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Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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1

Innovative Separations Technologies  

SciTech Connect (OSTI)

Reprocessing used nuclear fuel (UNF) is a multi-faceted problem involving chemistry, material properties, and engineering. Technology options are available to meet a variety of processing goals. A decision about which reprocessing method is best depends significantly on the process attributes considered to be a priority. New methods of reprocessing that could provide advantages over the aqueous Plutonium Uranium Reduction Extraction (PUREX) and Uranium Extraction + (UREX+) processes, electrochemical, and other approaches are under investigation in the Fuel Cycle Research and Development (FCR&D) Separations Campaign. In an attempt to develop a revolutionary approach to UNF recycle that may have more favorable characteristics than existing technologies, five innovative separations projects have been initiated. These include: (1) Nitrogen Trifluoride for UNF Processing; (2) Reactive Fluoride Gas (SF6) for UNF Processing; (3) Dry Head-end Nitration Processing; (4) Chlorination Processing of UNF; and (5) Enhanced Oxidation/Chlorination Processing of UNF. This report provides a description of the proposed processes, explores how they fit into the Modified Open Cycle (MOC) and Full Recycle (FR) fuel cycles, and identifies performance differences when compared to 'reference' advanced aqueous and fluoride volatility separations cases. To be able to highlight the key changes to the reference case, general background on advanced aqueous solvent extraction, advanced oxidative processes (e.g., volumetric oxidation, or 'voloxidation,' which is high temperature reaction of oxide UNF with oxygen, or modified using other oxidizing and reducing gases), and fluorination and chlorination processes is provided.

J. Tripp; N. Soelberg; R. Wigeland

2011-05-01T23:59:59.000Z

2

Separation technologies: Marketing factors  

SciTech Connect (OSTI)

The chemical and petroleum industries consume approximately 5.8 quads per year of energy. Within these industries, 43% of the energy is used by separation processes to recover and purify products. With 40,000 distillation columns in operation, distillation is used to make 95% of all separations in these two industries. Although separations are identified which are amenable to advanced separation technologies (that make distillation more energy-efficient), they are not implemented because of commercial barriers. The focus of this work was on barriers which can by overcome by implementing advanced separation-related technologies. Barriers were screened and prioritized, and Return On Investment (ROI) was calculated for each project designed to overcome a high priority barrier. Economic analyses were based on specific separations such as ethylene-ethane, propylene-propane, ethyl benzene-styrene, and ethanol-water. These separations were selected because they consume significant amounts of energy for separation. Thus, conclusions are based on a limited number of case studies; an approach necessary to complete this project within a reasonable time frame. Recommended projects are discussed and summarized.

Humphrey, J.L.; Seibert, A.F.; Goodpastor, C.V.

1991-12-01T23:59:59.000Z

3

Device and method for separating oxygen isotopes  

DOE Patents [OSTI]

A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

4

Actinide Separation Science and Technology  

Science Journals Connector (OSTI)

Both the science and technology of the actinides as we know them today owe much to separation science. Conversely, the field of metal ion separations, solvent extraction, and ion exchange in particular, would ...

Kenneth L. Nash; Charles Madic…

2011-01-01T23:59:59.000Z

5

Actinide Separation Science and Technology  

Science Journals Connector (OSTI)

Both the science and technology of the actinides as we know them today owe much to separation science. Conversely, the field of metal ion separations, solvent extraction, and ion exchange in particular, would ...

Kenneth L. Nash; Charles Madic…

2006-01-01T23:59:59.000Z

6

CRADA Final Report: Ionically Conductive Membranes Oxygen Separation  

SciTech Connect (OSTI)

Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

Visco, Steven J.

2001-10-29T23:59:59.000Z

7

SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION  

SciTech Connect (OSTI)

Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

Timothy L. Ward

2000-06-30T23:59:59.000Z

8

Separation process using microchannel technology  

DOE Patents [OSTI]

The disclosed invention relates to a process and apparatus for separating a first fluid from a fluid mixture comprising the first fluid. The process comprises: (A) flowing the fluid mixture into a microchannel separator in contact with a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the first fluid is sorbed by the sorption medium, removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing first fluid from the sorption medium and removing desorbed first fluid from the microchannel separator. The process and apparatus are suitable for separating nitrogen or methane from a fluid mixture comprising nitrogen and methane. The process and apparatus may be used for rejecting nitrogen in the upgrading of sub-quality methane.

Tonkovich, Anna Lee (Dublin, OH); Perry, Steven T. (Galloway, OH); Arora, Ravi (Dublin, OH); Qiu, Dongming (Bothell, WA); Lamont, Michael Jay (Hilliard, OH); Burwell, Deanna (Cleveland Heights, OH); Dritz, Terence Andrew (Worthington, OH); McDaniel, Jeffrey S. (Columbus, OH); Rogers, Jr.; William A. (Marysville, OH); Silva, Laura J. (Dublin, OH); Weidert, Daniel J. (Lewis Center, OH); Simmons, Wayne W. (Dublin, OH); Chadwell, G. Bradley (Reynoldsburg, OH)

2009-03-24T23:59:59.000Z

9

A survey of alternative oxygen production technologies  

Science Journals Connector (OSTI)

Utilization of the Martian atmosphere for the production of fuel and oxygen has been extensively studied. The baseline fuel production process is a Sabatier reactor which produces methane and water from carbon dioxide and hydrogen. The oxygen produced from the electrolysis of the water is only half of that needed for methane-based rocket propellant and additional oxygen is needed for breathing air fuel cells and other energy sources. Zirconia electrolysis cells for the direct reduction of CO 2 are being developed as an alternative means of producing oxygen but present many challenges for a large-scale oxygen production system. The very high operating temperatures and fragile nature of the cells coupled with fairly high operating voltages leave room for improvement. This paper will survey alternative oxygen production technologies present data on operating characteristics materials of construction and some preliminary laboratory results on attempts to implement each.

Dale E. Lueck; Clyde F. Parrish; William J. Buttner; Jan M. Surma

2001-01-01T23:59:59.000Z

10

Nuclear Separations Technologies Workshop Report 2011  

Broader source: Energy.gov (indexed) [DOE]

i i NUCLEAR SEPARATIONS TECHNOLOGIES WORKSHOP REPORT November 7, 2011 FINAL TABLE OF CONTENTS Acronyms and Initialisms............................................................................................................ iii Executive Summary ...................................................................................................................... 1 1. Introduction ............................................................................................................................. 9 1.1 Overview .......................................................................................................................... 9 1.2 Background .................................................................................................................... 10

11

Separation technologies: Marketing factors. Final report  

SciTech Connect (OSTI)

The chemical and petroleum industries consume approximately 5.8 quads per year of energy. Within these industries, 43% of the energy is used by separation processes to recover and purify products. With 40,000 distillation columns in operation, distillation is used to make 95% of all separations in these two industries. Although separations are identified which are amenable to advanced separation technologies (that make distillation more energy-efficient), they are not implemented because of commercial barriers. The focus of this work was on barriers which can by overcome by implementing advanced separation-related technologies. Barriers were screened and prioritized, and Return On Investment (ROI) was calculated for each project designed to overcome a high priority barrier. Economic analyses were based on specific separations such as ethylene-ethane, propylene-propane, ethyl benzene-styrene, and ethanol-water. These separations were selected because they consume significant amounts of energy for separation. Thus, conclusions are based on a limited number of case studies; an approach necessary to complete this project within a reasonable time frame. Recommended projects are discussed and summarized.

Humphrey, J.L.; Seibert, A.F.; Goodpastor, C.V.

1991-12-01T23:59:59.000Z

12

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2006-05-15T23:59:59.000Z

13

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2005-11-04T23:59:59.000Z

14

Crosscutting Technology Development at the Center for Advanced Separation Technologies  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2006-09-30T23:59:59.000Z

15

New Oxygen-Production Technology Proving Successful | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Oxygen-Production Technology Proving Successful Oxygen-Production Technology Proving Successful New Oxygen-Production Technology Proving Successful April 22, 2009 - 1:00pm Addthis Washington, DC -- The Office of Fossil Energy's National Energy Technology Laboratory (NETL) has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies. ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also enhance the economics of oxy-fired combustion technologies, making it an attractive option for the capture of carbon

16

Separations Technology for Clean Water and Energy  

SciTech Connect (OSTI)

Providing clean water and energy for about nine billion people on the earth by midcentury is a daunting challenge. Major investments in efficiency of energy and water use and deployment of all economical energy sources will be needed. Separations technology has an important role to play in producing both clean energy and water. Some examples are carbon dioxide capture and sequestration from fossil energy power plants and advanced nuclear fuel cycle scemes. Membrane separations systems are under development to improve the economics of carbon capture that would be required at a huge scale. For nuclear fuel cycles, only the PUREX liquid-liquid extraction process has been deployed on a large scale to recover uranium and plutonium from used fuel. Most current R and D on separations technology for used nuclear fuel focuses on ehhancements to a PUREX-type plant to recover the minor actinides (neptunium, americiu, and curium) and more efficiently disposition the fission products. Are there more efficient routes to recycle the actinides on the horizon? Some new approaches and barriers to development will be briefly reviewed.

Jarvinen, Gordon D [Los Alamos National Laboratory

2012-06-22T23:59:59.000Z

17

Corn Wet Milling: Separation Chemistry and Technology  

Science Journals Connector (OSTI)

Publisher Summary This chapter focuses on the separation chemistry and technology of corn wet milling. The purpose of corn wet milling is to separate the kernel into its constituent chemical components. Wet milling processing begins with steeping whole kernel corn in an aqueous solution of sulfur dioxide and lactic acid (produced by microorganisms) at 50°C for 24–48 hours. The corn is then coarsely ground and the lipid-containing germ and fibrous hull portions are separated. After the remaining components are more finely ground, the starch and protein are separated using hydrocyclones, essentially continuous centrifuges; corn starch is slightly denser than corn protein. Germ is further processed into oil and the protein and fiber components are usually blended and used as animal feeds. The wet starch is either dried, chemically modified to change its functional properties, converted into intermediate-sized glucose polymers, or fully depolymerized into sugars. Starch is also often used as a raw ingredient for adjacent processing facilities that produce ethanol or other alcohols and other industrial chemicals.

David S. Jackson; Donald L. Shandera Jr.

1995-01-01T23:59:59.000Z

18

NETL: Control Technology: ElectroCore Separator  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ElectroCore Separator ElectroCore Separator LSR Technologies and its subcontractors designed and installed a 8,500 m3/hr (5,000 acfm) Advanced ElectroCore system and a dry sulfur scrubber to test it using an exhaust gas slipstream at Alabama Power Company's Gaston Steam Plant. Shakedown is scheduled for August 15, 2001. The exhaust gas will be from Unit #4 of a 270 MWe sub-critical, pulverized coal boiler burning a low-sulfur bituminous coal. The Advanced ElectroCore system will consist of a conventional upstream ESP, a dry SO2 scrubber, a particle precharger and an Advanced ElectroCore separator. Particle concentrations and size distributions will be measured at the ESP inlet, at the dry scrubber outlet and at the ElectroCore outlet. The concentration of 12 common HAPs will be measured at these locations as well. For purposes of project organization and monitoring, the work will be divided into nine (9) tasks described below.

19

Crosscutting Technology Development at the Center for Advanced Separation Technologies  

SciTech Connect (OSTI)

The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium -- Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno - that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/biological extraction; (4) Modeling and control; and (5) Environmental control. Distribution of funds is handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. The successful projects are listed by category, along with brief abstracts of their aims and objectives.

Christopher Hull

2009-10-31T23:59:59.000Z

20

NETL: News Release - New Oxygen-Production Technology Proving Successful  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

22, 2009 22, 2009 New Oxygen-Production Technology Proving Successful Ceramic Membrane Enables Efficient, Cost-Effective Co-Production of Power and Oxygen Washington, D.C. -The Office of Fossil Energy's National Energy Technology Laboratory (NETL) has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies. ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also enhance the economics of oxy-fired combustion technologies, making it an attractive option for the capture of carbon dioxide from existing coal-fired power plants.

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

We discovered that the electronic structure and valence state of transition metal ions show significant variations, which have been identified to be attributed to the oxygen...

22

Nuclear Separations Technologies Workshop Report | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Separations Technologies Workshop Report Separations Technologies Workshop Report Nuclear Separations Technologies Workshop Report The Department of Energy (DOE) sponsored a workshop on nuclear separations technologies in Bethesda, Maryland, on July 27 and 28, 2011, to (1) identify common needs and potential requirements in separations technologies and opportunities for program partnerships, and (2) evaluate the need for a DOE nuclear separations center of knowledge to improve cross- program collaboration in separations technology. The workshop supported Goal 3 of the DOE Strategic Plan1 to enhance nuclear security through defense, nonproliferation, and environmental management. The Office of Environmental Management (EM), Office of Nuclear Energy (NE), and National Nuclear Security Administration (NNSA) jointly sponsored the workshop. The Office of Science

23

Nuclear Separations Technologies Workshop Report | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Nuclear Separations Technologies Workshop Report Nuclear Separations Technologies Workshop Report Nuclear Separations Technologies Workshop Report The Department of Energy (DOE) sponsored a workshop on nuclear separations technologies in Bethesda, Maryland, on July 27 and 28, 2011, to (1) identify common needs and potential requirements in separations technologies and opportunities for program partnerships, and (2) evaluate the need for a DOE nuclear separations center of knowledge to improve cross- program collaboration in separations technology. The workshop supported Goal 3 of the DOE Strategic Plan1 to enhance nuclear security through defense, nonproliferation, and environmental management. The Office of Environmental Management (EM), Office of Nuclear Energy (NE), and National Nuclear Security Administration (NNSA) jointly sponsored the workshop. The Office of Science

24

MHK Technologies/Oxygen Releasing and Carbon Absorbing Ocean Based  

Open Energy Info (EERE)

Releasing and Carbon Absorbing Ocean Based Releasing and Carbon Absorbing Ocean Based Renewable Energy System < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Oxygen Releasing and Carbon Absorbing Ocean Based Renewable Energy System.jpg Technology Profile Technology Description The benefits of the system developed and patented by AEEA are 1 exploitation of the greater wave energy density in the more remote off shore locations 2 usage of existing industrial fuel storage and distribution infrastructure 3 provision for a gradual transition to widespread electric vehicle use 4 avoidance of environmental destruction and visual impairment with minimal impact on commercial fishing and recreation uses 5 fostering the development of a new maritime and energy industry 6 avoidance of the high capital investment in mooring and anchoring seabed electrical cable installation and seabed restoration 7 development of flexibility by deployment of fleets of these vessels to supply widely separated market locations using coastal and national waterways and 8 provision for the addition of fleets without depletion of primary feed stocks as in nuclear energy systems 2 Fig 1 In summary the system converts wave energy from the nearly unlimited world wide

25

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (a) Solid-solid separation (b) Solid-liquid separation (c) Chemical/Biological Extraction (d) Modeling and Control, and (e) Environmental Control. Distribution of funds is being handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. The first of these solicitations, referred to as the CAST II-Round 1 RFP, was issued on October 28, 2002. Thirty-eight proposals were received by the December 10, 2002 deadline for this RFP-eleven (11) Solid-Solid Separation, seven (7) Solid-Liquid Separation, ten (10) Chemical/Biological Extraction, six (6) Modeling & Control and four (4) Environmental Control. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. This process took some 7 months to complete but 17 projects (one joint) were in place at the constituent universities (three at Virginia Tech, two at West Virginia University, three at University of Kentucky, three at University of Utah, three at Montana Tech, three at New Mexico Tech, and one at the University of Nevada, Reno) by May 17, 2003. These projects are listed by category, along with brief abstracts of their aims and objectives.

Hugh W. Rimmer

2003-11-15T23:59:59.000Z

26

Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor  

Broader source: Energy.gov [DOE]

Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

27

Evaluation of nitrate and nitrite destruction/separation technologies  

SciTech Connect (OSTI)

This report describes and evaluates four types of nitrate and nitrite destruction and separation technologies that could be used to treat the aqueous, alkaline, nitrate-bearing mixed waste that is generated by the In-Tank Precipitation (ITP) process at the Savannah River Site (SRS). The technologies considered in this report include thermal, hydrothermal, chemical, and electrochemical technologies.

Hobbs, D.T.

1997-08-29T23:59:59.000Z

28

Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production  

DOE Patents [OSTI]

A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

1988-01-01T23:59:59.000Z

29

SciTech Connect: Center for Advanced Separation Technology  

Office of Scientific and Technical Information (OSTI)

basic research and will be carried out in two broad areas: Advanced Pre-Combustion Clean Coal Technologies and Gas-Gas Separations. Distribution of funds is handled via...

30

Separation of heavy metals from industrial waste streams by membrane separation technology  

SciTech Connect (OSTI)

Industrial membrane technology is becoming increasingly attractive as a low-cost generic separation technique for volume reduction, recovery, and/or purification of the liquid phase and concentration and/or recovery of the contaminant or solute. It offers outstanding future potential in the reduction and/or recycling of hazardous pollutants from waste streams. Membrane separation technology may include: (1) commercial processes such as electrodialysis, reverse osmosis, nanofiltration, and ultrafiltration and (2) the development of hybrid processes such as liquid membranes, Donnan dialysis, and membrane bioreactor technology. Membrane separation technology as applied to waste treatment/reduction and environmental engineering problems has several advantages over conventional treatment processes. In contrast to distillation and solvent extraction membrane separation is achieved without a phase change and use of expensive solvents. The advantages of this technology are (1) low energy requirements; (2) small volumes of retentate that need to be handled; (3) selective removal of pollutants with the use of complexing agents and biocatalysts or by membrane surface modification; (4) the possibility for achieving zero discharge'' with reuse of product water, binding media and target, compounds; (5) continuous operation; (6) modular design without significant size limitations; (7) discrete membrane barrier to ensure physical separation of contaminants; and (8) minimal labor requirement.

Yichu Huang; Koseoglu, S.S. (Texas A and M Univ. System, College Station, TX (United States). Engineering Biosciences Research Center)

1993-01-01T23:59:59.000Z

31

Efficient Separations and Processing Crosscutting Program. Technology summary  

SciTech Connect (OSTI)

The Efficient Separations and Processing (ESP) Crosscutting Program was created in 1991 to identify, develop, and perfect separations technologies and processes to treat wastes and address environmental problems throughout the DOE Complex. The ESP funds several multi-year tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R and D) leading to demonstration or use of these separations technologies by other organizations within DOE-EM. Treating essentially all DOE defense wastes requires separation methods that concentrate the contaminants and/or purify waste streams for release to the environment or for downgrading to a waste form less difficult and expensive to dispose of. Initially, ESP R and D efforts focused on treatment of high-level waste (HLW) from underground storage tanks (USTs) because of the potential for large reductions in disposal costs and hazards. As further separations needs emerge and as waste management and environmental restoration priorities change, the program has evolved to encompass the breadth of waste management and environmental remediation problems.

NONE

1995-06-01T23:59:59.000Z

32

NETL: Gasification Systems - Advanced Acid Gas Separation Technology for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Feed Systems Feed Systems Advanced Acid Gas Separation Technology for the Utilization of Low-Rank Coals Project Number: DE-FE0007759 Refinery offgas PSA at Air Products' facility in Baytown, TX Refinery offgas PSA at Air Products' facility in Baytown, TX. Air Products, in collaboration with the University of North Dakota Energy and Environmental Research Center (EERC), is testing its Sour Pressure Swing Adsorption (Sour PSA) process that separates syngas into an hydrogen-rich stream and second stream comprising of sulfur compounds(primarily hydrogen sulfide)carbon dioxide (CO2), and other impurities. The adsorbent technology testing that has been performed to date utilized syngas streams derived from higher rank coals and petcoke. Using data from experiments based on petcoke-derived syngas, replacing the

33

Establishment of the Center for Advanced Separation Technologies  

SciTech Connect (OSTI)

This Final Technical Report covers the eight sub-projects awarded in the first year and the five projects awarded in the second year of Cooperative Agreement DE-FC26-01NT41091: Establishment of the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2006-09-30T23:59:59.000Z

34

Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process  

E-Print Network [OSTI]

and high temperature ion transport membranes. While polymeric membranes can produce oxygen enriched air of various concentrations, ion transport membranes can produce purities of close to 100%. Both membraHybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process Thomas

Struchtrup, Henning

35

Research and development of hydrogen separation technology with inorganic membranes  

SciTech Connect (OSTI)

Inorganic membrane technology has long been expected to provide new economical methods for industrial and waste management processes. At this time, the only commercially valuable inorganic membranes are the ultra filters derived from the French process that was used to produce the barrier for the French Gaseous Diffusion Plants. But these membranes are very expensive and have limited areas of application. Over the past fifteen years, scientists now in the Inorganic Membrane Technology Laboratory (IMTL) in Oak Ridge, Tennessee have developed theories and processes for inorganic membranes that can be used to design and produce inorganic membranes for a very broad range of applications. A part of the fabrication process is an adaptive spinoff from the still classified process used to manufacture barriers for the U.S. Gaseous Diffusion Process. Although that part of the process is classified, it is a very flexible and adaptable process and it can be used with a broad range of materials. With the theories and design capabilities developed in the last fifteen years, this new adaptive manufacturing technology can be used to manufacture commercial inorganic membranes that are not useful for the separation of uranium isotopes and they have little or no relation to the barriers that were used to separate uranium isotopes. The development and deployment of such inorganic membranes can be very beneficial to U.S. industry. Inorganic membranes can be specifically designed and manufactured for a large number of different applications. Such membranes can greatly improve the efficiency of a broad range of industrial processes and provide new technology for waste management. These inorganic membranes have the potential for major energy savings and conservation of energy. They can provide the means for significant improvements in the competitiveness of US Industry and improve the economy and health and welfare of the nation.

Fain, D.E.

1999-07-01T23:59:59.000Z

36

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2.3: Sulfur Primer  

SciTech Connect (OSTI)

This deliverable is Subtask 2.3 of Task 2, Gas Cleanup Design and Cost Estimates, of NREL Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Subtask 2.3 builds upon the sulfur removal information first presented in Subtask 2.1, Gas Cleanup Technologies for Biomass Gasification by adding additional information on the commercial applications, manufacturers, environmental footprint, and technical specifications for sulfur removal technologies. The data was obtained from Nexant's experience, input from GTI and other vendors, past and current facility data, and existing literature.

Nexant Inc.

2006-05-01T23:59:59.000Z

37

Oxygen reduction at platimun/ionomer interface: effects of phase separation of ionomer  

SciTech Connect (OSTI)

Oxygen reduction reaction (ORR) at the interface between platinum and recast ionomers (Nafion EW 1100 and 950 and 6F-40) was studied at different temperatures (20--80{sup o}C) and humidities (10--100%) employing smooth Pt and Pt-black-covered ultramicroelectrodes. ORR was strongly inhibited on smooth electrodes. The inhibition increased with the reduction time, temperature and humidity, but was absent for Nafion EW 1100 in contact with liquid water. It was attributed to the hydrophobic component of ionomer blocking both active sites and oxygen transport. It was postulated that the dynamic changes in interfacial phase separation of ionomer are facilitated by the attractive interactions between the hydrophobic component of ionomer and bare platinum and between oxide-covered Pt and the hydrophilic component of ionomer. These interactions were also proposed to be responsible for the differences in ORR voltammetry for films prepared and equilibrated under different conditions. The decrease in ORR inhibition, Nafion EW 950> Nafion EW 1100> 6F-40, was correlated with physical and molecular properties of the ionomers. The lack of inhibition for Pt-black-covered electrodes was attributed to the more random distribution of ionomer chains and the high activation barriers for the ionomer restructuring at rough interfaces.

Chlistunoff, Jerzy [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

38

Oxygen off-stoichiometry and phase separation in EuO thin films  

SciTech Connect (OSTI)

We report on our study on the influence of the growth conditions on the europium/oxygen stoichiometry, morphology, magnetic properties, and electrical conductivity of EuO thin films. SQUID magnetometry and x-ray photoelectron spectroscopy were utilized as complementary techniques to determine the oxygen content of EuO{sub 1{+-}x} thin films grown by molecular beam epitaxy with and without the employment of the so-called Eu distillation process. We found indications for phase separation to occur in Eu-rich as well as in over-oxidized EuO for films grown at substrate temperatures below the Eu distillation temperature. Only a fraction of the excess Eu contributes to the metal-insulator transition in Eu-rich films grown under these conditions. We also observed that the surfaces of these films were ill defined and may even contain more Eu excess than the film average. Only EuO films grown under distillation conditions are guaranteed to have the same magnetic and electrical properties as stoichiometric bulk EuO, and to have surfaces with the proper Eu/O stoichiometry and electronic structure.

Altendorf, S. G.; Efimenko, A.; Oliana, V. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany); Kierspel, H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Rata, A. D.; Tjeng, L. H. [Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany)

2011-10-15T23:59:59.000Z

39

Research and development separation technology: The DOE Industrial Energy Conservation Program  

SciTech Connect (OSTI)

This brochure summarizes the Office of Industrial Programs' RandD efforts in the advancement of separation technology. The purpose of this brochure is to provide interested parties with information on federal industrial energy conservation activities in separation technology. The brochure is comprised of the following sections: Separation Technology, summarizes the current state of separation technology and its uses. Potential Energy Savings, discusses the potential for industrial energy conservation through the implementation of advanced separation processes. Office of Industrial Programs' RandD Efforts in Separation Technology Development, describes the separation RandD projects conducted by IP. RandD Data Base, lists contractor, principal investigator, and location of each separation-related RandD effort sponsored by IP.

Not Available

1987-07-01T23:59:59.000Z

40

Advanced Acid Gas Separation Technology for Clean Power and Syngas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Syngas Processing Systems Syngas Processing Systems Advanced Acid Gas Separation Technology for Clean Power and Syngas Applications Air Products and Chemicals, Inc. Project Number: FE0013363 Project Description In this project, Air Products will operate a two-bed mobile system at the National Carbon Capture Center (NCCC) facility. A slipstream of authentic, high-hydrogen syngas based on low-rank coal will be evaluated as the feedstock. Testing will be conducted for approximately eight weeks, thereby providing far longer adsorbent exposure data than demonstrated to date. By utilizing real-world, high- hydrogen syngas, information necessary to understand the utility of the system for methanol production will be made available. In addition, Air Products will also operate a multi-bed PSA process development unit (PDU), located at its Trexlertown, PA headquarters, to evaluate the impact of incorporating pressure equalization steps in the process cycle. This testing will be conducted utilizing a sulfur-free, synthetic syngas, and will improve the reliability of the prediction of the system's operating performance at commercial scale.

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

42

NETL: Gasification Systems - Gas Separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation Separation Ion-Transport Membrane Oxygen Separation Modules Ion-Transport Membrane Oxygen Separation Modules Gas separation unit operations represent major cost elements in gasification plants. The gas separation technology being supported in the DOE program promises significant reduction in cost of electricity, improved thermal efficiency, and superior environmental performance. Gasification-based energy conversion systems rely on two gas separation processes: (1) separation of oxygen from air for feed to oxygen-blown gasifiers; and (2) post-gasification separation of hydrogen from carbon dioxide following (or along with) the shifting of gas composition when carbon dioxide capture is required or hydrogen is the desired product. Research efforts include development of advanced gas separation

43

Reduction Kinetics of Cu-Based Oxygen Carriers for Chemical Looping Air Separation  

Science Journals Connector (OSTI)

Only Sahir et al. performed a rate analysis from the reported batch fluidized bed CLOU experimental data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ... data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ...

Kun Wang; Qingbo Yu; Qin Qin

2013-08-02T23:59:59.000Z

44

The generation of singlet Delta oxygen - A technology overview. [For use in chemical oxygen iodine lasers  

SciTech Connect (OSTI)

The rate of generation of O2(1Delta g) using the chlorine-basic-hydrogen-peroxide reaction is a key element to predict the performance of the chemical oxygen iodine laser. O2(1Delta g) carries the energy in the laser, and thus is one of the prime determinants of power in the flow. To predict the performance of O2(1Delta g) generators requires the prediction of the utilization of chlorine, the yield of excited oxygen, and the concentration of potential contaminants in the chemical exhaust of the generator. This paper describes an approach to the analysis of O2(1Delta g) generators. 6 refs.

Mcdermott, W.E. (Rockwell International Corp., Rocketdyne Div., Canoga Park, CA (United States))

1992-07-01T23:59:59.000Z

45

Potential Energy Savings by Using Alternative Technologies for the Separation of Fluid Mixtures  

E-Print Network [OSTI]

POTENTIAL ENERGY SA~INGS BY USING ALTERNATIVE TECHNOLOGIES FOR THE SEPARATION OF FLUID MIXTURES J. L. BRAVO CENTER FOR ENERGY STUDIES THE UNIVERSITY OF ABSTRACT The focus of this work is to analyze alternative processes and technologies... for the separation of fluid mixtures with respect to energy consumption. In an effort to illustrate the dramatic potential energy savings of various alternative separation processes, evaluations of such processes for three industrially important fluid mixtures...

Bravo, J. L.

46

Conjugates of Actinide Chelator-Magnetic Nanoparticles for Used Fuel Separation Technology  

SciTech Connect (OSTI)

The actinide separation method using magnetic nanoparticles (MNPs) functionalized with actinide specific chelators utilizes the separation capability of ligand and the ease of magnetic separation. This separation method eliminated the need of large quantity organic solutions used in the liquid-liquid extraction process. The MNPs could also be recycled for repeated separation, thus this separation method greatly reduces the generation of secondary waste compared to traditional liquid extraction technology. The high diffusivity of MNPs and the large surface area also facilitate high efficiency of actinide sorption by the ligands. This method could help in solving the nuclear waste remediation problem.

You Qiang; Andrzej Paszczynski; Linfeng Rao

2011-10-30T23:59:59.000Z

47

MassMass transfer andtransfer and separation technologyseparation technology  

E-Print Network [OSTI]

liquid extraction involves three stages: ­ Contacting / extraction al-extraction.j ­ Separation the component of interest solute (A) will distribute over extract (E, phase II or 2) and raffinate (R, phase I with equilibrium constant K: 4 erföringo cA,II/cA,I = K´ , or Massöve xA,E/xA,R = xA,II/xA,I = xA,2/xA,1 = K K´= K

Zevenhoven, Ron

48

Advanced Refractory and Anti-Wearing Technology of Cyclone Separator in CFB Boiler  

Science Journals Connector (OSTI)

The circulating fluidized bed is playing more and more vital role in the electric power field. Cyclone separator as the heart of the circulating fluidized bed combustion boiler, the technology of fire-resistant a...

H. P. Chen; Y. Q. Shen; X. H. Wang…

2010-01-01T23:59:59.000Z

49

Advanced separation technology for flue gas cleanup. Topical report  

SciTech Connect (OSTI)

The objective of this work is to develop a novel system for regenerable SO{sub 2} and NO{sub x} scrubbing of flue gas that focuses on (1) a novel method for regenerating spent SO{sub 2} scrubbing liquor and (2) novel chemistry for reversible absorption of NO{sub x}. In addition, high efficiency hollow fiber contactors (HFC) are proposed as the devices for scrubbing the SO{sub 2} and NO{sub x} from the flue gas. The system will be designed to remove more than 95% of the SO{sub 2} and more than 75% of the NO{sub x} from flue gases typical of pulverized coal-fired power plants at a cost that is at least 20% less than combined wet limestone scrubbing of SO{sub x} and selective catalytic reduction of NO{sub x}. The process will generate only marketable by-products. Our approach is to reduce the capital cost by using high-efficiency hollow fiber devices for absorbing and desorbing the SO{sub 2} and NO{sub x}. We will also introduce new process chemistry to minimize traditionally well-known problems with SO{sub 2} and NO{sub x} absorption and desorption. Our novel chemistry for scrubbing NO{sub x} will consist of water-soluble phthalocyanine compounds invented by SRI as well as polymeric forms of Fe{sup ++} complexes similar to traditional NO{sub x} scrubbing media. The final novelty of our approach is the arrangement of the absorbers in cassette (stackable) form so that the NO{sub x} absorber can be on top of the SO{sub x} absorber. This arrangement is possible only because of the high efficiency of the hollow fiber scrubbing devices, as indicated by our preliminary laboratory data. This arrangement makes it possible for the SO{sub 2} and NO{sub x} scrubbing chambers to be separate without incurring the large ducting and gas pressure drop costs necessary if a second conventional absorber vessel were used. Because we have separate scrubbers, we will have separate liquor loops and simplify the chemical complexity of simultaneous SO{sub 2}/NO{sub x} scrubbing.

Bhown, A.S.; Alvarado, D.; Pakala, N.; Ventura, S. [and others

1995-01-01T23:59:59.000Z

50

Development of Brazing Technology for Use in High- Temperature Gas Separation Equipment  

SciTech Connect (OSTI)

The development of high-temperature electrochemical devices such as oxygen and hydrogen separators, fuel gas reformers, solid oxide fuel cells, and chemical sensors is part of a rapidly expanding segment of the solid state technology market. These devices employ an ionic conducting ceramic as the active membrane that establishes the electrochemical potential of the device, either under voltage (i.e. to carry out gas separation) or under chemical gradient (to develop an electrical potential and thereby generate electrical power). Because the device operates under an ionic gradient that develops across the electrolyte, hermiticity across this layer is paramount. That is, not only must this thin ceramic membrane be dense with no interconnected porosity, but it must be connected to the rest of the device, typically constructed from a heat resistant alloy, with a high-temperature, gas-tight seal. A significant engineering challenge in fabricating these devices is how to effectively join the thin electrochemically active membrane to the metallic body of the device such that the resulting seal is hermetic, rugged, and stable during continuous high temperature operation. Active metal brazing is the typical method of joining ceramic and metal engineering components. It employs a braze alloy that contains one or more reactive elements, often titanium, which will chemically reduce the ceramic faying surface and greatly improve its wetting behavior and adherence with the braze. However, recent studies of these brazes for potential use in fabricating high-temperature electrochemical devices revealed problems with interfacial oxidation and subsequent joint failure [1,2]. Specifically, it was found that the introduction of the ceramic electrolyte and/or heat resistant metal substrate dramatically affects the inherent oxidation behavior of the braze, often in a deleterious manner. These conclusions pointed to the need for an oxidation resistant, high-temperature ceramic-to-metal braze and consequently lead to the development of the novel reactive air brazing (RAB) concept. The goal in RAB is to reactively modify one or both oxide faying surfaces with an oxide compound dissolved in a molten noble metal alloy such that the newly formed surface is readily wetted by the remaining liquid filler material. In many respects, this concept is similar to active metal brazing, except that joining can be conducted in air and the final joint will be resistant to oxidation at high temperature. Potentially, there are a number of metal oxide-noble metal systems that can be considered for RAB, including Ag-CuO, Ag-V2O5, and Pt-Nb2O5. Our current interest is in determining whether the Ag-CuO system is suitable for air brazing functional ceramic-to-metal joints such as those needed in practical electrochemical devices. In a series of studies, the wetting behavior of the Ag-CuO braze was investigated with respect to a number of potential hydrogen separation, oxygen separation, and fuel cell electrolyte membrane materials and heat resistant metal systems, including: alumina, (La0.6Sr0.4)(Co0.2Fe0.8)O3, (La0.8Sr0.2)FeO3, YSZ, fecralloy, and Crofer-22APU. Selected findings from these studies as well as from our work on joint strength and durability during high-temperature exposure testing will be discussed.

Weil, K.S.; Hardy, J.S.; Kim, J.Y.

2003-04-23T23:59:59.000Z

51

99Mo/99mTc separation: An assessment of technology options  

Science Journals Connector (OSTI)

Several strategies for the effective separation of 99mTc from 99Mo have been developed and validated. Due to the success of column chromatographic separation using acidic alumina coupled with high specific activity fission 99Mo (F 99Mo) for production of 99Mo/99mTc generators, however, most technologies until recently have generated little interest. The reduced availability of F 99Mo and consequently the shortage of 99Mo/99mTc column generators in the recent past have resurrected interest in the production of 99Mo as well as 99mTc by alternate routes. Most of these alternative production processes require separation techniques capable of providing clinical grade 99mTc from low specific activity 99Mo or irradiated Mo targets. For this reason there has been renewed interest in alternate separation routes. This paper reviews the reported separation technologies which include column chromatography, solvent extraction, sublimation and gel systems that have been traditionally used for the fabrication of 99Mo/99mTc generator systems. The comparative advantage, disadvantage, and technical challenges toward adapting the emerging requirements are discussed. New developments such as solid-phase column extraction, electrochemical separation, extraction chromatography, supported liquid membrane (SLM) and thermochromatographic techniques are also being evaluated for their potential application in the changed scenario of providing 99mTc from alternate routes. Based on the analysis provided in this review, it appears that some proven separation technologies can be quickly resurrected for the separation of clinical grade 99mTc from macroscopic levels of reactor or cyclotron irradiated molybdenum targets. Furthermore, emerging technologies can be developed further to respond to the expected changing modes of 99mTc production.

Ashutosh Dash; F.F. (Russ) Knapp Jr.; M.R.A. Pillai

2013-01-01T23:59:59.000Z

52

Appendix B: CArBon dioxide CApture teChnology SheetS Oxygen PrOductiOn  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen PrOductiOn Oxygen PrOductiOn B-500 Oxygen PrOductiOn u.S. dePartment Of energy advanced carbOn diOxide caPture r&d PrOgram: technOlOgy uPdate, may 2013 itm Oxygen technOlOgy fOr integratiOn in igcc and Other advanced POwer generatiOn SyStemS primary project goals Air Products and Chemicals set out to design and develop an ion transport membrane (ITM) based on ceramics that selectively transport oxygen (O 2 ) ions when operated at high temperature. This high-temperature process may be integrated with advanced power genera- tion processes that require O 2 as a feedstock, such as integrated gasification combined cycle (IGCC) and other clean energy and industrial applications. technical goals * Design, construct, and operate a 0.1-ton/day (TPD) technology development unit

53

Sartobind IDA 75 A Separation Technology Based on Metal Chelate Membrane Adsorbers  

E-Print Network [OSTI]

Sartobind® IDA 75 A Separation Technology Based on Metal Chelate Membrane Adsorbers Operating Instructions 85030-517-46 Storage before use Unused Sartobind Metal Chelate Membrane Adsorbers can be stored. Introduction Sartobind Metal Chelate adsorbers represent a new generation of Immobilized Metal Affinity

Lebendiker, Mario

54

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network [OSTI]

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

55

SingleSep Disposable Capsules A Separation Technology Based on Microporous Membranes  

E-Print Network [OSTI]

Sartobind SingleSep Disposable Capsules A Separation Technology Based on Microporous Membranes into a conventional housing for easy and quick handling, making ion exchange purification nearly as easy as filtration procedures. For upscaling to production and downstream pro- cessing, Sartorius offers Sartobind Multi

Lebendiker, Mario

56

CO2 CAPTURE PROJECT - AN INTEGRATED, COLLABORATIVE TECHNOLOGY DEVELOPMENT PROJECT FOR NEXT GENERATION CO2 SEPARATION, CAPTURE AND GEOLOGIC SEQUESTRATION  

SciTech Connect (OSTI)

The CO{sub 2} Capture Project (CCP) is a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, Eni, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (1) European Union (DG Res & DG Tren), (2) Norway (Klimatek) and (3) the U.S.A. (Department of Energy). The project objective is to develop new technologies, which could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies are to be developed to ''proof of concept'' stage by the end of 2003. The project budget is approximately $24 million over 3 years and the work program is divided into eight major activity areas: (1) Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. (2) Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. (3) Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. (4) Capture Technology, Pre -Combustion: in which, natural gas and petroleum coke are converted to hydrogen and CO{sub 2} in a reformer/gasifier. (5) Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. (6) New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. (7) Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. (8) Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Technology development work dominated the past six months of the project. Numerous studies are making substantial progress towards their goals. Some technologies are emerging as preferred over others. Pre-combustion Decarbonization (hydrogen fuel) technologies are showing good progress and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. As expected, post-combustion technologies are emerging as higher cost options that may have niche roles. Storage, measurement, and verification studies are moving rapidly forward. Hyper-spectral geo-botanical measurements may be an inexpensive and non-intrusive method for long-term monitoring. Modeling studies suggest that primary leakage routes from CO{sub 2} storage sites may be along wellbores in areas disturbed by earlier oil and gas operations. This is good news because old wells are usually mapped and can be repaired during the site preparation process. Many studies are nearing completion or have been completed. Their preliminary results are summarized in the attached report and presented in detail in the attached appendices.

Dr. Helen Kerr

2003-08-01T23:59:59.000Z

57

Lithium Isotope Separation & Enrichment Technologies (4577), 2/9/2012  

Broader source: Energy.gov (indexed) [DOE]

Lithium Isotope Separation & Enrichment Technologies (4577) Lithium Isotope Separation & Enrichment Technologies (4577) Program or Field Office: Y-12 Site Office Location(s) (City/County/State): Oak Ridge, Anderson County, Tennessee Proposed Action Description: Submit by E-mail This is entirely a paper study. The scope of this Cooperative Research and Development (CRADA) is to: 1) systematically review existing potential lithium enrichment processes, 2) evaluate the individual process, 3) determine the economic feasibility, 4) rank the processes as a function of economic feasibility, technical probability, Health, Safety and Environmental impacts, 5) identify best candidate technology for proof of principle evaluation, 6) develop outside funding proposals, and 7) pursue funding to perform proof of principle/prototyping of candidate

58

Separation science and technology. Semiannual progress report, October 1993--March 1994  

SciTech Connect (OSTI)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory (ANL), in the period October 1993-March 1994. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process, (2) treatment schemes for liquid wastes stored are being generated at ANL, (3) a process based on sorbing modified TRUEX solvent on magnetic beads to be used for separation of contaminants from radioactive and hazardous waste streams, and (4) a process that uses low-enriched uranium targets for production of {sup 99}Mo for nuclear medicine uses.

Vandegrift, G.F.; Aase, S.B.; Buchholz, B. [and others

1997-12-01T23:59:59.000Z

59

Pilot-Scale Demonstration of Pefi's Oxygenated Transportation Fuels Production Technology  

SciTech Connect (OSTI)

Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

None

2005-05-01T23:59:59.000Z

60

Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals  

SciTech Connect (OSTI)

Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

Kloosterman, Jeff

2012-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Evaluation of the Boeing PAN AIR technologies code (A502i) through prediction of separation forces on the GBU-24 ; .  

E-Print Network [OSTI]

??The Boeing PAN AIR Technologies code (A502i) is investigated to explore its suitability for determination of separation forces on ordnance. To this end, A502i is… (more)

LeTourneau, Matthew A.

1996-01-01T23:59:59.000Z

62

A design-for-environment study for plating processes -- Evaluations of wastewater precipitation and separation technologies  

SciTech Connect (OSTI)

A wastewater pollution prevention study was performed for two plating processes. This study included wastewater precipitation process analysis, and evaluation of separation and recycling alternatives. The pollution prevention opportunity assessment goals are: to reduce and reuse wastewater, to develop a design-for-environment plating process, and to conduct a material life-cycle analysis (LCA) for selected materials and with well-defined boundary. From an analysis of coordination chemistry and a series of precipitation process tests, it was found that treatment with optimized pH and mixing rate, proper coprecipitants (such as iron salts), and chemical dosages were needed to dissociate metal ions from the chelated complexes (Cu-EDTA) in the wastewater. In this study, reverse osmosis and ion exchange, separation/recycling technologies were also evaluated. A water reclamation project with these two technologies was implemented. The analysis indicated, that with recycling systems, 33% of the wastewater could be reclaimed and more than 90% of reduction of copper in wastewater was achieved. With the LCA, a greener approach was implemented to reduce the wasted parts disposal problems.

Chang, L.Y. [Lawrence Berkeley National Lab., CA (United States)

1995-12-31T23:59:59.000Z

63

Chemical Looping Air Separation Unit and Methods of Use  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Looping Air Separation Unit and Methods of Use Looping Air Separation Unit and Methods of Use Contact NETL Technology Transfer Group techtransfer@netl.doe.gov October 2012 Opportunity Research is currently active on the patent-pending technology "Chemical Looping Air Separation Unit and Methods of Use" that combines the best attributes of chemical looping and oxy-fuel combustion technologies. Following patent approval, the technology will be available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Significance * Combines chemical looping and oxy-fuel technologies * Separates oxygen from air at high efficiencies * Removes CO

64

The integration of innovative technologies into a physical-separation-based soil washing system  

SciTech Connect (OSTI)

An innovative system`s approach to the treatment of soils at the Fernald Environmental Management Project (FEMP) has been proposed to effectively and cost competitively treat a significant mass of soil. The use of an integrated soil treatment system to decontaminate FEMP soils is a unique application of the soil washing technology. Due to the unfavorable soil particle size distribution and the ubiquitous distribution of uranium among these particle size fractions, conventional soil washing processes commonly used on predominantly sandy soils alone may not achieve the desirable waste minimization level without the inclusion of innovative technologies. This objective of this paper is to briefly describe the physical separation and chemical extraction process commonly used in soil washing operation and to present the baseline soil washing approach used on FEMP soils. Noting the successful and not-so-successful processes within the soil washing operation at the FEMP, a proposed innovative system`s approach to treating FEMP soils will be described. This system`s approach will integrate a conventional soil washing operation with proposed innovative technologies.

Krstich, M.A.

1995-11-01T23:59:59.000Z

65

Application of linear multiple model predictive control (MMPC) framework towards dynamic maximazation of oxygen yield in an elevated-pressure air separation unit  

SciTech Connect (OSTI)

In a typical air separation unit (ASU) utilizing either a simple gaseous oxygen (GOX) cycle or a pumped liquid oxygen (PLOX) cycle, the flowrate of liquid nitrogen (LN2) stream connecting high-pressure and low-pressure ASU columns plays an important role in the total oxygen yield. It has been observed that this yield reaches a maximum at a certain optimal flowrate of LN2 stream. At nominal full-load operation, the flowrate of LN2 stream is maintained near this optimum value, whereas at part-load conditions this flowrate is typically modified in proportion with the load-change (oxygen demand) through a ratio/feed-forward controller. Due to nonlinearity in the entire ASU process, the ratio-modified LN2 flowrate does not guarantee an optimal oxygen yield at part-load conditions. This is further exacerbated when process disturbances in form of “cold-box” heat-leaks enter the system. To address this problem of dynamically maximizing the oxygen yield while the ASU undergoes a load-change and/or a process disturbance, a multiple model predictive control (MMPC) algorithm is proposed. This approach has been used in previous studies to handle large ramp-rates of oxygen demand posed by the gasifier in an IGCC plant. In this study, the proposed algorithm uses linear step-response “blackbox” models surrounding the operating points corresponding to maximum oxygen yield points at different loads. It has been shown that at any operating point of the ASU, the MMPC algorithm, through model-weight calculation based on plant measurements, naturally and continuously selects the dominant model(s) corresponding to the current plant state, while making control-move decisions that approach the maximum oxygen yield point. This dynamically facilitates less energy consumption in form of compressed feed-air compared to a simple ratio control during load-swings. In addition, since a linear optimization problem is solved at each time step, the approach involves much less computational cost compared to a firstprinciple based nonlinear MPC. Introduction

Mahapatra, P.; Zitney, S.; Bequette, B. Wayne

2012-01-01T23:59:59.000Z

66

Wool scouring waste treatment by a combination of coagulation–flocculation process and membrane separation technology  

Science Journals Connector (OSTI)

Wool scouring produces a highly polluting effluent. This study discusses a process based on a combination of coagulation–flocculation process followed by a membrane separation technology to improve the removal efficiency. The optimum operating conditions for the coagulation–flocculation process were pH 4 and 500 mg/L in ferric chloride. Under these conditions, the settled liquor was treated with ceramic and polymeric membranes of various molecular weight cut-offs (MWCO). Rejection of total organic carbon (TOC) reached a maximum value of 86% for a 0.3 kDa MWCO polymeric membrane. Membrane fouling was more significant in the ceramic membranes than the polymeric ones. High quality permeate effluent was obtained by operating in a batch retentate-recycling mode for a 0.3 kDa MWCO membrane. A mathematical model permits estimates of TOC concentrations in the retentate and permeate obtainable by working in the batch retentate-recycling mode with different MWCO membranes.

Jordi Labanda; Joan Llorens

2008-01-01T23:59:59.000Z

67

AISI/DOE Technology Roadmap Program Hot Oxygen Injection Into The Blast Furnace  

SciTech Connect (OSTI)

Increased levels of blast furnace coal injection are needed to further lower coke requirements and provide more flexibility in furnace productivity. The direct injection of high temperature oxygen with coal in the blast furnace blowpipe and tuyere offers better coal dispersion at high local oxygen concentrations, optimizing the use of oxygen in the blast furnace. Based on pilot scale tests, coal injection can be increased by 75 pounds per ton of hot metal (lb/thm), yielding net savings of $0.84/tm. Potential productivity increases of 15 percent would yield another $1.95/thm. In this project, commercial-scale hot oxygen injection from a ''thermal nozzle'' system, patented by Praxair, Inc., has been developed, integrated into, and demonstrated on two tuyeres of the U.S. Steel Gary Works no. 6 blast furnace. The goals were to evaluate heat load on furnace components from hot oxygen injection, demonstrate a safe and reliable lance and flow control design, and qualitatively observe hot oxygen-coal interaction. All three goals have been successfully met. Heat load on the blowpipe is essentially unchanged with hot oxygen. Total heat load on the tuyere increases about 10% and heat load on the tuyere tip increases about 50%. Bosh temperatures remained within the usual operating range. Performance in all these areas is acceptable. Lance performance was improved during testing by changes to lance materials and operating practices. The lance fuel tip was changed from copper to a nickel alloy to eliminate oxidation problems that severely limited tip life. Ignition flow rates and oxygen-fuel ratios were changed to counter the effects of blowpipe pressure fluctuations caused by natural resonance and by coal/coke combustion in the tuyere and raceway. Lances can now be reliably ignited using the hot blast as the ignition source. Blowpipe pressures were analyzed to evaluate ht oxygen-coal interactions. The data suggest that hot oxygen increases coal combustion in the blow pipe and tuyere by 30, in line with pilot scale tests conducted previously.

Michael F. Riley

2002-10-21T23:59:59.000Z

68

Advanced Membrane Separation Technologies for Energy Recovery from Industrial Process Streams  

SciTech Connect (OSTI)

Recovery of energy from relatively low-temperature waste streams is a goal that has not been achieved on any large scale. Heat exchangers do not operate efficiently with low-temperature streams and thus require such large heat exchanger surface areas that they are not practical. Condensing economizers offer one option for heat recovery from such streams, but they have not been widely implemented by industry. A promising alternative to these heat exchangers and economizers is a prototype ceramic membrane system using transport membrane technology for separation of water vapor and recovery of heat. This system was successfully tested by the Gas Technology Institute (GTI) on a natural gas fired boiler where the flue gas is relatively clean and free of contaminants. However, since the tubes of the prototype system were constructed of aluminum oxide, the brittle nature of the tubes limited the robustness of the system and even limited the length of tubes that could be used. In order to improve the robustness of the membrane tubes and make the system more suitable for industrial applications, this project was initiated with the objective of developing a system with materials that would permit the system to function successfully on a larger scale and in contaminated and potentially corrosive industrial environments. This required identifying likely industrial environments and the hazards associated with those environments. Based on the hazardous components in these environments, candidate metallic materials were identified that are expected to have sufficient strength, thermal conductivity and corrosion resistance to permit production of longer tubes that could function in the industrial environments identified. Tests were conducted to determine the corrosion resistance of these candidate alloys, and the feasibility of forming these materials into porous substrates was assessed. Once the most promising metallic materials were identified, the ability to form an alumina membrane layer on the surface of the metallic tubes was evaluated. Evaluation of this new style of membrane tube involved exposure to SO{sub 2} containing gases as well as to materials with a potential for fouling. Once the choice of substrate and membrane materials and design were confirmed, about 150 tubes were fabricated and assembled into three modules. These modules were mounted on an industrial size boiler and their performance carefully monitored during a limited testing period. The positive results of this performance test confirm the feasibility of utilizing such a system for recovery of heat and water from industrial waste streams. The improved module design along with use of long metallic substrate tubes with a ceramic membrane on the outer surface resulted in the successful, limited scale demonstration of the Transport Membrane Condenser (TMC) technology in the GTI test facility. This test showed this technology can successfully recover a significant amount of heat and water from gaseous waste streams. However, before industry will make the investment to install a full scale TMC, a full scale system will need to be constructed, installed and successfully operated at a few industrial sites. Companies were identified that had an interest in serving as a host site for a demonstration system.

Keiser, J.R.; Wang, D. (Gas Technology Institute); Bischoff, B.; Ciora (Media and Process Technology); Radhakrishnan, B.; Gorti, S.B.

2013-01-14T23:59:59.000Z

69

CO2 Capture Project-An Integrated, Collaborative Technology Development Project for Next Generation CO2 Separation, Capture and Geologic Sequestration  

SciTech Connect (OSTI)

The CO{sub 2} Capture Project (CCP) was a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, ENI, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union [DG RES & DG TREN], the Norwegian Research Council [Klimatek Program] and the U.S. Department of Energy [NETL]). The project objective was to develop new technologies that could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies were to be developed to ''proof of concept'' stage by the end of 2003. Certain promising technology areas were increased in scope and the studies extended through 2004. The project budget was approximately $26.4 million over 4 years and the work program is divided into eight major activity areas: Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. Capture Technology, Pre-Combustion: in which, natural gas and petroleum cokes are converted to hydrogen and CO{sub 2} in a reformer/gasifier. Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Pre-combustion De-carbonization (hydrogen fuel) technologies showed excellent results and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. Post-combustion technologies emerged as higher cost options that may only have niche roles. Storage, measurement, and verification studies suggest that geologic sequestration will be a safe form of long-term CO{sub 2} storage. Economic modeling shows that options to reduce costs by 50% exist. A rigorous methodology for technology evaluation was developed. Public acceptance and awareness were enhanced through extensive communication of results to the stakeholder community (scientific, NGO, policy, and general public). Two volumes of results have been published and are available to all. Well over 150 technical papers were produced. All funded studies for this phase of the CCP are complete. The results are summarized in this report and all final reports are presented in the attached appendices.

Helen Kerr; Linda M. Curran

2005-04-15T23:59:59.000Z

70

CO2 CAPTURE PROJECT-AN INTEGRATED, COLLABORATIVE TECHNOLOGY DEVELOPMENT PROJECT FOR NEXT GENERATION CO2 SEPARATION, CAPTURE AND GEOLOGIC SEQUESTRATION  

SciTech Connect (OSTI)

The CO{sub 2} Capture Project (CCP) is a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, Eni, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union (DG Res & DG Tren), Norway (Klimatek) and the U.S.A. (Department of Energy)). The project objective is to develop new technologies, which could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies are to be developed to ''proof of concept'' stage by the end of 2003. The project budget is approximately $24 million over 3 years and the work program is divided into eight major activity areas: (1) Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. (2) Capture Technology, Post Combustion--technologies, which can remove CO{sub 2} from exhaust gases after combustion. (3) Capture Technology, Oxyfuel--where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with wet high concentrations of CO{sub 2} for storage. (4) Capture Technology, Pre-Combustion--in which, natural gas and petroleum coke are converted to hydrogen and CO{sub 2} in a reformer/gasifier. (5) Common Economic Model/Technology Screening--analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. (6) New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. (7) Geologic Storage, Monitoring and Verification (SMV)--providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. (8) Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Technology development work dominated the past six months of the project. Numerous studies have completed their 2003 stagegate review and are reported here. Some will proceed to the next stagegate review in 2004. Some technologies are emerging as preferred over others. Pre-combustion De-carbonization (hydrogen fuel) technologies are showing excellent results and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. The workscopes planned for the next key stagegates are under review before work begins based on the current economic assessment of their performance. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. As expected, post-combustion technologies are emerging as higher cost options but even so some significant potential reductions in cost have been identified and will continue to be explored. Storage, measurement, and verification studies are moving rapidly forward and suggest that geologic sequestration can be a safe form of long-term CO{sub 2} storage. Hyper-spectral geo-botanical measurements may be an inexpensive and non-intrusive method for long-term monitoring. Modeling studies suggest that primary leakage routes from CO{sub 2} storage sites may be along old wellbores in areas disturbed by earlier oil and gas operations. This is good news because old wells are usually mapped and can be repaired during the site preparation process. Wells are also easy to monitor and intervention is possible if needed. The project will continue to evaluate and bring in novel studies and ideas within the project scope as requested by the DOE. The results to date are summarized in the attached report and presented in detail in the attached appendices.

Helen Kerr

2004-04-01T23:59:59.000Z

71

ITP Chemicals: Hybripd Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction  

Broader source: Energy.gov [DOE]

Energy used to drive separation processes accounts for approximately sixty percent of the total energy used by the chemical and petroleum industries.

72

Preparation of a technology development roadmap for the Accelerator Transmutation of Waste (ATW) System : report of the ATW separations technologies and waste forms technical working group.  

SciTech Connect (OSTI)

In response to a Congressional mandate to prepare a roadmap for the development of Accelerator Transmutation of Waste (ATW) technology, a Technical Working Group comprised of members from various DOE laboratories was convened in March 1999 for the purpose of preparing that part of the technology development roadmap dealing with the separation of certain radionuclides for transmutation and the disposal of residual radioactive wastes from these partitioning operations. The Technical Working Group for ATW Separations Technologies and Waste Forms completed its work in June 1999, having carefully considered the technology options available. A baseline process flowsheet and backup process were identified for initial emphasis in a future research, development and demonstration program. The baseline process combines aqueous and pyrochemical processes to permit the efficient separation of the uranium, technetium, iodine and transuranic elements from the light water reactor (LWR) fuel in the head-end step. The backup process is an all- pyrochemical system. In conjunction with the aqueous process, the baseline flowsheet includes a pyrochemical process to prepare the transuranic material for fabrication of the ATW fuel assemblies. For the internal ATW fuel cycle the baseline process specifies another pyrochemical process to extract the transuranic elements, Tc and 1 from the ATW fuel. Fission products not separated for transmutation and trace amounts of actinide elements would be directed to two high-level waste forms, one a zirconium-based alloy and the other a glass/sodalite composite. Baseline cost and schedule estimates are provided for a RD&D program that would provide a full-scale demonstration of the complete separations and waste production flowsheet within 20 years.

Collins, E.; Duguid, J.; Henry, R.; Karell, E.; Laidler, J.; McDeavitt, S.; Thompson, M.; Toth, M.; Williamson, M.; Willit, J.

1999-08-12T23:59:59.000Z

73

Low cost hydrogen/novel membrane technology for hydrogen separation from synthesis gas  

SciTech Connect (OSTI)

To make the coal-to-hydrogen route economically attractive, improvements are being sought in each step of the process: coal gasification, water-carbon monoxide shift reaction, and hydrogen separation. This report addresses the use of membranes in the hydrogen separation step. The separation of hydrogen from synthesis gas is a major cost element in the manufacture of hydrogen from coal. Separation by membranes is an attractive, new, and still largely unexplored approach to the problem. Membrane processes are inherently simple and efficient and often have lower capital and operating costs than conventional processes. In this report current ad future trends in hydrogen production and use are first summarized. Methods of producing hydrogen from coal are then discussed, with particular emphasis on the Texaco entrained flow gasifier and on current methods of separating hydrogen from this gas stream. The potential for membrane separations in the process is then examined. In particular, the use of membranes for H{sub 2}/CO{sub 2}, H{sub 2}/CO, and H{sub 2}/N{sub 2} separations is discussed. 43 refs., 14 figs., 6 tabs.

Not Available

1986-02-01T23:59:59.000Z

74

Design of a Lunar Rover Utilizing Hydrogen-Oxygen Fuel Cell Technologies.  

E-Print Network [OSTI]

??Future exploration of the solar system will depend on new designs and technologies that are efficient and versatile. Roving systems have explored the Moon and… (more)

Snyder, Michael Phillip

2011-01-01T23:59:59.000Z

75

Review of Possible Technologies for Actinide Separations Using Other Extractants Than TBP  

Science Journals Connector (OSTI)

The properties of the extractants suitable for the new types of separations needed in the nuclear fuel cycle are reviewed. N,N-dialkylamides (RCO-NR’2), diamides ((RR’NCO)2CHR”), dialkylcarbamoylmethylenephosphon...

C. Musikas

1999-01-01T23:59:59.000Z

76

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Feed Systems Feed Systems Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems Air Products and Chemicals, Inc. Project Number: FC26-98FT40343 Project Description Air Products and Chemicals, Inc. is developing, scaling-up, and demonstrating a novel air separation technology for large-scale production of oxygen (O2) at costs that are approximately one-third lower than conventional cryogenic plants. An Ion Transport Membrane (ITM) Oxygen plant co-produces power and oxygen. A phased technology RD&D effort is underway to demonstrate all necessary technical and economic requirements for scale-up and industrial commercialization. The ITM Oxygen production technology is a radically different approach to producing high-quality tonnage oxygen and to enhance the performance of integrated gasification combined cycle and other advanced power generation systems. Instead of cooling air to cryogenic temperatures, oxygen is extracted from air at temperatures synergistic with power production operations. Process engineering and economic evaluations of integrated gasification combined cycle (IGCC) power plants comparing ITM Oxygen with a state-of-the-art cryogenic air separation unit are aimed to show that the installed capital cost of the air separation unit and the installed capital of IGCC facility are significantly lower compared to conventional technologies, while improving power plant output and efficiency. The use of low-cost oxygen in combustion processes would provide cost-effective emission reduction and carbon management opportunities. ITM Oxygen is an enabling module for future plants for producing coal derived shifted synthesis gas (a mixture of hydrogen [H2] and carbon dioxide [CO2]) ultimately for producing clean energy and fuels. Oxygen-intensive industries such as steel, glass, non-ferrous metallurgy, refineries, and pulp and paper may also realize cost and productivity benefits as a result of employing ITM Oxygen.

77

Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications  

SciTech Connect (OSTI)

Air Products is carrying out a scope of work under DOE Award No. DE-FE0012065 “Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications.” The Statement of Project Objectives (SOPO) includes a Task 4f in which a Decision Point shall be reached, necessitating a review of Tasks 2-5 with an emphasis on Task 4f. This Topical Report constitutes the Decision Point Application pertaining to Task 4f. The SOPO under DOE Award No. DE-FE0012065 is aimed at furthering the development of the Ion Transport Membrane (ITM) Oxygen production process toward a demonstration scale facility known as the Oxygen Development Facility (ODF). It is anticipated that the completion of the current SOPO will advance the technology significantly along a pathway towards enabling the design and construction of the ODF. Development progress on several fronts is critical before an ODF project can commence; this Topical Report serves as an early update on the progress in critical development areas. Progress was made under all tasks, including Materials Development, Ceramic Processing Development, Engineering Development, and Performance Testing. Under Task 4f, Air Products carried out a cost and performance study in which several process design and cost parameters were varied and assessed with a process model and budgetary costing exercise. The results show that the major variables include ceramic module reliability, ITM operating temperature, module production yield, and heat addition strategy. High-temperature compact heat exchangers are shown to contribute significant cost benefits, while directly firing into the feed stream to an ITM are even a mild improvement on the high-temperature recuperation approach. Based on the findings to-date, Air Products recommends no changes to the content or emphasis in the current SOPO and recommends its completion prior to another formal assessment of these factors.

Armstrong, Phillip

2014-11-01T23:59:59.000Z

78

Review and assessment of technologies for the separation of strontium from alkaline and acidic media  

SciTech Connect (OSTI)

A literature survey has been conducted to identify and evaluate methods for the separation of strontium from acidic and alkaline media as applied to Hanford tank waste. The most promising methods of solvent extraction, precipitation, and ion exchange are described. The following criteria were used for evaluating the separation methods: Appreciable strontium removal must be demonstrated; Strontium selectivity over bulk components must be demonstrated; The method must show promise for evolving into a practical and fairly simple process; The process should be safe to operate; The method must be robust (i.e., capable of separating strontium from various waste types); Secondary waste generation must be minimized; and The method must show resistance to radiation damage. The methods discussed did not necessarily satisfy all of the above criteria; thus, key areas requiring further development are also given for each method. Less promising solvent extraction, precipitation, and ion exchange methods were also identified; areas for potential development are included in this report.

Orth, R.J.; Kurath, D.E.

1994-01-01T23:59:59.000Z

79

WATER AND WASTEWATER POLISHING USING 3M SELECTIVE SEPARATION REMEDIATION CARTRIDGE TECHNOLOGY  

SciTech Connect (OSTI)

3M has developed technology for selectively removing trace levels of dissolved contaminant materials from liquids using systems operating at flow rates up to 50 gallons per minute. This technology combines active particle chemistries with a particle-loaded membrane to achieve a new medium for liquid waste processing--a spiral wound filter cartridge. This technology has shown success by generating high decontamination factors and reducing contaminants to part per trillion levels. The spiral wound cartridge offers simplified installation, convenient replacement, and clean, easy disposal of a concentrated waste. By incorporating small, high surface area particles (5 to 80 microns) into a sturdy, yet porous, membrane greater removal efficiencies of even trace contaminants can be achieved at higher flow rates than with conventional column systems. In addition, the captive-particle medium prevents channeling of liquids and insures uniform flow across the sorbing particle surface. The cartridges fit into standard, commercially-available housings and whole system capital costs are substantially lower than those of column or reverse osmosis systems. Developmental work at high degrees of water polishing have included removal of mercury from contaminated wastewater, various radionuclides from process water, and organometallic species from surface water discharges. Laboratory testing and on-site demonstration data of these applications show the levels of success that have been achieved thus far.

Hoffmann, K. M.; Scanlan, T. J.; Seely, D. C.

2002-02-25T23:59:59.000Z

80

CO2-Tolerant and Cobalt-Free SrFe0.8Nb0.2O3?? Perovskite Membrane for Oxygen Separation  

Science Journals Connector (OSTI)

The membranes can be integrated with a number of oxygen-involved industry processes, such as oxyfuel combustion and partial oxidation of methane into syngas (POM). ... (22) In the present study, the potential to use Sr(Fe, Nb)O3?? as oxygen permeable membranes, in particular for oxyfuel applications, was experimentally assessed. ... A proper balance between the chemical stability and performance as well as composition simplicity is achieved in SFN82, making it a promising candidate as oxygen permeable membrane for oxyfuel application. ...

Jianxin Yi; Michael Schroeder; Manfred Martin

2013-02-14T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

82

Liquid phase thermal swing chemical air separation  

DOE Patents [OSTI]

A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite. 2 figs.

Erickson, D.C.

1988-05-24T23:59:59.000Z

83

Liquid phase thermal swing chemical air separation  

DOE Patents [OSTI]

A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite.

Erickson, Donald C. (Annapolis, MD)

1988-01-01T23:59:59.000Z

84

Advanced Sorbents as a Versatile Platform for Gas Separation  

SciTech Connect (OSTI)

The program objective was to develop materials and processes for industrial gas separations to reduce energy use and enable waste reduction. The approach chosen combined novel oxygen selective adsorbents and pressure swing adsorption (PSA) processes. Preliminary materials development and process simulation results indicated that oxygen selective adsorbents could provide a versatile platform for industrial gas separations. If fully successful, this new technology offered the potential for reducing the cost of producing nitrogen/oxygen co-products, high purity nitrogen, argon, and possibly oxygen. The potential energy savings for the gas separations are appreciable, but the end users are the main beneficiaries. Lowering the cost of industrial gases expands their use in applications that can employ them for reducing energy consumption and emissions.

Neil Stephenson

2003-09-30T23:59:59.000Z

85

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

86

Low cost hydrogen/novel membrane technology for hydrogen separation from synthesis gas. Task 1, Literature survey  

SciTech Connect (OSTI)

To make the coal-to-hydrogen route economically attractive, improvements are being sought in each step of the process: coal gasification, water-carbon monoxide shift reaction, and hydrogen separation. This report addresses the use of membranes in the hydrogen separation step. The separation of hydrogen from synthesis gas is a major cost element in the manufacture of hydrogen from coal. Separation by membranes is an attractive, new, and still largely unexplored approach to the problem. Membrane processes are inherently simple and efficient and often have lower capital and operating costs than conventional processes. In this report current ad future trends in hydrogen production and use are first summarized. Methods of producing hydrogen from coal are then discussed, with particular emphasis on the Texaco entrained flow gasifier and on current methods of separating hydrogen from this gas stream. The potential for membrane separations in the process is then examined. In particular, the use of membranes for H{sub 2}/CO{sub 2}, H{sub 2}/CO, and H{sub 2}/N{sub 2} separations is discussed. 43 refs., 14 figs., 6 tabs.

Not Available

1986-02-01T23:59:59.000Z

87

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

88

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

89

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

90

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

91

A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants  

SciTech Connect (OSTI)

Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica/silicate are two common potential cycle-limiting minerals for using impaired waters. For produced waters, barium sulfate and calcium sulfate are two additional potential cycle-limiting minerals. For reclaimed municipal wastewater effluents, calcium phosphate scaling can be an issue, especially in the co-presence of high silica. Computational assessment, using a vast amount of Nalco's field data from coal fired power plants, showed that the limited use and reuse of impaired waters is due to the formation of deposit caused by the presence of iron, high hardness, high silica and high alkalinity in the water. Appropriate and cost-effective inhibitors were identified and developed - LL99B0 for calcite and gypsum inhibition and TX-15060 for silica inhibition. Nalco's existing dispersants HSP-1 and HSP-2 has excellent efficacy for dispersing Fe and Mn. ED and EDI were bench-scale tested by the CRADA partner Argonne National Laboratory for hardness, alkalinity and silica removal from synthetic make-up water and then cycled cooling water. Both systems showed low power consumption and 98-99% salt removal, however, the EDI system required 25-30% less power for silica removal. For Phase 2, the EDI system's performance was optimized and the length of time between clean-in-place (CIP) increased by varying the wafer composition and membrane configuration. The enhanced EDI system could remove 88% of the hardness and 99% of the alkalinity with a processing flux of 19.2 gal/hr/m{sup 2} and a power consumption of 0.54 kWh/100 gal water. Bench tests to screen alternative silica/silicate scale inhibitor chemistries have begun. The silica/silicate control approaches using chemical inhibitors include inhibition of silicic acid polymerization and dispersion of silica/silicate crystals. Tests were conducted with an initial silica concentration of 290-300 mg/L as SiO{sub 2} at pH 7 and room temperature. A proprietary new chemistry was found to be promising, compared with a current commercial product commonly used for silica/silicate control. Additional pilot cooling tower testing confirmed

Jasbir Gill

2010-08-30T23:59:59.000Z

92

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries  

SciTech Connect (OSTI)

Li-rich layered material Li1.2Ni0.2Mn0.6O2 possesses high voltage and high specific capacity, which makes it an attractive candidate for the transportation industry and sustainable energy storage systems. The rechargeable capacity of the Li-ion battery is linked largely to the structural stability of the cathode materials during the charge-discharge cycles. However, the structure and cation distribution in pristine (un-cycled) Li1.2Ni0.2Mn0.6O2 have not yet been fully characterized. Using a combination of aberration-corrected scanning/transmission electron microscopy, X-ray dispersive energy spectroscopy (XEDS), electron energy loss spectroscopy (EELS), and complementary multislice image simulation, we have probed the crystal structure, cation/anion distribution, and electronic structure of Li1.2Ni0.2Mn0.6O2 nanoparticle. We discovered that the electronic structure and valence state of transition metal ions show significant variations, which have been identified to be attributed to the oxygen deficiency near the particle surfaces. Characterization of the nanoscale phase separation and cation ordering in the pristine material are critical for understanding the capacity and voltage fading of this material for battery application.

Gu, Meng; Genc, Arda; Belharouak, Ilias; Wang, Dapeng; Amine, Khalil; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

2013-05-14T23:59:59.000Z

93

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL...

94

STATUS OF THE DEVELOPMENT OF IN-TANK/AT-TANK SEPARATIONS TECHNOLOGIES FOR FOR HIGH-LEVEL WASTE PROCESSING FOR THE U.S. DEPARTMENT OF ENERGY  

SciTech Connect (OSTI)

Within the U.S. Department of Energy's (DOE) Office of Technology Innovation and Development, the Office of Waste Processing manages a research and development program related to the treatment and disposition of radioactive waste. At the Savannah River (South Carolina) and Hanford (Washington) Sites, approximately 90 million gallons of waste are distributed among 226 storage tanks (grouped or collocated in 'tank farms'). This waste may be considered to contain mixed and stratified high activity and low activity constituent waste liquids, salts and sludges that are collectively managed as high level waste (HLW). A large majority of these wastes and associated facilities are unique to the DOE, meaning many of the programs to treat these materials are 'first-of-a-kind' and unprecedented in scope and complexity. As a result, the technologies required to disposition these wastes must be developed from basic principles, or require significant re-engineering to adapt to DOE's specific applications. Of particular interest recently, the development of In-tank or At-Tank separation processes have the potential to treat waste with high returns on financial investment. The primary objective associated with In-Tank or At-Tank separation processes is to accelerate waste processing. Insertion of the technologies will (1) maximize available tank space to efficiently support permanent waste disposition including vitrification; (2) treat problematic waste prior to transfer to the primary processing facilities at either site (i.e., Hanford's Waste Treatment and Immobilization Plant (WTP) or Savannah River's Salt Waste Processing Facility (SWPF)); and (3) create a parallel treatment process to shorten the overall treatment duration. This paper will review the status of several of the R&D projects being developed by the U.S. DOE including insertion of the ion exchange (IX) technologies, such as Small Column Ion Exchange (SCIX) at Savannah River. This has the potential to align the salt and sludge processing life cycle, thereby reducing the Defense Waste Processing Facility (DWPF) mission by 7 years. Additionally at the Hanford site, problematic waste streams, such as high boehmite and phosphate wastes, could be treated prior to receipt by WTP and thus dramatically improve the capacity of the facility to process HLW. Treatment of boehmite by continuous sludge leaching (CSL) before receipt by WTP will dramatically reduce the process cycle time for the WTP pretreatment facility, while treatment of phosphate will significantly reduce the number of HLW borosilicate glass canisters produced at the WTP. These and other promising technologies will be discussed.

Aaron, G.; Wilmarth, B.

2011-09-19T23:59:59.000Z

95

Chemical Looping Combustion of Biomass/Coal with Natural Iron Ore as Oxygen Carrier in a Continuous Reactor  

Science Journals Connector (OSTI)

Chemical Looping Combustion of Biomass/Coal with Natural Iron Ore as Oxygen Carrier in a Continuous Reactor ... Chemical looping combustion (CLC) is a new innovative technology with inherent separation of CO2 without energy penalty. ... Experiments on chemical looping combustion of biomass/coal were conducted in a 1 kWth continuous reactor, and an Australia iron ore was selected as oxygen carrier. ...

Haiming Gu; Laihong Shen; Jun Xiao; Siwen Zhang; Tao Song

2010-12-21T23:59:59.000Z

96

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

97

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Natural Ores as Oxygen Carriers in Chemical Looping Combustion ... Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. ...

Hanjing Tian; Ranjani Siriwardane; Thomas Simonyi; James Poston

2013-01-02T23:59:59.000Z

98

Ultracapacitor separator  

DOE Patents [OSTI]

An ultracapacitor includes two solid, nonporous current collectors, two porous electrodes separating the collectors, a porous separator between the electrodes and an electrolyte occupying the pores in the electrodes and separator. The electrolyte is a polar aprotic organic solvent and a salt. The porous separator comprises a wet laid cellulosic material.

Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); LeBlanc, Jr., Oliver Harris (Schenectady, NY)

2001-03-06T23:59:59.000Z

99

Oxygen Concentration Microgradients for Cell Culture.  

E-Print Network [OSTI]

??There is a growing need for technology that can control microscale oxygen gradients onto a tissue or culture sample in vitro. This dissertation introduces the… (more)

Park, Jaehyun

2010-01-01T23:59:59.000Z

100

Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

Swanson, Michael; Henderson, Ann

2012-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Energy Conservation Possibilities Using Gas Separating Membranes  

E-Print Network [OSTI]

The separation of gases using semi permeable membranes is a viable unit operation. A novel composite membrane combined with hollow fiber spinning technology enable Monsanto Co. to offer PRISM (TM); Separators to the industrial market. The separator...

Knieriem, H.; Henis, J. M. S.

1980-01-01T23:59:59.000Z

102

Neptunium separations  

SciTech Connect (OSTI)

Two procedures for the separation of Np are presented; the first involves separation of /sup 239/Np from irradiated /sup 238/U, and the second involves separation of /sup 237/Np from a solution representing that from a dissolved fuel element.

Wild, J.F.

1983-05-09T23:59:59.000Z

103

Oxygen in Underwater Cave  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen in Underwater Cave Oxygen in Underwater Cave Name: Natalie Status: student Grade: 9-12 Location: HI Country: USA Date: Spring 2011 Question: Is it possible for there to be free oxygen in an underwater cave? If it is, then how does it work? Replies: Yes it is possible as I have personally experienced. If the cave roof rises to a level above the water, air dissolved in the water will slowly out gas until the water is at the same level at all places. A pocket of breathable air will form. In many caves the roof dips below water level in one place but it above it on both sides. Think of a U shaped tube where the bottom of the U is blocked by water. This is called a siphon and I have passed through many of these to find breathable air on the other side. R. W. "Bob" Avakian Oklahoma State Univ. Inst. of Technology

104

Technolog  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research in Research in Science and Technolog y Sandia pushes frontiers of knowledge to meet the nation's needs, today and tomorrow Sandia National Laboratories' fundamental science and technology research leads to greater understanding of how and why things work and is intrinsic to technological advances. Basic research that challenges scientific assumptions enables the nation to push scientific boundaries. Innovations and breakthroughs produced at Sandia allow it to tackle critical issues, from maintaining the safety, security and effectiveness of the nation's nuclear weapons and preventing domestic and interna- tional terrorism to finding innovative clean energy solutions, develop- ing cutting-edge nanotechnology and moving the latest advances to the marketplace. Sandia's expertise includes:

105

successfully demonstrated the separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

successfully demonstrated the separation and capture of 90 percent successfully demonstrated the separation and capture of 90 percent of the c arbon dioxide (CO 2 ) from a pulve rized coal plant. In t he ARRA-funded project, Membrane Technology and Research Inc. (MTR) and its partners tested the Polaris(tm) membrane system, which uses a CO 2 -selective polymeric membrane material and module to capture CO 2 from a plant's flue gas. Since the Polaris(tm) membranes

106

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

107

Optimization of Oxygen Purity for Coal Conversion Energy Reduction  

E-Print Network [OSTI]

The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

Baker, C. R.; Pike, R. A.

1982-01-01T23:59:59.000Z

108

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

109

Novel Surface Architecture Synthesis for Gas Separation and Fuel-Cell Catalyst Applications James Guthrie, Georgia Institute of Technology, SURF 2010 Fellow  

E-Print Network [OSTI]

Novel Surface Architecture Synthesis for Gas Separation and Fuel-Cell Catalyst Applications James-shell nanoparticle, Pt was deposited onto a flat surface substrate. Three separate substrates were used, Au(111 not significantly change over different voltages [3]. STM work was done using electrochemically etched tungsten tips

Li, Mo

110

Advanced Separation Consortium  

SciTech Connect (OSTI)

The Center for Advanced Separation Technologies (CAST) was formed in 2001 under the sponsorship of the US Department of Energy to conduct fundamental research in advanced separation and to develop technologies that can be used to produce coal and minerals in an efficient and environmentally acceptable manner. The CAST consortium consists of seven universities - Virginia Tech, West Virginia University, University of Kentucky, Montana Tech, University of Utah, University of Nevada-Reno, and New Mexico Tech. The consortium brings together a broad range of expertise to solve problems facing the US coal industry and the mining sector in general. At present, a total of 60 research projects are under way. The article outlines some of these, on topics including innovative dewatering technologies, removal of mercury and other impurities, and modelling of the flotation process. 1 photo.

NONE

2006-01-01T23:59:59.000Z

111

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Presentations, Papers, and Publications Presentations, Papers, and Publications ITM Oxygen Development for Advanced Oxygen Supply (Oct 2011) Ted Foster, Air Products & Chemicals, Inc. presented at the Gasification Technologies Conference, San Francisco, CA Oct 9-12, 2011. ASU/IGCC Integration Strategies (Oct 2009), David McCarthy, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Taking the Next Step (Oct 2009), VanEric Stein, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Scaling Up a Low-Cost Oxygen Supply Technology (Oct 2006) Philip Armstrong, Air Products & Chemicals, Inc., 2006 Gasification Technologies Conference, Washington, D.C. ITM Oxygen: The New Oxygen Supply for the New IGCC Market (Oct 2005)

112

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1997-01-01T23:59:59.000Z

113

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1996-01-01T23:59:59.000Z

114

Separation system  

DOE Patents [OSTI]

A separation system for dewatering radioactive waste materials includes a disposal container, drive structure for receiving the container, and means for releasably attaching the container to the drive structure. Separation structure disposed in the container adjacent the inner surface of the side wall structure retains solids while allowing passage of liquids. Inlet port structure in the container top wall is normally closed by first valve structure that is centrifugally actuated to open the inlet port and discharge port structure at the container periphery receives liquid that passes through the separation structure and is normally closed by second valve structure that is centrifugally actuated to open the discharge ports. The container also includes coupling structure for releasable engagement with the centrifugal drive structure. Centrifugal force produced when the container is driven in rotation by the drive structure opens the valve structures, and radioactive waste material introduced into the container through the open inlet port is dewatered, and the waste is compacted. The ports are automatically closed by the valves when the container drum is not subjected to centrifugal force such that containment effectiveness is enhanced and exposure of personnel to radioactive materials is minimized.

Rubin, Leslie S. (Newton, MA)

1986-01-01T23:59:59.000Z

115

Efficient separations & processing crosscutting program  

SciTech Connect (OSTI)

The Efficient Separations and Processing Crosscutting Program (ESP) was created in 1991 to identify, develop, and perfect chemical and physical separations technologies and chemical processes which treat wastes and address environmental problems throughout the DOE complex. The ESP funds several multiyear tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R & D) leading to the demonstration or use of these separations technologies by other organizations within the Department of Energy (DOE), Office of Environmental Management.

NONE

1996-08-01T23:59:59.000Z

116

USABC Battery Separator Development | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es007smith2011p.pdf More Documents & Publications USABC Battery Separator Development Overview...

117

DOE/EA-1472: Finding of No Significant Impact for the Commercial Demonstration of the Low NOx Burner/Separated Over-Fire Air Integration System Emission Reduction Technology (03/11/03)  

Broader source: Energy.gov (indexed) [DOE]

IMPACT IMPACT COMMERCIAL DEMONSRATION OF THE LOW NOx BURNER/SEPARATED OVER- FIRE AIR (LNB/SOFA) INTEGRATON SYSTEM EMISSION REDUCTION TECHNOLOGY HOLCOMB STATION SUNFLOWER ELECTRIC POWER CORPORATION FINNEY COUNTY, KANSAS AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NO,

118

Electrochemically mediated separation for carbon capture  

E-Print Network [OSTI]

Carbon capture technology has been proposed as an effective approach for the mitigation of anthropogenic CO[subscript 2] emissions. Thermal-swing separation technologies based on wet chemical scrubbing show potential for ...

Simeon, Fritz

119

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

120

Absorption process for producing oxygen and nitrogen and solution therefor  

DOE Patents [OSTI]

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

Roman, I.C.; Baker, R.W.

1990-09-25T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Absorption process for producing oxygen and nitrogen and solution therefor  

DOE Patents [OSTI]

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

Roman, Ian C. [Wilmington, DE; Baker, Richard W. [Palo Alto, CA

1990-09-25T23:59:59.000Z

122

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

123

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

Cassano, Anthony A. (Allentown, PA)

1985-01-01T23:59:59.000Z

124

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

Cassano, A.A.

1985-07-02T23:59:59.000Z

125

Separation Processes, Second Edition  

E-Print Network [OSTI]

by; Uranium isotopes separation) Iteration methods (seemethod for activity coefficients, 43, 481 Uranium isotopes separation,

King, C. Judson

1980-01-01T23:59:59.000Z

126

Membrane separation processes for clean production  

SciTech Connect (OSTI)

Clean production can be considered as a strategic element in manufacturing technology for present and future products in the chemical industry. Demand is focused on the development of cost-effective technologies, the optimization of processes including separation steps, alternative processes for the reduction of waste, optimization of the use of resources and improvements in production efficiency. In many cases an environmentally friendly alternative to conventional separation processes could be membrane separation. Membrane separation techniques are suitable for mixtures of liquids, gases and vapors. Some examples of successful applications in the areas of waste water treatment and vapor recovery are given. Demands, advantages and problems of separation with membranes are also discussed.

Paul, D.; Ohlrogge, K. [GKSS Research Center, Geesthacht (Germany)

1998-12-31T23:59:59.000Z

127

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

128

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

129

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

130

A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites  

Science Journals Connector (OSTI)

...Department of Chemistry, Massachusetts Institute of Technology77 Massachusetts Avenue, 6-335, Cambridge...oxygen-evolving complex|catalysis|solar energy| 1. The nature...Department of Chemistry, Massachusetts Institute of Technology...

2008-01-01T23:59:59.000Z

131

Separations in the STATS report  

SciTech Connect (OSTI)

The Separations Technology and Transmutation Systems (STATS) Committee formed a Subcommittee on Separations. This subcommittee was charged with evaluating the separations proposed for the several reactor and accelerator transmutation systems. It was also asked to review the processing options for the safe management of high-level waste generated by the defense programs, in particular, the special problems involved in dealing with the waste at the U.S. Department of Energy (DOE) facility in Hanford, Washington. Based on the evaluations from the Subcommittee on Separations, the STATS Committee concluded that for the reactor transmutation programs, aqueous separations involving a combination of PUREX and TRUEX solvent extraction processes could be used. However, additional research and development (R&D) would be required before full plant-scale use of the TRUEX technology could be employed. Alternate separations technology for the reactor transmutation program involves pyroprocessing. This process would require a significant amount of R&D before its full-scale application can be evaluated.

Choppin, G.R. [Florida State Univ., Tallahassee, FL (United States)

1996-12-31T23:59:59.000Z

132

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

133

Effect of oxygen concentration on the magnetic properties of La2CoMnO6 Center for Materials for Information Technology and Department of Chemistry, University of Alabama,  

E-Print Network [OSTI]

Effect of oxygen concentration on the magnetic properties of La2CoMnO6 thin films H. Z. Guo Center; published online 16 November 2007 The dependence of the magnetic properties on oxygen concentration the oxygen background pressure during growth using pulsed laser deposition. Two distinct ferromagnetic FM

Pennycook, Steve

134

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

135

Report of the DOE Workshop on Hydrogen Separations and Purification  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy Energy Bringing you a prosperous future where energy is clean, abundant, reliable and affordable Report of the DOE Workshop on Hydrogen Separations and Purification September 8-9, 2004 Arlington, VA U.S. Department of Energy Office of Hydrogen, Fuel Cells & Infrastructure Technologies CONTENTS INTRODUCTION ...............................................................................................1 Background ................................................................................................................. 1 Current Hydrogen Separation Technology .................................................................. 2 Hydrogen Membrane Separation Technologies .......................................................... 3 HYDROGEN MEMBRANE SEPARATION PERFORMANCE TARGETS.........................6

136

Oxy-combustion: Oxygen Transport Membrane Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion: Oxygen Transport combustion: Oxygen Transport Membrane Development Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D

137

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

138

Effect of temperature on reduction of CaSO{sub 4} oxygen carrier in chemical-looping combustion of simulated coal gas in a fluidized bed reactor  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) is a promising combustion technology for gaseous and solid fuel with efficient use of energy and inherent separation of CO{sub 2}. The concept of a coal-fueled CLC system using, calcium sulfate (CaSO{sub 4}) as oxygen carrier is proposed in this study. Reduction tests of CaSO{sub 4} oxygen carrier with simulated coal gas were performed in a laboratory-scale fluidized bed reactor in the temperature range of 890-950{degree}C. A high concentration of CO{sub 2} was obtained at the initial reduction period. CaSO{sub 4} oxygen carrier exhibited high reactivity initially and decreased gradually at the late period of reduction. The sulfur release during the reduction of CaSO{sub 4} as oxygen carrier was also observed and analyzed. H{sub 2} and CO{sub 2} conversions were greatly influenced by reduction temperature. The oxygen carrier conversion and mass-based reaction rates during the reduction at typical temperatures were compared. Higher temperatures would enhance reaction rates and result in high conversion of oxygen carrier. An XRD patterns study indicated that CaS was the dominant product of reduction and the variation of relative intensity with temperature is in agreement with the solid conversion. ESEM analysis indicated that the surface structure of oxygen carrier particles changed significantly from impervious to porous after reduction. EDS analysis also demonstrated the transfer of oxygen from the oxygen carrier to the fuel gas and a certain amount of sulfur loss and CaO formation on the surface at higher temperatures. The reduction kinetics of CaSO{sub 4} oxygen carrier was explored with the shrinking unreacted-core model. The apparent kinetic parameters were obtained, and the kinetic equation well predicted the experimental data. Finally, some basic considerations on the use of CaSO{sub 4} oxygen carrier in a CLC system for solid fuels were discussed.

Song, Q.L.; Xiao, R.; Deng, Z.Y.; Shen, L.H.; Xiao, J.; Zhang, M.Y. [Southeast University, Nanjing (China)

2008-12-15T23:59:59.000Z

139

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

140

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Hybrid Membranes for Light Gas Separations  

E-Print Network [OSTI]

Membrane separations provide a potentially attractive technology over conventional processes due to their advantages, such as low capital cost and energy consumption. The goal of this thesis is to design hybrid membranes that facilitate specific gas...

Liu, Ting

2012-07-16T23:59:59.000Z

142

Superstructure Optimization of the Olefin Separation Process  

E-Print Network [OSTI]

, and C2~C5 components. Since we are mainly concerned with the recovery of ethylene and propylene, we Table 1: Separation technologies T1 Distillation column T2 Physical absorption tower T3 Membrane

Grossmann, Ignacio E.

143

Gaseous isotope separation using solar wind phenomena  

Science Journals Connector (OSTI)

...isotope separation using solar wind phenomena Chia-Gee...essentially the same as that of the solar wind propagation, in which...the author was measuring solar wind parameters under Dr. H. S. Bridge at Massachusetts Institute of Technology in...

Chia-Gee Wang

1980-01-01T23:59:59.000Z

144

Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

2007-03-31T23:59:59.000Z

145

Fundamental studies of heterostructured oxide thin film electrocatalysts for oxygen reduction at high temperatures  

E-Print Network [OSTI]

Searching for active and cost-effective catalysts for oxygen electrocatalysis is essential for the development of efficient clean electrochemical energy technologies. Perovskite oxides are active for surface oxygen exchange ...

Crumlin, Ethan J

2012-01-01T23:59:59.000Z

146

Encapsulated Metal Hydride for Hydrogen Separation  

E-Print Network [OSTI]

concentration feed stock, not for low concentration � Hydrogen economy will need hydrogen recovery from lowEncapsulated Metal Hydride for Hydrogen Separation (Formerly Separation Membrane Development) DOE Hydrogen Program 2003 Merit Review and Peer Evaluation L. Kit Heung, Jim Congdon Savannah River Technology

147

Environmental assessment of a membrane-based air separation for a coal-fired oxyfuel power plant  

Science Journals Connector (OSTI)

Abstract CO2 reduction from fossil-fired power plants can be achieved by carbon dioxide capture and storage (CCS). Among different CO2 capture technologies for power plants the oxyfuel power plant concept is a promising option. High temperature ceramic membranes for oxygen production have the potential to reduce the associated efficiency losses significantly compared to conventional air separation using cryogenic techniques. Focus of this paper is the environmental performance of membrane-based oxygen production for oxyfuel power plant technology. Included into the analysis are the production of the perovskite membrane (BSCF=Ba0.5Sr0.5Co0.8Fe0.2O3??), the incorporation into a steel module, and the integration of several modules into an oxyfuel power plant. The membrane-based oxygen production is compared to the conventional cryogenic air separation in oxyfuel power plants in an ecological way. The evaluation is performed using life cycle assessment (LCA) methodology from “cradle to grave”. The share in the overall environmental impacts of respective life cycle elements like membrane and module production but also coal supply processes as well as the operation of the oxyfuel power plant are identified. Sensitivity analyses referring to life-time, permeability and housing conditions of the membranes set benchmarks for further membrane development.

Andrea Schreiber; Josefine Marx; Petra Zapp

2013-01-01T23:59:59.000Z

148

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

149

Use of coal as fuel for chemical-looping combustion with Ni-based oxygen carrier  

SciTech Connect (OSTI)

Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas presents a monotonously increasing trend, whereas the dry basis concentration of CO, H{sub 2}, and CH{sub 4} decreases monotonously. The concentrations of CO{sub 2}, CO, H{sub 2}, and CH{sub 4} in the flue gas as a function of cyclic reduction number present a para-curve characteristic at 900{degree}C. With the increase of cyclic reduction number, the dry basis concentration of CO{sub 2} decreases remarkably, while the dry basis concentrations of CO, H{sub 2}, and CH{sub 4} increase rapidly. Moreover, the peak value of H{sub 2} concentration is less than that of CO. The performance of the NiO-based oxygen carriers was also evaluated using an X-ray diffractometer and a scanning electron microscope to characterize the solid residues of oxygen carrier. The results indicate that NiO is one of the suitable oxygen carriers for chemical-looping combustion of coal.

Gao, Z.P.; Shen, L.H.; Xiao, J.; Qing, C.J.; Song, Q.L. [Southeast University, Nanjing (China). Thermoenergy Engineering Research Institute

2008-12-15T23:59:59.000Z

150

Membrane separation advances in FE hydrogen program  

SciTech Connect (OSTI)

Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

NONE

2007-12-31T23:59:59.000Z

151

A Vortex Contactor for Carbon Dioxide Separations  

SciTech Connect (OSTI)

Many analysts identify carbon dioxide (CO2) capture and separation as a major roadblock in efforts to cost effectively mitigate greenhouse gas emissions via sequestration. An assessment 4 conducted by the International Energy Agency (IEA) Greenhouse Gas Research and Development Programme cited separation costs from $35 to $264 per tonne of CO2 avoided for a conventional coal fired power plant utilizing existing capture technologies. Because these costs equate to a greater than 40% increase in current power generation rates, it appears obvious that a significant improvement in CO2 separation technology is required if a negative impact on the world economy is to be avoided.

Raterman, Kevin Thomas; Mc Kellar, Michael George; Turner, Terry Donald; Podgorney, Anna Kristine; Stacey, Douglas Edwin; Stokes, B.; Vranicar, J.

2001-05-01T23:59:59.000Z

152

Hydrogen Separations and Purification  

E-Print Network [OSTI]

/mol 100 Water mol/mol 5 Total hydrocarbons mol/mol 2 Oxygen mol/mol 5 Helium, Nitrogen, Argon mol/mol 100

153

Research on Temperature Field Measuring of Oxygen Propane  

Science Journals Connector (OSTI)

By substituting alumina particles for soot created in burning flame and using the three-color method, the temperature field of the oxygen propane is calculated based on the image taken by CCD and digital image processing technology. The results show ... Keywords: CCD, oxygen propane flame, temperature field, image processing

Zhang Rui-ping

2010-09-01T23:59:59.000Z

154

Advanced isotope separation  

SciTech Connect (OSTI)

The Study Group briefly reviewed the technical status of the three Advanced Isotope Separation (AIS) processes. It also reviewed the evaluation work that has been carried out by DOE's Process Evaluation Board (PEB) and the Union Carbide Corporation-Nuclear Division (UCCND). The Study Group briefly reviewed a recent draft assessment made for DOE staff of the nonproliferation implications of the AIS technologies. The staff also very briefly summarized the status of GCEP and Advanced Centrifuge development. The Study Group concluded that: (1) there has not been sufficient progress to provide a firm scientific, technical or economic basis on which to select one of the three competing AIS processes for full-scale engineering development at this time; and (2) however, should budgetary restraints or other factors force such a selection, we believe that the evaluation process that is being carried out by the PEB provides the best basis available for making a decision. The Study Group recommended that: (1) any decisions on AIS processes should include a comparison with gas centrifuge processes, and should not be made independently from the plutonium isotope program; (2) in evaluating the various enrichment processes, all applicable costs (including R and D and sales overhead) and an appropriate discounting approach should be included in order to make comparisons on a private industry basis; (3) if the three AIS programs continue with limited resources, the work should be reoriented to focus only on the most pressing technical problems; and (4) if a decision is made to develop the Atomic Vapor Laser Isotope Separation process, the solid collector option should be pursued in parallel to alleviate the potential program impact of liquid collector thermal control problems.

Not Available

1982-05-04T23:59:59.000Z

155

Oxygen Atoms Display Novel Behavior on Common Catalyst  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

11, 2008 11, 2008 Oxygen Atoms Display Novel Behavior on Common Catalyst Like waltzing dancers, the two atoms of an oxygen molecule usually behave identically when they separate on the surface of a catalyst. However, new research from the Environmental Molecular Sciences Laboratory reveals that on a particular catalyst, the oxygen atoms act like a couple dancing the tango: one oxygen atom plants itself while the other shimmies away, probably with energy partially stolen from the stationary one. Scientists from EMSL and Pacific Northwest National Laboratory discovered this unanticipated behavior while studying how oxygen interacts with reduced titanium oxide, a popular catalyst and a model oxide. Their research began with a slice of titanium oxide crystal, oriented so that titanium and oxygen

156

SunShot Initiative Researcher Wins National Medal of Technology and  

Broader source: Energy.gov (indexed) [DOE]

SunShot Initiative Researcher Wins National Medal of Technology and SunShot Initiative Researcher Wins National Medal of Technology and Innovation SunShot Initiative Researcher Wins National Medal of Technology and Innovation October 7, 2011 - 11:10am Addthis SunShot Initiative Researcher Wins National Medal of Technology and Innovation Minh Le Minh Le Program Manager, Solar Program Last week, President Obama recognized Dr. Rakesh Agrawal with the National Medal of Technology and Innovation -- the nation's highest honor for advancing science and technology. Among five honored with this year's award, Rakesh Agrawal received the prize in recognition of his breakthroughs in gas separation and liquefaction. Very pure oxygen, nitrogen and other gases are important for the high-quality silicon wafers used in computer processors and cellular

157

Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of NiO reduction with H{sub 2}S is higher than the one with CO. There are only Ni and Ni{sub 3}S{sub 2} phases of nickel species in the fully reduced oxygen carrier, and no evidence for the existence of NiS or NiS{sub 2}. The formation of Ni{sub 3}S{sub 2} is completely reversible during the process of oxygen carrier redox. A liquid phase sintering on the external surface of reduced oxygen carriers is mainly attributed to the production of the low melting of Ni{sub 3}S{sub 2} in the nickel-based oxygen carrier reduction with a gaseous fuel containing H{sub 2}S. Due to the sintering of metallic nickel grains on the external surface of the reduced oxygen carrier, further reaction of the oxygen carrier with H{sub 2}S is constrained, and there is no increase of the sulfidation index of the reduced oxygen carrier with the cyclical reduction number. Also, a continuous operation with a syngas of carbon monoxide and hydrogen containing H{sub 2}S is carried out in a 1 kW{sub th} CLC prototype based on the nickel-based oxygen carrier, and the effect of the fuel reactor temperature on the release of gaseous products of sulfur species is investigated. (author)

Shen, Laihong; Gao, Zhengping; Wu, Jiahua; Xiao, Jun [Thermoenergy Engineering Research Institute, Southeast University, Nanjing 210096 (China)

2010-05-15T23:59:59.000Z

158

Nanostructured Oxygen Carriers for Chemical Looping Combustion and Chemical Looping Hydrogen Production.  

E-Print Network [OSTI]

??Chemical looping combustion (CLC) is an emerging technology for clean energy-production. In CLC, an oxygen carrier is periodically oxidized with air and then reduced in… (more)

Solunke, Rahul Dushyantrao

2011-01-01T23:59:59.000Z

159

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Presentation slides from the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, held March 12, 2013.

160

Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Video recording of the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, originally presented on March 12, 2013.

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Air separation by the Moltox process  

SciTech Connect (OSTI)

The report describes results of a development program on a new and energy saving process for air separation. The Moltox process involves reversibly reacting oxygen in air with a recirculating salt solution, such that oxygen is extracted without depressurizing the remaining nitrogen. Energy savings of approximately 50% are indicated for this process compared to conventional cryogenic air separation. The development program consisted of design, construction, and operation of a 6 liter/minute pilot plant; optimization of the process flowsheet through computer modelling; investigation of engineering aspects of the process including corrosion, safety, and NO/sub x/ generation; and an economic comparison to conventional cryogenic practice. All objectives were satisfactorily achieved except for continuous operation of the pilot plant, and the modifications necessary to achieve that have been identified. Economically the Moltox process shows a substantial advantage over large scale cryogenic plants which are powered by fuel vice electricity.

Erickson, D. C.

1981-04-01T23:59:59.000Z

162

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

2003-11-01T23:59:59.000Z

163

Plants making oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants making oxygen Plants making oxygen Name: Doug Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: How many plants are needed to make enough oxygen for one person for one hour? We are experimenting with Anacharis plants. Replies: The problem can be solved when broken down into smaller questions: 1. How much oxygen does a person need in an hour? 2. How much oxygen does a plant produce in an hour? 3. Based on the above, how many plants will provide the oxygen needs of the person for the hour? Here is the solution to the first question: A resting, healthy adult on an average, cool day breathes in about 53 liters of oxygen per hour. An average, resting, health adult breathes in about 500 mL of air per breath. This is called the normal tidal volume. Now, 150 mL of this air will go to non- functioning areas of the lung, called the "dead space." The average breath rate for this average person is 12 breaths per minute. So, the amount of air breathed in by the person which is available for use is 12 x (500 mL -150 mL) = 4,200 mL/minute. Multiply by 60 to get 252,000 mL/hour. That is, every hour, the person will breathe in 252 L of air. Now, on an average, cool, clear day, only 21% of that air is oxygen. So, 21% of 252 L is 53 L. So, in an hour, the person breathes in about 53 L of oxygen.

164

Algae for Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Algae for Oxygen Algae for Oxygen Name: Pam Burkardt Status: N/A Age: N/A Location: N/A Country: N/A Date: N/A Question: Hi, I am Pam Burkardt, a seventh grader at Fox Chapel School. I have a question on algae. I read somewhere that someday people might take bath tubs full of algae onto spaceships to provide oxygen for the crew. How much oxygen does algae give off, is this really possible? Replies: I think that most of the oxygen in the atmosphere comes in fact from one-celled plants in the oceans, like algae. They are likely to produce a lot of oxygen per unit weight because they don't have non-photosynthesizing bark, roots, branches, etc., nor (I think) a major dormant period like temperate-zone plants. The cost of space travel at present is dominated by the expense of heaving weight up into Earth orbit (it costs very little extra to send it to the Moon, for example, or Mars). For missions of short duration the weight of the compressed oxygen you need to carry is less than the weight of algae, water and extra plumbing you'd need to carry if you relied on algae to produce your oxygen. The important use of green plants would be in very long duration space flight (years) or permanent inhabitation of worlds like the Moon, where you need an unlimited supply of oxygen. Now if you want to fantasize, Venus' atmosphere is almost all carbon dioxide. Suppose you dropped a whole lot of specially gene-tailored one-celled plants into the atmosphere (not the surface, it's too hot). Why then they might eat up all the carbon dioxide and produce a breathable atmosphere. The "greenhouse effect" would go away, and Venus would become a nice habitable if tropical world only 50 million miles away.

165

Actinide separations conference  

SciTech Connect (OSTI)

This report contains the abstracts for 55 presentations given at the fourteenth annual Actinide Separations Conference. (JDL)

Not Available

1990-01-01T23:59:59.000Z

166

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

167

EERE SBIR Case Study: Sonic Energy Improves Industrial Separation and Mixing Processes  

Broader source: Energy.gov [DOE]

Advanced membrane separation technologies offered improvements over conventional processes, but were not being adopted in industrial operations.

168

Experimental Research of the Oxygen-Enriched Combustion of Sewage Sludge and Coal in CFB  

Science Journals Connector (OSTI)

Sewage sludge is the by-products of sewage treatment, and it is a fuel of high moisture, high ash and low caloric. Oxygen-enriched combustion technology is one of the new and clean coal combustion technologies...

S. W. Xin; X. F. Lu; H. Z. Liu

2010-01-01T23:59:59.000Z

169

GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

Nsakala ya Nsakala; Gregory N. Liljedahl

2003-05-15T23:59:59.000Z

170

februari 2008 MassMass transfer & separation technology 424302 2008transfer & separation technology 424302 2008 --APPENDIXAPPENDIX  

E-Print Network [OSTI]

Multicomponent mixturesmixtures"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna, DelftDelft University Press (2000Transfer in MulticomponentMulticomponent mixturesmixtures"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna, DelftDelft University Press (2000

Zevenhoven, Ron

171

Solar energy: Hydrogen and oxygen  

Science Journals Connector (OSTI)

Solar energy: Hydrogen and oxygen ... Demonstrating the electrolysis of water with solar energy. ...

John J. Farrell

1982-01-01T23:59:59.000Z

172

SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS  

Office of Scientific and Technical Information (OSTI)

SEPARATION SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS AND CONTAMINATED SOIL* Robert W. Peters + and Linda Shem Energy Systems Division Argonne National Laboratory 9700 South Cass Avenue Argonne, Illinois 60439 Abstract This paper reviews the applicable separation technologies relating to removal of heavy metals from solution and from soils in order to present the state-of-the-art in the field. Each technology is briefly described and typical operating conditions and technology performance are presented. Technologies described include chemical precipitation (including hydroxide, carbonate, or sulfide reagents), coagulation/flocculation, ion exchange, solvent extraction, extraction with chelating agents, complexation, electrochemical operation, cementation, membrane operations, evaporation, adsorption, solidification/stabilization, and

173

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

Kebabian, P.

1997-07-22T23:59:59.000Z

174

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

175

Membrane Separations Research  

E-Print Network [OSTI]

MEMBRANE SEPARATIONS RESEARCH James R. Fair Chemical Engineering Department The University of Texas at Austin Austin, TX 78712 ABSTRACT The use of membranes for separating gaseous and liquid mixtures has grown dramatically in the past 15... years. Applications have been dominated by light gas separations and water purification. During this pioneering period, equipment containing the membrane suIfaces has been developed to a point where failures are minimal and the membranes themselves...

Fair, J. R.

176

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

177

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

178

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

179

Substituted polyacetylene separation membrane  

DOE Patents [OSTI]

A separation membrane is described which is useful for gas separation, particularly separation of C{sub 2+} hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula shown in the accompanying diagram, wherein R{sub 1} is chosen from the group consisting of C{sub 1}-C{sub 4} alkyl and phenyl, and wherein R{sub 2} is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) [PMP]. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations. 4 figs.

Pinnau, I.; Morisato, Atsushi

1998-01-13T23:59:59.000Z

180

Substituted polyacetylene separation membrane  

DOE Patents [OSTI]

A separation membrane useful for gas separation, particularly separation of C.sub.2+ hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula: ##STR1## wherein R.sub.1 is chosen from the group consisting of C.sub.1 -C.sub.4 alkyl and phenyl, and wherein R.sub.2 is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) ›PMP!. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations.

Pinnau, Ingo (Palo Alto, CA); Morisato, Atsushi (Tokyo, JP)

1998-01-13T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Separators for flywheel rotors  

DOE Patents [OSTI]

A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors. 10 figs.

Bender, D.A.; Kuklo, T.C.

1998-07-07T23:59:59.000Z

182

Separators for flywheel rotors  

DOE Patents [OSTI]

A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors.

Bender, Donald A. (Dublin, CA); Kuklo, Thomas C. (Oakdale, CA)

1998-01-01T23:59:59.000Z

183

Nineteenth annual actinide separations conference: Conference program and abstracts  

SciTech Connect (OSTI)

This report contains the abstracts from the conference presentations. Sessions were divided into the following topics: Waste treatment; Spent fuel treatment; Issues and responses to Defense Nuclear Facility Safety Board 94-1; Pyrochemical technologies; Disposition technologies; and Aqueous separation technologies.

Bronson, M. [ed.

1995-12-31T23:59:59.000Z

184

Economic Analysis for Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect (OSTI)

The objective of the economic analysis is to prepare a budgetary estimate of capital and operating costs of the O{sub 2}-fired PC power plant as well as for the equivalent conventional PC-fired power plant. Capital and operating costs of conventional steam generation, steam heating, and power generation equipment are estimated based on Foster Wheeler's extensive experience and database. Capital and operating costs of equipment, such as oxygen separation and CO{sub 2} liquefaction, are based on vendor supplied data and FW process plant experience. The levelized cost of electricity is determined for both the air-fired and O{sub 2}-fired power plants as well as the CO{sub 2} mitigation cost. An economic comparison between the O{sub 2}-fired PC and other alternate technologies is presented.

Andrew Seltzer

2005-02-01T23:59:59.000Z

185

Immobilized fluid membranes for gas separation  

DOE Patents [OSTI]

Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.

Liu, Wei; Canfield, Nathan L; Zhang, Jian; Li, Xiaohong Shari; Zhang, Jiguang

2014-03-18T23:59:59.000Z

186

Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry  

E-Print Network [OSTI]

gasification with combined cycles biological oxygen demandsintegrated gasification combined cycle Intergovernmentalbe integrated with combined-cycle (CC) technology (BLGCC),

Kong, Lingbo

2014-01-01T23:59:59.000Z

187

Investigation of Coal Fueled Chemical Looping Combustion Using Fe3O4 as Oxygen Carrier  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a novel combustion technique with CO2 separation. Magnetite (Fe3O4) was selected as the oxygen carrier and Shenhua coal (Inner Mongolia, China) as the fuel for this study. The...

Wenguo Xlang; Xiaoyan Sun; Sha Wangt…

2010-01-01T23:59:59.000Z

188

Exploring Neutron-Rich Oxygen Isotopes with MoNA  

E-Print Network [OSTI]

The Modular Neutron Array (MoNA) was used in conjunction with a large-gap dipole magnet (Sweeper) to measure neutron-unbound states in oxygen isotopes close to the neutron dripline. While no excited states were observed in 24O, a resonance at 45(2) keV above the neutron separation energy was observed in 23O.

N. Frank; T. Baumann; D. Bazin; J. Brown; P. A. DeYoung; J. E. Finck; A. Gade; J. Hinnefeld; R. Howes; J. -L. Lecouey; B. Luther; W. A. Peters; H. Scheit; A. Schiller; M. Thoennessen

2007-08-20T23:59:59.000Z

189

USABC Battery Separator Development  

Broader source: Energy.gov (indexed) [DOE]

Separator Development P.I. - Ron Smith Presenter - Kristoffer Stokes, Ph.D. Celgard, LLC Project ID ES007 May 10, 2011 This presentation does not contain any proprietary,...

190

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

191

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

192

Hydrogen separation process  

DOE Patents [OSTI]

A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

2011-05-24T23:59:59.000Z

193

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

194

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

195

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

196

Cerium Oxide Promoted Iron-based Oxygen Carrier for Chemical Looping Combustion  

Science Journals Connector (OSTI)

Cerium Oxide Promoted Iron-based Oxygen Carrier for Chemical Looping Combustion ... It entails the use of an oxygen carrier (OC), usually a metal oxide, to provide oxygen for combusting fuels in a fuel reactor (FR) and then the reoxidization of the OC in a separate air reactor (AR). ... Preprints of Symposia - American Chemical Society, Division of Fuel Chemistry (2004), 49 (2), 815-816 CODEN: PSADFZ; ISSN:1521-4648. ...

Fang Liu; Liangyong Chen; James K. Neathery; Kozo Saito; Kunlei Liu

2014-10-01T23:59:59.000Z

197

Advanced Technology for the Capture of Carbon Dioxide from Flue Gases  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technology for the Capture of Carbon Dioxide Technology for the Capture of Carbon Dioxide from Flue Gases by Shrikar Chakravarti (shrikar_chakravarti@praxair.com; 716-879-4760) Amitabh Gupta (ami_gupta@praxair.com; 716-879-2194) Balazs Hunek (balazs_hunek@praxair.com; 716-879-2250) Praxair, Inc. Process & Systems R&D, CO 2 Technology 175 East Park Drive, P.O. Box 44 Tonawanda, NY 14150 USA key words: flue gas, carbon dioxide, separation, amine absorption, oxygen tolerant process, amine blends First National Conference on Carbon Sequestration Washington, DC, May 15-17, 2001 Copyright 2001, Praxair Technology, Inc. All Rights Reserved. 1 Abstract Cost effective carbon sequestration schemes have been identified as a key need for dealing with carbon dioxide's (CO 2 ) impact on global climate change. Two main

198

APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS PRE-COMBUSTION SOLVENTS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS PRE-COMBUSTION SOLVENTS PRE-COMBUSTION SORBENTS PRE-COMBUSTION MEMBRANES POST-COMBUSTION SOLVENTS POST-COMBUSTION SORBENTS POST-COMBUSTION MEMBRANES OXY-COMBUSTION OXYGEN PRODUCTION CHEMICAL LOOPING ADVANCED COMPRESSION R&D COLLABORATIONS B-1 APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS NATIONAL ENERGY TECHNOLOGY LABORATORY PRE-COMBUSTION SOLVENTS B-6 SRI International - CO 2 Capture Using AC-ABC Processt B-7 PRE-COMBUSTION SORBENTS B-14 TDA Research - CO 2 Capture for Low-Rank Coal IGCC Systems B-15 URS Group - Sorbent Development for WGS B-18 Air Products and Chemicals - Advanced Acid Gas Separation B-24 Ohio State University-Department of Chemical Engineering - Calcium Looping for Hydrogen Production B-33

199

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

200

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Organic Separation Test Results  

SciTech Connect (OSTI)

Separable organics have been defined as “those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer” (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be “no visible layer” of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2014-09-22T23:59:59.000Z

202

Oxygen transport membrane system and method for transferring heat to catalytic/process reactors  

DOE Patents [OSTI]

A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

2014-01-07T23:59:59.000Z

203

Ionically Conducting Membranes for Hydrogen Production and Separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IONICALLY CONDUCTING MEMBRANES IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND SEPARATION Presented by Tony Sammells Eltron Research Inc. Boulder, Colorado www.eltronresearch.com Presented at DOE Hydrogen Separations Workshop Arlington, Virginia September 8, 2004 ELTRON RESEARCH INC. TO BE DISCUSSED * Membranes for Hydrogen Production - Compositions - Feedstocks - Performance - Key Technical Hurdles * Membranes for Hydrogen Separation - Compositions - Ex Situ vs. In Situ WGS - Performance - Key Technical Hurdles ELTRON RESEARCH INC. OVERALL SCHEME FOR CONVERTING FEEDSTOCK TO HYDROGEN WITH SIMULTANEOUS CARBON DIOXIDE SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H 2 WGS H 2 O CO 2 /H 2 1618afs.dsf H 2 CO 2 ELTRON RESEARCH INC. INCENTIVES FOR OXYGEN TRANSPORT MEMBRANES FOR

204

Molecular dynamics simulation of nanoporous graphene for selective gas separation  

E-Print Network [OSTI]

Graphene with sub-nanometer sized pores has the potential to act as a filter for gas separation with considerable efficiency gains compared to traditional technologies. Nanoporous graphene membranes are expected to yield ...

Au, Harold (Harold S.)

2012-01-01T23:59:59.000Z

205

Separators for electrochemical cells  

DOE Patents [OSTI]

Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

Carlson, Steven Allen; Anakor, Ifenna Kingsley

2014-11-11T23:59:59.000Z

206

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

207

Novel Metallic Membranes for Hydrogen Separation  

SciTech Connect (OSTI)

To reduce dependence on oil and emission of greenhouse gases, hydrogen is favored as an energy carrier for the near future. Hydrogen can be converted to electrical energy utilizing fuel cells and turbines. One way to produce hydrogen is to gasify coal which is abundant in the U.S. The coal gasification produces syngas from which hydrogen is then separated. Designing metallic alloys for hydrogen separation membranes which will work in a syngas environment poses significant challenges. In this presentation, a review of technical targets, metallic membrane development activities at NETL and challenges that are facing the development of new technologies will be given.

Dogan, Omer

2011-02-27T23:59:59.000Z

208

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

209

OXYGEN ABUNDANCES IN CEPHEIDS  

SciTech Connect (OSTI)

Oxygen abundances in later-type stars, and intermediate-mass stars in particular, are usually determined from the [O I] line at 630.0 nm, and to a lesser extent, from the O I triplet at 615.7 nm. The near-IR triplets at 777.4 nm and 844.6 nm are strong in these stars and generally do not suffer from severe blending with other species. However, these latter two triplets suffer from strong non-local thermodynamic equilibrium (NLTE) effects and thus see limited use in abundance analyses. In this paper, we derive oxygen abundances in a large sample of Cepheids using the near-IR triplets from an NLTE analysis, and compare those abundances to values derived from a local thermodynamic equilibrium (LTE) analysis of the [O I] 630.0 nm line and the O I 615.7 nm triplet as well as LTE abundances for the 777.4 nm triplet. All of these lines suffer from line strength problems making them sensitive to either measurement complications (weak lines) or to line saturation difficulties (strong lines). Upon this realization, the LTE results for the [O I] lines and the O I 615.7 nm triplet are in adequate agreement with the abundance from the NLTE analysis of the near-IR triplets.

Luck, R. E.; Andrievsky, S. M. [Department of Astronomy, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7215 (United States); Korotin, S. N.; Kovtyukh, V. V., E-mail: luck@fafnir.astr.cwru.edu, E-mail: serkor@skyline.od.ua, E-mail: val@deneb1.odessa.ua, E-mail: scan@deneb1.odessa.ua [Department of Astronomy and Astronomical Observatory, Odessa National University, Isaac Newton Institute of Chile, Odessa Branch, Shevchenko Park, 65014 Odessa (Ukraine)

2013-07-01T23:59:59.000Z

210

Hydrogen isotope separation  

DOE Patents [OSTI]

A system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D.sub.2, DT, T.sub.2, and a tritium-free stream of HD for waste disposal.

Bartlit, John R. (Los Alamos, NM); Denton, William H. (Abingdon, GB3); Sherman, Robert H. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

211

Vehicle Technologies Office Merit Review 2014: Significant Cost...  

Broader source: Energy.gov (indexed) [DOE]

Direct Separator Coating, and Fast Formation Technologies Presentation given by Johnson Controls at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office...

212

Structure Evolution of Graphene Oxide during Thermally Driven Phase Transformation: Is the Oxygen Content Really Preserved?  

E-Print Network [OSTI]

A mild annealing procedure was recently proposed for the scalable enhancement of graphene oxide (GO) properties with the oxygen content preserved, which was demonstrated to be attributed to the thermally driven phase separation. In this work, the structure evolution of GO with mild annealing is closely investigated. It reveals that in addition to phase separation, the transformation of oxygen functionalities also occurs, which leads to the slight reduction of GO membranes and further the enhancement of GO properties. These results are further supported by the density functional theory based calculations. The results also show that the amount of chemically bonded oxygen atoms on graphene decreases gradually and we propose that the strongly physisorbed oxygen species constrained in the holes and vacancies on GO lattice might be responsible for the preserved oxygen content during the mild annealing procedure. The present experimental results and calculations indicate that both the diffusion and transformation of...

Sun, Pengzhan; Liu, He; Wang, Kunlin; Wu, Dehai; Xu, Zhiping; Zhu, Hongwei

2014-01-01T23:59:59.000Z

213

Measuring oxygen reduction/evolution reactions on the nanoscale  

SciTech Connect (OSTI)

The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

2011-01-01T23:59:59.000Z

214

BWR oxygen control demonstration program  

SciTech Connect (OSTI)

A number of cracks have occurred recently in certain BWR piping systems. The operating environment associated with oxidizing species such as oxygen and hydrogen peroxide is considered one of the factors in the mechanism of cracking. In April 1976, NWT Corporation was contracted to perform a BWR oxygen control demonstration program. Means for reducing reactor water oxygen and hydrogen peroxide concentrations during startup and shutdown transients were defined and demonstrated at Vermont Yankee and Browns Ferry Unit 3. Results of the demonstrations and an analytical review of impacts of major system variables on oxygen transients are discussed herein.

Pearl, W.L.; Kassen, W.R.; Sawochka, S.G.

1981-05-01T23:59:59.000Z

215

Health Effects from Advanced Combustion and Fuel Technologies  

SciTech Connect (OSTI)

This document requires a separate file for the figures. It is for DOE's Office of Vehicle Technologies Annual Report

Barone, Teresa L [ORNL; Parks, II, James E [ORNL; Lewis Sr, Samuel Arthur [ORNL; Connatser, Raynella M [ORNL

2010-01-01T23:59:59.000Z

216

Oxygen to the core  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1-01 1-01 For immediate release: 01/10/2013 | NR-13-01-01 Oxygen to the core Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Printer-friendly An artist's conception of Earth's inner and outer core. LIVERMORE, Calif. -- An international collaboration including researchers from Lawrence Livermore National Laboratory has discovered that the Earth's core formed under more oxidizing conditions than previously proposed. Through a series of laser-heated diamond anvil cell experiments at high pressure (350,000 to 700,000 atmospheres of pressure) and temperatures (5,120 to 7,460 degrees Fahrenheit), the team demonstrated that the depletion of siderophile (also known as "iron loving") elements can be produced by core formation under more oxidizing conditions than earlier

217

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

218

Morgantown Energy Technology Center, technology summary  

SciTech Connect (OSTI)

This document has been prepared by the DOE Environmental Management (EM) Office of Technology Development (OTD) to highlight its research, development, demonstration, testing, and evaluation activities funded through the Morgantown Energy Technology Center (METC). Technologies and processes described have the potential to enhance DOE`s cleanup and waste management efforts, as well as improve US industry`s competitiveness in global environmental markets. METC`s R&D programs are focused on commercialization of technologies that will be carried out in the private sector. META has solicited two PRDAs for EM. The first, in the area of groundwater and soil technologies, resulted in twenty-one contact awards to private sector and university technology developers. The second PRDA solicited novel decontamination and decommissioning technologies and resulted in eighteen contract awards. In addition to the PRDAs, METC solicited the first EM ROA in 1993. The ROA solicited research in a broad range of EM-related topics including in situ remediation, characterization, sensors, and monitoring technologies, efficient separation technologies, mixed waste treatment technologies, and robotics. This document describes these technology development activities.

Not Available

1994-06-01T23:59:59.000Z

219

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1989-04-25T23:59:59.000Z

220

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Materials and interfaces for catalysis, separation, storage, and environmental applications  

E-Print Network [OSTI]

and interfaces for a host of sustainable chemical processes that provide renewable (or cleaner) fuels the next generation of catalysts, separation processes, gas and liquid storage technologies, and environmental remediation methods. These materials and technologies are at the heart of industrial processes

Li, Mo

222

Dynamic Model for an Oxygen-Staged Slagging Entrained Flow Gasifier  

Science Journals Connector (OSTI)

The temperature distribution simulation results also showed that staged oxygen feeding can reduce the temperature near the main burner significantly, therefore extending the lifetime of the burner compared with that of without staged oxygen feed. ... Problems such as a short lifetime of burners and refractory walls and fouling and corrosion in syngas coolers have to be addressed in order to further improve the technology. ...

Zhiwei Yang; Zhe Wang; Yuxin Wu; Jihong Wang; Junfu Lu; Zheng Li; Weidou Ni

2011-07-05T23:59:59.000Z

223

Mass-selected Nanoparticles of PtxY as Model Catalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of PEMFCs has been hampered by the need for a large amount of platinum catalyst at the cathode, where oxygen reduction takes place. Even with current state-of-the-art technology,...

224

Preparation of Copper-Based Oxygen Carrier Supported on Titanium Dioxide.  

E-Print Network [OSTI]

?? Chemical-looping combustion is an indirect oxygen combustion strategy, considered to be the most cost-effective power generation technology with the CO2 inherently concentrated. In this… (more)

Cui, Yaowen

2012-01-01T23:59:59.000Z

225

Study on modification of Cu-based oxygen carrier for chemical looping combustion  

Science Journals Connector (OSTI)

Chemical looping combustion (CLC) is a promising technology for...2O4...spinel, formed after the first few redox cycles, which is responsible for promoting the thermal stability of the oxygen carriers. SEM result...

Hou-yin Zhao; Yan Cao; William Orndorff…

2013-09-01T23:59:59.000Z

226

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network [OSTI]

, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four: business administration, wind farm management, aircraft maintenance, tooling production, quality and safety or selected program track focus. Transfer students must talk to their advisor about transferring their courses

227

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network [OSTI]

: business administration, energy management, wind farm management, automation and controls, aircraft, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four students must talk to their advisor about transferring their courses over for WSU credit. Laboratory

228

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

229

Plants and Night Oxygen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants and Night Oxygen Production Plants and Night Oxygen Production Name: Ashar Status: other Grade: other Location: Outside U.S. Country: India Date: Winter 2011-2012 Question: I would like to know if there are any plants which produces oxygen at night (without photosynthesis). I was told by a friend that Holy Basil (Ocimum tenuiflorum) produces oxygen even at night and I'm not convinced. I would like to get confirmation from experts. Replies: Some plants (particularly those of dry regions, e.g., deserts) only open their stomates at night to avoid drying out to intake CO2 (and output O2) (CAM photosynthesis) http://en.wikipedia.org/wiki/Crassulacean_acid_metabolism Sincerely, Anthony R. Brach, PhD Missouri Botanical Garden Bringing oxygen producing plants into your home is a way to mimic the healthy lifestyle factors of longevity in humans from the longest lived cultures.

230

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

231

Building Technologies Office: Emerging Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emerging Technologies Emerging Technologies Printable Version Share this resource Send a link to Building Technologies Office: Emerging Technologies to someone by E-mail Share Building Technologies Office: Emerging Technologies on Facebook Tweet about Building Technologies Office: Emerging Technologies on Twitter Bookmark Building Technologies Office: Emerging Technologies on Google Bookmark Building Technologies Office: Emerging Technologies on Delicious Rank Building Technologies Office: Emerging Technologies on Digg Find More places to share Building Technologies Office: Emerging Technologies on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Technology Research, Standards, & Codes Popular Links Success Stories Previous Next Lighten Energy Loads with System Design.

232

Origin of deep subgap states in amorphous indium gallium zinc oxide: Chemically disordered coordination of oxygen  

SciTech Connect (OSTI)

The origin of the deep subgap states in amorphous indium gallium zinc oxide (a-IGZO), whether intrinsic to the amorphous structure or not, has serious implications for the development of p-type transparent amorphous oxide semiconductors. We report that the deep subgap feature in a-IGZO originates from local variations in the oxygen coordination and not from oxygen vacancies. This is shown by the positive correlation between oxygen composition and subgap intensity as observed with X-ray photoelectron spectroscopy. We also demonstrate that the subgap feature is not intrinsic to the amorphous phase because the deep subgap feature can be removed by low-temperature annealing in a reducing environment. Atomistic calculations of a-IGZO reveal that the subgap state originates from certain oxygen environments associated with the disorder. Specifically, the subgap states originate from oxygen environments with a lower coordination number and/or a larger metal-oxygen separation.

Sallis, S.; Williams, D. S. [Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States); Butler, K. T.; Walsh, A. [Center for Sustainable Technologies and Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY (United Kingdom); Quackenbush, N. F. [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Junda, M.; Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Fischer, D. A.; Woicik, J. C. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); White, B. E.; Piper, L. F. J., E-mail: lpiper@binghamton.edu [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States)

2014-06-09T23:59:59.000Z

233

NIST's Advanced Technology Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NIST's Advanced NIST's Advanced Technology Program NIST's Advanced Technology Program DOE Workshop on Hydrogen Separation and Purification Technologies Arlington, VA, Sept. 8-9, 2004 Jason Huang 301-975-4197 National Institute of Standards and Technology 100 Bureau Drive Stop 4730 Gaithersburg, MD 20899-4730 http://www.atp.nist.gov National Institute of Standards and Technology * Technology Administration * U.S. Department of Commerce ATP is part of NIST Helping America Measure Up NIST Mission ATP is part of NIST NIST Mission: Strengthen the U.S. economy and improve the quality of life by working with industry to develop and apply technology, measurements, and standards. * * * * * * 3,000 employees $771 million annual budget 2,000 field agents 1,800 guest researchers $2.2 billion co-funding of

234

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

235

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

236

Jupiter Oxygen Corporation/Albany Research Center Crada Progress Report, September  

SciTech Connect (OSTI)

The Albany Research Center (ARC) has developed a new Integrated Pollutant Removal (IPR) process for fossil-fueled boilers. Pursuant to a cooperative research and development agreement (CRADA) with Jupiter Oxygen Corporation, ARC currently is studying the IPR process as applied to the oxygen fuel technology developed by Jupiter. As discussed further below, these two new technologies are complementary. This interim report summarizes the study results to date and outlines the potential activities under the next phase of the CRADA with Jupiter.

Turner, Paul C.; Schoenfield, Mark (Jupiter Oxygen Corp.)

2004-09-13T23:59:59.000Z

237

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Haverford College Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy Sciences (BES), Chemistry, Hopper Rebecca Raber, rraber@haverford.edu, +1 610 896 1038 gtoc.jpg Carbon dioxide gas separation is important for many environmental and energy applications. Molecular dynamics simulations are used to characterize a two-dimensional hydrocarbon polymer, PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon dioxide from nitrogen, oxygen, and methane gases. Image by Joshua Schrier, Haverford College. Carbon dioxide is the primary greenhouse gas emitted through human activities, such as the combustion of fossil fuels for energy and

238

Enhanced membrane gas separations  

SciTech Connect (OSTI)

An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

Prasad, R.

1993-07-13T23:59:59.000Z

239

Explosively separable casing  

DOE Patents [OSTI]

An explosively separable casing including a cylindrical afterbody and a circular cover for one end of the afterbody is disclosed. The afterbody has a cylindrical tongue extending longitudinally from one end which is matingly received in a corresponding groove in the cover. The groove is sized to provide a pocket between the end of the tongue and the remainder of the groove so that an explosive can be located therein. A seal is also provided between the tongue and the groove for sealing the pocket from the atmosphere. A frangible holding device is utilized to hold the cover to the afterbody. When the explosive is ignited, the increase in pressure in the pocket causes the cover to be accelerated away from the afterbody. Preferably, the inner wall of the afterbody is in the same plane as the inner wall of the tongue to provide a maximum space for storage in the afterbody and the side wall of the cover is thicker than the side wall of the afterbody so as to provide a sufficiently strong surrounding portion for the pocket in which the explosion takes place. The detonator for the explosive is also located on the cover and is carried away with the cover during separation. The seal is preferably located at the longitudinal end of the tongue and has a chevron cross section.

Jacobson, Albin K. (Albuquerque, NM); Rychnovsky, Raymond E. (Livermore, CA); Visbeck, Cornelius N. (Livermore, CA)

1985-01-01T23:59:59.000Z

240

Investigation of coal fueled chemical looping combustion using Fe3O4 as oxygen carrier: Influence of variables  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a novel combustion technique with inherent CO2 separation. Magnetite (Fe3O4) was selected as the oxygen carrier. Shenhua coal (Inner Mongolia, China), straw coke and natural c...

Xiaoyan Sun; Wenguo Xiang; Sha Wang; Wendong Tian; Xiang Xu…

2010-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Air separation by the Moltox process. Interim final report  

SciTech Connect (OSTI)

Results are described of a development program on a new and energy-saving process for air separation. The Moltox process involves reversibly reacting oxygen in air with a recirculating salt solution, such that oxygen is extracted without depressurizing the remaining nitrogen. Energy savings of approximately 50% are indicated for this process compared to conventional cryogenic air separation. The development program consisted of design, construction, and operation of a 6 liter/minute pilot plant; optimization of the process flowsheet through computer modelling; investigation of engineering aspects of the process including corrosion, safety, and NO/sub x/ generation; and an economic comparison to conventional cryogenic practice. All objectives were satisfactorily achieved except for continuous operation of the pilot plant, and the modifications necessary to achieve that have been identified. Economically the Moltox process shows a substantial advantage over large scale cryogenic plants which are powered by fuel vice electricity.

Erickson, D.C.

1981-04-01T23:59:59.000Z

242

Development of an Electrochemical Separator and Compressor  

SciTech Connect (OSTI)

Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

Trent Molter

2011-04-28T23:59:59.000Z

243

Interaction of mineral matter of coal with oxygen carriers in chemical-looping combustion (CLC)  

Science Journals Connector (OSTI)

Abstract The chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) processes are novel solutions for efficient combustion with direct separation of carbon dioxide. These processes use a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor, where the fuel reacts with the solid oxygen carrier. When utilizing coal in CLC, the oxygen carrier particles could be affected through interaction with the ash-forming mineral matter found in coal, causing deactivation and/or agglomeration. In this work, possible interactions between minerals commonly encountered in coal and several promising oxygen carriers that are currently under investigation for their use in CLC are studied by both experiment and thermodynamic equilibrium calculations. Possible interaction was studied for both highly reducing and oxidizing conditions at 900 °C. Under highly reducing conditions pyrite was found to have by far the most deteriorating effect on the oxygen carrier particles, as the sulfur in the pyrite reacted with the oxygen carrier to form sulfides. Quartz and clay minerals were found to have a rather low influence on the oxygen carriers. Out of the oxygen carriers investigated, CuO/MgAl2O4 and the Mn3O4/ZrO2 oxygen carriers tended to be quite reactive towards mineral matter whereas ilmenite has been shown to be the most robust oxygen carrier. Although sulfur can clearly deactivate Ni, Cu and Mn based oxygen carriers under sub-stoichiometric conditions, when the fuel is converted fully to CO2 and H2O, sulfides are only expected for Ni-based oxygen carriers.

Martin Keller; Mehdi Arjmand; Henrik Leion; Tobias Mattisson

2014-01-01T23:59:59.000Z

244

Hydrogen (H2) Production by Oxygenic Phototrophs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical Challenges * Mixture of H 2 and O 2 ; H 2 separation and storage * CO 2 addition and overall reactor design Overcoming Low Efficiency: Improving ET * Eliminate or down-regulate pathways competing for ele * Production of organic acids * Formation of NADPH/carbon fixation

245

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

246

On The Importance of Organic Oxygen for Understanding Organic Aerosol  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

On The Importance of Organic Oxygen for Understanding Organic Aerosol On The Importance of Organic Oxygen for Understanding Organic Aerosol Particles Title On The Importance of Organic Oxygen for Understanding Organic Aerosol Particles Publication Type Journal Article Year of Publication 2006 Authors Pang, Yanbo, B. J. Turpin, and Lara A. Gundel Journal Journal of Aerosol Science and Technology Volume 40 Start Page Chapter Pagination 128-133 Abstract This study shows how aerosol organic oxygen data could provide new and independent information about organic aerosol mass, aqueous solubility of organic aerosols, formation of secondary organic aerosol (SOA) and the relative contributions of anthropogenic and biogenic sources. For more than two decades atmospheric aerosol organic mass concentration has usually been estimated by multiplying the measured carbon content by an assumed organic mass (OM)-to-organic carbon (OC ) factor of 1.4. However, this factor can vary from 1.0 to 2.5 depending on location. This great uncertainty about aerosol organic mass limits our understanding of the influence of organic aerosol on climate, visibility and health.New examination of organic aerosol speciation data shows that the oxygen content is the key factor responsible for the observed range in the OM-to-OC factor. When organic oxygen content is excluded, the ratio of non-oxygen organic mass to carbon mass varies very little across different environments (1.12 to 1.14). The non-oxygen-OM-to-non-oxygen OC factor for all studied sites (urban and non-urban) is 1.13± 0.02. The uncertainty becomes an order of magnitude smaller than the uncertainty in the best current estimates of organic mass to organic carbon ratios (1.6± 0.2 for urban and 2.1± 0.2 for non-urban areas). When aerosol organic oxygen data become available, organic aerosol mass can be quite accurately estimated using just OC and organic oxygen (OO) without the need to know whether the aerosol is fresh or aged. In addition, aerosol organic oxygen data will aid prediction of water solubility since compounds with OO-to-OC higher than 0.4 have water solubilities higher than 1g per 100 g water

247

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-11-01T23:59:59.000Z

248

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

249

Task 38 - commercial mercury remediation demonstrations: Thermal retorting and physical separation/chemical leaching. Topical report, December 1, 1994--June 30, 1996  

SciTech Connect (OSTI)

Results are presented on the demonstration of two commercial technologies for the removal of mercury from soils found at natural gas metering sites. Technologies include a thermal retorting process and a combination of separation, leaching, and electrokinetic separation process.

Charlton, D.S.; Fraley, R.H.; Stepan, D.J.

1998-12-31T23:59:59.000Z

250

Oxygen transfer in the implant environment  

E-Print Network [OSTI]

Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

Goor, Jared Braden

2007-01-01T23:59:59.000Z

251

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

252

Isotope separation apparatus  

DOE Patents [OSTI]

Isotope separation apparatus consisting of a plurality of cells disposed adjacent to each other in an evacuated container. A common magnetic field is established extending through all of the cells. A source of energetic electrons at one end of the container generates electrons which pass through the cells along the magnetic field lines. Each cell includes an array of collector plates arranged in parallel or in tandem within a common magnetic field. Sets of collector plates are disposed adjacent to each other in each cell. Means are provided for differentially energizing ions of a desired isotope by applying energy at the cyclotron resonant frequency of the desired isotope. As a result, the energized desired ions are preferentially collected by the collector plates.

Arnush, Donald (Rancho Palos Verdes, CA); MacKenzie, Kenneth R. (Pacific Palisades, CA); Wuerker, Ralph F. (Palos Verdes Estates, CA)

1980-01-01T23:59:59.000Z

253

Electrified Separation Processes in Industry  

E-Print Network [OSTI]

For any separation procedure in the chemical industry, a certain amount of reversible work in the form of free energy is required, as dictated by the second law of thermodynamics. Classical techniques for effecting liquid-phase separations...

Appleby, A. J.

1983-01-01T23:59:59.000Z

254

Electrochemical oxygen pumps. Final CRADA report.  

SciTech Connect (OSTI)

All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

Carter, J. D.

2009-10-01T23:59:59.000Z

255

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux  

E-Print Network [OSTI]

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

Mallin, Michael

256

Separation Nanotechnology of Diethylenetriaminepentaacetic Acid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded Magnetic Nanoparticles for Spent Nuclear Fuel. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded...

257

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network [OSTI]

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

258

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

259

Angling chromium to let oxygen through | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which enable facile oxygen anion diffusion at low temperature. Brighter spheres are strontium ions; less-bright spheres are chromium ions. Oxygen anions are barely visible, and...

260

Extracorporeal membrane oxygenation promotes long chain fatty...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network [OSTI]

Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

Kim, Kee Chul

2010-01-01T23:59:59.000Z

262

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

263

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...  

Broader source: Energy.gov (indexed) [DOE]

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Presentation slides from the June 19, 2012, Fuel...

264

Oxygenate Supply/Demand Balances  

Gasoline and Diesel Fuel Update (EIA)

Oxygenate Supply/Demand Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model By Tancred C.M. Lidderdale This article first appeared in the Short-Term Energy Outlook Annual Supplement 1995, Energy Information Administration, DOE/EIA-0202(95) (Washington, DC, July 1995), pp. 33-42, 83-85. The regression results and historical data for production, inventories, and imports have been updated in this presentation. Contents * Introduction o Table 1. Oxygenate production capacity and demand * Oxygenate demand o Table 2. Estimated RFG demand share - mandated RFG areas, January 1998 * Fuel ethanol supply and demand balance o Table 3. Fuel ethanol annual statistics * MTBE supply and demand balance o Table 4. EIA MTBE annual statistics * Refinery balances

265

It's Elemental - The Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine The Element Oxygen [Click for Isotope Data] 8 O Oxygen 15.9994 Atomic Number: 8 Atomic Weight: 15.9994 Melting Point: 54.36 K (-218.79°C or -361.82°F) Boiling Point: 90.20 K (-182.95°C or -297.31°F) Density: 0.001429 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 16 Group Name: Chalcogen What's in a name? From the greek words oxys and genes, which together mean "acid forming." Say what? Oxygen is pronounced as OK-si-jen. History and Uses: Oxygen had been produced by several chemists prior to its discovery in 1774, but they failed to recognize it as a distinct element. Joseph

266

The System Boron—Oxygen  

Science Journals Connector (OSTI)

This presentation covers the years 1985 to 1988 and, in part, to 1992. It continues the previous discussion of the system boron—oxygen in “Boron Compounds” 3rd Suppl. Vol. 2, 1987, pp. 1/184, and earlier liter...

Gert Heller

1993-01-01T23:59:59.000Z

267

Distillation process using microchannel technology  

DOE Patents [OSTI]

The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

2009-11-03T23:59:59.000Z

268

Gas separation process  

SciTech Connect (OSTI)

The method for production of high purity hydrogen and high purity carbon monoxide from a mixed gas stream comprising these components together with carbon dioxide and a zero to a minor amount of one or more other gaseous contaminants is described comprising the steps of: (a) passing the mixed gas stream into and through a first bed of solid adsorbent capable of selectively adsorbing carbon dioxide and water while discharging from the bed a dry CO/sub 2/-freed effluent; (b) introducing the dry CO/sub 2/-freed effluent into a cryogenic environment for cooling the same therein under conditions effective for condensation of at least the major part of the carbon monoxide present in the dry CO/sub 2/-freed effluent; (c) withdrawing from the cryogenic environment carbon monoxide of high purity; (d) separately withdrawing from the cryogenic environment an uncondensed first gas stream product comprised of crude hydrogen and subjecting the first gas stream product to selective adsorption of non-hydrogen components therefrom in a second bed of solid absorbent, while recovering from the second bed the non-sorbed fraction as a product stream of essentially pure hydrogen; (e) purging the second solid adsorbent bed to desorb non-hydrogen components sorbed therein in step (d), and withdrawing from the bed a gas stream comprising the desorbed non-hydrogen components.

Nicholas, D.M.; Hopkins, J.A.; Roden, T.M.; Bushinsky, J.P.

1988-03-22T23:59:59.000Z

269

Oxygen supply for oxyfuel CO2 capture  

Science Journals Connector (OSTI)

This paper presents the results of a study to develop Air Products’ air separation unit (ASU) offerings for oxyfuel coal CO2 capture projects. A scalable “reference plant” concept is described to match particular sizes of power generation equipment, taking into account factors such as safety, reliability, operating flexibility, efficiency, and low capital cost. We describe the selection of a process cycle to exploit the low purity requirements, as well as the options for compression machinery and drivers as the scale of the plant increases and the sizes of referenced equipment limit the possibilities. We also explore integration with other elements of the system, such as preheating condensate or heating and expanding pressurised nitrogen. In addition, we consider how the ASU affects the flexibility of the oxyfuel system and discuss how its power consumption can be reduced during periods of high power demand. Finally, the advantages and disadvantages of different execution strategies for air separation unit projects are discussed, as well as alternative commercial models for the supply of oxygen.

Paul Higginbotham; Vince White; Kevin Fogash; Galip Guvelioglu

2011-01-01T23:59:59.000Z

270

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

271

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

272

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

273

Water column oxygen demand and sediment oxygen flux: patterns of oxygen depletion in tidal creeks  

Science Journals Connector (OSTI)

Five study sites were chosen in Futch Creek, Hewletts Creek and Pages Creek,...1). Sites were chosen to reflect a range in the values of dissolved oxygen levels, chlorophyll a concentrations and nutrient (nitroge...

Tara A. MacPherson; Lawrence B. Cahoon; Michael A. Mallin

2007-07-01T23:59:59.000Z

274

Researchers Directly Observe Oxygen Signature in the Oxygen-evolving  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Researchers Directly Observe Oxygen Signature in the Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the evolution of complex aerobic life. Coupled to the reduction of carbon dioxide, biological photosynthesis contributes foodstuffs for nutrition while recycling CO2 from the atmosphere and replacing it with O2. By utilizing sunlight to power these energy-requiring reactions, photosynthesis also serves as a model for addressing societal energy needs as we enter an era of diminishing fossil fuel resources and climate change. Understanding, at the molecular level, the dynamics and mechanisms behind photosynthesis is of fundamental importance and will prove critical to the future design of devices aimed at converting sunlight into electrochemical energy and transportable fuel.

275

Enhanced Separation Efficiency in Olefin/Paraffin Distillation  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

276

A study of the separation of particles from gases  

SciTech Connect (OSTI)

Cyclones are the simplest and most reliable means of particles and gas separation. They also function as a method of air pollution control and as a cost efficient way of doing so. These basic machines have been in use for many years, and based on advances in technology, cyclones have now been designed for specific applications and conditions. These applications are restricted by inherent properties of the construction of the cyclone, and the materials being separated within the cyclone.

Stevens, G.L. II; Masudi, H.

1995-03-01T23:59:59.000Z

277

Pressurized chemical-looping combustion of coal with an iron ore-based oxygen carrier  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) is a new combustion technology with inherent separation of CO{sub 2}. Most of the previous investigations on CLC of solid fuels were conducted under atmospheric pressure. A pressurized CLC combined cycle (PCLC-CC) system is proposed as a promising coal combustion technology with potential higher system efficiency, higher fuel conversion, and lower cost for CO{sub 2} sequestration. In this study pressurized CLC of coal with Companhia Valedo Rio Doce (CVRD) iron ore was investigated in a laboratory fixed bed reactor. CVRD iron ore particles were exposed alternately to reduction by 0.4 g of Chinese Xuzhou bituminous coal gasified with 87.2% steam/N{sub 2} mixture and oxidation with 5% O{sub 2} in N{sub 2} at 970 C. The operating pressure was varied between 0.1 MPa and 0.6 MPa. First, control experiments of steam coal gasification over quartz sand were performed. H{sub 2} and CO{sub 2} are the major components of the gasification products, and the operating pressure influences the gas composition. Higher concentrations of CO{sub 2} and lower fractions of CO, CH{sub 4}, and H{sub 2} during the reduction process with CVRD iron ore was achieved under higher pressures. The effects of pressure on the coal gasification rate in the presence of the oxygen carrier were different for pyrolysis and char gasification. The pressurized condition suppresses the initial coal pyrolysis process while it also enhances coal char gasification and reduction with iron ore in steam, and thus improves the overall reaction rate of CLC. The oxidation rates and variation of oxygen carrier conversion are higher at elevated pressures reflecting higher reduction level in the previous reduction period. Scanning electron microscope and energy-dispersive X-ray spectroscopy (SEM-EDX) analyses show that particles become porous after experiments but maintain structure and size after several cycles. Agglomeration was not observed in this study. An EDX analysis demonstrates that there is very little coal ash deposited on the oxygen carrier particles but no appreciable crystalline phases change as verified by X-ray diffraction (XRD) analysis. Overall, the limited pressurized CLC experiments carried out in the present work suggest that PCLC of coal is promising and further investigations are necessary. (author)

Xiao, Rui; Song, Min; Zhang, Shuai; Shen, Laihong [School of Energy and Environment, Southeast University, Sipailou No. 2, Nanjing 210096 (China); Song, Qilei [School of Energy and Environment, Southeast University, Sipailou No. 2, Nanjing 210096 (China); Department of Chemical Engineering and Biotechnology, University of Cambridge, Pembroke Street, Cambridge CB2 3RA (United Kingdom); Lu, Zuoji [School of Energy and Environment, Southeast University, Sipailou No. 2, Nanjing 210096 (China); GCL Engineering Limited, Zhujiang No. 1, Nanjing 210008 (China)

2010-06-15T23:59:59.000Z

278

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped Ti-substituted perovskites, La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Ti{sub x}O{sub 3}, with 0 {le} x {le} 0.20, were investigated by neutron diffraction, magnetization, electric resistivity, and magnetoresistance (MR) measurements. All samples show a rhombohedral structure (space group R3C) from 10 K to room temperature. At room temperature, the cell parameters a, c and the unit cell volume increase with increasing Ti content. However, at 10 K, the cell parameter a has a maximum value for x = 0.10, and decreases for x > 0.10, while the unit cell volume remains nearly constant for x > 0.10. The average (Mn,Ti)-O bond length increases up to x = 0.15, and the (Mn,Ti)-O-(Mn,Ti) bond angle decreases with increasing Ti content to its minimum value at x = 0.15 at room temperature. Below the Curie temperature TC, the resistance exhibits metallic behavior for the x {le} 0.05 samples. A metal (semiconductor) to insulator transition is observed for the x {ge} 0.10 samples. A peak in resistivity appears below TC for all samples, and shifts to a lower temperature as x increases. The substitution of Mn by Ti decreases the 2p-3d hybridization between O and Mn ions, reduces the bandwidth W, and increases the electron-phonon coupling. Therefore, the TC shifts to a lower temperature and the resistivity increases with increasing Ti content. A field-induced shift of the resistivity maximum occurs at x {le} 0.10 compounds. The maximum MR effect is about 70% for La{sub 0.7}Sr{sub 0.3}Mn{sub 0.8}Ti{sub 0.2}O{sub 3}. The separation of TC and the resistivity maximum temperature T{sub {rho},max} enhances the MR effect in these compounds due to the weak coupling between the magnetic ordering and the resistivity as compared with La{sub 0.7}Sr{sub 0.3}MnO{sub 3}. The bulk densities of the membranes were determined using the Archimedes method. The bulk density was 5.029 and 5.57 g/cc for LSFT and dual phase membranes, respectively. The microstructure of the dual phase membrane was analyzed using SEM. It is evident from the micrograph that the microstructure is composed of dual phases. The dense circular regions are enclosed by the less dense, continuous phase which accommodates most of the pores. The pores are normally aggregated and found clustered along the dense regions where as the dense regions do not have pores. Upon closer observation of the micrograph it is revealed that the dense region has a clear circular cleavage or crack as their boundary. The circular cleavage clearly encompasses a dense region and which consists of no pore or any flaw that is visible. The size distribution of the dense, discontinuous regions is varying from 5 to 20 {micro}m with a D{sub 50} of 15 {micro}m. The grain size distribution was estimated from the micrographs using image analysis and a unimodal distribution of grains was observed with an average grain size of 1.99 {micro}m. The chemical compositions of the membranes were analyzed using EDS analysis and no other impurities were observed. The XRD analysis was carried out for the membranes and the phase purity was confirmed. The fracture toughness of LSFT membranes at room temperature has to be calculated using the Vickers indentation method. An electrochemical cell has been designed and built for measurements of the ionic conductivity by the use of blocking electrodes. Preliminary measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Modifications to the apparatus to improve the data quality have been completed. Electron microscopy studies of the origin of the slow kinetics on reduction of ferrites have been initiated. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradient

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-05-01T23:59:59.000Z

279

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network [OSTI]

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

280

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Ionic (Proton) Transport Hydrogen Separation Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(Proton) (Proton) Transport Hydrogen Separation Systems Summary Session Participants -- Ionic Transport Balachandran, Balu Cornelius, Chris Fleming, Greg Glass, Robert Hartvigsen, Joseph Higgins, Richard King, David Paster, Mark Paul, Dilo Robbins, John Samells, Anthony Schwartz, Michael Schinski, Bill Smith, Ronald Van Bibber, Lawrence Zalesky, Rick Argonne National Laboratory Sandia National Laboratory Air Liquide Lawrence Livermore National Laboratory Cerametec, Inc. CeraMem Corporation Battelle, PNNL DOE Science Applications International Corporation ExxonMobil Eltron Research, Inc. ITN Energy Systems ChevronTexaco SRI Consulting SAIC ChevronTexaco Technology Ventures Performance Goals 4-5 years (5 years upper limit) (100,000 hrs is 12 years) High durability 250-350

282

Krypton for Multi-Pane Windows: Selective Absorption of Krypton from Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Krypton for Multi-Pane Windows: Selective Absorption of Krypton from Oxygen Krypton for Multi-Pane Windows: Selective Absorption of Krypton from Oxygen in an Ionic Liquid Speaker(s): John Prausnitz Waheed Afzal Date: September 18, 2012 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Robert Hart Because of its low thermal conductivity, krypton is a useful gas for the vapor space of double- (or triple-) pane windows. However krypton is more expensive than argon, currently used for most of multi-pane windows. The high price of krypton is due to the energy-intensive cryogenic process for its recovery from oxygen that is obtained from air. Ionic liquids may provide a cost-effective absorption process for separation of krypton from the oxygen stream of a liquid-air plant. The polarizability of krypton is higher than that of oxygen; therefore, krypton solubility may be

283

Magnetism of solid oxygen  

Science Journals Connector (OSTI)

Magnetic susceptibilities of single-crystal ?-O2 and preferentially oriented polycrystalline samples of ?-O2 and ?-O2 have been measured, employing a mutual-inductance bridge method. The susceptibility of paramagnetic ?-O2 is isotropic and exhibits a temperature dependence which is not strictly Curie-Weiss, due to short-range correlations and partially hindered rotation. The susceptibility of ?-O2 exhibits very little anisotropy, but has an unusual temperature dependence which is probably due to the novel behavior of the lattice constants, modulation of inplane and out-of-plane exchange interactions, and short-range order. The susceptibility of anti-ferromagnetic ?-O2 is anisotropic, and data from five differently oriented samples have been analyzed in terms of principal antiferromagnetic susceptibilities. The data are consistent with the assumption that the easy axis is the twofold axis, b??, though the direction a?? cannot be excluded. A comprehensive analysis of the present susceptibility results and other magnetic, spectroscopic, and thermal measurements is made, with special reference to ?-O2. The perpendicular susceptibility implies an unreasonably large Néel temperature, 211 K, and a correspondingly large intersublattice exchange interaction, |J2|k=19.8 K. The effects of anisotropy and zeropoint spin deviations do not reduce this estimate by more than 15%. The temperature dependence of the parallel susceptibility suggests a much smaller value for the effective exchange interaction, |J|k=5.3 K, and appears to be well accounted for assuming a single spin-wave excitation. Antiferromagnetic resonance frequencies are analyzed and shown to yield, on assuming a dominant anisotropy equal to that of the free molecule, |J2|k=4.3 K. An approximate separation of lattice and magnetic heat capacities is effected, and a value |J|k=3.0 K deduced. The data appear to require the assumption of two spin-wave modes. Except for the perpendicular susceptibility, experimental results suggest a Néel temperature between 30 and 40 K. Meanfield and other theories lead to similar estimates, assuming that |J|k is between 3 and 4 K. The effect of the anisotropy on TN is minor, and no significant spin-shortening effect is predicted. Other experimental results are considered, and a disparate set of estimates for the exchange interaction and zone-boundary spin-wave energies is discussed. Including the effects of intrasublattice exchange interactions within the context of a two-sublattice model does not seem sufficient to remove the various discrepancies. An approximate calculation of relative overlap integrals and exchange interactions between different pairs of molecules in ?-O2 is made. It is suggested that a multisublattice model for the magnetic structure, and possibly one involving noncollinear sublattices, may provide an eventual resolution of the various difficulties. A "quasi-two-dimensional" description of ?-O2 is also considered, but appears not to offer a satisfactory explanation of the unusual and imperfectly correlated properties of this phase.

Gary C. DeFotis

1981-05-01T23:59:59.000Z

284

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

2013-08-01T23:59:59.000Z

285

MHK Technologies/Oxygen Releasing and Carbon Absorbing Ocean...  

Open Energy Info (EERE)

and 8 provision for the addition of fleets without depletion of primary feed stocks as in nuclear energy systems 2 Fig 1 In summary the system converts wave energy from the nearly...

286

Membrane Separations of Liquid Mixtures  

E-Print Network [OSTI]

MEMBRANE SEPARATIONS OF LIQUID MIXTURES Douglas R. Lloyd Separations Research Program Department of Chemical Engineering The University of Texas at Austin Austin, Texas In recent years considerable attention has been given to the need... for reduced energy costs in the chemical processing industry. A major portion of the energy consumed in this industry is associated with the separation and recovery of chemicals. Membrane processes offer energy-efficient, cost effective methods...

Lloyd, D. R.

287

Novel adsorption distillation hybrid scheme for propane/propylene separation  

SciTech Connect (OSTI)

A novel adsorption-distillation hybrid scheme is proposed for propane/propylene separation. The suggested scheme has potential for saving up to [approximately]50% energy and [approximately]15-30% in capital costs as compared with current technology. The key concept of the proposed scheme is to separate olefins from alkanes by adsorption and then separate individual olefins and alkanes by simple distillation, thereby eliminating energy intensive and expensive olefin-alkane distillation. A conceptual flow schematic for the proposed hybrid scheme and potential savings are outlined.s

Kumar, R.; Golden, T.C.; White, T.R.; Rokicki, A. (Air Products an Chemicals, Inc., Allentown, PA (United States))

1992-12-01T23:59:59.000Z

288

Technology Transfer: Available Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

test test Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you're interested in, please contact us at TTD@lbl.gov. Energy ENERGY EFFICIENT TECHNOLOGIES Aerosol Sealing Aerosol Remote Sealing System Clog-free Atomizing and Spray Drying Nozzle Air-stable Nanomaterials for Efficient OLEDs Solvent Processed Nanotube Composites OLEDS with Air-stable Structured Electrodes APIs for Online Energy Saving Tools: Home Energy Saver and EnergyIQ Carbon Dioxide Capture at a Reduced Cost Dynamic Solar Glare Blocking System Electrochromic Device Controlled by Sunlight Electrochromic Windows with Multiple-Cavity Optical Bandpass Filter Electrochromic Window Technology Portfolio Universal Electrochromic Smart Window Coating

289

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides  

E-Print Network [OSTI]

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

Paris-Sud XI, Université de

290

ELSEVIER Separations Technology 6 (1996)261-264 Short communication  

E-Print Network [OSTI]

of the acetonitrile-water system for protein purification David N. Pence, Tingyue Gu* Department of Chemical; Purification; Acetonitrile; Water; Protein 1.Introduction The acetonitrile-water system is one of the most Liquid-Liquid Equilibria (LLE) were measured at atmospheric pressure for the binary acetonitrile-water

Gu, Tingyue

291

Membrane systems for energy efficient separation of light gases  

SciTech Connect (OSTI)

Ethylene and propylene are two of the largest commodity chemicals in the United States and are major building blocks for the petrochemicals industry. These olefins are separated currently by cryogenic distillation which demands extremely low temperatures and high pressures. Over 75 billion pounds of ethylene and propylene are distilled annually in the US at an estimated energy requirement of 400 trillion BTU`s. Non-domestic olefin producers are rapidly constructing state-of-the-art plants. These energy-efficient plants are competing with an aging United States olefins industry in which 75% of the olefins producers are practicing technology that is over twenty years old. New separation opportunities are therefore needed to continually reduce energy consumption and remain competitive. Amoco has been a leader in incorporating new separation technology into its olefins facilities and has been aggressively pursuing non-cryogenic alternatives to light gas separations. The largest area for energy reduction is the cryogenic isolation of the product hydrocarbons from the reaction by-products, methane and hydrogen. This separation requires temperatures as low as {minus}150{degrees}F and pressures exceeding 450 psig. This CRADA will focus on developing a capillary condensation process to separate olefinic mixtures from light gas byproducts at temperatures that approach ambient conditions and at pressures less than 250 psig; this technology breakthrough will result in substantial energy savings. The key technical hurdle in the development of this novel separation concept is the precise control of the pore structure of membrane materials. These materials must contain specially-shaped channels in the 20-40A range to provide the driving force necessary to remove the condensed hydrocarbon products. In this project, Amoco is the technology end-user and provides the commercialization opportunity and engineering support.

Devlin, D.J.; Archuleta, T.; Barbero, R. [Los Alamos National Lab., NM (United States)] [and others

1997-04-01T23:59:59.000Z

292

Three phase downhole separator process  

DOE Patents [OSTI]

Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

Cognata, Louis John (Baytown, TX)

2008-06-24T23:59:59.000Z

293

Tennessee, Pennsylvania: Porous Power Technologies Improves Lithium Ion Battery, Wins R&D 100 Award  

Office of Energy Efficiency and Renewable Energy (EERE)

Porous Power Technologies, partnered with Oak Ridge National Laboratory (ORNL), developed SYMMETRIX HPX-F, a nanocomposite separator for improved lithium-ion battery technology.

294

E-Print Network 3.0 - annual magnet technology Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

& A is designed to separate magnet science and technology fact from fiction. If you have topics... . The application of this knowledge has led to such technological innovations as...

295

Novel, Ceramic Membrane System For Hydrogen Separation  

SciTech Connect (OSTI)

Separation of hydrogen from coal gas represents one of the most promising ways to produce alternative sources of fuel. Ceramatec, teamed with CoorsTek and Sandia National Laboratories has developed materials technology for a pressure driven, high temperature proton-electron mixed conducting membrane system to remove hydrogen from the syngas. This system separates high purity hydrogen and isolates high pressure CO{sub 2} as the retentate, which is amenable to low cost capture and transport to storage sites. The team demonstrated a highly efficient, pressure-driven hydrogen separation membrane to generate high purity hydrogen from syngas using a novel ceramic-ceramic composite membrane. Recognizing the benefits and limitations of present membrane systems, the all-ceramic system has been developed to address the key technical challenges related to materials performance under actual operating conditions, while retaining the advantages of thermal and process compatibility offered by the ceramic membranes. The feasibility of the concept has already been demonstrated at Ceramatec. This project developed advanced materials composition for potential integration with water gas shift rectors to maximize the hydrogenproduction.

Elangovan, S.

2012-12-31T23:59:59.000Z

296

Copper-Decorated Hematite as an Oxygen Carrier for in Situ Gasification Chemical Looping Combustion of Coal  

Science Journals Connector (OSTI)

Copper-Decorated Hematite as an Oxygen Carrier for in Situ Gasification Chemical Looping Combustion of Coal ... State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan, 430074 Hubei, People’s Republic of China ... Iron ore is a cheap and nontoxic oxygen carrier in chemical looping combustion (CLC) systems. ...

Weijing Yang; Haibo Zhao; Jinchen Ma; Daofeng Mei; Chuguang Zheng

2014-05-12T23:59:59.000Z

297

Technology Transfer: Available Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Please refer to the list of technologies below for licensing and research Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you're interested in, please contact us at TTD@lbl.gov. Biotechnology and Medicine DIAGNOSTICS AND THERAPEUTICS CANCER CANCER PROGNOSTICS 14-3-3 Sigma as a Biomarker of Basal Breast Cancer ANXA9: A Therapeutic Target and Predictive Marker for Early Detection of Aggressive Breast Cancer Biomarkers for Predicting Breast Cancer Patient Response to PARP Inhibitors Breast Cancer Recurrence Risk Analysis Using Selected Gene Expression Comprehensive Prognostic Markers and Therapeutic Targets for Drug-Resistant Breast Cancers Diagnostic Test to Personalize Therapy Using Platinum-based Anticancer Drugs Early Detection of Metastatic Cancer Progenitor Cells

298

Technology Transfer: Available Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Software and Information Technologies Software and Information Technologies Algorithm for Correcting Detector Nonlinearites Chatelet: More Accurate Modeling for Oil, Gas or Geothermal Well Production Collective Memory Transfers for Multi-Core Processors Energy Efficiency Software EnergyPlus:Energy Simulation Software for Buildings Tools, Guides and Software to Support the Design and Operation of Energy Efficient Buildings Flexible Bandwidth Reservations for Data Transfer Genomic and Proteomic Software LABELIT - Software for Macromolecular Diffraction Data Processing PHENIX - Software for Computational Crystallography Vista/AVID: Visualization and Allignment Software for Comparative Genomics Geophysical Software Accurate Identification, Imaging, and Monitoring of Fluid Saturated Underground Reservoirs

299

Chemical looping combustion of high-sulfur coal with NiFe2O4-combined oxygen carrier  

Science Journals Connector (OSTI)

Chemical looping combustion (CLC) of coal has gained increasing attention as a novel combustion technology for its attractive advantage in the...2. In relative to the single metal oxide-based oxygen carrier (OC),...

Baowen Wang; Gan Xiao; Xiaoyong Song…

2014-12-01T23:59:59.000Z

300

Evaluation of CuAl2O4 as an Oxygen Carrier in Chemical-Looping Combustion  

Science Journals Connector (OSTI)

Evaluation of CuAl2O4 as an Oxygen Carrier in Chemical-Looping Combustion ... † Department of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers University of Technology, SE-412 96 Göteborg, Sweden ...

Mehdi Arjmand; Abdul-Majeed Azad; Henrik Leion; Tobias Mattisson; Anders Lyngfelt

2012-10-03T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

EERE SBIR Case Study: Sonic Energy Improves Industrial Separation and Mixing Processes  

Broader source: Energy.gov (indexed) [DOE]

Resodyn to develop a simple, Resodyn to develop a simple, new technology that improves membrane performance by a factor of 5 to 10 compared to conventional mixing, offering far better separations capability for a wide variety of industries and applications. Resodyn Corporation (Butte, MT) is a small high-technology business whose objective is to develop, manufacture, and sell advanced technologies for high-

302

Robust Polymer Composite Membranes for Hydrogen Separation |...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Robust Polymer Composite Membranes for Hydrogen Separation Robust Polymer Composite Membranes for Hydrogen Separation polymercompositemembranes.pdf More Documents & Publications...

303

Quantifying the areal extent and dissolved oxygen concentrations of Archean oxygen oases.  

E-Print Network [OSTI]

??Several lines of evidence indicate that the advent of oxygenic photosynthesis preceded the oxygenation of the atmosphere—perhaps by as much as 300 million years. The… (more)

Olson, Stephanie

2013-01-01T23:59:59.000Z

304

Chapter 2 - Water Electrolysis Technologies  

Science Journals Connector (OSTI)

Abstract The purpose of this chapter is to provide an overview of the different water electrolysis technologies. In the introduction section, the general characteristics of water electrolysis (thermodynamics, kinetics, efficiency) are described. Main electrolysis technologies used to produce hydrogen and oxygen of electrolytic grade are then described in the following sections. Alkaline water electrolysis is described in Section 2.2, proton-exchange membrane water electrolysis in Section 2.3 and high-temperature water electrolysis in Section 2.4. For each technology, state-of-the-art performances are analyzed, limitations are identified and some perspectives are discussed.

Pierre Millet; Sergey Grigoriev

2013-01-01T23:59:59.000Z

305

Electrochemically Mediated Separation for Carbon Capture Michael C. Sterna  

E-Print Network [OSTI]

1 Electrochemically Mediated Separation for Carbon Capture Michael C. Sterna , Fritz Simeona. ___________________________________________________________________________________ Abstract Carbon capture technology has been proposed as an effective approach for the mitigation potential for facilitating CO2 capture at industrial-scale carbon emitters; however, the total operational

306

NETL: IEP – Oxy-Combustion CO2 Emissions Control - Oxygen-Based PC Boiler  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

– Oxy-Combustion CO2 Emissions Control – Oxy-Combustion CO2 Emissions Control Oxygen-Based PC Boiler Project No.: FC26-04NT42207 & FC26-03NT41736 Spatial Comparison of an Air-Fired Furnace versus an Oxygen-Fired Furnace. Spatial Comparison of an Air-Fired Furnace versus an Oxygen-Fired Furnace. Foster Wheeler North America Corporation will conduct to two projects to improve carbon dioxide (CO2) capture technology by developing a conceptual pulverized coal-fired boiler system design using oxygen as the combustion medium. Using oxygen instead of air produces a flue gas with a high CO2 concentration, which will facilitate CO2 capture for subsequent sequestration. The first project will develop modeling simulations that will lead to a conceptual design that addresses costs, performance, and emissions, and

307

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

308

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

309

Variable oxygen/nitrogen enriched intake air system for internal combustion engine applications  

DOE Patents [OSTI]

An air supply control system for selectively supplying ambient air, oxygen enriched air and nitrogen enriched air to an intake of an internal combustion engine includes an air mixing chamber that is in fluid communication with the air intake. At least a portion of the ambient air flowing to the mixing chamber is selectively diverted through a secondary path that includes a selectively permeable air separating membrane device due a differential pressure established across the air separating membrane. The permeable membrane device separates a portion of the nitrogen in the ambient air so that oxygen enriched air (permeate) and nitrogen enriched air (retentate) are produced. The oxygen enriched air and the nitrogen enriched air can be selectively supplied to the mixing chamber or expelled to atmosphere. Alternatively, a portion of the nitrogen enriched air can be supplied through another control valve to a monatomic-nitrogen plasma generator device so that atomic nitrogen produced from the nitrogen enriched air can be then injected into the exhaust of the engine. The oxygen enriched air or the nitrogen enriched air becomes mixed with the ambient air in the mixing chamber and then the mixed air is supplied to the intake of the engine. As a result, the air being supplied to the intake of the engine can be regulated with respect to the concentration of oxygen and/or nitrogen.

Poola, Ramesh B. (Woodridge, IL); Sekar, Ramanujam R. (Naperville, IL); Cole, Roger L. (Elmhurst, IL)

1997-01-01T23:59:59.000Z

310

AIR SEPARATION BY PRESSURE SWING ADSORPTION USING SUPERIOR ADSORBENTS  

Office of Scientific and Technical Information (OSTI)

AIR SEPARATION BY PRESSURE SWING ADSORPTION USING AIR SEPARATION BY PRESSURE SWING ADSORPTION USING SUPERIOR ADSORBENTS DE-FG26-98FT40115 FINAL TECHNICAL REPORT September 1, 1998 - August 31, 2001 Submitted to Dr. Kamalendu Das U.S. Department of Energy Federal Energy Technology Center 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 And FETC AAD Document Center Federal Energy Technology Center U.S. Department of Energy P. O. Box 10940 Pittsburgh, PA 15236-0940 By Ralph T. Yang Authors: Nick D. Hutson, Stefan C. Zajic, Salil U. Rege and Ralph T. Yang Department of Chemical Engineering University of Michigan Ann Arbor, MI 48109-2136 2 Table of Contents Page Disclaimer 3 Executive Summary 4 Chapter 1. Adsorption Properties and Structures of Pure Ag-Faujasites 7 Chapter 2. Mixed Ag-Li-X Zeolites and Their PSA Air Separation 48

311

NETL: Technology Transfer - Available Technologies for Partnership  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry Chemistry Month Posted Partnership Opportunity Patent Information 11/2013 Method and Apparatus for Production of Mixed-Metal Oxide Catalysts U.S. Patent Pending 6/2013 Carbon Capture with Ionic Liquid Sorbents 8,383,026 5/2013 Spheroid-Encapsulated Ionic Liquids for Gas Separation U.S. Patent Pending 5/2013 Pyrochlore-Based Catalysts for Syngas-Derived Alcohol Synthesis U.S. Patent Pending 3/2013 Metal Oxide Promoters for Improving the Reactivity and Capacity of Oxygen Carriers for the Chemical Looping Combustion Process U.S. Patent Pending 10/2012 Fuel Cell-Fuel Cell Hybrid System 6,623,880 10/2012 Visible Light Photoreduction of CO2 Using Heterostructured Catalysts U.S. Patent Pending 2/2012 Method for the Production of Mineral Wool and Iron from Serpentine Ore 8,033,140

312

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

313

Microbial oceanography of anoxic oxygen minimum zones  

E-Print Network [OSTI]

Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

Ulloa, Osvaldo

314

The Role of Oxygen in Coal Gasification  

E-Print Network [OSTI]

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

315

Oxygen reduction on platinum : an EIS study  

E-Print Network [OSTI]

The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

Golfinopoulos, Theodore

2009-01-01T23:59:59.000Z

316

Imaging Oxygen Molecules Up Close | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Imaging Oxygen Molecules Up Close Imaging Oxygen Molecules Up Close ARRA-enabled upgrades enhance research capabilities STM images of the same TiO2(110) area upon O2 chemisorption...

317

Pump and centrifugal separator apparatus  

SciTech Connect (OSTI)

The invention relates to agitating means for preventing the accumulation of particulate matter at the contaminate outlet orifices in a pump and centrifugal separator apparatus. The pump separator apparatus includes a rotatable casing forming a chamber for centrifugally separating the oil, water and contaminant matter in an oil well production fluid. The clean oil is collected by a stationary pitot tube in the chamber, the clean water is drawn off at an outlet port near the outer periphery of the chamber, and the dirty water and contaminants are discharged through outlet orifices formed in the outer wall of the casing. The agitating means includes rotating jet ports for directing streams of pressurized fluid tangentially along the inner surface of the casing to agitate accumulations of separated solid contaminant matter thereby preventing the clogging of the outlet orifices.

Erickson, J.W.

1981-08-11T23:59:59.000Z

318

Continuous magnetic separator and process  

DOE Patents [OSTI]

A continuous magnetic separator and process for separating a slurry comprising magnetic particles into a clarified stream and a thickened stream. The separator has a container with a slurry inlet, an overflow outlet for the discharge of the clarified slurry stream, and an underflow outlet for the discharge of a thickened slurry stream. Magnetic particles in the slurry are attracted to, and slide down, magnetic rods within the container. The slurry is thus separated into magnetic concentrate and clarified slurry. Flow control means can be used to control the ratio of the rate of magnetic concentrate to the rate of clarified slurry. Feed control means can be used to control the rate of slurry feed to the slurry inlet.

Oder, Robin R. (Export, PA); Jamison, Russell E. (Lower Burrell, PA)

2008-04-22T23:59:59.000Z

319

Fluorine separation and generation device  

DOE Patents [OSTI]

A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

The Regents of the University of California (Oakland, CA)

2008-12-23T23:59:59.000Z

320

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Contiguous Platinum Monolayer Oxygen Reduction Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Co-PIs: Jia Wang, Miomir Vukmirovic, Kotaro Sasaki, Brookhaven National Laboratory Yang Shao-Horn Massachusetts Institute of Technology Rachel O'Malley, David Thompsett, Sarah Ball, Graham Hard Johnson Matthey Fuel Cells Radoslav Adzic Brookhaven National Laboratory DOE Projects Kickoff Meeting September 30 , 2009 2 Project Overview Project Overview 1. Objectives: Objectives: Developing high performance fuel cell electrocatalysts for the oxygen reduction reaction (ORR) comprising contiguous Pt monolayer Pt monolayer on stable, inexpensive metal or alloy nanorods, nanowires, nanobars and

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Emerging Technologies  

Broader source: Energy.gov [DOE]

The Emerging Technologies (ET) Program of the Building Technologies Office (BTO) supports applied research and development (R&D) for technologies, systems, and models that contribute to building energy consumption.

322

Oxygen Electrocatalysts for Water Electrolyzers and Reversible Fuel Cells: Status and Perspective  

SciTech Connect (OSTI)

Hydrogen production by electrochemical water electrolysis has received great attention as an alternative technology for energy conversion and storage. The oxygen electrode has a substantial effect on the performance and durability in water electrolyzers and reversible fuel cells because of its intrinsically slow kinetics for oxygen evolution/reduction and poor durability under harsh operating environments. To improve oxygen kinetics and durability of the electrode, extensive studies for highly active and stable oxygen electrocatalyst have been performed. However, due to the thermodynamic instability of transition metals in acidic media, noble metal compounds have been primarily utilized as electrocatalysts in water electrolyzers and reversible fuel cells. For water electrolyzer applications, single noble metal oxides such as ruthenium oxide and iridium oxide have been studied, and binary or ternary metal oxides have been developed to take synergestic effects of each component. On the other hand, a variety of bifunctional electrocatalysts with a combination of monofunctional electrocatalysts such as platinum for oxygen reduction and iridium oxide for oxygen evolution for reversible fuel cell applications have been mainly proposed. Practically, supported iridium oxide-on-platinum, its reverse type, and non-precious metal-supported platinum and iridium bifunctional electrocatalysts have been developed. Recent theoretical calculations and experimental studies in terms of water electrolysis and fuel cell technology suggest effective ways to cope with current major challenges of cost and durability of oxygen electrocatalysts for technical applications.

Park, Seh Kyu; Shao, Yuyan; Liu, Jun; Wang, Yong

2012-11-01T23:59:59.000Z

323

Composite oxygen ion transport element  

SciTech Connect (OSTI)

A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

2007-06-12T23:59:59.000Z

324

Catalyst containing oxygen transport membrane  

SciTech Connect (OSTI)

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

2012-12-04T23:59:59.000Z

325

Respiration, photosynthesis, and oxygen isotope fractionation in ...  

Science Journals Connector (OSTI)

Jan 25, 1971 ... Respiration, photosynthesis, and oxygen isotope fractionation in oceanic surface water1. Peter M. Kroopnick. Department of Oceanography,.

2000-01-04T23:59:59.000Z

326

Structure having spatially separated photo-excitable electron-hole pairs and method of manufacturing same  

DOE Patents [OSTI]

A method for producing quantum dots. The method includes cleaning an oxide substrate and separately cleaning a metal source. The substrate is then heated and exposed to the source in an oxygen environment. This causes metal oxide quantum dots to form on the surface of the substrate.

Liang, Yong [Richland, WA; Daschbach, John L [Richland, WA; Su, Yali [Richland, WA; Chambers, Scott A [Kennewick, WA

2003-03-18T23:59:59.000Z

327

Technology Transfer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technology Transfer Since 1974, the Federal Laboratory Consortium (FLC) Award for Excellence in Technology Transfer has recognized scientists and engineers at federal government...

328

Tools & Technologies  

Broader source: Energy.gov [DOE]

We provide leadership for transforming workforce development through the power of technology. It develops corporate educational technology policy and enables the use of learning tools and...

329

Oxygen and nitrogen diffusion in ?-hafnium from first principles  

SciTech Connect (OSTI)

We use a combination of density functional theory and multistate diffusion formalism to analyze the diffusion of oxygen and nitrogen in technologically important hafnium metal. Comparing the local density approximation and the Perdew-Burke-Ernzerhof version of the generalized gradient approximation, we find that a better description of the hafnium lattice in the latter results in the correct sequence of stable and transition states for oxygen interstitials leading to essentially quantitative agreement with experiment. For oxygen diffusion, we find an isotropic temperature-dependent diffusion coefficient of D=0.082e{sup ?2.04/k{sub B}T}cm{sup 2}s{sup ?1} utilizing interstitial sites with hexahedral and octahedral coordination. For the diffusivity of nitrogen, we find that an additional stable interstitial site, the crowdion site, exists and that the diffusion coefficient is D=0.15e{sup ?2.68/k{sub B}T}cm{sup 2}s{sup ?1}. Our results also reproduce the experimental observation that nitrogen diffusivity is lower than that of oxygen in hafnium.

O'Hara, Andrew; Demkov, Alexander A., E-mail: demkov@physics.utexas.edu [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States)

2014-05-26T23:59:59.000Z

330

Technology Transfer: Available Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Sources and Beam Technologies Ion Sources and Beam Technologies GENERATORS AND DETECTORS Compact, Safe and Energy Efficient Neutron Generator Fast Pulsed Neutron Generator High Energy Gamma Generator Lithium-Drifted Silicon Detector with Segmented Contacts Low Power, High Energy Gamma Ray Detector Calibration Device Nested Type Coaxial Neutron Generator Neutron and Proton Generators: Cylindrical Neutron Generator with Nested Option, IB-1764 Neutron-based System for Nondestructive Imaging, IB-1794 Mini Neutron Tube, IB-1793a Ultra-short Ion and Neutron Pulse Production, IB-1707 Mini Neutron Generator, IB-1793b Compact Spherical Neutron Generator, IB-1675 Plasma-Driven Neutron/Gamma Generators Portable, Low-cost Gamma Source for Active Interrogation ION SOURCES WITH ANTENNAS External Antenna for Ion Sources

331

Oxygen Detection via Nanoscale Optical Indicators  

E-Print Network [OSTI]

Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

Ghosh, Ruby N.

332

8, 22252248, 2008 Detection of oxygen  

E-Print Network [OSTI]

ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

Paris-Sud XI, Université de

333

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network [OSTI]

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, mechanisms, and expected levels of oxygen and nitrogen contamination during gas tungsten arc, gas metal arc indicating the importance of dec9mposition of SiOz into silicon monoxide and oxygen are presented, indicating

Eagar, Thomas W.

334

The Mechanisms of Oxygen Reduction and Evolution Reactions in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

335

Oxygen consumption of bovine granulosa cells in vitro.  

E-Print Network [OSTI]

??The oxygen consumption rate of granulosa cells is considered to be a key determinant of oocyte oxygenation in follicles. The oxygen status of the oocyte… (more)

Li, Dongxing

2012-01-01T23:59:59.000Z

336

Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dependency of Thin Film Samaria Doped Ceria for Oxygen Sensing . Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen Sensing . Abstract: High temperature oxygen...

337

Technology Deployment List | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Deployment » Technology Deployment List Deployment » Technology Deployment List Technology Deployment List October 8, 2013 - 2:44pm Addthis Technology Ranking Criteria Technologies featured in the Technology Deployment List were ranked by: Federal Impact: Combination of energy savings potential and applicability in the Federal market (50% weighting) Cost Effectiveness: Relative cost of the implementation and average expected return typically reported in case studies as simple payback period (30% weighting) Probability of Success: Combination of the qualitative characteristics scored separately and averaged to determine probability of success. Criteria include strength of supply chain, knowledge base, implementation difficulty, and customer acceptance (20% weighting). The Federal Energy Management Program's (FEMP) Technology Deployment List

338

Clean coal technologies: A business report  

SciTech Connect (OSTI)

The book contains four sections as follows: (1) Industry trends: US energy supply and demand; The clean coal industry; Opportunities in clean coal technologies; International market for clean coal technologies; and Clean Coal Technology Program, US Energy Department; (2) Environmental policy: Clean Air Act; Midwestern states' coal policy; European Community policy; and R D in the United Kingdom; (3) Clean coal technologies: Pre-combustion technologies; Combustion technologies; and Post-combustion technologies; (4) Clean coal companies. Separate abstracts have been prepared for several sections or subsections for inclusion on the data base.

Not Available

1993-01-01T23:59:59.000Z

339

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as  

E-Print Network [OSTI]

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

340

Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes  

E-Print Network [OSTI]

1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Sandia technology & entrepreneurs improve Lasik  

SciTech Connect (OSTI)

Former Sandian Dan Neal started his company, WaveFront Sciences, based on wavefront sensing metrology technologies licensed from Sandia National Laboratories and by taking advantage of its Entrepreneurial Separation to Transfer Technology (ESTT) program. Abbott Medical Optics since acquired WaveFront and estimates that one million patients have improved the quality of their vision thanks to its products. ESTT is a valuable tool which allows Sandia to transfer technology to the private sector and Sandia employees to leave the Labs in order to start up new technology companies or help expand existing companies.

Neal, Dan; Turner, Tim

2013-11-21T23:59:59.000Z

342

Optimization of multigravity separation for recovery of ultrafine coal  

SciTech Connect (OSTI)

Enhanced gravity separation appears to be one of the most promising methods for processing all types of < 200-{mu}m coal feeds and tailings. Systems based on this technology are reviewed, and the results of investigations based on C900 Multi-Gravity Separator tests conducted to assess the treatment of < 200-{mu}m, extremely difficult-to-wash coal settling pond tailings are presented. Multi-Gravity Separator processing tests of ultra-fine tailings with a high clay particle size content (22.6% < 10 {mu}m and 60.1 % < 40 {mu}m) and a 69.56% ash content show that this material can be effectively treated after desliming (< 10 {mu}m) of clay-size particles to produce a coal with a 20.6% ash at a separator combustible material recovery of 69.3 %. Desliming is shown to be critical in reducing coal ash content and combustible material recovery. Similar improvements are anticipated in the recovery and separation processes for other enhanced gravity separation systems from the desliming of feeds. Although not a conventional form of treating Multi-Gravity Separator data, the existence of well-defined polynomial relationships based on the product of drum shake amplitude and shake frequency relative to product coal recovery, product ash content and yields at varying wash water flows is demonstrated. Low-amplitude and intermediate-to high-frequency bed agitation are shown to produce optimum ash reduction results.

Menendez, M.; Gent, M.; Torano, J.; Diego, I. [University of Oviedo, Oviedo (Spain)

2007-11-15T23:59:59.000Z

343

Savannah River Technology Center monthly report, January 1994  

SciTech Connect (OSTI)

This is the monthly progress report for the Savannah River Technology Center, which covers the following areas of interest, Tritium, Separation processes, Environmental Issues, and Waste Management.

Not Available

1994-01-01T23:59:59.000Z

344

Exploration Technologies Technology Needs Assessment  

Broader source: Energy.gov [DOE]

The Exploration Technologies Needs Assessment is a critical component of ongoing technology roadmapping efforts, and will be used to guide the program's research and development.

345

Energy Technologies  

Broader source: Energy.gov [DOE]

Best practices, project resources, and other tools on energy efficiency and renewable energy technologies.

346

Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion  

SciTech Connect (OSTI)

The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

Bhavsar, Saurabh; Veser, Goetz

2013-11-06T23:59:59.000Z

347

Microcellular foams via phase separation  

SciTech Connect (OSTI)

A study of wide variety of processes for making plastic foams shows that phase separation processes for polymers from solutions offers the most viable methods for obtaining rigid plastic foams which met the physical requirements for fusion target designs. Four general phase separation methods have been shown to give polymer foams with densities less than 0.1 g/cm/sup 3/ and cell sizes of 30..mu..m or less. These methods involve the utilization of non-solvent, chemical or thermal cooling processes to achieve a controlled phase separation wherein either two distinct phases are obtained where the polymer phase is a continuous phase or two bicontinuous phases are obtained where both the polymer and solvent are interpenetrating, continuous, labyrinthine phases. Subsequent removal of the solvent gives the final foam structure.

Young, A.T.

1985-01-01T23:59:59.000Z

348

Actinide Lanthanide Separation Process – ALSEP  

SciTech Connect (OSTI)

Separation of the minor actinides (Am, Cm) from the lanthanides at an industrial scale remains a significant technical challenge for closing the nuclear fuel cycle. To increase the safety of used nuclear fuel (UNF) reprocessing, as well as reduce associated costs, a novel solvent extraction process has been developed. The process allows for partitioning minor actinides, lanthanides and fission products following uranium/plutonium/neptunium removal; minimizing the number of separation steps, flowsheets, chemical consumption, and waste. This new process, Actinide Lanthanide SEParation (ALSEP), uses an organic solvent consisting of a neutral diglycolamide extractant, either N,N,N',N'-tetra(2 ethylhexyl)diglycolamide (T2EHDGA) or N,N,N',N'-tetraoctyldiglycolamide (TODGA), and an acidic extractant 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]), dissolved in an aliphatic diluent (e.g. n-dodecane). The An/Ln co-extraction is conducted from moderate-to-strong nitric acid, while the selective stripping of the minor actinides from the lanthanides is carried out using a polyaminocarboxylic acid/citrate buffered solution at pH anywhere between 3 and 4.5. The extraction and separation of the actinides from the fission products is very effective in a wide range of HNO3 concentrations and the minimum separation factors for lanthanide/Am exceed 30 for Nd/Am, reaching > 60 for Eu/Am under some conditions. The experimental results presented here demonstrate the great potential for a combined system, consisting of a neutral extractant such as T2EHDGA or TODGA, and an acidic extractant such as HEH[EHP], for separating the minor actinides from the lanthanides.

Gelis, Artem V.; Lumetta, Gregg J.

2014-01-29T23:59:59.000Z

349

Development of an electrochemical hydrogen separator  

SciTech Connect (OSTI)

The EHS is an electrochemical hydrogen separator based on the uniquely reversible nature of hydrogen oxidation-reduction reactions in electrochemical systems. The principle and the hardware concept are shown in Figure 1. Hydrogen from the mixed gas stream is oxidized to H{sup +} ions, transported through a cation transport electrolyte membrane (matrix) under an applied electric field and discharged in a pure hydrogen state on the cathode. The cation transfer electrolyte membrane provides a barrier between the feed and product gases. The EHS design is an offshoot of phosphoric acid fuel cell development. Although any proton transfer electrolyte can be used, the phosphoric acid based system offers a unique advantage because its operating temperature of {approximately}200{degree}C makes it tolerant to trace CO and also closely matches the water-shift reactor exit gas temperature ({approximately}250{degree}C). Hydrogen-containing streams in coal gasification systems have large carbon monoxide contents. For efficient hydrogen recovery, most of the CO must be converted to hydrogen by the low temperature water-shift reaction (Figure 2). Advanced coal gasification and gas separation technologies offer an important pathway to the clean utilization of coal resources.

Abens, S.; Fruchtman, J.; Kush, A.

1993-09-01T23:59:59.000Z

350

Modeling and Design of Material Separation Systems with Applications to Recycling  

E-Print Network [OSTI]

Material separation technology is critical to the success of the material recycling industry. End-of-life products, post-consumer waste, industrial excess, or otherwise collected materials for reuse are typically mixed ...

Wolf, Malima Isabelle, 1981-

2011-01-01T23:59:59.000Z

351

Size based separation of submicron nonmagnetic particles through magnetophoresis in structured obstacle arrays  

E-Print Network [OSTI]

The focus of this work was on developing a novel scalable size based separation technology for nonmagnetic particles in the submicron size range utilizing magnetophoretic forces. When a nonmagnetic particle is immersed in ...

Annavarapu, V. N. Ravikanth (Venkata Nagandra Ravikanth)

2010-01-01T23:59:59.000Z

352

Muon Capture in Oxygen-16  

Science Journals Connector (OSTI)

The muon capture rate in oxygen is used as a means for measuring the induced pseudoscalar coupling constant (CP) of weak interactions. The capture rate between the JP=0+ ground state of O16 and the 0-, 1-, 2-, and 3- states of N16 are calculated as a function of CP with different nuclear models. Using the experimental values of the transition rates, we then determine CP. We find that the transition rate, and therefore CP, depends strongly on the nuclear model. We conclude that 5

Vincent Gillet and David A. Jenkins

1965-10-11T23:59:59.000Z

353

Spectroscopic study of the ? phase of solid oxygen  

Science Journals Connector (OSTI)

The infrared spectrum of the ? phase of solid oxygen has been studied between room temperature and 20 K as a function of pressure up to 63 GPa. Besides the strong absorption in the fundamental O2 vibron mode and the broad doublet in the overtone region, another peak is detected in the far infrared region. The analysis of the overtone bands allows the determination of the density of states of the O2 vibron region which consists of two separated energy regions, including one the infrared and the other the Raman bands observed in the 1500–1650?cm-1 range. This result, consistent with the analysis of the other Raman and infrared bands at lower frequency, is interpreted on the basis of a crystal composed by a molecular unit formed by four oxygen atoms. This hypothesis explains the strong infrared absorption which is in contrast with the model of a crystal composed by diatomic oxygen molecules. Very thin crystalline slabs (measure the intensity of the strong infrared absorption at 1500–1550?cm-1. The measurement of the Raman spectrum as a function of the incident power and of the laser excitation frequency shows how the intensity and the frequency of the Raman lines are affected by the experimental conditions. Finally, a simple chain model provides indirect proof of our assignment of the low-frequency infrared mode and allows to rule out an association in polymeric units formed by more than four atoms even at pressures close to the insulator-metal transition.

Federico A. Gorelli; Lorenzo Ulivi; Mario Santoro; Roberto Bini

2001-02-20T23:59:59.000Z

354

Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping  

SciTech Connect (OSTI)

Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improves the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of oxygen carriers in the system by using the high-sulfur-laden asphalt fuels. In all, the scaled-up test in 10 kW CLC facility demonstrated that the preparation method of copper-based oxygen carrier not only help to maintain its good reactivity, also largely minimize its agglomeration tendency.

Pan, Wei-Ping; Cao, Yan

2012-11-30T23:59:59.000Z

355

Separations innovative concepts: Project summary  

SciTech Connect (OSTI)

This project summary includes the results of 10 innovations that were funded under the US Department's Innovative Concept Programs. The concepts address innovations that can substantially reduce the energy used in industrial separations. Each paper describes the proposed concept, and discusses the concept's potential energy savings, market applications, technical feasibility, prior work and state of the art, and future development needs.

Lee, V.E. (ed.)

1988-05-01T23:59:59.000Z

356

33rd Actinide Separations Conference  

SciTech Connect (OSTI)

Welcome to the 33rd Actinide Separations Conference hosted this year by the Lawrence Livermore National Laboratory. This annual conference is centered on the idea of networking and communication with scientists from throughout the United States, Britain, France and Japan who have expertise in nuclear material processing. This conference forum provides an excellent opportunity for bringing together experts in the fields of chemistry, nuclear and chemical engineering, and actinide processing to present and discuss experiences, research results, testing and application of actinide separation processes. The exchange of information that will take place between you, and other subject matter experts from around the nation and across the international boundaries, is a critical tool to assist in solving both national and international problems associated with the processing of nuclear materials used for both defense and energy purposes, as well as for the safe disposition of excess nuclear material. Granlibakken is a dedicated conference facility and training campus that is set up to provide the venue that supports communication between scientists and engineers attending the 33rd Actinide Separations Conference. We believe that you will find that Granlibakken and the Lake Tahoe views provide an atmosphere that is stimulating for fruitful discussions between participants from both government and private industry. We thank the Lawrence Livermore National Laboratory and the United States Department of Energy for their support of this conference. We especially thank you, the participants and subject matter experts, for your involvement in the 33rd Actinide Separations Conference.

McDonald, L M; Wilk, P A

2009-05-04T23:59:59.000Z

357

Gas Separations using Ceramic Membranes  

SciTech Connect (OSTI)

This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

Paul KT Liu

2005-01-13T23:59:59.000Z

358

Savannah River Technology Center monthly report  

SciTech Connect (OSTI)

This document contains many small reports from personnel at the technology center under the umbrella topics of reactors, tritium, separations, environment, waste management, and general engineering. Progress and accomplishments are given.

Not Available

1992-10-01T23:59:59.000Z

359

Reduced gravity rankine cycle design and optimization with passive vortex phase separation  

E-Print Network [OSTI]

. Potential drawbacks to the technology in a reduced gravity environment include two-phase fluid management processes such as liquid-vapor phase separation. The most critical location for phase separation is at the boiler exit where only vapor must be sent...

Supak, Kevin Robert

2009-05-15T23:59:59.000Z

360

Technology Roadmaps  

Broader source: Energy.gov [DOE]

This page contains links to DOE's Technology Roadmaps, multi-year plans outlining solid-state lighting goals, research and development initiatives aimed at accelerating technology advances and...

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Technology Development  

Science Journals Connector (OSTI)

In presenting this chapter on technology development, it must be stated that attempts to make an up-to-date technology survey are restricted, unfortunately, by the proprietary nature of recent advances, detail...

B. E. Conway

1999-01-01T23:59:59.000Z

362

Oxygen penetration into the bulk of palladium  

Science Journals Connector (OSTI)

Oxygen penetration into the bulk of palladium ... During heating, the reaction rate exhibited an activity maximum at 650 K, whereas no activity maximum was found during the ... ...

C. T. Campbell; D. C. Foyt; J. M. White

1977-01-01T23:59:59.000Z

363

Oxygen-Enriched Combustion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency. PROCESS HEATING...

364

Renewable Oxygenate Blending Effects on Gasoline Properties  

Science Journals Connector (OSTI)

Renewable Oxygenate Blending Effects on Gasoline Properties ... National Renewable Energy Laboratory, Golden, Colorado 80401, United States ... Energy Fuels, 2011, 25 (10), ...

Earl Christensen; Janet Yanowitz; Matthew Ratcliff; Robert L. McCormick

2011-08-16T23:59:59.000Z

365

Microsoft PowerPoint - IPRC 2012 Cold Finger Separation [9]  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fission Fission Product Separation by Cold Finger Crystal Growth Fission Product Separation by Cold Finger Crystal Growth Joshua R. Versey* and Supathorn Phongikaroon University of Idaho, Idaho Falls Center for Advanced Energy Studies *vers4197@vandals.uidaho.edu Michael F. Simpson Idaho National Laboratory Joshua R. Versey* and Supathorn Phongikaroon University of Idaho, Idaho Falls Center for Advanced Energy Studies *vers4197@vandals.uidaho.edu Michael F. Simpson Idaho National Laboratory 2012 IPRC Fontana, Wisconsin 2012 IPRC Fontana, Wisconsin Outline * Background * Motivation & Goals * Cold Finger Theory * Cold Finger Design * Experimental Program * Results & Discussion * Summary & Future Work 2 Background Advanced Pyrochemical Technology Concept 3 Background 4 Advanced Pyrochemical Technology Concept Background 5 Oxide Reduction Process Cathode

366

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

Tsuo, Y.S.

1991-08-20T23:59:59.000Z

367

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

Tsuo, Y. Simon (Lakewood, CO)

1991-01-01T23:59:59.000Z

368

Noise suppressing capillary separation system  

DOE Patents [OSTI]

A noise-suppressing capillary separation system for detecting the real-time presence or concentration of an analyte in a sample is provided. The system contains a capillary separation means through which the analyte is moved, a coherent light source that generates a beam which is split into a reference beam and a sample beam that irradiate the capillary, and a detector for detecting the reference beam and the sample beam light that transmits through the capillary. The laser beam is of a wavelength effective to be absorbed by a chromophore in the capillary. The system includes a noise suppressing system to improve performance and accuracy without signal averaging or multiple scans. 13 figs.

Yeung, E.S.; Xue, Y.

1996-07-30T23:59:59.000Z

369

Subtask 3.12 - Oxygen-Fired CFBC  

SciTech Connect (OSTI)

Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

Douglas Hajicek; Mark Musich; Ann Henderson

2007-02-28T23:59:59.000Z

370

Convex polytopes and quantum separability  

SciTech Connect (OSTI)

We advance a perspective of the entanglement issue that appeals to the Schlienz-Mahler measure [Phys. Rev. A 52, 4396 (1995)]. Related to it, we propose a criterium based on the consideration of convex subsets of quantum states. This criterium generalizes a property of product states to convex subsets (of the set of quantum states) that is able to uncover an interesting geometrical property of the separability property.

Holik, F.; Plastino, A. [Departamento de Matematica - Ciclo Basico Comun, Universidad de Buenos Aires - Pabellon III, Ciudad Universitaria, Buenos Aires, Argentina and CONICET (Argentina); National University La Plata and CONICET IFLP-CCT, C.C. 727 - 1900 La Plata (Argentina)

2011-12-15T23:59:59.000Z

371

Method to blend separator powders  

DOE Patents [OSTI]

A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

Guidotti, Ronald A. (Albuquerque, NM); Andazola, Arthur H. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM)

2007-12-04T23:59:59.000Z

372

Guayule resin separation and purification  

E-Print Network [OSTI]

fraction and reducing the presence of these terpenes to practically non-detectable levels in the polar fraction. A single component, as identified by gas chromatograph (GC) was also effectively extracted from the Texas A&M resins. Saponification..., using an FID Solvent fractionation of the Firestone resin between methanol and hexane was also apparently effective in separating the low molecular weight rubber. Figure 16 and Figure 17 show the gas chromatographs of the bottom phase (fraction "a...

Bajwa, Mohinder P.S.

1992-01-01T23:59:59.000Z

373

Advanced Development Of The Coal Fired Oxyfuel Process With CO2 Separation  

Open Energy Info (EERE)

Coal Fired Oxyfuel Process With CO2 Separation Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS) Place Germany Product Dresden based initiative that has been formed to assess oxyfuel CCS technology. References Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS) is a company located in Germany . References ↑ "Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS)" Retrieved from "http://en.openei.org/w/index.php?title=Advanced_Development_Of_The_Coal_Fired_Oxyfuel_Process_With_CO2_Separation_ADECOS&oldid=341776

374

Separation of Tritium from Wastewater  

SciTech Connect (OSTI)

A proprietary tritium loading bed developed by Molecular Separations, Inc (MSI) has been shown to selectively load tritiated water as waters of hydration at near ambient temperatures. Tests conducted with a 126 {micro}C{sub 1} tritium/liter water standard mixture showed reductions to 25 {micro}C{sub 1}/L utilizing two, 2-meter long columns in series. Demonstration tests with Hanford Site wastewater samples indicate an approximate tritium concentration reduction from 0.3 {micro}C{sub 1}/L to 0.07 {micro}C{sub 1}/L for a series of two, 2-meter long stationary column beds Further reduction to less than 0.02 {micro}C{sub 1}/L, the current drinking water maximum contaminant level (MCL), is projected with additional bed media in series. Tritium can be removed from the loaded beds with a modest temperature increase and the beds can be reused Results of initial tests are presented and a moving bed process for treating large quantities of wastewaters is proposed. The moving bed separation process appears promising to treat existing large quantities of wastewater at various US Department of Energy (DOE) sites. The enriched tritium stream can be grouted for waste disposition. The separations system has also been shown to reduce tritium concentrations in nuclear reactor cooling water to levels that allow reuse. Energy requirements to reconstitute the loading beds and waste disposal costs for this process appear modest.

JEPPSON, D.W.

2000-01-25T23:59:59.000Z

375

Anisotropic membranes for gas separation  

DOE Patents [OSTI]

A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7--25 C and then air dried at ambient temperature, typically 10--30 C. 2 figs.

Gollan, A.Z.

1987-07-21T23:59:59.000Z

376

Anisotropic membranes for gas separation  

DOE Patents [OSTI]

A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.

Gollan, Arye Z. (Newton, MA)

1987-01-01T23:59:59.000Z

377

Separation of CO2 from flue gas using electrochemical cells  

SciTech Connect (OSTI)

ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

2010-06-01T23:59:59.000Z

378

Advanced Palladium Membrane Scale-up for Hydrogen Separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Palladium Membrane Scale-up Palladium Membrane Scale-up for Hydrogen Separation Background Among the options being considered to establish greater U.S. independence from foreign energy sources is to increase the use of the nation's domestic coal reserves. The Department of Energy (DOE) is committed to supporting research and development of technologies for the reliable, efficient and environmentally friendly conversion of coal to hydrogen for utilization in advanced gasification-based electric power generation

379

Direct Observation of the Oxygenated Species during Oxygen Reduction on a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell cathode. The performance of polymer-electrolyte-membrane (PEM) fuel cells is limited by the reduction at the cathode of various oxygenated intermediates in the four-electron pathway of the oxygen reduction reaction. A research team led by SLAC scientists performed x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode

380

Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system  

E-Print Network [OSTI]

Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

Low, Clarke Alan

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations  

E-Print Network [OSTI]

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights to drive fast ionic transport. 1. Introduction The interest in Solid Oxide Fuel Cell (SOFC) technology. Current targets of cost and durability necessitate solid oxide fuel cells to operate in the intermediate

Yildiz, Bilge

382

Advanced Combustion Technologies | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Science & Innovation » Clean Coal » Advanced Combustion Science & Innovation » Clean Coal » Advanced Combustion Technologies Advanced Combustion Technologies Joe Yip, a researcher at FE's National Energy Technology Laboratory, uses laser-based Rayleigh light scattering to measure flame density and speed over a flat flame burner. Oxyfuel combustion, using oxygen in place of air with diluents such as steam or carbon dioxide, can reduce pollutant emissions in advanced power cycles using gas turbines. Photo courtesy of NETL Multimedia. Joe Yip, a researcher at FE's National Energy Technology Laboratory, uses laser-based Rayleigh light scattering to measure flame density and speed over a flat flame burner. Oxyfuel combustion, using oxygen in place of air with diluents such as steam or carbon dioxide, can reduce pollutant

383

Oxygen demand for the stabilization of the organic fraction of municipal solid waste in passively aerated bioreactors  

SciTech Connect (OSTI)

Highlights: • The use of an passively aerated reactor enables effective stabilization of OFMSW. • Convective air flow does not inhibit the aerobic stabilization of waste. • The use of an passively aerated reactor reduces the heat loss due to convection. • The volume of supplied air exceeds 1.7–2.88 times the microorganisms demand. - Abstract: Conventional aerobic waste treatment technologies require the use of aeration devices that actively transport air through the stabilized waste mass, which greatly increases operating costs. In addition, improperly operated active aeration systems, may have the adverse effect of cooling the stabilized biomass. Because active aeration can be a limiting factor for the stabilization process, passive aeration can be equally effective and less expensive. Unfortunately, there are few reports documenting the use of passive aeration systems in municipal waste stabilization. There have been doubts raised as to whether a passive aeration system provides enough oxygen to the organic matter mineralization processes. In this paper, the effectiveness of aeration during aerobic stabilization of four different organic fractions of municipal waste in a reactor with an integrated passive ventilation system and leachate recirculation was analyzed. For the study, four fractions separated by a rotary screen were chosen. Despite the high temperatures in the reactor, the air flow rate was below 0.016 m{sup 3}/h. Using Darcy’s equation, theoretical values of the air flow rate were estimated, depending on the intensity of microbial metabolism and the amount of oxygen required for the oxidation of organic compounds. Calculations showed that the volume of supplied air exceeded the microorganisms demand for oxidation and endogenous activity by 1.7–2.88-fold.

Kasinski, Slawomir, E-mail: slawomir.kasinski@uwm.edu.pl; Wojnowska-Baryla, Irena

2014-02-15T23:59:59.000Z

384

A High Pressure Carbon Dioxide Separation Process for IGCC Plants  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High Pressure Carbon Dioxide Separation Process for IGCC Plants High Pressure Carbon Dioxide Separation Process for IGCC Plants 1 A High Pressure Carbon Dioxide Separation Process for IGCC Plants S.S. Tam 1 , M.E. Stanton 1 , S. Ghose 1 , G. Deppe 1 , D.F. Spencer 2 , R.P. Currier 3 , J.S. Young 3 , G.K. Anderson 3 , L.A. Le 3 , and D.J. Devlin 3 1 Nexant, Inc. (A Bechtel Technology & Consulting Company) 45 Fremont St., 7 th Fl., San Francisco, CA 94506 2 SIMTECHE 13474 Tierra Heights Road, Redding, CA 96003 3 Los Alamos National Laboratory P.O. Box 1663 (MS J567), Los Alamos, NM 87545 1.0 INTRODUCTION Under separate contracts from the U.S. Department of Energy, Office of Fossil Energy (DOE- FE), Los Alamos National Laboratory, and a team of SIMTECHE and Nexant (a Bechtel Technology and Consulting Company) are jointly working to develop the proprietary process for

385

Department of Engineering Technology Technology Education  

E-Print Network [OSTI]

Department of Engineering Technology Technology Education A Teacher Education Program New Jersey Institute of Technology #12;WHAT WILL YOU LEARN? Technology teachers teach problem-based learning utilizing math, science and technology principles. Technological studies involve students: · Designing

Bieber, Michael

386

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen  

E-Print Network [OSTI]

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

Sibener, Steven

387

Cu-Pd Hydrogen Separation Membranes with Reduced Palladium Content and Improved Performance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cu-Pd Hydrogen Separation Membranes with Reduced Cu-Pd Hydrogen Separation Membranes with Reduced Palladium Content and Improved Performance Opportunity This patent-pending technology, "Cu-Pd Hydrogen Separation Membranes with Reduced Palladium Content and Improved Performance," consists of copper-palladium alloy compositions for hydrogen separation membranes that use less palladium and have a potential increase in hydrogen permeability and resistance to sulfur degradation compared to currently available copper-palladium membranes. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview NETL is working to help produce and deliver hydrogen from fossil fuels including coal in commercially applicable and environmentally

388

EPA speeds technology implementation  

SciTech Connect (OSTI)

Common barriers block the use of innovative remediation technologies. The Innovative Treatment Remediation Demonstration (ITRD) Program at the US Department of Energy`s (DOE`s) Sandia National Laboratories was initiated in 1993 in cooperation with the US Environmental Protection Agency`s (EPA`s) Technology Innovation Office in an attempt to reduce these barriers and accelerate the implementation of innovative remediation technologies. The innovative technologies considered for evaluation by the ITRD program lack the cost and performance information that would otherwise permit their full consideration as remedial alternatives. These technologies have often shown promise in pilot-scale applications but have limited full-scale data. Some examples in this category include: bioremediation, in situ dynamic stripping, soil washing and soil flushing, solvent and surfactant extraction and chemical treatment, in situ passive treatment, and advanced physical separation techniques. Currently, three ITRD projects are under way. ITRD sites are generally small, and most are characterized sites already scheduled for remediation. Thus, each project can be initiated quickly; additional program costs are minimized; and overall site remediation is accelerated. ITRD projects tend to target sites with typical soil and groundwater contamination problems. Contaminants at such sites include chlorinated solvents and petroleum products; pesticides, polychlorinated biphenyls (PCBs), and dioxins; heavy metals; explosives; and complex or multiconstituent contamination. The paper describes the activities at these three projects located at Pinellas, Mound Laboratory, and Fernald.

Hightower, M.M. [Sandia National Labs., Albuquerque, NM (United States). Environmental Programs Center

1996-04-01T23:59:59.000Z

389

Continuation of Crosscutting Technology Development at Cast  

SciTech Connect (OSTI)

This Final Technical Report describes progress made on the sub-projects awarded in the Cooperative Agreement DE-FC26-05NT42457: Continuation of Crosscutting Technology Development at Center for Advanced Separation Technologies (CAST). The final reports for each sub-project are attached in the appendix. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: a) Solid-solid separation b) Solid-liquid separation c) Chemical/Biological Extraction d) Modeling and Control, and e) Environmental Control.

Yoon, Roe-Hoan

2012-03-31T23:59:59.000Z

390

Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants  

SciTech Connect (OSTI)

Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

2001-11-06T23:59:59.000Z

391

Reactivity of a CaSO4-oxygen carrier in chemical-looping combustion of methane in a fixed bed reactor  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a promising technology for the combustion of gas or solid fuel with efficient...2. A reactivity study of CaSO4 oxygen carrier in CLC of methane was conducted in a laboratory s...

Qilei Song; Rui Xiao; Zhongyi Deng; Laihong Shen…

2009-03-01T23:59:59.000Z

392

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

393

Atomic Spectroscopy and Separated Isotopes  

Science Journals Connector (OSTI)

The advantages in the use of separated isotopes in atomic spectroscopy for the determination of nuclear momentsI ? Q and for studies of the isotope-shift phenomena are discussed. Illustrations of spectra are given for mercury uranium and samarium. In addition a summary is given of twenty-two so-called problem nuclei i.e. those naturally occurring isotopes for which the nuclear moments are completely uncertain. Concluding remarks are made on such problems as the evaluation of the absolute magnitude of isotope shifts the role of “forbidden transitions” in isotope spectra and the potential future value of spectro-isotopic assay techniques.

J. R. McNally Jr.

1952-01-01T23:59:59.000Z

394

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

395

Available Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 News Stories (and older) 6 News Stories (and older) 12.21.2005___________________________________________________________________ Genzyme acquires gene therapy technology invented at Berkeley Lab. Read more here. 07.19.2005 _________________________________________________________________ Symyx, a start up company using Berkeley Lab combinatorial chemistry technology licensed by the Technology Transfer Department and developed by Peter Schultz and colleagues in the Materials Sciences Division, will be honored with Frost & Sullivan's 2005 Technology Leadership Award at their Excellence in Emerging Technologies Awards Banquet for developing enabling technologies and methods to aid better, faster and more efficient R&D. Read more here. 07.11.2005 _________________________________________________________________ Nanosys, Inc., a Berkeley Lab startup, is among the solar nanotech companies investors along Sand Hill Road in Menlo Park hope that thinking small will translate into big profits. Read more here.

396

Clean coal technology applications  

SciTech Connect (OSTI)

{open_quotes}Coal is a stratified rock formed of the more or less altered remains of plants (together with associated mineral matter) which flourished in past ages{hor_ellipsis} The problem of the origin and maturing of coal is complicated by the fact that every coal contains, in addition to carbon, hydrogen and oxygen, variable proportions of nitrogen and sulfur which are combined in unknown ways in the organic molecules...{close_quotes}. The challenge with coal has always been the management of its mineral matter, sulfur and nitrogen contents during use. The carbon content of fuels, including coal, is a more recent concern. With clean coal technologies, there are opportunities for ensuring the sustained use of coal for a very long time. The clean coal technologies of today are already capable of reducing, if not eliminating, harmful emissions. The technologies of the future will allow coal to be burned with greatly reduced emissions, thus eliminating the necessity to treat them after they occur.

Bharucha, N.

1993-12-31T23:59:59.000Z

397

Singlet oxygen luminescence detection with a fibre-coupled superconducting  

E-Print Network [OSTI]

Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single Triplet State Singlet State 1O2 Ground State Oxygen 3O2 Singlet oxygen Free space singlet oxygen luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector

Greenaway, Alan

398

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

399

Fuel Technologies  

Broader source: Energy.gov [DOE]

Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

400

Layering Technologies  

Science Journals Connector (OSTI)

Planar technology requires that thin layers of materials be formed and patterned sequentially, commencing with a flat rigid substrate. The key aspects of each layer are its Thi...

Ivor Brodie; Julius J. Muray

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Prospects of Al2O3 and MgAl2O4-Supported CuO Oxygen Carriers in Chemical-Looping Combustion (CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU)  

Science Journals Connector (OSTI)

The chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) processes are attractive solutions for efficient combustion with direct separation of carbon dioxide. In this work, the feasibility of CuO supported on Al2O3 and MgAl...

Mehdi Arjmand; Abdul-Majeed Azad; Henrik Leion; Anders Lyngfelt; Tobias Mattisson

2011-10-21T23:59:59.000Z

402

Separations and safeguards model integration.  

SciTech Connect (OSTI)

Research and development of advanced reprocessing plant designs can greatly benefit from the development of a reprocessing plant model capable of transient solvent extraction chemistry. This type of model can be used to optimize the operations of a plant as well as the designs for safeguards, security, and safety. Previous work has integrated a transient solvent extraction simulation module, based on the Solvent Extraction Process Having Interaction Solutes (SEPHIS) code developed at Oak Ridge National Laboratory, with the Separations and Safeguards Performance Model (SSPM) developed at Sandia National Laboratory, as a first step toward creating a more versatile design and evaluation tool. The goal of this work was to strengthen the integration by linking more variables between the two codes. The results from this integrated model show expected operational performance through plant transients. Additionally, ORIGEN source term files were integrated into the SSPM to provide concentrations, radioactivity, neutron emission rate, and thermal power data for various spent fuels. This data was used to generate measurement blocks that can determine the radioactivity, neutron emission rate, or thermal power of any stream or vessel in the plant model. This work examined how the code could be expanded to integrate other separation steps and benchmark the results to other data. Recommendations for future work will be presented.

Cipiti, Benjamin B.; Zinaman, Owen

2010-09-01T23:59:59.000Z

403

Results of initial operation of the Jupiter Oxygen Corporation oxy-fuel 15 MWth burner test facility  

SciTech Connect (OSTI)

Jupiter Oxygen Corporation (JOC), in cooperation with the National Energy Technology Laboratory (NETL), constructed a 15 MWth oxy-fuel burner test facility with Integrated Pollutant Removal (IPRTM) to test high flame temperature oxy-fuel combustion and advanced carbon capture. Combustion protocols include baseline air firing with natural gas, oxygen and natural gas firing with and without flue gas recirculation, and oxygen and pulverized coal firing with flue gas recirculation. Testing focuses on characterizing burner performance, determining heat transfer characteristics, optimizing CO2 capture, and maximizing heat recovery, with an emphasis on data traceability to address retrofit of existing boilers by directly transforming burner systems to oxy-fuel firing.

Thomas Ochs, Danylo Oryshchyn, Rigel Woodside, Cathy Summers, Brian Patrick, Dietrich Gross, Mark Schoenfield, Thomas Weber and Dan O'Brien

2009-04-01T23:59:59.000Z

404

Preferential Use of an Anode as an Electron Acceptor by an Acidophilic Bacterium in the Presence of Oxygen  

Science Journals Connector (OSTI)

...microbial fuel cell development, in which bacteria...separated from the cathode compartment, generally...of the microbial electrocatalyst (5, 8, 30...for the further development of microbial fuel...oxygen reduction cathodes. Biosens. Bioelectron...cells and their development. Biosens. Bioelectron...

Moustafa Malki; Antonio L. De Lacey; Nuria Rodríguez; Ricardo Amils; Victor M. Fernandez

2008-05-16T23:59:59.000Z

405

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)  

E-Print Network [OSTI]

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

Levin, Lisa

406

Glass Technology  

Science Journals Connector (OSTI)

... WE have received from the Department of Glass Technology, University of Sheffield, a copy of vol. ii. of “Experimental Researches ... that department. The papers included have already appeared in the Journal of the Society of Glass Technology. They range over a somewhat wide field of the ...

1920-08-23T23:59:59.000Z

407

Charge Separation Kinetics in Intact Photosystem II Core Particles Is Trap-Limited. A Picosecond Fluorescence Study  

E-Print Network [OSTI]

-induced charge separation across the membrane occurs. Eventually the oxygen-evolving complex is oxidized centers. At least two new lifetime components of 2 and 9 ps have been resolved in the kinetics by global of the equilibrated excited reaction center in intact photosystem II and have found two early radical pairs before

Roegner, Matthias

408

NREL: Technology Deployment - Technology Acceleration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

assistance to federal and private industry to help address market barriers to sustainable energy technologies. Learn more about NREL's work in the following areas:...

409

Novel membrane technology for green ethylene production.  

SciTech Connect (OSTI)

Ethylene is currently produced by pyrolysis of ethane in the presence of steam. This reaction requires substantial energy input, and the equilibrium conversion is thermodynamically limited. The reaction also produces significant amounts of greenhouse gases (CO and CO{sub 2}) because of the direct contact between carbon and steam. Argonne has demonstrated a new way to make ethylene via ethane dehydrogenation using a dense hydrogen transport membrane (HTM) to drive the unfavorable equilibrium conversion. Preliminary experiments show that the new approach can produce ethylene yields well above existing pyrolysis technology and also significantly above the thermodynamic equilibrium limit, while completely eliminating the production of greenhouse gases. With Argonne's approach, a disk-type dense ceramic/metal composite (cermet) membrane is used to produce ethylene by dehydrogenation of ethane at 850 C. The gas-transport membrane reactor combines a reversible chemical reaction with selective separation of one product species and leads to increased reactant conversion to the desired product. In an experiment ethane was passed over one side of the HTM membrane and air over the other side. The hydrogen produced by the dehydrogenation of ethane was removed and transported through the HTM to the air side. The air provided the driving force required for the transport of hydrogen through the HTM. The reaction between transported hydrogen and oxygen in air can provide the energy needed for the dehydrogenation reaction. At 850 C and 1-atm pressure, equilibrium conversion of ethane normally limits the ethylene yield to 64%, but Argonne has shown that an ethylene yield of 69% with a selectivity of 88% can be obtained under the same conditions. Coking was not a problem in runs extending over several weeks. Further improved HTM materials will lower the temperature required for high conversion at a reasonable residence time, while the lower temperature will suppress unwanted side reactions and prolong membrane life. With the Argonne approach, oxygen does not contact the ethane/ethylene stream, so oxidation products are not formed. Consequently, higher selectivity to ethylene and fewer by-products can be achieved. Some benefits are: (1) Simplifies overall product purification and processing schemes; (2) Results in greater energy efficiency; (3) Completely eliminates greenhouse gases from the reactor section; and (4) Lowers the cost of the 'back end' purification train, which accounts for about 70% of the capital cost of a conventional ethylene production unit.

Balachandran, U.; Lee, T. H.; Dorris, S. E.; Udovich, C. A.; Scouten, C. G.; Marshall, C. L. (Energy Systems); ( CSE)

2008-01-01T23:59:59.000Z

410

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

411

Blood oxygen transport and depletion : the key of consummate divers  

E-Print Network [OSTI]

and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

Meir, Jessica Ulrika

2009-01-01T23:59:59.000Z

412

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

413

Vehicle Technologies Office: Vehicle Technologies Office Recognizes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vehicle Technologies Vehicle Technologies Office Recognizes Outstanding Researchers to someone by E-mail Share Vehicle Technologies Office: Vehicle Technologies Office Recognizes Outstanding Researchers on Facebook Tweet about Vehicle Technologies Office: Vehicle Technologies Office Recognizes Outstanding Researchers on Twitter Bookmark Vehicle Technologies Office: Vehicle Technologies Office Recognizes Outstanding Researchers on Google Bookmark Vehicle Technologies Office: Vehicle Technologies Office Recognizes Outstanding Researchers on Delicious Rank Vehicle Technologies Office: Vehicle Technologies Office Recognizes Outstanding Researchers on Digg Find More places to share Vehicle Technologies Office: Vehicle Technologies Office Recognizes Outstanding Researchers on AddThis.com...

414

Vehicle Technologies Office: Graduate Automotive Technology Education  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Deployment Deployment Site Map Printable Version Share this resource Send a link to Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) to someone by E-mail Share Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) on Facebook Tweet about Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) on Twitter Bookmark Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) on Google Bookmark Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) on Delicious Rank Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) on Digg Find More places to share Vehicle Technologies Office: Graduate Automotive Technology Education (GATE) on AddThis.com...

415

Building Technologies Office: Emerging Technologies Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emerging Technologies Emerging Technologies Activities to someone by E-mail Share Building Technologies Office: Emerging Technologies Activities on Facebook Tweet about Building Technologies Office: Emerging Technologies Activities on Twitter Bookmark Building Technologies Office: Emerging Technologies Activities on Google Bookmark Building Technologies Office: Emerging Technologies Activities on Delicious Rank Building Technologies Office: Emerging Technologies Activities on Digg Find More places to share Building Technologies Office: Emerging Technologies Activities on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Appliances Research Building Envelope Research Windows, Skylights, & Doors Research Space Heating & Cooling Research Water Heating Research

416

Guidelines For Developing Low Energy Separation Processes  

E-Print Network [OSTI]

A large portion of the energy required by the process industry is consumed by separation processes. This paper discusses current engineering techniques that can be used in the development and optimization of low energy separation processes....

Bojnowski, J. H.; Hanks, D. L.

1981-01-01T23:59:59.000Z

417

Separation of magnetic field lines  

SciTech Connect (OSTI)

The field lines of magnetic fields that depend on three spatial coordinates are shown to have a fundamentally different behavior from those that depend on two coordinates. Unlike two-coordinate cases, a flux tube in a magnetic field that depends on all three spatial coordinates that has a circular cross section at one location along the tube characteristically has a highly distorted cross section at other locations. In an ideal evolution of a magnetic field, the current densities typically increase. Crudely stated, if the current densities increase by a factor {sigma}, the ratio of the long to the short distance across a cross section of a flux tube characteristically increases by e{sup 2{sigma}}, and the ratio of the longer distance to the initial radius increases as e{sup {sigma}}. Electron inertia prevents a plasma from isolating two magnetic field structures on a distance scale shorter than c/{omega}{sub pe}, which is about 10 cm in the solar corona, and reconnection must be triggered if {sigma} becomes sufficiently large. The radius of the sun, R{sub Circled-Dot-Operator }=7 Multiplication-Sign 10{sup 10}cm is about e{sup 23} times larger, so when {sigma} Greater-Than-Or-Equivalent-To 23, two lines separated by c/{omega}{sub pe} at one location can be separated by the full scale of any magnetic structures in the corona at another. The conditions for achieving a large exponentiation, {sigma}, are derived, and the importance of exponentiation is discussed.

Boozer, Allen H. [Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027 (United States)

2012-11-15T23:59:59.000Z

418

Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF  

E-Print Network [OSTI]

neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

2010-01-01T23:59:59.000Z

419

Long-term oxygen sensor implantation in the porcine subcutaneous environment  

E-Print Network [OSTI]

Membrane-­?Covered  Oxygen  Electrode.   Analytical  Microvascular  and  tissue  oxygen   distribution.  vitro  stability  of  an  oxygen  sensor.   Anal  Chem,  

Kumosa, Lucas Stefan

2011-01-01T23:59:59.000Z

420

Direct-write milling of diamond by a focused oxygen ion beam  

E-Print Network [OSTI]

Recent advances in focused ion beam technology have enabled high-resolution, direct-write nanofabrication using light ions. Studies with light ions to date have, however, focused on milling of materials where sub-surface ion beam damage does not inhibit device performance. Here we report on direct-write milling of single crystal diamond using a focused beam of oxygen ions. Material quality is assessed by Raman and luminescence analysis, and reveals that the damage layer generated by oxygen ions can be removed by nonintrusive post-processing methods such as localised electron beam induced chemical etching.

Martin, Aiden A; Botman, Aurelien; Toth, Milos; Aharonovich, Igor

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal  

SciTech Connect (OSTI)

This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

Eric P. Robertson

2007-09-01T23:59:59.000Z

422

On the maximum value of the cosmic abundance of oxygen and the oxygen yield  

E-Print Network [OSTI]

We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2007-01-11T23:59:59.000Z

423

Liquid fossil fuel technology  

SciTech Connect (OSTI)

Progress reports are presented under the following headings: (1) extraction (technology assessment, oil research, gas research); (2) liquid processing (characterization, thermodynamics, processing technology); (3) utilization (energy conservation); and (4) project integration and technology transfer. BETC publications are also listed. Some of the highlights for this period are: the Bartlesville Energy Technology Center was converted into NIPER, the National Institute for Petroleum and Energy Research on October 1, 1983; modelling of enthalpies, heat capacities and volumes of aqueous surfactant solutions began using a mass action model; a series of experiments were run on upgrading by hydrogenation SRC-II coal liquid at different degrees of severity and the products have been analyzed; heavy crude oil extracts were separated into fraction with high performance liquid chromatography by Lawrence Berkeley Laboratory and the mass spectra and electron spin resonance were determin ed; and particulates from exhaust gases of diesel engines using fire fuel types are being collected and will be analyzed by chemical methods and results will be compared with those obtained by biological assay. (ATT)

Not Available

1983-01-01T23:59:59.000Z

424

Cascade Performance for Large Separation Factors  

Science Journals Connector (OSTI)

Technical Paper / Argonne National Laboratory Specialists’ Workshop on Basic Research Needs for Nuclear Waste Management / Isotopes Separation

George Emanuel*

425

Device for hydrogen separation and method  

DOE Patents [OSTI]

A device for hydrogen separation has a porous support and hydrogen separation material on the support. The support is prepared by heat treatment of metal microparticles, preferably of iron-based or nickel-based alloys that also include aluminum and/or yttrium. The hydrogen separation material is then deposited on the support. Preferred hydrogen separation materials include metals such as palladium, alloys, platinum, refractory metals, and alloys.

Paglieri, Stephen N. (White Rock, NM); Anderson, Iver E. (Ames, IA); Terpstra, Robert L. (Ames, IA)

2009-11-03T23:59:59.000Z

426

Fuel Cell Technologies Office: Glossary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Glossary Glossary This glossary contains terms and acronyms related to hydrogen and fuel cell technologies. A B C D E F G H I J K L M N O P Q R S T U V W X Y Z - Acronyms A AC Generator (or Alternator) An electric device that produces an electric current that reverses direction many times per second. Also called a synchronous generator. Adsorption The adhesion of the molecules of gases, dissolved substances, or liquids to the surface of the solids or liquids with which they are in contact. Air The mixture of oxygen, nitrogen, and other gases that, with varying amounts of water vapor, forms the atmosphere of the earth. Alkaline Fuel Cell (AFC) A type of hydrogen/oxygen fuel cell in which the electrolyte is concentrated potassium hydroxide (KOH) and the hydroxide ions (OH-) are transported from the cathode to the anode.

427

Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$  

E-Print Network [OSTI]

We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capaciti...

Santilli, R M

2000-01-01T23:59:59.000Z

428

GEOMETRIC SOURCE SEPARATION: MERGING CONVOLUTIVE SOURCE  

E-Print Network [OSTI]

adaptive beamforming algorithms by a cross-power criteria, we gain new geometric source separation with convo- lutive blind source separation. We concentrate on cross-power spectral min- imization which is su to ambiguities in the choice of separating lters. There are in theory multiple lters that invert the room

Parra, Lucas C.

429

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

430

Density Functional Theory Study of Oxygen Reduction Activity...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Abstract: The...

431

Testing Oxygen Reduction Reaction Activity with the Rotating...  

Broader source: Energy.gov (indexed) [DOE]

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

432

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

433

Oxygen detected in atmosphere of Saturn's moon Dione  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

434

Effects of Oxygen-Containing Functional Groups on Supercapacitor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular dynamics (MD)...

435

Isolation, Characterization of an Intermediate in an Oxygen Atom...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

436

Direct Measurement of Oxygen Incorporation into Thin Film Oxides...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

437

Oxygen Transport Studies in Nanocrystalline Ceria Films. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transport Studies in Nanocrystalline Ceria Films. Oxygen Transport Studies in Nanocrystalline Ceria Films. Abstract: Oxygen uptake and conductivity were measured by nuclear...

438

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...

439

Density Functional Study of the Structure, Stability and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

440

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

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441

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

442

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

443

LED–LED portable oxygen gas sensor  

Science Journals Connector (OSTI)

A portable instrument for oxygen determination, based on the quenching of phosphorescent octaethylporphyrin by gaseous O2..., has been developed using the fluorimetric paired emitter–detector diode technique (FPE...

I. M. Perez de Vargas-Sansalvador; C. Fay…

2012-12-01T23:59:59.000Z

444

Electron-impact excitation of neutral oxygen  

E-Print Network [OSTI]

Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

P. S. Barklem

2006-09-25T23:59:59.000Z

445

Design optimization of oxygenated fluid pump  

E-Print Network [OSTI]

In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

Piazzarolo, Bruno Aiala

2012-01-01T23:59:59.000Z

446

Interactions of oxygen with Zr(0001)  

SciTech Connect (OSTI)

Interaction of oxygen with Zr(0001) have been studied using low energy electron diffraction (LEED), work function ([Delta][phi]), static and dynamic secondary ion mass spectrometry (SSIMS, DSIMS), thermal desorption spectroscopy (TDS), Auger electron spectroscopy (AES) and nuclear reaction analysis (NRA). The initial sticking coefficient of oxygen is close to unity up to [approximately]0.75 ML at 90, 293 and 473 K. Oxygen chemisorption is disordered at room temperature and below. Heating the disordered surface to [approximately]473 K causes all oxygen to move to subsurface sites. A (1x2) ordered oxygen underlayer is formed consisting of three rotated domains of (1x2) superstructure with the oxygen atoms located between the first and second planes of zirconium atoms. This structure is stable up to about 573 K, above which temperature oxygen diffuses into the bulk. AES measurements employing oxide and metal signals were used to model the growth of oxide which was found to be temperature dependent. Both NRA and AES indicate linear oxygen uptake kinetics at 90 K with abrupt passivation as the limiting thickness is reached. SSIMS ion yield data taken during the oxidation of Zr(0001) at 90, 293 and 473 K was interpretable in the context of the oxygen coverage. Dissolution into the bulk of the saturated oxide layer grown at 90 K appears to occur by an island-type mechanism rather than layer-by-layer dissolution from the oxide-metal interface. Large [Delta][phi] changes that occur upon oxidation at 90 K and temperature ramping of the saturated oxide to 300 K are attributable to reversible molecular oxygen adsorption on the oxide. The diffusion of oxygen normal to the [0001] plane of zirconium has been measured by AES: D[sub 0] = (4.14.[+-]1.92) x 10[sup [minus]2] cm[sup [minus]2] s[sup [minus]1] and E[sub a]= 199.1 [+-]2.6 kJ mol[sup [minus]1]. The fundamental vibrational frequency for the [alpha]-Zr lattice was calculated to be (6.3 [+-] 2.9) x 10[sup 13]s[sup [minus]1].

Flinn, B.J.

1992-01-01T23:59:59.000Z

447

Building Technologies Office: Emerging Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Creating the Next Generation of Energy Efficient Technology Creating the Next Generation of Energy Efficient Technology The Emerging Technologies team partners with national laboratories, industry, and universities to advance research, development, and commercialization of energy efficient and cost effective building technologies. These partnerships help foster American ingenuity to develop cutting-edge technologies that have less than 5 years to market readiness, and contribute to the goal to reduce energy consumption by at least 50%. Sandia Cooler's innovative, compact design combines a fan and a finned metal heat sink into a single element, efficiently transferring heat in microelectronics and reducing energy use. Supporting Innovative Research to Help Reduce Energy Use and Advance Manufacturing Learn More

448

Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon  

SciTech Connect (OSTI)

The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

2012-08-19T23:59:59.000Z

449

Electron Paramagnetic Resonance Oxygen Image Hypoxic Fraction Plus Radiation Dose Strongly Correlates With Tumor Cure in FSa Fibrosarcomas  

SciTech Connect (OSTI)

Purpose: Tumor hypoxia has long been known to produce resistance to radiation. In this study, electron paramagnetic resonance (EPR) oxygen imaging was investigated for its power to predict the success of tumor control according to tumor oxygenation level and radiation dose. Methods and Materials: A total of 34 EPR oxygen images were obtained from the legs of C3H mice bearing 0.5-cm{sup 3} FSa fibrosarcomas under both normal (air breathing) and clamped tumor conditions. Under the same conditions as those during which the images were obtained, the tumors were irradiated to a variety of doses near the FSa dose at which 50% of tumors were cured. Tumor tissue was distinguished from normal tissue using co-registration of the EPR oxygen images with spin-echo magnetic resonance imaging of the tumor and/or stereotactic localization. The tumor voxel statistics in the EPR oxygen image included the mean and median partial pressure of oxygen and the fraction of tumor voxels below the specified partial pressure of oxygen values of 3, 6, and 10 mm Hg. Bivariate logistic regression analysis using the radiation dose and each of the EPR oxygen image statistics to determine which best separated treatment failure from success. Results: The measurements of the dose at which 50% of tumors were cured were similar to those found in published data for this syngeneic tumor. Bivariate analysis of 34 tumors demonstrated that tumor cure correlated with dose (p = 0.004) and with a <10 mm Hg hypoxic fraction (p = 0.023). Conclusion: Our results have shown that, together, radiation dose and EPR image hypoxic fraction separate the population of FSa fibrosarcomas that are cured from those that fail, thus predicting curability.

Elas, Martyna [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Faculty of Biochemistry, Biophysics and Biotechnology, Jagiellonian University, Krakow (Poland); Bell, Rebecca; Hleihel, Danielle; Barth, Eugene D.; McFaul, Colin [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Haney, Chad R. [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Department of Radiology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Bielanska, Joanna; Pustelny, Katarzyna [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Faculty of Biochemistry, Biophysics and Biotechnology, Jagiellonian University, Krakow (Poland); Ahn, Kang-Hyun [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States)] (and others)

2008-06-01T23:59:59.000Z

450

Underground coal gasification using oxygen and steam  

SciTech Connect (OSTI)

In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

2009-07-01T23:59:59.000Z

451

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Man