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1

Innovative Separations Technologies  

SciTech Connect (OSTI)

Reprocessing used nuclear fuel (UNF) is a multi-faceted problem involving chemistry, material properties, and engineering. Technology options are available to meet a variety of processing goals. A decision about which reprocessing method is best depends significantly on the process attributes considered to be a priority. New methods of reprocessing that could provide advantages over the aqueous Plutonium Uranium Reduction Extraction (PUREX) and Uranium Extraction + (UREX+) processes, electrochemical, and other approaches are under investigation in the Fuel Cycle Research and Development (FCR&D) Separations Campaign. In an attempt to develop a revolutionary approach to UNF recycle that may have more favorable characteristics than existing technologies, five innovative separations projects have been initiated. These include: (1) Nitrogen Trifluoride for UNF Processing; (2) Reactive Fluoride Gas (SF6) for UNF Processing; (3) Dry Head-end Nitration Processing; (4) Chlorination Processing of UNF; and (5) Enhanced Oxidation/Chlorination Processing of UNF. This report provides a description of the proposed processes, explores how they fit into the Modified Open Cycle (MOC) and Full Recycle (FR) fuel cycles, and identifies performance differences when compared to 'reference' advanced aqueous and fluoride volatility separations cases. To be able to highlight the key changes to the reference case, general background on advanced aqueous solvent extraction, advanced oxidative processes (e.g., volumetric oxidation, or 'voloxidation,' which is high temperature reaction of oxide UNF with oxygen, or modified using other oxidizing and reducing gases), and fluorination and chlorination processes is provided.

J. Tripp; N. Soelberg; R. Wigeland

2011-05-01T23:59:59.000Z

2

Hybrid membrane--PSA system for separating oxygen from air  

DOE Patents [OSTI]

A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

2011-01-25T23:59:59.000Z

3

Mixed oxygen ion/electron-conducting ceramics for oxygen separation  

SciTech Connect (OSTI)

Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

1995-05-01T23:59:59.000Z

4

CRADA Final Report: Ionically Conductive Membranes Oxygen Separation  

SciTech Connect (OSTI)

Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

Visco, Steven J.

2001-10-29T23:59:59.000Z

5

Entrepreneurial separation to transfer technology.  

SciTech Connect (OSTI)

Entrepreneurial separation to transfer technology (ESTT) program is that entrepreneurs terminate their employment with Sandia. The term of the separation is two years with the option to request a third year. Entrepreneurs are guaranteed reinstatement by Sandia if they return before ESTT expiration. Participants may start up or helpe expand technology businesses.

Fairbanks, Richard R.

2010-09-01T23:59:59.000Z

6

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

7

Acoustic Separation Technology  

SciTech Connect (OSTI)

Today's restrictive environmental regulations encourage paper mills to close their water systems. Closed water systems increase the level of contaminants significantly. Accumulations of solid suspensions are detrimental to both the papermaking process and the final products. To remove these solids, technologies such as flotation using dissolved air (DAF), centrifuging, and screening have been developed. Dissolved Air Flotation systems are commonly used to clarify whitewater. These passive systems use high pressure to dissolve air into whitewater. When the pressure is released, air micro-bubbles form and attach themselves to fibers and particles, which then float to the surface where they are mechanically skimmed off. There is an economic incentive to explore alternatives to the DAF technology to drive down the cost of whitewater processing and minimize the use of chemicals. The installed capital cost for a DAF system is significant and a typical DAF system takes up considerable space. An alternative approach, which is the subject of this project, involves a dual method combining the advantages of chemical flocculation and in-line ultrasonic clarification to efficiently remove flocculated contaminants from a water stream

Fred Ahrens; Tim Patterson

2002-02-22T23:59:59.000Z

8

SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION  

SciTech Connect (OSTI)

Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

Timothy L. Ward

2000-06-30T23:59:59.000Z

9

New Oxygen-Production Technology Proving Successful  

Broader source: Energy.gov [DOE]

The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

10

Separators - Technology review: Ceramic based separators for secondary batteries  

SciTech Connect (OSTI)

Besides a continuous increase of the worldwide use of electricity, the electric energy storage technology market is a growing sector. At the latest since the German energy transition ('Energiewende') was announced, technological solutions for the storage of renewable energy have been intensively studied. Storage technologies in various forms are commercially available. A widespread technology is the electrochemical cell. Here the cost per kWh, e. g. determined by energy density, production process and cycle life, is of main interest. Commonly, an electrochemical cell consists of an anode and a cathode that are separated by an ion permeable or ion conductive membrane - the separator - as one of the main components. Many applications use polymeric separators whose pores are filled with liquid electrolyte, providing high power densities. However, problems arise from different failure mechanisms during cell operation, which can affect the integrity and functionality of these separators. In the case of excessive heating or mechanical damage, the polymeric separators become an incalculable security risk. Furthermore, the growth of metallic dendrites between the electrodes leads to unwanted short circuits. In order to minimize these risks, temperature stable and non-flammable ceramic particles can be added, forming so-called composite separators. Full ceramic separators, in turn, are currently commercially used only for high-temperature operation systems, due to their comparably low ion conductivity at room temperature. However, as security and lifetime demands increase, these materials turn into focus also for future room temperature applications. Hence, growing research effort is being spent on the improvement of the ion conductivity of these ceramic solid electrolyte materials, acting as separator and electrolyte at the same time. Starting with a short overview of available separator technologies and the separator market, this review focuses on ceramic-based separators. Two prominent examples, the lithium-ion and sodium-sulfur battery, are described to show the current stage of development. New routes are presented as promising technologies for safe and long-life electrochemical storage cells.

Nestler, Tina; Schmid, Robert; Münchgesang, Wolfram; Bazhenov, Vasilii; Meyer, Dirk C. [Technische Universität Bergakademie Freiberg, Institut für Experimentelle Physik, Leipziger Str. 23, 09596 Freiberg (Germany); Schilm, Jochen [Fraunhofer-Institut für Keramische Technologien und Systeme IKTS, Winterbergstraße 28, 01277 Dresden (Germany); Leisegang, Tilmann [Fraunhofer-Technologiezentrum Halbleitermaterialien THM, Am St.-Niclas-Schacht 13, 09599 Freiberg (Germany)

2014-06-16T23:59:59.000Z

11

Separation process using microchannel technology  

DOE Patents [OSTI]

The disclosed invention relates to a process and apparatus for separating a first fluid from a fluid mixture comprising the first fluid. The process comprises: (A) flowing the fluid mixture into a microchannel separator in contact with a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the first fluid is sorbed by the sorption medium, removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing first fluid from the sorption medium and removing desorbed first fluid from the microchannel separator. The process and apparatus are suitable for separating nitrogen or methane from a fluid mixture comprising nitrogen and methane. The process and apparatus may be used for rejecting nitrogen in the upgrading of sub-quality methane.

Tonkovich, Anna Lee (Dublin, OH); Perry, Steven T. (Galloway, OH); Arora, Ravi (Dublin, OH); Qiu, Dongming (Bothell, WA); Lamont, Michael Jay (Hilliard, OH); Burwell, Deanna (Cleveland Heights, OH); Dritz, Terence Andrew (Worthington, OH); McDaniel, Jeffrey S. (Columbus, OH); Rogers, Jr.; William A. (Marysville, OH); Silva, Laura J. (Dublin, OH); Weidert, Daniel J. (Lewis Center, OH); Simmons, Wayne W. (Dublin, OH); Chadwell, G. Bradley (Reynoldsburg, OH)

2009-03-24T23:59:59.000Z

12

Cesium and Strontium Separation Technologies Literature Review  

SciTech Connect (OSTI)

Integral to the Advanced Fuel Cycle Initiative (AFCI) Program’s proposed closed nuclear fuel cycle, the fission products cesium and strontium in the dissolved spent nuclear fuel stream are to be separated and managed separately. A comprehensive literature survey is presented to identify cesium and strontium separation technologies that have the highest potential and to focus research and development efforts on these technologies. Removal of these high-heat-emitting fission products reduces the radiation fields in subsequent fuel cycle reprocessing streams and provides a significant short-term (100 yr) heat source reduction in the repository. This, along with separation of actinides, may provide a substantial future improvement in the amount of fuel that could be stored in a geologic repository. The survey and review of the candidate cesium and strontium separation technologies are presented herein. Because the AFCI program intends to manage cesium and strontium together, technologies that simultaneously separate both elements are of the greatest interest, relative to technologies that separate only one of the two elements.

T. A. Todd; T. A. Todd; J. D. Law; R. S. Herbst

2004-03-01T23:59:59.000Z

13

CENTER FOR ADVANCED SEPARATION TECHNOLOGY  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite-- Energy, science, and technology - C L A S S

14

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2005-11-04T23:59:59.000Z

15

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2006-05-15T23:59:59.000Z

16

Crosscutting Technology Development at the Center for Advanced Separation Technologies  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2006-09-30T23:59:59.000Z

17

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

This Technical Progress Report describes progress made on the seventeen subprojects awarded in the first year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices. Due to the time taken up by the solicitation/selection process, these cover the initial 6-month period of project activity only. The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium--Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno--that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation (2) Solid-liquid separation (3) Chemical/Biological Extraction (4) Modeling and Control, and (5) Environmental Control.

Hugh W. Rimmer

2004-05-12T23:59:59.000Z

18

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/Biological Extraction; (4) Modeling and Control; and (5) Environmental Control.

Christopher E. Hull

2005-01-20T23:59:59.000Z

19

Separations Technology for Clean Water and Energy  

SciTech Connect (OSTI)

Providing clean water and energy for about nine billion people on the earth by midcentury is a daunting challenge. Major investments in efficiency of energy and water use and deployment of all economical energy sources will be needed. Separations technology has an important role to play in producing both clean energy and water. Some examples are carbon dioxide capture and sequestration from fossil energy power plants and advanced nuclear fuel cycle scemes. Membrane separations systems are under development to improve the economics of carbon capture that would be required at a huge scale. For nuclear fuel cycles, only the PUREX liquid-liquid extraction process has been deployed on a large scale to recover uranium and plutonium from used fuel. Most current R and D on separations technology for used nuclear fuel focuses on ehhancements to a PUREX-type plant to recover the minor actinides (neptunium, americiu, and curium) and more efficiently disposition the fission products. Are there more efficient routes to recycle the actinides on the horizon? Some new approaches and barriers to development will be briefly reviewed.

Jarvinen, Gordon D [Los Alamos National Laboratory

2012-06-22T23:59:59.000Z

20

Crosscutting Technology Development at the Center for Advanced Separation Technologies  

SciTech Connect (OSTI)

The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium -- Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno - that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/biological extraction; (4) Modeling and control; and (5) Environmental control. Distribution of funds is handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. The successful projects are listed by category, along with brief abstracts of their aims and objectives.

Christopher Hull

2009-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (a) Solid-solid separation (b) Solid-liquid separation (c) Chemical/Biological Extraction (d) Modeling and Control, and (e) Environmental Control. Distribution of funds is being handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. The first of these solicitations, referred to as the CAST II-Round 1 RFP, was issued on October 28, 2002. Thirty-eight proposals were received by the December 10, 2002 deadline for this RFP-eleven (11) Solid-Solid Separation, seven (7) Solid-Liquid Separation, ten (10) Chemical/Biological Extraction, six (6) Modeling & Control and four (4) Environmental Control. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. This process took some 7 months to complete but 17 projects (one joint) were in place at the constituent universities (three at Virginia Tech, two at West Virginia University, three at University of Kentucky, three at University of Utah, three at Montana Tech, three at New Mexico Tech, and one at the University of Nevada, Reno) by May 17, 2003. These projects are listed by category, along with brief abstracts of their aims and objectives.

Hugh W. Rimmer

2003-11-15T23:59:59.000Z

22

Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor  

Broader source: Energy.gov [DOE]

Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

23

Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production  

DOE Patents [OSTI]

A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

1988-01-01T23:59:59.000Z

24

Nuclear Separations Technologies Workshop Report 2011  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced ScorecardReactor Technology Subcommittee of NEACSummary Nucleari NUCLEAR

25

advanced separation technology: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

advanced separation technology First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 February 2000 Advanced...

26

Efficient Separations and Processing Crosscutting Program. Technology summary  

SciTech Connect (OSTI)

The Efficient Separations and Processing (ESP) Crosscutting Program was created in 1991 to identify, develop, and perfect separations technologies and processes to treat wastes and address environmental problems throughout the DOE Complex. The ESP funds several multi-year tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R and D) leading to demonstration or use of these separations technologies by other organizations within DOE-EM. Treating essentially all DOE defense wastes requires separation methods that concentrate the contaminants and/or purify waste streams for release to the environment or for downgrading to a waste form less difficult and expensive to dispose of. Initially, ESP R and D efforts focused on treatment of high-level waste (HLW) from underground storage tanks (USTs) because of the potential for large reductions in disposal costs and hazards. As further separations needs emerge and as waste management and environmental restoration priorities change, the program has evolved to encompass the breadth of waste management and environmental remediation problems.

NONE

1995-06-01T23:59:59.000Z

27

Establishment of the Center for Advanced Separation Technologies  

SciTech Connect (OSTI)

This Final Technical Report covers the eight sub-projects awarded in the first year and the five projects awarded in the second year of Cooperative Agreement DE-FC26-01NT41091: Establishment of the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

Christopher E. Hull

2006-09-30T23:59:59.000Z

28

ESTABLISHMENT OF THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES  

SciTech Connect (OSTI)

Technical Progress Report describes progress made on the eight sub-projects awarded in the first year of Cooperative Agreement DE-FC26-01NT41091: Establishment of the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices. Due to the time taken up by the solicitation/selection process, these cover the initial 6-month period of activity only.

Hugh W. Rimmer

2003-07-01T23:59:59.000Z

29

Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process  

E-Print Network [OSTI]

and high temperature ion transport membranes. While polymeric membranes can produce oxygen enriched air of various concentrations, ion transport membranes can produce purities of close to 100%. Both membraHybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process Thomas

Struchtrup, Henning

30

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2.3: Sulfur Primer  

SciTech Connect (OSTI)

This deliverable is Subtask 2.3 of Task 2, Gas Cleanup Design and Cost Estimates, of NREL Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Subtask 2.3 builds upon the sulfur removal information first presented in Subtask 2.1, Gas Cleanup Technologies for Biomass Gasification by adding additional information on the commercial applications, manufacturers, environmental footprint, and technical specifications for sulfur removal technologies. The data was obtained from Nexant's experience, input from GTI and other vendors, past and current facility data, and existing literature.

Nexant Inc.

2006-05-01T23:59:59.000Z

31

Research and development of hydrogen separation technology with inorganic membranes  

SciTech Connect (OSTI)

Inorganic membrane technology has long been expected to provide new economical methods for industrial and waste management processes. At this time, the only commercially valuable inorganic membranes are the ultra filters derived from the French process that was used to produce the barrier for the French Gaseous Diffusion Plants. But these membranes are very expensive and have limited areas of application. Over the past fifteen years, scientists now in the Inorganic Membrane Technology Laboratory (IMTL) in Oak Ridge, Tennessee have developed theories and processes for inorganic membranes that can be used to design and produce inorganic membranes for a very broad range of applications. A part of the fabrication process is an adaptive spinoff from the still classified process used to manufacture barriers for the U.S. Gaseous Diffusion Process. Although that part of the process is classified, it is a very flexible and adaptable process and it can be used with a broad range of materials. With the theories and design capabilities developed in the last fifteen years, this new adaptive manufacturing technology can be used to manufacture commercial inorganic membranes that are not useful for the separation of uranium isotopes and they have little or no relation to the barriers that were used to separate uranium isotopes. The development and deployment of such inorganic membranes can be very beneficial to U.S. industry. Inorganic membranes can be specifically designed and manufactured for a large number of different applications. Such membranes can greatly improve the efficiency of a broad range of industrial processes and provide new technology for waste management. These inorganic membranes have the potential for major energy savings and conservation of energy. They can provide the means for significant improvements in the competitiveness of US Industry and improve the economy and health and welfare of the nation.

Fain, D.E.

1999-07-01T23:59:59.000Z

32

Feasibility evaluation of downhole oil/water separator (DOWS) technology.  

SciTech Connect (OSTI)

The largest volume waste stream associated with oil and gas production is produced water. A survey conducted by the American Petroleum Institute estimated that 20.9 billion barrels of produced water were disposed of in 1985 (Wakim 1987). Of this total, 91% was disposed of through disposal wells or was injected for enhanced oil recovery projects. Treatment and disposal of produced water represents a significant cost for operators. A relatively new technology, downhole oil/water separators (DOWS), has been developed to reduce the cost of handling produced water. DOWS separate oil and gas from produced water at the bottom of the well and reinject some of the produced water into another formation or another horizon within the same formation, while the oil and gas are pumped to the surface. Since much of the produced water is not pumped to the surface, treated, and pumped from the surface back into a deep formation, the cost of handling produced water is greatly reduced. When DOWS are used, additional oil may be recovered as well. In cases where surface processing or disposal capacity is a limiting factor for further production within a field, the use of DOWS to dispose of some of the produced water can allow additional production within that field. Simultaneous injection using DOWS minimizes the opportunity for contamination of underground sources of drinking water (USDWs) through leaks in tubing and casing during the injection process. This report uses the acronym 'DOWS' although the technology may also be referred to as DHOWS or as dual injection and lifting systems (DIALS). Simultaneous injection using DOWS has the potential to profoundly influence the domestic oil industry. The technology has been shown to work in limited oil field applications in the United States and Canada. Several technical papers describing DOWS have been presented at oil and gas industry conferences, but for the most part, the information on the DOWS technology has not been widely transferred to operators, particularly to small or medium-sized independent U.S. companies. One of the missions of the U.S. Department of Energy's (DOE's) National Petroleum Technology Office (NPTO) is to assess the feasibility of promising oil and gas technologies that offer improved operating performance, reduced operating costs, or greater environmental protection. To further this mission, the NPTO provided funding to a partnership of three organizations a DOE national laboratory (Argonne National Laboratory), a private-sector consulting firm (CH2M-Hill), and a state government agency (Nebraska Oil and Gas Conservation Commission) to assess the feasibility of DOWS. The purpose of this report is to provide general information to the industry on DOWS by describing the existing uses of simultaneous injection, summarizing the regulatory implications of simultaneous injection, and assessing the potential future uses of the technology. Chapter 2 provides a more detailed description of the two major types of DOWS. Chapter 3 summarizes the existing U.S. and Canadian installations of DOWS equipment, to the extent that operators have been willing to share their data. Data are provided on the location and geology of existing installations, production information before and after installation of the DOWS, and costs. Chapter 4 provides an overview of DOWS-specific regulatory requirements imposed by some state agencies and discusses the regulatory implications of handling produced water downhole, rather than pumping it to the surface and reinjecting it. Findings and conclusions are presented in Chapter 5 and a list of the references cited in the report is provided in Chapter 6. Appendix A presents detailed data on DOWS installations. This report presents the findings of Phase 1 of the simultaneous injection project, the feasibility assessment. Another activity of the Phase 1 investigation is to design a study plan for Phase 2 of the project, field pilot studies. The Phase 2 study plan is being developed separately and is not included in this report.

Veil, J. A.; Langhus, B. G.; Belieu, S.; Environmental Assessment; CH2M Hill; Nebraska Oil and Gas Conservation Commission

1999-01-31T23:59:59.000Z

33

Oxygen reduction at platimun/ionomer interface: effects of phase separation of ionomer  

SciTech Connect (OSTI)

Oxygen reduction reaction (ORR) at the interface between platinum and recast ionomers (Nafion EW 1100 and 950 and 6F-40) was studied at different temperatures (20--80{sup o}C) and humidities (10--100%) employing smooth Pt and Pt-black-covered ultramicroelectrodes. ORR was strongly inhibited on smooth electrodes. The inhibition increased with the reduction time, temperature and humidity, but was absent for Nafion EW 1100 in contact with liquid water. It was attributed to the hydrophobic component of ionomer blocking both active sites and oxygen transport. It was postulated that the dynamic changes in interfacial phase separation of ionomer are facilitated by the attractive interactions between the hydrophobic component of ionomer and bare platinum and between oxide-covered Pt and the hydrophilic component of ionomer. These interactions were also proposed to be responsible for the differences in ORR voltammetry for films prepared and equilibrated under different conditions. The decrease in ORR inhibition, Nafion EW 950> Nafion EW 1100> 6F-40, was correlated with physical and molecular properties of the ionomers. The lack of inhibition for Pt-black-covered electrodes was attributed to the more random distribution of ionomer chains and the high activation barriers for the ionomer restructuring at rough interfaces.

Chlistunoff, Jerzy [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

34

Research and development separation technology: The DOE Industrial Energy Conservation Program  

SciTech Connect (OSTI)

This brochure summarizes the Office of Industrial Programs' RandD efforts in the advancement of separation technology. The purpose of this brochure is to provide interested parties with information on federal industrial energy conservation activities in separation technology. The brochure is comprised of the following sections: Separation Technology, summarizes the current state of separation technology and its uses. Potential Energy Savings, discusses the potential for industrial energy conservation through the implementation of advanced separation processes. Office of Industrial Programs' RandD Efforts in Separation Technology Development, describes the separation RandD projects conducted by IP. RandD Data Base, lists contractor, principal investigator, and location of each separation-related RandD effort sponsored by IP.

Not Available

1987-07-01T23:59:59.000Z

35

MassMass transfer andtransfer and separation technologyseparation technology  

E-Print Network [OSTI]

- kemiteknik - Värme- och strömningsteknik Biskopsgatan 8, 20500 Åbo 4 #12;Example: Natural gas separationExample: Natural gas separationeknik Example: Natural gas separationExample: Natural gas separation .htmlSepa ­ A porous polymer, ceramic or metal, or ­ A liquid or gas N l l b 4 erföringo Natural polymers may be wood

Zevenhoven, Ron

36

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

37

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 1: Cost Estimates of Small Modular Systems  

SciTech Connect (OSTI)

This deliverable is the Final Report for Task 1, Cost Estimates of Small Modular Systems, as part of NREL Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Subtask 1.1 looked into processes and technologies that have been commercially built at both large and small scales, with three technologies, Fluidized Catalytic Cracking (FCC) of refinery gas oil, Steam Methane Reforming (SMR) of Natural Gas, and Natural Gas Liquids (NGL) Expanders, chosen for further investigation. These technologies were chosen due to their applicability relative to other technologies being considered by NREL for future commercial applications, such as indirect gasification and fluidized bed tar cracking. Research in this subject is driven by an interest in the impact that scaling has on the cost and major process unit designs for commercial technologies. Conclusions from the evaluations performed could be applied to other technologies being considered for modular or skid-mounted applications.

Nexant Inc.

2006-05-01T23:59:59.000Z

38

Conjugates of Actinide Chelator-Magnetic Nanoparticles for Used Fuel Separation Technology  

SciTech Connect (OSTI)

The actinide separation method using magnetic nanoparticles (MNPs) functionalized with actinide specific chelators utilizes the separation capability of ligand and the ease of magnetic separation. This separation method eliminated the need of large quantity organic solutions used in the liquid-liquid extraction process. The MNPs could also be recycled for repeated separation, thus this separation method greatly reduces the generation of secondary waste compared to traditional liquid extraction technology. The high diffusivity of MNPs and the large surface area also facilitate high efficiency of actinide sorption by the ligands. This method could help in solving the nuclear waste remediation problem.

You Qiang; Andrzej Paszczynski; Linfeng Rao

2011-10-30T23:59:59.000Z

39

MassMass transfer andtransfer and separation technologyseparation technology  

E-Print Network [OSTI]

liquid extraction involves three stages: ­ Contacting / extraction al-extraction.j ­ Separation the component of interest solute (A) will distribute over extract (E, phase II or 2) and raffinate (R, phase I with equilibrium constant K: 4 erföringo cA,II/cA,I = K´ , or Massöve xA,E/xA,R = xA,II/xA,I = xA,2/xA,1 = K K´= K

Zevenhoven, Ron

40

MHK Technologies/Oxygen Releasing and Carbon Absorbing Ocean Based  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpIncMAKGalway Bay IEOWC < MHK Technologies

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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41

Development of Brazing Technology for Use in High- Temperature Gas Separation Equipment  

SciTech Connect (OSTI)

The development of high-temperature electrochemical devices such as oxygen and hydrogen separators, fuel gas reformers, solid oxide fuel cells, and chemical sensors is part of a rapidly expanding segment of the solid state technology market. These devices employ an ionic conducting ceramic as the active membrane that establishes the electrochemical potential of the device, either under voltage (i.e. to carry out gas separation) or under chemical gradient (to develop an electrical potential and thereby generate electrical power). Because the device operates under an ionic gradient that develops across the electrolyte, hermiticity across this layer is paramount. That is, not only must this thin ceramic membrane be dense with no interconnected porosity, but it must be connected to the rest of the device, typically constructed from a heat resistant alloy, with a high-temperature, gas-tight seal. A significant engineering challenge in fabricating these devices is how to effectively join the thin electrochemically active membrane to the metallic body of the device such that the resulting seal is hermetic, rugged, and stable during continuous high temperature operation. Active metal brazing is the typical method of joining ceramic and metal engineering components. It employs a braze alloy that contains one or more reactive elements, often titanium, which will chemically reduce the ceramic faying surface and greatly improve its wetting behavior and adherence with the braze. However, recent studies of these brazes for potential use in fabricating high-temperature electrochemical devices revealed problems with interfacial oxidation and subsequent joint failure [1,2]. Specifically, it was found that the introduction of the ceramic electrolyte and/or heat resistant metal substrate dramatically affects the inherent oxidation behavior of the braze, often in a deleterious manner. These conclusions pointed to the need for an oxidation resistant, high-temperature ceramic-to-metal braze and consequently lead to the development of the novel reactive air brazing (RAB) concept. The goal in RAB is to reactively modify one or both oxide faying surfaces with an oxide compound dissolved in a molten noble metal alloy such that the newly formed surface is readily wetted by the remaining liquid filler material. In many respects, this concept is similar to active metal brazing, except that joining can be conducted in air and the final joint will be resistant to oxidation at high temperature. Potentially, there are a number of metal oxide-noble metal systems that can be considered for RAB, including Ag-CuO, Ag-V2O5, and Pt-Nb2O5. Our current interest is in determining whether the Ag-CuO system is suitable for air brazing functional ceramic-to-metal joints such as those needed in practical electrochemical devices. In a series of studies, the wetting behavior of the Ag-CuO braze was investigated with respect to a number of potential hydrogen separation, oxygen separation, and fuel cell electrolyte membrane materials and heat resistant metal systems, including: alumina, (La0.6Sr0.4)(Co0.2Fe0.8)O3, (La0.8Sr0.2)FeO3, YSZ, fecralloy, and Crofer-22APU. Selected findings from these studies as well as from our work on joint strength and durability during high-temperature exposure testing will be discussed.

Weil, K.S.; Hardy, J.S.; Kim, J.Y.

2003-04-23T23:59:59.000Z

42

An Introduction to CO2 Separation and Capture Technologies Howard Herzog  

E-Print Network [OSTI]

recovery (EOR) operations where CO2 is injected into oil reservoirs to increase the mobility of the oil andAn Introduction to CO2 Separation and Capture Technologies Howard Herzog MIT Energy Laboratory August, 1999 In general, to economically sequester CO2 produced from power plants, one must first produce

43

Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash  

E-Print Network [OSTI]

Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

Shawabkeh, Reyad A.

44

CO2 CAPTURE PROJECT - AN INTEGRATED, COLLABORATIVE TECHNOLOGY DEVELOPMENT PROJECT FOR NEXT GENERATION CO2 SEPARATION, CAPTURE AND GEOLOGIC SEQUESTRATION  

SciTech Connect (OSTI)

The CO{sub 2} Capture Project (CCP) is a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, Eni, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (1) European Union (DG Res & DG Tren), (2) Norway (Klimatek) and (3) the U.S.A. (Department of Energy). The project objective is to develop new technologies, which could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies are to be developed to ''proof of concept'' stage by the end of 2003. The project budget is approximately $24 million over 3 years and the work program is divided into eight major activity areas: (1) Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. (2) Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. (3) Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. (4) Capture Technology, Pre -Combustion: in which, natural gas and petroleum coke are converted to hydrogen and CO{sub 2} in a reformer/gasifier. (5) Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. (6) New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. (7) Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. (8) Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Technology development work dominated the past six months of the project. Numerous studies are making substantial progress towards their goals. Some technologies are emerging as preferred over others. Pre-combustion Decarbonization (hydrogen fuel) technologies are showing good progress and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. As expected, post-combustion technologies are emerging as higher cost options that may have niche roles. Storage, measurement, and verification studies are moving rapidly forward. Hyper-spectral geo-botanical measurements may be an inexpensive and non-intrusive method for long-term monitoring. Modeling studies suggest that primary leakage routes from CO{sub 2} storage sites may be along wellbores in areas disturbed by earlier oil and gas operations. This is good news because old wells are usually mapped and can be repaired during the site preparation process. Many studies are nearing completion or have been completed. Their preliminary results are summarized in the attached report and presented in detail in the attached appendices.

Dr. Helen Kerr

2003-08-01T23:59:59.000Z

45

Gas turbine engine adapted for use in combination with an apparatus for separating a portion of oxygen from compressed air  

DOE Patents [OSTI]

A gas turbine engine is provided comprising an outer shell, a compressor assembly, at least one combustor assembly, a turbine assembly and duct structure. The outer shell includes a compressor section, a combustor section, an intermediate section and a turbine section. The intermediate section includes at least one first opening and at least one second opening. The compressor assembly is located in the compressor section to define with the compressor section a compressor apparatus to compress air. The at least one combustor assembly is coupled to the combustor section to define with the combustor section a combustor apparatus. The turbine assembly is located in the turbine section to define with the turbine section a turbine apparatus. The duct structure is coupled to the intermediate section to receive at least a portion of the compressed air from the compressor apparatus through the at least one first opening in the intermediate section, pass the compressed air to an apparatus for separating a portion of oxygen from the compressed air to produced vitiated compressed air and return the vitiated compressed air to the intermediate section via the at least one second opening in the intermediate section.

Bland, Robert J. (Oviedo, FL); Horazak, Dennis A. (Orlando, FL)

2012-03-06T23:59:59.000Z

46

Novel Catalytic Fuel Reforming Using Micro-Technology with Advanced Separations Technology  

E-Print Network [OSTI]

when renewable resources power fuel cells. When compared to compressed hydrogen, reformed hydrocarbon sulfur-tolerant catalysts and hydrogen membrane technology to create a portable-sized hydrogen generator purification for electrical generation by a PEM fuel cell. This report presents the results of work

47

Pyrochemical separations technologies envisioned for the U. S. accelerator transmutation of waste system  

SciTech Connect (OSTI)

A program has been initiated for the purpose of developing the chemical separations technologies necessary to support a large Accelerator Transmutation of Waste (ATW) system capable of dealing with the projected inventory of spent fuel from the commercial nuclear power stations in the United States. The baseline process selected combines aqueous and pyrochemical processes to enable the efficient separation of uranium, technetium, iodine, and the transuranic elements from LWR spent fuel. The diversity of processing methods was chosen for both technical and economic factors. A six-year technology evaluation and development program is foreseen, by the end of which an informed decision can be made on proceeding with demonstration of the ATW system.

Laidler, J. J.

2000-02-17T23:59:59.000Z

48

Schwarz, T. and Wells, S. (1999) "Storm Water Particle Removal using Cross-Flow Filtration and Sedimentation," in Advances in Filtration and Separation Technology, Volume 12, ed. by W. Leung, American Filtrations and Separations Society, pp.219-226.  

E-Print Network [OSTI]

and Sedimentation," in Advances in Filtration and Separation Technology, Volume 12, ed. by W. Leung, American Filtrations and Separations Society, pp.219-226. CONTINUOUS DEFLECTION SEPARATION OF STORMWATER PARTICULATES

Wells, Scott A.

49

Separations Science and Technology, Semiannual progress report, October 1991--March 1992  

SciTech Connect (OSTI)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period October 1991--March 1992. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) a membrane-assisted solvent extraction method for treating natural and process waters contaminated by volatile organic compounds and (2) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process.

Vandegrift, G.F.; Betts, S.; Chamberlain, D.B. [and others

1994-01-01T23:59:59.000Z

50

Separation Science and Technology semiannual progress report, October 1992--March 1993  

SciTech Connect (OSTI)

This document reports on the work done by the Separations Science and Technology Section of the Chemical Technology Division, Argonne National Laboratory, in the period October 1992--March 1993. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process and (2) treatment schemes for liquid wastes stored or being generated at Argonne.

Vandegrift, G.F. [Argonne National Lab., IL (United States); Betts, S. [Illinois Univ., Chicago, IL (United States); Bowers, D.L. [Argonne National Lab., IL (United States)] [and others

1995-01-01T23:59:59.000Z

51

Separation science and technology. Semiannual progress report, April 1992--September 1992  

SciTech Connect (OSTI)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1992. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) a membrane-assisted solvent extraction method for treating natural and process waters contaminated by volatile organic compounds and (2) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process.

Vandegrift, G.F.; Betts, S.; Bowers, D.L. [and others

1994-09-01T23:59:59.000Z

52

Separation Science and Technology. Semiannual progress report, April 1993--September 1993  

SciTech Connect (OSTI)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1993. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process, (2) treatment schemes for liquid wastes stored or being generated at Argonne, (3) a process based on sorbing modified TRUEX solvent on magnetic beads to be used for separation of contaminants from radioactive and hazardous waste streams, and (4) a process that uses low-enriched uranium targets for production of {sup 99}Mo for nuclear medicine uses.

Vandegrift, G.F.; Chamberlain, D.B.; Conner, C. [and others

1996-01-01T23:59:59.000Z

53

Separation science and technology. Semiannual progress report, October 1993--March 1994  

SciTech Connect (OSTI)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory (ANL), in the period October 1993-March 1994. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process, (2) treatment schemes for liquid wastes stored are being generated at ANL, (3) a process based on sorbing modified TRUEX solvent on magnetic beads to be used for separation of contaminants from radioactive and hazardous waste streams, and (4) a process that uses low-enriched uranium targets for production of {sup 99}Mo for nuclear medicine uses.

Vandegrift, G.F.; Aase, S.B.; Buchholz, B. [and others

1997-12-01T23:59:59.000Z

54

Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals  

SciTech Connect (OSTI)

Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

Kloosterman, Jeff

2012-12-31T23:59:59.000Z

55

Application of linear multiple model predictive control (MMPC) framework towards dynamic maximazation of oxygen yield in an elevated-pressure air separation unit  

SciTech Connect (OSTI)

In a typical air separation unit (ASU) utilizing either a simple gaseous oxygen (GOX) cycle or a pumped liquid oxygen (PLOX) cycle, the flowrate of liquid nitrogen (LN2) stream connecting high-pressure and low-pressure ASU columns plays an important role in the total oxygen yield. It has been observed that this yield reaches a maximum at a certain optimal flowrate of LN2 stream. At nominal full-load operation, the flowrate of LN2 stream is maintained near this optimum value, whereas at part-load conditions this flowrate is typically modified in proportion with the load-change (oxygen demand) through a ratio/feed-forward controller. Due to nonlinearity in the entire ASU process, the ratio-modified LN2 flowrate does not guarantee an optimal oxygen yield at part-load conditions. This is further exacerbated when process disturbances in form of “cold-box” heat-leaks enter the system. To address this problem of dynamically maximizing the oxygen yield while the ASU undergoes a load-change and/or a process disturbance, a multiple model predictive control (MMPC) algorithm is proposed. This approach has been used in previous studies to handle large ramp-rates of oxygen demand posed by the gasifier in an IGCC plant. In this study, the proposed algorithm uses linear step-response “blackbox” models surrounding the operating points corresponding to maximum oxygen yield points at different loads. It has been shown that at any operating point of the ASU, the MMPC algorithm, through model-weight calculation based on plant measurements, naturally and continuously selects the dominant model(s) corresponding to the current plant state, while making control-move decisions that approach the maximum oxygen yield point. This dynamically facilitates less energy consumption in form of compressed feed-air compared to a simple ratio control during load-swings. In addition, since a linear optimization problem is solved at each time step, the approach involves much less computational cost compared to a firstprinciple based nonlinear MPC. Introduction

Mahapatra, P.; Zitney, S.; Bequette, B. Wayne

2012-01-01T23:59:59.000Z

56

Investigation of source-detector separation optimization for an implantable perfusion and oxygenation sensor for liver blood vessels  

SciTech Connect (OSTI)

An implanted system is being developed to monitor transplanted liver health during the critical 7-10 day period posttransplantation. The unit will monitor organ perfusion and oxygen consumption using optically-based probes placed on both the inflow and outflow blood vessels, and on the liver parenchymal surface. Sensing probes are based on a 3- wavelength LED source and a photodiode detector. Sample diffuse reflectance is measured at 735, 805, and 940 nm. To ascertain optimal source-to-photodetector spacing for perfusion measurement in blood vessels, an ex vivo study was conducted. In this work, a dye mixture simulating 80% blood oxygen saturation was developed and perfused through excised porcine arteries while collecting data for various preset probe source-to-photodetector spacings. The results from this study demonstrate a decrease in the optical signal with decreasing LED drive current and a reduction in perfusion index signal with increasing probe spacing. They also reveal a 2- to 4-mm optimal range for blood vessel perfusion probe source-to-photodetector spacing that allows for sufficient perfusion signal modulation depth with maximized signal to noise ratio (SNR). These findings are currently being applied to guide electronic configuration and probe placement for in vivo liver perfusion porcine model studies.

Baba, Justin S [ORNL; Akl, Tony [Texas A& M University; Cote, Gerard L. [Texas A& M University; Wilson, Mark A. [University of Pittsburgh School of Medicine, Pittsburgh PA; Ericson, Milton Nance [ORNL

2011-01-01T23:59:59.000Z

57

Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review  

SciTech Connect (OSTI)

This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

Not Available

1991-10-01T23:59:59.000Z

58

CO2 Capture Project-An Integrated, Collaborative Technology Development Project for Next Generation CO2 Separation, Capture and Geologic Sequestration  

SciTech Connect (OSTI)

The CO{sub 2} Capture Project (CCP) was a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, ENI, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union [DG RES & DG TREN], the Norwegian Research Council [Klimatek Program] and the U.S. Department of Energy [NETL]). The project objective was to develop new technologies that could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies were to be developed to ''proof of concept'' stage by the end of 2003. Certain promising technology areas were increased in scope and the studies extended through 2004. The project budget was approximately $26.4 million over 4 years and the work program is divided into eight major activity areas: Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. Capture Technology, Pre-Combustion: in which, natural gas and petroleum cokes are converted to hydrogen and CO{sub 2} in a reformer/gasifier. Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Pre-combustion De-carbonization (hydrogen fuel) technologies showed excellent results and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. Post-combustion technologies emerged as higher cost options that may only have niche roles. Storage, measurement, and verification studies suggest that geologic sequestration will be a safe form of long-term CO{sub 2} storage. Economic modeling shows that options to reduce costs by 50% exist. A rigorous methodology for technology evaluation was developed. Public acceptance and awareness were enhanced through extensive communication of results to the stakeholder community (scientific, NGO, policy, and general public). Two volumes of results have been published and are available to all. Well over 150 technical papers were produced. All funded studies for this phase of the CCP are complete. The results are summarized in this report and all final reports are presented in the attached appendices.

Helen Kerr; Linda M. Curran

2005-04-15T23:59:59.000Z

59

CO2 CAPTURE PROJECT-AN INTEGRATED, COLLABORATIVE TECHNOLOGY DEVELOPMENT PROJECT FOR NEXT GENERATION CO2 SEPARATION, CAPTURE AND GEOLOGIC SEQUESTRATION  

SciTech Connect (OSTI)

The CO{sub 2} Capture Project (CCP) is a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, Eni, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union (DG Res & DG Tren), Norway (Klimatek) and the U.S.A. (Department of Energy)). The project objective is to develop new technologies, which could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies are to be developed to ''proof of concept'' stage by the end of 2003. The project budget is approximately $24 million over 3 years and the work program is divided into eight major activity areas: (1) Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. (2) Capture Technology, Post Combustion--technologies, which can remove CO{sub 2} from exhaust gases after combustion. (3) Capture Technology, Oxyfuel--where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with wet high concentrations of CO{sub 2} for storage. (4) Capture Technology, Pre-Combustion--in which, natural gas and petroleum coke are converted to hydrogen and CO{sub 2} in a reformer/gasifier. (5) Common Economic Model/Technology Screening--analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. (6) New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. (7) Geologic Storage, Monitoring and Verification (SMV)--providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. (8) Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Technology development work dominated the past six months of the project. Numerous studies have completed their 2003 stagegate review and are reported here. Some will proceed to the next stagegate review in 2004. Some technologies are emerging as preferred over others. Pre-combustion De-carbonization (hydrogen fuel) technologies are showing excellent results and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. The workscopes planned for the next key stagegates are under review before work begins based on the current economic assessment of their performance. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. As expected, post-combustion technologies are emerging as higher cost options but even so some significant potential reductions in cost have been identified and will continue to be explored. Storage, measurement, and verification studies are moving rapidly forward and suggest that geologic sequestration can be a safe form of long-term CO{sub 2} storage. Hyper-spectral geo-botanical measurements may be an inexpensive and non-intrusive method for long-term monitoring. Modeling studies suggest that primary leakage routes from CO{sub 2} storage sites may be along old wellbores in areas disturbed by earlier oil and gas operations. This is good news because old wells are usually mapped and can be repaired during the site preparation process. Wells are also easy to monitor and intervention is possible if needed. The project will continue to evaluate and bring in novel studies and ideas within the project scope as requested by the DOE. The results to date are summarized in the attached report and presented in detail in the attached appendices.

Helen Kerr

2004-04-01T23:59:59.000Z

60

Advanced Membrane Separation Technologies for Energy Recovery from Industrial Process Streams  

SciTech Connect (OSTI)

Recovery of energy from relatively low-temperature waste streams is a goal that has not been achieved on any large scale. Heat exchangers do not operate efficiently with low-temperature streams and thus require such large heat exchanger surface areas that they are not practical. Condensing economizers offer one option for heat recovery from such streams, but they have not been widely implemented by industry. A promising alternative to these heat exchangers and economizers is a prototype ceramic membrane system using transport membrane technology for separation of water vapor and recovery of heat. This system was successfully tested by the Gas Technology Institute (GTI) on a natural gas fired boiler where the flue gas is relatively clean and free of contaminants. However, since the tubes of the prototype system were constructed of aluminum oxide, the brittle nature of the tubes limited the robustness of the system and even limited the length of tubes that could be used. In order to improve the robustness of the membrane tubes and make the system more suitable for industrial applications, this project was initiated with the objective of developing a system with materials that would permit the system to function successfully on a larger scale and in contaminated and potentially corrosive industrial environments. This required identifying likely industrial environments and the hazards associated with those environments. Based on the hazardous components in these environments, candidate metallic materials were identified that are expected to have sufficient strength, thermal conductivity and corrosion resistance to permit production of longer tubes that could function in the industrial environments identified. Tests were conducted to determine the corrosion resistance of these candidate alloys, and the feasibility of forming these materials into porous substrates was assessed. Once the most promising metallic materials were identified, the ability to form an alumina membrane layer on the surface of the metallic tubes was evaluated. Evaluation of this new style of membrane tube involved exposure to SO{sub 2} containing gases as well as to materials with a potential for fouling. Once the choice of substrate and membrane materials and design were confirmed, about 150 tubes were fabricated and assembled into three modules. These modules were mounted on an industrial size boiler and their performance carefully monitored during a limited testing period. The positive results of this performance test confirm the feasibility of utilizing such a system for recovery of heat and water from industrial waste streams. The improved module design along with use of long metallic substrate tubes with a ceramic membrane on the outer surface resulted in the successful, limited scale demonstration of the Transport Membrane Condenser (TMC) technology in the GTI test facility. This test showed this technology can successfully recover a significant amount of heat and water from gaseous waste streams. However, before industry will make the investment to install a full scale TMC, a full scale system will need to be constructed, installed and successfully operated at a few industrial sites. Companies were identified that had an interest in serving as a host site for a demonstration system.

Keiser, J.R.; Wang, D. (Gas Technology Institute); Bischoff, B.; Ciora (Media and Process Technology); Radhakrishnan, B.; Gorti, S.B.

2013-01-14T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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61

AISI/DOE Technology Roadmap Program Hot Oxygen Injection Into The Blast Furnace  

SciTech Connect (OSTI)

Increased levels of blast furnace coal injection are needed to further lower coke requirements and provide more flexibility in furnace productivity. The direct injection of high temperature oxygen with coal in the blast furnace blowpipe and tuyere offers better coal dispersion at high local oxygen concentrations, optimizing the use of oxygen in the blast furnace. Based on pilot scale tests, coal injection can be increased by 75 pounds per ton of hot metal (lb/thm), yielding net savings of $0.84/tm. Potential productivity increases of 15 percent would yield another $1.95/thm. In this project, commercial-scale hot oxygen injection from a ''thermal nozzle'' system, patented by Praxair, Inc., has been developed, integrated into, and demonstrated on two tuyeres of the U.S. Steel Gary Works no. 6 blast furnace. The goals were to evaluate heat load on furnace components from hot oxygen injection, demonstrate a safe and reliable lance and flow control design, and qualitatively observe hot oxygen-coal interaction. All three goals have been successfully met. Heat load on the blowpipe is essentially unchanged with hot oxygen. Total heat load on the tuyere increases about 10% and heat load on the tuyere tip increases about 50%. Bosh temperatures remained within the usual operating range. Performance in all these areas is acceptable. Lance performance was improved during testing by changes to lance materials and operating practices. The lance fuel tip was changed from copper to a nickel alloy to eliminate oxidation problems that severely limited tip life. Ignition flow rates and oxygen-fuel ratios were changed to counter the effects of blowpipe pressure fluctuations caused by natural resonance and by coal/coke combustion in the tuyere and raceway. Lances can now be reliably ignited using the hot blast as the ignition source. Blowpipe pressures were analyzed to evaluate ht oxygen-coal interactions. The data suggest that hot oxygen increases coal combustion in the blow pipe and tuyere by 30, in line with pilot scale tests conducted previously.

Michael F. Riley

2002-10-21T23:59:59.000Z

62

Preparation of a technology development roadmap for the Accelerator Transmutation of Waste (ATW) System : report of the ATW separations technologies and waste forms technical working group.  

SciTech Connect (OSTI)

In response to a Congressional mandate to prepare a roadmap for the development of Accelerator Transmutation of Waste (ATW) technology, a Technical Working Group comprised of members from various DOE laboratories was convened in March 1999 for the purpose of preparing that part of the technology development roadmap dealing with the separation of certain radionuclides for transmutation and the disposal of residual radioactive wastes from these partitioning operations. The Technical Working Group for ATW Separations Technologies and Waste Forms completed its work in June 1999, having carefully considered the technology options available. A baseline process flowsheet and backup process were identified for initial emphasis in a future research, development and demonstration program. The baseline process combines aqueous and pyrochemical processes to permit the efficient separation of the uranium, technetium, iodine and transuranic elements from the light water reactor (LWR) fuel in the head-end step. The backup process is an all- pyrochemical system. In conjunction with the aqueous process, the baseline flowsheet includes a pyrochemical process to prepare the transuranic material for fabrication of the ATW fuel assemblies. For the internal ATW fuel cycle the baseline process specifies another pyrochemical process to extract the transuranic elements, Tc and 1 from the ATW fuel. Fission products not separated for transmutation and trace amounts of actinide elements would be directed to two high-level waste forms, one a zirconium-based alloy and the other a glass/sodalite composite. Baseline cost and schedule estimates are provided for a RD&D program that would provide a full-scale demonstration of the complete separations and waste production flowsheet within 20 years.

Collins, E.; Duguid, J.; Henry, R.; Karell, E.; Laidler, J.; McDeavitt, S.; Thompson, M.; Toth, M.; Williamson, M.; Willit, J.

1999-08-12T23:59:59.000Z

63

Low cost hydrogen/novel membrane technology for hydrogen separation from synthesis gas  

SciTech Connect (OSTI)

To make the coal-to-hydrogen route economically attractive, improvements are being sought in each step of the process: coal gasification, water-carbon monoxide shift reaction, and hydrogen separation. This report addresses the use of membranes in the hydrogen separation step. The separation of hydrogen from synthesis gas is a major cost element in the manufacture of hydrogen from coal. Separation by membranes is an attractive, new, and still largely unexplored approach to the problem. Membrane processes are inherently simple and efficient and often have lower capital and operating costs than conventional processes. In this report current ad future trends in hydrogen production and use are first summarized. Methods of producing hydrogen from coal are then discussed, with particular emphasis on the Texaco entrained flow gasifier and on current methods of separating hydrogen from this gas stream. The potential for membrane separations in the process is then examined. In particular, the use of membranes for H{sub 2}/CO{sub 2}, H{sub 2}/CO, and H{sub 2}/N{sub 2} separations is discussed. 43 refs., 14 figs., 6 tabs.

Not Available

1986-02-01T23:59:59.000Z

64

CO2 Capture Project: An Integrated, Collaborative Technology Development Project For CO2 Separation, Capture And Geologic Sequestration  

SciTech Connect (OSTI)

This report (which forms part of the requirements of the Statement of Work Task 0, subtask 0.4) records progress towards defining a detailed Work Plan for the CCP 30 days after contract initiation. It describes the studies planned, workscope development and technology provider bid evaluation status at that time. Business sensitive information is provided separately in Appendix 1. Contract negotiations are on hold pending award of patent waiver status to the CCP.

Helen Kerr

2002-01-10T23:59:59.000Z

65

Integrated turbomachine oxygen plant  

SciTech Connect (OSTI)

An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

2014-06-17T23:59:59.000Z

66

Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications  

SciTech Connect (OSTI)

Air Products is carrying out a scope of work under DOE Award No. DE-FE0012065 “Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications.” The Statement of Project Objectives (SOPO) includes a Task 4f in which a Decision Point shall be reached, necessitating a review of Tasks 2-5 with an emphasis on Task 4f. This Topical Report constitutes the Decision Point Application pertaining to Task 4f. The SOPO under DOE Award No. DE-FE0012065 is aimed at furthering the development of the Ion Transport Membrane (ITM) Oxygen production process toward a demonstration scale facility known as the Oxygen Development Facility (ODF). It is anticipated that the completion of the current SOPO will advance the technology significantly along a pathway towards enabling the design and construction of the ODF. Development progress on several fronts is critical before an ODF project can commence; this Topical Report serves as an early update on the progress in critical development areas. Progress was made under all tasks, including Materials Development, Ceramic Processing Development, Engineering Development, and Performance Testing. Under Task 4f, Air Products carried out a cost and performance study in which several process design and cost parameters were varied and assessed with a process model and budgetary costing exercise. The results show that the major variables include ceramic module reliability, ITM operating temperature, module production yield, and heat addition strategy. High-temperature compact heat exchangers are shown to contribute significant cost benefits, while directly firing into the feed stream to an ITM are even a mild improvement on the high-temperature recuperation approach. Based on the findings to-date, Air Products recommends no changes to the content or emphasis in the current SOPO and recommends its completion prior to another formal assessment of these factors.

Armstrong, Phillip

2014-11-01T23:59:59.000Z

67

Review and assessment of technologies for the separation of strontium from alkaline and acidic media  

SciTech Connect (OSTI)

A literature survey has been conducted to identify and evaluate methods for the separation of strontium from acidic and alkaline media as applied to Hanford tank waste. The most promising methods of solvent extraction, precipitation, and ion exchange are described. The following criteria were used for evaluating the separation methods: Appreciable strontium removal must be demonstrated; Strontium selectivity over bulk components must be demonstrated; The method must show promise for evolving into a practical and fairly simple process; The process should be safe to operate; The method must be robust (i.e., capable of separating strontium from various waste types); Secondary waste generation must be minimized; and The method must show resistance to radiation damage. The methods discussed did not necessarily satisfy all of the above criteria; thus, key areas requiring further development are also given for each method. Less promising solvent extraction, precipitation, and ion exchange methods were also identified; areas for potential development are included in this report.

Orth, R.J.; Kurath, D.E.

1994-01-01T23:59:59.000Z

68

Technologies for the separation and recovery of hydrogen from refinery streams  

SciTech Connect (OSTI)

The effective use and recovery of hydrogen from the major hydrogen-containing streams in the refinery is an important strategy to meet the refining demands of the 1990`s. Hydrogen upgrading in refinery applications can be achieved by pressure swing adsorption (PSA), selective permeation using polymer membranes, and cryogenic separation. Each of these processes has different characteristics which are of advantage in different situations. Process selection and specific application examples are discussed.

Wilcher, F.P.; Miller, G.Q.; Mitariten, M.J. [UOP, Des Plaines, IL (United States)

1995-12-31T23:59:59.000Z

69

Zoey Herm | Center for Gas SeparationsRelevant to Clean Energy Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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70

2010 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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71

2010 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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72

2011 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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73

2011 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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74

2012 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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75

2012 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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76

2013 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

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77

2013 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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78

Potential Energy Savings by Using Alternative Technologies for the Separation of Fluid Mixtures  

E-Print Network [OSTI]

--ethanol water, air, and ethylbenzene-styrene--are included. No specific attempt was made to cover all possible energy-saving alternatives in the cases studied. The ones chosen for the evaluations are some of the more conventional processes that appear...-liquid extraction for the separation of ethanol and water. a liquid extraction step where a fluorocarbon sol vent [6,7] is put in contact with the ethanol-water stream. The fluorocarbon-ethanol mixture is distilled and the ethanol is recovered at the bottom...

Bravo, J. L.

79

Juan Meza | Center for Gas SeparationsRelevant to Clean Energy Technologies  

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80

2012 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

2013 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

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82

Jian Tian | Center for Gas SeparationsRelevant to Clean Energy Technologies  

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83

Jihan Kim | Center for Gas SeparationsRelevant to Clean Energy Technologies  

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84

Feng Xue | Center for Gas SeparationsRelevant to Clean Energy Technologies  

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85

Wen Ding | Center for Gas SeparationsRelevant to Clean Energy Technologies  

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86

2011 | Center for Gas SeparationsRelevant to Clean Energy Technologies |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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87

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

88

Liquid phase thermal swing chemical air separation  

DOE Patents [OSTI]

A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite. 2 figs.

Erickson, D.C.

1988-05-24T23:59:59.000Z

89

Liquid phase thermal swing chemical air separation  

DOE Patents [OSTI]

A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite.

Erickson, Donald C. (Annapolis, MD)

1988-01-01T23:59:59.000Z

90

Advanced Sorbents as a Versatile Platform for Gas Separation  

SciTech Connect (OSTI)

The program objective was to develop materials and processes for industrial gas separations to reduce energy use and enable waste reduction. The approach chosen combined novel oxygen selective adsorbents and pressure swing adsorption (PSA) processes. Preliminary materials development and process simulation results indicated that oxygen selective adsorbents could provide a versatile platform for industrial gas separations. If fully successful, this new technology offered the potential for reducing the cost of producing nitrogen/oxygen co-products, high purity nitrogen, argon, and possibly oxygen. The potential energy savings for the gas separations are appreciable, but the end users are the main beneficiaries. Lowering the cost of industrial gases expands their use in applications that can employ them for reducing energy consumption and emissions.

Neil Stephenson

2003-09-30T23:59:59.000Z

91

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

for technology that can control microscale oxygen gradientstechnology is the ability to rapidly generate and alter oxygentechnology should enable numerous studies in the field of biology where oxygen

Park, Jaehyun

2010-01-01T23:59:59.000Z

92

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

93

Low cost hydrogen/novel membrane technology for hydrogen separation from synthesis gas. Task 1, Literature survey  

SciTech Connect (OSTI)

To make the coal-to-hydrogen route economically attractive, improvements are being sought in each step of the process: coal gasification, water-carbon monoxide shift reaction, and hydrogen separation. This report addresses the use of membranes in the hydrogen separation step. The separation of hydrogen from synthesis gas is a major cost element in the manufacture of hydrogen from coal. Separation by membranes is an attractive, new, and still largely unexplored approach to the problem. Membrane processes are inherently simple and efficient and often have lower capital and operating costs than conventional processes. In this report current ad future trends in hydrogen production and use are first summarized. Methods of producing hydrogen from coal are then discussed, with particular emphasis on the Texaco entrained flow gasifier and on current methods of separating hydrogen from this gas stream. The potential for membrane separations in the process is then examined. In particular, the use of membranes for H{sub 2}/CO{sub 2}, H{sub 2}/CO, and H{sub 2}/N{sub 2} separations is discussed. 43 refs., 14 figs., 6 tabs.

Not Available

1986-02-01T23:59:59.000Z

94

The effects of wavelength, metals, and reactive oxygen species on the sunlight inactivation of microorganisms: observations and applications to the solar disinfection of drinking water  

E-Print Network [OSTI]

singlet oxygen. Environmental Science & Technology 41(13),Oxygen Mediated Inactivation. Environmental Science & TechnologyOxygen Mediated Inactivation. Environmental Science & Technology

Fisher, Michael Benjamin

2011-01-01T23:59:59.000Z

95

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

2005-07-12T23:59:59.000Z

96

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

2004-11-23T23:59:59.000Z

97

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

98

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

99

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

100

Vehicle Technologies Office Merit Review 2014: Significant Cost Improvement of Li-ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies  

Broader source: Energy.gov [DOE]

Presentation given by Johnson Controls at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Wood Feedstock  

SciTech Connect (OSTI)

As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for treatment of wood-derived syngas for use in the synthesis of liquid fuels. Two different 2,000 metric tonne per day gasification schemes, a low-pressure, indirect system using the gasifier, and a high-pressure, direct system using gasification technology were evaluated. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

Nexant Inc.

2006-05-01T23:59:59.000Z

102

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

103

Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

cement industry Oxygen enrichment technology Post-combustionOther Benefits: ? Oxygen enrichment technology reduces fuelprocess. Oxy-fuel technology uses oxygen instead of air in

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

104

Oxygen analyzer  

DOE Patents [OSTI]

An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

Benner, William H. (Danville, CA)

1986-01-01T23:59:59.000Z

105

A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants  

SciTech Connect (OSTI)

Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica/silicate are two common potential cycle-limiting minerals for using impaired waters. For produced waters, barium sulfate and calcium sulfate are two additional potential cycle-limiting minerals. For reclaimed municipal wastewater effluents, calcium phosphate scaling can be an issue, especially in the co-presence of high silica. Computational assessment, using a vast amount of Nalco's field data from coal fired power plants, showed that the limited use and reuse of impaired waters is due to the formation of deposit caused by the presence of iron, high hardness, high silica and high alkalinity in the water. Appropriate and cost-effective inhibitors were identified and developed - LL99B0 for calcite and gypsum inhibition and TX-15060 for silica inhibition. Nalco's existing dispersants HSP-1 and HSP-2 has excellent efficacy for dispersing Fe and Mn. ED and EDI were bench-scale tested by the CRADA partner Argonne National Laboratory for hardness, alkalinity and silica removal from synthetic make-up water and then cycled cooling water. Both systems showed low power consumption and 98-99% salt removal, however, the EDI system required 25-30% less power for silica removal. For Phase 2, the EDI system's performance was optimized and the length of time between clean-in-place (CIP) increased by varying the wafer composition and membrane configuration. The enhanced EDI system could remove 88% of the hardness and 99% of the alkalinity with a processing flux of 19.2 gal/hr/m{sup 2} and a power consumption of 0.54 kWh/100 gal water. Bench tests to screen alternative silica/silicate scale inhibitor chemistries have begun. The silica/silicate control approaches using chemical inhibitors include inhibition of silicic acid polymerization and dispersion of silica/silicate crystals. Tests were conducted with an initial silica concentration of 290-300 mg/L as SiO{sub 2} at pH 7 and room temperature. A proprietary new chemistry was found to be promising, compared with a current commercial product commonly used for silica/silicate control. Additional pilot cooling tower testing confirmed

Jasbir Gill

2010-08-30T23:59:59.000Z

106

STATUS OF THE DEVELOPMENT OF IN-TANK/AT-TANK SEPARATIONS TECHNOLOGIES FOR FOR HIGH-LEVEL WASTE PROCESSING FOR THE U.S. DEPARTMENT OF ENERGY  

SciTech Connect (OSTI)

Within the U.S. Department of Energy's (DOE) Office of Technology Innovation and Development, the Office of Waste Processing manages a research and development program related to the treatment and disposition of radioactive waste. At the Savannah River (South Carolina) and Hanford (Washington) Sites, approximately 90 million gallons of waste are distributed among 226 storage tanks (grouped or collocated in 'tank farms'). This waste may be considered to contain mixed and stratified high activity and low activity constituent waste liquids, salts and sludges that are collectively managed as high level waste (HLW). A large majority of these wastes and associated facilities are unique to the DOE, meaning many of the programs to treat these materials are 'first-of-a-kind' and unprecedented in scope and complexity. As a result, the technologies required to disposition these wastes must be developed from basic principles, or require significant re-engineering to adapt to DOE's specific applications. Of particular interest recently, the development of In-tank or At-Tank separation processes have the potential to treat waste with high returns on financial investment. The primary objective associated with In-Tank or At-Tank separation processes is to accelerate waste processing. Insertion of the technologies will (1) maximize available tank space to efficiently support permanent waste disposition including vitrification; (2) treat problematic waste prior to transfer to the primary processing facilities at either site (i.e., Hanford's Waste Treatment and Immobilization Plant (WTP) or Savannah River's Salt Waste Processing Facility (SWPF)); and (3) create a parallel treatment process to shorten the overall treatment duration. This paper will review the status of several of the R&D projects being developed by the U.S. DOE including insertion of the ion exchange (IX) technologies, such as Small Column Ion Exchange (SCIX) at Savannah River. This has the potential to align the salt and sludge processing life cycle, thereby reducing the Defense Waste Processing Facility (DWPF) mission by 7 years. Additionally at the Hanford site, problematic waste streams, such as high boehmite and phosphate wastes, could be treated prior to receipt by WTP and thus dramatically improve the capacity of the facility to process HLW. Treatment of boehmite by continuous sludge leaching (CSL) before receipt by WTP will dramatically reduce the process cycle time for the WTP pretreatment facility, while treatment of phosphate will significantly reduce the number of HLW borosilicate glass canisters produced at the WTP. These and other promising technologies will be discussed.

Aaron, G.; Wilmarth, B.

2011-09-19T23:59:59.000Z

107

Oxygen analyzer  

DOE Patents [OSTI]

An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

Benner, W.H.

1984-05-08T23:59:59.000Z

108

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

109

Development of Technologies for the Simultaneous Separation of Cesium and Strontium from Spent Nuclear Fuel as Part of an Advanced Fuel Cycle  

SciTech Connect (OSTI)

As part of the Advanced Fuel Cycle Initiative, two solvent extraction technologies are being developed to simultaneously separate cesium and strontium from dissolved spent nuclear fuel. The first process utilizes a solvent consisting of chlorinated cobalt dicarbollide and polyethylene glycol extractants in a phenyltrifluoromethyl sulfone diluent. Recent improvements to the process include development of a new, non-nitroaromatic diluent and development of new stripping reagents, including a regenerable strip reagent that can be recovered and recycled. Countercurrent flowsheets have been designed and tested on simulated and actual spent nuclear fuel feed streams with both cesium and strontium removal efficiencies of greater than 99 %. The second process developed to simultaneously separate cesium and strontium from spent nuclear fuel is based on two highly-specific extractants: 4,4',(5')-Di-(t-butyldicyclo-hexano)-18-crown-6 (DtBuCH18C6) and Calix[4]arene-bis-(tert-octylbenzo-crown-6) (BOBCalixC6). The DtBuCH18C6 extractant is selective for strontium and the BOBCalixC6 extractant is selective for cesium. A solvent composition has been developed that enables both elements to be removed together and, in fact, a synergistic effect was observed with strontium distributions in the combined solvent that are much higher that in the strontium extraction (SREX) process. Initial laboratory test results of the new combined cesium and strontium extraction process indicate good extraction and stripping performance. A flowsheet for treatment of spent nuclear fuel is currently being developed.

Jack D. Law; R. Scott HErbst; David H. Meikrantz; Dean R. Peterman; Catherine L. Riddle; Richard D. Tillotson; Terry A. Todd

2005-04-01T23:59:59.000Z

110

Assessing Statistical Understanding in Middle Schools: Emerging Issues in a Technology-Rich Environment  

E-Print Network [OSTI]

resources, such as “Oxygen” or using technology to producepower of technology, however, such as the Oxygen item, it is

Callingham, Rosemary

2011-01-01T23:59:59.000Z

111

Ultracapacitor separator  

DOE Patents [OSTI]

An ultracapacitor includes two solid, nonporous current collectors, two porous electrodes separating the collectors, a porous separator between the electrodes and an electrolyte occupying the pores in the electrodes and separator. The electrolyte is a polar aprotic organic solvent and a salt. The porous separator comprises a wet laid cellulosic material.

Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); LeBlanc, Jr., Oliver Harris (Schenectady, NY)

2001-03-06T23:59:59.000Z

112

Evaluation of CuAl2O4 as an Oxygen Carrier in Chemical-Looping Mehdi Arjmand,*,  

E-Print Network [OSTI]

Evaluation of CuAl2O4 as an Oxygen Carrier in Chemical-Looping Combustion Mehdi Arjmand,*, Abdul of Technology, SE-412 96 Goteborg, Sweden ABSTRACT: The chemical-looping combustion (CLC) process is a novel solution for efficient combustion with intrinsic separation of carbon dioxide. The process uses a metal

Azad, Abdul-Majeed

113

Oxygen Concentration Microgradients for Cell Culture.  

E-Print Network [OSTI]

??There is a growing need for technology that can control microscale oxygen gradients onto a tissue or culture sample in vitro. This dissertation introduces the… (more)

Park, Jaehyun

2010-01-01T23:59:59.000Z

114

Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

Swanson, Michael; Henderson, Ann

2012-04-01T23:59:59.000Z

115

Energy Conservation Possibilities Using Gas Separating Membranes  

E-Print Network [OSTI]

The separation of gases using semi permeable membranes is a viable unit operation. A novel composite membrane combined with hollow fiber spinning technology enable Monsanto Co. to offer PRISM (TM); Separators to the industrial market. The separator...

Knieriem, H.; Henis, J. M. S.

1980-01-01T23:59:59.000Z

116

Neptunium separations  

SciTech Connect (OSTI)

Two procedures for the separation of Np are presented; the first involves separation of /sup 239/Np from irradiated /sup 238/U, and the second involves separation of /sup 237/Np from a solution representing that from a dissolved fuel element.

Wild, J.F.

1983-05-09T23:59:59.000Z

117

Center for Gas Separations Relevant to  

E-Print Network [OSTI]

Center for Gas Separations Relevant to Clean Energy Technologies #12;Director Berend Smit Jeffrey, metal-organic framework. © 2013 EFRC Center for Gas Separation Relevant to Clean Energy Technology. All the current separation technology, developed over sixty years ago, requires 25-35% more coal to produce

Cohen, Ronald C.

118

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

119

Optimization of Oxygen Purity for Coal Conversion Energy Reduction  

E-Print Network [OSTI]

The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

Baker, C. R.; Pike, R. A.

1982-01-01T23:59:59.000Z

120

College of Engineering Electromagnetically Enhanced Hydrocyclone for Magnetite Separation during  

E-Print Network [OSTI]

designed the cyclone; a safer technology aimed at replacing the drum separators. The prototy er increase Electromagnetically Enhanced Hydrocyclone for Magnetite Separation during cyclone; a safer technology aimedPENNSTATE College of Engineering Electromagnetically Enhanced Hydrocyclone for Magnetite Separation

Demirel, Melik C.

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

122

Novel Surface Architecture Synthesis for Gas Separation and Fuel-Cell Catalyst Applications James Guthrie, Georgia Institute of Technology, SURF 2010 Fellow  

E-Print Network [OSTI]

Novel Surface Architecture Synthesis for Gas Separation and Fuel-Cell Catalyst Applications James-shell nanoparticle, Pt was deposited onto a flat surface substrate. Three separate substrates were used, Au(111 not significantly change over different voltages [3]. STM work was done using electrochemically etched tungsten tips

Li, Mo

123

Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies  

Broader source: Energy.gov [DOE]

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

124

Advanced Separation Consortium  

SciTech Connect (OSTI)

The Center for Advanced Separation Technologies (CAST) was formed in 2001 under the sponsorship of the US Department of Energy to conduct fundamental research in advanced separation and to develop technologies that can be used to produce coal and minerals in an efficient and environmentally acceptable manner. The CAST consortium consists of seven universities - Virginia Tech, West Virginia University, University of Kentucky, Montana Tech, University of Utah, University of Nevada-Reno, and New Mexico Tech. The consortium brings together a broad range of expertise to solve problems facing the US coal industry and the mining sector in general. At present, a total of 60 research projects are under way. The article outlines some of these, on topics including innovative dewatering technologies, removal of mercury and other impurities, and modelling of the flotation process. 1 photo.

NONE

2006-01-01T23:59:59.000Z

125

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas  

Broader source: Energy.gov [DOE]

The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower’s Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NOx control technologies.

126

Technology  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAboutManusScience and InnovationexperimentsTechnology

127

Joanna McFarlane, Refuyat Ashen, and K.C. Cushman Separations and Materials Research Group, Nuclear Science and Technology Division  

E-Print Network [OSTI]

, Nuclear Science and Technology Division Oak Ridge National Laboratory, P. O. Box 2008, MS-6008, Oak Ridge, Nuclear Science and Technology Division Oak Ridge National Laboratory, P. O. Box 2008, MS-6008, Oak Ridge. Fuel mixtures that were considered included: biodiesel and standard diesel fuel, methyl-butanoate and n

Pennycook, Steve

128

Application of oxygen-enriched combustion for locomotive diesel engines. Phase 1  

SciTech Connect (OSTI)

A thermodynamic simulation is used to study the effects of oxygen-enriched intake air on the performance and nitrogen oxide (NO) emissions of a locomotive diesel engine. The parasitic power of the air separation membrane required to supply the oxygen-enriched air is also estimated. For a given constraint on peak cylinder pressure, the gross and net power outputs of an engine operating under different levels of oxygen enrichment are compared with those obtained when a high-boost turbocharged engine is used. A 4% increase in peak cylinder pressure can result in an increase in net engine power of approximately 13% when intake air with an oxygen content of 28% by volume is used and fuel injection timing is retarded by 4 degrees. When the engine is turbocharged to a higher inlet boost, the same increase in peak cylinder pressure improves power by only 4%. If part of the significantly higher exhaust enthalpies available as a result of oxygen enrichment are recovered, the power requirements of the air separator membrane can be met, resulting in substantial net power improvements. Oxygen enrichment reduces particulate and visible smoke emissions but increases NO emissions. However, a combination of retarded fuel injection timing and post-treatment of exhaust gases may be adequate to meet the locomotive diesel engine NO{sub x} standards. Exhaust gas after-treatment and heat recovery would be required to realize the full potential of oxygen enrichment. Economic analysis shows that oxygen-enrichment technology is economically feasible and provides high returns on investment. The study also indicates the strong influence of membrane parasitic requirements and exhaust energy recovery on economic benefits. To obtain an economic advantage while using a membrane with higher parasitic power requirements, it is necessary to recover a part of the exhaust energy.

Poola, R.B.; Sekar, R.R.; Assanis, D.N.

1996-09-01T23:59:59.000Z

129

Novel Application of Air Separation Membranes Reduces NOx Emissions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Application of Air Separation Membranes Reduces NOx Emissions Technology available for licensing: Selective permeation of gases using an air separation membrane. Can be retrofitted...

130

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1997-01-01T23:59:59.000Z

131

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1996-01-01T23:59:59.000Z

132

Efficient separations & processing crosscutting program  

SciTech Connect (OSTI)

The Efficient Separations and Processing Crosscutting Program (ESP) was created in 1991 to identify, develop, and perfect chemical and physical separations technologies and chemical processes which treat wastes and address environmental problems throughout the DOE complex. The ESP funds several multiyear tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R & D) leading to the demonstration or use of these separations technologies by other organizations within the Department of Energy (DOE), Office of Environmental Management.

NONE

1996-08-01T23:59:59.000Z

133

Separation system  

DOE Patents [OSTI]

A separation system for dewatering radioactive waste materials includes a disposal container, drive structure for receiving the container, and means for releasably attaching the container to the drive structure. Separation structure disposed in the container adjacent the inner surface of the side wall structure retains solids while allowing passage of liquids. Inlet port structure in the container top wall is normally closed by first valve structure that is centrifugally actuated to open the inlet port and discharge port structure at the container periphery receives liquid that passes through the separation structure and is normally closed by second valve structure that is centrifugally actuated to open the discharge ports. The container also includes coupling structure for releasable engagement with the centrifugal drive structure. Centrifugal force produced when the container is driven in rotation by the drive structure opens the valve structures, and radioactive waste material introduced into the container through the open inlet port is dewatered, and the waste is compacted. The ports are automatically closed by the valves when the container drum is not subjected to centrifugal force such that containment effectiveness is enhanced and exposure of personnel to radioactive materials is minimized.

Rubin, Leslie S. (Newton, MA)

1986-01-01T23:59:59.000Z

134

Injectable polymer for in vivo oxygen sensing  

E-Print Network [OSTI]

This thesis documents the synthesis and characterization of an elastomeric polymer that is oxygen sensitive and can be interrogated using Magnetic Resonance Imaging (MRI) or Magnetic Resonance (MR) technology to report the ...

Imaad, Syed M. (Syed Muhammad)

2013-01-01T23:59:59.000Z

135

Electrochemically mediated separation for carbon capture  

E-Print Network [OSTI]

Carbon capture technology has been proposed as an effective approach for the mitigation of anthropogenic CO[subscript 2] emissions. Thermal-swing separation technologies based on wet chemical scrubbing show potential for ...

Simeon, Fritz

136

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

137

Particle separation  

DOE Patents [OSTI]

Embodiments of a method for selecting particles, such as based on their morphology, is disclosed. In a particular example, the particles are charged and acquire different amounts of charge, or have different charge distributions, based on their morphology. The particles are then sorted based on their flow properties. In a specific example, the particles are sorted using a differential mobility analyzer, which sorts particles, at least in part, based on their electrical mobility. Given a population of particles with similar electrical mobilities, the disclosed process can be used to sort particles based on the net charge carried by the particle, and thus, given the relationship between charge and morphology, separate the particles based on their morphology.

Moosmuller, Hans (Reno, NV); Chakrabarty, Rajan K. (Reno, NV); Arnott, W. Patrick (Reno, NV)

2011-04-26T23:59:59.000Z

138

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

Cassano, Anthony A. (Allentown, PA)

1985-01-01T23:59:59.000Z

139

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

Cassano, A.A.

1985-07-02T23:59:59.000Z

140

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Transport Reactor Development Unit Modification to Provide a Syngas Slipstream at Elevated Conditions to Enable Separation of 100 LB/D of Hydrogen by Hydrogen Separation Membranes Year - 6 Activity 1.15 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

Gasification of coal when associated with carbon dioxide capture and sequestration has the potential to provide low-cost as well as low-carbon hydrogen for electric power, fuels or chemicals production. The key element to the success of this concept is inexpensive, effective separation of hydrogen from carbon dioxide in synthesis gas. Many studies indicate that membrane technology is one of the most, if not the most, economical means of accomplishing separation; however, the advancement of hydrogen separation membrane technology is hampered by the absence of experience or demonstration that the technology is effective economically and environmentally at larger scales. While encouraging performance has been observed at bench scale (less than 12 lb/d hydrogen), it would be imprudent to pursue a largescale demonstration without testing at least one intermediate scale, such as 100 lb/d hydrogen. Among its many gasifiers, the Energy & Environmental Research Center is home to the transport reactor demonstration unit (TRDU), a unit capable of firing 200—500 lb/hr of coal to produce 400 scfm of synthesis gas containing more than 200 lb/d of hydrogen. The TRDU and associated downstream processing equipment has demonstrated the capability of producing a syngas over a wide range of temperatures and contaminant levels — some of which approximate conditions of commercial-scale gasifiers. Until this activity, however, the maximum pressure of the TRDU’ s product syngas was 120 psig, well below the 400+ psig pressures of existing large gasifiers. This activity installed a high-temperature compressor capable of accepting the range of TRDU products up to 450°F and compressing them to 500 psig, a pressure comparable to some large scale gasifiers. Thus, with heating or cooling downstream of the TRDU compressor, the unit is now able to present a near-raw to clean gasifier synthesis gas containing more than 100 lb/d of hydrogen at up to 500 psig over a wide range of temperatures to hydrogen separation membranes or other equipment for development and demonstration.

Schlasner, Steven

2012-03-01T23:59:59.000Z

142

Separation Processes, Second Edition  

E-Print Network [OSTI]

by; Uranium isotopes separation) Iteration methods (seemethod for activity coefficients, 43, 481 Uranium isotopes separation,

King, C. Judson

1980-01-01T23:59:59.000Z

143

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

144

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

145

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

146

Phosphazene membranes for gas separations  

DOE Patents [OSTI]

A polyphosphazene having a glass transition temperature ("Tg") of approximately -20.degree. C. or less. The polyphosphazene has at least one pendant group attached to a backbone of the polyphosphazene, wherein the pendant group has no halogen atoms. In addition, no aromatic groups are attached to an oxygen atom that is bound to a phosphorus atom of the backbone. The polyphosphazene may have a Tg ranging from approximately -100.degree. C. to approximately -20.degree. C. The polyphosphazene may be selected from the group consisting of poly[bis-3-phenyl-1-propoxy)phosphazene], poly[bis-(2-phenyl-1-ethoxy)phosphazene], poly[bis-(dodecanoxypolyethoxy)-phosphazene], and poly[bis-(2-(2-(2-.omega.-undecylenyloxyethoxy)ethoxy)ethoxy)phosphazene]. The polyphosphazene may be used in a separation membrane to selectively separate individual gases from a gas mixture, such as to separate polar gases from nonpolar gases in the gas mixture.

Stewart, Frederick F.; Harrup, Mason K.; Orme, Christopher J.; Luther, Thomas A.

2006-07-11T23:59:59.000Z

147

Effect of oxygen concentration on the magnetic properties of La2CoMnO6 Center for Materials for Information Technology and Department of Chemistry, University of Alabama,  

E-Print Network [OSTI]

Effect of oxygen concentration on the magnetic properties of La2CoMnO6 thin films H. Z. Guo Center; published online 16 November 2007 The dependence of the magnetic properties on oxygen concentration the oxygen background pressure during growth using pulsed laser deposition. Two distinct ferromagnetic FM

Pennycook, Steve

148

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

149

Solid state oxygen sensor  

DOE Patents [OSTI]

Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

1996-01-01T23:59:59.000Z

150

The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology  

E-Print Network [OSTI]

oxygen was only available when cryogenic air separation technologytechnology to date [100]. POX involves lean combustion of carbonaceous materials with oxygen.

He, Wei

2011-01-01T23:59:59.000Z

151

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

152

High Selectivity Oxygen Delignification  

SciTech Connect (OSTI)

The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

Arthur J. Ragauskas

2005-09-30T23:59:59.000Z

153

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon dioxide from nitrogen, oxygen, and methane gases. Image by Joshua Schrier, Haverford...

154

Hybrid System for Separating Oxygen from Air - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmasSandy-Nor'easter SituationHybrid Hybrid

155

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions andData andFleetEngineering Of Radiation Tolerant SiliconStudied

156

Performance of a Multistream Injection Chemical OxygenIodine Laser with Starlet Ejectors  

E-Print Network [OSTI]

and has the potential for higher pressure recovery. Pressures in the singlet-oxygen generator were technology development to date has focused on the singlet-oxygen generator (SOG). The liquid SOG technology- oxygen generation and transport efficiency. The idea of the starlet nozzle concept stems originally from

Carroll, David L.

157

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

158

Oxygen partial pressure sensor  

DOE Patents [OSTI]

A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

Dees, D.W.

1994-09-06T23:59:59.000Z

159

Hybrid Membranes for Light Gas Separations  

E-Print Network [OSTI]

Membrane separations provide a potentially attractive technology over conventional processes due to their advantages, such as low capital cost and energy consumption. The goal of this thesis is to design hybrid membranes that facilitate specific gas...

Liu, Ting

2012-07-16T23:59:59.000Z

160

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

2007-03-31T23:59:59.000Z

162

Encapsulated Metal Hydride for Hydrogen Separation  

E-Print Network [OSTI]

concentration feed stock, not for low concentration ­ Hydrogen economy will need hydrogen recovery from lowEncapsulated Metal Hydride for Hydrogen Separation (Formerly Separation Membrane Development) DOE Hydrogen Program 2003 Merit Review and Peer Evaluation L. Kit Heung, Jim Congdon Savannah River Technology

163

Fundamental studies of heterostructured oxide thin film electrocatalysts for oxygen reduction at high temperatures  

E-Print Network [OSTI]

Searching for active and cost-effective catalysts for oxygen electrocatalysis is essential for the development of efficient clean electrochemical energy technologies. Perovskite oxides are active for surface oxygen exchange ...

Crumlin, Ethan J

2012-01-01T23:59:59.000Z

164

E-Print Network 3.0 - actinide separations unique Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separations Technologies... . Both aqueous and nonaqueous (elec- trometallurgical) methods have been developed to separate and reduce... as to tailor their design to take...

165

Use of exhaust gas as sweep flow to enhance air separation membrane performance  

DOE Patents [OSTI]

An intake air separation system for an internal combustion engine is provided with purge gas or sweep flow on the permeate side of separation membranes in the air separation device. Exhaust gas from the engine is used as a purge gas flow, to increase oxygen flux in the separation device without increasing the nitrogen flux.

Dutart, Charles H. (Washington, IL); Choi, Cathy Y. (Morton, IL)

2003-01-01T23:59:59.000Z

166

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

167

A Vortex Contactor for Carbon Dioxide Separations  

SciTech Connect (OSTI)

Many analysts identify carbon dioxide (CO2) capture and separation as a major roadblock in efforts to cost effectively mitigate greenhouse gas emissions via sequestration. An assessment 4 conducted by the International Energy Agency (IEA) Greenhouse Gas Research and Development Programme cited separation costs from $35 to $264 per tonne of CO2 avoided for a conventional coal fired power plant utilizing existing capture technologies. Because these costs equate to a greater than 40% increase in current power generation rates, it appears obvious that a significant improvement in CO2 separation technology is required if a negative impact on the world economy is to be avoided.

Raterman, Kevin Thomas; Mc Kellar, Michael George; Turner, Terry Donald; Podgorney, Anna Kristine; Stacey, Douglas Edwin; Stokes, B.; Vranicar, J.

2001-05-01T23:59:59.000Z

168

Membrane separation advances in FE hydrogen program  

SciTech Connect (OSTI)

Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

NONE

2007-12-31T23:59:59.000Z

169

Instructions for use Removal of Oxygen and Nitrogen from Niobium  

E-Print Network [OSTI]

Instructions for use #12;------ Removal of Oxygen and Nitrogen from Niobium by External Gettering of Energy Science and Technology, Kyoto University Yoshida-Honmachi, Sakyo-ku, Kyoto 606-01 Japan Keywords External Gettering, Purification of Niobium, Thermodynamics of Impurities, Oxygen Diffusion, Purity

Tachizawa, Kazuya

170

Technology '90  

SciTech Connect (OSTI)

The US Department of Energy (DOE) laboratories have a long history of excellence in performing research and development in a number of areas, including the basic sciences, applied-energy technology, and weapons-related technology. Although technology transfer has always been an element of DOE and laboratory activities, it has received increasing emphasis in recent years as US industrial competitiveness has eroded and efforts have increased to better utilize the research and development resources the laboratories provide. This document, Technology '90, is the latest in a series that is intended to communicate some of the many opportunities available for US industry and universities to work with the DOE and its laboratories in the vital activity of improving technology transfer to meet national needs. Technology '90 is divided into three sections: Overview, Technologies, and Laboratories. The Overview section describes the activities and accomplishments of the DOE research and development program offices. The Technologies section provides descriptions of new technologies developed at the DOE laboratories. The Laboratories section presents information on the missions, programs, and facilities of each laboratory, along with a name and telephone number of a technology transfer contact for additional information. Separate papers were prepared for appropriate sections of this report.

Not Available

1991-01-01T23:59:59.000Z

171

Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Video recording of the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, originally presented on March 12, 2013.

172

Air separation by the Moltox process  

SciTech Connect (OSTI)

The report describes results of a development program on a new and energy saving process for air separation. The Moltox process involves reversibly reacting oxygen in air with a recirculating salt solution, such that oxygen is extracted without depressurizing the remaining nitrogen. Energy savings of approximately 50% are indicated for this process compared to conventional cryogenic air separation. The development program consisted of design, construction, and operation of a 6 liter/minute pilot plant; optimization of the process flowsheet through computer modelling; investigation of engineering aspects of the process including corrosion, safety, and NO/sub x/ generation; and an economic comparison to conventional cryogenic practice. All objectives were satisfactorily achieved except for continuous operation of the pilot plant, and the modifications necessary to achieve that have been identified. Economically the Moltox process shows a substantial advantage over large scale cryogenic plants which are powered by fuel vice electricity.

Erickson, D. C.

1981-04-01T23:59:59.000Z

173

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

2003-11-01T23:59:59.000Z

174

Meniscus Membranes For Separation  

DOE Patents [OSTI]

Gas separation membranes, especially meniscus-shaped membranes for gas separations are disclosed together with the use of such meniscus-shaped membranes for applications such as thermal gas valves, pre-concentration of a gas stream, and selective pre-screening of a gas stream. In addition, a rapid screening system for simultaneously screening polymer materials for effectiveness in gas separation is provided.

Dye, Robert C. (Irvine, CA); Jorgensen, Betty (Jemez Springs, NM); Pesiri, David R. (Aliso Viejo, CA)

2005-09-20T23:59:59.000Z

175

Meniscus membranes for separations  

DOE Patents [OSTI]

Gas separation membranes, especially meniscus-shaped membranes for gas separations are disclosed together with the use of such meniscus-shaped membranes for applications such as thermal gas valves, pre-concentration of a gas stream, and selective pre-screening of a gas stream. In addition, a rapid screening system for simultaneously screening polymer materials for effectiveness in gas separation is provided.

Dye, Robert C. (Irvine, CA); Jorgensen, Betty (Jemez Springs, NM); Pesiri, David R. (Aliso Viejo, CA)

2004-01-27T23:59:59.000Z

176

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

177

High Selectivity Oxygen Delignification  

SciTech Connect (OSTI)

Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

Lucian A. Lucia

2005-11-15T23:59:59.000Z

178

MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES  

E-Print Network [OSTI]

MOLTEN OXIDE ELECTROLYSIS FOR LUNAR OXYGEN GENERATION USING IN-SITU RESOURCES A.T. Vai1 , J.; Woburn, MA, 01801, USA Keywords: ISRU, Molten Oxide Electrolysis, Inert Anode, Oxygen Generation Abstract technology for generating oxygen from lunar regolith simulant. Prior to this work, iridium metal was the only

Sadoway, Donald Robert

179

Effects of applied voltages and dissolved oxygen on sustained power generation by microbial fuel cells  

E-Print Network [OSTI]

Effects of applied voltages and dissolved oxygen on sustained power generation by microbial fuel), Faculty of Advanced Technology, University of Glamorgan, Pontypridd RCT CF37 1DL, UK Oxygen intrusion chamber MFCs at the end of a cycle when the substrate is depleted. A slight increase in dissolved oxygen

180

GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

Nsakala ya Nsakala; Gregory N. Liljedahl

2003-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms  

DOE Patents [OSTI]

A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

2006-01-24T23:59:59.000Z

182

februari 2008 MassMass transfer & separation technology 424302 2008transfer & separation technology 424302 2008 --APPENDIXAPPENDIX  

E-Print Network [OSTI]

Multicomponent mixturesmixtures"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna, DelftDelft University Press (2000Transfer in MulticomponentMulticomponent mixturesmixtures"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna, DelftDelft University Press (2000

Zevenhoven, Ron

183

Membrane Separations Research  

E-Print Network [OSTI]

MEMBRANE SEPARATIONS RESEARCH James R. Fair Chemical Engineering Department The University of Texas at Austin Austin, TX 78712 ABSTRACT The use of membranes for separating gaseous and liquid mixtures has grown dramatically in the past 15... years. Applications have been dominated by light gas separations and water purification. During this pioneering period, equipment containing the membrane suIfaces has been developed to a point where failures are minimal and the membranes themselves...

Fair, J. R.

184

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

185

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

186

Methods for fluid separations, and devices capable of separating fluids  

DOE Patents [OSTI]

Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

2006-05-30T23:59:59.000Z

187

Methods for fluid separations, and devices capable of separating fluids  

DOE Patents [OSTI]

Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

TeGrotenhuis, Ward E. (Kennewick, WA); Stenkamp, Victoria S. (Richland, WA)

2007-09-25T23:59:59.000Z

188

Substituted polyacetylene separation membrane  

DOE Patents [OSTI]

A separation membrane is described which is useful for gas separation, particularly separation of C{sub 2+} hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula shown in the accompanying diagram, wherein R{sub 1} is chosen from the group consisting of C{sub 1}-C{sub 4} alkyl and phenyl, and wherein R{sub 2} is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) [PMP]. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations. 4 figs.

Pinnau, I.; Morisato, Atsushi

1998-01-13T23:59:59.000Z

189

Substituted polyacetylene separation membrane  

DOE Patents [OSTI]

A separation membrane useful for gas separation, particularly separation of C.sub.2+ hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula: ##STR1## wherein R.sub.1 is chosen from the group consisting of C.sub.1 -C.sub.4 alkyl and phenyl, and wherein R.sub.2 is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) ›PMP!. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations.

Pinnau, Ingo (Palo Alto, CA); Morisato, Atsushi (Tokyo, JP)

1998-01-13T23:59:59.000Z

190

Separators for flywheel rotors  

DOE Patents [OSTI]

A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors. 10 figs.

Bender, D.A.; Kuklo, T.C.

1998-07-07T23:59:59.000Z

191

Separators for flywheel rotors  

DOE Patents [OSTI]

A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors.

Bender, Donald A. (Dublin, CA); Kuklo, Thomas C. (Oakdale, CA)

1998-01-01T23:59:59.000Z

192

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

193

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

194

Nineteenth annual actinide separations conference: Conference program and abstracts  

SciTech Connect (OSTI)

This report contains the abstracts from the conference presentations. Sessions were divided into the following topics: Waste treatment; Spent fuel treatment; Issues and responses to Defense Nuclear Facility Safety Board 94-1; Pyrochemical technologies; Disposition technologies; and Aqueous separation technologies.

Bronson, M. [ed.

1995-12-31T23:59:59.000Z

195

Membrane separation systems---A research and development needs assessment  

SciTech Connect (OSTI)

Membrane based separation technology, a relative newcomer on the separations scene, has demonstrated the potential of saving enormous amounts of energy in the processing industries if substituted for conventional separation systems. Over 1 quad annually, out of 2.6, can possibly be saved in liquid-to-gas separations, alone, if membrane separation systems gain wider acceptance, according to a recent DOE/OIP (DOE/NBM-80027730 (1986)) study. In recent years great strides have been made in the field and offer even greater energy savings in the future when substituted for other conventional separation techniques such as distillation, evaporation, filtration, sedimentation, and absorption. An assessment was conducted by a group of six internationally known membrane separations experts who examined the worldwide status of research in the seven major membrane areas. This encompassed four mature technology areas: reverse osmosis, micorfiltration, ultrafiltration, and electrodialysis; two developing areas: gas separation and and pervaporation; and one emerging technology: facilitated transport. Particular attention was paid to identifying the innovative processes currently emerging, and even further improvements which could gain wider acceptance for the more mature membrane technology. The topics that were pointed out as having the greatest research emphasis are pervaporation for organic-organic separations; gas separation; micorfiltration; an oxidant-resistant reverse osmosis membrane; and a fouling-resistant ultrafiltration membrane. 35 refs., 6 figs., 22 tabs.

Baker, R.W. (Membrane Technology and Research, Inc., Menlo Park, CA (USA)); Cussler, E.L. (Minnesota Univ., Minneapolis, MN (USA). Dept. of Chemical Engineering and Materials Science); Eykamp, W. (California Univ., Berkeley, CA (USA)); Koros, W.J. (Texas Univ., Austin, TX (USA)); Riley, R.L. (Separation Systems Technology, San Diego, CA (USA)); Strathmann, H. (Fraunhofer-Institut fuer Grenzflaech

1990-03-01T23:59:59.000Z

196

Direct Observation of the Oxygenated Species during Oxygen Reduction...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

197

Economic Analysis for Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect (OSTI)

The objective of the economic analysis is to prepare a budgetary estimate of capital and operating costs of the O{sub 2}-fired PC power plant as well as for the equivalent conventional PC-fired power plant. Capital and operating costs of conventional steam generation, steam heating, and power generation equipment are estimated based on Foster Wheeler's extensive experience and database. Capital and operating costs of equipment, such as oxygen separation and CO{sub 2} liquefaction, are based on vendor supplied data and FW process plant experience. The levelized cost of electricity is determined for both the air-fired and O{sub 2}-fired power plants as well as the CO{sub 2} mitigation cost. An economic comparison between the O{sub 2}-fired PC and other alternate technologies is presented.

Andrew Seltzer

2005-02-01T23:59:59.000Z

198

Immobilized fluid membranes for gas separation  

DOE Patents [OSTI]

Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.

Liu, Wei; Canfield, Nathan L; Zhang, Jian; Li, Xiaohong Shari; Zhang, Jiguang

2014-03-18T23:59:59.000Z

199

Chromatographic hydrogen isotope separation  

DOE Patents [OSTI]

Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

Aldridge, Frederick T. (Livermore, CA)

1981-01-01T23:59:59.000Z

200

Gas Separation Using Membranes  

E-Print Network [OSTI]

Commercial membrane-based gas separator systems based upon high-flux, asymmetric polysulfone hollow fibers were first introduced in 1977 by Monsanto. These systems were packaged in compact modules containing large amounts of permeation surface area...

Koros, W. J.; Paul, D. R.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

USABC Battery Separator Development  

Broader source: Energy.gov (indexed) [DOE]

Separator Development P.I. - Ron Smith Presenter - Kristoffer Stokes, Ph.D. Celgard, LLC Project ID ES007 May 10, 2011 This presentation does not contain any proprietary,...

202

Hydrogen separation process  

DOE Patents [OSTI]

A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

2011-05-24T23:59:59.000Z

203

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

204

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

205

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

206

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

207

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

208

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

209

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

210

Organic Separation Test Results  

SciTech Connect (OSTI)

Separable organics have been defined as “those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer” (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be “no visible layer” of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2014-09-22T23:59:59.000Z

211

Molecular dynamics simulation of nanoporous graphene for selective gas separation  

E-Print Network [OSTI]

Graphene with sub-nanometer sized pores has the potential to act as a filter for gas separation with considerable efficiency gains compared to traditional technologies. Nanoporous graphene membranes are expected to yield ...

Au, Harold (Harold S.)

2012-01-01T23:59:59.000Z

212

Oxygen transport membrane system and method for transferring heat to catalytic/process reactors  

DOE Patents [OSTI]

A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

2014-01-07T23:59:59.000Z

213

Membrane separation of hydrocarbons  

DOE Patents [OSTI]

Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

1986-01-01T23:59:59.000Z

214

Separators for electrochemical cells  

DOE Patents [OSTI]

Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

Carlson, Steven Allen; Anakor, Ifenna Kingsley

2014-11-11T23:59:59.000Z

215

Simulating spin-charge separation with light  

E-Print Network [OSTI]

In this work we show that stationary light-matter excitations generated inside a hollow one-dimensional waveguide filled with atoms, can be made to generate a photonic two-component Lieb Liniger model. We explain how to prepare and drive the atomic system to a strongly interacting regime where spin-charge separation could be possible. We then proceed by explaining how to measure the corresponding effective spin and charge densities and velocities through standard optical methods based in measuring dynamically the emitted photon intensities or by analyzing the photon spectrum. The relevant interactions exhibit the necessary tunability both to generate and efficiently observe spin charge separation with current technology.

Dimitris G. Angelakis; Mingxia Huo; Elica Kyoseva; Leong Chuan kwek

2010-06-08T23:59:59.000Z

216

Novel Metallic Membranes for Hydrogen Separation  

SciTech Connect (OSTI)

To reduce dependence on oil and emission of greenhouse gases, hydrogen is favored as an energy carrier for the near future. Hydrogen can be converted to electrical energy utilizing fuel cells and turbines. One way to produce hydrogen is to gasify coal which is abundant in the U.S. The coal gasification produces syngas from which hydrogen is then separated. Designing metallic alloys for hydrogen separation membranes which will work in a syngas environment poses significant challenges. In this presentation, a review of technical targets, metallic membrane development activities at NETL and challenges that are facing the development of new technologies will be given.

Dogan, Omer

2011-02-27T23:59:59.000Z

217

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

218

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

219

Accelerator Generation and Thermal Separation (AGATS) of Technetium-99m  

ScienceCinema (OSTI)

Accelerator Generation and Thermal Separation (AGATS) of Technetium-99m is a linear electron accelerator-based technology for producing medical imaging radioisotopes from a separation process that heats, vaporizes and condenses the desired radioisotope. You can learn more about INL's education programs at http://www.facebook.com/idahonationallaboratory.

None

2013-05-28T23:59:59.000Z

220

Molten salt electrolyte separator  

DOE Patents [OSTI]

The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

Kaun, T.D.

1996-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Hydrogen isotope separation  

DOE Patents [OSTI]

A system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D.sub.2, DT, T.sub.2, and a tritium-free stream of HD for waste disposal.

Bartlit, John R. (Los Alamos, NM); Denton, William H. (Abingdon, GB3); Sherman, Robert H. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

222

Vehicle Technologies Office Merit Review 2014: Significant Cost...  

Broader source: Energy.gov (indexed) [DOE]

Direct Separator Coating, and Fast Formation Technologies Presentation given by Johnson Controls at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office...

223

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

224

Measuring oxygen reduction/evolution reactions on the nanoscale  

SciTech Connect (OSTI)

The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

2011-01-01T23:59:59.000Z

225

Oxygen-reducing catalyst layer  

DOE Patents [OSTI]

An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

2011-03-22T23:59:59.000Z

226

Pilot-Scale Demonstration of a Novel, Low-Cost Oxygen Supply Process and its Integration with Oxy-Fuel Coal-Fired Boilers  

SciTech Connect (OSTI)

In order to achieve DOE targets for carbon dioxide capture, it is crucial not only to develop process options that will generate and provide oxygen to the power cycle in a cost-effective manner compared to the conventional oxygen supply methods based on cryogenic air separation technology, but also to identify effective integration options for these new technologies into the power cycle with carbon dioxide capture. The Linde/BOC developed Ceramic Autothermal Recovery (CAR) process remains an interesting candidate to address both of these issues by the transfer of oxygen from the air to a recycled CO{sub 2} rich flue-gas stream in a cyclic process utilizing the high temperature sorption properties of perovskites. Good progress was made on this technology in this project, but significant challenges remain to be addressed before CAR oxygen production technology is ready for commercial exploitation. Phase 1 of the project was completed by the end of September 2008. The two-bed 0.7 tons/day O2 CAR process development unit (PDU) was installed adjacent to WRI's pilot scale coal combustion test facility (CTF). Start-up and operating sequences for the PDU were developed and cyclic operation of the CAR process demonstrated. Controlled low concentration methane addition allowed the beds to be heated up to operational temperature (800-900 C) and then held there during cyclic operation of the 2-bed CAR process, in this way overcoming unavoidable heat losses from the beds during steady state operation. The performance of the PDU was optimized as much as possible, but equipment limitations prevented the system from fully achieving its target performance. Design of the flue gas recirculation system to integrate CAR PDU with the CTF and the system was completed and integrated tests successfully performed at the end of the period. A detailed techno-economic analysis was made of the CAR process for supplying the oxygen in oxy-fuel combustion retrofit option using AEP's 450 MW Conesville, Ohio plant and contrasted with the cryogenic air separation option (ASU). Design of a large scale CAR unit was completed to support this techno-economic assessment. Based on the finding that the overall cost potential of the CAR technology compared to cryogenic ASU is nominal at current performance levels and that the risks related to both material and process scale up are still significant, the team recommended not to proceed to Phase 2. CAR process economics continue to look attractive if the original and still 'realistic' target oxygen capacities could be realized in practice. In order to achieve this end, a new fundamental materials development program would be needed. With the effective oxygen capacities of the current CAR materials there is, however, insufficient economic incentive to use this commercially unproven technology in oxy-fuel power plant applications in place of conventional ASUs. In addition, it is now clear that before a larger scale pilot demonstration of the CAR technology is made, a better understanding of the impact of flue-gas impurities on the CAR materials and of thermal transients in the beds is required.

Krish Krishnamurthy; Divy Acharya; Frank Fitch

2008-09-30T23:59:59.000Z

227

Separations and Actinide Science -- 2005 Roadmap  

SciTech Connect (OSTI)

The Separations and Actinide Science Roadmap presents a vision to establish a separations and actinide science research (SASR) base composed of people, facilities, and collaborations and provides new and innovative nuclear fuel cycle solutions to nuclear technology issues that preclude nuclear proliferation. This enabling science base will play a key role in ensuring that Idaho National Laboratory (INL) achieves its long-term vision of revitalizing nuclear energy by providing needed technologies to ensure our nation's energy sustainability and security. To that end, this roadmap suggests a 10-year journey to build a strong SASR technical capability with a clear mission to support nuclear technology development. If nuclear technology is to be used to satisfy the expected growth in U.S. electrical energy demand, the once-through fuel cycle currently in use should be reconsidered. Although the once-through fuel cycle is cost-effective and uranium is inexpensive, a once-through fuel cycle requires long-term disposal to protect the environment and public from long-lived radioactive species. The lack of a current disposal option (i.e., a licensed repository) has resulted in accumulation of more than 50,000 metric tons of spent nuclear fuel. The process required to transition the current once-through fuel cycle to full-recycle will require considerable time and significant technical advancement. INL's extensive expertise in aqueous separations will be used to develop advanced separations processes. Computational chemistry will be expanded to support development of future processing options. In the intermediate stage of this transition, reprocessing options will be deployed, waste forms with higher loading densities and greater stability will be developed, and transmutation of long-lived fission products will be explored. SASR will support these activities using its actinide science and aqueous separations expertise. In the final stage, full recycle will be enabled by advanced reactors and reprocessing methods based on pyrochemical methods and by using different fuel cycles that do not readily produce plutonium. SASR will facilitate the deployment of advanced pyrochemical separation technology and support development of reprocessing of thorium-based reactor fuels.

Not Available

2005-09-01T23:59:59.000Z

228

Health Effects from Advanced Combustion and Fuel Technologies  

SciTech Connect (OSTI)

This document requires a separate file for the figures. It is for DOE's Office of Vehicle Technologies Annual Report

Barone, Teresa L [ORNL; Parks, II, James E [ORNL; Lewis Sr, Samuel Arthur [ORNL; Connatser, Raynella M [ORNL

2010-01-01T23:59:59.000Z

229

Modeling and Control of High-Velocity Oxygen-Fuel (HVOF) Thermal Spray: A Tutorial Review  

E-Print Network [OSTI]

Spray Technology Volume 18(5-6) Mid-December 2009—765 Oxygenoxygen and fuel are available, a previously developed approach (Ref 11) can Journal of Thermal Spray TechnologyTechnology Peer Reviewed Substrate properties Gas mass flow rate Fuel/oxygen

Li, Mingheng; Christofides, Panagiotis D.

2009-01-01T23:59:59.000Z

230

Electrochemical studies of quinone oxygen  

SciTech Connect (OSTI)

Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

1990-02-01T23:59:59.000Z

231

Laser isotope separation  

DOE Patents [OSTI]

A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

1988-01-01T23:59:59.000Z

232

Photochemical isotope separation  

DOE Patents [OSTI]

A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

1987-01-01T23:59:59.000Z

233

Photochemical isotope separation  

DOE Patents [OSTI]

A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

1987-04-28T23:59:59.000Z

234

Steam separator latch assembly  

DOE Patents [OSTI]

A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

Challberg, R.C.; Kobsa, I.R.

1994-02-01T23:59:59.000Z

235

Steam separator latch assembly  

DOE Patents [OSTI]

A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof.

Challberg, Roy C. (Livermore, CA); Kobsa, Irvin R. (San Jose, CA)

1994-01-01T23:59:59.000Z

236

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

237

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1989-04-25T23:59:59.000Z

238

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

1989-01-01T23:59:59.000Z

239

Membrane separation of hydrocarbons  

DOE Patents [OSTI]

Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

1986-01-01T23:59:59.000Z

240

Separations/pretreatment considerations for Hanford privatization phase 2  

SciTech Connect (OSTI)

The Tank Focus Area is funded to develop, demonstrate, and deploy technologies that will assist in the treatment and closure of its nuclear waste tanks. Pretreatment technologies developed to support the privatization effort by the Department of Energy are reviewed. Advancements in evaporation, solid-liquid separation, sludge treatment, solids controls, sodium management, and radionuclide removal are considered.

Hunt, R.D.; McGinnis, C.P.; Welch, T.D.

1998-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Materials and interfaces for catalysis, separation, storage, and environmental applications  

E-Print Network [OSTI]

and interfaces for a host of sustainable chemical processes that provide renewable (or cleaner) fuels the next generation of catalysts, separation processes, gas and liquid storage technologies, and environmental remediation methods. These materials and technologies are at the heart of industrial processes

Li, Mo

242

Morgantown Energy Technology Center, technology summary  

SciTech Connect (OSTI)

This document has been prepared by the DOE Environmental Management (EM) Office of Technology Development (OTD) to highlight its research, development, demonstration, testing, and evaluation activities funded through the Morgantown Energy Technology Center (METC). Technologies and processes described have the potential to enhance DOE`s cleanup and waste management efforts, as well as improve US industry`s competitiveness in global environmental markets. METC`s R&D programs are focused on commercialization of technologies that will be carried out in the private sector. META has solicited two PRDAs for EM. The first, in the area of groundwater and soil technologies, resulted in twenty-one contact awards to private sector and university technology developers. The second PRDA solicited novel decontamination and decommissioning technologies and resulted in eighteen contract awards. In addition to the PRDAs, METC solicited the first EM ROA in 1993. The ROA solicited research in a broad range of EM-related topics including in situ remediation, characterization, sensors, and monitoring technologies, efficient separation technologies, mixed waste treatment technologies, and robotics. This document describes these technology development activities.

Not Available

1994-06-01T23:59:59.000Z

243

Microprocessor Based Combustion Monitoring and Control Systems Utilizing in Situ Opacity, Oxygen and CO Measurement  

E-Print Network [OSTI]

, self-diagnostics, field programmable memory, and improved operator interface. By measuring the products of combustion utilizing the latest In Situ Opacity, Oxygen, and CO Monitoring technology, the fuel air mixture ratio of industrial fuel burning...

Molloy, R. C.

1981-01-01T23:59:59.000Z

244

A miniature inexpensive, oxygen sensing element  

SciTech Connect (OSTI)

An exhaustive study was conducted to determine the feasibility of Nernst-type oxygen sensors based on ceramics containing Bi{sub 2}O{sub 3}. The basic sensor design consisted of a ceramic sensing module sealed into a metal tube. The module accommodated an internal heater and thermocouple. Thermal-expansion-matched metals, adhesives, and seals were researched and developed, consistent with sequential firings during sensor assembly. Significant effort was devoted to heater design/testing and to materials' compatibility with Pt electrodes. A systematic approach was taken to develop all sensor components which led to several design modifications. Prototype sensors were constructed and exhaustively tested. It is concluded that development of Nerst-type oxygen sensors based on Bi{sub 2}O{sub 3} will require much further effort and application of specialized technologies. However, during the course of this 3-year program much progress was reported in the literature on amperometric-type oxygen sensors, and a minor effort was devoted here to this type of sensor based on Bi{sub 2}O{sub 3}. These studies were made on Bi{sub 2}O{sub 3}-based ceramic samples in a multilayer-capacitor-type geometry and amperometric-type oxygen sensing was demonstrated at very low temperatures ({approximately} 160{degree}C). A central advantage here is that these types of sensors can be mass-produced very inexpensively ({approximately} 20--50 cents per unit). Research is needed, however, to develop an optimum diffusion-limiting barrier coating. In summary, the original goals of this program were not achieved due to unforeseen problems with Bi{sub 2}O{sub 3}-based Nernst sensors. However, a miniature amperometric sensor base on Bi{sub 2}O{sub 3} was demonstrated in this program, and it is now seen that this latter sensor is far superior to the originally proposed Nernst sensor. 6 refs., 24 figs.

Arenz, R.W.

1991-10-07T23:59:59.000Z

245

Origin of deep subgap states in amorphous indium gallium zinc oxide: Chemically disordered coordination of oxygen  

SciTech Connect (OSTI)

The origin of the deep subgap states in amorphous indium gallium zinc oxide (a-IGZO), whether intrinsic to the amorphous structure or not, has serious implications for the development of p-type transparent amorphous oxide semiconductors. We report that the deep subgap feature in a-IGZO originates from local variations in the oxygen coordination and not from oxygen vacancies. This is shown by the positive correlation between oxygen composition and subgap intensity as observed with X-ray photoelectron spectroscopy. We also demonstrate that the subgap feature is not intrinsic to the amorphous phase because the deep subgap feature can be removed by low-temperature annealing in a reducing environment. Atomistic calculations of a-IGZO reveal that the subgap state originates from certain oxygen environments associated with the disorder. Specifically, the subgap states originate from oxygen environments with a lower coordination number and/or a larger metal-oxygen separation.

Sallis, S.; Williams, D. S. [Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States); Butler, K. T.; Walsh, A. [Center for Sustainable Technologies and Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY (United Kingdom); Quackenbush, N. F. [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Junda, M.; Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Fischer, D. A.; Woicik, J. C. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); White, B. E.; Piper, L. F. J., E-mail: lpiper@binghamton.edu [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States)

2014-06-09T23:59:59.000Z

246

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

247

Cyclic membrane separation process  

DOE Patents [OSTI]

A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In one of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the other part, the membrane is inoperative while gas pressure rises in the ullage. Ambient air is charged to the membrane separation unit during the latter part of the cycle.

Bowser, John

2004-04-13T23:59:59.000Z

248

Cyclic membrane separation process  

DOE Patents [OSTI]

A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In the first part of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the second part, the membrane is inoperative while gas pressure rises in the ullage. In one aspect of this invention, a vacuum is drawn in the membrane separation unit thus reducing overall VOC emissions.

Nemser, Stuart M.

2005-05-03T23:59:59.000Z

249

Jupiter Oxygen Corporation/Albany Research Center Crada Progress Report, September  

SciTech Connect (OSTI)

The Albany Research Center (ARC) has developed a new Integrated Pollutant Removal (IPR) process for fossil-fueled boilers. Pursuant to a cooperative research and development agreement (CRADA) with Jupiter Oxygen Corporation, ARC currently is studying the IPR process as applied to the oxygen fuel technology developed by Jupiter. As discussed further below, these two new technologies are complementary. This interim report summarizes the study results to date and outlines the potential activities under the next phase of the CRADA with Jupiter.

Turner, Paul C.; Schoenfield, Mark (Jupiter Oxygen Corp.)

2004-09-13T23:59:59.000Z

250

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

251

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

252

Enhanced membrane gas separations  

SciTech Connect (OSTI)

An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

Prasad, R.

1993-07-13T23:59:59.000Z

253

Explosively separable casing  

DOE Patents [OSTI]

An explosively separable casing including a cylindrical afterbody and a circular cover for one end of the afterbody is disclosed. The afterbody has a cylindrical tongue extending longitudinally from one end which is matingly received in a corresponding groove in the cover. The groove is sized to provide a pocket between the end of the tongue and the remainder of the groove so that an explosive can be located therein. A seal is also provided between the tongue and the groove for sealing the pocket from the atmosphere. A frangible holding device is utilized to hold the cover to the afterbody. When the explosive is ignited, the increase in pressure in the pocket causes the cover to be accelerated away from the afterbody. Preferably, the inner wall of the afterbody is in the same plane as the inner wall of the tongue to provide a maximum space for storage in the afterbody and the side wall of the cover is thicker than the side wall of the afterbody so as to provide a sufficiently strong surrounding portion for the pocket in which the explosion takes place. The detonator for the explosive is also located on the cover and is carried away with the cover during separation. The seal is preferably located at the longitudinal end of the tongue and has a chevron cross section.

Jacobson, Albin K. (Albuquerque, NM); Rychnovsky, Raymond E. (Livermore, CA); Visbeck, Cornelius N. (Livermore, CA)

1985-01-01T23:59:59.000Z

254

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network [OSTI]

, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four: business administration, wind farm management, aircraft maintenance, tooling production, quality and safety or selected program track focus. Transfer students must talk to their advisor about transferring their courses

255

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network [OSTI]

: business administration, energy management, wind farm management, automation and controls, aircraft, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four students must talk to their advisor about transferring their courses over for WSU credit. Laboratory

256

Development of an Electrochemical Separator and Compressor  

SciTech Connect (OSTI)

Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

Trent Molter

2011-04-28T23:59:59.000Z

257

Air separation by the Moltox process. Interim final report  

SciTech Connect (OSTI)

Results are described of a development program on a new and energy-saving process for air separation. The Moltox process involves reversibly reacting oxygen in air with a recirculating salt solution, such that oxygen is extracted without depressurizing the remaining nitrogen. Energy savings of approximately 50% are indicated for this process compared to conventional cryogenic air separation. The development program consisted of design, construction, and operation of a 6 liter/minute pilot plant; optimization of the process flowsheet through computer modelling; investigation of engineering aspects of the process including corrosion, safety, and NO/sub x/ generation; and an economic comparison to conventional cryogenic practice. All objectives were satisfactorily achieved except for continuous operation of the pilot plant, and the modifications necessary to achieve that have been identified. Economically the Moltox process shows a substantial advantage over large scale cryogenic plants which are powered by fuel vice electricity.

Erickson, D.C.

1981-04-01T23:59:59.000Z

258

Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes  

E-Print Network [OSTI]

is the existence of hot spots in the catalyst bed due to the reaction exothermicity [1]. This hydrogen production process could be cost-effective if oxygen is provided by sources other than air separation plant. CO2 reforming (or dry reforming) of methane... information about equilibrium product compositions and equilibrium constants at different temperatures were provided by one of the former students in Dr Susan Williams’ research group [8]. Syngas can also be produced by coal gasification. The syngas...

Faraji, Sedigheh

2010-06-08T23:59:59.000Z

259

Task 38 - commercial mercury remediation demonstrations: Thermal retorting and physical separation/chemical leaching. Topical report, December 1, 1994--June 30, 1996  

SciTech Connect (OSTI)

Results are presented on the demonstration of two commercial technologies for the removal of mercury from soils found at natural gas metering sites. Technologies include a thermal retorting process and a combination of separation, leaching, and electrokinetic separation process.

Charlton, D.S.; Fraley, R.H.; Stepan, D.J.

1998-12-31T23:59:59.000Z

260

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

262

Electrified Separation Processes in Industry  

E-Print Network [OSTI]

For any separation procedure in the chemical industry, a certain amount of reversible work in the form of free energy is required, as dictated by the second law of thermodynamics. Classical techniques for effecting liquid-phase separations...

Appleby, A. J.

1983-01-01T23:59:59.000Z

263

Oxygen transfer in the implant environment  

E-Print Network [OSTI]

Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

Goor, Jared Braden

2007-01-01T23:59:59.000Z

264

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

265

Electrochemical oxygen pumps. Final CRADA report.  

SciTech Connect (OSTI)

All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

Carter, J. D.

2009-10-01T23:59:59.000Z

266

Separation Nanotechnology of Diethylenetriaminepentaacetic Acid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded Magnetic Nanoparticles for Spent Nuclear Fuel. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded...

267

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux  

E-Print Network [OSTI]

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

Mallin, Michael

268

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

269

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network [OSTI]

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

270

Extracorporeal membrane oxygenation promotes long chain fatty...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

271

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network [OSTI]

Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

Kim, Kee Chul

2010-01-01T23:59:59.000Z

272

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

273

Gas separation process  

SciTech Connect (OSTI)

The method for production of high purity hydrogen and high purity carbon monoxide from a mixed gas stream comprising these components together with carbon dioxide and a zero to a minor amount of one or more other gaseous contaminants is described comprising the steps of: (a) passing the mixed gas stream into and through a first bed of solid adsorbent capable of selectively adsorbing carbon dioxide and water while discharging from the bed a dry CO/sub 2/-freed effluent; (b) introducing the dry CO/sub 2/-freed effluent into a cryogenic environment for cooling the same therein under conditions effective for condensation of at least the major part of the carbon monoxide present in the dry CO/sub 2/-freed effluent; (c) withdrawing from the cryogenic environment carbon monoxide of high purity; (d) separately withdrawing from the cryogenic environment an uncondensed first gas stream product comprised of crude hydrogen and subjecting the first gas stream product to selective adsorption of non-hydrogen components therefrom in a second bed of solid absorbent, while recovering from the second bed the non-sorbed fraction as a product stream of essentially pure hydrogen; (e) purging the second solid adsorbent bed to desorb non-hydrogen components sorbed therein in step (d), and withdrawing from the bed a gas stream comprising the desorbed non-hydrogen components.

Nicholas, D.M.; Hopkins, J.A.; Roden, T.M.; Bushinsky, J.P.

1988-03-22T23:59:59.000Z

274

Organic contaminant separator  

DOE Patents [OSTI]

A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

Del Mar, P.

1993-12-28T23:59:59.000Z

275

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

276

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

277

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

278

Determination of oxygen in molten alkali halide salts by proton activation analysis  

SciTech Connect (OSTI)

The authors have recently used a lanthanum fluoride precipitation method to separate /sup 18/F produced from proton activation of /sup 18/O in alkali chloride and fluoride salts. The procedure was developed for studying dissolved oxide species in alkali halide melts. Determination of oxygen in these systems is important for research in batteries and in extractive metallurgy utilizing molten salts as solvents. The details are given oxygen determination in alkali chloride and fluoride systems.

Wai, C.M.; Dysart, M.E.

1986-12-01T23:59:59.000Z

279

Enhanced Separation Efficiency in Olefin/Paraffin Distillation  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

280

A study of the separation of particles from gases  

SciTech Connect (OSTI)

Cyclones are the simplest and most reliable means of particles and gas separation. They also function as a method of air pollution control and as a cost efficient way of doing so. These basic machines have been in use for many years, and based on advances in technology, cyclones have now been designed for specific applications and conditions. These applications are restricted by inherent properties of the construction of the cyclone, and the materials being separated within the cyclone.

Stevens, G.L. II; Masudi, H.

1995-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Science & technology review  

SciTech Connect (OSTI)

This document is the August, 1995 issue of the Science and Technology review, a Lawrence Berkeley Laboratory publication. It contains two major articles, one on Scanning Tunneling Microscopy - as applied to materials engineering studies, and one on risk assessment, in this case looking primarily at a health care problem. Separate articles will be indexed from this journal to the energy database.

NONE

1995-08-01T23:59:59.000Z

282

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped Ti-substituted perovskites, La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Ti{sub x}O{sub 3}, with 0 {le} x {le} 0.20, were investigated by neutron diffraction, magnetization, electric resistivity, and magnetoresistance (MR) measurements. All samples show a rhombohedral structure (space group R3C) from 10 K to room temperature. At room temperature, the cell parameters a, c and the unit cell volume increase with increasing Ti content. However, at 10 K, the cell parameter a has a maximum value for x = 0.10, and decreases for x > 0.10, while the unit cell volume remains nearly constant for x > 0.10. The average (Mn,Ti)-O bond length increases up to x = 0.15, and the (Mn,Ti)-O-(Mn,Ti) bond angle decreases with increasing Ti content to its minimum value at x = 0.15 at room temperature. Below the Curie temperature TC, the resistance exhibits metallic behavior for the x {le} 0.05 samples. A metal (semiconductor) to insulator transition is observed for the x {ge} 0.10 samples. A peak in resistivity appears below TC for all samples, and shifts to a lower temperature as x increases. The substitution of Mn by Ti decreases the 2p-3d hybridization between O and Mn ions, reduces the bandwidth W, and increases the electron-phonon coupling. Therefore, the TC shifts to a lower temperature and the resistivity increases with increasing Ti content. A field-induced shift of the resistivity maximum occurs at x {le} 0.10 compounds. The maximum MR effect is about 70% for La{sub 0.7}Sr{sub 0.3}Mn{sub 0.8}Ti{sub 0.2}O{sub 3}. The separation of TC and the resistivity maximum temperature T{sub {rho},max} enhances the MR effect in these compounds due to the weak coupling between the magnetic ordering and the resistivity as compared with La{sub 0.7}Sr{sub 0.3}MnO{sub 3}. The bulk densities of the membranes were determined using the Archimedes method. The bulk density was 5.029 and 5.57 g/cc for LSFT and dual phase membranes, respectively. The microstructure of the dual phase membrane was analyzed using SEM. It is evident from the micrograph that the microstructure is composed of dual phases. The dense circular regions are enclosed by the less dense, continuous phase which accommodates most of the pores. The pores are normally aggregated and found clustered along the dense regions where as the dense regions do not have pores. Upon closer observation of the micrograph it is revealed that the dense region has a clear circular cleavage or crack as their boundary. The circular cleavage clearly encompasses a dense region and which consists of no pore or any flaw that is visible. The size distribution of the dense, discontinuous regions is varying from 5 to 20 {micro}m with a D{sub 50} of 15 {micro}m. The grain size distribution was estimated from the micrographs using image analysis and a unimodal distribution of grains was observed with an average grain size of 1.99 {micro}m. The chemical compositions of the membranes were analyzed using EDS analysis and no other impurities were observed. The XRD analysis was carried out for the membranes and the phase purity was confirmed. The fracture toughness of LSFT membranes at room temperature has to be calculated using the Vickers indentation method. An electrochemical cell has been designed and built for measurements of the ionic conductivity by the use of blocking electrodes. Preliminary measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Modifications to the apparatus to improve the data quality have been completed. Electron microscopy studies of the origin of the slow kinetics on reduction of ferrites have been initiated. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradient

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-05-01T23:59:59.000Z

283

Synthesis of Amine-Modified Aerogel Sorbents and Metal-Organic Framework-5 (MOF-5) Membranes for Carbon Dioxide Separation.  

E-Print Network [OSTI]

??Amine-modified solid sorbents and membrane separation are promising technologies for separation and capture of carbon dioxide (CO2) from combustion flue gas. Amine absorption processes are… (more)

Rosa, Teresa M.

2010-01-01T23:59:59.000Z

284

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network [OSTI]

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

285

Faience Technology  

E-Print Network [OSTI]

by Joanne Hodges. Faience Technology, Nicholson, UEE 2009Egyptian materials and technology, ed. Paul T. Nicholson,Nicholson, 2009, Faience Technology. UEE. Full Citation:

Nicholson, Paul

2009-01-01T23:59:59.000Z

286

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

287

Evaluation of Novel Ceria-Supported Metal Oxides As Oxygen Carriers for Chemical-Looping Combustion  

E-Print Network [OSTI]

Evaluation of Novel Ceria-Supported Metal Oxides As Oxygen Carriers for Chemical-Looping Combustion of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Goteborg, Sweden States § Department of Energy and Environment, Chalmers University of Technology, SE-412 96 Goteborg

Azad, Abdul-Majeed

288

Gas separation membrane module assembly  

DOE Patents [OSTI]

A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains a tube sheet that divides the space within the housing into two gas-tight spaces. A permeate collection system within the housing gathers permeate gas from the tubes for discharge from the housing.

Wynn, Nicholas P (Palo Alto, CA); Fulton, Donald A. (Fairfield, CA)

2009-03-31T23:59:59.000Z

289

Membrane Separations of Liquid Mixtures  

E-Print Network [OSTI]

MEMBRANE SEPARATIONS OF LIQUID MIXTURES Douglas R. Lloyd Separations Research Program Department of Chemical Engineering The University of Texas at Austin Austin, Texas In recent years considerable attention has been given to the need... for reduced energy costs in the chemical processing industry. A major portion of the energy consumed in this industry is associated with the separation and recovery of chemicals. Membrane processes offer energy-efficient, cost effective methods...

Lloyd, D. R.

290

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

2013-08-01T23:59:59.000Z

291

Separation Membrane Development (Separation Using Encapsulated Metal Hydride)  

E-Print Network [OSTI]

Separation Membrane Development (Separation Using Encapsulated Metal Hydride) L. Kit Heung Savannah: The first is to produce a sol-gel encapsulated metal hydride packing material that will a) absorbs hydrogen may be that hydrogen must come from multiple sources. These sources will include renewable (solar

292

OXYGEN TRANSPORT MEMBRANE (OTM) AIDED  

E-Print Network [OSTI]

· Benefits to California · Overall Technology Assessment · Appendices o Appendix A: Final Report (under · Industrial/Agricultural/Water End-Use Energy Efficiency · Renewable Energy Technologies · Environmentally

293

MHK Technologies/Oxygen Releasing and Carbon Absorbing Ocean...  

Open Energy Info (EERE)

and 8 provision for the addition of fleets without depletion of primary feed stocks as in nuclear energy systems 2 Fig 1 In summary the system converts wave energy from the nearly...

294

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides  

E-Print Network [OSTI]

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

Paris-Sud XI, Université de

295

Oxygen uptake of benthic systems  

E-Print Network [OSTI]

mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

Priebe, William Franklin

1972-01-01T23:59:59.000Z

296

ELSEVIER Separations Technology 6 (1996)261-264 Short communication  

E-Print Network [OSTI]

excellent agreement in their representation of the phase envelope. Temperature dependent NRTL (non- matography (GC). Temperature-dependent NRTL parameters were correlated from the data to allow reconstruction

Gu, Tingyue

1996-01-01T23:59:59.000Z

297

MassMass transfer andtransfer and separation technologyseparation technology  

E-Print Network [OSTI]

-blade paddlea. Flat blade paddle ­ b. Pitch-blade paddle ­ c. Flat-blade turbine ­ d. Marine-type propeller ­ e a limit to tangential flow mixing Is created with blade- and turbine-type impellers, especially g by blade- and turbine- type impellers RoNzmars 2012 a vortex at the surface type impellers Picture: Z87 6

Zevenhoven, Ron

298

ITP Chemicals: Hybripd Separations/Distillation Technology. Research  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4InFindingIR-2003-Transmission &

299

SciTech Connect: Center for Advanced Separation Technology  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systems controllerAdditiveBetatron Radiation from aBrown Grease

300

Nuclear Separations Technologies Workshop Report | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergyDepartment of Energy Advanced1, 2014NuclearCommission,Science

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Center for Gas Separations Relevant to Clean Energy Technologies (CGS) |  

Office of Science (SC) Website

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 IndustrialIsadore Perlman,Bios High Energy PhysicsU.S. DOE Office of Science

302

Separator material for electrochemical cells  

DOE Patents [OSTI]

An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

Cieslak, W.R.; Storz, L.J.

1991-03-26T23:59:59.000Z

303

Separator material for electrochemical cells  

DOE Patents [OSTI]

An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

Cieslak, Wendy R. (1166 Laurel Loop NE., Albuquerque, NM 87122); Storz, Leonard J. (2215 Ambassador NE., Albuquerque, NM 87112)

1991-01-01T23:59:59.000Z

304

Three phase downhole separator process  

DOE Patents [OSTI]

Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

Cognata, Louis John (Baytown, TX)

2008-06-24T23:59:59.000Z

305

Novel, Ceramic Membrane System For Hydrogen Separation  

SciTech Connect (OSTI)

Separation of hydrogen from coal gas represents one of the most promising ways to produce alternative sources of fuel. Ceramatec, teamed with CoorsTek and Sandia National Laboratories has developed materials technology for a pressure driven, high temperature proton-electron mixed conducting membrane system to remove hydrogen from the syngas. This system separates high purity hydrogen and isolates high pressure CO{sub 2} as the retentate, which is amenable to low cost capture and transport to storage sites. The team demonstrated a highly efficient, pressure-driven hydrogen separation membrane to generate high purity hydrogen from syngas using a novel ceramic-ceramic composite membrane. Recognizing the benefits and limitations of present membrane systems, the all-ceramic system has been developed to address the key technical challenges related to materials performance under actual operating conditions, while retaining the advantages of thermal and process compatibility offered by the ceramic membranes. The feasibility of the concept has already been demonstrated at Ceramatec. This project developed advanced materials composition for potential integration with water gas shift rectors to maximize the hydrogenproduction.

Elangovan, S.

2012-12-31T23:59:59.000Z

306

Abrupt Decline in the Open-Circuit Voltage of Direct Methanol Fuel Cells at Critical Oxygen Feed Rate  

E-Print Network [OSTI]

Abrupt Decline in the Open-Circuit Voltage of Direct Methanol Fuel Cells at Critical Oxygen Feed and Technology, Clear Water Bay, Kowloon, Hong Kong, China The open-circuit voltage OCV of a direct methanol fuel cell DMFC was measured by varying the cathode oxygen flow rate OFR while keeping the methanol

Zhao, Tianshou

307

PHYSICAL REVIEW B 86, 085123 (2012) Composition-dependent oxygen vacancy formation in multicomponent wide-band-gap oxides  

E-Print Network [OSTI]

PHYSICAL REVIEW B 86, 085123 (2012) Composition-dependent oxygen vacancy formation University of Science and Technology, Rolla, Missouri 65409, USA (Received 17 April 2012; revised manuscript received 19 July 2012; published 16 August 2012) The formation and distribution of oxygen vacancy

Medvedeva, Julia E.

308

A double exponential model for biochemical oxygen demand Ian G. Mason a,*, Robert I. McLachlan b  

E-Print Network [OSTI]

A double exponential model for biochemical oxygen demand Ian G. Mason a,*, Robert I. McLachlan b , Daniel T. Ge´rard a a Institute of Technology and Engineering, Massey University, Palmerston North, New 2005 Abstract Biochemical oxygen demand (BOD) exertion patterns in anaerobically treated farm dairy

McLachlan, Robert

309

Hanford Site physical separations CERCLA treatability test plan  

SciTech Connect (OSTI)

This test plan describes specifications, responsibilities, and general procedures to be followed to conduct a physical separations soil treatability test in the North Process Pond of the 300-FF-1 Operable Unit at the Hanford Site, Washington. The objective of this test is to evaluate the use of physical separation systems as a means of concentrating chemical and radioactive contaminants into fine soil fractions and thereby minimizing waste volumes. If successful the technology could be applied to clean up millions of cubic meters of contaminated soils in waste sites at Hanford and other sites. It is not the intent of this test to remove contaminated materials from the fine soils. Physical separation is a simple and comparatively low cost technology to potentially achieve a significant reduction in the volume of contaminated soils. Organic contaminants are expected to be insignificant for the 300-FF-I Operable Unit test, and further removal of metals and radioactive contaminants from the fine fraction of soils will require secondary treatment such as chemical extraction, electromagnetic separation, or other technologies. Additional investigations/testing are recommended to assess the economic and technical feasibility of applying secondary treatment technologies, but are not within the scope of this test. This plan provides guidance and specifications for the treatability test to be conducted as a service contract. More detailed instructions and procedures will be provided as part of the vendors (sellers) proposal. The procedures will be approved by Westinghouse Hanford Company (Westinghouse Hanford) and finalized by the seller prior to initiating the test.

Not Available

1992-03-01T23:59:59.000Z

310

Quantifying the areal extent and dissolved oxygen concentrations of Archean oxygen oases.  

E-Print Network [OSTI]

??Several lines of evidence indicate that the advent of oxygenic photosynthesis preceded the oxygenation of the atmosphere—perhaps by as much as 300 million years. The… (more)

Olson, Stephanie

2013-01-01T23:59:59.000Z

311

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

312

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

313

Variable oxygen/nitrogen enriched intake air system for internal combustion engine applications  

DOE Patents [OSTI]

An air supply control system for selectively supplying ambient air, oxygen enriched air and nitrogen enriched air to an intake of an internal combustion engine includes an air mixing chamber that is in fluid communication with the air intake. At least a portion of the ambient air flowing to the mixing chamber is selectively diverted through a secondary path that includes a selectively permeable air separating membrane device due a differential pressure established across the air separating membrane. The permeable membrane device separates a portion of the nitrogen in the ambient air so that oxygen enriched air (permeate) and nitrogen enriched air (retentate) are produced. The oxygen enriched air and the nitrogen enriched air can be selectively supplied to the mixing chamber or expelled to atmosphere. Alternatively, a portion of the nitrogen enriched air can be supplied through another control valve to a monatomic-nitrogen plasma generator device so that atomic nitrogen produced from the nitrogen enriched air can be then injected into the exhaust of the engine. The oxygen enriched air or the nitrogen enriched air becomes mixed with the ambient air in the mixing chamber and then the mixed air is supplied to the intake of the engine. As a result, the air being supplied to the intake of the engine can be regulated with respect to the concentration of oxygen and/or nitrogen.

Poola, Ramesh B. (Woodridge, IL); Sekar, Ramanujam R. (Naperville, IL); Cole, Roger L. (Elmhurst, IL)

1997-01-01T23:59:59.000Z

314

New technology for the independent producer  

SciTech Connect (OSTI)

This technology transfer conference consisted of the following six sessions: reservoir characterization; drilling, testing and completion; enhanced oil recovery; 3-d seismic and amplitude variation with offset (AVO); biotechnology for field applications; and well logging technology. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

Not Available

1993-07-01T23:59:59.000Z

315

Continuous magnetic separator and process  

DOE Patents [OSTI]

A continuous magnetic separator and process for separating a slurry comprising magnetic particles into a clarified stream and a thickened stream. The separator has a container with a slurry inlet, an overflow outlet for the discharge of the clarified slurry stream, and an underflow outlet for the discharge of a thickened slurry stream. Magnetic particles in the slurry are attracted to, and slide down, magnetic rods within the container. The slurry is thus separated into magnetic concentrate and clarified slurry. Flow control means can be used to control the ratio of the rate of magnetic concentrate to the rate of clarified slurry. Feed control means can be used to control the rate of slurry feed to the slurry inlet.

Oder, Robin R. (Export, PA); Jamison, Russell E. (Lower Burrell, PA)

2008-04-22T23:59:59.000Z

316

Pump and centrifugal separator apparatus  

SciTech Connect (OSTI)

The invention relates to agitating means for preventing the accumulation of particulate matter at the contaminate outlet orifices in a pump and centrifugal separator apparatus. The pump separator apparatus includes a rotatable casing forming a chamber for centrifugally separating the oil, water and contaminant matter in an oil well production fluid. The clean oil is collected by a stationary pitot tube in the chamber, the clean water is drawn off at an outlet port near the outer periphery of the chamber, and the dirty water and contaminants are discharged through outlet orifices formed in the outer wall of the casing. The agitating means includes rotating jet ports for directing streams of pressurized fluid tangentially along the inner surface of the casing to agitate accumulations of separated solid contaminant matter thereby preventing the clogging of the outlet orifices.

Erickson, J.W.

1981-08-11T23:59:59.000Z

317

Fluorine separation and generation device  

DOE Patents [OSTI]

A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

Jacobson, Craig P. (Moraga, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA); Stefan, Constantin I. (Hayward, CA)

2010-03-02T23:59:59.000Z

318

Fluorine separation and generation device  

DOE Patents [OSTI]

A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

The Regents of the University of California (Oakland, CA)

2008-12-23T23:59:59.000Z

319

Wireless Harsh-Environment Oxygen Sensors D.W. Greve,1,2  

E-Print Network [OSTI]

and Environmental Engineering Carnegie Mellon University Pittsburgh, PA 15213 Abstract--Surface acoustic wave (SAW pollution. In oxy-fuel combustion of coal, separated oxygen is used so that the exhaust is nearly pure of multiple sensors to sample the nonhomogeneous exhaust flow. We recently reported on a surface acoustic wave

Greve, David.W.

320

Oxygen Electrocatalysts for Water Electrolyzers and Reversible Fuel Cells: Status and Perspective  

SciTech Connect (OSTI)

Hydrogen production by electrochemical water electrolysis has received great attention as an alternative technology for energy conversion and storage. The oxygen electrode has a substantial effect on the performance and durability in water electrolyzers and reversible fuel cells because of its intrinsically slow kinetics for oxygen evolution/reduction and poor durability under harsh operating environments. To improve oxygen kinetics and durability of the electrode, extensive studies for highly active and stable oxygen electrocatalyst have been performed. However, due to the thermodynamic instability of transition metals in acidic media, noble metal compounds have been primarily utilized as electrocatalysts in water electrolyzers and reversible fuel cells. For water electrolyzer applications, single noble metal oxides such as ruthenium oxide and iridium oxide have been studied, and binary or ternary metal oxides have been developed to take synergestic effects of each component. On the other hand, a variety of bifunctional electrocatalysts with a combination of monofunctional electrocatalysts such as platinum for oxygen reduction and iridium oxide for oxygen evolution for reversible fuel cell applications have been mainly proposed. Practically, supported iridium oxide-on-platinum, its reverse type, and non-precious metal-supported platinum and iridium bifunctional electrocatalysts have been developed. Recent theoretical calculations and experimental studies in terms of water electrolysis and fuel cell technology suggest effective ways to cope with current major challenges of cost and durability of oxygen electrocatalysts for technical applications.

Park, Seh Kyu; Shao, Yuyan; Liu, Jun; Wang, Yong

2012-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Oxygen reduction on platinum : an EIS study  

E-Print Network [OSTI]

The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

Golfinopoulos, Theodore

2009-01-01T23:59:59.000Z

322

The Role of Oxygen in Coal Gasification  

E-Print Network [OSTI]

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

323

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

324

Composite oxygen ion transport element  

SciTech Connect (OSTI)

A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

2007-06-12T23:59:59.000Z

325

Catalyst containing oxygen transport membrane  

SciTech Connect (OSTI)

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

2012-12-04T23:59:59.000Z

326

Structure having spatially separated photo-excitable electron-hole pairs and method of manufacturing same  

DOE Patents [OSTI]

A method for producing quantum dots. The method includes cleaning an oxide substrate and separately cleaning a metal source. The substrate is then heated and exposed to the source in an oxygen environment. This causes metal oxide quantum dots to form on the surface of the substrate.

Liang, Yong (Richland, WA); Daschbach, John L. (Richland, WA); Su, Yali (Richland, WA); Chambers, Scott A. (Kennewick, WA)

2006-08-22T23:59:59.000Z

327

Structure having spatially separated photo-excitable electron-hole pairs and method of manufacturing same  

DOE Patents [OSTI]

A method for producing quantum dots. The method includes cleaning an oxide substrate and separately cleaning a metal source. The substrate is then heated and exposed to the source in an oxygen environment. This causes metal oxide quantum dots to form on the surface of the substrate.

Liang, Yong [Richland, WA; Daschbach, John L [Richland, WA; Su, Yali [Richland, WA; Chambers, Scott A [Kennewick, WA

2003-03-18T23:59:59.000Z

328

Oxygen and nitrogen diffusion in ?-hafnium from first principles  

SciTech Connect (OSTI)

We use a combination of density functional theory and multistate diffusion formalism to analyze the diffusion of oxygen and nitrogen in technologically important hafnium metal. Comparing the local density approximation and the Perdew-Burke-Ernzerhof version of the generalized gradient approximation, we find that a better description of the hafnium lattice in the latter results in the correct sequence of stable and transition states for oxygen interstitials leading to essentially quantitative agreement with experiment. For oxygen diffusion, we find an isotropic temperature-dependent diffusion coefficient of D=0.082e{sup ?2.04/k{sub B}T}cm{sup 2}s{sup ?1} utilizing interstitial sites with hexahedral and octahedral coordination. For the diffusivity of nitrogen, we find that an additional stable interstitial site, the crowdion site, exists and that the diffusion coefficient is D=0.15e{sup ?2.68/k{sub B}T}cm{sup 2}s{sup ?1}. Our results also reproduce the experimental observation that nitrogen diffusivity is lower than that of oxygen in hafnium.

O'Hara, Andrew; Demkov, Alexander A., E-mail: demkov@physics.utexas.edu [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States)

2014-05-26T23:59:59.000Z

329

Separation of gases through gas enrichment membrane composites  

DOE Patents [OSTI]

Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

Swedo, R.J.; Kurek, P.R.

1988-07-19T23:59:59.000Z

330

AN ELECTRICAL OXYGEN-TEMPERATURE METER  

E-Print Network [OSTI]

426 AN ELECTRICAL OXYGEN-TEMPERATURE METER FOR FISHERY BIOLOGISTS SEP 2 1196: vuUiJo HIM. . SPECIAL and Wildlife, Daniel H. Janzen, Director AN ELECTRICAL OXYGEN-TEMPERATURE METER FOR FISHERY BIOLOGISTS -temperature meter 11 Maintenance and trouble -shooting 12 #12;AN ELECTRICAL OXYGEN-TEMPERATURE METER

331

Effects of oxygen on fracturing fluids  

SciTech Connect (OSTI)

The stability of polysaccharide gels at high temperature is limited by such factors as pH, mechanical degradation, and oxidants. Oxygen is unavoidably placed in fracturing fluids through dissolution of air. To prevent premature degradation of the fracturing fluid by this oxidant, oxygen scavengers are commonly used. In this paper, the effects of oxygen and various oxygen scavengers on gel stability will be presented. Mechanical removal of oxygen resulted in surprisingly stable fracturing gels at 275 F. However, chemical removal of oxygen gave mixed results. Test data from sodium thiosulfate, sodium sulfite, and sodium erythorbate used as oxygen scavengers/gel stabilizers showed that the efficiency of oxygen removal from gels did not directly coincide with the viscosity retention of the gel, and large excesses of additives were necessary to provide optimum gel stabilization. The inability of some oxygen scavengers to stabilize the gel was the result of products created from the interaction of oxygen with the oxygen scavenger, which in turn, produced species that degraded the gel. The ideal oxygen scavenger should provide superior gel stabilization without creating detrimental side reaction products. Of the materials tested, sodium thiosulfate appeared to be the most beneficial.

Walker, M.L.; Shuchart, C.E.; Yaritz, J.G.; Norman, L.R.

1995-11-01T23:59:59.000Z

332

Oxygen Detection via Nanoscale Optical Indicators  

E-Print Network [OSTI]

Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

Ghosh, Ruby N.

333

8, 22252248, 2008 Detection of oxygen  

E-Print Network [OSTI]

ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

Paris-Sud XI, Université de

334

The Mechanisms of Oxygen Reduction and Evolution Reactions in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

335

Oxygen consumption of bovine granulosa cells in vitro.  

E-Print Network [OSTI]

??The oxygen consumption rate of granulosa cells is considered to be a key determinant of oocyte oxygenation in follicles. The oxygen status of the oocyte… (more)

Li, Dongxing

2012-01-01T23:59:59.000Z

336

Activated Carbon Composites for Air Separation  

SciTech Connect (OSTI)

Coal-derived synthesis gas is a potential major source of hydrogen for fuel cells. Oxygen-blown coal gasification is an efficient approach to achieving the goal of producing hydrogen from coal, but a cost-effective means of enriching O2 concentration in air is required. A key objective of this project is to assess the utility of a system that exploits porous carbon materials and electrical swing adsorption to produce an O2-enriched air stream for coal gasification. As a complement to O2 and N2 adsorption measurements, CO2 was used as a more sensitive probe molecule for the characterization of molecular sieving effects. To further enhance the potential of activated carbon composite materials for air separation, work was implemented on incorporating a novel twist into the system; namely the addition of a magnetic field to influence O2 adsorption, which is accompanied by a transition between the paramagnetic and diamagnetic states. The preliminary findings in this respect are discussed.

Baker, Frederick S [ORNL; Contescu, Cristian I [ORNL; Tsouris, Costas [ORNL; Burchell, Timothy D [ORNL

2011-09-01T23:59:59.000Z

337

Advanced Nanostructured Molecular Sieves for Energy Efficient Industrial Separations  

SciTech Connect (OSTI)

Due to the very small relative volatility difference between propane and propylene, current propane/propylene separation by distillation requires very tall distillation towers (150-250 theoretical plates) and large reflux ratios (up to 15), which is considered to be the most energy consuming large-scale separation process. Adsorptive separation processes are widely considered to be more energy-efficient alternatives to distillation. However, slow diffusion kinetics/mass transport rate through the adsorbent bed often limits the performance of such processes, so further improvements are possible if intra-particle mass transfer rates can be improved. Rive Technology, Inc. is developing and commercializing its proprietary mesoporous zeolite technology for catalysis and separation. With well-controlled intracrystalline mesoporosity, diffusion kinetics through such mesoporous zeolite based catalysts is much improved relative to conventional zeolites, leading to significantly better product selectivity. This 'proof-of-principle' project (DE-EE0003470) is intended to demonstrate that Rive mesoporous zeolite technology can be extended and applied in adsorptive propane/propylene separation and lead to significant energy saving compared to the current distillation process. In this project, the mesoporous zeolite Y synthesis technology was successfully extended to X and A zeolites that are more relevant to adsorbent applications. Mesoporosity was introduced to zeolite X and A for the first time while maintaining adequate adsorption capacity. Zeolite adsorbents were tested for liquid phase separation performance using a pulse flow test unit and the test results show that the separation selectivity of the mesoporous zeolite adsorbent is much closer to optimal for a Simulated Moving Bed (SMB) separation process and the enhanced mesoporosity lead to >100% increase of overall mass transport rate for propane and propylene. These improvements will significantly improve the performance of an adsorptive separation unit for propane/propylene separation compared with traditional zeolite adsorbents. The enhanced transport will allow for more efficient utilization of a given adsorbent inventory by reducing process cycle time, allowing a faster production rate with a fixed amount of adsorbent or smaller adsorbent inventory at a fixed production rate. Smaller adsorbent inventory would also lead to significant savings in the capital cost due to smaller footprint of the equipment. Energy consumption calculation, based on the pulse test results for rived NaX zeolite adsorbent, of a hypothetical moderate-scale SMB propane/propylene separation plant that processes 6000 BPSD refinery grade propylene (70% propylene) will consume about 60-80% less energy (both re-boiler and condenser duties) compared to a C3 splitter that process the same amount of feed. This energy saving also translates to a reduction of 30,000-35,000 tons of CO2 emission per year at this moderate processing rate. The enhancement of mass transport achievable by introduction of controlled mesoporosity to the zeolite also opens the door for the technology to be applied to several other adsorption separation processes such as the separation of xylene isomers by SMB, small- and large scale production of O2/N2 from air by pressure swing adsorption, the separation of CO2 from natural gas at natural gas wellheads, and the purification of ultra-high purity H2 from the off gas produced by steam-methane-reforming.

Kunhao Li, Michael Beaver

2012-01-18T23:59:59.000Z

338

Nitrogen/oxygen separations in metal-organic frameworks for clean fossil  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell BatteriesArchives Events/News

339

Technology Catalogue. First edition  

SciTech Connect (OSTI)

The Department of Energy`s Office of Environmental Restoration and Waste Management (EM) is responsible for remediating its contaminated sites and managing its waste inventory in a safe and efficient manner. EM`s Office of Technology Development (OTD) supports applied research and demonstration efforts to develop and transfer innovative, cost-effective technologies to its site clean-up and waste management programs within EM`s Office of Environmental Restoration and Office of Waste Management. The purpose of the Technology Catalogue is to provide performance data on OTD-developed technologies to scientists and engineers assessing and recommending technical solutions within the Department`s clean-up and waste management programs, as well as to industry, other federal and state agencies, and the academic community. OTD`s applied research and demonstration activities are conducted in programs referred to as Integrated Demonstrations (IDs) and Integrated Programs (IPs). The IDs test and evaluate.systems, consisting of coupled technologies, at specific sites to address generic problems, such as the sensing, treatment, and disposal of buried waste containers. The IPs support applied research activities in specific applications areas, such as in situ remediation, efficient separations processes, and site characterization. The Technology Catalogue is a means for communicating the status. of the development of these innovative technologies. The FY93 Technology Catalogue features technologies successfully demonstrated in the field through IDs and sufficiently mature to be used in the near-term. Technologies from the following IDs are featured in the FY93 Technology Catalogue: Buried Waste ID (Idaho National Engineering Laboratory, Idaho); Mixed Waste Landfill ID (Sandia National Laboratories, New Mexico); Underground Storage Tank ID (Hanford, Washington); Volatile organic compound (VOC) Arid ID (Richland, Washington); and VOC Non-Arid ID (Savannah River Site, South Carolina).

Not Available

1994-02-01T23:59:59.000Z

340

Clean coal technologies: A business report  

SciTech Connect (OSTI)

The book contains four sections as follows: (1) Industry trends: US energy supply and demand; The clean coal industry; Opportunities in clean coal technologies; International market for clean coal technologies; and Clean Coal Technology Program, US Energy Department; (2) Environmental policy: Clean Air Act; Midwestern states' coal policy; European Community policy; and R D in the United Kingdom; (3) Clean coal technologies: Pre-combustion technologies; Combustion technologies; and Post-combustion technologies; (4) Clean coal companies. Separate abstracts have been prepared for several sections or subsections for inclusion on the data base.

Not Available

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Lycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic  

E-Print Network [OSTI]

, quenching singlet oxygen generated during the water-splitting process of photo- synthesis (10, 11). VariousLycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic photosynthetic cyclase. Instead, we show that CruP aids in preventing accumulation of reactive oxygen species (ROS

Wurtzel, Eleanore

342

Experimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine Laser  

E-Print Network [OSTI]

state I. Conventionally, a two-phase (gas-liquid) chemistry singlet oxygen generator (SOG) producesExperimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine of the electric discharge iodine laser continues, the role of oxygen atoms downstream of the discharge region

Carroll, David L.

343

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as  

E-Print Network [OSTI]

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

344

Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes  

E-Print Network [OSTI]

1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

Paris-Sud XI, Université de

345

Technology Assessment  

Broader source: Energy.gov (indexed) [DOE]

Roll to Roll (R2R) Processing 1 Technology Assessment 2 3 Contents 4 1. Introduction to the TechnologySystem ......

346

Hydroprocessing Bio-oil and Products Separation for Coke Production  

SciTech Connect (OSTI)

Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

2013-04-01T23:59:59.000Z

347

Savannah River Technology Center monthly report, January 1994  

SciTech Connect (OSTI)

This is the monthly progress report for the Savannah River Technology Center, which covers the following areas of interest, Tritium, Separation processes, Environmental Issues, and Waste Management.

Not Available

1994-01-01T23:59:59.000Z

348

N:\\redesign\\guides\\Food Technology-Food Engineering.doc 1 A Beginning Finding Aid to Materials  

E-Print Network [OSTI]

, J. Henry Oxygen by the ton Oxygen ­ Manufacture 12:22 March 1947 Parker, Milton E. Food technologyN:\\redesign\\guides\\Food Technology-Food Engineering.doc 1 A Beginning Finding Aid to Materials in the IIT Archives Related to Food Technology Index of IIT Archives Acc. No. 1998.149/News (Press) Releases

Heller, Barbara

349

Sandia technology & entrepreneurs improve Lasik  

SciTech Connect (OSTI)

Former Sandian Dan Neal started his company, WaveFront Sciences, based on wavefront sensing metrology technologies licensed from Sandia National Laboratories and by taking advantage of its Entrepreneurial Separation to Transfer Technology (ESTT) program. Abbott Medical Optics since acquired WaveFront and estimates that one million patients have improved the quality of their vision thanks to its products. ESTT is a valuable tool which allows Sandia to transfer technology to the private sector and Sandia employees to leave the Labs in order to start up new technology companies or help expand existing companies.

Neal, Dan; Turner, Tim

2013-11-21T23:59:59.000Z

350

Sandia technology & entrepreneurs improve Lasik  

ScienceCinema (OSTI)

Former Sandian Dan Neal started his company, WaveFront Sciences, based on wavefront sensing metrology technologies licensed from Sandia National Laboratories and by taking advantage of its Entrepreneurial Separation to Transfer Technology (ESTT) program. Abbott Medical Optics since acquired WaveFront and estimates that one million patients have improved the quality of their vision thanks to its products. ESTT is a valuable tool which allows Sandia to transfer technology to the private sector and Sandia employees to leave the Labs in order to start up new technology companies or help expand existing companies.

Neal, Dan; Turner, Tim

2014-02-26T23:59:59.000Z

351

Energy and technology review  

SciTech Connect (OSTI)

Research activities at Lawrence Livermore National Laboratory are described in the Energy and Technology Review. This issue includes articles on measuring chromosome changes in people exposed to cigarette smoke, sloshing-ion experiments in the tandem mirror experiment, aluminum-air battery development, and a speech by Edward Teller on national defense. Abstracts of the first three have been prepared separately for the data base. (GHT)

Brown, P.S. (ed.)

1983-06-01T23:59:59.000Z

352

Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion  

SciTech Connect (OSTI)

The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

Bhavsar, Saurabh; Veser, Goetz

2013-11-06T23:59:59.000Z

353

SULFUR HEXAFLUORIDE TREATMENT OF USED NUCLEAR FUEL TO ENHANCE SEPARATIONS  

SciTech Connect (OSTI)

Reactive Gas Recycling (RGR) technology development has been initiated at Savannah River National Laboratory (SRNL), with a stretch-goal to develop a fully dry recycling technology for Used Nuclear Fuel (UNF). This approach is attractive due to the potential of targeted gas-phase treatment steps to reduce footprint and secondary waste volumes associated with separations relying primarily on traditional technologies, so long as the fluorinators employed in the reaction are recycled for use in the reactors or are optimized for conversion of fluorinator reactant. The developed fluorination via SF{sub 6}, similar to the case for other fluorinators such as NF{sub 3}, can be used to address multiple fuel forms and downstream cycles including continued processing for LWR via fluorination or incorporation into a aqueous process (e.g. modified FLUOREX) or for subsequent pyro treatment to be used in advanced gas reactor designs such metal- or gas-cooled reactors. This report details the most recent experimental results on the reaction of SF{sub 6} with various fission product surrogate materials in the form of oxides and metals, including uranium oxides using a high-temperature DTA apparatus capable of temperatures in excess of 1000{deg}C . The experimental results indicate that the majority of the fission products form stable solid fluorides and sulfides, while a subset of the fission products form volatile fluorides such as molybdenum fluoride and niobium fluoride, as predicted thermodynamically. Additional kinetic analysis has been performed on additional fission products. A key result is the verification that SF{sub 6} requires high temperatures for direct fluorination and subsequent volatilization of uranium oxides to UF{sub 6}, and thus is well positioned as a head-end treatment for other separations technologies, such as the volatilization of uranium oxide by NF{sub 3} as reported by colleagues at PNNL, advanced pyrochemical separations or traditional full recycle approaches. Based on current results of the research at SRNL on SF{sub 6} fluoride volatility for UNF separations, SF{sub 6} treatment renders all anticipated volatile fluorides studied to be volatile, and all non-volatile fluorides studied to be non-volatile, with the notable exception of uranium oxides. This offers an excellent opportunity to use this as a head-end separations treatment process because: 1. SF{sub 6} can be used to remove volatile fluorides from a UNF matrix while leaving behind uranium oxides. Therefore an agent such as NF{sub 3} should be able to very cleanly separate a pure UF{sub 6} stream, leaving compounds in the bottoms such as PuF{sub 4}, SrF{sub 2} and CsF after the UNF matrix has been pre-treated with SF{sub 6}. 2. Due to the fact that the uranium oxide is not separated in the volatilization step upon direct contact with SF{sub 6} at moderately high temperatures (? 1000{deg}C), this fluoride approach may be wellsuited for head-end processing for Gen IV reactor designs where the LWR is treated as a fuel stock, and it is not desired to separate the uranium from plutonium, but it is desired to separate many of the volatile fission products. 3. It is likely that removal of the volatile fission products from the uranium oxide should simplify both traditional and next generation pyroprocessing techniques. 4. SF{sub 6} treatment to remove volatile fission products, with or without treatment with additional fluorinators, could be used to simplify the separations of traditional aqueous processes in similar fashion to the FLUOREX process. Further research should be conducted to determine the separations efficiency of a combined SF{sub 6}/NF{sub 3} separations approach which could be used as a stand-alone separations technology or a head-end process.

Gray, J.; Torres, R.; Korinko, P.; Martinez-Rodriguez, M.; Becnel, J.; Garcia-Diaz, B.; Adams, T.

2012-09-25T23:59:59.000Z

354

Multi-Spectral Detection of Microfluidic Separation Products.  

SciTech Connect (OSTI)

The objectives of this project were to develop a new scientific tool for studies of chemical processes at the single molecule level, and to provide enhanced capabilities for multiplexed, ultrasensitive separations and immunoassays. We have combined microfluidic separation techniques with our newly developed technology for spectrally and temporally resolved detection of single molecules. The detection of individual molecules can reveal fluctuations in molecular conformations, which are obscured in ensemble measurements, and allows detailed studies of reaction kinetics such as ligand or antibody binding. Detection near the single molecule level also enables the use of correlation techniques to extract information, such as diffusion rates, from the fluorescence signal. The micro-fluidic technology offers unprecedented control of the chemical environment and flow conditions, and affords the unique opportunity to study biomolecules without immobilization. For analytical separations, the fluorescence lifetime and spectral resolution of the detection makes it possible to use multiple parameters for identification of separation products to improve the certainty of identification. We have successfully developed a system that can measure fluorescence spectra, lifetimes and diffusion constants of the components of mixtures separated in a microfluidic electrophoresis chip.

Hayden, Carl C.; Meagher, Robert

2007-12-01T23:59:59.000Z

355

Modeling and Design of Material Separation Systems with Applications to Recycling  

E-Print Network [OSTI]

Material separation technology is critical to the success of the material recycling industry. End-of-life products, post-consumer waste, industrial excess, or otherwise collected materials for reuse are typically mixed ...

Wolf, Malima Isabelle, 1981-

2011-01-01T23:59:59.000Z

356

Size based separation of submicron nonmagnetic particles through magnetophoresis in structured obstacle arrays  

E-Print Network [OSTI]

The focus of this work was on developing a novel scalable size based separation technology for nonmagnetic particles in the submicron size range utilizing magnetophoretic forces. When a nonmagnetic particle is immersed in ...

Annavarapu, V. N. Ravikanth (Venkata Nagandra Ravikanth)

2010-01-01T23:59:59.000Z

357

Surface-Modified Membrane as A Separator for Lithium-Ion Polymer Battery  

E-Print Network [OSTI]

This paper describes the fabrication of novel modified polyethylene (PE) membranes using plasma technology to create high-performance and cost-effective separator membranes for practical applications in lithium-ion polymer ...

Kim, Jun Young

358

Plutonium Chemistry in the UREX+ Separation Processes  

SciTech Connect (OSTI)

The project "Plutonium Chemistry in the UREX+ Separation Processes” is led by Dr. Alena Paulenova of Oregon State University under collaboration with Dr. George Vandegrift of ANL and Dr. Ken Czerwinski of the University of Nevada at Las Vegas. The objective of the project is to examine the chemical speciation of plutonium in UREX+ (uranium/tributylphosphate) extraction processes for advanced fuel technology. Researchers will analyze the change in speciation using existing thermodynamics and kinetic computer codes to examine the speciation of plutonium in aqueous and organic phases. They will examine the different oxidation states of plutonium to find the relative distribution between the aqueous and organic phases under various conditions such as different concentrations of nitric acid, total nitrates, or actinide ions. They will also utilize techniques such as X-ray absorbance spectroscopy and small-angle neutron scattering for determining plutonium and uranium speciation in all separation stages. The project started in April 2005 and is scheduled for completion in March 2008.

ALena Paulenova; George F. Vandegrift, III; Kenneth R. Czerwinski

2009-10-01T23:59:59.000Z

359

Development of an electrochemical hydrogen separator  

SciTech Connect (OSTI)

The EHS is an electrochemical hydrogen separator based on the uniquely reversible nature of hydrogen oxidation-reduction reactions in electrochemical systems. The principle and the hardware concept are shown in Figure 1. Hydrogen from the mixed gas stream is oxidized to H{sup +} ions, transported through a cation transport electrolyte membrane (matrix) under an applied electric field and discharged in a pure hydrogen state on the cathode. The cation transfer electrolyte membrane provides a barrier between the feed and product gases. The EHS design is an offshoot of phosphoric acid fuel cell development. Although any proton transfer electrolyte can be used, the phosphoric acid based system offers a unique advantage because its operating temperature of {approximately}200{degree}C makes it tolerant to trace CO and also closely matches the water-shift reactor exit gas temperature ({approximately}250{degree}C). Hydrogen-containing streams in coal gasification systems have large carbon monoxide contents. For efficient hydrogen recovery, most of the CO must be converted to hydrogen by the low temperature water-shift reaction (Figure 2). Advanced coal gasification and gas separation technologies offer an important pathway to the clean utilization of coal resources.

Abens, S.; Fruchtman, J.; Kush, A.

1993-09-01T23:59:59.000Z

360

Actinide Lanthanide Separation Process – ALSEP  

SciTech Connect (OSTI)

Separation of the minor actinides (Am, Cm) from the lanthanides at an industrial scale remains a significant technical challenge for closing the nuclear fuel cycle. To increase the safety of used nuclear fuel (UNF) reprocessing, as well as reduce associated costs, a novel solvent extraction process has been developed. The process allows for partitioning minor actinides, lanthanides and fission products following uranium/plutonium/neptunium removal; minimizing the number of separation steps, flowsheets, chemical consumption, and waste. This new process, Actinide Lanthanide SEParation (ALSEP), uses an organic solvent consisting of a neutral diglycolamide extractant, either N,N,N',N'-tetra(2 ethylhexyl)diglycolamide (T2EHDGA) or N,N,N',N'-tetraoctyldiglycolamide (TODGA), and an acidic extractant 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]), dissolved in an aliphatic diluent (e.g. n-dodecane). The An/Ln co-extraction is conducted from moderate-to-strong nitric acid, while the selective stripping of the minor actinides from the lanthanides is carried out using a polyaminocarboxylic acid/citrate buffered solution at pH anywhere between 3 and 4.5. The extraction and separation of the actinides from the fission products is very effective in a wide range of HNO3 concentrations and the minimum separation factors for lanthanide/Am exceed 30 for Nd/Am, reaching > 60 for Eu/Am under some conditions. The experimental results presented here demonstrate the great potential for a combined system, consisting of a neutral extractant such as T2EHDGA or TODGA, and an acidic extractant such as HEH[EHP], for separating the minor actinides from the lanthanides.

Gelis, Artem V.; Lumetta, Gregg J.

2014-01-29T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping  

SciTech Connect (OSTI)

Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improves the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of oxygen carriers in the system by using the high-sulfur-laden asphalt fuels. In all, the scaled-up test in 10 kW CLC facility demonstrated that the preparation method of copper-based oxygen carrier not only help to maintain its good reactivity, also largely minimize its agglomeration tendency.

Pan, Wei-Ping; Cao, Yan

2012-11-30T23:59:59.000Z

362

OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES  

E-Print Network [OSTI]

OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

Byrn, Marianne; Calvin, Melvin

1965-01-01T23:59:59.000Z

363

Reduced gravity rankine cycle design and optimization with passive vortex phase separation  

E-Print Network [OSTI]

. Potential drawbacks to the technology in a reduced gravity environment include two-phase fluid management processes such as liquid-vapor phase separation. The most critical location for phase separation is at the boiler exit where only vapor must be sent...

Supak, Kevin Robert

2009-05-15T23:59:59.000Z

364

Hydrogen separation membranes annual report for FY 2006.  

SciTech Connect (OSTI)

The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry. This goal of this project is to develop two types of dense ceramic membrane for producing hydrogen nongalvanically, i.e., without electrodes or external power supply, at commercially significant fluxes under industrially relevant operating conditions. The first type of membrane, hydrogen transport membranes (HTMs), will be used to separate hydrogen from gas mixtures such as the product streams from coal gasification, methane partial oxidation, and water-gas shift reactions. Potential ancillary uses of HTMs include dehydrogenation and olefin production, as well as hydrogen recovery in petroleum refineries and ammonia synthesis plants, the largest current users of deliberately produced hydrogen. The second type of membrane, oxygen transport membranes (OTMs), will produce hydrogen by nongalvanically removing oxygen that is generated when water dissociates at elevated temperatures. This report describes progress that was made during FY 2006 on the development of OTM and HTM materials.

Balachandran, U.; Chen, L.; Ciocco, M.; Doctor, R. D.; Dorris, S.E.; Emerson, J. E.; Fisher, B.; Lee, T. H.; Killmeyer, R. P.; Morreale,B.; Picciolo, J. J.; Siriwardane, R. V.; Song, S. J.

2007-02-05T23:59:59.000Z

365

33rd Actinide Separations Conference  

SciTech Connect (OSTI)

Welcome to the 33rd Actinide Separations Conference hosted this year by the Lawrence Livermore National Laboratory. This annual conference is centered on the idea of networking and communication with scientists from throughout the United States, Britain, France and Japan who have expertise in nuclear material processing. This conference forum provides an excellent opportunity for bringing together experts in the fields of chemistry, nuclear and chemical engineering, and actinide processing to present and discuss experiences, research results, testing and application of actinide separation processes. The exchange of information that will take place between you, and other subject matter experts from around the nation and across the international boundaries, is a critical tool to assist in solving both national and international problems associated with the processing of nuclear materials used for both defense and energy purposes, as well as for the safe disposition of excess nuclear material. Granlibakken is a dedicated conference facility and training campus that is set up to provide the venue that supports communication between scientists and engineers attending the 33rd Actinide Separations Conference. We believe that you will find that Granlibakken and the Lake Tahoe views provide an atmosphere that is stimulating for fruitful discussions between participants from both government and private industry. We thank the Lawrence Livermore National Laboratory and the United States Department of Energy for their support of this conference. We especially thank you, the participants and subject matter experts, for your involvement in the 33rd Actinide Separations Conference.

McDonald, L M; Wilk, P A

2009-05-04T23:59:59.000Z

366

Gas Separations using Ceramic Membranes  

SciTech Connect (OSTI)

This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

Paul KT Liu

2005-01-13T23:59:59.000Z

367

Separations innovative concepts: Project summary  

SciTech Connect (OSTI)

This project summary includes the results of 10 innovations that were funded under the US Department's Innovative Concept Programs. The concepts address innovations that can substantially reduce the energy used in industrial separations. Each paper describes the proposed concept, and discusses the concept's potential energy savings, market applications, technical feasibility, prior work and state of the art, and future development needs.

Lee, V.E. (ed.)

1988-05-01T23:59:59.000Z

368

Integration of advanced nuclear materials separation processes  

SciTech Connect (OSTI)

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the structure, solubility, and stability of the key plutonium complexes. Installation and testing of flow and batch hydrothermal reactors in the Plutonium Facility was accomplished. Preliminary testing with Pu-contaminated organic solutions gave effluent solutions that readily met discard requirements. A new effort in FY 1998 will build on these promising initial results.

Jarvinen, G.D.; Worl, L.A.; Padilla, D.D.; Berg, J.M.; Neu, M.P.; Reilly, S.D.; Buelow, S.

1998-12-31T23:59:59.000Z

369

Savannah River Technology Center monthly report  

SciTech Connect (OSTI)

This document contains many small reports from personnel at the technology center under the umbrella topics of reactors, tritium, separations, environment, waste management, and general engineering. Progress and accomplishments are given.

Not Available

1992-10-01T23:59:59.000Z

370

Nuclear Technology Programs  

SciTech Connect (OSTI)

This document reports on the work done by the Nuclear Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April--September 1988. These programs involve R D in three areas: applied physical chemistry, separation science and technology, and nuclear waste management. The work in applied physical chemistry includes investigations into the processes that control the release and transport of fission products under accident-like conditions, the thermophysical properties of selected materials in environments simulating those of fusion energy systems. In the area of separation science and technology, the bulk of the effort is concerned with developing and implementing processes for the removal and concentration of actinides from waste streams contaminated by transuranic elements. Another effort is concerned with examining the feasibility of substituting low-enriched for high-enriched uranium in the production of fission-product {sup 99}Mo. In the area of waste management, investigations are underway on the performance of materials in projected nuclear repository conditions to provide input to the licensing of the nation's high-level waste repositories.

Harmon, J.E. (ed.)

1990-10-01T23:59:59.000Z

371

Identification of an Archean marine oxygen oasis  

SciTech Connect (OSTI)

The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

Riding, Dr Robert E [University of Tennessee (UT); Fralick, Dr Philip [Lakehead University, Canada; Liang, Liyuan [ORNL

2014-01-01T23:59:59.000Z

372

Myocardial Reloading after Extracorporeal Membrane Oxygenation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Protein Synthesis. Abstract: Extracorporeal membrane oxygenation (ECMO) unloads the heart providing a bridge to recovery in children after myocardial stunning. Mortality after...

373

Isotope separation by laser means  

DOE Patents [OSTI]

A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

1982-06-15T23:59:59.000Z

374

Noise suppressing capillary separation system  

DOE Patents [OSTI]

A noise-suppressing capillary separation system for detecting the real-time presence or concentration of an analyte in a sample is provided. The system contains a capillary separation means through which the analyte is moved, a coherent light source that generates a beam which is split into a reference beam and a sample beam that irradiate the capillary, and a detector for detecting the reference beam and the sample beam light that transmits through the capillary. The laser beam is of a wavelength effective to be absorbed by a chromophore in the capillary. The system includes a noise suppressing system to improve performance and accuracy without signal averaging or multiple scans. 13 figs.

Yeung, E.S.; Xue, Y.

1996-07-30T23:59:59.000Z

375

Efficient gas-separation process to upgrade dilute methane stream for use as fuel  

DOE Patents [OSTI]

A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Lin, Haiqing (Mountain View, CA); Thompson, Scott (Brecksville, OH); Daniels, Ramin (San Jose, CA)

2012-03-06T23:59:59.000Z

376

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

Tsuo, Y. Simon (Lakewood, CO)

1991-01-01T23:59:59.000Z

377

Convex polytopes and quantum separability  

SciTech Connect (OSTI)

We advance a perspective of the entanglement issue that appeals to the Schlienz-Mahler measure [Phys. Rev. A 52, 4396 (1995)]. Related to it, we propose a criterium based on the consideration of convex subsets of quantum states. This criterium generalizes a property of product states to convex subsets (of the set of quantum states) that is able to uncover an interesting geometrical property of the separability property.

Holik, F.; Plastino, A. [Departamento de Matematica - Ciclo Basico Comun, Universidad de Buenos Aires - Pabellon III, Ciudad Universitaria, Buenos Aires, Argentina and CONICET (Argentina); National University La Plata and CONICET IFLP-CCT, C.C. 727 - 1900 La Plata (Argentina)

2011-12-15T23:59:59.000Z

378

Supported liquid membrane electrochemical separators  

DOE Patents [OSTI]

Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

1986-01-01T23:59:59.000Z

379

Guayule resin separation and purification  

E-Print Network [OSTI]

fraction and reducing the presence of these terpenes to practically non-detectable levels in the polar fraction. A single component, as identified by gas chromatograph (GC) was also effectively extracted from the Texas A&M resins. Saponification..., using an FID Solvent fractionation of the Firestone resin between methanol and hexane was also apparently effective in separating the low molecular weight rubber. Figure 16 and Figure 17 show the gas chromatographs of the bottom phase (fraction "a...

Bajwa, Mohinder P.S.

1992-01-01T23:59:59.000Z

380

Subtask 3.12 - Oxygen-Fired CFBC  

SciTech Connect (OSTI)

Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

Douglas Hajicek; Mark Musich; Ann Henderson

2007-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Separation of CO2 from flue gas using electrochemical cells  

SciTech Connect (OSTI)

ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

2010-06-01T23:59:59.000Z

382

Anisotropic membranes for gas separation  

DOE Patents [OSTI]

A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.

Gollan, Arye Z. (Newton, MA)

1987-01-01T23:59:59.000Z

383

Anisotropic membranes for gas separation  

DOE Patents [OSTI]

A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7--25 C and then air dried at ambient temperature, typically 10--30 C. 2 figs.

Gollan, A.Z.

1987-07-21T23:59:59.000Z

384

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations  

E-Print Network [OSTI]

. Current targets of cost and durability necessitate solid oxide fuel cells to operate in the intermediateOxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights oxide fuel cells are of technological interest as they offer high efficiency for energy conversion

Yildiz, Bilge

385

Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols  

E-Print Network [OSTI]

Rare sulfur and triple oxygen isotope geochemistry of volcanogenic sulfate aerosols I.N. Bindeman a of Technology, Pasadena, CA, USA c Department of Earth and Planetary Sciences, McGill University, Montreal, Que., Canada d Department of Geology and Earth System Science Interdisciplinary Center, University of Maryland

Bindeman, Ilya N.

386

Oxygen demand for the stabilization of the organic fraction of municipal solid waste in passively aerated bioreactors  

SciTech Connect (OSTI)

Highlights: • The use of an passively aerated reactor enables effective stabilization of OFMSW. • Convective air flow does not inhibit the aerobic stabilization of waste. • The use of an passively aerated reactor reduces the heat loss due to convection. • The volume of supplied air exceeds 1.7–2.88 times the microorganisms demand. - Abstract: Conventional aerobic waste treatment technologies require the use of aeration devices that actively transport air through the stabilized waste mass, which greatly increases operating costs. In addition, improperly operated active aeration systems, may have the adverse effect of cooling the stabilized biomass. Because active aeration can be a limiting factor for the stabilization process, passive aeration can be equally effective and less expensive. Unfortunately, there are few reports documenting the use of passive aeration systems in municipal waste stabilization. There have been doubts raised as to whether a passive aeration system provides enough oxygen to the organic matter mineralization processes. In this paper, the effectiveness of aeration during aerobic stabilization of four different organic fractions of municipal waste in a reactor with an integrated passive ventilation system and leachate recirculation was analyzed. For the study, four fractions separated by a rotary screen were chosen. Despite the high temperatures in the reactor, the air flow rate was below 0.016 m{sup 3}/h. Using Darcy’s equation, theoretical values of the air flow rate were estimated, depending on the intensity of microbial metabolism and the amount of oxygen required for the oxidation of organic compounds. Calculations showed that the volume of supplied air exceeded the microorganisms demand for oxidation and endogenous activity by 1.7–2.88-fold.

Kasinski, Slawomir, E-mail: slawomir.kasinski@uwm.edu.pl; Wojnowska-Baryla, Irena

2014-02-15T23:59:59.000Z

387

Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system  

E-Print Network [OSTI]

Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

Low, Clarke Alan

2008-01-01T23:59:59.000Z

388

Apparatus and method for separating constituents  

DOE Patents [OSTI]

A centrifugal separator apparatus and method for improving the efficiency of the separation of constituents in a fluid stream. A cyclone separator includes an assembly for separately discharging both constituents through the same end of the separator housing. A rotary separator includes a rotary housing having a baffle disposed therein for minimizing the differential rotational velocities of the constituents in the housing, thereby decreasing turbulence, and increasing efficiency. The intensity of the centrifugal force and the time which the constituents reside within the housing can be independently controlled to improve efficiency of separation.

Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

1992-01-01T23:59:59.000Z

389

PHYSICAL REVIEW B 84, 035212 (2011) Intrinsic stoichiometry and oxygen-induced p-type conductivity of pyrite FeS2  

E-Print Network [OSTI]

PHYSICAL REVIEW B 84, 035212 (2011) Intrinsic stoichiometry and oxygen-induced p-type conductivity Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA 2 Center and induces p-type conductivity. At the experimental oxygen impurity concentration, the hole concentration

Ceder, Gerbrand

390

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen  

E-Print Network [OSTI]

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

Sibener, Steven

391

Department of Engineering Technology Technology Education  

E-Print Network [OSTI]

Department of Engineering Technology Technology Education A Teacher Education Program New Jersey Institute of Technology #12;WHAT WILL YOU LEARN? Technology teachers teach problem-based learning utilizing math, science and technology principles. Technological studies involve students: · Designing

Bieber, Michael

392

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network [OSTI]

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, shielded metal arc, self-shielded metal arc, and submerged arc welding are reviewed. Calcu- lations upon heating is also discussed. Introduction Oxygen and nitrogen ~ontamination of weld metal

Eagar, Thomas W.

393

Continuation of Crosscutting Technology Development at Cast  

SciTech Connect (OSTI)

This Final Technical Report describes progress made on the sub-projects awarded in the Cooperative Agreement DE-FC26-05NT42457: Continuation of Crosscutting Technology Development at Center for Advanced Separation Technologies (CAST). The final reports for each sub-project are attached in the appendix. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: a) Solid-solid separation b) Solid-liquid separation c) Chemical/Biological Extraction d) Modeling and Control, and e) Environmental Control.

Yoon, Roe-Hoan

2012-03-31T23:59:59.000Z

394

Influence of geometry on liquid oxygen magnetohydrodynamics  

SciTech Connect (OSTI)

Magnetic fluid actuators have performed well in industrial applications, but have a limited temperature range due to the freezing point of the carrier fluid. Liquid oxygen (LOX) presents a pure, paramagnetic fluid suitable for use in a cryogenic magnetic fluid system; therefore, it is a potential solution to increasing the thermal range of magnetic fluid technology without the need for magnetic particles. The current study presents experimental work regarding the influence of geometry on the dynamics of a LOX slug in a 1.9 mm quartz tube when pulsed by a solenoid in a closed volume. A numerical analysis calculated the optimal solenoid geometry and balanced the magnetic, damping, and pressure forces to determine optimal slug lengths. Three configurations comprised the experiment: (1) a 24-gauge wire solenoid with an optimized 2.7 cm length slug, (2) a 30-gauge wire solenoid with an optimized 1.3 cm length slug, and (3) a 30-gauge wire solenoid with a nonoptimized 2.5 cm length slug. Typically, the hydrodynamic breakdown limit is calculated and used to determine the system range; however the experiment showed that the hydrodynamic breakdown limit was never reached by the slug. This implied that, instead, the system range should factor in a probabilistic risk of failure calculated as a function of the induced pressure change from its oscillations. The experimental data were also used to establish a nondimensional relationship between the maximum displacement and initial magnetic pressure on the slug. The average initial velocity of the slug was found to be proportional to the initial magnetic pressure, Mason number, and slug length. The results of this study can be used in the design and optimization of a LOX fluid system for space or low-temperature applications. (author)

Boulware, Jeffrey C.; Ban, Heng [Department of Mechanical and Aerospace Engineering, Utah State University, 4130 Old Main Hill, Logan, UT 84322-4130 (United States); Jensen, Scott; Wassom, Steve [Space Dynamics Laboratory, Utah State University Research Foundation, 1695 North Research Park Way, North Logan, UT 84341 (United States)

2010-11-15T23:59:59.000Z

395

Proceedings of the First Hanford Separation Science Workshop  

SciTech Connect (OSTI)

The First Hanford Separation Science Workshop, sponsored by PNL had two main objectives: (1) assess the applicability of available separation methods for environmental restoration and for minimization, recovery, and recycle of mixed and radioactive mutes; and (2) identify research needs that must be addressed to create new or improved technologies. The information gathered at this workshop not only applies to Hanford but could be adapted to DOE facilities throughout the nation as well. These proceedings have been divided into three components: Background and Introduction to the Problem gives an overview of the history of the Site and the cleanup mission, including waste management operations, past disposal practices, current operations, and plans for the future. Also included in this section is a discussion of specific problems concerning the chemistry of the Hanford wastes. Separation Methodologies contains the papers given at the workshop by national experts in the field of separation science regarding the state-of-the-art of various methods and their applicability/adaptability to Hanford. Research Needs identifies further research areas developed in working group sessions. Individual papers are indexed separately.

Not Available

1993-05-01T23:59:59.000Z

396

Distributed Energy Technology Characterization (Desiccant Technologies...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Characterization (Desiccant Technologies), January 2004 Distributed Energy Technology Characterization (Desiccant Technologies), January 2004 The purpose of this report is to...

397

Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates  

SciTech Connect (OSTI)

Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

Zhao, Y.; Xu, Q.; Cheah, S.

2013-01-01T23:59:59.000Z

398

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

399

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

400

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Separations and safeguards model integration.  

SciTech Connect (OSTI)

Research and development of advanced reprocessing plant designs can greatly benefit from the development of a reprocessing plant model capable of transient solvent extraction chemistry. This type of model can be used to optimize the operations of a plant as well as the designs for safeguards, security, and safety. Previous work has integrated a transient solvent extraction simulation module, based on the Solvent Extraction Process Having Interaction Solutes (SEPHIS) code developed at Oak Ridge National Laboratory, with the Separations and Safeguards Performance Model (SSPM) developed at Sandia National Laboratory, as a first step toward creating a more versatile design and evaluation tool. The goal of this work was to strengthen the integration by linking more variables between the two codes. The results from this integrated model show expected operational performance through plant transients. Additionally, ORIGEN source term files were integrated into the SSPM to provide concentrations, radioactivity, neutron emission rate, and thermal power data for various spent fuels. This data was used to generate measurement blocks that can determine the radioactivity, neutron emission rate, or thermal power of any stream or vessel in the plant model. This work examined how the code could be expanded to integrate other separation steps and benchmark the results to other data. Recommendations for future work will be presented.

Cipiti, Benjamin B.; Zinaman, Owen

2010-09-01T23:59:59.000Z

402

Pyroprocessing Technologies  

E-Print Network [OSTI]

production by recycling the uranium and transuranics to fast reactors for energy production. 4 Markedly that an electrochemical process separated the desired actinides from the fission products for recycling into new fuel

Kemner, Ken

403

Results of initial operation of the Jupiter Oxygen Corporation oxy-fuel 15 MWth burner test facility  

SciTech Connect (OSTI)

Jupiter Oxygen Corporation (JOC), in cooperation with the National Energy Technology Laboratory (NETL), constructed a 15 MWth oxy-fuel burner test facility with Integrated Pollutant Removal (IPRTM) to test high flame temperature oxy-fuel combustion and advanced carbon capture. Combustion protocols include baseline air firing with natural gas, oxygen and natural gas firing with and without flue gas recirculation, and oxygen and pulverized coal firing with flue gas recirculation. Testing focuses on characterizing burner performance, determining heat transfer characteristics, optimizing CO2 capture, and maximizing heat recovery, with an emphasis on data traceability to address retrofit of existing boilers by directly transforming burner systems to oxy-fuel firing.

Thomas Ochs, Danylo Oryshchyn, Rigel Woodside, Cathy Summers, Brian Patrick, Dietrich Gross, Mark Schoenfield, Thomas Weber and Dan O'Brien

2009-04-01T23:59:59.000Z

404

Clean coal technology applications  

SciTech Connect (OSTI)

{open_quotes}Coal is a stratified rock formed of the more or less altered remains of plants (together with associated mineral matter) which flourished in past ages{hor_ellipsis} The problem of the origin and maturing of coal is complicated by the fact that every coal contains, in addition to carbon, hydrogen and oxygen, variable proportions of nitrogen and sulfur which are combined in unknown ways in the organic molecules...{close_quotes}. The challenge with coal has always been the management of its mineral matter, sulfur and nitrogen contents during use. The carbon content of fuels, including coal, is a more recent concern. With clean coal technologies, there are opportunities for ensuring the sustained use of coal for a very long time. The clean coal technologies of today are already capable of reducing, if not eliminating, harmful emissions. The technologies of the future will allow coal to be burned with greatly reduced emissions, thus eliminating the necessity to treat them after they occur.

Bharucha, N.

1993-12-31T23:59:59.000Z

405

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)  

E-Print Network [OSTI]

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

Levin, Lisa

406

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System  

E-Print Network [OSTI]

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

Carroll, David L.

407

Charge Separation Kinetics in Intact Photosystem II Core Particles Is Trap-Limited. A Picosecond Fluorescence Study  

E-Print Network [OSTI]

-induced charge separation across the membrane occurs. Eventually the oxygen-evolving complex is oxidized centers. At least two new lifetime components of 2 and 9 ps have been resolved in the kinetics by global of the equilibrated excited reaction center in intact photosystem II and have found two early radical pairs before

Roegner, Matthias

408

IS C O N SIN FUSION TECHNOLOGY INSTITUTE  

E-Print Network [OSTI]

· W IS C O N SIN · FUSION·T E CHNOLOGY · INSTITUTE FUSION TECHNOLOGY INSTITUTE UNIVERSITY Isotopes Using Inertial Electrostatic Confinement B.B. Cipiti Fusion Technology Institute University N was created using the 16 O(p,)13 N reaction from the oxygen in the water. Approximately 1.0 n

409

Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal  

SciTech Connect (OSTI)

This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

Eric P. Robertson

2007-09-01T23:59:59.000Z

410

Guidelines For Developing Low Energy Separation Processes  

E-Print Network [OSTI]

A large portion of the energy required by the process industry is consumed by separation processes. This paper discusses current engineering techniques that can be used in the development and optimization of low energy separation processes....

Bojnowski, J. H.; Hanks, D. L.

1981-01-01T23:59:59.000Z

411

Moltox™ Chemical Air Separation System-A Progress Report  

E-Print Network [OSTI]

MOLTOX~* CHEMICAL AIR SEPARATION SYSTEM - A PROGRESS REPORT Donald C. Er1ckson Energy Concepts Co. Annapo11s, Maryland W111iam R. Brown and Br1an R. Dunbobb1n A1r Products and Chem1ca1s, Inc. Allentown, Pennsy1van1a Robert G. Massey U....S. Department of Energy Wash1ngton, D.C. ABSTRACT A new low energy route to tonnage oxygen product1on, the HOLTOX~ system, 1s now commenc1ng p110t plant test1ng. The process, 1ts h1story, and potent1a1 app11cat10ns will be descr1bed, 1n add1t1on...

Erickson, D. C.; Brown, W. R.; Dunbobbin, B. R.; Massey, R. G.

412

State-of-the-art adsorption and membrane separation processes for carbon dioxide production from carbon dioxide emitting industries  

SciTech Connect (OSTI)

With the growing concern about global warming placing greater demands on improving energy efficiency and reducing CO{sub 2} emissions, the need for improving the energy intensive, separation processes involving CO{sub 2} is well recognized. The US Department of Energy estimates that the separation of CO{sub 2} represents 75% of the cost associated with its separation, storage, transport, and sequestration operations. Hence, energy efficient, CO{sub 2} separation technologies with improved economics are needed for industrial processing and for future options to capture and concentrate CO{sub 2} for reuse or sequestration. The overall goal of this review is to foster the development of new adsorption and membrane technologies to improve manufacturing efficiency and reduce CO{sub 2} emissions. This study focuses on the power, petrochemical, and other CO{sub 2} emitting industries, and provides a detailed review of the current commercial CO{sub 2} separation technologies, i.e., absorption, adsorption, membrane, and cryogenic, an overview of the emerging adsorption and membrane technologies for CO{sub 2} separation, and both near and long term recommendations for future research on adsorption and membrane technologies. Flow sheets of the principal CO{sub 2} producing processes are provided for guidance and new conceptual flow sheets with ideas on the placement of CO{sub 2} separations technologies have also been devised.

Ebner, A.D.; Ritter, J.A. [University of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering

2009-07-01T23:59:59.000Z

413

Characterization of an oxygen suspension used for intravenous infusion  

E-Print Network [OSTI]

Oxygenated fluid mixture can be used to treat critically ill patients suffering from asphyxia, lung injury, and cardiac arrest. This oxygenated fluid delivered intravenously re-oxygenates the bloodstream, allowing for more ...

Peña, Kristen Helen

2012-01-01T23:59:59.000Z

414

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

415

Blood oxygen transport and depletion : the key of consummate divers  

E-Print Network [OSTI]

and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

Meir, Jessica Ulrika

2009-01-01T23:59:59.000Z

416

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

417

Direct-write milling of diamond by a focused oxygen ion beam  

E-Print Network [OSTI]

Recent advances in focused ion beam technology have enabled high-resolution, direct-write nanofabrication using light ions. Studies with light ions to date have, however, focused on milling of materials where sub-surface ion beam damage does not inhibit device performance. Here we report on direct-write milling of single crystal diamond using a focused beam of oxygen ions. Material quality is assessed by Raman and luminescence analysis, and reveals that the damage layer generated by oxygen ions can be removed by nonintrusive post-processing methods such as localised electron beam induced chemical etching.

Martin, Aiden A; Botman, Aurelien; Toth, Milos; Aharonovich, Igor

2015-01-01T23:59:59.000Z

418

Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF  

E-Print Network [OSTI]

neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

2010-01-01T23:59:59.000Z

419

Long-term oxygen sensor implantation in the porcine subcutaneous environment  

E-Print Network [OSTI]

Membrane-­?Covered  Oxygen  Electrode.   Analytical  Microvascular  and  tissue  oxygen   distribution.  vitro  stability  of  an  oxygen  sensor.   Anal  Chem,  

Kumosa, Lucas Stefan

2011-01-01T23:59:59.000Z

420

Device for hydrogen separation and method  

DOE Patents [OSTI]

A device for hydrogen separation has a porous support and hydrogen separation material on the support. The support is prepared by heat treatment of metal microparticles, preferably of iron-based or nickel-based alloys that also include aluminum and/or yttrium. The hydrogen separation material is then deposited on the support. Preferred hydrogen separation materials include metals such as palladium, alloys, platinum, refractory metals, and alloys.

Paglieri, Stephen N. (White Rock, NM); Anderson, Iver E. (Ames, IA); Terpstra, Robert L. (Ames, IA)

2009-11-03T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

On the maximum value of the cosmic abundance of oxygen and the oxygen yield  

E-Print Network [OSTI]

We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2007-01-11T23:59:59.000Z

422

Cyclone separator having boundary layer turbulence control  

DOE Patents [OSTI]

A cyclone separator including boundary layer turbulence control that is operable to prevent undue build-up of particulate material at selected critical areas on the separator walls, by selectively varying the fluid pressure at those areas to maintain the momentum of the vortex, thereby preventing particulate material from inducing turbulence in the boundary layer of the vortical fluid flow through the separator.

Krishna, Coimbatore R. (Mt. Sinai, NY); Milau, Julius S. (Port Jefferson, NY)

1985-01-01T23:59:59.000Z

423

GEOMETRIC SOURCE SEPARATION: MERGING CONVOLUTIVE SOURCE  

E-Print Network [OSTI]

adaptive beamforming algorithms by a cross-power criteria, we gain new geometric source separation with convo- lutive blind source separation. We concentrate on cross-power spectral min- imization which is su to ambiguities in the choice of separating lters. There are in theory multiple lters that invert the room

Parra, Lucas C.

424

Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$  

E-Print Network [OSTI]

We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capaciti...

Santilli, R M

2000-01-01T23:59:59.000Z

425

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

426

Density Functional Theory Study of Oxygen Reduction Activity...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Abstract: The...

427

Selective reduction of NOx in oxygen rich environments with plasma...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

428

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

429

Oxygen detected in atmosphere of Saturn's moon Dione  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

430

Effects of Oxygen-Containing Functional Groups on Supercapacitor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular dynamics (MD)...

431

Testing Oxygen Reduction Reaction Activity with the Rotating...  

Broader source: Energy.gov (indexed) [DOE]

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

432

Isolation, Characterization of an Intermediate in an Oxygen Atom...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

433

Fractionation of Oxygen Isotopes in Phosphate during its Interactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides. Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides....

434

Direct Measurement of Oxygen Incorporation into Thin Film Oxides...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

435

Density Functional Study of the Structure, Stability and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

436

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

437

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

438

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

439

Reactive Gliosis Reactive Oxygen Species: Superoxide  

E-Print Network [OSTI]

. By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

440

Design optimization of oxygenated fluid pump  

E-Print Network [OSTI]

In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

Piazzarolo, Bruno Aiala

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen separation technologies" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Electron-impact excitation of neutral oxygen  

E-Print Network [OSTI]

Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

P. S. Barklem

2006-09-25T23:59:59.000Z

442

Electron Paramagnetic Resonance Oxygen Image Hypoxic Fraction Plus Radiation Dose Strongly Correlates With Tumor Cure in FSa Fibrosarcomas  

SciTech Connect (OSTI)

Purpose: Tumor hypoxia has long been known to produce resistance to radiation. In this study, electron paramagnetic resonance (EPR) oxygen imaging was investigated for its power to predict the success of tumor control according to tumor oxygenation level and radiation dose. Methods and Materials: A total of 34 EPR oxygen images were obtained from the legs of C3H mice bearing 0.5-cm{sup 3} FSa fibrosarcomas under both normal (air breathing) and clamped tumor conditions. Under the same conditions as those during which the images were obtained, the tumors were irradiated to a variety of doses near the FSa dose at which 50% of tumors were cured. Tumor tissue was distinguished from normal tissue using co-registration of the EPR oxygen images with spin-echo magnetic resonance imaging of the tumor and/or stereotactic localization. The tumor voxel statistics in the EPR oxygen image included the mean and median partial pressure of oxygen and the fraction of tumor voxels below the specified partial pressure of oxygen values of 3, 6, and 10 mm Hg. Bivariate logistic regression analysis using the radiation dose and each of the EPR oxygen image statistics to determine which best separated treatment failure from success. Results: The measurements of the dose at which 50% of tumors were cured were similar to those found in published data for this syngeneic tumor. Bivariate analysis of 34 tumors demonstrated that tumor cure correlated with dose (p = 0.004) and with a <10 mm Hg hypoxic fraction (p = 0.023). Conclusion: Our results have shown that, together, radiation dose and EPR image hypoxic fraction separate the population of FSa fibrosarcomas that are cured from those that fail, thus predicting curability.

Elas, Martyna [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Faculty of Biochemistry, Biophysics and Biotechnology, Jagiellonian University, Krakow (Poland); Bell, Rebecca; Hleihel, Danielle; Barth, Eugene D.; McFaul, Colin [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Haney, Chad R. [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Department of Radiology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Bielanska, Joanna; Pustelny, Katarzyna [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States); Faculty of Biochemistry, Biophysics and Biotechnology, Jagiellonian University, Krakow (Poland); Ahn, Kang-Hyun [Department of Radiation and Cellular Oncology, University of Chicago Pritzker School of Medicine, Chicago, IL (United States); Center for Electron Paramagnetic Resonance Imaging In Vivo Physiology, University of Chicago, Chicago, IL (United States)] (and others)

2008-06-01T23:59:59.000Z

443

Oxygen Enriched Combustion System Performance Study  

E-Print Network [OSTI]

}ched combustlon systems are technically, envlronmentally and economically feasible and offer significant energy savings and/or productivity improvement, and then to verify the performance of selected systems in research furnaces. Tests of several commercial... for 35 - 100 percent oxygen. The absolute levels of the NO x emissions also depended on the furnace temperature. INTRODUCTION Oxygen enriched combustion has been found to have significant energy saving potential in industrial furnace applications...

Chen, S. L.; Kwan, Y.; Abele, A. R.; Silver, L. S.; Kobayashi, H.

444

Centrifugal separator devices, systems and related methods  

DOE Patents [OSTI]

Centrifugal separator devices, systems and related methods are described. More particularly, fluid transfer connections for a centrifugal separator system having support assemblies with a movable member coupled to a connection tube and coupled to a fixed member, such that the movable member is constrained to movement along a fixed path relative to the fixed member are described. Also, centrifugal separator systems including such fluid transfer connections are described. Additionally, methods of installing, removing and/or replacing centrifugal separators from centrifugal separator systems are described.

Meikrantz, David H. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Garn, Troy G. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Macaluso, Lawrence L. (Carson City, NV)

2012-03-20T23:59:59.000Z

445

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

446

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

447

Magnetism in Lithium–Oxygen Discharge Product  

SciTech Connect (OSTI)

Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

2013-05-13T23:59:59.000Z

448

Atomic Oxygen in the Comae of Comets  

E-Print Network [OSTI]

We report on the detection of atomic oxygen lines in the spectra of 8 comets. These forbidden lines are a result of the photodissociation of the parent oxygen-bearing species directly into an excited state. We used high resolution spectra obtained at the McDonald Observatory 2.7m telescope to resolve the cometary oxygen lines from the telluric oxygen lines and from other cometary emissions. We find that the relative intensities of the two red lines (6300.304 and 6363.776A) are consistent with theory. The green line (5577.339A) has an intensity which is about 10% of the sum of the intensities of the two red lines. We show that collisional quenching may be important in the inner coma. If we assume the relative excitation rates of potential parents which have appeared in the literature, then H2O would be the parent of the cometary green oxygen line. However, those rates have been questioned. We measured the width of the three oxygen lines and find that the green line is wider than either of the two red lines. The finding of a wider line could imply a different parent for the green and red lines. However, the constancy of the green to red line flux ratio suggests the parent is the same for these lines but that the exciting photons have different energies.

Anita L. Cochran

2008-07-03T23:59:59.000Z

449

Zero Emissions Coal Syngas Oxygen Turbo Machinery  

SciTech Connect (OSTI)

Siemens Energy, Inc. (formerly Siemens Westinghouse Power Corporation) worked with Clean Energy Systems and Florida Turbine Technologies to demonstrate the commercial feasibility of advanced turbines for oxy-fuel based power systems that discharge negligible CO{sub 2} into the atmosphere. The approach builds upon ultra supercritical steam turbine and advanced gas turbine technology with the goal of attaining plant efficiencies above 50% in the 2015 timeframe. Conceptual designs were developed for baseline, near term, and long term oxy-fuel turbine cycles, representing commercial introductions of increasingly advanced thermal conditions and increasing exposure to steam-CO{sub 2} mixtures. An economic analysis and market demand study was performed by Science Applications International Corp. (SAIC), and indicated that long-term oxy-fuel turbine cycles start to look attractive in 2025 when the CO{sub 2} tax is assumed to reach $40/ ton, and by 2030 it has a clear advantage over both IGCC with sequestration and pulverized coal with sequestration. A separate risk analysis of the oxy-fuel combustor, HP turbine, re-heater, and IP turbine of the long-term cycle identified and categorized risks and proposed mitigation measures. In 2007 the program began to focus on a potential oxy-fuel turbine power generation demonstration project in the 2012 -13 time period while still maintaining a link to the requirements of the long-term oxy-syngas cycle. The SGT-900 turbine was identified as the best fit for modification into an intermediate pressure turbine (IPT) for this application. The base metals, bond coats, thermal barrier coatings (TBCs), and rotor materials used in the SGT-900 were tested for their ability to operate in the steam- CO{sub 2} environment of the oxy-fuel OFT-900. Test results indicated that these same materials would operate satisfactorily, and the plan, is to use SGT-900materials for the OFT-900. Follow-on programs for corrosion testing and evaluation of crack growth rates in oxy-fuel environments have been proposed to build on these results and provide quantifiable assessments of the effects of oxy-fuel environments on the service lives of turbine components.

Dennis Horazak

2010-12-31T23:59:59.000Z

450

FUEL CELL TECHNOLOGIES PROGRAM Technologies  

E-Print Network [OSTI]

and fuel cells offer great promise for our energy future. Fuel cell vehicles are not yet commercially, such as a hydrogen fueling station or hydrogen fuel cell vehicle. Technology validation does not certify, and the Federal Government to evaluate hydrogen fuel cell vehicle and infrastructure technologies together in real

451

Process for strontium-82 separation  

DOE Patents [OSTI]

A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed.

Heaton, Richard C. (Los Alamos, NM); Jamriska, Sr., David J. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM)

1992-01-01T23:59:59.000Z

452

Process for strontium-82 separation  

DOE Patents [OSTI]

A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed. 1 fig.

Heaton, R.C.; Jamriska, D.J. Sr.; Taylor, W.A.

1992-12-01T23:59:59.000Z

453

Separating hydrogen from coal gasification gases with alumina membranes  

SciTech Connect (OSTI)

Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

1991-01-01T23:59:59.000Z

454

Oxygen generator for medical applications (USIC)  

SciTech Connect (OSTI)

The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

Staiger, C. L.

2012-03-01T23:59:59.000Z

455

Blind Source Separation 2 Understanding Two Simultaneous Speeches by Blind Source Separation  

E-Print Network [OSTI]

Blind Source Separation 2 Understanding Two Simultaneous Speeches by Blind Source Separation) to segregate speech streams from a mixture of sounds, while the other ex- ploits Blind Source Separation the performance of Blind Source Separation by using the same three benchmarks of 500 mix- ture of two speeches

Ikeda, Shiro

456

Available Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAboutScience Program Cumulus Humilis,Technologies Available Technologies

457

A new approach to oxygen enriched high temperature blast generation  

SciTech Connect (OSTI)

When increasing fuel injection in a blast furnace in order to reduce coke consumption and/or to increase production, the blast furnace operator tries to keep similar raceway conditions, for instance, an equivalent flame temperature. To compensate for the cooling effect due to the higher injection rate, two solutions can be selected or combined: to raise the temperature of the blast and/or to increase the level of oxygen in the blast. Whatever the choice, the Blast Furnace manager will certainly try to reduce the resulting investment and operating costs to a minimum. Air Liquide and Kvaerner Davy are trying to provide a new way to address these needs by offering a new technology for blast heating. A higher blast temperature will not only allow a higher fuel injection at tuyere level, a lower coke consumption, but also a lower oxygen consumption. Air Liquide and Kvaerner Davy are now able to offer a new heat regenerator with major advantages over conventional stoves. This new device can be used as a permanent substitute for a stove, or as a temporary one during repair, or stove improvement. It can also be added to an existing set of stoves to increase the average blast temperature.

Queille, P.H.; Macauley, D.

1996-12-31T23:59:59.000Z

458

Radiation chemistry of alternative fuel oxygenates -- Substituted ethers  

SciTech Connect (OSTI)

The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.</