Sample records for oxides nox ozone

  1. A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States

    E-Print Network [OSTI]

    Sun, Lin, S.M. Massachusetts Institute of Technology

    2009-01-01T23:59:59.000Z

    Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

  2. 8, 49114947, 2008 NOx-induced ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract Chemistry and Physics Discussions Model simulations of stratospheric ozone loss caused by enhanced on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

  3. A Cost-Effectiveness Analysis of Alternative Ozone Control Strategies: Flexible Nitrogen Oxide (NOx) Abatement

    E-Print Network [OSTI]

    and Policy at the Massachusetts Institute of Technology June 2009 ©2009 Massachusetts Institute of Technology differentiated regulation for NOx emissions. Such a flexible NOx regulation policy, so-called "smart trading

  4. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents...

  5. Effect of Thermal Aging on NO oxidation and NOx storage in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap Effect of Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap...

  6. High ozone concentrations on hot days: The role of electric power demand and NOx1 , Linda Hembeck1

    E-Print Network [OSTI]

    Dickerson, Russell R.

    of tropospheric17 ozone, leading to concerns that global warming may exacerbate smog episodes. This18 widely1 High ozone concentrations on hot days: The role of electric power demand and NOx1 emissions2 3 Park,10 MD 20742, U.S.11 12 Key words: power plant emissions, ozone production efficiency, climate

  7. Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions

    E-Print Network [OSTI]

    Craig, Michael T. (Michael Timothy)

    2014-01-01T23:59:59.000Z

    Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

  8. Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems

    DOE Patents [OSTI]

    Park, Paul W.

    2004-03-16T23:59:59.000Z

    A lean NOx catalyst and method of preparing the same is disclosed. The lean NOx catalyst includes a ceramic substrate, an oxide support material, preferably .gamma.-alumina, deposited on the substrate and a metal promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium, cerium, vanadium, oxides thereof, and combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between about 80 to 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

  9. Method of preparing doped oxide catalysts for lean NOx exhaust

    DOE Patents [OSTI]

    Park, Paul W.

    2004-03-09T23:59:59.000Z

    The lean NOx catalyst includes a substrate, an oxide support material, preferably .gamma.-alumina deposited on the substrate and a metal or metal oxide promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium cerium, and vanadium, and oxides thereof, and any combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between 80 and 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to about 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

  10. Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms

    E-Print Network [OSTI]

    Martin, Katherine C.

    2007-01-01T23:59:59.000Z

    Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

  11. Implementing a time- and location-differentiated cap-and-trade program : flexible nitrogen oxide abatement from power plants in the eastern United States

    E-Print Network [OSTI]

    Martin, Katherine C

    2007-01-01T23:59:59.000Z

    Studies suggest that timing and location of emissions can change the amount of ozone formed from a given amount of nitrogen oxide (NOx) by a factor of five (Mauzerall et al. 2005). Yet existing NOx cap-and-trade programs ...

  12. Satellite constraints of nitrogen oxide (NOx) emissions from India based on OMI observations and WRFChem simulations

    E-Print Network [OSTI]

    Haak, Hein

    , and economic growth in India and attracted the attention of researchers and policy makers [Garg et al., 2001Satellite constraints of nitrogen oxide (NOx) emissions from India based on OMI observations emission inventory for India for 2005 using an inverse technique and iterative procedure. We used OMI

  13. Analytica Chimica Acta 573574 (2006) 913 Metal oxide thin films as sensing layers for ozone detection

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Analytica Chimica Acta 573­574 (2006) 9­13 Metal oxide thin films as sensing layers for ozone. Their structural, electrical and ozone sensing properties were analyzed. Structural investigations carried out with ultraviolet light and subsequent oxidation in ozone atmosphere at room temperature. © 2006 Elsevier B.V. All

  14. Atmospheric Environment 39 (2005) 28292838 Diurnal and seasonal cycles of ozone precursors observed from

    E-Print Network [OSTI]

    Wingenter, Oliver W.

    characteristics. Ethane and propane, largely originated from leakage of natural gas or liquefied petroleum gases) and nitrogen oxides (NO+NO2 ÂĽ NOx), ozone is photochemically pro- duced and can accumulate to hazardous levels

  15. Observations of the Temperature Dependent Response of Ozone to NOx Reductions in an Urban Plume

    SciTech Connect (OSTI)

    LaFranchi, B W; Goldstein, A H; Cohen, R C

    2011-01-25T23:59:59.000Z

    Observations of NO{sub x} in the Sacramento, CA region show that mixing ratios decreased by 30% between 2001 and 2008. Here we use an observation-based method to quantify net ozone production rates in the outflow from the Sacramento metropolitan region and examine the O{sub 3} decrease resulting from reductions in NO{sub x} emissions. This observational method does not rely on assumptions about detailed chemistry of ozone production, rather it is an independent means to verify and test these assumptions. We use an instantaneous steady-state model as well as a detailed 1-D plume model to aid in interpretation of the ozone production inferred from observations. In agreement with the models, the observations show that early in the plume, the NO{sub x} dependence for O{sub x} (O{sub x} = O{sub 3}+NO{sub 2}) production is strongly coupled with temperature, suggesting that temperature dependent biogenic VOC emissions can drive O{sub x} production between NO{sub x}-limited and NO{sub x}-suppressed regimes. As a result, NO{sub x} reductions were found to be most effective at higher temperatures over the 7 year period. We show that violations of the California 1-hour O{sub 3} standard (90 ppb) in the region have been decreasing linearly with decreases in NO{sub x} (at a given temperature) and predict that reductions of NO{sub x} concentrations (and presumably emissions) by an additional 30% (relative to 2007 levels) will eliminate violations of the state 1 hour standard in the region. If current trends continue, a 30% decrease in NO{sub x} is expected by 2012, and an end to violations of the 1 hour standard in the Sacramento region appears to be imminent.

  16. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3....

  17. SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD

    E-Print Network [OSTI]

    Holmén, Britt A.

    SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD+08 2.6e+08 2.8e+08 3e+08 Time--> Abundance TIC: 0914S4.D INTRODUCTION Diesel exhaust is one into the atmosphere diesel particles can be transformed through physical and chemical processes resulting

  18. Formation of ozone and oxidation of methane in a direct current corona discharge

    E-Print Network [OSTI]

    Tangirala, Umashanker

    1976-01-01T23:59:59.000Z

    FORMATION OF OZONE AND OXIDATION OF METHANE IN A DIRECT CURRENT CORONA DISCHARGE A Thesis by UMASHANKER TANGIRALA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE May 1976 Major Subject: Chemical Engineering FORMATION OF OZONE AND OXIDATION OF METHANE IN A DIRECT CURRENT CORONA DISCHARGE A Thesis by UMASHANKER TANGIRALA Approved as to style and content by: (Chairman of Committee) ( ad of Department...

  19. Reduction of NOx by plasma-assisted methods , F. Leipold1

    E-Print Network [OSTI]

    acid rain and ozone production when it is released into the air. Reduction of NOx in the exhaust gas

  20. Kudzu (Pueraria montana) invasion doubles emissions of nitric oxide and increases ozone pollution

    E-Print Network [OSTI]

    Mickley, Loretta J.

    Kudzu (Pueraria montana) invasion doubles emissions of nitric oxide and increases ozone pollution) The nitrogen-fixing legume kudzu (Pueraria montana) is a wide- spread invasive plant in the southeastern United the effects of kudzu invasions on soils and trace N gas emissions at three sites in Madison County, Georgia

  1. JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System

    SciTech Connect (OSTI)

    Scott Tolbert; Steven Benson

    2008-02-29T23:59:59.000Z

    Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

  2. Optimization of stabilized leachate treatment using ozone/persulfate in the advanced oxidation process

    SciTech Connect (OSTI)

    Abu Amr, Salem S. [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Aziz, Hamidi Abdul, E-mail: cehamidi@eng.usm.my [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Adlan, Mohd Nordin [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)

    2013-06-15T23:59:59.000Z

    Highlights: ? Ozone and persulfate reagent (O{sub 3}/S{sub 2}O{sub 8}{sup 2-}) was used to treat stabilized leachate. ? Central composite design (CCD) with response surface methodology (RSM) was applied. ? Operating variables including ozone and persulfate dosage, pH variance, and reaction time. ? Optimum removal of COD, color, and NH{sub 3}–N was 72%, 96%, and 76%, respectively. ? A good value of ozone consumption (OC) obtained with 0.60 (kg O{sub 3}/kg COD). - Abstract: The objective of this study was to investigate the performance of employing persulfate reagent in the advanced oxidation of ozone to treat stabilized landfill leachate in an ozone reactor. A central composite design (CCD) with response surface methodology (RSM) was applied to evaluate the relationships between operating variables, such as ozone and persulfate dosages, pH, and reaction time, to identify the optimum operating conditions. Quadratic models for the following four responses proved to be significant with very low probabilities (<0.0001): COD, color, NH{sub 3}–N, and ozone consumption (OC). The obtained optimum conditions included a reaction time of 210 min, 30 g/m{sup 3} ozone, 1 g/1 g COD{sub 0}/S{sub 2}O{sub 8}{sup 2-} ratio, and pH 10. The experimental results were corresponded well with predicted models (COD, color, and NH{sub 3}–N removal rates of 72%, 96%, and 76%, respectively, and 0.60 (kg O{sub 3}/kg COD OC). The results obtained in the stabilized leachate treatment were compared with those from other treatment processes, such as ozone only and persulfate S{sub 2}O{sub 8}{sup 2-} only, to evaluate its effectiveness. The combined method (i.e., O{sub 3}/S{sub 2}O{sub 8}{sup 2-}) achieved higher removal efficiencies for COD, color, and NH{sub 3}–N compared with other studied applications. Furthermore, the new method is more efficient than ozone/Fenton in advanced oxidation process in the treatment of the same studied leachate.

  3. Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam

    SciTech Connect (OSTI)

    Pratt, A. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Department of Physics, University of York, Heslington, York YO10 5DD (United Kingdom); Graziosi, P.; Bergenti, I.; Dediu, A. [CNR – ISMN, Consiglio Nazionale delle Ricerche – Istituto per lo Studio dei Materiali Nanostrutturati, v. Gobetti 101, 40129 Bologna (Italy); Prezioso, M. [Department of Electrical and Computer Engineering, Harold Frank Hall, University of California, Santa Barbara, California 93106 (United States); Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-07-15T23:59:59.000Z

    We present a novel method of delivering a low-concentration (<15%) ozone beam to an ultra-high vacuum environment for the purpose of cleaning and dosing experimental samples through oxidation processing. The system described is safe, low-cost, and practical and overcomes the limitations of ozone transport in the molecular flow environment of high or ultrahigh vacuum whilst circumventing the use of pure ozone gas which is potentially highly explosive. The effectiveness of this method in removing surface contamination is demonstrated through comparison of high-temperature annealing of a simple oxide (MgO) in ozone and oxygen environments as monitored using quadrupole mass spectroscopy and Auger electron spectroscopy. Additionally, we demonstrate the potential of ozone for obtaining clean complex oxide surfaces without the need for high-temperature annealing which may significantly alter surface structure.

  4. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control...

  5. Nox control for high nitric oxide concentration flows through combustion-driven reduction

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Ekmann, James M. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA); Drummond, Charles J. (Churchill, PA)

    1989-01-01T23:59:59.000Z

    An improved method for removing nitrogen oxides from concentrated waste gas streams, in which nitrogen oxides are ignited with a carbonaceous material in the presence of substoichiometric quantities of a primary oxidant, such as air. Additionally, reductants may be ignited along with the nitrogen oxides, carbonaceous material and primary oxidant to achieve greater reduction of nitrogen oxides. A scrubber and regeneration system may also be included to generate a concentrated stream of nitrogen oxides from flue gases for reduction using this method.

  6. Reducing NOx in Fired Heaters and Boilers 

    E-Print Network [OSTI]

    Garg, A.

    2000-01-01T23:59:59.000Z

    -6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... million BTU ? These levels can be achieved by Ultra Low NOx burners or FGR in boilers. ? Primary products of combustion ? Carbon dioxide ? Water vapors ? Oxygen ? Nitrogen ? Trace compounds NOx emissions ? NOx or Oxides of Nitrogen have...

  7. Proceedings: 2000 NOx Controls Workshop

    SciTech Connect (OSTI)

    None

    2001-04-01T23:59:59.000Z

    The 2000 EPRI workshop on nitrogen oxide (NOx) controls for utility boilers provided a medium for member utilities to augment their knowledge of recent operating experience and developments on NOx control technologies. The event focused on improving methods of compliance with emission regulations mandated by the Clean Air Act Amendments (CAAA) of 1990 without jeopardizing efficiency and plant performance.

  8. Potential of Ozone Formation by the Smog Mechanism to shield the surface of the Early Earth from UV radiation?

    E-Print Network [OSTI]

    John Lee Grenfell; Barbara Stracke; Beate Patzer; Ruth Titz; Heike Rauer

    2006-09-08T23:59:59.000Z

    We propose that the photochemical smog mechanism produced substantial ozone (O3) in the troposphere during the Proterozoic, which contributed to ultraviolet (UV) radiation shielding hence favoured the establishment of life. The smog mechanism is well-established and is associated with pollution hazes which sometimes cover modern cities. The mechanism proceeds via the oxidation of volatile organic compounds (VOCs) such as methane (CH4) in the presence of UV radiation and nitrogen oxides (NOx). It would have been particularly favoured during the Proterozoic given the high levels of CH4 (up to 1000 ppm) recently suggested. Proterozoic UV levels on the surface of the Earth were generally higher compared with today, which would also have favoured the mechanism. On the other hand, Proterozoic O2 required in the final step of the smog mechanism to form O3 was less abundant compared with present times. Further, results are sensitive to Proterozoic NOx concentrations, which are challenging to predict, since they depend on uncertain quantities such as NOx source emissions and OH concentrations. We review NOx sources during the Proterozoic and apply a photochemical box model having methane oxidation with NOx, HOx and Ox chemistry to estimate the O3 production from the smog mechanism. Runs suggest the smog mechanism during the Proterozoic can produce about double present day ozone columns for NOx levels of 1.53 10-9 by volume mixing ratio, which was attainable according to our NOx source analysis, with 1 per-cent present atmospheric levels (PALs) of O2. Clearly, forming ozone in the troposphere is a trade-off for survivability. On the one hand harmful UV is blocked, but on the other hand ozone is a respiratory irratant, which becomes fatal at concentrations exceeding about 1 ppmv.

  9. Industry-Utility Collaborative Efforts to Address Environmental Concerns- Dispatching for Localized NOx Reduction

    E-Print Network [OSTI]

    Hamilton, D. E.; Helmick, R. W.; Lambert, W. J.

    these objectives. The approach involves dispatching NOx-producing equipment (e.g., boilers and gas turbines) to achieve minimum NOx production during ozone alert periods and purchasing supplemental power under a special tariff to replace any loss in self...

  10. NOx adsorber and method of regenerating same

    DOE Patents [OSTI]

    Endicott, Dennis L. (Peoria, IL); Verkiel, Maarten (Metamora, IL); Driscoll, James J. (Dunlap, IL)

    2007-01-30T23:59:59.000Z

    New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

  11. Air Pollution Control Regulations: No. 41- Nox Budget Trading Program (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These...

  12. Process-scale modeling of elevated wintertime ozone in Wyoming.

    SciTech Connect (OSTI)

    Kotamarthi, V. R.; Holdridge, D. J.; Environmental Science Division

    2007-12-31T23:59:59.000Z

    Measurements of meteorological variables and trace gas concentrations, provided by the Wyoming Department of Environmental Quality for Daniel, Jonah, and Boulder Counties in the state of Wyoming, were analyzed for this project. The data indicate that highest ozone concentrations were observed at temperatures of -10 C to 0 C, at low wind speeds of about 5 mph. The median values for nitrogen oxides (NOx) during these episodes ranged between 10 ppbv and 20 ppbv (parts per billion by volume). Measurements of volatile organic compounds (VOCs) during these periods were insufficient for quantitative analysis. The few available VOCs measurements indicated unusually high levels of alkanes and aromatics and low levels of alkenes. In addition, the column ozone concentration during one of the high-ozone episodes was low, on the order of 250 DU (Dobson unit) as compared to a normal column ozone concentration of approximately 300-325 DU during spring for this region. Analysis of this observation was outside the scope of this project. The data analysis reported here was used to establish criteria for making a large number of sensitivity calculations through use of a box photochemical model. Two different VOCs lumping schemes, RACM and SAPRC-98, were used for the calculations. Calculations based on this data analysis indicated that the ozone mixing ratios are sensitive to (a) surface albedo, (b) column ozone, (c) NOx mixing ratios, and (d) available terminal olefins. The RACM model showed a large response to an increase in lumped species containing propane that was not reproduced by the SAPRC scheme, which models propane as a nearly independent species. The rest of the VOCs produced similar changes in ozone in both schemes. In general, if one assumes that measured VOCs are fairly representative of the conditions at these locations, sufficient precursors might be available to produce ozone in the range of 60-80 ppbv under the conditions modeled.

  13. Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

  14. Spectroscopic measurement of bromine oxide and ozone in the high Arctic during Polar Sunrise Experiment 1992

    SciTech Connect (OSTI)

    Hausmann, M.; Platt, U. [Universitaet Heidelberg (Germany)] [Universitaet Heidelberg (Germany)

    1994-12-20T23:59:59.000Z

    The authors report the measurement of BrO radical densities and ozone in the Arctic troposphere by means of differential optical absorption using very long paths. They observed levels of BrO which varied from below the detection limit to 17 ppt. Such concentrations alone cannot account for the catalytic destruction of ozone observed during periods of episodic ozone variation. The authors offer a model which involves BrO catalyzed reactions, advection, and atmospheric mixing which they argue could account for the observed ozone depletions.

  15. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

    2001-10-10T23:59:59.000Z

    This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

  16. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Documents & Publications Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic...

  17. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  18. NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation from the U.S....

  19. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30T23:59:59.000Z

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  20. Influence of combustion parameters on NOx production in an industrial boiler

    E-Print Network [OSTI]

    Aldajani, Mansour A.

    Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M; accepted 14 April 2007 Available online 24 June 2007 Abstract NOx formation during the combustion process occurs mainly through the oxidation of nitrogen in the combustion air (thermal NOx) and through oxidation

  1. Formation of ozone and oxidation of methane in a direct current corona discharge 

    E-Print Network [OSTI]

    Tangirala, Umashanker

    1976-01-01T23:59:59.000Z

    if they are not deliberately maintained below toxic levels. This kind of air pollution problem is quite different from that of industrial emissions as it calls for the removal of mere traces of contaminant from large volumes of gas. For this purpose, conventional treatment... current corona discharge reactor, over a wide range of experimental conditions. The experi- mental variables were corona current, voltage, reactor radius ratio (Ri/R2), gas flow rate and temperature. Generally, more ozone was produced in the negative...

  2. Plant-Wide NOx Reduction Strategies 

    E-Print Network [OSTI]

    Baukal, C.; Waibel, D.; Webster, T.

    2006-01-01T23:59:59.000Z

    (adapted from ref. 1). Technology Approximate Reduction (%) Approximate Emissions (lb/MMBtu) Standard Burners Base Case 0.14 Low-NOx Burners (LNB) 60% 0.06 Ultra-Low-NOx- Burners (ULNB) 80 – 95% 0.007 – 0.03 Flue Gas Recirculation 55% 0..., and oxidizer switching. Fuel switching is simply replacing a more polluting fuel with a less polluting fuel. For example, fuel oils generally contain some organically-bound nitrogen that produces fuel NOx. Natural gas does not normally contain any...

  3. Oxidation of methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by ozone and combined ozone/hydrogen peroxide

    SciTech Connect (OSTI)

    Leitner, N.K.V.; Papailhou, A.L.; Croue, J.P.; Dore, M. (Univ. de Poitiers (France)); Peyrot, J. (British Petroleum, Harfleur (France))

    1994-01-01T23:59:59.000Z

    The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O[sub 3]/H[sub 2]O[sub 2]. batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH[degree]-radical with MTBE and ETBE (k[sub OH[degree]/ETBE]/k[sub OH[degree]//MTBE] = 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE an ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds. 10 refs., 10 figs., 1 tab.

  4. The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest

    E-Print Network [OSTI]

    Collins, Gary S.

    The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest also acts as an antioxidant within a plant, reacting and neutralizing ozone and peroxides, though , and reacts photochemically in the presence of NOx to produce tropospheric ozone. The Model of Emissions

  5. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

    2008-10-21T23:59:59.000Z

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  6. Low NOx combustion

    SciTech Connect (OSTI)

    Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

    2007-06-05T23:59:59.000Z

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  7. NOx Sensor Development

    Broader source: Energy.gov (indexed) [DOE]

    and advanced testing facilities. - EmiSense LLC: licensed LLNL NOx technology and CRADA partners for continued development. Relevance - If 33% of U.S. drivers switched to...

  8. NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...

    Broader source: Energy.gov (indexed) [DOE]

    technology operation. - Chemical mechanisms of NOx adsorption, desorption, and reduction for inclusion in CLEERS models - emphasis this year: effect of CO 2 and H 2 O on NOx...

  9. Controlling NOx to Obtain Offsets or Meet Compliance 

    E-Print Network [OSTI]

    Mincy, J. E.

    1992-01-01T23:59:59.000Z

    Even before the Clean Air Act Amendments of 1990, regulatory authorities monitored and regulated a number of pollutants: lead, carbon monoxide, oxides of sulfur, oxides of nitrogen, ozone and PM-10. The Clean Air Act Amendments increased the focus...

  10. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine 

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01T23:59:59.000Z

    Ozone, a phytotoxic air pollutant, is formed from photochemical reactions of hydrocarbons and nitrogen oxides in the troposphere. Ozone is taken into the plant through the stomata, and quickly broken down into hydroxyl radicals. These hydroxyl...

  11. Nonaqueous ozonation of vulcanized rubber

    SciTech Connect (OSTI)

    Serkiz, S.M.

    1999-12-07T23:59:59.000Z

    A process and resulting product are provided in which a solid particulate, such as vulcanized crumb rubber, has the surface functional groups oxidized by ozonation using a nonpolar solvent. The ozonation process renders the treated crumb rubber more suitable for use in new rubber formulations. As a result, larger loading levels of the treated crumb rubber can be used in new rubber mixtures.

  12. Nonaqueous ozonation of vulcanized rubber

    SciTech Connect (OSTI)

    Serkiz, Steven M. (Aiken, SC)

    1999-01-01T23:59:59.000Z

    A process and resulting product is provided in which a solid particulate, such as vulcanized crumb rubber, has the surface functional groups oxidized by ozonation using a nonpolar solvent. The ozonation process renders the treated crumb rubber more suitable for use in new rubber formulations. As a result, larger loading levels of the treated crumb rubber can be used in new rubber mixtures.

  13. Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas

    E-Print Network [OSTI]

    Nam, Junsang

    2007-01-01T23:59:59.000Z

    High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

  14. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06T23:59:59.000Z

    study these interactions. This is important because the EPA has considered tightening the standards for both ozone and particulate matter. Industries would then need to reduce emissions or move farther from current sources of Cl or NOx pollution....

  15. CLEERS Activities: Diesel Soot Filter Characterization & NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen...

  16. tive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and

    E-Print Network [OSTI]

    Denver, University of

    tive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and associated NO.,. emissions automobiles. A much stronger response was found from changes in GPVVOC emissions. ROMNET 2.2 results also inroad from us- ing EVs is to reduce VOC emissions Smith comments that ozone is a daytime phenomenon

  17. On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California

    E-Print Network [OSTI]

    Pusede, S. E.

    The San Joaquin Valley (SJV) experiences some of the worst ozone air quality in the US, frequently exceeding the California 8 h standard of 70.4 ppb. To improve our understanding of trends in the number of ozone violations ...

  18. NOx Abatement Research and Development

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Work * Identify factors limiting NOx conversion during low temperature operation with CO and hydrocarbon (HC) reductants - Goal is to improve the effectiveness and efficiency of...

  19. Ozone Treatments of Fresh Atlantic Cod, Gadus morhua

    E-Print Network [OSTI]

    Ozone Treatments of Fresh Atlantic Cod, Gadus morhua ELINOR M. RAVESI, JOSEPH J. L1CCIARDELLO and LINDA D. RACICOT Introduction The strong oxidizing nature of ozone, known since its discovery in 1840 (1977) cited in a review article numerous reports of the successful use of ozone to I) control microbial

  20. Tropospheric Ozone ATOC/CHEM 5151

    E-Print Network [OSTI]

    Toohey, Darin W.

    polymers, such as rubber #12;12 Tropospheric ozone distribution · Generally increases with altitude) ( production! #12;18 Ozone production CO + OH CO2 + H loss · Photolysis (1.4 x 1011 cm-2 s-1) · Oxidation of CO (3.5 x 1011 cm-2 s-1) 4. Chemical production

  1. Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star

    E-Print Network [OSTI]

    Grenfell, J L; Patzer, B; Rauer, H; Segura, A; Stadelmann, A; Stracke, B; Titz, R; Von Paris, P; Grenfell, John Lee; Griessmeier, Jean-Mathias; Patzer, Beate; Rauer, Heike; Segura, Antigona; Stadelmann, Anja; Stracke, Barbara; Titz, Ruth; Paris, Philip von

    2007-01-01T23:59:59.000Z

    Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% ...

  2. NOx EMISSIONS PRODUCED WITH COMBUSTION OF POWDER RIVER BASIN COAL IN A UTILITY BOILER

    SciTech Connect (OSTI)

    John S. Nordin; Norman W. Merriam

    1997-04-01T23:59:59.000Z

    The objective of this report is to estimate the NOx emissions produced when Powder River Basin (PRB) coal is combusted in a utility boiler. The Clean Air Act regulations specify NOx limits of 0.45 lb/mm Btu (Phase I) and 0.40 lb/mm Btu (Phase II) for tangentially fired boilers, and 0.50 lb/mm 13tu (Phase II) and 0.46 lb/mm Btu (Phase II) for dry-bottom wall-fired boilers. The Clean Air Act regulations also specify other limits for other boiler types. Compliance for Phase I has been in effect since January 1, 1996. Compliance for Phase II goes into effect on January 1, 2000. Emission limits are expressed as equivalent NO{sub 2} even though NO (and sometimes N{sub 2}O) is the NOx species emitted during combustion. Regulatory agencies usually set even lower NOx emission limits in ozone nonattainment areas. In preparing this report, Western Research Institute (WRI) used published test results from utilities burning various coals, including PRB coal, using state-of-the art control technology for minimizing NOx emissions. Many utilities can meet Clean Air Act NOx emission limits using a combination of tight combustion control and low-NOx burners and by keeping furnaces clean (i.e., no slag buildup). In meeting these limits, some utilities also report problems such as increased carbon in their fly ash and excessive furnace tube corrosion. This report discusses utility experience. The theory of NOx emission formation during coal combustion as related to coal structure and how the coal is combusted is also discussed. From this understanding, projections are made for NOx emissions when processed PRB coal is combusted in a test similar to that done with other coals. As will be shown, there are a lot of conditions for achieving low NOx emissions, such as tight combustion control and frequent waterlancing of the furnace to avoid buildup of deposits.

  3. Measurement and Characterization of NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Adsorber Regeneration and Desulfation Measurement and Characterization of NOx Adsorber Regeneration and Desulfation 2003 DEER Conference Presentation: Oak Ridge National...

  4. Two-Stage Plasma-Catalysis for Diesel NOx Emission Control. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    producing nitrogen. Citation: Hoard J, and RG Tonkyn.2003."Two-Stage Plasma-Catalysis for Diesel NOx Emission Control."Journal of Advanced Oxidation Technologies 6(2):158-165....

  5. Interpreting Remote Sensing NOx Measurements

    E-Print Network [OSTI]

    Denver, University of

    Interpreting Remote Sensing NOx Measurements Robert Slott, Consultant, Donald Stedman and Saj tailpipe emissions (HC, CO, NOx) are changing with time hUse remote sensing hMeasurements in at least 4 of the year at each location hUniform QC/QA and data reporting Paper # 2001-01-3640 #12;Remote Sensing

  6. Al{sub 2}O{sub 3}/GeO{sub x} gate stack on germanium substrate fabricated by in situ cycling ozone oxidation method

    SciTech Connect (OSTI)

    Yang, Xu; Zeng, Zhen-Hua [Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210096 (China); Microwave Device and IC Department, Institute of Microelectronics of Chinese Academy of Sciences, Beijing 100029 (China); Wang, Sheng-Kai, E-mail: wangshengkai@ime.ac.cn, E-mail: xzhang62@aliyun.com, E-mail: liuhonggang@ime.ac.cn; Sun, Bing; Zhao, Wei; Chang, Hu-Dong; Liu, Honggang, E-mail: wangshengkai@ime.ac.cn, E-mail: xzhang62@aliyun.com, E-mail: liuhonggang@ime.ac.cn [Microwave Device and IC Department, Institute of Microelectronics of Chinese Academy of Sciences, Beijing 100029 (China); Zhang, Xiong, E-mail: wangshengkai@ime.ac.cn, E-mail: xzhang62@aliyun.com, E-mail: liuhonggang@ime.ac.cn [Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University, Nanjing 210096 (China)

    2014-09-01T23:59:59.000Z

    Al{sub 2}O{sub 3}/GeO{sub x}/Ge gate stack fabricated by an in situ cycling ozone oxidation (COO) method in the atomic layer deposition (ALD) system at low temperature is systematically investigated. Excellent electrical characteristics such as minimum interface trap density as low as 1.9?×?10{sup 11?}cm{sup ?2?}eV{sup ?1} have been obtained by COO treatment. The impact of COO treatment against the band alignment of Al{sub 2}O{sub 3} with respect to Ge is studied by x-ray photoelectron spectroscopy (XPS) and spectroscopic ellipsometry (SE). Based on both XPS and SE studies, the origin of gate leakage in the ALD-Al{sub 2}O{sub 3} is attributed to the sub-gap states, which may be correlated to the OH-related groups in Al{sub 2}O{sub 3} network. It is demonstrated that the COO method is effective in repairing the OH-related defects in high-k dielectrics as well as forming superior high-k/Ge interface for high performance Ge MOS devices.

  7. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect (OSTI)

    Hamid Farzan

    2003-12-31T23:59:59.000Z

    Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a subcontract for Fuel Tech has been started.

  8. Quantifying the contributions to stratospheric ozone changes from ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Quantifying the contributions to stratospheric ozone changes from ozone depleting substances Chemistry and Physics Quantifying the contributions to stratospheric ozone changes from ozone depleting by different combinations of long-lived Greenhouse Gases (GHGs) and Ozone Depleting Substances (ODSs

  9. Measurement and Characterization of Lean NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and...

  10. Reactive based NOx sensor

    E-Print Network [OSTI]

    Vassiliou, Christophoros Christou

    2006-01-01T23:59:59.000Z

    Diesel engines exhibit better fuel economy and emit fewer greenhouse gases than gasoline engines. Modern diesel technology has virtually eliminated carbon monoxide and particulate emissions. Sulfur oxide emissions have ...

  11. Plant-Wide NOx Reduction Strategies

    E-Print Network [OSTI]

    Baukal, C.; Waibel, D.; Webster, T.

    2006-01-01T23:59:59.000Z

    and the public's awareness increased, industry began looking for new strategies to curb NOx emissions. The strategies for reducing NOx are discussed next. Table 1 shows a summary of common NOx control technologies [1]. Table 1 NOx reduction technologies... for NOx Control, in Industrial Combustion Technologies, ed. by M.A. Lukasiewicz, American Society of Metals, Warren, PA, pp. 345-350, 1986. 7. A. Garg, Trimming NOx, Chem Eng., Vol. 99, No. 11, pp. 122-124, 1992. 8. C.E. Baukal, Industrial Combustion...

  12. NOx reduction with the use of feedlot biomass as a reburn fuel

    E-Print Network [OSTI]

    Goughnour, Paul Gordon

    2009-05-15T23:59:59.000Z

    ash because the residence time for char burnout is reduced. [16] 9 Another relatively new NOx reduction technique, that only recently became feasible, uses oxygen and re-circulated exhaust gas as the oxidizer in the combustion zone. Enough exhaust... gas is re-circulated to achieve a near 20% oxygen level prior to combustion. This concentration of oxygen is required to maintain the temperature at an acceptable level. This type of combustion scheme has been reported to reduce NOx levels by 75...

  13. Control of NOx by combustion process modifications

    E-Print Network [OSTI]

    Ber?, J. M.

    1981-01-01T23:59:59.000Z

    A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

  14. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01T23:59:59.000Z

    Global and zonal total ozone variations estimated fromon multidecadal total ozone simulations, J. Geophys. Res. ,and J. A. Logan (2007), Ozone climatolo- gical profiles for

  15. NOx Sensor Development

    SciTech Connect (OSTI)

    Woo, L Y; Glass, R S

    2009-10-27T23:59:59.000Z

    The objectives of this report are: (1) Develop an inexpensive, rapid-response, high-sensitivity and selective electrochemical sensor for oxides of nitrogen (NO{sub x}) for compression-ignition, direct-injection (CIDI) exhaust gas monitoring; (2) Explore and characterize novel, effective sensing methodologies based on impedance measurements; (3) Explore designs and manufacturing methods that could be compatible with mass fabrication; and (4) Collaborate with industry in order to (ultimately) transfer the technology to a supplier for commercialization.

  16. Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

    SciTech Connect (OSTI)

    Nigel N. Clark

    2006-12-31T23:59:59.000Z

    Nitric oxide (NO) and nitrogen dioxide (NO2) generated by internal combustion (IC) engines are implicated in adverse environmental and health effects. Even though lean-burn natural gas engines have traditionally emitted lower oxides of nitrogen (NOx) emissions compared to their diesel counterparts, natural gas engines are being further challenged to reduce NOx emissions to 0.1 g/bhp-hr. The Selective NOx Recirculation (SNR) approach for NOx reduction involves cooling the engine exhaust gas and then adsorbing the NOx from the exhaust stream, followed by the periodic desorption of NOx. By sending the desorbed NOx back into the intake and through the engine, a percentage of the NOx can be decomposed during the combustion process. SNR technology has the support of the Department of Energy (DOE), under the Advanced Reciprocating Engine Systems (ARES) program to reduce NOx emissions to under 0.1 g/bhp-hr from stationary natural gas engines by 2010. The NO decomposition phenomenon was studied using two Cummins L10G natural gas fueled spark-ignited (SI) engines in three experimental campaigns. It was observed that the air/fuel ratio ({lambda}), injected NO quantity, added exhaust gas recirculation (EGR) percentage, and engine operating points affected NOx decomposition rates within the engine. Chemical kinetic model predictions using the software package CHEMKIN were performed to relate the experimental data with established rate and equilibrium models. The model was used to predict NO decomposition during lean-burn, stoichiometric burn, and slightly rich-burn cases with added EGR. NOx decomposition rates were estimated from the model to be from 35 to 42% for the lean-burn cases and from 50 to 70% for the rich-burn cases. The modeling results provided an insight as to how to maximize NOx decomposition rates for the experimental engine. Results from this experiment along with chemical kinetic modeling solutions prompted the investigation of rich-burn operating conditions, with added EGR to prevent preignition. It was observed that the relative air/fuel ratio, injected NO quantity, added EGR fraction, and engine operating points affected the NO decomposition rates. While operating under these modified conditions, the highest NO decomposition rate of 92% was observed. In-cylinder pressure data gathered during the experiments showed minimum deviation from peak pressure as a result of NO injections into the engine. A NOx adsorption system, from Sorbent Technologies, Inc., was integrated with the Cummins engine, comprised a NOx adsorbent chamber, heat exchanger, demister, and a hot air blower. Data were gathered to show the possibility of NOx adsorption from the engine exhaust, and desorption of NOx from the sorbent material. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a benchtop adsorption system was constructed. The temperature of this apparatus was controlled while data were gathered on the characteristics of the sorbent material for development of a system model. A simplified linear driving force model was developed to predict NOx adsorption into the sorbent material as cooled exhaust passed over fresh sorbent material. A mass heat transfer analysis was conducted to analyze the possibility of using hot exhaust gas for the desorption process. It was found in the adsorption studies, and through literature review, that NO adsorption was poor when the carrier gas was nitrogen, but that NO in the presence of oxygen was adsorbed at levels exceeding 1% by mass of the sorbent. From the three experimental campaigns, chemical kinetic modeling analysis, and the scaled benchtop NOx adsorption system, an overall SNR system model was developed. An economic analysis was completed, and showed that the system was impractical in cost for small engines, but that economies of scale favored the technology.

  17. Process Modeling of Global Soil Nitrous Oxide Emissions

    E-Print Network [OSTI]

    Saikawa, E.

    2011-09-01T23:59:59.000Z

    Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

  18. Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux measurements

    E-Print Network [OSTI]

    Silver, Whendee

    Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux Abstract High ground-level ozone concentrations are typical of Mediterranean climates. Plant exposure to this oxidant is known to reduce carbon assimilation. Ozone damage has been traditionally measured through

  19. Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2

    E-Print Network [OSTI]

    Weber, Rodney

    1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 Problem 1: Nighttime loss of NOx in the lower troposphere proceeds by: 1 Air Pollution Physics and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

  20. Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star

    E-Print Network [OSTI]

    John Lee Grenfell; Jean-Mathias Griessmeier; Beate Patzer; Heike Rauer; Antigona Segura; Anja Stadelmann; Barbara Stracke; Ruth Titz; Philip von Paris

    2007-02-23T23:59:59.000Z

    Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on the Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M-star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M-star world differs considerably compared with the Earth.

  1. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30T23:59:59.000Z

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOE’s) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  2. LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE

    SciTech Connect (OSTI)

    Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

    2004-08-01T23:59:59.000Z

    In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

  3. NOx Reduction through Efficiency Gain

    E-Print Network [OSTI]

    Benz, R.; Thompson, R.; Staedter, M.

    2007-01-01T23:59:59.000Z

    Approach, Fifth Edition, McGraw-Hill, June 2005 Kuo, K. K., Principles of Combustion 2 nd Edition, Wiley, January 2005 Erickson, K. T., Plant-Wide Process Control, 1 st Edition, Wiley, April 2005 ESL-IE-07-05-42 Proceedings... putting financial stress on steam generation plants to adhere to environmental regulations we provide an incentive to do so. The simplicity and elegance of the CompuNOx system minimizes system changes. Control related changes consist...

  4. NOx reduction in gas turbine combustors

    E-Print Network [OSTI]

    Sung, Nak Won

    1976-01-01T23:59:59.000Z

    NOx REDUCTION IN GAS TURBINE COMBUSTORS A Thesis by Nak Won Sung Submitted to the Graduate College of Texas A&M University in partial fullfillment of the requirement for the degree of MASTER OF SCIENCE August 1976 Major Subject: Mechanical... Engineering NOx REDUCTION IN GAS TURBINE COMBUSTORS A Thesis by Nak Won Sung Approved as to style and content by: (Chairman of Committe (Head of Department) (Member) August 1976 "40308 (Member) 1 1. 1 ABSTRACT NOx Reduction in Gas Turbine...

  5. Three-Dimensional Composite Nanostructures for Lean NOx Emission Control

    SciTech Connect (OSTI)

    Gao, Pu-Xian

    2013-07-31T23:59:59.000Z

    This final report to the Department of Energy (DOE) and National Energy Technology Laboratory (NETL) for DE-EE0000210 covers the period from October 1, 2009 to July 31, 2013. Under this project, DOE awarded UConn about $1,248,242 to conduct the research and development on a new class of 3D composite nanostructure based catalysts for lean NOx emission control. Much of the material presented here has already been submitted to DOE/NETL in quarterly technical reports. In this project, through a scalable solution process, we have successfully fabricated a new class of catalytic reactors, i.e., the composite nanostructure array (nano-array) based catalytic converters. These nanocatalysts, distinct from traditional powder washcoat based catalytic converters, directly integrate monolithic substrates together with nanostructures with well-defined size and shape during the scalable hydrothermal process. The new monolithic nanocatalysts are demonstrated to be able to save raw materials including Pt-group metals and support metal oxides by an order of magnitude, while perform well at various oxidation (e.g., CO oxidation and NO oxidation) and reduction reactions (H{sub 2} reduction of NOx) involved in the lean NOx emissions. The size, shape and arrangement of the composite nanostructures within the monolithic substrates are found to be the key in enabling the drastically reduced materials usage while maintaining the good catalytic reactivity in the enabled devices. The further understanding of the reaction kinetics associated with the unique mass transport and surface chemistry behind is needed for further optimizing the design and fabrication of good nanostructure array based catalytic converters. On the other hand, the high temperature stability, hydrothermal aging stability, as well as S-poisoning resistance have been investigated in this project on the nanocatalysts, which revealed promising results toward good chemical and mechanical robustness, as well as S-poisoning resistance. Further investigation is needed for unraveling the understanding, design and selection principles of this new class of nanostructure based monolithic catalysts.

  6. Small, Inexpensive Combined NOx Sensor and O2 Sensor

    SciTech Connect (OSTI)

    W. N. Lawless; C. F. Clark, Jr.

    2008-09-08T23:59:59.000Z

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NOx sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NOx from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5 - $10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NOx. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650 - 700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NOx sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NOx sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NOx and oxygen sensors yields the NOx content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  7. Plasma Assisted Catalysis System for NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    2 NOXTECH NOXTECH PLASMA ASSISTED CATALYSIS SYSTEM FOR NOx REDUCTION BY NOXTECH With the Support & Cooperation of DOE Noxtech, Inc. *Delaware Corporation registered to do business...

  8. Investigation on Nitric Oxide and Soot of Biodiesel and Conventional Diesel using a Medium Duty Diesel Engine 

    E-Print Network [OSTI]

    Song, Hoseok

    2012-07-16T23:59:59.000Z

    Biodiesel has been suggested as an alternative fuel to the petroleum diesel fuel. It beneficially reduces regulated emission gases, but increases NOx (nitric oxide and nitrogen dioxide) Thus, the increase in NOx is the barrier for potential growth...

  9. Investigation on Nitric Oxide and Soot of Biodiesel and Conventional Diesel using a Medium Duty Diesel Engine

    E-Print Network [OSTI]

    Song, Hoseok

    2012-07-16T23:59:59.000Z

    Biodiesel has been suggested as an alternative fuel to the petroleum diesel fuel. It beneficially reduces regulated emission gases, but increases NOx (nitric oxide and nitrogen dioxide) Thus, the increase in NOx is the barrier for potential growth...

  10. Congressionally Directed Project for Passive NOx Removal Catalysts Research

    SciTech Connect (OSTI)

    Schneider, William

    2014-08-29T23:59:59.000Z

    The Recipient proposes to produce new scientific and technical knowledge and tools to enable the discovery and deployment of highly effective materials for the selective catalytic reduction (SCR) of nitrogen oxides (NOx) from lean combustion exhaust. A second goal is to demonstrate a closely coupled experimental and computational approach to heterogeneous catalysis research. These goals will be met through the completion of four primary technical objectives: First, an in-depth kinetic analysis will be performed on two prominent classes of NOx SCR catalysts, Fe- and Cu-exchanged beta and ZSM-5 zeolites, over a wide range of catalyst formulation and under identical, high conversion conditions as a function of gas phase composition. Second, the nanoscale structure and adsorption chemistry of these high temperature (HT) and low temperature (LT) catalysts will be determined using in situ and operando spectroscopy under the same reaction conditions. Third, first-principles molecular simulations will be used to model the metal-zeolite active sites, their adsorption chemistry, and key steps in catalytic function. Fourth, this information will be integrated into chemically detailed mechanistic and kinetic descriptions and models of the operation of these well- defined NOx SCR catalysts under practically relevant reaction conditions. The new knowledge and models that derive from this work will be published in the scientific literature.

  11. Power Generating Stationary Engines Nox Control: A Closed Loop...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generating Stationary Engines Nox Control: A Closed Loop Control Technology Power Generating Stationary Engines Nox Control: A Closed Loop Control Technology Poster presented at...

  12. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis for Heavy-Duty Diesel Emissions Control Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Dynamometer Evaluation of...

  13. An Experimental Investigation of the Origin of Increased NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling...

  14. Measurement and Characterization of Lean NOx Adsorber Regeneration...

    Broader source: Energy.gov (indexed) [DOE]

    parks.pdf More Documents & Publications Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts Measurement and Characterization of Lean NOx Adsorber Regeneration...

  15. Deactivation mechanisms of NOx storage materials arising from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning...

  16. Retrofit Diesel Emissions Control System Providing 50% NOxControl...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  17. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

  18. NOx Abatement Research and Development CRADA with Navistar Incorporate...

    Broader source: Energy.gov (indexed) [DOE]

    NOx Abatement Research and Development CRADA with Navistar Incorporated NOx Abatement Research and Development CRADA with Navistar Incorporated 2009 DOE Hydrogen Program and...

  19. Functionality of Commercial NOx Storage-Reduction Catalysts and...

    Broader source: Energy.gov (indexed) [DOE]

    Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  20. The Ozone Hole Some perspective

    E-Print Network [OSTI]

    Toohey, Darin W.

    The Ozone Hole · Some perspective · The British Antarctic Survey · The "Ozone Hole" · International of the predicted ozone losses! This was quite a controversy. Ultimately, ozone losses started appearing in the late 1980s (see Figure below), but by then, there was already a credibility issue for ozone scientists. #12

  1. Midlatitude Ozone: Loss and Trends

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 17 Midlatitude Ozone: Loss and Trends ATOC/CHEM 5151 #12;2 Importance of midlatitude ozone · Covers most of the world's populated areas · Provides protection from UV #12;3 Ozone loss picture, c. 1988 #12;4 Lower vs. Upper stratosphere #12;5 Ozone loss, post 1988 · Discovery of ozone hole

  2. ARM - Ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat fluxChinaNews : AMFAlaskaNewsOxides of

  3. Minimize NOx using only combustion control

    SciTech Connect (OSTI)

    Penterson, C.A.; Hules, K.R. [Riley Power Inc. (United States)

    2005-10-01T23:59:59.000Z

    The retrofit of a 600 MW opposed wall-fired utility boiler with low-NOx, dual air zone burners and overfire air cut the Wyoming PRB coal burner's NOx output by nearly half. The key to the project's success from the design stage through final testing and boiler tuning was CFD modeling. 7 figs., 2 tabs.

  4. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

    2007-09-01T23:59:59.000Z

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

  5. Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: Algorithm description and validation

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment October 2005. [1] Ozone profiles are derived from back scattered radiance spectra in the ultraviolet (289­339 nm) measured by the Global Ozone Monitoring Experiment (GOME) using the optimal estimation technique

  6. Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles.

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles breaks down before sunlight returns: smaller ozone hole { Formation of polar stratospheric clouds (PSC #3; Photo-initiation reactions: Cl 2 h#23; ! 2Cl HOCl h#23; ! OH + Cl #3; Rapid destruction of ozone

  7. 6, 74277469, 2006 Linear ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 7427­7469, 2006 Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Chemistry and Physics Discussions Evaluation of linear ozone photochemistry parametrizations Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Abstract Introduction

  8. Mercury oxidation promoted by a selective catalytic reduction catalyst under simulated Powder River Basin coal combustion conditions

    SciTech Connect (OSTI)

    Chun W. Lee; Shannon D. Serre; Yongxin Zhao; Sung Jun Lee; Thomas W. Hastings [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). Office of Research and Development, National Risk Management Research Laboratory

    2008-04-15T23:59:59.000Z

    A bench-scale reactor consisting of a natural gas burner and an electrically heated reactor housing a selective catalytic reduction (SCR) catalyst was constructed for studying elemental mercury (Hg{sup 0}) oxidation under SCR conditions. A low sulfur Powder River Basin (PRB) subbituminous coal combustion fly ash was injected into the entrained-flow reactor along with sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), hydrogen chloride (HCl), and trace Hg{sup 0}. Concentrations of Hg{sup 0} and total mercury (Hg) upstream and downstream of the SCR catalyst were measured using a Hg monitor. The effects of HCl concentration, SCR operating temperature, catalyst space velocity, and feed rate of PRB fly ash on Hg0 oxidation were evaluated. It was observed that HCl provides the source of chlorine for Hg{sup 0} oxidation under simulated PRB coal-fired SCR conditions. The decrease in Hg mass balance closure across the catalyst with decreasing HCl concentration suggests that transient Hg capture on the SCR catalyst occurred during the short test exposure periods and that the outlet speciation observed may not be representative of steady-state operation at longer exposure times. Increasing the space velocity and operating temperature of the SCR led to less Hg{sup 0} oxidized. Introduction of PRB coal fly ash resulted in slightly decreased outlet oxidized mercury (Hg{sup 2+}) as a percentage of total inlet Hg and correspondingly resulted in an incremental increase in Hg capture. The injection of ammonia (NH{sub 3}) for NOx reduction by SCR was found to have a strong effect to decrease Hg oxidation. The observations suggest that Hg{sup 0} oxidation may occur near the exit region of commercial SCR reactors. Passage of flue gas through SCR systems without NH{sub 3} injection, such as during the low-ozone season, may also impact Hg speciation and capture in the flue gas. 18 refs., 7 figs., 3 tabs.

  9. EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas

    Broader source: Energy.gov [DOE]

    The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower’s Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NOx control technologies.

  10. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect (OSTI)

    Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

    2013-09-30T23:59:59.000Z

    This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

  11. Selective NOx Recirculation for Stationary Lean-Burn Natural Gas Engines

    SciTech Connect (OSTI)

    Nigel Clark; Gregory Thompson; Richard Atkinson; Richard Turton; Chamila Tissera; Emre Tatli; Andy Zimmerman

    2005-12-28T23:59:59.000Z

    Selective NOx Recirculation (SNR) involves cooling the engine exhaust gas and then adsorbing the oxides of nitrogen (NOx) from the exhaust stream, followed by the periodic desorption of NOx. By returning the desorbed, concentrated NOx into the engine intake and through the combustion chamber, a percentage of the NOx is decomposed during the combustion process. An initial study of NOx decomposition during lean-burn combustion was concluded in 2004 using a 1993 Cummins L10G 240hp natural gas engine. It was observed that the air/fuel ratio, injected NO (nitric oxide) quantity and engine operating points affected NOx decomposition rates of the engine. Chemical kinetic modeling results were also used to determine optimum NOx decomposition operating points and were published in the 2004 annual report. A NOx decomposition rate of 27% was measured from this engine under lean-burn conditions while the software model predicted between 35-42% NOx decomposition for similar conditions. A later technology 1998 Cummins L10G 280hp natural gas engine was procured with the assistance of Cummins Inc. to replace the previous engine used for 2005 experimental research. The new engine was equipped with an electronic fuel management system with closed-loop control that provided a more stable air/fuel ratio control and improved the repeatability of the tests. The engine was instrumented with an in-cylinder pressure measurement system and electronic controls, and was adapted to operate over a range of air/fuel ratios. The engine was connected to a newly commissioned 300hp alternating current (AC) motoring dynamometer. The second experimental campaign was performed to acquire both stoichiometric and slightly rich (0.97 lambda ratio) burn NOx decomposition rates. Effects of engine load and speed on decomposition were quantified, but Exhaust Gas Recirculation (EGR) was not varied independently. Decomposition rates of up to 92% were demonstrated. Following recommendations at the 2004 ARES peer review meeting at Argonne National Laboratories, in-cylinder pressure was measured to calculate engine indicated mean effective pressure (IMEP) changes due to NOx injections and EGR variations, and to observe conditions in the cylinder. The third experimental campaign gathered NOx decomposition data at 800, 1200 and 1800 rpm. EGR was added via an external loop, with EGR ranging from zero to the point of misfire. The air/fuel ratio was set at both stoichiometric and slightly rich conditions, and NOx decomposition rates were calculated for each set of runs. Modifications were made to the engine exhaust manifold to record individual exhaust temperatures. The three experimental campaigns have provided the data needed for a comprehensive model of NOx decomposition during the combustion process, and data have confirmed that there was no significant impact of injected NO on in-cylinder pressure. The NOx adsorption system provided by Sorbent Technologies Corp. (Twinsburg, OH), comprised a NOx adsorber, heat exchanger and a demister. These components were connected to the engine, and data were gathered to show both the adsorption of NOx from the engine, and desorption of NOx from the carbon-based sorbent material back into the engine intake, using a heated air stream. In order to quantify the NOx adsorption/desorption characteristics of the sorbent material, a bench top adsorption system was constructed and instrumented with thermocouples and the system output was fed into a NOx analyzer. The temperature of this apparatus was controlled while gathering data on the characteristics of the sorbent material. These data were required for development of a system model. Preliminary data were gathered in 2005, and will continue in early 2006. To assess the economic benefits of the proposed SNR technology the WVU research team has been joined in the last quarter by Dr Richard Turton (WVU-Chemical Engineering), who is modeling, sizing and costing the major components. The tasks will address modeling and preliminary design of the heat exchanger, demister and NOx sorbent chamber s

  12. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2002deeraardahl.pdf More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in...

  13. NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY

    E-Print Network [OSTI]

    vi NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY Prepared as a NARSTO initiative, this tropospheric O3 in the accompanying Textbox, the NARSTO Ozone Assessment contains two product components. The first of these is a set aspects of tropospheric ozone pollution. The second component, the NARSTO Ozone Assessment Document

  14. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01T23:59:59.000Z

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  15. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    Ray Chamberland; Aku Raino; David Towle

    2006-09-30T23:59:59.000Z

    For more than two decades, ALSTOM Power Inc. (ALSTOM) has developed a range of low cost, in-furnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes ALSTOM's internally developed TFS 2000 firing system, and various enhancements to it developed in concert with the U.S. Department of Energy (DOE). As of 2004, more than 200 units representing approximately 75,000 MWe of domestic coal fired capacity have been retrofit with ALSTOM low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coals to 0.10 lb/MMBtu for subbituminous coals, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing (retrofit) boiler equipment. If enacted, proposed Clear Skies legislation will, by 2008, require an average, effective, domestic NOx emissions rate of 0.16 lb/MMBtu, which number will be reduced to 0.13 lb/MMBtu by 2018. Such levels represent a 60% and 67% reduction, respectively, from the effective 2000 level of 0.40 lb/MMBtu. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. In light of these needs, ALSTOM, in cooperation with the DOE, is developing an enhanced combustion, low NOx pulverized coal burner which, when integrated with ALSTOM's state-of-the-art, globally air staged low NOx firing systems, will provide a means to achieve less than 0.15 lb/MMBtu NOx at less than 3/4 the cost of an SCR with low to no impact on balance of plant issues when firing a high volatile bituminous coal. Such coals can be more economic to fire than subbituminous or Powder River Basin (PRB) coals, but are more problematic from a NOx control standpoint as existing firing system technologies do not provide a means to meet current or anticipated regulations absent the use of an SCR. The DOE/ALSTOM program performed large pilot scale combustion testing in ALSTOM's Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut. During this work, the near-field combustion environment was optimized to maximize NOx reduction while minimizing the impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down under globally reducing conditions. Initially, ALSTOM utilized computational fluid dynamic modeling to evaluate a series of burner and/or near field stoichiometry controls in order to screen promising design concepts in advance of the large pilot scale testing. The third and final test, to be executed, will utilize several variants of the best nozzle tip configuration and compare performance with 3 different coals. The fuels to be tested will cover a wide range of coals commonly fired at US utilities. The completion of this work will provide sufficient data to allow ALSTOM to design, construct, and demonstrate a commercial version of an enhanced combustion low NOx pulverized coal burner. A preliminary cost/performance analysis of the developed enhanced combustion low NOx burner applied to ALSTOM's state-of-the-art TFS 2000 firing system was performed to show that the burner enhancements is a cost effective means to reduce NOx.

  16. Artificial ozone holes

    E-Print Network [OSTI]

    S. N. Dolya

    2014-10-18T23:59:59.000Z

    This article considers an opportunity of disinfecting a part of the Earth surface, occupying a large area of ten thousand square kilometers. The sunlight will cause dissociation of molecular bromine into atoms; each bromine atom kills thirty thousand molecules of ozone. Each bromine plate has a mass of forty milligrams grams and destroys ozone in the area of hundred square meters. Thus, to form the ozone hole over the area of ten thousand square kilometers, it is required to have the total mass of bromine equal to the following four tons.

  17. Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis...

  18. Interaction of Gas-Phase Ozone at 296 K with Unsaturated Self-Assembled Monolayers: A New Look at an Old System

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Interaction of Gas-Phase Ozone at 296 K with Unsaturated Self-Assembled Monolayers: A New Look The oxidation of organics adsorbed on surfaces by ozone is of fundamental chemical interest and potentially- FTIR using ozone concentrations that spanned 5 orders of magnitude, from 1011 to 1016 molecules cm-3

  19. Ozone fluxes in a Pinus ponderosa ecosystem are dominated by non-stomatal processes: Evidence from long-term continuous measurements

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone fluxes in a Pinus ponderosa ecosystem are dominated by non-stomatal processes: Evidence from and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands 1. Introduction Ozone is considered one of the most dangerous oxidant molecules for plants (UNECE, 2004; EPA, 2007). Ozone concentra- tion

  20. Clean Cities ozone air quality attainment and maintenance strategies that employ alternative fuel vehicles, with special emphasis on natural gas and propane

    SciTech Connect (OSTI)

    Santini, D.J.; Saricks, C.L.

    1998-08-04T23:59:59.000Z

    Air quality administrators across the nation are coming under greater pressure to find new strategies for further reducing automotive generated non-methane hydrocarbon (NMHC) and nitrogen oxide (NOx) emissions. The US Environmental Protection Agency (EPA) has established stringent emission reduction requirements for ozone non-attainment areas that have driven the vehicle industry to engineer vehicles meeting dramatically tightened standards. This paper describes an interim method for including alternative-fueled vehicles (AFVs) in the mix of strategies to achieve local and regional improvements in ozone air quality. This method could be used until EPA can develop the Mobile series of emissions estimation models to include AFVs and until such time that detailed work on AFV emissions totals by air quality planners and emissions inventory builders is warranted. The paper first describes the challenges confronting almost every effort to include AFVs in targeted emissions reduction programs, but points out that within these challenges resides an opportunity. Next, it discusses some basic relationships in the formation of ambient ozone from precursor emissions. It then describes several of the salient provisions of EPA`s new voluntary emissions initiative, which is called the Voluntary Mobile Source Emissions Reduction Program (VMEP). Recent emissions test data comparing gaseous-fuel light-duty AFVs with their gasoline-fueled counterparts is examined to estimate percent emissions reductions achievable with CNG and LPG vehicles. Examples of calculated MOBILE5b emission rates that would be used for summer ozone season planning purposes by an individual Air Quality Control Region (AQCR) are provided. A method is suggested for employing these data to compute appropriate voluntary emission reduction credits where such (lighter) AFVs would be acquired. It also points out, but does not quantify, the substantial reduction credits potentially achievable by substituting gaseous-fueled for gasoline-fueled heavy-duty vehicles. Finally, it raises and expands on the relevance of AFVs and their deployment to some other provisions embedded in EPA`s current guidance for implementing 1-hour NAAQS--standards which currently remain in effect--as tools to provide immediate reductions in ozone, without waiting for promised future clean technologies.

  1. Energy Savings and NOx Emissions Reduction Potential from the 2012 Federal Legislation to Phase Out Incandescent Lamps in Texas

    E-Print Network [OSTI]

    Liu, Zi; Baltazar, Juan Carlos; Haberl, Jeff; Soman, Rohit

    296042501.6 100% Page 9 Table 5: Annual NOX Emissions A r ea Co u n t y A meri ca n E lec t r ic P o w er - W es t ( E RCO T ) /P CA NO x Redu ctio n s ( lbs) A u stin E n er g y /P CA NO x Redu ctio n s ( lbs) Brow n sv ille P u b... ort h E a s t T e x a s A re a Page 10 Table 6: Ozone Production Period NOx Emissions A r ea Co u n t y A meri ca n E lec t r ic P o w er - W es t ( E RCO T ) /P CA NO x Redu ctio n s ( lbs) A u stin E n er g y /P CA NO x Redu...

  2. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Energy Savers [EERE]

    CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel...

  3. Characterization of NOx Species in Dehydrated and Hydrated Na...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NOx Species in Dehydrated and Hydrated Na- and Ba-Y, FAU Zeolites Formed in NO Adsorption. Characterization of NOx Species in Dehydrated and Hydrated Na- and Ba-Y, FAU Zeolites...

  4. Model NOx storage systems: Storage capacity and thermal aging...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model NOx storage systems: Storage capacity and thermal aging of BaOtheta- Al2O3NiAl(100). Model NOx storage systems: Storage capacity and thermal aging of BaOtheta- Al2O3...

  5. Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air Cutting NOx from Diesel Engines with Membrane-Generated Nitrogen-Enriched Air 2005 Diesel Engine...

  6. Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-duty Engine in Conjunction with Ultra Low Sulfur Fuel (Presentation)

    SciTech Connect (OSTI)

    Thornton, M.; Tatur, M.; Tomazic, D.; Weber, P.; Webb, C.

    2005-08-25T23:59:59.000Z

    Discusses the full useful life exhaust emission performance of a NOx (nitrogen oxides) adsorber and diesel particle filter equipped light-duty and medium-duty engine using ultra low sulfur diesel fuel.

  7. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30T23:59:59.000Z

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  8. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

    2006-02-07T23:59:59.000Z

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  9. Modeling of NOx formation in circular laminar jet flames

    E-Print Network [OSTI]

    Siwatch, Vivek

    2007-04-25T23:59:59.000Z

    -premixed isolated circular laminar jet flame. The jet consists of the fuel rich inner region and the O2 rich outer region. The model estimates both thermal NOx and prompt NOx assuming single step kinetics for NOx formation and a thin flame model. Further the amount...

  10. Ozone (o3) efficacy on reduction of phytophthora capsici in recirculated horticultural irrigation water 

    E-Print Network [OSTI]

    McDonald, Garry Vernon

    2009-05-15T23:59:59.000Z

    Microorganisms that cause plant disease have been isolated in recirculated irrigation water and increase the risks of disease incidence in horticultural operations. Ozone is an effective oxidizer used to disinfect drinking water supplies and treat...

  11. Leadership in Low NOx/ Lochinvar Corporation 

    E-Print Network [OSTI]

    Sheko, D.; Boston, S.; Moore, J.

    2002-01-01T23:59:59.000Z

    Jlutant. The following several paragraphs will look closer at each of the criteria pollutants associated with gas combustion. Two of the criteria pollutants outlined by the EPA, ozone and particulate matter, are of concern in at least some portions of Texas.... These national ambient air quality standards established national levels for acceptable concentrations of six specific pol1utants related to outdoor air quality. These six pollutants are ground level ozone (Smog), particulate matter, lead, nitrogen dioxide...

  12. A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory

    SciTech Connect (OSTI)

    Ban-Weiss, G A; Chen, J Y; Buchholz, B A; Dibble, R W

    2007-01-30T23:59:59.000Z

    Biodiesel is a notable alternative to petroleum derived diesel fuel because it comes from natural domestic sources and thus reduces dependence on diminishing petroleum fuel from foreign sources, it likely lowers lifecycle greenhouse gas emissions, and it lowers an engine's emission of most pollutants as compared to petroleum derived diesel. However, the use of biodiesel often slightly increases a diesel engine's emission of smog forming nitrogen oxides (NO{sub x}) relative to petroleum diesel. In this paper, previously proposed theories for this slight NOx increase are reviewed, including theories based on biodiesel's cetane number, which leads to differing amounts of charge preheating, and theories based on the fuel's bulk modulus, which affects injection timing. This paper proposes an additional theory for the slight NO{sub x} increase of biodiesel. Biodiesel typically contains more double bonded molecules than petroleum derived diesel. These double bonded molecules have a slightly higher adiabatic flame temperature, which leads to the increase in NOx production for biodiesel. Our theory was verified using numerical simulations to show a NOx increase, due to the double bonded molecules, that is consistent with observation. Further, the details of these numerical simulations show that NOx is predominantly due to the Zeldovich mechanism.

  13. Thickness influence on surface morphology and ozone sensing properties of nanostructured ZnO transparent

    E-Print Network [OSTI]

    , 71004 Heraklion, Crete, Greece Available online 19 January 2006 Abstract Transparent zinc oxide (Zn Keywords: Zinc oxide; PLD; AFM; Ozone 1. Introduction Zinc oxide (ZnO) is an n-type semiconductor devices [3], varistors, planar optical waveguides [4], transparent electrodes [5,6], ultraviolet

  14. 5, 59575985, 2005 European ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract Introduction explain the trends in European ozone levels? J. E. Jonson 1 , D. Simpson 1 , H. Fagerli 1 , and S. Solberg License. 5957 #12;ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract

  15. 6, 56715709, 2006 Hemispheric ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page Chemistry and Physics Discussions Hemispheric ozone variability indices derived from satellite observations.erbertseder@dlr.de) 5671 #12;ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page

  16. 4, 32853332, 2004 Tropospheric ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 3285­3332, 2004 Tropospheric ozone over Equatorial Africa B. Sauvage et al. Title Page and Physics Discussions Tropospheric ozone over Equatorial Africa: regional aspects from the MOZAIC data B Correspondence to: B. Sauvage (saub@aero.obs-mip.fr) 3285 #12;ACPD 4, 3285­3332, 2004 Tropospheric ozone over

  17. 5, 38113845, 2005 Antarctic ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al. Title Page Discussions Indicators of Antarctic ozone depletion G. E. Bodeker 1 , H. Shiona 1 , and H. Eskes 2 1 National Commons License. 3811 #12;ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al

  18. Assimilation of Aura ozone data

    E-Print Network [OSTI]

    Assimilation of Aura ozone data I. Stajner, H. Hayashi, K. Wargan, L.-P. Chang, and S. Pawson Global Modeling and Assimilation Office (GMAO) NASA/Goddard AGU Fall meeting December 2004 #12;2 Ozone assimilation at GMAO · Total ozone columns and stratospheric profiles from SBUV/2 instrument are assimilated

  19. 2, 921942, 2002 Global ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 921­942, 2002 Global ozone forecasting H. J. Eskes et al. Title Page Abstract Introduction Geophysical Society 2002 Atmospheric Chemistry and Physics Discussions Global ozone forecasting based on ERS-2 July 2002 Correspondence to: H. J. Eskes (eskes@knmi.nl) 921 #12;ACPD 2, 921­942, 2002 Global ozone

  20. 6, 51375162, 2006 Oceanic ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W. Fairall et al. Title Page Abstract Discussions Water-side turbulence enhancement of ozone deposition to the ocean C. W. Fairall1 , D. Helmig2 , L. Fairall (chris.fairall@noaa.gov) 5137 #12;ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W

  1. Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity

    SciTech Connect (OSTI)

    Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

    2012-10-01T23:59:59.000Z

    Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

  2. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01T23:59:59.000Z

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  3. Ozone decomposition in water solutions 

    E-Print Network [OSTI]

    Hewes, Cecil Grayson

    1969-01-01T23:59:59.000Z

    OF LITERATUR 1V Vi ~ V111 III ~ EXPERIMENTAL SYSTEM AND ITS OPERATION 14 IV. DISCUSS10N OF RESULTS AND COiJCLUSION. . . 24 i~JOMENCLATUHE. BIBLIOGRAPIFY APPENDIX I. WASTE WATER REGENERATION BY OZONATION. II. AMINE REMOVAL BY OZONATION...ATER SOLUTIONS OF pH 8. XIII. REACTION RATE CONSTANTS FOR THE D'COMPOSITION OF OZONE IN INTER SOLUTIONS OF pH 8. XIV COD REMOVAL BY OZONE XV. OZONIZATION OF MATER CONTAINIiNG RESIDUAL AMINE. 57 60 LIST OF FIGURES FIGURE 1. FIOW DIAGRAM OF THZ...

  4. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

  5. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

    1999-01-01T23:59:59.000Z

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  6. N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone"

    E-Print Network [OSTI]

    Heller, Barbara

    as well. Images identified with "ozone" in the title are as follows: C187 Ozone Diagram C879 Lungs of two Toxicity Dr. Hans-Georg Clamann, physiologist C2346 Ozone Toxicity, M. King C2347 Ozone Toxicity, Pvt. D. F. Smith, Jr. Sgt. J. C. Rawdon C2348 Ozone Toxicity, S. Mittler, F. J. Hennigan C2349 Ozone Toxicity Pvt

  7. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Govt, Systems Integrator, Transportation, Tribal Government, Utility Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season...

  8. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut) These regulations may apply to fossil-fuel fired...

  9. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Utility Tax Credits, Rebates & Savings Tax Credits, Rebates & Savings Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season...

  10. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Govt Tax Credits, Rebates & Savings Tax Credits, Rebates & Savings Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season...

  11. HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS

    SciTech Connect (OSTI)

    Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

    2003-08-24T23:59:59.000Z

    Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

  12. New Houston NOx Rules: Implications and Solutions

    E-Print Network [OSTI]

    Cascone, R.

    Capex $MM NOx Reduction Tons/yr Net Cost NPV10 $MM Case 1 4 50 3.6 a. Defer 1 year 4.2 loss due to delay 0.6 b. Defer 2 years 5.4 loss due to delay 1.7 c. Defer 3 years 8.5 loss due to delay 4.8 Case 2 35 750 31.8 a. Defer 1 year 42...

  13. NOx sensor development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in Many Devils Wash, Shiprock,Departmentsensor development NOx sensor

  14. Solving the Tulsa ozone problem

    SciTech Connect (OSTI)

    Wagner, K.K. [Atmospheric Information Systems, Norman, OK (United States); Wilson, J.D. [Wilson Consulting Group, Tulsa, OK (United States); Gibeau, E. [Aeromet Inc., Tulsa, OK (United States)

    1998-12-31T23:59:59.000Z

    Local governments and interested parties in Tulsa, Oklahoma are planning actions to keep Tulsa in compliance with the ozone ambient air quality standard. Based on recent data Tulsa exceeds the new eight hour average national ambient air quality standard for ozone and occasionally exceeds the previous one hour standard. Currently, Tulsa is in attainment of the former one-hour ozone standard. The first planning step is to integrate the existing information about Tulsa`s ozone problem. Prior studies of Tulsa ozone are reviewed. Tulsa`s recent air quality and meteorological monitoring are evaluated. Emission inventory estimates are assessed. Factors identified with Tulsa`s ozone problem are the transport of ozone and precursor gases, a possible role for biogenic emissions, and a simplistic ozone forecasting method. The integration of information found that current air quality and meteorological monitoring is meager. Observations of volatile organic compounds and NO{sub y} are absent. Prior intensive studies in 1977 and 1985 are more than ten years old and lack relevance to today`s problem. Emission inventory estimates are scarce and uncertain. The current knowledge base was judged inadequate to properly characterize the present ozone problem. Actions are recommended to enlarge the information base to address Tulsa`s ozone problem.

  15. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    SciTech Connect (OSTI)

    Woo, L Y; Glass, R S

    2008-11-14T23:59:59.000Z

    Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

  16. Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel

    DOE Patents [OSTI]

    Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

    2012-11-20T23:59:59.000Z

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  17. Vortex combustor for low NOx emissions when burning lean premixed high hydrogen content fuel

    DOE Patents [OSTI]

    Steele, Robert C. (Woodinville, WA); Edmonds, Ryan G. (Renton, WA); Williams, Joseph T. (Kirkland, WA); Baldwin, Stephen P. (Winchester, MA)

    2009-10-20T23:59:59.000Z

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  18. 6, 66276694, 2006 linearized ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al. Title Chemistry and Physics Discussions CHEM2D-OPP: A new linearized gas-phase ozone photochemistry.mccormack@nrl.navy.mil) 6627 #12;ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al

  19. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts...

  20. NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

  1. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA:...

  2. Novel Application of Air Separation Membranes Reduces NOx Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    permeation of gases using an air separation membrane. Can be retrofitted to existing engines Significantly reduces NOx emissions (as much as 70%) with just a 2% nitrogen...

  3. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations

    Broader source: Energy.gov (indexed) [DOE]

    Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

  4. Durability Evaluation of an Integrated Diesel NOx Adsorber A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desulfurization Fuel Filter Development of NOx Adsorber System for Dodge Ram 2007 Heavy duty Pickup Truck Update on Diesel Exhaust Emission Control Technology and Regulations...

  5. Enhanced High and Low Temperature Performance of NOx Reduction...

    Energy Savers [EERE]

    High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

  6. Effect of reductive treatments on Pt behavior and NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    represent a promising approach to meet increasingly stringent NOx emission regulations on diesel and other lean-burn engines. Pt material properties, including dispersion and...

  7. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Annual Merit Review and Peer Evaluation ace026peden2011o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials...

  8. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting ace026peden2012o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High and Low...

  9. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    Dynamometer Evaluation of Plasma- Catalyst for Diesel NOx Reduction February 20, 2003 CRADA Protected Document and Data 2 Introduction * Engine dynamometer evaluation of...

  10. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Broader source: Energy.gov (indexed) [DOE]

    Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CumminsORNL-FEERC...

  11. Spatiotemporal Distribution of NOx Storage: a Factor Controlling...

    Broader source: Energy.gov (indexed) [DOE]

    LNT & SCR CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  12. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Plasma-Catalyst for Diesel NOx Reduction 2003 DEER Conference Presentation: Ford Motor Company 2003deerhoard.pdf More Documents & Publications Plasma Assisted Catalysis...

  13. Development on simultaneous reduction system of NOx and PM from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    system of NOx and PM from a diesel engine 2003 DEER Converence Presentation: Toyota Motor Corporation 2003deerwatanabe.pdf More Documents & Publications An Improvement of...

  14. aluminosilicates nox reduction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the CompuNOx system focus on a controls approach to minimize emissions without exposing steam generation plants to an unbearable financial burden. With minimal system changes we...

  15. Lean NOx Reduction with Dual Layer LNT/SCR Catalysts

    Broader source: Energy.gov (indexed) [DOE]

    emerging 2 NSRSCR Technology Goal: Reduce PGM & minimize fuel penalty in meeting NOx emission targets (adapted from Gandhi et al., US Patent, 2007) 3 Fundamental Issues for Dual...

  16. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Broader source: Energy.gov (indexed) [DOE]

    > Flexible tailoring capability ZnOABO 3 : No Chemical Interaction ZnO core + Shell Hollow Shell Sn Potential Multifunctional Nanocatalysts 4 1) Selective adsorptionstorage...

  17. Oxidation State Optimization for Maximum Efficiency of NOx Adsorber

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in ManyDepartmentOutreachDepartment ofProgram49, the Owens Corning

  18. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311,OfficialProducts |Catalysis of FuelLoan Portfolio |

  19. Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline...

  20. Combining Low-Temperature Combustion with Lean-NOx Trap Yields...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Combining Low-Temperature Combustion with Lean-NOx Trap Yields...

  1. NOx Uptake Mechanism on Pt/BaO/Al2O3 Catalysts. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Al2O3 Catalysts. NOx Uptake Mechanism on PtBaOAl2O3 Catalysts. Abstract: The NOx adsorption mechanism on PtBaOAl2O3 catalysts was investigated by performing NOx storage...

  2. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Suuberg; Eric Eddings; Larry Baxter

    2002-01-31T23:59:59.000Z

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.

  3. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26T23:59:59.000Z

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  4. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15T23:59:59.000Z

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  5. Evaluation of stratospheric NO2 retrieved from the Ozone Monitoring Instrument: Intercomparison, diurnal cycle,

    E-Print Network [OSTI]

    Boersma, Folkert

    [Intergovernmental Panel on Climate Change, 2007], influence the oxidizing capacity of the troposphere, and affect on the tem- poral behavior of NOx emissions. [3] Satellite remote sensing is used for measuring strato since the 1980s, e.g., SME (Solar Mesosphere Explorer) [Mount et al., 1984], which first used the DOAS

  6. Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts investigation of potential...

  7. Leadership in Low NOx/ Lochinvar Corporation

    E-Print Network [OSTI]

    Sheko, D.; Boston, S.; Moore, J.

    , Texas Nashville, Tennessee On April 19, 2000, the Texas Natural Resource Conservation Commission adopted statewide NOx emission limits for all natural gas-fired water heaters, boilers and process heaters with input rates of 2 million Btu/hr or less... for the purposes of generating efficient boilers, and process heaters having a BTU rating of up and environmentally friendly hot water production. to 2,000,000 BTU/hour within the state of Texas. Some readers of this paper may already be aware It's not everyday...

  8. Durability of NOx Absorbers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E TDrew Bittner About Us DrewDualLight-Duty2of NOx

  9. Two-stage Catalytic Reduction of NOx with Hydrocarbons

    SciTech Connect (OSTI)

    Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

    2005-12-21T23:59:59.000Z

    A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

  10. Photodissociation Dynamics of Halogen Oxide Species 

    E-Print Network [OSTI]

    Dooley, Kristin S.

    2010-07-14T23:59:59.000Z

    The focus of this dissertation is the study of the photodissociation dynamics of halogen oxide species (XO, X = Cl, Br, I). These radical species are known to be important in stratospheric and tropospheric ozone depletion ...

  11. NOx reduction by electron beam-produced nitrogen atom injection

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA)

    2002-01-01T23:59:59.000Z

    Deactivated atomic nitrogen generated by an electron beam from a gas stream containing more than 99% N.sub.2 is injected at low temperatures into an engine exhaust to reduce NOx emissions. High NOx reduction efficiency is achieved with compact electron beam devices without use of a catalyst.

  12. Passive Catalytic Approach to Low Temperature NOx Emission Abatement

    Broader source: Energy.gov (indexed) [DOE]

    ISF 2.8 during FTP-75 are too high for current state of the art NOx AT to meet T2B2 emission levels * Reduction in engine out NOx emissions from 2 gmi to 0.4 gmi allows for...

  13. Real-World Studies of Ambient Ozone Formation as a Function of NOx

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn April 23, 2014, an OHASeptember 2010In addition to 1Nationalcover_booked.inddReductions

  14. Selective catalytic reduction system and process for treating NOx emissions using a palladium and rhodium or ruthenium catalyst

    SciTech Connect (OSTI)

    Sobolevskiy, Anatoly (Orlando, FL); Rossin, Joseph A. (Columbus, OH); Knapke, Michael J. (Columbus, OH)

    2011-07-12T23:59:59.000Z

    A process for the catalytic reduction of nitrogen oxides (NOx) in a gas stream (29) in the presence of H.sub.2 is provided. The process comprises contacting the gas stream with a catalyst system (38) comprising zirconia-silica washcoat particles (41), a pre-sulfated zirconia binder (44), and a catalyst combination (40) comprising palladium and at least one of rhodium, ruthenium, or a mixture of ruthenium and rhodium.

  15. Multi-model assessment of stratospheric ozone return dates and ozone recovery in

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Multi- model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models of stratospheric ozone return dates and ozone recovery in CCMVal-2 models V. Eyring1, I. Cionni1, G. E. Bodeker2, A September 2010 ­ Published: 7 October 2010 Abstract. Projections of stratospheric ozone from a suite

  16. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  17. Ultra-Low NOx Advanced Vortex Combustor

    SciTech Connect (OSTI)

    Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

    2006-05-01T23:59:59.000Z

    An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

  18. ULTRA-LOW NOX ADVANCED VORTEX COMBUSTOR

    SciTech Connect (OSTI)

    Ryan G. Edmonds; Robert C. Steele; Joseph T. Williams; Douglas L. Straub; Kent H. Casleton; Avtar Bining

    2006-05-01T23:59:59.000Z

    An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

  19. Effects of Biodiesel on NOx Emissions

    SciTech Connect (OSTI)

    McCormick, R.

    2005-06-01T23:59:59.000Z

    A presentation about the effects of biodiesel on nitrogen oxide emissions presented at the ARB Biodiesel Workshop June 8, 2005.

  20. Investigation of Mixed Oxide Catalysts for NO Oxidation

    SciTech Connect (OSTI)

    Szanyi, Janos; Karim, Ayman M.; Pederson, Larry R.; Kwak, Ja Hun; Mei, Donghai; Tran, Diana N.; Herling, Darrell R.; Muntean, George G.; Peden, Charles HF; Howden, Ken; Qi, Gongshin; Li, Wei

    2014-12-09T23:59:59.000Z

    The oxidation of engine-generated NO to NO2 is an important step in the reduction of NOx in lean engine exhaust because NO2 is required for the performance of the LNT technology [2], and it enhances the activities of ammonia selective catalytic reduction (SCR) catalysts [1]. In particular, for SCR catalysts an NO:NO2 ratio of 1:1 is most effective for NOx reduction, whereas for LNT catalysts, NO must be oxidized to NO2 before adsorption on the storage components. However, NO2 typically constitutes less than 10% of NOx in lean exhaust, so catalytic oxidation of NO is essential. Platinum has been found to be especially active for NO oxidation, and is widely used in DOC and LNT catalysts. However, because of the high cost and poor thermal durability of Pt-based catalysts, there is substantial interest in the development of alternatives. The objective of this project, in collaboration with partner General Motors, is to develop mixed metal oxide catalysts for NO oxidation, enabling lower precious metal usage in emission control systems. [1] M. Koebel, G. Madia, and M. Elsener, Catalysis Today 73, 239 (2002). [2] C. H. Kim, G. S. Qi, K. Dahlberg, and W. Li, Science 327, 1624 (2010).

  1. Oceanic alkyl nitrates as a natural source of tropospheric ozone

    E-Print Network [OSTI]

    Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

    2008-01-01T23:59:59.000Z

    Chemical transport model ozone simulations for spring 2001ozonesondes, and Total Ozone Mapping Spectrometer columns,behaviour of tropospheric ozone precursors in a global 3-D

  2. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  3. Intercontinental Impacts of Ozone Pollution on Human Mortality

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    relationships for ozone pollution. J. Geophys. Res. 2009,benefits of mitigating ozone pollution with methane emissioninfluence of European pollution on ozone in the Near East

  4. Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    Part I: NO x , PAN and Ozone Relationships, J. Atmos.Bromine measurements in ozone depleted air over the Arcticto springtime tropospheric ozone maxima using TOPSE measure-

  5. Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants

    E-Print Network [OSTI]

    Frey, H. Christopher

    to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models for different source categories, NOx emissions from coal-fired power plants are analyzed in this #12;2 paper

  6. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  7. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  8. Indoor Secondary Pollutants from Household Product Emissions inthe Presence of Ozone: A Bench-Scale Chamber Study

    SciTech Connect (OSTI)

    Destaillats, Hugo; Lunden, Melissa M.; Singer, Brett C.; Coleman,Beverly K.; Hodgson, Alfred T.; Weschler, Charles J.; Nazaroff, William W.

    2005-10-01T23:59:59.000Z

    Ozone-driven chemistry is a major source of indoor secondary pollutants of health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields under most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of ultrafine particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10{sup 5} molecules cm{sup -3} were measured. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate test, we exposed the dry residue of two products to ozone in the chamber and observed the formation of gas-phase and particle-phase secondary oxidation products.

  9. Development of METHANE de-NOX Reburn Process for Wood Waste and Biomass Fired Stoker Boilers - Final Report - METHANE de-NOX Reburn Technology Manual

    SciTech Connect (OSTI)

    J. Rabovitser; B. Bryan; S. Wohadlo; S. Nester; J. Vaught; M. Tartan (Gas Technology Institute); R. Glickert (ESA Environmental Solutions)

    2007-12-31T23:59:59.000Z

    The overall objective of this project was to demonstrate the effectiveness of the METHANE de-NOX® (MdN) Reburn process in the Forest Products Industry (FPI) to provide more efficient use of wood and sludge waste (biosolids) combustion for both energy generation and emissions reduction (specifically from nitrogen oxides (NOx)) and to promote the transfer of the technology to the wide range of wood waste-fired stoker boilers populating the FPI. This document, MdN Reburn Commercial Technology Manual, was prepared to be a resource to promote technology transfer and commercialization activities of MdN in the industry and to assist potential users understand its application and installation requirements. The Manual includes a compilation of MdN commercial design data from four different stoker boiler designs that were baseline tested as part of the development effort. Design information in the Manual include boiler CFD model studies, process design protocols, engineering data sheets and commercial installation drawings. Each design package is unique and implemented in a manner to meet specific mill requirements.

  10. Nitrogen Isotopes as Indicators of NOx Source Contributions to

    E-Print Network [OSTI]

    Elliott, Emily M.

    of NOx are dominated by fossilfuelcombustion(63%)frombothstationary(e.g.,power plant electricity andassociatedatmosphericdepositionofnitrate(NO3 - )pose threats to global ecosystems and human health (2, 3). Contemporary global emissions

  11. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration Selectivity Towards N2O -- Similarities and Differences Between H2, CO and C3H6 Reductants Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and...

  12. Retrofit Diesel Emissions Control System Providing 50% NOxControl

    Broader source: Energy.gov (indexed) [DOE]

    Retrofit Diesel Emissions Control System Providing 50% NOx Control D. Yee, B. Adair, A. Boleda, B. Berry, T. Caron, J. Cizeron, T. Kinney, K. Lundberg and R. Dalla Betta Catalytica...

  13. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2015-01-01T23:59:59.000Z

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore »same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  14. Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements

    E-Print Network [OSTI]

    Keller, S. C.; Studniarz, J. J.

    AERODERIVATIVE GAS TURBINES CAN MEET STRINGENT NOx CONTROL REQUIREMENTS S. C. Keller, Manager Cogeneration Sales & Market Development General Electric Company Marine & Industrial Engines Cincinnati, Ohio ABSTRACT Gas Turbines operating... in the United States are required to meet federally mandated emission standards. This article will discuss how General Electric's 1M industrial aeroderivative gas turbines are meeting NOx requirements as low as 25 parts per ~tllion usi-ng steam injection...

  15. Air Pollution Control Regulations: No.27- Control of Nitrogen Oxide Emissions (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe...

  16. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    2014: Robust Nitrogen oxideAmmonia Sensors for Vehicle on-board Emissions Control CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  17. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends 

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16T23:59:59.000Z

    by themselves already require cleanup technology; newer regulations will require development of new and economical technologies. Using a blend of traditional fuels & biomass is a promising technology to reduce NOX emissions. Experiments conducted previously...

  18. Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

    SciTech Connect (OSTI)

    Harold, Michael; Crocker, Mark; Balakotaiah, Vemuri; Luss, Dan; Choi, Jae-Soon; Dearth, Mark; McCabe, Bob; Theis, Joe

    2013-09-30T23:59:59.000Z

    Oxides of nitrogen in the form of nitric oxide (NO) and nitrogen dioxide (NO{sub 2}) commonly referred to as NO{sub x}, is one of the two chemical precursors that lead to ground-level ozone, a ubiquitous air pollutant in urban areas. A major source of NO{sub x} is generated by equipment and vehicles powered by diesel engines, which have a combustion exhaust that contains NO{sub x} in the presence of excess O{sub 2}. Catalytic abatement measures that are effective for gasoline-fueled engines such as the precious metal containing three-way catalytic converter (TWC) cannot be used to treat O2-laden exhaust containing NO{sub x}. Two catalytic technologies that have emerged as effective for NO{sub x} abatement are NO{sub x} storage and reduction (NSR) and selective catalytic reduction (SCR). NSR is similar to TWC but requires much larger quantities of expensive precious metals and sophisticated periodic switching operation, while SCR requires an on-board source of ammonia which serves as the chemical reductant of the NO{sub x}. The fact that NSR produces ammonia as a byproduct while SCR requires ammonia to work has led to interest in combining the two together to avoid the need for the cumbersome ammonia generation system. In this project a comprehensive study was carried out of the fundamental aspects and application feasibility of combined NSR/SCR. The project team, which included university, industry, and national lab researchers, investigated the kinetics and mechanistic features of the underlying chemistry in the lean NOx trap (LNT) wherein NSR was carried out, with particular focus on identifying the operating conditions such as temperature and catalytic properties which lead to the production of ammonia in the LNT. The performance features of SCR on both model and commercial catalysts focused on the synergy between the LNT and SCR converters in terms of utilizing the upstream-generated ammonia and alternative reductants such as propylene, representing the hydrocarbon component of diesel exhaust. First-principle models of the LNT and SCR converters, which utilized the mechanistic-based kinetics and realistic treatments of the flow and transport processes, in combination with bench-scale reactor experiments helped to identify the best designs for combining the NSR and SCR catalysts over a range of operating conditions encountered in practice. This included catalysts having multiple zones and layers and additives with the focus on determining the minimal precious metal component needed to meet emission abatement targets over a wide range of operating conditions. The findings from this study provide diesel vehicle and catalyst companies valuable information to develop more cost effective diesel emissions catalysts which helps to expand the use of more fuel efficient diesel power. The fundamental modeling and experimental tools and findings from this project can be applied to catalyst technologies used in the energy and chemical industries. Finally, the project also led to training of several doctoral students who were placed in research jobs in industry and academia.

  19. ATOC 3500/CHEM 3151 Spring 2014 Stratospheric Ozone Destruction in the "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC 3500/CHEM 3151 Spring 2014 Problem 15 Stratospheric Ozone Destruction in the "Ozone Hole" The figure below shows typical observations of the total amount of ozone in a layer of air 8 km thick between 12 and 20 km over the South Pole (recall that we like to express the `thickness of ozone

  20. Ozone Reductions using Residential Building Envelopes

    E-Print Network [OSTI]

    Ozone Reductions using Residential Building Envelopes I.S. Walker, M.H. Sherman and W.W. Nazaroff or adequacy of the information in this report. #12;Arnold Schwarzenegger Governor Ozone Reductions Using

  1. Effects of a modular two-step ozone-water and annealing process on silicon carbide graphene

    SciTech Connect (OSTI)

    Webb, Matthew J., E-mail: matthew.webb@cantab.net; Lundstedt, Anna; Grennberg, Helena [Department of Chemistry—BMC, Uppsala University, Box 576, SE-751 23 Uppsala (Sweden); Polley, Craig; Niu, Yuran; Zakharov, Alexei A.; Balasubramanian, Thiagarajan [MAX IV Laboratory, Lund University, 22100 Lund (Sweden); Dirscherl, Kai [DFM—Danish Fundamental Metrology, Matematiktorvet 307, DK-2800 Lyngby (Denmark); Burwell, Gregory; Guy, Owen J. [College of Engineering, Faraday Tower, Singleton Park, Swansea University, Swansea SA2 8PP (United Kingdom); Palmgren, Pĺl [VG Scienta Scientific AB, Box 15120, Vallongatan 1, SE-750 15 Uppsala (Sweden); Yakimova, Rositsa [Department of Physics, Chemistry, and Biology, Linköping University, SE-581 83 Linköping (Sweden)

    2014-08-25T23:59:59.000Z

    By combining ozone and water, the effect of exposing epitaxial graphene on silicon carbide to an aggressive wet-chemical process has been evaluated after high temperature annealing in ultra high vacuum. The decomposition of ozone in water produces a number of oxidizing species, however, despite long exposure times to the aqueous-ozone environment, no graphene oxide was observed after the two-step process. The systems were comprehensively characterized before and after processing using Raman spectroscopy, core level photoemission spectroscopy, and angle resolved photoemission spectroscopy together with low energy electron diffraction, low energy electron microscopy, and atomic force microscopy. In spite of the chemical potential of the aqueous-ozone reaction environment, the graphene domains were largely unaffected raising the prospect of employing such simple chemical and annealing protocols to clean or prepare epitaxial graphene surfaces.

  2. Lean NOx Catalysis Research and Development

    Broader source: Energy.gov (indexed) [DOE]

    temperature range, poorly selective (N 2 O) Zeolites (ex. Cu-ZSM-5) active, selective hydro-thermally unstable Metal oxides (ex. AgAl 2 O 3 ) highly selective, stable,...

  3. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097­10129, 2007 Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Page Abstract Introduction

  4. 5, 243286, 2005 Retrieval of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 243­286, 2005 Retrieval of ozone column content during SOLVE II J. M. Livingston et al and Physics Discussions Retrieval of ozone column content from airborne Sun photometer measurements during Aerospace Center), Oberpfaffenhofen, Wessling, Germany 243 #12;ACPD 5, 243­286, 2005 Retrieval of ozone

  5. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  6. 6, 43254340, 2006 Scaling in ozone and

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title Chemistry and Physics Discussions Long-memory processes in global ozone and temperature variations C #12;ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title

  7. 7, 22492274, 2007 Vertical ozone over

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean and Central Europe P. D a Creative Commons License. Atmospheric Chemistry and Physics Discussions Vertical ozone measurements (kalabokas pavlos@yahoo.gr) 2249 #12;ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean

  8. 8, 31433162, 2008 Total ozone over

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 3143­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Chemistry and Physics Discussions Total column ozone variations over oceanic region around Indian sub­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Abstract Introduction

  9. 8, 50075060, 2008 Evaluation of ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 5007­5060, 2008 Evaluation of ozone trends from g-b FTIR observations C. Vigouroux et al.0 License. Atmospheric Chemistry and Physics Discussions Evaluation of tropospheric and stratospheric ozone Publications on behalf of the European Geosciences Union. 5007 #12;ACPD 8, 5007­5060, 2008 Evaluation of ozone

  10. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  11. 6, 84578483, 2006 Low ozone over the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 8457­8483, 2006 Low ozone over the UK M. Keil et al. Title Page Abstract Introduction Discussions The January 2006 low ozone event over the UK M. Keil, D. R. Jackson, and M. C. Hort Met Office 2006 Correspondence to: M. Keil (mike.keil@metoffice.gov.uk) 8457 #12;ACPD 6, 8457­8483, 2006 Low ozone

  12. 5, 96419668, 2005 The origin of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 9641­9668, 2005 The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions-5-9641 European Geosciences Union Atmospheric Chemistry and Physics Discussions The origin of ozone V. Grewe The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions References Tables Figures Back

  13. 6, 39133943, 2006 Svalbard total ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 3913­3943, 2006 Svalbard total ozone C. Vogler et al. Title Page Abstract Introduction Discussions Re-evaluation of the 1950­1962 total ozone record from Longyearbyen, Svalbard C. Vogler 1 , S. Br total ozone C. Vogler et al. Title Page Abstract Introduction Conclusions References Tables Figures Back

  14. 3, 187223, 2003 TOMS cloudy ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 3, 187­223, 2003 TOMS cloudy ozone anomaly X. Liu et al. Title Page Abstract Introduction Geosciences Union 2003 Atmospheric Chemistry and Physics Discussions Occurrence of ozone anomalies over cloudy 2003 Correspondence to: X. Liu (xliu@nsstc.uah.edu) 187 #12;ACPD 3, 187­223, 2003 TOMS cloudy ozone

  15. 3, 10811107, 2003 Mid-latitude ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 3, 1081­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page-dimensional model study of long-term mid-high latitude lower stratosphere ozone changes M. P. Chipperfield School­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page Abstract Introduction

  16. Ozone: Integrating Structured and Semistructured Data ?

    E-Print Network [OSTI]

    Abiteboul, Serge

    Ozone: Integrating Structured and Semistructured Data ? Tirthankar Lahiri 1 , Serge Abiteboul 2 language, and we implement our extensions in a system called Ozone. In our approach, structured data may full knowledge of structure. Ozone also enhances both ODMG/OQL and OEM/Lorel by virtue

  17. 4, 21672238, 2004 Ozone loss and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 2167­2238, 2004 Ozone loss and chlorine activation in the Arctic winters 1991­2003 S Union 2004 Atmospheric Chemistry and Physics Discussions Ozone loss and chlorine activation Correspondence to: S. Tilmes (simone.tilmes@t-online.de) 2167 #12;ACPD 4, 2167­2238, 2004 Ozone loss and chlorine

  18. Growth, physiology, and [delta] 13C of loblolly and shortleaf pine as affected by ozone and soil water deficit 

    E-Print Network [OSTI]

    Elsik, Christine Golemboski

    1992-01-01T23:59:59.000Z

    not only vitality of humans, animals, and plants, but also has an economic impact on agriculture and forestry. Air pollution has been shown to reduce agricultural crop and forest productivity. Ozone (0, ), a photochemical oxidant produced by a series.... 4 to 90 days. As an air mass containing 0, and its precursors moves, there is continued addition of pollutants I'rom new sources, so that 0, is continuously being produced and consumed during transport (Heck 1984). EFFECTS OF OZONE ON TREE...

  19. Microarray-based analysis of survival of soil microbial community during ozonation

    SciTech Connect (OSTI)

    Wang, Jian; Van Nostrand, Joy D.; He, Zhili; Wu, Liyou; Deng, Ye; Zhang, Xu; Zhou, Jizhong; Li, Guanghe

    2010-05-17T23:59:59.000Z

    A 15 h ozonation was performed on bioremediated soil to remove recalcitrant residual oil. To monitor the survival of indigenous microorganisms in the soil during in-situ chemical oxidation(ISCO) culturing and a functional genearray, GeoChip, was used to examine the functional genes and structure of the microbial community during ozonation (0h, 2h, 4h, 6h, 10hand15h). Breakthrough ozonation decreased the population of cultivable heterotrophic bacteria by about 3 orders of magnitude. The total functional gene abundance and diversity decreased during ozonation, as the number of functional genes was reduced by 48percent after 15 h. However, functional genes were evenly distributed during ozonation as judged by the Shannon-Weaver Evenness index. A sharp decrease in gene number was observed in the first 6 h of ozonation followed by a slower decrease in the next 9 h, which was consistent with microbial populations measured by a culture based method. Functional genes involved in carbon, nitrogen, phosphors and sulfur cycling, metal resistance and organic remediation were detected in all samples. Though the pattern of gene categories detected was similar for all time points, hierarchica lcluster of all functional genes and major functional categories all showed a time-serial pattern. Bacteria, archaea and fungi decreased by 96.1percent, 95.1percent and 91.3percent, respectively, after 15 h ozonation. Delta proteobacteria, which were reduced by 94.3percent, showed the highest resistance to ozonation while Actinobacteria, reduced by 96.3percent, showed the lowest resistance. Microorganisms similar to Rhodothermus, Obesumbacterium, Staphylothermus, Gluconobacter, and Enterococcus were dominant at all time points. Functional genes related to petroleum degradation decreased 1~;;2 orders of magnitude. Most of the key functional genes were still detected after ozonation, allowing a rapid recovery of the microbial community after ozonation. While ozone had a large impact on the indigenous soil microorganisms, a fraction of the key functional gene-containing microorganisms survived during ozonation and kept the community functional.

  20. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01T23:59:59.000Z

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  1. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst Study of effects of hydrocarbons on ammonia storage...

  2. Climate impact of aviation NOx? emissions : radiative forcing, temperature, and temporal heterogeneity

    E-Print Network [OSTI]

    Wong, Lawrence Man Kit

    2014-01-01T23:59:59.000Z

    Aviation NOx emissions are byproducts of combustion in the presence of molecular nitrogen. In the upper troposphere, NOx emissions result in the formation of O? but also reduce the lifetime of CH4 , causing an indirect ...

  3. Safe and compact ammonia storage/delivery systems for SCR-DeNOX...

    Energy Savers [EERE]

    Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

  4. Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel and EGR for Low-Temperature NOx and PM Reductions Combining Biodiesel and EGR for Low-Temperature NOx and PM Reductions Poster presentation at the 2007 Diesel...

  5. Development of a Stand-Alone Urea-SCR System for NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea...

  6. Effect of Engine-Out NOx Control Strategies on PM Size Distribution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in...

  7. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Abstract: Multiple catalytic functions...

  8. Water-induced morphology changes in BaO/?-Al2O3 NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials. Water-induced morphology changes in BaO?-Al2O3 NOx storage materials. Abstract: Exposure of NO2-saturated BaO?-Al2O3 NOx storage materials to H2O vapour...

  9. A Computational Approach to Understanding Aerosol Formation and Oxidant Chemistry in the Troposphere

    SciTech Connect (OSTI)

    Francisco, Joseph S.; Kathmann, Shawn M.; Schenter, Gregory K.; Dang, Liem X.; Xantheas, Sotiris S.; Garrett, Bruce C.; Du, Shiyu; Dixon, David A.; Bianco, Roberto; Wang, Shuzhi; Hynes, James T.; Morita, Akihiro; Peterson, Kirk A.

    2006-04-18T23:59:59.000Z

    An understanding of the mechanisms and kinetics of aerosol formation and ozone production in the troposphere is currently a high priority because these phenomena are recognized as two major effects of energy-related air pollution. Atmospheric aerosols are of concern because of their effect on visibility, climate, and human health. Equally important, aerosols can change the chemistry of the atmosphere, in dramatic fashion, by providing new chemical pathways (in the condensed phase) unavailable in the gas phase. The oxidation of volatile organic compounds (VOCs) and inorganic compounds (e.g., sulfuric acid, ammonia, nitric acid, ions, and mineral) can produce precursor molecules that act as nucleation seeds. The U.S. Department of Energy (DOE) Atmospheric Chemistry Program (ACP) has identified the need to evaluate the causes of variations in tropospheric aerosol chemical composition and concentrations, including determining the sources of aerosol particles and the fraction of such that are of primary and secondary origin. In particular, the ACP has called for a deeper understanding into aerosol formation because nucleation creates substantial concentrations of fresh particles that, via growth and coagulation, influence the Earth's radiation budget. Tropospheric ozone is also of concern primarily because of its impact on human health. Ozone levels are controlled by NOx and by VOCs in the lower troposphere. The VOCs can be either from natural emissions from such sources as vegetation and phytoplankton or from anthropogenic sources such as automobiles and oil-fueled power production plants. The major oxidant for VOCs in the atmosphere is the OH radical. With the increase in VOC emissions, there is rising concern regarding the available abundance of HOx species needed to initiate oxidation. Over the last five years, there have been four field studies aimed at initial measurements of HOx species (OH and HO? radicals). These measurements revealed HOx levels that are two to four times higher than expected from the commonly assumed primary sources. Such elevated abundances of HOx imply a more photochemically active troposphere than previously thought. This implies that rates of ozone formation in the lower region of the atmosphere and the oxidation of SO? can be enhanced, thus promoting the formation of new aerosol properties. Central to unraveling this chemistry is the ability to assess the photochemical product distributions resulting from the photodissociation of by-products of VOC oxidation. We propose to use state-of-the-art theoretical techniques to develop a detailed understanding of the mechanisms of aerosol formation in multicomponent (mixed chemical) systems and the photochemistry of atmospheric organic species. The aerosol studies involve an approach that determines homogeneous gas-particle nucleation rates from knowledge of the molecular interactions that are used to define properties of molecular clusters. Over the past several years we developed Dynamical Nucleation Theory (DNT), a novel advance in the theoretical description of homogeneous gas-liquid nucleation, and applied it to gas-liquid nucleation of a single component system (e.g., water). The goal of the present research is to build upon these advances by extending the theory to multicomponent systems important in the atmosphere (such as clusters containing sulfuric acid, water, ions, ammonia, and organics). In addition, high-level ab initio electronic structure calculations will be used to unravel the chemical reactivity of the OH radical and water clusters.

  10. 2, 15091543, 2002 Ozone production

    E-Print Network [OSTI]

    Boyer, Edmond

    .atmos-chem-phys.org/acpd/2/1509/ c European Geosciences Union 2002 Atmospheric Chemistry and Physics Discussions Ozone as a consequence of local catabatic winds. Aver- age mid-day peroxy radical concentrations at Mt. Cimone; Atlas and Ridley, 1996; Fischer et al., 1998; Zanis et al., 2000a, b). Often, free tropospheric

  11. Method of removing nitrogen oxides from exhaust gas mixtures

    SciTech Connect (OSTI)

    Batha, H.D.; Mason, J.H.; Thompson, S.R.

    1980-03-04T23:59:59.000Z

    A method of removing nitrogen oxides (NOX) from exhaust gas mixtures is described. The removal of NOX from exhaust gas mixtures is accomplished by exposing the exhaust gas mixture, in a manner that does not substantially impede the gas flow, to a ceramic material containing from about 75% to about 95% by weight silicon carbide and from about 0.3% to about 10.0% silica. A reduction of at least 85% of NOX from the mixture is to be expected and reductions up to 95 to 100% are attainable. Ceramic mixtures containing silicon nitride in amounts between about 10% and about 30% are found to reduce the amount of NOX in exhaust gases at temperatures as low as 200* C.

  12. Characteristics of Pt-K/MgAl2O4 lean NOx trap catalysts. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pt-KMgAl2O4 lean NOx trap catalysts. Characteristics of Pt-KMgAl2O4 lean NOx trap catalysts. Abstract: We report the various characteristics of Pt-KMgAl2O4 lean NOx trap (LNT)...

  13. Asian emissions of CO and NOx: Constraints from aircraft and Chinese station data

    E-Print Network [OSTI]

    Palmer, Paul

    Asian emissions of CO and NOx: Constraints from aircraft and Chinese station data Yuxuan X. Wang to constrain estimates of Asian emissions of CO and NOx. A priori emissions are based on a detailed bottom emissions of CO and NOx, respectively, distributed heterogeneously, with the largest adjustments required

  14. Small, Inexpensive Combined NOx and O2 Sensor

    SciTech Connect (OSTI)

    W. Lawless; C. Clark

    2008-09-01T23:59:59.000Z

    It has been successfully demonstrated in this program that a zirconia multilayer structure with rhodium-based porous electrodes performs well as an amperometric NO{sub x} sensor. The sensitivity of the sensor bodies operating at 650 to 700 C is large, with demonstrated current outputs of 14 mA at 500 ppm NO{sub x} from sensors with 30 layers. The sensor bodies are small (4.5 x 4.2 x 3.1 mm), rugged, and inexpensive. It is projected the sensor bodies will cost $5-$10 in production. This program has built on another successful development program for an oxygen sensor based on the same principles and sponsored by DOE. This oxygen sensor is not sensitive to NO{sub x}. A significant technical hurdle has been identified and solved. It was found that the 100% Rh electrodes oxidize rapidly at the preferred operating temperatures of 650-700 C, and this oxidation is accompanied by a volume change which delaminates the sensors. The problem was solved by using alloys of Rh and Pt. It was found that a 10%/90% Rh/Pt alloy dropped the oxidation rate of the electrodes by orders of magnitude without degrading the NO{sub x} sensitivity of the sensors, allowing long-term stable operation at the preferred operating temperatures. Degradation in the sensor output caused by temperature cycling was identified as a change in resistance at the junction between the sensor body and the external leads attached to the sensor body. The degradation was eliminated by providing strong mechanical anchors for the wire and processing the junctions to obtain good electrical bonds. The NO{sub x} sensors also detect oxygen and therefore the fully-packaged sensor needs to be enclosed with an oxygen sensor in a small, heated zirconia chamber exposed to test gas through a diffusion plug which limits the flow of gas from the outside. Oxygen is pumped from the interior of the chamber to lower the oxygen content and the combination of measurements from the NO{sub x} and oxygen sensors yields the NO{sub x} content of the gas. Two types of electronic control units were designed and built. One control unit provides independent constant voltages to the NOx and oxygen sensors and reads the current from them (that is, detects the amount of test gas present). The second controller holds the fully-assembled sensor at the desired operating temperature and controllably pumps excess oxygen from the test chamber. While the development of the sensor body was a complete success, the development of the packaging was only partially successful. All of the basic principles were demonstrated, but the packaging was too complex to optimize the operation within the resources of the program. Thus, no fully-assembled sensors were sent to outside labs for testing of cross-sensitivities, response times, etc. Near the end of the program, Sensata Technologies of Attleboro, MA tested the sensor bodies and confirmed the CeramPhysics measurements as indicated in the following attached letter. Sensata was in the process of designing their own packaging for the sensor and performing cross-sensitivity tests when they stopped all sensor development work due to the automotive industry downturn. Recently Ceramatec Inc. of Salt Lake City has expressed an interest in testing the sensor, and other licensing opportunities are being pursued.

  15. The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone

    E-Print Network [OSTI]

    Dominici, Francesca

    The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone for Ozone and Risk of Mortality and the Adequacy of Current Ozone Regulations Michelle L. Bell,1 Roger D.432.3817 E-mail: michelle.bell@yale.edu 1 #12;Running Title: Ozone and mortality: exposure

  16. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15T23:59:59.000Z

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  17. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    Jan de Leeuw; Shuojun Wang

    2011-01-01T23:59:59.000Z

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  18. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    de Leeuw, Jan; Wang, Shuojun

    2007-01-01T23:59:59.000Z

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  19. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01T23:59:59.000Z

    carbon filters for the control of ozone, sulfur dioxide, andMendell (2008). "Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  20. oZONE Faculty and Staff Enrolling Students

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Enrolling Students Log in to ozone.ou.edu. Click the Advising tab. Please lecture schedule CRN ­ Course Reference Number In oZONE the Registration Add Errors will display one

  1. Improving ozone profile retrieval from spaceborne UV backscatter

    E-Print Network [OSTI]

    Haak, Hein

    Chapter 2 Improving ozone profile retrieval from spaceborne UV backscatter spectrometers using convergence behaviour diagnostics Abstract The Ozone Profile Algorithm (OPERA), developed at KNMI, retrieves the vertical ozone distribution from nadir spectral satellite measurements of back scattered sunlight

  2. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01T23:59:59.000Z

    particles produced by ozone/limonene reactions in indoor airgas-phase reactions of ozone with organic compounds underNazaroff, W.W. , 2008. Ozone levels in passenger cabins of

  3. Elementary Steps and Site Requirements for NOx Adsorption and Oxidation on Metal and Oxide Surfaces

    E-Print Network [OSTI]

    Weiss, Brian M.

    2010-01-01T23:59:59.000Z

    s -1 in flowing dry air (Praxair, extra dry, 1 cm 3 s -1 g -heated in flowing dry air (Praxair, extra dry, 1 cm 3 s -1to 723 K in flowing dry air (Praxair, extra dry, 1 cm 3 s -1

  4. Alumina catalysts for reduction of NOx from methanol fueled diesel engine

    SciTech Connect (OSTI)

    Yamamoto, Toshiro; Noda, Akira; Sakamoto, Takashi; Sato, Yoshio [Ministry of Transport of Japan, Kumamoto (Japan)

    1996-09-01T23:59:59.000Z

    NOx selective reducing catalysts are expected to be used for lean-burn gasoline engines and diesel engines as an effective NOx reduction measure. The authors are interested in the combination of methanol, as a reducing agent, and alumina catalyst, and have considered the NOx reduction method using effectively much unburned methanol. In this report, in order to investigate the effect of NOx reduction by the alumina catalyst, the experiment was carried out by feeding the actual exhaust gas from the methanol engine into the alumina catalyst. As a result, it was confirmed that, without addition of any other reducing agents into the exhaust gas, the alumina catalyst has activity to reduce NOx.

  5. Simultaneous Removal of Particulates and NOx Using Catalyst Impregnated Fibrous Ceramic Filters

    SciTech Connect (OSTI)

    Choi, J.I.; Mun, S.H.; Kim, S.T.; Hong, M.S.; Lee, J.C.

    2002-09-19T23:59:59.000Z

    The research is focused on the development and commercialization of high efficiency, cost effective air pollution control system, which can replace in part air pollution control devices currently in use. In many industrial processes, hot exhaust gases are cooled down to recover heat and to remove air pollutants in exhaust gases. Conventional air pollution control devices such as bag filters, E.P. and adsorption towers withstand operating temperatures up to 300 C. Also, reheating is sometimes necessary to meet temperature windows for S.C.R. Since Oxidation reactions of acid gases such as SO{sub 2}, and HCl with lime are enhanced at high temperatures, catalyst impregnated ceramic filters can be candidate for efficient and cost effective air pollution control devices. As shown on Fig. 1., catalytic ceramic filters remove particulates on exterior surface of filters and acid gases are oxidized to salts reacting with limes injected in upstream ducts. Oxidation reactions are enhanced in the cake formed on exterior of filters. Finally, injected reducing gas such as NH{sub 3} react with NOx to form N{sub 2} and H{sub 2}O interior of filters in particulate-free environment. Operation and maintenance technology is similar to conventional bag filters except that systems are exposed to relatively high temperatures ranging 300-500 C.

  6. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  7. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01T23:59:59.000Z

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  8. The NOx system in nuclear waste. 1997 annual progress report

    SciTech Connect (OSTI)

    Meisel, D. [Argonne National Lab., IL (US). Chemistry Div.; Camaioni, D.; Orlando, T. [Pacific Northwest National Lab., Richland, WA (US)

    1997-01-01T23:59:59.000Z

    'The authors highlight their results from the title project. The project is a coordinated effort of the three Co-PIs to assist the Safety Programs at the Hanford and other DOE Environmental Management Sites. The authors present in the report their observations and interactively discuss their implications for safety concerns. They focus on three issues: (1) Reducing radicals in the NOx system The authors show that the only reducing radical that lasts longer than a few ns in typical waste solutions, and is capable of generating hydrogen, is NO{sub 3}{sup 2-}. The authors measured the lifetime of this species across the whole pH range (3 {le} pH {le} 14) and found it to be shorter than -15 \\265s, before it dissociates to give the strongly oxidizing NO, radicals. They found that it reacts with many proton donors (H{sup +}, phosphate, borate, NH{prime}, amines) in a reaction that is not merely an acid-base equilibrium reaction but is probably a dissociative proton transfer. They estimate the redox potential from theoretical considerations and obtain an experimental verification. They conclude that it is highly unlikely, although thermodynamically possible, that this radi-cal will generate hydrogen in waste solutions. (2) Aging of organic chelators and their degradation products by NO, Methodologies to study the degradation of organic substrates (including the important waste components, formate and oxalate) to CO;, or carbonate, by NO, were developed. This radical dimerizes and disproportionates to nitrate and nitrite. Therefore, mineraliza-tion of the organic substrates competes with the disproportionation of NO,. Among the organic substrates, formate and oxalate are also mineralized but because they are of low fuel value their mineralization is not very helpful, yet it consumes NO,. (3) Interfacial processes in aqueous suspensions Yields of charge transfer from solid silica particles to water and other liquids were meas-ured. If the particles are small enough, essentially all of the charge that is originally depos-ited in the solid escapes into the liquid. This implies that the solid/liquid interface does not provide a significant barrier to the transfer of charges into the solution when the particles are very small (I 20 nm). Electrons may reach the liquid and generate hydrogen, for example. On the other hand, the same mechanism may also provide a pathway for oxidative aging of organics by holes even when the organic is dissolved in the liquid or adsorbed on the solid surface. The authors have started to study reactions of NO,. Methodology and instrumentation to measure reactions of relevant organic radicals with NO, and with its parent NO, were developed. Because of low extinction coefficients, conductivity will be the method of choice.'

  9. Y-12 Plant Stratospheric Ozone Protection plan

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The Y-12 Plant staff is required by Lockheed Martin Energy Systems (Energy Systems) (formerly Martin Marietta Energy Systems) standard ESS-EP-129 to develop and implement a Stratospheric Ozone Protection Program which will minimize emissions of ozone-depleting substances to the environment and maximize the use of ozone-safe alternatives in order to comply with Title VI of the 1990 Clean Air Act (CAA) Amendments and the implementing regulations promulgated by the Environmental Protection Agency (EPA). This plan describes the requirements, initiatives, and accomplishments of the Y-12 Plant Stratospheric Ozone Protection Program.

  10. Tropospheric Ozone Pollution and Personal Exposure

    E-Print Network [OSTI]

    Toohey, Darin W.

    ://www.nctcog.org/trans/air/ozone/formation.gif #12;Health Effects · Chest pain, coughing, throat irritation, and congestion · Wheezing and difficulty

  11. The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination

    E-Print Network [OSTI]

    Thompson, Anne

    iii ABSTRACT The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination with other instruments tropospheric ozone residual (TOR) can be derived. In this study, the trajectory

  12. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Energy Savers [EERE]

    DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

  13. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Office of Environmental Management (EM)

    More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

  14. atmospheric ozone increases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    polar vortex and its changes for GHGs increase and ozone depletion and possible feedback of the stratospheric polar vortex to changes in GHGs and ozone, as simulated by...

  15. 5, 90039038, 2005 Ozone in Europe

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in the at- mospheric boundary layer, a low total ozone column and a reduced cloud cover, all favouring ozone 2003. In this paper we5 argue that a number of positive feedback effects between the weather conditions as the increased temperature and solar radiation indicate that biogenic emissions in Europe were increased during

  16. COST-EFFECTIVE CONTROL OF NOx WITH INTEGRATED ULTRA LOW-NOx BURNERS AND SNCR

    SciTech Connect (OSTI)

    Hamid Farzan

    2001-07-01T23:59:59.000Z

    Coal-fired electric utilities are facing a serious challenge with regards to curbing their NO{sub x} emissions. At issue are the NO{sub x} contributions to the acid rain, ground level ozone, and particulate matter formation. Substantial NO{sub x} control requirements could be imposed under the proposed Ozone Transport Rule, National Ambient Air Quality Standards, and New Source Performance Standards. McDermott Technology, Inc. (MTI), Babcock and Wilcox (B and W), and Fuel Tech are teaming to provide an integrated solution for NO{sub x} control. The system will be comprised of an ultra low-NO{sub x} pulverized coal (PC) burner technology plus a urea-based, selective non-catalytic reduction (SNCR) system. This system will be capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu and target ammonia (NH3) slip level targeted below 5 ppmV for commercial units. Our approach combines the best available combustion and post-combustion NO{sub x} control technologies. More specifically, B and W's DRB-4Z TM ultra low-NO{sub x} PC burner technology will be combined with Fuel Tech's NO{sub x}OUT (SNCR) and NO{sub x}OUT Cascade (SNCR/SCR hybrid) systems and jointly evaluated and optimized in a state-of-the-art test facility at MTI. Although the NO{sub x}OUT Cascade (SNCR/SCR hybrid) system will not be tested directly in this program, its potential application for situations that require greater NO{sub x} reductions will be inferred from other measurements (i.e., SNCR NO{sub x} removal efficiency plus projected NO{sub x} reduction by the catalyst based on controlled ammonia slip). Our analysis shows that the integrated ultra low-NO{sub x} burner and SNCR system has the lowest cost when the burner emissions are 0.25 lb NO{sub x}/10{sup 6} Btu or less. At burner NO{sub x} emission level of 0.20 lb NO{sub x}/10{sup 6} Btu, the levelized cost per ton of NO{sub x} removed is 52% lower than the SCR cost.

  17. SELECTIVE REDUCTION OF NOX IN OXYGEN RICH ENVIRONMENTS WITH PLASMA-ASSISTED CATALYSIS: CATALYST DEVELOPMENT AND MECHANISTIC STUDIES

    SciTech Connect (OSTI)

    Peden, C; Barlow, S; Hoard, J; Kwak, J; *Balmer-Millar, M; *Panov, A; Schmieg, S; Szanyi, J; Tonkyn, R

    2003-08-24T23:59:59.000Z

    The control of NOx (NO and NO2) emissions from so-called ''lean-burn'' vehicle engines remains a challenge. In recent years, there have been a number of reports that show that a plasma device combined with a catalyst can reduce as high as 90% or more of NOx in simulated diesel and other ''lean-burn'' exhaust. In the case of propylene containing simulated diesel exhaust, the beneficial role of a plasma treatment is now thought to be due to oxidation of NO to NO2, and the formation of partially oxidized hydrocarbons that are more active for the catalytic reduction of NO2 than propylene. Thus, the overall system can be most usefully described as hydrocarbon selective catalytic reduction (SCR) enhanced by 'reforming' the exhaust with a non-thermal plasma (NTP) device. For plasma-enhanced catalysis, both zeolite- and alumina-based materials have shown high activity, albeit in somewhat different temperature ranges, when preceded by an NTP reactor. This paper will briefly describe our research efforts aimed at optimizing the catalyst materials for NTP-catalysis devices based, in part, on our continuing studies of the NTP- and catalytic-reaction mechanisms. Various alkali- and alkaline earth-cation-exchanged Y zeolites have been prepared, their material properties characterized, and they have been tested as catalytic materials for NOx reduction in laboratory NTP-catalysis reactors. Interestingly, NO2 formed in the plasma and not subsequently removed over these catalysts, will back-convert to NO, albeit to varying extents depending upon the nature of the cation. Besides this comparative reactivity, we will also discuss selected synthesis strategies for enhancing the performance of these zeolite-based catalyst materials. A particularly important result from our mechanistic studies is the observation that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, acetaldehyde has been found to be especially effective in the thermal reduction of both NO and NO2 over Ba- and Na-Y zeolite catalysts.

  18. Catalysis of Reduction and Oxidation Reactions for Application in Gas Particle Filters

    SciTech Connect (OSTI)

    Udron, L.; Turek, T.

    2002-09-19T23:59:59.000Z

    The present study is a first part of an investigation addressing the simultaneous occurrence of oxidation and reduction reactions in catalytic filters. It has the objectives (a) to assess the state of knowledge regarding suitable (types of) catalysts for reduction and oxidation, (b) to collect and analyze published information about reaction rates of both NOx reduction and VOC oxidation, and (c) to adjust a lab-scale screening method to the requirements of an activity test with various oxidation/reduction catalysts.

  19. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Michael J. Bockelie

    2000-10-31T23:59:59.000Z

    This report summarizes the research that has been performed by Reaction Engineering International (REI) during the last three months on demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last six months have been on: (1) Field Tests for RRI at the Conectiv BL England Station Unit No.1, a 130 MW cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for Rich Reagent Injection (RRI) in cyclone fired boilers; (3) Applying the NOx model to evaluate RRI systems integrated into a boiler with Over Fired Air (OFA) and Selective Non-Catalytic Reduction (SNCR); (4) Field Tests of the REI Corrosion Probe at the Conectiv BL England Station Unit No.1; (5) Commence engineering study of ammonia adsorption mechanisms for Fly Ash; (6) Presentation of current program accomplishments and plans for future work to DoE staff members at NETL-FE (Pittsburgh); and (7) Presentation of preliminary field test results for RRI to EPRI CNCIG.

  20. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction

    SciTech Connect (OSTI)

    Schmieg, Steven J.; Oh, Se H.; Kim, Chang H.; Brown, David B.; Lee, Jong H.; Peden, Charles HF; Kim, Do Heui

    2012-04-30T23:59:59.000Z

    Multiple catalytic functions (NOx conversion, NO and NH3 oxidation, NH3 storage) of a commercial Cu-zeolite urea/NH3-SCR catalyst were assessed in a laboratory fixed-bed flow reactor system after differing degrees of hydrothermal aging. Catalysts were characterized by using x-ray diffraction (XRD), 27Al solid state nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM) / energy dispersive X-ray (EDX) spectroscopy to develop an understanding of the degradation mechanisms during catalyst aging. The catalytic reaction measurements of laboratory-aged catalysts were performed, which allows us to obtain a universal curve for predicting the degree of catalyst performance deterioration as a function of time at each aging temperature. Results show that as the aging temperature becomes higher, the zeolite structure collapses in a shorter period of time after an induction period. The decrease in SCR performance was explained by zeolite structure destruction and/or Cu agglomeration, as detected by XRD/27Al NMR and by TEM/EDX, respectively. Destruction of the zeolite structure and agglomeration of the active phase also results in a decrease in the NO/NH3 oxidation activity and the NH3 storage capacity of the catalyst. Selected laboratory aging conditions (16 h at 800oC) compare well with a 135,000 mile vehicle-aged catalyst for both performance and characterization criteria.

  1. INFLUENCE OF EGR COMPOUNDS ON THE OXIDATION OF AN HCCI-DIESEL SURROGATE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    INFLUENCE OF EGR COMPOUNDS ON THE OXIDATION OF AN HCCI-DIESEL SURROGATE J.M. ANDERLOHR*1,3 , A oxides (NOx), while the principle of CI assures a high efficiency close to that of a diesel engine comprehensively assessed [4]. A n-heptane/toluene mixture was used as a diesel surrogate with n-heptane having

  2. Summertime total ozone variations over middle and polar latitudes

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Summertime total ozone variations over middle and polar latitudes 1234567 89A64BC7DEF72B4 467342 $7D425BE27B725CE9393BE647 #12;Summertime total ozone variations over middle and polar latitudes and summertime ozone over middle and polar latitudes is analyzed using zonally averaged total ozone data. Short

  3. Ozone Depletion 2. O 3 generation and depletion

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion Outline: 1. O 3 , O 2 evolution 2. O 3 generation and depletion 3. Antarctic ozone 2 converted to ozone via: O 2 h#23; ! 2O #3; O #3; +O 2 ! O 3 + heat #15; O 3 absorbs near #21;#1;l #15; Decreasing l increases transmittance Imagine all ozone in atmosphere forming a thin layer

  4. Tropospheric Ozone Satellite Retrievals in the Pacific Northwest

    E-Print Network [OSTI]

    Collins, Gary S.

    Tropospheric Ozone Satellite Retrievals in the Pacific Northwest Jacqueline Costello1, Farren: Tropospheric ozone is difficult to retrieve from satellites because of the abundance of ozone in the stratosphere. Tropospheric ozone has become a significant environmental issue and can be exacerbated by UT

  5. Speeding up Ozone Profile Retrieval using Machine Learning Techniques

    E-Print Network [OSTI]

    Emmerich, Michael

    Speeding up Ozone Profile Retrieval using Machine Learning Techniques L.M. Strijbosch April 25 to the process of ozone profile retrieval, a method for retrieving a global ozone distribution from satellite Machines are selected to replace the forward model, which is the slowest part of ozone profile retrieval

  6. Effects of stratospheretroposphere chemistry coupling on tropospheric ozone

    E-Print Network [OSTI]

    Effects of stratospheretroposphere chemistry coupling on tropospheric ozone Wenshou Tian,1,2 Martyn in both the troposphere and stratosphere. The modeled total column ozone agrees well with Total Ozone Mapping Spectrometer observations. Modeled ozone profiles in the upper troposphere and lower stratosphere

  7. Atmospheric ozone and colors of the Antarctic twilight sky

    E-Print Network [OSTI]

    Lee Jr., Raymond L.

    Atmospheric ozone and colors of the Antarctic twilight sky Raymond L. Lee, Jr.,1, * Wolfgang Meyer absorption at longer wavelengths by ozone's Chappuis bands. Because stratospheric ozone is greatly depleted correlations between ozone concentration and twilight colors. We also used a spectroradiometer at a midlatitude

  8. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16T23:59:59.000Z

    Hydrogen Cyanide HHV Higher Heating Value LNB Low NOx Burner PRB Powder River Basin TAMU Texas A&M University CABEL Coal And Biomass Energy Laboratory ER Equivalence Ratio VM Volatile Matter FC Fixed Carbon OFA Over Fired Air (tertiary air... ......................................... 33 5.1 Numerical model algorithm ..................................................................... 47 5.2 Pure PRB NO vs. overall ER ................................................................... 49 5.3 Oxygen concentration along...

  9. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31T23:59:59.000Z

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  10. Exposure to Particulate Matter and Ozone of Outdoor Origin in Singapore

    E-Print Network [OSTI]

    Gall, Elliott T; Chen, Ailu; Chang, Victor; Nazaroff, William W

    2015-01-01T23:59:59.000Z

    ulate matter (PM) or ozone, at concentration increments of ~SL, Samet JM, Dominici F. Ozone and short-term mortality inthe penetration of ambient ozone into residential buildings.

  11. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01T23:59:59.000Z

    of healthy young volunteers to ozone causes cardiovasculareffects of five common ozone-initiated terpene reactiondecay rates, and removal of ozone and their relation to

  12. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    2008. Learning about ozone depletion. Climatic Change 89(1–and Physics of Stratospheric Ozone. San Diego, CA: AcademicPhotochemical behavior of the ozone layer. Report Number

  13. LARGE MULTICONFIGURATION SELF-CONSISTENT-FIELD WAVEFUNCTIONS FOR THE OZONE MOLECULE

    E-Print Network [OSTI]

    Schaefer III., Henry F.

    2013-01-01T23:59:59.000Z

    theory comparable to that employed here for ozone. HoweverB (cyclopentadiyl) > B (ozone) > B (methylene), based onfor the its state of ozone near geometry. Coefficients of

  14. Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.

    E-Print Network [OSTI]

    Destaillats, Hugo

    2012-01-01T23:59:59.000Z

    from Ozone Reaction with HVAC Filters Hugo Destaillats,from Ozone Reaction with HVAC Filters Hugo Destaillatsfrom Ozone Reaction with HVAC Filters Hugo Destaillats

  15. Ozone Climatologies Figure 1: Ozone climatology for control run in kg/m(a), percentage change in

    E-Print Network [OSTI]

    Feigon, Brooke

    Ozone Climatologies (a) (b) (c) Figure 1: Ozone climatology for control run in kg/mł(a), percentage change in ozone for the perturbed runs; tropopause region (b), whole stratosphere (c). Determining the impact of lower stratospheric ozone depletion on Southern Hemisphere climate Sarah P.E. Keeley and Nathan

  16. NOx reduction through combustion optimization at PEPCO`s Potomac River Station

    SciTech Connect (OSTI)

    Cramer, D.S.; Williams, S.E.; Watkins, J.T. [Potomac Electric Power Company, Upper Marlboro, MD (United States)] [and others

    1995-06-01T23:59:59.000Z

    This paper describes the work done under EPRI Project RP 3383 at Potomac River Station to reduce NOx emissions by adjusting boiler controls. it details the method followed by PEPCO and Lehigh engineers to achieve a 35% reduction in average NOx emissions over a one-month extended test. Parameters that had the largest effect on NOx are discussed. A description of instruments installed to better monitor and control combustion is included.

  17. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30T23:59:59.000Z

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

  18. oZONE Faculty and Staff Exporting and Importing Grades

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Exporting and Importing Grades Exporting/Importing Grades in oZONE The new - Log in to ozone.ou.edu using your OU Net ID (4+4) as you would in any other OU system. Click Importing Grades from a Exported oZONE template If you exported a course template from the oZONE grading

  19. Flexible CHP System with Low NOx, CO and VOC Emissions - Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sheet, 2014 Flexible CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 The Gas Technology Institute, in collaboration with Cannon Boiler Works, Integrated CHP...

  20. Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction

    E-Print Network [OSTI]

    Liu, Y. A.

    portion of the tower and 2 spray-scrubber sections in the bottom. The NOx-laden fumes enter the bottom

  1. Reduction of NOx in Synthetic Diesel Exhaust via Two-Step Plasma...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Citation: Tonkyn RG, SE Barlow, and J Hoard.2003."Reduction of NOx in Synthetic Diesel Exhaust via Two-Step Plasma-Catalysis Treatment."Applied Catalysis. B,...

  2. Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System

    SciTech Connect (OSTI)

    Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

    2006-05-01T23:59:59.000Z

    Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

  3. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Lean NOx Catalysis l Chemistry l Reducing Agent Effects l Collaboration with LEP CRADA l Aging Studies Plasma Initiation - + Electron Avalanche e - e - e - e - e - e - e -...

  4. NH3 generation over commercial Three-Way Catalysts and Lean-NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Emissions Control for Lean Gasoline Engines Emissions Control for Lean Gasoline Engines Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and...

  5. A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

  6. Defensive Investments and the Demand for Air Quality: Evidence from the NOx Budget Program and Ozone Reductions

    E-Print Network [OSTI]

    Deschęnes, Olivier

    2012-07-15T23:59:59.000Z

    The economic costs of environmental regulations have been widely debated since the U.S. began to restrict pollution emissions more than four decades ago. Using detailed production data from nearly 1.2 million plant ...

  7. Defensive Investments and the Demand for Air Quality: Evidence from the NOx Budget Program and Ozone Reductions

    E-Print Network [OSTI]

    Deschęnes, Olivier

    Willingness to pay for air quality is a function of health and the costly defensive investments that contribute to health, but there is little research assessing the empirical importance of defensive investments. The setting ...

  8. METHANE de-NOX FOR UTILITY PC BOILERS

    SciTech Connect (OSTI)

    Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

    2002-01-31T23:59:59.000Z

    The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the previous reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NOx at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O2). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor. During the current reporting period, one of the two modified PC burner designs was fabricated and installed in the pilot test facility. Testing of the modified pilot system (modified gas combustor and modified PC burner) during the quarter included 38 tests with PRB coal. NOx reduction was significantly improved to levels as low as 60-100 ppmv with CO in the range of 35-112 ppmv without any furnace air staging.

  9. Ozone determination in different copying centers 

    E-Print Network [OSTI]

    Lai, Chen-Fu

    1993-01-01T23:59:59.000Z

    Photocopying machines have been in existence for forty years: however, few people recognize their potential to create a human health hazard by ozone emission. This study was designed to determine the photocopier's emission rate and evaluate tile...

  10. Ozone treatment of biomass to enhance digestibility 

    E-Print Network [OSTI]

    Almendarez, Maria Elena

    2000-01-01T23:59:59.000Z

    is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

  11. Ozone treatment of biomass to enhance digestibility

    E-Print Network [OSTI]

    Almendarez, Maria Elena

    2000-01-01T23:59:59.000Z

    is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

  12. SOx/NOx sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1993-01-19T23:59:59.000Z

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  13. SOX/NOX sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1995-05-09T23:59:59.000Z

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilized spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths. 3 figs.

  14. Group effects on fuel NOx emissisons from coal

    E-Print Network [OSTI]

    Vadakkath, Anand Anakkara

    1991-01-01T23:59:59.000Z

    . 18 N to NO Conversion vs G Number via Volatiles . 55 56 19 N to NO Conversion vs G Number by Burn-out. . . 20 N to NO Conversion vs G Number by All Methods . 57 21 N to NO Conversion vs G number for Two Coal Diameters 60 Figure Page 22 N... Ratio of GC Rate to ISOC Rate versus G Number (Annamalai) 17 8 Group Combustion Model for a. Spherical Coal Cloud 20 9 Flow-chart for the Program 32 10 Experimental Set-up . 11 Water Cooled Collection System . 40 12 Connections for NOx Analyzer . 42...

  15. Lean NOx Catalysis Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetter Report:40PMDepartment ofs o u t h e a s t e rtheNOx

  16. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01T23:59:59.000Z

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  17. Experimental and numerical analysis of isothermal turbulent flows in interacting low NOx burners in coal-fired furnaces 

    E-Print Network [OSTI]

    Cvoro, Valentina

    Coal firing power stations represent the second largest source of global NOx emissions. The current practice of predicting likely exit NOx levels from multi-burner furnaces on the basis of single burner test rig data has been proven inadequate...

  18. Methane production from ozonated pulp mill effluent

    SciTech Connect (OSTI)

    Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

    1980-07-01T23:59:59.000Z

    A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

  19. NOx Dispatching in Plant Utility Systems Using Existing Tools

    E-Print Network [OSTI]

    Nath, R.; Kumana, J. D.

    NO x DISPATCHING IN PLANT UTILITY SYSTEMS - USING EXISTING TOOLS Ravi Nath and Jimmy D. Kumana Linnhoff March ABSTRACT Localized NO x reduction during Ozone Alerts is a problem of increasing importance to process industries in and around.... Economic dispatching of plant utility systems is commonly done by the gas and electric power companies and software tools for such dispatching already exist even at the industrial plant level [2]. The purpose of this paper is to show...

  20. NRF2 activation is involved in ozonated human serum upregulation of HO-1 in endothelial cells

    SciTech Connect (OSTI)

    Pecorelli, Alessandra [Department of Molecular and Developmental Medicine, University of Siena (Italy); Child Neuropsychiatry Unit, University Hospital, AOUS, Siena (Italy); Bocci, Velio [Department of Physiology, University of Siena (Italy); Acquaviva, Alessandra [Department of Molecular and Developmental Medicine, University of Siena (Italy); Belmonte, Giuseppe [Department of Biomedical Sciences, University of Siena (Italy); Gardi, Concetta [Department of Molecular and Developmental Medicine, University of Siena (Italy); Virgili, Fabio [INRAN, Rome (Italy); Ciccoli, Lucia [Department of Molecular and Developmental Medicine, University of Siena (Italy); Valacchi, Giuseppe, E-mail: giuseppe.valacchi@unife.it [Department of Life Sciences and Biotechnology, University of Ferrara (Italy); Department of Food and Nutrition, Kyung Hee University, Seoul (Korea, Republic of)

    2013-02-15T23:59:59.000Z

    During the last decade, it has been shown that the activation of NRF2 and the binding to electrophile-responsive element (EpREs), stimulates the expression of a great number of genes responsible for the synthesis of phase I and phase II proteins, including antioxidants enzymes and heme oxygenase-1 (HO-1). This critical cell response occurs in cardiovascular, degenerative and chronic infective diseases aggravated by a chronic oxidative stress. In our previous reports we have shown that ozonated plasma is able to up-regulate HO-1 expression in endothelial cells. In the present work we investigated a candidate mechanism involved in this process. After treatment with increasing doses of ozonated serum (20, 40 and 80 ?g/mL O{sub 3} per mL of serum), a clear dose dependent activation of NRF2 and the subsequent induction of HO-1 and NAD(P)H quinone oxidoreductase 1(NQO1) was observed. This effect was also present when cells were treated with serum and hydrogen peroxide (H{sub 2}O{sub 2}) or serum and 4-hydroxynonenal (4HNE). Moreover, the treatment with ozonated serum was associated with a dose-dependent activation of extracellular-signal-regulated kinases (ERK1/2) and p38 MAP kinases (p38), not directly involved in NRF2 activation. These data, provide a new insight on the mechanism responsible for the induction of HO-1 expression by ozonated serum in the endothelium, and have a practical importance as an expedient approach to the treatment of patients with both effective orthodox drugs and ozonated autohemotherapy, targeted to the restoration of redox homeostasis. - Highlights: ? Endothelial HO1 is upregulated by ozonated plasma ? This activation is induced by NRF2 and it is ERK independent. ? 4HNE and H{sub 2}O{sub 2} are the main molecules involved in this process. ? Ozonated plasma induced a hormetic effect ? Combination of orthodox medicine and ozonated plasma can be a useful treatment.

  1. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Brunner, Gregory; Zhang, Jianshun (Jensen); Fisk, William J.

    2011-05-01T23:59:59.000Z

    Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

  2. A Novel Technology for the Reduction of NOx on Char by Microwaves 

    E-Print Network [OSTI]

    Buenger, C.; Peterson, E.

    1994-01-01T23:59:59.000Z

    of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99...

  3. Promotional Effects of H2O Treatment on NOx Storage over Fresh...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aged Pt-BaOAl2O3 Lean NOx Trap Catalysts . Abstract: A simple liquid water treatment applied to fresh and thermally aged Pt(2wt%)-BaO(20wt%)Al2O3 lean NOx trap catalysts at...

  4. Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain 

    E-Print Network [OSTI]

    Benz, R,; Staedter, M.

    2008-01-01T23:59:59.000Z

    Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain Robert Benz Marcel Staedter... Industrial Energy Technology Conference, New Orleans, LA, May 6-9, 2008. M. Staedter, R. Benz / Low Carbon, Ultra Low NOx through Efficiency Gain where y denotes the mole fraction of excess...

  5. The effect of hydrogen addition on flammability limit and NOx emission in ultra-lean counterflow

    E-Print Network [OSTI]

    GĂĽlder, Ă?mer L.

    . They indicated that the addition of hydrogen to natural gas or methane resulted in an increase in NOx for most increases, and then decreases with the increase in the fraction of hydrogen. Overall, hydrogen enrichment rights reserved. Keywords: Hydrogen enrichment; NOx; Extinction limit; Ultra-lean premixed flame. 1

  6. APBF-DEC Light-duty NOx Adsorber/DPF Project

    Broader source: Energy.gov (indexed) [DOE]

    Light - Duty NOx AdsorberDPF Project Vehicle Tests - FTP 75 (Conducted at EPA NVFEL in Ann Arbor) NOx (gmi) 0.00 0.01 0.02 0.03 0.04 0.05 0.06 0.07 Test No. 1 2 3 4 5 PM (mgmi)...

  7. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...

    Broader source: Energy.gov (indexed) [DOE]

    Engine DOC LNT Engine Out Bench (SS1) UEGO1 UEGO2 UEGO3 SS2 NOx Sensor 1 NOx Sensor 2 Turbo 14 LNT 12 LNT 34 LNT FTIR GCMS bag (dilute) Air Bench 2 SpaciMS Tailpipe Bench...

  8. Peroxyacetyl Nitrates: Ozone in the cooling PAN

    E-Print Network [OSTI]

    Toohey, Darin W.

    automobile exhaust and refineries · Studies suggest that using blended gasoline with ethanol increases PAN; NOx increases with 10% ethanol #12;Reaction Mechanisms · CH3CO-O-O + NO CH3CO-O + NO2 · CH3CO-O CH3

  9. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

  10. Biogeochemical controls and isotopic signatures of nitrous oxide production by a marine ammonia-oxidizing bacterium

    E-Print Network [OSTI]

    Frame, Caitlin H.

    Nitrous oxide (N2O)[N subscript 2 O] is a trace gas that contributes to the greenhouse effect and stratospheric ozone depletion. The N2O [N subscript 2 O] yield from nitrification (moles N2O-N [N subscript 2 O - N] produced ...

  11. Economics of pollution trading for SO{sub 2} and NOx

    SciTech Connect (OSTI)

    Dallas Burtraw; David A. Evans; Alan Krupnick; Karen Palmer; Russell Toth

    2005-03-15T23:59:59.000Z

    For years economists have urged policymakers to use market-based approaches such as cap-and-trade programs or emission taxes to control pollution. The sulphur dioxide (SO{sub 2}) allowance market created by Title IV of the 1990 US Clean Air Act Amendments represents the first real test of the wisdom of economists' advice. Subsequent urban and regional applications of NOx emission allowance trading took shape in the 1990s in the United States, culminating in a second large experiment in emission trading in the eastern United States that began in 2003. This paper provides an overview of the economic rationale for emission trading and a description of the major US programs for SO{sub 2} and nitrogen oxides. These programs are evaluated along measures of performance including cost savings, environmental integrity, and incentives for technological innovation. The authors offer lessons for the design of future programs including, most importantly, those reducing carbon dioxide. 128 refs., 1 fig., 1 tab.

  12. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer Review 2012IowaFebruaryIronIron Find

  13. Predicting tropospheric ozone and hydroxyl radical in a global, three-dimensional, chemistry, transport, and deposition model

    SciTech Connect (OSTI)

    Atherton, C.S.

    1995-01-05T23:59:59.000Z

    Two of the most important chemically reactive tropospheric gases are ozone (O{sub 3}) and the hydroxyl radical (OH). Although ozone in the stratosphere is a necessary protector against the sun`s radiation, tropospheric ozone is actually a pollutant which damages materials and vegetation, acts as a respiratory irritant, and is a greenhouse gas. One of the two main sources of ozone in the troposphere is photochemical production. The photochemistry is initiated when hydrocarbons and carbon monoxide (CO) react with nitrogen oxides (NO{sub x} = NO + NO{sub 2}) in the presence of sunlight. Reaction with the hydroxyl radical, OH, is the main sink for many tropospheric gases. The hydroxyl radical is highly reactive and has a lifetime on the order of seconds. Its formation is initiated by the photolysis of tropospheric ozone. Tropospheric chemistry involves a complex, non-linear set of chemical reactions between atmospheric species that vary substantially in time and space. To model these and other species on a global scale requires the use of a global, three-dimensional chemistry, transport, and deposition (CTD) model. In this work, I developed two such three dimensional CTD models. The first model incorporated the chemistry necessary to model tropospheric ozone production from the reactions of nitrogen oxides with carbon monoxide (CO) and methane (CH{sub 4}). The second also included longer-lived alkane species and the biogenic hydrocarbon isoprene, which is emitted by growing plants and trees. The models` ability to predict a number of key variables (including the concentration of O{sub 3}, OH, and other species) were evaluated. Then, several scenarios were simulated to understand the change in the chemistry of the troposphere since preindustrial times and the role of anthropogenic NO{sub x} on present day conditions.

  14. Nitrous oxide (N?O) isotopic composition in the troposphere : instrumentation, observations at Mace Head, Ireland, and regional modeling

    E-Print Network [OSTI]

    Potter, Katherine Ellison

    2011-01-01T23:59:59.000Z

    Nitrous oxide (N?O) is a significant greenhouse gas and main contributor to stratospheric ozone destruction. Surface measurements of N?O mole fractions have been used to attribute source and sink strengths, but large ...

  15. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. 2005 Diesel Engine Emissions...

  16. LAB DOCUMENTATION MEASUREMENT OF OZONE EMISSION AND PARTICLE REMOVAL

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    PURIFIERS Stephen A. Mang,1 Maggie L. Walser,1 John M. Laux,2 Sergey A. Nizkorodov1* 1. Department............................................................. 12 III. Ozone Emission Rates from More Powerful Ozone Generators

  17. Low-Temperature Ozone Exposure Technique to Modulate the Stoichiometry of WO(x) Nanorods and Optimize the Electrochromic Performance

    SciTech Connect (OSTI)

    Lin, F.; Li, C. P.; Chen, G.; Tenent, R. C.; Wolden, C. A.; Gillaspie, D. T.; Dillon, A. C.; Richards, R. M.; Engtrakul, C.

    2012-06-29T23:59:59.000Z

    A low-temperature ozone exposure technique was employed for the post-treatment of WO{sub x} nanorod thin films fabricated from hot-wire chemical vapor deposition (HWCVD) and ultrasonic spray deposition (USD) techniques. The resulting films were characterized with x-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, UV-vis-NIR spectroscopy and x-ray photoelectron spectroscopy (XPS). The stoichiometry and surface crystallinity of the WO{sub x} thin films were subsequently modulated upon ozone exposure and thermal annealing without particle growth. The electrochromic performance was studied in a LiClO{sub 4}-propylene carbonate electrolyte, and the results suggest that the low-temperature ozone exposure technique is superior to the traditional high-temperature thermal annealing (employed to more fully oxidize the WO{sub x}). The optical modulation at 670 nm was improved from 35% for the as-deposited film to 57% for the film after ozone exposure at 150 C. The coloration efficiency was improved and the switching speed to the darkened state was significantly accelerated from 18.0 s for the as-deposited film to 11.8 s for the film after the ozone exposure. The process opens an avenue for low-temperature and cost-effective manufacturing of electrochromic films, especially on flexible polymer substrates.

  18. Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong-Hoo Park a

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong Received in revised form 26 May 2010 Accepted 2 June 2010 Keywords: Ozone fluxes Citrus Tropospheric ozone climates. In the summer, orchards in California experience high levels of tropospheric ozone, formed

  19. What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found in the strato-

    E-Print Network [OSTI]

    What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found it represents only a tiny fraction of the atmosphere, ozone is crucial for life on Earth. Ozone--acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. With- out ozone, the Sun

  20. The impact of interannual variability on multidecadal total ozone simulations

    E-Print Network [OSTI]

    Jackman, Charles H.

    to reinforce the chemical ozone depletion caused by the enhanced aerosol loading following the eruption of Mt

  1. The integration of low NOx control technologies at the Southern Energy, Inc. Birchwood Power Facility

    SciTech Connect (OSTI)

    Lauber, J.A. [Southern Energy, Inc. (United States); Cohen, M.B.; Donais, R.E. [ABB Combustion Engineering, Inc. (United States)

    1997-12-31T23:59:59.000Z

    The Southern Energy, Inc. (SEI) Birchwood Power Facility, a cogeneration unit, represents the first application worldwide of the TFS 2000{trademark} firing system and selective catalytic reduction (SCR). The installation of these state-of-the-art NOx control technologies was necessary to meet strict Commonwealth of Virginia environmental regulations requiring a 0.10 lbs/10{sup 6} Btu (0.043 g/MJ) NOx emission rate based upon a 30-day rolling average. The plant successfully completed all performance and emission testing on September 24, 1996. Commercial operation began November 14, 1996. Stack NOx emission rates are consistently maintained below 0.10 lbs/10{sup 6} Btu. The paper describes the integration of both in-furnace and post-combustion NOx control technologies into the overall boiler design. Operational data depicting boiler outlet NOx, stack NOx and loss on ignition (LOI) are presented across the design load range from 32% to 100% boiler output. The description, arrangement, design parameters and operation of the NOx control equipment are discussed. Novel design features include a split economizer, an air heater suitable for ammonia applications, Dynamic{trademark} classifiers, and a multi-zone secondary air flow control system utilized for the TFS 2000{trademark} firing system.

  2. Arctic ozone loss and climate sensitivity: Updated threedimensional model study

    E-Print Network [OSTI]

    Feng, Wuhu

    Arctic ozone loss and climate sensitivity: Updated three­dimensional model study Chipperfield winter­spring chemical ozone loss from 1991 2003, its observed correlation with low temperatures. CTM throughout studied. The model reproduces large column winters also captures shape of ozone loss profile

  3. ORIGINAL CONTRIBUTION Ozone and Short-term Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    ORIGINAL CONTRIBUTION Ozone and Short-term Mortality in 95 US Urban Communities, 1987-2000 MichelleD E XPOSURE TO TROPOSPHERIC OZONE is widespread in the United States,1,2 occurring also outside southernCalifornia,whereozone formation was first recognized.3 Short- term exposure to ozone has been

  4. Quantum origin of an anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Quantum origin of an anomalous isotope effect in ozone formation D. Babikov *, B.K. Kendrick, R mechanical calculations of the đJ Ľ 0Ţ energies and lifetimes of the metastable states of ozone on a new effect in the reaction that forms ozone because of their role in the energy transfer mechanism, in which

  5. Relative importance of radical families The "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    · Relative importance of radical families · The "Ozone Hole" · Introduction to heterogeneous chemistry Tuesday, March 8, 2011 #12;Review of important points so far Stratospheric ozone is only produced with these parameters Sir Sydney Chapman nearly got it right. He could account for the formation of the ozone layer

  6. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  7. The Ozone Layer in the 21st Lead Authors

    E-Print Network [OSTI]

    Robock, Alan

    CHAPTER 6 The Ozone Layer in the 21st Century Lead Authors: G.E. Bodeker D.W. Waugh Coauthors: H;#12;CHAPTER 6 THE OZONE LAYER IN THE 21ST CENTURY Contents SCIENTIFIC SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.5 6.2 A FRAMEWORK FOR EVALUATING CHANGES IN OZONE ABUNDANCES

  8. Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer

    E-Print Network [OSTI]

    Oppenheimer, Michael

    Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 ozone depletion has been much studied as a case history in the interaction between environmental science the photochemistry of ozone in order to illustrate how scientific learning has the potential to mislead policy makers

  9. On the statistical modeling of persistence in total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    On the statistical modeling of persistence in total ozone anomalies 1234567 89A64BC7DEF72B4 F9BC4B725CE9393BE647 #12;On the statistical modeling of persistence in total ozone anomalies D. I ozone anomalies on monthly to interannual timescales. Such a model is usually characterized by the Hurst

  10. Chemistry climate model simulations of1 spring Antarctic ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Chemistry climate model simulations of1 spring Antarctic ozone 1234567 89A64BC7DEF72B4 19B34EE3293C climate model simulations of spring Antarctic ozone John Austin,1,2 H. Struthers,3 J. Scinocca,4 D. A) and Intergovernmental Panel on Climate Change A1b Scenario. The simulations of the Antarctic ozone hole are compared

  11. Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E for their species effectiveness in reducing ozone concentrations in a simulated indoor environment. Continuously supply system were used to simulate an indoor environment in which ozone concentrations could be measured

  12. oZONE Faculty and Staff Course Overrides

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Course Overrides and the Registration Add Errors They Resolve Departments of the overrides within the registration component of oZONE. We have, however, retained a few instances where some. There is also a link to this document on the Student Training and Instructions page in the oZONE info site

  13. Low NOx nozzle tip for a pulverized solid fuel furnace

    DOE Patents [OSTI]

    Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

    2014-04-22T23:59:59.000Z

    A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

  14. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01T23:59:59.000Z

    and exposed to LSX ambient ozone for two months. Arrows indicate pestained SDS-PAGE molecular weight standards (kD) and Rubisco large subunit. Lane R = pure spinach Rubisco large subunit. Lanes 1 and 2 = control seedlings in the Ozoban study. Lanes 3 and 4... radicals are produced during normal metabolism when oxygen is reduced to water. Grimes et al. (1983) studied the products that form from ozone in cells and found no detectable superoxide radicals, leading them to propose that either ozone or hydroxyl...

  15. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31T23:59:59.000Z

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  16. METHANE de-NOX for Utility PC Boilers

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser Serguei Nester; Stan Wohadlo

    2004-06-30T23:59:59.000Z

    The primary focus for the project during the quarter was shakedown testing of the large-scale coal preheater prototype in the CBTF with non-caking PRB coal. Additional pilot-scale tests were conducted in the PSCF in support of developing a preheating system design suitable for use with caking coals. Thirty-two additional pilot tests were conducted during the quarter with caking coal. These tests further evaluated the use of the air-bleed and indirect air-cooled liner designs to reduce or eliminate combustor plugging with caking coal. The air-bleed configurations tested used air injection holes perpendicular to the liner's longitudinal axis with the number, size and air flow though the air-bleed holes varied to determine the effect on combustor plugging. The indirect cooling configurations tested included a stainless steel liner with spiral fins in the annular space between the liner and the combustor wall, and a silicon carbide liner without fins. Continuous pilot operation was maintained for up to 30 minutes at a coal feed rate of 50 lb/h with the air-bleed liner. The best result achieved was for the stainless steel indirect air-cooled liner with 20 minutes of continuous operation at 126 lb/h of coal followed by an additional 20 minutes at 150 lb/h. The NOx results from these continue to indicate that even greater NOx reduction is possible with caking coal than with the PRB coal tested. The installation of the large-scale prototype coal preheater for PRB testing in the CBTF was completed and shakedown testing with natural gas and PRB coal started during the quarter. Stable operation of the coal system, combustor and burner were achieved at coal feed rates up to 6000 lb/h (50 MMBtu/h).

  17. METHANE DE-NOX FOR UTILITY PC BOILERS

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

    2004-02-06T23:59:59.000Z

    The primary focus for the project continues to be on developing a PC PREHEAT system design suitable for use with caking coals and readying the 100 MMBtu/h CBTF for testing with noncaking PRB coal. During the current quarter, twenty-two pilot tests were conducted with Central Appalachian (CA) caking coal. The objective for these tests was to achieve continuous operation of the pilot system at its design coal feed rate of 156 lb/h, without plugging or agglomeration in the combustor. One combustor air distribution method tested achieved continuous operation at 110 lb/hr, and inspection of the combustor afterward indicated that this method has potential to solve the caking problem. The NOx results from the pilot caking coal runs indicate that even greater NOx reduction is possible with CA coal than with the PRB coal tested, to levels near 100 ppmv or lower at 4-6% exit oxygen. It was therefore decided to conduct additional pilot tests of the air distribution method to determine how to incorporate this into a workable CA combustor design. Based on current weather and manpower restrictions at the site, this pilot testing is expected to be started in February. The design for the 100 MMBtu/h unit for PRB testing in the CBTF was completed and fabrication and installation started during the quarter. While significant progress has been made in the installation of the unit, weather and combustor fabrication delays are expected to move the start of large-scale testing with PRB coal into February, which will push the project completion date beyond the current 3/30/04 end date. GTI is in the process of developing a revised project schedule and estimated cost to complete.

  18. Procedure to Calculate NOx Reductions Using the Emissions & Generation Resource Integrated Database (E-Grid) Spreadsheet

    E-Print Network [OSTI]

    Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.; Verdict, M.; Turner, W. D.

    2003-01-01T23:59:59.000Z

    and Renewable Energy projects (EE/RE) implemented in each Power Control Area (PCA) in the ERCOT region E-GRID is a comprehensive database of environmental attributes of electric power systems. E-GRID is based on available plant-specific data for all U... in Figure 9 that three counties (i.e., Ward, McLennan, and Mitchell) rise significantly in NOx reductions during peak days when compared to annual NOx reductions (Figure 5). Table 1. EPA's EGRID table: County-wide NOx Reductions in pounds per MWh for EE/RE...

  19. Current-biased potentiometric NOx sensor for vehicle emissions

    DOE Patents [OSTI]

    Martin, Louis Peter (Castro Valley, CA); Pham, Ai Quoc (San Jose, CA)

    2006-12-26T23:59:59.000Z

    A nitrogen oxide sensor system for measuring the amount of nitrogen oxide in a gas. A first electrode is exposed to the gas. An electrolyte is positioned in contact with the first electrode. A second electrode is positioned in contact with the electrolyte. A means for applying a fixed current between the first electrode and the second electrode and monitoring the voltage required to maintain the fixed current provides a measurement of the amount of nitrogen oxide in the gas.

  20. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Broader source: Energy.gov (indexed) [DOE]

    20 Composite nanowire array catalysts NO oxidation Sequential deposition: 68%, medium space velocity; Co-deposition: 45%, medium space velocity; both peak at 375...

  1. Tropospheric column ozone: matching individual profiles from Aura OMI and TES with a chemistry-transport model

    E-Print Network [OSTI]

    Tang, Q.; Prather, M. J

    2012-01-01T23:59:59.000Z

    Science Objectives of the Ozone Monitoring In- strument,G. J. , and Logan, J. A. : Ozone climatolog- ical profilestroposphere ex- change ozone flux related to deep

  2. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01T23:59:59.000Z

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  3. The Effects of Gaseous Ozone and Nitric Acid Deposition on two Crustose Lichen Species From Joshua Tree National Park

    E-Print Network [OSTI]

    Hessom, Elizabeth Curie

    2012-01-01T23:59:59.000Z

    photosynthetic rate responses to ozone in some foliose andof gaseous nitric acid and ozone on lichens. Dissertations &with nitric acid and ozone. Environmental Pollution, In

  4. Climate Co-benefits of Tighter SO2 and NOx Regulations in China

    E-Print Network [OSTI]

    Nam, Kyung-Min

    2012-10-01T23:59:59.000Z

    Air pollution has been recognized as a significant problem in China. In its Twelfth Five Year Plan (FYP), China proposes to reduce SO2 and NOx emissions significantly, and here we investigate the cost of achieving those ...

  5. A design strategy applied to sulfur resistant lean NOxĚł automotive catalysts

    E-Print Network [OSTI]

    Tang, Hairong

    2005-01-01T23:59:59.000Z

    Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

  6. APBF-DEC NOx Adsorber/DPF Project: SUV/Pick-Up Platform

    Broader source: Energy.gov (indexed) [DOE]

    Status Principal Investigators: Cynthia Webb Phillip Weber DEER August 25, 2003 APBF-DEC NOx AdsorberDPF Project: SUVPick-Up Platform Program Goals Objectives Light-Duty SUV ...

  7. Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and CHF Peden.2008."Excellent Sulfur Resistance of PtBaOCeO2 Lean NOx Trap Catalysts."Applied Catalysis. B, Environmental 84(3-4):545-551. doi:10.1016j.apcatb.2008.05.009...

  8. Diesel NOx-PM Reduction with Fuel Economy Increase by IMET-ŤOBC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Increase by IMET-OBC-DPF + Hydrated-EGR System for Retrofit of In-Use Trucks Diesel NOx-PM Reduction with Fuel Economy Increase by IMET-OBC-DPF + Hydrated-EGR System...

  9. Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)

    E-Print Network [OSTI]

    Kushner, Mark

    Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia) Department exhausts with hydrocarbons propane (C3H8) and propene (C3H6) has been investigated. In general

  10. Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-02-01T23:59:59.000Z

    Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

  11. Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Richard Blint, Michael B. Viola and Steven J. Schmieg General Motors R&D Center Warren, MI 48090-9055 DEER 2009 Tuesday,...

  12. Non-thermal plasma-assisted NOx reduction over Na-Y zeolites...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    investigated in the non-thermal plasma assisted NOx reduction reaction using a simulated diesel engine exhaust gas mixture. The acid sites were formed by NH4+ ion exchange and...

  13. Water-induced morphology changes in BaO/?-Al2O3 NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials: an FTIR, TPD, and time-resolved synchrotron XRD Water-induced morphology changes in BaO?-Al2O3 NOx storage materials: an FTIR, TPD, and time-resolved synchrotron...

  14. Calculation of NOx Emissions Reductions From Energy Efficient Residential Building Construction in Texas

    E-Print Network [OSTI]

    Haberl, J. S.; Culp, C.; Gilman, D.; Yazdani, B.; Fitzpatrick, T.; Muns, S.

    2006-05-23T23:59:59.000Z

    . These areas face severe sanctions if attainment is not reached by 2007. This paper provides an overview of the procedures that have been developed and used to calculate the electricity savings and NOx reductions from code-compliant residential construction...

  15. Reduction of NOx Emissions in Alamo Area Council of Government Projects

    E-Print Network [OSTI]

    Haberl, J. S.; Zhu, Y.; Im, P.

    2004-01-01T23:59:59.000Z

    This reports summarizes the electricity, natural gas and NOx emissions reductions from retrofit measures reported as part of the AACOG emissions reduction effort. The electricity and natural gas savings were collected by the Brooks Energy...

  16. Nuclear conflict and ozone depletion Quick summary

    E-Print Network [OSTI]

    Toohey, Darin W.

    Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

  17. Policy Response to Stratospheric Ozone Loss

    E-Print Network [OSTI]

    Toohey, Darin W.

    #12;12 In terms of human impact #12;13 How do we know what to regulate? · Need a metric for assessing on stratospheric ozone ­ Some significant global warming potential (GWP) ­ Concern about breakdown products ­ trifluoroacetyl halides (TFAs) #12;20 Global Warming Potentials Compound Estimated Atmospheric (at time horizons

  18. Global inventory of nitrogen oxide emissions constrained by space-based observations of NO2 columns

    E-Print Network [OSTI]

    Chance, Kelly

    Global inventory of nitrogen oxide emissions constrained by space-based observations of NO2 columns NO + NO2), and combine these with a priori information from a bottom- up emission inventory (with error and a factor of 2 over remote regions. We derive a top-down NOx emission inventory from the GOME data by using

  19. Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution

    E-Print Network [OSTI]

    Thompson, Anne

    Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution Anne M activities lead to intense smoke haze and ozone formation. The first ozone soundings in the heart surface ozone was over 90 ppbv and column tropospheric ozone exceeded 50 DU. These values are higher than

  20. METHANE de-NOX for Utility PC Boilers

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

    2003-09-30T23:59:59.000Z

    During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was continued with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was decided that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, the pilot gas combustor was changed to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Testing with caking coal in the horizontal pilot combustor achieved feed rates up to 126 lb/h, although some deposition and LOI issues remain. Several promising approaches to further improve operation with caking coal were identified. NOx results with caking coal are promising, with NOx as low as 150 ppmv at exit oxygen levels of 4% and higher. The 100 MMBtu/h commercial-scale prototype design is nearing completion. Design of the caking coal version of the unit continues with additional pilot testing in support of this design expected. GTI and RPI are expediting the fabrication of the 100 MMBtu/h PRB unit in order to start testing in early- to mid-December. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) is nearing completion. As of mid-September, this activity was 95% complete.

  1. Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide

    E-Print Network [OSTI]

    Harris, Eliza

    Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

  2. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01T23:59:59.000Z

    = Au, Pd, and TiO 2 ) with varying counter electrode", Solid= Au, Pd, and TiO 2 ) with varying counter electrode", Solidelectrodes (dense gold wires) Conductive paste (Au-Pd)

  3. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01T23:59:59.000Z

    Allen, “ Pulse CO Laser Drilling of Green Alumina Ceramic”,Susan D. Allen, “Pulse CO Laser Drilling of Green Alumina

  4. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01T23:59:59.000Z

    W. Ragland, Combustion Engineering, (McGraw Hill: Boston,and Kenneth W. Ragland, Combustion Engineering, McGraw-Hill:

  5. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01T23:59:59.000Z

    at several frequencies. EIS is performed as follows: - Applyand Saruhan performed EIS on NO x sensors with sputtered NiOTransformation (Aging) EIS was performed on LSM sensors on

  6. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01T23:59:59.000Z

    Chou, Steve Dai, Ramesh Koripella, Manny Oliver, Daniel Sadler, PaulChou, Steve Dai, Ramesh Koripella, Manny Oliver, Daniel Sadler, Paul

  7. Investigation on continuous soot oxidation and NOx reduction by SCR coated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetter Report: I11IG002 InvestigationFuel830, at thePowerDPF |

  8. Effect of Thermal Aging on NO oxidation and NOx storage in a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:RevisedAdvisory Board Contributionsreduction systemParticulateWearDepartment

  9. Exhaust-gas recirculation for retrofit NOx control on natural gas engines. Topical report, January-April 1988

    SciTech Connect (OSTI)

    Urban, C.M.

    1989-01-01T23:59:59.000Z

    Data on exhaust-gas recirculation obtained from Tenneco Gas Transportation Company were reviewed and analyzed, and a basic EGR system design and cost estimate were developed. EGR can provide practical NOx reductions of up to 50% in 2-cycle natural gas engines. The amount of NO reduction achievable is dependent on the initial baseline NOx emissions of the engine. On the basis of NOx reduction per unit of costs, EGR was found to be more cost effective than selective catalytic reduction. EGR is considered to provide a practical retrofit NOx control method in applications where the level of NOx control achievable with EGR meet regulatory requirements. One specific application is emissions offset to enable installation of additional engine horsepower. Also, EGR could become the primary NOx control method for any regulation in which costs are a major consideration.

  10. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-09-30T23:59:59.000Z

    This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

  11. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-12-31T23:59:59.000Z

    This is the eighteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Safety equipment for ammonia for the SCR slipstream reactor at Plant Gadsden was installed. The slipstream reactor was started and operated for about 1400 hours during the last performance period. Laboratory analysis of exposed catalyst and investigations of the sulfation of fresh catalyst continued at BYU. Thicker end-caps for the ECN probes were designed and fabricated to prevent the warpage and failure that occurred at Gavin with the previous design. A refurbished ECN probe was successfully tested at the University of Utah combustion laboratory. Improvements were implemented to the software that controls the flow of cooling air to the ECN probes.

  12. Release of Ammonium and Mercury from NOx Controlled Fly Ash

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; Kim, A.G

    2007-07-01T23:59:59.000Z

    One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

  13. Background information for RACT determination of NOx emissions from Maryland power plants. Part 1. Boilers. Technical report

    SciTech Connect (OSTI)

    Borkowicz, R.J.

    1993-10-01T23:59:59.000Z

    The purpose of the report is to provide an evaluation of potential NOx control technologies for utility boilers in the State of Maryland. The boilers discussed are owned and operated by Baltimore Gas Electric Company (BG E), Potomac Electric Power Company (PEPCO), Delmarva Power and Light (DP L), and Allegheny Power. The paper focuses on available technologies, costs, achievable NOx reductions, unique characteristics of specific units, and strategies for achieving low NOx emissions.

  14. Overall Rate Constant Measurements of the Reaction of Hydroxy-and Chloroalkylperoxy Radicals Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide

    E-Print Network [OSTI]

    Elrod, Matthew J.

    and to lead to additional ozone production in regions where isoprene oxidation chemistry is dominant Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide Hong Yuan Hsin and Matthew J. Elrod- and chloroalkylperoxy radicals, derived from the OH- and Cl-initiated oxidation of methacrolein and methyl vinyl ketone

  15. Investigation Of Synergistic NOx Reduction From Cofiring And Air Staged Combustion Of Coal And Low Ash Dairy Biomass In A 30 Kilowatt Low NOx Furnace

    E-Print Network [OSTI]

    Lawrence, Benjamin Daniel

    2013-08-01T23:59:59.000Z

    to address this concern. DB is evaluated as a cofired fuel with Wyoming Powder River Basin (PRB) sub-bituminous coal in a small-scale 29 kW_(t) low NO_(x) burner (LNB) facility. Fuel properties, of PRB and DB revealed the following: a higher heating value...

  16. Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy

    E-Print Network [OSTI]

    Brown, Matthew A.

    2008-01-01T23:59:59.000Z

    J. C. , Reactivity of ozone on solid potassium iodide.and mechanisms of aqueous ozone reactions with bromide,for Dry Deposition of Ozone to Seawater Surfaces. Journal of

  17. OZONE INDUCED CONDUCTANCE INCREASES ASSAYED WITH LIPID IMPREGNATED FILTER MEMBRANES-EFFECT OF VITAMIN E

    E-Print Network [OSTI]

    Sheih, P.K

    2011-01-01T23:59:59.000Z

    29-44. R. L. Heath (1975) Ozone, in Response of Plants toSince it is possible that ozone absorption "is incompleteof the filter. After the ozone treatment was stopped the

  18. Application of gaseous disinfectants ozone and chlorine dioxide for inactivation of Bacillus subtilis spores

    E-Print Network [OSTI]

    Aydogan, Ahmet

    2006-01-01T23:59:59.000Z

    inhibitor line Ozone Generator Oxygen Concentrator CellSequal oxygen concentrator and Pure-O-Tech ozone generator.This oxygen is then supplied into the ozone generator for

  19. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    SciTech Connect (OSTI)

    Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

    2009-09-01T23:59:59.000Z

    This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

  20. The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters 

    E-Print Network [OSTI]

    Buys, Ronald Earl

    1980-01-01T23:59:59.000Z

    as solids retention time increased. COD concentration decreased after ozonation and its percent removal increased with a lengthening of the solids retention time, Ozone consumption decreased and the ratio of COD reduction to ozone consumed increased..., with and without ozonation. . . . . . . . . . . . . 22 Effect of solids retention time on COD removal. Effect of solids retention time on ozone concentration consumed. 27 Effect of solids retention time on the ratio of COD reduction to ozone consumed. 28...

  1. Ozone treatment in a closed culture system for Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Yamaguchi, Ryoji

    1978-01-01T23:59:59.000Z

    removed from test aquaria, OTN reagent was added and color development was measured spectrophotometrically. Air mixed with ozone gas was injected into test solutions by diffuser (aquarium air stone) under specified conditions of temperature (28 C... of its high reactivity, ozone has been used for treating water to remove dissolved organic and inorganic wastes (Torricelli, 1959; Diaper, 1972) . The effectiveness of ozonation has been discussed by Dickerman et al. (1954), Fetner and Ingols (1959...

  2. airborne antarctic ozone: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  3. antarctic ozone recovery: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  4. antarctic ozone hole: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  5. antarctic ozone experiment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  6. antarctic ozone depletion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  7. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01T23:59:59.000Z

    An evaluation of different scrubber materials. Environmentalrun periodically. Inline ozone scrubbers were used for VOCwith a commercial, KI-filled scrubber (P/N WAT054420; Waters

  8. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01T23:59:59.000Z

    from the material balance on ozone (equation 4-1). S [O 3 ](equation 5-2, which reflects a steady-state material balance

  9. METHANE de-NOX for Utility PC Boilers

    SciTech Connect (OSTI)

    Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

    2005-09-30T23:59:59.000Z

    The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

  10. E-Print Network 3.0 - ambient ozone growth Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate and Environment (Climate) Impacts of ozone on trees and crops Summary: and carbon sequestration. Vegetation exposure to ozone reduces photosynthesis, growth, and...

  11. Application of gaseous disinfectants ozone and chlorine dioxide for inactivation of Bacillus subtilis spores

    E-Print Network [OSTI]

    Aydogan, Ahmet

    2006-01-01T23:59:59.000Z

    of gaseous ozone for MRSA decontamination of hospital side-H. ; Kamiki, T. , “Ozone decontamination of bioclean rooms”,Nelson, P.E. , “Decontamination of bacillus thuringiensis

  12. Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission

    E-Print Network [OSTI]

    Elliott, Emily M.

    Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

  13. Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

  14. Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    a maximum value of 15 ppm sulfur content in diesel fuel, and this ultra-low-sulfur fuel is expectedSulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Catalyst Qiang Wang,*, Jiahua of sulfur has not been investigated. In this article, the sulfur poisoning of the NOx storage

  15. URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA

    E-Print Network [OSTI]

    Boyer, Edmond

    Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

  16. Validation of satellite ozone profile retrievals using Beijing ozonesonde data

    E-Print Network [OSTI]

    Pan, Laura

    year time period (September 2002 to July 2005) are used to evaluate the performance of ozone profile, the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua satellite and the Microwave Limb Sounder (MLS) on the NASA Aura satellite. Since the Global Positioning System ozone sensors (GPSO3) used in Beijing

  17. Atmospheric Environment 41 (2007) 31513160 Ozone removal by HVAC filters

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Atmospheric Environment 41 (2007) 3151­3160 Ozone removal by HVAC filters P. Zhao, J.A. Siegel�, R May 2006; accepted 14 June 2006 Abstract Residential and commercial HVAC filters that have been loaded of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial

  18. Proceedings: Indoor Air 2005 OZONE REMOVAL BY RESIDENTIAL HVAC FILTERS

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Proceedings: Indoor Air 2005 2366 OZONE REMOVAL BY RESIDENTIAL HVAC FILTERS P Zhao1,2 , JA Siegel1, Austin, Texas 78758, USA ABSTRACT HVAC filters have a significant influence on indoor air quality% for Filter #2 at a face velocity of 0.81 cm/s. The potential for HVAC filters to affect ozone concentrations

  19. Reactive uptake of ozone at simulated leaf surfaces: implications for "non-stomatal" ozone flux 

    E-Print Network [OSTI]

    Cape, J Neil; Hamilton, Richard P; Heal, Mathew R

    2009-01-01T23:59:59.000Z

    The reaction of ozone (O3) with ?-pinene has been studied as a function of temperature and relative humidity and in the presence of wax surfaces that simulate a leaf surface. The objective was to determine whether the presence of a wax surface...

  20. An ozone climatology of the Dallas-Fort Worth area and its relationship to meteorology

    E-Print Network [OSTI]

    Nobis, Timothy Edward

    1998-01-01T23:59:59.000Z

    , no extensive studies on ozone in this area have been published. This study presents a broad overview of the ozone problem in the DFW area. An ozone spatial and temporal climatology was constructed using ozone data at 23 different monitoring sites from 1980...

  1. Modeling Transport E ects on Ground-Level Ozone Using a

    E-Print Network [OSTI]

    Huang, Su-Yun

    Modeling Transport E ects on Ground-Level Ozone Using a Non-Stationary Space-Time Model Hsin on Ground-Level Ozone 1 #12;Summary This article presents a novel autoregressive space-time model for ground-level ozone data, which models not only spatio-temporal dynamics of hourly ozone con- centrations, but also

  2. Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Aakash C. Rai1

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Dynamics2 3 10 Ozone is a major pollutant of indoor air. Many studies have demonstrated the adverse health effect of11 ozone and the byproducts generated as a result of ozone-initiated reactive chemistry

  3. Improving total column ozone retrievals by using cloud pressures derived from Raman scattering in the UV

    E-Print Network [OSTI]

    Joiner, Joanna

    Improving total column ozone retrievals by using cloud pressures derived from Raman scattering resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals. By default, the TOMS

  4. An intramolecular theory of the mass-independent isotope effect for ozone. I.

    E-Print Network [OSTI]

    Hathorn, Bryan C.

    An intramolecular theory of the mass-independent isotope effect for ozone. I. B. C. Hathorn and R-independent isotope effect for ozone formation and dissociation is described. The experiments include the enrichment and asymmetric ozone isotopomers, the enrichment of ozone formed from heavily enriched oxygen isotopes

  5. Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1

    E-Print Network [OSTI]

    Son, Seok-Woo

    Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1 Neil F. Tandon,2 Lorenzo M cooling resulting from ozone depletion has only recently been examined and a comprehensive picture on the stratospheric ozone forcing used, we here show that stratospheric ozone affects the entire atmospheric

  6. The effect of reformate gas enrichment on extinction limits and NOX formation

    E-Print Network [OSTI]

    Gülder, Ömer L.

    The effect of reformate gas enrichment on extinction limits and NOX formation in counterflow CH4 Dufferin Street, Toronto, Ont., Canada M3H 5T6 Abstract The reformate gas enriched counterflow lean premixed CH4/air flames were studied by numerical sim- ulation in this paper. The reformate gas was assumed

  7. NOx-Mediated Homogeneous Pathways for the Synthesis of Formaldehyde from CH4-O2 Mixtures

    E-Print Network [OSTI]

    Iglesia, Enrique

    CH4 conversion, because weaker C-H bonds in HCHO and CH3OH relative to CH4 lead to their fast that the O2 distribution along a reactor will not improve HCHO yields but may prove useful to inhibit NOx losses to less reactive N-compounds. 1. Introduction The practical conversion of remote natural gas

  8. Procedure to Calculate NOx Reductions Using the Emissions & Generation Resource Integrated Database (E-Grid) Spreadsheet 

    E-Print Network [OSTI]

    Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.; Verdict, M.; Turner, W. D.

    2003-01-01T23:59:59.000Z

    and Generation Resource Integrated Database (E-GRID) is presented. This procedure is proposed for calculating county-wide NOx reductions in pounds per MWh for Energy Efficiency and Renewable Energy projects (EE/RE) implemented in each Power Control Area (PCA...

  9. Estimation of Annual Reductions of NOx Emissions in ERCOT for the HB3693 Electricity Savings Goals 

    E-Print Network [OSTI]

    Diem, Art; Mulholland, Denise; Yarbrough, James; Baltazar, Juan Carlos; Im, Piljae; Haberl, Jeff

    2008-01-01T23:59:59.000Z

    avoided emission rate is approximately 0.51 pounds (lb) of NOx reduced per MWh of electricity savings. While House Bill 3693 is an Act related to energy and does not target emissions levels, the energy efficiency improvements would achieve air pollution...

  10. Isothermal desulfation of pre-sulfated Pt-BaO/?-Al2O3 lean NOx...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NOx trap catalysts with H2: the effect of H2 concentration and the roles of CO2 and H2O."Applied Catalysis. B, Environmental 111-112(1):342-348. doi:10.1016j.apcatb.2011.10.017...

  11. Interaction between soot particles and NOx during dielectric barrier discharge plasma remediation of simulated diesel exhaust

    E-Print Network [OSTI]

    Kushner, Mark

    of simulated diesel exhaust Rajesh Doraia) University of Illinois, Department of Chemical Engineering, 1406 from combustion effluent and from diesel exhausts in particular. Soot particles are inevitably present, a computational investigation of the effect of soot on the plasma chemistry of NOx removal in a simulated diesel

  12. Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz

    E-Print Network [OSTI]

    Jacob, Daniel J.

    Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz Advanced Study Program, MA 02138 (email djj@io.harvard.edu) #12;Abstract. Fossil fuel combustion is the largest global source-dimensional model of tropospheric chemistry and transport to study the impact of fossil fuel combustion

  13. Fuel NOx pollution production during the combustion of a low caloric value fuel gas

    E-Print Network [OSTI]

    Caraway, John Phillip

    1995-01-01T23:59:59.000Z

    of NOx is modeled by the kinetic and turbulent mixed destruction of ammonia (NH3). The destruction of NH3 is described using equations developed in prior experiments. The influences of the method of distribution of the inlet flow on the temperature...

  14. NOx emission characteristics of counterflow syngas diffusion flames with airstream dilution

    E-Print Network [OSTI]

    Aggarwal, Suresh K.

    NOx emission characteristics of counterflow syngas diffusion flames with airstream dilution Daniel Abstract Syngas is produced through a gasification process using variety of fossil fuels, including coal. Due to its wide flexibility in fuel sources and superior pollutants characteristics, the syngas

  15. IV CESPC, August 21 -25, 2011, Zlatibor, Serbia LIMITATIONS OF NOX REMOVAL BY PULSED CORONA REACTORS

    E-Print Network [OSTI]

    Ebert, Ute

    IV CESPC, August 21 - 25, 2011, Zlatibor, Serbia 37 LIMITATIONS OF NOX REMOVAL BY PULSED CORONA depends on the deposited energy. There are presently only a few papers investigating this problem [1 volume of 322 L. It is powered by pulses of 80 kV with 15 ns rise time, 150 ns width (power) and energy

  16. Evaluation of Corona Reactors of Several Geometries for a Plasma Assisted Nitrogen Oxide Emission Reduction Device

    SciTech Connect (OSTI)

    Herling, Darrell R.; Smith, Monty R.; Hemingway, Mark D.; Goulette, David; Silvis, Thomas W.

    2000-08-09T23:59:59.000Z

    Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system. This system is comprised of a two-stage corona generation device (plasma reactor) and reduction catalyst that reduces nitric oxide and nitrogen dioxide emissions to nitrogen.

  17. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31T23:59:59.000Z

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  18. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  19. Electrochemical cell and membrane for continuous NOx removal from natural gas-combustion exhaust gases. Final report, October 1, 1990-September 30, 1991

    SciTech Connect (OSTI)

    White, J.H.; Burt, J.; Cook, R.L.; Sammells, A.F.

    1991-01-01T23:59:59.000Z

    This program investigated the utility of electrochemically promoted NOx decomposition under conditions appropriate to those found in natural gas prime mover exhaust. In addition, the utility of mixed ionic and electronic conducting membranes for the spontaneous decomposition of NOx were investigated using catalytic sites identified during the electrochemical study. The program was conducted by initially evaluating perovskite related cathode electrocatalysts using high NOx concentrations. This was followed by investigations at NOx concentrations consistent with those encountered in natural gas prime mover exhausts. Preferred electrocatalysts were then incorporated into mixed conducting membranes for promoting NOx decomposition. Work showed that cobalt based electrocatalysts were active towards promoting NOx decomposition at high concentrations. At lower NOx concentrations initial activation, by passage of a large cathodic current, was required which probably resulted in producing a distinct population of surface oxygen vacancies before the subject decomposition reaction could proceed. This study showed that electrochemically promoted decomposition is feasible under conditions appropriate to those found in prime mover exhausts.

  20. Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region

    SciTech Connect (OSTI)

    Steiner, A. L.; Tawfik, A. B.; Shalaby, A.; Zakey, A. S.; Abdel Wahab, M. M.; Salah, Z.; Solmon, F.; Sillman, S.; Zaveri, Rahul A.

    2014-04-16T23:59:59.000Z

    An integrated chemistry-climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on Greater Cairo (GC) region. The densley populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjuction with natural sources such as dust and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average-ground-based NO2 observations of 40-60 ppb are substantially higher than modeled estimates (5-10 ppb), likely due to model grid resolution, improper boundary layer representation, and poor emissions inventories. Observed ozone concentrations range from 35 ppb (winter) to 80 ppb (summer). The model reproduces the seasonal cycle fairly well, but modeled summer ozone is understimated by approximately 15 ppb and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry-climate model captures the springtime peak aerosol optical depth (AOD) of 0.7-1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta, yet the model underestimates this fall observed AOD peak, as standard emissions inventories underestimate this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities are needed to improve air quality simulations in this region.

  1. Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects

    E-Print Network [OSTI]

    Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects on photosynthesis to a complex canopy architecture§ M.J. Martina, *, G.E. Hosta; accepted 17 July 2001 ``Capsule'': A process model is described that predicts the relative effects of ozone

  2. Global Health and Economic Impacts of Future Ozone Pollution

    E-Print Network [OSTI]

    Webster, Mort D.

    We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the ...

  3. air pollutants ozone: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E ndoor air pollution is ranked as one of the world's greatest public health risks (Wolverton,...

  4. Apparatus and method for stabilization or oxidation of polymeric materials

    DOE Patents [OSTI]

    Paulauskas, Felix L. (Knoxville, TN) [Knoxville, TN; Sherman, Daniel M. (Knoxville, TN) [Knoxville, TN

    2010-01-19T23:59:59.000Z

    An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere at a selected temperature; a means for supporting the polymeric material within the chamber; and, a source of ozone-containing gas, which decomposes at the selected temperature yielding at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at the selected temperature. The ozone may be generated by a plasma discharge or by various chemical processes. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments as well as to make flame-retardant fabrics.

  5. NOx Emissions Reduction from Continuous Commissioning(R) Measures for the Dallas-Fort Worth International Airport

    E-Print Network [OSTI]

    Yazdani, B.; Haberl, J. S.; Baltazar-Cervantes, J. C.

    Total NOx Reductions (lbs/day) Total NOx Reductions (Tons/day) TOT EQ ELECTRICITY (MWh) (Electricity and Chilled water) 4,761 7,278.7 3.6393 24.2 36.7 0.0184 HOT WATER (MCF) 8,358 1,170.2 0.5851 41.0 5.7 0.0029 Total 8,448.9 4.2244 42.5 0....0212 NOTES: 1) Assuming 7% for T&D losses and a Discount factor of 25%. Corresponding factors to integrated savings presented to the TCEQ. 2) A factor of 0.140 lb of NOx/MCF of Natural Gas (Controlled - Low NOx burners 140 A...

  6. Heavy-duty diesel vehicle Nox? aftertreatment in 2010 : the infrastructure and compliance challenges of urea-SCR

    E-Print Network [OSTI]

    Bodek, Kristian M

    2008-01-01T23:59:59.000Z

    Increasingly stringent heavy-duty vehicle emission regulations are prompting the use of PM and NOx aftertreatment systems in the US, the EU and Japan. In the US, the EPA Highway Diesel Rule, which will be fully implemented ...

  7. Calculation of Integrated Nox Emissions Reductions from Energy Efficiency Renewable Energy (EE/RE) Programs across State Agencies in Texas

    E-Print Network [OSTI]

    Hberl, J.; Yazdani, B.; Baltazar, J. C.; Kim, H.; Mukhopadhyay, J.; Zilbershtein, G.; Ellis, S.; Parker, P.

    2013-01-01T23:59:59.000Z

    This paper presents an update of the integrated NOx emissions reductions calculations developed by the Energy Systems Laboratory (ESL) for the State of Texas to satisfy the reporting requirements for Senate Bill 5 of the Texas State Legislature...

  8. Chemical Consequences of Heme Distortion and the Role of Heme Distortion in Signal Transduction of H-NOX Proteins

    E-Print Network [OSTI]

    Olea, Jr., Charles

    2010-01-01T23:59:59.000Z

    of wild-type Tt H-NOX as well as energy minimizations 19with energy minimizations and visual inspection of the wild-high- energy frontier orbitals. 81 Heme distortion in wild-

  9. Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause-Based Climatology and Optimal Estimation Approach

    E-Print Network [OSTI]

    Pan, Laura

    Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause for retrieving atmospheric ozone profile information from advanced satellite infrared sounders, this study investigates various methods to optimize ozone retrievals. A set of retrieval experiments has been performed

  10. Purification of carbon nanotubes by dynamic oxidation in air Nikolay Dementev,a

    E-Print Network [OSTI]

    Borguet, Eric

    ) are nanometre-wide hollow carbon structures with exceptional mechanical and elec- tronic properties.1 such as oxygen, carbon dioxide, water vapor or ozone. A detailed overview of existing purification techniquesPurification of carbon nanotubes by dynamic oxidation in air Nikolay Dementev,a Sebastian Osswald

  11. Calculation of Integrated Nox Emissions Reductions from Energy Efficiency Renewable Energy (EE/RE) Programs across State Agencies in Texas 

    E-Print Network [OSTI]

    Hberl, J.; Yazdani, B.; Baltazar, J. C.; Kim, H.; Mukhopadhyay, J.; Zilbershtein, G.; Ellis, S.; Parker, P.

    2013-01-01T23:59:59.000Z

    counties through 2011 were obtained from the SECO. The integrated savings also include MWh and NOx emissions savings from the currently installed green power generation (wind) capacity in west Texas for 2001 through 2011. Projections through 2012... was assumed for PUC programs, SECO, and SEER 13 entries. Figure 1 shows the overall information flow that was used to calculate the NOx emissions savings from the annual and OSD electricity savings (MWh) from all programs. For the Laboratory?s single...

  12. Closed loop engine control for regulating NOx emissions, using a two-dimensional fuel-air curve

    DOE Patents [OSTI]

    Bourn, Gary D.; Smith, Jack A.; Gingrich, Jess W.

    2007-01-30T23:59:59.000Z

    An engine control strategy that ensures that NOx emissions from the engine will be maintained at an acceptable level. The control strategy is based on a two-dimensional fuel-air curve, in which air manifold pressure (AMP) is a function of fuel header pressure and engine speed. The control strategy provides for closed loop NOx adjustment to a base AMP value derived from the fuel-air curve.

  13. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    SciTech Connect (OSTI)

    Leng, Xiang [Brookhaven National Lab. (BNL), Upton, NY (United States); Bozovic, Ivan [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on the same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.

  14. Nox control technology data base for gas-fueled prime movers: Phase 1. Topical report, March 1985-September 1986

    SciTech Connect (OSTI)

    Thring, R.H.; Hull, R.W.; Ingalls, M.; Urban, C.; Ariga, S.

    1988-04-01T23:59:59.000Z

    Phase 1 of a study to expand the performance and life-cycle cost data base for NOx control of gas-fueled prime movers has been accomplished through experimental evaluations of fuel effects, technical literature reviews of Japanese and domestic approaches to NOx control and through direct contacts with manufacturers and users in the United States and Japan. Engine tests confirm literature findings that natural gas and methanol provide an advantage over petroleum fuels in limiting NOx formation. For lean-burn engines (e.g., two-cycle and gas turbine engines), selective catalytic reduction offers the greatest amount of NOx control. Installation, operating and maintenance costs are very high; the method has received moderate acceptance in Japan but limited use in the United States. For rich-burn engines, nonselective catalytic reduction is gaining acceptance for NOx control. This method is basically the adaption of automotive three-way catalyst technology. Further RandD is recommended for alternative methods of NOx control which include combustion-cycle modifications and noncatalytic exhaust aftertreatment.

  15. UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    A.M. HEIN; J.Y. HWANG; M.G. MCKIMPSON; R.C. GREENLUND; X. HUANG

    1998-10-01T23:59:59.000Z

    Potomac Electric Power Company (PEPCo) Class F fly ash is the first material to be worked on in this project. A head sample was taken and a screen analysis performed. Each size fraction was evaluated for LOI content. Table 1 shows the distribution of the as-received material by size and LOI content. From the data, 80% of the as-received material is finer than 400 mesh and the LOI content goes from high at coarse fractions and decreases to a low at the finest size fraction. SEM chemical analysis identified the as-received fly ash to mainly consist of silica (46%), aluminum oxide (21%), and iron in various forms (16%). The high iron content presents an extreme case as compared to other fly ash samples we have evaluated previously. Its effect on product testing applications could identify physical and chemical limitations as product testing progresses. Because of the high iron content, it was realized that magnetic separation would be incorporated into the early part of the pilot plant flowsheet to remove magnetic iron and, hopefully, reduce the total iron content. More analytical data will be presented in the next reporting period.

  16. NOx reduction in combustion with concentrated coal streams and oxygen injection

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Snyder, William J.

    2004-03-02T23:59:59.000Z

    NOx formation in the combustion of solid hydrocarbonaceous fuel such as coal is reduced by obtaining, from the incoming feed stream of fuel solids and air, a stream having a ratio of fuel solids to air that is higher than that of the feed steam, and injecting the thus obtained stream and a small amount of oxygen to a burner where the fuel solids are combusted.

  17. Current Understanding of Cu-Exchanged Chabazite Molecular Sieves for Use as Commercial Diesel Engine DeNOx Catalysts

    SciTech Connect (OSTI)

    Gao, Feng; Kwak, Ja Hun; Szanyi, Janos; Peden, Charles HF

    2013-11-03T23:59:59.000Z

    Selective catalytic reduction (SCR) of NOx with ammonia using metal-exchanged molecular sieves with a chabazite (CHA) structure has recently been commercialized on diesel vehicles. One of the commercialized catalysts, i.e., Cu-SSZ-13, has received much attention for both practical and fundamental studies. For the latter, the particularly well-defined structure of this zeolite is allowing long-standing issues of the catalytically active site for SCR in metal-exchanged zeolites to be addressed. In this review, recent progress is summarized with a focus on two areas. First, the technical significance of Cu-SSZ-13 as compared to other Cu-ion exchanged zeolites (e.g., Cu-ZSM-5 and Cu-beta) is highlighted. Specifically, the much enhanced hydrothermal stability for Cu-SSZ-13 compared to other zeolite catalysts is addressed via performance measurements and catalyst characterization using several techniques. The enhanced stability of Cu-SSZ-13 is rationalized in terms of the unique small pore structure of this zeolite catalyst. Second, the fundamentals of the catalytically active center; i.e., the chemical nature and locations within the SSZ-13 framework are presented with an emphasis on understanding structure-function relationships. For the SCR reaction, traditional kinetic studies are complicated by intra-particle diffusion limitations. However, a major side reaction, nonselective ammonia oxidation by oxygen, does not suffer from mass-transfer limitations at relatively low temperatures due to significantly lower reaction rates. This allows structure-function relationships that are rather well understood in terms of Cu ion locations and redox properties. Finally, some aspects of the SCR reaction mechanism are addressed on the basis of in-situ spectroscopic studies.

  18. FY2011 Progress Report: Agreement 8697 - NOx Sensor Development

    SciTech Connect (OSTI)

    Woo, L Y; Glass, R S

    2011-11-01T23:59:59.000Z

    Objectives are: (1) Develop an inexpensive, rapid-response, high-sensitivity and selective electrochemical sensor for oxides of nitrogen (NO{sub x}) for compression-ignition, direct-injection (CIDI) OBD II systems; (2) Explore and characterize novel, effective sensing methodologies based on impedance measurements and designs and manufacturing methods that are compatible with mass fabrication; and (3) Collaborate with industry in order to (ultimately) transfer the technology to a supplier for commercialization. Approach used is: (1) Use an ionic (O{sup 2-}) conducting ceramic as a solid electrolyte and metal or metal-oxide electrodes; (2) Correlate NO{sub x} concentration with changes in cell impedance; (3) Evaluate sensing mechanisms and aging effects on long-term performance using electrochemical techniques; and (4) Collaborate with Ford Research Center to optimize sensor performance and perform dynamometer and on-vehicle testing. Work in FY2011 focused on using an algorithm developed in FY2010 in a simplified strategy to demonstrate how data from controlled laboratory evaluation could be applied to data from real-world engine testing. The performance of a Au wire prototype sensor was evaluated in the laboratory with controlled gas compositions and in dynamometer testing with diesel exhaust. The laboratory evaluation indicated a nonlinear dependence of the NO{sub x} and O{sub 2} sensitivity with concentration. For both NO{sub x} and O{sub 2}, the prototype sensor had higher sensitivity at concentrations less than {approx}20 ppm and {approx}7%, respectively, compared to lower NO{sub x} and O{sub 2} sensitivity at concentrations greater than {approx}50 ppm and {approx}10.5%, respectively. Results in dynamometer diesel exhaust generally agreed with the laboratory results. Diesel exhaust after-treatment systems will likely require detection levels less than {approx}20 ppm in order to meet emission regulations. The relevant mathematical expressions for sensitivity in different concentration regimes obtained from bench-level laboratory evaluation were used to adjust the sensor signal in dynamometer testing. Both NO{sub x} and O{sub 2} exhibited non-linear responses over the concentration regimes examined (0-100 ppm for NO{sub x} and 4-7% for O{sub 2}). Adjusted sensor signals had better agreement with both a commercial NO{sub x} sensor and FTIR measurements. However, the lack of complete agreement indicated that it was not possible to completely account for the nonlinear sensor behavior in certain concentration regimes. The agreement at lower NO{sub x} levels (less than 20 ppm) was better than at higher levels (50-100 ppm). Other progress in FY2011 included dynamometer testing of sensors with imbedded heaters and protective housings that were mounted directly into the exhaust manifold. Advanced testing protocols were used to evaluate the sensors. These experiments confirmed the potential for sensor robustness and durability. Advanced material processing methods appropriate for mass manufacturing, such as sputtering, are also being evaluated. A major milestone for this past year was the licensing of the LLNL NO{sub x} sensor technology to EmiSense Technologies, LLC. EmiSense has extensive experience and resources for the development of emission control sensors. A CRADA is in development that will allow LLNL to work in partnership with EmiSense to bring the LLNL NO{sub x} sensor technology to commercialization. Ford Motor Company is also a partner in this effort.

  19. Millisecond Oxidation of Alkanes

    SciTech Connect (OSTI)

    Scott Han

    2011-09-30T23:59:59.000Z

    This project was undertaken in response to the Department of Energy's call to research and develop technologies 'that will reduce energy consumption, enhance economic competitiveness, and reduce environmental impacts of the domestic chemical industry.' The current technology at the time for producing 140 billion pounds per year of propylene from naphtha and Liquified Petroleum Gas (LPG) relied on energy- and capital-intensive steam crackers and Fluidized Catalytic Cracking (FCC) units. The propylene is isolated from the product stream in a costly separation step and subsequently converted to acrylic acid and other derivatives in separate production facilities. This project proposed a Short Contact Time Reactor (SCTR)-based catalytic oxydehydrogenation process that could convert propane to propylene and acrylic acid in a cost-effective and energy-efficient fashion. Full implementation of this technology could lead to sizeable energy, economic and environmental benefits for the U. S. chemical industry by providing up to 45 trillion BTUs/year, cost savings of $1.8 billion/year and a combined 35 million pounds/year reduction in environmental pollutants such as COx, NOx, and SOx. Midway through the project term, the program directive changed, which approval from the DOE and its review panel, from direct propane oxidation to acrylic acid at millisecond contact times to a two-step process for making acrylic acid from propane. The first step was the primary focus, namely the conversion of propane to propylene in high yields assisted by the presence of CO2. The product stream from step one was then to be fed directly into a commercially practiced propylene-to-acrylic acid tandem reactor system.

  20. Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado

    SciTech Connect (OSTI)

    None

    1998-07-01T23:59:59.000Z

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

  1. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31T23:59:59.000Z

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  2. System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly; Rossin, Joseph A

    2014-04-08T23:59:59.000Z

    A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

  3. Past changes in the vertical distribution of ozone – Part 3: Analysis and interpretation of trends

    E-Print Network [OSTI]

    Harris, N. R. P.; Hassler, B.; Tummon, F.; Bodeker, G. E.; Hubert, D.; Petropavlovskikh, I.; Steinbrecht, W.; Anderson, J.; Bhartia, P. K.; Boone, C. D.; Bourassa, A.; Davis, S. M.; Degenstein, D.; Delcloo, A.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Jones, N.; Kurylo, M. J.; Kyrölä, E.; Laine, M.; Leblanc, S. T.; Lambert, J.-C.; Liley, B.; Mahieu, E.; Maycock, A.; de Mazičre, M.; Parrish, A.; Querel, R.; Rosenlof, K. H.; Roth, C.; Sioris, C.; Staehelin, J.; Stolarski, R. S.; Stübi, R.; Tamminen, J.; Vigouroux, C.; Walker, K.; Wang, H. J.; Wild, J.; Zawodny, J. M.

    2015-03-23T23:59:59.000Z

    Trends in the vertical distribution of ozone are reported and compared for a number of new and recently revised datasets. The amount of ozone-depleting compounds in the stratosphere (as measured by Equivalent Effective Stratospheric Chlorine – EESC...

  4. A delayed effect of ozone fumigation on photosynthesis of Norway spruce

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A delayed effect of ozone fumigation on photosynthesis of Norway spruce D. Eamus1 A.W. Davis J into the long-lastincl effects of ozone fumiga- tion upon photosynthesis of Norway spruce. Measurements were

  5. E-Print Network 3.0 - acid regulates ozone-induced Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ozone-induced Search Powered by Explorit Topic List Advanced Search Sample search results for: acid regulates ozone-induced Page: << < 1 2 3 4 5 > >> 1 Plant Molecular Biology 51:...

  6. Comparison of three vertically resolved ozone data sets: climatology, trends and radiative forcings

    E-Print Network [OSTI]

    Hassler, B.

    Climate models that do not simulate changes in stratospheric ozone concentrations require the prescription of ozone fields to accurately calculate UV fluxes and stratospheric heating rates. In this study, three different ...

  7. Environmental factors affecting the permitting of a gas turbine cogeneration system located in an area designated non-attainment for ozone and carbon monoxide

    SciTech Connect (OSTI)

    Memarzadeh, F. [National Inst. of Health, Bethesda, MD (United States). Office of Research

    1994-12-31T23:59:59.000Z

    This paper will describe air permitting regulations that apply to a new cogeneration facility or the modification of any existing facility. The permitting depends on several factors including the attainment status of the emitted criteria pollutants within the project area, with the facility classified as either a ``major new source`` or a ``major modification``. Depending on the attainment status of a given pollutant, either the Prevention of Significant Deterioration (PSD) or the Non-attainment area (NAA) regulations (Title I of the Clean Air Act Amendments of 1990) will apply for that pollutant. Since the greatest percentage of emissions generated by a gas turbine are nitrogen oxides (ozone precursors) and carbon monoxide this paper presents an overview of clean air regulations pertinent to those areas of the country that are designated as attaining the National Ambient Air Quality Standards (NAAQS) for sulphur dioxide (SO{sub 2}), particulate matter (PM), nitrogen oxides (NO{sub x}) and lead (Pb), and as areas of nonattainment for ozone (O{sub 3}) and carbon monoxide (CO). A hypothetical case is presented and all the environmental issues such as applicability of PSD and NAA regulations, available pollution offsets, and air quality compliance requirements for a modification to an existing facility located in a serious ozone and moderate carbon monoxide non-attainment area will be illustrated.

  8. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01T23:59:59.000Z

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  9. Gille-ESYS 10 1 Is I had a billion dollars to save the ozone layer ....

    E-Print Network [OSTI]

    Gille, Sarah T.

    Gille-ESYS 10 1 Is I had a billion dollars to save the ozone layer .... The scene: A backyard-destroying metered dose inhalers? If I had a billion dollars to save the ozone layer, I'd spend it all to get rid to save the ozone layer, I'd worry more about methyl bromide, which is not only an ozone destroyer

  10. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F. [Russian Academy of Sciences, Kemerovo (Russian Federation)

    2007-05-15T23:59:59.000Z

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  11. Meteorological Simulations of Ozone Episode Case Days during the 1996 Paso del Norte Ozone Study

    SciTech Connect (OSTI)

    Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

    1999-02-01T23:59:59.000Z

    Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13,1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were petiormed using the HOTMAC mesoscale meteorological model using a 1,2,4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11-13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawirisonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. We found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

  12. Meteorological simulations of ozone episode case days during the 1996 Paso del Norte ozone study

    SciTech Connect (OSTI)

    Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

    1999-07-01T23:59:59.000Z

    Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13, 1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were performed using the HOTMAC mesoscale meteorological model using a 1, 2, 4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11--13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawinsonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. The authors found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

  13. Development of an ozone climatology for Harris County, Texas

    SciTech Connect (OSTI)

    Balentine, H.W.; Carter, J.C. (Radian Corp., Austin, TX (USA)); Preston, J. (Tenneco Polymers, Houston, TX (US))

    1987-01-01T23:59:59.000Z

    The Houston Regional Monitoring Corporation (HRM) has performed continuous ambient air quality and meteorological monitoring in the Ship Channel area of east Harris County since August 1981. The HRM monitoring network is one of the largest Environmental Protection Agency (EPA) approved Prevention of Significant Deterioration (PSD) monitoring network in the United States operated by an industrial group. As an adjunct to its monitoring. HRM has funded extensive meteorological and statistical analyses of ozone monitoring data in Harris County. One of the goals of these studies was to determine those meteorological conditions responsible for the formation of elevated ozone concentrations in Harris County. The analyses performed included the use of principal component analysis and cluster analysis. These analysis techniques have individually been applied to ozone and air quality research problems. The combined use of these techniques in this analysis, however, is a unique application of these statistical tools to an ozone air quality analysis. As a result of these analyses, a climatology of those episodes conducive to elevated ozone formation in Harris County was developed.

  14. Comparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane

    E-Print Network [OSTI]

    Jacobson, Mark

    Comparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane is the effects of aviation emissions on ozone and atmospheric chemistry. In this study the effects of aviation emissions on atmospheric ozone for 2006 and two projections for 2050 are compared among seven models

  15. Efficient quantum-classical method for computing thermal rate constant of recombination: Application to ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    : Application to ozone formation Mikhail V. Ivanov and Dmitri Babikov Citation: J. Chem. Phys. 136, 184304 (2012 for computing thermal rate constant of recombination: Application to ozone formation Mikhail V. Ivanov of ozone. Comparison of the predicted rate vs. experimental result is presented. © 2012 American Institute

  16. Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun

    E-Print Network [OSTI]

    Folkins, Ian

    Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun Department] The climatological ozone profile in the tropics is shaped like an ``S,'' with a minimum at the surface, a maximum. These features can be reproduced by a very simple model whose only free parameter is the mean ozone mixing ratio

  17. Ozone database in support of CMIP5 simulations: results and corresponding

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing 1234567 Attribution 3.0 License. Atmospheric Chemistry and Physics Ozone database in support of CMIP5 simulations 2011 Abstract. A continuous tropospheric and stratospheric ver- tically resolved ozone time series

  18. A review of statistical methods for the meteorological adjustment of tropospheric ozone

    E-Print Network [OSTI]

    Washington at Seattle, University of

    A review of statistical methods for the meteorological adjustment of tropospheric ozone Mary Lou adjustment of tropospheric ozone Mary Lou Thompson1 Joel Reynolds1 Lawrence H. Cox2 Peter Guttorp1 Paul D.larry@epamail.epa.gov ABSTRACT: A variety of statistical methods for meteorological adjustment of ozone have been proposed

  19. Effects of ozone cooling in the tropical lower stratosphere and upper troposphere

    E-Print Network [OSTI]

    Effects of ozone cooling in the tropical lower stratosphere and upper troposphere Piers M. Forster lower stratosphere and upper troposphere and elucidate the key role of ozone changes in driving of tropical ozone decreases at 70 hPa and lower pressures can lead to significant cooling not only

  20. THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING BAYESIAN MODELS

    E-Print Network [OSTI]

    West, Mike

    THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING University. The authors thank Alex Guenther for supplying the high frequency ozone concentration measurements a multiscale Bayesian model for separating ozone (O 3 ) concentration turbulent fluctuations from such inherent

  1. Ensemble-based air quality forecasts: A multimodel approach applied to ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1 21 September 2006. [1] The potential of ensemble techniques to improve ozone forecasts ozone-monitoring networks. We found that several linear combinations of models have the potential

  2. Conditional quantiles when the covariates are curves : an application to Ozone pollution

    E-Print Network [OSTI]

    Bercu, Bernard

    Conditional quantiles when the covariates are curves : an application to Ozone pollution forecasting Summary This work deals with the study of pollution data with the aim of forecas- ting the Ozone of the maximum of Ozone one day kno- wing one or several of these functional variables the day before. To do this

  3. Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a)

    E-Print Network [OSTI]

    Reid, Scott A.

    Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a) Brian K for an anomalous isotope effect in ozone formation is given in terms of the energy transfer mechanism, where the metastable states of ozone are formed first, and then stabilized by collisions with other atoms. Unusual

  4. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean 

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31T23:59:59.000Z

    Despite the known reactivity of ozone (O_(3)) in water and ozone’s environmental importance in the atmosphere, there are relatively few studies published examining the chemistry of O_(3) in seawater. This study focused on developing a flow injection...

  5. Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air Purifiers

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air ozone (O3) during operation, either in- tentionally or as a byproduct of air ionization standards. Sev- eral types of air purifiers were tested for their ability to produce ozone in various indoor

  6. Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone treatment

    E-Print Network [OSTI]

    Parikh, Atul N.

    Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone (structure code: MFI) following a previously published procedure. The films were illuminated using an ozone. Results presented here indicate that the UV/ozone treatment under nominally room temperature conditions

  7. EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH

    E-Print Network [OSTI]

    McKendry, Ian

    EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH, hourly average ozone concentrations were mea- sured at three sites of differing elevation (188, 588. Sites experienced ozone concentrations ranging from 0 to 88 ppb in 2001, and 0 to 96 ppb in 2002. Daily

  8. Seasonal persistence of northern low-and middle-latitude anomalies of ozone and

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases #12;Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases 10 July 2008; accepted 23 July 2008; published 11 November 2008. [1] Analysis of observed ozone

  9. Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend

    E-Print Network [OSTI]

    Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend W. J. Collins, R of circulation changes in a changed climate on the exchange of ozone between the stratosphere and the troposphere. We have identified an increase in the net transport of ozone into the troposphere in the future

  10. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. , NO. , PAGES 1?? , Analysis of 19701995 Trends in Tropospheric Ozone at

    E-Print Network [OSTI]

    Jacob, Daniel J.

    in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS­CHEM Model Andrew C. Fusco Department. The causes of trends in tropospheric ozone at Northern Hemisphere mid­ latitudes from 1970 to 1995 to investigate the sensitivity of tropospheric ozone with respect to (1) changes in the anthropogenic emission

  11. The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation

    E-Print Network [OSTI]

    Waugh, Darryn W.

    The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation Luke D impact on tropospheric circulation causes significant changes to the distribution of ozone. Here we derive the lower tropospheric to lower stratospheric ozone response to ENSO from observations

  12. Semiclassical molecular dynamics simulations of ultrafast photodissociation dynamics associated with the Chappuis band of ozone

    E-Print Network [OSTI]

    Miller, William H.

    with the Chappuis band of ozone Victor S. Batista and William H. Millera) Department of Chemistry, University A ) of ozone following photoexcitation of the molecule in the gas phase with visible light. Our algorithm and recurrence events, as well as an interpretation of experimental studies of the Chappuis band of ozone

  13. Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery 1234567 89A64BC7DEF72B4BE647 #12;Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery J. F. Scinocca,1. [1] We investigate the sensitivity of Northern Hemisphere polar ozone recovery to a scenario in which

  14. PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on

    E-Print Network [OSTI]

    PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone. Kelly*1 The corrosion of Ag in an atmosphere of ozone and humidity with or without irradiation corrosion product to chloride in the reduction solution. The presence of both ozone and UV radiation

  15. How Bromate and Ozone Concentrations can be Modelled at Full Scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 How Bromate and Ozone Concentrations can be Modelled at Full Scale based on Lab-Scale Experiments ­ A Case Study Running head title How to model bromate & ozone at full scale based on lab tests Pierre-scale modelling study of an industrial ozonation unit for practical application. The modelling framework combines

  16. A global picture of the seasonal persistence of stratospheric ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    A global picture of the seasonal persistence of stratospheric ozone anomalies 1234567 89A64BC7DEF72 ozone anomalies S. Tegtmeier,1,2 V. E. Fioletov,1 and T. G. Shepherd3 Received 13 August 2009; revised in vertical profiles of stratospheric ozone, in both equatorial and extratropical regions, have been shown

  17. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  18. Technical note Barriers and opportunities for passive removal of indoor ozone

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Technical note Barriers and opportunities for passive removal of indoor ozone Elliott T. Gall presents a Monte Carlo simulation to assess passive removal materials (PRMs) that remove ozone of homes in Houston, Texas, were taken from the literature and combined with back- ground ozone removal

  19. Evaluating Ozone Air Pollution Effects on Pines in the Western United States

    E-Print Network [OSTI]

    Standiford, Richard B.

    Evaluating Ozone Air Pollution Effects on Pines in the Western United States United States. Evaluating ozone air pollution effects on pines in the western United States. Gen. Tech. Rep. PSW­GTR­155. Historical and technical background is provided about ozone air pollution effects on ponderosa (Pinus

  20. Semiclassical wave packet study of anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Semiclassical wave packet study of anomalous isotope effect in ozone formation Evgeny Vetoshkin represent the metastable O3 * species and play a central role in the process of ozone formation.1063/1.2778432 I. INTRODUCTION Ozone O3 is formed in the stratosphere as a product of the following recombination