980-01-01T23:59:59.000Z

43

Atmospheric chemistry of automotive fuel additives: Diisopropyl ether  

SciTech Connect (OSTI)

To quantify the atmospheric reactivity of diisopropyl ether (DIPE), we have conducted a study of the kinetics and mechanism of reaction 1: OH + DIPE {r_arrow} products. Kinetic measurements of reaction 1 were made using both relative (at 295 K) and absolute techniques (over the temperature range 240-440 K). Rate data from both techniques can be represented by the following: k{sub 1} = (2.2{sub -0.8}{sup +14}) x 10{sup -12} exp[(445 {plus_minus} 145)/T] cm{sup 3} molecule{sup -1}s{sup -1}. At 298 K, k{sub 1} = 9.8 x 10{sup -12} cm{sup 3} molecule{sup -1}s{sup -1}. The products of the simulated atmospheric oxidation of DIPE were identified using FT-IR spectroscopy; isopropyl acetate and HCHO were the main products. The atmospheric oxidation of DIPE can be represented by i-C{sub 3}H{sub 7}O-i-C{sub 3}H{sub 7} + OH + 2NO {r_arrow} HCHO + i-C{sub 3}H{sub 7}OC(O)CH{sub 3} + HO{sub 2} + 2NO{sub 2}. Our kinetic and mechanistic data were incorporated into a 1-day simulation of atmospheric chemistry to quantify the relative incremental reactivity of DIPE. Results are compared with other oxygenated fuel additives. 30 refs., 9 figs.

Wallington, T.J.; Andino, J.M.; Potts, A.R. [Ford Motor Company, Dearborn, MI (United States)] [and others

1993-01-01T23:59:59.000Z

44

Crown Ethers Flatten in Graphene for Strong, Specific Binding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crown Ethers Flatten in Graphene for Strong, Specific Binding ORNL discovery holds potential for separations, sensors, batteries, biotech and more This sheet of graphene contains...

45

Furfuryl alcohol cellular product  

DOE Patents [OSTI]

Self-extinguishing rigid foam products are formed by polymerization of furfuryl alcohol in the presence of a lightweight, particulate, filler, zinc chloride and selected catalysts.

Sugama, T.; Kukacka, L.E.

1982-05-26T23:59:59.000Z

46

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents [OSTI]

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

47

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect (OSTI)

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

48

Alcohol | OpenEI  

Open Energy Info (EERE)

Alcohol Alcohol Dataset Summary Description The Energy Statistics Database contains comprehensive energy statistics on the production, trade, conversion and final consumption of primary and secondary; conventional and non-conventional; and new and renewable sources of energy. The Energy Statistics dataset, covering the period from 1990 on, is available at UNdata. This dataset relates to the consumption of alcohol by the transportation industry. Source United Nations (UN) Date Released December 09th, 2009 (5 years ago) Date Updated Unknown Keywords Agriculture Alcohol consumption transportation industry UN Data application/xml icon UN Data: consumption by transportation industry XML (xml, 95 KiB) text/csv icon UN Data: consumption by transportation industry XLS (csv, 21.6 KiB)

49

Reactions of Methyl Perfluoroalkyl Ethers with Isopropyl Alcohol: Experimental and Theoretical Studies  

Science Journals Connector (OSTI)

B&W Pantex, LLC, Amarillo, Texas 79120, United States ... Chemicals and Materials ... Physical Chemistry Chemical Physics (2007), 9 (29), 3864-3871 CODEN: PPCPFQ; ISSN:1463-9076. ...

Howard C. Knachel; Vladimir Benin; Chadwick D. Barklay; Janine C. Birkbeck; Billy D. Faubion; William E. Moddeman

2012-07-16T23:59:59.000Z

50

Peak-Shift Technique in Gas-Liquid Chromatography : Trimethylsilyl Ether Derivatives of Alcohols  

Science Journals Connector (OSTI)

... in Mass Spectrometry. Proc. Joint Conf. by Inst. Petroleum Hydrocarbon Res. Group and ASTM Comm. E-14, edit. by Waldron, J. (Pergamon Press, London 1959) ...

STANLEY H. LANGER; PETER PANTAGES

1961-07-08T23:59:59.000Z

51

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

52

Properties Investigation of Sulfonated Poly(ether ether ketone)/Polyacrylonitrile Acid–Base Blend Membrane for Vanadium Redox Flow Battery Application  

Science Journals Connector (OSTI)

Acid–base blend membrane prepared from sulfonated poly(ether ether ketone) (SPEEK) and polyacrylonitrile (PAN) was detailedly evaluated for vanadium redox flow battery (VRFB) application. SPEEK/PAN blend membrane exhibited dense and homogeneous cross-...

Zhaohua Li; Wenjing Dai; Lihong Yu; Le Liu; Jingyu Xi; Xinping Qiu; Liquan Chen

2014-10-15T23:59:59.000Z

53

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect (OSTI)

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

54

Alcohol Poisoning Death in New Mexico  

E-Print Network [OSTI]

Alcohol poisoning results from the rapid ingestion of large quantities of alcohol, which can lead to very high blood alcohol concentrations and death. In the past several years, the highly publicized alcohol-poisoning

unknown authors

55

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network [OSTI]

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

56

Kinetic mechanism of dimethyl ether production process using syngas from integrated gasification combined cycle power plant  

Science Journals Connector (OSTI)

In a 1-step synthesis gas-to-dimethyl ether process, synthesis gas is converted into dimethyl ether (DME) in a single reactor. Three reactions are involved in this process: methanol synthesis, methanol dehydra...

Hee-Woo Park; Jin-Kuk Ha; Euy Soo Lee

2014-07-01T23:59:59.000Z

57

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units  

Science Journals Connector (OSTI)

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units ... Vehicle manufacturers are rushing ahead with research into alternative fuels such as dimethyl ether (DME), biodiesel, methanol, ethanol, and hydrogen. ...

Marita Nilsson; Lars J. Pettersson; Bård Lindström

2006-07-29T23:59:59.000Z

58

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

59

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

60

DME-to-oxygenates process studies  

SciTech Connect (OSTI)

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Fuel alcohol opportunities for Indiana  

SciTech Connect (OSTI)

Prepared at the request of US Senator Birch Bayh, Chairman of the National Alcohol Fuels Commission, this study may be best utilized as a guidebook and resource manual to foster the development of a statewide fuel alcohol plan. It examines sectors in Indiana which will impact or be impacted upon by the fuel alcohol industry. The study describes fuel alcohol technologies that could be pertinent to Indiana and also looks closely at how such a fuel alcohol industry may affect the economic and policy development of the State. Finally, the study presents options for Indiana, taking into account the national context of the developing fuel alcohol industry which, unlike many others, will be highly decentralized and more under the control of the lifeblood of our society - the agricultural community.

None

1980-08-01T23:59:59.000Z

62

Alcohol Use, Comorbidity, and Mortality  

E-Print Network [OSTI]

with alcohol use: previous heart attack, previous stroke,and prior history of heart attack, stroke, hypertension, andNonsmoker Hypertension, % Heart attack, % Stroke, % Diabetes

2006-01-01T23:59:59.000Z

63

Alcohol policy process in Thailand.  

E-Print Network [OSTI]

??The thesis describes and analyses the Thai alcohol policy process in the period 1997 - 2006, in order to investigate the characteristics and areas for… (more)

Thaksaphon, Thamarangsi

2008-01-01T23:59:59.000Z

64

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

65

Synthesis of Medium Ring Ethers. 5. The Synthesis of (+)-Laurencin  

Science Journals Connector (OSTI)

The eight-membered medium ring ether natural product (+)-laurencin 1 is the prototypical member of a growing family of marine natural product cyclic ethers isolated from red algae and those marine organisms which feed on Laurencia species. ... The reaction mixture immediately became yellow and gradually turned dark red as gas was evolved. ... We thank the Engineering and Physical Sciences Research Council (EPSRC) UK for a research grant, Pfizer Central Research, and Corpus Christi College Cambridge for the award of a studentship and a Junior Research Fellow ship (J.W.B.), the Cambridge European Overseas Trust, Ciba (Novartis) and the Swiss Foundation for Gifted Students (scholarship to S.D.), and the Commission of the European Communities (TMR award to T.C.S.) for generous financial support. ...

Jonathan W. Burton; J. Stephen Clark; Sam Derrer; Thomas C. Stork; Justin G. Bendall; Andrew B. Holmes

1997-08-13T23:59:59.000Z

66

Dimethyl Ether Autoignition at Engine-Relevant Conditions  

Science Journals Connector (OSTI)

† Key Laboratory for Power Machinery and Engineering of M.O.E., Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China ... The autoignition of dimethyl ether (DME), an alternative diesel engine fuel, has been studied at elevated pressures. ... In addition to studies aimed at ascertaining the performance of compression–ignition internal combustion engines fuel with DME,(2, 3) there have been a number of studies focused on experimental characterization of fundamental combustion properties for DME. ...

Zhenhua Li; Weijing Wang; Zhen Huang; Matthew A. Oehlschlaeger

2013-04-01T23:59:59.000Z

67

2' and 3' Carboranyl uridines and their diethyl ether adducts  

DOE Patents [OSTI]

There is disclosed a process for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. Said carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of said compounds in methods for boron neutron capture therapy in mammalian tumor cells.

Soloway, Albert H. (Worthington, OH); Barth, Rolf F. (Columbus, OH); Anisuzzaman, Abul K. (Columbus, OH); Alam, Fazlul (Anaheim, CA); Tjarks, Werner (Columbus, OH)

1992-01-01T23:59:59.000Z

68

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

69

Gene therapy in alcoholic rats  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

70 70 Sept. 9, 2001 Gene Therapy Reduces Drinking in "Alcoholic" Rats UPTON, NY - Scientists at the U.S. Department of Energy's Brookhaven National Laboratory have shown that increasing the level of a brain protein important for transmitting pleasure signals can turn rats that prefer alcohol into light drinkers, and those with no preference into near teetotalers. The findings, published in the first September 2001 issue of the Journal of Neurochemistry (Vol. 78, No. 5), may have implications for the prevention and treatment of alcoholism in humans. "This is a preliminary study, but when you see a rat that chooses to drink 80 to 90 percent of its daily fluid as alcohol, and then three days later it's down to 20 percent, that's a dramatic drop in alcohol intake - a very clear change in behavior," said Panayotis Thanos, the lead researcher. "This gives us great hope that we can refine this treatment for future clinical use."

70

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

71

Miniature Enzyme-Based Electrodes for Detection of Hydrogen Peroxide Release from Alcohol-Injured Hepatocytes  

E-Print Network [OSTI]

generated by hepatocytes has not been undertaken to the best of our knowledge. Hydrogen peroxide (H2O2Miniature Enzyme-Based Electrodes for Detection of Hydrogen Peroxide Release from Alcohol clinical and experimental studies, it has been found that the production of reactive oxygen species (ROS

Ferrara, Katherine W.

72

Synthesis of higher alcohols from carbon monoxide and hydrogen in a slurry reactor  

SciTech Connect (OSTI)

Higher, i.e. C{sub 2{sup +}}, alcohols are desired as gasoline additives, feedstocks for producing ethers and as alternative fuels for automobiles. In all cases, the backbone branching of an alcohol improves octane rating, which is essential for good engine performance. These types of branched, higher alcohols are the desired products for a process converting synthesis gas, a CO and H{sub 2} mixture, often generated from coal gasification. Based on this premise, promoted ZnCr oxide catalysts appear to be as one of the best avenues for further investigation. Once this investigation is complete, a natural extension is to replace the Cr in the ZnCr oxide catalyst with Mo and W, both in the same elemental triad with Cr. Mo has already been shown as an active HAS catalyst, both on a SiO{sub 2} support and in the MoS{sub 2} form. The three catalyst combinations, ZnMo, ZnW, and MnCr oxides will be tested in the stirred autoclave system. However, if none of the three indicate any comparable activity and/or selectivity toward higher alcohols as compared with other HAS catalysts, then an investigation of the effects of Cs promotion on the ZnCr oxide methanol catalysts will be executed.

McCutchen, M.S.

1992-08-28T23:59:59.000Z

73

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

74

E-Print Network 3.0 - allyl glycidyl ether Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 15 () Trichloromethane ()1,1,2,2-1,1,2,2-Tetrachloroethane Summary: ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

75

POLYCHLORINATED BIPHENYLS AND POLYBROMINATED DIPHENYL ETHERS IN GALAPAGOS SEA LIONS (ZALOPHUS WOLLEBAEKI)  

E-Print Network [OSTI]

), polybrominated diphenyl ethers (PBDEs), polychlorinated dibenzo-p- dioxins (PCDDs), and polychlorinated dibenzo-p-dioxins (PCDDs), and polychlorinated dibenzofurans (PCDFs) repre- sent persistent

Gobas, Frank

76

Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Alternative Fuels lDimethyl Ether Rheology and Materials Studies Liquid Fuels from Biomass BiodieselFuelManagementBestPracticesReport.pdf...

77

Solvent Effects on Metal Complexation with Crown Ethers from Liquid to Supercritical Fluids (DE-FG07-98ER 149 13)  

SciTech Connect (OSTI)

The purpose of this project is to study the salvation effects of metal-crown ether complexation in different solvents. It has been suggested in the literature that supercritical fluid carbon dioxide (SF-CO2) is a tunable solvent because its salvation environment can be varied with the fluid density. In this project, spectroscopic techniques including nuclear magnetic resonance (NMR) and Fourier Transform Infrared (FTIR) were used to evaluate salvation effects of metal crown complexation in organic solvents and in SF-CO2. In most solvent extraction systems, water is often involved in the extraction processes. We have carried out extensive studies of water-crown ether interactions in different solvents and in SF-CO2 using NMR and FTIR techniques. Water molecules can be attached to crown ethers through hydrogen bonding of H-0-H to the oxygen atoms of crown ether cavities. This type of interaction is like a Lewis acid-Lewis base complexation. During the course of this project, we noticed that some CO2 soluble Lewis base such as tri-n-butyl-phosphate (TBP) can also form such Lewis acid-Lewis base complexes with water and other inorganic acids including nitric acid and hydrochloric acid. Inorganic acids (e.g. nitric acid) are normally not soluble in SF-CO2. However, because TBP is highly soluble in SF-CO2, an inorganic acid bound to TBP via hydrogen bonding becomes CO2 soluble. This Lewis acid-Lewis base complex approach provides a method of introducing inorganic acids into supercritical fluid CO2 for chemical reactions.

Wai, C.M.

2002-06-01T23:59:59.000Z

78

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

79

Polybrominated diphenyl ether flame retardants in the antarctic environment  

E-Print Network [OSTI]

, the historical record of dioxins, PCBs and DDTs in the same cores showed a decreasing trend. At present, PBDEs are recognized as a worldwide pollution problem since they have reached remote areas such as the deep ocean, the Arctic and Antarctica (de Boer et al... that cheerful and warm Brazilian spirit. You are my Aggie family! viii NOMENCLATURE #1; critical value of a statistical test used to reject the null hypothesis ANOVA Analysis of Variance BDE Brominated Diphenyl Ether BFR Brominated Flame Retardant DC...

Yogui, Gilvan Takeshi

2009-05-15T23:59:59.000Z

80

Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities  

SciTech Connect (OSTI)

Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K. [Div. of Decontamination and Decommissioning Technology Development, Korea Atomic Energy Research Inst., Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2012-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Mixed Alcohol Synthesis Catalyst Screening 2007 Progress Report  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) and National Renewable Energy Laboratory (NREL) are researching the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is obtaining commercially available mixed alcohol or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. The most promising catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. After a review of the literature in 2006 and conversations with companies that produce catalysts, it was determined that no commercial mixed-alcohol synthesis catalysts were available. One manufacturer supplied a modified methanol catalyst that was tested in the PNNL laboratory-scale system and provided to NREL for further testing. PNNL also prepared and tested the behavior of 10 other catalysts representing the distinct catalyst classes for mixed alcohol syntheses. Based on those results,testing in 2007 focused on the performance of the rhodium-based catalysts. The effects of adding promoters to the rhodium catalysts in addition to the manganese already being used were examined. The iron and rhenium promoters both stood out as achieving higher carbon selectivities , followed by Cu. Iridium and Li, on the other hand, had low carbon selectivity ratios of 0.27 and 0.22, respectively. Although testing of candidate promoters is not complete, it appears that Ir and Li promoters warrant further optimization and possibly combination to further improve STYs and carbon selectivities to C2+ oxygenates. However, using these promoters, it will be necessary to incorporate a separate hydrogenation catalyst to improve the yield of C2+ alcohols with respect to the other oxygenates. Fe, Re, and Cu stand out as possible candidates in this respect, but additional research is needed to examine whether they can be combined with the other promoters on the Rh-based catalyst or need to be optimized on a separate catalyst support that is either physically mixed or used in series with the promoted Rh-based catalyst.

Gerber, Mark A.; White, J. F.; Gray, Michel J.; Stevens, Don J.

2007-11-01T23:59:59.000Z

82

Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis  

E-Print Network [OSTI]

1 Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis of Single-phase thermal decomposition of ethanol and dimethyl ether (DME) at typical SWNT growth conditions using to the predicted decomposition mechanism. Signature peak intensities indicated concentrations of both ethanol

Maruyama, Shigeo

83

Composition and Digestibility of the Ether Extract of Hays and Fodders.  

E-Print Network [OSTI]

556-712-5m TEXAS AGRICULTURAL EXPERIMENT STATIONS. BULLETIN NO . 150 AUGUST , 1912. Division o f Chemistry TECHNICAL BULLETIN Composition and Digestibility of the Ether Extract of Hays and Fodders By G S. FRAPS and J. B. RATHER POSTOFFICE... Digestibility of the Constituents............................................................. 23 Summary and Conclusions.......................................................................29 BLANK PAGE IN ORIGINAL Composition and Digestibility of the Ether...

Fraps, G. S.; Rather, J. B.

1912-01-01T23:59:59.000Z

84

Proton-conducting polymer electrolyte membranes based on fluoropolymers incorporating perfluorovinyl ether sulfonic acids and fluoroalkenes  

E-Print Network [OSTI]

acids. A novel synthetic route describing the preparation of perfluorovinyl ether monomer containing. The radical (co) and terpolymerization of 4-[(,,-trifluorovinyl)oxy]benzene sulfonyl chloride (TFVOBSC) with 1,1-difluoroethylene (or vinylidene fluoride, VDF), hexafluoropropene (HFP), and perfluoromethyl vinyl ether (PMVE

Paris-Sud XI, Université de

85

Modelling the fate of polybrominated diphenyl ethers (PBDEs) during the municipal sewage treatment process  

Science Journals Connector (OSTI)

Sewage treatment plants (STPs) are an important source to the environment for many chemicals of concern (COCs). Polybrominated diphenyl ethers (PBDEs) are one such group of COCs of present day concern for which studies on fate and transport during the ... Keywords: chemical fate and transport, mass balance model, polybrominated diphenyl ethers, risk assessment, sewage treatment, water and wastewater management

Kerry N. McPhedran; Rajesh Seth

2007-08-01T23:59:59.000Z

86

Catalyst Activity Comparison of Alcohols over Zeolites. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Activity Comparison of Alcohols over Zeolites. Catalyst Activity Comparison of Alcohols over Zeolites. Abstract: Alcohol transformation to transportation fuel range hydrocarbon on...

87

Use of ethers as high-octane components of gasolines  

SciTech Connect (OSTI)

This article reports on a study of the possible utilization of methyl tert-amyl ether (MTAE) as an automotive gasoline component, both by itself and in combination with methyl tert-butyl ether (MTBE). The naphtha used in these studies consisted of 80% reformer naphtha produced under severe conditions and 20% straight-run IBP-62/sup 0/C cut. The physicochemical properties of the MTAE, the MTBE, and the naphtha base stock are given. It is determined that MTAE, which has a slightly poorer knock resistance than MTBE, is fully equal to MTBE in all other respects and can be used as an automotive gasoline component; that a gasoline blend prepared from 89% naphtha base stock, 5.5% MTAE, and 5.5% MTBE meets all of the requirements of the standard GOST 2084-77 for Grade AI-93 gasoline; and that the use of MTAE offers a means for expanding the resources of high-octane components, lowering the toxicity of the gasolines and the exhaust gas (in comparison with organometallic antiknock agents), and bringing non-petroleum raw materials into the fuel production picture.

Gureev, A.A.; Baranova, G.N.; Korotkov, I.V.; Levinson, G.I.

1984-01-01T23:59:59.000Z

88

Fuel Ethanol Oxygenate Production  

Gasoline and Diesel Fuel Update (EIA)

Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area May-13 Jun-13 Jul-13 Aug-13 Sep-13 Oct-13 View History U.S. 27,197 26,722 26,923 26,320 25,564 27,995 1981-2013 East Coast (PADD 1) 628 784 836 842 527 636 2004-2013 Midwest (PADD 2) 25,209 24,689 24,786 24,186 23,810 26,040 2004-2013 Gulf Coast (PADD 3) 523 404 487 460 431 473 2004-2013 Rocky Mountain (PADD 4) 450 432 430 432 415 429 2004-2013 West Coast (PADD 5)

89

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

90

Pyrochlore-Based Catalysts for Syngas-Derived Alcohol Synthesis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pyrochlore-Based Catalysts for Syngas-Derived Pyrochlore-Based Catalysts for Syngas-Derived Alcohol Synthesis Contact NETL Technology Transfer Group techtransfer@netl.doe.gov PON-13-006 August 2013 Opportunity This technology provides an advantageous means to convert syngas into a class of chemicals known as higher oxygenates as well as other long-chain hydrocarbons. Research is currently active on this patent-pending technology "Method of CO and/or CO2 Hydrogenation Using Doped Mixed Metal Oxides." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Significance * Improves the conversion of syngas from natural gas, coal, or biomass * Enhances the potential use of oxygenates as

91

Plants making oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants making oxygen Plants making oxygen Name: Doug Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: How many plants are needed to make enough oxygen for one person for one hour? We are experimenting with Anacharis plants. Replies: The problem can be solved when broken down into smaller questions: 1. How much oxygen does a person need in an hour? 2. How much oxygen does a plant produce in an hour? 3. Based on the above, how many plants will provide the oxygen needs of the person for the hour? Here is the solution to the first question: A resting, healthy adult on an average, cool day breathes in about 53 liters of oxygen per hour. An average, resting, health adult breathes in about 500 mL of air per breath. This is called the normal tidal volume. Now, 150 mL of this air will go to non- functioning areas of the lung, called the "dead space." The average breath rate for this average person is 12 breaths per minute. So, the amount of air breathed in by the person which is available for use is 12 x (500 mL -150 mL) = 4,200 mL/minute. Multiply by 60 to get 252,000 mL/hour. That is, every hour, the person will breathe in 252 L of air. Now, on an average, cool, clear day, only 21% of that air is oxygen. So, 21% of 252 L is 53 L. So, in an hour, the person breathes in about 53 L of oxygen.

92

Algae for Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Algae for Oxygen Algae for Oxygen Name: Pam Burkardt Status: N/A Age: N/A Location: N/A Country: N/A Date: N/A Question: Hi, I am Pam Burkardt, a seventh grader at Fox Chapel School. I have a question on algae. I read somewhere that someday people might take bath tubs full of algae onto spaceships to provide oxygen for the crew. How much oxygen does algae give off, is this really possible? Replies: I think that most of the oxygen in the atmosphere comes in fact from one-celled plants in the oceans, like algae. They are likely to produce a lot of oxygen per unit weight because they don't have non-photosynthesizing bark, roots, branches, etc., nor (I think) a major dormant period like temperate-zone plants. The cost of space travel at present is dominated by the expense of heaving weight up into Earth orbit (it costs very little extra to send it to the Moon, for example, or Mars). For missions of short duration the weight of the compressed oxygen you need to carry is less than the weight of algae, water and extra plumbing you'd need to carry if you relied on algae to produce your oxygen. The important use of green plants would be in very long duration space flight (years) or permanent inhabitation of worlds like the Moon, where you need an unlimited supply of oxygen. Now if you want to fantasize, Venus' atmosphere is almost all carbon dioxide. Suppose you dropped a whole lot of specially gene-tailored one-celled plants into the atmosphere (not the surface, it's too hot). Why then they might eat up all the carbon dioxide and produce a breathable atmosphere. The "greenhouse effect" would go away, and Venus would become a nice habitable if tropical world only 50 million miles away.

93

Hello, my name is ____, and I'm an alcoholic: A study of organizational identification and commitment to Alcoholics Anonymous  

E-Print Network [OSTI]

vice (www.alcoholics- anonymous.org/ The alcoholic can recover, n.d.). This description of the dual components of alcoholism provides a glimpse into the difficulties alcoholics face, once they realize they have a drinking problem. A lifetime...

Hall, Dana Ferguson

2008-07-31T23:59:59.000Z

94

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

95

Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization  

SciTech Connect (OSTI)

Carbon-oxygen bonds are the primary inter-monomer linkages lignin polymers in plant cell walls, and as such, catalyst development to cleave these linkages is of paramount importance to deconstruct biomass to its constituent monomers for the production of renewable fuels and chemicals. For many decades, acid catalysis has been used to depolymerize lignin. Lignin is a primary component of plant cell walls, which is connected primarily by aryl-ether linkages, and the mechanism of its deconstruction by acid is not well understood, likely due to its heterogeneous and complex nature compared to cellulose. For effective biomass conversion strategies, utilization of lignin is of significant relevance and as such understanding the mechanisms of catalytic lignin deconstruction to constituent monomers and oligomers is of keen interest. Here, we present a comprehensive experimental and theoretical study of the acid catalysis of a range of dimeric species exhibiting the b-O-4 linkage, the most common inter-monomer linkage in lignin. We demonstrate that the presence of a phenolic species dramatically increases the rate of cleavage in acid at 150 degrees C. Quantum mechanical calculations on dimers with the para-hydroxyl group demonstrate that this acid-catalyzed pathway differs from the nonphenolic dimmers. Importantly, this result implies that depolymerization of native lignin in the plant cell wall will proceed via an unzipping mechanism wherein b-O-4 linkages will be cleaved from the ends of the branched, polymer chains inwards toward the center of the polymer. To test this hypothesis further, we synthesized a homopolymer of b-O-4 with a phenolic hydroxyl group, and demonstrate that it is cleaved in acid from the end containing the phenolic hydroxyl group. This result suggests that genetic modifications to lignin biosynthesis pathways in plants that will enable lower severity processes to fractionate lignin for upgrading and for easier access to the carbohydrate fraction of the plant cell wall.

Sturgeon, M. R.; Kim, S.; Chmely, S. C.; Foust, T. D.; Beckham, G. T.

2013-01-01T23:59:59.000Z

96

Separation of methyl t-butyl ether from close boiling C[sub 5] hydrocarbons by extractive distillation  

SciTech Connect (OSTI)

A method for recovering methyl t-butyl ether from a mixture of methyl t-butyl ether and 1-pentene which comprises distilling a mixture of methyl t-butyl ether and 1-pentene in the presence of about one part of an extractive agent per part of methyl t-butyl ether -- 1-pentene mixture, recovering the 1-pentene as overhead product and obtaining the methyl t-butyl ether and the extractive agent from the still pot, wherein said extractive agent consists of one material selected from the group consisting of sulfolane, nitroethane, t-butanol, ethylene glycol diacetate, 1-methoxy-2-propanol acetate, methyl isoamyl ketone, ethylene glycol methyl ether, propylene glycol phenyl ether and diethyl malonate.

Berg, L.

1993-07-20T23:59:59.000Z

97

Solar energy: Hydrogen and oxygen  

Science Journals Connector (OSTI)

Solar energy: Hydrogen and oxygen ... Demonstrating the electrolysis of water with solar energy. ...

John J. Farrell

1982-01-01T23:59:59.000Z

98

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

Kebabian, P.

1997-07-22T23:59:59.000Z

99

E-Print Network 3.0 - acid-labile cholesterol-vinyl ether-peg...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystallization of Recombinant Crithidia fasciculata Tryparedoxin Summary: of 30% polyethylene glycol monomethyl ether (PEG MME) 2000, 0.1 M TrisHCl, pH 8.2, 1% dimethyl Source:...

100

Polybrominated diphenyl ethers in combusted residues and soils from an open burning site of electronic wastes  

Science Journals Connector (OSTI)

Polybrominated diphenyl ethers (PBDEs) are ubiquitous environmental contaminants due to their extensive use. Combusted residue from electronic waste (e-waste) combustion is one of the contamination sources ... tr...

Qian Luo; Ming Hong Wong; Zijian Wang; Zongwei Cai

2013-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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101

Solvent Effects on Cesium Complexation with Crown Ethers from Liquid to Supercritical Fluids  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) techniques were used to study crown ether-water interactions in solvents of low dielectric constants such as chloroform and carbon tetrachloride. Water forms a 1:1 complex with a number of crown ethers including 12-crown-4, 15-crown-5, 18-crown-6, dicyclohexano-18=crown-6, dicyclohexano-24-crown 8, and dibenzl-24-crown-8 in chloroform. Among these crown ethers, the 18-crown-6-H2 complex has the largest equilibrium constant (K=545) and 97% of the crown is complexed to water in chloroform. Addition of carbon tetrachloride to chloroform lowers the equilibrium constants of the crown-water complexes. The partition coefficients of crown ethers (D=crown in water/crown in solvent) between water and organic solvent also vary with solvent composition.

Chien M. Wai; Anne Rustenholtz; Shaofen Wang; Su-Chen Lee; Jamie Herman; Richard A. Porter

2004-03-15T23:59:59.000Z

102

Oxygen in Underwater Cave  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen in Underwater Cave Oxygen in Underwater Cave Name: Natalie Status: student Grade: 9-12 Location: HI Country: USA Date: Spring 2011 Question: Is it possible for there to be free oxygen in an underwater cave? If it is, then how does it work? Replies: Yes it is possible as I have personally experienced. If the cave roof rises to a level above the water, air dissolved in the water will slowly out gas until the water is at the same level at all places. A pocket of breathable air will form. In many caves the roof dips below water level in one place but it above it on both sides. Think of a U shaped tube where the bottom of the U is blocked by water. This is called a siphon and I have passed through many of these to find breathable air on the other side. R. W. "Bob" Avakian Oklahoma State Univ. Inst. of Technology

103

Effect of use of low oxygenate gasoline blends upon emissions from California vehicles. Final report  

SciTech Connect (OSTI)

The objective of this project was to investigate the emissions effects of low-oxygenate gasoline blends on exhaust and evaporative emissions from a test fleet of California certified light-duty autos. Thirteen vehicles were procured and tested using four gasoline-oxygenate blends over three test cycles. The four gasoline blends were: Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and 'match' and 'splash' blends of ethanol (in the 'match' blend the fuel Reid Vapor Pressure (RVP) is held constant, while in the 'splash' blend the fuel RVP is allowed to increase). Hydrocarbon and carbon monoxide exhaust emissions were generally reduced for the oxygenated blends, the exception being the 'splash-blended' ethanol gasoline which showed mixed results. Older technology vehicles (e.g., non-catalyst and oxidation catalyst) showed the greatest emissions reductions regardless of gasoline blend, while later technology vehicles showed the smallest reductions. Evaporative emissions and toxics were generally reduced for ETBE, while results for the other blends were mixed.

Born, G.L.; Lucas, S.V.; Scott, R.D.; DeFries, T.H.; Kishan, S.

1994-02-01T23:59:59.000Z

104

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

SciTech Connect (OSTI)

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

105

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

106

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

107

Biodegradation of Methyl tert-Butyl Ether and Other Fuel Oxygenates by a New Strain, Mycobacterium austroafricanum IFP 2012  

Science Journals Connector (OSTI)

...and the O2 consumption rate was measured with a 12-mm...France). The measured rates were corrected for endogenous...Cells were broken by three passes through a French press...from 105 to 200C at a rate of 10C/min. Helium...flushed with a Spectra-Physics SCM 400 vacuum flusher...

Alan François; Hugues Mathis; Davy Godefroy; Pascal Piveteau; Françoise Fayolle; Frédéric Monot

2002-06-01T23:59:59.000Z

108

DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Their strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis (FMEA, referred to by Air Products as a ''HAZOP'' analysis) with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operational in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation Institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

2003-04-01T23:59:59.000Z

109

Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon  

SciTech Connect (OSTI)

The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

2012-08-19T23:59:59.000Z

110

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

111

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

112

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

113

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

114

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

115

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

116

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

117

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

118

Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .  

SciTech Connect (OSTI)

The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

Wallner, T. (Energy Systems)

2011-08-01T23:59:59.000Z

119

Alcohol-based fuels from syngases  

SciTech Connect (OSTI)

Development of catalysts and reactor systems for producing alcohol-based fuels from coal-derived synthesis gases is outlined. Also, utilization of alcohol-based fuels either as gasoline blending stocks at 10-20% addition rates or as straight-run fuels is discussed. (Refs. 4).

Greene, M.I.

1982-08-01T23:59:59.000Z

120

Design Case Summary: Production of Mixed Alcohols from Municipal...  

Office of Environmental Management (EM)

Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via...

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121

Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...  

Energy Savers [EERE]

Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of...

122

Application of sPC-SAFT-JC and sPC-SAFT-GV to Phase Equilibria Predictions of Alkane/Alcohol, Alcohol/Alcohol, and Water/Alcohol Binary Systems  

Science Journals Connector (OSTI)

Application of sPC-SAFT-JC and sPC-SAFT-GV to Phase Equilibria Predictions of Alkane/Alcohol, Alcohol/Alcohol, and Water/Alcohol Binary Systems ... This paper reports on the ability of sPC-SAFT extended with the polar terms of Gross and Vrabec (GV) and Jog and Chapman (JC) to predict the phase equilibria of alkane/alcohol, alcohol/alcohol, and water/alcohol binary systems. ... For these selected binary systems, the GV and JC polar terms deliver similar results when incorporated into sPC-SAFT. ...

Adriaan J. de Villiers; Cara E. Schwarz; Krasimir G. Chobanov; Andries J. Burger

2014-03-12T23:59:59.000Z

123

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

124

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

125

Catalyst system and process for benzyl ether fragmentation and coal liquefaction  

DOE Patents [OSTI]

Dibenzyl ether can be readily cleaved to form primarily benzaldehyde and toluene as products, along with minor amounts of bibenzyl and benzyl benzoate, in the presence of a catalyst system comprising a Group 6 metal, preferably molybdenum, a salt, and an organic halide. Although useful synthetically for the cleavage of benzyl ethers, this cleavage also represents a key model reaction for the liquefaction of coal; thus this catalyst system and process should be useful in coal liquefaction with the advantage of operating at significantly lower temperatures and pressures.

Zoeller, Joseph Robert (Kingsport, TN)

1998-04-28T23:59:59.000Z

126

The Total Fatty Acids and Other Ether-Soluable Constituents of Feedstuffs.  

E-Print Network [OSTI]

586-914-10m TEXAS AGRICULTURAL EXPERIMENT STATION BULLETIN NO. 169 SEPTEMBER, 19I4 DIVISION OF CHEMISTRY The Total Fatty Acids and Other Ether-Soluble Constituents of Feedstuffs BY J. B. RATHER Assistant Chemist POSTOFFICE COLLEGE STATION... IS T .* In previous publications of this Experiment Station (Fraps and Bather, Bulletins Nos. 150 and 162) it has been shown that the un? saponifiable matter in the ether extract of hays and fodders averages about 58 per cent. Of the total extract, and is of much...

Rather, J. B. (James Burness)

1914-01-01T23:59:59.000Z

127

Toxicity of polychlorinated diphenyl ethers in Hydra attenuata and in rat whole embryo culture  

E-Print Network [OSTI]

TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A?TENUATA AND IN RAT WHOLE EMBRYO CULTURE A Thesis by MARION CAROL BECKER Submitted to the Office of Graduate Studies of Texas A8cM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Toxicology TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A1TENUATA AND IN RAT WHOLE EMBRYO CULTURE by MARION CAROL BECKER Approved as to style and content by: Stephen H. S (Ca...

Becker, Marion Carol

2012-06-07T23:59:59.000Z

128

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

129

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

130

OXYGEN ABUNDANCES IN CEPHEIDS  

SciTech Connect (OSTI)

Oxygen abundances in later-type stars, and intermediate-mass stars in particular, are usually determined from the [O I] line at 630.0 nm, and to a lesser extent, from the O I triplet at 615.7 nm. The near-IR triplets at 777.4 nm and 844.6 nm are strong in these stars and generally do not suffer from severe blending with other species. However, these latter two triplets suffer from strong non-local thermodynamic equilibrium (NLTE) effects and thus see limited use in abundance analyses. In this paper, we derive oxygen abundances in a large sample of Cepheids using the near-IR triplets from an NLTE analysis, and compare those abundances to values derived from a local thermodynamic equilibrium (LTE) analysis of the [O I] 630.0 nm line and the O I 615.7 nm triplet as well as LTE abundances for the 777.4 nm triplet. All of these lines suffer from line strength problems making them sensitive to either measurement complications (weak lines) or to line saturation difficulties (strong lines). Upon this realization, the LTE results for the [O I] lines and the O I 615.7 nm triplet are in adequate agreement with the abundance from the NLTE analysis of the near-IR triplets.

Luck, R. E.; Andrievsky, S. M. [Department of Astronomy, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7215 (United States); Korotin, S. N.; Kovtyukh, V. V., E-mail: luck@fafnir.astr.cwru.edu, E-mail: serkor@skyline.od.ua, E-mail: val@deneb1.odessa.ua, E-mail: scan@deneb1.odessa.ua [Department of Astronomy and Astronomical Observatory, Odessa National University, Isaac Newton Institute of Chile, Odessa Branch, Shevchenko Park, 65014 Odessa (Ukraine)

2013-07-01T23:59:59.000Z

131

Is alcohol more dangerous than heroin? The physical, social and financial costs of alcohol  

Science Journals Connector (OSTI)

A recent paper claimed in its classification of harmful substances, that alcohol is more dangerous than heroin. This paper aims to weigh up some of the evidence in the literature on the physical, social and financial effects of alcohol and the associated disease burden. We will also explore alcohol within the context of emergency department (ED) presentations. Reasons for ED attendance can be overtly and directly alcohol related such as alcohol intoxication, assaults, injuries and falls and indirectly such as child neglect, psychological problems and chronic diseases. Alcohol is often viewed as an isolated incident or factor for ED presentations but there are data that refute this perception. In ED, the priority is to treat the patient and their primary complaint, however it may be appropriate to screen for alcohol use, give advice and potentially offer an intervention to the patient. With the recent UK and Australian guidelines on reducing health risks from drinking alcohol, the ED has the ability to play an active role in reducing the harmful effects of alcohol through screening, advising and undertaking intervention as appropriate. However this cannot be achieved in isolation but within the broader political and health policy framework. There is now a growing body of literature supporting the need to make alcohol less affordable, less easy to buy and reducing alcohol advertising. Although alcohol is a legal substance, this paper concludes that examining the wider effects in physical, social and financial terms, alcohol is more dangerous than heroin. It has become an endemic problem in society affecting the individual and the whole community.

Geraldine A. Lee; Marcus Forsythe

2011-01-01T23:59:59.000Z

132

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

133

BWR oxygen control demonstration program  

SciTech Connect (OSTI)

A number of cracks have occurred recently in certain BWR piping systems. The operating environment associated with oxidizing species such as oxygen and hydrogen peroxide is considered one of the factors in the mechanism of cracking. In April 1976, NWT Corporation was contracted to perform a BWR oxygen control demonstration program. Means for reducing reactor water oxygen and hydrogen peroxide concentrations during startup and shutdown transients were defined and demonstrated at Vermont Yankee and Browns Ferry Unit 3. Results of the demonstrations and an analytical review of impacts of major system variables on oxygen transients are discussed herein.

Pearl, W.L.; Kassen, W.R.; Sawochka, S.G.

1981-05-01T23:59:59.000Z

134

Oxygen to the core  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1-01 1-01 For immediate release: 01/10/2013 | NR-13-01-01 Oxygen to the core Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Printer-friendly An artist's conception of Earth's inner and outer core. LIVERMORE, Calif. -- An international collaboration including researchers from Lawrence Livermore National Laboratory has discovered that the Earth's core formed under more oxidizing conditions than previously proposed. Through a series of laser-heated diamond anvil cell experiments at high pressure (350,000 to 700,000 atmospheres of pressure) and temperatures (5,120 to 7,460 degrees Fahrenheit), the team demonstrated that the depletion of siderophile (also known as "iron loving") elements can be produced by core formation under more oxidizing conditions than earlier

135

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

136

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

137

Dimethyl ether (DME) from coal as a household cooking fuel in China  

E-Print Network [OSTI]

technologies. Given China's rich coal resources, the production and use of coal-derived DME as a cooking fuelDimethyl ether (DME) from coal as a household cooking fuel in China Eric D. Larson Princeton gas (LPG) as a household cooking fuel. As such, DME is an attractive fuel for clean cooking. DME can

138

E-Print Network 3.0 - alkyl-tert alkyl ethers Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: of ProtonatedAlkyl tert-ButylEthers RO(H)C(CH&+ (To.6 Values in meV...

139

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose ethers in mortars2  

E-Print Network [OSTI]

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose : 10.1016/j.cemconres.2012.06.002 #12;2 ABSTRACT22 23 We show how nuclear magnetic spin-lattice relaxation dispersion of protons-water24 (NMRD) can be used to elucidate the effect of cellulose ethers

Boyer, Edmond

140

Third international symposium on alcohol fuels technology  

SciTech Connect (OSTI)

At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health and safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.

none,

1980-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

142

Plants and Night Oxygen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants and Night Oxygen Production Plants and Night Oxygen Production Name: Ashar Status: other Grade: other Location: Outside U.S. Country: India Date: Winter 2011-2012 Question: I would like to know if there are any plants which produces oxygen at night (without photosynthesis). I was told by a friend that Holy Basil (Ocimum tenuiflorum) produces oxygen even at night and I'm not convinced. I would like to get confirmation from experts. Replies: Some plants (particularly those of dry regions, e.g., deserts) only open their stomates at night to avoid drying out to intake CO2 (and output O2) (CAM photosynthesis) http://en.wikipedia.org/wiki/Crassulacean_acid_metabolism Sincerely, Anthony R. Brach, PhD Missouri Botanical Garden Bringing oxygen producing plants into your home is a way to mimic the healthy lifestyle factors of longevity in humans from the longest lived cultures.

143

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

144

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

145

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

146

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

147

E-Print Network 3.0 - alcohols catalyst names Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

synthesized catalysts for alcohol synthesis. We focus on structural... the use of biogas to create alcohol for fuel. Higher alcohols ... Source: Dunin-Borkowski, Rafal E. -...

148

E-Print Network 3.0 - alcohol dependence results Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

With Deprivation and Summary: between age at onset of alcohol use and DSM-IV alcohol dependence: results of the National Longitudinal... at onset of alcohol use...

149

E-Print Network 3.0 - alcohol breath tests Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

VERSUS SOPHISTICATED MODELS OF BREATH ALCOHOL Summary: Alcohol & Alcoholism, Vol. 31, No. 1, pp. 61-67, 1996 SIMPLE VERSUS SOPHISTICATED MODELS OF BREATH... -2420, USA,...

150

E-Print Network 3.0 - acute alcohol intoxication Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Alcohol Summary: "high" and "intoxication" during an intravenous (IV) alcohol infusion. Methods: Nine healthy control... (60 mg% 5 mg%) alcohol infusion. Numerical ratings...

151

E-Print Network 3.0 - alcohol effects Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

comply with all of the attached alcohol policies. Ticketed events serving alcohol must rent... that I have read and understood all policies, including the alcohol policy and I...

152

E-Print Network 3.0 - alcoholic beverage hormesis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

may approve the sale of alcohol on campus, only the Division of Alcoholic Beverages... . Advertising for any university event where alcoholic ... Source: Sura, Philip - Department...

153

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

154

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-11-01T23:59:59.000Z

155

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

156

Extended performance of alcohol fumigation in diesel engines through different multipoint alcohol injection timing cycles  

SciTech Connect (OSTI)

This paper reports on the results of using multipoint port injection alcohol fumigation of a four-cycle turbocharged diesel engine in which the fumigation injection cycle was varied. The three cycles, dual with one-half of the alcohol injection on each engine revolution, single with all of the alcohol injection during the open intake valve revolution, and single with all of the alcohol injected during the closed intake valve revolution, lead to significant differences in the engines pressure-volume history and alcohol energy replacement tolerance. The engine was fumigated with both industrial grade ethanol and methanol and complete performance and emissions data (excluding aldehydes) were measured at low, medium, and high values of BMEP and rpm.

Savage, L.D.; White, R.A.; Cole, S.; Pritchett, G.

1986-01-01T23:59:59.000Z

157

Oxygen transfer in the implant environment  

E-Print Network [OSTI]

Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

Goor, Jared Braden

2007-01-01T23:59:59.000Z

158

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

159

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux  

E-Print Network [OSTI]

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

Mallin, Michael

160

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect (OSTI)

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network [OSTI]

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

162

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

163

Angling chromium to let oxygen through | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which enable facile oxygen anion diffusion at low temperature. Brighter spheres are strontium ions; less-bright spheres are chromium ions. Oxygen anions are barely visible, and...

164

Extracorporeal membrane oxygenation promotes long chain fatty...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

165

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network [OSTI]

Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

Kim, Kee Chul

2010-01-01T23:59:59.000Z

166

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

167

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...  

Broader source: Energy.gov (indexed) [DOE]

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Presentation slides from the June 19, 2012, Fuel...

168

Oxygenate Supply/Demand Balances  

Gasoline and Diesel Fuel Update (EIA)

Oxygenate Supply/Demand Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model By Tancred C.M. Lidderdale This article first appeared in the Short-Term Energy Outlook Annual Supplement 1995, Energy Information Administration, DOE/EIA-0202(95) (Washington, DC, July 1995), pp. 33-42, 83-85. The regression results and historical data for production, inventories, and imports have been updated in this presentation. Contents * Introduction o Table 1. Oxygenate production capacity and demand * Oxygenate demand o Table 2. Estimated RFG demand share - mandated RFG areas, January 1998 * Fuel ethanol supply and demand balance o Table 3. Fuel ethanol annual statistics * MTBE supply and demand balance o Table 4. EIA MTBE annual statistics * Refinery balances

169

It's Elemental - The Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine The Element Oxygen [Click for Isotope Data] 8 O Oxygen 15.9994 Atomic Number: 8 Atomic Weight: 15.9994 Melting Point: 54.36 K (-218.79°C or -361.82°F) Boiling Point: 90.20 K (-182.95°C or -297.31°F) Density: 0.001429 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 16 Group Name: Chalcogen What's in a name? From the greek words oxys and genes, which together mean "acid forming." Say what? Oxygen is pronounced as OK-si-jen. History and Uses: Oxygen had been produced by several chemists prior to its discovery in 1774, but they failed to recognize it as a distinct element. Joseph

170

The System Boron—Oxygen  

Science Journals Connector (OSTI)

This presentation covers the years 1985 to 1988 and, in part, to 1992. It continues the previous discussion of the system boron—oxygen in “Boron Compounds” 3rd Suppl. Vol. 2, 1987, pp. 1/184, and earlier liter...

Gert Heller

1993-01-01T23:59:59.000Z

171

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

2003-11-01T23:59:59.000Z

172

Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion  

SciTech Connect (OSTI)

We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

2012-08-14T23:59:59.000Z

173

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tadé

2000-05-09T23:59:59.000Z

174

2[prime] and 3[prime] Carboranyl uridines and their diethyl ether adducts  

DOE Patents [OSTI]

A process is described for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. The carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of the compounds in methods for boron neutron capture therapy in mammalian tumor cells. No Drawings

Soloway, A.H.; Barth, R.F.; Anisuzzaman, A.K.; Alam, F.; Tjarks, W.

1992-12-15T23:59:59.000Z

175

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect (OSTI)

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

176

The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics  

SciTech Connect (OSTI)

This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

NONE

1995-10-01T23:59:59.000Z

177

Water column oxygen demand and sediment oxygen flux: patterns of oxygen depletion in tidal creeks  

Science Journals Connector (OSTI)

Five study sites were chosen in Futch Creek, Hewletts Creek and Pages Creek,...1). Sites were chosen to reflect a range in the values of dissolved oxygen levels, chlorophyll a concentrations and nutrient (nitroge...

Tara A. MacPherson; Lawrence B. Cahoon; Michael A. Mallin

2007-07-01T23:59:59.000Z

178

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

179

Researchers Directly Observe Oxygen Signature in the Oxygen-evolving  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Researchers Directly Observe Oxygen Signature in the Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the evolution of complex aerobic life. Coupled to the reduction of carbon dioxide, biological photosynthesis contributes foodstuffs for nutrition while recycling CO2 from the atmosphere and replacing it with O2. By utilizing sunlight to power these energy-requiring reactions, photosynthesis also serves as a model for addressing societal energy needs as we enter an era of diminishing fossil fuel resources and climate change. Understanding, at the molecular level, the dynamics and mechanisms behind photosynthesis is of fundamental importance and will prove critical to the future design of devices aimed at converting sunlight into electrochemical energy and transportable fuel.

180

The energy relationships of corn production and alcohol fermentation  

Science Journals Connector (OSTI)

The energy relationships of corn production and alcohol fermentation ... The production of alcohol from corn lends itself well to illustrating the practical applications of scientific principles that deal with energy transformations and inefficiencies. ...

Thomas E. Van Koevering; Michael D. Morgan; Thomas J. Younk

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

The effects of alcohol use on zinc status  

E-Print Network [OSTI]

Alcohol consumption has been shown to have adverse affects on bone growth and maintenance, although the mechanism has not been elucidated. The objective of this research was to look at the relationship between zinc and alcohol as a possible...

Chapman, Lisa Louise

1998-01-01T23:59:59.000Z

182

Cold-Start Performance and Emissions Behavior of Alcohol Fuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine...

183

Pharmacokinetic and Pharmacodynamic Drug Interactions with Ethanol (Alcohol)  

Science Journals Connector (OSTI)

Ethanol (alcohol) is one of the most widely used legal drugs in the world. Ethanol is metabolized by alcohol dehydrogenase (ADH) ... lead to a clinically significant pharmacokinetic interaction with ethanol, whic...

Lingtak-Neander Chan; Gail D. Anderson

2014-12-01T23:59:59.000Z

184

Alkali/TX sub 2 catalysts for CO/H sub 2 conversion to C sub 1 -C sub 4 alcohols  

SciTech Connect (OSTI)

The objective of this research is to investigate and develop novel catalysts for the conversion of coal-derived synthesis gas into C{sub 1}--C{sub 4} alcohols by a highly selective process. Therefore, the variations of catalyst activity and selectivity for the synthesis of alcohols from H{sub 2}/CO {le}1 synthesis gas for a series of A/TX{sub 2} compounds, where A is a surface alkali dopant, T is a transition metal, and X is a S, Se, or Te, will be determined. The alkali component A, which is essential for C-O and C-C bond forming reactions leading to alcohols, will be highly dispersed on the TX{sub 2} surfaces by using chemical vapor deposition (CVD) and chemical complexation/anchoring (CCA) methods. Catalysts that have been prepared during this quarter include RuS{sub 2}, NbS{sub 2}, K/MoS{sub 2}, and K/Crown either/MoS{sub 2}. Catalysts tested include KOH/MoS{sub 2} and K/Crown ether/MoS{sub 2}. 9 refs., 10 figs., 2 tabs.

Klier, K.; Herman, R.G.; Brimer, A.; Richards, M.; Kieke, M.; Bastian, R.D.

1990-09-01T23:59:59.000Z

185

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network [OSTI]

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

186

Alcohol-based fuels from syngases. [Alkanol fuels  

SciTech Connect (OSTI)

Explains how a mixture of methanol and C/sub 2/-C/sub 6/ saturated alcohols (Alkanol fuel) has the potential for providing a gasoline-blending stock superior to that of straight-run methanol or ethanol. Summarizes the technical and economic advantages of producing and utilizing Alkanol fuels. Although methanol is cheaper, Alkanols represent a higher-quality fuel product with lower-oxygen content and higher hydrogen content. Increasing the methanol content of the Alkanol mixture has the potential to reduce the Alkanols cost of production to the equivalent of that of methanol on a constant heating value basis. The optimal composition will depend on production costs as well as on the properties of Alkanol mixtures necessary to generate a premium, synthetic transportation fuel. The Mobil M-Gasoline Process is an alternative route to converting methanol to synthetic transportation fuels. Concludes that development of the Alkanols Process is in its early stages and further work needs to be done in identifying and solving potential technical bottlenecks related to catalyst stability/selectivity and recovery of water-free Alkanol fuel mixtures. Current work is involved in the study of the performance and stability of several catalyst candidates utilizing a slurry reaction system and in the identification of optimal compositions of Alkanols for use as gasoline blending stocks.

Greene, M.I.

1982-08-01T23:59:59.000Z

187

An explanation for enhanced perceptions of attractiveness after alcohol consumption  

E-Print Network [OSTI]

An explanation for enhanced perceptions of attractiveness after alcohol consumption L.G. Halseya alcohol consumption increases ratings of attractiveness to faces. This may help to explain increased attraction may be the result of alcohol consumption decreasing ability to detect bilateral asymmetry

Little, Tony

188

Division of Human Resources Alcohol & Drug Testing (CDL)  

E-Print Network [OSTI]

Division of Human Resources Alcohol & Drug Testing (CDL) Definitions of Terms Employee Relations/Alcohol & Drug Testing (CDL) Questions: (813) 974-2970 Rev. 12/2008 The definitions listed below are for common words/phrases used in the alcohol and drug testing procedures. Accident - An occurrence associated

Meyers, Steven D.

189

Division of Human Resources Alcohol & Drug Testing for  

E-Print Network [OSTI]

Division of Human Resources Alcohol & Drug Testing for Jobs Requiring CDL Employee Relations/Alcohol & Drug Testing (CDL) Questions: (813) 974-2970 Rev. 12/2008 · Report for duty or remain on duty requiring-accident testing is required, or until he/she undergoes a post-accident alcohol test, whichever occurs first

Meyers, Steven D.

190

The Employee Stress and Alcohol Project: The development of a computer-based alcohol abuse prevention program for employees  

Science Journals Connector (OSTI)

The Employee Stress and Alcohol Project (ESAP) developed an interactive computer-based alcohol abuse prevention and early intervention program accessible to employees over the Internet. Behavioral health research...

Robert A. Matano Ph.D.…

2000-05-01T23:59:59.000Z

191

E-Print Network 3.0 - alcohol ethyl alcohol Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

By The University of Texas at Arlington Police Department... 817-272-3381 Tips for Young Adults: The Truth about Alcohol If you are the victim of a crime on the U... . One...

192

REQUEST FORM PERMISSION TO SERVE ALCOHOL  

E-Print Network [OSTI]

. Celebrations held off-site during lunch or other working hours should be strongly discouraged for reasons both of safety and loss of productivity. Employees who consume alcohol during any off-site luncheon or event shall not return to work the same day. If circumstances make it necessary to schedule off-site events

193

Marketing of Unhealthy Foods, Beverages, and Alcohol  

E-Print Network [OSTI]

of other channels (movies, internet, billboards) shows similar exposure levels for youth Many new marketing is it located, what does it advertise and how is it related to intentions and use among young adolescents and driving Risky sexual behaviors Violent or deviant behaviors Alcohol abuse or dependence in both

Illinois at Chicago, University of

194

Detection and Quantification of Methyl tert-Butyl Ether-Degrading Strain PM1 by Real-Time TaqMan PCR  

Science Journals Connector (OSTI)

...purification Fresh Water microbiology Geologic...Polymerase metabolism Water Pollution, Chemical...bioremediation detection ethers ground water hydrocarbons methyl tert-butyl...pollutants pollution remediation sampling water resources...

Krassimira R. Hristova; Christian M. Lutenegger; Kate M. Scow

2001-11-01T23:59:59.000Z

195

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides  

E-Print Network [OSTI]

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

Paris-Sud XI, Université de

196

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

197

Quantifying the areal extent and dissolved oxygen concentrations of Archean oxygen oases.  

E-Print Network [OSTI]

??Several lines of evidence indicate that the advent of oxygenic photosynthesis preceded the oxygenation of the atmosphere—perhaps by as much as 300 million years. The… (more)

Olson, Stephanie

2013-01-01T23:59:59.000Z

198

Alcohol-based fuels from syngases  

SciTech Connect (OSTI)

This paper summarizes results of a research program which was undertaken to find the most advantageous method of using methanol in gasoline blends. It is demonstrated that a mixture called methanol and C/sub 2/C/sub 6/ saturated alcohols, called Alkanol fuel, has the potential for providing a gasoline-blending stock superior to that of straight-run methanol or ethanol. Extensive property data and test results are tabulated, plotted, and discussed. Economic considerations are included. 4 refs.

Greene, M.I.

1982-08-01T23:59:59.000Z

199

Flash photolysis resonance fluorescence investigation of the gas-phase reactions of hydroxyl radicals with cyclic ethers  

SciTech Connect (OSTI)

Absolute rate constants were measured for the gas-phase reactions of hydroxyl radicals with a series of dioxanes and other cyclic ethers by using the flash photolysis resonance fluorescence technique. Kinetic data for 1,3-dioxane and 1,4-dioxane, reactions 1 and 2, over the temperature range 240-440 K were used to derive the Arrhenius expressions. These results are compared to our earlier measurements for aliphatic ethers and are discussed in terms of reaction mechanisms and the prediction of reaction rates for such compounds from group reactivity values.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1990-03-08T23:59:59.000Z

200

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Microbial oceanography of anoxic oxygen minimum zones  

E-Print Network [OSTI]

Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

Ulloa, Osvaldo

202

The Role of Oxygen in Coal Gasification  

E-Print Network [OSTI]

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

203

Oxygen reduction on platinum : an EIS study  

E-Print Network [OSTI]

The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

Golfinopoulos, Theodore

2009-01-01T23:59:59.000Z

204

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

205

Imaging Oxygen Molecules Up Close | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Imaging Oxygen Molecules Up Close Imaging Oxygen Molecules Up Close ARRA-enabled upgrades enhance research capabilities STM images of the same TiO2(110) area upon O2 chemisorption...

206

Composite oxygen ion transport element  

SciTech Connect (OSTI)

A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

2007-06-12T23:59:59.000Z

207

Catalyst containing oxygen transport membrane  

SciTech Connect (OSTI)

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

2012-12-04T23:59:59.000Z

208

Respiration, photosynthesis, and oxygen isotope fractionation in ...  

Science Journals Connector (OSTI)

Jan 25, 1971 ... Respiration, photosynthesis, and oxygen isotope fractionation in oceanic surface water1. Peter M. Kroopnick. Department of Oceanography,.

2000-01-04T23:59:59.000Z

209

Oxygen Detection via Nanoscale Optical Indicators  

E-Print Network [OSTI]

Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

Ghosh, Ruby N.

210

8, 22252248, 2008 Detection of oxygen  

E-Print Network [OSTI]

ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

Paris-Sud XI, Université de

211

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network [OSTI]

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, mechanisms, and expected levels of oxygen and nitrogen contamination during gas tungsten arc, gas metal arc indicating the importance of dec9mposition of SiOz into silicon monoxide and oxygen are presented, indicating

Eagar, Thomas W.

212

The Mechanisms of Oxygen Reduction and Evolution Reactions in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

213

Oxygen consumption of bovine granulosa cells in vitro.  

E-Print Network [OSTI]

??The oxygen consumption rate of granulosa cells is considered to be a key determinant of oocyte oxygenation in follicles. The oxygen status of the oocyte… (more)

Li, Dongxing

2012-01-01T23:59:59.000Z

214

Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dependency of Thin Film Samaria Doped Ceria for Oxygen Sensing . Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen Sensing . Abstract: High temperature oxygen...

215

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as  

E-Print Network [OSTI]

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

216

Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes  

E-Print Network [OSTI]

1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

Paris-Sud XI, Université de

217

Dry dig: Ethics and alcohol in Middle Eastern archaeological practice  

E-Print Network [OSTI]

ARTICLE DRY DIG ETHICS AND ALCOHOL IN MIDDLE EASTERNhad encountered discussions of ethics, archaeology, andtower discussions regarding ethics and archaeology can ring

Porter, Benjamin W.

2010-01-01T23:59:59.000Z

218

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network [OSTI]

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

219

Cold-Start Performance and Emissions Behavior of Alcohol Fuels...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Methods Andrew Ickes & Thomas Wallner Argonne National Laboratory 17 th Directions in...

220

HD Applications of Significantly Downsized SI Engines Using Alcohol...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

SI Engines Using Alcohol DI for Knock Avoidance Direct injection of a second fuel (ethanol or methanol) is explored as a means of avoiding knock in turbocharged,...

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Hispanics, Blacks and Whites driving under the influence of alcohol: results from the 1995 National Alcohol Survey  

Science Journals Connector (OSTI)

Objective: To report nationwide survey data on patterns of driving under the influence of alcohol among Whites, Blacks and Hispanics. Method: Data were obtained from a probability sample consisting of 1582 Blacks, 1585 Hispanics and 1636 Whites in the US household population. Interviews averaging 1 h in length were conducted in respondents’ homes by trained interviewers. Results: Self-reported rates of driving a car after having drunk enough ‘to be in trouble if stopped by the police’ were highest among White and Hispanic men (22 and 21%, respectively), as were lifetime arrest rates for driving under the influence of alcohol (13% for White men, 19% for Hispanic men). Additionally, our analyses suggest that drinkers who drive under the influence of alcohol are more likely to be men (regardless of ethnicity), consume more alcohol, and be alcohol dependent than drinkers who do not engage in alcohol-impaired driving.

Raul Caetano; Catherine L Clark

2000-01-01T23:59:59.000Z

222

Title: Decomposition of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes  

E-Print Network [OSTI]

of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes Author list: Bo Hou (single-walled carbon nanotubes) was investigated. Gas-phase thermal decomposition of ethanol and DME ethanol and DME decomposition, confirming expected reaction trends and primary byproducts. Peak

Maruyama, Shigeo

223

Liver proteomics in progressive alcoholic steatosis  

SciTech Connect (OSTI)

Fatty liver is an early stage of alcoholic and nonalcoholic liver disease (ALD and NALD) that progresses to steatohepatitis and other irreversible conditions. In this study, we identified proteins that were differentially expressed in the livers of rats fed 5% ethanol in a Lieber–DeCarli diet daily for 1 and 3 months by discovery proteomics (two-dimensional gel electrophoresis and mass spectrometry) and non-parametric modeling (Multivariate Adaptive Regression Splines). Hepatic fatty infiltration was significantly higher in ethanol-fed animals as compared to controls, and more pronounced at 3 months of ethanol feeding. Discovery proteomics identified changes in the expression of proteins involved in alcohol, lipid, and amino acid metabolism after ethanol feeding. At 1 and 3 months, 12 and 15 different proteins were differentially expressed. Of the identified proteins, down regulation of alcohol dehydrogenase (? 1.6) at 1 month and up regulation of aldehyde dehydrogenase (2.1) at 3 months could be a protective/adaptive mechanism against ethanol toxicity. In addition, betaine-homocysteine S-methyltransferase 2 a protein responsible for methionine metabolism and previously implicated in fatty liver development was significantly up regulated (1.4) at ethanol-induced fatty liver stage (1 month) while peroxiredoxin-1 was down regulated (? 1.5) at late fatty liver stage (3 months). Nonparametric analysis of the protein spots yielded fewer proteins and narrowed the list of possible markers and identified D-dopachrome tautomerase (? 1.7, at 3 months) as a possible marker for ethanol-induced early steatohepatitis. The observed differential regulation of proteins have potential to serve as biomarker signature for the detection of steatosis and its progression to steatohepatitis once validated in plasma/serum. -- Graphical abstract: The figure shows the Hierarchial cluster analysis of differentially expressed protein spots obtained after ethanol feeding for 1 (1–3) and 3 (4–6) months. C and E represent pair-fed control and ethanol-fed rats, respectively. Highlights: ? Proteins related to ethanol-induced steatosis and mild steatohepatitis are identified. ? ADH1C and ALDH2 involved in alcohol metabolism are differentially expressed at 1 and 3 months. ? Discovery proteomics identified a group of proteins to serve as potential biomarkers. ? Using nonparametric analysis DDT is identified as a possible marker for liver damage.

Fernando, Harshica [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Wiktorowicz, John E.; Soman, Kizhake V. [Department of Biochemistry and Molecular Biology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Department of Biochemistry and Molecular Biology, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Kaphalia, Bhupendra S.; Khan, M. Firoze [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Shakeel Ansari, G.A., E-mail: sansari@utmb.edu [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)

2013-02-01T23:59:59.000Z

224

Muon Capture in Oxygen-16  

Science Journals Connector (OSTI)

The muon capture rate in oxygen is used as a means for measuring the induced pseudoscalar coupling constant (CP) of weak interactions. The capture rate between the JP=0+ ground state of O16 and the 0-, 1-, 2-, and 3- states of N16 are calculated as a function of CP with different nuclear models. Using the experimental values of the transition rates, we then determine CP. We find that the transition rate, and therefore CP, depends strongly on the nuclear model. We conclude that 5

Vincent Gillet and David A. Jenkins

1965-10-11T23:59:59.000Z

225

Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis – 2012 Progress Report  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory has been conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). In recent years, this research has primarily involved the further development of catalysts containing rhodium and manganese based on the results of earlier catalyst screening tests. Testing continued in FY 2012 to further improve the Ir-promoted RhMn catalysts on both silica and carbon supports for producing mixed oxygenates from synthesis gas. This testing re-examined selected alternative silica and carbon supports to follow up on some uncertainties in the results with previous test results. Additional tests were conducted to further optimize the total and relative concentrations of Rh, Mn, and Ir, and to examine selected promoters and promoter combinations based on earlier results. To establish optimum operating conditions, the effects of the process pressure and the feed gas composition also were evaluated.

Gerber, Mark A.; Gray, Michel J.; Albrecht, Karl O.; Thompson, Becky L.

2012-11-01T23:59:59.000Z

226

Extent of Alcohol Consumption among Adult Survivors of Childhood Cancer: The British Childhood Cancer Survivor Study  

Science Journals Connector (OSTI)

...4). Alcohol consumption could exacerbate...6). Alcohol consumption has been investigated...brew or make at home? Current alcohol...estimate their average weekly consumption in units (1 unit...health, pain, and energy/vitality. Using...

Clare Frobisher; Emma R. Lancashire; Raoul C. Reulen; David L. Winter; Michael C.G. Stevens; and Michael M. Hawkins

2010-05-01T23:59:59.000Z

227

Direct hydro-liquefaction of sawdust in petroleum ether and comprehensive bio-oil products analysis  

Science Journals Connector (OSTI)

Abstract The effect of temperature, time, hydrogen pressure and amount of catalyst on production distribution and the bio-oil yield obtained from the direct liquefaction of sawdust in the petroleum ether (60–90 °C) are investigated. The highest sawdust conversion obtained was 72.32% with a bio-oil yield of 47.69% were obtained at 370 °C, 40 min and 5wt.% catalyst content with the initial H2 pressure of 3.0 MPa. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approach was utilized to analyze the non-volatile fraction. In this study, the composition of bio-oil could be analyzed in an unprecedented detail through a combination of GC–MS and FT-ICR MS techniques.

Dong Liu; Linhua Song; Pingping Wu; Yan Liu; Qingyin Li; Zifeng Yan

2014-01-01T23:59:59.000Z

228

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents [OSTI]

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, D.; Waller, F.J.

1998-04-28T23:59:59.000Z

229

Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process  

DOE Patents [OSTI]

The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

1998-01-01T23:59:59.000Z

230

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents [OSTI]

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, Dorai (Allentown, PA); Waller, Francis Joseph (Allentown, PA)

1998-01-01T23:59:59.000Z

231

Using Heteropolyacids in the Anode Catalyst Layer of Dimethyl Ether PEM Fuel Cells  

SciTech Connect (OSTI)

In this study, polarization experiments were performed on a direct dimethyl ether fuel cell (DMEFC). The experimental setup allowed for independent control of water and DME flow rates. Thus the DME flow rate, backpressure, and water flow rate were optimized. Three heteropoly acids, phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and silicotungstic acid (STA) were incorporated into the anode catalyst layer in combination with Pt/C. Both PTA-Pt and STA-Pt showed higher performance than the Pt control at 30 psig of backpressure. Anodic polarizations were also performed, and Tafel slopes were extracted from the data. The trends in the Tafel slope values are in agreement with the polarization data. The addition of phosphotungstic acid more than doubled the power density of the fuel cell, compared to the Pt control.

Ferrell III, J. R.; Turner, J. A.; Herring, A. M.

2008-01-01T23:59:59.000Z

232

Quantification of Fuel Oxygenate Ethers in Human Blood using Solid-Phase Microextraction Coupled with Gas Chromatography-High-Resolution Mass Spectrometry  

Science Journals Connector (OSTI)

......which performsautomatedsample heating, SPME extraction, and GC injection...fibers were preconditioned by heating at 250~ for 2 h. Fuel oxy...accurate, the high purchase price of the HRMSand the high cost...Information Administration, Office of Oil and Gas. Petroleum Supply Monthly......

Lalith K. Silva; Clayton R. Wilburn; Michael A. Bonin; Mitchell M. Smith; Katherine A. Reese; David L. Ashley; Benjamin C. Blount

2008-05-01T23:59:59.000Z

233

Stress, Risk Taking, Alcohol/Drugs, and Parents as Partners  

E-Print Network [OSTI]

college � Particular Interests Alcohol and other drug abuse Prescription stimulant abuse Marijuana, bronchitis, Strep throat 9.0% Internet use/computer games 17.3% Finances 8.9% Depression 16.3% Alcohol use 8 other students are doing #12;Parents Still Matter! � In adolescents and young adults, shift

Stowell, Michael

234

Division of Human Resources Alcohol & Drug Testing (CDL)  

E-Print Network [OSTI]

Division of Human Resources Alcohol & Drug Testing (CDL) Summary of Program Responsibilities Employee Relations/Alcohol & Drug Testing (CDL) Questions: (813) 974-2970 Rev. 12/2008 · Report for duty for eight hours following an accident or until undergoing a post-accident test. · Report for duty or remain

Meyers, Steven D.

235

Performance and Emissions of a Compression Ignition Engine Fueled with Diesel/Oxygenate Blends for Various Fuel Delivery Advance Angles  

Science Journals Connector (OSTI)

State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an, People's Republic of China ... In the application of pure oxygenated fuels, Fleisch et al.,1 Kapus and Ofner,2 and Sorenson and Mikkelsen3 have studied dimethyl ether (DME) in a modified diesel engine, and their results showed that the engine could achieve ultralow-emission prospects without a fundamental change in combustion systems. ... Although some previous work has revealed the characteristics of diesel/ethanol blends in a compression ignition engine (Satge de Caro et al.,14 Ali et al.15), there, however, is still much work that needs to be done in regard to the application of diesel/methanol blends in compression ignition engines, especially in clarifying the basic combustion and emission. ...

Zuohua Huang; Hongbing Lu; Deming Jiang; Ke Zeng; Bing Liu; Junqiang Zhang; Xibin Wang

2005-02-02T23:59:59.000Z

236

E-Print Network 3.0 - alcohol consumption city Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: alcohol consumption city Page: << < 1 2 3 4 5 > >> 1 Dublin City University Student Alcohol Policy...

237

E-Print Network 3.0 - alcohol restrictions reduse Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Events, or Groups had age restrictions.9 Alcohol companies... on Metro trains and buses, there are no restrictions on the placement of alcohol ads on...

238

E-Print Network 3.0 - aliphatic alcohols studies Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alcohols studies Search Powered by Explorit Topic List Advanced Search Sample search results for: aliphatic alcohols studies Page: << < 1 2 3 4 5 > >> 1 Journal of Electron...

239

E-Print Network 3.0 - alcohol synthesis catalysts Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

synthesized catalysts for alcohol synthesis. We focus on structural... the use of biogas to create alcohol for ... Source: Dunin-Borkowski, Rafal E. - Department of Materials...

240

E-Print Network 3.0 - alcohols quarterly technical Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Denmark, Fysikvej, Building 307, DK-2800 Lyngby, Denmark. The development... the use of biogas to create alcohol for fuel. Higher alcohols are favorable due to their high energy...

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - alcohol drinking study Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Costs of the Problem >20% of Americans drink at levels that exceed... billion annually in lost productivity, absenteeism 12;What Are Alcoholism and Problem Drinking? Alcoholic......

242

E-Print Network 3.0 - alcohol dependent patients Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

memory deficits and executive dysfunctions in alcoholic Summary: , according to the DSM IV criteria of alcohol dependence (American ). Patients had no history of other...

243

E-Print Network 3.0 - alcohol abuse model Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Alcoholism Risk in Different Ethnic Groups Summary: ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal... ...

244

E-Print Network 3.0 - alcohol abusing runaway Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Alcoholism Risk in Different Ethnic Groups Summary: ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal... ...

245

E-Print Network 3.0 - alcohol dependence implicates Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

million individuals meet criteria for alcohol abuse or dependence... , according to the DSM IV criteria of alcohol dependence ... Source: Ecole Polytechnique, Centre de...

246

E-Print Network 3.0 - alcohol dependence severity Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alcohol dependence, drug addiction, craving, consumption (BMI... ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal......

247

E-Print Network 3.0 - alcohol abuse associations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Alcoholism Risk in Different Ethnic Groups Summary: ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal......

248

E-Print Network 3.0 - alcohol abuse Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Alcoholism Risk in Different Ethnic Groups Summary: ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal... ...

249

E-Print Network 3.0 - alcohol dependence patients Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

memory deficits and executive dysfunctions in alcoholic Summary: , according to the DSM IV criteria of alcohol dependence (American ). Patients had no history of other...

250

E-Print Network 3.0 - alcohol dependence evidence Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alcohol dependence, drug addiction, craving, consumption (BMI... ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal......

251

E-Print Network 3.0 - alcohol exposure related Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of thousands of alcohol-related... , Gordon, R, Hastings, G, "Impact of Alcohol Advertising and Media Exposure on ... Source: Yorke, James - Institute for Physical Science and...

252

E-Print Network 3.0 - alcohol drinking Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Mathematics ; Engineering 10 brainfunction How Much Alcohol Summary: alcohol level can continue to rise after the person has stopped drinking, she should be...

253

E-Print Network 3.0 - alcohol drinking individuals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

higher blood alcohol levels than heavier individuals, and are at higher risk... alcohol level can continue to rise after the person has stopped drinking, she should be...

254

E-Print Network 3.0 - alcohol drinking behaviors Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Physics ; Materials Science 3 brainfunction How Much Alcohol Summary: alcohol level can continue to rise after the person has stopped drinking, she should be...

255

E-Print Network 3.0 - amino propargylic alcohols Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and aryl propargyl alcohols7 using our rhenium-catalyzed propargylic substitu- tion reaction.5 Avoiding... ) to propargylic alcohol 4 ... Source: Holman, Theodore -...

256

E-Print Network 3.0 - alcohol pendant groups Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pendant groups Search Powered by Explorit Topic List Advanced Search Sample search results for: alcohol pendant groups Page: << < 1 2 3 4 5 > >> 1 Alcohol Use Policy The...

257

Device and method for separating oxygen isotopes  

DOE Patents [OSTI]

A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

258

A survey of alternative oxygen production technologies  

Science Journals Connector (OSTI)

Utilization of the Martian atmosphere for the production of fuel and oxygen has been extensively studied. The baseline fuel production process is a Sabatier reactor which produces methane and water from carbon dioxide and hydrogen. The oxygen produced from the electrolysis of the water is only half of that needed for methane-based rocket propellant and additional oxygen is needed for breathing air fuel cells and other energy sources. Zirconia electrolysis cells for the direct reduction of CO 2 are being developed as an alternative means of producing oxygen but present many challenges for a large-scale oxygen production system. The very high operating temperatures and fragile nature of the cells coupled with fairly high operating voltages leave room for improvement. This paper will survey alternative oxygen production technologies present data on operating characteristics materials of construction and some preliminary laboratory results on attempts to implement each.

Dale E. Lueck; Clyde F. Parrish; William J. Buttner; Jan M. Surma

2001-01-01T23:59:59.000Z

259

Drug-Alcohol Flush Reaction and Breath Acetaldehyde Concentration: No Interference with an Infrared Breath Alcohol Analyzer  

Science Journals Connector (OSTI)

......absorptiometry and absorbs IR energy at a wavelength...lntoxilyzerdevice were, on the average, less than those...00 mg/L the average Intoxilyzer readings...defense against over-consumption of alcohol. The...References 1. Home Office Report on...crease alcohol consumption. New Eng/. J......

A.W. Jones

1986-01-01T23:59:59.000Z

260

Oxygen penetration into the bulk of palladium  

Science Journals Connector (OSTI)

Oxygen penetration into the bulk of palladium ... During heating, the reaction rate exhibited an activity maximum at 650 K, whereas no activity maximum was found during the ... ...

C. T. Campbell; D. C. Foyt; J. M. White

1977-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Oxygen-Enriched Combustion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency. PROCESS HEATING...

262

Renewable Oxygenate Blending Effects on Gasoline Properties  

Science Journals Connector (OSTI)

Renewable Oxygenate Blending Effects on Gasoline Properties ... National Renewable Energy Laboratory, Golden, Colorado 80401, United States ... Energy Fuels, 2011, 25 (10), ...

Earl Christensen; Janet Yanowitz; Matthew Ratcliff; Robert L. McCormick

2011-08-16T23:59:59.000Z

263

Oxygen Concentration Microgradients for Cell Culture.  

E-Print Network [OSTI]

??There is a growing need for technology that can control microscale oxygen gradients onto a tissue or culture sample in vitro. This dissertation introduces the… (more)

Park, Jaehyun

2010-01-01T23:59:59.000Z

264

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

Tsuo, Y.S.

1991-08-20T23:59:59.000Z

265

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

Tsuo, Y. Simon (Lakewood, CO)

1991-01-01T23:59:59.000Z

266

Direct Observation of the Oxygenated Species during Oxygen Reduction on a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell cathode. The performance of polymer-electrolyte-membrane (PEM) fuel cells is limited by the reduction at the cathode of various oxygenated intermediates in the four-electron pathway of the oxygen reduction reaction. A research team led by SLAC scientists performed x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode

267

Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system  

E-Print Network [OSTI]

Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

Low, Clarke Alan

2008-01-01T23:59:59.000Z

268

Sulfobutyl Ether b-Cyclodextrin (SBE-b-CD) in Eyedrops Improves the Tolerability of a Topically Applied Pilocarpine Prodrug in Rabbits  

E-Print Network [OSTI]

The effects of a novel, modified ?-cyclodextrin (SBE4-?-CD; a variably substituted sulfobutyl ether with an average degree of substitution of four) on eye irritation and miotic response of an ophthalmically applied pilocarpine ...

Stella, Valentino J.; Jä rvinen, Tomi; Jä rvinen, Kristina; Thompson, Diame; Urtti, Arto

1995-01-01T23:59:59.000Z

269

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen  

E-Print Network [OSTI]

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

Sibener, Steven

270

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

271

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1997-01-01T23:59:59.000Z

272

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1996-01-01T23:59:59.000Z

273

Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran with molecular oxygen in the presence of N-hydroxyphthalimide  

Science Journals Connector (OSTI)

Abstract Catalytic system Cu(NO3)2/NHPI can be successfully used for the mild oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran with molecular oxygen. The oxidation reaction takes place at 50 °C and 1 atm O2 and selectively converts the primary hydroxymethyl group of HMF to the aldehyde one. The selective formation of aromatic aldehyde is observed because of the higher rate of hydrogen abstraction from primary alcohols by the phthalimide-N-oxyl radical, as compared to the rate of the hydrogen abstraction from the aldehydes.

M.O. Kompanets; O.V. Kushch; Yu.E. Litvinov; O.L. Pliekhov; K.V. Novikova; A.O. Novokhatko; A.N. Shendrik; A.V. Vasilyev; I.O. Opeida

2014-01-01T23:59:59.000Z

274

Singlet oxygen luminescence detection with a fibre-coupled superconducting  

E-Print Network [OSTI]

Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single Triplet State Singlet State 1O2 Ground State Oxygen 3O2 Singlet oxygen Free space singlet oxygen luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector

Greenaway, Alan

275

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

276

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

277

Disintegration of Charged Liquid Jets: Results with Isopropyl Alcohol  

Science Journals Connector (OSTI)

...Disintegration of Charged Liquid Jets: Results with Isopropyl Alcohol 10.1126/science.168.3927.118 A. L. Huebner Rocketdyne Division of North American Rockwaell Corporation 6633 Canogoa A venue, Canoga Park, Colifornia 91304 Disintegration processes...

A. L. Huebner

1970-04-03T23:59:59.000Z

278

Zymomonas mobilis Mutants with an Increased Rate of Alcohol Production  

Science Journals Connector (OSTI)

...University of Florida, Gainesville, Florida 32611 Received...retention of higher rates of ethanol production...beverages and fuel, variations...maintenance of higher rates of glycolysis...Department of Energy, Office of...Agriculture, Alcohol Fuels Program. We...

Y. A. Osman; L. O. Ingram

1987-07-01T23:59:59.000Z

279

Detection of Physiologically Relevant Alcohol Concentrations Using Raman Spectroscopy  

E-Print Network [OSTI]

This is the first step in a series of studies to test the feasibility of using Raman Spectroscopy (RS) to non-invasively detect physiologically relevant blood alcohol concentrations. Blood tests, urine tests, and the breathalyzer are currently...

McKay, Joshua L.

2006-08-16T23:59:59.000Z

280

The effects of alcohol and aspirin on neonatal brain development  

E-Print Network [OSTI]

solution that contained no alcohol. Body weights were measured daily, and forebrain, cerebellum, and brainstem weights were measured on PD 9. Forebrain, cerebellum, and brainstem weight to body weight ratios were calculated, and a significant effect...

Beshear, Myra Dawn

2013-02-22T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)  

E-Print Network [OSTI]

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

Levin, Lisa

282

Patterns of role-impairment among alcoholic workers  

E-Print Network [OSTI]

behavior of alcoholic workers. Five dimensions of work behavior were examined with respect to possible modes of role impairment: work efficiency; absenteeism; cover-up practices; job turn-over; and. lost-time accident rates. The data were obtained from... in general No relationship between alcoholism and lost- time accidents was found. Three factors which may explain the low rate of accidents among problem drinkers were identified: (l) most respondents reported that there was little possibility of having...

Goldstein, Carolyn Lesley Klein

2012-06-07T23:59:59.000Z

283

Alcohol effects on navigational ability using ship handling simulator  

Science Journals Connector (OSTI)

In this paper, to examine the drinking status of officers on board multiple choice questionnaires were circularized under instruction and surveyed for 118 officers. Also, with a ship handling simulator, the effect of alcohol on maritime navigational performance is studied for the three blood alcohol concentrations (BACs) levels (0.0%, 0.05% and 0.08%). The eight participants were volunteer deck officer cadets in their senior year, at least 22 years of age, with previous experience on a bridge simulator. Additional experiments were done on maritime pilots. For baseline and performance trials, participants were randomized to one of four bridge simulator scenarios according to the current and the direction of the wind. In order to study the effects of alcohol on maritime navigational ability, (1) bio-signals using electrocardiogram (ECG), (2) performance using a simulator, and (3) mental workload using NASA-TLX were measured. As a result, this study found that alcohol intake significantly impairs the physical and mental ability of the ship operator. In particular, alcohol intake was found to have a direct correlation with changes in bio-signals such as heart rate not to mention simulator performance. In addition, alcohol intake increased mental workload according to the subjective mental workload evaluation undertaken by the test subject. The result of the analysis in this study includes the limited quantitative measure of the effects of alcohol, which is a major cause of operator fatigue. Relevance to Industry The alcohol effects on navigational ability and the frequency of drunken navigation are one of important interests in the maritime industry.

Hongtae Kim; Chan-Su Yang; Bong-Wang Lee; Young-Hoon Yang; Seoungkweon Hong

2007-01-01T23:59:59.000Z

284

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

285

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Natural Ores as Oxygen Carriers in Chemical Looping Combustion ... Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. ...

Hanjing Tian; Ranjani Siriwardane; Thomas Simonyi; James Poston

2013-01-02T23:59:59.000Z

286

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

287

Blood oxygen transport and depletion : the key of consummate divers  

E-Print Network [OSTI]

and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

Meir, Jessica Ulrika

2009-01-01T23:59:59.000Z

288

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

289

Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF  

E-Print Network [OSTI]

neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

2010-01-01T23:59:59.000Z

290

Long-term oxygen sensor implantation in the porcine subcutaneous environment  

E-Print Network [OSTI]

Membrane-­?Covered  Oxygen  Electrode.   Analytical  Microvascular  and  tissue  oxygen   distribution.  vitro  stability  of  an  oxygen  sensor.   Anal  Chem,  

Kumosa, Lucas Stefan

2011-01-01T23:59:59.000Z

291

On the maximum value of the cosmic abundance of oxygen and the oxygen yield  

E-Print Network [OSTI]

We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2007-01-11T23:59:59.000Z

292

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

293

Density Functional Theory Study of Oxygen Reduction Activity...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Abstract: The...

294

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL...

295

Testing Oxygen Reduction Reaction Activity with the Rotating...  

Broader source: Energy.gov (indexed) [DOE]

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

296

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

297

Oxygen detected in atmosphere of Saturn's moon Dione  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

298

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

299

Effects of Oxygen-Containing Functional Groups on Supercapacitor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular dynamics (MD)...

300

Isolation, Characterization of an Intermediate in an Oxygen Atom...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Direct Measurement of Oxygen Incorporation into Thin Film Oxides...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

302

Oxygen Transport Studies in Nanocrystalline Ceria Films. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transport Studies in Nanocrystalline Ceria Films. Oxygen Transport Studies in Nanocrystalline Ceria Films. Abstract: Oxygen uptake and conductivity were measured by nuclear...

303

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...

304

Density Functional Study of the Structure, Stability and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

305

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

306

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

307

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

308

LED–LED portable oxygen gas sensor  

Science Journals Connector (OSTI)

A portable instrument for oxygen determination, based on the quenching of phosphorescent octaethylporphyrin by gaseous O2..., has been developed using the fluorimetric paired emitter–detector diode technique (FPE...

I. M. Perez de Vargas-Sansalvador; C. Fay…

2012-12-01T23:59:59.000Z

309

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

310

Electron-impact excitation of neutral oxygen  

E-Print Network [OSTI]

Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

P. S. Barklem

2006-09-25T23:59:59.000Z

311

Design optimization of oxygenated fluid pump  

E-Print Network [OSTI]

In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

Piazzarolo, Bruno Aiala

2012-01-01T23:59:59.000Z

312

Interactions of oxygen with Zr(0001)  

SciTech Connect (OSTI)

Interaction of oxygen with Zr(0001) have been studied using low energy electron diffraction (LEED), work function ([Delta][phi]), static and dynamic secondary ion mass spectrometry (SSIMS, DSIMS), thermal desorption spectroscopy (TDS), Auger electron spectroscopy (AES) and nuclear reaction analysis (NRA). The initial sticking coefficient of oxygen is close to unity up to [approximately]0.75 ML at 90, 293 and 473 K. Oxygen chemisorption is disordered at room temperature and below. Heating the disordered surface to [approximately]473 K causes all oxygen to move to subsurface sites. A (1x2) ordered oxygen underlayer is formed consisting of three rotated domains of (1x2) superstructure with the oxygen atoms located between the first and second planes of zirconium atoms. This structure is stable up to about 573 K, above which temperature oxygen diffuses into the bulk. AES measurements employing oxide and metal signals were used to model the growth of oxide which was found to be temperature dependent. Both NRA and AES indicate linear oxygen uptake kinetics at 90 K with abrupt passivation as the limiting thickness is reached. SSIMS ion yield data taken during the oxidation of Zr(0001) at 90, 293 and 473 K was interpretable in the context of the oxygen coverage. Dissolution into the bulk of the saturated oxide layer grown at 90 K appears to occur by an island-type mechanism rather than layer-by-layer dissolution from the oxide-metal interface. Large [Delta][phi] changes that occur upon oxidation at 90 K and temperature ramping of the saturated oxide to 300 K are attributable to reversible molecular oxygen adsorption on the oxide. The diffusion of oxygen normal to the [0001] plane of zirconium has been measured by AES: D[sub 0] = (4.14.[+-]1.92) x 10[sup [minus]2] cm[sup [minus]2] s[sup [minus]1] and E[sub a]= 199.1 [+-]2.6 kJ mol[sup [minus]1]. The fundamental vibrational frequency for the [alpha]-Zr lattice was calculated to be (6.3 [+-] 2.9) x 10[sup 13]s[sup [minus]1].

Flinn, B.J.

1992-01-01T23:59:59.000Z

313

Oxy-combustion: Oxygen Transport Membrane Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion: Oxygen Transport combustion: Oxygen Transport Membrane Development Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D

314

Ethoxyresorufin O-deethylase induction of polychlorinated diphenyl ethers in H4IIE cells  

SciTech Connect (OSTI)

The ethoxyresorufin O-deethylase (EROD) induction potencies of 29 polychlorinated diphenyl ethers were determined in the rat hepatoma H4IIE cell bioassay and compared with that of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Two polychlorinated biphenyls (PCBs) were included as additional reference substances. PCDE congeners tested were PCDEs 47, 66, 77, 85, 99, 105, 118, 126, 128, 137, 138, 140, 147, 153, 154, 156, 157, 167, 170, 180, 181, 182, 190, 194, 195, 196, 197, 203 and 206. The purity of these congeners was > 99%. Because several of these congeners induced EROD activity when tested at high concentrations, the amount of PCDD and PCDF impurities of these active PCDEs was determined by gas chromatography/mass spectrometry. The activity of the active PCDEs was concluded to be mainly due to contamination with 2,3,7,8-chloro substituted PCDFS, because after an additional clean-up on a Florisil column, which removes PCDDs and PCDFs, only three PCDEs (156, 180, 194) remained active. The potencies of PCDEs 156, 180 and 194 (TEF {approximately} 10{sup {minus}6}), however, were about 100-fold less than that of PCB 77 (TEF {approximately} 10{sup {minus}4}). The poor induction potencies of the non- and mono-ortho-PCDEs indicates that PCDEs do not have structure-activity relationships analogous to those of PCBs. If the authors use EROD inducing potency in H4IIE cells as a relative measure of potential Ah receptor-mediated toxic potency, the PCDEs in the study would be expected to be less toxic than analogous PCBs and considerably less-toxic than certain PCDDs and PCDFs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaskyla (Finland)

1995-12-31T23:59:59.000Z

315

The lightness of being: mass, ether, and unification of the forces  

SciTech Connect (OSTI)

How can an electron be both a wave and a particle? At the same time? Because it is a quantum field. That key insight seems to be underappreciated, given the awe and mysticism that permeate most nontechnical discussions of modern physics. Perhaps the root of the problem is that most popularizations of quantum mechanics and of particle physics shy away from quantized fields, the natural language for microscopic phenomena. In 'The Lightness of Being: Mass, Ether, and the Unification of Forces', Frank Wilczek confronts quantum field theory head on, demystifying not only wave-particle duality but also the origin of mass for hadrons (that is, everyday matter). Wilczek is the Herman Feshbach Professor of Physics at MIT and a co-recipient of the 2004 Nobel Prize in Physics. His research has spanned almost all aspects of theoretical particle physics, with significant forays into condensed-matter physics and dense nuclear matter (condensed quark matter, one might say). Recurring themes are the richness of quantum chromodynamics (QCD) and the alluring ideas of unification. His breadth and depth make him a sought after speaker for colloquia and public lectures. Wilczek also contributes an occasional Reference Frame column to 'Physics Today'. The material in 'The Lightness of Being' reflects the scope of the author's research. The book consists of three parts: the quantum fields of QCD (the ether that makes mass), gravitation (the ether that feels mass), and unification. Part 1, which traces notions of mass from Isaac Newton's time through theoretical and computational results of the past 40 years, is the most substantial and original; it is rich, modern, and rooted in observed phenomena. Part 2 continues in the same vein as it connects gravity, also an observed phenomenon, to QCD. Part 3 is more conventional, for a popularization of particle physics, in its focus on speculative ideas that (still) await direct experimental tests. Readers of 'Physics Today' will know that Wilczek can write with wit, grace, and an uncanny facility for using lightweight language to express heavy-duty ideas. They will find much of that kind of writing in 'The Lightness of Being'. Wilczek addresses subtle ideas with vim and vigor. He avoids some of the jargon of quantum field theory; for example, he calls the vertex in a Feynman diagram a hub. In more ambitious terminology, he refers to space-filling, everfluctuating quantum fields--be they electrons, quarks, gluons, or gravity--as 'the Grid'. The term is supposed to be short and familiar, evoking the ubiquitous electric grid (and soon-to-beubiquitous computing grid). It also, for the expert, cleverly alludes to lattice gauge theory. Indeed, after vividly explaining how the dynamics of QCD and the constraints of Heisenberg uncertainty conspire to create mass from the Grid, Wilczek emphasizes that the picture is backed by lattice QCD computations of 'heroic' proportions. Unfortunately, too much of 'The Lightness' is laden with clunky affectation: silly names (a pulsed electron accelerator is called the 'ultrastroboscopic nanomicroscope'), sophomoric jokes ('hadron' is 'not a typo'), references to pop culture (Wilczek might have called quantum fields 'the Matrix, but the sequels tarnished that candidate'), and many pointless footnotes. In a public lecture the audience may guffaw at such jokes, but on the printed page they fall flat. Wilczek explains physics so well that the inappropriate humor is the biggest unexplained puzzle of the book. It is fine to be silly, even crude, as long as the reader's path to understanding is made easier. A joke can inform with an unexpected perspective or simply give the mind a pause to refresh. Some of the humor achieves such aims, but too many gags impede the pace of the otherwise fine exposition. Three appendices, a glossary, and a set of endnotes are crisp and sober. They are excellent. 'The Lightness of Being' is not unbearable, but it is weighed down with too much clutter to rank as a masterpiece. It's a pity: Wilczek's best writing--some of it in this book--is l

Kronfeld, Andreas S.

2009-03-01T23:59:59.000Z

316

Underground coal gasification using oxygen and steam  

SciTech Connect (OSTI)

In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

2009-07-01T23:59:59.000Z

317

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

318

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

319

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

320

Oxygen generator for medical applications (USIC)  

SciTech Connect (OSTI)

The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

Staiger, C. L.

2012-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Geothermal source potential and utilization for alcohol production  

SciTech Connect (OSTI)

A study was conducted to assess the technical and economic feasibility of using a potential geothermal source to drive a fuel grade alcohol plant. Test data from the well at the site indicated that the water temperature at approximately 8500 feet should approach 275/sup 0/F. However, no flow data was available, and so the volume of hot water that can be expected from a well at this site is unknown. Using the available data, numerous fuel alcohol production processes and various heat utilization schemes were investigated to determine the most cost effective system for using the geothermal resource. The study found the direct application of hot water for alcohol production based on atmospheric processes using low pressure steam to be most cost effective. The geothermal flow rates were determined for various sizes of alcohol production facility using 275/sup 0/F water, 235/sup 0/F maximum processing temperature, 31,000 and 53,000 Btu per gallon energy requirements, and appropriate process approach temperatures. It was determined that a 3 million gpy alcohol plant is the largest facility that can practically be powered by the flow from one large geothermal well. An order-of-magnitude cost estimate was prepared, operating costs were calculated, the economic feasibility of the propsed project was examined, and a sensitivity analysis was performed.

Austin, J.C.

1981-11-01T23:59:59.000Z

322

Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report  

SciTech Connect (OSTI)

This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation Calvin–Benson–Bassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide into complex cellular molecules using the energy from hydrogen. In this research project, engineered strains of R. eutropha redirected the excess carbon from PHB storage into the production of isobutanol and 3-methyl-1-butanol (branched-chain higher alcohols). These branched-chain higher alcohols can be used directly as substitutes for fossil-based fuels and are seen as alternative biofuels to ethanol and biodiesel. Importantly, these alcohols have approximately 98 % of the energy content of gasoline, 17 % higher than the current gasoline additive ethanol, without impacting corn market production for feed or food. Unlike ethanol, these branched-chain alcohols have low vapor pressure, hygroscopicity, and water solubility, which make them readily compatible with the existing pipelines, gasoline pumps, and engines in our transportation infrastructure. While the use of alternative energies from solar, wind, geothermal, and hydroelectric has spread for stationary power applications, these energy sources cannot be effectively or efficiently employed in current or future transportation systems. With the ongoing concerns of fossil fuel availability and price stability over the long term, alternative biofuels like branched-chain higher alcohols hold promise as a suitable transportation fuel in the future. We showed in our research that various mutant strains of R. eutropha with isobutyraldehyde dehydrogenase activity, in combination with the overexpression of plasmid-borne, native branched-chain amino acid biosynthesis pathway genes and the overexpression of heterologous ketoisovalerate decarboxylase gene, would produce isobutanol and 3-methyl-1-butanol when initiated during nitrogen or phosphorus limitation. Early on, we isolated one mutant R. eutropha strain which produced over 180 mg/L branched-chain alcohols in flask culture while being more tolerant of isobutanol toxicity. After the targeted elimination of genes encoding several potential carbon sinks (ilvE, bkdAB, and aceE), the production titer of the improved to 270 mg/L isobutanol and 40 mg/L 3-methyl-1-butanol.

Sinskey, Anthony J. [MIT] [MIT; Worden, Robert Mark [Michigan State University MSU] [Michigan State University MSU; Brigham, Christopher [MIT] [MIT; Lu, Jingnan [MIT] [MIT; Quimby, John Westlake [MIT] [MIT; Gai, Claudia [MIT] [MIT; Speth, Daan [MIT] [MIT; Elliott, Sean [Boston University] [Boston University; Fei, John Qiang [MIT] [MIT; Bernardi, Amanda [MIT] [MIT; Li, Sophia [MIT] [MIT; Grunwald, Stephan [MIT] [MIT; Grousseau, Estelle [MIT] [MIT; Maiti, Soumen [MSU] [MSU; Liu, Chole [MSU] [MSU

2013-12-16T23:59:59.000Z

323

Absorption process for producing oxygen and nitrogen and solution therefor  

DOE Patents [OSTI]

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

Roman, I.C.; Baker, R.W.

1990-09-25T23:59:59.000Z

324

Absorption process for producing oxygen and nitrogen and solution therefor  

DOE Patents [OSTI]

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

Roman, Ian C. [Wilmington, DE; Baker, Richard W. [Palo Alto, CA

1990-09-25T23:59:59.000Z

325

Oxygen Toxicity Calculations by Erik C. Baker, P.E.  

E-Print Network [OSTI]

1 Oxygen Toxicity Calculations by Erik C. Baker, P.E. Management of exposure to oxygen toxicity myself using the good ole' FORTRAN programming language, I found that incorporating oxygen toxicity for others. Background Two oxygen toxicity parameters are typically "tracked" in technical diving

Read, Charles

326

Energetic neutral atoms at Mars 4. Imaging of planetary oxygen  

E-Print Network [OSTI]

Energetic neutral atoms at Mars 4. Imaging of planetary oxygen S. Barabash and M. Holmstro of the Martian oxygen exosphere/corona results in the production of planetary oxygen ions. The newborn ions start. The oxygen ions can then charge exchange with the neutral gases (H, H2, and O) of the Martian exosphere

Lukyanov, Alex

327

Alcohol Consumption and the Risk for Prostate Cancer in the European Prospective Investigation into Cancer and Nutrition  

Science Journals Connector (OSTI)

...Communications Alcohol Consumption and the Risk for...Welfare and Sports; World Cancer Research...association of alcohol consumption at recruitment...and nonalcohol energy intake. Overall, neither alcohol consumption at baseline nor...

Sabine Rohrmann; Jakob Linseisen; Timothy J. Key; Majken K. Jensen; Kim Overvad; Nina Føns Johnsen; Anne Tjønneland; Rudolf Kaaks; Manuela M. Bergmann; Cornelia Weikert; Androniki Naska; Antonia Trichopoulou; Dimitrios Trichopoulos; Valeria Pala; Carlotta Sacerdote; Domenico Palli; Rosario Tumino; H. Bas Bueno-de-Mesquita; Alina Vrieling; Carlos A. González; Nerea Larrañaga; Carmen Navarro; Aurelio Barricarte; J. Ramon Quiros; Carmen Martínez-García; Göran Hallmans; Pär Stattin; Jonas Manjer; Elisabet Wirfält; Sheila Bingham; Key-Tee Khaw; Lars Egevad; Pietro Ferrari; Mazda Jenab; and Elio Riboli

2008-05-01T23:59:59.000Z

328

The effect of alcohol advertising, marketing and portrayal on drinking behaviour in young people: systematic review of prospective cohort studies  

Science Journals Connector (OSTI)

Exposure to alcohol advertising, product placement and portrayal of alcohol use in the media is associated with an increased likelihood of subsequent alcohol consumption among 10 to 26 year olds.

Lesley A Smith; David R Foxcroft

2009-02-06T23:59:59.000Z

329

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-02-01T23:59:59.000Z

330

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

331

On the solar nickel and oxygen abundances  

E-Print Network [OSTI]

Determinations of the solar oxygen content relying on the neutral forbidden transition at 630 nm depend upon the nickel abundance, due to a Ni I blend. Here we rederive the solar nickel abundance, using the same ab initio 3D hydrodynamic model of the solar photosphere employed in the recent revision of the abundances of C, N, O and other elements. Using 17 weak, unblended lines of Ni I together with the most accurate atomic and observational data available we find log epsilon_Ni = 6.17 +/- 0.02 (statistical) +/- 0.05 (systematic), a downwards shift of 0.06 to 0.08 dex relative to previous 1D-based abundances. We investigate the implications of the new nickel abundance for studies of the solar oxygen abundance based on the [O I] 630 nm line in the quiet Sun. Furthermore, we demonstrate that the oxygen abundance implied by the recent sunspot spectropolarimetric study of Centeno & Socas-Navarro needs to be revised downwards from log epsilon_O = 8.86 +/- 0.07 to 8.71 +/- 0.10. This revision is based on the new nickel abundance, application of the best available gf-value for the 630 nm forbidden oxygen line, and a more transparent treatment of CO formation. Determinations of the solar oxygen content relying on forbidden lines now appear to converge around log epsilon_O = 8.7.

Pat Scott; Martin Asplund; Nicolas Grevesse; A. Jacques Sauval

2008-11-05T23:59:59.000Z

332

Oxygen abundance of open cluster dwarfs  

E-Print Network [OSTI]

We present oxygen abundances of dwarfs in the young open cluster IC 4665 deduced from the OI $\\lambda$7774 triplet lines and of dwarfs in the open cluster Pleiades derived from the [OI] $\\lambda$6300 forbidden line. Stellar parameters and oxygen abundances were derived using the spectroscopic synthesis tool SME (Spectroscopy Made Easy). We find a dramatic increase in the upper boundary of the OI triplet abundances with decreasing temperature in the dwarfs of IC 4665, consistent with the trend found by Schuler et al. in the open clusters Pleiades and M 34, and to a less extent in the cool dwarfs of Hyades (Schuler et al. 2006a) and UMa (King & Schuler 2005). By contrast, oxygen abundances derived from the [OI] $\\lambda$6300 forbidden line for stars in Pleiades and Hyades (Schuler et al. 2006b) are constant within the errors. Possible mechanisms that may lead a varying oxygen triplet line abundance are examined, including systematic errors in the stellar parameter determinations, the NLTE effects, surface activities and granulation. The age-related effects stellar surface activities (especially the chromospheric activities) are suggested by our analysis to blame for the large spreads of oxygen triplet line abundances.

Z. -X. Shen; X. -W. Liu; H. -W. Zhang; B. Jones; D. N. C. Lin

2007-03-30T23:59:59.000Z

333

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts  

Science Journals Connector (OSTI)

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts ... Catalytic Reactions on the Open-Edge Sites of Nitrogen-Doped Carbon Nanotubes as Cathode Catalyst for Hydrogen Fuel Cells ... Despite significant progress made the past decade on reducing the platinum catalyst loading in the PEMFC electrodes, further ... ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2011-02-24T23:59:59.000Z

334

Alcohol consumption, Lewis phenotypes, and risk of ischemic heart disease  

SciTech Connect (OSTI)

The authors have previously found an increased risk of ischemic heart disease (IHD) in men with the Lewis phenotype Le(a[minus]b[minus]) and suggested that the Lewis blood group has a close genetic relation with insulin resistance. The authors have investigated whether any conventional risk factors explain the increased risk in Le(a[minus]b[minus]) men. 3,383 men aged 53-75 years were examined in 1985-86, and morbidity and mortality during the next 4 years were recorded. At baseline, the authors excluded 343 men with a history of myocardial infarction, angina pectoris, intermittent claudication, or stroke. The potential risk factors examined were alcohol consumption, physical activity, tobacco smoking, serum cotinine, serum lipids, body-mass index, blood pressure, prevalence of hypertension and non-insulin-dependent diabetes mellitus, and social class. In 280 (9.6%) men with Le(a[minus]b[minus]), alcohol was the only risk factor significantly associated with risk of IHD. There was a significant inverse dose-effect relation between alcohol consumption and risk; trend tests, with adjustment for age, were significant for fatal IHD (p=0.02), all IHD (p=0.03), and all causes of death (p=0.02). In 2649 (90.4%) men with other phenotypes, there was a limited negative association with alcohol consumption. In Le(a[minus]b[minus]) men, a group genetically at high risk of IHD, alcohol consumption seems to be especially protective. The authors suggest that alcohol consumption may modify insulin resistance in Le(a[minus]b[minus]) men.

Hein, H.O.; Suadicani, P.; Gyntelberg, F. (Rigshospitalet State Univ. Hospital, Copenhagen (Denmark). Epidemiological Research Unit); Sorenson, H. (Rigshospitalet State Univ. Hospital, Copenhagen (Denmark). Dept. of Chemical Immunology); Hein, H.O. (Univ. of Copenhagen (Denmark). Dept. of Internal Medicine)

1993-02-13T23:59:59.000Z

335

Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully influence organisms living in near  

E-Print Network [OSTI]

Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully to the winter of 2014. Their scholarly work is presented in this collection. #12;1 Oxygen: From Environment", 2013, 2014 Table of contents Page 2. Laura Lilly - Low-oxygen formation along the California current. 6

336

Photochemical Escape of Oxygen from Early Mars  

E-Print Network [OSTI]

Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

Zhao, Jinjin

2015-01-01T23:59:59.000Z

337

Inelastic neutron scattering from confined molecular oxygen  

Science Journals Connector (OSTI)

Inelastic neutron-scattering measurements were carried out on condensed bulk and confined molecular oxygen. The phase transitions of the oxygen confined in cylindrical pores with diameter of ?94?Å are suppressed below their bulk temperatures or in the case of the lowest-temperature transition to the ? phase are suppressed entirely. This last observation is possibly due to the low latent heat of transition for this transition. Both elastic and inelastic neutron-scattering data indicate a mixing of oxygen crystal phases upon confinement. Magnetic ordering fluctuations in the ? phase are found to have similar energy-dependent profiles for confined and bulk excitations showing that the magnetic correlation function decay is unaffected by the finite crystal size in confinement.

Duncan Kilburn; Paul E. Sokol; Craig M. Brown

2008-12-29T23:59:59.000Z

338

STEP 1: TO BE COMPLETED BY ALCOHOL TECHNICIAN  

Broader source: Energy.gov (indexed) [DOE]

7 (07/03) OMB Control No. 1910-5122 7 (07/03) OMB Control No. 1910-5122 U.S. Department of Energy (DOE) Human Reliability Program (HRP) Alcohol Testing Form (Instructions for completing this form are attached.) STEP 1: TO BE COMPLETED BY ALCOHOL TECHNICIAN A. Employee Name __________________________________________________________________ (Print) First M.I. Last B. Employee ID No. __________________________________________________________ C. Employer Name __________________________________________________________ _____________________________________(____)________________ HRP Supervisor Phone Number D. Reason for Test: Random Reasonable Susp. Post-Accident Return to Duty Follow-up Pre-employment

339

Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether (Triton X-100) Surfactant Mobile Phases in the Thin-Layer Chromatography of Heavy-Metal Cations  

Science Journals Connector (OSTI)

......Article The analytical potential of poly(ethylene glycol) p-isooctyl-phenyl ether...40, March 2002 Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether...Bidlingmeyer, S.N. Deming, W.P. Price, B. Sachok, and M. Petrusek. Retention......

Ali Mohammad; Eram Iraqi; Iftkhar Alam Khan

2002-03-01T23:59:59.000Z

340

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons  

Science Journals Connector (OSTI)

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons ... (1, 3-6) Methanol and derived dimethyl ether (DME) are also excellent fuels in internal combustion engines (ICE) and in a new generation of direct oxidation methanol fuel cells (DMFC), as well as convenient starting materials for producing light olefins (ethylene and propylene) and subsequently practically any derived hydrocarbon product. ... Methanol produced this way was used in the 19th century for lighting, cooking, and heating purposes but was later replaced by cheaper fuels, especially kerosene. ...

George A. Olah; Alain Goeppert; G. K. Surya Prakash

2008-12-08T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Experimental investigation on thermal barrier coated diesel engine fueled with diesel-biodiesel-ethanol-diethyl ether blends  

Science Journals Connector (OSTI)

In the present work diesel-biodiesel-ethanol (DBE) and diesel-biodiesel-diethyl ether (DBD) fuels are tested with normal diesel engine and the diesel engine coated with the layers of aluminum oxide (Al 2O3) of 0.3?mm and yttria-stabilized zirconia of 0.2?mm. The various performance and emission parameters are analyzed and determined. The experimental work was carried out in a single cylinder water cooled engine coupled with eddy current dynamometer. The AVL make five gas analyzer and smoke meter were used to measure the different exhaust pollutants. The result shows that the brake thermal efficiency of coated engine is more than that of base diesel at high loads. The thermal barrier coated engine using fuel as diesel biodiesel and ethanol (TDBE) produces the lowest carbon monoxide (CO) emissions among all the fuels that are selected. In addition it produces the lowest carbon dioxide (CO2) at higher loads. Both the thermal barrier coated engine using fuel as diesel biodiesel and diethyl ether (TDBD) and TDBE have higher NOx emissions among almost all the fuels used. The TDBE and TDBD have higher smoke emissions at initial loads but eventually show lower smoke emissions at higher loads. The thermal barrier coated diesel engine fueled with DBE and DBD shows an increase in engine power and specific fuel consumption as well as significant improvements in exhaust gas emissions except NOx.

2013-01-01T23:59:59.000Z

342

E-Print Network 3.0 - alcohols technical progress Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a pro- found effect on both your personal and your work life. When someone... adults -- abuse alcohol or are alcoholics. Throw in the ... Source: Oliver, Douglas L. - Department of...

343

Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants 2004 Diesel Engine...

344

E-Print Network 3.0 - alcohol outcome expectancies Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Director Center of Alcohol Studies Gail G. Milgram, Ed.D., Professor Emerita Nancy M. Violette, Ph.D., LCSW... to use alcohol, tobacco and other drugs than the general...

345

E-Print Network 3.0 - alcoholic beverage preference Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cocaine, and it is snorted, placed in alcoholic beverages, or smoked in combination with marijuana... Alcohol & Other Drugs How Do I Know If I Have A Drinking Problem? Below ......

346

E-Print Network 3.0 - alcohol chemical tests Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Higher Alcohols using Electron... and better production paths. One of these is using biogas to create alcohol as a fuel. ... Source: Dunin-Borkowski, Rafal E. - Department of...

347

E-Print Network 3.0 - alcohol drinking patterns Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for: alcohol drinking patterns Page: << < 1 2 3 4 5 > >> 1 StraightTalk A guide for parents on teenage drinking Summary: to use alcohol? 14 Why do teenagers drink? 15 What...

348

E-Print Network 3.0 - alcohol hospitalizes dozens Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: for an alcohol related incident, police are NOT notified by the staff of the hospital. Not only... for alcohol related incidents at any of the local hospitals, including...

349

E-Print Network 3.0 - alcohol dependence increases Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Alcohol dependence in Native and Mexican Americans in San... ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National Longitudinal......

350

E-Print Network 3.0 - alcohol survey hablas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Alcoholism Risk in Different Ethnic Groups Cindy L Ehlers... ;12 month prevalence of DSM-IV alcohol abuse and dependence by race-ethnicity from the National ... Source:...

351

E-Print Network 3.0 - alcohol gas additives Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alcohol. In addition, you will not want to use... , methyl gas, hydrogen, carbon dioxide, carbon monoxide, wood alcohol, carbon, water, and a lot of other... if gas storage tanks...

352

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

353

Oxygen control in makeup water for PWRs  

SciTech Connect (OSTI)

This study describes the oxygen control program and improvements to the make-up water system components of PWR nuclear plants with the ultimate goal of reducing corrosion related problems in the steam generators and other secondary system components. A PWR plant that has a vacuum degasifier has been selected to establish the basis for the program. Following the investigation of the make-up water system components, the report presents instrumentation developed for the program. Recommendations are provided for improvements to the various make-up water system components to lower the dissolved oxygen levels. 5 refs., 23 figs., 3 tabs.

Silaghy, F. (Burns and Roe, Inc., Oradell, NJ (USA))

1990-08-01T23:59:59.000Z

354

Alcohol production from various enzyme-converted starches with or without cooking  

SciTech Connect (OSTI)

The effectiveness of alcoholic fermentation was compared by measuring alcoholic yields from various starch mashes, both cooked and uncooked. Alcohol yields from cooked and liquefied starch by bacterial ..cap alpha..-amylase were 93.9% for corn, 92.0% for cassava, 90.6% for potato, and 73.0% for babassu, whereas alcohol yields from raw starch were 90.0% for corn, 89.0% for cassava, 48.9% for babassu, and 11.4% for potato. (JMT)

Park, Y.K.; Rivera, B.C.

1982-02-01T23:59:59.000Z

355

E-Print Network 3.0 - alcohol synthesis cu-co-cr Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Psychopharmacology, Central Institute for Mental Health, D 68159 Mannheim, Germany I. Alcohol Addiction, Genetic... Susceptibility, and Neuroadaptation II. Animal...

356

E-Print Network 3.0 - alcohol synthesis cu-co Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Psychopharmacology, Central Institute for Mental Health, D 68159 Mannheim, Germany I. Alcohol Addiction, Genetic... Susceptibility, and Neuroadaptation II. Animal...

357

E-Print Network 3.0 - alcohol outlet density Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Psychopharmacology, Central Institute for Mental Health, D 68159 Mannheim, Germany I. Alcohol Addiction, Genetic... Susceptibility, and Neuroadaptation II. Animal...

358

Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels  

Broader source: Energy.gov [DOE]

Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

359

Alcohol consumption is controlled by angiotensin II1 BJOERN MAUL,2  

E-Print Network [OSTI]

Alcohol consumption is controlled by angiotensin II1 BJOERN MAUL,2 WOLF-EBERHARD SIEMS, MARGRET R- ther explain the effects in the transgenic mice. PRINCIPAL FINDINGS 1. Alcohol consumption is directly correlated with angiotensin levels To clarify the role of AII in alcohol consumption, we tested

Hoehe, Margret

360

Breast Cancer and Alcohol Consumption: A Case-Control Study in Northern Italy  

Science Journals Connector (OSTI)

...INTRODUCTION Alcohol consumption has been inconsistently...Since alcohol consumption is wide spread among...conducted in the homes of the respondents...following surgery (on average, 7.8 months after...estimating alcohol consumption in European countries...nutrient, and energy values were compiled...

Paolo Toniolo; Elio Riboli; Fulvia Protta; Martine Charrel; and Alberto P. M. Cappa

1989-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

DRD2 Gene Transfer Into the Nucleus Accumbens Core of the Alcohol Preferring and Nonpreferring Rats  

E-Print Network [OSTI]

DRD2 Gene Transfer Into the Nucleus Accumbens Core of the Alcohol Preferring and Nonpreferring Rats in alcohol intake in Sprague Dawley rats. This overexpression of DRD2 reduced alcohol consumption in a two) and -nonpreferring (NP) rats. In addition, micro­positron emission tomography imaging was used at the completion

Homes, Christopher C.

362

Atmospheric Oxygen: Isotopic Composition and Solubility Fractionation  

Science Journals Connector (OSTI)

...where the subscripts aq and gas refer to the aqueous phase and the gas phase, respectively. The single-stage...adsorption and desorp-tion of oxygen gas on type SA molecular sieve...material seems to be debris of the Cyprus-sized planetesimal that produced...

P. Kroopnick; H. Craig

1972-01-07T23:59:59.000Z

363

Oxygen addition to sulfur of metal thiolates  

E-Print Network [OSTI]

, and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

Soma, Takako

2012-06-07T23:59:59.000Z

364

Oxygen Limitation within a Bacterial Aggregate  

Science Journals Connector (OSTI)

...standard deviation of the average of cells exposed to 2...and Doring G. 2002. Effects of reduced mucus oxygen...Lewandowski Z. 1994. Effects of biofilm structures...Dietrich LE , Okegbe C, Price-Whelan A, Sakhtah...capability. Energy Fuels 20 :1565-1571. doi...

Aimee K. Wessel; Talha A. Arshad; Mignon Fitzpatrick; Jodi L. Connell; Roger T. Bonnecaze; Jason B. Shear; Marvin Whiteley

2014-04-01T23:59:59.000Z

365

Oxygen Transport Ceramic Membranes Quarterly Report  

E-Print Network [OSTI]

/Reaction rates in Ion 21 Transport Membranes using Isotope Tracer and Transient Kinetic Techniques CONCLUSIONS 30Oxygen Transport Ceramic Membranes Quarterly Report January 2003 ­ March 2003 Principal Authors on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane

Eagar, Thomas W.

366

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

367

Methods for sequestering carbon dioxide into alcohols via gasification fermentation  

DOE Patents [OSTI]

The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

2013-11-26T23:59:59.000Z

368

Digit switch evaluations and capillary IPA (isopropyl alcohol) study  

SciTech Connect (OSTI)

Capillary flow of isopropyl alcohol under the wire insulation of an eleven-wire cable dissolved trapped flux from the pretinning and soldering operations and caused it to deposit on the circuit board inside a digit switch. Conformal coatings were successful in sealing the wire insulation gap to prevent solvent flow. 16 figs., 2 tabs.

Mizik, P.M.; Kibalo, E.F.

1990-12-01T23:59:59.000Z

369

The University of Mississippi Drug and Alcohol Testing  

E-Print Network [OSTI]

The University of Mississippi Drug and Alcohol Testing Summary/Purpose: In furtherance of the University's interest to maintain a drug-free workplace, the University reserves the right to test any of the University's interest to maintain a drug-free workplace, the University reserves the right to test any

Tchumper, Gregory S.

370

A Stereodivergent Approach to Amino Acids, Amino Alcohols, or  

E-Print Network [OSTI]

of r-amino acids, amino alcohols, or oxazolidinones. The sequence includes the SN2 displacement Society Published on Web 07/08/2004 #12;regioselective and stereospecific SN2 displacement of an allylic as a readily available and recyclable chiral auxiliary for a short sequence of reactions that includes as one

Spino, Claude

371

Impairment of Timing Behavior after Prolonged Alcohol Consumption in Rats  

Science Journals Connector (OSTI)

...and performance of DRL 30 days after alcohol was omitted from the diet. Twenty-four male Sprague-Dawley rats (Carworth CFE strain), 90 days old, were reduced to 85 percent of their body weights (when they were fed freely) and were trained to press...

Don W. Walker; Gerhard Freund

1973-11-09T23:59:59.000Z

372

Oxygen-producing inert anodes for SOM process  

DOE Patents [OSTI]

An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

Pal, Uday B

2014-02-25T23:59:59.000Z

373

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

374

Role of Endocytosis in the Action of Ether Lipids on WEHI-3B, HL60, and FDCP-Mix A4 Cells  

Science Journals Connector (OSTI)

...Lipid by WEHI-3B Cells Has an Energy- dependent and an Energy-independent Component. Uptake...protective agents, suggested that the energy-dependent component of ether...of ET-18-OCH., by FDCP-mix A4 cells was measured, it was...

G. W. Bazill and T. M. Dexter

1990-12-01T23:59:59.000Z

375

Production of Mixed Alcohols from Bio-syngas over Mo-based Catalyst  

Science Journals Connector (OSTI)

A series of Mo-based catalysts prepared by sol-gel method using citric acid as complexant were successfully applied in the high efficient production of mixed alcohols from bio-syngas derived from the biomass gasification. The Cu1Co1Fe1Mo1Zn0.5? 6%K catalyst exhibited a higher activity on the space-time yield of mixed alcohols compared with the other Mo-based catalysts. The carbon conversion significantly increases with rising temperature below 340 °C but the alcohol selectivity has an opposite trend. The maximum mixed alcohols yield derived from biomass gasification is 494.8 g/(kgcatal·h) with the C2+ (C2—C6 higher alcohols) alcohols of 80.4% under the tested conditions. The alcohol distributions are consistent with the Schulz-Flory plots except methanol. In the alcohols products the C2+ alcohols (higher alcohols) dominate with a weight ratio of 70%–85%. The Mo-based catalysts have been characterized by X-ray diffraction and N2 adsorption/desorption. The clean bio-fules of mixed alcohols derived from bio-syngas with higher octane values could be used as transportation fuels or petrol additives.

Song-bai Qiu; Wei-wei Huang; Yong Xu; Lu Liu; Quan-xin Li

2011-01-01T23:59:59.000Z

376

Reactions of 15-crown-5 and bis-15-crown-5 ethers with metal acetylacetonate ions in the gas phase  

SciTech Connect (OSTI)

A study was carried out on the ion-molecule reactions of ions arising in the dissociation of ferric, cobaltic, chromic, manganous, neodymium(II), gallium(III), and indium(III) acetylacetonates upon electron impact with 15-crown-5 and bis-15-crown-5. The ratio of the yields of (acac)x-1 /SUP M+L/ ions is determined by the case of reduction of M /SUP x+1+/ to M /SUP x+/ and for (acac)/sub 3/M complexes, this ratio decreases in the series Nd, In, GA > Cr > Fe, Co. The rate constant for the formation of acacCoL/sup +/ ions is greater than for acacFeL/sup +/ ions. The possibility of fixing transition metals in unstable oxidation states by crown ethers is demonstrated in the case of nickel.

Timofeev, O.S.; Bogatskii, A.V.; Gren, A.I.; Lobach, A.V.; Nekarsov, Y.S.; Zagorevskii, D.V.

1985-05-20T23:59:59.000Z

377

Single-Step Syngas-to-Dimethyl Ether Processes for Optimal Productivity, Minimal Emissions, and Natural Gas-Derived Syngas  

Science Journals Connector (OSTI)

Single-step conversion of synthesis gas (syngas, H2/CO mixture) to dimethyl ether (DME, CH3OCH3) is very attractive as a route for indirect coal liquefaction, natural gas utilization, and production of synthetic liquid fuels, fuel additives, and chemicals. ... The main driving force for developing a single-step syngas-to-DME process is to produce DME at a cost lower than that from the commercially available two-step process, namely, syngas-to-methanol followed by methanol dehydration in sequential reactors. ... Furthermore, the composition of most commercially available syngas (except that produced by a CO2?methane reformer) is not the optimal composition (1:1 H2:CO) for the syngas-to-DME reactor. ...

X. D. Peng; A. W. Wang; B. A. Toseland; P. J. A. Tijm

1999-09-28T23:59:59.000Z

378

The Economics of Oxygen Enriched Air Production Via Membranes  

E-Print Network [OSTI]

Oxygen enriched air combustion is a recognized approach to energy conservation. Conventional methods of producing oxygen enriched air: Pressure Swing Adsorption and Cryogenics, are energy-intensive and expensive. In this paper the economics of using...

Gollan, A.; Kleper, M. H.

1984-01-01T23:59:59.000Z

379

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

380

Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Abstract: In...

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Optimization of Oxygen Purity for Coal Conversion Energy Reduction  

E-Print Network [OSTI]

The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

Baker, C. R.; Pike, R. A.

1982-01-01T23:59:59.000Z

382

Transient Mobility of Oxygen Adatoms upon O2 Dissociation on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transient Mobility of Oxygen Adatoms upon O2 Dissociation on Reduced TiO2 (110). Transient Mobility of Oxygen Adatoms upon O2 Dissociation on Reduced TiO2 (110). Abstract: Tracking...

383

Methane Adsorption and Dissociation and Oxygen Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

384

Inhibitive Influence of Oxygen Vacancies for Photoactivity on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Abstract: Scanning tunneling...

385

Oxygen-induced magnetic properties and metallic behavior of a...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Abstract: In this paper, ab initio...

386

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-10-01T23:59:59.000Z

387

Photosynthesis and the dynamics of oxygen consumption in a ...  

Science Journals Connector (OSTI)

photosynthesis minus oxygen consumption), and gross photosynthesis at high ... The depth distribution of gross photosynthesis, as obtained by the cycling ...

1999-11-15T23:59:59.000Z

388

Oxygen-Enriched Combustion for Military Diesel Engine Generators  

Broader source: Energy.gov [DOE]

Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion

389

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

390

Bridge-bonded atomic oxygen on Pt(110)  

Science Journals Connector (OSTI)

We use hybrid density-functional theory (DFT) and scanning tunneling microscopy (STM) to study oxygen adsorption on the Pt(110) surface. In the STM images oxygen appear as bright protrusions on the ridges of the “missing row” reconstructed surface. DFT calculations of binding energies for atomic oxygen on a bridge site shows a clear preference over hollow sites.

E. Janin; H. von Schenck; M. Göthelid; U. O. Karlsson; M. Svensson

2000-05-15T23:59:59.000Z

391

Oxygen Consumption Rates of Bacteria under Nutrient-Limited Conditions  

Science Journals Connector (OSTI)

...research-article Environmental Microbiology Oxygen Consumption Rates of Bacteria under Nutrient-Limited...heterotrophic bacteria was measured. The oxygen consumption and population density of batch cultures...tracked for up to 200 days. The oxygen consumption per CFU (QO2) declined by more than...

Timothy E. Riedel; William M. Berelson; Kenneth H. Nealson; Steven E. Finkel

2013-06-14T23:59:59.000Z

392

IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS  

E-Print Network [OSTI]

1 IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS Jacek Makinia*, Scott A in a full-scale activated sludge reactor. The Activated Sludge Model No. 1 was used to describe for dissolved oxygen. KEYWORDS Activated sludge; dispersion; dissolved oxygen dynamics; mass transfer

Wells, Scott A.

393

Oceanic oxygen changes as a bellwether of climate change  

E-Print Network [OSTI]

Oceanic oxygen changes as a bellwether of climate change Term paper in Biogeochemistry@ethz.ch] Tutor: Prof. Dr. Nicholas Gruber [nicholas.gruber@env.ethz.ch] Abstract The response of oceanic oxygen of climate change. Recent publications indicate that the oceanic oxygen outgassing is substaintially larger

Fischlin, Andreas

394

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence  

E-Print Network [OSTI]

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear molybdenum chloride clusters. Measurements of the probe operating in a 0%­21% gaseous oxygen environment have

Ghosh, Ruby N.

395

THE OXYGEN REQUIREMENTS OF SHELLFISH By Philip H. Mitchell  

E-Print Network [OSTI]

THE OXYGEN REQUIREMENTS OF SHELLFISH ~ By Philip H. Mitchell 2°7 #12;Blank page retained for pagination #12;THE OXYGEN REQUIREMENTS OF SHELLFISH. By PHILIP H. MITCHELL. J1, The respiratory exchanges to temperature changes, a smaller utili- zation of oxygen in proportion to the body weight with increase in size

396

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

397

E-Print Network 3.0 - acute oxygen sensing Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dissolved oxygen with global warming. In coastal regimes oxygen deficits represent acute ecosystem... Ocean oxygen minima expansions and their biological impacts Lothar Stramma...

398

Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals  

E-Print Network [OSTI]

Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

2006-01-01T23:59:59.000Z

399

OXYGEN REDUCTION WITH CARBON SUPPORTED METALLIC CLUSTER CATALYSTS IN ALKALINE ELECTROLYTE  

E-Print Network [OSTI]

be published in the Proceedings OXYGEN REDUCTION WITH CARBONof California. LBL-11891 Oxygen Reduction with Carbonof Pt interacts with both oxygen and water more strongly

Ross Jr., Philip N.

2013-01-01T23:59:59.000Z

400

Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.  

E-Print Network [OSTI]

Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

Chakraborty, Subrata

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Working Group Meeting Working Group Meeting 11/06/2007 Renewable Hydrogen Production Using Renewable Hydrogen Production Using Sugars and Sugar Alcohols Sugars and Sugar Alcohols * * Problem: Problem: Need Need to develop renewable to develop renewable hydrogen production technologies using hydrogen production technologies using diverse diverse feedstocks feedstocks 10 15 20 CH 4 : C 6 H 14 ln(P) * * Description: Description: The BioForming The BioForming TM TM process uses process uses aqueous phase reforming to cost effectively aqueous phase reforming to cost effectively produce hydrogen from a range of feedstocks, produce hydrogen from a range of feedstocks, including glycerol and sugars. The key including glycerol and sugars. The key breakthrough is a proprietary catalyst that breakthrough is a proprietary catalyst that

402

Alcohol-free alkoxide process for containing nuclear waste  

DOE Patents [OSTI]

Disclosed is a method of containing nuclear waste. A composition is first prepared of about 25 to about 80%, calculated as SiO.sub.2, of a partially hydrolyzed silicon compound, up to about 30%, calculated as metal oxide, of a partially hydrolyzed aluminum or calcium compound, about 5 to about 20%, calculated as metal oxide, of a partially hydrolyzed boron or calcium compound, about 3 to about 25%, calculated as metal oxide, of a partially hydrolyzed sodium, potassium or lithium compound, an alcohol in a weight ratio to hydrolyzed alkoxide of about 1.5 to about 3% and sufficient water to remove at least 99% of the alcohol as an azeotrope. The azeotrope is boiled off and up to about 40%, based on solids in the product, of the nuclear waste, is mixed into the composition. The mixture is evaporated to about 25 to about 45% solids and is melted and cooled.

Pope, James M. (Monroeville, PA); Lahoda, Edward J. (Edgewood, PA)

1984-01-01T23:59:59.000Z

403

Electrocatalyst for alcohol oxidation at fuel cell anodes  

DOE Patents [OSTI]

In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

Adzic, Radoslav (East Setauket, NY); Kowal, Andrzej (Cracow, PL)

2011-11-02T23:59:59.000Z

404

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

405

Production and Use of Alcohol on the Farm.  

E-Print Network [OSTI]

projects. 4. The plant manufacturer should be able to guarantee the following production factors: ? Yield factor (gallons of alcohol produced per unit volume or weight of feedstock at a given dry starch and/or sugar content; for example, gallons per... of Operation Capital recovery (depreciation and interest) $ 90,000 x 0.1598 $125,000 x 0.1598 Insurance (estimated) Property taxes (estimated) Mise. (permits, bonding, ete.) Total Fixed Costs Average Fixed Cost Per Gallon Assumptions: Salvage value...

O'Neal, Henry; Rothe, Joe M.

1981-01-01T23:59:59.000Z

406

Fumigation of alcohol in a light duty automotive diesel engine  

SciTech Connect (OSTI)

A light-duty automotive diesel engine was fumigated with methanol and ethanol in amounts up to 35% and 50% of the total fuel energy respectively. The main purpose of this study was to determine the effect of alcohol (methanol and ethanol) fumigation on engine performance at various operating conditions. Engine fuel efficiency, emissions, smoke, and the occurrence of severe knock were the parameters used to evaluate performance. Raw exhaust particulate and its soluble organic extract were screened for biological activity using the Ames Salmonella typhimurium assay. Results are given for a test matrix made up of twelve steady-state operating conditions. For all conditions except the 1/4 rack (light load) condition, modest thermal efficiency gains were noted upon ethanol fumigation. Methanol showed the same increase at 3/4 and full rack (high load) conditions. However, engine roughness or the occurrence of severe knock limited the maximum amount of alcohol that could be fumigated. Brake specific NO/sub x/ concentrations were found to decrease for all ethanol conditions tested. Oxides of nitrogen emissions, on a volume basis, decreased for all alcohol conditions tested. Based on the limited particulate data analyzed, it appears as though ethanol fumigation, like methanol fumigation, while lowering the mass of particulate emitted, does enhance the biological activity of that particulate.

Broukhiyan, E.M.H.; Lestz, S.S.

1981-08-01T23:59:59.000Z

407

Improving GC-PPC-SAFT equation of state for LLE of hydrocarbons and oxygenated compounds with water  

Science Journals Connector (OSTI)

Abstract The GC-PPC-SAFT model has been shown to be useful for predicting the liquid–liquid phase split with water [Nguyen-Huynh et al. Ind. Eng. Chem. Res. 50 (2011) 7467–7483]. In order to extend the use of this model to oxygenated compounds for a large number of families (aliphatic ethers, aldehydes, ketones, formates, acetates, propionates/butyrates, n-aliphatic acids), it is proposed to consider cross-association in addition to a binary interaction parameter lij on the combining rules for the cross-segment diameter between water and the investigated compound. The binary interaction parameters lij, u ? ? , and w ? ? are fitted on mutual solubilities of water and organic compounds. The regressed values which are obtained for each chemical family, are subsequently used for predicting infinite dilution activity coefficient in water and n-octanol/water partition coefficient. In general, the results obtained are very much improved compared to the predictive approach discussed previously [Nguyen et al. Ind. Eng. Chem. Res. 52 (2013) 7014–7029]. The global deviation values on the decimal log scale for infinite dilution activity coefficient in water, water solubility and n-octanol/water partition coefficient are 0.377, 0.419, and 0.469, respectively.

Thanh-Binh Nguyen; Jean-Charles de Hemptinne; Benoit Creton; Georgios M. Kontogeorgis

2014-01-01T23:59:59.000Z

408

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Presentations, Papers, and Publications Presentations, Papers, and Publications ITM Oxygen Development for Advanced Oxygen Supply (Oct 2011) Ted Foster, Air Products & Chemicals, Inc. presented at the Gasification Technologies Conference, San Francisco, CA Oct 9-12, 2011. ASU/IGCC Integration Strategies (Oct 2009), David McCarthy, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Taking the Next Step (Oct 2009), VanEric Stein, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Scaling Up a Low-Cost Oxygen Supply Technology (Oct 2006) Philip Armstrong, Air Products & Chemicals, Inc., 2006 Gasification Technologies Conference, Washington, D.C. ITM Oxygen: The New Oxygen Supply for the New IGCC Market (Oct 2005)

409

Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters the water by diffusion from air, as a by-product of photosynthesis and  

E-Print Network [OSTI]

Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters and rapids. There is an inverse relationship between temperature and DO, i.e. colder water holds more oxygen it supplies oxygen to aquatic organisms. Higher DO levels also give the water a better taste. Figure 2. During

Tyler, Christy

410

The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries  

SciTech Connect (OSTI)

The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

2014-09-30T23:59:59.000Z

411

Ethynyl terminated ethers. Synthesis and thermal characterization of 2,2 bis (ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl) propane and 2,2 bis (ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl) propane  

Science Journals Connector (OSTI)

Two ethynyl end-capped ethers 2,2 Bis [ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl] propane and 2,2 Bis [ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl] propane have been prepared by a three steps...

Georges Lucotte; Laurent Cormier; Bruno Delfort

1990-12-01T23:59:59.000Z

412

Efficient production of 5-hydroxymethylfurfural through the dehydration of sugars with caprolactam hydrogen sulfate ([CPL]HSO4) ionic liquid catalyst in a water/proprylene glycol monomethyl ether mixed solvent  

Science Journals Connector (OSTI)

Efficient production of 5-hydroxymethylfurfural (HMF) through the dehydration of sugars...4) ionic liquid or using metal halide as the co-catalyst in a new water/proprylene glycol monomethyl ether solvent system....

Pingzhen Huang; Aijuan Gu; Jinxing Wang

2014-04-01T23:59:59.000Z

413

SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION  

SciTech Connect (OSTI)

Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

Timothy L. Ward

2000-06-30T23:59:59.000Z

414

Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator  

DOE Patents [OSTI]

Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

Joshi, Ashok V. (Salt Lake City, UT); Balagopal, Shekar (Sandy, UT); Pendelton, Justin (Salt Lake City, UT)

2011-12-13T23:59:59.000Z

415

Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends  

SciTech Connect (OSTI)

Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

Storey, John Morse [ORNL] [ORNL; Lewis Sr, Samuel Arthur [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL; Barone, Teresa L [ORNL] [ORNL; Eibl, Mary A [ORNL] [ORNL; Nafziger, Eric J [ORNL] [ORNL; Kaul, Brian C [ORNL] [ORNL

2014-01-01T23:59:59.000Z

416

The effect of generalization of extinction on relapse following aversion therapy for alcoholism  

E-Print Network [OSTI]

therapeutic approaches have been taken in the treat- ment of alcoholism, yet low relapse rate continues to be the exception rather than the rule. Hadley and Hadley (1972) surveyed alcoholism treatment in California facilities and encountered the full range... therapy. To summarize: relapse of uncontrolled drinking after treatment continues in spite of numer- ous therapeutic efforts and approaches in the field, and research on alcoholism has been plagued with methodological problems, making conclusions...

Godsey, Robert Lane

2012-06-07T23:59:59.000Z

417

Advances in the design of co-poly(ether-imide) membranes for CO2 separations. Influence of aromatic rigidity on crystallinity, phase segregation and gas transport  

Science Journals Connector (OSTI)

Abstract In our previous works, it was observed a clear relationship between the structure and the properties for different copoly(ether-imide)s, besides a good relation was found between SAXS characterization and permeability results. Here, a series of aliphatic aromatic copoly(ether-imide)s, based on an aromatic diamine (ODA), a diamine terminated poly(ethylene oxide) (PEO2000) of a molecular weight of 2000 g/mol and different aromatic dianhydrides (BPDA, BKDA (or BTDA) and PMDA) has been synthesized and characterized. The permeability for O2, N2, CO2 and CH4, increased with the rigidity of the monomers (BKDA CO2/N2 separation. This work gives indications on how to design advanced materials for this separation with the increasing possibilities of controlled structure and properties.

Alberto Tena; Ángel Marcos-Fernández; Mónica de la Viuda; Laura Palacio; Pedro Prádanos; Ángel E. Lozano; Javier de Abajo; Antonio Hernández

2015-01-01T23:59:59.000Z

418

Foam insulation for a liquid oxygen densifier  

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Analyses indicated that it would not be cost effective to vacuum insulate a 7 foot diameter by 30 foot long liquid nitrogen vessel for a launch facility liquid oxygen densifier. Foam insulation appeared to be the logical choice for this infrequently used ground support equipment but the history of foam problems due to cracking, adhesive failure and internal shearing weighed against the use of commercial spray-on material. These problems were solved with a system consisting of alternate sealing and flexible foam layers: (1) an inner membrane sealed to itself but not attached to the cold shell or pipe; (2) a flexible foam insulation layer; (3) a vapor-tight sealing membrane; (4) a second flexible foam insulation layer and (5) an outer aluminized sealing membrane. The second and subsequent layers are sealed to each underlying layer by flexible foam contact adhesive. The inner sealing membrane is particularly vital in that it allows the first foam layer to expand and contract as the tank temperature changes and it also protects the tank from chloride corrosion from the foam. This paper describes preliminary testing to prove out the system and the steps taken to install flexible foam insulation on the oxygen densifier vessel.

G.E. McIntosh; R. Stuckenschmidt

2012-01-01T23:59:59.000Z

419

Polybrominated Diphenyl Ethers in U.S. Sewage Sludges and Biosolids: Temporal and Geographical Trends and Uptake by Corn Following Land Application  

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Robert C. Hale *, Mark J. La Guardia , Ellen Harvey , Da Chen , Thomas M. Mainor , and Drew R. Luellen , ... An internal standard (decachlorodiphenyl ether) was added and the final extracts were analyzed by gas chromatography/mass spectrometry (GC/MS) with electron-capture negative chemical ionization (EC-NCI). ... This work surveyed PBDE in spruce needles and air (gaseous and particle-bound) over an annual cycle to model PBDE accumulation in vegetation. ...

Robert C. Hale; Mark J. La Guardia; Ellen Harvey; Da Chen; Thomas M. Mainor; Drew R. Luellen; Lakhwinder S. Hundal

2012-01-26T23:59:59.000Z

420

E-Print Network 3.0 - alcohol problem services Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

screen- ing tools. Is Alcohol a Problem for You... : niaaaweb-r@exchange.nih.gov Internet address: ... Source: Lotko, William - Thayer School of Engineering, Dartmouth College...

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
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421

E-Print Network 3.0 - alcohol screening day Sample Search Results  

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At Michigan Tech I. Guiding Principles * Clear evidence exists... that the misuse and abuse of alcoholic beverages and drugs can erode the foundation of the University's ......

422

Alcohol Mixed with Caffeinated Energy Drinks: Consumption Patterns and Trends Among Canadian Youth & Young Adults.  

E-Print Network [OSTI]

??Use of caffeinated energy drinks (CEDs) and alcohol mixed with energy drinks (AmEDs) is a growing trend worldwide, and in Canada, youth and young adults… (more)

McCrory, Cassondra

2015-01-01T23:59:59.000Z

423

Alcohol-Related Harm and Primary Health Care in British Columbia, Canada.  

E-Print Network [OSTI]

???In recent years there has been a renewed focus on reducing the harms of addictive substances such as alcohol while at the same time restraining… (more)

Slaunwhite, Amanda Kathleen

2015-01-01T23:59:59.000Z

424

E-Print Network 3.0 - alcohol expectancies integrating Sample...  

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most... many students: "I especially like the fact that the alcohol project ... Source: Daniel, Susan - Department of Chemistry and Chemical Biology, Cornell University...

425

E-Print Network 3.0 - activity predicts alcohol Sample Search...  

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can start as low as blood alcohol levels ... Source: Kaminsky, Werner - Center for Nanotechnology and NanoTechnology & Department of Chemistry, University of Washington at Seattle...

426

E-Print Network 3.0 - alcoholic beverage consumption Sample Search...  

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consumption Search Powered by Explorit Topic List Advanced Search Sample search results for: alcoholic beverage consumption Page: << < 1 2 3 4 5 > >> 1 University of Nebraska at...

427

E-Print Network 3.0 - alcohol consumption affect Sample Search...  

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consumption affect Search Powered by Explorit Topic List Advanced Search Sample search results for: alcohol consumption affect Page: << < 1 2 3 4 5 > >> 1 Dublin City University...

428

E-Print Network 3.0 - alcohol consumption aggravates Sample Search...  

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Powered by Explorit Topic List Advanced Search Sample search results for: alcohol consumption aggravates Page: << < 1 2 3 4 5 > >> 1 Drug-Free School Statement (Student Policy)...

429

E-Print Network 3.0 - acute alcohol consumption Sample Search...  

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consumption Search Powered by Explorit Topic List Advanced Search Sample search results for: acute alcohol consumption Page: << < 1 2 3 4 5 > >> 1 GENETIC VARIATION AND BRAIN GENE...

430

E-Print Network 3.0 - alcohol consumption disrupted Sample Search...  

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Powered by Explorit Topic List Advanced Search Sample search results for: alcohol consumption disrupted Page: << < 1 2 3 4 5 > >> 1 University of Toronto Governing Council...

431

E-Print Network 3.0 - alcohol consumption meals Sample Search...  

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Powered by Explorit Topic List Advanced Search Sample search results for: alcohol consumption meals Page: << < 1 2 3 4 5 > >> 1 University of Nebraska at Omaha Administrative...

432

E-Print Network 3.0 - alcohol consumption taqib Sample Search...  

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Powered by Explorit Topic List Advanced Search Sample search results for: alcohol consumption taqib Page: << < 1 2 3 4 5 > >> 1 0145-600819912304-059203.0010...

433

E-Print Network 3.0 - alcohol transportation fuels Sample Search...  

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resources demands new... and better production paths. One of these is using biogas to create alcohol as a fuel. Higher... Characterization of Catalysts for Synthesis of...

434

E-Print Network 3.0 - alcohol fuel production Sample Search Results  

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using Electron Microscopy Summary: and better production paths. One of these is using biogas to create alcohol as a fuel. Higher... Characterization of Catalysts for Synthesis of...

435

E-Print Network 3.0 - alcohol fuels Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

using Electron Microscopy Summary: and better production paths. One of these is using biogas to create alcohol as a fuel. Higher... Characterization of Catalysts for Synthesis of...

436

E-Print Network 3.0 - alcohol fuels provisions Sample Search...  

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CA, USA,3 Alcohol and Drug Research, National Institute for Health and Welfare, Helsinki, Finland Source: Stockholm Observatory Collection: Physics 75 DistributorProducer...

437

E-Print Network 3.0 - alcohol dependence schizophrenia Sample...  

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search results for: alcohol dependence schizophrenia Page: << < 1 2 3 4 5 > >> 1 Curriculum Vitae Deanna Marie Barch Summary: , International Congress on Schizophrenia Research...

438

Seminars in Medicine of the Beth Israel Hospital, Boston: Medical Disorders of Alcoholism  

Science Journals Connector (OSTI)

...effects on vitamin A. Although ethanol is rich in energy, long-term consumption of up to 2000 calories per day in the form of alcohol does not produce the expected gain in body weight. This deficit can be attributed, in part, to the poor yield of energy produced from fat oxidation in damaged mitochondria... Alcohol is the most frequently abused drug throughout the world. In the United States, it is consumed regularly by about half the adult population, and about 15 to 20 million people are alcoholics. Alcoholism claims 100,000 lives annually and carries an ...

Lieber C.S.

1995-10-19T23:59:59.000Z

439

E-Print Network 3.0 - alcohol withdrawal delirium Sample Search...  

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ability to control... :www.nlm.nih.govmedlineplussubstanceabuseproblems.html 12;DSM-IV Definitions ALCOHOL ABUSE: episodic problems, no physical symptoms of withdrawal......

440

E-Print Network 3.0 - alcohol abusers compared Sample Search...  

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dependence smoking 12... :www.nlm.nih.govmedlineplussubstanceabuseproblems.html 12;DSM-IV Definitions ALCOHOL ABUSE: episodic problems, no physical symptoms of withdrawal......

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Attitudinal Antecedents of the First- and Third-Person Effect of Alcohol Advertising On College Students.  

E-Print Network [OSTI]

??Data collected from a survey questionnaire via personal interviews among 488 college students was used to examine relationships among attitude toward alcohol advertising, attitude toward… (more)

Begin, Georgia

2005-01-01T23:59:59.000Z

442

E-Print Network 3.0 - allyl alcohols catalyzed Sample Search...  

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of Chicago Collection: Chemistry 25 Mechanism of Selective Oxidation of Propene to Acrolein on Bismuth Molybdates from Quantum Mechanical Calculations Summary: alcohol, allyl...

443

E-Print Network 3.0 - alcohol series based Sample Search Results  

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University, Kinsey Institute Collection: Biology and Medicine 5 ,t Hehuviorai Gmc.tic hltdds 373 Behavioral Genetic Models Summary: . Signifi- alcoholism. Although...

444

E-Print Network 3.0 - alcohol marketing predicts Sample Search...  

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marketing predicts Search Powered by Explorit Topic List Advanced Search Sample search results for: alcohol marketing predicts Page: << < 1 2 3 4 5 > >> 1 Ancient history of sexual...

445

E-Print Network 3.0 - alcohol-based hand hygiene Sample Search...  

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of germs. Follow these everyday steps... with soap and water, especially after you cough or sneeze. Alcohol-based hand cleaners are also effective... , including the CDC,...

446

E-Print Network 3.0 - alcohol-based formulations proposed Sample...  

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of germs. Follow these everyday steps... with soap and water, especially after you cough or sneeze. Alcohol-based hand cleaners are also effective Source: Collection:...

447

E-Print Network 3.0 - alcoholism Sample Search Results  

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Information Sciences 50 Financial Policy Highlights: ReimbursementPayment for Summary: Financial Policy Highlights: ReimbursementPayment for Alcohol Purchases (Policy 2.1.1 -...

448

E-Print Network 3.0 - alcoholates Sample Search Results  

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Information Sciences 50 Financial Policy Highlights: ReimbursementPayment for Summary: Financial Policy Highlights: ReimbursementPayment for Alcohol Purchases (Policy 2.1.1 -...

449

E-Print Network 3.0 - alcohols Sample Search Results  

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Information Sciences 50 Financial Policy Highlights: ReimbursementPayment for Summary: Financial Policy Highlights: ReimbursementPayment for Alcohol Purchases (Policy 2.1.1 -...

450

E-Print Network 3.0 - alcohol testing program Sample Search Results  

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fine; and attend an alcohol education program. It is illegal for anyone to host... ; completion of alcoholdrug education or training program. Lending a driver's license or...

451

E-Print Network 3.0 - anhydrous alcohol evaporated Sample Search...  

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peroxide Copper, chromium, iron, most metals or their salts, alcohols, acetone... , carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia...

452

E-Print Network 3.0 - alcoholic fatty liver Sample Search Results  

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of alcoholic fatty liver. Am J Physiol Gastrointest Liver... %-80%) aerobic process for energy production in the heart, liver, and skeletal muscle. Abnormalities of fatty... Dis...

453

Oxidation Kinetics of Cu2O in Oxygen Carriers for Chemical Looping with Oxygen Uncoupling  

Science Journals Connector (OSTI)

(7) Application to CLC was first demonstrated by Mattisson et al.,(8) who showed that the release of oxygen allows conversion of petcoke by CLOU to be as much as 50 times faster than conversion by conventional CLC with an iron-based carrier, which requires in situ conversion of petcoke to syngas by relatively slow gasification reactions. ...

Christopher K. Clayton; H. Y. Sohn; Kevin J. Whitty

2014-01-28T23:59:59.000Z

454

Comparison of the Impact of Intake Oxygen Enrichment and Fuel Oxygenation on Diesel Combustion and Emissions  

Science Journals Connector (OSTI)

turbocharged, Intercooler?(air-air), electronically?controlled?EGR with?actuator ... Fumigation into the intake surge tank was chosen to allow thorough mixing of the oxygen?air mixture through the subsequent components of the intake system, such as the air filter, turbocharger, and intercooler, before entering the intake manifold. ...

Juhun Song; Vince Zello; André L. Boehman; Francis J. Waller

2004-07-10T23:59:59.000Z

455

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

456

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

457

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

458

Electrochemical oxygen pumps. Final CRADA report.  

SciTech Connect (OSTI)

All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

Carter, J. D.

2009-10-01T23:59:59.000Z

459

Design and synthesis of the next generation of crown ethers for waste separations: An inter-laboratory comprehensive proposal. 1998 annual progress report  

SciTech Connect (OSTI)

'The purpose of this task is to undertake the design, synthesis, and characterization of the next generation of crown ethers for metal-ion separations applicable to USDOE''s environmental needs. Target problems include: Li{sup +} ions leaching from burial sites at the Oak Ridge Y-12 Plant; fission products 90 Sr and {sup 137}Cs contaminating high-level tank wastes at Hanford, INEEL, and Savannah River; and radium in wastes at the Niagara Falls Storage Site. Unfortunately, the technologies needed to address these problems either do not exist or exhibit substantial deficiencies. Separation techniques such as solvent extraction and ion exchange promise to play a strong role, especially as enhanced with highly selective crown ethers and calixarenes. This project is midway through year 2 of a 3-year effort. Below is given a summary of progress in the approximate period September, 1997, to May, 1998, for each of the four co-investigators at Pacific Northwest National Laboratory (PNNL), Argonne National Laboratory (ANL), Oak Ridge National Laboratory (ORNL), and the University of Tennessee (UTK). The overall approach entails utilization of theory and molecular modeling (PNNL), organic synthesis of novel crown compounds (ORNL), solvent extraction studies (ORNL and ANL), and studies of polymer-immobilized crown ethers (UTK).'

Moyer, B.A.; Hay, B.P.; Dietz, M.L.; Alexandratos, S.D.; Sachleben, R.A.; Chiarizia, R.

1998-06-01T23:59:59.000Z

460

Promoting effect of polyoxyethylene octylphenol ether on Cu/ZnO catalysts for low-temperature methanol synthesis  

Science Journals Connector (OSTI)

Cu/ZnO catalysts were prepared by the co-precipitation method with the addition of OP-10 (polyoxyethylene octylphenol ether) and were chemically and structurally characterized by means of XRD, BET, H2-TPR, CO-TPD and N2O-titration. The effect of OP-10 addition on the activity of Cu/ZnO for the slurry phase methanol synthesis at 150 °C was evaluated. The results showed that Cu/ZnO prepared with addition of 8% OP-10 (denoted as C8) exhibited the promoted activity for the methanol synthesis. The conversion of CO and the STY (space time yield) of methanol were 42.5% and 74.6% higher than those of Cu/ZnO prepared without addition of OP-10 (denoted as C0), respectively. The precursor of C8 contained more aurichalcite and rosasite, and the concerted effect of Cu-Zn in C8 was found to be stronger than that in C0. Compared with C0, C8 showed smaller particle size, lower reduction temperature and larger BET and Cu surface areas.

Ling Liu; Tiansheng Zhao; Qingxiang Ma; Yufang Shen

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Ethoxyresorufin-O-deethylase induction potency of polychlorinated diphenyl ethers in H4IIE rat hepatoma cells  

SciTech Connect (OSTI)

Polychlorinated diphenyl ethers (PCDEs) are structurally similar to polychlorinated biphenyls (PCBs), and some PCDE congeners have been reported to cause toxic responses similar to those caused by some of the non-ortho-substituted PCBs, which are mediated by the aryl hydrocarbon receptor (AhR). Twenty-nine PCDEs were tested for their potency as AhR agonists relative to 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) by measuring their ability to induce the cytochrome P-450 1A1-associated enzyme activity, ethoxyresorufin-O-deethylase (EROD), in the H4IIE rat hepatoma cell bioassay. All PCDE congeners tested were found to be inactive as EROD inducers except for PCDE 156, which was a weak EROD inducer with a 2,3,7,8-TCDD equivalency factor of about 1.2 {times} 10{sup {minus}5}. During this study the authors determined that small amounts of polychlorinated dibenzofurans (PCDFs) that occurred as impurities in the PCDE preparations were the cause of the apparent EROD induction initially measured in their experiments. Once the PCDF impurities were removed by purification on florisil, little or no activity could be attributed to the PCDEs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaeskylae (Finland). Dept. of Chemistry

1996-11-01T23:59:59.000Z

462

Investigation of HCCI Combustion of Diethyl Ether and Ethanol Mixtures Using Carbon 14 Tracing and Numerical Simulations  

SciTech Connect (OSTI)

Despite the rapid combustion typically experienced in Homogeneous Charge Compression Ignition (HCCI), components in fuel mixtures do not ignite in unison or burn equally. In our experiments and modeling of blends of diethyl ether (DEE) and ethanol (EtOH), the DEE led combustion and proceeded further toward completion, as indicated by {sup 14}C isotope tracing. A numerical model of HCCI combustion of DEE and EtOH mixtures supports the isotopic findings. Although both approaches lacked information on incompletely combusted intermediates plentiful in HCCI emissions, the numerical model and {sup 14}C tracing data agreed within the limitations of the single zone model. Despite the fact that DEE is more reactive than EtOH in HCCI engines, they are sufficiently similar that we did not observe a large elongation of energy release or significant reduction in inlet temperature required for light-off, both desired effects for the combustion event. This finding suggests that, in general, HCCI combustion of fuel blends may have preferential combustion of some of the blend components.

Mack, J H; Dibble, R W; Buchholz, B A; Flowers, D L

2004-01-16T23:59:59.000Z

463

Calcitriol inhibits Ether-a go-go potassium channel expression and cell proliferation in human breast cancer cells  

SciTech Connect (OSTI)

Antiproliferative actions of calcitriol have been shown to occur in many cell types; however, little is known regarding the molecular basis of this process in breast carcinoma. Ether-a-go-go (Eag1) potassium channels promote oncogenesis and are implicated in breast cancer cell proliferation. Since calcitriol displays antineoplastic effects while Eag1 promotes tumorigenesis, and both factors antagonically regulate cell cycle progression, we investigated a possible regulatory effect of calcitriol upon Eag1 as a mean to uncover new molecular events involved in the antiproliferative activity of this hormone in human breast tumor-derived cells. RT real-time PCR and immunocytochemistry showed that calcitriol suppressed Eag1 expression by a vitamin D receptor (VDR)-dependent mechanism. This effect was accompanied by inhibition of cell proliferation, which was potentiated by astemizole, a nonspecific Eag1 inhibitor. Immunohistochemistry and Western blot demonstrated that Eag1 and VDR abundance was higher in invasive-ductal carcinoma than in fibroadenoma, and immunoreactivity of both proteins was located in ductal epithelial cells. Our results provide evidence of a novel mechanism involved in the antiproliferative effects of calcitriol and highlight VDR as a cancer therapeutic target for breast cancer treatment and prevention.

Garcia-Becerra, Rocio [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Diaz, Lorenza, E-mail: lorenzadiaz@gmail.com [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Camacho, Javier [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico)] [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico); Barrera, David; Ordaz-Rosado, David; Morales, Angelica [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Ortiz, Cindy Sharon [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Avila, Euclides [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Bargallo, Enrique [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Arrecillas, Myrna [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Halhali, Ali; Larrea, Fernando [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)

2010-02-01T23:59:59.000Z

464

Monodisperse porous polymer particles containing macrocyclic ether as a new class of sorbent for SR(II) separation  

SciTech Connect (OSTI)

Strontium{sup 90} is one of the typical fission products that may be found in high level liquid waste (HLLW). Separation of Sr{sup 90} prior to the vitrification is beneficial to the final treatment of solid radioactive waste. In this study, a new class of sorbent for Sr(II) was developed by loading the macrocyclic ether DtBuCH18C6 into the monodisperse porous polymer particles (MPPPs). The MPPPs are well-known as a promising chromatographic material due to the uniform particle size, porous morphology, good compatibility with organic extractants, and rigid matrix. The structure and micro-morphology of the sorbent particles were characterized. The adsorption behavior towards Sr(II) in HNO{sub 3} media was investigated by both batch and column experiments. High adsorption efficiency and selective separation of Sr(II) was obtained. The sorbent particles can be recycled for at least several times before obvious lose of the adsorption ability. This kind of sorbent possesses the potential to be used for strontium separation in radioactive liquid waste.

Leng, Yuxiao; Bai, Feifei [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 100084 (China); Ye, Gang; Wei, Jichao; Wang, Jianchen; Chen, Jing [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

2013-07-01T23:59:59.000Z

465

Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation  

SciTech Connect (OSTI)

Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

Yoon, S.S. [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi-do 445-706 (Korea); Anh, D.H. [Korea Electric Power Research Institute, Daejeon 305-380 (Korea); Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea)

2008-08-15T23:59:59.000Z

466

Life cycle study of coal-based dimethyl ether as vehicle fuel for urban bus in China  

Science Journals Connector (OSTI)

With life cycle assessment (LCA) methodology, a life cycle model of coal-based dimethyl ether (CBDME) as a vehicle fuel is established for China. Its life cycle from well to wheel are divided into three phases. They are feedstock extraction, fuel production and fuel consumption in vehicle. The primary energy consumption (PEC) and global warming potential (GWP) of CBDME pathway are analyzed and compared with coal-based diesel (CBD) as a latent rival to replace conventional petroleum-based diesel (CPBD). This study demonstrates that the LCA methodology is very suitable and effective for the choice of vehicle fuels. One result is that the greenhouse gases (GHGs) emission of coal-based vehicle fuel pathways is usually concentrated on fuel production stage. The percentages of CBDME and CBD pathways both exceed 60%. The application of carbon capture and storage (CCS) is helpful for coal-based vehicle fuel pathways to improve their global warming effect dramatically. Compared with CBD pathway, CBDME pathway consumes less PEC and emits less \\{GHGs\\} emission as well. Even though the CCS and CH4-fired generation are used, the advantages of CBDME are still kept. For saving petroleum energy and reducing global warming effect, CBDME has greater potential than CBD to substitute CPBD under current fuel synthesis technologies. If the hurdles such as the maturity of engine and vehicle technologies, corresponding regulations and standards and infrastructures are reliably solved, CBDME will have better prospect in China.

Liang Zhang; Zhen Huang

2007-01-01T23:59:59.000Z

467

Oxygen Atoms Display Novel Behavior on Common Catalyst  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

11, 2008 11, 2008 Oxygen Atoms Display Novel Behavior on Common Catalyst Like waltzing dancers, the two atoms of an oxygen molecule usually behave identically when they separate on the surface of a catalyst. However, new research from the Environmental Molecular Sciences Laboratory reveals that on a particular catalyst, the oxygen atoms act like a couple dancing the tango: one oxygen atom plants itself while the other shimmies away, probably with energy partially stolen from the stationary one. Scientists from EMSL and Pacific Northwest National Laboratory discovered this unanticipated behavior while studying how oxygen interacts with reduced titanium oxide, a popular catalyst and a model oxide. Their research began with a slice of titanium oxide crystal, oriented so that titanium and oxygen

468

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

469

New Oxygen-Production Technology Proving Successful | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Oxygen-Production Technology Proving Successful Oxygen-Production Technology Proving Successful New Oxygen-Production Technology Proving Successful April 22, 2009 - 1:00pm Addthis Washington, DC -- The Office of Fossil Energy's National Energy Technology Laboratory (NETL) has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies. ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also enhance the economics of oxy-fired combustion technologies, making it an attractive option for the capture of carbon

470

T4 DNA condensation in water-alcohol media  

E-Print Network [OSTI]

The process of compaction of high molecular weight DNA T4 is investigated directly in a AFM liquid cell. The AFM-images of globules formed by DNA molecules in the result of compaction in water-alcohol environments at high izopropanol concentration (80%) are received; it is found that at intermediate concentration of izopropanol (40-50%) the DNA molecules form partially compacted formations in which the separate coils of macromolecules twist in toroidal structures. It is shown using the technique of deconvolution of the AFM-images that the globule include only one closely packed DNA molecule. The model of DNA packing is proposed on the basis of AFM experiment.

M. O. Gallyamov; O. A. Pyshkina; V. G. Sergeyev; I. V. Yaminsky

2011-07-21T23:59:59.000Z

471

Role of osteopontin in hepatic neutrophil infiltration during alcoholic steatohepatitis  

SciTech Connect (OSTI)

Alcoholic liver disease (ALD) is a major complication of heavy alcohol (EtOH) drinking and is characterized by three progressive stages of pathology: steatosis, steatohepatitis, and fibrosis/cirrhosis. Alcoholic steatosis (AS) is the initial stage of ALD and consists of fat accumulation in the liver accompanied by minimal liver injury. AS is known to render the hepatocytes increasingly sensitive to toxicants such as bacterial endotoxin (LPS). Alcoholic steatohepatitis (ASH), the second and rate-limiting step in the progression of ALD, is characterized by hepatic fat accumulation, neutrophil infiltration, and neutrophil-mediated parenchymal injury. However, the pathogenesis of ASH is poorly defined. It has been theorized that the pathogenesis of ASH involves interaction of increased circulating levels of LPS with hepatocytes being rendered highly sensitive to LPS due to heavy EtOH consumption. We hypothesize that osteopontin (OPN), a matricellular protein (MCP), plays an important role in the hepatic neutrophil recruitment due to its enhanced expression during the early phase of ALD (AS and ASH). To study the role of OPN in the pathogenesis of ASH, we induced AS in male Sprague-Dawley rats by feeding EtOH-containing Lieber-DeCarli liquid diet for 6 weeks. AS rats experienced extensive fat accumulation and minimal liver injury. Moderate induction in OPN was observed in AS group. ASH was induced by feeding male Sprague-Dawley rats EtOH-containing Lieber-DeCarli liquid diet for 6 weeks followed by LPS injection. The ASH rats had substantial neutrophil infiltration, coagulative oncotic necrosis, and developed higher liver injury. Significant increases in the hepatic and circulating levels of OPN was observed in the ASH rats. Higher levels of the active, thrombin-cleaved form of OPN in the liver in ASH group correlated remarkably with hepatic neutrophil infiltration. Finally, correlative studies between OPN and hepatic neutrophil infiltration was corroborated in a simple rat peritoneal model where enhanced peritoneal fluid neutrophil infiltration was noted in rats injected OPN intraperitoneally. Taken together these data indicate that OPN expression induced during ASH may play a significant role in the pathogenesis of ASH by stimulating neutrophil transmigration.

Apte, Udayan M. [Department of Pathobiology, College of Veterinary Medicine, Texas A and M University, MS4467, College Station, TX 77843-4467 (United States); Banerjee, Atrayee [Department of Pathobiology, College of Veterinary Medicine, Texas A and M University, MS4467, College Station, TX 77843-4467 (United States); McRee, Rachel [Department of Pathobiology, College of Veterinary Medicine, Texas A and M University, MS4467, College Station, TX 77843-4467 (United States); Wellberg, Elizabeth [Department of Pathobiology, College of Veterinary Medicine, Texas A and M University, MS4467, College Station, TX 77843-4467 (United States); Ramaiah, Shashi K. [Department of Pathobiology, College of Veterinary Medicine, Texas A and M University, MS4467, College Station, TX 77843-4467 (United States)]. E-mail: sramaiah@cvm.tamu.edu

2005-08-22T23:59:59.000Z

472

Alcohol Dispersions of Calcium Hydroxide Nanoparticles for Stone Conservation  

Science Journals Connector (OSTI)

Alcohol dispersions of Ca(OH)2 nanoparticles, the so-called nanolimes, are emerging as an effective conservation material for the consolidation of stone, mortars, and plasters present in old masonry and/or mural paintings. ... Considering that past studies on the consolidation of stone using nanolime dispersions have focused on carbonate stones such as limestones, here we test the ability of these treatments to consolidate silicate stones. ... D’Armada, P.; Hirst, E.Nano-lime for consolidation of plaster and stone J. Architect. ...

Carlos Rodriguez-Navarro; Amelia Suzuki; Encarnacion Ruiz-Agudo

2013-08-06T23:59:59.000Z

473

Gas-Liquid Chromatographic Analysis of Long-Chain Fatty Alcohols  

Science Journals Connector (OSTI)

......6 FEBRUARY 1968 of lithium aluminum hydride hydrogenolysis...starting materials for the synthesis of glyceryl ethers...polar liquid phases. Acetate derivatives used by...TMS) and trifluoro- acetate (TFA) derivatives...the methyl esters by lithium aluminum hydride reduction......

Randall Wood

1968-02-01T23:59:59.000Z

474

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Feed Systems Feed Systems Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems Air Products and Chemicals, Inc. Project Number: FC26-98FT40343 Project Description Air Products and Chemicals, Inc. is developing, scaling-up, and demonstrating a novel air separation technology for large-scale production of oxygen (O2) at costs that are approximately one-third lower than conventional cryogenic plants. An Ion Transport Membrane (ITM) Oxygen plant co-produces power and oxygen. A phased technology RD&D effort is underway to demonstrate all necessary technical and economic requirements for scale-up and industrial commercialization. The ITM Oxygen production technology is a radically different approach to producing high-quality tonnage oxygen and to enhance the performance of integrated gasification combined cycle and other advanced power generation systems. Instead of cooling air to cryogenic temperatures, oxygen is extracted from air at temperatures synergistic with power production operations. Process engineering and economic evaluations of integrated gasification combined cycle (IGCC) power plants comparing ITM Oxygen with a state-of-the-art cryogenic air separation unit are aimed to show that the installed capital cost of the air separation unit and the installed capital of IGCC facility are significantly lower compared to conventional technologies, while improving power plant output and efficiency. The use of low-cost oxygen in combustion processes would provide cost-effective emission reduction and carbon management opportunities. ITM Oxygen is an enabling module for future plants for producing coal derived shifted synthesis gas (a mixture of hydrogen [H2] and carbon dioxide [CO2]) ultimately for producing clean energy and fuels. Oxygen-intensive industries such as steel, glass, non-ferrous metallurgy, refineries, and pulp and paper may also realize cost and productivity benefits as a result of employing ITM Oxygen.

475

Electrons, life and the evolution of Earth's oxygen cycle  

Science Journals Connector (OSTI)

...efficiency of organic matter and...increased production of oxygen...eukaryotic host cells, allowing...outside of our Solar System...efficiency of organic matter and...increased production of oxygen...eukaryotic host cells, allowing...outside of our Solar System...efficiency of organic matter and...increased production of oxygen...eukaryotic host cells, allowing...outside of our Solar System...

2008-01-01T23:59:59.000Z

476

Molecular oxygen sensors based on photoluminescent silica aerogels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molecular oxygen sensors based on photoluminescent silica aerogels Molecular oxygen sensors based on photoluminescent silica aerogels Title Molecular oxygen sensors based on photoluminescent silica aerogels Publication Type Journal Article Year of Publication 1998 Authors Ayers, Michael R., and Arlon J. Hunt Journal Journal of Non-Crystalline Solids Volume 225 Pagination 343-347 Keywords aerogel, air pressure, oxygen concentration, oxygen molecules, photoluminescence Abstract Photoluminescent silica aerogel acts as the active element of an optical sensor for molecular oxygen. The luminescent aerogel is prepared by the action of energized reducing gases on a standard silica aerogel. Intensity of aerogel photoluminescence decreases as the collision frequency between oxygen molecules and the luminescent carriers in the aerogel matrix increases. This behavior is a characteristic of many photoluminescent materials and arises from a transfer of energy from the aerogel to surrounding oxygen molecules. A sensor for oxygen concentration or air pressure can therefore be simply constructed utilizing an ultraviolet source for excitation and a suitable detector for the emitted visible signal. Stern-Volmer quenching constants for the aerogel sensing element are 1.55×10-2 Torr-1 for hydrophilic aerogel and 2.4×10-3 Torr-1 for hydrophobic aerogel.

477

Effect of feedwater oxygen control at the Vermont Yankee BWR  

SciTech Connect (OSTI)

Results of a test program to evaluate the impact of oxygen injection on the release and transport of iron, nickel, cobalt, copper and zinc in the feedwater system at the Vermont Yankee boiling water reactor (BWR) are presented. Design and operation of the oxygen injection system are discussed. Conclusions and recommendations relative to generic application of oxygen injection for corrosion product control in BWRs during normal operation are presented. Application of oxygen injection to assist in feedwater system materials passivation after an extended outage also is discussed. 12 refs., 16 figs., 5 tabs.

Hobart, R.L.; Palino, G.F.

1985-07-01T23:59:59.000Z

478

OXYGEN CONSUMPTION BY THE SEABED IV. SHIPBOARD AND ...  

Science Journals Connector (OSTI)

respiratory consumption; in these experiments the rate of chemical oxidation decreases with decreasing oxygen tension, whiIe the rate of respiration is relatively.

Orcas

2000-02-13T23:59:59.000Z

479

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

We discovered that the electronic structure and valence state of transition metal ions show significant variations, which have been identified to be attributed to the oxygen...

480

Geothermal reservoir temperatures estimated from the oxygen isotope...  

Open Energy Info (EERE)

temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search GEOTHERMAL...

Note: This page contains sample records for the topic "oxygenates alcohols ethers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Microbial metatranscriptomics in a permanent marine oxygen minimum zone  

E-Print Network [OSTI]

Simultaneous characterization of taxonomic composition, metabolic gene content and gene expression in marine oxygen minimum zones (OMZs) has potential to broaden perspectives on the microbial and biogeochemical dynamics ...

Stewart, Frank J.

482

Oxygen-Enriched Combustion for Military Diesel Engine Generators...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak...

483

Oxygen Coverage Dependence of NO Oxidation on Pt(111). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dependence of NO Oxidation on Pt(111). Abstract: The interaction of NO with adsorbed atomic oxygen on Pt(111) was studied with temperature programmed desorption (TPD),...

484

Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence  

E-Print Network [OSTI]

in oxygen atmospheres 0%­21% were obtained with a signal to noise ratio better than 150. Photobleaching physical principles, electrochemistry or luminescence. Electrochemical devices result in analyte

Ghosh, Ruby N.

485

Oxygen-nutrient relationships in the Pacific Ocean  

Science Journals Connector (OSTI)

Aug 18, 1972 ... In the northeastern Pacific Ocean the oxygen-phosphate ... different stations in the Pacific and Indian Oceans to study their water masses.

2000-01-04T23:59:59.000Z

486

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

487

Modeling Oxygen Transport in Three-Dimensional Capillary Networks.  

E-Print Network [OSTI]

??The purpose of this thesis was to examine how the use of real 3-dimensional (3D) capillary network geometries affect models of oxygen transport to tissue.… (more)

Fraser, Graham M

2012-01-01T23:59:59.000Z

488

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Precursor Transport Through the Hydrogen Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the Hydrogen...

489

Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon Excluding...

490

Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

- - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

491

Hydrogen (H2) Production by Oxygenic Phototrophs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical Challenges * Mixture of H 2 and O 2 ; H 2 separation and storage * CO 2 addition and overall reactor design Overcoming Low Efficiency: Improving ET * Eliminate or down-regulate pathways competing for ele * Production of organic acids * Formation of NADPH/carbon fixation

492

It's Elemental - Isotopes of the Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine Isotopes of the Element Oxygen [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 16 99.757% STABLE 17 0.038% STABLE 18 0.205% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 12 1.139×10-21 seconds Proton Emission No Data Available 13 8.58 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 100.00% 14 70.620 seconds Electron Capture 100.00% 15 122.24 seconds Electron Capture 100.00% 16 STABLE - - 17 STABLE - - 18 STABLE - - 19 26.88 seconds Beta-minus Decay 100.00%

493

Dilute Oxygen Combustion - Phase 3 Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, Michael F.

2000-05-31T23:59:59.000Z

494

Dilute Oxygen Combustion Phase 3 Final Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, M.F.; Ryan, H.M.

2000-05-31T23:59:59.000Z

495

Floated Catalyst CVD Generation of Single-Walled Carbon Nanotubes from Alcohol  

E-Print Network [OSTI]

Floated Catalyst CVD Generation of Single-Walled Carbon Nanotubes from Alcohol Shigeo Maruyama to other configuration, a floated catalyst type generation of SWNTs. Using ferrocene as a precursor of floated iron catalyst clusters, high-purity SWNTs were generated from alcohol. Mist of ferrocene ethanol

Maruyama, Shigeo

496

E-Print Network 3.0 - alcohol abuse measurement Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

metabolism and sensitivity... .0% N 21 18.0% N s5 U.S. U.S. Sweden Registration DSM-III alcohol abusedependence DSM-III alcohol... ) (N 577) (0.37) kJ.S. DSM-III...

497

Updated 10/2012 Alcohol/Substance Abuse Treatment OP/IOP/PHP*  

E-Print Network [OSTI]

Updated 10/2012 Alcohol/Substance Abuse Treatment OP/IOP/PHP* Please note patient or family member, some limitations with Medicare 4 Adult locations with OP, IOP, and sometimes PHP 1) Plainville 2) New-OP, IOP, PHP; Primary Substance Abuse-OP, IOP; Senior Program > 55y.o., alcohol only substance, take

Oliver, Douglas L.

498

Analysis of Fatty Acid and Alcoholic Components of Sebaceous Lipid Types  

Science Journals Connector (OSTI)

......chromatography of the acetates. Ratios were determined...specificity for the synthesis of alcohols. Introduction...and Alcohols For the synthesis of cyclopropanoid acids...the methyl esters with lithium aluminum hydride. The...anhydride and the respective acetates together with the methyl......

Hugh J. O'Neill; Leon L. Gershbein

1976-01-01T23:59:59.000Z

499

The harmful effects of late-onset alcohol consumption on cortical bone in aged rats  

E-Print Network [OSTI]

This study looked at the effects of late-onset alcohol consumption for 8 weeks on the aged rat model (15 months old). Thirty 15 month old female Fisher 344 rats were divided into three diet groups: Alcohol (n=9), pair-fed (n=9), and pellet (n=6...

Bowlin, Julie Lee

2012-06-07T23:59:59.000Z

500

Ethanol-induced alcohol dehydrogenase E (AdhE) potentiates pneumolysin in Streptococcus pneumoniae  

Science Journals Connector (OSTI)

...Rights Reserved. 2014 research-article Ethanol-induced alcohol dehydrogenase E (AdhE...showed that S. pneumoniae type 2 D39 is ethanol tolerant, and that alcohol up-regulates...factor. Moreover, in the presence of ethanol, S. pneumoniae AdhE produced acetaldehyde...

Truc Thanh Luong; Eun-Hye Kim; Jong Phil Bak; Cuong Thach Nguyen; Sangdun Choi; David E. Briles; Suhkneung Pyo; Dong-Kwon Rhee

2014-10-13T23:59:59.000Z