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Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
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1

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

2

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

3

Cupola Furnace Computer Process Model  

SciTech Connect (OSTI)

The cupola furnace generates more than 50% of the liquid iron used to produce the 9+ million tons of castings annually. The cupola converts iron and steel into cast iron. The main advantages of the cupola furnace are lower energy costs than those of competing furnaces (electric) and the ability to melt less expensive metallic scrap than the competing furnaces. However the chemical and physical processes that take place in the cupola furnace are highly complex making it difficult to operate the furnace in optimal fashion. The results are low energy efficiency and poor recovery of important and expensive alloy elements due to oxidation. Between 1990 and 2004 under the auspices of the Department of Energy, the American Foundry Society and General Motors Corp. a computer simulation of the cupola furnace was developed that accurately describes the complex behavior of the furnace. When provided with the furnace input conditions the model provides accurate values of the output conditions in a matter of seconds. It also provides key diagnostics. Using clues from the diagnostics a trained specialist can infer changes in the operation that will move the system toward higher efficiency. Repeating the process in an iterative fashion leads to near optimum operating conditions with just a few iterations. More advanced uses of the program have been examined. The program is currently being combined with an ''Expert System'' to permit optimization in real time. The program has been combined with ''neural network'' programs to affect very easy scanning of a wide range of furnace operation. Rudimentary efforts were successfully made to operate the furnace using a computer. References to these more advanced systems will be found in the ''Cupola Handbook''. Chapter 27, American Foundry Society, Des Plaines, IL (1999).

Seymour Katz

2004-12-31T23:59:59.000Z

4

AISI/DOE Advanced Process Control Program Vol. 1 of 6: Optical Sensors and Controls for Improved Basic Oxygen Furnace Operations  

SciTech Connect (OSTI)

The development of an optical sensor for basic oxygen furnace (BOF) off-gas composition and temperature in this Advanced Process Control project has been a laboratory spectroscopic method evolve into a pre-commercialization prototype sensor system. The sensor simultaneously detects an infrared tunable diode laser ITDL beam transmitted through the process off-gas directly above the furnace mouth, and the infrared greybody emission from the particulate-laden off-gas stream. Following developmental laboratory and field-testing, the sensor prototype was successfully tested in four long-term field trials at Bethlehem Steel's Sparrows Point plant in Baltimore, MD> The resulting optical data were analyzed and reveal correlations with four important process variables: (1) bath turndown temperature; (2) carbon monoxide post-combustion control; (2) bath carbon concentration; and (4) furnace slopping behavior. The optical sensor measurement of the off-gas temperature is modestly correlated with bath turndown temperature. A detailed regression analysis of over 200 heats suggests that a dynamic control level of +25 Degree F can be attained with a stand-alone laser-based optical sensor. The ability to track off-gas temperatures to control post-combustion lance practice is also demonstrated, and may be of great use in optimizing post-combustion efficiency in electric furnace steelmaking operations. In addition to the laser-based absorption spectroscopy data collected by this sensor, a concurrent signal generated by greybody emission from the particle-laden off-gas was collected and analyzed. A detailed regression analysis shows an excellent correlation of a single variable with final bath turndown carbon concentration. Extended field trials in 1998 and early 1999 show a response range from below 0.03% to a least 0.15% carbon concentration with a precision of +0.0007%. Finally, a strong correlation between prolonged drops in the off-gas emission signal and furnace slopping events was observed. A simple computer algorithm was written that successfully predicts furnace slopping for 90% of the heats observed; over 80% are predicted with at least a 30-second warning prior to the initial slopping events,

Sarah Allendorf; David Ottesen; Donald Hardesty

2002-01-31T23:59:59.000Z

5

Cement advanced furnace and process  

SciTech Connect (OSTI)

This patent describes a suspension shaft furnace for producing discrete cement clinkers from discrete pellets of cement-forming batch materials which are gravity-migrated therethrough. It comprises a vertical furnace housing enclosing a top pellet-feeding and preheating zone comprising an elongate vertical shaft section opening into an intermediate fluidized bed section comprising fuel inlet conduits, an air-permeable clinker-impermeable support; a lower clinker-cooling section beneath the fluidized bed section; clinker-discharge means communicating between the fluidized bed section and the cooling section and air inlet means.

Litka, A.F.; Cohen, S.M.

1992-06-02T23:59:59.000Z

6

Improving the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs, and Side Vents  

Broader source: Energy.gov [DOE]

This factsheet describes the benefits of a high-performance aluminum bronze alloy to basic oxygen furnace and electric arc furnace components such as hoods, roofs, and side vents.

7

Evaluation of Advanced PSA and Oxygen Combustion System for Industrial Furnace Applications  

E-Print Network [OSTI]

M. A. Delano Union Carbide Corp. Tarrytown, NY ABSTRACT EVALUATION OF ADVANCED PSA AND OXYGEN COMBUSTION SYSTEM FOR INDUSTRIAL FURNACE APPLICATIONS D. Lagree Union Carbide Corp. Tonawanda, NY The performance of a pilot scale advanced PSA... oxygen generation system and a low NO x oxygen burner was evaluated for industrial furnace applications. The PSA system employs a two-bed vacuum cycle design with a capacity of 1.3 TPD at 90% O 2 purity. The oxygen generated from the PSA system...

Delano, M. A.; Lagree, D.; Kwan, Y.

8

Blast furnace injection of massive quantities of coal with enriched air or pure oxygen  

SciTech Connect (OSTI)

An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. (Center de Recherches Metallurgiques, Liege (Belgium))

1993-01-01T23:59:59.000Z

9

Optical cavity furnace for semiconductor wafer processing  

DOE Patents [OSTI]

An optical cavity furnace 10 having multiple optical energy sources 12 associated with an optical cavity 18 of the furnace. The multiple optical energy sources 12 may be lamps or other devices suitable for producing an appropriate level of optical energy. The optical cavity furnace 10 may also include one or more reflectors 14 and one or more walls 16 associated with the optical energy sources 12 such that the reflectors 14 and walls 16 define the optical cavity 18. The walls 16 may have any desired configuration or shape to enhance operation of the furnace as an optical cavity 18. The optical energy sources 12 may be positioned at any location with respect to the reflectors 14 and walls defining the optical cavity. The optical cavity furnace 10 may further include a semiconductor wafer transport system 22 for transporting one or more semiconductor wafers 20 through the optical cavity.

Sopori, Bhushan L.

2014-08-05T23:59:59.000Z

10

A new direct steel making process based upon the blast furnace (Including scrap processing with recovery of tramp elements)  

SciTech Connect (OSTI)

Steel is produced from raw materials containing iron and alloying elements with direct elimination of oxygen and impurities in the blast furnace process. The blast furnace shaft is modified to take off load from the liquid bath and carbon is prevented from going into the liquid steel. In the gas purification system sulphur and CO{sub 2} removal facilities are included and purified reducing gases so obtained are combusted in the hearth with oxygen to produce heat for smelting. Scrap can be charged as raw material with the recovery of tramp elements with continuous production of liquid steel.

Nabi, G.

1996-12-31T23:59:59.000Z

11

Optical processing furnace with quartz muffle and diffuser plate  

DOE Patents [OSTI]

An optical furnace for annealing a process wafer comprising a source of optical energy, a quartz muffle having a door to hold the wafer for processing, and a quartz diffuser plate to diffuse the light impinging on the quartz muffle; a feedback system with a light sensor located in the door or wall of the muffle is also provided for controlling the source of optical energy. The quartz for the diffuser plate is surface etched (to give the quartz diffusive qualities) in the furnace during a high intensity burn-in process.

Sopori, Bhushan L. (Denver, CO)

1995-01-01T23:59:59.000Z

12

AISI/DOE Technology Roadmap Program Hot Oxygen Injection Into The Blast Furnace  

SciTech Connect (OSTI)

Increased levels of blast furnace coal injection are needed to further lower coke requirements and provide more flexibility in furnace productivity. The direct injection of high temperature oxygen with coal in the blast furnace blowpipe and tuyere offers better coal dispersion at high local oxygen concentrations, optimizing the use of oxygen in the blast furnace. Based on pilot scale tests, coal injection can be increased by 75 pounds per ton of hot metal (lb/thm), yielding net savings of $0.84/tm. Potential productivity increases of 15 percent would yield another $1.95/thm. In this project, commercial-scale hot oxygen injection from a ''thermal nozzle'' system, patented by Praxair, Inc., has been developed, integrated into, and demonstrated on two tuyeres of the U.S. Steel Gary Works no. 6 blast furnace. The goals were to evaluate heat load on furnace components from hot oxygen injection, demonstrate a safe and reliable lance and flow control design, and qualitatively observe hot oxygen-coal interaction. All three goals have been successfully met. Heat load on the blowpipe is essentially unchanged with hot oxygen. Total heat load on the tuyere increases about 10% and heat load on the tuyere tip increases about 50%. Bosh temperatures remained within the usual operating range. Performance in all these areas is acceptable. Lance performance was improved during testing by changes to lance materials and operating practices. The lance fuel tip was changed from copper to a nickel alloy to eliminate oxidation problems that severely limited tip life. Ignition flow rates and oxygen-fuel ratios were changed to counter the effects of blowpipe pressure fluctuations caused by natural resonance and by coal/coke combustion in the tuyere and raceway. Lances can now be reliably ignited using the hot blast as the ignition source. Blowpipe pressures were analyzed to evaluate ht oxygen-coal interactions. The data suggest that hot oxygen increases coal combustion in the blow pipe and tuyere by 30, in line with pilot scale tests conducted previously.

Michael F. Riley

2002-10-21T23:59:59.000Z

13

Optical processing furnace with quartz muffle and diffuser plate  

DOE Patents [OSTI]

An optical furnace for annealing a process wafer comprising a source of optical energy, a quartz muffle having a door to hold the wafer for processing, and a quartz diffuser plate to diffuse the light impinging on the quartz muffle; a feedback system with a light sensor located in the wall of the muffle is also provided for controlling the source of optical energy.

Sopori, Bhushan L. (Denver, CO)

1996-01-01T23:59:59.000Z

14

Lance for fuel and oxygen injection into smelting or refining furnace  

DOE Patents [OSTI]

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

Schlichting, Mark R. (Chesterton, IN)

1994-01-01T23:59:59.000Z

15

Lance for fuel and oxygen injection into smelting or refining furnace  

DOE Patents [OSTI]

A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

Schlichting, M.R.

1994-12-20T23:59:59.000Z

16

Optical processing furnace with quartz muffle and diffuser plate  

DOE Patents [OSTI]

An optical furnace for annealing a process wafer is disclosed comprising a source of optical energy, a quartz muffle having a door to hold the wafer for processing, and a quartz diffuser plate to diffuse the light impinging on the quartz muffle; a feedback system with a light sensor located in the wall of the muffle is also provided for controlling the source of optical energy. 5 figs.

Sopori, B.L.

1996-11-19T23:59:59.000Z

17

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

18

Process control techniques for the Sidmar blast furnaces  

SciTech Connect (OSTI)

The major challenge for modern blast furnace operation is the achievement of a very high productivity, excellent hot metal quality, low fuel consumption and longer blast furnace campaigns. The introduction of predictive models, decision supporting software and expert systems has reduced the standard deviation of the hot metal silicon content. The production loss due to the thermal state of the blast furnace has decreased three times since 1990. An appropriate control of the heat losses with high pulverized coal injection rates, is of the utmost importance for the life of the blast furnace. Different rules for the burden distribution of both blast furnaces are given. At blast furnace A, a peripheral gas flow is promoted, while at blast furnace B a more central gas flow is promoted.

Vandenberghe, D.; Bonte, L.; Nieuwerburgh, H. van [Sidmar N.V., Ghent (Belgium)

1995-12-01T23:59:59.000Z

19

Processing electric arc furnace dust into saleable chemical products  

SciTech Connect (OSTI)

The modern steel industry uses electric arc furnace (EAF) technology to manufacture steel. A major drawback of this technology is the production of EAF dust, which is listed by the U.S. Environmental Protection Agency as a hazardous waste under the Resource Conservation and Recovery Act. The annual disposal of approximately 0.65 million tons of EAF dust in the United States and Canada is an expensive, unresolved problem for the steel industry. EAF dust byproducts are generated during the manufacturing process by a variety of mechanisms. The dust consists of various metals (e.g., zinc, lead, cadmium) that occur as vapors at 1,600{degrees}C (EAF hearth temperature); these vapors are condensed and collected in a baghouse. The production of one ton of steel will generate approximately 25 pounds of EAF dust as a byproduct, which is currently disposed of in landfills.

NONE

1998-04-01T23:59:59.000Z

20

Process control techniques at the blast furnaces of Thyssen Stahl AG  

SciTech Connect (OSTI)

Process improvements, capacity increases and the use of modern measuring and process control techniques have helped to ensure that the blast furnace will remain an indispensable means of supplying steelworks with hot metal until well into the next century. The survival of a future-oriented company such as Thyssen Stahl AG depends on long-term improvements in economic viability. Today, Thyssen Stahl AG operates two blast furnace plants comprising a total of five blast furnaces with hearth diameters ranging from 9.3 to 14.9m. This choice of furnaces permits flexible adjustment to changing workload situations and enables about ten million tons of hot metal to be produced each year. The wide range of measuring devices specially fitted on Schwelgern blast furnace No. 1 made a vital contribution to the development of blast furnace models. The purpose of these models was to make a general assessment of the state of the furnace and so create an objective basis for furnace operation. The paper describes the development of these measuring techniques and process model and the application of the model.

Kowalski, W.; Bachhofen, H.J.; Beppler, E.; Kreibich, K.; Muelheims, K.; Peters, M.; Wieters, C.U. [Thyssen Stahl AG, Duisburg (Germany)

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Recent developments in blast furnace process control within British Steel  

SciTech Connect (OSTI)

British Steel generally operates seven blast furnaces on four integrated works. All furnaces have been equipped with comprehensive instrumentation and data logging computers over the past eight years. The four Scunthorpe furnaces practice coal injection up to 170 kg/tHM (340 lb/THM), the remainder injecting oil at up to 100 kg/tHM (200 lb/THM). Distribution control is effected by Paul Wurth Bell-Less Tops on six of the seven furnaces, and Movable Throat Armour with bells on the remaining one. All have at least one sub burden probe. The blast furnace operator has a vast quantity of data and signals to consider and evaluate when attempting to achieve the objective of providing a consistent supply of hot metal. Techniques have been, and are being, developed to assist the operator to interpret large numbers of signals. A simple operator guidance system has been developed to provide advice, based on current operating procedures and interpreted data. Further development will involve the use of a sophisticated Expert System software shell.

Warren, P.W. [British Steel Technical, Middlesbrough (United Kingdom). Teesside Labs.

1995-12-01T23:59:59.000Z

22

Processing automotive shredder fluff for a blast furnace injection  

E-Print Network [OSTI]

led to an optimized iron recovery of 78.5 % corresponding to an elemental iron content of 51 %, close to the ore grade required in a blast furnace. At the global scale of ELV recycling, these results entail an increase by 4 % of the fluff recycling rate, thus helping to meet the European requirements for 2015

Boyer, Edmond

23

On numerical simulation of flow, heat transfer and combustion processes in tangentially-fired furnace  

SciTech Connect (OSTI)

In this work, an Eulerian/Lagrangian approach has been employed to investigate numerically flow characteristics, heat transfer and combustion processes inside corner-fired power plant boiler furnace. To avoid pseudo-diffusion that is significant in modeling tangentially-fired furnaces, some attempts have been made at improving the finite-difference scheme. Comparisons have been made between standard {kappa}-{epsilon} model and RNG {kappa}-{epsilon} model. Some new developments on turbulent diffusion of particles are taken into account in an attempt to improve computational accuracy. Finally, temperature deviation is studied numerically so as to gain deeper insight into tangentially fired furnace.

Sun, P.; Fan, J.; Cen, K.

1999-07-01T23:59:59.000Z

24

Development and application of new techniques for blast furnace process control at SSAB Tunnplaat, Luleaa Works  

SciTech Connect (OSTI)

SSAB Tunnplaat AB operates two blast furnaces (M1 and M2) in Luleaa. In recent years research efforts have to a great extent been aimed at the development of new techniques for blast furnace process control. An example is the installation of a burden profile measurement system, which was useful in the development of a new burden distribution praxis on the big furnace (M2), equipped with a bell-less-top. Hearth level detection and continuous measurement of the hot metal temperature in the runner are under evaluation. The purpose of these techniques is to give earlier information concerning the state of the blast furnace process. Parallel to this work, models for prediction of silicon in hot metal, the position and shape of the cohesive zone and slip-warning are being developed and tested off-line. These new models and information from new measuring techniques will be integrated into a new Operating Guidance System, hopefully resulting in a powerful tool in the efforts to stabilize blast furnace operations.

Braemming, M.; Hallin, M. [SSAB Tunnplaat AB, Luleaa (Sweden); Zuo, G. [Luleaa Univ. (Sweden). Dept. of Process Metallurgy

1995-12-01T23:59:59.000Z

25

Pellet property requirements for future blast-furnace operations and other new ironmaking processes  

SciTech Connect (OSTI)

The requirements for the physical, chemical and metallurgical properties of pellets have continued to become more stringent as blast-furnace productivity and coke rate have been rapidly improved during the last decade. In addition, the age and deterioration of the North American coke batteries, the lack of capital to sufficiently rebuild them, and the threat of increasingly more stringent environmental controls for the coke batteries has forced North American ironmakers to begin implementing pulverized coal injection to minimize the coke requirements for the blast furnace and to seriously investigate developing other ironmaking processes that use coal instead of coke. Therefore, the next major step in North American ironmaking has included injecting pulverized coal (PC) at 200 kilograms per ton of hot metal (kg/ton) [400 pounds per net ton of hot metal (lb/NTHM)] or greater which will result in the coke rate decreasing to less than 300 kg/ton (600 lb/NTHM) or less. As a result, the pellets will spend more time in the furnace and will be required to support more total weight. Pellets can also be a major iron unit source for other cokeless ironmaking processes such as the COREX process or the AISI direct ironmaking process. This paper will explore the pellet property requirements for future blast-furnace operations and cokeless ironmaking processes.

Agrawal, A.K.; Oshnock, T.W. [U.S. Steel, Monroeville, PA (United States)

1995-12-01T23:59:59.000Z

26

Paired Straight Hearth Furnace-Transformational Ironmaking Process  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergyDepartment ofOil's Impact on2005-74LaboratoriesCERCLA Process Project

27

Method for processing aluminum spent potliner in a graphite electrode arc furnace  

DOE Patents [OSTI]

A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spend aluminum pot liner is crushed, iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine, and CO.

O'Connor, William K.; Turner, Paul C.; Addison, G.W. (AJT Enterprises, Inc.)

2002-12-24T23:59:59.000Z

28

Method for processing aluminum spent potliner in a graphite electrode ARC furnace  

DOE Patents [OSTI]

A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spent aluminum pot liner is crushed iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine and CO.

O'Connor, William K. (Lebanon, OR); Turner, Paul C. (Independence, OR); Addison, Gerald W. (St. Stephen, SC)

2002-12-24T23:59:59.000Z

29

Estimation of radiative properties and temperature distributions in coal-fired boiler furnaces by a portable image processing system  

SciTech Connect (OSTI)

This paper presented an experimental investigation on the estimation of radiative properties and temperature distributions in a 670 t/h coal-fired boiler furnace by a portable imaging processing system. The portable system has been calibrated by a blackbody furnace. Flame temperatures and emissivities were measured by the portable system and equivalent blackbody temperatures were deduced. Comparing the equivalent blackbody temperatures measured by the portable system and the infrared pyrometer, the relative difference is less than 4%. The reconstructed pseudo-instantaneous 2-D temperature distributions in two cross-sections can disclose the combustion status inside the furnace. The measured radiative properties of particles in the furnace proved there is significant scattering in coal-fired boiler furnaces and it can provide useful information for the calculation of radiative heat transfer and numerical simulation of combustion in coal-fired boiler furnaces. The preliminary experimental results show this technology will be helpful for the combustion diagnosis in coal-fired boiler furnaces. (author)

Li, Wenhao; Lou, Chun; Sun, Yipeng; Zhou, Huaichun [State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan, 430074 Hubei (China)

2011-02-15T23:59:59.000Z

30

NREL's Optical Cavity Furnace Brings Together a Myriad of Advances for Processing Solar Cells (Fact Sheet)  

SciTech Connect (OSTI)

Fact sheet on 2011 R&D 100 Award winner, the Optical Cavity Furnace. The innovative furnace uses light and unique light-induced effects to make higher-efficiency solar cells at lower cost.

Not Available

2011-08-01T23:59:59.000Z

31

Fuel and oxygen addition for metal smelting or refining process  

DOE Patents [OSTI]

A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

Schlichting, Mark R. (Chesterton, IN)

1994-01-01T23:59:59.000Z

32

Fuel and oxygen addition for metal smelting or refining process  

DOE Patents [OSTI]

A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

Schlichting, M.R.

1994-11-22T23:59:59.000Z

33

Recycling and Reuse of Basic Oxygen Furnace (BOF)/Basic Oxygen Process (BOP) Steelmaking Slags  

Broader source: Energy.gov [DOE]

This factsheet describes a project to develop technologies and methodologies to allow value-added utilization of steelmaking slag, thus reducing waste and saving energy.

34

DME-to-oxygenates process studies  

SciTech Connect (OSTI)

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

35

Interated Intelligent Industrial Process Sensing and Control: Applied to and Demonstrated on Cupola Furnaces  

SciTech Connect (OSTI)

The final goal of this project was the development of a system that is capable of controlling an industrial process effectively through the integration of information obtained through intelligent sensor fusion and intelligent control technologies. The industry of interest in this project was the metal casting industry as represented by cupola iron-melting furnaces. However, the developed technology is of generic type and hence applicable to several other industries. The system was divided into the following four major interacting components: 1. An object oriented generic architecture to integrate the developed software and hardware components @. Generic algorithms for intelligent signal analysis and sensor and model fusion 3. Development of supervisory structure for integration of intelligent sensor fusion data into the controller 4. Hardware implementation of intelligent signal analysis and fusion algorithms

Mohamed Abdelrahman; roger Haggard; Wagdy Mahmoud; Kevin Moore; Denis Clark; Eric Larsen; Paul King

2003-02-12T23:59:59.000Z

36

Nanoparticulate-catalyzed oxygen transfer processes  

DOE Patents [OSTI]

Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

Hunt, Andrew T. (Atlanta, GA); Breitkopf, Richard C. (Dunwoody, GA)

2009-12-01T23:59:59.000Z

37

Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals  

E-Print Network [OSTI]

Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

2006-01-01T23:59:59.000Z

38

Insulation of Pipe Bends Improves Efficiency of Hot Oil Furnaces  

E-Print Network [OSTI]

Thermodynamic analyses of processes indicated low furnace efficiencies on certain hot oil furnaces. Further investigation, which included Infrared (IR) thermography testing of several furnaces, identified extremely hot surfaces on the outside...

Haseltine, D. M.; Laffitte, R. D.

39

Waste Heat Recovery – Submerged Arc Furnaces (SAF)  

E-Print Network [OSTI]

Submerged Arc Furnaces are used to produce high temperature alloys. These furnaces typically run at 3000°F using high voltage electricity along with metallurgical carbon to reduce metal oxides to pure elemental form. The process as currently...

O'Brien, T.

2008-01-01T23:59:59.000Z

40

Oxygen Enrichment in the Process and Chemical Industries  

E-Print Network [OSTI]

The rapid escalation in energy prices during recent years has resulted in a resurgence of interest in the energy-saving aspects of oxygen enrichment techniques available to the process and chemical industries. Important side benefits which may...

Milne, R. T.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Furnace assembly  

DOE Patents [OSTI]

A method of and apparatus for heating test specimens to desired elevated temperatures for irradiation by a high energy neutron source. A furnace assembly is provided for heating two separate groups of specimens to substantially different, elevated, isothermal temperatures in a high vacuum environment while positioning the two specimen groups symmetrically at equivalent neutron irradiating positions.

Panayotou, Nicholas F. (Kennewick, WA); Green, Donald R. (Richland, WA); Price, Larry S. (Pittsburg, CA)

1985-01-01T23:59:59.000Z

42

Independent Validation and Verification of Process Design and Optimization Technology Diagnostic and Control of Natural Gas Fired Furnaces via Flame Image Analysis Technology  

SciTech Connect (OSTI)

The United States Department of Energy, Industrial Technologies Program has invested in emerging Process Design and Optimizations Technologies (PDOT) to encourage the development of new initiatives that might result in energy savings in industrial processes. Gas fired furnaces present a harsh environment, often making accurate determination of correct air/fuel ratios a challenge. Operation with the correct air/fuel ratio and especially with balanced burners in multi-burner combustion equipment can result in improved system efficiency, yielding lower operating costs and reduced emissions. Flame Image Analysis offers a way to improve individual burner performance by identifying and correcting fuel-rich burners. The anticipated benefit of this technology is improved furnace thermal efficiency, and lower NOx emissions. Independent validation and verification (V&V) testing of the FIA technology was performed at Missouri Forge, Inc., in Doniphan, Missouri by Environ International Corporation (V&V contractor) and Enterprise Energy and Research (EE&R), the developer of the technology. The test site was selected by the technology developer and accepted by Environ after a meeting held at Missouri Forge. As stated in the solicitation for the V&V contractor, 'The objective of this activity is to provide independent verification and validation of the performance of this new technology when demonstrated in industrial applications. A primary goal for the V&V process will be to independently evaluate if this technology, when demonstrated in an industrial application, can be utilized to save a significant amount of the operating energy cost. The Seller will also independently evaluate the other benefits of the demonstrated technology that were previously identified by the developer, including those related to product quality, productivity, environmental impact, etc'. A test plan was provided by the technology developer and is included as an appendix to the summary report submitted by Environ (Appendix A). That plan required the V&V contractor to: (1) Establish the as-found furnace operating conditions; (2) Tune the furnace using currently available technology to establish baseline conditions; (3) Tune the furnace using the FIA technology; and (4) Document the improved performance that resulted from application of the FIA technology. It is important to note that the testing was not designed to be a competition or comparison between two different methodologies that could be used for furnace tuning. Rather, the intent was to quantify improvements in furnace performance that could not be achieved with existing technology. Therefore, the measure of success is improvement beyond the furnace efficiency obtainable using existing furnace optimization methods rather than improvement from the as found condition.

Cox, Daryl [ORNL

2009-05-01T23:59:59.000Z

43

Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption  

SciTech Connect (OSTI)

The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

1995-12-01T23:59:59.000Z

44

Process for conversion of lignin to reformulated, partially oxygenated gasoline  

DOE Patents [OSTI]

A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

2001-01-09T23:59:59.000Z

45

The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems  

E-Print Network [OSTI]

The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

46

Direct current, closed furnace silicon technology  

SciTech Connect (OSTI)

The dc closed furnace technology for smelting silicon offers technical operating challenges, as well as, economic opportunities for off-gas recovery, reduced electrode consumption, reduced reductant oxidation losses, reduced energy consumption, and improved silicon recovery. The 10 mva dc closed furnace is located in East Selkirk, Manitoba. Construction of this pilot plant was started in September 1990. Following successful commissioning of the furnace in 1992, a number of smelting tests have been conducted aimed at optimization of the furnace operation and the raw material mix. The operation of a closed furnace is significantly different from an open furnace operation. The major difference being in the mechanical movement of the mix, off-gas recovery, and inability to observe the process. These differences made data collection and analysis critical in making operating decisions. This closed furnace was operated by computer control (state of the art in the smelling industry).

Dosaj, V.D. [Dow Corning Corp., Midland, MI (United States); May, J.B. [Dow Corning Corp., Freeland, MI (United States); Arvidson, A.N. [Meadow Materials, Manitoba (Canada)

1994-05-01T23:59:59.000Z

47

Steam Cracker Furnace Energy Improvements  

E-Print Network [OSTI]

Channel, ~ 25 mi. east of Houston ? Includes 4 manufacturing sites, 2 technology/engineering offices ?Significant community involvement Baytown Refinery Page 4 Steam Cracking to Olefins ? Process 60+ years old; ExxonMobil one of pioneers... Steam Cracker Furnace Energy Improvements Tim Gandler Energy Coordinator Baytown Olefins Plant, Baytown Tx 2010 Industrial Energy Technology Conference May, 2010 Page 2 ? Baytown Complex ? Steam Cracking to Olefins ? Furnace overview...

Gandler, T.

48

Ferrosilicon smelting in a direct current furnace  

DOE Patents [OSTI]

The present invention is a process for smelting ferrosilicon alloy. The process comprises adding a carbon source and tailings comprising oxides of silicon and iron to a substantially closed furnace. Heat is supplied to the furnace by striking a direct current arc between a cathode electrode and an anode functional hearth. In a preferred embodiment of the present invention, the cathode electrode is hollow and feed to the substantially closed furnace is through the hollow electrode. 1 figure.

Dosaj, V.D.; May, J.B.

1992-12-29T23:59:59.000Z

49

Variable frequency microwave furnace system  

DOE Patents [OSTI]

A variable frequency microwave furnace system (10) designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity (34) for testing or other selected applications. The variable frequency microwave furnace system (10) includes a microwave signal generator (12) or microwave voltage-controlled oscillator (14) for generating a low-power microwave signal for input to the microwave furnace. A first amplifier (18) may be provided to amplify the magnitude of the signal output from the microwave signal generator (12) or the microwave voltage-controlled oscillator (14). A second amplifier (20) is provided for processing the signal output by the first amplifier (18). The second amplifier (20) outputs the microwave signal input to the furnace cavity (34). In the preferred embodiment, the second amplifier (20) is a traveling-wave tube (TWT). A power supply (22) is provided for operation of the second amplifier (20). A directional coupler (24) is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter (30) is provided for measuring the power delivered to the microwave furnace (32). A second power meter (26) detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load (28).

Bible, Don W. (Clinton, TN); Lauf, Robert J. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

50

Variable frequency microwave furnace system  

DOE Patents [OSTI]

A variable frequency microwave furnace system designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity for testing or other selected applications. The variable frequency microwave furnace system includes a microwave signal generator or microwave voltage-controlled oscillator for generating a low-power microwave signal for input to the microwave furnace. A first amplifier may be provided to amplify the magnitude of the signal output from the microwave signal generator or the microwave voltage-controlled oscillator. A second amplifier is provided for processing the signal output by the first amplifier. The second amplifier outputs the microwave signal input to the furnace cavity. In the preferred embodiment, the second amplifier is a traveling-wave tube (TWT). A power supply is provided for operation of the second amplifier. A directional coupler is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter is provided for measuring the power delivered to the microwave furnace. A second power meter detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load. 5 figs.

Bible, D.W.; Lauf, R.J.

1994-06-14T23:59:59.000Z

51

Application of microwave heating to ceramic processing: Design and initial operation of a 2.45-GHz single-mode furnace  

SciTech Connect (OSTI)

High-power microwave and millimeter-wave sources are currently being applied to ceramic processing studies at the Naval Research Laboratory (NRL). A single-mode cavity microwave furnace, operating in the TE{sub 103} mode at 2.45 GHz, is operational and is being used to investigate sintering of nanocrystalline ceramics. This paper reports the design of the 2.45-GHz furnace and its use in initial microwave sintering experiments on nanocrystalline alumina and titania compacts. The high purity Al{sub 2}O{sub 3} and TiO{sub 2} nanocrystalline powders used in the sintering experiments were prepared by the sol-gel method. These powders were first uniaxially pressed to 14 MPa, cold isostatically pressed (CIP`ed) to various pressures {ge}420 MPa, and finally sectioned into wafers. The density of the green compacts was 30 to 38% theoretical density (TD). The compacts were placed in insulating fiberboard caskets which were sufficiently lossy to provide hybrid heating at room temperature. The compacts were heated in the microwave furnace for up to three hours at temperatures {ge}1720 C. The temperature of the workpiece was monitored using an optical pyrometer. Final densities up to 80% TD have been obtained to date for Al{sub 2}O{sub 3} and up to 52% TD for TiO{sub 2}. The sintered compacts were characterized by X-ray diffraction and by scanning electron microscopy (SEM) to determine the phase and grain size.

Fliflet, A.W. [Naval Research Lab., Washington, DC (United States)] [Naval Research Lab., Washington, DC (United States); Bruce, R.W.; Kinkead, A.K. [Sachs/Freeman Associates Inc., Landover, MD (United States)] [and others] [Sachs/Freeman Associates Inc., Landover, MD (United States); and others

1996-06-01T23:59:59.000Z

52

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

Morris, D.E.

1993-09-14T23:59:59.000Z

53

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1993-01-01T23:59:59.000Z

54

High-resolution NMR process analyzer for oxygenates in gasoline  

SciTech Connect (OSTI)

We report a high-resolution 42-MHz[sup 1]HFT-NMR instrument that is suitable for use as a process analyzer and demonstrate its use in the determination of methyl tert-butyl ether (MTBE) in a flowing stream of gasoline. This spectrometer is based on a 55-kg permanent magnet with essentially no fringe field. A spectral resolution of 3 Hz was typically obtained for spinning samples, and this performance was only slightly degraded with flowing samples. We report a procedure for magnet drift compensation using a software procedure rather than a field-frequency lock channel. This procedure allowed signal averaging without loss of resolution. Regulatory changes to be implemented in the near future have created a need for the development of methods for the determination of MTBE and other oxygenates in reformulated gasolines. Existing methods employing gas chromatography are not fast enough for process control of a gasoline blender and suffer from other limitations. This study demonstrates that process analysis NMR is well-suited to the determination of MTBE in a simulated gasoline blender. The detection limit of 0.5 vol % MTBE was obtained with a measurement time of 1 min. The absolute standard deviation of independent determinations was 0.17% when the MTBE concentration was 10%, a nominal value. Preliminary results also suggest that the method may be applicable to gasolines containing mixtures of oxygenate additives as well as the measurement of aromatic and olefinic hydrogens. 33 refs., 9 figs.

Skloss, T.W.; Kim, A.J.; Haw, J.F. (Texas A M Univ., College Station, TX (United States))

1994-02-15T23:59:59.000Z

55

Existing and prospective blast-furnace conditions  

SciTech Connect (OSTI)

Blast-furnace conditions are investigated by means of a multizone model. The expected performance of prospective technologies is assessed, as well as the trends in blast-furnace processes. The model permits the identification of means of overcoming practical difficulties.

I.G. Tovarovskii; V.I. Bol'shakov; V.P. Lyalyuk; A.E. Merkulov; D. V. Pinchuk [Ukrainian Academy of Sciences, Dnepropetrovsk (Ukraine). Institute of Ferrous Metallurgy

2009-07-15T23:59:59.000Z

56

Thermal Imaging Control of Furnaces and Combustors  

SciTech Connect (OSTI)

The object if this project is to demonstrate and bring to commercial readiness a near-infrared thermal imaging control system for high temperature furnaces and combustors. The thermal imaging control system, including hardware, signal processing, and control software, is designed to be rugged, self-calibrating, easy to install, and relatively transparent to the furnace operator.

David M. Rue; Serguei Zelepouga; Ishwar K. Puri

2003-02-28T23:59:59.000Z

57

Oxygen-producing inert anodes for SOM process  

DOE Patents [OSTI]

An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

Pal, Uday B

2014-02-25T23:59:59.000Z

58

Surface Science 425 (1999) 114 Non-adiabatic charge transfer process of oxygen on  

E-Print Network [OSTI]

Surface Science 425 (1999) 1­14 Non-adiabatic charge transfer process of oxygen on metal surfaces November 1998 Abstract The dynamics of charge transfer processes of oxygen on metal surfaces a different charged oxygen species. Empirical universal potential energy functions have been constructed

Zeiri, Yehuda

59

Heat treatment furnace  

DOE Patents [OSTI]

A furnace heats through both infrared radiation and convective air utilizing an infrared/purge gas design that enables improved temperature control to enable more uniform treatment of workpieces. The furnace utilizes lamps, the electrical end connections of which are located in an enclosure outside the furnace chamber, with the lamps extending into the furnace chamber through openings in the wall of the chamber. The enclosure is purged with gas, which gas flows from the enclosure into the furnace chamber via the openings in the wall of the chamber so that the gas flows above and around the lamps and is heated to form a convective mechanism in heating parts.

Seals, Roland D; Parrott, Jeffrey G; DeMint, Paul D; Finney, Kevin R; Blue, Charles T

2014-10-21T23:59:59.000Z

60

Proceedings of the 45th electric furnace conference  

SciTech Connect (OSTI)

This book contains the proceedings of the 46th Electric Furnace Conference. Topics included are: EAF Dust Decomposition and Metals Recovery at ScanDust, Optimization of Electric Arc Furnace Process by Pneumatic Stirring, and Melt Down Control for Electric Arc Furnaces.

Not Available

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Two chamber reaction furnace  

DOE Patents [OSTI]

A vertical two chamber reaction furnace. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium-copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700.degree. and 800.degree. C.) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800.degree. to 950.degree. C. to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product.

Blaugher, Richard D. (Evergreen, CO)

1998-05-05T23:59:59.000Z

62

Fermentation process using specific oxygen uptake rates as a process control  

DOE Patents [OSTI]

Specific oxygen uptake (OUR) is used as a process control parameter in fermentation processes. OUR is determined during at least the production phase of a fermentation process, and process parameters are adjusted to maintain the OUR within desired ranges. The invention is particularly applicable when the fermentation is conducted using a microorganism having a natural PDC pathway that has been disrupted so that it no longer functions. Microorganisms of this sort often produce poorly under strictly anaerobic conditions. Microaeration controlled by monitoring OUR allows the performance of the microorganism to be optimized.

Van Hoek, Pim; Aristidou, Aristos; Rush, Brian

2014-09-09T23:59:59.000Z

63

Fermentation process using specific oxygen uptake rates as a process control  

DOE Patents [OSTI]

Specific oxygen uptake (OUR) is used as a process control parameter in fermentation processes. OUR is determined during at least the production phase of a fermentation process, and process parameters are adjusted to maintain the OUR within desired ranges. The invention is particularly applicable when the fermentation is conducted using a microorganism having a natural PDC pathway that has been disrupted so that it no longer functions. Microorganisms of this sort often produce poorly under strictly anaerobic conditions. Microaeration controlled by monitoring OUR allows the performance of the microorganism to be optimized.

Van Hoek; Pim (Minnetonka, MN), Aristidou; Aristos (Maple Grove, MN), Rush; Brian (Minneapolis, MN)

2007-06-19T23:59:59.000Z

64

Fermentation process using specific oxygen uptake rates as a process control  

DOE Patents [OSTI]

Specific oxygen uptake (OUR) is used as a process control parameter in fermentation processes. OUR is determined during at least the production phase of a fermentation process, and process parameters are adjusted to maintain the OUR within desired ranges. The invention is particularly applicable when the fermentation is conducted using a microorganism having a natural PDC pathway that has been disrupted so that it no longer functions. Microorganisms of this sort often produce poorly under strictly anaerobic conditions. Microaeration controlled by monitoring OUR allows the performance of the microorganism to be optimized.

Van Hoek, Pim (Minnetonka, MN); Aristidou, Aristos (Maple Grove, MN); Rush, Brian (Minneapolis, MN)

2011-05-10T23:59:59.000Z

65

Fossil fuel furnace reactor  

DOE Patents [OSTI]

A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

Parkinson, William J. (Los Alamos, NM)

1987-01-01T23:59:59.000Z

66

High productivity in Australian blast furnaces  

SciTech Connect (OSTI)

Since the emergence of the Australian domestic economy from recession in 1992, the productivity of BHP`s blast furnace has increased significantly to meet the demands of both domestic and export markets. BHP Steel operates six blast furnaces at its three Australian integrated plants. These furnaces vary widely in their size, feed, technology and current campaign status. This paper reviews the principal issues associated with productivity improvements over recent years. These gains have been achieved through activities associated with a wide range of process, equipment and human resource based issues.

Nightingale, R.J.; Mellor, D.G. [BHP Slab and Plate Products Div., Port Kembla, New South Wales (Australia); Jelenich, L. [BHP Rod and Bar Products Div., Newcastle, New South Wales (Australia); Ward, R.F. [BHP Long Products Div., Whyalla, South Australia (Australia)

1995-12-01T23:59:59.000Z

67

Modeling of the oxygen transfer in the respiratory process Sebastien Martin  

E-Print Network [OSTI]

in the acinar periphery. Introduction The respiratory system is designed to achieve two main functions: oxygenModeling of the oxygen transfer in the respiratory process S´ebastien Martin Laboratoire de Math, coupled with a lumped mechanical model for the ventilation process. Objectives. We aim at investigating

Paris-Sud XI, Université de

68

Blast furnace supervision and control system  

SciTech Connect (OSTI)

On December 1992, a group of companies headed by Techint, took over Somisa, the state-owned integrated steel plant located at San Nicolas, Province of Buenos Aires, Argentina, culminating an ambitious government privatization scheme. The blast furnace 2 went into a full reconstruction and relining in January 1995. After a 140 MU$ investment the new blast furnace 2 was started in September 1995. After more than one year of operation of the blast furnace the system has proven itself useful and reliable. The main reasons for the success of the system are: same use interface for all blast furnace areas -- operation, process, maintenance and management, (full horizontal and vertical integration); and full accessibility to all information and process tools though some restrictions apply to field commands (people empowerment). The paper describes the central system.

Remorino, M.; Lingiardi, O.; Zecchi, M. [Siderar S.A.I.C./Ingdesi, San Nicolas (Argentina)

1997-12-31T23:59:59.000Z

69

Waste Heat Reduction and Recovery for Improving Furnace Efficiency...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Heat Reduction and Recovery for Improving Furnace Efficiency, Productivity and Emissions Performance: A BestPractices Process Heating Technical Brief Waste Heat Reduction and...

70

Interpenetrative and transverse growth process of self-catalyzed ZnO nanorods  

E-Print Network [OSTI]

for short-wavelength optoelectronics [1] and transparent con- ducting windows for solar cells [2 evaporation process in a horizontal tube furnace. Commercial grade ZnO powder was place in the center of a single zone tube furnace and evacuated for several hours to purge oxygen in the chamber. Polycrystalline

Wang, Zhong L.

71

Trends in furnace control  

SciTech Connect (OSTI)

This paper relates Italimpianti's experiences over the past few years in the area of control of reheat furnaces for the steel industry. The focus is on the level 1 area; specifically on the use of PLC-based systems to perform both combustion control and mechanical/hydraulic control. Some topics to be discussed are: overview of reheat furnace control system requirements; PLC only control vs separate PLC and DCS systems; PLC hardware requirements; man machine interface (MMI) requirements; purge, light-on and safety logic; implementation of more sophisticated level 1 control algorithms; furnace temperature optimization: look up tables vs full thermal modeling; and recent trends including integrated PLC/DCS system.

McDonald, T.J.; Keefe, M.D. (Italimpianti of America, Inc., Coraopolis, PA (United States). Instrumentation and Controls Dept.)

1993-07-01T23:59:59.000Z

72

Method of operating a centrifugal plasma arc furnace  

DOE Patents [OSTI]

A centrifugal plasma arc furnace is used to vitrify contaminated soils and other waste materials. An assessment of the characteristics of the waste is performed prior to introducing the waste into the furnace. Based on the assessment, a predetermined amount of iron is added to each batch of waste. The waste is melted in an oxidizing atmosphere into a slag. The added iron is oxidized into Fe.sub.3 O.sub.4. Time of exposure to oxygen is controlled so that the iron does not oxidize into Fe.sub.2 O.sub.3. Slag in the furnace remains relatively non-viscous and consequently it pours out of the furnace readily. Cooled and solidified slag produced by the furnace is very resistant to groundwater leaching. The slag can be safely buried in the earth without fear of contaminating groundwater.

Kujawa, Stephan T. (Butte, MT); Battleson, Daniel M. (Butte, MT); Rademacher, Jr., Edward L. (Butte, MT); Cashell, Patrick V. (Butte, MT); Filius, Krag D. (Butte, MT); Flannery, Philip A. (Ramsey, MT); Whitworth, Clarence G. (Butte, MT)

1998-01-01T23:59:59.000Z

73

Method of operating a centrifugal plasma arc furnace  

DOE Patents [OSTI]

A centrifugal plasma arc furnace is used to vitrify contaminated soils and other waste materials. An assessment of the characteristics of the waste is performed prior to introducing the waste into the furnace. Based on the assessment, a predetermined amount of iron is added to each batch of waste. The waste is melted in an oxidizing atmosphere into a slag. The added iron is oxidized into Fe{sub 3}O{sub 4}. Time of exposure to oxygen is controlled so that the iron does not oxidize into Fe{sub 2}O{sub 3}. Slag in the furnace remains relatively non-viscous and consequently it pours out of the furnace readily. Cooled and solidified slag produced by the furnace is very resistant to groundwater leaching. The slag can be safely buried in the earth without fear of contaminating groundwater. 3 figs.

Kujawa, S.T.; Battleson, D.M.; Rademacher, E.L. Jr.; Cashell, P.V.; Filius, K.D.; Flannery, P.A.; Whitworth, C.G.

1998-03-24T23:59:59.000Z

74

Control of carbon balance in a silicon smelting furnace  

DOE Patents [OSTI]

The present invention is a process for the carbothermic reduction of silicon dioxide to form elemental silicon. Carbon balance of the process is assessed by measuring the amount of carbon monoxide evolved in offgas exiting the furnace. A ratio of the amount of carbon monoxide evolved and the amount of silicon dioxide added to the furnace is determined. Based on this ratio, the carbon balance of the furnace can be determined and carbon feed can be adjusted to maintain the furnace in carbon balance.

Dosaj, V.D.; Haines, C.M.; May, J.B.; Oleson, J.D.

1992-12-29T23:59:59.000Z

75

Blast furnace control after the year 2000  

SciTech Connect (OSTI)

Rapid technical development together with developments in work organization makes it important to investigate possible ways to achieve a cost efficient process control of different metallurgical processes. This paper describes a research project, and proposes a human oriented Information Technology Strategy, ITS, for control of the Blast Furnace process. The method used is that of deductive reasoning from a description of the prevailing technological level and experiences from various development activities. The paper is based on experiences from the No. 2 Blast Furnace at Luleaa Works but the conclusions do not at this stage necessarily reflect the opinion of the management and personnel or reflect their intentions for system development at SSAB.

Gyllenram, R.; Wikstroem, J.O. [MEFOS, Luleaa (Sweden); Hallin, M. [SSAB Tunnplaat AB, Luleaa (Sweden)

1996-12-31T23:59:59.000Z

76

Proceedings of the 1998 CMP Electric Arc Furnace Dust Management Symposium: A Summary of Presentations on Regulations and Processes  

SciTech Connect (OSTI)

This report contains the entire talk or a summary of the presentations made at the symposium on the present state of regulations and enforcement, commercial and emerging technologies, recycling dust back to the EAF and markets for products derived from treating dust. Also, a round table comprised of six steel company environmental managers discussed firsthand experiences with various treatment processes and their remarks are contained in the report.

None

1998-03-01T23:59:59.000Z

77

Biological Kraft Chemical Recycle for Augmentation of Recovery Furnace Capacity  

SciTech Connect (OSTI)

The chemicals used in pulping of wood by the kraft process are recycled in the mill in the recovery furnace, which oxidizes organics while simultaneously reducing sulfate to sulfide. The recovery furnace is central to the economical operation of kraft pulp mills, but it also causes problems. The total pulp production of many mills is limited by the recovery furnace capacity, which cannot easily be increased. The furnace is one of the largest sources of air pollution (as reduced sulfur compounds) in the kraft pulp mill.

Stuart E. Strand

2001-12-06T23:59:59.000Z

78

Improved graphite furnace atomizer  

DOE Patents [OSTI]

A graphite furnace atomizer for use in graphite furnace atomic absorption spectroscopy is described wherein the heating elements are affixed near the optical path and away from the point of sample deposition, so that when the sample is volatilized the spectroscopic temperature at the optical path is at least that of the volatilization temperature, whereby analyteconcomitant complex formation is advantageously reduced. The atomizer may be elongated along its axis to increase the distance between the optical path and the sample deposition point. Also, the atomizer may be elongated along the axis of the optical path, whereby its analytical sensitivity is greatly increased.

Siemer, D.D.

1983-05-18T23:59:59.000Z

79

Residential Furnace Blower Performance  

E-Print Network [OSTI]

conditioner performance1 , standby power, as well as igniter and combustion air blower power. Energy savings for a typical three-and-a-half ton air conditioner with typical California ducts are 45 kWh. Peak demand combinations of blowers and residential furnaces were tested for air moving performance. The laboratory test

80

Effects of oxygen transport limitation on nitrification in the activated sludge process  

E-Print Network [OSTI]

Effects of oxygen transport limitation on nitrification in the activated sludge process ABSTRACT: Apseudohomogeneous model ofthe nitrifying activated sludge process was developed to investigate the effects ofmass and autotrophic ammonia oxidation within activated sludge flocs were described by an interactive-type, multiple

Stenstrom, Michael K.

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Optimized Utility Systems and Furnace Integration  

E-Print Network [OSTI]

OPTIMIZED UTILITY SYSTEMS AND FURNACE INTEGRATION A. S. McMullan and H. D. Spriggs, Linnhoff March, Inc., Leesburg, Va. ABSTRACT Conventional process design philosophy usually results in utility systems being designed after process design... defines the Process/Utility interface. Clearly, changing the process design can result in different utility demands and possibly in different utility system designs. This paper presents a procedure, using Pinch Technology, for the simultaneous design...

McMullan, A. S.; Spriggs, H. D.

82

Measure Guideline: High Efficiency Natural Gas Furnaces  

SciTech Connect (OSTI)

This Measure Guideline covers installation of high-efficiency gas furnaces. Topics covered include when to install a high-efficiency gas furnace as a retrofit measure, how to identify and address risks, and the steps to be used in the selection and installation process. The guideline is written for Building America practitioners and HVAC contractors and installers. It includes a compilation of information provided by manufacturers, researchers, and the Department of Energy as well as recent research results from the Partnership for Advanced Residential Retrofit (PARR) Building America team.

Brand, L.; Rose, W.

2012-10-01T23:59:59.000Z

83

Oxygen Enriched Combustion System Performance Study  

E-Print Network [OSTI]

}ched combustlon systems are technically, envlronmentally and economically feasible and offer significant energy savings and/or productivity improvement, and then to verify the performance of selected systems in research furnaces. Tests of several commercial... for 35 - 100 percent oxygen. The absolute levels of the NO x emissions also depended on the furnace temperature. INTRODUCTION Oxygen enriched combustion has been found to have significant energy saving potential in industrial furnace applications...

Chen, S. L.; Kwan, Y.; Abele, A. R.; Silver, L. S.; Kobayashi, H.

84

Energy Savings in Electric Arc Furnace Melting  

E-Print Network [OSTI]

Arc furnace melting which at one time was almost exclusively used to produce alloy steel and steel castings is now widely accepted in the industry as an efficient process to produce all types of steel and iron. Presently, about 28% of steel...

Lubbeck, W.

1982-01-01T23:59:59.000Z

85

Oxygen at Nanomolar Levels Reversibly Suppresses Process Rates and Gene Expression in Anammox and Denitrification in the Oxygen Minimum Zone off Northern Chile  

E-Print Network [OSTI]

A major percentage (20 to 40%) of global marine fixed-nitrogen loss occurs in oxygen minimum zones (OMZs). Concentrations of O[subscript 2] and the sensitivity of the anaerobic N[subscript 2]-producing processes of anammox ...

Dalsgaard, Tage

86

Vertical two chamber reaction furnace  

DOE Patents [OSTI]

A vertical two chamber reaction furnace. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium-copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700.degree. and 800.degree. C.) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800.degree. to 950.degree. C. to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product.

Blaugher, Richard D. (Evergreen, CO)

1999-03-16T23:59:59.000Z

87

Catalytic conversion of glycerol to oxygenated fuel additive in a continuous flow reactor: Process optimization  

E-Print Network [OSTI]

Catalytic conversion of glycerol to oxygenated fuel additive in a continuous flow reactor: Process optimization Malaya R. Nanda a , Zhongshun Yuan a , Wensheng Qin b , Hassan S. Ghaziaskar c , Marc for synthesis of solketal from glycerol was optimized. A maximum yield of 94 ± 2% was obtained at optimum

Qin, Wensheng

88

Non-carbon induction furnace  

DOE Patents [OSTI]

The present invention is directed to an induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of non-carbon materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloys. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an rf induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650/sup 0/C for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.

Holcombe, C.E.; Masters, D.R.; Pfeiler, W.A.

1984-01-06T23:59:59.000Z

89

Blast furnace taphole drill  

SciTech Connect (OSTI)

A blast furnace taphole drill has a flaring head with cutting edges at its cutting end formed by intersecting angled faces. A central bore carries cleaning air to the cutting end. To prevent blockage of the cleaning air bore by debris and possible jamming of the drill, the head has deep radial grooves formed at the bottoms of the valley shapes between the cutting edges. The grooves extend radially from the air bore and conduct the air so that it can get behind or under jammed debris. Reduced taphole drilling times can be achieved.

Gozeling, J.A.; de Boer, S.; Spiering, A.A.

1984-06-26T23:59:59.000Z

90

Furnaces | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Power Basics (TheEtelligence (SmartHomeFremont,using RenewableFurnaces Jump to:

91

Process for selection of Oxygen-tolerant algal mutants that produce H.sub.2  

DOE Patents [OSTI]

A process for selection of oxygen-tolerant, H.sub.2 -producing algal mutant cells comprising: (a) growing algal cells photoautotrophically under fluorescent light to mid log phase; (b) inducing algal cells grown photoautrophically under fluorescent light to mid log phase in step (a) anaerobically by (1) resuspending the cells in a buffer solution and making said suspension anaerobic with an inert gas; (2) incubating the suspension in the absence of light at ambient temperature; (c) treating the cells from step (b) with metronidazole, sodium azide, and added oxygen to controlled concentrations in the presence of white light. (d) washing off metronidazole and sodium azide to obtain final cell suspension; (e) plating said final cell suspension on a minimal medium and incubating in light at a temperature sufficient to enable colonies to appear; (f) counting the number of colonies to determine the percent of mutant survivors; and (g) testing survivors to identify oxygen-tolerant H.sub.2 -producing mutants.

Ghirardi, Maria L. (Lakewood, CO); Seibert, Michael (Lakewood, CO)

1999-01-01T23:59:59.000Z

92

Process for the conversion of lower alcohols to higher branched oxygenates  

DOE Patents [OSTI]

A process is provided for the production of branched C.sub.4+ oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

Barger, Paul T. (Arlington Heights, IL)

1996-01-01T23:59:59.000Z

93

Process for the conversion of lower alcohols to higher branched oxygenates  

DOE Patents [OSTI]

A process is provided for the production of branched C{sub x} oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

Barger, P.T.

1996-09-24T23:59:59.000Z

94

In Situ CO, Oxygen, and Opacity Measurement for Optimizing Combustion Control System Performance  

E-Print Network [OSTI]

Applications Alumino Kilns Bog Houses Carbon Black (Furnace Process) Cement KiIns Cool Fired Steam Generators Copper Smelters Electrostatic Precipitators Electr ic Arc Furnaces Fluid Catalytic Cracking Units Glass Furnaces Incinerators Industrial...

Molloy, R. C.

1982-01-01T23:59:59.000Z

95

High-Efficiency Low-Dross Combustion System for Aluminum Remelting Reverberatory Furnaces, Project Final Report, July 2005  

SciTech Connect (OSTI)

GTI, and its commercial partners, have developed a high-efficiency low-dross combustion system that offers environmental and energy efficiency benefits at lower capital costs for the secondary aluminum industry users of reverberatory furnaces. The high-efficiency low-dross combustion system, also called Self-Optimizing Combustion System (SOCS), includes the flex-flame burner firing an air or oxygen-enriched natural gas flame, a non-contact optical flame sensor, and a combustion control system. The flex-flame burner, developed and tested by GTI, provides an innovative firing process in which the flame shape and velocity can be controlled. The burner produces a flame that keeps oxygen away from the bath surface by including an O2-enriched fuel-rich zone on the bottom and an air-fired fuel-lean zone on the top. Flame shape and velocity can be changed at constant firing rate or held constant over a range of firing conditions. A non-intrusive optical sensor is used to monitor the flame at all times. Information from the optical sensor(s) and thermocouples can be used to control the flow of natural gas, air, and oxygen to the burner as needed to maintain desired flame characteristics. This type of control is particularly important to keep oxygen away from the melt surface and thus reduce dross formation. This retrofit technology decreases fuel usage, increases furnace production rate, lowers gaseous emissions, and reduces dross formation. The highest priority research need listed under Recycled Materials is to turn aluminum process waste into usable materials which this technology accomplishes directly by decreasing dross formation and therefore increasing aluminum yield from a gas-fired reverberatory furnace. Emissions of NOx will be reduced to approximately 0.3 lb/ton of aluminum, in compliance with air emission regulations.

Soupos, V.; Zelepouga, S.; Rue, D.

2005-06-30T23:59:59.000Z

96

Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process  

E-Print Network [OSTI]

and high temperature ion transport membranes. While polymeric membranes can produce oxygen enriched air of various concentrations, ion transport membranes can produce purities of close to 100%. Both membraHybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process Thomas

Struchtrup, Henning

97

Process Metallurgy Course Outline  

E-Print Network [OSTI]

-6 8 Reactor design 6 Midsession exam Week 6-7 8 Blast furnace ironmaking 7-8 Assignment 9 Reactions in the blast furnace 9 10 Development of the blast furnace ironmaking to decrease carbon footprint 9 11 Alternative ironmaking processes 10 12 Steelmaking: Bessemer and BOS processes, Electric arc furnace 10-11 13

New South Wales, University of

98

Rebuilding of Rautaruukki blast furnaces  

SciTech Connect (OSTI)

Rautaruukki Oy Raahe Steel rebuilt its blast furnaces in 1995 (BF1) and 1996 (BF2) after 10 year campaigns and production of 9,747 THM/m{sup 3} (303 NTHM/ft{sup 3}) and 9,535 THM/m{sup 3} (297 NTHM/ft{sup 3}), respectively. At the end of the campaigns, damaged cooling system and shell cracks were increasingly disturbing the availability of furnaces. The goal for rebuilding was to improve the cooling systems and refractory quality in order to attain a 15 year campaign. The furnaces were slightly enlarged to meet the future production demand. The blast furnace control rooms and operations were centralized and the automation and instrumentation level was considerably improved in order to improve the operation efficiency and to reduce manpower requirements. Investments in direct slag granulation and improved casthouse dedusting improved environmental protection. The paper describes the rebuilding.

Kallo, S.; Pisilae, E.; Ojala, K. [Rautaruukki Oy Raahe Steel (Finland)

1997-12-31T23:59:59.000Z

99

Process for selection of oxygen-tolerant algal mutants that produce H{sub 2}  

DOE Patents [OSTI]

A process for selection of oxygen-tolerant, H{sub 2}-producing algal mutant cells comprises: (a) growing algal cells photoautotrophically under fluorescent light to mid log phase; (b) inducing algal cells grown photoautotrophically under fluorescent light to mid log phase in step (a) anaerobically by (1) resuspending the cells in a buffer solution and making said suspension anaerobic with an inert gas and (2) incubating the suspension in the absence of light at ambient temperature; (c) treating the cells from step (b) with metronidazole, sodium azide, and added oxygen to controlled concentrations in the presence of white light; (d) washing off metronidazole and sodium azide to obtain final cell suspension; (e) plating said final cell suspension on a minimal medium and incubating in light at a temperature sufficient to enable colonies to appear; (f) counting the number of colonies to determine the percent of mutant survivors; and (g) testing survivors to identify oxygen-tolerant H{sub 2}-producing mutants. 5 figs.

Ghirardi, M.L.; Seibert, M.

1999-02-16T23:59:59.000Z

100

Oxygen sublattice defect in cobalt oxide : formation, migration, charge localization and thermodynamic processes  

E-Print Network [OSTI]

643 Oxygen sublattice defect in cobalt oxide : formation, migration, charge localization of oxygen defects in CoO using classical simulations. The charge localization in the oxygen vacancy has]. The defect concentration in the oxygen sublattice is several orders of magnitude smaller, but never- theless

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Semicoke production and quality at Chinese vertical SJ furnaces  

SciTech Connect (OSTI)

In Russia there has been little interest on the thermal processing of non-sintering coal. However it may be used to obtain many special types of coke and semicoke that are necessary for processes other than blast furnace smelting and employing small metallurgical coke fractions that do not meet the relevant quality requirements. China has recently made great progress in developing the thermal processing of coal (mainly energy coal) to obtain a highly effective product, semicoke, primarily used in metallurgy and adsorption process. The article considers the operation of a Chinese semicoking plant equipped with vertical SJ furnaces. The plant is in the Shenmu district of Shanxi province (Inner Mongolia). The enterprise includes two furnaces of total output of about 100,000 t/yr of semicoke.

V.M. Strakhov; I.V. Surovtseva; A.V. D'yachenko; V.M. Men'shenin [Kuznetsk Center, Eastern Coal-Chemistry Institute (Russian Federation)

2007-05-15T23:59:59.000Z

102

BPM Motors in Residential Gas Furnaces: What are the Savings?  

E-Print Network [OSTI]

of the total electricity consumption by BPM furnaces. Thisbecause furnace electricity consumption is significant.of furnace electricity consumption. Therefore, accurate

Lutz, James; Franco, Victor; Lekov, Alex; Wong-Parodi, Gabrielle

2006-01-01T23:59:59.000Z

103

Furnace Blower Electricity: National and Regional Savings Potential  

E-Print Network [OSTI]

Inc. Pigg, Scott. 2003. Electricity Use by New Furnaces: Astage furnaces offer national electricity savings, but withABORATORY Furnace Blower Electricity: National and Regional

Franco, Victor; Florida Solar Energy Center

2008-01-01T23:59:59.000Z

104

BPM Motors in Residential Gas Furnaces: What are the Savings?  

E-Print Network [OSTI]

standby power consumption in BPM furnaces is significantlytotal electricity consumption by BPM furnaces. This is notOverall, it appears the BPM motors used in furnaces offer

Lutz, James; Franco, Victor; Lekov, Alex; Wong-Parodi, Gabrielle

2006-01-01T23:59:59.000Z

105

Evaluation of Possible Surrogates for Validation of the Oxidation Furnace for the Plutonium Disposition Project  

SciTech Connect (OSTI)

The Plutonium Disposition project (PuD) is considering an alternative furnace design for direct metal oxidation (DMO) of plutonium metal to use as a feed for potential disposition routes. The proposed design will use a retort to oxidize the feed at temperatures up to 500 C. The atmosphere will be controlled using a metered mixture of oxygen, helium and argon to control the oxidation at approximately 400 torr. Since plutonium melts at 664 C, and may potentially react with retort material to form a lower melting point eutectic, the oxidation process will be controlled by metering the flow of oxygen to ensure that the bulk temperature of the material does not exceed this temperature. A batch processing time of <24 hours is desirable to meet anticipated furnace throughput requirements. The design project includes demonstration of concept in a small-scale demonstration test (i.e., small scale) and validation of design in a full-scale test. These tests are recommended to be performed using Pu surrogates due to challenges in consideration of the nature of plutonium and operational constraints required when handling large quantities of accountable material. The potential for spreading contamination and exposing workers to harmful levels of cumulative radioactive dose are motivation to utilize non-radioactive surrogates. Once the design is demonstrated and optimized, implementation would take place in a facility designed to accommodate these constraints. Until then, the use of surrogates would be a safer, less expensive option for the validation phase of the project. This report examines the potential for use of surrogates in the demonstration and validation of the DMO furnace for PuD. This report provides a compilation of the technical information and process requirements for the conversion of plutonium metal to oxide by burning in dry environments. Several potential surrogates were evaluated by various criteria in order to select a suitable candidate for large scale demonstration. First, the structure of the plutonium metal/oxide interface was compared to potential surrogates. Second the data for plutonium oxidation kinetics were reviewed and rates for oxidation were compared with surrogates. The criteria used as a basis for recommendation was selected in order to provide a reasonable oxidation rate during the validation phase. Several reference documents were reviewed and used to compile the information in this report. Since oxidation of large monolithic pieces of plutonium in 75% oxygen is the preferable oxidizing atmosphere for the intended process, this report does not focus on the oxidation of powders, but focuses instead on larger samples in flowing gas.

Duncan, A.

2007-12-31T23:59:59.000Z

106

Waste Heat Reduction and Recovery for Improving Furnace Efficiency, Productivity and Emissions Performance: A BestPractices Process Heating Technical Brief  

SciTech Connect (OSTI)

This technical brief is a guide to help plant operators reduce waste heat losses associated with process heating equipment.

Not Available

2004-11-01T23:59:59.000Z

107

Effect of Combustion Air Preheat on a Forged Furnace Productivity  

E-Print Network [OSTI]

to determine are the effects of combustion air preheat on four additional furnace operating characteristics. These characteristics are: (1) fuel utilization of a furnace operating cycle; (2) time to heat the furnace load; (3) scale production; and (4) furnace...

Ward, M. E.; Bohn, J.; Davis, S. R.; Knowles, D.

1984-01-01T23:59:59.000Z

108

Comparing Residential Furnace Blowers for  

E-Print Network [OSTI]

of air conditioner performance, standby power, as well as igniter and combustion air blower power results in 10% lower air conditioner efficiency. For heating, the advantage of the BPM blower was to assess the performance of residential furnace blowers for both heating, cooling and air distribution

109

Furnace Blower Electricity: National and Regional Savings Potential  

E-Print Network [OSTI]

Currently, total electricity consumption of furnaces isthe total furnace electricity consumption and are primarilyto calculate the electricity consumption during cooling

Franco, Victor; Florida Solar Energy Center

2008-01-01T23:59:59.000Z

110

Oxygen transport membrane system and method for transferring heat to catalytic/process reactors  

DOE Patents [OSTI]

A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

2014-01-07T23:59:59.000Z

111

Modeling energy consumption of residential furnaces and boilers in U.S. homes  

SciTech Connect (OSTI)

In 2001, DOE initiated a rulemaking process to consider whether to amend the existing energy efficiency standards for furnaces and boilers. A key factor in DOE's consideration of new standards is their cost-effectiveness to consumers. Determining cost-effectiveness requires an appropriate comparison of the additional first cost of energy efficiency design options with the savings in operating costs. This report describes calculation of equipment energy consumption (fuel and electricity) based on estimated conditions in a sample of homes that are representative of expected furnace and boiler installations. To represent actual houses with furnaces and boilers in the United States, we used a set of houses from the Residential Energy Consumption Survey of 1997 conducted by the Energy Information Administration. Our calculation methodology estimates the energy consumption of alternative (more-efficient) furnaces, if they were to be used in each house in place of the existing equipment. We developed the method of calculation described in this report for non-weatherized gas furnaces. We generalized the energy consumption calculation for this product class to the other furnace product classes. Fuel consumption calculations for boilers are similar to those for the other furnace product classes. The electricity calculations for boilers are simpler than for furnaces, because boilers do not provide thermal distribution for space cooling as furnaces often do.

Lutz, James; Dunham-Whitehead, Camilla; Lekov, Alex; McMahon, James

2004-02-01T23:59:59.000Z

112

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

113

Removing oxygen from a solvent extractant in an uranium recovery process  

DOE Patents [OSTI]

An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous and accumulation of complex iron phosphates or cruds.

Hurst, Fred J. (Oak Ridge, TN); Brown, Gilbert M. (Knoxville, TN); Posey, Franz A. (Concord, TN)

1984-01-01T23:59:59.000Z

114

Method for oxygen reduction in a uranium-recovery process. [US DOE patent application  

DOE Patents [OSTI]

An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous iron and accumulation of complex iron phosphates or cruds.

Hurst, F.J.; Brown, G.M.; Posey, F.A.

1981-11-04T23:59:59.000Z

115

Minimization of Blast furnace Fuel Rate by Optimizing Burden and Gas Distribution  

SciTech Connect (OSTI)

The goal of the research is to improve the competitive edge of steel mills by using the advanced CFD technology to optimize the gas and burden distributions inside a blast furnace for achieving the best gas utilization. A state-of-the-art 3-D CFD model has been developed for simulating the gas distribution inside a blast furnace at given burden conditions, burden distribution and blast parameters. The comprehensive 3-D CFD model has been validated by plant measurement data from an actual blast furnace. Validation of the sub-models is also achieved. The user friendly software package named Blast Furnace Shaft Simulator (BFSS) has been developed to simulate the blast furnace shaft process. The research has significant benefits to the steel industry with high productivity, low energy consumption, and improved environment.

Dr. Chenn Zhou

2012-08-15T23:59:59.000Z

116

Crystal growth furnace with trap doors  

DOE Patents [OSTI]

An improved furnace is provided for growing crystalline bodies from a melt. The improved furnace is characterized by a door assembly which is remotely controlled and is arranged so as to selectively shut off or permit communication between an access port in the furnace enclosure and a hot zone within that enclosure. The invention is especially adapted to facilitate use of crystal growing cartridges of the type disclosed in U.S. Pat. No. 4,118,197.

Sachs, Emanual M. (Watertown, MA); Mackintosh, Brian H. (Lexington, MA)

1982-06-15T23:59:59.000Z

117

Measurement of airflow in residential furnaces  

SciTech Connect (OSTI)

In order to have a standard for furnaces that includes electricity consumption or for the efficiency of furnace blowers to be determined, it is necessary to determine the airflow of a furnace or furnace blower. This study focused on airflow testing, in order to determine if an existing test method for measuring blower airflow could be used to measure the airflow of a furnace, under conditions seen in actual installations and to collect data and insights into the operating characteristics of various types of furnace blowers, to use in the analysis of the electricity consumption of furnaces. Results of the measured airflow on furnaces with three types of blower and motor combinations are presented in the report. These included: (1) a forward-curved blower wheel with a typical permanent split capacitor (PSC) motor, (2) a forward-curved blower wheel with an electronically-commutated motor (ECM), and (3) a prototype blower, consisting of a backward-inclined blower wheel matched to an ECM motor prototype, which is being developed as an energy-saving alternative to conventional furnace blowers. The testing provided data on power consumption, static and total pressure, and blower speed.

Biermayer, Peter J.; Lutz, James; Lekov, Alex

2004-01-24T23:59:59.000Z

118

Furnaces Data | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG | Department of Energy Freeport LNGEnergy Research | Department ofFurnaces

119

Raceway behaviors in blast furnace with pulverized coal injection  

SciTech Connect (OSTI)

The blast furnace raceway shows different characteristics with PCR (pulverized coal injection rate). It was found in this study that with the increase of PCR the raceway depth decreases, and the size of birds nest and sometimes with liquid holdup, increases. Oxygen enrichment with co-axial lances was known to be very effective on the extension of raceway depth and size reduction of birds nest. It was also found that there are various factors which affect the coke properties at tuyere level of the blast furnace. Coke traveling time was calculated to be extended with PCR and it had a close relationship with the coke size in bosh. Coke mean size decreased with the increase of coke traveling time, that is, with the increase of PCR. Both DI (the strength of coke in cold) and CSR (the strength of coke after reaction) were also decreased with PCR. RAFT (Raceway Adiabatic Flame Temperature) had a tendency to be decreased with the increase of PCR, which is obtained by the estimation of coke temperature via XRD analysis. From the analysis of alkali contents in coke sampled along the radius of the blast furnace, it was understood that no difference in alkali contents between fine and lump coke represents that coke fines generated from upper burden might appear at tuyere level.

Chung, J.K.; Han, J.W.; Cho, B.R. [POSCO, Cheollanamdo (Korea, Republic of)

1995-12-01T23:59:59.000Z

120

Steel project fact sheet: Steel reheating for further processing  

SciTech Connect (OSTI)

Steel reheating is an energy-intensive process requiring uniform temperature distribution within reheating furnaces. Historically, recuperators have ben used to preheat combustion air, thereby conserving energy. More recent innovations include oxygen enrichment and the use of regenerative burners, which provide higher preheat air temperatures than recuperators. These processes have limitations such as equipment deterioration, decreasing energy efficiency over time, high maintenance costs, and increased NO{sub x} emissions with increased air preheat temperature, unless special equipment is used. Praxair, Inc., supplier of oxygen and other industrial gases to the steel industry, proposes to introduce an innovative oxy-fuel burner technology (using 100% oxygen) to the steel reheating industry. Oxy-fuel combustion reduces or eliminates nitrogen in combustion air and substantially reduces waste heat carried out with flue gas. Based on technology currently used in the glass, hazardous waste, and aluminum industries, Praxair has developed and patented low temperature, oxy-fuel burners that can be used in high temperature industrial furnaces where temperature uniformity is critical and extremely low NO{sub x} emissions are desired. The technical goal of the project is to demonstrate the use of oxy-fuel burners in a slab reheat furnace while reducing energy consumption by 45% and NO{sub x} emissions by 90% within the converted furnace zones. Successful implementation of this technology also will eliminate the need to periodically replace recuperators and install NO{sub x} removal equipment.

NONE

1998-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Tuning magnetic properties of yttrium iron garnet film with oxygen partial pressure in sputtering and annealing process  

SciTech Connect (OSTI)

In this paper, the magnetic properties of these films which deposited and annealed at different atmospheres were investigated. The experimental results show that the magnetic properties of yttrium iron garnet films prepared by rf magnetron sputtering method can be tuned with oxygen partial pressure in sputtering and annealing processes. The optimal condition is depositing in atmosphere of R=0 and annealing at 0.5 Pa O{sub 2}, or depositing in atmosphere of R=2% and annealed in vacuum.

Yang Qinghui; Zhang Huaiwu; Wen Qiye; Liu Yingli [State Key Laboratory of Electronic Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Xiao, John Q. [Department of Physics and Astronomy, University of Delaware, Newark, Delaware 19716 (United States)

2009-04-01T23:59:59.000Z

122

Optical Furnace offers improved semiconductor device processing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002 WholesaleEnergy'sRunningOperations

123

Development of a Novel Oxygen Supply Process and its Integration with an Oxy-Fuel Coal-Fired Boiler  

SciTech Connect (OSTI)

BOC, the world's second largest industrial gas company, has developed a novel high temperature sorption based technology referred to as CAR (Cyclic Autothermal Recovery) for oxygen production and supply to oxy-fuel boilers with flue gas recycle. This technology is based on sorption and storage of oxygen in a fixed bed containing mixed ionic and electronic conductor materials. The objective of the proposed work was to construct a CAR PDU that was capable of producing 10-scfm of oxygen, using steam or recycled flue gas as the sweep gas, and install it in the Combustion Test Facility. The unit was designed and fabricated at BOC/The Linde Group, Murray Hill, New Jersey. The unit was then shipped to WRI where the site had been prepared for the unit by installation of air, carbon dioxide, natural gas, nitrogen, computer, electrical and infrastructure systems. Initial experiments with the PDU consisted of flowing air into both sides of the absorption systems and using the air heaters to ramp up the bed temperatures. The two beds were tested individually to operational temperatures up to 900 C in air. The cycling process was tested where gases are flowed alternatively from the top then bottom of the beds. The PDU unit behaved properly with respect to flow, pressure and heat during tests. The PDU was advanced to the point where oxygen production testing could begin and integration to the combustion test facility could occur.

None

2006-12-31T23:59:59.000Z

124

Oxygen enhanced switching to combustion of lower rank fuels  

DOE Patents [OSTI]

A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

Kobayashi, Hisashi; Bool III, Lawrence E.; Wu, Kuang Tsai

2004-03-02T23:59:59.000Z

125

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

126

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

127

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

128

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

129

Biomass Boiler and Furnace Emissions and Safety Regulations in...  

Open Energy Info (EERE)

Biomass Boiler and Furnace Emissions and Safety Regulations in the Northeast States Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Biomass Boiler and Furnace Emissions...

130

DOE Publishes Notice of Proposed Rulemaking for Residential Furnace...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Furnace Fans Energy Conservation Standards DOE Publishes Notice of Proposed Rulemaking for Residential Furnace Fans Energy Conservation Standards October 25, 2013 - 12:00am Addthis...

131

Optimizing Blast Furnace Operation to Increase Efficiency and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs cfdblastfurnace.pdf More...

132

Coal combustion under conditions of blast furnace injection  

SciTech Connect (OSTI)

Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal with particular reference to the coals from the Illinois Basin. Although this research is not yet completed the results to date support the following conclusions: (1) based on the results of computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in their injection properties with a variety of other bituminous coals, although the replacement ratio improves with increasing rank; (2) based on the results of petrographic analysis of material collected from an active blast furnace, it is clear the coal derived char is entering into the raceway of the blast furnace; (3) the results of reactivity experiments on a variety of coal chars at a variety of reaction temperatures show that lower rank bituminous coals, including coal from the Illinois basin, yield chars with significantly higher reactivities in both air and CO{sub 2} than chars from higher rank Appalachian coals and blast furnace coke. These results indicate that the chars from the lower rank coals should have a superior burnout rate in the tuyere and should survive in the raceway environment for a shorter time. These coals, therefore, will have important advantages at high rates of injection that may overcome their slightly lower replacement rates.

Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

1995-12-01T23:59:59.000Z

133

Alterations of bitumen produced by the in-situ combustion process at the oxygen Wolf Lake Project, Alberta  

SciTech Connect (OSTI)

The Oxygen Wolf Lake Project, operated by BP Resources Canada Limited, recovers bitumen by an in-situ combustion process. Bitumen samples produced from this process were analyzed and compared with analyses of unaltered bitumen from the same formation. The naphtha and middle distillate fractions were greater in the samples produced by the in-situ combustion process, which indicates thermal cracking has occurred. Gas chromatograph and Mass Spectral analyses of these samples have been used to further describe the changes to the oil. The compositional changes found in the study have been related to reductions in viscosity and density. Implications of bitumen alterations to the performance of the combustion process and production problems are discussed.

Riechert, C.; Fuhr, B. (Alberta Research Council, Edmonton (Canada)); Williams, G. (British Petroleum Canada Ltd., Calgary, Alberta (Canada)); Sawatzky, H.; Jha, K.; Lafleur, R. (Canmet, Energy Mines and Resources Canada, Ottawa, Ontario (Canada))

1989-04-01T23:59:59.000Z

134

Time and Temperature Test Results for PFP Thermal Stabilization Furnaces  

SciTech Connect (OSTI)

The national standard for plutonium storage acceptability (standard DOE-STD-3013-99, generally known as ''the 3013 standard'') has been revised to clarify the requirement for processes that will produce acceptable storage materials. The 3013 standard (Reference 1) now states that ''Oxides shall be stabilized by heating the material in an oxidizing atmosphere to a Material Temperature of at least 950 C (1742 F) for not less than 2 hours.'' The process currently in use for producing stable oxides for storage at the Plutonium Finishing Plant (PFP) heats a furnace atmosphere to 1000 C and holds it there for 2 hours. The temperature of the material being stabilized is not measured directly during this process. The Plutonium Process Support Laboratories (PPSL) were requested to demonstrate that the process currently in use at PFP is an acceptable method of producing stable plutonium dioxide consistently. A spare furnace identical to the production furnaces was set up and tested under varying conditions with non-radioactive surrogate materials. Reference 2 was issued to guide the testing program. The process currently in use at the PFP for stabilizing plutonium-bearing powders was shown to heat all the material in the furnace to at least 950 C for at least 2 hours. The current process will work for (1) relatively pure plutonium dioxide, (2) dioxide powders mixed with up to 20 weight percent magnesium oxide, and (3) dioxide powders with up to 11 weight percent magnesium oxide and 20 weight percent magnesium nitrate hexahydrate. Time and temperature data were also consistent with a successful demonstration for a mixture containing 10 weight percent each of sodium and potassium chloride; however, the molten chloride salts destroyed the thermocouples in the powder and temperature data were unavailable for part of that run. These results assume that the current operating limits of no more than 2500 grams per furnace charge and a powder height of no more than 1.5 inches remain in effect, although deeper powder beds (up to 2 inches) also yielded temperatures of greater than 950 C for longer than 2 hours.

COMPTON, J.A.

2000-08-09T23:59:59.000Z

135

Recycling of electric-arc-furnace dust  

SciTech Connect (OSTI)

Electric arc furnace (EAF) dust is one of the largest solid waste streams produced by steel mills, and is classified as a waste under the Resource Conservation and Recovery Act (RCRA) by the U.S. Environmental Protection Agency (EPA). Successful recycle of the valuable metals (iron, zinc, and lead) present in the dust will result in resource conservation while simultaneously reducing the disposal problems. Technical feasibility of a novel recycling method based on using hydrogen as the reductant was established under this project through laboratory experiments. Sponge iron produced was low in zinc, cadmium, and lead to permit its recycle, and nontoxic to permit its safe disposal as an alternative to recycling. Zinc oxide was analyzed to contain 50% to 58% zinc by weight, and can be marketed for recovering zinc and lead. A prototype system was designed to process 2.5 tons per day (600 tons/year) of EAF dust, and a preliminary economic analysis was conducted. The cost of processing dust by this recycling method was estimated to be comparable to or lower than existing methods, even at such low capacities.

Sresty, G.C.

1990-05-01T23:59:59.000Z

136

Plasma-supported coal combustion in boiler furnace  

SciTech Connect (OSTI)

Plasma activation promotes more effective and environmentally friendly low-rank coal combustion. This paper presents Plasma Fuel Systems that increase the burning efficiency of coal. The systems were tested for fuel oil-free start-up of coal-fired boilers and stabilization of a pulverized-coal flame in power-generating boilers equipped with different types of burners, and burning all types of power-generating coal. Also, numerical modeling results of a plasma thermochemical preparation of pulverized coal for ignition and combustion in the furnace of a utility boiler are discussed in this paper. Two kinetic mathematical models were used in the investigation of the processes of air/fuel mixture plasma activation: ignition and combustion. A I-D kinetic code PLASMA-COAL calculates the concentrations of species, temperatures, and velocities of the treated coal/air mixture in a burner incorporating a plasma source. The I-D simulation results are initial data for the 3-D-modeling of power boiler furnaces by the code FLOREAN. A comprehensive image of plasma-activated coal combustion processes in a furnace of a pulverized-coal-fired boiler was obtained. The advantages of the plasma technology are clearly demonstrated.

Askarova, A.S.; Karpenko, E.I.; Lavrishcheva, Y.I.; Messerle, V.E.; Ustimenko, A.B. [Kazakh National University, Alma Ata (Kazakhstan). Dept. of Physics

2007-12-15T23:59:59.000Z

137

A consortium approach to glass furnace modeling.  

SciTech Connect (OSTI)

Using computational fluid dynamics to model a glass furnace is a difficult task for any one glass company, laboratory, or university to accomplish. The task of building a computational model of the furnace requires knowledge and experience in modeling two dissimilar regimes (the combustion space and the liquid glass bath), along with the skill necessary to couple these two regimes. Also, a detailed set of experimental data is needed in order to evaluate the output of the code to ensure that the code is providing proper results. Since all these diverse skills are not present in any one research institution, a consortium was formed between Argonne National Laboratory, Purdue University, Mississippi State University, and five glass companies in order to marshal these skills into one three-year program. The objective of this program is to develop a fully coupled, validated simulation of a glass melting furnace that may be used by industry to optimize the performance of existing furnaces.

Chang, S.-L.; Golchert, B.; Petrick, M.

1999-04-20T23:59:59.000Z

138

Energy Assessment Protocol for Glass Furnaces  

E-Print Network [OSTI]

The Department of Energy funded development of a methodology that could be used by glass producers to increase furnace efficiency, and that could serve as a model for other energy-intensive industries. Accordingly, a team comprising PPG Industries...

Plodinec, M. J.; Kauffman, B. M.; Norton, O. P.; Richards, C.; Connors, J.; Wishnick, D.

2005-01-01T23:59:59.000Z

139

Blast-furnace ironmaking -- Existing capital and continued improvements are a winning formula for a bright future  

SciTech Connect (OSTI)

Throughout the years the blast-furnace process has been improved upon significantly. Increases to the hot-blast temperature, improvements to the physical, chemical, and metallurgical properties of coke and burden materials, the use of more fuel injectants, and improvements to the design of the furnace facilities have led to significant decreases in furnace coke rate, increases in productivity, and increases in furnace campaign life. As a result, many of the alternative cokeless reduction processes have not replaced blast-furnace hot-metal production in North America. In the future, these continued blast-furnace improvements will potentially result in coke rates decreasing to 400 pounds per net ton of hot metal (lb/NTHM) as more pulverized coal is injected. These improvements, coupled with the fact that existing blast furnaces and coke plants can be refurbished for approximately $110 per annual ton of hot metal [$100 per annual net ton of hot metal (NTHM)], will result in extending the life of the North American blast furnaces well into the twenty-first century.

Oshnock, T.W.; Colinear, J.A. [U.S. Steel, Monroeville, PA (United States)

1995-12-01T23:59:59.000Z

140

Optimized Design of a Furnace Cooling System  

E-Print Network [OSTI]

-evaluate the dynamics of heat transfer for a key piece of industrial equipment, a sintering furnace. The goal is to optimize furnace operations to relieve an operations bottleneck for a tungsten carbide drill nozzle production facility. In light of plans to mitigate... convection are the radiation shield and the inner chamber door. 2) Analysis Preliminary analysis and calculations have been made to determine the impact of increased convection. This was done by creating a theoretical spherical mass of tungsten carbide...

Morelli, F.; Bretschneider, R.; Dauzat, J.; Guymon, M.; Studebaker, J.; Rasmussen, B. P.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Dilute Oxygen Combustion - Phase 3 Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, Michael F.

2000-05-31T23:59:59.000Z

142

Dilute Oxygen Combustion Phase 3 Final Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, M.F.; Ryan, H.M.

2000-05-31T23:59:59.000Z

143

Computational fluid dynamics modeling of chemical looping combustion process with calcium sulphate oxygen carrier - article no. A19  

SciTech Connect (OSTI)

To concentrate CO{sub 2} in combustion processes by efficient and energy-saving ways is a first and very important step for its sequestration. Chemical looping combustion (CLC) could easily achieve this goal. A chemical-looping combustion system consists of a fuel reactor and an air reactor. Two reactors in the form of interconnected fluidized beds are used in the process: (1) a fuel reactor where the oxygen carrier is reduced by reaction with the fuel, and (2) an air reactor where the reduced oxygen carrier from the fuel reactor is oxidized with air. The outlet gas from the fuel reactor consists of CO{sub 2} and H{sub 2}O, while the outlet gas stream from the air reactor contains only N{sub 2} and some unused O{sub 2}. The water in combustion products can be easily removed by condensation and pure carbon dioxide is obtained without any loss of energy for separation. Until now, there is little literature about mathematical modeling of chemical-looping combustion using the computational fluid dynamics (CFD) approach. In this work, the reaction kinetic model of the fuel reactor (CaSO{sub 4}+ H{sub 2}) is developed by means of the commercial code FLUENT and the effects of partial pressure of H{sub 2} (concentration of H{sub 2}) on chemical looping combustion performance are also studied. The results show that the concentration of H{sub 2} could enhance the CLC performance.

Baosheng Jin; Rui Xiao; Zhongyi Deng; Qilei Song [Southeast University (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education

2009-07-01T23:59:59.000Z

144

Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies  

SciTech Connect (OSTI)

The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting iron ore to metallic iron nodules. Various types of coals including a bio-coal produced though torrefaction can result in production of NRI at reduced GHG levels. The process results coupled with earlier already reported developments indicate that this process technique should be evaluated at the next level in order to develop parameter information for full scale process design. Implementation of the process to full commercialization will require a full cost production analysis and comparison to other reduction technologies and iron production alternatives. The technical results verify that high quality NRI can be produced under various operating conditions at the pilot level.

Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

2011-12-22T23:59:59.000Z

145

RCRA, superfund and EPCRA hotline training module. Introduction to: Boilers and industrial furnaces (40 cfr part 266, subpart h) updated July 1996  

SciTech Connect (OSTI)

The module summarizes the regulations affecting hazardous waste processes in boilers and industrial furnaces (BIFs). If defines boilers and industrial furnaces and describes the criteria associated with the definitions. It describes the requirements for processing hazardous waste in BIFs, including the distinctions between permitted and interim status units. It explains the requirements for the specially regulated BIFs and gives examples of each.

NONE

1996-07-01T23:59:59.000Z

146

Coke oven gas injection to blast furnaces  

SciTech Connect (OSTI)

U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

1995-12-01T23:59:59.000Z

147

Pyrometric temperature measurement method and apparatus for measuring particle temperatures in hot furnaces: Application to reacting black liquor  

SciTech Connect (OSTI)

A specialized two-color pyrometric method has been developed for the measurement of particle surface temperatures in hot, radiating environments. In this work, the method has been applied to the measurement of surface temperatures of single reacting black liquor char particles in an electrically heated muffle furnace. Black liquor was introduced into the hot furnace as wet droplets. After drying, the resulted particles were processed in different atmospheres corresponding to combustion, pyrolysis, and gasification at furnace temperatures of 700{endash}900{degree}C. The pyrometric measurement is performed using two silicon photodiode detectors and 10 nm bandpass filters centered at 650 and 1050 nm. Thermal radiation is transferred using an uncooled fiberoptic probe brought into the vicinity of the char particle. The key features of the pyrometric apparatus and analysis method are: (1) Single particle temperature is resolved temporally at high speed. (2) The thermal radiation originating from the furnace and reflected by the particle is accounted for in the measurement of the surface temperature. (3) Particle temperatures above or below the furnace temperature can be measured without the need of a cooled background assisting the measurement in the hot furnace. To accomplish this, a minimum particle size is needed that is a function of the temperature difference between the particle and furnace. Particles cooler than the furnace can be measured if their diameter is more than 0.7 mm. Surface temperatures of 300{endash}400{degree}C above the furnace temperature were measured during combustion of black liquor char particles in air. In atmospheres corresponding to gasification, endothermic reactions occurred, and char temperature remained typically 40{degree} below the furnace temperature. {copyright} {ital 1996 American Institute of Physics.}

Stenberg, J. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Frederick, W.J. [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States)] [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States); Bostroem, S. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland); Hernberg, R. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Hupa, M. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)

1996-05-01T23:59:59.000Z

148

New processes to recovery methanol and remove oxygenates from Valero MTBE unit  

SciTech Connect (OSTI)

The refiner today has to evaluate every available option to increase octane in the gasoline pool to make up for the loss in octane created by lead phase down. Production of MTBE is one of the most attractive options. MTBE is produced by selectivity reacting isobutylene with methanol. Valero Refining's refinery at Corpus Christie, Texas (formerly Saber Refining) is one of the most modern refineries built in the last decade to upgrade resids. As part of the gasoline upgrading Valero had built a Butamer Unit to convert normal butane to isobutane upstream of their HF Alkylation Unit. In 1984 as an ongoing optimization of its operations, Valero Refining evaluated various processes to enable it to increase the octane output, and decided to build an MTBE unit. Valero selected the MTBE process licensed by Arco Technology, Inc. and contracted with Jacobs Engineering Group, Inc., Houston, Texas to provide detailed engineering and procurement services.

Hillen, P.; Clemmons, J.

1987-01-01T23:59:59.000Z

149

Continuous austempering fluidized bed furnace. Final report  

SciTech Connect (OSTI)

The intended objective of this project was to show the benefits of using a fluidized bed furnace for austenitizing and austempering of steel castings in a continuous manner. The division of responsibilities was as follows: (1) design of the fluidized bed furnace--Kemp Development Corporation; (2) fabrication of the fluidized bed furnace--Quality Electric Steel, Inc.; (3) procedure for austempering of steel castings, analysis of the results after austempering--Texas A and M University (Texas Engineering Experiment Station). The Department of Energy provided funding to Texas A and M University and Kemp Development Corporation. The responsibility of Quality Electric Steel was to fabricate the fluidized bed, make test castings and perform austempering of the steel castings in the fluidized bed, at their own expense. The project goals had to be reviewed several times due to financial constraints and technical difficulties encountered during the course of the project. The modifications made and the associated events are listed in chronological order.

Srinivasan, M.N. [Lamar Univ., Beaumont, TX (United States). Dept. of Mechanical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Mechanical Engineering

1997-09-23T23:59:59.000Z

150

Graphite electrode DC arc furnace. Innovative technology summary report  

SciTech Connect (OSTI)

The Graphite Electrode DC Arc Furnace (DC Arc) is a high-temperature thermal process, which has been adapted from a commercial technology, for the treatment of mixed waste. A DC Arc Furnace heats waste to a temperature such that the waste is converted into a molten form that cools into a stable glassy and/or crystalline waste form. Hazardous organics are destroyed through combustion or pyrolysis during the process and the majority of the hazardous metals and radioactive components are incorporated in the molten phase. The DC Arc Furnace chamber temperature is approximately 593--704 C and melt temperatures are as high as 1,500 C. The DC Arc system has an air pollution control system (APCS) to remove particulate and volatiles from the offgas. The advantage of the DC Arc is that it is a single, high-temperature thermal process that minimizes the need for multiple treatment systems and for extensive sorting/segregating of large volumes of waste. The DC Arc has the potential to treat a wide range of wastes, minimize the need for sorting, reduce the final waste volumes, produce a leach resistant waste form, and destroy organic contaminants. Although the DC arc plasma furnace exhibits great promise for treating the types of mixed waste that are commonly present at many DOE sites, several data and technology deficiencies were identified by the Mixed Waste Focus Area (MWFA) regarding this thermal waste processing technique. The technology deficiencies that have been addressed by the current studies include: establishing the partitioning behavior of radionuclides, surrogates, and hazardous metals among the product streams (metal, slag, and offgas) as a function of operating parameters, including melt temperature, plenum atmosphere, organic loading, chloride concentration, and particle size; demonstrating the efficacy of waste product removal systems for slag and metal phases; determining component durability through test runs of extended duration, evaluating the effect of feed composition variations on process operating conditions and slag product performance; and collecting mass balance and operating data to support equipment and instrument design.

NONE

1999-05-01T23:59:59.000Z

151

Segmented ceramic liner for induction furnaces  

DOE Patents [OSTI]

A non-fibrous ceramic liner for induction furnaces is provided by vertically stackable ring-shaped liner segments made of ceramic material in a light-weight cellular form. The liner segments can each be fabricated as a single unit or from a plurality of arcuate segments joined together by an interlocking mechanism. Also, the liner segments can be formed of a single ceramic material or can be constructed of multiple concentric layers with the layers being of different ceramic materials and/or cellular forms. Thermomechanically damaged liner segments are selectively replaceable in the furnace. 5 figs.

Gorin, A.H.; Holcombe, C.E.

1994-07-26T23:59:59.000Z

152

Nitrogen Control in Electric Arc Furnace Steelmaking by DRI (TRP 0009)  

SciTech Connect (OSTI)

Nitrogen is difficult to remove in electric arc furnace (EAF) steelmaking, requiring the use of more energy in the oxygen steelmaking route to produce low-nitrogen steel. The objective of this work was to determine if the injection of directly reduced iron (DRI) fines into EAFs could reduce the nitrogen content by creating fine carbon monoxide bubbles that rinse nitrogen from the steel. The proposed work included physical and chemical characterization of DRI fines, pilot-scale injection into steel, and mathematical modeling to aid in scale-up of the process. Unfortunately, the pilot-scale injections were unsuccessful, but some full-scale data was obtained. Therefore, the original objectives were met, and presented in the form of recommendations to EAF steelmakers regarding: (1) The best composition and size of DRI fines to use; (2) The amount of DRI fines required to achieve a specific reduction in nitrogen content in the steel; and (3) The injection conditions. This information may be used by steelmakers in techno-economic assessments of the cost of reducing nitrogen with this technology.

Dr. Gordon A. Irons

2004-03-31T23:59:59.000Z

153

Design and fabrication of a tin-sulfide annealing furnace  

E-Print Network [OSTI]

A furnace was designed and its heat transfer properties were analyzed for use in annealing thin-film tins-ulfide solar cells. Tin sulfide has been explored as an earth abundant solar cell material, and the furnace was ...

Lewis, Raymond (Raymond A.)

2011-01-01T23:59:59.000Z

154

DOE Publishes Final Rule for Residential Furnace Fan Test Procedure...  

Broader source: Energy.gov (indexed) [DOE]

Residential Furnace Fan Test Procedure DOE Publishes Final Rule for Residential Furnace Fan Test Procedure January 3, 2014 - 12:00am Addthis The Department of Energy (DOE) has...

155

Furnace Blower Electricity: National and Regional Savings Potential  

E-Print Network [OSTI]

Solar Energy Center ABSTRACT Currently, total electricity consumption of furnacesFurnace Blower Electricity: National and Regional Savings Potential Victor Franco, James Lutz, Alex Lekov, and Lixing Gu (Florida Solar

Franco, Victor; Florida Solar Energy Center

2008-01-01T23:59:59.000Z

156

Residential Two-Stage Gas Furnaces - Do They Save Energy?  

E-Print Network [OSTI]

of two-stage furnaces with BPM motors provides electricityof two-stage furnaces with BPM motors provides electricityPSC) and brushless permanent magnet (BPM) 1 . PSC motors are

Lekov, Alex; Franco, Victor; Lutz, James

2006-01-01T23:59:59.000Z

157

A Feasibility Study for Recycling Used Automotive Oil Filters In A Blast Furnace  

SciTech Connect (OSTI)

This feasibility study has indicated that of the approximately 120,000 tons of steel available to be recycled from used oil filters (UOF's), a maximum blast furnace charge of 2% of the burden may be anticipated for short term use of a few months. The oil contained in the most readily processed UOF's being properly hot drained and crushed is approximately 12% to 14% by weight. This oil will be pyrolized at a rate of 98% resulting in additional fuel gas of 68% and a condensable hydrocarbon fraction of 30%, with the remaining 2% resulting as carbon being added into the burden. Based upon the writer's collected information and assessment, there appears to be no operational problems relating to the recycling of UOF's to the blast furnace. One steel plant in the US has been routinely charging UOF's at about 100 tons to 200 tons per month for many years. Extensive analysis and calculations appear to indicate no toxic consideration as a result of the pyrolysis of the small contained oil ( in the 'prepared' UOFs) within the blast furnace. However, a hydrocarbon condensate in the ''gasoline'' fraction will condense in the blast furnace scrubber water and may require additional processing the water treatment system to remove benzene and toluene from the condensate. Used oil filters represent an additional source of high quality iron units that may be effectively added to the charge of a blast furnace for beneficial value to the operator and to the removal of this resource from landfills.

Ralph M. Smailer; Gregory L. Dressel; Jennifer Hsu Hill

2002-01-21T23:59:59.000Z

158

Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993  

SciTech Connect (OSTI)

A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

Crelling, J.C.

1993-12-31T23:59:59.000Z

159

Dofasco`s No. 4 blast furnace hearth breakout, repair and rescue  

SciTech Connect (OSTI)

On May 5, 1994, after producing 9.5 million metric tons of iron, Dofasco`s No. 4 Blast Furnace experienced a hearth breakout 250 millimeters below the west taphole. The hot metal spill caused a fire resulting in severe damage and 33 days of lost production. During a 26-day period, electrical wiring, water drainage systems and both tapholes were repaired. Recovery from an unprepared furnace stop of this length, with the deadman depleted is difficult. To aid with the rescue Hoogovens-designed oxygen/fuel lances were commissioned. The furnace recovery began with a lance in each taphole and all tuyeres plugged. Six days after startup the furnace was casting into torpedo cars, and after nine days operation had returned to normal. This incident prompted Dofasco to expand the hearth monitoring system to detect and prevent similar occurrences. During the repair, 203 new thermocouples were installed in the hearth, concentrating on the tapholes and elephant foot areas. These thermocouples were installed at various depths and locations to allow heat flux calculations. This hearth monitoring system has already identified other problem areas and provided valuable information about hearth drainage patterns. This information has allowed them to develop control strategies to manage localized problem areas.

Donaldson, R.J.; Fischer, A.J.; Sharp, R.M.; Stothart, D.W. [Dofasco Inc., Hamilton, Ontario (Canada)

1995-12-01T23:59:59.000Z

160

Install Waste Heat Recovery Systems for Fuel-Fired Furnaces (English/Chinese) (Fact Sheet)  

SciTech Connect (OSTI)

Chinese translation of ITP fact sheet about installing Waste Heat Recovery Systems for Fuel-Fired Furnaces. For most fuel-fired heating equipment, a large amount of the heat supplied is wasted as exhaust or flue gases. In furnaces, air and fuel are mixed and burned to generate heat, some of which is transferred to the heating device and its load. When the heat transfer reaches its practical limit, the spent combustion gases are removed from the furnace via a flue or stack. At this point, these gases still hold considerable thermal energy. In many systems, this is the greatest single heat loss. The energy efficiency can often be increased by using waste heat gas recovery systems to capture and use some of the energy in the flue gas. For natural gas-based systems, the amount of heat contained in the flue gases as a percentage of the heat input in a heating system can be estimated by using Figure 1. Exhaust gas loss or waste heat depends on flue gas temperature and its mass flow, or in practical terms, excess air resulting from combustion air supply and air leakage into the furnace. The excess air can be estimated by measuring oxygen percentage in the flue gases.

Not Available

2011-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Heat Recovery From Arc Furnaces Using Water Cooled Panels  

E-Print Network [OSTI]

HEAT RECOVERY FROM ARC FURNACES USING WATER COOLED PANELS D. F. Darby Deere & Company Moline, Illinois ABSTRACT In 1980-81, the John Deere Foundry at East Moline underwent an expansion program that in creased its capacity by over 60...%. This expansion was centered around the melt department where the four existing 13MVA electric arc furnaces were augmented with two additional 13MVA arc furnaces. A waste heat recovery system was installed on all six of the arc furnaces which, with modifica...

Darby, D. F.

162

Residential Two-Stage Gas Furnaces - Do They Save Energy?  

E-Print Network [OSTI]

total fuel and electricity consumption under laboratoryto decrease the electricity consumption of furnaces, mainlytotal fuel and electricity consumption under laboratory

Lekov, Alex; Franco, Victor; Lutz, James

2006-01-01T23:59:59.000Z

163

Covered Product Category: Residential Gas Furnaces  

Broader source: Energy.gov [DOE]

FEMP provides acquisition guidance across a variety of product categories, including residential gas furnaces, which are an ENERGY STAR®-qualified product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

164

Partial SOP for Tube Anneal Furnace, EML: 9/04 Instructions for temp controller for Anneal furnace  

E-Print Network [OSTI]

Partial SOP for Tube Anneal Furnace, EML: 9/04 Instructions for temp controller for Anneal furnace the "C" clamp. Take the ceramic and quartz end caps off. 2. Load your samples into a quartz boat. Load

Reif, Rafael

165

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect (OSTI)

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the report for the time period April 1, 2002 through September 30, 2002. During the current period, process economic estimates were developed, comparing the costs of the furnace magnesium hydroxide slurry injection process tested as part of this project to a number of other candidate SO{sub 3}/sulfuric acid control technologies for coal-fired power plants. The results of this economic evaluation are included in this progress report.

Gary M. Blythe

2003-10-01T23:59:59.000Z

166

Energy Efficiency Improvement by Measurement and Control: A Case Study of Reheating Furnaces in the Steel Industry  

E-Print Network [OSTI]

ENERGY EFFICIENCY IMPROVEMENT BY MEASUREMENT AND CONTROL A case study of reheating furnaces in the steel industry Anders Mlirtensson Department of Environmental and Energy Systems Studies Lund University S-22362 Lund Sweden ABSTRACT... of process studied, as a result of approach using steel reheating furnaces as a case study. investments in information technology; it is also concluded that The steel industry is a large user of energy: in Sweden it used such investments are cost...

Martensson, A.

167

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

168

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL  

SciTech Connect (OSTI)

The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

Gary M. Blythe

2004-01-01T23:59:59.000Z

169

Temperatures in the blast furnace refractory lining  

SciTech Connect (OSTI)

The campaign life duration of a blast furnace is mainly determined by the condition of the refractory lining in heavy-duty zones such as the hearth, bosh, belly and lower stack. To achieve a desired lifetime, the temperature of the lining in these areas thereby proved to be the decisive controllable parameter. Low operating temperatures result in prolonged service life and are attained through high cooling efficiency. Besides the refractory grade chosen, the wear profile is mainly determined by the type of cooling system applied and the cooling intensity. Therefore, an appropriate compromise between long service life and energy losses has to be found in each case. In order to predict the service life of a lining it is important to know the wear condition at all times during the campaign. The paper describes the approaches the authors have made so far on European blast furnaces, on a theoretical and practical basis, on how to analyze the lining wear.

Hebel, R.; Streuber, C. [Didier-M and P Energietechnik GmbH, Wiesbaden (Germany); Steiger, R. [Didier-M and P Engineering Services, Highland, IN (United States); Jeschar, R. [TU Clausthal (Germany). Inst. fuer Energieverfahrenstechnik und Brennstofftechnik

1995-12-01T23:59:59.000Z

170

Pulverized coal firing of aluminum melting furnaces. Second annual technical progress report, July 1979-June 1980  

SciTech Connect (OSTI)

The ultimate objective of this program is the commercial demonstration of an efficient, environmentally acceptable coal firing process suitable for implementation on melting furnaces throughout the aluminum industry. To achieve this goal, the program has been divided into two phases. Phase I has proceeded through design and construction of a 350 pound (coal) per hour staged slagging cyclone combustor (SSCC) attached to a 7-ft diameter aluminum melting ladle furnace. Process development will culminate with a 1000 pph prototype SSCC firing a 40,000 pound capacity open hearth melting furnace at the Alcoa Laboratories. Phase II implementation is currently planned for Alcoa's Lafayette, IN, Works, where two of the ingot plant's five open hearth melting furnaces will be converted to utilize coal. In addition to confirmation of data gathered in Phase I, the effect of extended production schedule operation on equipment and efficiencies will be determined. This work would begin in 1982 pursuant to technical and economic evaluation of the process development at that time.

West, C E; Stewart, D L

1980-08-01T23:59:59.000Z

171

Pulverized coal firing of aluminum melting furnaces. Quarterly technical progress report, July 1-September 30, 1979  

SciTech Connect (OSTI)

The ultimate objective of this program is the commercial demonstration of an efficient, environmentally acceptable coal firing process suitable for implementation on melting furnaces throughout the aluminum industry. To achieve this goal, the program has been divided into two phases. Phase I has begun with the design and construction of a 350 pound (coal) per hour staged slagging cyclone combustor (SSCC) attached to a 7-ft diameter aluminum melting ladle furnace. Process development will culminate with a 1000 pph prototype SSCC firing a 40,000 pound capacity open hearth melting furnace at the Alcoa Laboratories. Phase II implementation is currently planned for Alcoa's Lafayette, IN, Works, where two of the ingot plant's five open hearth melting furnaces will be converted to utilize coal. In addition to confirmation of data gathered in Phase I, the effect of extended production schedule operation on equipment and efficiencies will be determined. This work would begin in 1982 pursuant to technical and economic evaluation of the process development at that time.

West, C E

1980-09-01T23:59:59.000Z

172

Reduce Air Infiltration in Furnaces (English/Chinese) (Fact Sheet)  

SciTech Connect (OSTI)

Chinese translation of the Reduce Air Infiltration in Furnaces fact sheet. Provides suggestions on how to improve furnace energy efficiency. Fuel-fired furnaces discharge combustion products through a stack or a chimney. Hot furnace gases are less dense and more buoyant than ambient air, so they rise, creating a differential pressure between the top and the bottom of the furnace. This differential, known as thermal head, is the source of a natural draft or negative pressure in furnaces and boilers. A well-designed furnace (or boiler) is built to avoid air leakage into the furnace or leakage of flue gases from the furnace to the ambient. However, with time, most furnaces develop cracks or openings around doors, joints, and hearth seals. These openings (leaks) usually appear small compared with the overall dimensions of the furnace, so they are often ignored. The negative pressure created by the natural draft (or use of an induced-draft fan) in a furnace draws cold air through the openings (leaks) and into the furnace. The cold air becomes heated to the furnace exhaust gas temperature and then exits through the flue system, wasting valuable fuel. It might also cause excessive oxidation of metals or other materials in the furnaces. The heat loss due to cold air leakage resulting from the natural draft can be estimated if you know four major parameters: (1) The furnace or flue gas temperature; (2) The vertical distance H between the opening (leak) and the point where the exhaust gases leave the furnace and its flue system (if the leak is along a vertical surface, H will be an average value); (3) The area of the leak, in square inches; and (4) The amount of operating time the furnace spends at negative pressure. Secondary parameters that affect the amount of air leakage include these: (1) The furnace firing rate; (2) The flue gas velocity through the stack or the stack cross-section area; (3) The burner operating conditions (e.g., excess air, combustion air temperature, and so on). For furnaces or boilers using an induced-draft (ID) fan, the furnace negative pressure depends on the fan performance and frictional losses between the fan inlet and the point of air leakage. In most cases, it would be necessary to measure or estimate negative pressure at the opening. The amount of air leakage, the heat lost in flue gases, and their effects on increased furnace or boiler fuel consumption can be calculated by using the equations and graphs given in Industrial Furnaces (see W. Trinks et al., below). Note that the actual heat input required to compensate for the heat loss in flue gases due to air leakage would be greater than the heat contained in the air leakage because of the effect of available heat in the furnace. For a high-temperature furnace that is not maintained properly, the fuel consumption increase due to air leakage can be as high as 10% of the fuel input.

Not Available

2011-10-01T23:59:59.000Z

173

Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace  

SciTech Connect (OSTI)

Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

Dr. Chenn Zhou

2008-10-15T23:59:59.000Z

174

Benefits of ceramic fiber for saving energy in reheat furnaces  

SciTech Connect (OSTI)

Refractory ceramic fiber products offer thermal insulation investment in reheat furnaces by helping to keep operating cost low and product quality high. These products are used in a range of applications that include: furnace linings; charge and discharge door insulation; skidpipe insulation; and furnace repair and maintenance. The many product forms (blankets, modules, boards, textiles, and coatings) provide several key benefits: faster cycling, energy savings and personnel protection.

Norris, A. (Carborundum Co., Niagara Falls, NY (United States))

1993-07-01T23:59:59.000Z

175

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

176

Laser-induced breakdown spectroscopy at high temperatures in industrial boilers and furnaces.  

SciTech Connect (OSTI)

Laser-induced breakdown spectroscopy (LIBS) was applied (1) near the superheater of an electric power generation boiler burning biomass, coat, or both, (2) at the exit of a glass-melting furnace burning natural gas and oxygen, and (3) near the nose arches of two paper mill recovery boilers burning black liquor. Difficulties associated with the high temperatures and high particle loadings in these environments were surmounted by use of novel LIBS probes. Echelle and linear spectrometers coupled to intensified CCD cameras were used individually and sometimes simultaneously. Elements detected include Na, K, Ca, Mg, C, B, Si, Mn, Al, Fe, Rb, Cl, and Ti.

Walsh, Peter M. (University of Alabama at Birmingham and Southern Research Institute, Birmingham, AL); Shaddix, Christopher R.; Sickafoose, Shane M.; Blevins, Linda Gail

2003-02-01T23:59:59.000Z

177

Simple Maintenance Saves Costly Furnace Repair/Replacement |...  

Broader source: Energy.gov (indexed) [DOE]

furnace maintenance, which includes: Checking the condition of the vent connection pipe and chimney Checking the physical integrity of the heat exchanger Adjusting the...

178

Breakthrough Furnace Can Cut Solar Industry Costs (Fact Sheet)  

SciTech Connect (OSTI)

A game-changing Optical Cavity Furnace (OCF), developed by NREL, uses optics to heat and purify solar cells at unmatched precision, while also boosting the cells' efficiency.

Not Available

2013-08-01T23:59:59.000Z

179

Residential Two-Stage Gas Furnaces - Do They Save Energy?  

E-Print Network [OSTI]

ASHRAE test procedure for several furnace efficiency levels (80%, 81%, 90%,ASHRAE Test Procedure 80% AFUE (Two-stage, BPM) 81% AFUE (Two-stage, BPM) 90%

Lekov, Alex; Franco, Victor; Lutz, James

2006-01-01T23:59:59.000Z

180

Furnace and Boiler Basics | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAX POLICIES7.pdfFuel Cell Vehicle Basics Fuel CellStandardsMotors |EnergyFurnace and

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Furnace Litigation Settled | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProvedDecember 2005DepartmentDecember U.S.FinancialofFuel CycleDepartment ofFurnace

182

List of Furnaces Incentives | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place:KeystoneSolar (Texas)BiofuelsInsulationFurnaces Incentives

183

Pilot-Scale Demonstration of a Novel, Low-Cost Oxygen Supply Process and its Integration with Oxy-Fuel Coal-Fired Boilers  

SciTech Connect (OSTI)

In order to achieve DOE targets for carbon dioxide capture, it is crucial not only to develop process options that will generate and provide oxygen to the power cycle in a cost-effective manner compared to the conventional oxygen supply methods based on cryogenic air separation technology, but also to identify effective integration options for these new technologies into the power cycle with carbon dioxide capture. The Linde/BOC developed Ceramic Autothermal Recovery (CAR) process remains an interesting candidate to address both of these issues by the transfer of oxygen from the air to a recycled CO{sub 2} rich flue-gas stream in a cyclic process utilizing the high temperature sorption properties of perovskites. Good progress was made on this technology in this project, but significant challenges remain to be addressed before CAR oxygen production technology is ready for commercial exploitation. Phase 1 of the project was completed by the end of September 2008. The two-bed 0.7 tons/day O2 CAR process development unit (PDU) was installed adjacent to WRI's pilot scale coal combustion test facility (CTF). Start-up and operating sequences for the PDU were developed and cyclic operation of the CAR process demonstrated. Controlled low concentration methane addition allowed the beds to be heated up to operational temperature (800-900 C) and then held there during cyclic operation of the 2-bed CAR process, in this way overcoming unavoidable heat losses from the beds during steady state operation. The performance of the PDU was optimized as much as possible, but equipment limitations prevented the system from fully achieving its target performance. Design of the flue gas recirculation system to integrate CAR PDU with the CTF and the system was completed and integrated tests successfully performed at the end of the period. A detailed techno-economic analysis was made of the CAR process for supplying the oxygen in oxy-fuel combustion retrofit option using AEP's 450 MW Conesville, Ohio plant and contrasted with the cryogenic air separation option (ASU). Design of a large scale CAR unit was completed to support this techno-economic assessment. Based on the finding that the overall cost potential of the CAR technology compared to cryogenic ASU is nominal at current performance levels and that the risks related to both material and process scale up are still significant, the team recommended not to proceed to Phase 2. CAR process economics continue to look attractive if the original and still 'realistic' target oxygen capacities could be realized in practice. In order to achieve this end, a new fundamental materials development program would be needed. With the effective oxygen capacities of the current CAR materials there is, however, insufficient economic incentive to use this commercially unproven technology in oxy-fuel power plant applications in place of conventional ASUs. In addition, it is now clear that before a larger scale pilot demonstration of the CAR technology is made, a better understanding of the impact of flue-gas impurities on the CAR materials and of thermal transients in the beds is required.

Krish Krishnamurthy; Divy Acharya; Frank Fitch

2008-09-30T23:59:59.000Z

184

Molten metal holder furnace and casting system incorporating the molten metal holder furnace  

DOE Patents [OSTI]

A bottom heated holder furnace (12) for containing a supply of molten metal includes a storage vessel (30) having sidewalls (32) and a bottom wall (34) defining a molten metal receiving chamber (36). A furnace insulating layer (42) lines the molten metal receiving chamber (36). A thermally conductive heat exchanger block (54) is located at the bottom of the molten metal receiving chamber (36) for heating the supply of molten metal. The heat exchanger block (54) includes a bottom face (65), side faces (66), and a top face (67). The heat exchanger block (54) includes a plurality of electrical heaters (70) extending therein and projecting outward from at least one of the faces of the heat exchanger block (54), and further extending through the furnace insulating layer (42) and one of the sidewalls (32) of the storage vessel (30) for connection to a source of electrical power. A sealing layer (50) covers the bottom face (65) and side faces (66) of the heat exchanger block (54) such that the heat exchanger block (54) is substantially separated from contact with the furnace insulating layer (42).

Kinosz, Michael J. (Apollo, PA); Meyer, Thomas N. (Murrysville, PA)

2003-02-11T23:59:59.000Z

185

Oxygen analyzer  

DOE Patents [OSTI]

An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

Benner, William H. (Danville, CA)

1986-01-01T23:59:59.000Z

186

STRIP TEMPERATURE IN A METAL COATING LINE ANNEALING FURNACE  

E-Print Network [OSTI]

continuously through the furnace, to certain temperatures and then cooling it, resulting in a change, and subsequent coating. The temperature along the furnace is controlled by varying the power supplied to the heating elements and by use of cooling tubes. The cooling tubes are located in the last half

McGuinness, Mark

187

Heat pipes and use of heat pipes in furnace exhaust  

DOE Patents [OSTI]

An array of a plurality of heat pipe are mounted in spaced relationship to one another with the hot end of the heat pipes in a heated environment, e.g. the exhaust flue of a furnace, and the cold end outside the furnace. Heat conversion equipment is connected to the cold end of the heat pipes.

Polcyn, Adam D. (Pittsburgh, PA)

2010-12-28T23:59:59.000Z

188

Oxygen analyzer  

DOE Patents [OSTI]

An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

Benner, W.H.

1984-05-08T23:59:59.000Z

189

Recent improvements in casthouse practices at the Kwangyang blast furnaces  

SciTech Connect (OSTI)

POSCO`s Kwangyang blast furnaces have continuously carried out high production and low fuel operation under a high pulverized coal injection rate without complications since the Kwangyang No. 1 blast furnace was blown-in in 1987. The Kwangyang blast furnaces have focused on improving the work environment for the increase of competitive power in terms of increased production, cost savings, and management of optimum manpower through use of low cost fuel and raw material. At this time, the casthouse work lags behind most work in the blast furnace. Therefore, the Kwangyang blast furnaces have adopted a remote control system for the casthouse equipment to solve complications in the casthouse work due to high temperature and fumes. As the result, the casthouse workers can work in clean air and the number of workers has been reduced to 9.5 personnel per shift by reduction of the workload.

Jang, Y.S.; Han, K.W.; Kim, K.Y.; Cho, B.R.; Hur, N.S.

1997-12-31T23:59:59.000Z

190

Effect of furnace atmosphere on E-glass foaming  

SciTech Connect (OSTI)

The effect of furnace atmosphere on E-glass foaming generated in crucible has been studied with a specific goal to understand the impact of increased water content on foaming in oxy-fired furnaces. E-glass foams were generated in a fused-quartz crucible located in a quartz window furnace equipped with video recording. The present study showed that humidity in the furnace atmosphere destabilizes foam, while other gases have little effect on foam stability. This study suggests that the higher foaming in oxy-fired furnace compared to air-fired is caused by the effect of water on early sulfate decomposition, promoting more efficient refining gas generation from sulfate (known as “dilution effect”).

Kim, Dong-Sang; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

2006-12-01T23:59:59.000Z

191

E-Print Network 3.0 - arc furnace dust Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Renewable Energy 2 The Effec' of Furnace Design and Operation on Air Pollution Summary: chemical constituents in furnace gases arc very malodorous, or toxic, when...

192

E-Print Network 3.0 - air-conditioners furnaces air Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Residential Space Summary: and electricity. These include boilers and furnaces for heating, air-conditioning systems and heat-pump systems... ) Space Heating Only Furnaces:...

193

Development of the household sample for furnace and boilerlife-cycle cost analysis  

SciTech Connect (OSTI)

Residential household space heating energy use comprises close to half of all residential energy consumption. Currently, average space heating use by household is 43.9 Mbtu for a year. An average, however, does not reflect regional variation in heating practices, energy costs, or fuel type. Indeed, a national average does not capture regional or consumer group cost impacts from changing efficiency levels of heating equipment. The US Department of Energy sets energy standards for residential appliances in, what is called, a rulemaking process. The residential furnace and boiler efficiency rulemaking process investigates the costs and benefits of possible updates to the current minimum efficiency regulations. Lawrence Berkeley National Laboratory (LBNL) selected the sample used in the residential furnace and boiler efficiency rulemaking from publically available data representing United States residences. The sample represents 107 million households in the country. The data sample provides the household energy consumption and energy price inputs to the life-cycle cost analysis segment of the furnace and boiler rulemaking. This paper describes the choice of criteria to select the sample of houses used in the rulemaking process. The process of data extraction is detailed in the appendices and is easily duplicated. The life-cycle cost is calculated in two ways with a household marginal energy price and a national average energy price. The LCC results show that using an national average energy price produces higher LCC savings but does not reflect regional differences in energy price.

Whitehead, Camilla Dunham; Franco, Victor; Lekov, Alex; Lutz, Jim

2005-05-31T23:59:59.000Z

194

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

195

Use of sinter in Taranto blast furnaces  

SciTech Connect (OSTI)

Lowering the production cost of the crude steel is the ultimate aim when planning operations in an integrated steelworks. Designing the Blast Furnace burden is a crucial point in this context, for which account must be taken not only of the raw materials cost but also of other important aims such as maximum plants productivity, minimum possible energy consumption, a proper product quality at the various production stages. This paper describes the criteria used in Ilva Laminati Piani (ILP) Taranto Works to design the BF burden, based on sinter, using the results of extensive research activity carried out by Centro Sviluppo Materiali (CSM), the Research Center with major involvement with the R and D of the Italian Steel Industry. Great attention is paid at ILP to the sinter quality in order to obtain the optimum performance of the BFs, which are operating at high productivity, high pulverized coal rate and low fuel consumption.

Palchetti, M.; Palomba, R.; Tolino, E. [CSM Taranto (Italy); Salvatore, E.; Calcagni, M. [ILP Taranto Works (Italy)

1995-12-01T23:59:59.000Z

196

Recycling of electric arc furnace dust: Jorgensen steel facility  

SciTech Connect (OSTI)

This document is an evaluation of the Ek Glassification(TM) Process to recycle and convert K061-listed waste (Electric Arc Furnace or EAF dust) and other byproducts of the steel-making industry into usable products. The Process holds potential for replacing the need for expensive disposal costs associated with the listed waste with the generation of marketable products. The products include colored glass and glass-ceramics; ceramic glazes, colorants, and fillers; roofing granules and sandblasting grit; and materials for Portland cement production. Field testing of the technology was conducted by the U.S. Environmental Protection Agency (U.S. EPA) in early July of 1991 at the Earle M. Jorgensen Steel Co. (EMJ) plant in Seattle, Washington, and both technical and economic aspects of the technology were examined. TCLP testing of the product determined that leachability characteristics of metals in the product meet treatment standards for K061-listed waste. The Process was also shown to be economically viable, based on capital and operating cost estimates, and profit and revenue forecasts for a 21,000 ton-per-year operation. Although this effort showed that the technology holds promise, regulatory compliance should be evaluated on the basis of the actual hardware configuration and operating procedures along with the leachability of the specific product formulations to be used.

Jackson, T.W.; Chapman, J.S.

1995-01-01T23:59:59.000Z

197

No. 5 blast furnace 1995 reline and upgrade  

SciTech Connect (OSTI)

The 1995 reline of No. 5 Blast Furnace is an undertaking which has never been approached in previous relines of any blast furnace in the history of Wheeling Pittsburgh Steel Corporation. The scope of the project is such that it represents a radical departure from W.P.S.C.`s traditional methods of ironmaking. The reline of No. 5 Blast Furnace is one of the largest capital improvements performed at W.P.S.C. Blast Furnaces. The improvements made at one single time are taking a furnace from 1960`s technology into the 21st century. With this in mind, employee training was one of the largest parts of the project. Training for the automated stockhouse, castfloor, new skip drive, new instrumentation, new castfloor equipment, hydraulics and overall furnace operation were an absolute necessity. The reline has laid the ground work to give the Corporation an efficient, higher productive, modern Blast Furnace which will place W.P.S.C. in the world class category in ironmaking well into the 21st century.

Kakascik, T.F. Jr.

1996-12-31T23:59:59.000Z

198

Application of AI techniques to blast furnace operations  

SciTech Connect (OSTI)

It was during the first stages of application of artificial intelligence (AI) to industrial fields, that the ironmaking division of Mizushima works at Kawasaki Steel recognized its potential. Since that time, the division has sought applications for these techniques to solve various problems. AI techniques applied to control the No. 3 blast furnace operations at the Mizushima works include: Blast furnace control by a diagnostic type of expert system that gives guidance to the actions required for blast furnace operation as well as control of furnace heat by automatically setting blast temperature; Hot stove combustion control by a combination of fuzzy inference and a physical model to insure good thermal efficiency of the stove; and blast furnace burden control using neural networks makes it possible to connect the pattern of gas flow distribution with the condition of the furnace. Experience of AI to control the blast furnace and other ironmaking operations has proved its capability for achieving automation and increased operating efficiency. The benefits are very high. For these reasons, the applications of AI techniques will be extended in the future and new techniques studied to further improve the power of AI.

Iida, Osamu; Ushijima, Yuichi; Sawada, Toshiro [Kawasaki Steel Corp., Kurashiki (Japan)

1995-10-01T23:59:59.000Z

199

Coal combustion under conditions of blast furnace injection. [Quarterly] technical report, 1 March 1993--31 May 1993  

SciTech Connect (OSTI)

A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. The basic program is designed to determine the reactivity of both coal and its derived char under blast furnace conditions and to compare the results to similar properties of blast furnace coke. The results of the first two experiments in which coal char pyrolyzed in nitrogen at 1000{degrees}C in an EPR were reacted isothermally in air at 1000{degrees}C and 1200{degrees}C. The reactivity values of the same char in these two experiments were different by an order of magnitude. The char reactivity at 1000{degrees}C was 9.7 {times} 10{sup {minus}4} grams per minute while the reactivity. of the char at 1200{degrees}C was 1.6 {times} 10{sup {minus}3} grams per minute. These results suggest that the temperature of the blast air in the tuyere may be critical in achieving complete carbon burnout.

Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology; Case, E.R. [Armco, Inc., Middletown, OH (United States). Research and Technology Div.

1993-09-01T23:59:59.000Z

200

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides  

E-Print Network [OSTI]

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

A detailed chemical analysis of changes to bitumen produced by the in situ combustion process at the oxygen Wolf Lake Project, Alberta. Part 11; Whole oil samples  

SciTech Connect (OSTI)

The detailed chemical changes in bitumen brought about over a one year period by a in situ combustion process in an oil sands reservoir have been investigated. Relative to a core sample, the fireflood-produced oils exhibited a significant reduction in density and viscosity which began early in the production cycle. This behavior was correlated with a marked increase in material boiling in the naphtha and middle distillate ranges and a concomitant decrease in the residue cut. The sulfur and nitrogen contents in the produced oils decreased relative to the core sample. A reduction in the acid number of the produced oil samples was coupled with an increase in the oxygen content as the fireflood proceeded. In this paper the relationship between these changes and the dynamics of the in situ combustion process are discussed.

Alex, R.F.; Fuhr, B.; Reichert, C. (Alberta Research Council, Oil Sands and Hydrocarbon Recovery, Edmonton, Alberta T6H 5X2 (CA))

1992-01-01T23:59:59.000Z

202

The push for increased coal injection rates -- Blast furnace experience at AK Steel Corporation  

SciTech Connect (OSTI)

An effort has been undertaken to increase the coal injection rate on Amanda blast furnace at AK Steel Corporation`s Ashland Works in Ashland, Kentucky to decrease fuel costs and reduce coke demand. Operating practices have been implemented to achieve a sustained coal injection rate of 140 kg/MT, increased from 100--110 kg/MT. In order to operate successfully at the 140 kg/MT injection rate; changes were implemented to the furnace charging practice, coal rate control methodology, orientation of the injection point, and the manner of distribution of coal to the multiple injection points. Additionally, changes were implemented in the coal processing facility to accommodate the higher demand of pulverized coal; grinding 29 tonnes per hour, increased from 25 tonnes per hour. Further increases in injection rate will require a supplemental supply of fuel.

Dibert, W.A.; Duncan, J.H.; Keaton, D.E.; Smith, M.D. [AK Steel Corp., Middletown, OH (United States)

1994-12-31T23:59:59.000Z

203

Valorization of Automotive Shredder Residues in metallurgical furnaces Project REFORBA  

E-Print Network [OSTI]

) and the electric arc furnace (EAF) routes, P1 could be used as substitute for coal or coke, and P2 could replace with raw materials cheaper than coke. As additional potential benefits the amount of CO2 generated

Paris-Sud XI, Université de

204

Operating experience with 100% pellet burden on Amanda blast furnace  

SciTech Connect (OSTI)

A number of significant changes in operations at the Ashland Works of the Armco Steel Company occurred in 1992 which directly impacted the Amanda Blast Furnace operation. These changes included the shutdown of the hot strip mill which resulted in coke oven gas enrichment of the Amanda stoves and an increase of 75 C in hot blast temperature, transition to 100% continuous cast operation which resulted in increased variation of the hot metal demand, and the July idling of the sinter plant. Historically, the Amanda Blast Furnace burden was 30% fluxed sinter and 70% acid pellet. It was anticipated that the change to 100% pellet burden would require changes in charging practice and alter furnace performance. The paper gives a general furnace description and then describes the burden characteristics, operating practice with 30% sinter/70% acid pellet burden, preparations for the 100% acid pellet burden operation, the 100% acid pellet operation, and the 100% fluxed pellet burden operation.

Keaton, D.E.; Minakawa, T. (Armco Steel Co., Middletown, OH (United States). Ironmaking Dept.)

1993-01-01T23:59:59.000Z

205

Legendary West Virginia Senior Citizen Stays Warm With New Furnace...  

Broader source: Energy.gov (indexed) [DOE]

concerned for Beulah's safety, told her about the weatherization assistance program. "A tree fell on my house and damaged a lot of things, including my furnace," Beulah says. "I...

206

Voltage flicker prediction for two simultaneously operated ac arc furnaces  

SciTech Connect (OSTI)

An EMTP-based arc furnace model was developed for evaluation of flicker concerns associated with supplying a large integrated steel mill as they go from one to two furnace operation and as system changes are implemented that will affect the short circuit capacity at the 230 kV power supply substation. The model includes a dynamic arc representation which is designed to be characteristic of the initial portions of the melt cycle when the arc characteristics are the most variable (worst flicker conditions). The flicker calculations are verified using previous measurements with one furnace operation. Flicker simulations were then performed to evaluate a variety of different possible system strengths with both one and two furnaces in operation. The primary flicker measure used for this study is the unweighted rms value of the fluctuation envelope, expressed as a percentage of the rms line-to-ground voltage magnitude.

Tang, L. [ABB Power T and D Co., Inc., Raleigh, NC (United States)] [ABB Power T and D Co., Inc., Raleigh, NC (United States); Kolluri, S. [Entergy Services, New Orleans, LA (United States)] [Entergy Services, New Orleans, LA (United States); McGranaghan, M.F. [Electrotek Concepts, Inc., Knoxville, TN (United States)] [Electrotek Concepts, Inc., Knoxville, TN (United States)

1997-04-01T23:59:59.000Z

207

Automatic Control System of Car-Bottom Reheating Furnace  

E-Print Network [OSTI]

At present China has large quantities of two-regenerator gas reheating furnaces which are old in fashion and low in calorific efficiency. Therefore, the question how to increase the calorific efficiency is very much concerned on condition...

Xueqiao, M.; Weilian, X.; Hongchen, Z.

208

New Energy Efficiency Standards for Furnace Fans to Reduce Carbon...  

Office of Environmental Management (EM)

by at least 3 billion metric tons in total by 2030, equal to more than a year's carbon pollution from the entire U.S. electricity system. Furnace fans are used to circulate air...

209

Effect of furnace atmosphere on E-glass foaming  

E-Print Network [OSTI]

oxy-fired furnaces. E-glass foams were generated in a fused-81.05.K 1. Introduction Glass foams generated in glass-that the stability of E-glass foam decreased with increasing

Kim, D. S.; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

2006-01-01T23:59:59.000Z

210

Modelling of multiphase flow in ironmaking blast furnace  

SciTech Connect (OSTI)

A mathematical model for the four-phase (gas, powder, liquid, and solids) flow in a two-dimensional ironmaking blast furnace is presented by extending the existing two-fluid flow models. The model describes the motion of gas, solid, and powder phases, based on the continuum approach, and implements the so-called force balance model for the flow of liquids, such as metal and slag in a blast furnace. The model results demonstrate a solid stagnant zone and dense powder hold-up region, as well as a dense liquid flow region that exists in the lower part of a blast furnace, which are consistent with the experimental observations reported in the literature. The simulation is extended to investigate the effects of packing properties and operational conditions on the flow and the volume fraction distribution of each phase in a blast furnace. It is found that solid movement has a significant effect on powder holdup distribution. Small solid particles and low porosity distribution are predicted to affect the fluid flow considerably, and this can cause deterioration in bed permeability. The dynamic powder holdup in a furnace increases significantly with the increase of powder diameter. The findings should be useful to better understand and control blast furnace operations.

Dong, X.F.; Yu, A.B.; Burgess, J.M.; Pinson, D.; Chew, S.; Zulli, P. [University of New South Wales, Sydney, NSW (Australia). School for Material Science and Engineering

2009-01-15T23:59:59.000Z

211

Automatic thermocouple positioner for use in vacuum furnaces  

DOE Patents [OSTI]

The invention is a simple and reliable mechanical arrangement for automatically positioning a thermocouple-carrying rod in a vacuum-furnace assembly of the kind including a casing, a furnace mounted in the casing, and a charge-containing crucible mounted in the furnace for vertical movement between a lower (loading) position and a raised (charge-melting) position. In a preferred embodiment, a welded-diaphragm metal bellows is mounted above the furnace, the upper end of the bellows being fixed against movement and the lower end of the bellows being affixed to support means for a thermocouple-carrying rod which is vertically oriented and extends freely through the furnace lid toward the mouth of the crucible. The support means and rod are mounted for relative vertical movement. Before pumpdown of the furnace, the differential pressure acting on the bellows causes it to contract and lift the thermocouple rod to a position where it will not be contacted by the crucible charge when the crucible is elevated to its raised position. During pumpdown, the bellows expands downward, lowering the thermocouple rod and its support. The bellows expands downward beyond a point where downward movement of the thermocouple rod is arrested by contact with the crucible charge and to a point where the upper end of the thermocouple extends well above the thermocouple support. During subsequent melting of the charge, the thermocouple sinks into the melt to provide an accurate measurement of melt temperatures.

Mee, D.K.; Stephens, A.E.

1980-06-06T23:59:59.000Z

212

Laboratory Evaluation of Residential Furnace BlowerPerformance  

SciTech Connect (OSTI)

A testing program was undertaken at Lawrence Berkeley National Laboratory and an electric utility (Pacific Gas and Electric Co.) to compare the performance of furnace blowers. This laboratory testing program was undertaken to support potential changes to California Building Standards regarding in-field furnace blower energy use. This technical support includes identifying suitable performance metrics and target performance levels for use in standards. Five different combinations of blowers and residential furnaces were tested for air moving performance. Three different types of blower and motor combinations were tested in two different furnace cabinets. The blowers were standard forward--curved impellors and a prototype impeller with reverse-inclined blades. The motors were two 6-pole permanent split capacitor (PSC) single-phase induction motors, a brushless permanent magnet (BPM) motor and a prototype BPM designed for use with a prototype reverse-inclined impellor. The laboratory testing operated each blower and furnace combination over a range of air flows and pressure differences to determine air flow performance, power consumption and efficiency. Additional tests varied the clearance between the blower housing and the furnace cabinet, and the routing of air flow into the blower cabinet.

Walker, Iain S.; Lutz, Jim D.

2005-09-01T23:59:59.000Z

213

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

214

Thermal Treatment of Solid Wastes Using the Electric Arc Furnace  

SciTech Connect (OSTI)

A thermal waste treatment facility has been developed at the Albany Research Center (ARC) over the past seven years to process a wide range of heterogeneous mixed wastes, on a scale of 227 to 907 kg/h (500 to 2,000 lb/h). The current system includes a continuous feed system, a 3-phase AC, 0.8 MW graphite electrode arc furnace, and a dedicated air pollution control system (APCS) which includes a close-coupled thermal oxidizer, spray cooler, baghouse, and wet scrubber. The versatility of the complete system has been demonstrated during 5 continuous melting campaigns, ranging from 11 to 25 mt (12 to 28 st) of treated wastes per campaign, which were conducted on waste materials such as (a) municipal incinerator ash, (b) simulated low-level radioactive, high combustible-bearing mixed wastes, (c) simulated low-level radioactive liquid tank wastes, (d) heavy metal contaminated soils, and (e) organic-contaminated dredging spoils. In all cases, the glass or slag products readily passed the U.S. Environmental Protection Agency (EPA) Toxicity Characteristic Leachability Program (TCLP) test. Additional studies are currently under way on electric utility wastes, steel and aluminum industry wastes, as well as zinc smelter residues. Thermal treatment of these solid waste streams is intended to produce a metallic product along with nonhazardous glass or slag products.

O'Connor, W.K.; Turner, P.C.

1999-09-01T23:59:59.000Z

215

Desulphurization and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge  

SciTech Connect (OSTI)

Laboratory tests were conducted for removal of SO{sub 2} from simulated flue gas and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge. Tests were conducted for the flue gas flow from 12 to 18 Nm{sup 3}/h, the simulated gas temperature from 80 to 120 {sup o}C, the inlet flux of wastewater from 33 to 57 L/h, applied voltage from 0 to 27 kV, and SO{sub 2} initial concentration was about 1,430 mg/m{sup 3}. Results showed that wastewater from blast furnace has an excellent ability of desulphurization (about 90%) and pulsed corona discharge can enhance the desulphurization efficiency. Meanwhile, it was observed that the SO{sub 2} removal ratio decreased along with increased cycle index, while it increased as the flux of flue gas was reduced, and increased when the flux of wastewater from blast furnace was increased. In addition, results demonstrated that the content of sulfate radical produced in wastewater increase with an increment of applied pulsed voltage, cycle index, or the flux of flue gas. Furthermore, the results indicated that the higher the inlet content of cyanide the better removal effect of it, and the removal rate can reach 99.9% with a residence time of 2.1 s in the pulsed corona zone during the desulphurization process when the inlet content was higher, whereas there was almost no removal effect when the inlet content was lower. This research may attain the objective of waste control, and can provide a new way to remove SO{sub 2} from flue gas and simultaneously degrade wastewater from blast furnace for integrated steel plants.

Li, S.L.; Feng, Q.B.; Li, L.; Xie, C.L.; Zhen, L.P. [Huazhong University of Science and Technology, Wuhan (China)

2009-03-15T23:59:59.000Z

216

Fireside carburization of stainless steel furnace tubes  

SciTech Connect (OSTI)

Most heavy Venezuelan crudes are recognized for having a high total acid number (TAN) that is usually associated with a high tendency to produce naphthenic acid corrosion. To resist this type of corrosion in vacuum heaters, 9Cr-1Mo steel and stainless steels containing molybdenum are usually recommended. In 1993 the original 5Cr-1/2Mo roof tubes of the furnace in a vacuum unit were replaced by stainless steel 316Ti to minimize tube replacement and increase heater reliability. Unexpectedly, some of the new tubes failed after only three years of service, and just one year after undergoing the last turnaround inspection. The damage occurred in the form of deep holes and perforations, starting from the outside tube surface on the fireside. Coke build-up occurred due to severe operating conditions, overheating the tubes on the fireside, above 675 C (1250 F). Metallographic and Scanning Electron Microscopic (SEM) examination revealed internal and external carburization of the material due to the presence of coke and combustion ashes, respectively. The increase in the skin metal temperature facilitated the diffusion of carbon from these carbon-rich deposits into the low carbon content material (0.023 O/O).Depletion of chromium at the grain boundaries due to the massive formation of chromium carbides, resulted in a severe intergranular corrosion attack by molten salts rich in vanadium and sulfur due to asphalt burning. Normal operating practice demands the use of steam for the heater tubes to control coke build-up. This practice had been first reduced and then eliminated, during the past two years prior to the failure, because of economic incentives. This paper describes the root cause analysis conducted to account for these premature tube failures.

Mirabal, E.; Molina, C. [PDVSA-Refineria Isla, Curayao (Netherlands); Mayorga, A.; Hau, J.L. [PDVSA-Intevep, Caracas (Venezuela)

1999-11-01T23:59:59.000Z

217

A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screening  

E-Print Network [OSTI]

. This process offers an attractive route for converting glycerol, the main by-product of biodiesel, to solketal: www.elsevier.com/locate/apenergy #12;1. Introduction The booming of biodiesel industry all over for the sustainability of biodiesel industry. In this regard, the fuel industry seems to be a suitable market where

Qin, Wensheng

218

The Use of Oxygen Gradients as a Texturing Mechanism During Isothermal Melt Processing of Bi-2212 Superconductors  

SciTech Connect (OSTI)

Isothermal melt processing has been used to produce high critical currents (I{sub c}`s) and current densities (J{sub c}`s) in Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub y} round wires and flat tapes. I{sub c}`s and J{sub c}`s of 225 A and 80 kA/cm{sup 2} have been obtained in short length, monocore wires. However, voids and other macroscopic defects have limited performance over longer lengths. Isothermally melt processed tapes have yielded I{sub c} and J{sub c} values up to 341 A and 245 kA/cm{sup 2}, although performance over longer lengths is somewhat reduced. A test coil made from 0.5 m of tape yielded, I{sub c} and J{sub c} values of 208 A and 153 kA/cm{sup 2}, respectively.

Holesinger, T.G.; Hults, W.L.; Smith, J.L. [Los Alamos National Lab., NM (United States); Dai, Weiming; Marken, K.R. [Oxford Instruments Inc., Carteret, NJ (United States)

1997-01-01T23:59:59.000Z

219

Oxygen-reducing catalyst layer  

DOE Patents [OSTI]

An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

2011-03-22T23:59:59.000Z

220

Device for use in a furnace exhaust stream for thermoelectric generation  

DOE Patents [OSTI]

A device for generating voltage or electrical current includes an inner elongated member mounted in an outer elongated member, and a plurality of thermoelectric modules mounted in the space between the inner and the outer members. The outer and/or inner elongated members each include a plurality of passages to move a temperature altering medium through the members so that the device can be used in high temperature environments, e.g. the exhaust system of an oxygen fired glass melting furnace. The modules are designed to include a biasing member and/or other arrangements to compensate for differences in thermal expansion between the first and the second members. In this manner, the modules remain in contact with the first and second members. The voltage generated by the modules can be used to power electrical loads.

Polcyn, Adam D.

2013-06-11T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The 1994 intermediate reline of H-3 furnace  

SciTech Connect (OSTI)

LTV Steel`s Indiana Harbor Works H-3 Blast Furnace was rebuilt in 1988 to provide reliable operations at high production rates without damage to the shell for an overall campaign. This Rebuild included: (1) complete bosh and partial stack shell replacement; (2) a spray cooled carbon bosh; (3) a row of staves at the mantle and six rows of stack staves, all stack staves had noses (ledges at the top of the stave) with the exception of row 5; (4) silicon carbide filled semi graphite brick for the bosh, silicon carbide brick from the mantle area and to the top of stave row No. 1, super duty brick in front of the remaining staves and phosphate bonded high alumina brick in the upper stack; (5) movable throat armor; (6) upgraded instrumentation to follow furnace operation and lining wear occurring in the furnace. No work was done to the hearth walls and bottom, since these had been replaced in 1982 with a first generation graphite cooled design and has experienced 7.7 million NTHM. The furnace was blown in November 18, 1988 and operated through September 3, 1994, at which time it was blown down for its first intermediate repair after 7.85 million NTHM. This paper summarizes the operation of the furnace and then discusses the major aspects of the 1994 intermediate repair.

James, J.D.; Nanavati, K.S.; Spirko, E.J.; Wakelin, D.H.

1995-12-01T23:59:59.000Z

222

The Role of Oxygen in Coal Gasification  

E-Print Network [OSTI]

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

223

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

224

Lycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic  

E-Print Network [OSTI]

, quenching singlet oxygen generated during the water-splitting process of photo- synthesis (10, 11). VariousLycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic photosynthetic cyclase. Instead, we show that CruP aids in preventing accumulation of reactive oxygen species (ROS

Wurtzel, Eleanore

225

Hot metal Si control at Kwangyang blast furnaces  

SciTech Connect (OSTI)

Studies of Si transfer in blast furnaces have shown that the Si level in pig iron is influenced more by the reaction of silicon oxide gas generation in the raceway than the chemical reaction between hot metal and slag at the drop zone. Specifications require a Si content of pig iron below 0.15% at the Kwangyang Works, but the use of soft coking coal in the blend for coke ovens, high pulverized coal injection rate into the blast furnace, and the application of lower grade iron ore has resulted in the need to develop methods to control Si in hot metal. In this paper, the results of in furnace Si control and the desiliconization skills at the casthouse floor are described.

Hur, N.S.; Cho, B.R.; Kim, G.Y.; Choi, J.S.; Kim, B.H. [POSCO, Cheollanamdo (Korea, Republic of). Kwangyang Works

1995-12-01T23:59:59.000Z

226

Direct tuyere injection of oxygen for enhanced coal combustion  

SciTech Connect (OSTI)

Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

1996-12-31T23:59:59.000Z

227

The effects of high temperature processing on the structural and optical properties of oxygenated CdS window layers in CdTe solar cells  

SciTech Connect (OSTI)

High efficiency CdTe solar cells typically use oxygenated CdS (CdS:O) window layers. We synthesize CdS:O window layers at room temperature (RT) and 270?°C using reactive sputtering. The band gaps of CdS:O layers deposited at RT increase when O{sub 2}/(O{sub 2}?+?Ar) ratios in the deposition chamber increase. On the other hand, the band gaps of CdS:O layers deposited at 270?°C decrease as the O{sub 2}/(O{sub 2}?+?Ar) ratios increase. Interestingly, however, our high temperature closed-space sublimation (CSS) processed CdTe solar cells using CdS:O window layers deposited at RT and 270?°C exhibit very similar cell performance, including similar short-circuit current densities. To understand the underlying reasons, CdS:O thin films deposited at RT and 270?°C are annealed at temperatures that simulate the CSS process of CdTe deposition. X-ray diffraction, atomic force microscopy, and UV-visible light absorption spectroscopy characterization of the annealed films reveals that the CdS:O films deposited at RT undergo grain regrowth and/or crystallization and exhibit reduced band gaps after the annealing. Our results suggest that CdS:O thin films deposited at RT and 270?°C should exhibit similar optical properties after the deposition of CdTe layers, explaining the similar cell performance.

Paudel, Naba R.; Grice, Corey R.; Xiao, Chuanxiao; Yan, Yanfa [Department of Physics and Astronomy, and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, Ohio 43606 (United States)

2014-07-28T23:59:59.000Z

228

Furnace Blower Electricity: National and Regional Savings Potential  

SciTech Connect (OSTI)

Currently, total electricity consumption of furnaces is unregulated, tested at laboratory conditions using the DOE test procedure, and is reported in the GAMA directory as varying from 76 kWh/year to 1,953 kWh/year. Furnace blowers account for about 80percent of the total furnace electricity consumption and are primarily used to distribute warm air throughout the home during furnace operation as well as distribute cold air during air conditioning operation. Yet the furnace test procedure does not provide a means to calculate the electricity consumption during cooling operation or standby, which account for a large fraction of the total electricity consumption. Furthermore, blower electricity consumption is strongly affected by static pressure. Field data shows that static pressure in the house distribution ducts varies widely and that the static pressure used in the test procedure as well as the calculated fan power is not representative of actual field installations. Therefore, accurate determination of the blower electricity consumption is important to address electricity consumption of furnaces and air conditioners. This paper compares the potential regional and national energy savings of two-stage brushless permanent magnet (BPM) blower motors (the blower design option with the most potential savings that is currently available in the market) to single-stage permanent split capacitor (PSC) blower motors (the most common blower design option). Computer models were used to generate the heating and cooling loads for typical homes in 16 different climates which represent houses throughout the United States. The results show that the potential savings of using BPM motors vary by region and house characteristics, and are very strongly tied to improving house distribution ducts. Savings decrease dramatically with increased duct pressure. Cold climate locations will see savings even in the high static pressure duct situations, while warm climate locations will see less savings overall and negative savings in the high static pressure duct situations. Moderate climate locations will see little or no savings.

Florida Solar Energy Center; Franco, Victor; Franco, Victor; Lutz, Jim; Lekov, Alex; Gu, Lixing

2008-05-16T23:59:59.000Z

229

Improvement of tap holes at Wakayama No. 5 blast furnace  

SciTech Connect (OSTI)

The service life of blast furnaces, as the result of various improvement measures, has been extended from the conventional 5 to 7 years to 15 to 20 years. Wakayama No. 5 blast furnace adopted SiC bricks. Though SiC brick excelled in strength and durability, it has raised problems such as tap hole inside temperature lowering attributable to its high thermal conductivity, insufficient mud burning and gas blow-out. Nevertheless, various countermeasures described within have been taken against such problems, and as the result it has now become possible to maintain tap holes in stable conditions.

Yamashita, M.; Kashiwada, M.; Shibuta, H. [Sumitomo Metal Industries, Ltd., Wakayama (Japan). Wakayama Steel Works

1995-12-01T23:59:59.000Z

230

ALTERNATE REDUCTANT COLD CAP EVALUATION FURNACE PHASE I TESTING  

SciTech Connect (OSTI)

Savannah River Remediation (SRR) conducted a Systems Engineering Evaluation (SEE) to determine the optimum alternate reductant flowsheet for the Defense Waste Processing Facility (DWPF). Specifically, two proposed flowsheets (nitric–formic–glycolic and nitric–formic–sugar) were evaluated based upon results from preliminary testing. Comparison of the two flowsheets among evaluation criteria indicated a preference towards the nitric–formic–glycolic flowsheet. Further evaluation of this flowsheet eliminated the formic acid1, and as a result, the nitric–glycolic flowsheet was recommended for further testing. Based on the development of a roadmap for the nitric–glycolic acid flowsheet, Waste Solidification Engineering (WS-E) issued a Technical Task Request (TTR) to address flammability issues that may impact the implementation of this flowsheet. Melter testing was requested in order to define the DWPF flammability envelope for the nitric glycolic acid flowsheet. The Savannah River National Laboratory (SRNL) Cold Cap Evaluation Furnace (CEF), a 1/12th scale DWPF melter, was selected by the SRR Alternate Reductant project team as the melter platform for this testing. The overall scope was divided into the following sub-tasks as discussed in the Task Technical and Quality Assurance Plan (TTQAP): ? Phase I - A nitric–formic acid flowsheet melter test (unbubbled) to baseline the Cold Cap Evaluation Furnace (CEF) cold cap and vapor space data to the benchmark melter flammability models ? Phase II - A nitric–glycolic acid flowsheet melter test (unbubbled and bubbled) to: o Define new cold cap reactions and global kinetic parameters for the melter flammability models o Quantify off-gas surging potential of the feed o Characterize off-gas condensate for complete organic and inorganic carbon species Prior to startup, a number of improvements and modifications were made to the CEF, including addition of cameras, vessel support temperature measurement, and a heating element near the pour tube. After charging the CEF with cullet from a previous Sludge Batch 6 (SB6) run, the melter was slurry-fed with SB6-Frit 418 melter feed at 36% waste loading and was operated continuously for 6 days. Process data was collected throughout testing and included melter operation variables and off-gas chemistry. In order to satisfy the objective of Phase I testing, vapor space steady testing in the range of ~300°C-700°C was conducted without argon bubbling to baseline the melter data to the existing DWPF melter flammability model. Adjustments to heater outputs, air flows and feed rate were necessary in order to achieve the vapor space temperatures in this range. The results of the Phase I testing demonstrated that the CEF is capable of operating under the low vapor space temperatures A melter pressure of -5 inches of water was not sustained throughout the run, but the melter did remain slightly negative even with the maximum air flows required for the lowest temperature conditions were used. The auxiliary pour tube heater improved the pouring behavior at all test conditions, including reduced feed rates required for the low vapor space testing. Argon bubbling can be used to promote mixing and increase feed rate at multiple conditions. Improvements due to bubbling have been determined previously; however, the addition of the cameras to the CEF allows for visual observation during a range of bubbling configurations. The off-gas analysis system proved to be robust and capable of operating for long durations. The total operational hours on the melter vessel are approximately 385 hours. Dimensional measurements taken prior to Phase I testing and support block temperatures recorded during Phase I testing are available if an extension of service life beyond 1250 hours is desired in the future.

Johnson, F.; Miller, D.; Zamecnik, J.; Lambert, D.

2014-04-22T23:59:59.000Z

231

RCRA/UST, superfund, and EPCRA hotline training module. Introduction to: Boilers and indutrial furnaces (40 CFR part 266, subpart H) updated as of July 1995  

SciTech Connect (OSTI)

The module summarizes the regulations affecting hazardous waste processes in boilers and industrial furnaces (BIFs). It defines boilers and industrial furnaces and describes the criteria associated with the definitions. It explains the difference in applicability between regulations found in Part 266, Subpart H, and those found in Part 266, Subpart E. It describes the requirements for processing hazardous waste in BIFs, including the distinctions between permitted and interim status units and explains the requirements for the specially regulated BIF units and gives examples of each.

NONE

1995-11-01T23:59:59.000Z

232

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

233

2015-02-13 Issuance: Test Procedure for Furnaces and Boilers...  

Energy Savers [EERE]

2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed...

234

Estimation of Fuel Savings by Recuperation of Furnace Exhausts to Preheat Combustion Air  

E-Print Network [OSTI]

The recovery of waste energy in furnace exhaust gases is gaining in importance as fuel costs continue to escalate. Installation of a recuperator in the furnace exhaust stream to preheat the combustion air can result in considerable savings in fuel...

Rebello, W. J.; Kohnken, K. H.; Phipps, H. R., Jr.

1980-01-01T23:59:59.000Z

235

Economics of residential gas furnaces and water heaters in United States new construction market  

E-Print Network [OSTI]

furnaces and storage water heaters, finds that installing aAs shown in Table 2, storage water heaters in single-familya gas furnace and a gas storage water heater. This market is

Lekov, Alex B.

2010-01-01T23:59:59.000Z

236

Economics of residential gas furnaces and water heaters in US new construction market  

E-Print Network [OSTI]

furnaces and storage water heaters, finds that installing aAs shown in Table 2, storage water heaters in single-familya gas furnace and a gas storage water heater. This market is

Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

2010-01-01T23:59:59.000Z

237

Subtask 3.12 - Oxygen-Fired CFBC  

SciTech Connect (OSTI)

Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

Douglas Hajicek; Mark Musich; Ann Henderson

2007-02-28T23:59:59.000Z

238

Evaluation of heat flux through blast furnace shell with attached sensors  

SciTech Connect (OSTI)

Plant trials to evaluate heat fluxes through a lining/cooling system of a blast furnace were conducted in order to realize the cooling efficiency of the blast furnace under operation. For this purpose, several experiments to measure the in-furnace gas temperatures were cautiously made, and numerical simulations for the temperature distributions over the blast furnace shell and cooling/lining systems were also carried out.

Han, J.W. [Kyonggi Univ., Suwon, Kyonggi (Korea, Republic of). Dept. of Materials Engineering; Lee, J.H.; Suh, Y.K. [POSCO, Kwangyang, Cheonnam (Korea, Republic of). Technical Research Labs.

1996-12-31T23:59:59.000Z

239

Processing factors contributing to growth and decline in the steel industry  

E-Print Network [OSTI]

During the second half of the twentieth century, a technological shift occurred in the steel industry. A different mix of refining and melting furnaces were used, with increasing use being made of basic oxygen and electric ...

Dufalla, Michele (Michele Helene)

2007-01-01T23:59:59.000Z

240

Using a dual plasma process to produce cobalt--polypyrrole catalysts for the oxygen reduction reaction in fuel cells -- part II: analysing the chemical structure of the films  

E-Print Network [OSTI]

The chemical structure of cobalt--polypyrrole -- produced by a dual plasma process -- is analysed by means of X-ray photoelectron spectroscopy (XPS), near edge X-ray absorption spectroscopy (NEXAFS), X-ray diffraction (XRD), energy-dispersive X-Ray spectroscopy (EDX) and extended x-ray absorption spectroscopy (EXAFS).It is shown that only nanoparticles of a size of 3\\,nm with the low temperature crystal structure of cobalt are present within the compound. Besides that, cobalt--nitrogen and carbon--oxygen structures are observed. Furthermore, more and more cobalt--nitrogen structures are produced when increasing the magnetron power. Linking the information on the chemical structure to the results about the catalytic activity of the films -- which are presented in part I of this contribution -- it is concluded that the cobalt--nitrogen structures are the probable catalytically active sites. The cobalt--nitrogen bond length is calculated as 2.09\\,\\AA\\ and the carbon--nitrogen bond length as 1.38\\,\\AA.

Walter, Christian; Vyalikh, Denis; Brüser, Volker; Quade, Antje; Weltmann, Klaus-Dieter; 10.1149/2.043209jes

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Single taphole blast furnace casthouse performance optimizing cost and availability  

SciTech Connect (OSTI)

The No. 2 blast furnace is a single taphole furnace with a convection air-cooled iron trough. The iron runner system is designed to fill four 90 ton open-top ladles per cast, which are transported by locomotive to the steel shop. The slag runner system is capable of filling three 800 ft{sup 3} slag pots per cast. The No. 2 blast furnace was blown in from mini-reline with this new casthouse configuration in early December 1991. It was operated for nearly three years until it was banked for planned stove repairs and a trough rebuild in late September 1994. During this period, the furnace produced just over 2.5 million tons of hot metal across the original trough refractory lining system, with 13 intermediate hot patch castable repairs. The entire casthouse refractory usage (main trough, runner systems, and covers) during this campaign was 1.06 pounds per net ton of hot metal. Investigation of the lining during demolition indicated that the trough lining campaign could have been extended to at least 3.0 million tons. This paper will discuss how operating practices, mechanical design, refractory design, maintenance philosophy, and attention to detail synergistically contributed to the long campaign life and low refractory consumption rate.

Fowles, R.D.; Searls, J.B.; Peay, W.R. [Geneva Steel, Provo, UT (United States); Brenneman, R.G.

1995-12-01T23:59:59.000Z

242

Field measurements of interactions between furnaces and forced air distribution systems  

E-Print Network [OSTI]

of equipment that provides the heating energy (the furnace, boiler or heat pump) and the method usedLBNL 40587 Field measurements of interactions between furnaces and forced air distribution systems Vol. 104 Part 1 Field measurements of interactions between furnaces and forced air distribution

243

High temperature furnaces for small and large angle neutron scattering of disordered materials  

E-Print Network [OSTI]

725 High temperature furnaces for small and large angle neutron scattering of disordered materials and small angle neutron scattering (SANS) experiments respectively. They are vacuum furnaces with a thin maintained in a tantalum box. In a neutron beam, the furnaces produce a very low scattering level (without

Boyer, Edmond

244

Electrode Arrangement As Substitute Bottom For An Electrothermic Slag Smelting Furnace.  

DOE Patents [OSTI]

The electrode arrangement uses vertically oriented electrodes with side wall contacts for an electrothermic smelting furnace for aluminum production. The side wall contacts are radially moveable into the furnace to compensate for wear on the contacts. The side wall contacts can be hollow to allow a slag forming charge to be fed to the furnace.

Aune, Jan Arthur (Enebakk, NO); Brinch, Jon Christian (Oslo, NO); Johansen, Kai (Kristiansand, NO)

2005-12-27T23:59:59.000Z

245

Evaluation of steelmaking processes  

SciTech Connect (OSTI)

Objective of the AISI Direct Steelmaking Program is to develop a process for producing steel directly from ore and coal; the process should be less capital intensive, consume less energy, and have higher productivity. A task force was formed to examine available processes: trough, posthearth, IRSID, Electric Arc Furnace, energy optimizing furnace. It is concluded that there is insufficient incentive to replace a working BOF with any of these processes to refine hot metal; however, if new steelmaking capacity is required, IRSID and EOF should be considered. A fully continuous process should not be considered until direct ironmaking and continuous refining are perfected.

Fruehan, R.J. [Carnegie-Mellon Univ., Pittsburgh, PA (United States)

1994-01-01T23:59:59.000Z

246

Advanced Combustion Diagnostics and Control for Furnaces, Fired Heaters and Boilers  

SciTech Connect (OSTI)

The objective of this project was to develop and apply enabling tools and methods towards advanced combustion diagnostics and control of fired-equipment in large-scale petrochemical manufacturing. There are a number of technology gaps and opportunities for combustion optimization, including technologies involving advanced in-situ measurements, modeling, and thermal imaging. These technologies intersect most of manufacturing and energy systems within the chemical industry. This project leveraged the success of a previous DOE funded project led by Dow, where we co-developed an in-situ tunable diode laser (TDL) analyzer platform (with Analytical Specialties Inc, now owned by Yokogawa Electric Corp.). The TDL platform has been tested and proven in a number of combustion processes within Dow and outside of Dow. The primary focus of this project was on combustion diagnostics and control applied towards furnaces, fired heaters and boilers. Special emphasis was placed on the development and application of in-situ measurements for O2, CO and methane since these combustion gases are key variables in optimizing and controlling combustion processes safely. Current best practice in the industry relies on measurements that suffer from serious performance gaps such as limited sampling volume (point measurements), poor precision and accuracy, and poor reliability. Phase I of the project addressed these gaps by adding improved measurement capabilities such as CO and methane (ppm analysis at combustion zone temperatures) as well as improved optics to maintain alignment over path lengths up to 30 meters. Proof-of-concept was demonstrated on a modern olefins furnace located at Dow Chemical's facility in Freeport TX where the improved measurements were compared side-by-side to accepted best practice techniques (zirconium oxide and catalytic bead or thick film sensors). After developing and installing the improved combustion measurements (O2, CO, and methane), we also demonstrated the ability to improve control of an olefins furnace (via CO-trim) that resulted in significant energy savings and lower emissions such as NOx and other greenhouse gases. The cost to retrofit measurements on an existing olefins furnace was found to be very attractive, with an estimated payback achieved in 4 months or less.

Tate, J. D.; Le, Linh D.; Knittel,Trevor; Cowie, Alan

2010-03-20T23:59:59.000Z

247

Modeling coal combustion behavior in an ironmaking blast furnace raceway: model development and applications  

SciTech Connect (OSTI)

A numerical model has been developed and validated for the investigation of coal combustion phenomena under blast furnace operating conditions. The model is fully three-dimensional, with a broad capacity to analyze significant operational and equipment design changes. The model was used in a number of studies, including: Effect of cooling gas type in coaxial lance arrangements. It was found that oxygen cooling improves coal burnout by 7% compared with natural gas cooling under conditions that have the same amount of oxygen enrichment in the hot blast. Effect of coal particle size distribution. It was found that during two similar periods of operation at Port Kembla's BF6, a difference in PCI capability could be attributed to the difference in coal size distribution. Effect of longer tuyeres. Longer tuyeres were installed at Port Kembla's BF5, leading to its reline scheduled for March 2009. The model predicted an increase in blast velocity at the tuyere nose due to the combustion of volatiles within the tuyere, with implications for tuyere pressure drop and PCI capability. Effect of lance tip geometry. A number of alternate designs were studied, with the best-performing designs promoting the dispersion of the coal particles. It was also found that the base case design promoted size segregation of the coal particles, forcing smaller coal particles to one side of the plume, leaving larger coal particles on the other side. 11 refs., 15 figs., 4 tabs.

Maldonado, D.; Austin, P.R.; Zulli, P.; Guo B. [BlueScope Steel Research Laboratories, Port Kembla, NSW (Australia)

2009-03-15T23:59:59.000Z

248

ALTERNATE REDUCTANT COLD CAP EVALUATION FURNACE PHASE II TESTING  

SciTech Connect (OSTI)

Savannah River Remediation (SRR) conducted a Systems Engineering Evaluation (SEE) to determine the optimum alternate reductant flowsheet for the Defense Waste Processing Facility (DWPF). Specifically, two proposed flowsheets (nitric–formic–glycolic and nitric–formic–sugar) were evaluated based upon results from preliminary testing. Comparison of the two flowsheets among evaluation criteria indicated a preference towards the nitric–formic–glycolic flowsheet. Further research and development of this flowsheet eliminated the formic acid, and as a result, the nitric–glycolic flowsheet was recommended for further testing. Based on the development of a roadmap for the nitric–glycolic acid flowsheet, Waste Solidification Engineering (WS-E) issued a Technical Task Request (TTR) to address flammability issues that may impact the implementation of this flowsheet. Melter testing was requested in order to define the DWPF flammability envelope for the nitric-glycolic acid flowsheet. The Savannah River National Laboratory (SRNL) Cold Cap Evaluation Furnace (CEF), a 1/12th scale DWPF melter, was selected by the SRR Alternate Reductant project team as the melter platform for this testing. The overall scope was divided into the following sub-tasks as discussed in the Task Technical and Quality Assurance Plan (TTQAP): ? Phase I - A nitric–formic acid flowsheet melter test (unbubbled) to baseline the CEF cold cap and vapor space data to the benchmark melter flammability models; ? Phase II - A nitric–glycolic acid flowsheet melter test (unbubbled and bubbled) to: o Define new cold cap reactions and global kinetic parameters in support of the melter flammability model development; o Quantify off-gas surging potential of the feed; o Characterize off-gas condensate for complete organic and inorganic carbon species. After charging the CEF with cullet from Phase I CEF testing, the melter was slurry-fed with glycolic flowsheet based SB6-Frit 418 melter feed at 36% waste loading and was operated continuously for 25 days. Process data was collected throughout testing and included melter operation parameters and off-gas chemistry. In order to generate off-gas data in support of the flammability model development for the nitric-glycolic flowsheet, vapor space steady state testing in the range of ~300-750°C was conducted under the following conditions, (i) 100% (nominal and excess antifoam levels) and 125% stoichiometry feed and (ii) with and without argon bubbling. Adjustments to feed rate, heater outputs and purge air flow were necessary in order to achieve vapor space temperatures in this range. Surge testing was also completed under nominal conditions for four days with argon bubbling and one day without argon bubbling.

Johnson, F.; Stone, M.; Miller, D.

2014-09-03T23:59:59.000Z

249

Incineration of radioactive waste in shaft furnace  

SciTech Connect (OSTI)

Development of nuclear technology depends greatly on solving the problems, concerning the treatment of waste, arising from power station activity. A great deal of waste will arise in the process of atomic power station decommissioning. One of the methods for radioactive waste treatment is a method of combustion. The volume reduction factor of the final product is 60--100. In the process of combustion, the organic radwaste is transported into gaseous wastes and ash. For better environmental protection, one must achieve the minimal release of nuclides from partially burned products in the gaseous phase, and maximize the waste in ash form suitable for final disposal.

Dmitriev, S.A.; Knyasev, I.A.; Kobelev, A.P. [Moscow SIA Radon, Sergiev Posad (Russian Federation). Dept. of Engineering Supply

1993-12-31T23:59:59.000Z

250

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

251

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

252

Low NOx nozzle tip for a pulverized solid fuel furnace  

DOE Patents [OSTI]

A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

2014-04-22T23:59:59.000Z

253

A new approach to oxygen enriched high temperature blast generation  

SciTech Connect (OSTI)

When increasing fuel injection in a blast furnace in order to reduce coke consumption and/or to increase production, the blast furnace operator tries to keep similar raceway conditions, for instance, an equivalent flame temperature. To compensate for the cooling effect due to the higher injection rate, two solutions can be selected or combined: to raise the temperature of the blast and/or to increase the level of oxygen in the blast. Whatever the choice, the Blast Furnace manager will certainly try to reduce the resulting investment and operating costs to a minimum. Air Liquide and Kvaerner Davy are trying to provide a new way to address these needs by offering a new technology for blast heating. A higher blast temperature will not only allow a higher fuel injection at tuyere level, a lower coke consumption, but also a lower oxygen consumption. Air Liquide and Kvaerner Davy are now able to offer a new heat regenerator with major advantages over conventional stoves. This new device can be used as a permanent substitute for a stove, or as a temporary one during repair, or stove improvement. It can also be added to an existing set of stoves to increase the average blast temperature.

Queille, P.H.; Macauley, D.

1996-12-31T23:59:59.000Z

254

Furnace control apparatus using polarizing interferometer  

DOE Patents [OSTI]

A system for non-destructively measuring an object and controlling industrial processes in response to the measurement is disclosed in which an impulse laser generates a plurality of sound waves over timed increments in an object. A polarizing interferometer is used to measure surface movement of the object caused by the sound waves and sensed by phase shifts in the signal beam. A photon multiplier senses the phase shift and develops an electrical signal. A signal conditioning arrangement modifies the electrical signals to generate an average signal correlated to the sound waves which in turn is correlated to a physical or metallurgical property of the object, such as temperature, which property may then be used to control the process. External, random vibrations of the workpiece are utilized to develop discernible signals which can be sensed in the interferometer by only one photon multiplier. In addition the interferometer includes an arrangement for optimizing its sensitivity so that movement attributed to various waves can be detected in opaque objects. The interferometer also includes a mechanism for sensing objects with rough surfaces which produce speckle light patterns. Finally the interferometer per se, with the addition of a second photon multiplier is capable of accurately recording beam length distance differences with only one reading.

Schultz, Thomas J. (Maumee, OH); Kotidis, Petros A. (Waban, MA); Woodroffe, Jaime A. (North Reading, MA); Rostler, Peter S. (Newton, MA)

1995-01-01T23:59:59.000Z

255

Furnace control apparatus using polarizing interferometer  

DOE Patents [OSTI]

A system for nondestructively measuring an object and controlling industrial processes in response to the measurement is disclosed in which an impulse laser generates a plurality of sound waves over timed increments in an object. A polarizing interferometer is used to measure surface movement of the object caused by the sound waves and sensed by phase shifts in the signal beam. A photon multiplier senses the phase shift and develops an electrical signal. A signal conditioning arrangement modifies the electrical signals to generate an average signal correlated to the sound waves which in turn is correlated to a physical or metallurgical property of the object, such as temperature, which property may then be used to control the process. External, random vibrations of the workpiece are utilized to develop discernible signals which can be sensed in the interferometer by only one photon multiplier. In addition the interferometer includes an arrangement for optimizing its sensitivity so that movement attributed to various waves can be detected in opaque objects. The interferometer also includes a mechanism for sensing objects with rough surfaces which produce speckle light patterns. Finally the interferometer per se, with the addition of a second photon multiplier is capable of accurately recording beam length distance differences with only one reading. 38 figures.

Schultz, T.J.; Kotidis, P.A.; Woodroffe, J.A.; Rostler, P.S.

1995-03-28T23:59:59.000Z

256

Onsite recycling of electric arc furnace dust: The Jorgensen Steel Facility  

SciTech Connect (OSTI)

The steel-making industry produces a large amount of Electric Arc Furnace (EAF) dust as part of normal production. This waste is listed as KO61, defined as {open_quotes}emission control dust/sludge from the primary production of steel in electric arc furnaces{close_quotes} under 40 CFR 261.32. A glass making technology called Ek Glassification{trademark} (hereafter called {open_quotes}the Process{close_quotes}) has been developed by Roger B. Ek and Associates, Inc. (hereafter called {open_quotes}the Developer{close_quotes}) to recycle EAF dust and convert it, along with other byproducts of the steel-making industry, into marketable commodities. This Process was evaluated under the Waste Reduction Innovative Technology Evaluation (WRITE) Program. The project was designed and conducted in cooperation with the Washington State Department of Environmental Quality, the Process Developer and the host test site, the Earle M. Jorgensen (EMJ) Steel Company of Seattle, Washington. Test personnel for EPA were supplied by SAIC Inc., on contract to EPA. The overall objectives of the project were to conduct a pilot scale evaluation of the Process, investigate if toxic metals are leached from the products (such as colored glass and glass-ceramics; ceramic glazes, colorants, and fillers; roofing granules and sand-blasting grit; and materials for Portland cement production). Three glass recipes (Glass I, II, and III) were designed by the developer for potential use at EMJ. The EPA portion was focused on determining the toxic metals concentrations of the Glass II recipe, evaluating the P2 impact of using this Process in comparison to traditional methods of waste treatment and disposal, and assessing the economics of both.

Licis, I.J. [Environmental Protection Agency, Cincinnati, OH (United States); Bermark, R.C. [Washington State Dept. of Ecology, Olympia, WA (United States)

1995-10-01T23:59:59.000Z

257

Manufacturing capabilities of high power electron beam furnaces for melting ignots to 40 tons in weight  

SciTech Connect (OSTI)

A tendency to using special technologies of melting steels and alloys to get large ingots free of macrodefects and shrinking shells used to provide defectless products, ensuring an increase of ingot-to-product yield is well known. The electron beam furnace process improves the economical efficiency of production of large ingots, slabs for rolling mills, where high quality of special purpose steels and alloys is required. Metals, made by means of electron beam melting can be used for power, nuclear and chemical machine-buildings, aircraft and automotive, instrument and bearing productions, injection moulds and moulds for cold rollings, magnetic and titanium alloys, ship shafts, propellers and high speed power turbine parts. Melting technologies, which is one of the most important stages in production of steels and alloys, predetermines a required quality of metals and alloys to get the following characteristics of remelted metals: impact strength; isotropy of properties in central and surface zones of ingots; fatigue strength and resistance under mechanical and heat loads; corrosion resistance to attack by aggressive media; and polishing properties. The furnace is equipped with five electron beam guns, type EH-1200/50 and pumps for pumping out cavities of technological equipments: melting and ingot chambers, charging devices.

Boiko, Ju.P.; Braim, V.P.; Kormitch, A.T.; Zorin, G.V.; Kostenuk, Ju.V.; Nikitin, V.S.; Pokrovsky, S.V.

1994-12-31T23:59:59.000Z

258

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect (OSTI)

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the previous semi-annual technical progress report (April 1, 2001 through September 30, 2001). During the current reporting period, additional balance of plant impact information was determined for one of the two tests. These additional balance-of-plant results are presented and discussed in this report. There was no other technical progress to report, because all planned testing as part of this project has been completed.

Gary M. Blythe

2002-04-29T23:59:59.000Z

259

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect (OSTI)

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

Gary M. Blythe

2001-11-06T23:59:59.000Z

260

AISI/DOE Technology Roadmap Program: Behavior of Phosphorus in DRI/HBI During Electric Furnace Steelmaking  

SciTech Connect (OSTI)

Many common scrap substitutes such as direct reduced iron pellets (DRI), hot briquetted iron (HBI), iron carbide, etc., contain significantly higher levels of phosphorus steelmaking for the production of higher quality steels, control of phosphorus levels in the metal will become a concern. This study has developed a more complete understanding of the behavior of phosphorus in DRI during EAF steelmaking, through a thorough investigation of the kinetics and thermodynamics of phosphorus transfer in the EAF based upon laboratory and plant experiments and trials. Laboratory experiments have shown that phosphorus mass transfer between oxide and metallic phases within commercial direct reduced iron pellets occurs rapidly upon melting according to the local equilibrium for these phases. Laboratory kinetic experiments indicate that under certain conditions, phosphorus mass transfer between slag and metal is influenced by dynamic phenomena, which affect the mass transfer coefficient for the reaction and/or the slag metal interfacial area. Plant trials were conducted to directly evaluate the conditions of mass transfer in the electric furnace and to determine the effects of different scrap substitute materials upon the slag chemistry, the behavior of phosphorus in the steel, and upon furnace yield. The data from these trials were also used to develop empirical models for the slag chemistry and furnace temperature as functions of time during a single heat. The laboratory and plant data were used to develop a numerical process model to describe phosphorus transfer in the EAF

Richard J. Frueham; Christopher P. Manning cmanning@bu.edu

2001-10-05T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Precision control of high temperature furnaces using an auxiliary power supply and charged practice current flow  

DOE Patents [OSTI]

Two power supplies are combined to control a furnace. A main power supply heats the furnace in the traditional manner, while the power from the auxiliary supply is introduced as a current flow through charged particles existing due to ionized gas or thermionic emission. The main power supply provides the bulk heating power and the auxiliary supply provides a precise and fast power source such that the precision of the total power delivered to the furnace is improved.

Pollock, George G. (San Ramon, CA)

1997-01-01T23:59:59.000Z

262

Precision control of high temperature furnaces using an auxiliary power supply and charged particle current flow  

DOE Patents [OSTI]

Two power supplies are combined to control a furnace. A main power supply heats the furnace in the traditional manner, while the power from the auxiliary supply is introduced as a current flow through charged particles existing due to ionized gas or thermionic emission. The main power supply provides the bulk heating power and the auxiliary supply provides a precise and fast power source such that the precision of the total power delivered to the furnace is improved. 5 figs.

Pollock, G.G.

1997-01-28T23:59:59.000Z

263

Economics of residential gas furnaces and water heaters in United States new construction market  

E-Print Network [OSTI]

Experiences of residential consumers and utilities. OakStar (2008). Energy Star Residential Water Heaters: Finalefficiency improvements for residential gas furnaces in the

Lekov, Alex B.

2010-01-01T23:59:59.000Z

264

Economics of residential gas furnaces and water heaters in US new construction market  

E-Print Network [OSTI]

appliance_standards/residential/water_ pool_heaters_prelim_Star (2008). Energy star residential water heaters: Finalefficiency improvements for residential gas furnaces in the

Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

2010-01-01T23:59:59.000Z

265

E-Print Network 3.0 - arc furnace steel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TID electric arc furnaces for MSW ash are ... Source: Columbia University - Waste-to-Energy Research and Technology Council (WTERT) Collection: Renewable Energy Page: << < 1 2...

266

Electricity and Natural Gas Efficiency Improvements for Residential Gas Furnaces in the U.S.  

E-Print Network [OSTI]

by natural gas. Electricity consumption by a furnace blowerto the annual electricity consumption of a major appliance.not account for the electricity consumption of the appliance

Lekov, Alex; Franco, Victor; Meyers, Steve; McMahon, James E.; McNeil, Michael; Lutz, Jim

2006-01-01T23:59:59.000Z

267

Electricity and Natural Gas Efficiency Improvements for Residential Gas Furnaces in the U.S.  

E-Print Network [OSTI]

offsets the sizable electricity savings. References TitleElectricity and Natural Gas Efficiency Improvements forfueled by natural gas. Electricity consumption by a furnace

Lekov, Alex; Franco, Victor; Meyers, Steve; McMahon, James E.; McNeil, Michael; Lutz, Jim

2006-01-01T23:59:59.000Z

268

E-Print Network 3.0 - arc furnaces Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Solar Energy for the Production of Fullerenes and Summary: with the Odeillo (finance) solar furnace facilities, can be used to vaporize graphite in inert gas atmosphere......

269

E-Print Network 3.0 - arc plasma furnace Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PLASMA PHYSICS AND ENGINEERING Summary: replace costly traditional technologies as incineration and conventional plasma arc furnaces, and provide... ASSOCIATED LABORATORY ON...

270

E-Print Network 3.0 - arc furnace steelmaking Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the furnace cavity. This special ... Source: Oak Ridge National Laboratory Fossil Energy Program; Pint, Bruce A. - Materials Science & Technology Division, Oak Ridge...

271

E-Print Network 3.0 - air furnace design Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IN MUNICIPAL INCINERATOR Summary: cal to good furnace performance and to mainten ance of air pollution control. Early in 1967 the writer... of the grate roughly equivalent to...

272

Economics of Condensing Gas Furnaces and Water Heaters Potential in Residential Single Family Homes  

E-Print Network [OSTI]

develop condensing gas storage water heaters to qualify forgas furnace and gas storage water heater. This study focusesis predominantly storage water heaters. Regionally, gas-

Lekov, Alex

2011-01-01T23:59:59.000Z

273

Advanced In-Furnace NOx Control for Wall and Cyclone-Fired Boilers  

SciTech Connect (OSTI)

A NO{sub x} minimization strategy for coal-burning wall-fired and cyclone boilers was developed that included deep air staging, innovative oxygen use, reburning, and advanced combustion control enhancements. Computational fluid dynamics modeling was applied to refine and select the best arrangements. Pilot-scale tests were conducted by firing an eastern high-volatile bituminous Pittsburgh No.8 coal at 5 million Btu/hr in a facility that was set up with two-level overfire air (OFA) ports. In the wall-fired mode, pulverized coal was burned in a geometrically scaled down version of the B and W DRB-4Z{reg_sign} low-NO{sub x} burner. At a fixed overall excess air level of 17%, NO{sub x} emissions with single-level OFA ports were around 0.32 lb/million Btu at 0.80 burner stoichiometry. Two-level OFA operation lowered the NO{sub x} levels to 0.25 lb/million Btu. Oxygen enrichment in the staged burner reduced the NO{sub x} values to 0.21 lb/million Btu. Oxygen enrichment plus reburning and 2-level OFA operation further curbed the NO{sub x} emissions to 0.19 lb/million Btu or by 41% from conventional air-staged operation with single-level OFA ports. In the cyclone firing arrangement, oxygen enrichment of the cyclone combustor enabled high-temperature and deeply staged operation while maintaining good slag tapping. Firing the Pittsburgh No.8 coal in the optimum arrangement generated 112 ppmv NO{sub x} (0.15 lb/million Btu) and 59 ppmv CO. The optimum emissions results represent 88% NO{sub x} reduction from the uncontrolled operation. Levelized costs for additional NO{sub x} removal by various in-furnace control methods in reference wall-fired or cyclone-fired units already equipped with single-level OFA ports were estimated and compared with figures for SCR systems achieving 0.1 lb NO{sub x}/10{sup 6} Btu. Two-level OFA ports could offer the most economical approach for moderate NO{sub x} control, especially for smaller units. O{sub 2} enrichment in combination with 2-level OFA was not cost effective for wall-firing. For cyclone units, NO{sub x} removal by two-level OFA plus O{sub 2} enrichment but without coal reburning was economically attractive.

Hamid Sarv

2009-02-28T23:59:59.000Z

274

Active radiometer for self-calibrated furnace temperature measurements  

DOE Patents [OSTI]

Radiometer with a probe beam superimposed on its field-of-view for furnace temperature measurements. The radiometer includes a heterodyne millimeter/submillimeter-wave receiver including a millimeter/submillimeter-wave source for probing. The receiver is adapted to receive radiation from a surface whose temperature is to be measured. The radiation includes a surface emission portion and a surface reflection portion which includes the probe beam energy reflected from the surface. The surface emission portion is related to the surface temperature and the surface reflection portion is related to the emissivity of the surface. The simultaneous measurement of surface emissivity serves as a real time calibration of the temperature measurement.

Woskov, Paul P. (Bedford, MA); Cohn, Daniel R. (Chestnut Hill, MA); Titus, Charles H. (Newtown Square, PA); Wittle, J. Kenneth (Chester Springs, PA); Surma, Jeffrey E. (Kennewick, WA)

1996-01-01T23:59:59.000Z

275

The limitation of hearth sidewall wear at Redcar blast furnace  

SciTech Connect (OSTI)

The Redcar blast furnace with 14m hearth diameter was blown-in for its second campaign in August 1996. It is currently in its 10th year of operation and to date has produced just over 30 million tonnes. Current plans are to continue the second campaign to the year 2000 and beyond, producing over 40 million tonnes. In order to achieve this objective, any further wear on the lining, and in particular the hearth sidewall, needs to be minimized. This paper describes the present hearth design, the monitoring of hearth wear, the predicted wear profile, and the protection measures that have been taken or are being considered.

Parratt, J.E.

1996-12-31T23:59:59.000Z

276

A system for interpretation of blast furnace stockrod measurements  

SciTech Connect (OSTI)

A system for intelligent monitoring and interpretation of signals from blast furnace stockrods is presented. The system visualizes the measurements and estimates the local burden layer thickness (under the rods) after every dump. Furthermore, it analyzes the burden descent rate to distinguish between slips, hangings, normal descent and peaks, etc., and also combines the stockrod information with findings of temperature measurements from an above-burden probe. The preprocessing of the signals and some features of the system, which is under development, are treated in this paper.

Hinnelae, J.; Saxen, H. [Aabo Akademi Univ. (Finland). Dept. of Chemical Engineering

1997-12-31T23:59:59.000Z

277

Covered Product Category: Residential Gas Furnaces | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top FiveDepartmentfor EngineeringDepartment ofBoilersDataHotofFurnaces Covered

278

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

279

Operational results of shaft repair by installing stave type cooler at Kimitsu Nos. 3 and 4 blast furnaces  

SciTech Connect (OSTI)

Nos. 3 and 4 blast furnaces in Nippon Steel Corporation Kimitsu Works were both initially fitted with cooling plate systems. With the aging of each furnace, the damage to their respective inner-shaft profiles had become serious. Thus, in order to prevent operational change and prolong the furnace life, the inner-shaft profile of each furnace was repaired by replacing the former cooling plate system with the stave type cooler during the two-week-shutdowns. With this repair, stability of burden descent and gas flow near the wall part of the furnace have been achieved. Thus the prolongation of the furnace life is naturally expected.

Oda, Hiroshi; Amano, Shigeru; Sakamoto, Aiichiro; Anzai, Osamu [Nippon Steel Corp., Kimitsu, Chiba (Japan). Kimitsu Works; Nakagome, Michiru; Kuze, Toshisuke [Nippon Steel Corp., Futtsu, Chiba (Japan); Imuta, Akira [Nippon Steel Corp., Tokyo (Japan). Plant and Machinery Div.

1997-12-31T23:59:59.000Z

280

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Thermal Plasma Systems for Industrial Processes  

E-Print Network [OSTI]

furnaces, extending from below 2000 F to almost any conceivably useful processing temperature, with efficiencies much higher than can be achieved with combustion heating equipment. Numerous applications for plasma systems exist in the chemical...

Fey, M. G.; Meyer, T. N.; Reed, W. H.; Philbrook, W. O.

1982-01-01T23:59:59.000Z

282

Blast furnace coke quality in relation to petroleum coke addition  

SciTech Connect (OSTI)

The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

1995-12-01T23:59:59.000Z

283

Self-calibrated active pyrometer for furnace temperature measurements  

DOE Patents [OSTI]

Pyrometer with a probe beam superimposed on its field-of-view for furnace temperature measurements. The pyrometer includes a heterodyne millimeter/sub-millimeter-wave or microwave receiver including a millimeter/sub-millimeter-wave or microwave source for probing. The receiver is adapted to receive radiation from a surface whose temperature is to be measured. The radiation includes a surface emission portion and a surface reflection portion which includes the probe beam energy reflected from the surface. The surface emission portion is related to the surface temperature and the surface reflection portion is related to the emissivity of the surface. The simultaneous measurement of surface emissivity serves as a real time calibration of the temperature measurement. In an alternative embodiment, a translatable base plate and a visible laser beam allow slow mapping out of interference patterns and obtaining peak values therefor. The invention also includes a waveguide having a replaceable end portion, an insulating refractory sleeve and/or a source of inert gas flow. The pyrometer may be used in conjunction with a waveguide to form a system for temperature measurements in a furnace. The system may employ a chopper or alternatively, be constructed without a chopper. The system may also include an auxiliary reflector for surface emissivity measurements.

Woskov, Paul P. (Bedford, MA); Cohn, Daniel R. (Chestnuthill, MA); Titus, Charles H. (Newtown Square, PA); Surma, Jeffrey E. (Kennewick, WA)

1998-01-01T23:59:59.000Z

284

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

285

Long life hearth in blast furnace -- Kokura No. 2 B.F. of Sumitomo Metals  

SciTech Connect (OSTI)

The factors elongating hearth life of Sumitomo Kokura No. 2 B.F. were investigated by use of an estimation system of the furnace hearth condition, which consisted of four mathematical simulation models. Lowered heat load operation together with integrated design of both refractories and cooling enabled the furnace life to be extended for over 16 years without severe damage in the hearth.

Yamamoto, Takaiku; Sunahara, Kouhei; Inada, Takanobu; Takatani, Kouji; Miyahara, Mitsuo; Sato, Yasusi; Hatano, Yasuhiko; Takata, Kouzo

1997-12-31T23:59:59.000Z

286

Air Leakage of Furnaces and Air Handlers Iain S. Walker, Mike Lubliner, Darryl Dickerhoff,  

E-Print Network [OSTI]

Air Leakage of Furnaces and Air Handlers of California. #12;1 Air Leakage of Furnaces and Air Handlers Iain S. Walker, LBNL Mike Lubliner, Washington been made in reducing air leakage in residential and to a lesser extent small commercial forced air

287

Evaluation of PFP Furnace Systems for Thermal Stabilization of Washed High Chloride Plutonium Oxide Items  

SciTech Connect (OSTI)

High chloride content plutonium (HCP) oxides are impure plutonium oxide scrap which contains NaCl, KCl, MgCl2 and/or CaCl2 salts at potentially high concentrations and must be stabilized at 950 C per the DOE Standard, DOE-STD-3013-2000. The chlorides pose challenges to stabilization because volatile chloride salts and decomposition products can corrode furnace heating elements and downstream ventilation components. A high-temperature furnace (same make and model as used at the RMC at Plutonium Finishing Plant) and the associated offgas system were set up at PNNL to identify system vulnerabilities and to investigate alternative materials and operating conditions that would mitigate any corrosion and plugging of furnace and offgas components. The key areas of interest for this testing were the furnace heating elements, the offgas line located inside the furnace, the offgas line between the furnace and the filter/knockout pot, the filter/knockout pot, the sample boat, and corrosion coupons to evaluate alternative materials of construction. The evaluation was conducted by charging the furnace with CeO2 that had been impregnated with a mixture of chloride salts (selected to represent the expected residual chloride salt level in washed high chloride items) and heated in the furnace in accordance with the temperature ramp rates and hold times used at PFP.

Fischer, Christopher M.; Elmore, Monte R.; Schmidt, Andrew J.; Gerber, Mark A.; Muzatko, Danielle S.; Gano, Susan R.; Thornton, Brenda M.

2002-12-17T23:59:59.000Z

288

Improving the Field Performance of Natural Gas Furnaces, Chicago, Illinois (Fact Sheet)  

SciTech Connect (OSTI)

The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

Rothgeb, S.; Brand, L.

2013-11-01T23:59:59.000Z

289

Our scenario is akin to the magnetic furnace model proposed by Axford and  

E-Print Network [OSTI]

Our scenario is akin to the magnetic furnace model proposed by Axford and McKenzie (14­16) and to ideas invoking reconnection of mesoscale loops (38, 39). We adopt from the furnace model the idea. However, our model of the nascent solar wind is intrinsically 3-D, and the magnetic field geometry

Pe'er, Dana

290

Development and installation of an advanced beam guidance system on Viking`s 2.4 megawatt EB furnace  

SciTech Connect (OSTI)

Viking Metallurgical is a manufacturer of titanium alloy and superalloy seamless ring forgings for the aerospace industry. For more than 20 years Viking has used electron beam cold hearth melting to recover titanium alloy scrap and to produce commercially pure titanium ingot for direct forging. In the 1970`s Viking pioneered electron beam cold hearth melting and in 1983 added a two-gun, 2.4 MW furnace. As part of Vikings efforts to improve process control we have commissioned and installed a new electron beam guidance system. The system is capable of generating virtually unlimited EB patterns resulting in improved melt control.

Motchenbacher, C.A.; Grosse, I.A. [Viking Metallurgical, Verdi, NV (United States)

1994-12-31T23:59:59.000Z

291

Using a dual plasma process to produce cobalt--polypyrrole catalysts for the oxygen reduction reaction in fuel cells -- part I: characterisation of the catalytic activity and surface structure  

E-Print Network [OSTI]

A new dual plasma coating process to produce platinum-free catalysts for the oxygen reduction reaction in a fuel cell is introduced. The catalysts thus produced were analysed with various methods. Electrochemical characterisation was carried out by cyclic voltammetry, rotating ring- and rotating ring-disk electrode. The surface porosity of the different catalysts thus obtained was characterised with the nitrogen gas adsorption technique and scanning electron microscopy was used to determine the growth mechanisms of the films. It is shown that catalytically active compounds can be produced with this dual plasma process. Furthermore, the catalytic activity can be varied significantly by changing the plasma process parameters. The amount of H$_2$O$_2$ produced was calculated and shows that a 2 electron mechanism is predominant. The plasma coating mechanism does not significantly change the surface BET area and pore size distribution of the carbon support used. Furthermore, scanning electron microscopy pictures o...

Walter, Christian; Vyalikh, Denis; Brüser, Volker; Quade, Antje; Weltmann, Klaus-Dieter; 10.1149/2.078208jes

2012-01-01T23:59:59.000Z

292

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

293

Optimization of ferrous burden high temperature properties to meet blast furnace requirements in British Steel  

SciTech Connect (OSTI)

The high temperature properties of ferrous burden materials have long been an important consideration in the operation of British Steel blast furnaces. Previous research presented at this conference has shown that the behavior of materials in the lower stack and bosh can have a significant effect on furnace permeability and stability of operation. However, with increasing levels of hydrocarbon injection via the tuyeres, the reduction conditions inside British Steel blast furnaces have significantly altered over recent years. This paper focuses on the further work that has been undertaken to study the effect on ferrous burden high temperatures properties of the widely differing reduction regimes which can be experienced in today`s blast furnaces. The implications of the findings, and how they have been used in optimizing blast furnace operation and burden quality, are discussed.

Bergstrand, R.

1996-12-31T23:59:59.000Z

294

Solid state oxygen sensor  

DOE Patents [OSTI]

Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

1996-01-01T23:59:59.000Z

295

BPM Motors in Residential Gas Furnaces: What are theSavings?  

SciTech Connect (OSTI)

Residential gas furnaces contain blowers to distribute warm air. Currently, furnace blowers use either a Permanent Split Capacitor (PSC) or a Brushless Permanent Magnet (BPM) motor. Blowers account for the majority of furnace electricity consumption. Therefore, accurate determination of the blower electricity consumption is important for understanding electricity consumption of furnaces. The electricity consumption of blower motors depends on the static pressure across the blower. This paper examines both types of blower motors in non-condensing non-weatherized gas furnaces at a range of static pressures. Fan performance data is based on manufacturer product literature and laboratory tests. We use field-measured static pressure in ducts to get typical system curves to calculate how furnaces would operate in the field. We contrast this with the electricity consumption of a furnace blower operating under the DOE test procedure and manufacturer rated conditions. Furnace electricity use is also affected by operating modes that happen at the beginning and end of each furnace firing cycle. These operating modes are the pre-purge and post-purge by the draft inducer, the on-delay and off-delay of the blower, and the hot surface ignitor operation. To accurately calculate this effect, we use the number of firing cycles in a typical California house in the Central Valley of California. Cooling hours are not considered in the DOE test procedure. We also account for furnace blower use by the air conditioner and stand-by power. Overall BPM motors outperform PSC motors, but the total electricity savings are significantly less than projected using the DOE test procedure conditions. The performance gains depend on the static pressure of the household ducts, which are typically much higher than in the test procedures.

Lutz, James; Franco, Victor; Lekov, Alex; Wong-Parodi, Gabrielle

2006-05-12T23:59:59.000Z

296

Energy Conservation Program for Certain Industrial Equipment: Energy Conservation Standards for Commercial Warm Air Furnaces, Notice of Proposed Rulemaking  

Broader source: Energy.gov [DOE]

Energy Conservation Program for Certain Industrial Equipment: Energy Conservation Standards for Commercial Warm Air Furnaces, Notice of Proposed Rulemaking

297

Quantification of Liquid Holdup in the Dropping Zone of a Blast Furnace--A Cold Model Study  

E-Print Network [OSTI]

.S. GUPTA and K. NAVEEN A two-dimensional cold model study, replicating an ironmaking blast furnace dropping

298

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

299

Magnetic resonance imaging of the cerebral metabolic rate of oxygen (CMRO?)  

E-Print Network [OSTI]

Oxygen consumption is an essential process of the functioning brain. The rate at which the brain consumes oxygen is known as the cerebral metabolic rate of oxygen (CMRO?). CMRO? is intimately related to brain health and ...

Bolar, Divya Sanam

2010-01-01T23:59:59.000Z

300

Technical and economical considerations of new DRI melting process  

SciTech Connect (OSTI)

The new DRI melting process can effectively and economically produce high quality molten iron. This process utilizes hot charging of DRI directly from a reduction furnace into a dedicated new melting furnace. The molten iron from this DRI premelter can be charged into a steelmaking furnace, such as an electric arc furnace (EAF), where the molten iron, together with other iron sources, can be processed to produce steel. Alternatively the molten iron can be pigged or granulated for off-site merchant sales. Comprehensive research and development of the new process has been conducted including operational process simulation, melting tests using FASTMET DRI, slag technology development, and refractory corrosion testing. This paper describes the process concept, its operational characteristics and further applications of the process.

Ito, Shuzo; Tokuda, Koji; Sammt, F.; Gray, R.

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2011  

E-Print Network [OSTI]

solubility and porosity · Defects · Design rules · Economics #12;ME 6222: Manufacturing Processes and Systems with charge · steel making in blast furnace -mix coke with steel · Furnace material - refractory ­ high;Melting Time · Estimate by · Take into account oven efficiency ME 6222: Manufacturing Processes

Colton, Jonathan S.

302

Polyx multicrystalline silicon solar cells processed by PF+5 unanalysed ion implantation and rapid thermal annealing  

E-Print Network [OSTI]

of terrestrial solar cells as compared to classical furnace or pulsed laser annealing. Unfortunately, drawbacks695 Polyx multicrystalline silicon solar cells processed by PF+5 unanalysed ion implantation with classical furnace annealing or with classical diffusion process. Revue Phys. Appl. 22 (1987) 695-700 JUILLET

Paris-Sud XI, Université de

303

Operational considerations for high level blast furnace fuel injection  

SciTech Connect (OSTI)

Injection levels of over 400 lbs/NTHM for coal, over 250 lbs/NTHM for natural gas and over 200 lbs/NTHM for oil have been achieved. Such high levels of fuel injection has a major impact on many aspects of blast furnace operation. In this paper the author begins by reviewing the fundamentals of fuel injection with emphasis on raceway thermochemical phenomena. The operational impacts which are generic to high level injection of any injectant are then outlined. The author will then focus on the particular characteristics of each injectant, with major emphasis on coal and natural gas. Operational considerations for coping with these changes and methods of maximizing the benefits of fuel injection will be reviewed.

Poveromo, J.J. [Quebec Cartier Mining Co., Bethlehem, PA (United States)

1996-12-31T23:59:59.000Z

304

Effect of furnace atmosphere on E-glass foaming Dong-Sang Kim a,*, Bryan C. Dutton b  

E-Print Network [OSTI]

Effect of furnace atmosphere on E-glass foaming Dong-Sang Kim a,*, Bryan C. Dutton b , Pavel R in revised form 21 August 2006 Abstract The effect of furnace atmosphere on E-glass foaming has been studied with the specific goal of understanding the impact of increased water content on foaming in oxy-fired furnaces. E-glass

Pilon, Laurent

305

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

306

Photolytic Processes  

Broader source: Energy.gov [DOE]

Photolytic processes use the energy in sunlight to separate water into hydrogen and oxygen. These processes are in the very early stages of research but offer long-term potential for sustainable...

307

Optical Sensors for Post Combustion Control in Electric Arc Furnace Steelmaking (TRP 9851)  

SciTech Connect (OSTI)

Working in collaboration with Stantec Global Technologies, Process Metrix Corporation, and The Timken Company, Sandia National Laboratories constructed and evaluated a novel, laser-based off-gas sensor at the electric arc furnace facility of Timken's Faircrest Steel Plant (Canton, Ohio). The sensor is based on a mid-infrared tunable diode laser (TDL), and measures the concentration and temperature of specific gas species present in the off-gas emanating from the EAF. The laser beam is transmitted through the gas stream at the fourth hole of the EAF, and provides a real-time, in situ measurement that can be used for process optimization. Two sets of field tests were performed in parallel with Stantec's extractive probe off-gas system, and the tests confirm the TDL sensor's operation and applicability for electric steel making. The sensor measures real-time, in situ line-of-sight carbon monoxide (CO) concentrations between 5% and 35% CO, and measures off-gas temperature in the range of 1400 to 1900 K. In order to achieve commercial-ready status, future work is required to extend the sensor for simultaneous CO and CO{sub 2} concentration measurements. In addition, long-term endurance tests including process optimization must be completed.

Sarah W. Allendorf; David K. Ottesen; Robert W. Green; Donald R. Hardesty; Robert Kolarik; Howard Goodfellow; Euan Evenson; Marshall Khan; Ovidiu Negru; Michel Bonin; Soren Jensen

2003-12-31T23:59:59.000Z

308

Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas  

SciTech Connect (OSTI)

The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

309

Monitoring lining and hearth conditions at Inland`s No. 7 blast furnace  

SciTech Connect (OSTI)

The paper describes: furnace statistics; mini-reline undertaken in November, 1993; the stack condition; throat gunning; stabilizing the graphite bricks; the hearth condition; reactions to temperature excursions; future instrumentation; and hot blast system areas of concern. The present data from monitoring systems and inspections indicate that the furnace should be able to operate well beyond the expectation for the 1993 mini-reline (3--5 years) with: (1) consistent, high quality raw materials; (2) instrumentation, diagnostic, remedial, and preventative techniques developed; and (3) stopping quickly any water leaks into the furnace. The longevity of this campaign has undoubtedly been a result of this monitoring program.

Quisenberry, P.; Grant, M.; Carter, W.

1997-12-31T23:59:59.000Z

310

Model of the radial distribution of gas in the blast furnace  

SciTech Connect (OSTI)

This paper describes an on-line model for estimating the radial gas distribution in blast furnaces. The model is based on molar and energy flow balances for the blast furnace throat region, and utilizes the top gas temperature and gas temperature measurements from a fixed above-burden probe. The distribution of the gas flux is estimated by a Kalman filter. The method is illustrated to capture short-term dynamics and to detect sudden major changes in the gas distribution in Finnish blast furnace.

Nikus, M.; Saxen, H. [Aabo Akademi Univ. (Finland). Dept. of Chemical Engineering

1996-12-31T23:59:59.000Z

311

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

312

Oxygen partial pressure sensor  

DOE Patents [OSTI]

A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

Dees, D.W.

1994-09-06T23:59:59.000Z

313

Future Steelmaking Processes  

SciTech Connect (OSTI)

There is an increasing demand for an ironmaking process with lower capital cost, energy consumption and emissions than a blast furnace. It is the hypothesis of the present work that an optimized combination of two reasonable proven technologies will greatly enhance the overall process. An example is a rotary hearth furnace (RHF) linked to a smelter (e.g., AISI, HIsmelt). The objective of this research is to select promising process combinations, develop energy, materials balance and productivity models for the individual processes, conduct a limited amount of basic research on the processes and evaluate the process combinations. Three process combinations were selected with input from the industrial partners. The energy-materials and productivity models for the RHF, smelter, submerged arc furnace and CIRCOFER were developed. Since utilization of volatiles in coal is critical for energy and CO{sub 2} emission reduction, basic research on this topic was also conducted. The process models developed are a major product developed in this research. These models can be used for process evaluation by the industry. The process combinations of an RHF-Smelter and a simplified CIRCOFER-Smelter appear to be promising. Energy consumption is reduced and productivity increased. Work on this project is continuing using funds from other sources.

Prof. R. J. Fruehan

2004-09-20T23:59:59.000Z

314

High Selectivity Oxygen Delignification  

SciTech Connect (OSTI)

The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

Arthur J. Ragauskas

2005-09-30T23:59:59.000Z

315

Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect (OSTI)

Coal is presently the world's primary fuel for generating electrical power and, being more abundant and less expensive than oil or natural gas, is expected to continue its dominance into the future. Coal, however, is more carbon intensive than natural gas and oil and consequently coal-fired power plants are large point source emitters of carbon dioxide (CO{sub 2}). Since CO{sub 2} is a greenhouse gas, which may have an adverse impact on the world's climate/weather patterns, studies have been conducted to determine the feasibility and economic impact of capturing power plant CO{sub 2} emissions for pipeline transport to a sequestration/storage site. The stack gas that exhausts from a modern coal-fired power plant typically contains about 15% CO{sub 2} on a dry volume basis. Although there are numerous processes available for removing CO{sub 2} from gas streams, gas scrubbing with amine solvent is best suited for this application because of the large gas volumes and low CO{sub 2} concentrations involved. Unfortunately the energy required to regenerate the solvent for continued use as a capturing agent is large and imposes a severe energy penalty on the plant. In addition this ''back end'' or post combustion cleanup requires the addition of large vessels, which, in retrofit applications, are difficult to accommodate. As an alternative to post combustion scrubbing, Foster Wheeler (FW) has proposed that the combustion process be accomplished with oxygen rather than air. With all air nitrogen eliminated, a CO{sub 2}-water vapor rich flue gas will be generated. After condensation of the water vapor, a portion of the flue gas will be recirculated back to the boiler to control the combustion temperature and the balance of the CO{sub 2} will be processed for pipeline transport. This proposed oxygen-carbon dioxide (O{sub 2}/CO{sub 2}) combustion process eliminates the need for CO{sub 2} removal/separation and reduces the cost of supplying a CO{sub 2} rich stream for sequestration. FW has developed a conceptual design of an O{sub 2} fired boiler to determine overall plant performance and economics. Five subtasks were conducted: (1) a literature review, (2) a system design and analysis, (3) a low NOx burner design and analysis, (4) a furnace and heat recovery area design analysis, and (5) an economic analysis. The objective of the literature search is to locate any data/information relevant to the Oxygen-Based PC Boiler conceptual design. The objective of the system design and analysis task is to optimize the PC boiler plant by maximizing system efficiency within practical considerations. Simulations of the oxygen-fired plant with CO{sub 2} sequestration were conducted using Aspen Plus and were compared to a reference air-fired 460 MW plant. Flue gas recycle is used in the O{sub 2}-fired PC to control the flame temperature. Parametric runs were made to determine the effect of flame temperature on system efficiency and required waterwall material and thickness. The degree of improvement on system efficiency of various modifications including hot gas recycle, purge gas recycle, flue gas feedwater recuperation, and recycle purge gas expansion were investigated. The selected O{sub 2}-fired design case has a system efficiency of 30.6% compared to the air-fired system efficiency of 36.7%. The design O{sub 2}-fired case requires T91 waterwall material and has a waterwall surface area of only 65% of the air-fired reference case. The objective of the low NOx burner design and analysis task is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent CFD computer program. Four burner designs were developed: (1) with no OFG and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas sw

Andrew Seltzer; Zhen Fan

2005-09-01T23:59:59.000Z

316

Video imaging system and thermal mapping of the molten hearth in an electron beam melting furnace  

SciTech Connect (OSTI)

This project was initiated to develop an enhanced video imaging system for the Liquid Metal Processing Laboratory Electron Beam Melting (EB) Furnace at Sandia and to use color video images to map the temperature distribution of the surface of the molten hearth. In a series of test melts, the color output of the video image was calibrated against temperatures measured by an optical pyrometer and CCD camera viewing port above the molten pool. To prevent potential metal vapor deposition onto line-of-sight optical surfaces above the pool, argon backfill was used along with a pinhole aperture to obtain the vide image. The geometry of the optical port to the hearth set the limits for the focus lens and CCD camera`s field of view. Initial melts were completed with the pyrometer and pinhole aperture port in a fixed position. Using commercially available vacuum components, a second flange assembly was constructed to provide flexibility in choosing pyrometer target sights on the hearth and to adjust the field of view for the focus lens/CCD combination. RGB video images processed from the melts verified that red wavelength light captured with the video camera could be calibrated with the optical pyrometer target temperatures and used to generate temperature maps of the hearth surface. Two color ratio thermal mapping using red and green video images, which has theoretical advantages, was less successful due to probable camera non-linearities in the red and green image intensities.

Miszkiel, M.E.; Davis, R.A.; Van Den Avyle, J.A. [Sandia National Laboratories, Albuquerque, NM (United States)] [and others

1995-12-31T23:59:59.000Z

317

An example of alkalization of SiO{sub 2} in a blast furnace coke  

SciTech Connect (OSTI)

Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2007-09-15T23:59:59.000Z

318

Titanium addition practice, and maintenance for the hearths in AHMSA`s blast furnaces  

SciTech Connect (OSTI)

Altos Hornos de Mexico (AHMSA) is a steel company located in Northern Mexico, in the state of Coahuila. Currently there are three blast furnaces in operation and one more about to finish its general repair. This last one is to remain as a back-up unit. Because of blast furnace hearth wear outs AHMSA has developed some maintenance procedures. These procedures are based on titanium ore additions and hearth thermic control monitoring. There are also some other maintenance practices adopted to the working operations to assure that such operations detect and avoid in time hearth wear outs that place personnel and/or the unit in danger (due to hearth leaks). This paper describes titanium ore addition to No. 2 blast furnace during the final campaign and it also illustrates maintenance practices and continuous monitoring of temperature trends both of which were implemented at AHMSA`s No. 5 blast furnace.

Boone, A.G.; Jimenez, G.; Castillo, J. [Altos Hornos de Mexico, Monclova (Mexico)

1997-12-31T23:59:59.000Z

319

Operational results for high pulverized coal injection rate at Kimitsu No. 3 blast furnace  

SciTech Connect (OSTI)

In order to further develop the technology for high-rate pulverized coal injection (PCI), namely over 200 kg/t-pig, Nippon Steel performed a high injection rate test at the Kimitsu No. 3 blast furnace in November, 1993. The paper describes PCI equipment; the operational design of the test, including blast conditions, reducibility of sinter, coke strength and burden distribution; and test results. These results include a discussion of the transition of operation, burden distribution control, replacement ratio of coke, permeability at upper and lower parts of the furnace, reducibility at lower part of the furnace, accumulation of fines in the deadman, and generation and accumulation of unburnt char. Stable operation was achieved at a PCI rate of 190 kg/t-pig. With injection rates between 200--300 kg/t-pig, the problem becomes how to improve the reduction-meltdown behavior in the lower part of the furnace.

Ueno, Hiromitsu; Matsunaga, Shin`ichi; Kakuichi, Kazumoto; Amano, Shigeru; Yamaguchi, Kazuyoshi

1995-12-01T23:59:59.000Z

320

Residential Bulk-Fed Wood-Pellet Central Boilers and Furnace Rebate Program  

Broader source: Energy.gov [DOE]

The New Hampshire Public Utilities Commission (PUC) is offering rebates of 30% of the installed cost of qualifying new residential bulk-fed, wood-pellet central heating boilers or furnaces. The...

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Improved Heat Transfer and Performance of High Intensity Combustion Systems for Reformer Furnace Applications  

E-Print Network [OSTI]

and should enable substantial capital cost savings in new furnace applications. Recent performance improvements established from tests of high intensity combustion systems are described along with advances made in the analytical prediction of design...

Williams, F. D. M.; Kondratas, H. M.

1983-01-01T23:59:59.000Z

322

BLAST FURNACE GRANULAR COAL INJECTION SYSTEM. Final Report Volume 2: Project Performance and Economics  

SciTech Connect (OSTI)

Bethlehem Steel Corporation (BSC) requested financial assistance from the Department of Energy (DOE), for the design, construction and operation of a 2,800-ton-per-day blast furnace granulated coal injection (BFGCI) system for two existing iron-making blast furnaces. The blast furnaces are located at BSC's facilities in Burns Harbor, Indiana. The demonstration project proposal was selected by the DOE and awarded to Bethlehem in November 1990. The design of the project was completed in December 1993 and construction was completed in January 1995. The equipment startup period continued to November 1995 at which time the operating and testing program began. The blast furnace test program with different injected coals was completed in December 1998.

Unknown

1999-10-01T23:59:59.000Z

323

Economics of residential gas furnaces and water heaters in US new construction market  

E-Print Network [OSTI]

2001 Residential Energy Consumption Survey (RECS 2001; USenergy consumption of residential furnaces and boilers in U.S.US Department of Energy (2001). Residential energy consump- tion survey: household energy consumption

Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

2010-01-01T23:59:59.000Z

324

Understanding environmental leachability of electric arc furnace dust  

SciTech Connect (OSTI)

Dust from production of steel in an electric arc furnace (EAF) contains a mixture of elements that pose a challenge for both recovery and disposal. This paper relates the leachability of six Canadian EAF dusts in four leaching tests [distilled water, Ontario Regulation 347 Leachate Extraction Procedure, Amount Available for Leaching (AALT), and pH 5 Stat] to their mineralogy. Chromium and nickel contaminants in EAF dust are largely unleachable (<5% available in AALT and pH 5 Stat), as they are found with the predominant spinel ferrite phase in EAF dust. However, even a small proportion of oxidized chromium can result in significant leachate concentrations of highly toxic chromate. The leachability of zinc (7--50% available), lead (2--17% available), and cadmium (9--55% available) can be significant, as large fractions of these contaminants are found as chlorides and oxides. The leaching of these metals is largely controlled by pH. The acid neutralization capacity of the EAF dusts appeared to be controlled by dissolution of lime and zincite, and results from regulatory leaching tests can be misleading because the variable acid neutralization capacity of EAF dusts can lead to very different final leachate pHs (5--12.4). A more informative approach would be to evaluate the total amounts of contaminants available in the long term, and the acid neutralization capacity.

Stegemann, J.A.; Roy, A.; Caldwell, R.J.; Schilling, P.J.; Tittsworth, R.

2000-02-01T23:59:59.000Z

325

Vertical feed stick wood fuel burning furnace system  

DOE Patents [OSTI]

A new and improved stove or furnace for efficient combustion of wood fuel including a vertical feed combustion chamber for receiving and supporting wood fuel in a vertical attitude or stack, a major upper portion of the combustion chamber column comprising a water jacket for coupling to a source of water or heat transfer fluid and for convection circulation of the fluid for confining the locus of wood fuel combustion to the bottom of the vertical gravity feed combustion chamber. A flue gas propagation delay channel extending from the laterally directed draft outlet affords delayed travel time in a high temperature environment to assure substantially complete combustion of the gaseous products of wood burning with forced air as an actively induced draft draws the fuel gas and air mixture laterally through the combustion and high temperature zone. Active sources of forced air and induced draft are included, multiple use and circuit couplings for the recovered heat, and construction features in the refractory material substructure and metal component superstructure.

Hill, Richard C. (Orono, ME)

1984-01-01T23:59:59.000Z

326

Vertical feed stick wood fuel burning furnace system  

DOE Patents [OSTI]

A stove or furnace for efficient combustion of wood fuel includes a vertical feed combustion chamber (15) for receiving and supporting wood fuel in a vertical attitude or stack. A major upper portion of the combustion chamber column comprises a water jacket (14) for coupling to a source of water or heat transfer fluid for convection circulation of the fluid. The locus (31) of wood fuel combustion is thereby confined to the refractory base of the combustion chamber. A flue gas propagation delay channel (34) extending laterally from the base of the chamber affords delayed travel time in a high temperature refractory environment sufficient to assure substantially complete combustion of the gaseous products of wood burning with forced air prior to extraction of heat in heat exchanger (16). Induced draft draws the fuel gas and air mixture laterally through the combustion chamber and refractory high temperature zone to the heat exchanger and flue. Also included are active sources of forced air and induced draft, multiple circuit couplings for the recovered heat, and construction features in the refractory material substructure and metal component superstructure.

Hill, Richard C. (Orono, ME)

1982-01-01T23:59:59.000Z

327

Detailed model for practical pulverized coal furnaces and gasifiers  

SciTech Connect (OSTI)

The need to improve efficiency and reduce pollutant emissions commercial furnaces has prompted energy companies to search for optimized operating conditions and improved designs in their fossil-fuel burning facilities. Historically, companies have relied on the use of empirical correlations and pilot-plant data to make decisions about operating conditions and design changes. The high cost of collecting data makes obtaining large amounts of data infeasible. The main objective of the data book is to provide a single source of detailed three-dimensional combustion and combustion-related data suitable for comprehensive combustion model evaluation. Five tasks were identified as requirements to achieve the main objective. First, identify the types of data needed to evaluate comprehensive combustion models, and establish criteria for selecting the data. Second, identify and document available three-dimensional combustion data related to pulverized coal combustion. Third, collect and evaluate three-dimensional data cases, and select suitable cases based on selection criteria. Fourth, organize the data sets into an easy-to-use format. Fifth, evaluate and interpret the nature and quality of the data base. 39 refs., 15 figs., 14 tabs.

Philips, S.D.; Smoot, L.D.

1989-08-01T23:59:59.000Z

328

Hearth monitoring experiences at Dofasco`s No. 4 blast furnace  

SciTech Connect (OSTI)

As a result of a 1994 taphole breakout at Dofasco`s No. 4 Blast Furnace, extensive effort has gone into monitoring, understanding and controlling hearth wear. This paper reviews the hearth monitoring system developed and the various hearth operating and maintenance techniques used to ensure No. 4 Blast Furnace safely reaches its 1998 reline date. The impact of changes in coke quality, productivity, casting practice and leaking cooling members on hearth refractory temperature fluctuations will also be examined.

Stothart, D.W.; Chaykowski, R.D.; Donaldson, R.J.; Pomeroy, D.H.

1997-12-31T23:59:59.000Z

329

Refinery Furnaces Retrofit with Gas Turbines Achieve Both Energy Savings and Emission Reductions  

E-Print Network [OSTI]

REFINERY FURNACES RETROFIT WITH GAS TURBINES ACHIEVE BOTH ENERGY SAVINGS AND EMISSION REDUCTIONS F. Giacobbe*, G. Iaquaniello**, R. G. Minet*, P. Pietrogrande* *KTI Corp., Research and Development Division, Monrovia, California **KTI Sp...A., Rome, Italy ABSTRACT Integrating gas turbines with refinery furnaces can be a cost effective means of reducing NO emissions while also generating electricity ~t an attractive heat rate. Design considerations and system costs are presented...

Giacobbe, F.; Iaquaniello, G.; Minet, R. G.; Pietrogrande, P.

330

Expert Meeting Report: Achieving the Best Installed Performance from High-Efficiency Residential Gas Furnaces  

SciTech Connect (OSTI)

This report describes a Building America expert meeting hosted on July 28, 2011, by the Partnership for Advanced Residential Retrofit team. The purpose of this meeting was to identify installation practices that provide the best installed efficiency for residential gas furnaces, explain how AFUE and field efficiency can differ, and investigate the impact of installation practices on the efficiency and long-term durability of the furnace.

Brand, L.

2012-03-01T23:59:59.000Z

331

Integrated turbomachine oxygen plant  

SciTech Connect (OSTI)

An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

2014-06-17T23:59:59.000Z

332

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

2005-07-12T23:59:59.000Z

333

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

2004-11-23T23:59:59.000Z

334

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

335

Pulverized coal injection (PCI) at Inland`s No. 7 blast furnace  

SciTech Connect (OSTI)

Fuel injection at the tuyeres has always been part of normal operating practice on this blast furnace. It has been used as much because of the beneficial effects on furnace operation as for the replacement of some of the coke that would otherwise be consumed. Fuel oil was used at first, but since the early 1980s it was more economical to inject natural gas. Studies in 1990 indicated that natural gas could be increased to 75 kg/tHM on No. 7 Furnace, and this would result in a coke rate of approximately 360 kg/tHM. It was apparent that coal injection offered significantly more opportunity for coke savings. Coke rate could be lowered to 300 kg/tHM with coal injected at 175 kg/tHM. Some combustion limitations were expected at that level. A coke rate of 270 kg/tHM with coal at 200 kg/tHM may be possible once these limitations are overcome. Furnace permeability was expected to limit the ability to reduce coke rate any further. In addition, the relative cost of coal would be significantly lower than the cost of coke it replaced. This lead to the decision late in 1991 to install pulverized coal injection (PCI) equipment for all of Inland`s blast furnaces. This paper will deal with PCI experience at No. 7 Blast Furnace.

Carter, W.L.; Greenawald, P.B.; Ranade, M.G.; Ricketts, J.A.; Zuke, D.A. [Inland Steel Co., East Chicago, IN (United States)

1995-12-01T23:59:59.000Z

336

Gas-powder flow in blast furnace with different shapes of cohesive zone  

SciTech Connect (OSTI)

With high PCI rate operations, a large quantity of unburned coal/char fines will flow together with the gas into the blast furnace. Under some operating conditions, the holdup of fines results in deterioration of furnace permeability and lower production efficiency. Therefore, it is important to understand the behaviour of powder (unburnt coal/char) inside the blast furnace when operating with different cohesive zone (CZ) shapes. This work is mainly concerned with the effect of cohesive zone shape on the powder flow and accumulation in a blast furnace. A model is presented which is capable of simulating a clear and stable accumulation region in the lower central region of the furnace. The results indicate that powder is likely to accumulate at the lower part of W-shaped CZs and the upper part of V- and inverse V-shaped CZs. For the same CZ shape, a thick cohesive layer can result in a large pressure drop while the resistance of narrow cohesive layers to gas-powder flow is found to be relatively small. Implications of the findings to blast furnace operation are also discussed.

Dong, X.F.; Pinson, D.; Zhang, S.J.; Yu, A.B.; Zulli, P. [University of New South Wales, Sydney, NSW (Australia)

2006-11-15T23:59:59.000Z

337

alloy processing plant: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pricing. This, in turn, negatively...-product of the olefins cracking process. This off-gas is routinely used as fuel for the olefins furnaces. Supplemental fuel for the...

338

acid processing plant: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pricing. This, in turn, negatively...-product of the olefins cracking process. This off-gas is routinely used as fuel for the olefins furnaces. Supplemental fuel for the...

339

Fuel Saving Ideas for Metal and Ceramic Processing  

E-Print Network [OSTI]

An easy method is presented for analyzing sources of heat loss from industrial processing furnaces, kilns, and ovens; and thus for recognizing opportunities for fuel saving. This will relate to melting, heat treating and hot forming of metals...

Reed, R. J.

1982-01-01T23:59:59.000Z

340

Effect of blast furnace slag on self-healing of microcracks in cementitious materials  

SciTech Connect (OSTI)

The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH){sub 2} solution as activator, it was found that the reaction products formed in cracks are composed of C-S-H, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of C-S-H in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO{sub 4}{sup 2?} ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50 h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high. - Highlights: • Self-healing reaction products in slag cement paste were characterized. • Self-healing reaction products formed in time were quantified with image analysis. • Self-healing in slag cement paste was simulated with a reactive transport model. • Effect of carbonation on self-healing was investigated by thermodynamic modeling. • Effect of slag on self-healing was discussed based on experiments and simulation.

Huang, Haoliang, E-mail: haoliang.huang@tudelft.nl [Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology (Netherlands); Ye, Guang [Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology (Netherlands); Magnel Laboratory for Concrete Research, Department of Structural Engineering, Ghent University (Belgium); Damidot, Denis [Université Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France)

2014-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

Nsakala ya Nsakala; Gregory N. Liljedahl

2003-05-15T23:59:59.000Z

342

Uncertainty of calorimeter measurements at NREL's high flux solar furnace  

SciTech Connect (OSTI)

The uncertainties of the calorimeter and concentration measurements at the High Flux Solar Furnace (HFSF) at the National Renewable Energy Laboratory (NREL) are discussed. Two calorimeter types have been used to date. One is an array of seven commercially available circular foil calorimeters (gardon or heat flux gages) for primary concentrator peak flux (up to 250 W/cm{sup 2}). The second is a cold-water calorimeter designed and built by the University of Chicago to measure the average exit power of the reflective compound parabolic secondary concentrator used at the HFSF (over 3.3 kW across a 1.6cm{sup {minus}2} exit aperture, corresponding to a flux of about 2 kW/cm{sup 2}). This paper discussed the uncertainties of the calorimeter and pyrheliometer measurements and resulting concentration calculations. The measurement uncertainty analysis is performed according to the ASME/ANSI standard PTC 19.1 (1985). Random and bias errors for each portion of the measurement are analyzed. The results show that as either the power or the flux is reduced, the uncertainties increase. Another calorimeter is being designed for a new, refractive secondary which will use a refractive material to produce a higher average flux (5 kW/cm{sup 2}) than the reflective secondary. The new calorimeter will use a time derivative of the fluid temperature as a key measurement of the average power out of the secondary. A description of this calorimeter and test procedure is also presented, along with a pre-test estimate of major sources of uncertainty. 8 refs., 4 figs., 3 tabs.

Bingham, C.E.

1991-12-01T23:59:59.000Z

343

Evaluation of Retrofit Variable-Speed Furnace Fan Motors  

SciTech Connect (OSTI)

In conjunction with the New York State Energy Research and Development Authority (NYSERDA) and Proctor Engineering Group, Ltd. (PEG), the Consortium for Advanced Residential Buildings (CARB) has evaluated the Concept 3 (tm) replacement motors for residential furnaces. These brushless, permanent magnet (BPM) motors can use much less electricity than their PSC (permanent split capacitor) predecessors. This evaluation focuses on existing homes in the heating-dominated climate of upstate New York with the goals of characterizing field performance and cost-effectiveness. The results of this study are intended to be useful to home performance contractors, HVAC contractors, and home efficiency program stakeholders. The project includes eight homes in and near Syracuse, NY. Tests and monitoring was performed both before and after fan motors were replaced. Average fan power reductions were approximately 126 Watts during heating and 220 Watts during cooling operation. Over the course of entire heating and cooling seasons, these translated into average electric energy savings of 163 kWh. Average cost savings were $20 per year. Homes where the fan was used outside of heating and cooling mode saved an additional $42 per year on average. Results indicate that BPM replacement motors will be most cost-effective in HVAC systems with longer run times and relatively low duct static pressures. More dramatic savings are possible if occupants use the fan-only setting when there is no thermal load. There are millions of cold-climate, U.S. homes that meet these criteria, but the savings in most homes tested in this study were modest.

Aldrich, R.; Williamson, J.

2014-01-01T23:59:59.000Z

344

Sandjet- A New Alternative for Cleaning Furnace Tubes  

E-Print Network [OSTI]

Industrial Energy Technology Conference Houston, TX, April 26-29, 1981 The reaction in which oxygen combines with carbon to form carbon dioxide (C02) is a very efficient way of removing carbonaceous material. Since it is highly exothermic, steam is added... of tube walls. Shot peening is normally considered to be a superficial stress relieving technique and Sandjet cleaning can be considered to be analogous to in-place shot peening. Steam-air decoking previously described involves the exothermic reaction...

Pollock, C. B.

1981-01-01T23:59:59.000Z

345

Recent Progress in the DEOX Process  

SciTech Connect (OSTI)

Recent Progress in the DEOX Process B.R. Westphal, K.J. Bateman, R.P. Lind, and D.L. Wahlquist Idaho National Laboratory: P.O. Box 1625, Idaho Falls, ID, 83415, and brian.westphal@inl.gov INTRODUCTION A head-end processing step is being developed for the treatment of spent oxide fuel by either aqueous or pyrochemical technologies. The head-end step, termed DEOX for its emphasis on decladding via oxidation, employs high temperatures to promote the oxidation of UO2 to U3O8 via an oxygen carrier gas. During oxidation, the spent fuel experiences a 30% increase in lattice structure volume resulting in the separation of fuel from cladding. An added benefit of the head-end step is the removal of fission products, either via direct release from the broken fuel structure or via oxidation and volatilization by the high temperature process. The DEOX program at the Idaho National Laboratory has progressed from an initial exploratory phase, where the objective was the optimization of particle size and fuel-clad separation [1], to a phase more applicable to current flowsheet development, i.e. the removal and collection of targeted fission products [2]. The behavior of fission products has been investigated via testing with irradiated spent fuel to determine the effects of temperature, pressure, oxidative gas, and cladding on the removal efficiencies of targeted fission products. In addition, a preliminary design for the retention of fission products in an off-gas treatment system has been initiated as part of a collaborative effort with Korea Atomic Energy Research Institute through an International Nuclear Energy Research Initiative (I-NERI). RECENT PROGRESS Using a set low temperature oxidation cycle near 500oC, additional conditions have been applied to distinguish their effects on the removal of targeted fission products. Both oxygen and air have been utilized during the oxidation portion followed by vacuum conditions to temperatures as high as 1050oC. In addition, the effects of cladding on fission product removal have also been investigated with released fuel to temperatures greater than 500oC. Results from these experiments as well as those from on-going tests will be presented. Shown in Fig. 1 is the conceptual design for a vertical split tube furnace which includes four separately controlled heating zones. The lowest zone contains the spent oxide fuel while the upper three zones are for the collection of specific off-gassed fission products. The sealed inner assembly will have the ability to be remotely disassembled so that the trapping units with filter media can be individually analyzed. Design and fabrication efforts for this furnace are currently being performed. Fig. 1. DEOX Furnace with Off-Gas Treatment System Assembly. REFERENCES 1. B.R. WESTPHAL et al., Results of Phase I Testing for the DEOX Process, Trans. Am. Nucl. Soc., 91, pp. 519-20 (2004). 2. B.R. WESTPHAL, K.J. BATEMAN, R.P. LIND, K.L. HOWDEN, and G.D. DEL CUL, Fission Product Removal from Spent Oxide Fuel by Head-End Processing, Proc. Global 2005, AESJ, Tsukuba, Japan (2005).

B.R. Westphal; K.J. Bateman; R.P. Lind; D.L. Wahlquist

2006-06-01T23:59:59.000Z

346

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

347

Effect of coal and coke qualities on blast furnace injection and productivity at Taranto  

SciTech Connect (OSTI)

Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

1995-12-01T23:59:59.000Z

348

Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittal’s Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel; however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.

Seaman, John

2013-01-14T23:59:59.000Z

349

Economics of residential gas furnaces and water heaters in United States new construction market  

SciTech Connect (OSTI)

New single-family home construction represents a significant and important market for the introduction of energy-efficient gas-fired space heating and water-heating equipment. In the new construction market, the choice of furnace and water-heater type is primarily driven by first cost considerations and the availability of power vent and condensing water heaters. Few analysis have been performed to assess the economic impacts of the different combinations of space and water-heating equipment. Thus, equipment is often installed without taking into consideration the potential economic and energy savings of installing space and water-heating equipment combinations. In this study, we use a life-cycle cost analysis that accounts for uncertainty and variability of the analysis inputs to assess the economic benefits of gas furnace and water-heater design combinations. This study accounts not only for the equipment cost but also for the cost of installing, maintaining, repairing, and operating the equipment over its lifetime. Overall, this study, which is focused on US single-family new construction households that install gas furnaces and storage water heaters, finds that installing a condensing or power-vent water heater together with condensing furnace is the most cost-effective option for the majority of these houses. Furthermore, the findings suggest that the new construction residential market could be a target market for the large-scale introduction of a combination of condensing or power-vent water heaters with condensing furnaces.

Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

2009-05-06T23:59:59.000Z

350

Brazing open cell reticulated copper foam to stainless steel tubing with vacuum furnace brazed gold/indium alloy plating  

DOE Patents [OSTI]

A method of fabricating a heat exchanger includes brush electroplating plated layers for a brazing alloy onto a stainless steel tube in thin layers, over a nickel strike having a 1.3 .mu.m thickness. The resultant Au-18 In composition may be applied as a first layer of indium, 1.47 .mu.m thick, and a second layer of gold, 2.54 .mu.m thick. The order of plating helps control brazing erosion. Excessive amounts of brazing material are avoided by controlling the electroplating process. The reticulated copper foam rings are interference fit to the stainless steel tube, and in contact with the plated layers. The copper foam rings, the plated layers for brazing alloy, and the stainless steel tube are heated and cooled in a vacuum furnace at controlled rates, forming a bond of the copper foam rings to the stainless steel tube that improves heat transfer between the tube and the copper foam.

Howard, Stanley R. (Windsor, SC); Korinko, Paul S. (Aiken, SC)

2008-05-27T23:59:59.000Z

351

A mathematical simulation of oxygen and lactic acid transport in skeletal muscle subject to periodic ischemia  

E-Print Network [OSTI]

oxidative processes . However, as Jobis and Chance point out, the 21 22 23 oxygen utilization of respiring cells w111 become oxygen dependent at some critical partial pressure of oxygen (p02) such that as the p02 falls so will the oxygen consumpt1on rate...

Artigue, Ronald Stephen

1974-01-01T23:59:59.000Z

352

High Selectivity Oxygen Delignification  

SciTech Connect (OSTI)

Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

Lucian A. Lucia

2005-11-15T23:59:59.000Z

353

A DIGITAL CONTROL SYSTEM FOR OPTIMAL OXYGEN TRANSFER  

E-Print Network [OSTI]

A DIGITAL CONTROL SYSTEM FOR OPTIMAL OXYGEN TRANSFER EFFICIENCY Arnold Schwarzenegger Governor system ............................. 10 5.2 Types of aeration processes of fine bubble diffusers for sub-surface aeration ............ 13 5.5 Process design considerations

354

The formation of an ore free blast furnace center by bell charging  

SciTech Connect (OSTI)

A research program has been started to clarify and support the central gas flow control philosophy of Hoogovens` bell-charged No. 7 blast furnace. Small scale burdening experiments and sampling of the stock surface during shut-downs suggest that a sufficiently high central gas flow is an important condition for maintenance of an ore free, highly permeable furnace center and that fluidization of coke plays a part in its formation. On the basis of these experiments a hypothesis was formulated regarding the formation of an ore free blast furnace center, but could not be confirmed satisfactorily. Forthcoming full-scale burdening experiments will provide a better insight in the burden distribution and its control.

Exter, P. den; Steeghs, A.G.S.; Godijn, R.; Chaigneau, R.; Timmer, R.M.C. [Hoogovens Research and Development, IJmuiden (Netherlands); Toxopeus, H.L.; Vliet, C. van der [Hoogovens Staal Primary Products, IJmuiden (Netherlands)

1997-12-31T23:59:59.000Z

355

Hoogovens blast furnace No. 6 -- The first eleven years of a continuing campaign  

SciTech Connect (OSTI)

Blast furnace No. 6 of Hoogovens Steel has just completed its eleventh year of the fourth (running) campaign, with a total production of approx. 23 million metric tonnes of hot metal. During the last reline in 1985 the furnace was equipped with a third taphole and a bell-less top. The lining consists of graphite and semi-graphite and the cooling consists of a dense pattern of copper plate coolers. The current campaign is marked by several important operational events, in particular the high productivity and PCI rates, but also by the remarkable performance of the lining which has shown limited wear in the first four years of the campaign, and hardly any reduction of the lining thickness in the last seven years. This paper discusses the design of the furnace, and the history of the current campaign with respect to its productivity, PCI rates and lining wear.

Tijhuis, G.; Toxopeus, H.; Berg, H. van den; Vliet, C. van der [Hoogovens Steel, IJmuiden (Netherlands)

1997-12-31T23:59:59.000Z

356

Apparatus having inductively coupled coaxial coils for measuring buildup of slay or ash in a furnace  

DOE Patents [OSTI]

The buildup of slag or ash on the interior surface of a furnace wall is monitored by disposing two coils to form a transformer which is secured adjacent to the inside surface of the furnace wall. The inductive coupling between the two coils of the transformer is affected by the presence of oxides of iron in the slag or ash which is adjacent to the transformer, and the application of a voltage to one winding produces a voltage at the other winding that is related to the thickness of the slag or ash buildup on the inside surface of the furnace wall. The output of the other winding is an electrical signal which can be used to control an alarm or the like or provide an indication of the thickness of the slag or ash buildup at a remote location.

Mathur, Mahendra P. (Pittsburgh, PA); Ekmann, James M. (Bethel Park, PA)

1989-01-01T23:59:59.000Z

357

Liquid Metal Processing and Casting Experiences at the U.S. Department of Energy's Albany Research Center  

SciTech Connect (OSTI)

In this paper we will discuss some of the early pioneering work as well as some of our more recent research. The Albany Research Center (ARC) has been involved with the melting and processing of metals since it was established in 1942. In the early days, hardly anything was known about melting refractory or reactive metals and as such, virtually everything had to be developed in-house. Besides the more common induction heated air-melt furnaces, ARC has built and/or utilized a wide variety of furnaces including vacuum arc remelt ingot and casting furnaces, cold wall induction furnaces, electric arc furnaces, cupola furnaces and reverberatory furnaces. The melt size of these furnaces range from several grams to a ton or more. We have used these furnaces to formulate custom alloys for wrought applications as well as for such casting techniques as spin casting, investment casting and lost foam casting among many. Two early spin-off industrializations were Wah Chang (wrought zirconium alloys for military and commercial nuclear applications) and Oremet (both wrought and cast Ti). Both of these companies are now part of the ATI Allegheny Ludlum Corporation.

Jablonski, Paul D.; Turner, Paul C.

2005-09-01T23:59:59.000Z

358

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

359

Altos Hornos de Mexico blast furnace No. 5 certification in ISO-9002 standard  

SciTech Connect (OSTI)

Altos Hornos de Mexico`s Blast Furnace No. 5, as a means to improve its product quality, sought and obtained the certification of its quality system based on the international standard ISO-9002. The certification was obtained under this quality standard in Dec. 1995 and has successfully been maintained after two continuance audits. For blast furnace No. 5 (BF5) the benefits are reflected by a reduction in the hot metal silicon content variability, a decrease in fuel consumption and a higher productivity. Benefits were also obtained in the working environment where the personnel became more highly motivated, procedures were carried out to completion and the quality records were filled correctly.

Gamez, O.; Liceaga, F.; Arredondo, J. [Altos Hornos de Mexico, Monclova (Mexico)

1997-12-31T23:59:59.000Z

360

Continuous measurement of blast furnace burden profile at SSAB Tunnplat AB  

SciTech Connect (OSTI)

A unique profile meter system is installed on Blast Furnace No. 2 in SSAB - Swedish Steel AB, Lulea, Sweden. This system measures the charge material burden profile across the furnace top diameter before and after each charge. The system generates real-time data, which is graphically presented by the system on a monitor and includes burden descent speed, layer thickness of the coke and ore (corrected for descent), ore to coke ratio, and burden skewing. The system is described along with operational results.

Virtala, J.; Edberg, N.; Hallin, M. (SSAB Tunnplat AB, Lulea (Sweden). Ironmaking Division)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Bosh repairs No. 3 blast furnace, Edgar Thomson Plant Mon Valley Works  

SciTech Connect (OSTI)

The paper describes in detail the steps taken from quenching to dry out of the furnace to repair the bosh area of the No.3 blast furnace. Inspection of the area revealed that there was no brick anywhere in the bosh. Brick in the tuyere breast area had been peeled back to reveal the steel plate, and descaling revealed 14 pipes fully exposed. None were leaking, but one seemed badly deteriorated. Conventional repairs could not take place before the scheduled blow-in. Installation of coolers were instead tried.

Stoupis, M.G.

1993-01-01T23:59:59.000Z

362

Coal-fired furnace for testing of thermionic converters. Topical report  

SciTech Connect (OSTI)

The development of thermionic converter technology has progressed to make near-term applications interesting. One of these applications is the thermionic topping of a pulverized coal-fired central station powerplant. Up to now, thermionic converters have been flame tested using natural gas as fuel. A new test furnace is required for evaluation of thermionic converters in a coal-fired environment. The design and costs of a facility which adapts a coal-fired furnace built by Foster Wheeler Development Corporation (FWDC) for thermionic converter testing are discussed. Such a facility would be exempt from air pollution regulations because of its low firing rate.

Not Available

1980-10-01T23:59:59.000Z

363

Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology  

SciTech Connect (OSTI)

The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

Swanson, Michael; Henderson, Ann

2012-04-01T23:59:59.000Z

364

Removal of ammonia from tarry water using a tubular furnace  

SciTech Connect (OSTI)

An ammonia-processing system without the use of live steam from OAO Alchevskkoks plant's supply network is considered. Steam obtained from the wastewater that leaves the ammonia column is used to process the excess tarry water, with the release of volatile ammonia.

V.V. Grabko; V.A. Kofanova; V.M. Li; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

365

Studies of charging stream trajectories and burden distribution in the blast furnace  

SciTech Connect (OSTI)

This work discusses the sensitivity of key blast furnace performance parameters to different gas flow distributions achieved by altering the burden distribution. The changes in burden distribution are brought about by different charging stream trajectories, and methods developed and evaluated for measuring the trajectories both on and off line are described.

McCarthy, M.J.; Mayfield, P.L.; Zulli, P.; Rex, A.J.; Tanzil, W.B.U.

1993-01-01T23:59:59.000Z

366

Development of quick repairing technique for ceramic burner in hot stove of blast furnace  

SciTech Connect (OSTI)

Refractories of ceramic burner in hot stoves at Wakayama No. 4 blast furnace were damaged. There are only three hot stoves, so repairing must be done in a short. Therefore, a quick repairing technique for ceramic burners has been developed, and two ceramic burners were repaired in just 48 hours.

Kondo, Atsushi; Doura, Kouji; Nakamura, Hirofumi [Sumitomo Metal Industries, Ltd., Wakayama (Japan). Wakayama Steel Works

1997-12-31T23:59:59.000Z

367

Recovery of titanium values from titanium grinding swarf by electric furnace smelting  

DOE Patents [OSTI]

A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

Gerdemann, Stephen J. (Albany, OR); White, Jack C. (Albany, OR)

1999-01-01T23:59:59.000Z

368

Recovery of titanium values from titanium grinding swarf by electric furnace smelting  

DOE Patents [OSTI]

A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

Gerdemann, Stephen J. (Albany, OR); White, Jack C. (Albany, OR)

1998-01-01T23:59:59.000Z

369

Recovery of titanium values from titanium grinding swarf by electric furnace smelting  

DOE Patents [OSTI]

A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag. 1 fig.

Gerdemann, S.J.; White, J.C.

1998-08-04T23:59:59.000Z

370

Directly induced swing for closed loop control of electroslag remelting furnace  

DOE Patents [OSTI]

An apparatus and method are disclosed for controlling an electroslag remelting furnace, imposing a periodic fluctuation on electrode drive speed and thereby generating a predictable voltage swing signal. The fluctuation is preferably done by imposition of a sine, square, or sawtooth wave on the drive dc offset signal. 8 figs.

Damkroger, B.

1998-04-07T23:59:59.000Z

371

Energy Conservation Program for Consumer Products: Test Procedures for Residential Furnaces Fans; Correction  

Broader source: Energy.gov [DOE]

On January 3, 2014 the U.S. Department of Energy (DOE) published a final rule in the Federal Register that established the test procedure for residential furnace fans. Due to drafting errors, that document inadvertently removed necessary incorporation by reference material in the Code of Federal Regulations (CFR). This final rule rectifies this error by once again adding the removed material.

372

Savings from new oil furnaces: A study conducted as part of Washington State's Oil Help Program  

SciTech Connect (OSTI)

The Washington State Energy Office (WSEO) has been running the Oil Help program for three years. Originally operated as a loan program, Oil Help switched to rebates during the 1987 and 1988. Rebates for oil furnace replacements made up over 70 percent of rebate funds, which totaled about $1.3 million. WSEO Evaluation started research in summer of 1988, with the goal of including 100 new furnace households (with a control group of similar size) in the study. Our intention was to look at long-term oil consumption comparing each household with itself over the two periods. The final study group consists of 43 households and a control group of 87 households. The report begins with a review of related research. A discussion of research methodology, weather normalization procedure, data attrition, and important descriptive details follows. Changes in consumption for the new furnace and control groups are reported and are tested for significance. Finally, we discuss the implications of the results for the cost effectiveness of an oil furnace replacement.

Davis, R.

1989-12-01T23:59:59.000Z

373

Temperature Compensated Air/Fuel Ratio Control on a Recuperated Furnace  

E-Print Network [OSTI]

When recuperation is added to a furnace, air/ fuel ratio control seemingly becomes more complicated. Two methods normally used are mass flow control where the fuel pressure or flow is proportional to the mass flow of air or cross-connected control...

Ferri, J. L.

1983-01-01T23:59:59.000Z

374

Laser-excited atomic fluorescence spectrometry in a graphite furnace with an  

E-Print Network [OSTI]

Laser-excited atomic fluorescence spectrometry in a graphite furnace with an optical parametric oscillator laser for sequential multi-element determination of cadmium, cobalt, lead, manganese and thallium, for the ® rst time, that solid-state lasers required for analysis (ml or mg) and the technique has direct based

Michel, Robert G.

375

Effect of Electric Arc Furnace Bag House Dust on Concrete Durability Researcher: Fahad Al-Mutlaq  

E-Print Network [OSTI]

Effect of Electric Arc Furnace Bag House Dust on Concrete Durability Researcher: Fahad Al billions of dollars annually. While steel is normally protected from corrosion in concrete by a passive of the effects of addition of Bag House Dust (BHD) on aspects of concrete durability. BHD is a fine powder

Birmingham, University of

376

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

377

Optimization of the process of plasma ignition of coal  

SciTech Connect (OSTI)

Results are given of experimental and theoretical investigations of plasma ignition of coal as a result of its thermochemical preparation in application to the processes of firing up a boiler and stabilizing the flame combustion. The experimental test bed with a commercial-scale burner is used for determining the conditions of plasma ignition of low-reactivity high-ash anthracite depending on the concentration of coal in the air mixture and velocity of the latter. The calculations produce an equation (important from the standpoint of practical applications) for determining the energy expenditure for plasma ignition of coal depending on the basic process parameters. The tests reveal the difficulties arising in firing up a boiler with direct delivery of pulverized coal from the mill to furnace. A scheme is suggested, which enables one to reduce the energy expenditure for ignition of coal and improve the reliability of the process of firing up such a boiler. Results are given of calculation of plasma thermochemical preparation of coal under conditions of lower concentration of oxygen in the air mixture.

Peregudov, V.S. [Russian Academy of Sciences, Novosibirsk (Russian Federation)

2009-04-15T23:59:59.000Z

378

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

379

Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*,  

E-Print Network [OSTI]

Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*, Lee D. Bryant,, Andreas Matzinger obtained from 11 eutrophic lakes and suggests a model describing the consumption of dissolved oxygen (O2) in the hypolimnia of eutrophic lakes as a result of only two fundamental processes: O2 is consumed (i) by settled

Wehrli, Bernhard

380

Singlet oxygen luminescence detection with a fibre-coupled superconducting  

E-Print Network [OSTI]

Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector, is an intermediate in many biological processes. We employ a superconducting nanowire single-photon detector (SNSPD

Greenaway, Alan

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Furnace Pressure Controllers; Industrial Technologies Program (ITP) Energy Tips - Process Heating Tip Sheet #6 (Fact Sheet).  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional ElectricalEnergyQualityAUGUSTPart 3 of3.2.103 Fungal6 *

382

Integrated use of burden profile probe and in-burden probe for gas flow control in the blast furnace  

SciTech Connect (OSTI)

Gas flow in the blast furnace is one of the most important factors in controlling a furnace. It not only determines the production but also the fuel consumption and the campaign life. At Nos. 4 and 5 blast furnaces of ROGESA, probes are installed for detection of the burden profiles and of the gas flow distribution. For an optimum use of these probes a program system has been developed by ROGESA and Dango and Dienenthal. With this program system it is possible to analyze the operating condition of a blast furnace by means of a fuzzy logic analysis. In case of deviations from the defined desired condition, recommendations for corrective measures for the material distribution are made. Both furnaces are equipped with a bell-less top, a coal injection system, high-temperature hot blast stoves with heat recovery and a top gas pressure recovery turbine. Most of the time it is impossible to control all the required parameters. For this reason it is meaningful to measure the actual material distribution at the furnace top by means of a burden profile probe which permits quick and repeated measurements without any retroactive effects. The paper describes the instrumentation of the furnace, correlation of measuring methods, and a program system for analysis of measuring data.

Bordemann, F.; Hartig, W.H. [AG der Dillinger Huettenweke, Dillingen (Germany); Grisse, H.J. [Dango and Dienenthal Siegen (Germany); Speranza, B.E. [Dango and Dienenthal, Inc., Highland, IN (United States)

1995-12-01T23:59:59.000Z

383

Direct Observation of the Oxygenated Species during Oxygen Reduction...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

384

A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace  

SciTech Connect (OSTI)

A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

Murray, J.P.

1989-01-01T23:59:59.000Z

385

Oxygen generator for medical applications (USIC)  

SciTech Connect (OSTI)

The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

Staiger, C. L.

2012-03-01T23:59:59.000Z

386

Record production on Gary No. 13 blast furnace with 450 lb./THM co-injection rates  

SciTech Connect (OSTI)

Coal injection was initiated on No. 13 Blast Furnace in 1993 with 400 lb/THM achieved in 9 months. In early 1994, cold weather and coal preparation upsets led to the use of a second injectant, oil atomized by natural gas, to supplement the coal. Various combinations of coal and oil were investigated as total injection was increased to 450 lb/THM. Beginning in the last half of 1994, a continuing effort has been made to increase furnace production while maintaining this high co-injection level. Typical furnace production is now in excess of 10,000 THM/day compared with about 8500 THM/day in late 1993.

Schuett, K.J.; White, D.G. [US Steel Group, Gary, IN (United States). Gary Works

1996-12-31T23:59:59.000Z

387

Next Generation Metallic Iron Nodule Technology in Electric Furnace Steelmaking  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose objective is to investigate reducing processing temperature, controlling the gas temperature and gas atmosphere over metalized iron nodules, and effectively using sub-bituminous coal as a reductant for producing high quality metalized iron nodules at low cost.

388

Photochemical Escape of Oxygen from Early Mars  

E-Print Network [OSTI]

Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

Zhao, Jinjin

2015-01-01T23:59:59.000Z

389

The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries  

SciTech Connect (OSTI)

The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

2014-09-30T23:59:59.000Z

390

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-02-01T23:59:59.000Z

391

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

392

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

393

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

394

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

395

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

396

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

397

Waste form development for a DC arc furnace  

SciTech Connect (OSTI)

A laboratory crucible study was conducted to develop waste forms to treat nonradioactive simulated {sup 238}Pu heterogeneous debris waste from Savannah River, metal waste from the Idaho National Engineering Laboratory (INEL), and nominal waste also from INEL using DC arc melting. The preliminary results showed that the different waste form compositions had vastly different responses for each processing effect. The reducing condition of DC arc melting had no significant effects on the durability of some waste forms while it decreased the waste form durability from 300 to 700% for other waste forms, which resulted in the failure of some TCLP tests. The right formulations of waste can benefit from devitrification and showed an increase in durability by 40%. Some formulations showed no devitrification effects while others decreased durability by 200%. Increased waste loading also affected waste form behavior, decreasing durability for one waste, increasing durability by 240% for another, and showing no effect for the third waste. All of these responses to the processing and composition variations were dictated by the fundamental glass chemistry and can be adjusted to achieve maximal waste loading, acceptable durability, and desired processing characteristics if each waste formulation is designed for the result according to the glass chemistry.

Feng, X.; Bloomer, P.E.; Chantaraprachoom, N.; Gong, M.; Lamar, D.A.

1996-09-01T23:59:59.000Z

398

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

Tsuo, Y. Simon (Lakewood, CO)

1991-01-01T23:59:59.000Z

399

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

400

Gary No. 13 blast furnace achieves 400 lbs/THM coal injection in 9 months  

SciTech Connect (OSTI)

Number 13 Blast Furnace at Gary began injecting Pulverized Coal in March 1993. The injection level was increased over the next nine months until a level off 409 lbs/THM was achieved for the month of December 1993. Several major areas were critical in achieving this high level of Pulverized coal injection (PCI) including furnace conditions, lance position, tuyere blockage, operating philosophy, and outages. The paper discusses the modifications made to achieve this level of injection. This injection level decreased charged dry coke rate from 750 lbs/THM to about 625 lbs/THM, while eliminating 150 lbs/THM of oil and 20 lbs/THM of natural gas. Assuming a 1.3 replacement ratio for an oil/natural gas mixture, overall coke replacement for the coal is about 0.87 lbs coke/lbs coal. Gary Works anticipates levels of 500 lbs/THM are conceivable.

Sherman, G.J.; Schuett, K.J.; White, D.G.; O`Donnell, E.M. [U.S. Steel Group, Gary, IN (United States)

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Determination of the fundamental softening and melting characteristics of blast furnace burden materials  

SciTech Connect (OSTI)

An experimental technique to investigate the fundamental mechanisms taking place on a microscale in the softening and melting zone in the blast furnace, is presented. In the present paper, attention is focused on determination of the softening viscosity of porous wustite. The technique may be potentially useful to investigate more complex samples of ironbearing material, as occurring in the blast furnace. In comparison with the results obtained by other researchers the viscosity of porous wustite found in the present work is substantially higher than reported elsewhere for sinter and pellets. This may be an indication that softening is not merely a reflection of the solid state deformation under load of wustite. An important factor may be local melting of some of the phases present within the sinter and pellet structures.

Bakker, T.; Heerema, R.H. [Delft Univ. of Technology (Netherlands). Faculty of Mining and Petroleum Engineering

1996-12-31T23:59:59.000Z

402

Modulating furnace and zoned-heating system development. Final report, July 1987-December 1989  

SciTech Connect (OSTI)

The report describes an experimental modulating furnace and a zoned warm air heating system for use in residences. The system was installed and tested at the National Association of Home Builders' (NAHB) SMART HOUSE in Bowie, Maryland. The key features of this system include: (1) continuous modulation of firing rate and supply air over a wide range, (2) closed-loop control to maintain a desired supply air flow under varying system resistances, (3) continuous modulation of combustion air to maintain efficiency, (4) a proportional-integral control algorithm operating on measured temperatures and set points in each zone to set the furnace firing rate, (5) low-cost on/off dampers to direct air flow to those zones calling for heat, and (6) a single microprocessor-based controller that integrates all aspects of the system.

Feldman, S.J.

1991-01-01T23:59:59.000Z

403

The operation results with the modified charging equipment and ignition furnace at Kwangyang No. 2 sinter plant  

SciTech Connect (OSTI)

There will be another blast furnace, the production capacity of which is 3.0 million tonnes per year in 1999 and mini mill plant, the production capacity of which is 1.8 million tonnes per year in 1996 at Kwangyang Works. Therefore, the coke oven gas and burnt lime will be deficient and more sinter will be needed. To meet with these situations, the authors modified the charging equipment and ignition furnace at Kwangyang No. 2 sinter plant in April 1995. After the modification of the charging equipment and ignition furnace, the consumption of burnt lime and coke oven gas could be decreased and the sinter productivity increased in spite of the reduction of burnt lime consumption. This report describes the operation results with the modification of the charging equipment and ignition furnace in No. 2 sinter plant Kwangyang works.

Lee, K.J.; Pi, Y.J.; Kim, J.R.; Lee, J.N. [POSCO, Kwangyang, Cheonnam (Korea, Republic of)

1996-12-31T23:59:59.000Z

404

Experimental and numerical analysis of isothermal turbulent flows in interacting low NOx burners in coal-fired furnaces   

E-Print Network [OSTI]

Coal firing power stations represent the second largest source of global NOx emissions. The current practice of predicting likely exit NOx levels from multi-burner furnaces on the basis of single burner test rig data has been proven inadequate...

Cvoro, Valentina

405

New Energy Efficiency Standards for Furnace Fans to Reduce Carbon  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy HealthCommentsAugustNationalMarkets with Wind PowerProcesses |FY

406

Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms  

DOE Patents [OSTI]

A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

2006-01-24T23:59:59.000Z

407

The determination of some anions using ion chromatography and ion chromatography-graphite furnace atomic absorption spectrometry  

E-Print Network [OSTI]

THE DETERMINATION OF SOME ANIONS USING ION CHROMATOGRAPHY AND ION CHROMATOGRAPHY-GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY A Thesis by DANIEL C. J. HILLMAN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1981 Major Subject: Chemistry THE DETERMINATION OF SOME ANIONS USING ION CHROMATOGRAPHY AND ION CHROMATOGRAPHY-GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY A Thesis by DANIEL C. J. HILLMAN...

Hillman, Daniel C

1981-01-01T23:59:59.000Z

408

Gary Works No. 13 blast furnace: A new removable trough design  

SciTech Connect (OSTI)

No. 13 Blast Furnace at US Steel`s Gary Works is a 35 tuyere furnace with a 36.5 ft. hearth capable of producing over 9,000 tons of hot metal per day. The current casthouse design was placed in service following the second reline in the fall of 1979. This design anticipated daily production rates averaging 7,500 tons of hot metal per day and provided for removable troughs at two of the three tapholes. At the time, the troughs were rammed with a high alumina/silicon carbide granular ramming material that provided the operators with trough campaign lives between 60,000--70,000 tons of hot metal produced. As refractory technology progressed, low cement/low moisture castables were introduced to the trough systems on No. 13 Blast Furnace. The immediate success of the castables was tempered by emergence of a new unexpected problem. That problem was the thermal expansion of the castable. The paper describes the problems that resulted in the need to modify the trough design, the new design of the trough, and its improvement in iron trough campaign life and reliability.

Schuett, K.J.; Pawlak, J.P. [U.S. Steel Group, Gary, IN (United States). Gary Works; Traina, L.; Brenneman, R.G.

1995-12-01T23:59:59.000Z

409

Production and blast-furnace smelting of boron-alloyed iron-ore pellets  

SciTech Connect (OSTI)

Industrial test data are presented regarding the production (at Sokolovsk-Sarbaisk mining and enrichment enterprise) and blast-furnace smelting (at Magnitogorsk metallurgical works) of boron-alloyed iron-ore pellets (500000 t). It is shown that, thanks to the presence of boron, the compressive strength of the roasted pellets is increased by 18.5%, while the strength in reduction is doubled; the limestone consumption is reduced by 11%, the bentonite consumption is halved, and the dust content of the gases in the last section of the roasting machines is reduced by 20%. In blast-furnace smelting, the yield of low-sulfur (<0.02%) hot metal is increased from 65-70 to 85.1% and the furnace productivity from 2.17-2.20 to 2.27 t/(m{sup 3} day); coke consumption is reduced by 3-8 kg/t of hot metal. The plasticity and stamping properties of 08IO auto-industry steel are improved by microadditions of boron.

A.A. Akberdin; A.S. Kim [Abishev Chemicometallurgical Institute, Abishev (Kazakhstan)

2008-08-15T23:59:59.000Z

410

RADIATION HEAT TRANSFER ENVIRONMENT IN FIRE AND FURNACE TESTS OF RADIOACTIVE MATERIALS PAKCAGES  

SciTech Connect (OSTI)

The Hypothetical Accident Conditions (HAC) sequential test of radioactive materials packages includes a thermal test to confirm the ability of the package to withstand a transportation fire event. The test specified by the regulations (10 CFR 71) consists of a 30 minute, all engulfing, hydrocarbon fuel fire, with an average flame temperature of at least 800 C. The requirements specify an average emissivity for the fire of at least 0.9, which implies an essentially black radiation environment. Alternate test which provide equivalent total heat input at the 800 C time averaged environmental temperature may also be employed. When alternate tests methods are employed, such as furnace or gaseous fuel fires, the equivalence of the radiation environment may require justification. The effects of furnace and open confinement fire environments are compared with the regulatory fire environment, including the effects of gases resulting from decomposition of package overpack materials. The results indicate that furnace tests can produce the required radiation heat transfer environment, i.e., equivalent to the postulated pool fire. An open enclosure, with transparent (low emissivity) fire does not produce an equivalent radiation environment.

Smith, A

2008-12-31T23:59:59.000Z

411

Investigation of lignite and firewood co-combustion in a furnace for tobacco curing application  

SciTech Connect (OSTI)

Co-combustion of lignite and firewood was investigated for an application in tobacco curing industry in Northern Thailand. Extensive experiments have been carried out in a newly developed furnace suitable for small curing unit, in place of locally made furnace. The aim of this investigation is to evaluate the performance of the combustion chamber in the required thermal output range for tobacco curing and to examine the influence of fuel feed rate, fuel mixture ratio and air staging on the combustion and emission characteristics of the furnace during steady state operation. Their effects are characterized in terms of the observed variations of temperature distributions, emissions of CO, SO{sub 2}, CO{sub 2}, O{sub 2} and combustion efficiency. Co-firing of firewood and lignite has been found to exhibit acceptable temperature distribution, high combustion efficiency and low emissions over a wide thermal output span. Stable operation at low (50 kW) and high (150 kW) thermal output was achieved with average CO and SO{sub 2} content in flue gas typically below 1400 and 100 ppm, respectively. Under the conditions considered, it was showed that the fuel feed rate had greater influence on combustion and emissions than firewood and lignite mixture ratio and air staging.

Nakorn Tippayawong; Chutchawan Tantakitti; Satis Thavornun

2006-07-01T23:59:59.000Z

412

Economics of Condensing Gas Furnaces and Water Heaters Potential in Residential Single Family Homes  

SciTech Connect (OSTI)

Residential space and water heating accounts for over 90percent of total residential primary gas consumption in the United States. Condensing space and water heating equipment are 10-30percent more energy-efficient than conventional space and water heating. Currently, condensing gas furnaces represent 40 percent of shipments and are common in the Northern U.S. market. Meanwhile, manufacturers are planning to develop condensing gas storage water heaters to qualify for Energy Star? certification. Consumers, installers, and builders who make decisions about installing space and water heating equipment generally do not perform an analysis to assess the economic impacts of different combinations and efficiencies of space and water heating equipment. Thus, equipment is often installed without taking into consideration the potential life-cycle economic and energy savings of installing space and water heating equipment combinations. Drawing on previous and current analysis conducted for the United States Department of Energy rulemaking on amended standards for furnaces and water heaters, this paper evaluates the extent to which condensing equipment can provide life-cycle cost-effectiveness in a representative sample of single family American homes. The economic analyses indicate that significant energy savings and consumer benefits may result from large-scale introduction of condensing water heaters combined with condensing furnaces in U.S. residential single-family housing, particularly in the Northern region. The analyses also shows that important benefits may be overlooked when policy analysts evaluate the impact of space and water heating equipment separately.

Lekov, Alex; Franco, Victor; Meyers, Steve

2010-05-14T23:59:59.000Z

413

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

414

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

415

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

416

HIGH-TEMPERATURE HEAT EXCHANGER TESTING IN A PILOT-SCALE SLAGGING FURNACE SYSTEM  

SciTech Connect (OSTI)

The University of North Dakota Energy & Environmental Research Center (EERC), in partnership with United Technologies Research Center (UTRC) under a U.S. Department of Energy (DOE) contract, has designed, constructed, and operated a 3.0-million Btu/hr (3.2 x 10{sup 6} kJ/hr) slagging furnace system (SFS). Successful operation has demonstrated that the SFS meets design objectives and is well suited for testing very high-temperature heat exchanger concepts. Test results have shown that a high-temperature radiant air heater (RAH) panel designed and constructed by UTRC and used in the SFS can produce a 2000 F (1094 C) process air stream. To support the pilot-scale work, the EERC has also constructed laboratory- and bench-scale equipment which was used to determine the corrosion resistance of refractory and structural materials and develop methods to improve corrosion resistance. DOE projects that from 1995 to 2015, worldwide use of electricity will double to approach 20 trillion kilowatt hours. This growth comes during a time of concern over global warming, thought by many policy makers to be caused primarily by increases from coal-fired boilers in carbon dioxide (CO{sub 2}) emissions through the use of fossil fuels. Assuming limits on CO{sub 2} emissions from coal-fired boilers are imposed in the future, the most economical CO{sub 2} mitigation option may be efficiency improvements. Unless efficiency improvements are made in coal-fired power plants, utilities may be forced to turn to more expensive fuels or buy CO{sub 2} credits. One way to improve the efficiency of a coal-fired power plant is to use a combined cycle involving a typical steam cycle along with an indirectly fired turbine cycle using very high-temperature but low-pressure air as the working fluid. At the heart of an indirectly fired turbine combined-cycle power system are very high-temperature heat exchangers that can produce clean air at up to 2600 F (1427 C) and 250 psi (17 bar) to turn an aeroderivative turbine. The overall system design can be very similar to that of a typical pulverized coal-fired boiler system, except that ceramics and alloys are used to carry the very high-temperature air rather than steam. This design makes the combined-cycle system especially suitable as a boiler-repowering technology. With the use of a gas-fired duct heater, efficiencies of 55% can be achieved, leading to reductions in CO{sub 2} emissions of 40% as compared to today's coal-fired systems. On the basis of work completed to date, the high-temperature advanced furnace (HITAF) concept appears to offer a higher-efficiency technology option for coal-fired power generation systems than conventional pulverized coal firing. Concept analyses have demonstrated the ability to achieve program objectives for emissions (10% of New Source Performance Standards, i.e., 0.003 lb/MMBtu of particulate), efficiency (47%-55%), and cost of electricity (10%-25% below today's cost). Higher-efficiency technology options for new plants as well as repowering are important to the power generation industry in order to conserve valuable fossil fuel resources, reduce the quantity of pollutants (air and water) and solid wastes generated per MW, and reduce the cost of power production in a deregulated industry. Possibly more important than their potential application in a new high-temperature power system, the RAH panel and convective air heater tube bank are potential retrofit technology options for existing coal-fired boilers to improve plant efficiencies. Therefore, further development of these process air-based high-temperature heat exchangers and their potential for commercial application is directly applicable to the development of enabling technologies in support of the Vision 21 program objectives. The objective of the work documented in this report was to improve the performance of the UTRC high-temperature heat exchanger, demonstrate the fuel flexibility of the slagging combustor, and test methods for reducing corrosion of brick and castable refractory in such combustion environments. Specif

Michael E. Collings; Bruce A. Dockter; Douglas R. Hajicek; Ann K. Henderson; John P. Hurley; Patty L. Kleven; Greg F. Weber

1999-12-01T23:59:59.000Z

417

Ironmaking Process Alternative Screening Study, Volume 1  

SciTech Connect (OSTI)

Iron in the United States is largely produced from iron ore mined in the United States or imported from Canada or South America. The iron ore is typically smelted in Blast Furnaces that use primarily iron ore, iron concentrate pellets metallurgical coke, limestone and lime as the raw materials. Under current operating scenarios, the iron produced from these Blast Furnaces is relatively inexpensive as compared to current alternative iron sources, e.g. direct iron reduction, imported pig iron, etc. The primary problem the Blast Furnace Ironmaking approach is that many of these Blast furnaces are relatively small, as compared to the newer, larger Blast Furnaces; thus are relatively costly and inefficient to operate. An additional problem is also that supplies of high-grade metallurgical grade coke are becoming increasingly in short supply and costs are also increasing. In part this is due to the short supply and costs of high-grade metallurgical coals, but also this is due to the increasing necessity for environmental controls for coke production. After year 2003 new regulations for coke product environmental requirement will likely be promulgated. It is likely that this also will either increase the cost of high-quality coke production or will reduce the available domestic U.S. supply. Therefore, iron production in the United States utilizing the current, predominant Blast Furnace process will be more costly and would likely be curtailed due to a coke shortage. Therefore, there is a significant need to develop or extend the economic viability of Alternate Ironmaking Processes to at least partially replace current and declining blast furnace iron sources and to provide incentives for new capacity expansion. The primary conclusions of this comparative Study of Alternative Ironmaking Process scenarios are: (1) The processes with the best combined economics (CAPEX and OPEX impacts in the I.R.R. calculation) can be grouped into those Fine Ore based processes with no scrap charge and those producing Hot Metal for charge to the EAF. (2) A pronounced sensitivity to Steel Scrap Cost was felt less by the Hot Metal Processes and the Fine Ore Processes that typically do not utilize much purchased scrap. (3) In terms of evolving processes, the Tecnored Process (and in particular, the lower-operating cost process with integral co-generation of electrical power) was in the most favorable groupings at all scrap cost sensitivities. (4) It should be noted also that the Conventional Blast Furnace process utilizing Non-Recovery coke (from a continuous coking process with integral co-generation of electrical power) and the lower-capital cost Mini Blast Furnace also showed favorable Relative Economics for the low and median Scrap Cost sensitivities. (5) The lower-cost, more efficient MauMee Rotary Hearth Process that uses a Briquetted Iron Unit Feed (instead of a dried or indurated iron ore pellet) also was in the most favorable process groupings. Those processes with lower-cost raw materials (i.e. fine ore and/or nonmetallurgical coal as the reductant) had favorable combined economics. In addition, the hot metal processes (in part due to the sensible heat impacts in the EAF and due to their inherently lower costs) also had favorable combined economics.

Lockwood Greene, . .

2005-01-06T23:59:59.000Z

418

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

419

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

420

JOINING ADVANCED MATERIALS BY PLASTIC FLOW PROVIDES SOLUTION FOR OXYGEN SENSOR APPLICATIONS  

E-Print Network [OSTI]

JOINING ADVANCED MATERIALS BY PLASTIC FLOW PROVIDES SOLUTION FOR OXYGEN SENSOR APPLICATIONS's unique plastic deformation process. · Abilitytodeploymultipleoxygen sensors (due to their lower cost

Kemner, Ken

Note: This page contains sample records for the topic "oxygen process furnaces" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

422

Electrochemical studies of quinone oxygen  

SciTech Connect (OSTI)

Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

1990-02-01T23:59:59.000Z

423

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

424

DENSE PHASE REBURN COMBUSTION SYSTEM (DPRCS) DEMONSTRATION ON A 154 MWE TANGENTIAL FURNACE: ADDITIONAL AREA OF INTEREST-TO DEVELOP AND DEMONSTRATE AN IN-FURNACE MULTI-POLLUTANT REDUCTION TECHNOLOGY TO REDUCE NOx, SO2 & Hg  

SciTech Connect (OSTI)

Semi-dense phase pneumatic delivery and injection of calcium and sodium sorbents, and microfine powdered coal, at various sidewall elevations of an online operating coal-fired power plant, was investigated for the express purpose of developing an in-furnace, economic multi-pollutant reduction methodology for NO{sub x}, SO{sub 2} & Hg. The 154 MWe tangentially-fired furnace that was selected for a full-scale demonstration, was recently retrofitted for NO{sub x} reduction with a high velocity rotating-opposed over-fire air system. The ROFA system, a Mobotec USA technology, has a proven track record of breaking up laminar flow along furnace walls, thereby enhancing the mix of all constituents of combustion. The knowledge gained from injecting sorbents and micronized coal into well mixed combustion gases with significant improvement in particulate retention time, should serve well the goals of an in-furnace multi-pollutant reduction technology; that of reducing back-end cleanup costs on a wide variety of pollutants, on a cost per ton basis, by first accomplishing significant in-furnace reductions of all pollutants.

Allen C. Wiley; Steven Castagnero; Geoff Green; Kevin Davis; David White

2004-03-01T23:59:59.000Z

425

Electrolytic Processes | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Energy Research Center in Arcata, California. Electrolysis is the process of using electricity to split water into hydrogen and oxygen. This reaction takes place in a unit called...

426

Measuring oxygen reduction/evolution reactions on the nanoscale  

SciTech Connect (OSTI)

The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

2011-01-01T23:59:59.000Z

427

Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks  

SciTech Connect (OSTI)

Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

428

Process for production of a borohydride compound  

DOE Patents [OSTI]

A process for production of a borohydride compound. The process comprises combining a compound comprising boron and oxygen with an adduct of alane.

Chin, Arthur Achhing; Jain, Puja; Linehan, Suzanne; Lipiecki, Francis Joseph; Maroldo, Stephen Gerard; November, Samuel J; Yamamoto, John Hiroshi

2013-02-19T23:59:59.000Z

429

How Plants Do It: Light, Oxygen, Action!  

SciTech Connect (OSTI)

Plants have been doing it with ease for millions of years, and yet science has yet to fully comprehend how: Photosynthesis. It's a fundamental process of all plant life on Earth, using the simple and abundant ingredients of water and light to create food and enrich the planet's atmosphere with life-giving oxygen. In this talk, Professor Yachandra discusses how understanding the process of photosynthesis holds the key to a whole new level of mastery of how energy is produced, with enormous implications for the economy and the environment.

Yachandra, Vittal (University of California, Berkeley) [University of California, Berkeley

2008-08-26T23:59:59.000Z

430

Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace  

SciTech Connect (OSTI)

This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

2014-01-01T23:59:59.000Z

431

THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS  

SciTech Connect (OSTI)

At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

Ramasamy, Karthikeyan K.; Wang, Yong

2013-06-01T23:59:59.000Z

432

A method for burden distribution estimation from probe data in the blast furnace  

SciTech Connect (OSTI)

A novel approach for estimation of burden distribution in the blast furnace is presented. The proposed model makes use of only temperature measurements from an above-burden probe, and interprets the changes in temperature at charging in terms of burden distribution. In this study it is demonstrated that the temperature changes can be predicted quite accurately for all dumps in a charging sequence using neural networks., The basic structures of both an on-line and an off-line model are presented.

Nikus, M.; Saxen, H.; Bulsari, A. [Aabo Akademi Univ. (Finland). Dept. of Chemical Engineering

1996-12-31T23:59:59.000Z

433

The rule of the stock distribution with large bell in blast furnace  

SciTech Connect (OSTI)

This paper describes in detail, starting from the basic equation of materials falling from a two bell furnace top system, how a number of mathematical expressions which govern the stock distribution of the throat were derived. An analysis was then made by applying these equations on topics, such as stockline levels, charging sequences, stock grain size, large bell angle and batch weight. This demonstrates that a reasonable two bells top charging system and practice could be established theoretically. Furthermore, character numbers for stock distribution, such as E{sub B} and D{sub K}, were developed for a possible computer application.

Liu Yuncai [Shoudu Iron and Steel Co., Beijing (China)

1996-12-31T23:59:59.000Z

434

AGA/APGA Questions re Furnace NOPR, EERE-2014-BT-STD-0031 | Department of  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energyon ArmedWaste and Materials2014 ChiefEnergy Furnace NOPR, EERE-2014-BT-STD-0031

435

Method for making oxygen-reducing catalyst layers  

DOE Patents [OSTI]

Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

2010-06-22T23:59:59.000Z

436

Process to eliminate production of fly ash by wet bottom boilers  

SciTech Connect (OSTI)

This patent describes a process for the reduction of fly ash in a wet bottom boiler of the type having a primary and secondary furnace. It comprises collecting the fly ash from one of an electrostatic precipitator, a bag house, a cyclone collector, a multi- cyclone collector, a gravity separator and a sharply curved duct; removing the fly ash in a stream of carrier gas into the furnace; adding a fuel to the stream of carrier gas and fly ash; introducing the carrier gas and fly ash and fuel into one of the primary and secondary furnaces, wherein the fuel and the heat from at least one of the surrounding gas and molten slag provide energy to melt the fly ash; and discharging the melted fly ash with slag from the furnace bottom.

Breen, B.P.; Schrecengost, R.A.; Gabrielson, J.E.

1991-09-03T23:59:59.000Z

437

Development of combustion data to utilize low-Btu gases as industrial process fuels: modification of flame characteristics. Project 61041 quarterly report, 1 January-31 March 1980  

SciTech Connect (OSTI)

This program consists of an experimental program to determine the burner modifications that will yield suitable flame characteristics and shapes with oxygen-blown gases manufactured from coal. Experiments will also be conducted to evaluate methods of enchancing the flame characteristics of manufactured gases from air-blown gasifiers. Progress to date includes a partial completion of the oxygen-enrichment system, preparation of the furnace for the trials, and discussions of the burner modifications needed for combustion trials with the burner manufacturer.

Waibel, R.T.

1980-04-01T23:59:59.000Z

438

Mixed oxygen ion/electron-conducting ceramics for oxygen separation  

SciTech Connect (OSTI)

Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

1995-05-01T23:59:59.000Z

439

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

440

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

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