National Library of Energy BETA

Sample records for oxygen occurs naturally

  1. Naturally occurring radionuclides in agricultural products: An overview

    SciTech Connect (OSTI)

    Hanlon, E.A.

    1994-07-01

    Low levels of naturally occurring radionuclides exist in phosphatic clays, a by-product of phosphatic mining and beneficiation processes. Concerns about these radionuclides entering the human food chain were an immediate research priority before the phosphate clays could be reclaimed for intensive agricultural purposes. Efforts included the assembly of a large body of data from both sons and plants, part of which were produced by the Polk County (Florida) Mined Lands Agricultural Research/Demonstration Project MLAR/DP. Additional detailed studies involving dairy and beef cattle (Bos taurus) were conducted by researchers working with the MLAR/DP. A national symposium was conducted in which data concerning the MLAR/DP work and other research projects also dealing with naturally occurring radionuclides in agriculture could be discussed. The symposium included invited review papers dealing with the identification of radionuclide geological origins, the geochemistry and movement of radionuclides within the environment, mechanisms of plant uptake, entry points into the food chain, and evaluation of dose and risk assessment to the consumer of low levels of radionuclides. The risk to human health of an individual obtaining 0.1 of his or her dietary intake from crops produced on phosphatic clays increased by 1 in 5 x 10{sup 6}/yr above a control individual consuming no food grown on phosphatic clays. Leaf tissues were found to be generally higher than fruit, grain, or root tissues. The natural range in radionuclide content among various food types was greater than the difference in radionuclides content between the same food produced on phosphatic clays vs. natural soils. 19 refs.

  2. Is anyone regulating naturally occurring radioactive material? A state survey

    SciTech Connect (OSTI)

    Gross, E.M.; Barisas, S.G.

    1993-08-01

    As far as we know, naturally occurring radioactive material (NORM) has surrounded humankind since the beginning of time. However, recent data demonstrating that certain activities concentrate NORM have increased concern regarding its proper handling and disposal and precipitated the development of new NORM-related regulations. The regulation of NORM affects the management of government facilities as well as a broad range of industrial processes. Recognizing that NORM regulation at the federal level is extremely limited, Argonne National Laboratory (ANL) conducted a 50-state survey to determine the extent to which states have assumed the responsibility for regulating NORM as well as the NORM standards that are currently being applied at the state level. Though the survey indicates that NORM regulation comprises a broad spectrum of controls from full licensing requirements to virtually no regulation at afl, a trend is emerging toward recognition of the need for increased regulation of potential NORM hazards, particularly in the absence of federal standards.

  3. Manufactured Home Testing in Simulated and Naturally Occurring High Winds

    SciTech Connect (OSTI)

    W. D. Richins; T. K. Larson

    2006-08-01

    A typical double-wide manufactured home was tested in simulated and naturally occurring high winds to understand structural behavior and improve performance during severe windstorms. Seven (7) lateral load tests were conducted on a double-wide manufactured home at a remote field test site in Wyoming. An extensive instrumentation package monitored the overall behavior of the home and collected data vital to validating computational software for the manufactured housing industry. The tests were designed to approach the design load of the home without causing structural damage, thus allowing the behavior of the home to be accessed when the home was later exposed to high winds (to 80-mph). The data generally show near-linear initial system response with significant non-linear behavior as the applied loads increase. Load transfer across the marriage line is primarily compression. Racking, while present, is very small. Interface slip and shear displacement along the marriage line are nearly insignificant. Horizontal global displacements reached 0.6 inch. These tests were designed primarily to collect data necessary to calibrate a desktop analysis and design software tool, MHTool, under development at the Idaho National Laboratory specifically for manufactured housing. Currently available analysis tools are, for the most part, based on methods developed for “stick built” structures and are inappropriate for manufactured homes. The special materials utilized in manufactured homes, such as rigid adhesives used in the connection of the sheathing materials to the studs, significantly alter the behavior of manufactured homes under lateral loads. Previous full scale tests of laterally loaded manufactured homes confirm the contention that conventional analysis methods are not applicable. System behavior dominates the structural action of manufactured homes and its prediction requires a three dimensional analysis of the complete unit, including tiedowns. This project was sponsored by the US Department of Energy, US Department of Housing and Urban Development, and the Manufactured Housing Institute. The results of this research can lead to savings in annual losses of life and property by providing validated information to enable the advancement of code requirements and by developing engineering software that can predict and optimize wind resistance.

  4. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    SciTech Connect (OSTI)

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  5. Naturally occurring arsenic in the groundwater at the Kansas City Plant

    SciTech Connect (OSTI)

    Korte, N.E.

    1990-12-01

    This report describes an investigation concerning the presence of arsenic in concentrations exceeding 0.4 mg/L in the groundwater under the Department of Energy's Kansas City Plant (KCP). The study consisted of four distinct phases: a thorough review of the technical literature, a historical survey of arsenic use at the facility, a laboratory study of existing techniques for determining arsenic speciation, and a field program including water, soil, and sediment sampling. The historical survey and literature review demonstrated that plant activities had not released significant quantities of arsenic to the environment but that similar occurrences of arsenic in alluvial groundwater are widespread in the midwestern United States. Laboratory studies showed that a chromatographic separation technique was necessary to accurately determine arsenic speciation for the KCP groundwater samples. Field studies revealed that naturally occurring reducing conditions prevalent in the subsurface are responsible for dissolving arsenic previously sorbed by iron oxides. Indeed, the data demonstrated that the bulk arsenic concentration of site subsoils and sediments is {approximately}7 mg/kg, whereas the arsenic content of iron oxide subsamples is as high as 84 mg/kg. Literature showed that similar concentrations of arsenic in sediments occur naturally and are capable of producing the levels of arsenic found in groundwater monitoring wells at the KCP. The study concludes, therefore, that the arsenic present in the KCP groundwater is the result of natural phenomena. 44 refs., 8 figs., 14 tabs.

  6. Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies

    DOE Patents [OSTI]

    Fliermans; , Carl B.

    2012-08-07

    Some or all of the needs above can be addressed by embodiments of the invention. According to embodiments of the invention, systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies can be implemented. In one embodiment, a method for storing hydrogen can be provided. The method can include providing diatoms comprising diatomaceous earth or diatoms from a predefined culture. In addition, the method can include heating the diatoms in a sealed environment in the presence of at least one of titanium, a transition metal, or a noble metal to provide a porous hydrogen storage medium. Furthermore, the method can include exposing the porous hydrogen storage medium to hydrogen. In addition, the method can include storing at least a portion of the hydrogen in the porous hydrogen storage medium.

  7. An overview of naturally occurring radioactive materials (NORM) in the petroleum industry

    SciTech Connect (OSTI)

    Smith, K.P.

    1992-12-01

    Oil and gas extraction and processing operations sometimes accumulate naturally occurring radioactive materials (NORM) at concentrations above normal in by-product waste streams. Results from NORM surveys indicate that radionuclide concentrations can be quite variable, ranging from undetectable to extremely high levels. To date, efforts to characterize the geographic distribution of NORM have been limited by poor statistical representation. In addition, the fate of NORM in the environment has not been fully defined, and few human health risk assessment have been conducted. Both the petroleum industry and regulators are becoming increasingly concerned about the presence of NORM. At present, most existing federal environmental regulations do not address oil and gas NORM, and only a few states have developed regulatory programs. Available data suggest that the occurrence of NORM (and associated health risks) is significant enough to warrant increased regulatory control. However, before these regulations can be developed, additional research is needed to (1) better characterize the occurrence and distribution of NORM throughout the industry, (2) quantify hazards posed by NORM to industry workers and the general public, and (3) develop effective waste treatment and minimization technologies that will lower the risk associated with NORM and reduce disposal costs.

  8. Manufactured Home Testing in Simulated and Naturally Occurring High Winds for WCTE Conference

    SciTech Connect (OSTI)

    William D. Richins; Thomas K. Larson; Jeffrey M. Lacy; Ryan G. Kobbe

    2006-08-01

    A typical double-wide manufactured home was tested in simulated and naturally occurring high winds to understand structural behavior and improve performance during severe windstorms. Seven (7) lateral load tests were conducted on a double-wide manufactured home at a remote field test site in Wyoming. An extensive instrumentation package monitored the overall behavior of the home and collected data vital to validating computational software for the manufactured housing industry. The tests were designed to approach the design load of the home without causing structural damage, thus allowing the behavior of the home to be accessed when the home was later exposed to high winds (to 80-mph). The data generally show near-linear initial system response with significant non-linear behavior as the applied loads increase. Load transfer across the marriage line is primarily compression. Racking, while present, is very small. Interface slip and shear displacement along the marriage line are nearly insignificant. Horizontal global displacements reached 0.6 inch. These tests were designed primarily to collect data necessary to calibrate a desktop analysis and design software tool, MHTool, under development at the Idaho National Laboratory specifically for manufactured housing. Currently available analysis tools are, for the most part, based on methods developed for "stick built" structures and are inappropriate for manufactured homes. The special materials utilized in manufactured homes, such as rigid adhesives used in the connection of the sheathing materials to the studs, significantly alter the behavior of manufactured homes under lateral loads. Previous full scale tests of laterally loaded manufactured homes confirm the contention that conventional analysis methods are not applicable. System behavior dominates the structural action of manufactured homes and its prediction requires a three dimensional analysis of the complete unit, including tie-downs. This project was sponsored by the US Department of Energy, US Department of Housing and Urban Development, and the Manufactured Housing Institute. The results of this research can lead to savings in annual losses of life and property by providing validated information to enable the advancement of code requirements and by developing engineering software that can predict and optimize wind resistance.

  9. Investigation of Naturally Occurring Radio Nuclides in Shir-kuh Granites

    SciTech Connect (OSTI)

    Mazarei, Mohammad Mehdi; Zarei, Mojtaba

    2011-12-26

    One of the principle natural radiation resources is Granite which can be dangerous for human because of its radiations. Based on this fact, in this research we attempt to specify the activity amount of these natural radio nuclides, existing in Shir-kuh Granite of Yazd state. To specify the activity amount of this natural radio nuclides, it has been applied the measurement method of Gamma spectroscopy using high purity Germanium (HPGe) detector.

  10. Evaluation of alkali concentration in conditions relevant to oxygen/natural

    Office of Scientific and Technical Information (OSTI)

    gas glass furnaces by laser-induced breakdown spectroscopy. (Conference) | SciTech Connect Conference: Evaluation of alkali concentration in conditions relevant to oxygen/natural gas glass furnaces by laser-induced breakdown spectroscopy. Citation Details In-Document Search Title: Evaluation of alkali concentration in conditions relevant to oxygen/natural gas glass furnaces by laser-induced breakdown spectroscopy. A number of industrial combustion systems are adopting oxygen-enhanced firing

  11. Sulphoraphane, a naturally occurring isothiocyanate induces apoptosis in breast cancer cells by targeting heat shock proteins

    SciTech Connect (OSTI)

    Sarkar, Ruma; Mukherjee, Sutapa [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)] [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India); Biswas, Jaydip [Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)] [Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India); Roy, Madhumita, E-mail: mitacnci@yahoo.co.in [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)] [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)

    2012-10-12

    Highlights: Black-Right-Pointing-Pointer HSPs (27, 70 and 90) and HSF1 are overexpressed in MCF-7 and MDA-MB-231 cells. Black-Right-Pointing-Pointer Sulphoraphane, a natural isothiocyanate inhibited HSPs and HSF1 expressions. Black-Right-Pointing-Pointer Inhibition of HSPs and HSF1 lead to regulation of apoptotic proteins. Black-Right-Pointing-Pointer Alteration of apoptotic proteins activate of caspases particularly caspase 3 and 9 leading to induction of apoptosis. Black-Right-Pointing-Pointer Alteration of apoptotic proteins induce caspases leading to induction of apoptosis. -- Abstract: Heat shock proteins (HSPs) are involved in protein folding, aggregation, transport and/or stabilization by acting as a molecular chaperone, leading to inhibition of apoptosis by both caspase dependent and/or independent pathways. HSPs are overexpressed in a wide range of human cancers and are implicated in tumor cell proliferation, differentiation, invasion and metastasis. HSPs particularly 27, 70, 90 and the transcription factor heat shock factor1 (HSF1) play key roles in the etiology of breast cancer and can be considered as potential therapeutic target. The present study was designed to investigate the role of sulphoraphane, a natural isothiocyanate on HSPs (27, 70, 90) and HSF1 in two different breast cancer cell lines MCF-7 and MDA-MB-231 cells expressing wild type and mutated p53 respectively, vis-a-vis in normal breast epithelial cell line MCF-12F. It was furthermore investigated whether modulation of HSPs and HSF1 could induce apoptosis in these cells by altering the expressions of p53, p21 and some apoptotic proteins like Bcl-2, Bax, Bid, Bad, Apaf-1 and AIF. Sulphoraphane was found to down-regulate the expressions of HSP70, 90 and HSF1, though the effect on HSP27 was not pronounced. Consequences of HSP inhibition was upregulation of p21 irrespective of p53 status. Bax, Bad, Apaf-1, AIF were upregulated followed by down-regulation of Bcl-2 and this effect was prominent in MCF-7 than in MDA-MB-231. However, very little change in the expression of Bid was observed. Alteration in Bcl-2 Bax ratio resulted in the release of cytochrome c from mitochondria and activation of caspases 3 and 9 which are in agreement with apoptotic index values. Sulphoraphane therefore can be regarded as a potent inducer of apoptosis due to HSP modulation in breast cancer cells.

  12. Using naturally occurring radionuclides to determine drinking water age in a community water system

    SciTech Connect (OSTI)

    Waples, James T.; Bordewyk, Jason K.; Knesting, Kristina M.; Orlandini, Kent A.

    2015-07-22

    Drinking water quality in a community water system is closely linked to the age of water from initial treatment to time of delivery. However, water age is difficult to measure with conventional chemical tracers; particularly in stagnant water, where the relationship between disinfectant decay, microbial growth, and water age is poorly understood. Using radionuclides that were naturally present in source water, we found that measured activity ratios of 90Y/90Sr and 234Th/238U in discrete drinking water samples of known age accurately estimated water age up to 9 days old (?est: ± 3.8 h, P < 0.0001, r2 = 0.998, n = 11) and 25 days old (?est: ± 13.3 h, P < 0.0001, r2 = 0.996, n = 12), respectively. Moreover, 90Y-derived water ages in a community water system (6.8 × 104 m3 d–1 capacity) were generally consistent with water ages derived from an extended period simulation model. Radionuclides differ from conventional chemical tracers in that they are ubiquitous in distribution mains and connected premise plumbing. The ability to measure both water age and an analyte (e.g., chemical or microbe) in any water sample at any time allows for new insight into factors that control drinking water quality.

  13. Using naturally occurring radionuclides to determine drinking water age in a community water system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Waples, James T.; Bordewyk, Jason K.; Knesting, Kristina M.; Orlandini, Kent A.

    2015-07-22

    Drinking water quality in a community water system is closely linked to the age of water from initial treatment to time of delivery. However, water age is difficult to measure with conventional chemical tracers; particularly in stagnant water, where the relationship between disinfectant decay, microbial growth, and water age is poorly understood. Using radionuclides that were naturally present in source water, we found that measured activity ratios of 90Y/90Sr and 234Th/238U in discrete drinking water samples of known age accurately estimated water age up to 9 days old (σest: ± 3.8 h, P < 0.0001, r2 = 0.998, n =more » 11) and 25 days old (σest: ± 13.3 h, P < 0.0001, r2 = 0.996, n = 12), respectively. Moreover, 90Y-derived water ages in a community water system (6.8 × 104 m3 d–1 capacity) were generally consistent with water ages derived from an extended period simulation model. Radionuclides differ from conventional chemical tracers in that they are ubiquitous in distribution mains and connected premise plumbing. The ability to measure both water age and an analyte (e.g., chemical or microbe) in any water sample at any time allows for new insight into factors that control drinking water quality.« less

  14. Effectiveness of mineral soil to adsorb the natural occurring radioactive material (norm), uranium and thorium

    SciTech Connect (OSTI)

    Amir, Muhammad Nur Iman; Ismail, Nurul Izzatiafifi; Wood, Ab. Khalik Saat, Ahmad; Hamzah, Zaini

    2015-04-29

    A study has been performed on U-soil and Th-soil adsorption of three types of soil collected from Selangor State of Malaysia which are Saujana Putra, Bukit Changgang and Jenderam Hilir. In this study, natural radionuclide (U and Th) soil adsorption based on batch experiments with various initial concentrations of the radionuclide elements were carried out. Parameters that were set constant include pH at 5;amount of soil used was 5?g each, contact time was 24 hour and different initial concentration for each solution of U and Th which is 5?mg/L, 10?mg/L, 15?mg/L, 20?mg/L, 25?mg/L and 40?mg/L were used. The K{sub d} values for each type of soil were determined in this batch experiments which was based on US-EPA method, in order to estimate adsorption capacity of the soil.The K{sub d} values of Th found higher than Kd values of U for all of the soil samples, and the highest was found on the soil collected from Bukit Changgang. The soil clay content was one of factors to influence the adsorption of both U and Th from dilute initial solution. The U-soil and Th-soil adsorption process for all the soil samples studied are generally obeying unimolecular layer Langmuir isotherm model. From Langmuir isotherm, the maximum adsorption capacity for U was 0.393mg/g and for Th was 1.53?mg/g for the soil that was taken from Bukit Changgang. From the study, it suggested that the soil from Bukit Changgang applicable as potential enhanced barrier for site disposing waste containing U and Th.

  15. Prediction of rodent carcinogenic potential of naturally occurring chemicals in the human diet using high-throughput QSAR predictive modeling

    SciTech Connect (OSTI)

    Valerio, Luis G. . E-mail: luis.valerio@FDA.HHS.gov; Arvidson, Kirk B.; Chanderbhan, Ronald F.; Contrera, Joseph F.

    2007-07-01

    Consistent with the U.S. Food and Drug Administration (FDA) Critical Path Initiative, predictive toxicology software programs employing quantitative structure-activity relationship (QSAR) models are currently under evaluation for regulatory risk assessment and scientific decision support for highly sensitive endpoints such as carcinogenicity, mutagenicity and reproductive toxicity. At the FDA's Center for Food Safety and Applied Nutrition's Office of Food Additive Safety and the Center for Drug Evaluation and Research's Informatics and Computational Safety Analysis Staff (ICSAS), the use of computational SAR tools for both qualitative and quantitative risk assessment applications are being developed and evaluated. One tool of current interest is MDL-QSAR predictive discriminant analysis modeling of rodent carcinogenicity, which has been previously evaluated for pharmaceutical applications by the FDA ICSAS. The study described in this paper aims to evaluate the utility of this software to estimate the carcinogenic potential of small, organic, naturally occurring chemicals found in the human diet. In addition, a group of 19 known synthetic dietary constituents that were positive in rodent carcinogenicity studies served as a control group. In the test group of naturally occurring chemicals, 101 were found to be suitable for predictive modeling using this software's discriminant analysis modeling approach. Predictions performed on these compounds were compared to published experimental evidence of each compound's carcinogenic potential. Experimental evidence included relevant toxicological studies such as rodent cancer bioassays, rodent anti-carcinogenicity studies, genotoxic studies, and the presence of chemical structural alerts. Statistical indices of predictive performance were calculated to assess the utility of the predictive modeling method. Results revealed good predictive performance using this software's rodent carcinogenicity module of over 1200 chemicals, comprised primarily of pharmaceutical, industrial and some natural products developed under an FDA-MDL cooperative research and development agreement (CRADA). The predictive performance for this group of dietary natural products and the control group was 97% sensitivity and 80% concordance. Specificity was marginal at 53%. This study finds that the in silico QSAR analysis employing this software's rodent carcinogenicity database is capable of identifying the rodent carcinogenic potential of naturally occurring organic molecules found in the human diet with a high degree of sensitivity. It is the first study to demonstrate successful QSAR predictive modeling of naturally occurring carcinogens found in the human diet using an external validation test. Further test validation of this software and expansion of the training data set for dietary chemicals will help to support the future use of such QSAR methods for screening and prioritizing the risk of dietary chemicals when actual animal data are inadequate, equivocal, or absent.

  16. Radiological Impact Associated to Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) from Coal-Fired Power Plants Emissions - 13436

    SciTech Connect (OSTI)

    Dinis, Maria de Lurdes; Fiuza, Antonio; Soeiro de Carvalho, Jose; Gois, Joaquim; Meira Castro, Ana Cristina

    2013-07-01

    Certain materials used and produced in a wide range of non-nuclear industries contain enhanced activity concentrations of natural radionuclides. In particular, electricity production from coal is one of the major sources of increased human exposure to naturally occurring radioactive materials. A methodology was developed to assess the radiological impact due to natural radiation background. The developed research was applied to a specific case study, the Sines coal-fired power plant, located in the southwest coastline of Portugal. Gamma radiation measurements were carried out with two different instruments: a sodium iodide scintillation detector counter (SPP2 NF, Saphymo) and a gamma ray spectrometer with energy discrimination (Falcon 5000, Canberra). Two circular survey areas were defined within 20 km of the power plant. Forty relevant measurements points were established within the sampling area: 15 urban and 25 suburban locations. Additionally, ten more measurements points were defined, mostly at the 20-km area. The registered gamma radiation varies from 20 to 98.33 counts per seconds (c.p.s.) corresponding to an external gamma exposure rate variable between 87.70 and 431.19 nGy/h. The highest values were measured at locations near the power plant and those located in an area within the 6 and 20 km from the stacks. In situ gamma radiation measurements with energy discrimination identified natural emitting nuclides as well as their decay products (Pb-212, Pb-2142, Ra-226, Th-232, Ac-228, Th-234, Pa-234, U- 235, etc.). According to the results, an influence from the stacks emissions has been identified both qualitatively and quantitatively. The developed methodology accomplished the lack of data in what concerns to radiation rate in the vicinity of Sines coal-fired power plant and consequently the resulting exposure to the nearby population. (authors)

  17. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank R. Rack

    2006-09-20

    Cooperative Agreement DE-FC26-01NT41329 between Joint Oceanographic Institutions and DOE-NETL was divided into two phases based on successive proposals and negotiated statements of work pertaining to activities to sample and characterize methane hydrates on ODP Leg 204 (Phase 1) and on IODP Expedition 311 (Phase 2). The Phase 1 Final Report was submitted to DOE-NETL in April 2004. This report is the Phase 2 Final Report to DOE-NETL. The primary objectives of Phase 2 were to sample and characterize methane hydrates using the systems and capabilities of the D/V JOIDES Resolution during IODP Expedition 311, to enable scientists the opportunity to establish the mass and distribution of naturally occurring gas and gas hydrate at all relevant spatial and temporal scales, and to contribute to the DOE methane hydrate research and development effort. The goal of the work was to provide expanded measurement capabilities on the JOIDES Resolution for a dedicated hydrate cruise to the Cascadia continental margin off Vancouver Island, British Columbia, Canada (IODP Expedition 311) so that hydrate deposits in this region would be well characterized and technology development continued for hydrate research. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. The statement of work for this project included three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd.; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). Additional small tasks that arose during the course of the research were included under these three primary tasks in consultation with the DOE-NETL Program Manager. All tasks outlined in the original statement of work were accomplished except for the deployment and use of the X-ray CT system under Subtask 2-2. This reduction in scope provided resources that were applied to other activities to support the overall project. Post-expedition analysis of results and report writing will continue beyond this reporting period, however, all field deployments associated with this project have been successfully concluded as of this writing.

  18. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Rack, Frank R.; Dickens, Gerald; Ford, Kathryn; Schroeder, Derryl; Storms, Michael

    2002-08-01

    The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the preparation of tools and measurement systems for deployment, testing and use on ODP Leg 204, which will study hydrate deposits on Hydrate Ridge, offshore Oregon. Additional accomplishments were related to the postcruise evaluation of tools and measurements systems used on ODP Leg 201 along the Peru margin from January through March, 2002. The operational results from the use of the Pressure Core Sampler (PCS) tool and the PCS Gas Manifold on ODP Leg 201 are evaluated in this progress report in order to prepare for the upcoming deployments on ODP Leg 204 in July, 2002. The PCS was deployed 17 times during ODP Leg 201 and successfully retrieved cores from a broad range of lithologies and sediment depths along the Peru margin. Eleven deployments were entirely successful, collecting between 0.5 and 1.0 meters of sediment at greater than 75% of hydrostatic pressure. The PCS gas manifold was used in conjunction with the Pressure Core Sampler (PCS) throughout ODP Leg 201 to measure the total volume and composition of gases recovered in sediment cores associated with methane gas hydrates. The FUGRO Pressure Corer (FPC), one of the HYACE/HYACINTH pressure coring tools, was also deployed on the D/V JOIDES Resolution during ODP Legs 201 to field-test this coring system at three shallow-water sites located offshore Peru. The field-testing of these tools provides a corollary benefit to DOE/NETL at no cost to this project. The testing of these tools on the D/V JOIDES Resolution was negotiated as part of a cooperative agreement between JOI/ODP and the HYACINTH partners. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were used extensively during ODP Leg 201. The data obtained from the successful deployments of these tools is still being evaluated by the scientists and engineers involved in this testing; however, preliminary results are presented in this report. An infrared-thermal imaging system (IR-TIS) was deployed for the first time on ODP Leg 201. This system was used to identify methane hydrate intervals in the recovered cores. Initial discussions of these experiments are provided in this report. This report is an overview of the field measurements made on recovered sediment cores and the downhole measurements made during ODP Leg 201. These results are currently being used to incorporate the ''lessons learned'' from these deployments to prepare for a dedicated ODP leg to study the characteristics of naturally-occurring hydrates in the subsurface environment of Hydrate Ridge, offshore Oregon during ODP Leg 204, which will take place from July through September, 2002.

  19. Blimp-1{delta}exon7: A naturally occurring Blimp-1 deletion mutant with auto-regulatory potential

    SciTech Connect (OSTI)

    Schmidt, Doris; Nayak, Arnab; Schumann, Julia E.; Schimpl, Anneliese; Berberich, Ingolf Berberich-Siebelt, Friederike

    2008-12-10

    Blimp-1 is a master regulator of terminal B cell differentiation and plays a pivotal role in various developmental processes. In addition to full length Blimp-1, a Blimp-1 mRNA lacking exon 7 (Blimp-1{delta}7) has been described to occur in murine B cells. The activity and function of the mutant mRNA-encoded protein (Blimp-1{delta}7), lacking three crucial zinc fingers necessary for DNA interaction, is completely unknown. Since isoforms of other prdm family proteins affect each other's functions, we wondered whether Blimp-1{delta}7 still plays a role in B cells, independent of direct DNA binding. In this study, we found that Blimp-1{delta}7 is preferentially expressed in naive CD19{sup +} B cells. A fraction of Blimp-1{delta}7 migrates to the nucleus, colocalizes with HDAC2 and is found at sites of repressed chromatin, although it does not bind to the Blimp-1 DNA consensus site. Unexpectedly, Blimp-1 and Blimp-1{delta}7 homodimerize as well as heterodimerize with each other. Ectopic expression of Blimp-1{delta}7 in WEHI 231 cells, a Blimp-1-negative murine lymphoma line, leads to cessation of proliferation and enhancement of apoptosis. Importantly, LPS-induced differentiation is suppressed in the presence of Blimp-1{delta}7. This is in agreement with our finding that Blimp-1{delta}7 interferes with endogenous Blimp-1 expression. Thus, our data suggest an auto-regulatory mechanism of Blimp-1 activation.

  20. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank

    2003-06-30

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Frank Rack, Anne Trehu, and Tim Collett presented preliminary results and operational outcomes of ODP Leg 204 at the American Association of Petroleum Geologists annual meeting in Salt Lake City, UT; (2) several Leg 204 scientists participated in special hydrate sessions at the international EGS/AGU/EUG meeting in Nice, France and presented initial science results from the cruise, which included outcomes arising from this cooperative agreement; and, (3) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. At the EGS/EUG/AGU meeting in Nice, France in April, Leg 204 Co-chiefs Anne Trehu and Gerhard Bohrmann, as well as ODP scientists Charlie Paull, Erwin Suess, and Jim Kennett, participated in a press conference on hydrates. The well-attended press conference entitled ''Gas Hydrates: Free methane found and controversy over the 'hydrate gun''' led to stories in Nature on-line and BBC radio, among others. There were six (6) oral and fifteen (15) poster presentations on ODP Leg 204 hydrate science at the EGS/AGU/EUG Meeting in Nice, France on April 6-11, 2003. This was a very strong showing at a meeting just over six month following the completion of the drilling cruise and highlighted many of the results of the leg, including the results obtained with instruments and equipment funded under this cooperative agreement. At the AAPG annual meeting in Salt Lake City, UT on May 11-14, 2003, Anne Trehu gave an oral presentation about the scientific results of Leg 204, and Frank Rack presented a poster outlining the operational and technical accomplishments. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  1. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Bohrmann, Gerhard; Trehu, Anne; Storms, Michael; Schroeder, Derryl

    2002-09-30

    The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the deployment of tools and measurement systems on ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September, 2002. During Leg 204, we cored and logged 9 sites on the Oregon continental margin to determine the distribution and concentration of gas hydrates in an accretionary ridge and adjacent slope basin, investigate the mechanisms that transport methane and other gases into the gas hydrate stability zone (GHSZ), and obtain constraints on physical properties of hydrates in situ. A 3D seismic survey conducted in 2000 provided images of potential subsurface fluid conduits and indicated the position of the GHSZ throughout the survey region. After coring the first site, we acquired Logging-While-Drilling (LWD) data at all but one site to provide an overview of downhole physical properties. The LWD data confirmed the general position of key seismic stratigraphic horizons and yielded an initial estimate of hydrate concentration through the proxy of in situ electrical resistivity. These records proved to be of great value in planning subsequent coring. The second new hydrate proxy to be tested was infrared thermal imaging of cores on the catwalk as rapidly as possible after retrieval. The thermal images were used to identify hydrate samples and to map estimate the distribution and texture of hydrate within the cores. Geochemical analyses of interstitial waters and of headspace and void gases provide additional information on the distribution and concentration of hydrate within the stability zone, the origin and pathway of fluids into and through the GHSZ, and the rates at which the process of gas hydrate formation is occurring. Bio- and lithostratigraphic description of cores, measurement of physical properties, and in situ pressure core sampling and thermal measurements complement the data set, providing ground-truth tests of inferred physical and sedimentological properties. Among the most interesting preliminary results are: (1) the discovery that gas hydrates are distributed through a broad depth range within the GHSZ and that different physical and chemical proxies for hydrate distribution and concentration give generally consistent results; (2) evidence for the importance of sediment properties for controlling the migration of fluids in the accretionary complex; (3) geochemical indications that the gas hydrate system at Hydrate Ridge contains significant concentrations of higher order hydrocarbons and that fractionation and mixing signals will provide important constraints on gas hydrate dynamics; and (4) the discovery of very high chlorinity values that extend for at least 10 mbsf near the summit, indicating that hydrate formation here must be very rapid.

  2. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  3. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  4. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM)

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  5. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  6. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H. (Danville, CA)

    1986-01-01

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  7. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  8. EVALUATING AN INNOVATIVE OXYGEN SENSOR FOR REMOTE SUBSURFACE OXYGEN MEASUREMENTS

    SciTech Connect (OSTI)

    Millings, M; Brian Riha, B; Warren Hyde, W; Karen Vangelas, K; Brian02 Looney, B

    2006-10-12

    Oxygen is a primary indicator of whether anaerobic reductive dechlorination and similar redox based processes contribute to natural attenuation remedies at chlorinated solvent contaminated sites. Thus, oxygen is a viable indicator parameter for documenting that a system is being sustained in an anaerobic condition. A team of researchers investigated the adaptation of an optical sensor that was developed for oceanographic applications. The optical sensor, because of its design and operating principle, has potential for extended deployment and sensitivity at the low oxygen levels relevant to natural attenuation. The results of the research indicate this tool will be useful for in situ long-term monitoring applications, but that the traditional characterization tools continue to be appropriate for characterization activities.

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  10. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  11. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phase membranes have been evaluated for structural properties. An increasing crack growth resistance was observed for the membranes heat-treated at 1000 C in air and N{sub 2} with increasing crack length. The combined effect of thermal and elastic mismatch stresses on the crack path was studied and the fracture behavior of the dual phase composite at the test conditions was analyzed. Ceramic/metal (C/M) seals are needed to form a leak-tight interface between the OTM and a nickel-base super alloy. It was concluded that Ni-based brazing alloys provided the best option in terms of brazing temperature and final operating conditions after analyzing several possible brazing systems. A mechanical testing procedure has been developed. This model was tested with model ceramic/metal systems but it is expected to be useful for testing concentric perovskite/metal seals.

  12. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  13. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  14. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, Dennis W.

    1994-01-01

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured.

  15. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  16. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  17. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  18. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    resources, but challenges occur in producing this resource because of the impermeable nature of the reservoir rocks, small reservoir compartment, abnormal pressures, difficulty in...

  20. Researchers Directly Observe Oxygen Signature in the Oxygen-evolving...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic...

  1. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  2. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  3. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  4. USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS...

    Open Energy Info (EERE)

    Combination of boron from both phases into the liquid phase results in the Cl;B ratio dropping from 40 to as low as 20. Authors Adams and M.C. Published PROCEEDINGS, Twenty-Ninth...

  5. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1997-01-01

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  6. Descriptions of selected accidents that have occurred at nuclear reactor facilities

    SciTech Connect (OSTI)

    Bertini, H.W.

    1980-04-01

    This report was prepared at the request of the President's Commission on the Accident at Three Mile Island to provide the members of the Commission with some insight into the nature and significance of accidents that have occurred at nuclear reactor facilities in the past. Toward that end, this report presents a brief description of 44 accidents which have occurred throughout the world and which meet at least one of the severity criteria that were established.

  7. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect (OSTI)

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  8. Intake Air Oxygen Sensor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ignition can occur at elevated gas temperatures and with aged sensor Next Steps FMEA Study to understand ignition risk for failure modes identified by FMEA Identify...

  9. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

  10. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  11. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  12. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, Howard R. (Ames, IA); Bevolo, Albert J. (Ames, IA); Danielson, Gordon C. (Ames, IA); Weber, Michael F. (Wichita, KS)

    1980-11-04

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

  13. High pressure effects on the iron iron oxide and nickel nickel oxide oxygen

    Office of Scientific and Technical Information (OSTI)

    fugacity buffers (Journal Article) | SciTech Connect High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers Citation Details In-Document Search Title: High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers The chemical potential of oxygen in natural and experimental samples is commonly reported relative to a specific oxygen fugacity (fO{sub 2}) buffer. These buffers are precisely known at 1 bar, but under high

  14. High pressure effects on the iron iron oxide and nickel nickel oxide oxygen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fugacity buffers (Journal Article) | SciTech Connect High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers Citation Details In-Document Search Title: High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers The chemical potential of oxygen in natural and experimental samples is commonly reported relative to a specific oxygen fugacity (fO{sub 2}) buffer. These buffers are precisely known at 1 bar, but under high

  15. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    by 14.4 percent. During this period, U.S. manufacturers used less petroleum and coal in manufacturing processes. This expansion of gas use occurred although natural gas prices to...

  16. Radioactive Mineral Occurences in Nevada | Open Energy Information

    Open Energy Info (EERE)

    Radioactive Mineral Occurences in Nevada Abstract Abstract unavailable. Author Larry J. Garside Organization Nevada Bureau of Mines and Geology Published Nevada Bureau of...

  17. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  18. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  19. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas Lucian A. Lucia Hasan Jameel

    2005-09-30

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  20. Novel Membranes and Processes for Oxygen Enrichment

    SciTech Connect (OSTI)

    Lin, Haiqing

    2011-11-15

    The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

  1. Understanding Nature's Choreography in Batteries | U.S. DOE Office...

    Office of Science (SC) Website

    Understanding Nature's Choreography in Batteries Basic Energy Sciences (BES) BES Home ... key: red oxygen; green carbon; purple manganese; blue lithium; grey hydrogen). ...

  2. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  3. Oxygenates from synthesis gas

    SciTech Connect (OSTI)

    Falter, W.; Keim, W.

    1994-12-31

    The direct synthesis of oxygenates starting from synthesis gas is feasible by homogeneous and heterogeneous catalysis. Homogeneous Rh and Ru based catalysts yielding methyl formate and alcohols will be presented. Interestingly, modified heterogeneous catalysts based on {open_quotes}Isobutyl Oel{close_quotes} catalysis, practized in Germany (BRD) up to 1952 and in the former DDR until recently, yield isobutanol in addition to methanol. These {open_quotes}Isobutyl Oel{close_quotes} catalysts are obtained by adding a base such as Li < Na < K < Cs to a Zn-Cr{sub 2}O{sub 3} methanol catalyst. Isobutanol is obtained in up to 15% yield. Our best catalyst a Zr-Zn-Mn-Li-Pd catalyst produced isobotanol up to 60% at a rate of 740g isobutanol per liter catalyst and hour.

  4. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  5. MTBE, Oxygenates, and Motor Gasoline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased

  6. EIA-819, Monthly Oxygenate Report ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (EIA) Form EIA-819, "Monthly Biofuel and Oxygenate Report," is used to collect data on ethanol production capacity, as well as stocks, receipts, inputs, production, and blending of...

  7. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

    2007-08-28

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  8. Some mismatches occurred when simulating fractured reservoirs as homogeneous porous media

    SciTech Connect (OSTI)

    Mario Cesar Suarez Arriaga; Fernando Samaniego V.; Fernando Rodriguez

    1996-01-24

    The understanding of transport processes that occur in naturally fractured geothermal systems is far from being complete. Often, evaluation and numerical simulations of fractured geothermal reservoirs, are carried out by assuming equivalent porous media and homogeneous petrophysical properties within big matrix blocks. The purpose of this paper, is to present a comparison between results obtained from numerical studies of a naturally fractured reservoir treated as a simple porous medium and the simulation of some real aspects of the fractured reservoir. A general conclusion outlines the great practical importance of considering even approximately, the true nature of such systems. Our results show that the homogeneous simplified evaluation of the energy resource in a fractured system, could result in unrealistic estimates of the reservoir capacity to generate electricity.

  9. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  10. Oxygenate Supply/Demand Balances

    Gasoline and Diesel Fuel Update (EIA)

    Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model By Tancred C.M. Lidderdale This article first appeared in the Short-Term Energy Outlook Annual Supplement 1995, Energy Information Administration, DOE/EIA-0202(95) (Washington, DC, July 1995), pp. 33-42, 83-85. The regression results and historical data for production, inventories, and imports have been updated in this presentation. Contents * Introduction o Table 1. Oxygenate production capacity and demand *

  11. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19,...

  12. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  13. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  14. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  15. Heat distribution by natural convection

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1985-01-01

    Natural convection can provide adequate heat distribution in many situtations that arise in buildings. This is appropriate, for example, in passive solar buildings where some rooms tend to be more strongly solar heated than others or to reduce the number of heating units required in a building. Natural airflow and heat transport through doorways and other internal building apertures is predictable and can be accounted for in the design. The nature of natural convection is described, and a design chart is presented appropriate to a simple, single-doorway situation. Natural convective loops that can occur in buildings are described and a few design guidelines are presented.

  16. The effect of plutonium dioxide water surface coverage on the generation of hydrogen and oxygen

    SciTech Connect (OSTI)

    Veirs, Douglas K.; Berg, John M.; Crowder, Mark L.

    2012-06-20

    The conditions for the production of oxygen during radiolysis of water adsorbed onto plutonium dioxide powder are discussed. Studies in the literature investigating the radiolysis of water show that both oxygen and hydrogen can be generated from water adsorbed on high-purity plutonium dioxide powder. These studies indicate that there is a threshold in the amount of water below which oxygen is not generated. The threshold is associated with the number of monolayers of adsorbed water and is shown to occur at approximately two monolayers of molecularly adsorbed water. Material in equilibrium with 50% relative humidity (RH) will be at the threshold for oxygen generation. Using two monolayers of molecularly adsorbed water as the threshold for oxygen production, the total pressure under various conditions is calculated assuming stoichiometric production of hydrogen and oxygen. The specific surface area of the oxide has a strong effect on the final partial pressure. The specific surface areas resulting in the highest pressures within a 3013 container are evaluated. The potential for oxygen generation is mitigated by reduced relative humidity, and hence moisture adsorption, at the oxide surface which occurs if the oxide is warmer than the ambient air. The potential for oxygen generation approaches zero as the temperature difference between the ambient air and the material approaches 6 C.

  17. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  18. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

    2007-06-12

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  19. Catalyst containing oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  20. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank R

    2004-09-30

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  1. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack

    2005-06-30

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were to refine budgets and operational plans for Phase 2 of this cooperative agreement based on the scheduling of a scientific ocean drilling expedition to study marine methane hydrates along the Cascadia margin, in the NE Pacific as part of the Integrated Ocean Drilling Program (IODP) using the R/V JOIDES Resolution. The proposed statement of work for Phase 2 will include three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd., who will work with Fugro and Lawrence Berkeley National Laboratory to accomplish some of the subtasks; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). More details about these tasks are provided in the following sections of this report. The appendices to this report contain a copy of the scientific prospectus for the upcoming IODP Expedition 311 (Cascadia Margin Hydrates), which provides details of operational and scientific planning for this expedition.

  2. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Schroeder, Derryl; Storms, Michael

    2001-03-31

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were the deployment of tools and measurement systems for testing on ODP Leg 201, which is intended to study hydrate deposits on the Peru margin as part of other scientific investigations. Additional accomplishments were related to the continuing evolution of tools and measurements systems in preparation for deployment on ODP Leg 204, Hydrate Ridge, offshore Oregon in July 2002. The design for PCS Gas Manifold was finalized and parts were procured to assemble the gas manifold and deploy this system with the Pressure Core Sampler (PCS) tool on ODP Leg 201. The PCS was deployed 17 times during ODP Leg 201 and successfully retrieved cores from a broad range of lithologies and sediment depths along the Peru margin. Eleven deployments were entirely successful, collecting between 0.5 and 1.0 meters of sediment at greater than 75% of hydrostatic pressure. The PCS gas manifold was used in conjunction with the Pressure Core Sampler (PCS) throughout ODP Leg 201 to measure the total volume and composition of gases recovered in sediment cores associated with methane hydrates. The results of these deployments will be the subject of a future progress report. The FUGRO Pressure Corer (FPC), one of the HYACE/HYACINTH pressure coring tools, and two FUGRO engineers were deployed on the D/V JOIDES Resolution during ODP Legs 201 to field-test this coring system at sites located offshore Peru. The HYACINTH project is a European Union (EU) funded effort to develop tools to characterize methane hydrate and measure physical properties under in-situ conditions. The field-testing of these tools provides a corollary benefit to DOE/NETL at no cost to this project. The opportunity to test these tools on the D/V JOIDES Resolution was negotiated as part of a cooperative agreement between JOI/ODP and the HYACINTH partners. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were deployed onboard the R/V JOIDES Resolution and used extensively during ODP Leg 201. Preliminary results indicate successful deployments of these tools. An infrared-thermal imaging system (IR-TIS) was delivered to JOI/ODP for testing and use on ODP Leg 201 to identify methane hydrate intervals in the recovered cores. The results of these experiments will be the subject of a future progress report. This report presents an overview of the primary methods used for deploying the ODP memory tools and PCS on ODP Leg 201 and the preliminary operational results of this leg. Discussions regarding the laboratory analysis of the recovered cores and downhole measurements made during these deployments will be covered in a future progress report.

  3. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack

    2004-05-01

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Frank Rack presented preliminary results and operational outcomes of ODP Leg 204 at the DOE/NETL project review and two made two presentations at the ChevronTexaco Gulf of Mexico Hydrate JIP meeting, which were both held in Westminster, CO; and, (2) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  4. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Peter Schultheiss; Melanie Holland

    2005-01-01

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) follow-up logging of pressure cores containing hydrate-bearing sediment; and (2) opening of some of these cores to establish ground-truth understanding. The follow-up measurements made on pressure cores in storage are part of a hydrate geriatric study related to ODP Leg 204. These activities are described in detail in Appendices A and B of this report. Work also continued on developing plans for Phase 2 of this cooperative agreement based on evolving plans to schedule a scientific ocean drilling expedition to study marine methane hydrates along the Cascadia margin, in the NE Pacific as part of the Integrated Ocean Drilling Program (IODP) using the R/V JOIDES Resolution.

  5. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Storms, Michael; Schroeder, Derryl; Dugan, Brandon; Schultheiss, Peter

    2002-12-31

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were (1) the preliminary postcruise evaluation of the tools and measurement systems that were used during ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September 2002; and (2) the preliminary study of the hydrate-bearing core samples preserved in pressure vessels and in liquid nitrogen cryofreezers, which are now stored at the ODP Gulf Coast Repository in College Station, TX. During ODP Leg 204, several newly modified downhole tools were deployed to better characterize the subsurface lithologies and environments hosting microbial populations and gas hydrates. A preliminary review of the use of these tools is provided herein. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were used extensively and successfully during ODP Leg 204 aboard the D/V JOIDES Resolution. These systems provided a strong operational capability for characterizing the in situ properties of methane hydrates in subsurface environments on Hydrate Ridge during ODP Leg 204. Pressure was also measured during a trial run of the Fugro piezoprobe, which operates on similar principles as the DVTP-P. The final report describing the deployments of the Fugro Piezoprobe is provided in Appendix A of this report. A preliminary analysis and comparison between the piezoprobe and DVTP-P tools is provided in Appendix B of this report. Finally, a series of additional holes were cored at the crest of Hydrate Ridge (Site 1249) specifically geared toward the rapid recovery and preservation of hydrate samples as part of a hydrate geriatric study partially funded by the Department of Energy (DOE). In addition, the preliminary results from gamma density non-invasive imaging of the cores preserved in pressure vessels are provided in Appendix C of this report. An initial visual inspection of the samples stored in liquid nitrogen is provided in Appendix D of this report.

  6. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack

    2001-12-31

    The primary accomplishments during the first quarter were to mobilize materials and supplies to meet the deployment schedule for equipment and activities, as proposed under the DOE/NETL cooperative agreement with JOI, with initial testing and use of specialized tools and equipment on Ocean Drilling Program (ODP) Leg 201. As a requirement of the award, two copies of a technical feasibility report entitled ''Preliminary Evaluation of Existing Pressure/Temperature Coring Systems'' were delivered to DOE/NETL on October 22, 2001. The report was written to provide a discussion of the availability and compatibility of the four existing pressure coring devices in existence. Most of these systems are available for use by JOI/ODP aboard the D/V JOIDES Resolution, via purchase, lease, modification, etc. and the proposed capabilities to upgrade existing devices or systems for use on other platforms. In addition, the report provided a discussion of the compatibility of each existing coring device in conjunction with the use of the other coring devices, such as the advanced piston coring (APC) system used by ODP. Based on an evaluation of the JOI report, the DOE/NETL Program Manager William Gwilliam provided a ''Go'' decision to JOI for the further development of the ODP Pressure Coring System (PCS) and PCS Gas Manifold. During the reporting period negotiations were conducted with various potential subcontractors and vendors to establish the specific cost-sharing arrangements and work breakdown necessary to definitize the terms of the DOE/NETL cooperative agreement with JOI. The discussions were communicated with the DOE/NETL Program Manager, William Gwilliam, to keep NETL closely informed about events as this project evolved. A series of meetings were also held with ODP engineers, technical staff, and to plan for the implementation of the various tasks outlined in the JOI proposal to DOE for deployment during ODP Legs 201 and 204. These meetings helped to answer numerous unresolved questions and establish a firm timetable of remaining activities that needed to be accomplished by January 28, 2002, when ODP Leg 201 will begin.

  7. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Tim Francis; Peter Schultheiss; Philip E. Long; Barry M. Freifeld

    2005-04-01

    The primary activities accomplished during this quarter were continued efforts to develop plans for Phase 2 of this cooperative agreement based on the evolving operational planning for IODP Expedition 311, which will use the JOIDES Resolution to study marine methane hydrates along the Cascadia margin, offshore Vancouver Island. IODP Expedition 311 has been designed to further constrain the models for the formation of marine gas hydrate in subduction zone accretionary prisms. The objectives include characterizing the deep origin of the methane, its upward transport, its incorporation in gas hydrate, and its subsequent loss to the seafloor. The main attention of this expedition is on the widespread seafloor-parallel layer of dispersed gas hydrate located just above the base of the predicted stability field. In a gas hydrate formation model, methane is carried upward through regional sediment or small-scale fracture permeability, driven by the tectonic consolidation of the accretionary prism. The upward moving methane is incorporated into the gas hydrate clathrate as it enters the methane hydrate stability zone. Also important is the focusing of a portion of the upward methane flux into localized plumes or channels to form concentrations of near-seafloor gas hydrate. The amount of gas hydrate in local concentrations near the seafloor is especially important for understanding the response of marine gas hydrate to climate change. The expedition includes coring and downhole measurements at five sites across the Northern Cascadia accretionary prism. The sites will track the history of methane in an accretionary prism from (1) its production by mainly microbiological processes over a thick sediment vertical extent, (2) its upward transport through regional or locally focused fluid flow, (3) its incorporation in the regional hydrate layer above the BSR or in local concentrations at or near the seafloor, (4) methane loss from the hydrate by upward diffusion, and (5) methane oxidation and incorporation in seafloor carbonate, or expulsion to the ocean. This expedition builds on the previous Cascadia gas hydrate drilling of ODP Leg 146 and on more recent ODP Leg 204 off Oregon. Important experiments being considered for DOE/NETL funding as part of the JOI cooperative agreement include, (1) Logging-While-Drilling/Measurements-While-Drilling (LWD/MWD), (2) Pressure Core Sampling (PCS/HYACINTH) of gas hydrate, and fluid recovery under in situ conditions, (3) X-ray CT logging of whole cores under in situ conditions, and (4) Infrared thermal imaging of whole round cores to map temperature variations resulting from the presence of hydrate. Preliminary budget estimates have been made for each of these tasks and discussions are ongoing with DOE/NETL program managers to develop a final plan that can be implemented within the constraints of the available funding and logistical considerations.

  8. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Schultheiss, Peter

    2005-12-31

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were the implementation of a scientific ocean drilling expedition to study marine methane hydrates along the Cascadia margin, in the NE Pacific as part of Integrated Ocean Drilling Program (IODP) Expedition 311 using the R/V JOIDES Resolution and the deployment of all required equipment and personnel to provide the required services during this expedition. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. New ODP Pressure Coring System (PCS) aluminum autoclave chambers were fabricated prior to the expedition. During the expedition, 16 PCS autoclaves containing pressure cores were X-rayed before and after depressurization using a modified Geotek MSCL-P (multi-sensor core logger-pressure) system. These PCS cores were density scanned using the MSCL-V (multi-sensor core logger-vertical) during depressurization to monitor gas evolution. The MSCL-V was set up in a 20-foot-long refrigerated container provided by Texas A&M University through the JOI contract with TAMRF. IODP Expedition 311 was the first time that PCS cores were examined before (using X-ray), during (using MSCL-V gamma density) and after (using X-ray) degassing to determine the actual volume and distribution of sediment and gas hydrate in the pressurized core, which will be important for more accurate determination of mass balances between sediment, gas, gas hydrate, and fluids in the samples collected. Geotek, Ltd was awarded a contract by JOI to provide equipment and personnel to perform pressure coring and related work on IODP Expedition 311 (Cascadia Margin Gas Hydrates). Geotek, Ltd. provided an automated track for use with JOI's infrared camera systems. Four auxiliary monitors showed infrared core images in real time to aid hydrate identification and sampling. Images were collected from 185 cores during the expedition and processed to provide continuous core temperature data. The HYACINTH pressure coring tools, subsystems, and core logging systems were mobilized to Astoria, Oregon. Both HYACINTH pressure coring tools, the HRC (HYACE Rotary Corer) and the FPC (Fugro Pressure Corer) were mobilized and used during the expedition. Two HYACINTH engineers supervised the use of the tools and five good pressure cores were obtained. Velocity, density and X-ray linear scanning data were collected from these cores at near in situ pressure using the MSCL-P system. Dr. Barry Freifeld from Lawrence Berkeley National Laboratory provided an X-ray source and detector for X-ray imaging of pressure cores and helped Geotek with the design and mobilization of the MSCL-P system. Pressure core handling, transfer, and logging was performed in a refrigerated 20-foot container supplied by Geotek, Ltd. After scanning, the pressure cores were stored for on-shore analysis in aluminum barrels. Additional studies were conducted at the Pacific Geoscience Center (PGC), where a shore based laboratory was established after Expedition 311.

  9. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank

    2004-06-30

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) post-cruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  10. In-Situ Sampling and Characterization of Naturally Occuring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Guerin, Gilles; Goldberg, David

    2003-12-31

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Leg 204 scientific party members presented preliminary results and operational outcomes of ODP Leg 204 at the American Geophysical Union Fall meeting, which was held in San Francisco, CA; and, (2) a report was prepared by Dr. Gilles Guerin and David Goldberg from Lamont-Doherty Earth Observatory of Columbia University on their postcruise evaluation of the data, tools and measurement systems that were used for vertical seismic profiling (VSP) experiments during ODP Leg 204. The VSP report is provided herein. Intermediate in scale and resolution between the borehole data and the 3-D seismic surveys, the Vertical Seismic Profiles (VSP) carried during Leg 204 were aimed at defining the gas hydrate distribution on hydrate ridge, and refining the signature of gas hydrate in the seismic data. VSP surveys were attempted at five sites, following completion of the conventional logging operations. Bad hole conditions and operational difficulties did not allow to record any data in hole 1245E, but vertical and constant offset VSP were successful in holes 1244E, 1247B and 1250F, and walk-away VSP were successfully completed in holes 1244E, 1250F and 1251H. Three different tools were used for these surveys. The vertical VSP provided the opportunity to calculate interval velocity that could be compared and validated with the sonic logs in the same wells. The interval velocity profiles in Holes 1244E and 1247B are in very good agreement with the sonic logs. Information about the Leg 204 presentations at the AGU meeting are included in a separate Topical Report, which has been provided to DOE/NETL in addition to this Quarterly Report. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  11. Ocean disposal option for bulk wastes containing naturally occurring radionuclides: an assessment case history. [From Niagara Falls storage site

    SciTech Connect (OSTI)

    Stull, E.A.; Merry-Libby, P.

    1985-01-01

    There are 180,000 m/sup 3/ of slightly contaminated radioactive wastes (36 pCi/g radium-226) currently stored at the US Department of Energy's Niagara Falls Storage Site (NFSS), near Lewiston, New York. These wastes resulted from the cleanup of soils that were contaminated above the guidelines for unrestricted use of property. An alternative to long-term management of these wastes on land is dispersal in the ocean. A scenario for ocean disposal is present

  12. Oxygen-Enriched Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion Oxygen-Enriched Combustion This tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency. PROCESS HEATING TIP SHEET #3 PDF icon Oxygen-Enriched Combustion (September 2005) More Documents & Publications Save Energy Now in Your Process Heating Systems Waste Heat Reduction and Recovery for Improving Furnace Efficiency, Productivity and Emissions Performance: A

  13. High-temperature potentiometric oxygen sensor with internal reference

    DOE Patents [OSTI]

    Routbort, Jules L. (Hinsdale, IL); Singh, Dileep (Naperville, IL); Dutta, Prabir K. (Worthington, OH); Ramasamy, Ramamoorthy (North Royalton, OH); Spirig, John V. (Columbus, OH); Akbar, Sheikh (Hilliard, OH)

    2011-11-15

    A compact oxygen sensor is provided, comprising a mixture of metal and metal oxide an enclosure containing said mixture, said enclosure capable of isolating said mixture from an environment external of said enclosure, and a first wire having a first end residing within the enclosure and having a second end exposed to the environment. Also provided is a method for the fabrication of an oxygen sensor, the method comprising confining a metal-metal oxide solid mixture to a container which consists of a single material permeable to oxygen ions, supplying an electrical conductor having a first end and a second end, whereby the first end resides inside the container as a reference (PO.sub.2).sup.ref, and the second end resides outside the container in the atmosphere where oxygen partial pressure (PO.sub.2).sup.ext is to be measured, and sealing the container with additional single material such that grain boundary sliding occurs between grains of the single material and grains of the additional single material.

  14. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect (OSTI)

    Kelly, Seán; Turner, Miles M.

    2013-09-28

    A “plasma needle” is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  15. Proton Dripping Tests a Fundamental Force of Nature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    off, similar to the water in this photo, leaving an oxygen-13 nucleus behind. Like gravity, the strong interaction is a fundamental force of nature. It is the essential "glue"...

  16. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  17. Natural air motion in passive buildings

    SciTech Connect (OSTI)

    Balcomb, J.D.; Jones, G.F.

    1985-01-01

    The nature of natural convection is described, and a design chart is presented appropriate to a simple, single-doorway situation. Natural convective loops that can occur in buildings are described and a few experimental results are presented. Observations of stratification are discussed, similitude experiments are described, and the beginnings of a complete-system mathematical model are presented.

  18. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  19. Hydrogen and oxygen concentrations in IXCs: A compilation

    SciTech Connect (OSTI)

    Liljegren, L.M.; Terrones, G.T.; Melethil, P.K.

    1996-06-01

    This paper contains four reports and two internal letters that address the estimation of hydrogen and oxygen concentrations in ion exchange columns that treat the water of the K-East and K-West Basins at Hanford. The concern is the flammability of this mixture of gases and planning for safe transport during decommissioning. A transient will occur when the hydrogen filter is temporarily blocked by a sandbag. Analyses are provided for steady-state, transients, and for both wet and dry resins.

  20. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Stability-Low-Cost Supports | Department of Energy Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 PDF icon adzic_bnl_kickoff.pdf More Documents & Publications Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

  1. Jupiter Oxygen Corporation | Open Energy Information

    Open Energy Info (EERE)

    Place: Schiller Park, Illinois Zip: 60176 Product: Illinois-based oxy-fuel combustion company involved in the capture of CO2. References: Jupiter Oxygen Corporation1...

  2. Identification of an Archean marine oxygen oasis

    SciTech Connect (OSTI)

    Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

    2014-01-01

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  3. Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  4. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  5. EIA-819, Monthly Oxygenate Report Page 1

    Gasoline and Diesel Fuel Update (EIA)

    EIA-819, Monthly Oxygenate Report Page 1 U. S. DEPARTMENT OF ENERGY ENERGY INFORMATION ADMINISTRATION Washington, D. C. 20585 OMB No. 1905-0165 Expiration Date: 05/31/2016 (Revised 2013) EIA-819 MONTHLY OXYGENATE REPORT INSTRUCTIONS ................................................................................................................................................................................................................................... QUESTIONS If, after reading the

  6. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1996-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  7. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1997-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  8. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  9. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic

    Office of Scientific and Technical Information (OSTI)

    Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Fluid-Bed Testing of Greatpoint

  10. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic

    Office of Scientific and Technical Information (OSTI)

    Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Fluid-Bed Testing of Greatpoint

  11. Local Leaders: Respond to Natural Gas Disruptions | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Because natural gas is distributed through underground pipelines, delivery disruptions occur less often than electrical outages. Severe storms, flooding, and earthquakes can expose ...

  12. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    resources, but challenges occur in producing this resource because of the impermeable nature of the reservoir rocks, small reservoir compartment, abnormal pressures, difficulty in...

  13. Homeowners: Respond to Natural Gas Disruptions | Department of Energy

    Energy Savers [EERE]

    Natural Gas Disruptions Homeowners: Respond to Natural Gas Disruptions Homeowners: Respond to Natural Gas Disruptions Because natural gas is distributed through underground pipelines, delivery disruptions occur less often than electrical outages. Severe storms, flooding, and earthquakes can expose and break pipes, however. When disruptions do occur, it can take weeks or even months to restore. Homeowners should take care in identifying and reporting any problems, as they may pose substantial

  14. Local Leaders: Respond to Natural Gas Disruptions | Department of Energy

    Energy Savers [EERE]

    Natural Gas Disruptions Local Leaders: Respond to Natural Gas Disruptions Local Leaders: Respond to Natural Gas Disruptions Because natural gas is distributed through underground pipelines, delivery disruptions occur less often than electrical outages. Severe storms, flooding, and earthquakes can expose and break pipes, however. When disruptions do occur, it can take weeks or even months to restore. Communicate effectively with the public, and ensure that first responders and gas companies have

  15. Petrochemical feedstock from basic oxygen steel furnace

    SciTech Connect (OSTI)

    Greenwood, C.W.; Hardwick, W.E.

    1983-10-01

    Iron bath gasification in which coal, lime, steam and oxygen are injected into a bath of molten iron for the production of a medium-Btu gas is described. The process has its origin in basic oxygen steelmaking. It operates at high temperatures and is thus not restrictive on the type of coal used. The ash is retained in the slag. The process is also very efficient. The authors suggest that in the present economic climate in the iron and steel industry, such a plant could be sited where existing coal-handling, oxygen and steelmaking equipment are available.

  16. Thickness independent reduced forming voltage in oxygen engineered HfO{sub 2} based resistive switching memories

    SciTech Connect (OSTI)

    Sharath, S. U. Kurian, J.; Komissinskiy, P.; Hildebrandt, E.; Alff, L.; Bertaud, T.; Walczyk, C.; Calka, P.; Schroeder, T.

    2014-08-18

    The conducting filament forming voltage of stoichiometric hafnium oxide based resistive switching layers increases linearly with layer thickness. Using strongly reduced oxygen deficient hafnium oxide thin films grown on polycrystalline TiN/Si(001) substrates, the thickness dependence of the forming voltage is strongly suppressed. Instead, an almost constant forming voltage of about 3?V is observed up to 200?nm layer thickness. This effect suggests that filament formation and switching occurs for all samples in an oxidized HfO{sub 2} surface layer of a few nanometer thickness while the highly oxygen deficient thin film itself merely serves as a oxygen vacancy reservoir.

  17. Engineering MulticomponentNanocatalystsfor Oxygen Reduction (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Engineering MulticomponentNanocatalystsfor Oxygen Reduction Citation Details In-Document Search Title: Engineering MulticomponentNanocatalystsfor Oxygen Reduction Authors: Guo, Shaojun [1] + Show Author Affiliations Los Alamos National Laboratory [Los Alamos National Laboratory Publication Date: 2014-03-27 OSTI Identifier: 1126640 Report Number(s): LA-UR-13-28233 DOE Contract Number: AC52-06NA25396 Resource Type: Conference Resource Relation: Conference: 247th ACS National

  18. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19, 2012, Fuel Cell Technologies Program webinar, "BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs)." PDF icon BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs) Webinar Slides More Documents & Publications Contiguous Platinum

  19. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Plainfield, IL); Kobylinski, Thaddeus P. (Prospect, PA); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1998-01-01

    Preparation, structure, and properties of mixed metal oxide compositions and their uses are described. Mixed metal oxide compositions of the invention have stratified crystalline structure identifiable by means of powder X-ray diffraction patterns. In the form of dense ceramic membranes, the present compositions demonstrate an ability to separate oxygen selectively from a gaseous mixture containing oxygen and one or more other volatile components by means of ionic conductivities.

  20. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.W.

    1997-05-01

    Cryenco and Los Alamos are collaborating to develop a natural-gas-powered natural-gas liquefier that will have no moving parts and require no electrical power. It will have useful efficiency, remarkable reliability, and low cost. The liquefaction of natural gas, which occurs at only 115 Kelvin at atmospheric pressure, has previously required rather sophisticated refrigeration machinery. The 1990 invention of the thermoacoustically driven orifice pulse-tube refrigerator (TA-DOPTR) provides cryogenic refrigeration with no moving parts for the first time. In short, this invention uses acoustic phenomena to produce refrigeration from heat. The required apparatus consists of nothing more than helium-filled heat exchangers and pipes, made of common materials, without exacting tolerances. In the Cryenco-Los Alamos collaboration, the authors are developing a version of this invention suitable for use in the natural-gas industry. The project is known as acoustic liquefier for short. The present program plans call for a two-phase development. Phase 1, with capacity of 500 gallon per day (i.e., approximately 40,000 scfd, requiring a refrigeration power of about 7 kW), is large enough to illuminate all the issues of large-scale acoustic liquefaction without undue cost, and to demonstrate the liquefaction of 60--70% of input gas, while burning 30--40%. Phase 2 will target versions of approximately 10{sup 6} scfd = 10,000 gallon per day capacity. In parallel with both, they continue fundamental research on the technology, directed toward increased efficiency, to build scientific foundations and a patent portfolio for future acoustic liquefiers.

  1. Magnetism in Lithium–Oxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13

    Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  2. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

  3. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  4. Artificial oxygen transport protein (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Artificial oxygen transport protein Citation Details In-Document Search Title: Artificial oxygen transport protein You are accessing a document from the Department of...

  5. Artificial oxygen transport protein (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Artificial oxygen transport protein Citation Details In-Document Search Title: Artificial oxygen transport protein This invention provides heme-containing peptides capable...

  6. Testing Oxygen Reduction Reaction Activity with the Rotating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique ...

  7. Webinar: Testing Oxygen Reduction Reaction Activity with the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique ...

  8. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines ...

  9. Self-powered Hydrogen + Oxygen Injection System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Self-powered Hydrogen + Oxygen Injection System Self-powered Hydrogen + Oxygen Injection System Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by ...

  10. Migration Mechanisms of Oxygen Interstitial Clusters in UO2 ...

    Office of Scientific and Technical Information (OSTI)

    Migration Mechanisms of Oxygen Interstitial Clusters in UO2 Citation Details In-Document Search Title: Migration Mechanisms of Oxygen Interstitial Clusters in UO2 Understanding the ...

  11. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and...

  12. Effect of cation ordering on oxygen vacancy diffusion pathways in double perovskites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Uberuaga, Blas Pedro; Pilania, Ghanshyam

    2015-07-08

    Perovskite structured oxides (ABO3) are attractive for a number of technological applications, including as superionics because of the high oxygen conductivities they exhibit. Double perovskites (AA’BB’O6) provide even more flexibility for tailoring properties. Using accelerated molecular dynamics, we examine the role of cation ordering on oxygen vacancy mobility in one model double perovskite SrLaTiAlO6. We find that the mobility of the vacancy is very sensitive to the cation ordering, with a migration energy that varies from 0.6 to 2.7 eV. In the extreme cases, the mobility is both higher and lower than either of the two end member single perovskites.more » Further, the nature of oxygen vacancy diffusion, whether one-dimensional, two-dimensional, or three-dimensional, also varies with cation ordering. We correlate the dependence of oxygen mobility on cation structure to the distribution of Ti4+ cations, which provide unfavorable environments for the positively charged oxygen vacancy. The results demonstrate the potential of using tailored double perovskite structures to precisely control the behavior of oxygen vacancies in these materials.« less

  13. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  14. Direct Observation of the Oxygenated Species during Oxygen Reduction on a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Fuel Cell Cathode | Stanford Synchrotron Radiation Lightsource Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell

  15. Oxygen generator for medical applications (USIC)

    SciTech Connect (OSTI)

    Staiger, C. L.

    2012-03-01

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas demand, thereby contributing to larger net injections of natural gas into storage. Other Market Trends: EIA Releases The Natural Gas Annual 2006: The Energy...

  17. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-12-20

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

  18. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  19. Complexes of self-interstitials with oxygen atoms in Ge

    SciTech Connect (OSTI)

    Khirunenko, L. I.; Pomozov, Yu. V.; Sosnin, M. G.; Abrosimov, N. V.; Riemann, H.

    2014-02-21

    Interactions of germanium self-interstitials with interstitial oxygen atoms in Ge subjected to irradiation at ?80 K and subsequently to annealing have been studied. To distinguish the processes involving vacancies and self-interstitials the doping with tin was used. It was shown that absorption lines with maximum at 602, 674, 713 and 803 cm{sup ?1} are self-interstitials-related. Two lines at 602 and 674, which develop upon annealing in the temperature range 180–240 K, belong to IO complexes, while the bands at 713 and 803 cm{sup ?1}, which emerge after annealing at T>220 K, are associated with I{sub 2}O. It is argued that the annealing of IO occurs by two mechanisms: by dissociation and by diffusion.

  20. Oxygen vacancy ordering within anion-deficient Ceria

    SciTech Connect (OSTI)

    Hull, S.; Norberg, S.T.; Ahmed, I.; Eriksson, S.G.; Marrocchelli, D.; Madden, P.A.

    2009-10-15

    The structural properties of anion deficient ceria, CeO{sub 2-{delta}}, have been studied as a function of oxygen partial pressure, p(O{sub 2}), over the range 0>=log{sub 10p}(O{sub 2})>=-18.9 at 1273(2) K using the neutron powder diffraction technique. Rietveld refinement of the diffraction data collected on decreasing p(O{sub 2}) showed increases in the cubic lattice parameter, a, the oxygen nonstoichiometry, delta, and the isotropic thermal vibration parameters, u{sub Ce} and u{sub O}, starting at log{sub 10p}(O{sub 2}){approx}-11. The increases are continuous, but show a distinct kink at log{sub 10p}(O{sub 2}){approx}-14.5. Analysis of the total scattering (Bragg plus diffuse components) using reverse Monte Carlo (RMC) modelling indicates that the O{sup 2-} vacancies preferentially align as pairs in the <111> cubic directions as the degree of nonstoichiometry increases. This behaviour is discussed with reference to the chemical crystallography of the CeO{sub 2}-Ce{sub 2}O{sub 3} system at ambient temperature and, in particular, to the nature of the long-range ordering of O{sup 2-} vacancies within the crystal structure of Ce{sub 7}O{sub 12}. - Graphical abstract: Partial radial distribution function for oxygen vacancies within CeO{sub 1.710} at 1273 K (solid line) showing the increased tendency for local ordering in <111> directions compared to a random distribution (dashed line).

  1. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  2. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, I.C.; Baker, R.W.

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

  3. Revealing the True Nature of a Metal Oxide | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Revealing the True Nature of a Metal Oxide Extensive calculations revealed that the calcium-iridium-oxygen compound CaIrO3 is a Slater-type insulator, putting to rest the debate of...

  4. Oxygen transport in the internal xenon plasma of a dispenser hollow cathode

    SciTech Connect (OSTI)

    Capece, Angela M. Shepherd, Joseph E.; Polk, James E.; Mikellides, Ioannis G.

    2014-04-21

    Reactive gases such as oxygen and water vapor modify the surface morphology of BaO dispenser cathodes and degrade the electron emission properties. For vacuum cathodes operating at fixed temperature, the emission current drops rapidly when oxygen adsorbs on top of the low work function surface. Previous experiments have shown that plasma cathodes are more resistant to oxygen poisoning and can operate with O{sub 2} partial pressures one to two orders of magnitude higher than vacuum cathodes before the onset of poisoning occurs. Plasma cathodes used for electric thrusters are typically operated with xenon; however, gas phase barium, oxygen, and tungsten species may be found in small concentrations. The densities of these minor species are small compared with the plasma density, and thus, their presence in the discharge does not significantly alter the xenon plasma parameters. It is important, however, to consider the transport of these minor species as they may deposit on the emitter surface and affect the electron emission properties. In this work, we present the results of a material transport model used to predict oxygen fluxes to the cathode surface by solving the species conservation equations in a cathode with a 2.25?mm diameter orifice operated at a discharge current of 15?A, a Xe flow rate of 3.7 sccm, and 100?ppm of O{sub 2}. The dominant ionization process for O{sub 2} is resonant charge exchange with xenon ions. Ba is effectively recycled in the plasma; however, BaO and O{sub 2} are not. The model shows that the oxygen flux to the surface is not diffusion-limited; therefore, the high resistance to oxygen poisoning observed in plasma cathodes likely results from surface processes not considered here.

  5. Experiments on oxygen desorption from surface warm seawater under open-cycle ocean thermal energy conversion

    SciTech Connect (OSTI)

    Pesaran, A.A. )

    1992-11-01

    This paper presents the results of scoping deaeration experiments conducted with warm surface seawater under open-cycle ocean thermal energy conversion (OC-OTEC) conditions. Concentrations of dissolved oxygen in seawater at three locations (in the supply water, water leaving the predeaerator, and discharge water from an evaporator) were measured and used to estimate oxygen desorption levels. The results suggest that 7 percent to 60 percent of the dissolved oxygen in the supply water was desorbed from seawater in the predeaerator for pressures ranging from 35 to 9 kPa. Bubble injection in the upcomer increased the oxygen desorption rate by 20 percent to 60 percent. The data also indicated that at typical OC-OTEC evaporator pressures, when flash evaporation in the evaporator occurred, 75 percent to 95 percent of the dissolved oxygen was desorbed overall from the warm seawater. The results were used to find the impact of a single-stage predeaeration scheme on the power to remove noncondensable gases in an OC-OTEC plant.

  6. Method of producing metallized chloroplasts and use thereof in the photochemical production of hydrogen and oxygen

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1987-01-01

    The invention is primarily a metallized chloroplast composition for use in a photosynthetic reaction. A catalytic metal is precipitated on a chloroplast membrane at the location where a catalyzed reduction reaction occurs. This metallized chloroplast is stabilized by depositing it on a support medium such as fiber so that it can be easily handled. A possible application of this invention is the splitting of water to form hydrogen and oxygen that can be used as a renewable energy source.

  7. Ammonia producing engine utilizing oxygen separation

    DOE Patents [OSTI]

    Easley, Jr., William Lanier (Dunlap, IL); Coleman, Gerald Nelson (Petersborough, GB); Robel, Wade James (Peoria, IL)

    2008-12-16

    A power system is provided having a power source, a first power source section with a first intake passage and a first exhaust passage, a second power source section with a second intake passage and a second exhaust passage, and an oxygen separator. The second intake passage may be fluidly isolated from the first intake passage.

  8. Experiments on oxygen desorption from surface warm seawater under open-cycle ocean thermal energy conversion (OC-OTEC) conditions

    SciTech Connect (OSTI)

    Pesaran, A.A.

    1989-12-01

    This paper reports the results of scoping deaeration experiments conducted with warm surface seawater under open-cycle ocean thermal energy conversion (OC-OTEC). Concentrations of dissolved oxygen in seawater at three locations (in the supply water, water leaving a predeaerator, and discharge water from an evaporator) were measured and used to estimate oxygen desorption levels. The results suggest that 7% to 60% of dissolved oxygen in the supply water was desorbed from seawater in the predeaerator for pressures ranging from 9 to 35 kPa. Bubble injection in the upcomer increased the oxygen desorption rate by 20% to 60%. The dependence of oxygen desorption with flow rate could not be determined. The data also indicated that at typical OC-OTEC evaporator pressures when flashing occurred, 75% to 95% of dissolved oxygen was desorbed overall from the warm seawater. The uncertainty in results is larger than one would desire. These uncertainties are attributed to the uncertainties and difficulties in the dissolved oxygen measurements. Methods to improve the measurements for future gas desorption studies for warm surface and cold deep seawater under OC-OTEC conditions are recommended. 14 refs., 5 figs., 2 tabs.

  9. Mechanism of singlet oxygen deactivation in an electric discharge oxygen – iodine laser

    SciTech Connect (OSTI)

    Azyazov, V N; Mikheyev, P A; Torbin, A P; Pershin, A A; Heaven, M C

    2014-12-31

    We have determined the influence of the reaction of molecular singlet oxygen with a vibrationally excited ozone molecule O{sub 2}(a {sup 1}?) + O{sub 3}(?) ? 2O{sub 2} + O on the removal rate of O{sub 2}(a {sup 1}?) in an electric-discharge-driven oxygen – iodine laser. This reaction has been shown to be a major channel of O{sub 2}(a {sup 1}?) loss at the output of an electric-discharge singlet oxygen generator. In addition, it can also contribute significantly to the loss of O{sub 2}(a {sup 1}?) in the discharge region of the generator. (lasers)

  10. Cadmium-induced glutathionylation of actin occurs through a ROS-independent mechanism: Implications for cytoskeletal integrity

    SciTech Connect (OSTI)

    Choong, Grace; Liu, Ying; Xiao, Weiqun; Templeton, Douglas M.

    2013-10-15

    Cadmium disrupts the actin cytoskeleton in rat mesangial cells, and we have previously shown that this involves a complex interplay involving activation of kinase signaling, protein translocation, and disruption of focal adhesions. Here we investigate the role that glutathionylation of actin plays in Cd{sup 2+}-associated cytoskeletal reorganization. Low concentrations of Cd{sup 2+} (0.5–2 ?M) caused an increase in actin glutathionylation by 6 h, whereas at higher concentrations glutathionylation remained at basal levels. Although oxidation with diamide increased glutathionylation, reactive oxygen species (ROS) were not involved in the Cd{sup 2+}-dependent effect, as only Cd{sup 2+} concentrations above 2 ?M were sufficient to increase ROS. However, low [Cd{sup 2+}] increased total glutathione levels without affecting the ratio of reduced/oxidized glutathione, and inhibition of glutathione synthesis suppressed actin glutathionylation. Cadmium increased the activity of the enzyme glutaredoxin, which influences the equilibrium between glutathionylated and deglutathionylated proteins and thus may influence levels of glutathionylated actin. Together these observations show that cadmium-dependent effects on actin glutathionylation are affected by glutathione metabolism and not by direct effects of ROS on thiol chemistry. In vitro polymerization assays with glutathionylated actin show a decreased rate of polymerization. In contrast, immunofluorescence of cytoskeletal structure in intact cells suggests that increases in actin glutathionylation accompanying increased glutathione levels occurring under low Cd{sup 2+} exposure are protective in vivo, with cytoskeletal disruption ensuing only when higher Cd{sup 2+} concentrations increase ROS levels and prevent an increase in actin–glutathione conjugates. - Highlights: • Cadmium disrupts the actin cytoskeleton in mesangial cells. • Cadmium induces glutathionylation of actin at low concentrations. • Glutathionylation requires glutathione synthesis but is independent of ROS. • Glutathionylation is protective against cytoskeletal disruption at low cadmium.

  11. NATURAL GAS FROM SHALE: Questions and Answers

    Office of Environmental Management (EM)

    Where is shale gas found in the United States? Shale gas is located in many parts of the United States. These deposits occur in shale "plays" - a set of discovered, undiscovered or possible natural gas accumulations that exhibit similar geological characteristics. Shale plays are located within large-scale basins or accumulations of sedimentary rocks, often hundreds of miles across, that also may contain other oil and gas resources. 1 Shale gas production is currently occurring in 16

  12. Oxygen-producing inert anodes for SOM process

    DOE Patents [OSTI]

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  13. Elucidation of the Local and Long-Range Structural Changes that Occur in

    Office of Scientific and Technical Information (OSTI)

    Germanium Anodes in Lithium-Ion Batteries (Journal Article) | SciTech Connect Elucidation of the Local and Long-Range Structural Changes that Occur in Germanium Anodes in Lithium-Ion Batteries Citation Details In-Document Search Title: Elucidation of the Local and Long-Range Structural Changes that Occur in Germanium Anodes in Lithium-Ion Batteries Authors: Jung, Hyeyoung ; Allan, Phoebe K ; Hu, Yan-Yan ; Borkiewicz, Olaf ; Wang, Xiao-Liang ; Han, Wei-Qiang ; Du, Lin-Shu ; Pickard, Chris J.

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Sources & Uses Petroleum & Other Liquids Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2009 Next Release: August 13, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 5, 2009) Natural...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    , 2008 Next Release: July 10, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 25, natural gas spot prices...

  17. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  18. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  19. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  20. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    cooling demand for natural gas. Meanwhile, it became increasingly clear that Hurricane Frances likely would not pose a significant threat to natural gas production in the Gulf of...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas vehicles. The Department of Energys Office of Energy Efficiency and Renewable Energy reports that there were 841 compressed natural gas (CNG) fuel stations and 41...

  2. Natural Gas Weekly Update

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    wide array of affiliates in all sectors of the energy market. Along with the changing nature of the energy affiliates, the changing nature of the transmission providers themselves...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5, 2009 Next Release: July 2, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 24, 2009) Natural gas...

  4. Natural Gas Weekly Update

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    Next Release: Thursday, May 19, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 11, 2011) Natural...

  5. Natural Gas Weekly Update

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    Release: Thursday, April 28, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 20, 2011) Natural...

  6. Natural Gas Weekly Update

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    Release: Thursday, August 26, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 18, 2010) Natural...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: November 6, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, October 29) Natural gas...

  8. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2008 Next Release: June 26, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 11, natural gas spot prices...

  10. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  11. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R. (Lansdale, PA); Bond, James A. (Exton, PA)

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  12. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  13. Excess Oxygen Defects in Layered Cuprates

    DOE R&D Accomplishments [OSTI]

    Lightfoot, P.; Pei, S. Y.; Jorgensen, J. D.; Manthiram, A.; Tang, X. X.; Goodenough, J. B.

    1990-09-01

    Neutron powder diffraction has been used to study the oxygen defect chemistry of two non-superconducting layered cuprates, La{sub 1. 25}Dy{sub 0.75}Cu{sub 3.75}F{sub 0.5}, having a T{sup {asterisk}}- related structure, and La{sub 1.85}Sr{sub 1.15}Cu{sub 2}O{sub 6.25}, having a structure related to that of the newly discovered double-layer superconductor La{sub 2-x}Sr{sub x}CaCu{sub 2}O{sub 6}. The role played by oxygen defects in determining the superconducting properties of layered cuprates is discussed.

  14. Molecular modeling of slip supposed to occur in the shock initiation of crystalline PETN

    SciTech Connect (OSTI)

    Ritchie, J.P.

    1992-12-01

    Some molecular modeling of slip using both rigid and flexible molecules of PETN in perfect, but finite, lattices has been performed. Results show that it is likely that molecular deformations occur and have an important effect in determining the shear strength.

  15. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Radoslav Adzic Co-workers: Jia Wang, Miomir Vukmirovic, Kotaro Sasaki, Stoyan Bliznakov, Yun Cai, Yu Zhang, Kurian Kuttiyiel, Kuanping Gong, YongMan Choi, Ping Liu, Hideo Naohara 1 Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973 1 Toyota Motor Corporation, Susono, Japan Webinar June 19, 2012 Outline - Introduction on fuel cells, electrocatalysis, existing developments and remaining obstacles to

  16. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S.; Kulik, C.J.

    1994-12-31

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  17. Impact of interstitial oxygen on the electronic and magnetic...

    Office of Scientific and Technical Information (OSTI)

    interstitial oxygen on the electronic and magnetic structure in superconducting Fe 1 + y Te O x thin films Citation Details In-Document Search Title: Impact of interstitial oxygen...

  18. Oxygen Catalysis: The Other Half of the Equation

    SciTech Connect (OSTI)

    Turner, J.

    2008-10-01

    Artificial photosynthesis--splitting water with light--is an attractive way to make hydrogen, but what happens to the oxygen? A catalyst that aids in the efficient production of gaseous oxygen improves the viability of this approach.

  19. Revision Policy for EIA Weekly Underground Natural Gas Storage Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Revision Policy for EIA Weekly Underground Natural Gas Storage Estimates Latest Update: November 16, 2015 This report consists of the following sections: General EIA Weekly Natural Gas Storage Report Revisions Policy - a description of how revisions to the Weekly Natural Gas Storage Report estimates may occur EIA Weekly Natural Gas Storage Report Policy to Allow Unscheduled Release of Revisions - a description of the policy that will be implemented in the event of an out-of-cycle release

  20. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 13159553.pdf (405 KB) Technology Marketing Summary This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen

  1. Oxygen-Enriched Combustion for Military Diesel Engine Generators |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Oxygen-Enriched Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion PDF icon deer09_yelvington.pdf More Documents & Publications Development Methodology for Power-Dense Military Diesel Engine Oxygen-Enriched Combustion Emission Control Strategy for Downsized Light-Duty Diesels

  2. EIA - Natural Gas Pipeline Network - Natural Gas Transmission...

    U.S. Energy Information Administration (EIA) Indexed Site

    Transmission Path Diagram About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Natural Gas Transmission Path Natural...

  3. Natural gas-assisted steam electrolyzer

    DOE Patents [OSTI]

    Pham, Ai-Quoc (San Jose, CA); Wallman, P. Henrik (Berkeley, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01

    An efficient method of producing hydrogen by high temperature steam electrolysis that will lower the electricity consumption to an estimated 65 percent lower than has been achievable with previous steam electrolyzer systems. This is accomplished with a natural gas-assisted steam electrolyzer, which significantly reduces the electricity consumption. Since this natural gas-assisted steam electrolyzer replaces one unit of electrical energy by one unit of energy content in natural gas at one-quarter the cost, the hydrogen production cost will be significantly reduced. Also, it is possible to vary the ratio between the electricity and the natural gas supplied to the system in response to fluctuations in relative prices for these two energy sources. In one approach an appropriate catalyst on the anode side of the electrolyzer will promote the partial oxidation of natural gas to CO and hydrogen, called Syn-Gas, and the CO can also be shifted to CO.sub.2 to give additional hydrogen. In another approach the natural gas is used in the anode side of the electrolyzer to burn out the oxygen resulting from electrolysis, thus reducing or eliminating the potential difference across the electrolyzer membrane.

  4. Carbonyl sulfide hydrolysis in natural gas

    SciTech Connect (OSTI)

    Russo, F.; Caribotti, P.; Garofalo, N.

    1988-01-01

    Carbonyl sulfide may naturally occur in high H/sub 2/S - CO/sub 2/ content sour natural gases. Furthermore part of the H/sub 2/S present in natural gases may be converted into COS if molecular sieves are used as H/sub 2/S removal substances in natural gas desulphurization plants. Carbonyl sulfide might then hydrolize to H/sub 2/S in the gas storage fields and transmission lines. This paper illustrates experimental data relevant to the kinetics and thermodynamics of the reaction between carbonyl sulfide and water both at gas and gas/liquid phases. Results may suggest whether carbonyl sulfide should be included in natural gas quality specifications.

  5. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore » a new strategy of developing the catalyst for oxygen evolution reaction.« less

  6. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  7. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  8. Cathode architectures for alkali metal / oxygen batteries

    DOE Patents [OSTI]

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  9. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    by 14.4 percent. During this period, U.S. manufacturers used less petroleum and coal in manufacturing processes. This expansion of gas use occurred although natural gas prices to...

  10. Global Natural Gas Market Trends, 2. edition

    SciTech Connect (OSTI)

    2007-07-15

    The report provides an overview of major trends occurring in the natural gas industry and includes a concise look at the drivers behind recent rapid growth in gas usage and the challenges faced in meeting that growth. Topics covered include: an overview of Natural Gas including its history, the current market environment, and its future market potential; an analysis of the overarching trends that are driving a need for change in the Natural Gas industry; a description of new technologies being developed to increase production of Natural Gas; an evaluation of the potential of unconventional Natural Gas sources to supply the market; a review of new transportation methods to get Natural Gas from producing to consuming countries; a description of new storage technologies to support the increasing demand for peak gas; an analysis of the coming changes in global Natural Gas flows; an evaluation of new applications for Natural Gas and their impact on market sectors; and, an overview of Natural Gas trading concepts and recent changes in financial markets.

  11. Synergetic effects of mixed copper-iron oxides oxygen carriers in chemical looping combustion

    SciTech Connect (OSTI)

    Siriwardane, Ranjani; Tian, Hanjing; Simonyi, Thomas; Poston, James

    2013-06-01

    Chemical looping combustion (CLC) is an emerging technology for clean energy production from fuels. CLC produces sequestration-ready CO{sub 2}-streams without a significant energy penalty. Development of efficient oxygen carriers is essential to successfully operate a CLC system. Copper and iron oxides are promising candidates for CLC. Copper oxide possesses high reactivity but it has issues with particle agglomeration due to its low melting point. Even though iron oxide is an inexpensive oxygen carrier it has a slower reactivity. In this study, mixed metal oxide carriers containing iron and copper oxides were evaluated for coal and methane CLC. The components of CuO and Fe{sub 2}O{sub 3} were optimized to obtain good reactivity while maintaining physical and chemical stability during cyclic reactions for methane-CLC and solid-fuel CLC. Compared with single metal oxygen carriers, the optimized Cu–Fe mixed oxide oxygen carriers demonstrated high reaction rate, better combustion conversion, greater oxygen usage and improved physical stability. Thermodynamic calculations, XRD, TGA, flow reactor studies and TPR experiments suggested that there is a strong interaction between CuO and Fe{sub 2}O{sub 3} contributing to a synergistic effect during CLC reactions. The amount of oxygen release of the mixed oxide carrier in the absence of a fuel was similar to that of the single metal oxides. However, in the presence of fuels, the oxygen consumption and the reaction profiles of the mixed oxide carriers were significantly better than that of the single metal oxides. The nature of the fuel not only influenced the reactivity, but also the final reduction status of the oxygen carriers during chemical looping combustion. Cu oxide of the mixed oxide was fully reduced metallic copper with both coal and methane. Fe oxide of the mixed oxide was fully reduced Fe metal with methane but it was reduced to only FeO with coal. Possible mechanisms of how the presence of CuO enhances the reduction of Fe{sub 2}O{sub 3} are discussed.

  12. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D. Noble, J.

    2009-10-01

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  13. EIA - Natural Gas Publications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    these data from 2005 to 2009 are presented for each State. (12282010) U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves: 2009 National and State...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    York Mercantile Exchange (NYMEX), the August 2011 natural gas contract price also lost ground over the week, closing at 4.217 per MMBtu on Wednesday. The natural gas rotary rig...

  15. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    York Mercantile Exchange (NYMEX), the August 2011 natural gas contract price also lost ground over the week, closing at 4.315 per MMBtu on Wednesday. The natural gas rotary rig...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas into storage. However, shut-in natural gas production in the Gulf of Mexico reduced available current supplies, and so limited net injections during the report...

  17. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    a high degree of price volatility seems inherent in natural gas markets because of the nature of the commodity. However, the annual volatility during 1994 and 2006 does not exhibit...

  18. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    heating-related demand for natural gas that limited the size of the net addition to storage. The economic incentives for storing natural gas for next winter are considerably...

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    The report provides an overview of U.S. international trade in 2008 as well as historical data on natural gas imports and exports. Net natural gas imports accounted for only 13...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    next heating season. Net injections reported in today's release of EIA's Weekly Natural Gas Storage Report brought natural gas storage supplies to 2,163 Bcf as of Friday, June 1,...

  1. Natural gas annual 1996

    SciTech Connect (OSTI)

    1997-09-01

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  2. Natural Phenomena Hazards Program

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) Natural Phenomena Hazards Program develops and maintains state-of-the-art program standards and guidance for DOE facilities exposed to natural phenomena hazards (NPHs).

  3. Natural gas annual 1995

    SciTech Connect (OSTI)

    1996-11-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels | Prices | States | International | Country Analysis...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Independence Avenue, SW Washington, DC 20585 . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels |...

  6. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  7. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2002-07-01

    Mixed-conducting ceramics have the ability to conduct oxygen with perfect selectivity at elevated temperatures, making them extremely attractive as membrane materials for oxygen separation and membrane reactor applications. While the conductivity of these materials can be quite high at elevated temperatures (typically 800-1000 C), much higher oxygen fluxes, or, alternatively, equivalent fluxes at lower temperatures, could be provided by supported thin or thick film membrane layers. Based on that motivation, the objective of this project was to explore the use of ultrafine aerosol-derived powder of a mixed-conducting ceramic material for fabrication of supported thick-film dense membranes. The project focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} (SCFO) because of the desirable permeability and stability of that material, as reported in the literature. Appropriate conditions to produce the submicron SrCo{sub 0.5}FeO{sub x} powder using aerosol pyrolysis were determined. Porous supports of the same composition were produced by partial sintering of a commercially obtained powder that possessed significantly larger particle size than the aerosol-derived powder. The effects of sintering conditions (temperature, atmosphere) on the porosity and microstructure of the porous discs were studied, and a standard support fabrication procedure was adopted. Subsequently, a variety of paste and slurry formulations were explored utilizing the aerosol-derived SCFO powder. These formulations were applied to the porous SCFO support by a doctor blade or spin coating procedure. Sintering of the supported membrane layer was then conducted, and additional layers were deposited and sintered in some cases. The primary characterization methods were X-ray diffraction and scanning electron microscopy, and room-temperature nitrogen permeation was used to assess defect status of the membranes.We found that non-aqueous paste/slurry formulations incorporating dispersant, plasticizer and binder provided superior cracking resistance compared to simple water, alcohol, or polyethylene glycol (PEG) based formulations. With a formulation employing castor oil as dispersant, isopropyl alcohol/mineral spirits as solvent, polyvinyl butyral as binder, and dibutyl phthalate/PEG as plasticizer, sintered SCFO membrane layers approximately 5 {micro}m thick with no apparent cracks were prepared using spin coating with several coats and sintering cycles. A similar but more viscous formulation applied by doctor blade gave a {approx} 10 {micro}m thick membrane layer in one coat, but with some apparent cracking. We demonstrated that the membrane layer could be densified while retaining porosity in the chemically identical support. This was accomplished by pre-sintering the support in air (1050 C), which coarsened the grain size and provided a relatively stable plate-shaped granular microstructure, followed by membrane layer fabrication with the highly-sinterable aerosol powder. Final densification was conducted by sintering in nitrogen ({approx}1100 C), which provided accelerated sintering rates and led to the desired layered perovskite phase content. In spite of these successes, low-temperature pressure-driven permeation testing with N2 showed that even the best membranes were not sufficiently defect free for high-temperature oxygen permeation testing. The source of these defects were not readily apparent from scanning electron microscopy, though incomplete or nonuniform membrane layer coverage from edge to edge of the support was probably one important factor.

  8. Preliminary Study of Oxygen-Enhanced Longitudinal Relaxation in MRI: A Potential Novel Biomarker of Oxygenation Changes in Solid Tumors

    SciTech Connect (OSTI)

    O'Connor, James P.B.; Naish, Josephine H.; Parker, Geoff J.M.; Waterton, John C.; Watson, Yvonne; Jayson, Gordon C.; Buonaccorsi, Giovanni A.; Cheung, Sue; Buckley, David L.; McGrath, Deirdre M.; West, Catharine M.L.; Davidson, Susan E.; Roberts, Caleb; Mills, Samantha J.; Mitchell, Claire L.; Hope, Lynn; Ton, N. Chan; Jackson, Alan

    2009-11-15

    Purpose: There is considerable interest in developing non-invasive methods of mapping tumor hypoxia. Changes in tissue oxygen concentration produce proportional changes in the magnetic resonance imaging (MRI) longitudinal relaxation rate (R{sub 1}). This technique has been used previously to evaluate oxygen delivery to healthy tissues and is distinct from blood oxygenation level-dependent (BOLD) imaging. Here we report application of this method to detect alteration in tumor oxygenation status. Methods and materials: Ten patients with advanced cancer of the abdomen and pelvis underwent serial measurement of tumor R{sub 1} while breathing medical air (21% oxygen) followed by 100% oxygen (oxygen-enhanced MRI). Gadolinium-based dynamic contrast-enhanced MRI was then performed to compare the spatial distribution of perfusion with that of oxygen-induced DELTAR{sub 1}. Results: DELTAR{sub 1} showed significant increases of 0.021 to 0.058 s{sup -1} in eight patients with either locally recurrent tumor from cervical and hepatocellular carcinomas or metastases from ovarian and colorectal carcinomas. In general, there was congruency between perfusion and oxygen concentration. However, regional mismatch was observed in some tumor cores. Here, moderate gadolinium uptake (consistent with moderate perfusion) was associated with low area under the DELTAR{sub 1} curve (consistent with minimal increase in oxygen concentration). Conclusions: These results provide evidence that oxygen-enhanced longitudinal relaxation can monitor changes in tumor oxygen concentration. The technique shows promise in identifying hypoxic regions within tumors and may enable spatial mapping of change in tumor oxygen concentration.

  9. Arsenite induces cell transformation by reactive oxygen species, AKT, ERK1/2, and p70S6K1

    SciTech Connect (OSTI)

    Carpenter, Richard L.; Jiang, Yue; Jing, Yi; He, Jun; Rojanasakul, Yon; Liu, Ling-Zhi; Jiang, Bing-Hua

    2011-10-28

    Highlights: Black-Right-Pointing-Pointer Chronic exposure to arsenite induces cell proliferation and transformation. Black-Right-Pointing-Pointer Arsenite-induced transformation increases ROS production and downstream signalings. Black-Right-Pointing-Pointer Inhibition of ROS levels via catalase reduces arsenite-induced cell transformation. Black-Right-Pointing-Pointer Interruption of AKT, ERK, or p70S6K1 inhibits arsenite-induced cell transformation. -- Abstract: Arsenic is naturally occurring element that exists in both organic and inorganic formulations. The inorganic form arsenite has a positive association with development of multiple cancer types. There are significant populations throughout the world with high exposure to arsenite via drinking water. Thus, human exposure to arsenic has become a significant public health problem. Recent evidence suggests that reactive oxygen species (ROS) mediate multiple changes to cell behavior after acute arsenic exposure, including activation of proliferative signaling and angiogenesis. However, the role of ROS in mediating cell transformation by chronic arsenic exposure is unknown. We found that cells chronically exposed to sodium arsenite increased proliferation and gained anchorage-independent growth. This cell transformation phenotype required constitutive activation of AKT, ERK1/2, mTOR, and p70S6K1. We also observed these cells constitutively produce ROS, which was required for the constitutive activation of AKT, ERK1/2, mTOR, and p70S6K1. Suppression of ROS levels by forced expression of catalase also reduced cell proliferation and anchorage-independent growth. These results indicate cell transformation induced by chronic arsenic exposure is mediated by increased cellular levels of ROS, which mediates activation of AKT, ERK1/2, and p70S6K1.

  10. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of molecular oxygen ions in the upper-most atmosphere of Dione. March 3, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics

  11. Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technique | Department of Energy Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Presentation slides from the Fuel Cell Technologies Office webinar, "Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique," held March 12, 2013. Presenters were Shyam S. Kocha, National Renewable Energy Laboratory; Yannick Garsany, Naval Research

  12. Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Elusive Oxygen Isotope Captured with Groundbreaking Sensitivity Oxygen is one of the most ubiquitous elements in chemistry and materials science, yet one of the most elusive elements for spectroscopic investigation by solid-state Nuclear Magnetic Resonance (SSNMR). Used to determine the structure of materials and chemicals on the atomic scale, SSNMR requires nuclei that have magnetic moments. Yet, less than four of every 10,000 oxygen nuclei are 17O, the only NMR-active isotope of

  13. Hybrid System for Separating Oxygen from Air - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Hybrid System for Separating Oxygen from Air Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (765 KB) Technology Marketing Summary Sandia has developed a portable, oxygen generation system capable of delivering oxygen gas at purities greater than 98 percent and flow rates significantly greater than commercially

  14. EIA - Natural Gas Pipeline Network - Combined Natural Gas Transportation

    Gasoline and Diesel Fuel Update (EIA)

    Maps Combined Natural Gas Transportation Maps About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates U.S. Natural Gas Pipeline Network Map of U.S. Natural Gas Pipeline Network Major Natural Gas Supply Basins Relative to Natural Gas Pipeline Transportation Corridors Map of Major Natural Gas Supply Basins Relative to Natural Gas Pipeline Transportation Corridors see related text enlarge see related text enlarge U.S. Regional Breakdown

  15. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock ...

  16. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an ...

  17. Probing oxygen vacancy concentration and homogeneity in solid...

    Office of Scientific and Technical Information (OSTI)

    Here, we develop an approach for direct mapping of oxygen vacancy concentrations based on local lattice parameter measurements by scanning transmission electron microscopy. The ...

  18. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen...

    Energy Savers [EERE]

    Review 2015: Intake Air Oxygen Sensor Vehicle Technologies Office Merit Review 2014: Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  19. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen...

    Energy Savers [EERE]

    Office Merit Review 2014: Intake Air Oxygen Sensor Bosch Powertrain Technologies Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  20. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  1. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  2. Oxidation State and Interfacial Effects on Oxygen Vacancies in...

    Office of Scientific and Technical Information (OSTI)

    Oxygen Vacancies in Tantalum Pentoxide. Abstract not provided. Authors: Bondi, Robert James ; Marinella, Matthew Publication Date: 2014-10-01 OSTI Identifier: 1184499 Report...

  3. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to...

  4. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  5. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  6. EIA - Natural Gas Pipeline Network - Natural Gas Pipeline Mileage...

    U.S. Energy Information Administration (EIA) Indexed Site

    Mileage by State About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Estimated Natural Gas Pipeline Mileage in the...

  7. Oxygen diffusion of anodic surface oxide film on titanium studied by Auger electron spectroscopy. [Oxygen diffusivity

    SciTech Connect (OSTI)

    Wang, P.S.; Wittberg, T.N.; Keil, R.G.

    1982-01-01

    TiO/sub 2/ films of about 1000 A were grown onto titanium foils anodically under galvanostatic conditions at 20 mA/cm/sup 2/ in saturated aqueous solutions of ammonium tetraborate. The samples were then aged at 450, 500, and 550/sup 0/C, and oxygen diffusion was observed by Auger electron spectroscopy (AES) profilings. The oxygen diffusivities were calculated by Fick's Second Law, using the Boltzmann-Matano solution, to be 9.4 x 10/sup -17/, 2.6 x 10/sup -16/, and 1.2 x 10/sup -15/ cm/sup 2//sec at 450, 500, and 550/sup 0/C, respectively. The diffusivities obtained by this method were also compared with those obtained using an exact solution to Fick's Second Law. The activation energy was calculated to be 30 kcal/mole.

  8. Fermentation process using specific oxygen uptake rates as a process control

    DOE Patents [OSTI]

    Van Hoek; Pim (Minnetonka, MN), Aristidou; Aristos (Maple Grove, MN), Rush; Brian (Minneapolis, MN)

    2007-06-19

    Specific oxygen uptake (OUR) is used as a process control parameter in fermentation processes. OUR is determined during at least the production phase of a fermentation process, and process parameters are adjusted to maintain the OUR within desired ranges. The invention is particularly applicable when the fermentation is conducted using a microorganism having a natural PDC pathway that has been disrupted so that it no longer functions. Microorganisms of this sort often produce poorly under strictly anaerobic conditions. Microaeration controlled by monitoring OUR allows the performance of the microorganism to be optimized.

  9. Fermentation process using specific oxygen uptake rates as a process control

    DOE Patents [OSTI]

    Van Hoek, Pim (Minnetonka, MN); Aristidou, Aristos (Maple Grove, MN); Rush, Brian (Minneapolis, MN)

    2011-05-10

    Specific oxygen uptake (OUR) is used as a process control parameter in fermentation processes. OUR is determined during at least the production phase of a fermentation process, and process parameters are adjusted to maintain the OUR within desired ranges. The invention is particularly applicable when the fermentation is conducted using a microorganism having a natural PDC pathway that has been disrupted so that it no longer functions. Microorganisms of this sort often produce poorly under strictly anaerobic conditions. Microaeration controlled by monitoring OUR allows the performance of the microorganism to be optimized.

  10. Fermentation process using specific oxygen uptake rates as a process control

    DOE Patents [OSTI]

    Van Hoek, Pim; Aristidou, Aristos; Rush, Brian

    2014-09-09

    Specific oxygen uptake (OUR) is used as a process control parameter in fermentation processes. OUR is determined during at least the production phase of a fermentation process, and process parameters are adjusted to maintain the OUR within desired ranges. The invention is particularly applicable when the fermentation is conducted using a microorganism having a natural PDC pathway that has been disrupted so that it no longer functions. Microorganisms of this sort often produce poorly under strictly anaerobic conditions. Microaeration controlled by monitoring OUR allows the performance of the microorganism to be optimized.

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    sand with very little natural rock bottom and reef habitat. Without artificial reefs, fish and marine life typically would become widely dispersed. In the Gulf of Mexico...

  12. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  13. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  14. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, July 1, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 23, 2010)...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, September 9, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 1,...

  16. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, January 14, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 6,...

  17. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Next Release: Thursday, November 19, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, November 11,...

  18. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, June 17, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 9, 2010)...

  19. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, August 12, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 4, 2010)...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, September 2, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 25,...

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, August 5, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 28, 2010)...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, May 13, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 5, 2010)...

  3. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2009 Next Release: April 16, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 8, 2009) Since...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2009 Next Release: January 23, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 14, 2009) In...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16, 2009 Next Release: April 23, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 15, 2009) Since...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 to Wednesday, December 12) Released: December 13 Next release: December 20, 2007 Natural gas spot and futures prices increased this report week (Wednesday to Wednesday,...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, April 15, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 7, 2010) Since...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, February 25, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 17, 2010)...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, March 18, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 10, 2010) Since...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, March 24, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 16, 2011) With...

  11. Natural gas annual 1997

    SciTech Connect (OSTI)

    1998-10-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Other Market Trends EIA Proposes Extending Oil and Natural Gas Reserves Survey Forms. The Energy Information Administration (EIA) on July 15 published a notice in the Federal...

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    and October 2010 contracts all fell by less than 1 cent. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas inventories set a new record,...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    recorded last year. Other Market Trends: FERC Releases Report on Underground Natural Gas Storage: The Federal Energy Regulatory Commission (FERC) issued a report last week that...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Estimates Database. Other Market Trends: Comments Received on Proposed Weekly Natural Gas Storage Report Revision Policy: The Energy Information Administration (EIA) solicited...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    compared with its settlement price a week ago, ending yesterday at 5.974 per MMBtu. The Energy Information Administration (EIA) reported that natural gas inventories in...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    storage facilities. Other Market Trends: EIA Releases Report on Underground Natural Gas Storage Developments: The Energy Information Administration (EIA) released a special...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    , 2009 Next Release: July 9, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 2, 2009) Since...

  20. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6, 2008 Next Release: November 14, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, November 5) Since...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    0, 2009 Next Release: August 6, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 29, 2009) Since...

  2. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    7, 2008 Next Release: July 24, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview The report week ended July 16 registered significant...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Inventory of Onshore Federal Lands' Oil and Gas Resources and the Extent and Nature of Restrictions or Impediments to Their Development. The report, which was...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Accounting Standards Board. The changes will allow FERC an understanding of the nature and extent to which hedging activities are used by electric utilities and gas...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    storm activity has been above average this year, there has been little impact on natural gas markets. Tropical Depression 6 showed up in the eastern Caribbean early this...

  6. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2008 Next Release: December 11, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, December 3, 2008) Since...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2009 Next Release: March 26, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 18, 2009) Warmer...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    P.M. Next Release: October 29, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 21, 2009) Since...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2008 Next Release: October 2, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (Wednesday, September 17, to Wednesday, September 24)...

  10. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, January 20, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 12, 2011)...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    with hopes for the eventual return of winter was likely the catalyst enabling natural gas prices to recapture the 4 mark this week despite an environment of negative...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Thursday, September 16, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 8, 2010) Price...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thursday, September 23, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 15, 2010)...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Next Release: Thursday, May 12, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 4, 2011) Wholesale...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    which summarizes the likely demand, supply, and prices for natural gas, heating oil, propane, and electricity during the upcoming winter (October 2004 - March 2005). According to...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Storage Estimates Database. Other Market Trends: EIA Releases New Report on the Fundamentals of Natural Gas Storage: EIA prepared a new report to provide general background...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Significant New Deepwater Oil and Natural Gas Discovery: A successful production test in the deepwater Gulf of Mexico has confirmed a significant new oil play in the lower...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    average, the general price level in the natural gas market has shown surprising resilience over the past few weeks. After an extended price decline since mid December, spot...

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, January 7, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 16, 2009)...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: November 5, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 28, 2009)...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, March 4, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 24, 2010)...

  2. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, January 6, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 15, 2010)...

  3. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the technology that drove Enron's North American wholesale electricity and natural gas trading unit. That technology, together with reportedly over 600 former Enron...

  4. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    , 2009 Next Release: April 9, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 1, 2009) Despite a...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2009 Next Release: February 19, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 11, 2009)...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, November 4, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 27, 2010) As the...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: November 20, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (Wednesday, November 5, to Thursday, November 13)...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, October 28, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 20, 2010)...

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 3, 2008) Released: January 4, 2008 Next release: January 10, 2008 Natural gas spot and futures prices increased this report week (Wednesday to Thursday, December 26,...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Wednesday, November 10, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, November 3, 2010) Price...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, August 19, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 11, 2010) Summer...

  12. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: October 23, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For week ending Wednesday, October 15) Since Wednesday,...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, February 3, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 26, 2011)...

  14. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    requested by Secretary of Energy Spencer Abraham in an effort to enhance natural gas market information and efficiency. Survey respondents would include all operators of...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, December 16, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 8, 2010) In...

  16. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prices using spot prices from producing areas, plus an allowance for interstate natural gas pipeline and local distribution company charges to transport the gas to market. Such a...

  17. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    Historical Natural Gas Annual . 1996 Published October 1997 1997 Published October 1998 1998 Published October 1999 1999 Published October 2000 2000 Published December 2001

  18. Natural Resources Specialist

    Broader source: Energy.gov [DOE]

    (See Frequently Asked Questions for more information). Where would I be working? Western Area Power Administration, Corporate Services Office, Office of the Chief Operating Officer, Natural...

  19. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the New York Mercantile Exchange (NYMEX), futures prices also increased this week in tandem with the crude oil prices. The natural gas futures contract for delivery in June...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 7, 2009) Since Wednesday, December...

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 12, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Spot gas at most market locations (outside the Rocky Mountain Region) traded...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    March 12, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 4, 2009) A late winter cold spell in...

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    data to EIA. The number of companies reporting increased by 3 from 2008, to include Alon USA, Chalmette Refining LLC, and Western Refining, Inc. Natural Gas Transportation Update...

  4. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    As of February 14, Northern Natural Gas implemented a system overrun limitation (SOL) affecting all market area zones. These zones are located in the northern part of the...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Upward pressure on prices at the NYMEX also appears related to concerns over events in Japan that could affect energy markets. Japan, the worlds largest liquefied natural gas...

  6. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Historical Natural Gas Annual . 1996 Published October 1997 1997 Published October 1998 1998 Published October 1999 1999 Published October 2000 2000 Published December 2001

  7. LCO Nature | Open Energy Information

    Open Energy Info (EERE)

    LCO Nature Jump to: navigation, search Name: LCO Nature Place: Germany Sector: Renewable Energy Product: Based in Hamburg, LCO Nature is a consultancy and renewable energy project...

  8. Easy natur | Open Energy Information

    Open Energy Info (EERE)

    natur Jump to: navigation, search Name: Easy-natur Place: Germany Sector: Buildings Product: Installs PV systems on residential buildings. References: Easy-natur1 This article is...

  9. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M.; Romanov, Vyacheslav N.; Cygan, Randall Timothy

    2010-11-01

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  10. Vermont Agency of Natural Resources Natural Resources Atlas ...

    Open Energy Info (EERE)

    Vermont Agency of Natural Resources Natural Resources Atlas Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Vermont Agency of Natural Resources Natural...

  11. EIA - Natural Gas Pipeline Network - Natural Gas Supply Basins...

    U.S. Energy Information Administration (EIA) Indexed Site

    Corridors About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates U.S. Natural Gas Supply Basins Relative to Major Natural...

  12. Learning How Nature Uses Sunlight to Split Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mn4Ca Structure. (click on image for diagram portraying the water-splitting catalytic cycle) Scientific Highlight LBNL Press Release Physical Biosciences, LBNL 30 November 2006 Learning How Nature Splits Water (Condensed by Brad Plummer from a press release issued by Lawrence Berkeley National Laboratory) Billions of years ago, primitive bacteria developed a way to harness sunlight to split water molecules into protons, electrons and oxygen-the cornerstone of photosynthesis. Now, a team of

  13. Effects of oxygen and catalyst on tetraphenylborate decomposition rate

    SciTech Connect (OSTI)

    Walker, D.D.

    1999-12-15

    Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.

  14. Low NOx combustion using cogenerated oxygen and nitrogen streams

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, Lawrence E. (East Aurora, NY); Snyder, William J. (Ossining, NY)

    2009-02-03

    Combustion of hydrocarbon fuel is achieved with less formation of NOx by feeding the fuel into a slightly oxygen-enriched atmosphere, and separating air into oxygen-rich and nitrogen-rich streams which are fed separately into the combustion device.

  15. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Huang, Tao (Manorville, NY)

    2009-12-15

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  16. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T. (Atlanta, GA); Breitkopf, Richard C. (Dunwoody, GA)

    2009-12-01

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  17. Willamette Oxygen Supplementation Studies : Annual Report 1994.

    SciTech Connect (OSTI)

    Ewing, R.D.; Ewing, S.K.; Sheahan, J.E.

    1994-09-01

    Hydropower development and operations in the Columbia River basin have caused the loss of 5 million to 11 million salmonids. An interim goal of the Northwest Power Planning Council is to reestablish these historical numbers by doubling the present runs from 2.5 million adult fish to 5.0 million adult fish. This increase in production will be accomplished through comprehensive management of both wild and hatchery fish, but artificial propagation will play a major role in the augmentation process. The current husbandry techniques in existing hatcheries require improvements that may include changes in rearing densities, addition of oxygen, removal of excess nitrogen, and improvement in raceway design. Emphasis will be placed on the ability to increase the number of fish released from hatcheries that survive to return as adults. Rearing density is one of the most important elements in fish culture. Fish culturists have attempted to rear fish in hatchery ponds at densities that most efficiently use the rearing space available. Such efficiency studies require a knowledge of cost of rearing and the return of adults to the fisheries and to the hatchery.

  18. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.; Gardner, D.; Hayden, M.; Radebaugh, R.; Wollan, J.

    1996-07-01

    This is the final report of a two-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project sought to develop a natural-gas-powered natural-gas liquefier that has absolutely no moving parts and requires no electrical power. It should have high efficiency, remarkable reliability, and low cost. The thermoacoustic natural-gas liquefier (TANGL) is based on our recent invention of the first no-moving-parts cryogenic refrigerator. In short, our invention uses acoustic phenomena to produce refrigeration from heat, with no moving parts. The required apparatus comprises nothing more than heat exchangers and pipes, made of common materials, without exacting tolerances. Its initial experimental success in a small size lead us to propose a more ambitious application: large-energy liquefaction of natural gas, using combustion of natural gas as the energy source. TANGL was designed to be maintenance-free, inexpensive, portable, and environmentally benign.

  19. Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics

    SciTech Connect (OSTI)

    Kamil Klier; Richard G. Herman

    2005-11-30

    This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Br�������¸nsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

  20. NATURAL CONVECTION IN ROOM GEOMETRIES

    SciTech Connect (OSTI)

    Gadgil, A.; Bauman, Fred; Kammerud, R.; Ruberg, K.

    1980-06-01

    Computer programs have been developed to numerically simulate natural convection in room geometries in two and three dimensions. The programs have been validated using published data from the literature, results from a full-scale experiment performed at Massachusetts Institute of Technology, and results from a small-scale experiment reported here. One of the computer programs has been used to study the influence of natural convection on the thermal performance of a single thermal zone in a direct-gain passive solar building. The results indicate that the building heating loads calculated by standard building energy analysis methods may be in error by as much as 50% as a result of their use of common assumptions regarding the convection processes which occur in an enclosure. It is also found that the convective heat transfer coefficients between the air and the enclosure surfaces can be substantially different from the values assumed in the standard building energy analysis methods, and can exhibit significant variations across a given surface.

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with the largest decreases generally occurring in the western half of the country. The Henry Hub spot price decreased by 0.34 to 3.02 per million Btu (MMBtu). At the New York...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    at 2.35-20 cents higher than the previous Friday. This increase occurred as market fundamentals were generally unchanged last week with continued weakness in weather-related...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    increase in the Lower 48 States since last Wednesday occurred at the Southern California Border market, where relatively warm weather resulted in a price increase of 71 cents per...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    were slightly less and scattered price increases even occurred. With the continuing transition to spring-like weather, consumption was limited to an average of about 58.2 Bcf per...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be taking advantage of the reduction in demand that typically occurs in April, the first shoulder month of the year, and the recent price declines. After beginning the week down,...

  6. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 ?g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  7. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Natural gas stocks stood at 2,155 Bcf as of Friday, July 9,...

  8. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Friday was undone the following day. The futures price for August delivery was able to stay ahead of the previous week by 12.2 cents to settle at 3.218 on Friday. Spot natural...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    levels and 25 percent below the 5-year average. Natural gas prices are likely to stay high as long as above-normal storage injection demand competes with industrial and...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    regions of the country and weather forecasts indicated colder temperatures are here to stay until at least the end of the month. Natural gas in storage declined to 2,195 Bcf with...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this week led to decreases in consumption of natural gas for power generation. Power burn fell almost 4 percent week over week, according to data from Bentek Energy Services,...

  12. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    reverse direction and fall to 3.91 per MMBtu yesterday. Natural gas demand for power burn increased across the country during the report week. According to data from BENTEK...

  13. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    In contrast to natural gas spot prices, crude oil prices continued to soften. After dropping over 1 per barrel the previous week, the average spot price for West Texas...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    that likely contributed to the run-up in natural gas prices late last week was the spike in crude oil prices as WTI crude oil surged 2.70 per barrel to average 30.10 per...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 (next release 2:00 p.m. on December 16) Both natural gas spot and futures prices fell significantly over the week (Wednesday to Wednesday, December 1-8), as temperatures in most...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    withdrawal from working gas storage reported last Thursday. A contributing factor to the run-up in natural gas prices could be climbing crude oil prices, which rallied late last...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monday, December 29 (next release 2:00 p.m. on January 8) A trend of increasing natural gas spot prices since mid-November abruptly halted late in the week before Christmas, owing...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    part of a 65 billion project to supply the United States with oil, natural gas, and electricity from Siberia. The tunnel, which would be the world's longest, would take 10 to 15...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Holiday Notice: Due to the federal holiday in observance of Martin Luther King Day on Monday, January 21, 2002, the next issue of the Natural Gas Weekly Update will be published on...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Although prices in the West were generally lower on the week by a dime or less, a turbine outage on El Paso Natural Gas in the San Juan Basin boosted prices temporarily. El...

  1. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    at 2:00 P.M. Next Release: October 8, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 30,...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8, 2007 (next release 2:00 p.m. on November 15, 2007) Natural gas spot price movements varied this week (Wednesday-Wednesday, October 31-November 7). Prices in Lower 48 market...

  3. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5) Released: March 6, 2008 Next release: March 13, 2008 Since Wednesday, February 27, natural gas prices increased on both the spot and futures markets. There were a few...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    natural gas spot prices fell at most market locations in the Lower 48 States, with the Henry Hub spot price falling to 3.56 per million Btu (MMBtu), about a 7 percent decline...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    week's gas markets. As of Friday, May 11, 2001, the spot price of natural gas at the Henry Hub dropped 0.24 from the previous Friday to 4.25 per MMBtu. The NYMEX price of...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prices have generally decreased for the week (Wednesday-Wednesday, February 2-9). The Henry Hub natural gas spot price fell 18 cents, or about 3 percent, while prices at most...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    7, 2010 at 2:00 P.M. Next Release: Thursday, October 14, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday,...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    4, 2010 at 2:00 P.M. Next Release: Thursday, October 21, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday,...

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What Consumers Should Know An Assessment of Prices of Natural Gas Futures Contracts As A Predictor of Realized Spot Prices at the Henry Hub Overview of U.S. Legislation and...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    8, 2007 (next release 2:00 p.m. on October 25, 2007) Natural gas spot prices increased since Wednesday, October 10, at nearly all market locations. For the week (Wednesday to...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Leasing. The U. S. Department of the Interior's Minerals Management Service (MMS) held a sale of offshore oil and natural gas leases in the Central Gulf of Mexico on March 20,...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    the lease sale could result in the recovery of between 276 and 654 million barrels of oil and from 1.59 to 3.30 trillion cubic feet of natural gas. Sale 197 in the Eastern Gulf...

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of Mexico continued to recover from the hurricane damage suffered in 2005. The Minerals Management Service (MMS) reported that shut-in natural gas production fell to 1.95 Bcf per...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    12), shut-in natural gas production exceeded 2.3 Bcf per day, as reported by the Minerals Management Service (MMS). Cumulative "lost" production since late August is 526.2 Bcf,...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    over the period covered by this report (September 28 to October 5). The Minerals Management Service (MMS) reported that as of Wednesday, October 5, shut-in natural gas...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    or 9 percent to 4.68 per MMBtu. Lighter cooling demand for natural gas owing to the Labor Day holiday weekend and milder temperatures east of the Rockies likely contributed...

  17. Natural gas monthly

    SciTech Connect (OSTI)

    1996-05-01

    This document highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Data presented include volume and price, production, consumption, underground storage, and interstate pipeline activities.

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    per MMBtu, falling 23 cents or 3 percent since Wednesday, December 12. Natural gas in storage was 3,173 billion cubic feet (Bcf) as of December 14, which is 9 percent above the...

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    a decrease of about 0.36, or 6.9 percent, since last Wednesday. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas in storage totaled 2,213 Bcf as...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    237 Producing Region 609 424 44% 10 599 Total Lower 48 1,594 1,250 28% 39 1,555 Source: Energy Information Administration: Form EIA-912, "Weekly Underground Natural Gas Storage...

  1. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Producing Region 779 755 24 788 -1.1% Total Lower 48 2,863 2,788 75 2,900 -1.3% Source: Energy Information Administration: Form EIA-912, "Weekly Underground Natural Gas Storage...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of natural gas into storage, despite robust inventories. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage increased to 3,258 Bcf as of...

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    5.06 per MMBtu, a decrease of only 0.01 per MMBtu on the week. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas in storage increased to 2,762...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    to withdraw natural gas from storage to meet current demand. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage decreased to 2,406 Bcf as of...

  5. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    167 Producing Region 206 416 -50.5% -2 208 Total Lower 48 671 1,200 -44.1% -9 680 Source: Energy Information Administration: Form EIA-912, "Weekly Underground Natural Gas Storage...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    decreasing about 0.23, or 4.4 percent, since last Wednesday. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas in storage increased to 2,840...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    MMBtu lower than the final price of the November 2009 contract. Wellhead Prices Annual Energy Review More Price Data Storage As of Friday, September 24, working natural gas in...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    fell 31 cents, from 5.554 last Wednesday to 5.239 yesterday. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas in storage increased to 2,165...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Working gas in storage was 3,121 Bcf as of Friday, Oct 24, 2003, according to the Energy Information Administration (EIA) Weekly Natural Gas Storage Report. This is 2.7...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Region 291 458 -36.5% -42 333 Total Lower 48 1,014 1,522 33.4% -154 1,168 Source: Energy Information Administration: Form EIA-912, "Weekly Underground Natural Gas Storage...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Region 751 772 -2.7% -43 794 Total Lower 48 2,794 2,876 -2.9% -162 2,956 Source: Energy Information Administration: Form EIA-912, "Weekly Underground Natural Gas Storage...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    8 284 Producing Region 714 515 39% 15 699 Total Lower 48 1,974 1,650 20% 81 1,893 Source: Energy Information Administration: Form EIA-912, "Weekly Underground Natural Gas Storage...

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Henry Hub increased a moderate 0.023 per MMBtu for the week to 3.877. Natural gas in storage decreased to 3,097 Bcf, which exceeds the 5-year average by 2.4 percent. A general...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    intraday trading at more than 110 per barrel) likely provided upward pressure on all energy commodities. The largest daily natural gas price increase of the week (0.25 per...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2, 2010 at 2:00 P.M. Next Release: Thursday, April 29, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday,...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    73 cents since last Wednesday to close yesterday at 4.201 per MMBtu. Natural gas in storage as of Friday, September 22, was 3,254 Bcf, which is 12.2 percent above the 5-year...

  17. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2010 at 2:00 P.M. Next Release: Thursday, May 6, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday,...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    3, 2011 at 2:00 P.M. Next Release: Thursday, February 10, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    gas in combination with water. Gas hydrate is thought to exist in great abundance in nature and has the potential to be a significant new energy source to meet future energy...

  20. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    18 (next release 2:00 p.m. on August 25) Since Wednesday, August 10, natural gas spot prices increased more than 50 cents per MMBtu at virtually all market locations in the Lower...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    26 (next release 2:00 p.m. on November 2, 2006) Since Wednesday, October 18, natural gas spot prices increased significantly at all market locations, as colder weather moved across...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the price response was more robust (up 4.4 percent) with the August 2011 natural gas contract price gaining ground over the week, closing at 4.403 per MMBtu on Wednesday....

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    August 5 (next release 2:00 p.m. on August 12) Since Wednesday, July 28, natural gas spot prices have decreased at most market locations in the Lower 48 States. For the week...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    last Wednesday's level, to 5.097 per MMBtu at yesterday's close of trading. Natural gas stocks as of Friday, March 21 stood at 643 Bcf, which is 47.4 percent less than the...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    spike on Tuesday following the East Coast earthquake but the September 2011 natural gas contract eventually gave most of the gain back and closed at 3.922 per MMBtu on...

  6. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    7 (next release 2:00 p.m. on November 3) Natural gas spot prices increased sharply this week (Wednesday-Wednesday, October 19-26), as a large volume of production continued to be...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    delivery fell 29 cents on the week to close at 5.429 yesterday (March 24). Natural gas in storage as of Friday, March 19, decreased to 1,032 Bcf, which is 8.2 percent below...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Ending Wednesday, October 5, 2011) Like autumn leaves floating down to earth, natural gas prices dropped decidedly from their 4 support branch this past week. In a whirlwind of...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    August 3 (next release 2:00 p.m. on August 10, 2006) Natural gas spot prices increased sharply this week (Wednesday-Wednesday, July 26 - August 2), as demand for power generation...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    April 22, 2004 (next release 2:00 p.m. on April 29) Since Wednesday, April 14, natural gas spot prices have decreased at virtually all market locations in the Lower 48 States. For...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (MMBtu) on October 26. At the New York Mercantile Exchange (NYMEX), the November 2011 natural gas contract rose just under half a cent per MMBtu for the week to close at 3.590...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    21 (next release 2:00 p.m. on July 28) Since Wednesday, July 13, changes to natural gas spot prices were mixed, increasing at most market locations in the Lower 48 States, while...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    response was somewhat more pronounced (down 5.3 percent) with the September 2011 natural gas contract losing ground over the week, closing at 4.090 per MMBtu on Wednesday. Working...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    the holiday-shortened week, falling crude oil prices, and a favorable supply situation led to widespread declines in natural gas spot prices in the Lower 48 States since last...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on Thursday, May 9, 2002. A sample of EIA's report can be seen at: Weekly Gas Storage Test Page. The Natural Gas Weekly Market Update report will convert to the new data series...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    in waters up to 9000 feet deep. Southern Natural Gas Company has scheduled a shut-in test at the Muldon Storage Field in Mississippi for April 5 through April 11. Under the...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    further downward pressure on spot prices. As of yesterday, October 1, the Minerals Management Service (MMS) reported that 3.5 billion cubic feet (Bcf) per day of natural gas...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Trends Natural Gas and Crude Oil Production Shut-ins in the Gulf of Mexico. The Minerals Management Service (MMS) of the Department of the Interior reported that a significant...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of 1 Tcf from the 1994 estimate of 51 Tcf. Ultimate potential for natural gas is a science-based estimate of the total amount of conventional gas in the province and is an...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    July 28 (next release 2:00 p.m. on August 4) Since Wednesday, July 20, natural gas spot prices have decreased at all market locations in the Lower 48 States. For the week...

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 1 (next release 2:00 p.m. on June 8, 2006) Natural gas spot prices were virtually unchanged at most market locations in the Lower 48 States during the holiday-shortened...

  2. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    1 (next release 2:00 p.m. on October 28) Increased natural gas demand owing to falling temperatures this week (Wednesday-Wednesday, October 13-20) combined with higher petroleum...

  3. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 (next release 2:00 p.m. on August 18) Natural gas spot prices exhibited increases in most locations this week (Wednesday - Wednesday, August 3 - 10) as demand responded to above...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Spring-like temperatures in most regions of the country this week led to lower natural gas spot and futures prices in the Lower 48 States since Wednesday, March 7. On the week...

  5. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    10 (next release 2:00 p.m. on March 17) Natural gas spot prices increased this week (Wednesday to Wednesday, March 2-9) as a late season cold front moved into major gas-consuming...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the week. Nearly 75 percent of this increase (0.282) came in Monday's trading. Natural gas in storage as of Friday, November 15 decreased by 1 Bcf to 3,096 Bcf, which exceeds the...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    26, 2007 (next release 2:00 p.m. on August 2, 2007) Since Wednesday, July 18, natural gas spot prices have decreased at all market locations in the Lower 48 States, with the...

  8. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (next release 2:00 p.m. on February 10) Since Wednesday, January 26, natural gas spot price movements have been mixed, increasing at most market locations in the Lower 48 States...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    (April 11). The first weekly report of the traditional injection season brought natural gas volumes in underground storage to 1,592 Bcf as of Friday, April 6, which is 28.4...

  10. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 2003 (next release 2:00 p.m. on May 29) Natural gas spot prices at most market locations in the Lower 48 States have dipped 5 to 20 cents per MMBtu since Wednesday, May 14....

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 (next release 2:00 p.m. on November 30, 2006) Changes in natural gas spot prices were modest at most trading locations in the Lower 48 States this week (Wednesday-Wednesday,...

  12. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 2007 (next release 2:00 p.m. on March 8, 2007) Natural gas spot prices decreased at almost all market locations this week in spite of continuing cold weather through most of the...

  13. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5, 2007) Warmer-than-normal temperatures throughout the country led to lower natural gas spot prices at many trading locations in the Lower 48 States. For the week...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    14 (next release 2:00 p.m. on December 21, 2006) Softening natural gas market conditions led to spot price decreases at most market locations in the Lower 48 States since...

  15. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    8 (next release 2:00 p.m. on July 15) Natural gas spot prices climbed 15 to 62 cents per MMBtu across the Lower 48 States this week (Wednesday, June 30-Wednesday, July 7)....

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    25, 2007 (next release 2:00 p.m. on February 1, 2007) Natural gas spot prices across the country surged this week (Wednesday-Wednesday, January 17-24) as a blast of Arctic cold...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 24, 2003 (next release 2:00 p.m. on May 1) Since Wednesday, April 16, natural gas spot prices were lower at nearly all locations in the Lower 48 States. For the week...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2007 (next release 2:00 p.m. on February 8, 2007) Since Wednesday, January 24, natural gas spot prices have increased at most market locations in the Lower 48 States, with...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    country this week and slightly lower prices for crude oil led to an easing of natural gas spot prices in the Lower 48 States since Wednesday, May 3. On the week...

  20. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    18 (next release 2:00 p.m. on May 25, 2006) Natural gas spot prices decreased this week (Wednesday - Wednesday, May 10-17) at virtually all market locations, partly because of weak...

  1. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    May 6 (next release 2:00 p.m. on May 13) Upward pressure on spot and futures natural gas prices continued for a second consecutive week (Wednesday-Wednesday, April 28-May 5), owing...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    the trend of week-over-week increases for the fifth consecutive week. Natural gas in storage was 1,285 billion cubic feet (Bcf) as of April 18, which is 1.9 percent...

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    0, 2003 (next release 2:00 p.m. on March 27) Natural gas spot prices declined at nearly all trading locations for a third consecutive week (March 12-19) as temperatures became more...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    February 7, 2008 Next release: February 14, 2008 Since Wednesday, January 30, natural gas spot prices decreased at most markets in the Lower 48 States. Prices at the Henry Hub...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    December 30 (next release 2:00 p.m. on January 6) Since Wednesday, December 22, natural gas spot prices have decreased sharply at virtually all market locations in the Lower 48...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5, 2002 (next release 2:00 p.m. on July 11) Natural gas spot prices declined by 30 cents or more at most market locations in the Lower 48 last week as temperatures across the...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9 (next release 2:00 p.m. on March 16, 2006) Natural gas spot price movements were mixed this week (Wednesday to Wednesday, March 1-8) as temperatures varied across the Lower 48...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    to Wednesday, April 2) Released: April 3, 2008 Next release: April 10, 2008 Natural gas spot prices increased in all trading regions in the Lower 48 States this report week...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    16, 2007 (next release 2:00 p.m. on August 23, 2007) Since Wednesday, August 8, natural gas spot prices increased at virtually all markets in the Lower 48 States outside the Rocky...

  10. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    settled at 7.737 per MMBtu, only 0.001 per MMBtu lower on the week. Recent Natural Gas Market Data Estimated Average Wellhead Prices Sept-04 Oct-04 Nov-04 Dec-04 Jan-05...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13, 2003 (next release 2:00 p.m. on March 20) Since Wednesday, March 5, natural gas spot prices have decreased at nearly all locations in the Lower 48 States, falling more than...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    March 3 (next release 2:00 p.m. on March 10) Following the cold weather trend, natural gas prices have increased since Wednesday, February 23 at most market locations in the Lower...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Friday, July 6, 2007 (next release 2:00 p.m. on July 12, 2007) Natural gas spot prices decreased sharply this week (Wednesday-Thursday, June 27-July 5), although crude oil prices...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    30, 2003 (next release 2:00 p.m. on February 6) Since Wednesday, January 22, natural gas spot prices have decreased at nearly all locations in the Lower 48 States, falling up to...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 (next release 2:00 p.m. on November 4) Natural gas spot prices spiked significantly higher for the second consecutive week, while futures prices for delivery months beyond...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    8, 2007 (next release 2:00 p.m. on March 15, 2007) Since Wednesday, February 28, natural gas spot prices generally increased east of the Rocky Mountains and decreased in the Rocky...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crude oil prices and increasing cooling demand in some regions contributed to natural gas spot prices climbing more than 10 percent at trading locations in the Lower 48 States...

  18. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12, 2002 (next release 2:00 p.m. on September 19) Natural gas spot prices have moved up by 10 to 25 cents at most trading locations since Wednesday, September 4. For the week...

  19. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 2003 (next release 2:00 p.m. on July 10) Compared with Wednesday, June 25, natural gas spot prices were lower at all locations in the Lower 48 States in trading on July 2....

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 (next release 2:00 p.m. on March 30, 2006) Natural gas spot prices showed relatively modest changes at most market locations in the Lower 48 States since Wednesday, March 15,...

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for the March contract ended the week up almost 5 cents at 2.191 per MMBtu. Natural gas stocks remained well above last year's level as estimated net withdrawals were 82 Bcf...

  2. Dry Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Estimated natural gas plant liquids and dry natural gas content of total natural gas proved reserves, 2014 million barrels and billion cubic feet 2014 Dry Natural Gas billion cubic feet billion cubic feet Alaska 6,805 241 6,745 Lower 48 States 382,036 14,788 361,959 Alabama 2,121 59 2,036 Arkansas 12,795 5 12,789 California 2,260 112 2,107 Coastal Region Onshore 277 12 261 Los Angeles Basin Onshore 84 4 80 San Joaquin Basin Onshore 1,823 96 1,690 State Offshore 76 0 76 Colorado 21,992 813 20,851

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    February 5, 2004 (next release 2:00 p.m. on February 12) Since Wednesday, January 28, natural gas spot prices have decreased at most market locations in the Lower 48 States. For...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Btu (MMBtu). The NEB noted the contrast of this forecast to the market prices of last summer, when natural gas prices peaked at more than 13 per MMBtu and crude oil reached a...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    its oil and natural gas royalty-in-kind (RIK) program, which is expected to increase revenue and lower administrative costs linked with the program. The RIK approach takes...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Hurricanes Katrina and Rita has disrupted natural gas supplies and continued to prop up prices at near-record highs around the nation. According to the Minerals Management...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Price, West Texas Intermediate Crude Oil Spot Price, and Henry Hub Natural Gas Spot Price Graph More Summary Data Prices Prices increased at all trading locations during the week,...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    delivery volumes. Northern Natural Gas Company issued a system overrun limitation (SOL) for all market-area zones for gas day February 21, 2008. The SOL was the result of...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    increases ranged from 5 to 16 cents at every market location tracked by Natural Gas Intelligence. And even though the storm was fast-moving and short-lived, cash prices for...

  10. Current issues in natural gas lubrication

    SciTech Connect (OSTI)

    Reber, J.

    1997-10-01

    Because of the ability of natural gas to burn completely relatively easily, supplying excess oxygen to promote complete reactions is a viable alternative to catalysts. Hence, lean burn technology has a natural fit for this industry. Lube oil is not adversely affected by lean burn operation. There is a slight tendency to cause more oil nitration than oxidation, but the real difference is not significant. Operators may notice somewhat more varnish (caramel color) and less sludge (black) as a result. Because the fuel is burned more completely, there is less problem with fuel-derived oil contamination. Also because of the excess air in the combustion chamber, overall cylinder temperature is lower, causing less stress on the oil. Oil life is generally lengthened. One common misconception that lean burn engines require different lubricants may stem from a change at Waukesha Engine Division--Dresser Industries. Waukesha has changed its lube oil requirements for VHP 3521, 5115, 7042, 9390 GL turbocharged and lean burn model engines. The lube oil specification for these engines is 1% to 1.7% ash with the same 0.10% zinc maximum. This change is not because of the lean burn nature of these engines, rather it is because of drastically decreased lube oil consumption. With less oil consumption, less ash is carried to the critical exhaust valve seat area to prevent valve recession.

  11. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  12. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min; Shen, Zhigang; Zhao, Xiaohu; Liang, Shuaishuai; Liu, Lei

    2014-04-07

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  13. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universität Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  14. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  15. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  16. polymers produced by nature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    polymers produced by nature - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  17. Future of Natural Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts * Supply vs. Capacity * Sources * Consumption * Pipeline system * Gas Interruptions - Operational Flow Orders * Pricing Federal Utility Partnership Working Group November 5-6, 2014 Cape Canaveral, FL Sources of Natural Gas * Mine * Import * Remove from storage Federal Utility Partnership Working Group November 5-6,

  18. Natural Ventilation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Ventilation Natural Ventilation Opening a window is a simple natural ventilation strategy. | Credit: ©iStockphoto/Simotion Opening a window is a simple natural ventilation strategy. | Credit: ©iStockphoto/Simotion Natural ventilation relies on the wind and the "chimney effect" to keep a home cool. Natural ventilation works best in climates with cool nights and regular breezes. The wind will naturally ventilate your home by entering or leaving windows, depending on their

  19. Pulsed laser-induced oxygen deficiency at TiO{sub 2} surface: Anomalous structure and electrical transport properties

    SciTech Connect (OSTI)

    Nakajima, Tomohiko; Tsuchiya, Tetsuo; Kumagai, Toshiya

    2009-09-15

    We have studied pulsed laser-induced oxygen deficiencies at rutile TiO{sub 2} surfaces. The crystal surface was successfully reduced by excimer laser irradiation, and an oxygen-deficient TiO{sub 2-{delta}} layer with 160 nm thickness was formed by means of ArF laser irradiation at 140 mJ/cm{sup 2} for 2000 pulses. The TiO{sub 2-{delta}} layer fundamentally maintained a rutile structure, though this structure was distorted by many stacking faults caused by the large oxygen deficiency. The electrical resistivity of the obtained TiO{sub 2-{delta}} layer exhibited unconventional metallic behavior with hysteresis. A metal-insulator transition occurred at 42 K, and the electrical resistivity exceeded 10{sup 4} OMEGA cm below 42 K. This metal-insulator transition could be caused by bipolaronic ordering derived from Ti-Ti pairings that formed along the stacking faults. The constant magnetization behavior observed below 42 K is consistent with the bipolaronic scenario that has been observed previously for Ti{sub 4}O{sub 7}. These peculiar electrical properties are strongly linked to the oxygen-deficient crystal structure, which contains many stacking faults formed by instantaneous heating during excimer laser irradiation. - Graphical abstract: A pulsed laser-irradiated TiO{sub 2-{delta}} substrate showed an unconventional metallic phase, with hysteresis over a wide range of temperatures and a metal-insulator transition at 42 K.

  20. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  1. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensor.

  2. Enhancing SNCR-aided combustion with oxygen addition

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool, III, Lawrence E.

    2004-03-09

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  3. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR ...

  4. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

    2011-01-25

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  5. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Armstrong, M R; Zaug, J M; Grant, C D; Crowhurst, J C; Bastea, S 75...

  6. Interplay between gadolinium dopants and oxygen vacancies in...

    Office of Scientific and Technical Information (OSTI)

    by decrease of Vsub O concentration. Our findings would clarify the debate about the influence of Gd doping on the oxygen vacancies in HfOsub 2. Authors: Zhang, Wei 1 ;...

  7. In-situ generation of oxygen-releasing metal peroxides

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

    2007-01-09

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  8. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Silicates In The Larderello Geothermal Field, Italy Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The...

  9. Neutrinos: Nature's Identity Thieves?

    ScienceCinema (OSTI)

    Dr. Don Lincoln

    2013-07-22

    The oscillation of neutrinos from one variety to another has long been suspected, but was confirmed only about 15 years ago. In order for these oscillations to occur, neutrinos must have a mass, no matter how slight. Since neutrinos have long been thought to be massless, in a very real way, this phenomena is a clear signal of physics beyond the known. In this video, Fermilab's Dr Don Lincoln explains how we know it occurs and hints at the rich experimental program at several international laboratories designed to understand this complex mystery.

  10. Neutrinos: Nature's Identity Thieves?

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07

    The oscillation of neutrinos from one variety to another has long been suspected, but was confirmed only about 15 years ago. In order for these oscillations to occur, neutrinos must have a mass, no matter how slight. Since neutrinos have long been thought to be massless, in a very real way, this phenomena is a clear signal of physics beyond the known. In this video, Fermilab's Dr Don Lincoln explains how we know it occurs and hints at the rich experimental program at several international laboratories designed to understand this complex mystery.

  11. Method for making oxygen-reducing catalyst layers

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

    2010-06-22

    Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  12. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  13. Hydrogen (H2) Production by Oxygenic Phototrophs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygenic Phototrophs Hydrogen (H2) Production by Oxygenic Phototrophs Presentation by Eric Hegg, Michigan State University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_hegg.pdf More Documents & Publications Renewable Hydrogen Production from Biological Systems Autofermentative Biological Hydrogen Production by Cyanobacteria 2013 Biological Hydrogen Production Workshop

  14. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Authors: Armstrong, M R ; Zaug, J M ; Grant, C D ; Crowhurst, J C ; Bastea, S Publication Date: 2014-06-24 OSTI Identifier: 1149544 Report Number(s):

  15. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and

  16. Ab Initio Calculations of Even Oxygen Isotopes with Chiral

    Office of Scientific and Technical Information (OSTI)

    Two-Plus-Three-Nucleon Interactions (Journal Article) | SciTech Connect Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Citation Details In-Document Search Title: Ab Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Authors: Hergert, H. ; Binder, S. ; Calci, A. ; Langhammer, J. ; Roth, R. Publication Date: 2013-06-10 OSTI Identifier: 1102833 Type: Publisher's Accepted Manuscript Journal Name: Physical

  17. Oxygen-permeable ceramic membranes for gas separation

    SciTech Connect (OSTI)

    Balachandran, U.; Ma, B.; Maiya, P.S.; Dusek, J.T.; Mieville, R.L.; Picciolo, J.J.

    1998-02-01

    Mixed-conducting oxides have a wide range of applications, including fuel cells, gas separation systems, sensors, and electrocatalytic equipment. Dense ceramic membranes made of mixed-conducting oxides are particularly attractive for gas separation and methane conversion processes. Membranes made of Sr-Fe-Co oxide, which exhibits high combined electronic and oxygen ionic conductivities, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, i.e., CO + H{sub 2}). The authors have fabricated tubular Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes and tested them (some for more than 1,000 h) in a methane conversion reactor that was operating at 850--950 C. An oxygen permeation flux of {approx} 10 scc/cm{sup 2} {center_dot} min was obtained at 900 C in a tubular membrane with a wall thickness of 0.75 mm. Using a gas-tight electrochemical cell, the authors have also measured the steady-state oxygen permeability of flat Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes as a function of temperature and oxygen partial pressure(pO{sub 2}). Steady-state oxygen permeability increases with increasing temperature and with the difference in pO{sub 2} on the two sides of the membrane. At 900 C, an oxygen permeability of {approx} 2.5 scc/cm{sup 2} {center_dot} min was obtained in a 2.9-mm-thick membrane. This value agrees with that obtained in methane conversion reactor experiments. Current-voltage (I-V) characteristics determined in the gas-tight cell indicate that bulk effect, rather than surface exchange effect, is the main limiting factor for oxygen permeation of {approx} 1-mm-thick Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes at elevated temperatures (> 650 C).

  18. Role of an Oxygen Vacancy Nanostructure on the Switchable Photovoltaic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect in BiFeO3 | Stanford Synchrotron Radiation Lightsource Role of an Oxygen Vacancy Nanostructure on the Switchable Photovoltaic Effect in BiFeO3 Monday, February 29, 2016 In all oxide compounds, oxygen vacancies intrinsically exist and their role and impact on materials' properties have been studied for several decades. Mostly they have been considered as defects that disturb a 'perfect world'. Nowadays, however, researchers consider them as new parameters for controlling

  19. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for the intake manifold of a diesel engine equipped with EGR, along with a virtual intake manifold O2 sensor, show good accuracy with stationary measurements PDF icon deer09_traver.pdf More Documents & Publications Simulation and Analysis of HP/LP EGR for Heavy-Duty Applications

  20. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transport Membrane (OTM) (Presentation) | Department of Energy Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 11_anl_distributed_reforming_using_otm.pdf More Documents & Publications Cost

  1. Research Update: Interface-engineered oxygen octahedral tilts in perovskite

    Office of Scientific and Technical Information (OSTI)

    oxide heterostructures (Journal Article) | SciTech Connect Research Update: Interface-engineered oxygen octahedral tilts in perovskite oxide heterostructures Citation Details In-Document Search Title: Research Update: Interface-engineered oxygen octahedral tilts in perovskite oxide heterostructures Interface engineering of structural distortions is a key for exploring the functional properties of oxide heterostructures and superlattices. In this paper, we report on our comprehensive

  2. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Authors: Armstrong, M R ; Zaug, J M ; Grant, C D ; Crowhurst, J C ; Bastea, S Publication Date: 2014-06-24 OSTI Identifier: 1149544 Report Number(s):

  3. Study of the photochemically generated of oxygen species by fullerene photosensitized CoS{sub 2} nanocompounds

    SciTech Connect (OSTI)

    Meng, Ze-Da; Zhu, Lei; Ullah, Kefayat; Ye, Shu; Sun, Qian; Jang, Won Kweon; Oh, Won-Chun

    2014-01-01

    Graphical abstract: - Highlights: • Reactive oxygen species was detected through oxidation reaction from DPCI to DPCO. • Generated reactive oxygen species and hydroxyl radicals can be analysis by DPCI degradation. • C{sub 60} has good effect during the photo-degradation processes. • Photocatalytic activity attributed to photo-absorption effect by C{sub 60} and cooperative effect of CoS{sub 2}. - Abstract: Reactive oxygen species (ROS) can be produced by interactions between sunlight and light-absorbing substance in natural water environment and can completely destroy various organic pollutants in wastewaters. In this study, CoS{sub 2} and CoS{sub 2}–fullerene were irradiated by visible light respectively. The generation of reactive oxygen species were detected through the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). In comparison with the separate effects of CoS{sub 2} and fullerene nanoparticles, the photochemically effect of the fullerene photosensitized CoS{sub 2} composites is increased significantly due to the synergetic effect between the fullerene and the CoS{sub 2} nanoparticles.

  4. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference ...

  5. EIA - Natural Gas Pipeline Network - Intrastate Natural Gas Pipeline...

    U.S. Energy Information Administration (EIA) Indexed Site

    SoCal and PG&E are two of the largest distribution companies in the entire United States. ... Intrastate Natural Gas Pipeline Companies -spreadsheet Other Natural Gas ...

  6. Interaction of light with the ZnO surface: Photon induced oxygen “breathing,” oxygen vacancies, persistent photoconductivity, and persistent photovoltage

    SciTech Connect (OSTI)

    Gurwitz, Ron; Cohen, Rotem; Shalish, Ilan

    2014-01-21

    ZnO surfaces adsorb oxygen in the dark and emit CO{sub 2} when exposed to white light, reminiscent of the lungs of living creatures. We find that this exchange of oxygen with the ambient affects the integrity of the ZnO surface. Thus, it forms a basis for several interesting surface phenomena in ZnO, such as photoconductivity, photovoltage, and gas sensing, and has a role in ZnO electrical conduction. Using x-ray photoelectron spectroscopy on ZnO nanowires, we observed a decomposition of ZnO under white light and formation of oxygen-depleted surface, which explains photoconductivity by the electron donation of oxygen vacancies. Our findings suggest that the observed decomposition of the ZnO lattice may only take place due to photon-induced reduction of ZnO by carbon containing molecules (or carbo-photonic reduction), possibly from the ambient gas, accounting in a consistent way for both the reduced demands on the energy required for decomposition and for the observed emission of lattice oxygen in the form of CO{sub 2}. The formation of oxygen-vacancy rich surface is suggested to induce surface delta doping, causing accumulation of electrons at the surface, which accounts for both the increase in conductivity and the flattening of the energy bands. Using surface photovoltage spectroscopy in ultra high vacuum, we monitored changes in the deep level spectrum. We observe a wide optical transition from a deep acceptor to the conduction band, which energy position coincides with the position of the so called “green luminescence” in ZnO. This green transition disappears with the formation of surface oxygen vacancies. Since the oxygen vacancies are donors, while the green transition involves surface acceptors, the results suggest that the initial emission of oxygen originates at the defect sites of the latter, thereby eliminating each other. This suggests that the green transition originates at surface Zn vacancy acceptors. Removing an oxygen atom from a Zn vacancy completes the vacancy to become a full ZnO molecule vacancy, which does not produce deep levels. Our results explain why ZnO finds use as an electrical detector for oxygen and for carbon containing gas molecules. They may also shed new light on photocatalytic uses of ZnO. It is suggested that similar surface phenomena may affect other semiconducting oxides.

  7. International Natural Gas Workshop Presnetations

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Session 3: Asian Natural Gas Outlook Asian Natural Gas: A Softer Market is coming Robert Smith, FGE Dubai PDF Session 4: LNG Exports and the Future International Natural Gas Market ...

  8. EIA - Natural Gas Analysis Basics

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas industry restructuring in each state, focusing on the residential customer class. About U.S. Natural Gas Pipelines State Energy Profiles What role does liquefied...

  9. Historical Natural Gas Annual 1999

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1999 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  10. Nature Energie | Open Energy Information

    Open Energy Info (EERE)

    Nature Energie Jump to: navigation, search Name: Nature Energie Place: France Sector: Solar, Wind energy Product: French developer of wind and solar energy projects. References:...

  11. Natural gas industry directory

    SciTech Connect (OSTI)

    1999-11-01

    This directory has information on the following: associations and organizations; exploration and production; gas compression; gas processors; gathering and transmission companies; liquefied natural gas; local distribution companies; marketing firms; regulatory agencies; service companies; suppliers and manufacturers; and regional buyer`s guide.

  12. Natural resources law handbook

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This book covers legal topics ranging from ownership-related issues (including disposition, use and management of privately and publicly-owned lands, resources, minerals and waters) to the protection and maintenance of our nation's natural resources. It contains chapters on oil and gas resources, coal resources, and minerals and mining.

  13. EIA - Natural Gas Pipeline Network - Natural Gas Transportation Corridors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Map Corridors > Major U.S. Natural Gas Transportation Corridors Map About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Major U.S. Natural Gas Transportation Corridors, 2008

  14. EIA - Natural Gas Pipeline Network - Generalized Natural Gas Pipeline

    U.S. Energy Information Administration (EIA) Indexed Site

    Capacity Design Schematic Generalized Design Schematic About U.S. Natural Gas Pipelines- Transporting Natural Gas based on data through 2007/2008 with selected updates Generalized Natural Gas Pipeline Capacity Design Schematic Generalized Natural Gas Pipeline Capcity Design Schematic

  15. Experimental study on transmission of an overdriven detonation wave from propane/oxygen to propane/air

    SciTech Connect (OSTI)

    Li, J.; Lai, W.H.; Chung, K.; Lu, F.K.

    2008-08-15

    Two sets of experiments were performed to achieve a strong overdriven state in a weaker mixture by propagating an overdriven detonation wave via a deflagration-to-detonation transition (DDT) process. First, preliminary experiments with a propane/oxygen mixture were used to evaluate the attenuation of the overdriven detonation wave in the DDT process. Next, experiments were performed wherein a propane/oxygen mixture was separated from a propane/air mixture by a thin diaphragm to observe the transmission of an overdriven detonation wave. Based on the characteristic relations, a simple wave intersection model was used to calculate the state of the transmitted detonation wave. The results showed that a rarefaction effect must be included to ensure that there is no overestimate of the post-transmission wave properties when the incident detonation wave is overdriven. The strength of the incident overdriven detonation wave plays an important role in the wave transmission process. The experimental results showed that a transmitted overdriven detonation wave occurs instantaneously with a strong incident overdriven detonation wave. The near-CJ state of the incident wave leads to a transmitted shock wave, and then the transition to the overdriven detonation wave occurs downstream. The attenuation process for the overdriven detonation wave decaying to a near-CJ state occurs in all tests. After the attenuation process, an unstable detonation wave was observed in most tests. This may be attributed to the increase in the cell width in the attenuation process that exceeds the detonability cell width limit. (author)

  16. Surface control of epitaxial manganite films via oxygen pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tselev, Alexander; Vasudevan, Rama K.; Gianfrancesco, Anthony G.; Qiao, Liang; Ganesh, Panchapakesan; Meyer, Tricia L.; Lee, Ho Nyung; Biegalski, Michael D.; Baddorf, Arthur P.; Kalinin, Sergei

    2015-03-11

    The trend to reduce device dimensions demands increasing attention to atomic-scale details of structure of thin films as well as to pathways to control it. We found that this is of special importance in the systems with multiple competing interactions. We have used in situ scanning tunneling microscopy to image surfaces of La5/8Ca3/8MnO3 films grown by pulsed laser deposition. The atomically resolved imaging was combined with in situ angle-resolved X-ray photoelectron spectroscopy. We find a strong effect of the background oxygen pressure during deposition on structural and chemical features of the film surface. Deposition at 50 mTorr of O2 leadsmore » to mixed-terminated film surfaces, with B-site (MnO2) termination being structurally imperfect at the atomic scale. Moreover, a relatively small reduction of the oxygen pressure to 20 mTorr results in a dramatic change of the surface structure leading to a nearly perfectly ordered B-site terminated surface with only a small fraction of A-site (La,Ca)O termination. This is accompanied, however, by surface roughening at a mesoscopic length scale. The results suggest that oxygen has a strong link to the adatom mobility during growth. The effect of the oxygen pressure on dopant surface segregation is also pronounced: Ca surface segregation is decreased with oxygen pressure reduction.« less

  17. Combinatorial density functional theory-based screening of surface alloys for the oxygen reduction reaction.

    SciTech Connect (OSTI)

    Greeley, J.; Norskov, J.; Center for Nanoscale Materials; Technical Univ. of Denmark

    2009-03-26

    A density functional theory (DFT) -based, combinatorial search for improved oxygen reduction reaction (ORR) catalysts is presented. A descriptor-based approach to estimate the ORR activity of binary surface alloys, wherein alloying occurs only in the surface layer, is described, and rigorous, potential-dependent computational tests of the stability of these alloys in aqueous, acidic environments are presented. These activity and stability criteria are applied to a database of DFT calculations on nearly 750 binary transition metal surface alloys; of these, many are predicted to be active for the ORR but, with few exceptions, they are found to be thermodynamically unstable in the acidic environments typical of low-temperature fuel cells. The results suggest that, absent other thermodynamic or kinetic mechanisms to stabilize the alloys, surface alloys are unlikely to serve as useful ORR catalysts over extended periods of operation.

  18. EIA - Natural Gas Pipeline Network - Major Natural Gas Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corridors Major Natural Gas Transportation Corridors About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Major Natural Gas Transportation Corridors Corridors from the Southwest | From Canada | From Rocky Mountain Area | Details about Transportation Corridors The national natural gas delivery network is intricate and expansive, but most of the major transportation routes can be broadly categorized into 11 distinct corridors or flow

  19. EIA - Natural Gas Pipeline Network - Underground Natural Gas Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Underground Natural Gas Storage Overview | Regional Breakdowns Overview Underground natural gas storage provides pipelines, local distribution companies, producers, and pipeline shippers with an inventory management tool, seasonal supply backup, and access to natural gas needed to avoid imbalances between receipts and deliveries on a pipeline network. There are three

  20. EIA - Natural Gas Pipeline Network - Underground Natural Gas Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facilities Map Storage > U.S. Underground Natural Gas Storage Facilities Map About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates U.S. Underground Natural Gas Storage Facilities, Close of 2007 more recent map U.S. Underground Natural Gas Storage Facilities, 2008 The EIA has determined that the informational map displays here do not raise security concerns, based on the application of the Federal Geographic Data Committee's