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Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Sulfur dioxide oxidation and plume formation at cement kilns  

SciTech Connect (OSTI)

Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

1980-10-01T23:59:59.000Z

2

Sulfur Dioxide Regulations (Ohio)  

Broader source: Energy.gov [DOE]

This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

3

KINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ  

E-Print Network [OSTI]

clarified the role of aqueous-phase production of strong acids in the atmosphere. Oxidation of dissolvedKINETICS OF OXIDATION OF AQUEOUS SULFUR(IV) BY NITROGEN DIOXIDE YIN-NAN LEE AND STEPHEN E. SCHWARTZ) are the precursors of the strong acids (i.e., HzS04 and HN03) found in precipitation,! the detailed mechanisms

Schwartz, Stephen E.

4

Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide  

SciTech Connect (OSTI)

The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

1988-11-10T23:59:59.000Z

5

Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions  

E-Print Network [OSTI]

with sulfuric and nitric acids formed from at- mospheric oxidations of sulfur dioxide SO2 and nitrogen oxides mobile sources comes from the combustion of sulfur compounds in fuel. The U.S. is in the process of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

Denver, University of

6

Estimated monthly emissions of sulfur dioxide, oxides of nitrogen, and volatile organic compounds for the 48 contiguous states, 1985-1986: Volume 2, Sectoral emissions by month for states  

SciTech Connect (OSTI)

A listing by source of sulfur dioxide, nitrogen oxides and volatile organic compounds emitted in 48 states of the US is provided. (CBS)

Kohout, E.J.; Knudson, D.A.; Saricks, C.L.; Miller, D.J.

1987-11-01T23:59:59.000Z

7

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect (OSTI)

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

8

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect (OSTI)

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

9

E-Print Network 3.0 - atmospheric sulfur dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: (O3), nitrogen oxides (NOx), carbon monoxide (CO), and sulfur dioxide (SO2) will be measured... Ren...

10

Sulfur dioxide removal by enhanced electrostatics  

SciTech Connect (OSTI)

The economic removal of sulfur dioxide (SO{sub 2}) still represents a significant technical challenge which could determine the use of certain types of fossil fuels for energy production. This paper will present the preliminary results of an innovative research project utilizing a low-cost wet electrostatic precipitator to remove sulfur dioxide. There are many aspects for gas removal in an electrostatic precipitator which are not currently being used. This project utilizes electron attachment of free electrons onto gas molecules and ozone generation to remove sulfur dioxide which is a typical flue gas pollutant. This research was conducted on a bench-scale, wet electrostatic precipitator. A direct-current negative discharge corona is used to generate the ozone in-situ. This ozone will be used to oxidize SO{sub 2} to form sulfuric acid, which is very soluble in water. However, it is believed that the primary removal mechanism is electron attachment of the free electrons from the corona which force the SO{sub 2} to go to equilibrium with the water and be removed from the gas stream. Forcing the equilibrium has been shown to achieve removal efficiencies of up to 70%. The bench scale unit has been designed to operate wet or dry, positive and negative for comparison purposes. The applied dc voltage is variable from 0 to 100 kV, the flow rate is a nominal 7 m{sup 3}/hr and the collecting electrode area is 0.20 m{sup 2}. Tests are conducted on a simulated flue gas stream with SO{sub 2} ranging from 0 to 4,000 ppmv. This paper presents the results of tests conducted to determine the effect of operating conditions on removal efficiency. The removal efficiency was found to vary with gas residence time, water flow rate, inlet concentration, applied power, and the use of corona pulsing.

Larkin, K.; Tseng, C.; Keener, T.C.; Khang, S.J. [Univ. of Cincinnati, OH (United States)

1997-12-31T23:59:59.000Z

11

Catalyst for the reduction of sulfur dioxide to elemental sulfur  

DOE Patents [OSTI]

The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

1996-01-01T23:59:59.000Z

12

Catalyst for the reduction of sulfur dioxide to elemental sulfur  

DOE Patents [OSTI]

The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

Jin, Y.; Yu, Q.; Chang, S.G.

1996-02-27T23:59:59.000Z

13

Sugar yields from dilute sulfuric acid and sulfur dioxide pretreatments and subsequent enzymatic hydrolysis of switchgrass  

E-Print Network [OSTI]

Sugar yields from dilute sulfuric acid and sulfur dioxide pretreatments and subsequent enzymatic Dilute sulfuric acid Sulfur dioxide Biofuels Switchgrass a b s t r a c t Dacotah switchgrass was pretreated with sulfuric acid concentrations of 0.5, 1.0, and 2.0 wt.% at 140, 160, and 180 °C and with 1

California at Riverside, University of

14

Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer  

E-Print Network [OSTI]

Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer in the thermochemical conversion of sulfur dioxide to sulfuric acid for the large-scale production of hydrogen, 2009. Published May 19, 2009. The hybrid sulfur process is being investigated as an efficient way

Weidner, John W.

15

Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005  

SciTech Connect (OSTI)

Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

John E. Pinkerton [National Council of the Paper Industry for Air and Stream Improvement Inc., Research Triangle Park, NC (United States). Air Quality Program

2007-08-15T23:59:59.000Z

16

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

17

Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control  

DOE Patents [OSTI]

Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

Li, Liyu [Richland, WA; King, David L [Richland, WA

2011-03-15T23:59:59.000Z

18

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

19

Process for sequestering carbon dioxide and sulfur dioxide  

DOE Patents [OSTI]

A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

2009-10-20T23:59:59.000Z

20

Auction design and the market for sulfur dioxide emissions  

E-Print Network [OSTI]

Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

Joskow, Paul L.

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Sulfur oxide adsorbents and emissions control  

DOE Patents [OSTI]

High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

Li, Liyu (Richland, WA); King, David L. (Richland, WA)

2006-12-26T23:59:59.000Z

22

Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results  

SciTech Connect (OSTI)

A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

2004-01-25T23:59:59.000Z

23

Method for Determining Performance of Sulfur Oxide Adsorbents...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Method for Determining Performance of Sulfur Oxide Adsorbents for Diesel Emission Control Using Online Measurement of SO2 and Method for Determining Performance of Sulfur Oxide...

24

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

25

Intensities of electronic transitions in sulfur dioxide vapor  

E-Print Network [OSTI]

. Relation between Oscillator Strength and Probability Coefficient of Absorption . . . . . . . . . . . . . . . . 20 V. The Ultraviolet Spectrum of Sulfur Dioxide Gas . . . . . . 22 ) VI. Experimental Procedure and Computations . . . . . . . . . 23 U A... where )(e is defined as the dielectric constant of the medium. This equation holds for radiation which has a frequency sufficiently dif- ferent from that of the resonant frequencies of'the molecules of the medium, The polarizability o( of a molecule...

McCray, James Arthur

1955-01-01T23:59:59.000Z

26

Instrument Development and Measurements of the Atmospheric Pollutants Sulfur Dioxide, Nitrate Radical, and Nitrous Acid by Cavity Ring-down Spectroscopy and Cavity Enhanced Absorption Spectroscopy  

E-Print Network [OSTI]

A. , A method of nitrogen dioxide and sulphur dioxidedetermination of nitrogen dioxide and sulfur dioxide in theDOAS) have measured nitrogen dioxide (NO 2 ), nitrate

Medina, David Salvador

2011-01-01T23:59:59.000Z

27

E-Print Network 3.0 - absorbing sulfur dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

28

E-Print Network 3.0 - ambient sulfur dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

29

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

30

Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget  

E-Print Network [OSTI]

processes, volca- noes) or produced within the atmosphere by oxidation of re- duced sulfur speciesTransition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur importance of sulfate production by Fe(III)- and Mn(II)-catalyzed oxidation of S(IV) by O2. We scale

Alexander, Becky

31

EVALUATION OF PROTON-CONDUCTING MEMBRANES FOR USE IN A SULFUR-DIOXIDE DEPOLARIZED ELECTROLYZER  

SciTech Connect (OSTI)

The chemical stability, sulfur dioxide transport, ionic conductivity, and electrolyzer performance have been measured for several commercially available and experimental proton exchange membranes (PEMs) for use in a sulfur dioxide depolarized electrolyzer (SDE). The SDE's function is to produce hydrogen by using the Hybrid Sulfur (HyS) Process, a sulfur based electrochemical/thermochemical hybrid cycle. Membrane stability was evaluated using a screening process where each candidate PEM was heated at 80 C in 60 wt. % H{sub 2}SO{sub 4} for 24 hours. Following acid exposure, chemical stability for each membrane was evaluated by FTIR using the ATR sampling technique. Membrane SO{sub 2} transport was evaluated using a two-chamber permeation cell. SO{sub 2} was introduced into one chamber whereupon SO{sub 2} transported across the membrane into the other chamber and oxidized to H{sub 2}SO{sub 4} at an anode positioned immediately adjacent to the membrane. The resulting current was used to determine the SO{sub 2} flux and SO{sub 2} transport. Additionally, membrane electrode assemblies (MEAs) were prepared from candidate membranes to evaluate ionic conductivity and selectivity (ionic conductivity vs. SO{sub 2} transport) which can serve as a tool for selecting membranes. MEAs were also performance tested in a HyS electrolyzer measuring current density versus a constant cell voltage (1V, 80 C in SO{sub 2} saturated 30 wt% H2SO{sub 4}). Finally, candidate membranes were evaluated considering all measured parameters including SO{sub 2} flux, SO{sub 2} transport, ionic conductivity, HyS electrolyzer performance, and membrane stability. Candidate membranes included both PFSA and non-PFSA polymers and polymer blends of which the non-PFSA polymers, BPVE-6F and PBI, showed the best selectivity.

Hobbs, D.; Elvington, M.; Colon-Mercado, H.

2009-11-11T23:59:59.000Z

32

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report  

SciTech Connect (OSTI)

This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temperatures about 450{degrees}C or higher with the feed gas of stoichiometric composition. Reaction of SO{sub 2} and CO over these catalysts demonstrated a strong correlation of catalytic activity with the catalyst oxygen mobility. Furthermore, the catalytic activity and resistance to H{sub 2}O and CO{sub 2} poisoning of these catalysts were significantly enhanced by adding small amounts of transition metals, such as Co, Ni, Co, etc. The resulting transition metal-fluorite oxide composite catalyst has superior activity and stability, and shows promise in long use for the development of a greatly simplified single-step sulfur recovery process to treat variable and dilute SO{sub 2} concentration gas streams. Among various active composite catalyst systems the Cu-CeO{sub 2} system has been extensively studied. XRD, XPS, and STEM analyses of the used Cu-CeO{sub 2} catalyst found that the fluorite crystal structure of ceria was stable at the present reaction conditions, small amounts of copper was dispersed and stabilized on the ceria matrix, and excess copper oxide particles formed copper sulfide crystals of little contribution to catalytic activity. A working catalyst consisted of partially sulfated cerium oxide surface and partially sulfided copper clusters. The overall reaction kinetics were approximately represented by a first order equation.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1995-06-01T23:59:59.000Z

33

Adsorption of sulfur dioxide from coal combustion gases on natural zeolite  

SciTech Connect (OSTI)

In this study, better efficiency of SO{sub 2} removal in flue gas from lignite coal combustion by adding of NZ in the gas phase was achieved. Natural zeolite was exposed to flue gas containing sulfur dioxide at varying conditions of relative humidity and temperature. It was found that the amount of sulfate on the zeolite increased with increasing relative humidity and temperature. The percents of adsorbed sulfur dioxide were 86, 74, 56, and 35, while the values of relative humidity (RH) were 75, 60, 45, and 30% for 40 minutes, respectively. The percents of adsorbed sulfur dioxide sharply increased within the first 40 min for the values of RH were 75 and 60, and after 40 min, slightly increased, then reached a plateau. In general, as increasing the RH increased the amount of sulfur dioxide adsorbed by natural zeolite. The amounts of adsorbed sulfur dioxide increased with exposure time. It increased and reached 30.2 mg/g for 40 min. After 40 min, it slightly increased and then reached a plateau. The NZ adsorbs 35.1 mg SO{sub 2} per gram adsorbent with 75% RH at 298 K from a simulated coal combustion flue gas. The amounts of adsorbed sulfur dioxide increased with increasing temperature. The NZ adsorbs 71.5 mg SO{sub 2} per gram adsorbent with 75% RH for 100 min exposure time from the flue gas mixture.

Demirbas, A. [Selcuk University, Konya (Turkey). Dept. for Chemical Engineering

2006-10-15T23:59:59.000Z

34

Process for removing sulfur dioxide from flue gases  

SciTech Connect (OSTI)

This patent describes an improvement in a dry process for the removal of sulfur dioxide from flue gases by the addition thereto of hydrated lime containing sugar in a coal combustion unit, wherein the flue gases result from the combustion of a coal in a combustion chamber, and the flue gases are treated in an electrostatic precipitator prior to discharge to the atmosphere the improvement comprising: passing the flue gases, after the addition of the hydrated lime is of fine particles of a specific surface of 7 to 25 square meters per gram, through a conduit towards the electrostatic precipitator; and adding an aqueous media to the flue gases in the conduit in an amount to increase the water content of the flue gases and cool the same by evaporative cooling to a temperature no lower than 20{sup 0}F. about the dew point of the gas, so as to avoid forming water droplets in the gas, so as to prevent condensation of water therefrom.

Robinson, M.W. Jr.

1989-08-29T23:59:59.000Z

35

Sulfur dioxide-induced chronic bronchitis in beagle dogs  

SciTech Connect (OSTI)

This study was done to produce a model of chronic bronchitis. Twelve beagle dogs were exposed to 500 ppm sulfur dioxide (SO/sub 2/) for 2 h/d, 5d/wk for 21 wk and 4 dogs were sham-exposed to filtered ambient air for the same period. Exposure effects were evaluated by periodically examining the dogs using chest radiographs, pulmonary function, tracheal mucous clearance, and the cellular and soluble components of bronchopulmonary lavage fluids. Dogs were serially sacrificed after 13 and 21 wk of exposure and after 6 and 14 wk of recovery. Clinical signs produced in the SO/sub 2/-exposed dogs included mucoid nasal discharge, productive cough, moist rales on auscultation, tonsilitis, and conjunctivitis. Chest radiographs revealed mild peribronchiolar thickening. Histopathology, tracheal mucous clearance measurements, and lavage cytology were consistent with a diagnosis of chronic bronchitis. It is concluded that repeated exposure to 500 ppm SO/sub 2/ for 21 wk produced chronic bronchitis in the beagle dog. Complete recovery occurred within 5 wk following cessation of SO/sub 2/ exposure. 43 references, 2 figures, 2 tables.

Greene, S.A.; Wolff, R.K.; Hahn, F.F.; Henderson, R.F.; Mauderly, J.L.; Lundgren, D.L.

1984-01-01T23:59:59.000Z

36

SULFUR-TOLERANT CATALYST FOR THE SOLID OXIDE FUEL CELL.  

E-Print Network [OSTI]

??JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which… (more)

Bozeman, Joe Frank, III

2010-01-01T23:59:59.000Z

37

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

world-best-practice-energy- intensity-values-selected-World Best Practice Energy Intensity Values for Selectedof the Targets for Energy Intensity and Sulfur Dioxide in

Zhou, Nan

2013-01-01T23:59:59.000Z

38

Sulfur dioxide emissions from primary nonferrous smelters in the Western United States  

SciTech Connect (OSTI)

The greatest source of sulfur dioxide emissions in the West has been the pyrometallurgical processing of copper, lead, and zinc ores. Until the early 1970s, the emissions from most nonferrous metal smelters were released without control into the environment. However, recent Federal and State legislation has mandated the need for large reductions of emissions, a task that will require the introduction of highly efficient sulfur dioxide control technology. The particular processes at each smelter, the smelter location, the capital and operating costs including the cost of energy, the resolution of currently litigated issues, and the metal market prices will be major influences on the choice of technology and on the schedule for implementation of smelter control plans. These parameters are examined, and the problems and issues associated with them are described. The future impact of smelter sulfur dioxide emissions is discussed within the framework of the relevant economic, technologial, and legal issues.

Mangeng, C.; Mead, R.

1980-08-01T23:59:59.000Z

39

Cathodic reduction of sulfur dioxide at porous, phthalocyanine-containing electrodes in nonaqueous electrolytes  

SciTech Connect (OSTI)

Electrodes containing catalysts, particularly electrodes containing metal chelate compounds, were studied for their effect on reducing cathodic sulfur dioxide. The electrodes were prepared with an iron phthalocyanine polymer deposited onto activated carbon. Fluoropolymer dispersions was used as the binder and electrochemical studies were performed in a glove box under dry argon. Lithium perchlorate solution in propylene carbonate was used as the electrolyte solution. The results indicate that materials with high catalytic activity show promise in raising the discharge voltage in power sources of the lithium-sulfur dioxide system.

Shembel', E.M.; Ksenzhek, O.S.; Danilova, N.P.; Shustov, V.A.

1988-03-01T23:59:59.000Z

40

Morbidity And Sulfur Dioxide: Evidence From French Strikes At Oil Refineries  

E-Print Network [OSTI]

This paper examines the impact of sulfur dioxide (SO2) in France on health outcomes at a census track level. To do so, we use recent strikes affecting oil refineries in France, in October 2010, as a natural experiment. Our work offers several contributions. We first show that a temporal shut down in the refining process leads to a reduction in sulfur dioxide concentration. We then use this narrow time frame exogenous shock to assess the impact of a change in air pollution concentration on respiratory outcomes. Our estimates suggest that daily variation in SO2 air pollution has economically significant health effects at levels below the current standard. 0

Matthew Neidell; Emmanuelle Lavaine

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1996-12-01T23:59:59.000Z

42

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Sixth quarterly technical progress report, January - March 1997  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-03-01T23:59:59.000Z

43

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range (400--650{degree}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2} formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1993-12-31T23:59:59.000Z

44

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 4, April--June 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650{degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams, The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Williams, R.S.

1993-12-31T23:59:59.000Z

45

Catalysts for the selective oxidation of hydrogen sulfide to sulfur  

DOE Patents [OSTI]

This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

Srinivas, Girish (Thornton, CO); Bai, Chuansheng (Baton Rouge, LA)

2000-08-08T23:59:59.000Z

46

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October 1993--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400-650 {degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought {open_quotes}Claus-alternative{close_quotes} for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1996-01-01T23:59:59.000Z

47

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network [OSTI]

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

48

On-Road Motor Vehicle Emissions including Ammonia, Sulfur Dioxide and Nitrogen Dioxide Don Stedman, Gary Bishop, Allison Peddle, University of Denver Department of Chemistry and Biochemistry Denver CO 80208. www.feat.biochem.du.edu  

E-Print Network [OSTI]

On-Road Motor Vehicle Emissions including Ammonia, Sulfur Dioxide and Nitrogen Dioxide Don Stedman Nitrogen dioxide: Less than 5% of the NOx BUT with an outstanding peak for the 2007 MY in Fresno 0. Nitrogen dioxide: less than 5% of NOx except the Fresno fleet containing the 2007 Sprinter ambulances. #12;

Denver, University of

49

The vibrational and rotational structure of the 2400 to 1950 A? absorption spectrum of sulfur dioxide  

E-Print Network [OSTI]

0. $ ? Vs TBE YiaUSXOKtf U ? m sm U M A L M W of thb 2400 to 1950 2 Ammwim mmmm m s u m m m a m A. BisMrtatiim % James Willbom Biggs, Jfe. Submitted to the Gra4taata Sdtotd tdt HA* Agricultural and Maofcudoal Qtlltc* %ff I'M* 3*i partial... fulfillment of' %hm r*tuir??Mi*s f?r %ift ??' m m m m m m & m s t Major Sttfejoott Rupeio* THE VIBRATIONAL AND ROTATIONAL STRUCTURE OP THE 2400 TO 1950 A ABSORPTION SPECTRUM OP SULFUR DIOXIDE A Dissertation 37 James Willborn Riggs, Jr. Approved...

Riggs, James Willborn

1958-01-01T23:59:59.000Z

50

Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite  

E-Print Network [OSTI]

Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite C H E N H . S H E N A N D G by absorption in sulfite solution in existing scrubbers for desulfurization. Rates of NO2 absorption and sulfite absorption initiates sulfite oxidation in the presence of oxygen, and this study quantified the effect

Rochelle, Gary T.

51

Cathodic reduction of sulfur dioxide in nonaqueous electrolytes. polarization curves at porous Electrodes  

SciTech Connect (OSTI)

This paper describes some results obtained from studying the poloarization characteristics of cathodic sulfur dioxide reduction at porous electrodes made by applying a mixture of carbon black, graphite, and binder to a metal screen serving as current collector. Solutions of lithium perchlorate in propylene carbonate and in a mixture of propylene carbonate and acetonitrile were used as the electrolytes. Some typical galvanostatic discharge curves are shown for sulfur dioxide reduction at porous electrodes. The discharge capacity increases with increasing electrode porosity and decreasing current density. One can see when comparing the curves that the discharge capacities differ substantially for highly porous electrodes which had practically the same porosity of about 70%. The effect of current density is more important in solutions with a high SO/sub 2/ concentration. The operating efficiency of porous electrodes which serve as cathodes in high power Li-SO/sub 2/ power sources can be predicted on the basis of polorization curves for the porous electrodes which reflect the influence of macrostructure on the cathodic process.

Shembel, E.M.; Danilova, N.P.; Ksenzhek, O.S.

1986-03-01T23:59:59.000Z

52

Standard specification for sintered gadolinium oxide-uranium dioxide pellets  

E-Print Network [OSTI]

1.1 This specification is for finished sintered gadolinium oxide-uranium dioxide pellets for use in light-water reactors. It applies to gadolinium oxide-uranium dioxide pellets containing uranium of any 235U concentration and any concentration of gadolinium oxide. 1.2 This specification recognizes the presence of reprocessed uranium in the fuel cycle and consequently defines isotopic limits for gadolinium oxide-uranium dioxide pellets made from commercial grade UO2. Such commercial grade UO2 is defined so that, regarding fuel design and manufacture, the product is essentially equivalent to that made from unirradiated uranium. UO2 falling outside these limits cannot necessarily be regarded as equivalent and may thus need special provisions at the fuel fabrication plant or in the fuel design. 1.3 This specification does not include (1) provisions for preventing criticality accidents or (2) requirements for health and safety. Observance of this specification does not relieve the user of the obligation to be aw...

American Society for Testing and Materials. Philadelphia

2008-01-01T23:59:59.000Z

53

Longitudinal study of children exposed to sulfur oxides  

SciTech Connect (OSTI)

This study is a longitudinal comparison of the health of children exposed to markedly different concentrations of sulfur dioxide and moderately different concentrations of particulate sulfate. The four groups of subjects lived in two areas of one smelter town and in two other towns, one of which was also a smelter town. In the area of highest pollution, children were intermittently exposed to high SO/sub 2/ levels (peak three-hour average concentration exceeded 2,500 micrograms/m3) and moderate particulate SO/sub 4/= levels (average concentration was 10.1 micrograms/m3). When the children were grouped by the four gradients of pollution observed, the prevalence of cough (measured by questionnaire) correlated significantly with pollution levels (trend chi-square = 5.6, p = 0.02). No significant differences in the incidence of cough or other symptoms occurred among the groups of subjects over three years, and pulmonary function and lung function growth over the study were roughly equal among all the groups. These results suggest that intermittent elevations in SO/sub 2/ concentration, in the presence of moderate particulate SO/sub 4/= concentration, produced evidence of bronchial irritation in the subjects, but no chronic effect on lung function or lung function growth was detected.

Dodge, R.; Solomon, P.; Moyers, J.; Hayes, C.

1985-05-01T23:59:59.000Z

54

Remote measurement of sulfur dioxide emissions using an ultraviolet light sensitive video system  

SciTech Connect (OSTI)

Remote measurements of SO/sub 2/ emissions and plume velocities were made with a portable ultraviolet light-sensitive video system and compared with EPA in-stack compliance measurement methods. The instrument system measures the ultraviolet light absorption of SO/sub 2/ and movement of SO/sub 2/ fluctuations in the effluent plume and relates these measurements to the SO/sub 2/ concentration and velocity of the plume. Laboratory and field tests were conducted to establish the potential for using this technique for rapid surveillance of SO/sub 2/ emissions. The effects caused by submicron aerosols also were investigated. The field tests were performed on two occasions. On the first occasion, SO/sub 2/ and plume velocity measurements were made at a typical coal-fired power plant with flue gas desulfurization (FGD) controls (concentrations ranged from 80 to 365 ppm). The second occasion involved participation in an urban particulate modeling study, which resulted in routine SO/sub 2/ emission measurements performed at 12 industrial sites. The results of smoke generator and field tests indicate that the sulfur dioxide concentration of smoke stack emissions can be made with an accuracy less than +/-120 ppm (relative to the EPA stack test compliance method), provided the particulate opacity of the emissions is less than 22 percent. The velocity measurement feature of the instrument correlated poorly with the EPA compliance method for stack gas velocity.

McElhoe, H.B.; Conner, W.D.

1986-01-01T23:59:59.000Z

55

Health status and sulfur dioxide exposure of nickel smelter workers and civic laborers  

SciTech Connect (OSTI)

We examined a group of 143 nickel smelter workers who processed a high sulfide ore, and compared their health status with that of 117 civic laborers. All subjects were studied over the first four days of a week of work, administering a health questionnaire on day 1, measuring their pulmonary function on the morning of day 1 and day 4, and monitoring their personal exposure to SO/sub 2/ and particulates over the same period. The smelter workers were exposed to an average of 0.374 mg/m/sup 3/ of respirable particulates, a threefold higher level than the controls, and to 0.67 ppm of sulfur dioxide, a 40-fold greater amount than the controls, but were found to show no excess of chronic respiratory symptoms and did not differ from the controls either in their baseline pulmonary function or in their change from the morning of day 1 to day 4. However, there were several indicators of a healthy worker effect in the smelter worker group.

Broder, I.; Smith, J.W.; Corey, P.; Holness, L.

1989-04-01T23:59:59.000Z

56

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India  

E-Print Network [OSTI]

High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

Chatterjee, A.

57

Elemental sulfur recovery process  

DOE Patents [OSTI]

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

58

Novel Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

One of the unique advantages of SOFCs over other types of fuel cells is the potential for direct utilization of hydrocarbon fuels (it may involve internal reforming). Unfortunately, most hydrocarbon fuels contain sulfur, which would dramatically degrade SOFC performance at parts-per-million (ppm) levels. Low concentration of sulfur (ppm or below) is difficult to remove efficiently and cost-effectively. Therefore, knowing the exact poisoning process for state-of-the-art anode-supported SOFCs with Ni-YSZ cermet anodes, understanding the detailed anode poisoning mechanism, and developing new sulfur-tolerant anodes are essential to the promotion of SOFCs that run on hydrocarbon fuels. The effect of cell operating conditions (including temperature, H{sub 2}S concentration, cell voltage/current density, etc.) on sulfur poisoning and recovery of nickel-based anode in SOFCs was investigated. It was found that sulfur poisoning is more severe at lower temperature, higher H{sub 2}S concentration or lower cell current density (higher cell voltage). In-situ Raman spectroscopy identified the nickel sulfide formation process on the surface of a Ni-YSZ electrode and the corresponding morphology change as the sample was cooled in H{sub 2}S-containing fuel. Quantum chemical calculations predicted a new S-Ni phase diagram with a region of sulfur adsorption on Ni surfaces, corresponding to sulfur poisoning of Ni-YSZ anodes under typical SOFC operating conditions. Further, quantum chemical calculations were used to predict the adsorption energy and bond length for sulfur and hydrogen atoms on various metal surfaces. Surface modification of Ni-YSZ anode by thin Nb{sub 2}O{sub 5} coating was utilized to enhance the sulfur tolerance. A multi-cell testing system was designed and constructed which is capable of simultaneously performing electrochemical tests of 12 button cells in fuels with four different concentrations of H{sub 2}S. Through systematical study of state-of-the-art anode-supported SOFC button cells, it is seen that the long-term sulfur poisoning behavior of those cells indicate that there might be a second-stage slower degradation due to sulfur poisoning, which would last for a thousand hour or even longer. However, when using G-18 sealant from PNNL, the 2nd stage poisoning was effectively prohibited.

Lei Yang; Meilin Liu

2008-12-31T23:59:59.000Z

59

Prevalence of persistent cough and phlegm in young adults in relation to long-term ambient sulfur oxide exposure  

SciTech Connect (OSTI)

In early 1976, a survey of persistent co gh and plegma (PCP) prevalence was conducted in 5623 young adults in four Utah communities. Over the previous five years, community specific mean sulfur dioxide levels had been 11, 18, 36, and 115 ug/mT. Corresponding mean suspended sulfate levels had been 5, 7, 8, and 14 g/mT No intercommunity exposure gradient of total suspended particulates or suspended nitrates was observed. In mothers, PCP prevalence among non-smokers was 4.2% in the high-exposure community and about 2.0% in all other communities. In smoking mothers, PCP prevalence was 21.8% in the high-exposure community and about 15.0% elsewhere. In fathers, PCP prevalence among non-smokers was about 8.0% in the high-exposure community and averaged about 3.0% elsewhere. In smoking fathers, PCP prevalence was less strongly associated with sulfur oxide exposure. PCP prevalence rates estimated in a categorical logistic regression model were qualitatively consistent with the prevalences presented above.

Chapman, R.S.; Calafiore, D.C.; Hasselblad, V.

1985-01-01T23:59:59.000Z

60

Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light  

E-Print Network [OSTI]

) or directly through adsorbed nitrogen and hydrogen atoms (11, 12). Ammonia emissions from tunnel studies have mea- surements than all other data combined. Sulfur compounds in gasoline combust in the engine to help facilitate the stringent 2007 diesel engine emission requirements. These reductions

Denver, University of

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Development of a new FGD process that converts sulfur dioxide to salable ammonium phosphate fertilizer  

SciTech Connect (OSTI)

Rich mineral resources have enabled Chinese coal output and energy consumption to rank second and third in the world, respectively. In 1992, up to 70 percent of the country`s electric power was generated by the combustion of some 300 million tons of coal. Although the average sulfur content level in Chinese coals is only about 0.8 percent, the share of high- sulfur coals with 2 percent or more sulfur content is as high as 18 percent. As a result, air pollution accompanied by acid rain now occurs over most of the country, especially in southwestern China. Currently, the area comprising Guangdong, Guangxi, the Sichuan Basin, and the greater part of Gueizhou, where the sulfur content in coal is between 2 and 7 percent and the average pH values of rain water are between 4 and 5 per annum, has become one of the three biggest acid rain-affected areas in the world. In 1992, the national installed coal-fired electricity generation capacity exceeded 100,000 MWe. By the year 2000, it is expected to reach as much as 200,000 MWe, according to a new scheduled program. Environmental pollution caused by large-scale coal combustion is a very important issue that needs to be considered in the implementation of the program. To ensure that the effects of coal-fired power generation on the environment can be properly controlled in the near future, TPRI (Thermal Power Research Institute), the sole thermal power engineering research institution within the Ministry of Electric Power Industry (MOEPI), has conducted a long-term research program to develop sulfur emission control technologies suitable to the special conditions prevalent in China since the early 1970s. The details are summarized. The objective of this chapter is to describe the fundamental concept and major pilot test results and present an economic evaluation of a new process combining flue gas desulfurization (FGD) and ammonium phosphate fertilizer production.

Ji-lu Chen

1993-12-31T23:59:59.000Z

62

ADVANCED SULFUR CONTROL CONCEPTS  

SciTech Connect (OSTI)

Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

2003-01-01T23:59:59.000Z

63

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India*  

E-Print Network [OSTI]

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India* A.L. Ganesan Program on the Science and Policy of Global Change combines cutting-edge scientific research with independent policy analysis to provide a solid foundation for the public and private decisions needed

64

RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

Hobbs, D.

2010-07-22T23:59:59.000Z

65

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline Gallium Oxide

66

Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream  

DOE Patents [OSTI]

A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

Cohen, M.R.; Gal, E.

1993-04-13T23:59:59.000Z

67

Abatement of Air Pollution: Control of Sulfur Dioxide Emissions from Power  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' ResearchThe Office of FossilMembershipoftheManagementHasdecDioxidePlants and Other

68

Development of a countercurrent multistage fluidized-bed reactor and mathematical modeling for prediction of removal efficiency of sulfur dioxide from flue gases  

SciTech Connect (OSTI)

A bubbling countercurrent multistage fluidized-bed reactor for the sorption of sulfur dioxide by hydrated lime particles was simulated employing a two-phase model, with the bubble phase assumed to be in plug flow and with the emulsion phase either in plug flow (EGPF model) or in perfectly mixed flow (EGPM model). The model calculations were compared with experimental data in term of percentage removal efficiency of sulfur dioxide. Both models were applied to understand the influence of operating parameters on the reactor performance. The comparison showed that the EGPF model agreed well with the experimental data. From the perspective of use of a multistage fluidized-bed reactor as air pollution control equipment in industry, the model could be considered general enough for predicting the performance of reactors for gas-solid treatment.

Mohanty, C.R.; Malavia, G.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

2009-02-15T23:59:59.000Z

69

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

2000-04-10T23:59:59.000Z

70

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded research of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures.

Ates Akyurtlu; Jale F. Akyurtlu

1999-11-30T23:59:59.000Z

71

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

Akyurtlu, A.; Akyurtlu, J.F.

1999-03-31T23:59:59.000Z

72

Ground level concentration of sulfur dioxide at Kuwait`s major population centers during the oil-field fires  

SciTech Connect (OSTI)

During the Iraqi occupation, Kuwait`s oil wells were ignited. the fires were damaging to the country`s oil resources and air quality. The impact of the oil-field fires on the air quality was studied to determine the level of exposure to pollutants in major population centers. The period of July-September 1991 was selected for examination. A mathematical model was used to compute the ground-level concentration isopleths. The results of these computations are supported by significant concentrations measured and reported by the Environmental Protection Council, Kuwait. The ground-level concentrations of sulfur dioxide in the major population centers, whether measure or estimated, were less than the ambient standards of the U.S. Environmental Protection Agency`s air pollution index. The dispersive characteristics were classified according to wind conditions. The results of this assessment provide historical data on Kuwait`s oil fires and may be useful in assessing risks resulting from this catastrophe. 6 refs., 10 fig., 2 tab.

Al-Ajmi, D.N.; Marmoush, Y.R. [Kuwait Institute for Scientific Research (Kuwait)] [Kuwait Institute for Scientific Research (Kuwait)

1996-08-01T23:59:59.000Z

73

Standard test methods for analysis of sintered gadolinium oxide-uranium dioxide pellets  

E-Print Network [OSTI]

1.1 These test methods cover procedures for the analysis of sintered gadolinium oxide-uranium dioxide pellets to determine compliance with specifications. 1.2 The analytical procedures appear in the following order: Section Carbon (Total) by Direct CombustionThermal Conductivity Method C1408 Test Method for Carbon (Total) in Uranium Oxide Powders and Pellets By Direct Combustion-Infrared Detection Method Chlorine and Fluorine by Pyrohydrolysis Ion-Selective Electrode Method C1502 Test Method for Determination of Total Chlorine and Fluorine in Uranium Dioxide and Gadolinium Oxide Gadolinia Content by Energy-Dispersive X-Ray Spectrometry C1456 Test Method for Determination of Uranium or Gadolinium, or Both, in Gadolinium Oxide-Uranium Oxide Pellets or by X-Ray Fluorescence (XRF) Hydrogen by Inert Gas Fusion C1457 Test Method for Determination of Total Hydrogen Content of Uranium Oxide Powders and Pellets by Carrier Gas Extraction Isotopic Uranium Composition by Multiple-Filament Surface-Ioni...

American Society for Testing and Materials. Philadelphia

2006-01-01T23:59:59.000Z

74

Catalyst for elemental sulfur recovery process  

DOE Patents [OSTI]

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

75

Effects of reactive element additions and sulfur removal on the oxidation behavior of FECRAL alloys  

SciTech Connect (OSTI)

The results of this study have shown that desulfurization of FeCrAl alloys by hydrogen annealing can result in improvements in cyclic oxidation comparable to that achieved by doping with reactive elements. Moreover, specimens of substantial thicknesses can be effectively desulfurized because of the high diffusivity of sulfur in bcc iron alloys. The results have also shown that there is less stress generation during the cyclic oxidation of Y-doped FeCrAl compared to Ti-doped or desulfurized FeCrAl. This indicates that the growth mechanism, as well as the strength of the oxide/alloy interface, influences the ultimate oxidation morphology and stress state which will certainly affect the length of time the alumina remains protective.

Stasik, M.C.; Pettit, F.S.; Meier, G.H. (Univ. of Pittsburgh, PA (United States). Dept. of Materials Science and Engineering); Ashary, A. (Praxair, Indianapolis, IN (United States)); Smialek, J.L. (NASA Lewis Research Center, Cleveland, OH (United States))

1994-12-15T23:59:59.000Z

76

Zinc-catalyzed copolymerization of carbon dioxide and propylene oxide  

E-Print Network [OSTI]

dioxide has recently been paid attention in the field of extraction, separation, and reaction medium, its aptitude for both a reaction solvent and a reactant was examined in zinc glutarate-catalyzed reactions. As a result, it was proved that supercritical...

Katsurao, Takumi

1994-01-01T23:59:59.000Z

77

Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

K.C. Kwon

2005-11-01T23:59:59.000Z

78

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

79

Comparison of thermoelectric and permeation dryers for sulfur dioxide removal during sample conditioning of wet gas streams  

SciTech Connect (OSTI)

Flue gas conditioning for moisture removal is commonly performed for criteria pollutant measurements, in particular for extractive CEM systems at combustion sources. An implicit assumption is that conditioning systems specifically remove moisture without affecting pollutant and diluent concentrations. Gas conditioning is usually performed by passing the flue gas through a cold trap (Peltier or thermoelectric dryer) to remove moisture by condensation, which is subsequently extracted by a peristaltic pump. Many air pollutants are water-soluble and potentially susceptible to removal in a condensation dryer from gas interaction with liquid water. An alternative technology for gas conditioning is the permeation dryer, where the flue gas passes through a selectively permeable membrane for moisture removal. In this case water is transferred through the membrane while other pollutants are excluded, and the gas does not contact condensed liquid. Laboratory experiments were performed to measure the relative removal of a water-soluble pollutant (sulfur dioxide, SO{sub 2}) by the two conditioning techniques. A wet gas generating system was used to create hot, wet gas streams of known composition (15% and 30% moisture, balance nitrogen) and flow rate. Pre-heated SO{sub 2} was dynamically spiked into the wet stream using mass flow meters to achieve concentrations of 20, 50, and 100 ppm. The spiked gas was directed through a heated sample line to either a thermoelectric or a permeation conditioning system. Two gas analyzers (Western Research UV gas monitor, KVB/Analect FTIR spectrometer) were used to measure the SO{sub 2} concentration after conditioning. Both analytic methods demonstrated that SO{sub 2} is removed to a significantly greater extent by the thermoelectric dryer. These results have important implications for SO{sub 2} monitoring and emissions trading.

Dunder, T.A. [Entropy, Inc., Research Triangle Park, NC (United States). Research Div.; Leighty, D.A. [Perma Pure, Inc., Toms River, NJ (United States)

1997-12-31T23:59:59.000Z

80

Transition metal-promoted oxygen ion conductors as oxidation catalyst  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the complete oxidation of carbon monoxide and hydrocarbons was prepared by combining oxygen ion conducting materials with active transition metals. The oxygen ion conductors used were typical fluorite-type oxides, such as ceria, zirconia, and others. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of oxygen ion conductors. The intimate contact of the two kinds of materials gave rise to a highly active oxidation catalyst. On Cu-Ce-O composite catalysts, 95% of carbon monoxide was oxidized by air at {approximately} 100 C. Complete methane oxidation on the same catalyst took place at {approximately} 550 C. When the stoichiometric amount of sulfur dioxide was sued to oxidize carbon monoxide, 96% of sulfur dioxide was reduced to elemental sulfur at temperatures above 460 C with 99% of sulfur dioxide conversion. This type of composite catalyst also showed excellent resistance to water poisoning.

Liu, W.; Sarofim, A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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81

Sulfuric acid-sulfur heat storage cycle  

DOE Patents [OSTI]

A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

Norman, John H. (LaJolla, CA)

1983-12-20T23:59:59.000Z

82

Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur  

SciTech Connect (OSTI)

Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 şC to ~750 şC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

Ziomek-Moroz, M.; Hawk, Jeffrey A.

2005-01-01T23:59:59.000Z

83

METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY  

SciTech Connect (OSTI)

HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

2009-06-22T23:59:59.000Z

84

INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}.

Ates Akyurtlu; Jale F. Akyurtle

2001-08-01T23:59:59.000Z

85

High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor  

SciTech Connect (OSTI)

Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

2011-07-31T23:59:59.000Z

86

Lubricant oil consumption effects on diesel exhaust ash emissions using a sulfur dioxide trace technique and thermogravimetry  

E-Print Network [OSTI]

A detailed experimental study was conducted targeting lubricant consumption effects on ,diesel exhaust ash levels using a model year 2002 5.9L diesel engine, high and low Sulfur commercial lubricants, and clean diesel ...

Plumley, Michael J

2005-01-01T23:59:59.000Z

87

Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants  

E-Print Network [OSTI]

sulfur content is highly dependent upon coal type. In gen~ral, conventional coal cleaning does not effect sufficient sulfur reduction to permit combustion without! i additional flue gas desulfurization. Several novel technologies now under development..., or equilibrium limita tions requires that super stoichiometric quantities of CaO be charged to the boiler. Operationally the introduction of large amounts of calcium additive can pose increased problems due to slagging and fouling in the combustion chamber...

Schwartz, M. H.

1979-01-01T23:59:59.000Z

88

Method of and apparatus for removing sulfur oxides from exhaust gases formed by combustion  

SciTech Connect (OSTI)

A process is described for removing sulfur oxides from exhaust gas formed by combustion particularly exhaust gas from an electricity generating power plant. The exhaust gas flows through a reaction zone which operates like a spray dryer. A purifying liquor consisting of an aqueous solution of sodium carbonate and/or sodium bicarbonate is sprayed into the reaction zone, in which the heat content of the exhaust gases causes virtually all of the water content of the purifying liquor to be evaporated. The exhaust gas is subsequently passed through a filter. Anhydrous solids are withdrawn from the reaction zone and the filter and contain at least 75% of sodium sulfite, sodium sulfate and sodium chloride and are processed to form sodium carbonate. To that end the solids are dissolved and sulfite is oxidized to form sulfate so that a solution that contains sodium sulfate and sodium chloride is formed. The sulfate is separated from that solution and the remaining solution is used in the recovery of sodium carbonate by the solvay process.

Voeste, T.

1981-01-27T23:59:59.000Z

89

Effects of ambient sulfur oxides and suspended particles on respiratory health of preadolescent children  

SciTech Connect (OSTI)

Reported here are the results from an ongoing study of outdoor air pollution and respiratory health of children living in six cities in the eastern and midwestern United States. The study enrolled 10,106 white preadolescent children between 1974 and 1977 in 3 successive annual visits to each city. Each child received a spirometric examination, and a parent completed a standard questionnaire. Of this cohort, 8,380 children were seen for a second examination 1 yr later. An air pollution monitoring program was begun in each community at about the time of the first examination. For this report, measurements of total suspended particulates (TSP), the sulfate fraction of TSP (TSO/sub 4/), and sulfur dioxide (SO2) concentrations at study-affiliated outdoor stations were combined with measurements at other public and private monitoring sites to create a record of TSP, TSO/sub 4/, and SO/sub 2/ concentrations in each of 9 air pollution regions during the 1-yr period preceding each examination and, for TSP, during each child's lifetime up to the time of testing. Across the 6 cities, frequency of cough was significantly associated with the average of 24-h mean concentrations of all 3 air pollutants during the year preceding the health examination (p less than 0.01). Rates of bronchitis and a composite measure of lower respiratory illness were significantly associated with average particulate concentrations (p less than 0.05). In analyses restricted to lifetime residents, these outcomes were significantly associated with measures of lifetime mean TSP concentration. Within the cities, however, temporal and spatial variation in air pollutant concentrations and illness and symptom rates were not positively associated.

Ware, J.H.; Ferris, B.G. Jr.; Dockery, D.W.; Spengler, J.D.; Stram, D.O.; Speizer, F.E.

1986-05-01T23:59:59.000Z

90

Sulfur-tolerant anode materials for solid oxide fuel cell application  

SciTech Connect (OSTI)

This paper summarizes the degradation mechanisms for SOFC anodes in the presence of sulfur and recent developments in sulfur-tolerant anodes. There are two primary sulfur-degradation mechanisms for the anode materials: physical absorption of sulfur that blocks the hydrogen reaction sites, and chemical reaction that forms nickel sulfide. The sulfur-tolerant anodes are categorized into three kinds of materials: thiospinels and metal sulfides, metal cermets, and mixed ionic and electronic conductors. Each material has its own advantages and disadvantages, and the combined application of available materials to serve as different functional components in anodes through proper design may be effective to achieve a balance between stability and performance.

Gong, M. (West Virginia University, Morgantown, WV); Liu, X. (West Virginia University, Morgantown, WV); Trembly, J.; Johnson, C.

2007-06-01T23:59:59.000Z

91

Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides  

DOE Patents [OSTI]

A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

Ramkumar, Shwetha; Fan, Liang-Shih

2013-07-30T23:59:59.000Z

92

Sulfur Versus Iron Oxidation in an Iron-Thiolate Model Complex  

SciTech Connect (OSTI)

In the absence of base, the reaction of [Fe{sup II}(TMCS)]PF{sub 6} (1, TMCS = 1-(2-mercaptoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane) with peracid in methanol at -20 C did not yield the oxoiron(IV) complex (2, [Fe{sup IV}(O)(TMCS)]PF{sub 6}), as previously observed in the presence of strong base (KO{sup t}Bu). Instead, the addition of 1 equiv of peracid resulted in 50% consumption of 1. The addition of a second equivalent of peracid resulted in the complete consumption of 1 and the formation of a new species 3, as monitored by UV-vis, ESI-MS, and Moessbauer spectroscopies. ESI-MS showed 3 to be formulated as [Fe{sup II}(TMCS) + 2O]{sup +}, while EXAFS analysis suggested that 3 was an O-bound iron(II)-sulfinate complex (Fe-O = 1.95 {angstrom}, Fe-S = 3.26 {angstrom}). The addition of a third equivalent of peracid resulted in the formation of yet another compound, 4, which showed electronic absorption properties typical of an oxoiron(IV) species. Moessbauer spectroscopy confirmed 4 to be a novel iron(IV) compound, different from 2, and EXAFS (Fe{double_bond}O = 1.64 {angstrom}) and resonance Raman ({nu}{sub Fe{double_bond}O} = 831 cm{sup -1}) showed that indeed an oxoiron(IV) unit had been generated in 4. Furthermore, both infrared and Raman spectroscopy gave indications that 4 contains a metal-bound sulfinate moiety ({nu}{sub s}(SO{sub 2}) {approx} 1000 cm{sup -1}, {nu}{sub as}(SO{sub 2}) {approx} 1150 cm{sup -1}). Investigations into the reactivity of 1 and 2 toward H{sup +} and oxygen atom transfer reagents have led to a mechanism for sulfur oxidation in which 2 could form even in the absence of base but is rapidly protonated to yield an oxoiron(IV) species with an uncoordinated thiol moiety that acts as both oxidant and substrate in the conversion of 2 to 3.

A McDonald; M Bukowski; E Farquhar; T Jackson; K Koehntop; M Seo; R De Hont; A Stubna; J Halfen; E Munck

2011-12-31T23:59:59.000Z

93

Carbon dioxide adsorbents containing magnesium oxide suitable for use at high temperatures  

DOE Patents [OSTI]

Adsorption of carbon dioxide from gas streams at temperatures in the range of 300 to 500.degree. C. is carried out with a solid adsorbent containing magnesium oxide, preferably promoted with an alkali metal carbonate or bicarbonate so that the atomic ratio of alkali metal to magnesium is in the range of 0.006 to 2.60. Preferred adsorbents are made from the precipitate formed on addition of alkali metal and carbonate ions to an aqueous solution of a magnesium salt. Atomic ratios of alkali metal to magnesium can be adjusted by washing the precipitate with water. Low surface area adsorbents can be made by dehydration and CO.sub.2 removal of magnesium hydroxycarbonate, with or without alkali metal promotion. The process is especially valuable in pressure swing adsorption operations.

Mayorga, Steven Gerard (Allentown, PA); Weigel, Scott Jeffrey (Allentown, PA); Gaffney, Thomas Richard (Allentown, PA); Brzozowski, Jeffrey Richard (Macungie, PA)

2001-01-01T23:59:59.000Z

94

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect (OSTI)

During this quarter, progress was made on the following tasks: TPD techniques were employed to study the reaction mechanism of the selective catalytic reduction of nitrogen oxide with ammonia over iron oxide pillared clay catalyst; and a sulfur dioxide resistant iron oxide/titanium oxide catalyst was developed.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

95

Sulfur adsorption on nickel(100) and its effect on carbon monoxide, nitric oxide, and deuterium chemisorption  

SciTech Connect (OSTI)

The adsorption of CO, NO, and D/sub 2/ was studied on clean and sulfided Ni(100) near 100K using Auger electron spectroscopy, thermal desorption spectroscopy, X-ray and ultraviolet photoelectron spectroscopies, and work function change measurements. The evidence suggests that sulfur's effects are predominantly steric in nature. Weak, short-range (approx.4 angstrom) electrostatic effects are also present, due to charge transfer of about 0.04 of an electron from nickel to sulfur. The blocking effect of S on the adsorption of each gas at various temperatures is discussed.

Hardegree, E.L.

1985-01-01T23:59:59.000Z

96

Photocatalytic and chemical oxidation of organic compounds in supercritical carbon dioxide. Progress report for FY97  

SciTech Connect (OSTI)

'The background for the project is briefly reviewed and the work done during the nine months since funding was received is documented. Work began in January, 1997. A post doctoral fellow joined the team in April. The major activities completed this fiscal year were: staffing the project, design of the experimental system, procurement of components, assembly of the system. preparation of the Safe Operating Procedure and ES and H compliance, pressure testing, establishing data collection and storage methodology, and catalyst preparation. Objective The objective of the project is to develop new chemistry for the removal of organic contaminants from supercritical carbon dioxide. This has application in processes used for continuous cleaning and extraction of parts and waste materials. A secondary objective is to increase the fundamental understanding of photocatalytic chemistry. Cleaning and extraction using supercritical carbon dioxide (scCO{sub 2}) can be applied to the solution of a wide range of environmental and pollution prevention problems in the DOE complex. Work is being done that explores scCO{sub 2} in applications ranging from cleaning contaminated soil to cleaning components constructed from plutonium. The rationale for use of scCO{sub 2} are based on the benign nature, availability and low cost, attractive solvent properties, and energy efficient separation of the extracted solute from the solvent by moderate temperature or pressure changes. To date, R and D has focussed on the methods and applications of the extraction steps of the process. Little has been done that addresses methods to polish the scCO{sub 2} for recycle in the cleaning or extraction operations. In many applications it will be desirable to reduce the level of contamination from that which would occur at steady state operation of a process. This proposal addresses chemistry to achieve that. This would be an alternative to removing a fraction of the contaminated scCO{sub 2} for disposal and using makeup scCO{sub 2}. A chemical polishing operation can reduce the release of CO{sub 2} from the process. It can also reduce the consumption of reagents that may be used in the process to enhance extraction and cleaning. A polishing operation will also reduce or avoid formation of an additional waste stream. Photocatalytic and other photochemical oxidation chemistry have not been investigated in scCO{sub 2}. The large base of information for these reactions in water, organic solvents, or air suggest that the chemistry will work in carbon dioxide. There are compelling reasons to believe that the properties of scCO{sub 2} should increase the performance of photocatalytic chemistry over that found in more conventional fluid phases.'

Blake, D.M.; Bryant, D.L.; Reinsch, V.

1997-09-30T23:59:59.000Z

97

Method to prevent sulfur accumulation in membrane electrode assembly  

DOE Patents [OSTI]

A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

Steimke, John L; Steeper, Timothy J; Herman, David T

2014-04-29T23:59:59.000Z

98

Method of detecting sulfur dioxide  

DOE Patents [OSTI]

(CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy.

Spicer, Leonard D. (Salt Lake City, UT); Bennett, Dennis W. (Clemson, SC); Davis, Jon F. (Salt Lake City, UT)

1985-01-01T23:59:59.000Z

99

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation  

E-Print Network [OSTI]

The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

100

KINETICS, CATALYSIS, AND REACTION ENGINEERING Nonthermal Plasma Reactions of Dilute Nitrogen Oxide Mixtures  

E-Print Network [OSTI]

for the conversion of nitrogen oxides,1,2,4-10 sulfur dioxide,11 and volatile organic car- bons.12 Despite itsKINETICS, CATALYSIS, AND REACTION ENGINEERING Nonthermal Plasma Reactions of Dilute Nitrogen Oxide Mixtures: NOx in Nitrogen Gui-Bing Zhao, Xudong Hu, Man-Chung Yeung, Ovid A. Plumb,§ and Maciej Radosz

Yeung, Man-Chung

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

CLOSEOUT REPORT FOR HYBRID SULFUR PRESSURIZED BUTTON CELL TEST FACILITY  

SciTech Connect (OSTI)

This document is the Close-Out Report for design and partial fabrication of the Pressurized Button Cell Test Facility at Savannah River National Laboratory (SRNL). This facility was planned to help develop the sulfur dioxide depolarized electrolyzer (SDE) that is a key component of the Hybrid Sulfur Cycle for generating hydrogen. The purpose of this report is to provide as much information as possible in case the decision is made to resume research. This report satisfies DOE Milestone M3GSR10VH030107.0. The HyS Cycle is a hybrid thermochemical cycle that may be used in conjunction with advanced nuclear reactors or centralized solar receivers to produce hydrogen by watersplitting. The HyS Cycle utilizes the high temperature (>800 C) thermal decomposition of sulfuric acid to produce oxygen and regenerate sulfur dioxide. The unique aspect of HyS is the generation of hydrogen in a water electrolyzer that is operated under conditions where dissolved sulfur dioxide depolarizes the anodic reaction, resulting in substantial voltage reduction. Low cell voltage is essential for both high thermodynamic efficiency and low hydrogen cost. Sulfur dioxide is oxidized at the anode, producing sulfuric acid that is sent to the high temperature acid decomposition portion of the cycle. Sulfur dioxide from the decomposer is cycled back to electrolyzers. The electrolyzer cell uses the membrane electrode assembly (MEA) concept. Anode and cathode are formed by spraying a catalyst, typically platinized carbon, on both sides of a Proton Exchange Membrane (PEM). SRNL has been testing SDEs for several years including an atmospheric pressure Button Cell electrolyzer (2 cm{sup 2} active area) and an elevated temperature/pressure Single Cell electrolyzer (54.8 cm{sup 2} active area). SRNL tested 37 MEAs in the Single Cell electrolyzer facility from June 2005 until June 2009, when funding was discontinued. An important result of the final months of testing was the development of a method that prevents the formation of a sulfur layer previously observed in MEAs used in the Hybrid Sulfur Cycle electrolyzer. This result is very important because the sulfur layer increased cell voltage and eventually destroyed the MEA that is the heart of the cell. Steimke and Steeper [2005, 2006, 2007, 2008] reported on testing in the Single Cell Electrolyzer test facility in several periodic reports. Steimke et. al [2010] issued a final facility close-out report summarizing all the testing in the Single Cell Electrolyzer test facility. During early tests, significant deterioration of the membrane occurred in 10 hours or less; the latest tests ran for at least 200 hours with no sign of deterioration. Ironically, the success with the Single Cell electrolyzer meant that it became dedicated to long runs and not available for quick membrane evaluations. Early in this research period, the ambient pressure Button Cell Electrolyzer test facility was constructed to quickly evaluate membrane materials. Its small size allowed testing of newly developed membranes that typically were not available in sizes large enough to test in the Single Cell electrolyzer. The most promising membranes were tested in the Single Cell Electrolyzer as soon as sufficient large membranes could be obtained. However, since the concentration of SO{sub 2} gas in sulfuric acid decreases rapidly with increasing temperature, the ambient pressure Button Cell was no longer able to achieve the operating conditions needed to evaluate the newer improved high temperature membranes. Significantly higher pressure operation was required to force SO{sub 2} into the sulfuric acid to obtain meaningful concentrations at increased temperatures. A high pressure (200 psig), high temperature (120 C) Button Cell was designed and partially fabricated just before funding was discontinued in June 2009. SRNL completed the majority of the design of the test facility, including preparation of a process and instrument drawing (P&ID) and preliminary designs for the major components. SRNL intended to complete the designs and procu

Steeper, T.

2010-09-15T23:59:59.000Z

102

Carbon dioxide fixation by Metallosphaera yellowstonensis and acidothermophilic iron-oxidizing microbial communities from Yellowstone National Park  

SciTech Connect (OSTI)

The fixation of inorganic carbon (as carbon dioxide) has been documented in all three domains of life and results in the biosynthesis of a diverse suite of organic compounds that support the growth of heterotrophic organisms. The primary aim of this study was to assess the importance of carbon dioxide fixation in high-temperature Fe(III)-oxide mat communities and in pure cultures of one of the dominant Fe(II)-oxidizing organisms (Metallosphaera yellowstonensis strain MK1) present in situ. Protein-encoding genes of the complete 3-hydroxypropionate/4-hydroxybutyrate (3-HP/4-HB) carbon fixation pathway were identified in pure-cultures of M. yellowstonensis strain MK1. Metagenome sequencing from the same environments also revealed genes for the 3-HP/4-HB pathway belonging to M. yellowstonensis populations, as well as genes for a complete reductive TCA cycle from Hydrogenobaculum spp. (Aquificales). Stable isotope (13CO2) labeling was used to measure the fixation of CO2 by M. yellowstonensis strain MK1, and in ex situ assays containing live Fe(III)-oxide microbial mats. Results showed that M. yellowstonensis strain MK1 fixes CO2 via the 3-HP/4-HB pathway with a fractionation factor of ~ 2.5 ‰. Direct analysis of the 13C composition of dissolved inorganic C (DIC), dissolved organic C (DOC), landscape C and microbial mat C showed that mat C is comprised of both DIC and non-DIC sources. The estimated contribution of DIC carbon to biomass C (> ~ 35%) is reasonably consistent with the relative abundance of known chemolithoautotrophs and corresponding CO2 fixation pathways detected in metagenome sequence. The significance of DIC as a major source of carbon for Fe-oxide mat communities provides a foundation for examining microbial interactions in these systems that are dependent on the activity of autotrophic organisms such as Hydrogenobaculum and Metallosphaera spp.

Jennings, Ryan; Whitmore, Laura M.; Moran, James J.; Kreuzer, Helen W.; Inskeep, William P.

2014-05-01T23:59:59.000Z

103

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation .  

E-Print Network [OSTI]

??The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test… (more)

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

104

Advanced byproduct recovery: Direct catalytic reduction of SO{sub 2} to elemental sulfur. First quarterly technical progress report, [October--December 1995  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation will be conducting Phase I of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. this catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria or zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an ongoing DOE-sponsored University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicates that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. the performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

Benedek, K. [Little (Arthur D.), Inc., Cambridge, MA (United States); Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States)

1996-02-01T23:59:59.000Z

105

Transferring oxygen isotopes to 1,2,4-benzotriazine 1-oxides forming the corresponding 1,4-dioxides by using the HOF$CH3CN complex  

E-Print Network [OSTI]

Transferring oxygen isotopes to 1,2,4-benzotriazine 1-oxides forming the corresponding 1,4-dioxides Available online 14 August 2012 Keywords: Oxygen transfer 18 O isotope Tirapazamine HOF$CH3CN F2/N2 N is their ability to capitalize on the low oxygen (hypoxic) environment found in many solid tumors. The lead

Gates, Kent. S.

106

Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides. Semiannual report, Apr 1, 1998--Oct 31, 1998  

SciTech Connect (OSTI)

Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823--900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4} air mixtures. The sorbents consisting of cerium oxide and copper oxide impregnated on alumina have been prepared and characterized. Their sulfation performance has been investigated in a TGA setup, studying mainly the effects of temperature and sorbent composition. The results of the sulfation experiments have been evaluated and presented in this report. A study to model the sulfation selectivity of the two constituents of the sorbents is also underway.

Dr. Ates Akyurtlu; Dr. Jale F. Akyurtlu

1998-10-31T23:59:59.000Z

107

Diphosphine Dioxide Cages and Hydrogen Peroxide Adducts of Phosphine Oxides: Syntheses and Applications in Surface Science  

E-Print Network [OSTI]

and in HRMAS NMR spectra the reduction of the originally large CSA, the residual halfwidth, as well as the downfield shift of the signals when adsorbing phosphine oxides on silica surfaces are most indicative. This research provides new insights regarding...

Hilliard, Casie Renee

2013-12-09T23:59:59.000Z

108

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect (OSTI)

This second quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. Previous reports described development of a catalyst with the required selectivity and efficiency for producing sulfur dioxide from H{sub 2}S. In the laboratory, the catalyst was shown to be robust and stable in the presence of several intentionally added contaminants, including condensate from the pilot plant site. This report describes testing using the laboratory apparatus but operated at the pilot plant using the actual pilot plant gas, which contains far more contaminants than can be simulated in the laboratory. The results are very encouraging, with stable and efficient operation being obtained for a prolonged period of time.

Girish Srinivas; Steven C. Gebhard; David W. DeBerry

2002-07-01T23:59:59.000Z

109

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

110

Dissolution of metal oxides and separation of uranium from lanthanides and actinides in supercritical carbon dioxide  

SciTech Connect (OSTI)

This paper investigates the feasibility of extracting and separating uranium from lanthanides and other actinides by using supercritical fluid carbon dioxide (sc-CO{sub 2}) as a solvent modified with tri-n-butylphosphate (TBP) for the development of a counter current stripping technique, which would be a more efficient and environmentally benign technology for spent nuclear fuel reprocessing compared to traditional solvent extraction. Several actinides (U, Pu, and Np) and europium were extracted in sc-CO{sub 2} modified with TBP over a range of nitric acid concentrations and then the actinides were exposed to reducing and complexing agents to suppress their extractability. According to this study, uranium/europium and uranium/plutonium extraction and separation in sc-CO{sub 2} modified with TBP is successful at nitric acid concentrations of less than 6 M and at nitric acid concentrations of less than 3 M with acetohydroxamic acid or oxalic acid, respectively. A scheme for recycling uranium from spent nuclear fuel by using sc-CO{sub 2} and counter current stripping columns is presented. (authors)

Quach, D.L.; Wai, C.M. [Department of Chemistry, University of Idaho, Moscow, Idaho 83844 (United States); Mincher, B.J. [Idaho National Lab, Idaho Falls, Idaho (United States)

2013-07-01T23:59:59.000Z

111

DISSOLUTION OF METAL OXIDES AND SEPARATION OF URANIUM FROM LANTHANIDES AND ACTINIDES IN SUPERCRITICAL CARBON DIOXIDE  

SciTech Connect (OSTI)

This paper investigates the feasibility of extracting and separating uranium from lanthanides and other actinides by using supercritical fluid carbon dioxide (sc-CO2) as a solvent modified with tri-n-butylphosphate (TBP) for the development of a counter current stripping technique, which would be a more efficient and environmentally benign technology for spent nuclear fuel reprocessing compared to traditional solvent extraction. Several actinides (U, Pu, and Np) and europium were extracted in sc-CO2 modified with TBP over a range of nitric acid concentrations and then the actinides were exposed to reducing and complexing agents to suppress their extractability. According to this study, uranium/europium and uranium/plutonium extraction and separation in sc-CO2 modified with TBP is successful at nitric acid concentrations of less than 6 M and at nitric acid concentrations of less than 3 M with acetohydroxamic acid or oxalic acid, respectively. A scheme for recycling uranium from spent nuclear fuel by using sc-CO2 and counter current stripping columns is presented.

Donna L. Quach; Bruce J. Mincher; Chien M. Wai

2013-10-01T23:59:59.000Z

112

REDUCTION AND SEQUESTRATION OF PERTECHNETATE TO TECHNETIUM DIOXIDE AND PROTECTION FROM RE-OXIDATION  

SciTech Connect (OSTI)

This effort is part of the technetium management initiative and provides data for the handling and disposition of technetium. To that end, the objective of this effort was to challenge tin(II)apatite (Sn(II)apatite) against double-shell tank 241-AN-I0S simulant spiked with pertechnetate (TcO{sub 4}{sup -}). The Sn(II)apatite used in this effort was synthesized on site using a recipe developed at and provided by Sandia National Laboratories; the synthesis provides a high quality product while requiring minimal laboratory effort. The Sn(II)apatite reduces pertechnetate from the mobile +7 oxidation state to the non-mobile +4 oxidation state. It also sequesters the technetium and does not allow for re-oxidization to the mobile +7 state under acidic or oxygenated conditions within the tested period of time (6 weeks). Previous work indicated that the Sn(II)apatite can achieve an ANSI leachability index in Cast Stone of 12.8. The technetium distribution coefficient for Sn(II)apatite exhibits a direct correlation with the pH of the contaminated media. Table 1 shows Sn(II)apatite distribution coefficients as a function of pH. The asterisked numbers indicate that the lower detection limit of the analytical instrument was used to calculate the distribution coefficient as the concentration of technetium left in solution was less than the detection limit.

DUNCAN JB; JOHNSON JM; MOORE WP; HAGERTY KJ; RHODES RN; MOORE RC

2012-07-11T23:59:59.000Z

113

GLOBAL BIOGEOCHEMICAL CYCLES, VOL. ???, XXXX, DOI:10.1029/, Global Dry Deposition of Nitrogen Dioxide and1  

E-Print Network [OSTI]

-DERIVED NO2 AND SO2 DRY DEPOSITION 1. Introduction Nitrogen dioxide (NO2) and sulfur dioxide (SO2) haveGLOBAL BIOGEOCHEMICAL CYCLES, VOL. ???, XXXX, DOI:10.1029/, Global Dry Deposition of Nitrogen Dioxide and1 Sulfur Dioxide Inferred from Space-Based2 Measurements3 C. R. Nowlan, 1,2 R. V. Martin, 1,2 S

Martin, Randall

114

Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming  

SciTech Connect (OSTI)

In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

Gunther Dieckmann

2006-06-30T23:59:59.000Z

115

New materials for intermediate-temperature solid oxide fuel cells to be powered by carbon- and sulfur-containing fuels.  

E-Print Network [OSTI]

??Unlike polymer electrolyte fuel cells, solid-oxide fuel cells (SOFCs) have the potential to use a wide variety of fuels, including hydrocarbons and gasified coal or… (more)

Yang, Lei

2011-01-01T23:59:59.000Z

116

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect (OSTI)

This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a portion of the inlet H{sub 2}S. Oxidation catalysts may also produce some elemental sulfur under these conditions, which can be removed and recovered prior to the CrystaSulf absorber. The CrystaSulf-DO process can utilize direct oxidation catalyst from many sources. Numerous direct oxidation catalysts are available from many suppliers worldwide. They have been used for H{sub 2}S oxidation to sulfur and/or SO{sub 2} for decades. It was believed at the outset of the project that TDA Research, Inc., a subcontractor, could develop a direct oxidation catalyst that would offer advantages over other commercially available catalysts for this CrystaSulf-DO process application. This project involved the development of several of TDA's candidate proprietary direct oxidation catalysts through laboratory bench-scale testing. These catalysts were shown to be effective for conversion of H{sub 2}S to SO{sub 2} and to elemental sulfur under certain operating conditions. One of these catalysts was subsequently tested on a commercial gas stream in a bench-scale reactor at CrystaTech's pilot plant site in west Texas with good results. However, commercial developments have precluded the use of TDA catalysts in the CrystaSulf-DO process. Nonetheless, this project has advanced direct oxidation catalyst technology for H{sub 2}S control in energy industries and led to several viable paths to commercialization. TDA is commercializing the use of its direct oxidation catalyst technology in conjunction with the SulfaTreat{reg_sign} solid scavenger for natural gas applications and in conjunction with ConocoPhillips and DOE for gasification applications using ConocoPhillips gasification technology. CrystaTech is commercializing its CrystaSulf-DO process in conjunction with Gas Technology Institute for natural gas applications (using direct oxidation catalysts from other commercial sources) and in conjunction with ChevronTexaco and DOE for gasification applications using ChevronTexaco's gasification technology.

Dennis Dalrymple

2004-06-01T23:59:59.000Z

117

In situ derivation of sulfur activated TiO{sub 2} nano porous layers through pulse-micro arc oxidation technology  

SciTech Connect (OSTI)

Highlights: {yields} S-TiO{sub 2} layers were grown by MAO technique under pulse current for the first time. {yields} Effect of growth parameters on chemical composition, topography, and morphology of the layers was studied. {yields} A correlation between photocatalytic performance and growth conditions was proposed. -- Abstract: Micro arc oxidation technique, as a facile and efficient process, was employed to grow sulfur doped titania porous layers. This research sheds light on the photocatalytic performance of the micro arc oxidized S-TiO{sub 2} nano-porous layers fabricated under pulse current. Morphological and topographical studies, performed by SEM and AFM techniques, revealed that increasing the frequency and/or decreasing the duty cycle resulted in formation of finer pores and smoother surfaces. XRD and XPS results showed that the layers consisted of anatase and rutile phases whose fraction was observed to change depending on the synthesis conditions. The highest anatase relative content was obtained at the frequency of 500 Hz and the duty cycle of 5%. Furthermore, photocatalytic activity of the layers was examined by measuring the decomposition rate of methylene blue under both ultraviolet and visible photo irradiations. Maximum photodegradation reaction rate constants over the pulse-grown S-TiO{sub 2} layers were respectively measured as 0.0202 and 0.0110 min{sup -1} for ultraviolet and visible irradiations.

Bayati, M.R., E-mail: mbayati@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695 (United States); School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Golestani-Fard, F. [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of) [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of); Center of Excellence for Advanced Materials, Iran University of Science and Technology, P.O. Box 16845-195, Tehran (Iran, Islamic Republic of); Moshfegh, A.Z. [Department of Physics, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of) [Department of Physics, Sharif University of Technology, P.O. Box 11155-9161, Tehran (Iran, Islamic Republic of); Institute for Nanoscience and Nanotechnology, Sharif University of Technology, P.O. Box 14588-89694, Tehran (Iran, Islamic Republic of); Molaei, Roya [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of)] [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, P.O. Box 16845-161, Tehran (Iran, Islamic Republic of)

2011-10-15T23:59:59.000Z

118

Process for removing sulfur from coal  

DOE Patents [OSTI]

A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

Aida, T.; Squires, T.G.; Venier, C.G.

1983-08-11T23:59:59.000Z

119

Integrated boiler, superheater, and decomposer for sulfuric acid decomposition  

DOE Patents [OSTI]

A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

2010-01-12T23:59:59.000Z

120

Intertemporal pricing of sulfur dioxide allowances  

E-Print Network [OSTI]

The Clean Air Act Amendments of 1990 initiated the first large-scale use of the tradable permit approach to pollution control. The theoretical case for this approach rests on the assumption of an efficient market for ...

Bailey, Elizabeth M.

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision  

SciTech Connect (OSTI)

The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

1994-03-10T23:59:59.000Z

122

Bisphosphine dioxides  

DOE Patents [OSTI]

A process for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

Moloy, Kenneth G. (Charleston, WV)

1990-01-01T23:59:59.000Z

123

Bisphosphine dioxides  

DOE Patents [OSTI]

A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

Moloy, K.G.

1990-02-20T23:59:59.000Z

124

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect (OSTI)

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

125

Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium  

SciTech Connect (OSTI)

An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.

Marcalo, Joaquim; Gibson, John K.

2009-08-10T23:59:59.000Z

126

THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

Gorensek, M.; Summers, W.

2010-03-24T23:59:59.000Z

127

Sulfur minimization in bacterial leaching  

SciTech Connect (OSTI)

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

128

Surface Science Letters Bulk-defect dependent adsorption on a metal oxide surface  

E-Print Network [OSTI]

-6028(01)01067-6 #12;Titanium dioxide is a wide-band gap semicon- ductor (Egap 3 eV) that can easily be reducedSurface Science Letters Bulk-defect dependent adsorption on a metal oxide surface: S/TiO2(1 1 0) E Abstract The adsorption of molecular sulfur on TiO2(1 1 0)(1 Ă? 1) has been studied with scanning tunneling

Diebold, Ulrike

129

Nanostructured Tin Dioxide Materials for Gas Sensor Applications  

E-Print Network [OSTI]

CHAPTER 30 Nanostructured Tin Dioxide Materials for Gas Sensor Applications T. A. Miller, S. D) levels for some species. Tin dioxide (also called stannic oxide or tin oxide) semi- conductor gas sensors undergone extensive research and development. Tin dioxide (SnO2) is the most important material for use

Wooldridge, Margaret S.

130

Personal and Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma  

E-Print Network [OSTI]

1994. Nitric oxide and nitrogen dioxide: Method 6014. In:Molecular mechanisms of nitrogen dioxide induced epithelialEC, OC), and 24-hr nitrogen dioxide. Ambient exposures

2006-01-01T23:59:59.000Z

131

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures  

E-Print Network [OSTI]

6/4/2013 Page 1 of 12 Nitrogen Dioxide SOP Standard Operating Procedures Nitrogen Dioxide and Nitric Oxide Print a copy and insert into your laboratory the precautions and safe handling procedures for the use of Nitrogen Dioxide

Cohen, Ronald C.

132

A kinetic and adsorption study of CO oxidation over unsupported fine gold powder and over gold supported on titanium dioxide  

SciTech Connect (OSTI)

The catalytic oxidation of CO with O{sub 2} and adsorption of CO{sub 2} and O{sub 2} on Au deposited on TiO{sub 2} (AuTiO{sub 2}, mean diameter of gold particles 3.5 nm), TiO{sub 2}, and unsupported Au powder (mean diameter 76 nm) have been investigated by using a closed recirculation reaction system. The catalytic oxidation of CO with O{sub 2} on Au/TiO{sub 2} measured at 253--293 K proceeded very rapidly. In the same temperature range, fine gold powder was catalytically active, while TiO{sub 2} alone was entirely inactive for the oxidation. The rate constant of CO oxidation per unit of surface area of gold was larger by two orders of magnitude for Au/TiO{sub 2} than for Au powder. Adsorption of CO and CO{sub 2} occurred almost instantaneously and reversibly on preoxidized Au/TiO{sub 2}, whereas a slow increase in the O{sub 2} pressure was observed at 273 K in the absence of evacuation. A similar increase of O{sub 2} pressure was observed from oxidized TiO{sub 2}, but Au powder did not show any increase. The increase was ascribed to the desorption of weakly adsorbed O{sub 2} on the support surface of Au/TiO{sub 2}. The rate of reduction of preoxidized Au/TiO{sub 2} with CO almost corresponded to the increase in the O{sub 2} pressure and was far smaller than the rate of the catalytic oxidation of CO with O{sub 2} on the catalyst, indicating that molecular oxygen weakly adsorbed on the support surface of Au/TiO{sub 2} contributes only partly to the catalytic oxidation of CO. During the oxidation, O{sub 2} in the gas phase may be directly activated on the surface of deposited gold particles and/or on the very narrow perimeter interface between the gold and the support.

Iizuka, Yasuo; Tode, Toshihisa; Takao, Toshiaki; Yatsu, Kenichiro; Takeuchi, Toshiaki; Tsubota, Susumu; Haruta, Masatake

1999-10-01T23:59:59.000Z

133

Low Temperature Deposition of Metal Oxide Thin Films in Supercritical Carbon Dioxide using Metal-organic Precursors  

E-Print Network [OSTI]

and are driven by the energy provided by a heated substrate. Both these vacuum-based techniques require in the precursor adsorption, oxidation and by-product desorption. [5] Use of solvation energy may provide a viable. Pressurized CO2 was delivered using an ISCO 260D syringe pump through a high- pressure manifold. Resistive

Gougousi, Theodosia

134

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

135

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

136

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

137

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

138

Uranium dioxide electrolysis  

DOE Patents [OSTI]

This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO.sub.2, is added to a solution of UCl.sub.4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

Willit, James L. (Batavia, IL); Ackerman, John P. (Prescott, AZ); Williamson, Mark A. (Naperville, IL)

2009-12-29T23:59:59.000Z

139

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

NONE

1992-12-31T23:59:59.000Z

140

Molecular cloning and sequence of the thdF gene involved in the thiophene and furan oxidation by Escherichia coli  

SciTech Connect (OSTI)

Since sulfur dioxide emission from burning high sulfur coals is a major contributor to acid rain, it is important to develop bacteria which are capable of efficiently removing the sulfur from coal before combustion. Inorganic sulfur can be removed from coal by certain strains of Thiobacillus or Sulfolobus; however the organic sulfur remains intransigent. Since high sulfur Illinois coals typically contain 60% to 70% of their sulfur in the form of the heterocyclic thiophene ring we have started to investigate the biodegradation of derivatives of thiophene and the corresponding oxygen heterocycle, furan. Our previous work resulted in the isolation of a triple mutant, NAR30, capable of oxidizing a range of furan and thiophene derivatives. However, NAR30 does not completely degrade thiophenes or furans and its oxidation of these compounds is slow and inefficient. We decided to clone the thd genes both in order to increase the efficiency of degradation and to investigate the nature of the reactions involved. 37 refs., 4 figs., 3 tabs.

Alam, K.Y.; Clark, D.P.

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

NONE

1995-11-01T23:59:59.000Z

142

Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction technology for the control of nitrogen oxide emissions from high-sulfur coal-fired boilers. First and second quarterly technical progress reports, [January--June 1995]. Final report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia (NH{sub 3}) into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor containing a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW nameplate capacity) near Pensacola, Florida. The project is funded by the US Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing all aspects of this project.

NONE

1995-12-31T23:59:59.000Z

143

Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 1. Final report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO.) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO. to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal- fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: 1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels. 2) performance of the technology and effects on the balance-of- plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. 3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacturer under typical high-sulfur coal-fired utility operating conditions. These uncertainties were explored by operating nine small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. In addition, the test facility operating experience provided a basis for an economic study investigating the implementation of SCR technology.

NONE

1996-10-01T23:59:59.000Z

144

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

145

Basic Engineering Research for D and D of R Reactor Storage Pond Sludge: Electrokinetics, Carbon Dioxide Extraction, and Supercritical Water Oxidation  

SciTech Connect (OSTI)

Large quantities of mixed low level waste (MLLW) that fall under the Toxic Substances Control Act (TSCA) exist and will continue to be generated during D and D operations at DOE sites across the country. The standard process for destruction of MLLW is incineration, which has an uncertain future. The extraction and destruction of PCBs from MLLW was the subject of this research Supercritical Fluid Extraction (SFE) with carbon dioxide with 5% ethanol as cosolvent and Supercritical Waster Oxidation (SCWO) were the processes studied in depth. The solid matrix for experimental extraction studies was Toxi-dry, a commonly used absorbent made from plant material. PCB surrogates were 1.2,4-trichlorobenzene (TCB) and 2-chlorobiphenyl (2CBP). Extraction pressures of 2,000 and 4,000 psi and temperatures of 40 and 80 C were studied. Higher extraction efficiencies were observed with cosolvent and at high temperature, but pressure little effect. SCWO treatment of the treatment of the PCB surrogates resulted in their destruction below detection limits.

Michael A. Matthews; David A. Bruce,; Thomas A. Davis; Mark C. Thies; John W. Weidner; Ralph E. White

2002-04-01T23:59:59.000Z

146

E-Print Network 3.0 - ambient nitric oxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oxides (NOx)." Other nitrogen oxides include nitrous acid and nitric acid. While... . Nitrogen Dioxide: Nitrogen dioxide (NO2) is one of a group of highly reactive gasses known...

147

Standard test methods for chemical and mass spectrometric analysis of nuclear-grade gadolinium oxide (Gd2O3) powder  

E-Print Network [OSTI]

1.1 These test methods cover procedures for the chemical and mass spectrometric analysis of nuclear-grade gadolinium oxide powders to determine compliance with specifications. 1.2 The analytical procedures appear in the following order: Sections Carbon by Direct CombustionThermal Conductivity C1408 Test Method for Carbon (Total) in Uranium Oxide Powders and Pellets By Direct Combustion-Infrared Detection Method Total Chlorine and Fluorine by Pyrohydrolysis Ion Selective Electrode C1502 Test Method for Determination of Total Chlorine and Fluorine in Uranium Dioxide and Gadolinium Oxide Loss of Weight on Ignition 7-13 Sulfur by CombustionIodometric Titration Impurity Elements by a Spark-Source Mass Spectrographic C761 Test Methods for Chemical, Mass Spectrometric, Spectrochemical,Nuclear, and Radiochemical Analysis of Uranium Hexafluoride C1287 Test Method for Determination of Impurities In Uranium Dioxide By Inductively Coupled Plasma Mass Spectrometry Gadolinium Content in Gadolinium Oxid...

American Society for Testing and Materials. Philadelphia

2006-01-01T23:59:59.000Z

148

Process for production of synthesis gas with reduced sulfur content  

DOE Patents [OSTI]

A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

1989-01-01T23:59:59.000Z

149

Method of burning sulfur-containing fuels in a fluidized bed boiler  

DOE Patents [OSTI]

A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

Jones, Brian C. (Windsor, CT)

1982-01-01T23:59:59.000Z

150

Glutamate Surface Speciation on Amorphous Titanium Dioxide and  

E-Print Network [OSTI]

Glutamate Surface Speciation on Amorphous Titanium Dioxide and Hydrous Ferric Oxide D I M I T R I (HFO) and titanium dioxide exhibit similar strong attachment of many adsorbates including biomolecules on amorphous titanium dioxide. The results indicate that glutamate adsorbs on HFO as a deprotonated divalent

Sverjensky, Dimitri A.

151

Safety considerations for the use of sulfur in sulfur-modified pavement materials  

E-Print Network [OSTI]

on the surround1ng environment. As sulfur-modified paving materials were being developed, there was a corresponding concern for studying the amounts of gaseous emiss1ons that were generated. The Texas Trans- portat1on Inst1tute (TTI) was one of the first... organizations in the United States to become 1nvolved in the research and development of sulfur-modified pavements, Throughout 1ts laboratory stud1es TTI cont1nually mon1tored hydrogen sulf1de (H25) and sulfur d1oxide (502) em1ssions produced during mix...

Jacobs, Carolyn Yuriko

2012-06-07T23:59:59.000Z

152

University of Minnesota Energy Conservation and Use  

E-Print Network [OSTI]

(Carbon monoxide) NOx (Nitrogen oxides) SO2 (Sulfur dioxide) CO2 (Carbon dioxide) 1996 280 1,371 597

Gulliver, Robert

153

acetylcholine-evoked nitric oxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

are not consistent, urban and industrial pollutionmainly particles (PM2.5 and PM10), nitrogen dioxide (NO2), and sulfur dioxide (SO2)as well as formaldehyde and electric...

154

Chemistry of Sulfur Oxides on Transition Metals I: Configurations, Energetics, Orbital Analyses, and Surface Coverage Effects of SO2 on Pt(111)  

E-Print Network [OSTI]

on understanding how SO2 promotes the oxidation of alkanes, such as propane.3-5 To understand the reactivity, Polcik et al. did not pro- pose any detailed structural information for this flat-lying configuration

Lin, Xi

155

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

156

Sulfur Degassing From Volcanoes: Source Conditions, Surveillance, Plume Chemistry and Earth System Impacts  

E-Print Network [OSTI]

of sulfur in magmas owes much to its multiple valence states (-II, 0, IV, VI), speciation (e.g., S2, H2S, SO on the redox chemistry of sulfur: by reducing sulfur, thiosulfate, sulfite and sulfate to H2S, or oxidizing sulfur and H2S to sulfate (e.g., Takano et al. 1997; Amend and Shock 2001; Shock et al. 2010

Boyer, Edmond

157

Technology Innovations and Experience Curves for Nitrogen Oxides Control Technologies  

E-Print Network [OSTI]

red power plants. Nitrogen dioxide (NO 2 ) is one of the sixeffects, including nitrogen dioxide (NO 2 ) and ground-levelgradually oxidized to nitrogen dioxide (NO 2 ) once emitted

Yeh, Sonia; Rubin, Edward S.; Taylor, Margaret R.

2007-01-01T23:59:59.000Z

158

A Sensor System Based on Semi-Conductor Metal Oxide Technology for In Situ Detection of Coal Fired Combustion Gases  

SciTech Connect (OSTI)

Sensor Research and Development Corporation (SRD) proposed a two-phase program to develop a robust, autonomous prototype analyzer for in situ, real-time detection, identification, and measurement of coal-fired combustion gases and perform field-testing at an approved power generation facility. SRD developed and selected sensor materials showing selective responses to carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, ammonia, sulfur dioxide and hydrogen chloride. Sensor support electronics were also developed to enable prototype to function in elevated temperatures without any issues. Field-testing at DOE approved facility showed the ability of the prototype to detect and estimate the concentration of combustion by-products accurately with relatively low false-alarm rates at very fast sampling intervals.

Brent Marquis

2007-05-31T23:59:59.000Z

159

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

160

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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161

DSRP, direct sulfur production  

SciTech Connect (OSTI)

The objective of this work is to demonstrate on a bench-scale the Direct Sulfur Recovery Process (DSRP) for up to 99 percent or higher recovery of sulfur (as elemental sulfur) from regeneration off-gases and coal-gas produced in integrated gasification combined cycle (IGCC) power generating systems. Fundamental kinetic and thermodynamic studies will also be conducted to enable development of a model to predict DSRP performance in large-scale reactors and to shed light on the mechanism of DSRP reactions. The ultimate goal of the project is to advance the DSRP technology to the point where industry is willing to support its further development.

McMichael, W.J.; Agarwal, S.K.; Jang, B.L.; Howe, G.B. [Research Triangle Institute, Research Triangle Park, NC (United States); Chen, D.H.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

1993-06-01T23:59:59.000Z

162

Development of the Hybrid Sulfur Thermochemical Cycle  

SciTech Connect (OSTI)

The production of hydrogen via the thermochemical splitting of water is being considered as a primary means for utilizing the heat from advanced nuclear reactors to provide fuel for a hydrogen economy. The Hybrid Sulfur (HyS) Process is one of the baseline candidates identified by the U.S. Department of Energy [1] for this purpose. The HyS Process is a two-step hybrid thermochemical cycle that only involves sulfur, oxygen and hydrogen compounds. Recent work has resulted in an improved process design with a calculated overall thermal efficiency (nuclear heat to hydrogen, higher heating value basis) approaching 50%. Economic analyses indicate that a nuclear hydrogen plant employing the HyS Process in conjunction with an advanced gas-cooled nuclear reactor system can produce hydrogen at competitive prices. Experimental work has begun on the sulfur dioxide depolarized electrolyzer, the major developmental component in the cycle. Proof-of-concept tests have established proton-exchange-membrane cells (a state-of-the-art technology) as a viable approach for conducting this reaction. This is expected to lead to more efficient and economical cell designs than were previously available. Considerable development and scale-up issues remain to be resolved, but the development of a viable commercial-scale HyS Process should be feasible in time to meet the commercialization schedule for Generation IV gas-cooled nuclear reactors.

Summers, William A.; Steimke, John L

2005-09-23T23:59:59.000Z

163

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

164

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

165

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

166

Process for combined control of mercury and nitric oxide.  

SciTech Connect (OSTI)

Continuing concern about the effects of mercury in the environment may lead to requirements for the control of mercury emissions from coal-fired power plants. If such controls are mandated, the use of existing flue-gas cleanup systems, such as wet scrubbers currently employed for flue-gas desulfurization, would be desirable, Such scrubbers have been shown to be effective for capturing oxidized forms of mercury, but cannot capture the very insoluble elemental mercury (Hg{sup 0}) that can form a significant fraction of the total emissions. At Argonne National Laboratory, we have proposed and tested a concept for enhancing removal of Hg{sup 0}, as well as nitric oxide, through introduction of an oxidizing agent into the flue gas upstream of a scrubber, which readily absorbs the soluble reaction products. Recently, we developed a new method for introducing the oxidizing agent into the flue-gas stream that dramatically improved reactant utilization. The oxidizing agent employed was NOXSORB{trademark}, which is a commercial product containing chloric acid and sodium chlorate. When a dilute solution of this agent was introduced into a gas stream containing Hg{sup 0} and other typical flue-gas species at 300 F, we found that about 100% of the mercury was removed from the gas phase and recovered in process liquids. At the same time, approximately 80% of the nitric oxide was removed. The effect of sulfur dioxide on this process was also investigated and the results showed that it slightly decreased the amount of Hg{sup 0} oxidized while appearing to increase the removal of nitric oxide from the gas phase. We are currently testing the effects of variations in NOXSORB{trademark} concentration, sulfur dioxide concentration, nitric oxide concentration, and reaction time (residence time). Preliminary economic projections based on the results to date indicate that the chemical cost for nitric oxide oxidation could be less than $5,000/ton removed, while for Hg{sup 0} oxidation it would be about $20,000/lb removed.

Livengood, C. D.; Mendelsohn, M. H.

1999-11-03T23:59:59.000Z

167

FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER  

SciTech Connect (OSTI)

This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced at SNL and Clemson. These membranes also exhibit good chemical stability and conductivity in concentrated sulfuric acid solutions and, thus, serve as promising candidates for the SDE. Therefore, we recommend further testing of these membranes including electrolyzer testing to determine if the reduced SO{sub 2} transport eliminates the formation of sulfur-containing films at the membrane/cathode interface. SO{sub 2} transport measurements in the custom built characterization cell identified experimental limitations of the original design. During the last quarter of FY08 we redesigned and fabricated a new testing cell to overcome the previous limitations. This cell also offers the capability to test membranes under polarized conditions as well as test the performance of MEAs under selected electrolyzer conditions.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-09-01T23:59:59.000Z

168

Understanding the ocean carbon and sulfur cycles in the context of a variable ocean : a study of anthropogenic carbon storage and dimethylsulfide production in the Atlantic Ocean  

E-Print Network [OSTI]

Anthropogenic activity is rapidly changing the global climate through the emission of carbon dioxide. Ocean carbon and sulfur cycles have the potential to impact global climate directly and through feedback loops. Numerical ...

Levine, Naomi Marcil

2010-01-01T23:59:59.000Z

169

E-Print Network 3.0 - actual nitric oxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion are nitric oxide (NO) and nitrogen... of the nitric oxide is oxidized to nitrogen dioxide, so the environmental effects of emissions of both... O emissions at coal...

170

E-Print Network 3.0 - affects nitric oxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion are nitric oxide (NO) and nitrogen... of the nitric oxide is oxidized to nitrogen dioxide, so the environmental effects of emissions of both... O emissions at coal...

171

Correlation for the total sulfur content in char after devolatilization  

SciTech Connect (OSTI)

The overall process of coal combustion takes place in two successive steps: devolatilization and char combustion. The fate of sulfur during the devolatilization of coal of different rank was investigated. The significance of the investigation is in fact that a major part of sulfur release occurs during devolatilization of coal, (i.e., emission of sulfur oxides during combustion of coal largely depends on sulfur release during devolatilization). The experimental investigations were conducted to obtain the data about the quantitative relation between sulfur content in the coal and sulfur content in the char. Standard procedures were used for obtaining the chars in a laboratory oven and determining the sulfur forms in the coal and char samples. The experiments were done with ground coal samples ({lt}0.2 mm), at the temperatures in the range of 500-1000{sup o}C. We showed that the amount of sulfur remaining in the char decreases, but not significantly in the temperature range 600-900{sup o}C. On the basis of the theoretical consideration of behavior of sulfur forms during devolatilization, certain simplifying assumptions, and obtained experimental data, we propose two correlations to associate the content of sulfur in the coal and in the char. The correlations are based on the results of the proximate analysis and sulfur forms in coal. Good agreement was found when the proposed correlations were compared with the experimental results obtained for investigated coals. Moreover, the correlations were verified by results found in the literature for numerous Polish, Albanian, and Turkish coals. Significant correlations (P {lt}0.05) between observed and calculated data with correlation coefficient, R {gt}0.9, were noticed in the case of all coals. 25 refs., 3 figs., 2 tabs.

Vasilije Manovic; Borislav Grubor [University of Belgrade, Belgrade (Serbia & Montenegro)

2006-02-01T23:59:59.000Z

172

Device and method for detecting sulfur dioxide at high temperatures  

DOE Patents [OSTI]

The present invention relates to a method for selectively detecting and/or measuring gaseous SO.sub.2 at a temperature of at least 500.degree. C., the method involving: (i) providing a SO.sub.2-detecting device including an oxygen ion-conducting substrate having on its surface at least three electrodes comprising a first, second, and third electrode; (ii) driving a starting current of specified magnitude and temporal variation between the first and second electrodes; (iii) contacting the SO.sub.2-detecting device with the SO.sub.2-containing sample while maintaining the magnitude and any temporal variation of the starting current, wherein said SO.sub.2-containing sample causes a change in the electrical conductance of said device; and (iv) detecting the change in electrical conductance of the device based on measuring an electrical property related to or indicative of the conductance of the device between the first and third electrodes, or between the second and third electrodes, and detecting SO.sub.2 in the SO.sub.2-containing sample based on the measured change in electrical conductance.

West, David L. (Oak Ridge, TN); Montgomery, Frederick C. (Oak Ridge, TN); Armstrong, Timothy R. (Clinton, TN)

2011-11-01T23:59:59.000Z

173

Abatement of Air Pollution: Control of Sulfur Dioxide Emissions...  

Broader source: Energy.gov (indexed) [DOE]

apply to fossil-fuel fired stationary sources which serve a generator with a nameplate capacity of 15 MW or more, or fossil-fuel fired boilers or indirect heat exchangers with a...

174

Sulfur Dioxide Treatment from Flue Gases Using a Biotrickling  

E-Print Network [OSTI]

acid rain and adversely affect human health, livestock, and plants. Various methods exist to reduce SO2 I L I P Department of Civil Engineering, Indian Institute of Technology, Madras, India 600 036 M A R

175

Synthetic Assessment of Historical Anthropogenic Sulfur Dioxide (SO2) Emissions  

E-Print Network [OSTI]

and climate change since industrial revolution. · This study assesses the original researches on historical 1850, anthropogenic SO2 emissions were distributed mostly by open burning sources and industrial

176

Formation of rare earth carbonates using supercritical carbon dioxide  

DOE Patents [OSTI]

The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

1991-09-03T23:59:59.000Z

177

Nitrogen dioxide detection  

DOE Patents [OSTI]

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

Sinha, Dipen N. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM); Christensen, William H. (Buena Park, CA)

1993-01-01T23:59:59.000Z

178

ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES  

SciTech Connect (OSTI)

The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

2013-08-20T23:59:59.000Z

179

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents [OSTI]

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

180

Sulfur tolerant highly durable CO.sub.2 sorbents  

DOE Patents [OSTI]

A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent containing calcium oxide (CaO) and at least one refractory dopant having a Tammann temperature greater than about 530.degree. C., wherein the refractory dopant enhances resistance to sintering, thereby conserving performance of the sorbent at temperatures of at least about 530.degree. C. Also provided are doped CaO sorbents for the capture of carbon dioxide in the presence of SO.sub.2.

Smirniotis, Panagiotis G. (Cincinnati, OH); Lu, Hong (Urbana, IL)

2012-02-14T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

182

Standard specification for uranium oxides with a 235U content of less than 5 % for dissolution prior to conversion to nuclear-grade uranium dioxide  

E-Print Network [OSTI]

1.1 This specification covers uranium oxides, including processed byproducts or scrap material (powder, pellets, or pieces), that are intended for dissolution into uranyl nitrate solution meeting the requirements of Specification C788 prior to conversion into nuclear grade UO2 powder with a 235U content of less than 5 %. This specification defines the impurity and uranium isotope limits for such urania powders that are to be dissolved prior to processing to nuclear grade UO2 as defined in Specification C753. 1.2 This specification provides the nuclear industry with a general standard for such uranium oxide powders. It recognizes the diversity of conversion processes and the processes to which such powders are subsequently to be subjected (for instance, by solvent extraction). It is therefore anticipated that it may be necessary to include supplementary specification limits by agreement between the buyer and seller. 1.3 The scope of this specification does not comprehensively cover all provisions for prevent...

American Society for Testing and Materials. Philadelphia

2005-01-01T23:59:59.000Z

183

Carbon dioxide capture process with regenerable sorbents  

DOE Patents [OSTI]

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

184

The Effects of Oxy-firing Conditions on Gas-phase Mercury Oxidation by Chlorine and Bromine  

SciTech Connect (OSTI)

Bench-scale experiments were conducted in a quartz-lined, natural gas-fired reactor with the combustion air replaced with a blend of 27 mole percent oxygen, with the balance carbon dioxide. Quench rates of 210 and 440 K/s were tested. In the absence of sulfur dioxide, the oxy-firing environment caused a remarkable increase in oxidation of mercury by chlorine. At 400 ppm chlorine (as HCl equivalent), air-firing results in roughly 5 percent oxidation. At the same conditions with oxy-firing, oxidation levels are roughly 80 percent. Oxidation levels with bromine at 25 and 50 ppm (as HBr equivalent) ranged from 80 to 95 percent and were roughly the same for oxy- and air-firing conditions. Kinetic calculations of levels of oxidation at air- and oxy-conditions captured the essential features of the experimental results but have not revealed a mechanistic basis for the oxidative benefits of oxy-firing conditions. Mixtures of 25 ppm bromine and 100 and 400 ppm chlorine gave more than 90 percent oxidation. At all conditions, the effects of quench rate were not significant. The presence of 500 ppm SO2 caused a dramatic decline in the levels of oxidation at all oxy-fired conditions examined. This effect suggests that SO2 may be preventing oxidation in the gas phase or preventing oxidation in the wetconditioning system that was used in quantifying oxidized and elemental mercury concentrations. Similar effects of SO2 have been noted with air-firing. The addition of sodium thiosulfate to the hydroxide impingers that are part of wet conditioning systems may prevent liquid-phase oxidation from occurring.

Buitrago, Paula; Silcox, Geoffrey

2010-06-30T23:59:59.000Z

185

Heterogeneous-phase reactions of nitrogen dioxide with vermiculite-supported magnesium oxide (as applied to the control of jet engine test cell emissions). Doctoral thesis  

SciTech Connect (OSTI)

Controlling nitrogen oxides (NOx) from a non-steady-state stationary source like a jet engine test cell (JETC) requires a method that is effective over a wide range of conditions. A heterogeneous, porous, high surface area sorbent material comprised of magnesium oxide powder attached to a vermiculite substrate has been commercially developed for this purpose. Data from extensive laboratory testing of this material in a packed-bed flow system are presented. NO2 removal efficiencies, kinetics, and proposed NO2 removal mechanisms over a range of representative JETC exhaust gas characteristics are described. Exhaust gas variables evaluated included: NO2 concentration, temperature, flow rate (retention time), oxygen content, and moisture content. Availability of water and oxygen were found to be important variables. It is probable that water is necessary for the conversion of MgO to Mg(OH)2, which is a more reactive compound having thermal stability over the range of temperatures evaluated. Gaseous oxygen serves to oxidize NO to NO2, the latter being more readily removed from the gas stream. The presence of oxygen also serves to offset thermal decomposition of NO2 or surface nitrite/nitrate. Effective `lifetime` and regenerability of the exposed sorbent material were also evaluated. NO2 removal efficiencies were found to greatly exceed those for NO, with a maximum value greater than 90 percent. The effective conversion of NO to NO2 is a crucial requirement for removal of the former. The reaction between NO2 and MgO-vermiculite is first-order with respect to NO2.

Kimm, L.T.

1995-11-01T23:59:59.000Z

186

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

187

Assessing historical global sulfur emission patterns for the period 1850--1990  

SciTech Connect (OSTI)

Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

Lefohn, A.S. [A.S.L. and Associates, Helena, MT (United States); Husar, J.D.; Husar, R.B. [Washington Univ., St. Louis, MO (United States). Center for Air Pollution Impact and Trend Analysis; Brimblecombe, P. [Univ. of East Anglia, Norwich (United Kingdom)

1996-07-19T23:59:59.000Z

188

Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream  

DOE Patents [OSTI]

The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

2014-07-08T23:59:59.000Z

189

What's Next for Vanadium Dioxide?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy...

190

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

191

The Hybrid Sulfur Cycle for Nuclear Hydrogen Production  

SciTech Connect (OSTI)

Two Sulfur-based cycles--the Sulfur-Iodine (SI) and the Hybrid Sulfur (HyS)--have emerged as the leading thermochemical water-splitting processes for producing hydrogen utilizing the heat from advanced nuclear reactors. Numerous international efforts have been underway for several years to develop the SI Cycle, but development of the HyS Cycle has lagged. The purpose of this paper is to discuss the background, current status, recent development results, and the future potential for this thermochemical process. Savannah River National Laboratory (SRNL) has been supported by the U.S. Department of Energy Office of Nuclear Energy, Science, and Technology since 2004 to evaluate and to conduct research and development for the HyS Cycle. Process design studies and flowsheet optimization have shown that an overall plant efficiency (based on nuclear heat converted to hydrogen product, higher heating value basis) of over 50% is possible with this cycle. Economic studies indicate that a nuclear hydrogen plant based on this process can be economically competitive, assuming that the key component, the sulfur dioxide-depolarized electrolyzer, can be successfully developed. SRNL has recently demonstrated the use of a proton-exchange-membrane electrochemical cell to perform this function, thus holding promise for economical and efficient hydrogen production.

Summers, William A.; Gorensek, Maximilian B.; Buckner, Melvin R.

2005-09-08T23:59:59.000Z

192

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions  

SciTech Connect (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

DOE; ORNL; NREL; EMA; MECA

1999-11-15T23:59:59.000Z

193

Continuous sulfur removal process  

DOE Patents [OSTI]

A continuous process for the removal of hydrogen sulfide from a gas stream using a membrane comprising a metal oxide deposited on a porous support is disclosed. 4 figures.

Jalan, V.; Ryu, J.

1994-04-26T23:59:59.000Z

194

LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.  

SciTech Connect (OSTI)

This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than the potential service costs reduction, it is very significant. It represents an important red

BATEY, J.E.; MCDONALD, R.J.

2005-06-01T23:59:59.000Z

195

Carbon dioxide removal process  

DOE Patents [OSTI]

A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

2003-11-18T23:59:59.000Z

196

Technical Support Document: Energy Conservation Standards for  

Broader source: Energy.gov (indexed) [DOE]

decrease air pollu- tion by decreasing future energy demand. The greatest decreases in air pollution , will be in sulfur oxides (listed in equivalent weight of sulfur dioxide,...

197

E-Print Network 3.0 - aox total nitrogen Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

appropriate environmental controls been applied? Summary: to the environment of sulfur dioxide, nitrogen oxides, total particulate matter, mercury, absorbable organic...

198

4, 23012331, 2004 Nitrogen oxides  

E-Print Network [OSTI]

of nitrogen oxide (NO), nitrogen dioxide (NO2) and ozone (O3) were performed simul- taneously with aerosolACPD 4, 2301­2331, 2004 Nitrogen oxides measurements in an Amazon site A. M. Cordova et al. Title and Physics Discussions Nitrogen oxides measurements in an Amazon site and enhancements associated with a cold

Paris-Sud XI, Université de

199

Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes  

SciTech Connect (OSTI)

Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

2014-06-17T23:59:59.000Z

200

Sulfur-Free Selective Pulping  

E-Print Network [OSTI]

A joint research effort is being conducted on ways to produce cost-effective pulping catalysts from lignin. This project addresses improving selectivities and reducing the levels of sulfur chemicals used in pulping. Improved selectivity means...

Dimmel, D. R.; Bozell, J. J.

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Solid oxide fuel cell process and apparatus  

DOE Patents [OSTI]

Conveying gas containing sulfur through a sulfur tolerant planar solid oxide fuel cell (PSOFC) stack for sulfur scrubbing, followed by conveying the gas through a non-sulfur tolerant PSOFC stack. The sulfur tolerant PSOFC stack utilizes anode materials, such as LSV, that selectively convert H.sub.2S present in the fuel stream to other non-poisoning sulfur compounds. The remaining balance of gases remaining in the completely or near H.sub.2S-free exhaust fuel stream is then used as the fuel for the conventional PSOFC stack that is downstream of the sulfur-tolerant PSOFC. A broad range of fuels such as gasified coal, natural gas and reformed hydrocarbons are used to produce electricity.

Cooper, Matthew Ellis (Morgantown, WV); Bayless, David J. (Athens, OH); Trembly, Jason P. (Durham, NC)

2011-11-15T23:59:59.000Z

202

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 1  

SciTech Connect (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim data report summarizes results as of August, 1999, on the status of the test programs being conducted on three technologies: lean-NO{sub x} catalysts, diesel particulate filters and diesel oxidation catalysts.

DOE; ORNL; NREL; EMA; MECA

1999-08-15T23:59:59.000Z

203

apoplastic polyamine oxidation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

di-oxidized spermine autodegradation, including trace amounts of stable and cytotoxic acrolein (arrested S phase), were unlikely to have contributed significantly to the arrest....

204

Project Profile: Direct Supercritical Carbon Dioxide Receiver...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo The National...

205

Separation of carbon dioxide from flue emissions using Endex principles  

E-Print Network [OSTI]

In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

Ball, R

2009-01-01T23:59:59.000Z

206

Carbon dioxide sensor  

DOE Patents [OSTI]

The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

2011-11-15T23:59:59.000Z

207

CARBON DIOXIDE EMISSION REDUCTION  

E-Print Network [OSTI]

.5 Primary Energy Use and Carbon Dioxide Emissions for Selected US Chemical Subsectors in 1994 ...............................................................................................................16 Table 2.7 1999 Energy Consumption and Specific Energy Consumption (SEC) in the U.S. Cement Efficiency Technologies and Measures in Cement Industry.................22 Table 2.9 Energy Consumption

Delaware, University of

208

863 58884112 FAX:58884035  

E-Print Network [OSTI]

Zare, because sulfur dioxide will be oxidized to sulfuric acid, which acidifies rains, is it going to have negative climate outcomes such as acid rain while utilizing sulfur dioxide aerosol to block causes acid rain, but the atmosphere we mentioned is specifically stratosphere. All the sulfur dioxide

Zare, Richard N.

209

Measuring Sulphur Dioxide (SO2) Emissions in October, 2010 Catastrophic Eruption from Merapi Volcano in Java, Indonesia  

E-Print Network [OSTI]

Volcano in Java, Indonesia with Ozone Monitoring Instrument (OMI) José A. Morales-Collazo Geology This paper discusses sulfur dioxide (SO2) cloud emissions from Merapi Volcano in Java, Indonesia during, Indonesia. In October 26th , 2010, a catastrophic eruption was reported from Merapi causing nearly 386

Gilbes, Fernando

210

Electro Catalytic Oxidation (ECO) Operation  

SciTech Connect (OSTI)

The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

Morgan Jones

2011-03-31T23:59:59.000Z

211

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

212

ADVANCED OXIDATION PROCESS  

SciTech Connect (OSTI)

The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

Dr. Colin P. Horwitz; Dr. Terrence J. Collins

2003-11-04T23:59:59.000Z

213

Fermentation, Hydrogen, and Sulfur Metabolism in Multiple Uncultivated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fermentation, Hydrogen, and Sulfur Metabolism in Multiple Uncultivated Bacterial Phyla. Fermentation, Hydrogen, and Sulfur Metabolism in Multiple Uncultivated Bacterial Phyla....

214

Two stage sorption of sulfur compounds  

DOE Patents [OSTI]

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

215

CARBON DIOXIDE FIXATION.  

SciTech Connect (OSTI)

Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

FUJITA,E.

2000-01-12T23:59:59.000Z

216

INCOMPATIBLE CHEMICAL LIST PRUDENT PRACTICES FOR HANDLING CHEMICALS IN LABORATORIES  

E-Print Network [OSTI]

tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia (anhydrous) Mercury (in oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals, sulfur tetrachloride, carbon dioxide, water Potassium chlorate Sulfuric and other acids Potassium perchlorate (see also

Cho, Junghyun

217

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Draft final report  

SciTech Connect (OSTI)

The primary goal of this project was to demonstrate the use of Selective Catalytic Reduction (SCR) to reduce NO{sub x} emissions from pulverized-coal utility boilers using medium- to high-sulfur US coal. The prototype SCR facility, built in and around the ductwork of Plant Crist Unit 5, consisted of three large SCR reactor units (Reactors A, B, and C), each with a design capacity of 5,000 standard cubic feet per minute (scfm) of flue gas, and six smaller reactors (Reactors D through J), each with a design capacity of 400 scfm of flue gas. The three large reactors contained commercially available SCR catalysts as offered by SCR catalyst suppliers. These reactors were coupled with small-scale air preheaters to evaluate (1) the long-term effects of SCR reaction chemistry on air preheater deposit formation and (2) the impact of these deposits on the performance of air preheaters. The small reactors were used to test additional varieties of commercially available catalysts. The demonstration project was organized into three phases: (1) Permitting, Environmental Monitoring Plan (EMP) Preparation, and Preliminary Engineering; (2) Detail Design Engineering and Construction; and (3) Operation, Testing, Disposition, and Final Report Preparation. Section 2 discusses the planned and actual EMP monitoring for gaseous, aqueous, and solid streams over the course of the SCR demonstration project; Section 3 summarizes sampling and analytical methods and discusses exceptions from the methods specified in the EMP; Section 4 presents and discusses the gas stream monitoring results; Section 5 presents and discusses the aqueous stream monitoring results; Section 6 presents and discusses the solid stream monitoring results; Section 7 discusses EMP-related quality assurance/quality control activities performed during the demonstration project; Section 8 summarizes compliance monitoring reporting activities; and Section 9 presents conclusions based on the EMP monitoring results.

NONE

1996-06-14T23:59:59.000Z

218

Silicon dioxide and hafnium dioxide evaporation characteristics from a high-frequency sweep e-beam system  

SciTech Connect (OSTI)

Reactive oxygen evaporation characteristics were determined as a function of the front-panel control parameters provided by a programmable, high-frequency sweep e-beam system. An experimental design strategy used deposition rate, beam speed, pattern, azimuthal rotation speed, and dwell time as the variables. The optimal settings for obtaining a broad thickness distribution, efficient silicon dioxide boule consumption, and minimal hafnium dioxide defect density were generated. The experimental design analysis showed the compromises involved with evaporating these oxides. {copyright} {ital 1996 Optical Society of America.}

Chow, R. [Lawrence Livermore National Laboratory, Livermore, California 94551-0808 (United States); Tsujimoto, N. [MDC Vacuum Products Corporation, Hayward, California 94545 (United States)

1996-09-01T23:59:59.000Z

219

A ACID RAIN Audrey Gibson  

E-Print Network [OSTI]

- SO2 Emissions of sulfur dioxide (SO2) and oxides of nitrogen (NOx) react in the atmosphere with water;Gas Natural Sources Concentration Carbon dioxide CO2 Decomposition 355 ppm Nitric oxide NO Electric discharge 0.01 ppm Sulfur dioxide SO2 Volcanic gases 0-0.01 ppm Table 1 Carbon dioxide, produced

Toohey, Darin W.

220

Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility  

SciTech Connect (OSTI)

The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis). If the amount of sulfur exceeds its tolerance level a molten salt will accumulate and upset melter operations and potentially shorten melter useful life. Therefore relatively conservative limits have been placed on sulfur loading in melter feed which in-turn significantly impacts the amount of glass that will be produced, in particular at the Hanford site. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 312 individual glass compositions. This model was shown to well represent the data, accounting for over 80% of the variation in data and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed based on 19 scaled melter tests. The model is appropriate for control of waste glass processing which includes uncertainty quantification. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5 ? TiO2 < CaO < P2O5 ? ZnO. The components that most decrease sulfur solubility are Cl > Cr2O3 > SiO2 ? ZrO2 > Al2O3.

Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Gregory F.; Kruger, Albert A.

2014-10-25T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Toward Understanding the Effect of Nuclear Waste Glass Composition of Sulfur Solubility  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

2014-02-13T23:59:59.000Z

222

NONEQUILIBRIUM SULFUR CAPTURE & RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR  

SciTech Connect (OSTI)

Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. The reacted particles impact and melt in the liquid slag layer on the combustor wall by the centrifugal force of the swirling combustion gases. Due to the low solubility of sulfur in slag, it must be rapidly drained from the combustor to limit sulfur gas re-evolution. Prior analyses and laboratory scale data indicated that for Coal Tech's 20 MMBtu/hour, air-cooled, slagging coal combustor slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to validate this sulfur-in-slag model in a group of combustor tests. A total of 36 days of testing on the combustor were completed during the period of performance of this project. This was more that double the 16 test days that were required in the original work statement. The extra tests were made possible by cost saving innovations that were made in the operation of the combustor test facility and in additional investment of Coal Tech resources in the test effort. The original project plan called for two groups of tests. The first group of tests involved the injection of calcium sulfate particles in the form of gypsum or plaster of Paris with the coal into the 20 MMBtu/hour-combustor. The second group of tests consisted of the entire two-step process, in which lime or limestone is co-injected with coal and reacts with the sulfur gas released during combustion to form calcium sulfate particles that impact and dissolve in the slag layer. Since this sulfur capture process has been validated in numerous prior tests in this combustor, the primary effort in the present project was on achieving the high slag flow rates needed to retain the sulfur in the slag.

Bert Zauderer

2003-04-21T23:59:59.000Z

223

Carbon Dioxide Reduction Through Urban Forestry  

E-Print Network [OSTI]

. Retrieval Terms: urban forestry, carbon dioxide, sequestration, avoided energy The Authors E. Gregory McCarbon Dioxide Reduction Through Urban Forestry: Guidelines for Professional and Volunteer Tree; Simpson, James R. 1999. Carbon dioxide reduction through urban forestry

Standiford, Richard B.

224

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 4: Diesel Particulate Filters -- Final Report  

SciTech Connect (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This is the fourth and final report for the DPF test program and covers the effect of diesel sulfur level on: a catalyzed diesel particulate filter (CDPF), and a continuously regenerating diesel particulate filter (CR-DPF).

DOE; ORNL; NREL; EMA; MECA

2000-01-15T23:59:59.000Z

225

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, October 1, 1994--December 31, 1994  

SciTech Connect (OSTI)

During the past quarter, progress was made in three tasks. The poisoning effects of alkali metals (as Na{sub 2}O, K{sub 2}0 and Cs{sub 2}O) on iron oxide pillared clay (Fe-Bentonite) catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3} were investigated. The effects of sulfur dioxide and water vapor on the performance of the high activity catalyst, that is, Ce-doped Fe-Bentonite pillared clay (Ce-Fe-Bentonite) were examined. In addition, an iron ion-exchanged titania pillared clay (Ti-PILC) was prepared and its catalytic activity for the SCR of NO with NH{sub 3} was studied, which showed a high activity and a high S0{sub 2} and H{sub 2}0 resistance at high temperatures (i.e., above 400{degree}C).

Li, W.B.; Yang, R.T.

1994-12-31T23:59:59.000Z

226

Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one...

227

Optimize carbon dioxide sequestration, enhance oil recovery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

228

Optimize carbon dioxide sequestration, enhance oil recovery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields...

229

Carbon dioxide and climate  

SciTech Connect (OSTI)

Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

Not Available

1990-10-01T23:59:59.000Z

230

ADVANCED SULFUR CONTROL CONCEPTS FOR HOT-GAS DESULFURIZATION TECHNOLOGY  

SciTech Connect (OSTI)

This research project examined the feasibility of a second generation high-temperature coal gas desulfurization process in which elemental sulfur is produced directly during the sorbent regeneration phase. Two concepts were evaluated experimentally. In the first, FeS was regenerated in a H2O-O2 mixture. Large fractions of the sulfur were liberated in elemental form when the H2O-O2 ratio was large. However, the mole percent of elemental sulfur in the product was always quite small (<<1%) and a process based on this concept was judged to be impractical because of the low temperature and high energy requirements associated with condensing the sulfur. The second concept involved desulfurization using CeO2 and regeneration of the sulfided sorbent, Ce2O2S, using SO2 to produce elemental sulfur directly. No significant side reactions were observed and the reaction was found to be quite rapid over the temperature range of 500°C to 700°C. Elemental sulfur concentrations (as S2) as large as 20 mol% were produced. Limitations associated with the cerium sorbent process are concentrated in the desulfurization phase. High temperature and highly reducing coal gas such as produced in the Shell gasification process are required if high sulfur removal efficiencies are to be achieved. For example, the equilibrium H2S concentration at 800°C from a Shell gas in contact with CeO2 is about 300 ppmv, well above the allowable IGCC specification. In this case, a two-stage desulfurization process using CeO2 for bulk H2S removal following by a zinc sorbent polishing step would be required. Under appropriate conditions, however, CeO2 can be reduced to non-stoichiometric CeOn (n<2) which has significantly greater affinity for H2S. Pre-breakthrough H2S concentrations in the range of 1 ppmv to 5 ppmv were measured in sulfidation tests using CeOn at 700°C in highly reducing gases, as measured by equilibrium O2 concentration, comparable to the Shell gas. Good sorbent durability was indicated in a twenty-five-cycle test. The sorbent was exposed for 58 consecutive days to temperatures between 600°C and 800°C and gas atmospheres from highly reducing to highly oxidizing without measurable loss of sulfur capacity or reactivity. In the process analysis phase of this study, a two-stage desulfurization process using cerium sorbent with SO2 regeneration followed by zinc sorbent with dilute O2 regeneration was compared to a single-stage process using zinc sorbent and O2 regeneration with SO2 in the regeneration product gas converted to elemental sulfur using the direct sulfur recovery process (DSRP). Material and energy balances were calculated using the process simulation package PRO/II. Major process equipment was sized and a preliminary economic analysis completed. Sorbent replacement rate, which is determined by the multicycle sorbent durability, was found to be the most significant factor in both processes. For large replacement rates corresponding to average sorbent lifetimes of 250 cycles or less, the single-stage zinc sorbent process with DSRP was estimated to be less costly. However, the cost of the two-stage cerium sorbent process was more sensitive to sorbent replacement rate, and, as the required replacement rate decreased, the economics of the two-stage process improved. For small sorbent replacement rates corresponding to average sorbent lifetimes of 1000 cycles or more, the two-stage cerium process was estimated to be less costly. In the relatively wide middle range of sorbent replacement rates, the relative economics of the two processes depends on other factors such as the unit cost of sorbents, oxygen, nitrogen, and the relative capital costs.

A. LOPEZ ORTIZ; D.P. HARRISON; F.R. GROVES; J.D. WHITE; S. ZHANG; W.-N. HUANG; Y. ZENG

1998-10-31T23:59:59.000Z

231

Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor  

E-Print Network [OSTI]

monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures thanSulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20­600 times greater

Tobin, Roger G.

232

Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein  

DOE Patents [OSTI]

A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cylic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

Bamberger, Carlos E. (Oak Ridge, TN); Robinson, Paul R. (Knoxville, TN)

1980-01-01T23:59:59.000Z

233

Natural Gas Processing Plant- Sulfur (New Mexico)  

Broader source: Energy.gov [DOE]

This regulation establishes sulfur emission standards for natural gas processing plants. Standards are stated for both existing and new plants. There are also rules for stack height requirements,...

234

Journal of Molecular Catalysis A: Chemical 259 (2006) 296301 Pt-catalyzed oxidative carbonylation of methane to  

E-Print Network [OSTI]

of methane to acetic acid in sulfuric acid Mark Zerella, Alexis T. Bell Department of Chemical Engineering carbonylation of methane to acetic acid was investigated using Pt(II) cations as the catalyst and sulfuric acid Elsevier B.V. All rights reserved. Keywords: Methane; Acetic acid; Platinum; Sulfuric acid; Oxidative

Bell, Alexis T.

235

on man, nature & air pollution  

E-Print Network [OSTI]

converted to form more nitrogen dioxide (this is where theillustrate the nitrogen dioxide-ozone connection. Aroundnitrogen di- oxide ( no 2)–as well as particles, organ- ic compounds, and sulfur dioxide (

Finlayson-Pitts, Barbara J

2008-01-01T23:59:59.000Z

236

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network [OSTI]

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

237

December 2002 Issue #13 2002 SULFUR RESPONSES AND THE WISCONSIN ALFALFA SULFUR  

E-Print Network [OSTI]

December 2002 Issue #13 ­ 2002 SULFUR RESPONSES AND THE WISCONSIN ALFALFA SULFUR SURVEY 1/ K response of alfalfa in the final 2 years of a 4-year experiment at Arlington on a 3.8% organic matter soil better identification of sulfur need and improved S management on Wisconsin alfalfa. Question #1

Balser, Teri C.

238

Co-firing high sulfur coal with refuse derived fuels. Final report  

SciTech Connect (OSTI)

This project was designed to evaluate the combustion performance of and emissions from a fluidized bed combustor during the combustion of mixtures of high sulfur and/or high chlorine coals and municipal solid waste (MSW). The project included four major tasks, which were as follows: (1) Selection, acquisition, and characterization of raw materials for fuels and the determination of combustion profiles of combination fuels using thermal analytical techniques; (2) Studies of the mechanisms for the formation of chlorinated organics during the combustion of MSW using a tube furnace; (3) Investigation of the effect of sulfur species on the formation of chlorinated organics; and (4) Examination of the combustion performance of combination fuels in a laboratory scale fluidized bed combustor. Several kinds of coals and the major combustible components of the MSW, including PVC, newspaper, and cellulose were tested in this project. Coals with a wide range of sulfur and chlorine contents were used. TGA/MS/FTIR analyses were performed on the raw materials and their blends. The possible mechanism for the formation of chlorinated organics during combustion was investigated by conducting a series of experiments in a tube furnace. The effect of sulfur dioxide on the formation of molecular chlorine during combustion processes was examined in this study.

Pan, W.P.; Riley, J.T.; Lloyd, W.G.

1997-11-30T23:59:59.000Z

239

CARBON DIOXIDE AND OUR OCEAN LEGACY  

E-Print Network [OSTI]

is a biologist at the California State Univer- sity San Marcos, with expertise in the effects of carbon dioxideCARBON DIOXIDE AND OUR OCEAN LEGACY G Carbon Dioxide: Our Role The United States is the single. Every day the average American adds about 118 pounds of carbon dioxide to the atmos- phere, due largely

240

The catalytic oxidation of propylene: investigation of catalyst activity.  

E-Print Network [OSTI]

- thur oxidation resulted in the formation oi' dioxymsthylperoxides acetalde- hydes formic aoids carbon monoxide, carbon dioxide~ hydrogen and water, &t temperatures above 500 degrees Centigrade the polymer1sation of eth- ylene became significant... that water vapor exerted a catalytio effeot on the oxidation of ethylene, while carbon dioxide showed no aooelerating effeot. Davis (ll) observed that water vapor possessed a oatalytio ei'- feet on ths oxidation of olefins. Thompson and Hinshslwood (SS...

Woodham, John Frank

1953-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide from the post-  

E-Print Network [OSTI]

Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide dioxide separation and sequestration because the lower cost of carbon dioxide separation from for injection of carbon dioxide into oil or gas-bearing formations. An advantage of sequestration involving

242

Nonequilibrium sulfur capture and retention in an air cooled slagging coal combustor. Quarterly technical progress report, 1996  

SciTech Connect (OSTI)

The objective of this 24 month project is to determine the degree of sulfur retention in slag in a full scale cyclone coal combustor with sulfur capture by calcium oxide sorbent injection into the combustor. This sulfur capture process consists of two steps: Capture of sulfur with calcined calcium oxide followed by impact of the reacted sulfur-calcium particles on the liquid slag lining the combustor. The sulfur bearing slag must be removed within several minutes from the combustor to prevent re-evolution of the sulfur from the slag. To accomplish this requires slag mass flow rates in the range of several 100 lb/hr. To study this two step process in the combustor, two groups of tests are being implemented. In the first group, calcium sulfate in the form of gypsum, or plaster of Paris, was injected in the combustor to determine sulfur evolution from slag. In the second group, the entire process is tested with limestone and/or calcium hydrate injected into the combustor. This entire effort consists of a series of up to 16 parametric tests in a 20 MMtu/hr slagging, air cooled, cyclone combustor. During the present quarterly reporting period ending September 30,1996, three tests in this project were implemented, bringing the total tests to 5. In addition, a total of 10 test days were completed during this quarter on the parallel project that utilizes the same 20 MMtu/hr combustor. The results of that project, especially those related to improved slagging performance, have a direct bearing on this project in assuring proper operation at the high slag flow rates that may be necessary to achieve high sulfur retention in slag.

Zauderer, B.

1996-11-01T23:59:59.000Z

243

Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)  

SciTech Connect (OSTI)

Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

Mark Perna; Anant Upadhyayula; Mark Scotto

2012-11-05T23:59:59.000Z

244

Bioprocessing of High-sulfur Crudes Via Appliaction of Critical Fluid Biocatalysis  

SciTech Connect (OSTI)

This experimental research project investigated protein-based biocatalysis in supercritical fluid solvents as an integrated process approach to catalyze the removal of sulfur atoms from crude oils and fuels. The work focused on the oxidation of model sulfur-containing compounds in supercritical reaction media and included three major tasks: microbiological induction experiments, proteincatalyzed biooxidation in supercritical solvents, and a work-in-kind cooperative research and development agreement (CRADA). This work demonstrated that the biooxidation reaction could be improved by an order-of-magnitude by carrying out the reaction in emulsions in supercritical fluids.

Ginosar, Daniel Michael; Bala, Greg Alan; Anderson, Raymond Paul; Fox, Sandra Lynn; Stanescue, Marina A.

2002-05-01T23:59:59.000Z

245

Carbon Dioxide: Threat or Opportunity?  

E-Print Network [OSTI]

catastrophic long term effects on world climate. An alternative to discharging carbon dioxide into the atmosphere is to find new uses. One possible use is in 'Biofactories'. Biofactories may be achieved by exploiting two new developing technologies: Solar...

McKinney, A. R.

1982-01-01T23:59:59.000Z

246

Reducing carbon dioxide to products  

DOE Patents [OSTI]

A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

2014-09-30T23:59:59.000Z

247

Recuperative supercritical carbon dioxide cycle  

DOE Patents [OSTI]

A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

2014-11-18T23:59:59.000Z

248

Manipulating the Surface Reactions in Lithium Sulfur Batteries...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode...

249

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

250

Formation of Nitrogen- and Sulfur-Containing Light-Absorbing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen- and Sulfur-Containing Light-Absorbing Compounds Accelerated by Evaporation of Water from Secondary Formation of Nitrogen- and Sulfur-Containing Light-Absorbing Compounds...

251

Method of removal of sulfur from coal and petroleum products  

DOE Patents [OSTI]

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

252

Effect of Environmental Factors on Sulfur Gas Emissions from Drywall  

SciTech Connect (OSTI)

Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square meter per hour [{micro}g/m{sup 2}/h]. The dominant sulfur containing compounds in the RSG emission stream were hydrogen sulfide with emission factors between 17-201 {micro}g/m{sup 2}/h, and sulfur dioxide with emission factors between 8-64 {micro}g/m{sup 2}/h. The four highest emitting samples also had a unique signature of VSC emissions including > 40 higher molecular weight sulfur-containing compounds although the emission rate for the VSCs was several orders of magnitude lower than that of the RSGs. All of the high emitting drywall samples were manufactured in China in 2005-2006. Results from Phase 1 provided baseline emission factors for drywall samples manufactured in China and in North America but the results exclude variations in environmental conditions that may exist in homes or other built structures, including various combinations of temperature, RH, ventilation rate and the influence of coatings such as texture and paints. The objective of Phase 2 was to quantify the effect of temperature and RH on the RSG emission factors for uncoated drywall, and to measure the effect of plaster and paint coatings on RSG emission factors from drywall. Additional experiments were also performed to assess the influence of ventilation rate on measured emission factors for drywall.

Maddalena, Randy

2011-08-20T23:59:59.000Z

253

Computational Study of Sulfur–nickel Interactions: A New S–Ni Phase Diagram  

SciTech Connect (OSTI)

Prediction of the interactions between H2S-contaminated hydrogen fuel and Ni surfaces under conditions similar to those for solid oxide fuel cell (SOFC) operation using DFT (density function theory) calculations (with thermodynamic corrections) has resulted in a new S–Ni phase diagram, which suggests the existence of an intermediate state between clean Ni surfaces and nickel sulfides – sulfur atoms adsorbed on Ni surfaces. This prediction is consistent with many experimental observations relevant to sulfur poisoning of Nibased anodes in SOFCs, which cannot be explained using the existing S–Ni bulk phase diagram from classical thermodynamics. The accurate prediction of the adsorption phase is vital to a fundamental understanding of the sulfur poisoning mechanism of Ni-based anodes under SOFC operating conditions.

Wang, Jeng-Han; Liu, Meilin

2007-06-22T23:59:59.000Z

254

Electrochemical separation and concentration of sulfur containing gases from gas mixtures  

DOE Patents [OSTI]

A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

1981-01-01T23:59:59.000Z

255

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 2: NO{sub x} Adsorber Catalysts  

SciTech Connect (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report discusses the results of the DECSE test program that demonstrates the potential of NOx adsorber catalyst technology across the range of diesel engine operation with a fuel economy penalty less than 4%.

DOE; ORNL; NREL; EMA; MECA

1999-10-15T23:59:59.000Z

256

The south Karelia air pollution study: Effects of low-level expsoure to malodorous sulfur compounds on symptoms  

SciTech Connect (OSTI)

Exposure to very low levels of ambient-air malodorous sulfur compounds and their effect on eye irritation, respiratory-tract symptoms, and central nervous system symptoms in adults were assessed. A cross-sectional self-administered questionnaire (response rate = 77%) was distributed during March and April 1992 to adults (n = 336) who lived in a neighborhood that contained a pulp mill and in a nonpolluted reference community (n = 380). In the exposed community, the measured annual mean concentrations of total reduced sulfur compounds and sulfur dioxide measured in two stations were 2 to 3 {mu}g/m{sup 3} and 1 {mu}g/m{sup 3}, respectively. In the reference community, the annual mean concentration of sulfur dioxide was 1 {mu}g/m{sup 3}. The residents of the community near the pulp mill reported an excess of cough, respiratory infections, and headache during the previous 4 wk, as well as during the preceding 12 mo. The relative risk for headache was increased significantly in the exposed community, compared with the reference area: the adjusted odds ratio (aOR) was 1.83 (95% confidence interval [95% Cl] = 1.06-3.15) during the previous 4 wk and 1.70 (95% Cl = 1.05-2.73) during the preceding 12 mo. The relative risk for cough was also increased during the preceding 12 mo (aOR = 1.64, 95% Cl = 1.01-2.64). These results indicated that adverse health effects of malodorous sulfur compounds occur at lower concentrations than reported previously. 25 refs., 3 tabs.

Partti-Pellinen, K.; Marttila, O. [South Karelia Allergy and Environment Inst., Tiuruniemi (Finland); Vilkka, V. [South Karelia Central Hospital, Lappeenranta (Finland); Jaakkola, J.J. [Univ. of Helsinki (Finland)]|[National Inst. of Public Health, Oslo (Norway)] [and others

1996-07-01T23:59:59.000Z

257

Method for providing oxygen ion vacancies in lanthanide oxides  

DOE Patents [OSTI]

A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

1989-12-05T23:59:59.000Z

258

Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer  

E-Print Network [OSTI]

transport to the anode influences the concentration of the sulfuric acid produced. The resulting sulfuric loss is the diffusion of SO2 through the sulfuric acid to the catalyst site. Here, we extend our and correlated the operating potential to the sulfuric acid concentration produced at the anode.15-17 We have

Weidner, John W.

259

Definition of Non-Conventional Sulfur Utilization in Western Kazakhstan for Sulfur Concrete (Phase 1)  

SciTech Connect (OSTI)

Battelle received a contract from Agip-KCO, on behalf a consortium of international oil and gas companies with exploration rights in the North Caspian Sea, Kazakhstan. The objective of the work was to identify and help develop new techniques for sulfur concrete products from waste, by-product sulfur that will be generated in large quantitites as drilling operations begin in the near future. BNL has significant expertise in the development and use of sulfur concrete products and has direct experience collaborating with the Russian and Kazakh partners that participated. Feasibility testing was successfully conducted for a new process to produce cost-effective sulfur polymer cement that has broad commerical applications.

Kalb, Paul

2007-05-31T23:59:59.000Z

260

Sulfur oxidation influence on rock phosphate solubilization in soil  

E-Print Network [OSTI]

cd 7. 2 e 10. 6 c 13. 8 b 15. 1 a 8. 8 Catalgo RP Source 0 100 200 400 800 0 100 200 400 800 0 0 0 0 0 (5:1) (5:I) (5:I) (5:I) (5:I) 0. 5 b 0. 8 b 0. 8 b 0. 9 b 0. 9 b 0. 5 b 0. 9 b 1. 7 a 1. 9 a 0. 8 b 3. 6 4. 9 4. 7... 14. 7 a 9. 8 e Patos de Minas RP Source 0 100 200 400 800 0 100 200 400 800 0 0 0 0 0 (5:I) (5:I) (5:I) (5:I) (5:I) 0. 5 bc 0. 7 bc 0. 6 bc 0. 9 b 1. 0 b 0. 6 bc 1. 1 b 1. 6 a 0. 7 bc 0. 4 c 3. 7 d 4. 4 cd 4. 7 cd 5. 4...

Correa de Souza, Osni

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Hydrothermally Stable, Sulfur-Tolerant Platinum-Based Oxidation Catalysts  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Department of Energy andHydrothermal Processing ofvia

262

Method for Determining Performance of Sulfur Oxide Adsorbents for Diesel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping theEnergy StorageAdvancedMetamaterialsInnovationEnergyMethod

263

Low-quality natural gas sulfur removal/recovery: Task 2. Topical report, September 30, 1992--August 29, 1993  

SciTech Connect (OSTI)

The primary purpose of this Task 2 Report is to present conceptual designs developed to treat a large portion of proven domestic natural gas reserves which are low quality. The conceptual designs separate hydrogen sulfide and large amounts of carbon dioxide (>20%) from methane, convert hydrogen sulfide to elemental sulfur, produce a substantial portion of the carbon dioxide as EOR or food grade CO{sub 2}, and vent residual CO{sub 2} virtually free of contaminating sulfur containing compounds. A secondary purpose of this Task 2 Report is to review existing gas treatment technology and identify existing commercial technologies currently used to treat large volumes of low quality natural gas with high acid content. Section II of this report defines low quality gas and describes the motivation for seeking technology to develop low quality gas reserves. The target low quality gas to be treated with the proposed technology is identified, and barriers to the production of this gas are reviewed. Section III provides a description of the Controlled Freeze Zone (CFG)-CNG technologies, their features, and perceived advantages. The three conceptual process designs prepared under Task 2 are presented in Section IV along with the design basis and process economics. Section V presents an overview of existing gas treatment technologies, organized into acid gas removal technology and sulfur recovery technology.

Cook, W.J.; Neyman, M.; Brown, W. [Acrion Technologies, Inc., Cleveland, OH (United States); Klint, B.W.; Kuehn, L.; O`Connell, J.; Paskall, H.; Dale, P. [Bovar, Inc., Calgary, Alberta (Canada)

1993-08-01T23:59:59.000Z

264

Doped tantalum oxide high K dielectric thin films  

E-Print Network [OSTI]

, it was doped with varying amounts of titanium oxide, aluminum oxide and silicon dioxide. The composite oxide films were deposited by reactive radio frequency (RF) cc-sputtering of two targets in a variety of oxygen and argon feed gas mixtures. The targets used...

Donnelly, Joseph Patrick

2000-01-01T23:59:59.000Z

265

World copper smelter sulfur balance-1988  

SciTech Connect (OSTI)

In 1989, the US Bureau of Mines initiated a contract to gather engineering, operating, and environmental cost data for 1988 for 30 major foreign primary copper smelters in market economy countries. Data were collected for 29 of the designated smelters together with information on applicable environmental regulations. Materials balance data obtained were used with available data for the eight US smelters to determine the approximate extent of copper smelter sulfur emission control in 1988. A broad characterization of the status of sulfur emission control regulation was made. The 37 US and foreign smelters represented roughly 73.2% of world and 89.3% of market economy primary copper production in 1988. The 29 non-US smelters attained 55.3% control of their input sulfur in 1988. Combined with the 90.4% control of US smelters, an aggregate 63.4% sulfur control existed. Roughly 1,951,100 mt of sulfur was emitted from the 37 market economy smelters in 1988. Identifiable SO[sub 2] control regulations covered 72.4% of the 29 foreign smelters, representing 65.5% of smelting capacity. Including US smelters, 78.4% of the major market economy smelters were regulated, representing 73.1% of smelting capacity. Significant changes since 1988 that may increase sulfur emission control are noted.

Towle, S.W. (Bureau of Mines, Denver, CO (United States))

1993-01-01T23:59:59.000Z

266

THE NITROGEN OXIDES CONTROVERSY  

E-Print Network [OSTI]

including observed nitrogen dioxide," Pure App. Geophys.HN0 ) and probably nitrogen dioxide (N0 ) at a few parts perorganic molecule and nitrogen dioxide. Several examples

Johnston, Harold S.

2012-01-01T23:59:59.000Z

267

Application Of Optical Processing For Growth Of Silicon Dioxide  

DOE Patents [OSTI]

A process for producing a silicon dioxide film on a surface of a silicon substrate. The process comprises illuminating a silicon substrate in a substantially pure oxygen atmosphere with a broad spectrum of visible and infrared light at an optical power density of from about 3 watts/cm.sup.2 to about 6 watts/cm.sup.2 for a time period sufficient to produce a silicon dioxide film on the surface of the silicon substrate. An optimum optical power density is about 4 watts/cm.sup.2 for growth of a 100.ANG.-300.ANG. film at a resultant temperature of about 400.degree. C. Deep level transient spectroscopy analysis detects no measurable impurities introduced into the silicon substrate during silicon oxide production and shows the interface state density at the SiO.sub.2 /Si interface to be very low.

Sopori, Bhushan L. (Denver, CO)

1997-06-17T23:59:59.000Z

268

Iron distribution among phases in high- and low-sulfur coal fly ash  

SciTech Connect (OSTI)

Moessbauer spectroscopy, reflected-light optical microscopy, scanning-electron microscopy, wet chemical, and X-ray diffraction studies were conducted on six fly ash samples. The fly ashes, representing the combustion by-products of coals with total sulfur contents of less than 2% to greater than 4%, ranged from 17.6 to 32.0% Fe{sub 2}O{sub 3} by XRF analysis. Wet chemical analysis was used to determine the Fe{sup 3+}/{summation}Fe content of the ashes, which ranged from 72% to 83%. Optical analysis of the ashes indicated that the spinel, encompassing iron oxides of various compositions, ranges from 4.0 to 12.6% (vol.). Moessbauer analyses confirmed the presence of three Fe-bearing phases: magnetite, hematite (possibly of two different compositions), and glass. The variation in the Fe-oxidation state follows the variation in the sulfur, consequently pyrite, content of the feed coal.

Hower, J.C.; Graham, U.M.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Dyar, M.D.; Taylor, M.E. [West Chester Univ., PA (United States). Dept. of Geology and Astronomy

1995-12-31T23:59:59.000Z

269

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW  

E-Print Network [OSTI]

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW J. E. Santos1, G. B. Savioli2, J. M. Carcione3, D´e, Argentina SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. I Storage of CO2). SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. II CO2 is separated from natural

Santos, Juan

270

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

E-Print Network [OSTI]

looping gasification using a calcium oxide-carbonate cycle, in which a pure stream of CO2 is generatedSteam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture Nicholas S. Siefert operating a CaO-CaCO3 chemical looping gasification reactor. For example, the steam-coal gasification

Litster, Shawn

271

Vapor-liquid equilibria of sulfur dioxide in polar organic solvents  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data for SO/sub 2/ in eight polar organic solvents and three mixtures of organic solvents were investigated over the temperature range 30-95/sup 0/C and over a concentration range of 0.02-0.16 weight fraction of SO/sub 2/. The solvents investigated were N, N-dimethylaniline (DMA); quinoline; the dimethyl ethers of diethylene glycol, triethylene glycol, and tetraethylene glycol; the monomethyl ether of diethylene glycol (DGM); tetramethylene sulfone; and tributyl phosphate. The mixed solvents investigated were various mixtures of DMA and DGM. The data were correlated by using the UNIQUAC, NRTL, Wilson, and Henry's law phase-equilibrium models.

Demyanovich, R.J.; Lynn, S.

1987-03-01T23:59:59.000Z

272

The excited state geometry associated with the 2900A absorption spectrum of sulfur dioxide  

E-Print Network [OSTI]

Za in Eqs. [18], [19], and [ZO], and the ground state vibrational frequencies Vl" and VZ" in Eq. [16]. Once the L" matrix has been determined, the normal coordi- nates ql" and qZ" could be obtained by the transformation [24] written for the ground... vs. log E for any plate or film has the form shown in Figure l. a b Log Exposure Figure l. Optical density vs. log exposure for a film or plate. Note that over the range (a, b) the graph is practically linear, We may also write Eq. I 2...

Smith, David Robert, Jr

2012-06-07T23:59:59.000Z

273

Wave lengths of some new absorption bands of sulfur dioxide vapor  

E-Print Network [OSTI]

000 020 R 010 100 L 010 020 f 011 120 031 210 R 000 010 L 020 020 f 101 200 002 120 L 100 100 040 110 300 210 Wave number from ) Russell's Formula 24110, 9 A24224, 4 24624. 6 24740 ' 5 24746. 6 24985. 4 25107. 5 25096, 1 25105 F 1...

Landrum, Bobby Lee

2012-06-07T23:59:59.000Z

274

Quantitative application of the Franck-Condon theory to sulfur dioxide  

E-Print Network [OSTI]

ELECTRONIC STATE AND THE NORMAL COORDINATES OF THE GROUND ELECTRONIC STATE OF THE SO MOLECULE....................................................... ....... 26 2 A. Eigenvectors and Normal Coordinates. . . 26 B. Vibrational Eigenfunctions... ? ? ? ? ? ? ? ? ? ? ? ? ? 53 IV. Intensities Versus { ? ? ? ? ? ? .......... 53 V. Values of c-^ and Cg. ? ? ..................... 55 iv V LIST OP FIGURES Figure Page Chapter II 1. Normal Modes of Vibration. 12 2. Rectangular Coordinates. ? ? . . . . ? ? ? . ? 15 3...

Coffman, Moody Lee

1954-01-01T23:59:59.000Z

275

Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Department-2023 Idaho4Fuel Consumption Solutions

276

The solubility of elemental sulfur in methane, carbon dioxide and hydrogen sulfide gas  

E-Print Network [OSTI]

.90 4000 2.06 3.76 6.10 11.71 25.05 3.71 3000 1.47 1.90 2.46 7.34 15.76 1.26 2000 0.83 0.59 0.83 2.37 4.31 0.88 1000 0.063 0.44 0.37 0.63 0.69 0.64 200 ?F 6000 15.7 23.12 32.87 62.83 109.40 44.50 5000 9.93 15.70 24.10 47.01 78.01 26.83 4000 3.58 8....30 2000 20.87 137.30 384.00 205.90 1000 8.98 37.04 136.50 123.20 CO CM CMO X O ? C>- ? ?oin-S- 437.50 359.50 300.20 234.70 57.50 9.20 972.60 797.20 587.50 264.50 67.70 17.10 2,027.00 970.10 658.40 278.40 64.50 20.30 ^ 9 TABLE 1 ( C...

Wieland, Denton R.

1958-01-01T23:59:59.000Z

277

Toward Understanding the Effect of Nuclear Waste Glass Composition of Sulfur Solubility  

SciTech Connect (OSTI)

The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

2014-02-13T23:59:59.000Z

278

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide  

E-Print Network [OSTI]

Interactions of Fluorine Redistribution and Nitrogen Incorporation with Boron Diffusion in Silicon Dioxide Mitra Navi and Scott Dunham Department of Electrical and Computer Engineering Boston University diffusion. Gate oxides were grown with nitrogen contents varying from 0 to 1.4%. A series of SIMS mea

Dunham, Scott

279

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Documents & Publications CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur...

280

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

U.S. Energy Information Administration (EIA) - Sector  

Gasoline and Diesel Fuel Update (EIA)

Emissions On This Page Concerns about GHG... Growth of carbon... Sulfur dioxide emissions... Nitrogen oxide emissions... Concerns about GHG legislation affect the long-term outlook...

282

ENVIRONMENTAL ASSESSMENT FOR THE PROPOSED ENERGY CONSERVATION...  

Broader source: Energy.gov (indexed) [DOE]

use and, therefore, a reduction of power plant emissions. The greatest decreases in air pollution would be for sulfur oxides, listed in equivalent -weight of sulfbr dioxide,...

283

NETL Report format template  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NGCC Natural gas combined cycle NOx Oxides of nitrogen PC Sub Pulverized coal subcritical PC Sup Pulverized coal supercritical PM Particulate matter SO 2 Sulfur dioxide...

284

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-03-04T23:59:59.000Z

285

SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

Gary M. Blythe; Richard McMillan

2002-07-03T23:59:59.000Z

286

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-02-04T23:59:59.000Z

287

An Aerosol Condensation Model for Sulfur Trioxide  

SciTech Connect (OSTI)

This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

Grant, K E

2008-02-07T23:59:59.000Z

288

Remote Sensing of In-Use Heavy-Duty Diesel Trucks  

E-Print Network [OSTI]

-road measurements in 2005 of carbon monoxide (CO), hydrocarbons, nitric oxide, nitrogen dioxide, and sulfur dioxide produce significant quantities of nitric oxide (NO) and, to a lesser extent, nitrogen dioxide (NO2) (1, 2. Carbon monoxide and nitric oxide show increasing emissions with increased altitude. Oxides of nitrogen

Denver, University of

289

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

290

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

291

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

292

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

293

ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR  

SciTech Connect (OSTI)

Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

Robert S. Weber

1999-05-01T23:59:59.000Z

294

Nitrogen dioxide and respiratory illnesses in infants  

SciTech Connect (OSTI)

Nitrogen dioxide is an oxidant gas that contaminates outdoor air and indoor air in homes with unvented gas appliances. A prospective cohort study was carried out to test the hypothesis that residential exposure to NO2 increases incidence and severity of respiratory illnesses during the first 18 months of life. A cohort of 1,205 healthy infants from homes without smokers was enrolled. The daily occurrence of respiratory symptoms and illnesses was reported by the mothers every 2 wk. Illnesses with wheezing or wet cough were classified as lower respiratory tract. Indoor NO2 concentrations were serially measured with passive samplers place in the subjects' bedrooms. In stratified analyses, illness incidence rates did not consistently increase with exposure to NO2 or stove type. In multivariate analyses that adjusted for potential confounding factors, odds ratios were not significantly elevated for current or lagged NO2 exposures, or stove type. Illness duration, a measure of illness severity, was not associated with NO2 exposure. The findings can be extended to homes with gas stoves in regions of the United States where the outdoor air is not heavily polluted by NO2.

Samet, J.M.; Lambert, W.E.; Skipper, B.J.; Cushing, A.H.; Hunt, W.C.; Young, S.A.; McLaren, L.C.; Schwab, M.; Spengler, J.D. (Univ. of New Mexico Medical Center, Albuquerque (United States))

1993-11-01T23:59:59.000Z

295

Development of High Energy Density Lithium-Sulfur Cells  

Broader source: Energy.gov (indexed) [DOE]

for increased sulfur loading Cathode Anode Investigatingoptimizing Li and Si composite anodes Exploring polymer electrolytes Electrolyte Determining new...

296

Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers  

SciTech Connect (OSTI)

Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of mineral accessible surface area, and should not be used in reactive transport modeling. Our work showed that reaction rates would be overestimated by three to five times.

Peters, Catherine A

2013-02-28T23:59:59.000Z

297

An analysis of the impact of having uranium dioxide mixed in with plutonium dioxide  

SciTech Connect (OSTI)

An assessment was performed to show the impact on airborne release fraction, respirable fraction, dose conversion factor and dose consequences of postulated accidents at the Plutonium Finishing Plant involving uranium dioxide rather than plutonium dioxide.

MARUSICH, R.M.

1998-10-21T23:59:59.000Z

298

Oil recovery by carbon dioxide injection into consolidated and unconsolidated sandstone  

E-Print Network [OSTI]

and field in the past decade. The analysis of these tests indicated that additional oil beyond that obtained by normal water flooding could be recovered with carbon d1oxide. The c1tations on the following pages follow the style of the Journal.... Yon Gonten The use of carbon dioxide as an oil recovery agent in petro- leum reservoirs has been investigated for many years. Both la- boratory and field studies have established that carbon dioxide can be an efficient oil displacing agent...

Lin, Fwu-Jin Frank

1975-01-01T23:59:59.000Z

299

Posting type Advisory update Subject Inconstant bias in XRF sulfur  

E-Print Network [OSTI]

Posting type Advisory update Subject Inconstant bias in XRF sulfur Module/Species A/ S Sites entire attention to observable discontinuities in XRF sulfur data. Shifts in the sulfur/sulfate ratio during 2003-4 were shown to coincide with recalibrations of the XRF system and to correlate with other XRF biases

Fischer, Emily V.

300

Short communication Influence of molybdenum and sulfur on copper  

E-Print Network [OSTI]

Short communication Influence of molybdenum and sulfur on copper metabolism in sheep: comparison of molybdenum able to trigger the copper sulfur molybdenum interference in sheep was measured with either only) and 4 increasing molybdenum doses. The sulfur-molybdenum-copper interference was quantified

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Process for removing sulfur from sulfur-containing gases: high calcium fly-ash  

DOE Patents [OSTI]

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

1991-01-01T23:59:59.000Z

302

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW  

E-Print Network [OSTI]

SEISMIC MONITORING OF. CARBON DIOXIDE FLUID FLOW. J. E. Santos. 1. , G. B. Savioli. 2. , J. M. Carcione. 3. , D. Gei. 3. 1. CONICET, IGPUBA, Fac.

santos

303

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL  

SciTech Connect (OSTI)

The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

Gary M. Blythe

2004-01-01T23:59:59.000Z

304

Mechanistic, sensitivity, and uncertainty studies of the atmospheric oxidation of dimethylsulfide  

E-Print Network [OSTI]

The global-scale emissions and reactivity of dimethylsulfide (CH3SCH3, DMS) make it an integral component in the atmospheric sulfur cycle. DMS is rapidly oxidized in the atmosphere by a complex gas-phase mechanism involving ...

Lucas, Donald David, 1969-

2003-01-01T23:59:59.000Z

305

VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM  

E-Print Network [OSTI]

(for water: the SPC-, SPC/E-, and TIP4P-potential models; for carbon dioxide: the EPM2 potential model dioxide are calculated. For water, the SPC- and TIP4P-models give superior results for the vapor pressure when compared to the SPC/E-model. The vapor liquid equilibrium of the binary mixture carbon dioxide

306

Sulfur K-edge X-ray absorption spectroscopy as an experimental probe for S-nitroso proteins  

SciTech Connect (OSTI)

X-ray absorption spectroscopy at the sulfur K-edge (2.4-2.6 keV) provides a sensitive and specific technique to identify S-nitroso compounds, which have significance in nitric oxide-based cell signaling. Unique spectral features clearly distinguish the S-nitroso-form of a cysteine residue from the sulfhydryl-form or from a methionine thioether. Comparison of the sulfur K-edge spectra of thiolate, thiol, thioether, and S-nitroso thiolate compounds indicates high sensitivity of energy positions and intensities of XAS pre-edge features as determined by the electronic environment of the sulfur absorber. A new experimental setup is being developed for reaching the in vivo concentration range of S-nitroso thiol levels in biological samples.

Szilagyi, Robert K. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)]. E-mail: Szilagyi@Montana.EDU; Schwab, David E. [Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717 (United States)

2005-04-29T23:59:59.000Z

307

Nitrogen and Sulfur Requirements for Clostridium thermocellum and Caldicellulosiruptor bescii on Cellulosic Substrates in Minimal Nutrient Media  

SciTech Connect (OSTI)

Growth media for cellulolytic Clostridium thermocellum and Caldicellulosiruptor bescii bacteria usually contain excess nutrients that would increase costs for consolidated bioprocessing for biofuel production and create a waste stream with nitrogen, sulfur and phosphate. C. thermocellum was grown on crystalline cellulose with varying concentrations of nitrogen and sulfur compounds, and growth rate and alcohol production response curves were determined. Both bacteria assimilated sulfate in the presence of ascorbate reductant, increasing the ratio of oxidized to reduced fermentation products. From these results, a low ionic strength, defined minimal nutrient medium with decreased nitrogen, sulfur, phosphate and vitamin supplements was developed for the fermentation of cellobiose, cellulose and acid-pretreated Populus. Carbon and electron balance calculations indicate the unidentified residual fermentation products must include highly reduced molecules. Both bacterial populations were maintained in co-cultures with substrates containing xylan or hemicellulose in defined medium with sulfate and basal vitamin supplements.

Kridelbaugh, Donna M [ORNL; Nelson, Josh C [ORNL; Engle, Nancy L [ORNL; Tschaplinski, Timothy J [ORNL; Graham, David E [ORNL

2013-01-01T23:59:59.000Z

308

Supporting Information for Impact of Chlorine Emissions from Sea-Salt Aerosol on Coastal Urban Ozone  

E-Print Network [OSTI]

DIOXIDE H2O2 HYDROGEN PEROXIDE NH3 AMMONIA NIT AEROSOL NITRATE SO2 SULFUR DIOXIDE SO3 SULFUR TRIOXIDE OSD extensions* NO NITRIC OXIDE NO2 NITROGEN DIOXIDE O3 OZONE HONO NITROUS ACID HNO3 NITRIC ACID HNO4 PERNITRIC ACID N2O5 NITROGEN PENTOXIDE NO3 NITRATE RADICAL HO2 HYDROPEROXY RADICAL CO CARBON MONOXIDE CO2 CARBON

Dabdub, Donald

309

Geothermal Power Plants — Meeting Clean Air Standards  

Broader source: Energy.gov [DOE]

Geothermal power plants can meet the most stringent clean air standards. They emit little carbon dioxide, very low amounts of sulfur dioxide, and no nitrogen oxides. See Charts 1, 2, and 3 below.

310

The use of onboard diagnostics to reduce emissions in automobiles  

E-Print Network [OSTI]

The emissions from automobiles are very harmful and include gases such as Carbon Dioxide, Nitrous Oxide, and Sulfur Dioxide. One of the main reasons OBD was created was to control emissions however it currently only monitors ...

Perez, Alberto, Jr

2009-01-01T23:59:59.000Z

311

atmospheric sulphur dioxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon dioxide CERN Preprints Summary: The primary ingredient of Anthropogenic Global Warming hypothesis is the assumption that atmospheric carbon dioxide variations are the cause...

312

Carbon dioxide-assisted fabrication of highly uniform submicron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dioxide-assisted fabrication of highly uniform submicron-sized colloidal carbon spheres via hydrothermal carbonization Carbon dioxide-assisted fabrication of highly uniform...

313

Optimize carbon dioxide sequestration, enhance oil recovery  

E-Print Network [OSTI]

- 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

314

Modeling of UO{sub 2} oxidation in steam atmosphere  

SciTech Connect (OSTI)

Nuclear fuel oxidation is an important phenomenon affecting fission product behavior. As indicated by a number of studies, uranium dioxide shows a very wide range of nonstoichiometric states. In steam, fuel oxidation produces a hyperstoichiometric composition, changing the transport properties. Variation of stoichiometry changes diffusion coefficients for oxygen, noble gases, and fission products substantially, affecting the release of fission products.

Dobrov, B.V.; Likhanskii, V.V. [Triniti Research Center, Triniti, Moscow (Russian Federation); Ozrin, V.D. [Nuclear Safety Institute IBREA, Moscow (Russian Federation)] [and others

1997-12-01T23:59:59.000Z

315

Molybdenum Dioxide As A Solid Oxide Fuel Cell Anodic Catalyst  

E-Print Network [OSTI]

its strength. Application of the cathode occurs next. An LSCF or similar powder is mixed allowing the water to evaporate from the LSCF, the half-cell is sintered again. The anode is applied

Collins, Gary S.

316

Oxidation kinetics of by-product calcium sulfite  

E-Print Network [OSTI]

constant and order of reaction for calcium sulfite oxidation using succinic acid as an additive 6. Corrosion behavior of metals and alloys in contact with sulfuric and acetic acid . 7. Maximum operating temperature for lining material . . . 8. Costs... of sodium thiosulfate required to inhibit the oxidation was very sma11 The second mechanism suggests that the thiosulfate reacts with the metal ions which were considered to catalyze the sulfite oxidation. The third possible mechanism involves...

Othman, Hasliza

1992-01-01T23:59:59.000Z

317

Enzymatic conversion of carbon dioxide to methanol: Enhanced methanol production in silica sol-gel matrices  

SciTech Connect (OSTI)

Strategies for effective conversion of atmospheric CO{sub 2} to methanol offer promising new technologies not only for recycling of the greenhouse gas but also for an efficient production of fuel alternatives. Partial hydrogenation of carbon dioxide has been accomplished by means of heterogeneous catalysis, electrocatalysis, and photocatalysis. Oxide-based catalysts are predominantly used for industrial fixation of carbon dioxide. A unique approach in this direction involves the use of enzymes as catalysts for conversion of carbon dioxide to methanol. The use of enzymes is particularly appealing since it provides a facile low-temperature route for generation of methanol directly from gaseous carbon dioxide. The authors report an enzymatically coupled sequential reduction of carbon dioxide to methanol by using a series of reactions catalyzed by three different dehydrogenases. Overall, the process involves an initial reduction of CO{sub 2} to formate catalyzed by formate dehydrogenase (F{sub ate}DH), followed by reduction of formate to formaldehyde by formaldehyde dehydrogenase (F{sub ald}DH), and finally formaldehyde is reduced to methanol by alcohol dehydrogenase (ADH). In this process, reduced nicotinamide adenine dinucleotide (NADH) acts as a terminal electron donor for each dehydrogenase-catalyzed reduction.

Obert, R.; Dave, B.C.

1999-12-29T23:59:59.000Z

318

Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993  

SciTech Connect (OSTI)

The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

Hepworth, M.T.

1993-03-31T23:59:59.000Z

319

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents [OSTI]

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

320

Enhanced light-conversion efficiency of titanium-dioxide dye-sensitized solar cells with the addition of  

E-Print Network [OSTI]

Enhanced light-conversion efficiency of titanium- dioxide dye-sensitized solar cells-doped tin oxide (FTO) nanoparticles and the application of such electrodes on dye-sensitized solar cell to the presence of ITO or FTO nanoparticles. Keywords: dye-sensitized solar cell, nanoparticle, electrode film

Cao, Guozhong

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Carbon dioxide and methane in karst systems Supervisors: Prof Dave Mattey, Dr Dave Lowry and Dr. Rebecca Fisher  

E-Print Network [OSTI]

Carbon dioxide and methane in karst systems Supervisors: Prof Dave Mattey, Dr Dave Lowry and Dr in the carbon cycle and very little is known about the behavior of methane in karst systems. Methane carbon isotopic evidence for oxidation of atmospheric methane in a dynamically ventilated cave

Royal Holloway, University of London

322

Non-destructive radiocarbon and stable isotopic analyses of archaeological materials using plasma oxidation  

E-Print Network [OSTI]

Plasma oxidation, an alternative to combustion, is shown to be a non-destructive method for obtaining radiocarbon dates on perishable organic artifacts. Electrically excited oxygen gently converts organic carbon to carbon dioxide. Radiocarbon...

Steelman, Karen Lynn

2005-11-01T23:59:59.000Z

323

Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion  

SciTech Connect (OSTI)

Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

Shen, M.; Yang, R.T.

1980-09-30T23:59:59.000Z

324

H[sub 2]S-removal and sulfur-recovery processes using metal salts  

SciTech Connect (OSTI)

Scrubbing a sour gas stream with a solution of copper sulfate allows the clean-up temperature to be increased from ambient to the adiabatic saturation temperature of the gas. The copper ion in solution reacts with the H[sub 2]S to produce insoluble CuS. The choice of copper sulfate was set by the very low solubility of CuS and the very rapid kinetics of the Cus formation. Since the copper sulfate solutions used are acidic, CO[sub 2] will not be co-absorbed. In a subsequent step the solid CuS is oxidized by a solution of ferric sulfate. The copper sulfate is regenerated, and elemental sulfur is formed together with ferrous sulfate. The ferrous sulfate is reoxidized to ferric sulfate using air. Since the copper sulfate and ferric solutions are regenerated, the overall reaction in this process is the oxidation of hydrogen sulfide with oxygen to form sulfur. The use of copper sulfate has the further advantage that the presence of sulfuric acid, even as concentrated as 1 molar, does not inhibit the sorption of H[sub 2]S. Furthermore, the absorption reaction remains quite favorable thermodynamically over the temperature range of interest. Because the reaction goes to completion, only a single theoretical stage is required for complete H[sub 2]S removal and cocurrent gas/liquid contacting may be employed. The formation of solids precludes the use of a packed column for the contacting device. However, a venturi scrubber would be expected to perform satisfactorily. The kinetics of the oxidation of metal sulfides, in particular zinc and copper sulfide, is reported in the literature to be slow at near-ambient temperatures. The proposed process conditions for the oxidation step are different from those reported in the literature, most notably the higher temperature. The kinetics of the reaction must be studied at high temperatures and corresponding pressures. An important goal is to obtain sulfur of high purity, which is a salable product.

Lynn, S.; Cairns, E.J.

1992-01-01T23:59:59.000Z

325

H{sub 2}S-removal and sulfur-recovery processes using metal salts  

SciTech Connect (OSTI)

Scrubbing a sour gas stream with a solution of copper sulfate allows the clean-up temperature to be increased from ambient to the adiabatic saturation temperature of the gas. The copper ion in solution reacts with the H{sub 2}S to produce insoluble CuS. The choice of copper sulfate was set by the very low solubility of CuS and the very rapid kinetics of the Cus formation. Since the copper sulfate solutions used are acidic, CO{sub 2} will not be co-absorbed. In a subsequent step the solid CuS is oxidized by a solution of ferric sulfate. The copper sulfate is regenerated, and elemental sulfur is formed together with ferrous sulfate. The ferrous sulfate is reoxidized to ferric sulfate using air. Since the copper sulfate and ferric solutions are regenerated, the overall reaction in this process is the oxidation of hydrogen sulfide with oxygen to form sulfur. The use of copper sulfate has the further advantage that the presence of sulfuric acid, even as concentrated as 1 molar, does not inhibit the sorption of H{sub 2}S. Furthermore, the absorption reaction remains quite favorable thermodynamically over the temperature range of interest. Because the reaction goes to completion, only a single theoretical stage is required for complete H{sub 2}S removal and cocurrent gas/liquid contacting may be employed. The formation of solids precludes the use of a packed column for the contacting device. However, a venturi scrubber would be expected to perform satisfactorily. The kinetics of the oxidation of metal sulfides, in particular zinc and copper sulfide, is reported in the literature to be slow at near-ambient temperatures. The proposed process conditions for the oxidation step are different from those reported in the literature, most notably the higher temperature. The kinetics of the reaction must be studied at high temperatures and corresponding pressures. An important goal is to obtain sulfur of high purity, which is a salable product.

Lynn, S.; Cairns, E.J.

1992-11-01T23:59:59.000Z

326

Displacement of crude oil by carbon dioxide  

E-Print Network [OSTI]

by Carbon Dioxide (December 1980) Olusegun Omole, B. S. , University of Ibadan, Nigeria Chairman of Advisory Committee: Dr. J. S. Osoba It has long been recognized that carbon dioxide could be used as an oil recovery agent. Both laboratory and field...- tion. Crude oil from the Foster Field in West Texas, of 7 cp and 34 API, 0 was used as the oil in place. Oil displacements were conducted at pres- sures between 750 psig and 1800 ps1g, and at a temperature of 110 F. 0 Carbon dioxide was injected...

Omole, Olusegun

1980-01-01T23:59:59.000Z

327

Identifying and Developing New, Carbon Dioxide Consuming Processes , Sudheer Indalaa  

E-Print Network [OSTI]

of propane, styrene from ethyl benzene and carbon dioxide, and methanol from hydrogenation of carbon dioxide408b Identifying and Developing New, Carbon Dioxide Consuming Processes Aimin Xua , Sudheer Indalaa@hal.lamar.edu, yawscl@hal.lamar.edu Key words; Carbon Dioxide Processes, Greenhouse Gases, Chemical Complex, Sustainable

Pike, Ralph W.

328

Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge  

SciTech Connect (OSTI)

Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

Wang, Bin [Vanderbilt University, Nashville; Alhassan, Saeed M. [The Petroleum Institute; Pantelides, Sokrates T [ORNL

2014-01-01T23:59:59.000Z

329

Analyses of sulfur-asphalt field trials in Texas  

E-Print Network [OSTI]

128 LIST OF FIGURES FIGURE PAGF Layout of SNPA sulfur bitumen binder pavem nt test ? U. S. Highway 69, Lufkin, Texas 15 Col 1oi d mi 1 1 furnished by SNPA for preparation of sul fur-asphalt emulsions View of mixing station showing sulfur... designed to investigate the advantage of using a colloid mill to prepare sulfur-asphalt binders as compared to comingling the asphalt and molten sulfur in a pipeline leading directly to the pug mill. After only six months of testing, the results...

Newcomb, David Edward

1979-01-01T23:59:59.000Z

330

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

of long cycle-life in half cells and expand the synthesis of sulfurcarbon composite materials of various sulfur loadings 2. Compare the performance for different...

331

Fundamental Studies of Lithium-Sulfur Cell Chemistry  

Broader source: Energy.gov (indexed) [DOE]

Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

332

LARGE-SCALE MEASUREMENT OF AIRBORNE PARTICULATE SULFUR  

E-Print Network [OSTI]

dispersive x-ray fluorescence (XRF) analysis. Concentrationsvalida- tion studies of XRF measurements have establishedelemental sulfur measurement by XRF can be closely related

Loo, B.W.

2010-01-01T23:59:59.000Z

333

Project Profile: Baseload CSP Generation Integrated with Sulfur...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Related Links FAQs Contact Us Offices You are here Home Concentrating Solar Power Project Profile: Baseload CSP Generation Integrated with Sulfur-Based...

334

Sulfur-Modified Zero-Valent Iron for Remediation Applications at DOE Sites - 13600  

SciTech Connect (OSTI)

Many DOE remediation sites have chemicals of concern that are compounds in higher oxidation states, which make them both more mobile and more toxic. The chemical reduction of these compounds both prevents the migration of these chemicals and in some cases reduces the toxicity. It has also been shown that zero-valent iron is a very effective substance to use in reducing oxygenated compounds in various treatment processes. These have included the treatment of halogenated hydrocarbons in the form volatile organic compounds used as solvents and pesticides. Zero-valent iron has also been used to reduce various oxidized metals such as chromium, arsenic, and mercury in order to immobilize them, decrease their toxicity, and prevent further transport. In addition, it has been used to immobilize or break down other non-metallic species such as selenium compounds and nitrates. Of particular interest at several DOE remediation sites is the fact that zero-valent iron is very effective in immobilizing several radioactive metals which are mobile in their oxidized states. These include both technetium and uranium. The main difficulty in using zero-valent iron has been its tendency to become inactive after relatively short periods of time. While it is advantageous to have the zero-valent iron particles as porous as possible in order to provide maximum surface area for reactions to take place, these pores can become clogged when the iron is oxidized. This is due to the fact that ferric oxide has a greater volume for a given mass than metallic iron. When the surfaces of the iron particles oxidize to ferric oxide, the pores become narrower and will eventually shut. In order to minimize the degradation of the chemical activity of the iron due to this process, a modification of zero-valent iron has been developed which prevents or slows this process, which decreases its effectiveness. It is called sulfur-modified iron, and it has been produced in high purity for applications in municipal water treatment applications. Sulfur-modified iron has been found to not only be an extremely economical treatment technology for municipal water supplies, where very large quantities of water must be treated economically, but it has also been demonstrated to immobilize technetium. It has the added benefit of eliminating several other harmful chemicals in water supplies. These include arsenic and selenium. In one large-scale evaluation study an integrated system implemented chemical reduction of nitrate with sulfur-modified iron followed by filtration for arsenic removal. The sulfur-modified iron that was used was an iron-based granular medium that has been commercially developed for the removal of nitrate, co-contaminants including uranium, vanadium and chromium, and other compounds from water. The independent study concluded that 'It is foreseen that the greatest benefit of this technology (sulfur-modified iron) is that it does not produce a costly brine stream as do the currently accepted nitrate removal technologies of ion exchange and reverse osmosis. This investigation confirmed that nitrate reduction via sulfur-modified iron is independent of the hydraulic loading rate. Future sulfur-modified iron treatment systems can be designed without restriction of the reactor vessel dimensions. Future vessels can be adapted to existing site constraints without being limited to height-to-width ratios that would exist if nitrate reduction were to depend on hydraulic loading rate'. Sulfur-modified iron was studied by the Pacific Northwest National Laboratory (PNNL) for its effectiveness in the reduction and permanent sequestration of technetium. The testing was done using Hanford Site groundwater together with sediment. The report stated, 'Under reducing conditions, TcO{sub 4} is readily reduced to TcIV, which forms highly insoluble oxides such at TcO{sub 2}.nH{sub 2}O. However, (re)oxidation of TcIV oxides can lead to remobilization. Under sulfidogenic conditions, most TcIV will be reduced and immobilized as Tc{sub 2}S{sub 7}, which is less readily re-mobilized, ev

Fogwell, Thomas W. [Fogwell Consulting, P.O. Box 20221, Piedmont, CA 94620 (United States)] [Fogwell Consulting, P.O. Box 20221, Piedmont, CA 94620 (United States); Santina, Pete [SMI-PS, Inc., 2073 Prado Vista, Lincoln, CA 95648 (United States)] [SMI-PS, Inc., 2073 Prado Vista, Lincoln, CA 95648 (United States)

2013-07-01T23:59:59.000Z

335

Oriented conductive oxide electrodes on SiO2/Si and glass  

DOE Patents [OSTI]

A thin film structure is provided including a silicon substrate with a layer of silicon dioxide on a surface thereof, and a layer of cubic oxide material deposited upon the layer of silicon dioxide by ion-beam-assisted-deposition, said layer of cubic oxide material characterized as biaxially oriented. Preferably, the cubic oxide material is yttria-stabilized zirconia. Additional thin layers of biaxially oriented ruthenium oxide or lanthanum strontium cobalt oxide are deposited upon the layer of yttria-stabilized zirconia. An intermediate layer of cerium oxide is employed between the yttria-stabilized zirconia layer and the lanthanum strontium cobalt oxide layer. Also, a layer of barium strontium titanium oxide can be upon the layer of biaxially oriented ruthenium oxide or lanthanum strontium cobalt oxide. Also, a method of forming such thin film structures, including a low temperature deposition of a layer of a biaxially oriented cubic oxide material upon the silicon dioxide surface of a silicon dioxide/silicon substrate is provided.

Jia, Quanxi (Los Alamos, NM); Arendt, Paul N. (Los Alamos, NM)

2001-01-01T23:59:59.000Z

336

Regulating carbon dioxide capture and storage  

E-Print Network [OSTI]

This essay examines several legal, regulatory and organizational issues that need to be addressed to create an effective regulatory regime for carbon dioxide capture and storage ("CCS"). Legal, regulatory, and organizational ...

De Figueiredo, Mark A.

2007-01-01T23:59:59.000Z

337

Carbon Dioxide Emission Factors for Coal  

Reports and Publications (EIA)

The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

1994-01-01T23:59:59.000Z

338

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

1988-01-01T23:59:59.000Z

339

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

Narain, N.K.; Ruether, J.A.; Smith, D.N.

1987-10-07T23:59:59.000Z

340

Ceramic coating system or water oxidation environments  

DOE Patents [OSTI]

A process for water oxidation of combustible materials in which during at least a part of the oxidation corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises titanium dioxide coated onto a titanium metal substrate. Such ceramic composites have been found to be highly resistant to environments encountered in the process of supercritical water oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases, and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 700.degree. C. The ceramic composites are also resistant to degradation mechanisms caused by thermal stresses.

Hong, Glenn T. (Tewksbury, MA)

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Thorium dioxide: properties and nuclear applications  

SciTech Connect (OSTI)

This is the sixth book on reactor materials published under sponsorship of the Naval Reactors Office of the United States Department of Energy, formerly the United States Atomic Energy Commission. This book presents a comprehensive compilation of the most significant properties of thorium dioxide, much like the book Uranium Dioxide: Properties and Nuclear Applications presented information on the fuel material used in the Shippingport Pressurized Water Reactor core.

Belle, J.; Berman, R.M. (eds.)

1984-01-01T23:59:59.000Z

342

Corrosion of austenitic and ferritic-martensitic steels exposed to supercritical carbon dioxide  

SciTech Connect (OSTI)

Supercritical carbon dioxide (S-CO{sub 2}) is a potential coolant for advanced nuclear reactors. The corrosion behavior of austenitic steels (alloys 800H and AL-6XN) and ferritic-martensitic (FM) steels (F91 and HCM12A) exposed to S-CO{sub 2} at 650 C and 20.7 MPa is presented in this work. Oxidation was identified as the primary corrosion phenomenon. Alloy 800H had oxidation resistance superior to AL-6XN. The FM steels were less corrosion resistant than the austenitic steels, which developed thick oxide scales that tended to exfoliate. Detailed microstructure characterization suggests the effect of alloying elements such as Al, Mo, Cr, and Ni on the oxidation of the steels.

Tan, Lizhen [ORNL; Anderson, Mark [University of Wisconsin, Madison; Taylor, D [Bechtel Marine Propulsion Corporation; Allen, Todd R. [University of Wisconsin, Madison

2011-01-01T23:59:59.000Z

343

Distribution and origin of sulfur in Colorado oil shale  

SciTech Connect (OSTI)

The sulfur content of 1,225 samples of Green River oil shale from two core holes in the Piceance Creek Basin, Colorado, ranges from nearly 0 to 4.9 weight percent. In one core hole, the average sulfur content of a sequence of oil shale 555 m thick, which represents nearly the maximum thickness of oil shale in the basin, is 0.76 weight percent. The vertical distribution of sulfur through the oil shale is cyclic. As many as 25 sulfur cycles have lateral continuity and can be traced between the core holes. Most of the sulfur resides in iron sulfides (pyrite, marcasite, and minor. pyrrhotite), and small amounts are organically bound in kerogen. In general, the concentration of sulfur correlates moderately with oil shale yield, but the degree of association ranges from quite high in the upper 90 m of the oil shale sequence to low or none in the leached zone and in illitic oil shale in the lower part of the sequence. Sulfur also correlates moderately with iron in the carbonate oil shale sequence, but no correlation was found in the illitic samples. Sulfide mineralization is believed to have occurred during early and late stages of diagenesis, and after lithification, during development of the leached zone. Significant amounts of iron found in ankeritic dolomite and in illite probably account for the lack of a strong correlation between sulfur and iron.

Dyni, J.R.

1983-04-01T23:59:59.000Z

344

Process for removing pyritic sulfur from bituminous coals  

DOE Patents [OSTI]

A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

1990-01-01T23:59:59.000Z

345

Sulfuric acid deposition from stratospheric geoengineering with sulfate aerosols  

E-Print Network [OSTI]

aerosols can potentially result in an increase in acid deposition. [4] Acid rain has been studiedSulfuric acid deposition from stratospheric geoengineering with sulfate aerosols Ben Kravitz,1 Alan limit of hydration of all sulfate aerosols into sulfuric acid. For annual injection of 5 Tg of SO2

Robock, Alan

346

Detecting Hazardous Gas Analytes Using Porous Silicon Sensors Coated with Metal Oxide Nanoparticles Eddie Goude, University of Florida Georgia Tech SURF 2011  

E-Print Network [OSTI]

), Sulfur Dioxide (SO2), Phosphine (PH3), and Carbon Monoxide (CO) while the resistance across the sensors of ethanol etched the sample. Then the electron beam process places a layer of titanium then a layer of gold (Au), Nickel (Ni) and Titanium (Ti) nanoparticles. However, the Tin and Gold are the main focus

Li, Mo

347

Increasing carbon dioxideIncreasing carbon dioxide & its effect on forest& its effect on forest  

E-Print Network [OSTI]

ecosystem's natural capacity toA forest ecosystem's natural capacity to capture energy, capture energy's natural capacity toA forest ecosystem's natural capacity to capture energy, capture energy, sustain life10/13/2010 1 Increasing carbon dioxideIncreasing carbon dioxide & its effect on forest& its effect

Gray, Matthew

348

Metal-sulfur type cell having improved positive electrode  

DOE Patents [OSTI]

An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

Dejonghe, Lutgard C. (Berkeley, CA); Visco, Steven J. (Berkeley, CA); Mailhe, Catherine C. (Berkeley, CA); Armand, Michel B. (St. Martin D'Uriage, FR)

1989-01-01T23:59:59.000Z

349

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium...

350

Effect of sulfur loading on the desulfation chemistry of a commercial...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sulfur loading on the desulfation chemistry of a commercial lean NOx trap catalyst. Effect of sulfur loading on the desulfation chemistry of a commercial lean NOx trap catalyst....

351

E-Print Network 3.0 - amoco sulfur recovery process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 80 Sulfur and oxygen isotope composition of the atmosphere in Saxony (Germany) Tichomirowa et al. Summary: ? a) Mixing processes 12;Sulfur and oxygen isotope...

352

High-sulfur coals in the eastern Kentucky coal field  

SciTech Connect (OSTI)

The Eastern Kentucky coal field is notable for relatively low-sulfur, [open quotes]compliance[close quotes] coals. Virtually all of the major coals in this area do have regions in which higher sulfur lithotypes are common, if not dominant, within the lithologic profile. Three Middle Pennsylvanian coals, each representing a major resource, exemplify this. The Clintwood coal bed is the stratigraphically lowest coal bed mined throughout the coal field. In Whitley County, the sulfur content increase from 0.6% at the base to nearly 12% in the top lithotype. Pyrite in the high-sulfur lithotype is a complex mixture of sub- to few-micron syngenetic forms and massive epigenetic growths. The stratigraphically higher Pond Creek coal bed is extensively mined in portions of the coal field. Although generally low in sulfur, in northern Pike and southern Martin counties the top one-third can have up to 6% sulfur. Uniformly low-sulfur profiles can occur within a few hundred meters of high-sulfur coal. Pyrite occurs as 10-50 [mu]m euhedra and coarser massive forms. In this case, sulfur distribution may have been controlled by sandstone channels in the overlying sediments. High-sulfur zones in the lower bench of the Fire Clay coal bed, the stratigraphically highest coal bed considered here, are more problematical. The lower bench, which is of highly variable thickness and quality, generally is overlain by a kaolinitic flint clay, the consequence of a volcanic ash fall into the peat swamp. In southern Perry and Letcher counties, a black, illite-chlorite clay directly overlies the lower bench. General lack of lateral continuity of lithotypes in the lower bench suggests that the precursor swamp consisted of discontinuous peat-forming environments that were spatially variable and regularly inundated by sediments. Some of the peat-forming areas may have been marshlike in character.

Hower, J.C.; Graham, U.M. (Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington, KY (United States))

1993-08-01T23:59:59.000Z

353

An Analysis of PM and NOx Train Emissions in the Alameda Corridor, CA  

E-Print Network [OSTI]

Environment. Estimation of Nitrogen Dioxide Concentrationsmatter, ozone, nitrogen dioxide and sulfur dioxide - Globalnitrate particles and nitrogen dioxide can reduce visibility

Sangkapichai, Mana; Saphores, Jean-Daniel M; Ritchie, Stephen G.; You, Soyoung Iris; Lee, Gunwoo

2008-01-01T23:59:59.000Z

354

Molecular Structures of Polymer/Sulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life  

SciTech Connect (OSTI)

Vulcanizedpolyaniline/sulfur (SPANI/S) nanostructures were investigated for Li-S battery applications, but the detailed molecular structures of such composites have not been fully illustrated. In this paper, we synthesize SPANI/S composites with different S content in a nanorod configuration. FTIR, Raman, XPS, XRD, SEM and elemental analysis methods are used to characterize the molecular structure of the materials. We provide clear evidence that a portion of S was grafted on PANI during heating and connected the PANI chains with disulfide bonds to form a crosslinked network and the rest of S was encapsulated within it.. Polysulfides and elementary sulfur nanoparticles are physically trapped inside the polymer network and are not chemically bound to the polymer. The performance of the composites is further improved by reducing the particle size. Even after 500 cycles a capacity retention rate of 68.8% is observed in the SPANI/S composite with 55% S content.

Xiao, Lifen; Cao, Yuliang; Xiao, Jie; Schwenzer, Birgit; Engelhard, Mark H.; Saraf, Laxmikant V.; Nie, Zimin; Exarhos, Gregory J.; Liu, Jun

2013-04-26T23:59:59.000Z

355

Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids  

SciTech Connect (OSTI)

The mechanisms by which various fuel component hydrocarbons related to both heavy petroleum and coal-derived liquids are converted to hydrogen without forming carbon were investigated. Reactive differences between paraffins and aromatics in autothermal reforming (ATR) were shown to be responsible for the observed fuel-specific carbon formation characteristics. The types of carbon formed in the reformer were identified by SEM and XRD analyses of catalyst samples and carbon deposits. From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation. The effects of propylene addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics, synergistic effects on conversion characteristics were identified. Indications that the sulfur content of the fuel may be the limiting factor for efficient ATR operation were found. The conversion and degradation effects of the sulfur additive (thiophene) were examined.

Not Available

1981-10-01T23:59:59.000Z

356

Gasification combined cycle: Carbon dioxide recovery, transport, and disposal  

SciTech Connect (OSTI)

The objective of the project is to develop engineering evaluations of technologies for the capture, use, and disposal of carbon dioxide (CO{sub 2}). This project emphasizes CO{sub 2}-capture technologies combined with integrated gasification combined-cycle (IGCC) power systems. Complementary evaluations address CO{sub 2} transportation, CO{sub 2} use, and options for the long-term sequestering of unused CO{sub 2}. Commercially available CO{sub 2}-capture technology is providing a performance and economic baseline against which to compare innovative technologies. The intent is to provide the CO{sub 2} budget, or an {open_quotes}equivalent CO{sub 2}{close_quotes} budget, associated with each of the individual energy-cycle steps, in addition to process design capital and operating costs. The value used for the {open_quotes}equivalent CO{sub 2}{close_quotes} budget is 1 kg of CO{sub 2} per kilowatt-hour (electric). The base case is a 458-MW IGCC system that uses an air-blown Kellogg-Rust-Westinghouse agglomerating fluidized-bed gasifier, Illinois No. 6 bituminous coal feed, and in-bed sulfur removal. Mining, feed preparation, and conversion result in a net electric power production of 454 MW, with a CO{sub 2} release rate of 0.835 kg/kWhe. Two additional life-cycle energy balances for emerging technologies were considered: (1) high-temperature CO{sub 2} separation with calcium- or magnesium-based sorbents, and (2) ambient-temperature facilitated-transport polymer membranes for acid-gas removal.

Doctor, R.D.; Molburg, J.C.; Thimmapuram, P.R.; Berry, G.F.; Livengood, C.D.

1994-09-01T23:59:59.000Z

357

Investigation on Nitric Oxide and Soot of Biodiesel and Conventional Diesel using a Medium Duty Diesel Engine  

E-Print Network [OSTI]

Biodiesel has been suggested as an alternative fuel to the petroleum diesel fuel. It beneficially reduces regulated emission gases, but increases NOx (nitric oxide and nitrogen dioxide) Thus, the increase in NOx is the barrier for potential growth...

Song, Hoseok

2012-07-16T23:59:59.000Z

358

Fabrication of Cerium Oxide and Uranium Oxide Microspheres for Space Nuclear Power Applications  

SciTech Connect (OSTI)

Cerium oxide and uranium oxide microspheres are being produced via an internal gelation sol-gel method to investigate alternative fabrication routes for space nuclear fuels. Depleted uranium and non-radioactive cerium are being utilized as surrogates for plutonium-238 (Pu-238) used in radioisotope thermoelectric generators and for enriched uranium required by nuclear thermal rockets. While current methods used to produce Pu-238 fuels at Los Alamos National Laboratory (LANL) involve the generation of fine powders that pose a respiratory hazard and have a propensity to contaminate glove boxes, the sol-gel route allows for the generation of oxide microsphere fuels through an aqueous route. The sol-gel method does not generate fine powders and may require fewer processing steps than the LANL method with less operator handling. High-quality cerium dioxide microspheres have been fabricated in the desired size range and equipment is being prepared to establish a uranium dioxide microsphere production capability.

Jeffrey A. Katalenich; Michael R. Hartman; Robert C. O'Brien

2013-02-01T23:59:59.000Z

359

Respiratory effects of two-hour exposure with intermittent exercise to ozone, sulfur dioxide and nitrogen dioxide alone and in combination in normal subjects  

SciTech Connect (OSTI)

Seven adult male healthy volunteer subjects were exposed to 0.15 ppm each of O/sub 3/, SO/sub 2/ and NO/sub 2/ alone and in combination, with intermittent light exercise for two hours. Three of the 7 subjects developed cough during deep inspiration and one subject had chest pain during exposure to O/sub 3/ alone. Among the various indices of pulmonary function tests, specific airway conductane (G/sub aw//V/sub tg/) was the most sensitive index to examine the changes produced by the exposure to O/sub 3/ and other pollutants. Significant decrease of G/sub aw//V/sub tg/ in comparison with control measurements was observed in 6 of 7 subjects during exposure to O/sub 3/ alone, and in all subjects during exposures to the mixture of O/sub 3/ and other pollutants. However, no significant enhancement of effect was observed in the mixture of O/sub 3/ and other pollutants, although a slightly greater decrease of airway resistance/volume of thoracic gas (G/sub aw//V/sub tg/) was observed for the mixture of O/sub 3/ and other pollutants than for O/sub 3/ alone.

Kagawa, J.

1983-01-01T23:59:59.000Z

360

Reaction of titanium polonides with carbon dioxide  

SciTech Connect (OSTI)

It has been ascertained that heating titanium and tantalum in carbon dioxide to temperatures of 500 or 800/sup 0/C alters the composition of the gas phase, causing the advent of carbon monoxide and lowering the oxygen content. Investigation of the thermal stability of titanium polonides in a carbon dioxide medium has shown that titanium mono- and hemipolonides are decomposed at temperatures below 350/sup 0/C. The temperature dependence of the vapor pressure of polonium produced in the decomposition of these polonides in a carbon dioxide medium have been determined by a radiotensimetric method. The enthalpy of the process, calculated from this relationship, is close to the enthalpy of vaporization of elementary polonium in vacuo.

Abakumov, A.S.; Malyshev, M.L.; Reznikova, N.F.

1987-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

SEQUESTERING CARBON DIOXIDE IN COALBEDS  

SciTech Connect (OSTI)

The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also provided direct synergism with the original goals of our work. Specific accomplishments of this project are summarized below in three broad categories: experimentation, model development, and coal characterization.

K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

2003-04-30T23:59:59.000Z

362

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

363

A methodology for forecasting carbon dioxide flooding performance  

E-Print Network [OSTI]

A methodology was developed for forecasting carbon dioxide (CO2) flooding performance quickly and reliably. The feasibility of carbon dioxide flooding in the Dollarhide Clearfork "AB" Unit was evaluated using the methodology. This technique is very...

Marroquin Cabrera, Juan Carlos

1998-01-01T23:59:59.000Z

364

Dry process fluorination of uranium dioxide using ammonium bifluoride  

E-Print Network [OSTI]

An experimental study was conducted to determine the practicality of various unit operations for fluorination of uranium dioxide. The objective was to prepare ammonium uranium fluoride double salts from uranium dioxide and ...

Yeamans, Charles Burnett, 1978-

2003-01-01T23:59:59.000Z

365

Carbon Dioxide Capture/Sequestration Tax Deduction (Kansas)  

Broader source: Energy.gov [DOE]

Carbon Dioxide Capture/Sequestration Tax Deduction allows a taxpayer a deduction to adjusted gross income with respect to the amortization of the amortizable costs of carbon dioxide capture,...

366

Louisiana Geologic Sequestration of Carbon Dioxide Act (Louisiana)  

Broader source: Energy.gov [DOE]

This law establishes that carbon dioxide and sequestration is a valuable commodity to the citizens of the state. Geologic storage of carbon dioxide may allow for the orderly withdrawal as...

367

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network [OSTI]

carbon dioxide emissions per 1,000 cubic feet of natural gas. In this case, there is much less energy

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

368

VHF EPR quantitation and speciation of organic sulfur in coal. Technical report, 1 March--31 May 1994  

SciTech Connect (OSTI)

The existence of free electrons in coals` natural state offers a great attraction for Electron Paramagnetic Resonance (EPR) analysis to aid in the study of the structure and composition of coal. This direct and non-destructive approach to coal analysis has been hindered by the problem of resolution using the conventional 9.5 GHz EPR spectrometers. In the past few years, the authors have developed techniques including W-band Very High Frequency EPR spectroscopy as a means of determining the quantity and structure of organic sulfur in native and desulfurized coals. The state-of-the-art 95 GHz (W-band) EPR spectrometer which they have constructed shows a well resolved spectrum including the interaction between unpaired electrons and the heteroatom like sulfur. The spectra also provide quantitative as well as qualitative information regarding different sulfur species. In this quarter, the authors have been concentrating their efforts on developing a new standard protocol in handling and preparing the coal samples for EPR measurements to provide a quantitative comparison between the EPR spectra of coal in the natural state and desulfurized. Sixteen new coal samples, both native and desulfurized, have been provided to us as well as to the University of Kentucky for analysis by XANES. These samples have been run in both laboratories. The results from these samples, which were kept in an oxygen-free environment, are compared to those of 10 previous samples, which were air-oxidized. Significant differences in the EPR spectra of air-oxidized and oxygen free samples are noted; results from Kentucky are not yet available. Desulfurized samples show a significant decrease in organic sulfur as measured by the VHF-EPR method.

Clarkson, R.B.; Belford, R.L.

1994-09-01T23:59:59.000Z

369

Air Pollution XVI 247 Emissions of Nitrogen Dioxide from Modern  

E-Print Network [OSTI]

Air Pollution XVI 247 Emissions of Nitrogen Dioxide from Modern Diesel Vehicles G.A. Bishop and D negative implications for local photochemical ozone production. Keywords: Nitrogen dioxide, automobile strategies, Lemaire [1] suggests that nitrogen dioxide (NO2) was forgotten as a separate component of the NOx

Denver, University of

370

Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere  

E-Print Network [OSTI]

dioxide Water vapor #12;Atmospheric composition (parts per million by volume) · Nitrogen (N2) 780Thermal Infrared Radiation and Carbon Dioxide in the Atmosphere Bill Satzer 3M Company #12;Outline,840 · Oxygen (O2) 209,460 · Argon (Ar) 9340 · Carbon dioxide (CO2) 394 · Methane (CH4) 1.79 · Ozone (O3) 0

Olver, Peter

371

Designed amyloid fibers as materials for selective carbon dioxide capture  

E-Print Network [OSTI]

Designed amyloid fibers as materials for selective carbon dioxide capture Dan Lia,b,c,1 , Hiroyasu demonstrate that amyloids, self-assembling protein fibers, are effective for selective carbon dioxide capture. Solid-state NMR proves that amyloid fibers containing alkylamine groups reversibly bind carbon dioxide

372

Array of titanium dioxide nanostructures for solar energy utilization  

DOE Patents [OSTI]

An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

Qiu, Xiaofeng; Parans Paranthaman, Mariappan; Chi, Miaofang; Ivanov, Ilia N; Zhang, Zhenyu

2014-12-30T23:59:59.000Z

373

Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in  

E-Print Network [OSTI]

Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

Rochelle, Gary T.

374

Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries  

E-Print Network [OSTI]

lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit at C/2. KEYWORDS: Lithium sulfur batteries; energy storage; surface modification Increasing the energy

Cui, Yi

375

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents [OSTI]

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

376

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

377

Inhibition of NADPH cytochrome P450 reductase by the model sulfur mustard vesicant 2-chloroethyl ethyl sulfide is associated with increased production of reactive oxygen species  

SciTech Connect (OSTI)

Inhalation of vesicants including sulfur mustard can cause significant damage to the upper airways. This is the result of vesicant-induced modifications of proteins important in maintaining the integrity of the lung. Cytochrome P450s are the major enzymes in the lung mediating detoxification of sulfur mustard and its metabolites. NADPH cytochrome P450 reductase is a flavin-containing electron donor for cytochrome P450. The present studies demonstrate that the sulfur mustard analog, 2-chloroethyl ethyl sulfide (CEES), is a potent inhibitor of human recombinant cytochrome P450 reductase, as well as native cytochrome P450 reductase from liver microsomes of saline and {beta}-naphthoflavone-treated rats, and cytochrome P450 reductase from type II lung epithelial cells. Using rat liver microsomes from {beta}-naphthoflavone-treated rats, CEES was found to inhibit CYP 1A1 activity. This inhibition was overcome by microsomal cytochrome P450 reductase from saline-treated rats, which lack CYP 1A1 activity, demonstrating that the CEES inhibitory activity was selective for cytochrome P450 reductase. Cytochrome P450 reductase also generates reactive oxygen species (ROS) via oxidation of NADPH. In contrast to its inhibitory effects on the reduction of cytochrome c and CYP1A1 activity, CEES was found to stimulate ROS formation. Taken together, these data demonstrate that sulfur mustard vesicants target cytochrome P450 reductase and that this effect may be an important mechanism mediating oxidative stress and lung injury.

Gray, Joshua P. [Department of Science, United States Coast Guard Academy, New London, CT (United States); Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Mishin, Vladimir [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Heck, Diane E. [Department of Environmental Health Science, New York Medical College, Valhalla, NY (United States); Laskin, Debra L. [Department of Pharmacology and Toxicology, Rutgers University, Piscataway, NJ (United States); Laskin, Jeffrey D., E-mail: jlaskin@eohsi.rutgers.ed [Environmental and Occupational Medicine, UMDNJ-Robert Wood Johnson Medical School, Piscataway, NJ (United States)

2010-09-01T23:59:59.000Z

378

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

2013-08-13T23:59:59.000Z

379

Kinetics of the heterogeneous photocatalytic oxidation of isopropanol  

SciTech Connect (OSTI)

Intrinsic kinetics for the ambient temperature photocatalytic oxidation (PCO) of dilute isopropanol (IPA) in humid air over near-ultraviolet (UV) irradiated titanium dioxide have been determined using a continuous microreactor flow system. The IPA disappearance rate exhibits a Langmuir-Hinshelwood-Hougen-Watson (LHHW) type dependence on IPA concentration. The rate is nearly first order in UV irradiance at low UV flux. The rate is independent of relative humidity R{sub H} at low R{sub H} levels, but is enhanced by water vapor concentration at higher levels. This relatively unique behavior is likely a direct consequence of the adsorption strength of alcohols on titania, which in general is considerably higher than the corresponding adsorption strengths for other classes of organic compounds. In addition to carbon dioxide, acetone is generated as a product of IPA destruction. This acetone is itself photocatalytically oxidized to carbon dioxide and water vapor at longer residence time. 10 refs., 3 figs.

Ameen, M.; Kalaga, M.; Annapragada, R.; Raupp, G.B. [Arizona State Univ., Tempe, AZ (United States)

1996-12-31T23:59:59.000Z

380

Sulfurized olefin lubricant additives and compositions containing same  

SciTech Connect (OSTI)

Lubricant additives having substantially improved extreme pressure characteristics are provided by modifying certain sulfurized olefins by reacting said olefins with a cyclic polydisulfide under controlled reaction conditions and at a temperature of at least about 130/sup 0/ C.

Braid, M.

1980-03-25T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Diesel Emissions Control-Sulfur Effects (DECSE) Program Status  

SciTech Connect (OSTI)

Determine the impact of fuel sulfur levels on emission control systems that could be implemented to lower emissions of NO{sub x} and PM from on-highway trucks in the 2002-2004 time frame.

None

1999-06-29T23:59:59.000Z

382

Introduction Air Quality and Nitrogen Dioxide  

E-Print Network [OSTI]

- Global update 2005. Primary sources of air pollutants include combustion products from power generationIntroduction Air Quality and Nitrogen Dioxide Air pollution can be defined as "the presence effects to man and/or the environment". (DEFRA) "Clean air is considered to be a basic requirement

383

Carbon Dioxide Corrosion: Modelling and Experimental Work  

E-Print Network [OSTI]

Carbon Dioxide Corrosion: Modelling and Experimental Work Applied to Natural Gas Pipelines Philip in the corrosion related research institutions at IFE and the Ohio University or any other scientific research;#12;Introduction - v - Summary CO2 corrosion is a general problem in the industry and it is expensive. The focus

384

Atmospheric Lifetime of Fossil Fuel Carbon Dioxide  

E-Print Network [OSTI]

Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

Scherer, Norbert F.

385

Hydroelectric Reservoirs -the Carbon Dioxide and Methane  

E-Print Network [OSTI]

Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

Fischlin, Andreas

386

Acid sorption regeneration process using carbon dioxide  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent in the presence of carbon dioxide under pressure. The acids are freed from the sorbent phase by a suitable regeneration method, one of which is treating them with an organic alkylamine solution thus forming an alkylamine-carboxylic acid complex which thermally decomposes to the desired carboxylic acid and the alkylamine.

King, C. Judson (Kensington, CA); Husson, Scott M. (Anderson, SC)

2001-01-01T23:59:59.000Z

387

Carbon dioxide storage professor Martin Blunt  

E-Print Network [OSTI]

of CCS storage there are over a hundred sites worldwide where Co2 is injected under- ground as partCarbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS and those for injection and storage in deep geological formations. all the individual elements operate today

388

Carbon Dioxide Capture from Coal-Fired  

E-Print Network [OSTI]

. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologiesCarbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005 environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

389

Carbon Dioxide Corrosion and Inhibition Studies  

E-Print Network [OSTI]

· Corrosion inhibition very important in the oil industry · Film forming inhibitors containing nitrogenCarbon Dioxide Corrosion and Inhibition Studies Kristin Gilida #12;Outline · Background = Zreal + Zim Rp 1/Corr Rate #12;Tafel · Measures corrosion rate directly · Measures iCORR from A and C

Petta, Jason

390

The South Karelia Air Pollution Study. The effects of malodorous sulfur compounds from pulp mills on respiratory and other symptoms  

SciTech Connect (OSTI)

The paper mills in South Karelia, the southeast part of Finland, are responsible for releasing a substantial amount of malodorous sulfur compounds such as hydrogen sulfide (H2S), methyl mercaptan (CH3SH), and methyl sulfides ((CH3)2S and (CH3)2S2), into ambient air. In the most polluted residential area the annual mean concentrations of hydrogen sulfide and methyl mercaptan are estimated to be 8 and 2 to 5 micrograms/m3 and the highest daily average concentration 100 and 50 micrograms/m3. The annual mean and highest daily concentrations of sulfur dioxide (SO2) are very low. We studied the effects of malodorous sulfur compounds on eye, nasal and respiratory symptoms, and headache in adults. A cross-sectional self-administered questionnaire was distributed in February 1987 and responded to by 488 adults living in a severely (n = 198), a moderately (n = 204), and a nonpolluted community (n = 86). This included questions about occurrence of the symptoms of interest during the previous 4 wk and 12 months and individual, behavioral, and other environmental determinants of the symptoms. The response rate was 83%. The odds ratios (OR) for symptoms experienced often or constantly in severely versus nonpolluted and moderately versus nonpolluted communities were estimated in logistic regression analysis controlling potential confounders. The odds ratios for eye (moderate exposure OR 11.70, Cl95% 2.33 to 58.65; severe exposure OR 11.78, Cl95% 2.35 to 59.09) and nasal symptoms (OR 2.01, Cl95% 0.97 to 4.15; OR 2.19, Cl95% 1.06 to 4.55) and cough (OR 1.89, Cl95% 0.61 to 5.86; OR 3.06, Cl95% 1.02 to 9.29) during the previous 12 months were increased, with a dose-response pattern.

Jaakkola, J.J.; Vilkka, V.; Marttila, O.; Jaeppinen, P.H.; Haahtela, T. (South Karelia Allergy and Environment Institute, Espoo (Finland))

1990-12-01T23:59:59.000Z

391

Nitrous Oxide Fluxes from the Gulf of Mexico "Dead Zone" Primary Investigator: Craig Stow -NOAA GLERL  

E-Print Network [OSTI]

forecasts require accurate estimates of greenhouse gas emission rates. Currently, there are few measurements Management Research Laboratory Overview Nitrous oxide is a potent greenhouse gas with a global warming oxide is a potent greenhouse gas with a global warming potential ~300 times that of carbon dioxide

392

Low temperature fracture evaluation of plasticized sulfur paving mixtures  

E-Print Network [OSTI]

May 1985 Major Subject: Civil Engineering LOW TEMPERATURE FRACTURE EVALUATION OF PLASTICIZED SULFUR PAVING MIXTURES A Thesis by KAMYAR MAHBOUB Approved as to style and content by: Dallas N. Li tie (Chai rman of Committee) Ro e . Lytto Member... modifications to the standard ASTM procedure. These modifications were required due to the nature of plasticized sulfur mixtures and asphalt cement mixtures. The J-integral version of Paris ' law was successfully used to characterize the fatigue...

Mahboub, Kamyar

2012-06-07T23:59:59.000Z

393

Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes  

E-Print Network [OSTI]

is called the pumping-power advantage factor, and has the value 2. 5 x 10 for sodium. The only metals having a higher value of H are 13 lithium 7 and bismuth. Lithium 7 comprises 92. 5% of natural lithium, but the cost of separating it from lithium 6...-section for thermal neutrons being 0. 130 barns. For comparison, water has an absorption cross-section of 0. 58 barns for thermal neutrons (2) . Sulfur is not activated by exposure to neutron flux in such a way as to produce a radioactive isotope which...

Stone, Porter Walwyn

1960-01-01T23:59:59.000Z

394

Role of Moisture in Adsorption, Photocatalytic Oxidation, and  

E-Print Network [OSTI]

various Hg emission sources. A novel low-cost methodology using titanium dioxide (TiO2) nanoparticlesRole of Moisture in Adsorption, Photocatalytic Oxidation, and Reemission of Elemental Mercury gas. Without UV irradiation, Hg0 adsorption was found to be insignificant, but it could be enhanced

Li, Ying

395

The effects of atmospheric sulfur dioxide and bisulfite containing solutions on four St. Augustinegrass (Stenotaphrum secundatum (Walt.)Kuntze) cultivars  

E-Print Network [OSTI]

canopy vertical growth rate (mm day ') of four St. Auoustineqrass cultivars (+SD). Effects of a 5-week (4 h day-', 5 days week ') exposure to 0. 20 ul liter ' SO, on stolon internode elongation (mm) of four St. Auqustinegrass cultivars (+SD) 23 24... following a 2 h exposure to 50 mM KHSO~, and mean visible injury ratings 20 h after fumiqation with 1. 0 ul liter ' SO, ( 10 h day ', 4 consecutive days) of four St. Augustineqrass cultivars 54 VI. Mean percent in, jury to leaf blade sections of four...

Amthor, Jeffrey Scott

1980-01-01T23:59:59.000Z

396

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

SciTech Connect (OSTI)

Since 2006, China has set goals of reducing energy intensity, emissions, and pollutants in multiple guidelines and in the Five Year Plans. Various strategies and measures have then been taken to improve the energy efficiency in all sectors and to reduce pollutants. Since controlling energy, CO{sub 2} emissions, and pollutants falls under the jurisdiction of different government agencies in China, many strategies are being implemented to fulfill only one of these objectives. Co-controls or integrated measures could simultaneously reduce greenhouse gas (GHG) emissions and criteria air pollutant emissions. The targets could be met in a more cost effective manner if the integrated measures can be identified and prioritized. This report provides analysis and insights regarding how these targets could be met via co-control measures focusing on both CO{sub 2} and SO{sub 2} emissions in the cement, iron &steel, and power sectors to 2030 in China. An integrated national energy and emission model was developed in order to establish a baseline scenario that was used to assess the impact of actions already taken by the Chinese government as well as planned and expected actions. In addition, CO{sub 2} mitigation scenarios and SO{sub 2} control scenarios were also established to evaluate the impact of each of the measures and the combined effects. In the power sector, although the end of pipe SO{sub 2} control technology such as flue gas desulfurization (FGD) has the largest reduction potential for SO{sub 2} emissions, other CO{sub 2} control options have important co-benefits in reducing SO{sub 2} emissions of 52.6 Mt of SO{sub 2} accumulatively. Coal efficiency improvements along with hydropower, renewable and nuclear capacity expansion will result in more than half of the SO{sub 2} emission reductions as the SO{sub 2} control technology through 2016. In comparison, the reduction from carbon capture and sequestration (CCS) is much less and has negative SO{sub 2} reductions potential. The expanded biomass generation scenario does not have significant potential for reducing SO{sub 2} emissions, because of its limited availability. For the cement sector, the optimal co-control strategy includes accelerated adoption of energy efficiency measures, decreased use of clinker in cement production, increased use of alternative fuels, and fuel-switching to biomass. If desired, additional SO{sub 2} mitigation could be realized by more fully adopting SO{sub 2} abatement mitigation technology measures. The optimal co-control scenario results in annual SO{sub 2} emissions reductions in 2030 of 0.16 Mt SO{sub 2} and annual CO{sub 2} emissions reductions of 76 Mt CO{sub 2}. For the iron and steel sector, the optimal co-control strategy includes accelerated adoption of energy efficiency measures, increased share of electric arc furnace steel production, and reduced use of coal and increased use of natural gas in steel production. The strategy also assumes full implementation of sinter waste gas recycling and wet desulfurization. This strategy results in annual SO{sub 2} emissions reductions in 2030 of 1.3 Mt SO{sub 2} and annual CO{sub 2} emissions reductions of 173 Mt CO{sub 2}.

Zhou, Nan; Price, Lynn; Zheng, Nina; Ke, Jing; Hasanbeigi, Ali

2011-10-15T23:59:59.000Z

397

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

coal Gas coal Fat coal Coking coal Lean coal Meagre coalCoal used for coking Natural Gas Coal used as fuel Source:

Zhou, Nan

2013-01-01T23:59:59.000Z

398

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

NG Fired CC Nuclear Power Wind Power Coal Not all of theand other Renew Solar Wind Power Hydropower Nuclear Power NGcapacity of solar and wind power increasing rapidly after

Zhou, Nan

2013-01-01T23:59:59.000Z

399

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

87 kWh/t cement for vertical shaft kiln (VSK) production (cement is produced by either a rotary kiln or a verticalChinese Cement Kilns. Rotary Kiln Production Vertical Shaft

Zhou, Nan

2013-01-01T23:59:59.000Z

400

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

committed to reduce its carbon intensity (CO 2 per unit ofcommitted to reduce its carbon intensity (CO 2 per unit of2 emissions, and the 40-45% carbon intensity reduction goals

Zhou, Nan

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

Agency (IEA). 2009. World Energy Outlook 2009. Paris: OECDscenario in the 2009 World Energy Outlook (IEA 2009). Table

Zhou, Nan

2013-01-01T23:59:59.000Z

402

New methodology for estimating biofuel consumption for cooking: Atmospheric emissions of black carbon and sulfur dioxide from India  

E-Print Network [OSTI]

New methodology for estimating biofuel consumption for cooking: Atmospheric emissions of black; accepted 8 June 2004; published 30 July 2004. [1] The dominance of biofuel combustion emissions in the Indian region, and the inherently large uncertainty in biofuel use estimates based on cooking energy

Dickerson, Russell R.

403

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

David Kline of the National Renewable Energy Laboratory foralong with hydropower, renewable and nuclear capacityCapacity Accelerated Renewable Generation Power Sector CO2

Zhou, Nan

2013-01-01T23:59:59.000Z

404

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

China CIS Electricity Generation Capacity, 2000-2030 Installed Capacity (GW) SolarChina Electricity Generation under Reference Scenario, 2000-2030 Generation Output (TWh) Biomass and other Renew Solar

Zhou, Nan

2013-01-01T23:59:59.000Z

405

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

improvements along with hydropower, renewable and nuclearreport are: Power Sector Hydropower in particular has theEfficiency Expanded Hydropower Generation Capacity

Zhou, Nan

2013-01-01T23:59:59.000Z

406

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

Improvements in Coal Generation Efficiency Expanded2 emissions. Improving coal generation efficiency for CO 2the contribution from coal generation efficiency declines,

Zhou, Nan

2013-01-01T23:59:59.000Z

407

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

as energy use per unit of gross domestic product (GDP) byas energy use per unit of gross domestic product (GDP) by

Zhou, Nan

2013-01-01T23:59:59.000Z

408

Remediation of chromium(VI) in the vadose zone: stoichiometry and kinetics of chromium(VI) reduction by sulfur dioxide  

E-Print Network [OSTI]

. The reaction was also rapid, with the half-time of about 45 minutes at pH 6 and about 16 hours at pH 7. A two-step kinetic model was developed to describe changes in concentrations of Cr(VI), S(IV), and S(V). Nonlinear regression was applied to obtain...

Ahn, Min

2004-11-15T23:59:59.000Z

409

Method of detecting sulfur dioxide. [DOE patent application; 1,1,1-trimethyl-N-sulfinyl silanamine  

DOE Patents [OSTI]

(CH/sub 3/)/sub 3/SiNSO is produced by the reaction of ((CH/sub 3/)/sub 3/Si)/sub 2/NH with SO/sub 2/. Also produced in the reaction are ((CH/sub 3/)/sub 3/Si)/sub 2/O and a new solid compound (NH/sub 4/)((CH/sub 3/)/sub 3/SiOSO/sub 2/). Both (C/sub 3/)/sub 3/SiNSO and (NH/sub 4/)((CH/sub 3/)/sub 3/SiOSO/sub 2/) have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO/sub 2/ pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH/sub 3/)/sub 3/Si)/sub 2/NH, whereby any SO/sub 2/ present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO/sub 2/ in the original gas sample. The solid product (NH/sub 4/)((CH/sub 3/)/sub 3/SiOSO/sub 2/) may be used as a standard in solid state NMR spectroscopy.

Spicer, L.D.; Bennett, D.W.; Davis, J.F.

1981-06-12T23:59:59.000Z

410

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

coal power plants, and promoting the installation of the most efficient power generation technologies such as ultra-supercritical

Zhou, Nan

2013-01-01T23:59:59.000Z

411

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

consuming more energy than rural households, especiallyeffort and energy. In addition, the rural population stillenergy demand growth. In addition, incomes are rising for both urban and rural

Zhou, Nan

2013-01-01T23:59:59.000Z

412

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

controls or integrated measures could simultaneously reduce greenhouse gas (GHG) emissions and criteria air pollutantcontrols or integrated measures that simultaneously reduce greenhouse gas (GHG) emissions and criteria air pollutantcontrols or integrated measures that are defined as simultaneously reducing greenhouse gas (GHG) emissions and criteria air pollutant

Zhou, Nan

2013-01-01T23:59:59.000Z

413

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

water outflow of the steam turbine condenser. Due to theHigh-temperature CHP Steam expansion turbine Combined CycleNatural gas expansion turbine Steam Distribution System

Zhou, Nan

2013-01-01T23:59:59.000Z

414

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

90%. SO 2 emission intensity of coal-fired power plants byCoal Efficiency + Decarbonization Power Sector CO 2 Emissions (SO 2 emissions from the existing coal-fired power plants is

Zhou, Nan

2013-01-01T23:59:59.000Z

415

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

Generation Power Sector CO2 Emissions (Mt CO2) ExpandedSO2 Control Power Sector CO2 Emissions (Mt CO 2 ) Reference9 Figure ES-10 Total CO2 Emissions for Steel Production in

Zhou, Nan

2013-01-01T23:59:59.000Z

416

HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS  

SciTech Connect (OSTI)

This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

2009-05-12T23:59:59.000Z

417

EMSL - oxides  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oxides en Influence of Adsorption Site and Wavelength on the Photodesorption of NO from the (Fe,Cr)3O4(111) Mixed Oxide Surface. http:www.emsl.pnl.govemslwebpublications...

418

Solid oxide electrochemical reactor science.  

SciTech Connect (OSTI)

Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

2010-09-01T23:59:59.000Z

419

A simple synthesis method of sulfur-free Fe-N-C catalyst witih high ORR activity  

SciTech Connect (OSTI)

To try to deconvolute which factors affect the activity and durability of metal-nitrogen-carbon (M-N-C) type non-precious catalysts for oxygen reduction reaction (ORR), M-N-C catalysts based on ion chloride, polyaniline (PANI) and Ketjen Black carbon support were synthesized using different synthetic conditions. The catalysts were characterized electrochemically and tested as cathodes for Hydrogen fuel cells. PANI is usually chemically oxidative polymerized using ammonium persulfate (APS) as oxidant. To eliminate sulfur in the synthesized catalysts, a simple synthesis method using ion chloride as oxidant for aniline polymerization was developed. Two different aniline polymerization conditions led to very different product morphologies. Synthesized at low initial proton concentration, the final product was composed of dense micrometer sized particles. A decomposable salt was found to be able to prohibit PANI cross linking during the drying and annealing process and thus led to porous product. The porous catalyst has much higher ORR activity than the dense product due to more accessible active sites. Synthesized at high proton concentration, the catalyst appeared to be porous. The decomposable salt treatment did not make too much improvement in the porous structure and electrochemical activity. However, fuel cell testing using air as cathode feeder indicates that the salt treatment improves mass transfer in the cathode layer. Catalyst synthesized using this simple method has performance comparable to our state-of-the art catalyst synthesized in a much more complicated procedure. The factor that sulfur sources are completely eliminated in the synthesis suggests that sulfur is not necessary for the ORR catalysis activity.

Ding, Zhongfen [Los Alamos National Laboratory; Johnston, Christina M [Los Alamos National Laboratory; Zelenay, Piotr [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

420

Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans--1,2 End-On Disulfide Complex: New Directions in Copper-Sulfur Chemistry  

E-Print Network [OSTI]

Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans-µ-1,2 End-On Disulfide Complex: New Directions in Copper-Sulfur Chemistry Matthew E. Helton, Peng Chen, Partha P. Paul, Zolta, investigations into copper-sulfur interactions have been of marked interest in the research fields of copper

Chen, Peng

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Hydrogen sulfide decomposition into hydrogen and sulfur by quinone cycles. First annual report, June 1989-May 1990  

SciTech Connect (OSTI)

The research is evaluating the fundamental mechanisms for recovery of sulfur and H{sub 2} from H{sub 2}S, using mild condition cycles based on oxidation of H{sub 2}S by quinones. During this first year, the research focused on the reaction of H{sub 2}S with tertiary butyl anthraquinone to form tertiary butyl anthrahydroquinone. The progress achieved included extending the quinone conversion from 60-80% to complete conversion, significantly increasing the rate of conversion by varying the solvent, and developing a proposed mechanism for this part of the process.

Plummer, M.A.

1990-06-01T23:59:59.000Z

422

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular...

Harkness, J.; Doctor, R. D.

423

Hybrid Sulfur Thermochemical Process Development Annual Report  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) Thermochemical Process is a means of producing hydrogen via water-splitting through a combination of chemical reactions and electrochemistry. Energy is supplied to the system as high temperature heat (approximately 900 C) and electricity. Advanced nuclear reactors (Generation IV) or central solar receivers can be the source of the primary energy. Large-scale hydrogen production based on this process could be a major contributor to meeting the needs of a hydrogen economy. This project's objectives include optimization of the HyS process design, analysis of technical issues and concerns, creation of a development plan, and laboratory-scale proof-of-concept testing. The key component of the HyS Process is the SO2-depolarized electrolyzer (SDE). Studies were performed that showed that an electrolyzer operating in the range of 500-600 mV per cell can lead to an overall HyS cycle efficiency in excess of 50%, which is superior to all other currently proposed thermochemical cycles. Economic analysis indicated hydrogen production costs of approximately $1.60 per kilogram for a mature nuclear hydrogen production plant. However, in order to meet commercialization goals, the electrolyzer should be capable of operating at high current density, have a long operating lifetime , and have an acceptable capital cost. The use of proton-exchange-membrane (PEM) technology, which leverages work for the development of PEM fuel cells, was selected as the most promising route to meeting these goals. The major accomplishments of this project were the design and construction of a suitable electrolyzer test facility and the proof-of-concept testing of a PEM-based SDE.

Summers, William A.; Buckner, Melvin R.

2005-07-21T23:59:59.000Z

424

Extracting metals directly from metal oxides  

DOE Patents [OSTI]

A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

Wai, C.M.; Smart, N.G.; Phelps, C.

1997-02-25T23:59:59.000Z

425

Extracting metals directly from metal oxides  

DOE Patents [OSTI]

A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

1997-01-01T23:59:59.000Z

426

Removing sulphur oxides from a fluid stream  

DOE Patents [OSTI]

A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

2014-04-08T23:59:59.000Z

427

Iridium material for hydrothermal oxidation environments  

DOE Patents [OSTI]

A process for hydrothermal oxidation of combustible materials in which, during at least a part of the oxidation, corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises iridium, iridium oxide, an iridium alloy, or a base metal overlaid with an iridium coating. Iridium has been found to be highly resistant to environments encountered in the process of hydrothermal oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 800.degree. C.

Hong, Glenn T. (Tewksbury, MA); Zilberstein, Vladimir A. (Brookline, MA)

1996-01-01T23:59:59.000Z

428

Influence of fuel sulfur on the selective reduction of NO by NH/sub 3/  

SciTech Connect (OSTI)

More intensive regulations of the emissions of nitrogen oxides from stationary combustion sources have prompted the innovation and characterization of new control technologies suitable for applications in utilities. One of the more recent and attractive abatement technologies is the Thermal DeNO/sub x/ process which has been described by Lyon and Longwell. This process removes NO by selectively reducing it with NH/sub 3/ added to the post-combustion gases containing excess oxygen. This process is thus independent of the NO formation mechanism and makes no distinction between thermal and fuel NO. The present study is concerned with characterizing the selective reduction process for light distillate oil fuel admixed with variable amounts of pyridene and thiophene in a laboratory scale combustion tunnel under a variety of experimental conditions. This paper reports on those aspects of the study concerned with the investigation of possible synergistic effects between the sulfur and selective reduction chemistry.

Lucas, D.; Brown, N.J.

1981-01-01T23:59:59.000Z

429

Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report  

SciTech Connect (OSTI)

This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

1989-04-28T23:59:59.000Z

430

Anisotropic reactive ion etching of vanadium dioxide  

E-Print Network [OSTI]

. Weichold Vanadium dioxide (V02) was anisotropically reactive ion etched using carbon tetrafluoride (CF4) . CF4, as an etch gas, provided the chemistry along with the control needed to achieve an anisotropic etch. This chemistry was practically inert... with vanadium quite easily. This leads to interest in using a fluorine- based chemistry. The goal of this research is to produce a selective anisotropic reactive ion etch for VO2 /photoresist using only carbon tetrafluoride (CFq) . Reactive ion etching...

Radle, Byron K

1990-01-01T23:59:59.000Z

431

HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE  

SciTech Connect (OSTI)

HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE Lucia M. Petkovic, Harry W. Rollins, Daniel M. Ginosar, and Kyle C. Burch Idaho National Laboratory P.O. Box 1625 Idaho Falls, ID 83415-2208 Introduction Anthropogenic emissions of carbon dioxide, a gas often associated with global warming, have increased considerably since the beginning of the industrial age.1 In the U.S., stationary CO2 sources, such as electricity generation plants, produce about one-third of the anthropogenic CO2 generation. Reports2 indicate that the power required to recover 90% of the CO2 from an integrated coal-fired power-plant is about 10% of the power-plant capacity. This energy requirement can be reduced to less than 1% if the recovered CO2 is applied to the production of synthetic fuels. However, the lack of efficient catalysts along with the costs of energy and hydrogen has prevented the development of technologies for direct hydrogenation of CO2.3 Although the cost of hydrogen for hydrogenating CO2 is not economically attractive at present, the future production of hydrogen by nuclear power sources could completely change this scenario.2 Still, an efficient catalyst will be essential for commercial application of those processes. The objective of the work presented here was the development of hybrid catalysts for one-step carbon dioxide hydrogenation to liquid fuels. The hybrid catalysts, which were prepared by two novel techniques, included a copper/zinc oxide catalytic function distributed within an acidic zeolitic matrix. Results of catalyst activity and selectivity studies at atmospheric pressure are presented in this contribution. Experimental Catalysts were prepared by two novel techniques and under several different conditions to produce copper/zinc oxide/zeolite materials. Once synthesized, samples were pelletized and the fraction between 40-60 mesh was utilized for the experiments. Two hundred milligrams of catalyst were loaded in a U-tube stainless steel reactor and a flow of 100 cm3/min of a 10:90 H2:Ar mixture was passed through the catalyst bed while the temperature was increased from room temperature to 513 K at 1.8 K/min and held at 513 K for 15 h. A reactant gas mixture composed by 10 cm3/min of CO2 and 30 cm3/min of H2 was then passed through the catalyst bed and the reaction products monitored by on-line gas chromatographic analyses using an SRI Multiple Gas Analyzer #2 equipped with 3 columns (MoleSieve 13X, Hayesep-D, and MXT-1) and 3 detectors (TCD, FID, and FID-methanizer). This GC system allowed for quantification of inert gases, CO, CO2, methanol, dimethylether, higher alcohols, water, and hydrocarbons up to C20. One hundred milligrams of a commercial syngas-to-methanol catalyst along with the same amount of a commercial zeolite catalyst was utilized under the same reaction conditions for comparison purposes. These catalysts were utilized either in two-layers (Com1) or mixed together (Com2). Results and Discussion Under the conditions applied in this study, the main reaction products were CO, CH3OH, CH3OCH3, and H2O. Methanol and dimethylether production rates and selectivities with respect to CO formation are presented in Figures 1 and 2, respectively. Although the activity of the synthesized catalysts did not surpass the commercial catalysts, the selectivity to oxygenates with respect to CO on most of the synthesized catalysts were better than on the commercial catalysts. For example, cat

Licia M. Petkovic; Harry W. Rollins; Daniel M. Ginosar; Kyle C. Burch

2006-09-01T23:59:59.000Z

432

Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents  

SciTech Connect (OSTI)

Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

2007-06-30T23:59:59.000Z

433

Process and system for removing sulfur from sulfur-containing gaseous streams  

DOE Patents [OSTI]

A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

2012-08-14T23:59:59.000Z

434

Standard test methods for chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets  

E-Print Network [OSTI]

1.1 These test methods cover procedures for the chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets to determine compliance with specifications. 1.2 The analytical procedures appear in the following order: Sections Plutonium Sample Handling 8 to 10 Plutonium by Controlled-Potential Coulometry Plutonium by Ceric Sulfate Titration Plutonium by Amperometric Titration with Iron(II) Plutonium by Diode Array Spectrophotometry Nitrogen by Distillation Spectrophotometry Using Nessler Reagent 11 to 18 Carbon (Total) by Direct Combustion–Thermal Conductivity 19 to 30 Total Chlorine and Fluorine by Pyrohydrolysis 31 to 38 Sulfur by Distillation Spectrophotometry 39 to 47 Plutonium Isotopic Analysis by Mass Spectrometry Rare Earth Elements by Spectroscopy 48 to 55 Trace Elements by Carrier–Distillation Spectroscopy 56 to 63 Impurities by ICP-AES Impurity Elements by Spark-Source Mass Spectrography 64 to 70 Moisture by the Coulomet...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

435

Indication of Meissner Effect in Sulfur-Substituted Strontium Ruthenates  

E-Print Network [OSTI]

Ceramic samples of Sr2RuO(4-y)Sy (y=0.03-1.2) with intended isovalent substitution of oxygen by sulfur have been synthesized and explored in the temperature range 4-300K. It is found that at a range of optimum sulfur substitution the magnetic response of ceramic samples reveals large diamagnetic signal with amplitudes approaching comparability with that of the YBCO-superconductors. Contrary to a pure ceramic Sr2RuO4, if properly optimized, the resistivity of sulfur-substituted samples has a metallic behavior except at lower temperatures where an upturn occurs. Both synthesis conditions and results of measurements are reported. The Meissner effect may point to high-temperature superconductivity.

Gulian, Armen

2011-01-01T23:59:59.000Z

436

Selective Extraction of Uranium from Liquid or Supercritical Carbon Dioxide  

SciTech Connect (OSTI)

Current liquid-liquid extraction processes used in recycling irradiated nuclear fuel rely on (1) strong nitric acid to dissolve uranium oxide fuel, and (2) the use of aliphatic hydrocarbons as a diluent in formulating the solvent used to extract uranium. The nitric acid dissolution process is not selective. It dissolves virtually the entire fuel meat which complicates the uranium extraction process. In addition, a solvent washing process is used to remove TBP degradation products, which adds complexity to the recycling plant and increases the overall plant footprint and cost. A liquid or supercritical carbon dioxide (l/sc -CO2) system was designed to mitigate these problems. Indeed, TBP nitric acid complexes are highly soluble in l/sc -CO2 and are capable of extracting uranium directly from UO2, UO3 and U3O8 powders. This eliminates the need for total acid dissolution of the irradiated fuel. Furthermore, since CO2 is easily recycled by evaporation at room temperature and pressure, it eliminates the complex solvent washing process. In this report, we demonstrate: (1) A reprocessing scheme starting with the selective extraction of uranium from solid uranium oxides into a TBP-HNO3 loaded Sc-CO2 phase, (2) Back extraction of uranium into an aqueous phase, and (3) Conversion of recovered purified uranium into uranium oxide. The purified uranium product from step 3 can be disposed of as low level waste, or mixed with enriched uranium for use in a reactor for another fuel cycle. After an introduction on the concept and properties of supercritical fluids, we first report the characterization of the different oxides used for this project. Our extraction system and our online monitoring capability using UV-Vis absorbance spectroscopy directly in sc-CO2 is then presented. Next, the uranium extraction efficiencies and kinetics is demonstrated for different oxides and under different physical and chemical conditions: l/sc -CO2 pressure and temperature, TBP/HNO3 complex used, reductant or complexant used for selectivity, and ionic liquids used as supportive media. To complete the extraction and recovery cycle, we then demonstrate uranium back extraction from the TBP loaded sc-CO2 phase into an aqueous phase and the characterization of the uranium complex formed at the end of this process. Another aspect of this project was to limit proliferation risks by either co-extracting uranium and plutonium, or by leaving plutonium behind by selectively extracting uranium. We report that the former is easily achieved, since plutonium is in the tetravalent or hexavalent oxidation state in the oxidizing environment created by the TBP-nitric acid complex, and is therefore co-extracted. The latter is more challenging, as a reductant or complexant to plutonium has to be used to selectively extract uranium. After undertaking experiments on different reducing or complexing systems (e.g., AcetoHydroxamic Acid (AHA), Fe(II), ascorbic acid), oxalic acid was chosen as it can complex tetravalent actinides (Pu, Np, Th) in the aqueous phase while allowing the extraction of hexavalent uranium in the sc-CO2 phase. Finally, we show results using an alternative media to commonly used aqueous phases: ionic liquids. We show the dissolution of uranium in ionic liquids and its extraction using sc-CO2 with and without the presence of AHA. The possible separation of trivalent actinides from uranium is also demonstrated in ionic liquids using neodymium as a surrogate and diglycolamides as the extractant.

Farawila, Anne F.; O'Hara, Matthew J.; Wai, Chien M.; Taylor, Harry Z.; Liao, Yu-Jung

2012-07-31T23:59:59.000Z

437

Failure of ozone and nitrogen dioxide to enhance lung tumor development in hamsters  

SciTech Connect (OSTI)

We tested the hypothesis that the two common oxidant air pollutants, ozone and nitrogen dioxide, modulate the development of respiratory tract tumors in Syrian golden hamsters. The animals received subcutaneous injections of the carcinogen diethylnitrosamine (20 mg/kg) twice a week while being exposed continuously to an atmosphere of 0.8 parts per million (ppm)* of ozone or 15 ppm of nitrogen dioxide. Animals were killed 16 weeks or 24 to 32 weeks after the beginning of the treatment. Ozone delayed the appearance of tracheal tumors and reduced the incidence of tumors in the lung periphery. A suspected neuroendocrine differentiation of those lung tumors could not be established by immunocytochemistry due to overfixation of tissues. On the other hand, ozone seemed to mitigate development of hepatotoxic lesions mediated by diethylnitrosamine. In animals treated with diethylnitrosamine and exposed to nitrogen dioxide, fewer tracheal tumors and no lung tumors were found. Only a few lung tumors were produced in animals treated with diethylnitrosamine and kept in an atmosphere of 65% oxygen. The previously observed neuroendocrine nature of tumors induced by simultaneous exposure to diethylnitrosamine and hyperoxia could not be established because the long fixation of tissues precluded immunocytochemical stains. Animals treated with diethylnitrosamine and kept in filtered air while being housed in wire-mesh cages developed fewer lung tumors than animals given the same treatment and kept on conventional bedding in shoebox cages. Although all inhalants tested are known to produce substantial cell proliferation in the respiratory tract, it was not possible to document whether this would enhance lung tumor development. The role of the two common air pollutants, ozone and nitrogen dioxide, as possible additional risks in the pathogenesis of lung cancer in animals continues to remain uncertain.

Witschi, H.; Breider, M.A.; Schuller, H.M. (Univ. of California, Davis, CA (United States))

1993-09-01T23:59:59.000Z

438

Sulfur gas geochemical detection of hydrothermal systems. Final report  

SciTech Connect (OSTI)

The purpose of this investigation was to determine whether a system of exploration using sulfur gases was capable of detecting convecting hydrothermal systems. Three surveying techniques were used at the Roosevelt Hot Springs KGRA in Utah. These were (a) a sniffing technique, capable of instantaneous determinations of sulfur gas concentration, (b) an accumulator technique, capable of integrating the sulfur gas emanations over a 30 day interval, and (c) a method of analyzing the soils for vaporous sulfur compounds. Because of limitations in the sniffer technique, only a limited amount of surveying was done with this method. The accumulator and soil sampling techniques were conducted on a 1000 foot grid at Roosevelt Hot Springs, and each sample site was visited three times during the spring of 1980. Thus, three soil samples and two accumulator samples were collected at each site. The results are shown as averages of three soil and two accumulator determinations of sulfur gas concentrations at each site. Soil surveys and accumulator surveys were conducted at two additional KGRA's which were chosen based on the state of knowledge of these hydrothermal systems and upon their differences from Roosevelt Hot Springs in an effort to show that the exploration methods would be effective in detecting geothermal reservoirs in general. The results at Roosevelt Hot Springs, Utah show that each of the three surveying methods was capable of detecting sulfur gas anomalies which can be interpreted to be related to the source at depth, based on resistivity mapping of that source, and also correlatable with major structural features of the area which are thought to be controlling the geometry of the geothermal reservoir. The results of the surveys at Roosevelt did not indicate that either the soil sampling technique or the accumulator technique was superior to the other.

Rouse, G.E.

1984-01-01T23:59:59.000Z

439

Hydrogen and sulfur recovery from hydrogen sulfide wastes  

DOE Patents [OSTI]

A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

1993-05-18T23:59:59.000Z

440

Hydrogen and sulfur recovery from hydrogen sulfide wastes  

DOE Patents [OSTI]

A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides sulfur dioxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Gel and process for preventing carbon dioxide break through  

SciTech Connect (OSTI)

A process is described for retarding the flow of carbon dioxide in carbon dioxide break-through fingers in a subterranean formation, the process comprising: (a) introducing a gas selected from the group consisting of carbon dioxide and gases containing carbon dioxide into a subterranean deposit containing carbon dioxide break-through fingers; (b) after the carbon dioxide break-through fingers have sorbed a predetermined amount of the gas, stopping the flow of the gas into the subterranean formation, (c) after stopping the flow of the gas into the subterranean formation, introducing an effective amount of a gel-forming composition into the subterranean formation and into the carbon dioxide break-through fingers, the gel-forming composition being operable, when contacting carbon dioxide break-through fingers containing the brine which has absorbed substantial amounts of carbon dioxide to form a gel in the fingers which is operable for retarding the flow of the gas in the finger. The gel-forming composition comprises: i. an aqueous solution comprising a first substance selected from the group consisting of polyvinyl alcohols, polyvinyl alcohol copolymers, and mixtures thereof, and ii. an amount of a second substance selected from the group consisting of aldehydes, aldehyde generating substances, acetals, acetal generating substances, and mixtures thereof.

Sandiford, B.B.; Zillmer, R.C.

1987-06-16T23:59:59.000Z

442

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network [OSTI]

dioxide impact of electricity consumption in different majorand residential electricity consumption. Car usage and homefor fuel oil and electricity consumption. We then use

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

443

Carbon dioxide absorbent and method of using the same  

SciTech Connect (OSTI)

In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.

Perry, Robert James; O'Brien, Michael Joseph

2014-06-10T23:59:59.000Z

444

Carbon Dioxide Capture and Storage Demonstration in Developing...  

Open Energy Info (EERE)

Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Capture and Storage Demonstration in Developing Countries: Analysis of Key Policy Issues and Barriers...

445

assisted silicon dioxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dioxide substrates is described. The approach consists of solid such as displays and thin-film polycrystalline solar cells. Particularly important for low- cost thin-film solar...

446

Feasibility of actinide separation from UREX-like raffinates using a combination of sulfur- and oxygen-donor extractants  

SciTech Connect (OSTI)

A synergistic combination of bis(o-trifluoromethylphenyl)dithios-phosphinic acid and trioctylphosphine oxide has been recently shown to selectively remove uranium, neptunium, plutonium and americium from aqueous environment containing up to 0.5 M nitric acid and 5.5 g/l fission products. Here the feasibility of performing this complete actinide recovery from aqueous mixtures is forecasted for a new organic formulation containing sulfur donor extractant of modified structure based on Am(III) and Eu(III) extraction data. A mixture of bis(bis-m,m-trifluoromethyl)phenyl)-dithios-phosphinic acid and TOPO in toluene enhances the extraction performance, accomplishing Am/Eu differentiation in aqueous mixtures up to 1 M nitric acid. The new organic recipe is also less susceptible to oxidative damage resulting from radiolysis. (authors)

Zalupski, P.R.; Peterman, D.R.; Riddle, C.L. [Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415 (United States)

2013-07-01T23:59:59.000Z

447

Feasibility of actinide separation from UREX-like raffinates using a combination of sulfur- and oxygen-donor extractants  

SciTech Connect (OSTI)

A synergistic combination of bis(o-trifluoromethylphenyl)dithiosphosphinic acid and trioctylphosphine oxide has been recently shown to selectively remove uranium, neptunium, plutonium and americium from aqueous environment containing up to 0.5 M nitric acid and 5.5 g/L fission products. Here the feasibility of performing this complete actinide recovery from aqueous mixtures is forecasted for a new organic formulation containing sulfur donor extractant of modified structure based on Am(III) and Eu(III) extraction data. A mixture of bis(bis-m,m-trifluoromethyl)phenyl)-dithiosphosphinic acid and TOPO in toluene enhances the extraction performance, accomplishing Am/Eu differentiation in aqueous mixtures up to 1 M nitric acid. The new organic recipe is also less susceptible to oxidative damage resulting from radiolysis.

Peter R. Zalupski; Dean R. Peterman; Catherine L. Riddle

2013-09-01T23:59:59.000Z

448

Method for selective catalytic reduction of nitrogen oxides  

DOE Patents [OSTI]

A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

2005-02-15T23:59:59.000Z

449

Method For Selective Catalytic Reduction Of Nitrogen Oxides  

DOE Patents [OSTI]

A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

2005-02-15T23:59:59.000Z

450

Studies on the sulfur poisoning of Ru-RuO{sub x}/TiO{sub 2} catalyst for the adsorption and methanation of carbon monoxide  

SciTech Connect (OSTI)

The effects of sulfur poisoning on the chemisorption and on the methanation of carbon monoxide over Ru/TiO{sub 2} catalyst were investigated by FTIR spectroscopy and volumetric gas adsorption measurements. The CS{sub 2} molecules are {eta}` bonded to Ru sites through one of the sulfur atoms and decompose to the constituent elements on thermal activation. Each S atom may deactivate 3 to 10 metal sites even at low coverages, the effect being more pronounced on the chemisorption of hydrogen. The deposited sulfur (and possibly carbon also) sterically hinders the formation of certain multicarbonyl and monocarbonyl species (vCO in 2055-2140 cm{sup -1} region), which otherwise transform to methane via surface methylene groups in the presence of chemisorbed hydrogen and are found to play an important role in the low-temperature methanation activity of the studied catalyst. The Ru-CO species giving rise to lower frequency vibrational bands are affected to a lesser extent. The presence of sulfur also results in the development of some new CO binding states which are weak and are identified with the CO and S coadsorbed at Ru sites of different oxidation states or of varying crystallographic nature. The CO adsorbed in these states is not reactive to hydrogen. 45 refs., 9 figs., 1 tab.

Kamble, V.S.; Londhe, V.P.; Gupta, N.M. [Bhambha Atomic Research centre, Bombay (India)] [and others] [Bhambha Atomic Research centre, Bombay (India); and others

1996-02-01T23:59:59.000Z

451

The Quantitation of Sulfur Mustard By-Products, Sulfur-Containing Herbicides, and Organophosphonates in Soil and Concrete  

SciTech Connect (OSTI)

Over the past fifty years, the facilities at Rocky Mountain Arsenal have been used for the manufacturing, bottling, and shipping sulfur- containing herbicides, sulfur mustard, and Sarin. There is a need for analytical methods capable of determining these constituents quickly to determine exactly how specific waste structural materials should be handled, treated, and landfilled.These species are extracted rapidly from heated samples of soil or crushed concrete using acetonitrile at elevated pressure, then analyzed using a gas chromatograph equipped with a flame photometric detector. Thiodiglycol, the major hydrolysis product of sulfur mustard, must be converted to a silylated derivative prior to quantitation. Detection limits, calculated using two statistically-unbiased protocols, ranged between 2-13 micrograms analyte/g soil or concrete.

Tomkins, B.A., Sega, G.A. [Oak Ridge National Lab., TN (United States)], Macnaughton, S.J. [Microbial Insights, Inc., Rockford, TN (United States)

1997-12-31T23:59:59.000Z

452

Investigation of the Atmospheric Ozone Impacts of Methyl Iodide  

E-Print Network [OSTI]

J. R. Holmes (1977): “Nitrogen Dioxide Photolysis in the LosO3 Ozone NO Nitric Oxide NO2 Nitrogen Dioxide NO3 NitrateNitrogen Pentoxide HONO Nitrous Acid HNO3 Nitric Acid HNO4 Peroxynitric Acid HO2H Hydrogen Peroxide CO Carbon Monoxide SO2 Sulfur Dioxide

Carter, W P L

2007-01-01T23:59:59.000Z

453

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

2012-03-06T23:59:59.000Z

454

A design strategy applied to sulfur resistant lean NOxĚł automotive catalysts  

E-Print Network [OSTI]

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

455

Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mitigation of Sulfur Poisoning of NiZirconia SOFC Anodes by Antimony and Tin . Mitigation of Sulfur Poisoning of NiZirconia SOFC Anodes by Antimony and Tin . Abstract: Surface...

456

Correction to "Sulfuric acid deposition from stratospheric geoengineering with sulfate aerosols"  

E-Print Network [OSTI]

Correction to "Sulfuric acid deposition from stratospheric geoengineering with sulfate aerosols (2010), Correction to "Sulfuric acid deposition from stratospheric geoengineering with sulfate aerosols from stratospheric geoengineering with sulfate aerosols" (Journal of Geophysical Research, 114, D14109

Robock, Alan

457

The effect of phosphorus on the formation of tungsten dioxide: A novel morphology  

SciTech Connect (OSTI)

The industrial production of tungsten is based on the hydrogen reduction of tungsten oxides, ammonium paratungstate (APT) or ammonium tungsten oxide bronze (ATOB). Hydrogen reduction is applied when high purity tungsten is required and when the addition of other elements or compounds (dopants) is desired for modification of the properties of the metal powder. The first stage of