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1

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network (OSTI)

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

2

Nitrogen Oxides (NOx), Why and How They are Controlled  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

3

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10li.pdf More Documents & Publications Lean NOx Trap...

4

Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms  

E-Print Network (OSTI)

Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

Martin, Katherine C.

2007-01-01T23:59:59.000Z

5

Observation of NOx enhancement and ozone depletion in the Northern and Southern  

E-Print Network (OSTI)

Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, and H. Fischer Institut fu¨r Meteorologie und Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, H. Fischer, and C. H. Jackman (2005), Observation of NOx

Jackman, Charles H.

6

Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2010-09-15T23:59:59.000Z

7

Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbates storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2011-04-20T23:59:59.000Z

8

Establishing Policy Relevant Background (PRB) Ozone Concentrations in the United States  

Science Journals Connector (OSTI)

National Oceanic and Atmospheric Administration, Boulder, Colorado ... Processes that contribute to PRB ozone concentrations include photochemistry associated with natural emissions of volatile organic compounds (VOCs), nitrogen oxides (NOx), and carbon monoxide (CO) from sources such as biogenic emissions (not including agricultural activities), wildfires, lightning, the long-range transport of ozone and its precursors from outside of North America, and stratospheric-tropospheric exchange (STE) of ozone. ... Models generally find little ozone production in wildfire plumes for short aging times (days) because NOx emissions are low and conversion to peroxyacetylnitrate (PAN) is rapid. ...

Elena C. McDonald-Buller; David T Allen; Nancy Brown; Daniel J. Jacob; Daniel Jaffe; Charles E. Kolb; Allen S. Lefohn; Samuel Oltmans; David D. Parrish; Greg Yarwood; Lin Zhang

2011-10-10T23:59:59.000Z

9

16 - Ultra-low nitrogen oxides (NOx) emissions combustion in gas turbine systems  

Science Journals Connector (OSTI)

Abstract: The historical development of gas turbine low \\{NOx\\} combustion from the pioneering NASA work in the early 1970s to the present generation of ultra-low \\{NOx\\} industrial gas turbine combustors is reviewed. The principles of operation of single digit ultra-low \\{NOx\\} gas turbine combustion for industrial applications are outlined. The review shows the potential has been demonstrated by several investigators using different flame stabilizers for \\{NOx\\} to be reduced to 1ppm at 1700K, 2ppm at 1800K and 34ppm at 1900K with no influence of operating pressure and with a practical operating flame stability margin. Under these conditions it is shown that no thermal \\{NOx\\} should occur and all the \\{NOx\\} is formed by the prompt \\{NOx\\} mechanisms. The elimination of thermal \\{NOx\\} makes the \\{NOx\\} emissions independent of residence time or reference velocity and independent of pressure. Also there is no influence of air inlet temperature for the same flame temperature. Where legislation requires emissions to be as low as can be achieved, emissions below 4ppm in production engines are current technology and this review shows the potential to get even lower than this in the future.

G.E. Andrews

2013-01-01T23:59:59.000Z

10

Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

Presents latest progress in the development of a new type of lean NOx trapping catalyst based on heterogenous composite nanowires, which could potentially be used in gasoline and diesel engines.

11

Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ambient Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts DOE's Studies of WeekdayWeekend Ozone Pollution in Southern...

12

JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System  

SciTech Connect

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

Scott Tolbert; Steven Benson

2008-02-29T23:59:59.000Z

13

Sensitivity Analysis of Ozone Formation and Transport for a Central  

NLE Websites -- All DOE Office Websites (Extended Search)

Sensitivity Analysis of Ozone Formation and Transport for a Central Sensitivity Analysis of Ozone Formation and Transport for a Central California Air Pollution Episode Title Sensitivity Analysis of Ozone Formation and Transport for a Central California Air Pollution Episode Publication Type Journal Article Year of Publication 2008 Authors Jin, Ling, Shaheen R. Tonse, Daniel S. Cohan, Xianglei Mao, Robert A. Harley, and Nancy J. Brown Journal Environmental Science & Technology Volume 42 Start Page 3683 Issue 10 Pagination 3683-3689 Date Published 05/2008 Abstract We developed a first- and second-order sensitivity analysis approach with the decoupled direct method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a 5 day ozone episode (Jul 29th to Aug 3rd, 2000). Despite considerable spatial variations, nitrogen oxides (NOx) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8 h ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1 h ozone standard. Interbasin source contributions of NOx emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NOx and AVOC, and the rate coefficient of the OH + NO2 termination reaction, have the greatest effect on first-order ozone responses to changes in NOx emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

14

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

for Application in Solid Oxide Fuel Cells", (DoctoralImpedance of Solid Oxide Fuel Cell LSM/YSZ CompositeCathode materials of solid oxide fuel cells: a review, J

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

15

Industry-Utility Collaborative Efforts to Address Environmental Concerns- Dispatching for Localized NOx Reduction  

E-Print Network (OSTI)

these objectives. The approach involves dispatching NOx-producing equipment (e.g., boilers and gas turbines) to achieve minimum NOx production during ozone alert periods and purchasing supplemental power under a special tariff to replace any loss in self...

Hamilton, D. E.; Helmick, R. W.; Lambert, W. J.

16

Production of ozone and nitrogen oxides by laser filamentation  

SciTech Connect

We have experimentally measured that laser filaments in air generate up to 10{sup 14}, 3x10{sup 12}, and 3x10{sup 13} molecules of O{sub 3}, NO, and NO{sub 2}, respectively. The corresponding local concentrations in the filament active volume are 10{sup 16}, 3x10{sup 14}, and 3x10{sup 15} cm{sup -3}, and allows efficient oxidative chemistry of nitrogen, resulting in concentrations of HNO{sub 3} in the parts per million range. The latter forming binary clusters with water, our results provide a plausible pathway for the efficient nucleation recently observed in laser filaments.

Petit, Yannick; Henin, Stefano; Kasparian, Jerome; Wolf, Jean-Pierre [GAP Biophotonics, Universite de Geneve, 20 rue de l'Ecole de Medecine, CH1211 Geneve 4 (Switzerland)

2010-07-12T23:59:59.000Z

17

NOx | OpenEI  

Open Energy Info (EERE)

NOx NOx Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx SO2 sulfur dioxide emissions

18

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation...

19

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network (OSTI)

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

20

Reducing NOx in Fired Heaters and Boilers  

E-Print Network (OSTI)

-6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... it is essential to estimate accurately baseline NOx emissions. ? This will establish each units current compliance status. ? Emissions ? Current excess air level ? Carbon monoxide ? Combustibles ? NOx corrected to 3% 02 314 ESL-IE-00-04-46 Proceedings...

Garg, A.

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

22

Formation of ozone and oxidation of methane in a direct current corona discharge  

E-Print Network (OSTI)

than in the positive corona when using air, while the reverse was observed with oxygen. At low currents and high gas flow rates, the ozone production rate increased linearly with corona current independent of gas flow rate. At high currents... humidity) and positive corona. Their results show: (1) a linear relation between ozone concentration and corona current; (2) an (non- linear) inverse relation between the ozone concentration and air flow; and (3) for a given corona current, the ozone...

Tangirala, Umashanker

1976-01-01T23:59:59.000Z

23

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

2001-10-10T23:59:59.000Z

24

A Return Stroke NOx Production Model  

Science Journals Connector (OSTI)

A model is introduced for estimating the nitrogen oxides (NOx = NO + NO2) production from a lightning return stroke channel. A realistic Modified Transmission Line Model return stroke current is assumed to propagate vertically upward along a ...

William J. Koshak; Richard J. Solakiewicz; Harold S. Peterson

25

Wastewater Ozonation Catalyzed by Iron  

Science Journals Connector (OSTI)

Another attempt to improve ozonation removal efficiency is the use of metals or their oxides to catalyze ozonation. ... The waveforms were generated by a potentiostat BAS model Epsilon-2. ... Sreethawong, T.; Chavadej, S.Color removal of distillery wastewater by ozonation in the absence and presence of immobilized iron oxide catalyst J. Hazard. ...

Anaid Cano Quiroz; Carlos Barrera-Di?az; Gabriela Roa-Morales; Patricia Balderas Herna?ndez; Rubi? Romero; Reyna Natividad

2010-09-23T23:59:59.000Z

26

Atmospheric pressure gas plasma-induced colorectal cancer cell death is mediated by Nox2ASK1 apoptosis pathways and oxidative stress is mitigated by SrxNrf2 anti-oxidant system  

Science Journals Connector (OSTI)

Abstract Atmospheric pressure gas plasma (AGP) generates reactive oxygen species (ROS) that induce apoptosis in cultured cancer cells. The majority of cancer cells develop a ROS-scavenging anti-oxidant system regulated by Nrf2, which confers resistance to ROS-mediated cancer cell death. Generation of ROS is involved in the AGP-induced cancer cell death of several colorectal cancer cells (Caco2, HCT116 and SW480) by activation of ASK1-mediated apoptosis signaling pathway without affecting control cells (human colonic sub-epithelial myofibroblasts; CO18, human fetal lung fibroblast; MRC5 and fetal human colon; FHC). However, the identity of an oxidase participating in AGP-induced cancer cell death is unknown. Here, we report that AGP up-regulates the expression of Nox2 (NADPH oxidase) to produce ROS. RNA interference designed to target Nox2 effectively inhibits the AGP-induced ROS production and cancer cell death. In some cases both colorectal cancer HT29 and control cells showed resistance to AGP treatment. Compared to AGP-sensitive Caco2 cells, HT29 cells show a higher basal level of the anti-oxidant system transcriptional regulator Nrf2 and its target protein sulfiredoxin (Srx) which are involved in cellular redox homeostasis. Silencing of both Nrf2 and Srx sensitized HT29 cells, leads to ROS overproduction and decreased cell viability. This indicates that in HT29 cells, Nrf2/Srx axis is a protective factor against AGP-induced oxidative stress. The inhibition of Nrf2/Srx signaling should be considered as a central target in drug-resistant colorectal cancer treatments.

Musarat Ishaq; Margaret D.M. Evans; Kostya (Ken) Ostrikov

2014-01-01T23:59:59.000Z

27

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx Reduction Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx...

28

Low NOx combustion system for heavy oil  

SciTech Connect

As a result of the increasing demand for white oil as one of countermeasures for pollution control and as a fuel for motor vehicle, coupled with the increasing import of heavy crude oil, heavy oils such as asphalt and distillation residue have become surplus in Japan. It is difficult by the conventional low NOx technology to control the NOx emission from the industrial small and medium capacity boilers, which use heavy oil as their fuels. The authors have been developing and improving NOx control technologies for boilers such as low NOx burners, two-stage combustion methods and so on. They have developed a new combustion system for heavy oil, which generates less NOx and soot than conventional systems, by applying the knowledge, obtained in the course of their development of Coal Partial Combustor (CPC). The conventional low NOx combustion method for oil firing boilers has been developed based on decreasing the flame temperature and delaying the combustion reaction. In the system, however, the heavy oil shall be combusted in the intense reducing atmosphere at the high flame temperature between 1,500 C and 1,600 C, and then the combustions gas shall be cooled and oxidized by two-stage combustion air. With this system, NOx emission can be suppressed below 100ppm (converted as O{sub 2}=4%).

Kurata, Chikatoshi; Sasaki, Hideki

1999-07-01T23:59:59.000Z

29

Low NOx combustion  

SciTech Connect

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

30

Low NOx combustion  

SciTech Connect

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

31

Fe Promoted NOx Storage Materials: Structural Properties and NOx Uptake  

Science Journals Connector (OSTI)

According to the European Union regulations (EURO VI),(2) by the end of 2014, diesel passenger cars will be subject to a 3-fold decrease in NOx emissions from 0.25 to 0.08 g km?1. ... Barium oxide crystallizes in the rock salt structure, and the first order Raman scattering is symmetry forbidden(32, 33) However, broad and weak bands within 350?500 cm?1 due to the lattice modes of the defective BaO domains can still be visible via Raman spectroscopy (see for instance, Figure 3 in the Supporting Information). ...

Emine Kayhan; Stanislava M. Andonova; Go?ksu S. S?entu?rk; Charles C. Chusuei; Emrah Ozensoy

2009-12-11T23:59:59.000Z

32

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

33

Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

41 - Nox Budget Trading 41 - Nox Budget Trading Program (Rhode Island) Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These regulations apply to units that serve generators with a nameplate capacity greater than 15 MWe and sell any amount of electricity, as well as to units that have a maximum

34

Growth behavior and properties of atomic layer deposited tin oxide on silicon from novel tin(II)acetylacetonate precursor and ozone  

SciTech Connect

In this work, a novel liquid tin(II) precursor, tin(II)acetylacetonate [Sn(acac){sub 2}], was used to deposit tin oxide films on Si(100) substrate, using a custom-built hot wall atomic layer deposition (ALD) reactor. Three different oxidizers, water, oxygen, and ozone, were tried. Resulting growth rates were studied as a function of precursor dosage, oxidizer dosage, reactor temperature, and number of ALD cycles. The film growth rate was found to be 0.1??0.01?nm/cycle within the wide ALD temperature window of 175300?C using ozone; no film growth was observed with water or oxygen. Characterization methods were used to study the composition, interface quality, crystallinity, microstructure, refractive index, surface morphology, and resistivity of the resulting films. X-ray photoelectron spectra showed the formation of a clean SnO{sub x}Si interface. The resistivity of the SnO{sub x} films was calculated to be 0.3?? cm. Results of this work demonstrate the possibility of introducing Sn(acac){sub 2} as tin precursor to deposit conducting ALD SnO{sub x} thin films on a silicon surface, with clean interface and no formation of undesired SiO{sub 2} or other interfacial reaction products, for transparent conducting oxide applications.

Kannan Selvaraj, Sathees [Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607 (United States); Feinerman, Alan [Department of Electrical and Computer Engineering, University of Illinois at Chicago, Chicago, Illinois 60607 (United States); Takoudis, Christos G., E-mail: takoudis@uic.edu [Departments of Bioengineering and Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607 (United States)

2014-01-15T23:59:59.000Z

35

NOx Reduction from Biodiesel Fuels  

Science Journals Connector (OSTI)

NOx Reduction from Biodiesel Fuels ... NOx emissions appear to be different for biodiesels from different feedstocks. ... For the suite of biodiesels prepared from nearly pure fatty acids, all biodiesel fuels produced higher NOx than certification diesel with the following exceptions:? methyl palmitate, methyl laurate, ethyl stearate, and the ethyl ester of hydrogenated soybean oil. ...

Sandun Fernando; Chris Hall; Saroj Jha

2005-11-19T23:59:59.000Z

36

Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas  

E-Print Network (OSTI)

High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

Nam, Junsang

2007-01-01T23:59:59.000Z

37

Understanding the Distributed Intra-Catalyst Impact of Sulfation on Water Gas Shift in a Lean NOx Trap Catalyst  

Energy.gov (U.S. Department of Energy (DOE))

The Lean NOx Trap catalyst is an aftertreatment technology for abatement of nitrogen-oxide emissions from lean-burn vehicle engines.

38

Reduction of NOx emission on NiCrAl-Titanium Oxide coated direct injection diesel engine fuelled with radish (Raphanus sativus) biodiesel  

Science Journals Connector (OSTI)

The main aim of this study is the experimental investigation of single cylinder DI diesel engine with and without coating. Diesel and radish (Raphanus sativus) oil Methyl Ester are used as fuels and the results are compared to find the effect of biodiesel in a thermal barrier coating engine. For this purpose engine cylinder head valves and piston crown are coated with 100??m of nickel-chrome-aluminium bond coat and 450??m of TiO2 by the plasma spray method. Radish oil methyl ester is produced by the transesterification process method. From the experimental investigation slight increase in specific fuel consumption in thermal barrier coating engine is observed when compared with the uncoated engine whereas NOx HC Smoke and CO emissions decreased with coated engine for all test fuels used in the coated engine when compared with that of the uncoated engine.

V. Ravikumar; D. Senthilkumar

2013-01-01T23:59:59.000Z

39

Stratospheric ozone depletion  

Science Journals Connector (OSTI)

...atmospheric lifetimes. The water solubility of the CFCs is very...surface back into the gas phase, where they...sufficient additional water molecules can accumulate...stratospheric ozone by nitrogen oxide catalysts from...Gille, J.C1986The water vapor budget of the...

2006-01-01T23:59:59.000Z

40

A post-Kyoto partner: Considering the stratospheric ozone regime as a tool to manage nitrous oxide  

Science Journals Connector (OSTI)

...There is a balance between ozone production...because the mass of N 2 O...such as wastewater, are developing...such as wastewater treatment and aquaculture...coal power plants) emit N...how to balance funding...nitric acid plants in the United...

David Kanter; Denise L. Mauzerall; A. R. Ravishankara; John S. Daniel; Robert W. Portmann; Peter M. Grabiel; William R. Moomaw; James N. Galloway

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

11USDA Forest Service Gen. Tech. Rep. PSW-GTR-166. 1998. Urban air basin produced oxidants, notably ozone, induce a decline in productivity in plants. This loss of productivity  

E-Print Network (OSTI)

11USDA Forest Service Gen. Tech. Rep. PSW-GTR-166. 1998. Abstract Urban air basin produced oxidants, notably ozone, induce a decline in productivity in plants. This loss of productivity is manifested have been well-studied: increased production and more rapid turnover of antioxidant systems; production

Standiford, Richard B.

42

Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz  

E-Print Network (OSTI)

potential than emissions in the United States to perturb the global oxidizing power of the atmosphere. #12% of NOx concentrations in the lower and middle troposphere throughout the extratropical northern of the ocean. Sources in the United States are found to contribute about half of the fossil fuel NOx over

Jacob, Daniel J.

43

Measurement and Characterization of NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects...

44

NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY  

E-Print Network (OSTI)

. Atmospheric scientists examine O3 production and transport through measurements, analysis, and the application Canada, the United States, and Mexico. Although policy recommendations are not within the purview organic compounds (VOCs) and nitrogen oxides (NOx ) are exposed to sunlight. Since the emissions

45

NETL: Advanced NOx Emissions Control: Control Technology - NOx Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions from Multi-Burners Emissions from Multi-Burners The University of Utah working with Reaction Engineering International and Brigham Young University is investigating a project that consists of integrated experimental, theoretical and computational modeling efforts. The primary objective is to evaluate NOx formation/destruction processes as they occur in multi-burner arrays, a geometry almost always utilized in utility practice. Most controlled experimental work examining NOx has been conducted on single burners. The range of potential intra-burner interactions are likely to provide added degrees of freedom for reducing NOx. The resultant findings may allow existing utilities to arrange fuel and air distribution to minimize NOx. In new applications, orientation of individual burners within an array may also be altered to reduce NOx. Comprehensive combustion codes will be modified to incorporate the latest submodels of nitrogen release and heterogeneous chemistry. Comparison of pilot scale experiments and simulations will be utilized to validate/develop theory.

46

Compact Potentiometric NOx Sensor | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Potentiometric NOx Sensor Compact Potentiometric NOx Sensor 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

47

9, 11231155, 2009 Lightning NOx  

E-Print Network (OSTI)

of lightning intensities. By im-20 posing an updated lightning NO production value of 520 mol NO/Flash, weACPD 9, 1123­1155, 2009 Lightning NOx emissions over the USA investigated using TES L. Jourdain et to the corresponding final paper in ACP if available. Lightning NOx emissions over the USA investigated using TES, NLDN

48

Pulsed ozone generation in oxygen  

SciTech Connect

Ozone is a powerful oxidant and bactericide which is increasingly replacing chlorine in applications such as potable water treatment, swimming pool water sterilisation and bleaching. Ozone can be produced in a number of ways but the conventional method (1) is by producing an AC barrier discharge in a uniform-field arrangement containing a thin dielectric barrier. The process is highly inefficient with most of the energy supplied being converted to unwanted heat. Thus ozone treatment, although environmentally {open_quotes}friendly{close_quotes}, tends to be more costly and so there is a compelling argument for investigating ways of increasing the efficiency.

Chalmers, I.D.; Zanella, L.; MacGregor, S.J. [Univ. of Strathclyde, Glasgow (Germany)] [and others

1995-12-31T23:59:59.000Z

49

NETL: Advanced NOx Emissions Control: Control Technology - Model for NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

Model for NOx Emissions in Biomass Cofiring Model for NOx Emissions in Biomass Cofiring Southern Research Institute is developing a validated tool or methodology to accurately and confidently design and optimize biomass-cofiring systems for full-scale utility boilers to produce the lowest NOX emissions and the least unburned carbon. The computer model will be validated through an extensive set of tests at the 6 MMBtu/hr pilot combustor in the Southern Company/Southern Research Institute Combustion Research Facility. Full-scale demonstration testing can be compared to the model for further validation. The project is designed to balance the development of a systematic and expansive database detailing the effects of cofiring parameters on NOx formation with the complementary modeling effort that will yield a capability to predict, and therefore optimize, NOx reductions by the selection of those parameters. The database of biomass cofiring results will be developed through an extensive set of pilot-scale tests at the Southern Company/Southern Research Institute Combustion Research Facility. The testing in this program will monitor NOx, LOI, and other emissions over a broad domain of biomass composition, coal quality, and cofiring injection configurations to quantify the dependence of NOx formation and LOI on these parameters. This database of cofiring cases will characterize an extensive suite of emissions and combustion properties for each of the fuel and injection configuration combinations tested.

50

Nox1 and Nox4 enzymes are persistently elevated in human hepatocytes producing infectious hepatitis C virus  

E-Print Network (OSTI)

location of NOX4 and NOX1 enzymes by cell fractionation. 6.13. Proposed role of hepatocyte NOX enzymes in HCV-inducedMERCED Nox1 and Nox4 enzymes are persistently elevated in

Reyes de Mochel, Nabora Soledad

2009-01-01T23:59:59.000Z

51

On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California  

E-Print Network (OSTI)

The San Joaquin Valley (SJV) experiences some of the worst ozone air quality in the US, frequently exceeding the California 8 h standard of 70.4 ppb. To improve our understanding of trends in the number of ozone violations ...

Pusede, S. E.

52

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network (OSTI)

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% ...

Grenfell, J L; Patzer, B; Rauer, H; Segura, A; Stadelmann, A; Stracke, B; Titz, R; Von Paris, P; Grenfell, John Lee; Griessmeier, Jean-Mathias; Patzer, Beate; Rauer, Heike; Segura, Antigona; Stadelmann, Anja; Stracke, Barbara; Titz, Ruth; Paris, Philip von

2007-01-01T23:59:59.000Z

53

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

54

Controlling NOx to Obtain Offsets or Meet Compliance  

E-Print Network (OSTI)

monitored and regu lated a number of pollutants: lead, carbon monoxide, oxides of sulfur, oxides of nitrogen, ozone and PM-lO. The Clean Air Act Amendments increased the focus on these pollutants, mandating the reductions to specified limits. Title I...

Mincy, J. E.

55

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, First quarter 1991  

SciTech Connect

This project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 (LS-2) located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This quarterly update provides a description of the flow modeling study. This modeling effort centers on evaluating the in-furnace flow and mixing phenomena for the various low NOx firing systems being demonstrated at LS-2. Testing on the 1/12 scale model of the LS-2 boiler and the 1/6 scale model of the overfire air ductwork was completed. The test matrix included an analysis of the overfire air ductwork and three different boiler configurations. This report also contains results from the Phase 1 baseline tests. Data from the diagnostic, performance, and verification tests are presented. In addition, NOx emissions data and unit load profiles collected during long-term testing are reported. At the full load condition, the baseline NOx emission level at LS-2 is 0.62 lb/mBtu.

Not Available

1991-12-31T23:59:59.000Z

56

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, Third quarter 1992  

SciTech Connect

The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving 50% NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level 1 long-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-12-31T23:59:59.000Z

57

The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NO ) Emissions From Coal-Fired Boilers X Demonstration Project: A DOE Assessment March 2000 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

58

NOx Sensor Development  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

zirconia (PSZ) for better mechanical properties * (bottom) Dense LSM (Strontium-doped lanthanum manganite oxide) with yttria fully- stabilized zirconia (YSZ) for...

59

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single Leg NOx Adsorber...

60

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Development of Chemical Kinetic Models for Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps...

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Advanced furnace air staging and burner modifications for ultra-low NOx firing systems  

SciTech Connect

Overfire air is an effective means to reduce NOx emissions from coal fired furnaces. The current range of overfire air usage on wall-fired boilers in the US is in the range of 10 to 20%. In most cases this is enough to achieve current Title IV NOx reduction requirements. Future applications are likely to go beyond 20% Overfire Air to reduce NOx further for lower investment and operating costs of SCR retrofits. Summer ozone reduction requires NOx emissions of 0.15 lb/MBtu. Currently, industry is exploring the conditions under which this goal is attainable. The paper discussed the approach to achieve ultra-low NOx emissions by using advanced furnace air staging. It describes the unique approach of redesigning the burner to maintain low NOx burner performance when the overfire air system is added or increased in capacity. The impact on furnace corrosion and unburned carbon losses are presented. A case study is used to show the effects of overfire air both on emissions and unburned carbon.

McCarthy, K.; Laux, S.; Grusha, J.

1999-07-01T23:59:59.000Z

62

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

63

Role of gas phase reactions in subatmospheric chemical-vapor deposition ozone/TEOS processes for oxide deposition  

E-Print Network (OSTI)

-vapor deposition. Our results for oxide deposition show optimum process window around 200 Torr for producing films a po- tentially optimum process window in which film properties, deposition rates, film uniformity requires high quality dielectric films that can be deposited rapidly and conformally on high aspect ratio

Rubloff, Gary W.

64

Control of NOx by combustion process modifications  

E-Print Network (OSTI)

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

65

NETL: News Release - DOE Selects Five NOx-Control Projects to Combat Acid  

NLE Websites -- All DOE Office Websites (Extended Search)

November 5, 2004 November 5, 2004 DOE Selects Five NOx-Control Projects to Combat Acid Rain and Smog Industry Partners to Focus on Reducing Emissions While Cutting Energy Costs PITTSBURGH, PA - Continuing efforts to cut acid rain and smog-producing nitrogen oxides (NOx) have prompted the U.S. Department of Energy to partner with industry experts to develop advanced NOx-control technologies. With the selection of five new NOx-control projects, the Energy Department continues as a leader in developing advanced technologies to achieve environmental compliance for the nation's fleet of coal-fired power plants. Although today's NOx-control workhorses, such as low-NOx burners and selective catalytic reduction (SCR), have been successfully deployed to address existing regulations, proposed regulations will require deeper cuts in NOx emissions, at a greater number of generating facilities. Many of the smaller affected plants will not be able to cost-effectively use today's technologies; these are the focus of the advanced technologies selected in this announcement.

66

NETL: Advanced NOx Emissions Control: Control Technology - Ultra Low-NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

Ultra Low NOx Integrated System Ultra Low NOx Integrated System TFS 2000(tm) Low NOx Firing System Project Summary: ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important,

67

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

68

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network (OSTI)

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on the Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M-star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M-star world differs considerably compared with the Earth.

John Lee Grenfell; Jean-Mathias Griessmeier; Beate Patzer; Heike Rauer; Antigona Segura; Anja Stadelmann; Barbara Stracke; Ruth Titz; Philip von Paris

2007-02-23T23:59:59.000Z

69

CLEERS Activities: Diesel Soot Filter Characterization & NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit...

70

Evaluating ozone dose for AOC removal in two-step GAC filters  

Science Journals Connector (OSTI)

Upgrading an existing post-ozonation plant with two-step granular activated carbon (GAC) filtration for assimilable organic carbon (AOC) removal was studied. The effects of ozone dose on AOC formation and its removal in the subsequent two-step GAC filtration was studied using chemically pretreated 2 to 14 C humic lake water. Two parallel pilot-plant trains with different ozone doses (0 to 1.2 mgO3/mgTOC) and a shortterm ozonation study were performed. The optimum ozone dose for maximum AOC formation was 0.40.5 mgO3/mgTOC. The AOC-P17 of ozonated water was three-fold higher and AOC-NOX over ten-fold higher than in non-ozonated water, while the following biofiltration (first step) removed 51 % and 72 % of AOC-P17 and AOC-NOX, respectively. The adsorber (second step) contributed to less than 10% of the overall AOC reduction. It appeared that biofiltration is a feasible method in upgrading water treatment plants for AOC removal even when treating cold humic waters, while the subsequent adsorber seems to have less significance for AOC removal.

R. Vahala; T. Ala-Peijari; J. Rintala; R. Laukkanen

1998-01-01T23:59:59.000Z

71

NETL: Advanced NOx Emissions Control: Control Technology - NOx Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Options and Integration Control Options and Integration Reaction Engineering International (REI) is optimizing the performance of, and reduce the technical risks associated with the combined application of low-NOx firing systems (LNFS) and post combustion controls through modeling, bench-scale testing, and field verification. Teaming with REI are the University of Utah and Brown University. During this two-year effort, REI will assess real-time monitoring equipment to evaluate waterwall wastage, soot formation, and burner stoichiometry, demonstrate analysis techniques to improve LNFS in combination with reburning/SNCR, assess selective catalytic reduction catalyst life, and develop UBC/fly ash separation processes. The REI program will be applicable to coal-fired boilers currently in use in the United States, including corner-, wall-, turbo-, and cyclone-fired units. However, the primary target of the research will be cyclone boilers, which are high NOx producing units and represent about 20% of the U.S. generating capacity. The results will also be applicable to all U.S. coals. The research will be divided into four key components:

72

Catalytic ozonation of phenol in water with natural brucite and magnesia  

Science Journals Connector (OSTI)

Natural brucite and magnesia were applied as catalysts in catalytic ozonation of phenol in this work. It was found that both brucite and magnesia had remarkable accelerations on degradation of phenol and removal of COD in water. On this basis, effective and feasible routes for catalytic ozonation of phenol in water were proposed. The influence of initial pH value, radical scavengers and reaction temperature were investigated. The results revealed that there were different ozonation mechanisms in two systems: molecular ozone direct oxidation mechanism was proved in catalytic ozonation with brucite, and hydroxyl radical mechanism was demonstrated to play a main role in catalytic ozonation with magnesia.

Kun He; Yu Ming Dong; Zhen Li; Lin Yin; Ai Min Zhang; Yi Chun Zheng

2008-01-01T23:59:59.000Z

73

Transmural Catalysis - High Efficiency Catalyst Systems for NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation...

74

SCR Technologies for NOx Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technologies for NOx Reduction SCR Technologies for NOx Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deerhesser.pdf More...

75

An Improvement of Diesel PM and NOx Reduction System | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Development on simultaneous reduction system of NOx and PM from a diesel engine An Improvement of Diesel PM and NOx Reduction System New Diesel Emissions...

76

Development on simultaneous reduction system of NOx and PM from...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications An Improvement of Diesel PM and NOx Reduction System An Improvement of Diesel PM and NOx Reduction System EPA Mobile Source Rule Update...

77

Passive Catalytic Approach to Low Temperature NOx Emission Abatement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

78

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Three-Dimensional Composite Nanostructures for Lean NOx Emission Control 2010 DOE Vehicle Technologies and...

79

Effect of Biodiesel Blends on NOx Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Blends on NOx Emissions Effect of Biodiesel Blends on NOx Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

80

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor...

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Enhanced High and Low Temperature Performance of NOx Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells...

82

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

83

Modeling the Regeneration Chemistry of Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored...

84

Electrochemical NOxSensor for Monitoring Diesel Emissions | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Diesel Emissions Electrochemical NOxSensor for Monitoring Diesel Emissions pm02glass.pdf More Documents & Publications Electrochemical NOx Sensor for Monitoring Diesel...

85

IEP - Advanced NOx Emissions Control: Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP - Advanced NOx Emissions Control Regulatory Drivers Regulatory Drivers for Existing Coal-Fired Power Plants Regulatory and legislative requirements have predominantly driven the need to develop NOx control technologies for existing coal-fired power plants. The first driver was the Title IV acid rain program, established through the 1990 Clean Air Act Amendments (CAAA). This program included a two-phase strategy to reduce NOx emissions from coal-fired power plants – Phase I started January 1, 1996 and Phase II started January 1, 2000. The Title IV NOx program was implemented through unit-specific NOx emission rate limits ranging from 0.40 to 0.86 lb/MMBtu depending on the type of boiler/burner configuration and based on application of LNB technology.

86

Process Modeling of Global Soil Nitrous Oxide Emissions  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

Saikawa, E.

2011-09-01T23:59:59.000Z

87

REAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS  

E-Print Network (OSTI)

are International. b DOC = Diesel Oxidation Catalyst; DPF = Diesel Particulate Filter; EGR = Exhaust GasREAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS Gurdas Sandhu H 26-28, 2012 #12;2 Objectives 1. Quantify inter-run variability in exhaust emission rates 2. Assess

Frey, H. Christopher

88

Substrate Utilization by an Oxalate-Consuming Spirillum Species in Relation to Its Growth in Ozonated Water  

Science Journals Connector (OSTI)

...assimilable organic car- bon compounds (AOC), were calculated from the obtained Nmax values and the Y values for acetate. The AOC concen- trations for both strains were...with each oth- er. In ozonated water, AOC concentrations available for strain NOX...

D. van der Kooij; W. A. M. Hijnen

1984-03-01T23:59:59.000Z

89

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

90

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the October 1 to December 31, 2003 time period.

S. Wu

2003-12-31T23:59:59.000Z

91

Electrochemical NOx Sensors for Monitoring Diesel Emissions  

Energy.gov (U.S. Department of Energy (DOE))

A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs

92

An Automated System for the Measurement of Nitrogen Oxides and Ozone Concentrations from a Passenger Aircraft:? Instrumentation and First Results of the NOXAR Project  

Science Journals Connector (OSTI)

Exhaust gas from the analyzer is drawn through a thermal ozone scrubber (ECO PHYSICS) and into the vacuum pump (P1 in Figures 1 and 3). ... The individual capacity of each one of the 110 W fans (2100 m3/h in free air) is sufficient to ensure that the rack will not overheat even if the other should malfunction. ... Photolysis rates were calculated for clear-sky conditions from all daytime NO and O3 measurements at solar zenith angles <85 using the STAR (system for transfer of atmospheric radiation) model (27). ...

Peter Dias-Lalcaca; Dominik Brunner; Walter Imfeld; Werner Moser; Johannes Staehelin

1998-09-04T23:59:59.000Z

93

Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels  

SciTech Connect

This final report documents the technical results of the 3-year project entitled, Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels, funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

2013-09-30T23:59:59.000Z

94

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

95

Catalytic ozonation of azo dye active brilliant red X-3B in water with natural mineral brucite  

Science Journals Connector (OSTI)

Natural mineral brucite was used directly in catalytic ozonation of dye wastewater of active brilliant red X-3B. Compared with single ozonation, degradation of X-3B increased from 47% to 89%, and removal rate of COD increased from 9% to 32.5% in catalytic ozonation for 15min. The catalytic ozonation of X-3B followed a direct oxidization mechanism by ozone molecule, and this was actually a homogeneous catalysis of OH? due to dissolution of Mg(OH)2 from natural brucite. As a natural mineral catalyst, brucite has supplied an economical and feasible choice for catalytic ozonation of X-3B in industrial wastewater.

Yuming Dong; Kun He; Bo Zhao; Ying Yin; Lin Yin; Aimin Zhang

2007-01-01T23:59:59.000Z

96

The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters  

E-Print Network (OSTI)

and biochemical oxygen demands were measured before and after ozaontion as well as the amount of ozone consumed. Non-adsorbable COD was measured and a comparison of ozonized and unozonized wastewater made. BOD concentration rose after ozonation, but decreased... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

Buys, Ronald Earl

2012-06-07T23:59:59.000Z

97

Advanced NOx Emissions Control: Control Technology - Second Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems To support trends in the electric generating industry of moving from seasonal to year-round operation of Selective Catalytic Reduction (SCR) for control of NOx and mercury, as well as extending the time between generating unit outages, Fossil Energy Research Corporation (FERCo) is developing technology to determine SCR catalyst activity and remaining life without requiring an outage to obtain and analyze catalyst samples. FERCo intends to use SCR catalyst performance results measured with their in situ device at Alabama Power’s Plant Gorgas during the 2005 and 2006 ozone seasons, along with EPRI’s CatReactTM catalyst management software, to demonstrate the value of real-time activity measurements with respect to the optimization of catalyst replacement strategy. Southern Company and the Electric Power Research Institute are co-funding the project.

98

Mercury oxidation promoted by a selective catalytic reduction catalyst under simulated Powder River Basin coal combustion conditions  

SciTech Connect

A bench-scale reactor consisting of a natural gas burner and an electrically heated reactor housing a selective catalytic reduction (SCR) catalyst was constructed for studying elemental mercury (Hg{sup 0}) oxidation under SCR conditions. A low sulfur Powder River Basin (PRB) subbituminous coal combustion fly ash was injected into the entrained-flow reactor along with sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), hydrogen chloride (HCl), and trace Hg{sup 0}. Concentrations of Hg{sup 0} and total mercury (Hg) upstream and downstream of the SCR catalyst were measured using a Hg monitor. The effects of HCl concentration, SCR operating temperature, catalyst space velocity, and feed rate of PRB fly ash on Hg0 oxidation were evaluated. It was observed that HCl provides the source of chlorine for Hg{sup 0} oxidation under simulated PRB coal-fired SCR conditions. The decrease in Hg mass balance closure across the catalyst with decreasing HCl concentration suggests that transient Hg capture on the SCR catalyst occurred during the short test exposure periods and that the outlet speciation observed may not be representative of steady-state operation at longer exposure times. Increasing the space velocity and operating temperature of the SCR led to less Hg{sup 0} oxidized. Introduction of PRB coal fly ash resulted in slightly decreased outlet oxidized mercury (Hg{sup 2+}) as a percentage of total inlet Hg and correspondingly resulted in an incremental increase in Hg capture. The injection of ammonia (NH{sub 3}) for NOx reduction by SCR was found to have a strong effect to decrease Hg oxidation. The observations suggest that Hg{sup 0} oxidation may occur near the exit region of commercial SCR reactors. Passage of flue gas through SCR systems without NH{sub 3} injection, such as during the low-ozone season, may also impact Hg speciation and capture in the flue gas. 18 refs., 7 figs., 3 tabs.

Chun W. Lee; Shannon D. Serre; Yongxin Zhao; Sung Jun Lee; Thomas W. Hastings [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). Office of Research and Development, National Risk Management Research Laboratory

2008-04-15T23:59:59.000Z

99

Ammonia Sensor for SCR NOX Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sensor for SCR NOX Reduction Ammonia Sensor for SCR NOX Reduction Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,...

100

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

Results show that a series of dual layer catalysts with a bottom layer of LNT catalyst and a top layer of SCR catalyst can carry out coupled ammonia generation and NOx reduction, achieving high NOx conversion with minimal ammonia slip

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


101

Photochemical Oxidant Processes in the Presence of Dust: An Evaluation of the Impact of Dust on Particulate Nitrate and Ozone Formation  

Science Journals Connector (OSTI)

The influence of dust on the tropospheric photochemical oxidant cycle is studied through the use of a detailed coupled aerosol and gas-phase chemistry model. Dust is a significant component of the troposphere throughout Asia and provides a ...

Yang Zhang; Young Sunwoo; Veerabhadra Kotamarthi; Gregory R. Carmichael

1994-07-01T23:59:59.000Z

102

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

2007-06-30T23:59:59.000Z

103

NETL: Advanced NOx Emissions Control: Control Technology - Methane de-NOx  

NLE Websites -- All DOE Office Websites (Extended Search)

METHANE de-NOx® METHANE de-NOx® The Gas Technology Institute (GTI) is teaming with the All-Russian Thermal Engineering Institute and DB Riley to develop a pulverized-coal (PC)-combustion system that is an extension of IGT's METHANE de-NOx® technology. The technology is composed of a novel PC burner design using natural gas fired coal preheating developed and demonstrated in Russia, LNBs with internal combustion staging, and additional natural gas injection with overfire air. The coal is preheated at elevated temperatures (up to 1500oF) in oxygen deficient conditions prior to combustion. Coal preheat releases fuel-bound nitrogen together with volatiles present in the coal. These conditions promote the conversion of fuel-bound nitrogen to molecular nitrogen rather than to NOx.

104

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers. Quarterly report No. 5, July--September 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

105

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions  

Science Journals Connector (OSTI)

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions ... Life cycle GHG emissions were found to decrease by less than 4% in almost all scenarios modeled. ... Resulting changes in fuel use, life cycle greenhouse gas (GHG) emissions, and emissions of sulfur and nitrogen oxides are estimated. ...

Aranya Venkatesh; Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

2012-08-13T23:59:59.000Z

106

Mass Balance of Gaseous and Particulate Products from ?-Pinene/O3/Air in the Absence of Light and ?-Pinene/NOx/Air in the Presence of Natural Sunlight  

Science Journals Connector (OSTI)

The gas and particle phase products from the reaction of ?-pinene with the atmospheric oxidants O3 and OH radicals in the presence of NOx were investigated using both gas chromatography-mass spectrometry (GC-MS) ...

M. Jaoui; R. M. Kamens

2003-06-01T23:59:59.000Z

107

One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light  

Science Journals Connector (OSTI)

...nitric acid oxidation method (3). The first step is air oxidation of cyclohexane under high temperatures (125 to 165...Finlayson-Pitts B. J. Pitts J. N. Jr. , Tropospheric air pollution: Ozone, airborne toxics, polycyclic aromatic hydrocarbons...

Kuo Chu Hwang; Arunachalam Sagadevan

2014-12-19T23:59:59.000Z

108

Ozone in Michigan's Environment 18761880  

Science Journals Connector (OSTI)

Atmospheric ozone was monitored in Michigan during the late 1880's using Schoenbein's test paper. A conversion chart was constructed to relate the Schoenbein ozone scale at various relative humidifies to ozone levels indicated by a Dasibi ozone ...

Dale E. Linvill; W. J. Hooker; Brian Olson

1980-11-01T23:59:59.000Z

109

Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity  

SciTech Connect

Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

2012-10-01T23:59:59.000Z

110

Study to determine the nature and extent of ozone and ozone precursor transport in selected areas of California. Final report  

SciTech Connect

The project was designed to assess the contribution of transported pollutants to violations of the state ozone standard within the air basins covered by the report using existing data and advanced data analysis techniques. The objectives of the project were to determine the characteristics of ozone and ozone precursor transport within the California air basins covered by the report and to identify whether the contribution of transported pollutants to ozone violations in each downwind area was inconsequential, significant, or overwhelming, relative to locally-emitted pollutants. The precursor pollutants of interest were nitrogen oxides and reactive organic gases. The project evaluated transport to the following areas: The Broader Sacramento Area and the Upper Sacramento Valley; The North Central Coast Air Basin; The Southeast Desert Air Basin (SEDAB); and the Imperial County portion of the SEDAB.

Roberts, P.T.; Musarra, S.; Smith, T.B.; Lurmann, F.W.

1992-04-01T23:59:59.000Z

111

A decoupled approach for NOxN2O 3-D CFD modeling in CFB plants  

Science Journals Connector (OSTI)

Abstract In this study, a 3D CFD model for the formation of \\{NOx\\} and N2O in a lignite fired 1.2MWth CFB pilot plant is developed. The decoupled approach (decoupled from combustion simulation) is tested for the minimization of computational cost. As combustion simulation is prerequired, this was achieved through a simplified 3-D CFD combustion model. The developed model is then applied to the pilot-scale 1.2MWth CFB plant and validated against experimental data. As concerns the NOxN2O model, an extensive literature review is also carried out for the incorporation of the appropriate reactions network and respective reaction rates expressions. Results show that homogenous reactions are favoured on the lower section of the bed, due to the abundance of fuel devolatilization products. On the other hand, on the upper section, heterogeneous reactions govern nitric oxide formation/reduction. It is found that for the lignite examined in this work, HCN is released in negligible amounts during char combustion. The proposed and validated CFD model for \\{NOx\\} and N2O, is capable of examining the effect of different operational parameters and coal properties on the overall nitric oxides emissions from a CFB combustor, with low computational cost and without the additional expenses for pilot-scale experiments.

A. Nikolopoulos; I. Malgarinos; N. Nikolopoulos; P. Grammelis; S. Karrelas; E. Kakaras

2014-01-01T23:59:59.000Z

112

As-Received, Ozone Cleaned and Ar+ Sputtered Surfaces of Hafnium Oxide Grown by Atomic Layer Deposition and Studied by XPS  

SciTech Connect

In this study, X-ray photoelectron spectroscopy (XPS) characterization was performed on 47 nm thick hafnium oxide (HfO{sub 2}) films grown by atomic layer deposition using TEMA-Hf/H{sub 2}O at 250 C substrate temperature. HfO{sub 2} is currently being studied as a possible replacement for Silicon Oxide (SiO{sub 2}) as a gate dielectric in electronics transistors. XPS spectra were collected on a Physical Electronics Quantum 2000 Scanning ESCA Microprobe using a monochromatic Al K{sub a} X-ray (1486.7 eV) excitation source. The sample was analyzed under the following conditions: as received, after UV irradiation for five minutes, and after sputter cleaning with 2 kV Ar{sup +} ions for 180 seconds. Survey scans showed carbon, oxygen, and hafnium as the major species in the film, while the only minor species of argon and carbide was detected after sputtering. Adventitious carbon initially composed approximately 18.6 AT% of the surface, but after UV cleaning it was reduced to 2.4 AT%. This demonstrated that that the majority of carbon was due to adventitious carbon. However, after 2 kV Ar{sup +} sputtering there was still only trace amounts of carbon at {approx}1 AT%, Some of this trace carbon is now in the form of a carbide due to the interaction with Ar{sup +} used for sputter cleaning. Furthermore, the stoiciometric ratio of oxygen and hafnium is consistent with a high quality HfO{sub 2} film.

Engelhard, Mark H.; Herman, Jacob A.; Wallace, Robert; Baer, Donald R.

2012-06-27T23:59:59.000Z

113

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

114

7, 97959828, 2007 Tropospheric ozone  

E-Print Network (OSTI)

ACPD 7, 9795­9828, 2007 Tropospheric ozone climatology over Beijing A. J. Ding et al. Title Page Chemistry and Physics Discussions Tropospheric ozone climatology over Beijing: analysis of aircraft data;ACPD 7, 9795­9828, 2007 Tropospheric ozone climatology over Beijing A. J. Ding et al. Title Page

Paris-Sud XI, Université de

115

8, 1106311101, 2008 Tropospheric Ozone  

E-Print Network (OSTI)

ACPD 8, 11063­11101, 2008 Tropospheric Ozone climatology in the southern subtropics G. Clain et al.0 License. Atmospheric Chemistry and Physics Discussions Tropospheric ozone climatology at two southern Tropospheric Ozone climatology in the southern subtropics G. Clain et al. Title Page Abstract Introduction

Paris-Sud XI, Université de

116

Ozone removal by HVAC filters  

Science Journals Connector (OSTI)

Residential and commercial HVAC filters that have been loaded with particles during operation in the field can remove ozone from intake or recirculated air. However, knowledge of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial buildings is incomplete. We measured the ozone removal efficiencies of clean (unused) fiberglass, clean synthetic filters, and field-loaded residential and commercial filters in a controlled laboratory setting. For most filters, the ozone removal efficiency declined rapidly but converged to a non-zero (steady-state) value. This steady-state ozone removal efficiency varied from 0% to 9% for clean filters. The mean steady-state ozone removal efficiencies for loaded residential and commercial filters were 10% and 41%, respectively. Repeated exposure of filters to ozone following a 24-h period of no exposure led to a regeneration of ozone removal efficiency. Based on a theoretical scaling analysis of mechanisms that are involved in the ozone removal process, we speculate that the steady-state ozone removal efficiency is limited by reactant diffusion out of particles, and that regeneration is due to internal diffusion of reactive species to sites available to ozone for reaction. Finally, by applying our results to a screening model for typical residential and commercial buildings, HVAC filters were estimated to contribute 22% and 95%, respectively, of total ozone removal in HVAC systems.

P. Zhao; J.A. Siegel; R.L. Corsi

2007-01-01T23:59:59.000Z

117

Synthetic zeolites and other microporous oxide molecular sieves  

Science Journals Connector (OSTI)

...Many variations on the process cycle were developed to improve efficiency...NOx ) emitted from lean-burn diesel engines. Many catalyst developers...hydrocarbon oxidation in conventional diesel engines and NOx reduction...reduction and system durability. General Motors achieved 50,000-mile-aged...

John D. Sherman

1999-01-01T23:59:59.000Z

118

Lower Freezing DEF For Higher NOx Reduction Attainment  

Energy.gov (U.S. Department of Energy (DOE))

NOx emissions data from bench-scale experiments and Class III truck operated using a low freezing point diesel exhaust fluid

119

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA:...

120

Unique Catalyst System for NOx Reduction in Diesel Exhaust |...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

More Documents & Publications Noxtechs PAC System Development and Demonstration Plasma Assisted Catalysis System for NOx Reduction Clean Diesel Engine Component Improvement...

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Two Catalyst Formulations - One Solution for NOx After-treatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Two Catalyst Formulations - One Solution for NOx After-treatment Systems Low-temperature SCR combined with standard high-temperature SCR catalyst formulation in one system provides...

122

Measurement and Characterization of Lean NOx Adsorber Regeneration...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

for the Department of Energy Purpose of Work: Enable efficient lean engine market penetration by meeting emission regulations with aftertreatment * Research of Lean NOx...

123

Enhanced High and Low Temperature Performance of NOx Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Low Temperature Performance of NOx Reduction Materials 2013 DOE AMR Review This presentation does not contain any proprietary, confidential, or otherwise restricted...

124

NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

125

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

126

Investigation of Aging Mechanisms in Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland. merit08johnson.pdf More Documents & Publications Investigation of Aging Mechanisms in Lean NOx Traps...

127

Fuel Processor Enabled NOx Adsorber Aftertreatment System for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

for Diesel Engine Emissions Control R. Dalla Betta, D. Sheridan, J. Cizeron Catalytica Energy Systems Inc. Mountain View, California 2 Outline Why use a fuel processor for NOx...

128

Status of APBF-DEC NOx Adsorber/DPF Projects  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

* Examine other fuel properties 6 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Each platform will determine effects of fuel properties on: * NOx and PM reduction...

129

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

130

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts...

131

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nanowire Lean NOx Emission Control Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts Three-Dimensional Composite Nanostructures for Lean...

132

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Energy.gov (U.S. Department of Energy (DOE))

Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

133

Rapid Aging Protocols for Diesel Aftertreatment Devices: NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Aftertreatment (Agreement 13415) Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by LeanRich Cycling Impacts of Biodiesel on Emission Control Devices...

134

Nitrogen oxide emissions from a kraft recovery furnace  

SciTech Connect

Nitrogen Oxide (NOx) emissions from a rebuilt kraft recovery furnace slightly exceeded the specified limit of 1.1 lb/ton (0.55 kg/metric ton) of black-liquor solids. Mill trials were undertaken to determine whether NOx emissions could be minimized by modifying furnace operation. NOx emissions increased when secondary air was shifted to tertiary ports. NOx emissions fell when the amounts of primary and total air were decreased, but this increased emissions of other pollutants. After demonstrating that best operation of the furnace could not meet the permit with an emissions limit that matched the furnace's performance at best operation.

Prouty, A.L.; Stuart, R.C. (James River Corp., Camas, WA (United States)); Caron, A.L. (NCASI West Coast Regional Office, Corvallis, OR (United States))

1993-01-01T23:59:59.000Z

135

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single-Leg NOX Adsorber...

136

Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline...

137

Investigation of the Atmospheric Ozone Impacts of Methyl Iodide  

E-Print Network (OSTI)

J. R. Holmes (1977): Nitrogen Dioxide Photolysis in the LosO3 Ozone NO Nitric Oxide NO2 Nitrogen Dioxide NO3 NitrateNitrogen Pentoxide HONO Nitrous Acid HNO3 Nitric Acid HNO4 Peroxynitric Acid HO2H Hydrogen Peroxide CO Carbon Monoxide SO2 Sulfur Dioxide

Carter, W P L

2007-01-01T23:59:59.000Z

138

Response: Stratospheric Ozone  

Science Journals Connector (OSTI)

...Stratospheric Ozone The Upper Atmosphere Research Pro-gram...not coincide with true atmospheric change. A major review...report "Spacelab-2 plasma depletion experiments...correct figure 5 is printed below. N 2.5 OMS...360 MHz0 o 1.704 MHz'(a O, 2.108 MHz...

KENNETH P. BOWMAN

1988-02-19T23:59:59.000Z

139

Ozone decomposing filter  

DOE Patents (OSTI)

In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

1999-01-01T23:59:59.000Z

140

Ozone and ethylene stress  

Science Journals Connector (OSTI)

... SIR"In a recent News and Views article1 "Adding ethylene to injury", M. Unsworth discussed the results of Mehlhorn and Wellburn2, who reported ... M. Unsworth discussed the results of Mehlhorn and Wellburn2, who reported that both endogenous ethylene (a stress-hormone) and exogenous ozone are cooperating prerequisites for injury to pea plants ...

E. F. ELSTNER

1987-08-06T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

142

Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions -...

143

Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011 Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011...

144

Experimental investigation of the thermal and diluent effects of EGR components on combustion and \\{NOx\\} emissions of a turbocharged natural gas SI engine  

Science Journals Connector (OSTI)

Abstract Exhaust gas recirculation (EGR) is one of effective measures used in natural gas (NG) engines to reduce nitrogen oxides (NOx) emissions. Each component of EGR gases can exert different effects on NG combustion and \\{NOx\\} formation rates, such as thermal effect, diluent effect, and chemical effect. In this study, the thermal and diluent effects of the main components of EGR gases, including carbon dioxide (CO2) and nitrogen (N2), were experimentally investigated. The experiments were arranged based on an electronically controlled heavy-duty natural gas spark-ignition (SI) engine with multi-point injection and 6-cylinder. In order to define the diluent effect of EGR components, argon (Ar) was introduced to the test, for its low and unchangeable specific heat capacity under different temperatures. The results showed that the contribution of the diluent effect on \\{NOx\\} reductions was 5060% and 4153% for N2 and CO2 respectively, and the relevant contribution of the thermal effect was 4050% and 4759% respectively. CO2 had greater effects on NG combustion and \\{NOx\\} formation rates than N2 at the same dilution ratio. Increasing Ar improved the thermal efficiency due to the higher specific heat ratio provided. Meanwhile, \\{NOx\\} emissions were found to be decreased with increasing DR as a result of the diluent effect of Ar on combustion and \\{NOx\\} formations.

Weifeng Li; Zhongchang Liu; Zhongshu Wang; Yun Xu

2014-01-01T23:59:59.000Z

145

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines  

SciTech Connect

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL; Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

146

Ultra-Low NOx Advanced Vortex Combustor  

SciTech Connect

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energys National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

2006-05-01T23:59:59.000Z

147

ULTRA-LOW NOX ADVANCED VORTEX COMBUSTOR  

SciTech Connect

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energys National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Ryan G. Edmonds; Robert C. Steele; Joseph T. Williams; Douglas L. Straub; Kent H. Casleton; Avtar Bining

2006-05-01T23:59:59.000Z

148

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

149

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

150

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

151

Ozone Depletion and Global Warming.  

E-Print Network (OSTI)

??Abstract This thesis examines global warming and the possible contribution that ozone depletion provides to this warming. An examination is performed to determine the extent (more)

Fow, Alista John

2006-01-01T23:59:59.000Z

152

Annual and Seasonal Global Variation in Total Ozone and Layer-Mean Ozone,  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » Ozone » Total Ozone and Layer-Mean Ozone Atmospheric Trace Gases » Ozone » Total Ozone and Layer-Mean Ozone Annual and Seasonal Global Variation in Total Ozone and Layer-Mean Ozone, 1958-1987 (1991) DOI: 10.3334/CDIAC/atg.ndp023 data Data Investigators J. K. Angell, J. Korshover, and W. G. Planet Description For 1958 through 1987, this data base presents total ozone variations and layer mean ozone variations expressed as percent deviations from the 1958 to 1977 mean. The total ozone variations were derived from mean monthly ozone values published in Ozone Data for the World by the Atmospheric Environment Service in cooperation with the World Meteorological Organization. The layer mean ozone variations are derived from ozonesonde and Umkehr observations. The data records include year, seasonal and annual

153

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

154

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

155

Tropospheric and Lower Stratospheric Ozone Profiles From AERI-X Emission Spectra  

NLE Websites -- All DOE Office Websites (Extended Search)

Tropospheric and Lower Stratospheric Ozone Profiles Tropospheric and Lower Stratospheric Ozone Profiles From AERI-X Emission Spectra P. F. Fogal and F. J. Murcray Department of Physics and Astronomy University of Denver Denver, Colorado Introduction The University of Denver Atmospheric Emission Radiometric Interferometer-Extended (AERI-X) has been in regular operation at the Southern Great Plains (SGP) Atmospheric Radiation Measurements (ARM) Program site, conditions permitting, since the mid-1990s. We present here the analysis of several spectra from May 10, 1999, and demonstrate the ability to retrieve the tropospheric ozone profile at the ARM site. While the presence of ozone in the stratosphere is of vital importance for several reasons, in the troposphere, ozone is a pollutant and a powerful oxidizer. For these reasons, it is

156

Flexible CHP System with Low NOx, CO and VOC Emissions- Fact Sheet, 2014  

Energy.gov (U.S. Department of Energy (DOE))

Utilizing Supplemental Ultra-Low-NOx Burner Technology to Meet Emissions Standards and Improve System Efficiency

157

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

NLE Websites -- All DOE Office Websites (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

158

Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition  

SciTech Connect

The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

2014-01-15T23:59:59.000Z

159

Functionality of Commercial NOx Storage-Reduction Catalysts and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

N.A. Ottinger, J.A. Pihl, T.J. Toops, C. Finney, M. Lance, C. Stuart Daw, "Types, Spatial Distribution, Stability, and Performance Impact of Sulfur on a Lean NOx Trap...

160

Reducing NOx emissions using the humid air motor concept  

Science Journals Connector (OSTI)

The use of water to prevent NOx...formation during the combustion process is well known. The H.A.M. system (Humid Air Motor) is an original and promising solution compared ... . This system involves evaporating l...

Emmanuel Riom; Lars-Ola Larsson; Ulf Hagstrm

2002-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ace026peden2010o.pdf More Documents & Publications Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials...

162

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration  

SciTech Connect

Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

Choi, Jae-Soon [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Partridge Jr, William P [ORNL] [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Chambon, Paul H [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

2010-01-01T23:59:59.000Z

163

Reducing fishing vessel fuel consumption and NOX emissions  

Science Journals Connector (OSTI)

There is a growing concern with the impact of marine operations on the environment. This requires reducing fuel consumption and vessel pollution during operation. On-board computers and satellite communications will enable the operator to reduce fuel consumption and NOX emissions during vessel operations. This paper presents the results of a study on this problem and how such an on-board system could be implemented to reduce fuel consumption and engine NOX emissions.

Robert Latorre

2001-01-01T23:59:59.000Z

164

Group effects on fuel NOx emissisons from coal  

E-Print Network (OSTI)

GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1991 Major Subject: Mechanical Engineering GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Approved ss to style and content by: K. Annamalai (Chair of Committee) Cr, R. Laster (Member) J. Wagne (Member...

Vadakkath, Anand Anakkara

2012-06-07T23:59:59.000Z

165

6, 39133943, 2006 Svalbard total ozone  

E-Print Network (OSTI)

(Farman et al., 1985) and25 global ozone layer reduction, the chemical and dynamical processes causing

Boyer, Edmond

166

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

167

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

168

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30T23:59:59.000Z

169

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

170

Hole in the ozone layer?  

NLE Websites -- All DOE Office Websites (Extended Search)

Hole in the ozone layer? Hole in the ozone layer? Name: Kelley Location: N/A Country: N/A Date: N/A Question: Is there really a hole in the ozone layer? Replies: That depends on what one means by a "hole". There is a thinning of the layer that is particularly severe during certain seasons at the poles. But the ozone layer is thinning most everywhere. The thinning around the south pole of earth is particularly stunning, and has been referred to as a hole even though some ozone still exists there, it is much less concentrated. As you may know, this ozone destruction is probably due to human release of pollutants such as clorofluorocarbons (CFCs) an due to natural sources such as chemicals from volcanic eruptions. CFCs are used is cooling systems such as refrigerators and air conditioning. There is an international agreement to phase out the use of these destructive chemicals but they won't be banned entirely for years for fears of losing money. Meanwhile the ozone layer thins and we are exposed to increasingly higher doses of cancer causing radiation

171

Effects of diesel-water emulsion combustion on diesel engine NOx emissions. Final report, 1 January 1998--1 May 1999  

SciTech Connect

This study examines the effects of combusting a mixture of diesel fuel, water, and surfactant on the nitrogen oxides (NOx) emissions from a compression ignition diesel engine. Extensive previous research in the literature has attributed the observed reduction of nitrogen oxide emissions to a suppression of flame temperature due to quenching effects from the water, thereby reducing thermal NOx formation. The report highlights the relevant theory, operation, and design parameters of diesel internal combustion engines. Experimental procedures conducted using a Detroit Diesel 4-cylinder diesel engine are discussed. Results from testing diesel fuel with varying ratios of water balanced with a surfactant to stabilize the emulsion are presented and discussed. The data shows significant NOx emission reduction with up to 45 percent water, by volume, in the fuel. These results are correlated with thermodynamic first law and equilibrium combustion products analyses to estimate the adiabatic flame temperature of the standard fuel and fuel-water emulsion cases. Results indicate that thermal NOx is indeed reduced by quenching and flame temperature suppression, confirming reports in the literature. Recommendations are given for further studies, including improving the fuel-water emulsion and considerations for long-term testing.

Canfield, A.C.

1999-05-01T23:59:59.000Z

172

NETL: Advanced NOx Emissions Control: Control Technology - SCNR Field  

NLE Websites -- All DOE Office Websites (Extended Search)

SNCR Field Demonstration SNCR Field Demonstration American Electric Power (AEP), in conjunction with the U.S. Department of Energy, FuelTech, the Ohio Coal Development Office, and fourteen EPRI member utilities, performed a full-scale demonstration of a urea-based Selective Non-Catalytic Reduction (SNCR) system at Cardinal Unit 1. Cardinal Unit 1 is a 600MWe opposed-wall dry bottom pulverized coal-fired boiler that began service in 1967. This unit burns eastern bituminous high-sulfur coal, (3.72%S). This unit was retrofitted with low NOx burners (LNB's) during its scheduled fall 1998 outage and the SNCR system was installed concurrently. SNCR is a post-combustion NOx control process developed to reduce NOx emissions from fossil-fuel combustion systems. SNCR processes involve the injection of a chemical containing nitrogen into the combustion products, where the temperature is in the range of 1600°F - 2200°F (870°C - 1205°C). In this temperature range, the chemical reacts selectively with NOx in the presence of oxygen, forming primarily nitrogen and water. Although a number of chemicals have been investigated and implemented for SNCR NOx reduction, urea and ammonia have been most widely used for full-scale applications.

173

Increased Cytotoxicity of Oxidized Flame Soot  

NLE Websites -- All DOE Office Websites (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

174

NETL: Advanced NOx Emissions Control: Control Technology - Optimized Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Optimized Fuel Injector Design Optimized Fuel Injector Design This project includes fundamental research and engineering development of low NOx burners and reburning fuel injectors. The team of Reaction Engineering International (REI), the University of Utah, Brown University and DB Riley, Inc., will develop fundamental information on low NOx burners. The work has two phases. In the first phase, the University of Utah will examine two-phase mixing and near-field behavior of coal injectors using a 15-million Btu/hr bench-scale furnace, Brown University will examine char deactivation and effectiveness of reburning, and REI will develop a comprehensive burner model using the data produced by the University of Utah and Brown University. In the second phase, an optimized injector design will be tested at the 100-million Btu/hr Riley Coal Burner Test Facility. It is anticipated that this work will provide improved hardware designs and computer simulation models for reduced NOx emissions and minimized carbon loss.

175

Ozone concentrations in El Paso, Texas  

SciTech Connect

El Paso, Texas may have a problem in meeting ambient air standards due to influx of pollutants from foreign sources. Cd. Juarez, Chihuahua, and Fort Bliss abut the city and are areas over which the Texas Air Control Board (TACB) has little or no jurisdiction. The Board maintains two Continuous Air Monitoring Stations (CAM) in El Paso. Ozone, nitric oxide, and nitrogen dioxide data were obtained from these stations. If the EPA Empirical Kinetic Model is used for El Paso, reducing NMHC concentrations may increase rather than decrease O/sub 3/ concentrations. The Texas State Implementation Plan, while not based on Empirical Kinetic Modeling, calls for a reduction of 18% in NMHC. However, 31% of all NMHC in El Paso arise from sources over which Texas had little (a federal military reservation) or no (Cd. Juarez) jurisdiction. It appears the TACB is correct in believing the SIP for O/sub 3/ may not bring El Paso into compliance. (JMT)

Crocker, J.E. (Texas Air Control Board, Austin); Applegate, H.G.

1983-02-01T23:59:59.000Z

176

SCReaming for Low NOx - SCR for the Light Duty Market | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

SCReaming for Low NOx - SCR for the Light Duty Market SCReaming for Low NOx - SCR for the Light Duty Market Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan....

177

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer...

178

Safe and compact ammonia storage/delivery systems for SCR-DeNOX...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

179

Development of a Stand-Alone Urea-SCR System for NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea SCR...

180

Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge...

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181

Initial Results of the DeNOx SCR System by Urea Injection in...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus 2005 Diesel Engine Emissions...

182

The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst  

Energy.gov (U.S. Department of Energy (DOE))

Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost

183

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given...

184

NOx formation by steam injection using detailed chemical kinetics  

Science Journals Connector (OSTI)

In order to improve thermal efficiency of gas turbine system and better control NOx emission, the injection of steam into a gas turbine combustor has been employed. This study has used both chemical equilibrium calculations and the counterflow diffusion flame calculations of methane-air flame aiming at the elucidation of the NOx reduction mechanism due to the steam injection. The influence of the equivalence ratios, the amount of steam and method of injection, the influence of the temperature of the preheated air and fuel has been also investigated. In this study, the GRI-Mech was employed for modelling the chemical reactions.

H. Yamashita; D. Zhao; S.N. Danov; T. Furuhata; N. Arai

2001-01-01T23:59:59.000Z

185

Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements  

E-Print Network (OSTI)

for controlling NOx emissions will be discussed. Steam injection has a very favorable effect on engine performance raising both the power output and efficiency. As an example, full steam injection in the GE LM5000 gas turbine :tncreases the power output from... methods for reducing the NOx levels of the LM2500 and LM5000 engines. These engines are aircraft-derivative turbine engines, which are used in a variety of industrial applications. Efforts have been concentrated on the use of water or steam injection...

Keller, S. C.; Studniarz, J. J.

186

Oxidative Tritium Decontamination System  

SciTech Connect

The Princeton Plasma Physics Laboratory, Tritium Systems Group has developed and fabricated an Oxidative Tritium Decontamination System (OTDS), which is designed to reduce tritium surface contamination on various components and items. The system is configured to introduce gaseous ozone into a reaction chamber containing tritiated items that require a reduction in tritium surface contamination. Tritium surface contamination (on components and items in the reaction chamber) is removed by chemically reacting elemental tritium to tritium oxide via oxidation, while purging the reaction chamber effluent to a gas holding tank or negative pressure HVAC system. Implementing specific concentrations of ozone along with catalytic parameters, the system is able to significantly reduce surface tritium contamination on an assortment of expendable and non-expendable items. This paper will present the results of various experimentation involving employment of this system.

Charles A. Gentile; John J. Parker; Gregory L. Guttadora; Lloyd P. Ciebiera

2002-02-11T23:59:59.000Z

187

E-Print Network 3.0 - air pollutants ozone Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

1 Global Ozone Project Ozone Formation in Summary: , power plants and industry all emit air pollution that forms ground-level ozone. Ozone is a primary... Stratospheric and...

188

NOx, SO{sub 3} in the spotlight at NETL's 2006 Environmental Controls conference  

SciTech Connect

As emissions caps drop, technological solutions must become increasingly effective and efficient. Researchers, equipment vendors, and plant operators are exploring alternatives to SCR and SNCR, with a view to reducing the overall costs of NOx reduction. They have also achieved 95% to 99% removal of SO{sub 3}, with no visible plume opacity. These topics were discussed at ECC 2006. The first conference session focussed on selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) control of nitrogen oxide emissions; the second session addressed the related issue of reducing stack emissions and flue gas concentrations of sulfur trioxide. The article summarises many papers presented. Summaries and/or full versions of all the papers mentioned, and others, are posted at www.netl.doe.gov/publications/proceedings/06/ecc/index.html. 2 figs.

Mann, A.N.; Makovsky, L.E.; Sarkus, T.A. [Technology and Management Services Inc. (United States)

2007-02-15T23:59:59.000Z

189

The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines  

SciTech Connect

This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

Lyon, Richard

2001-08-05T23:59:59.000Z

190

Shifting primary energy source and NOx emission location with plug-in hybrid vehicles  

Science Journals Connector (OSTI)

Plug-in hybrid vehicles (PHEVs) present an interesting technological opportunity for using non-fossil primary energy in light duty passenger vehicles, with the associated potential for reducing air pollutant and greenhouse gas emissions, to the extent that the electric power grid is fed by non-fossil sources. This perspective, accompanying the article by Thompson et al (2011) in this issue, will touch on two other studies that are directly related: the Argonne study (Elgowainy et al 2010) and a PhD thesis from Utrecht (van Vliet 2010). Thompson et al (2011) have examined air quality effects in a case where the grid is predominantly fossil fed. They estimate a reduction of 7.42 tons/day of NOx from motor vehicles as a result of substituting electric VMTs for 20% of the light duty gasoline vehicle miles traveled. To estimate the impact of this reduction on air quality they also consider the increases in NOx emissions due to the increased load on electricity generating units. The NOx emission increases are estimated as 4.0, 5.5 and 6.3 tons for the Convenience, Battery and Night charging scenarios respectively. The net reductions are thus in the 1.13.4 tons/day range. The air quality modelling results presented show that the air quality impact from a ground-level ozone perspective is favorable overall, and while the effect is stronger in some localities, the difference between the three scenarios is small. This is quite significant and suggests that localization of the NOx emissions to point sources has a more pronounced effect than the absolute reductions achieved. Furthermore it demonstrates that localization of NOx emissions to electricity generating units by using PHEVs in vehicle traffic has beneficial effects for air quality not only by minimizing direct human exposure to motor vehicle emissions, but also due to reduced exposure to secondary pollutants (i.e. ozone). In an electric power grid with a smaller share of fossil fired generating units, the beneficial effects would be more pronounced. In such a case, it would also be possible to realize reductions in greenhouse gas emissions. The significance of the electric power generation mix for plug-in hybrid vehicles and battery electric vehicles is a key aspect of Argonne National Laboratories' well-to-wheel study which focuses on petroleum use and greenhouse gas emissions (Elgowainy et al 2010). The study evaluates possible reductions in petroleum use and GHG emissions in the electric power systems in four major regions of the United States as well as the US average generation mix, using Argonne's GREET life-cycle analysis model. Two PHEV designs are investigated through a Powertrain System Analysis Toolkit (PSAT) model: the power-split configuration (e.g. the current Toyota Prius model with Hymotion conversion), and a future series configuration where the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle. Since the petroleum share is small in the electricity generation mix for most regions in the United States, it is possible to achieve significant reductions in petroleum use by PHEVs. However, GHG reduction is another story. In one of the cases in the study, PHEVs in the charge depleting mode and recharging from a mix with a large share of coal generation (e.g., Illinois marginal mix) produce GHG emissions comparable to those of baseline gasoline internal combustion engine vehicles (with a range from ?15% to +10%) but significantly higher than those of gasoline hybrid electric vehicles (with a range from +20% to +60%). In what is called the unconstrained charging scenario where investments in new generation capacity with high efficiency and low carbon intensity are envisaged, it becomes possible to achieve significant reductions in both petroleum use and GHG emissions. In a PhD dissertation at Utrecht University, van Vliet (2010) presents a comprehensive analysis of alternatives to gasoline and diesel by looking at various fuel and vehicle technologies. Three chapters are of particular interest from the

Deniz Karman

2011-01-01T23:59:59.000Z

191

NETL: Advanced NOx Emissions Control: Control Technology - ALTA for Cyclone  

NLE Websites -- All DOE Office Websites (Extended Search)

Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers The primary goal of this project was to evaluate a technology called advanced layered technology application (ALTA) as a means to achieve NOx emissions below 0.15 lb/MMBtu in a cyclone boiler. Reaction Engineering International (REI) conducted field testing and combustion modeling to refine the process design, define the optimum technology parameters, and assess system performance. The ALTA NOx control technology combines deep staging from overfire air, rich reagent injection (RRI), and selective non-catalytic reduction (SNCR). Field testing was conducted during May-June 2005 at AmerenUE's Sioux Station Unit 1, a 500 MW cyclone boiler unit that typically burns an 80/20 blend of Powder River Basin subbituminous coal and Illinois No. 6 bituminous coal. Parametric testing was also conducted with 60/40 and 0/100 blends. The testing also evaluated process impacts on balance-of-plant issues such as the amount of unburned carbon in the ash, slag tapping, waterwall corrosion, ammonia slip, and heat distribution.

192

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Roles of ceria in LNT SCR: I ncreases NOx storage & NO conversion at low tem perature P rom otes W GS reaction Conditions: Lean: 500 ppm NO, 5% O 2 ; 60s Rich: 2.5% H 2 ; 5s X H2...

193

Impact of ozonation and biological treatment on disinfection by-products  

SciTech Connect

The paper summarizes several recent studies on the impact of ozonation and biological treatment on DBP formation. Ozonation was characterized by the formation of ozonation DBPs such as aldehydes, assimilable organic carbon (AOC), biodegradable dissolved organic carbon (BDOC) and the oxidation of bromide to bromate. The oxidation of the DBP precursor compounds and the effectiveness of biotreatent for the control of DBPs were monitored by the formation potential (FP) for total organic halogen (TOX), total THMs (TTHMs) and total measured haloacetic acid (THAAs). Special attention was also given to the impact of bromide concentration on the speciation of the DBPs. A specific objective of the paper was to compare DBP control by batch biological treatment at the bench-scale to that by a continuous flow sand filter at the pilot-scale.

Shukairy, H.M.; Summers, R.S.; Miltner, R.J.

1994-01-01T23:59:59.000Z

194

Isotope Evidence for Ozone Formation on Surfaces  

Science Journals Connector (OSTI)

Remarkably, the gas-phase recombination or association reaction of ozone has an unusually large (?10%) isotope effect and shows almost equal enrichments of the ozone molecules containing two different oxygen isotopes. ... For a better understanding of the pressure and temperature dependence of ozone isotopic composition in oxygen discharges, we developed a relatively simple isotope kinetic model that accounts for the processes of (i) heterogeneous ozone formation at the reactor walls, (ii) isotope exchange of oxygen atoms with O2 molecules, and (iii) ozone formation in the gas phase. ...

Christof Janssen; Bla Tuzson

2010-05-06T23:59:59.000Z

195

Ozone Reductions Using Residential Building Envelopes  

SciTech Connect

Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

Walker, Iain S.; Sherman, Max; Nazaroff, William W.

2009-02-01T23:59:59.000Z

196

Simultaneous measurements of stratospheric HOx, NOx, and Clx: Comparison with a photochemical model  

E-Print Network (OSTI)

related gases involved in catalytic destruction of ozone. Stratospheric balloon platforms carrying several

197

Interplay of air pollution and asthma immunopathogenesis: A focused review of diesel exhaust and ozone  

Science Journals Connector (OSTI)

Abstract Controlled human exposure experiments with diesel exhaust particles (DEPs) and ozone serve to illustrate the important role pollutants play in modulating both allergic mechanisms and immune responses to affect the immunopathogenesis of airway diseases such as asthma. For DEP, evidence is stronger for the exacerbation of existing asthma rather than for the development of new disease. To the extent that this enhancement occurs, the augmentation of Th2-type immunity seems to be a common element. For ozone, neutrophilic inflammation, altered immune cell phenotype and function and oxidative stress are all marked responses that likely contribute to underlying immune-inflammatory features of asthma. Evidence is also emerging that unique gene signatures and epigenetic control of immune and inflammatory-based genes are playing important roles in the magnitude of the impact ozone is having on respiratory health. Indeed, the interplay between air pollutants such as DEP and ozone and asthma immunopathogenesis is an ongoing concern in terms of understanding how exposure to these agents can lead to worsening of disease. To this end, asthmatics may be pre-disposed to the deleterious effects of pollutants like ozone, having constitutively modified host defense functions and gene signatures. Although this review has utilized DEP and ozone as example pollutants, more research is needed to better understand the interplay between air pollution in general and asthma immumopathogenesis.

Neil E. Alexis; Chris Carlsten

2014-01-01T23:59:59.000Z

198

Supporting Information for Impact of Chlorine Emissions from Sea-Salt Aerosol on Coastal Urban Ozone  

E-Print Network (OSTI)

DIOXIDE H2O2 HYDROGEN PEROXIDE NH3 AMMONIA NIT AEROSOL NITRATE SO2 SULFUR DIOXIDE SO3 SULFUR TRIOXIDE OSD extensions* NO NITRIC OXIDE NO2 NITROGEN DIOXIDE O3 OZONE HONO NITROUS ACID HNO3 NITRIC ACID HNO4 PERNITRIC ACID N2O5 NITROGEN PENTOXIDE NO3 NITRATE RADICAL HO2 HYDROPEROXY RADICAL CO CARBON MONOXIDE CO2 CARBON

Dabdub, Donald

199

Ozone decomposition in water solutions  

E-Print Network (OSTI)

. Hewes, III; B. S. , Texas ASH University Directed by Dr. R. R. Davison The rate of the decomposition of ozone in water solutions at various pH's and temperatures were ob- tained by an iodometrical method. The orders of the reactions and the reaction...

Hewes, Cecil Grayson

1969-01-01T23:59:59.000Z

200

6, 74277469, 2006 Linear ozone  

E-Print Network (OSTI)

from biases in the schemes' climatology coefficients. Cariolle v2.1 analyses showed biases of up to 20 and Kelder (1998) ozone climatology into the scheme. Chem2D-OPP v2.1 analyses showed biases up to 20 analysed temperatures and the temperature climatology supplied with the scheme. Future developments should

Boyer, Edmond

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Elementary Steps and Site Requirements for NOx Adsorption and Oxidation on Metal and Oxide Surfaces  

E-Print Network (OSTI)

Ed. ), CRC Handbook of Chemistry and Physics, 89 th ed. ,Haynes, CRC Handbook of Chemistry and Physics, 91st Edition,Haynes, CRC Handbook of Chemistry and Physics, 91st Edition,

Weiss, Brian M.

2010-01-01T23:59:59.000Z

202

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

203

DOE/EA-1472: Finding of No Significant Impact for the Commercial Demonstration of the Low NOx Burner/Separated Over-Fire Air Integration System Emission Reduction Technology (03/11/03)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

IMPACT IMPACT COMMERCIAL DEMONSRATION OF THE LOW NOx BURNER/SEPARATED OVER- FIRE AIR (LNB/SOFA) INTEGRATON SYSTEM EMISSION REDUCTION TECHNOLOGY HOLCOMB STATION SUNFLOWER ELECTRIC POWER CORPORATION FINNEY COUNTY, KANSAS AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NO,

204

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control  

Science Journals Connector (OSTI)

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control ... Despite these challenges, the proposed system was able to make several advances:? (1) meeting the T2B5 CO, HC, and PM standards; (2) quantifying the ability to meet T2B5 NOx levels with a more durable DOC and a rapid warm-up strategy to heat the exhaust, especially during the initial cold-start portion of the Federal Test Procedure (FTP) drive cycle. ... The remainder of this work is organized as follows:? The formulation, calibration, and validation of the DOC and SCR models are presented in section 2. The DOC and SCR models are combined for an analysis of the AT system as a whole in section 3. The final section of the article summarizes the results and offers some general conclusions. ...

Santhoji R. Katare; Joseph E. Patterson; Paul M. Laing

2007-03-16T23:59:59.000Z

205

Influence of operating conditions and coal properties on \\{NOx\\} and N2O emissions in pressurized fluidized bed combustion of subbituminous coals  

Science Journals Connector (OSTI)

This experimental study is aimed at finding effects of operating conditions in PFBC on nitrogen oxide emissions for subbituminous coals differing in ash content/composition, combustion/gasification reactivities and in particle size distribution. The experiments have been done on a smaller laboratory apparatus with ID=8 cm. The effects of operating pressure (0.11 MPa), temperature of the fluidized bed (800900 C), freeboard temperature and oxygen concentration (310vol.%) on the nitrogen oxides emissions are relatively complex, coupled with temperature of burning coal particles. The coal ash content/composition (esp. CaO and Fe2O3) and fly ash freeboard concentration play an important role in formation/destruction chemistry of both NO and N2O. The \\{NOx\\} emissions decrease with increasing operating pressure at the same volumetric oxygen concentration and temperature. Temperature, volatile content, reactivities of coals and ash composition are the most important factors for N2O emissions. The N2O emissions are either almost constant or can exhibit a maximum at increasing operating pressure. Influence of increasing oxygen concentration on \\{NOx\\} and N2O emissions is more pronounced at lower operating pressures, esp. for the less reactive, medium ash coal. The particle size distribution of the coal (influence of coal dust) can cause characteristic changes in \\{NOx\\} and N2O emissions in PFBC, esp. at lower combustion temperatures (800840 C). The emission changes are dependent on ash properties/composition.

Karel Svoboda; Michael Poho?el

2004-01-01T23:59:59.000Z

206

Discharge cell for ozone generator  

DOE Patents (OSTI)

A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

Nakatsuka, Suguru (Amagasaki, JP)

2000-01-01T23:59:59.000Z

207

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect

This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

2006-06-30T23:59:59.000Z

208

Ozone bleaching of recycled paper  

SciTech Connect

Chlorinated bleaching chemicals, notably chlorine and hypochlorite, are still being used to bleach deinked, woodfree pulps. Increasing environmental concern about the use of these chemicals--coupled with the industry's efforts to increase the use of recycled fibers--highlight the need to develop better techniques for producing high-quality deinked pulp. Results presented in this report suggest that deinked fibers can be treated with ozone followed by a peroxide bleaching stage to produce a high-quality pulp.

Muguet, M.; Kogan, J. (American Air Liquide, Countryside, IL (United States))

1993-11-01T23:59:59.000Z

209

Y-12 Plant Stratospheric Ozone Protection plan  

SciTech Connect

The Y-12 Plant staff is required by Lockheed Martin Energy Systems (Energy Systems) (formerly Martin Marietta Energy Systems) standard ESS-EP-129 to develop and implement a Stratospheric Ozone Protection Program which will minimize emissions of ozone-depleting substances to the environment and maximize the use of ozone-safe alternatives in order to comply with Title VI of the 1990 Clean Air Act (CAA) Amendments and the implementing regulations promulgated by the Environmental Protection Agency (EPA). This plan describes the requirements, initiatives, and accomplishments of the Y-12 Plant Stratospheric Ozone Protection Program.

NONE

1995-09-01T23:59:59.000Z

210

DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

211

The Weekend Ozone Effect - The Weekly Ambient Emissions Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

212

Toxicity of ozonated estuarine water to juvenile blue crabs (Callinectes sapidus) and Juvenile Atlantic menhaden (Brevoortia tyrannus)  

SciTech Connect

Large quantitites of estuarine and marine water are treated with chlorine to prevent condenser system fouling at power plants. Chlorine and its residual by-products, however, are toxic to many forms of aquatic life. Ozone is one alternative oxidant which has proven to be an effective biocide and disinfectant in many fresh water applications. Ozonation of estuarine and marine waters, however, may produce residual compounds similar to those produced by chlorination. This study was initiated to provide baseline information on the toxicity of ozonated estuarine water to two representative estuarine species. The blue crab, Callinectes sapidus Rathbun, and the Atlantic menhaden, Brevoortia tyrannus Latrobe, were selected because of their wide distribution and commercial importance. The toxicity of ozone has been compared with chlorine toxicity data from the literature in an effort to examine possible similarities in toxicity.

Richardson, L.B.; Burton, D.T.

1981-02-01T23:59:59.000Z

213

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

214

High-Throughput Program for the Discovery of NOx Reduction Catalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2004deerblint.pdf More Documents & Publications WA02042GENERALMOTORSPOWERTRAINDIVWaiverofDomestic.pdf Heavy-Duty NOx Emissions Control: Reformer-Assisted vs....

215

Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX Emissions  

Energy.gov (U.S. Department of Energy (DOE))

Advanced engines using HCCI or HCCI-like combustion can provide both high efficiencies and very low emissions of NOX and PM

216

Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Combustion and Lean NOx Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment....

217

E-Print Network 3.0 - aluminosilicates nox reduction Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

RELATIONSHIP BETWEEN Summary: Non-Catalytic Reduction SNCR NOx control throughout the United States and Canada. They correspond... explain why mass balances are not an appro...

218

Flexible CHP System with Low NOx, CO and VOC Emissions | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emissions Flexible CHP System with Low NOx, CO and VOC Emissions Introduction A combined heat and power (CHP) system can be a financially attractive energy option for many...

219

Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)  

SciTech Connect

This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

Not Available

2008-12-01T23:59:59.000Z

220

Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning  

Energy.gov (U.S. Department of Energy (DOE))

Presents the reliationship between Pt particle size and NOx storage performance over model catalysts. Novel reaction protocol designed to decouple effects of thermal deactivation and incomplete desulfation.

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the previous reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NOx at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O2). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor. During the current reporting period, one of the two modified PC burner designs was fabricated and installed in the pilot test facility. Testing of the modified pilot system (modified gas combustor and modified PC burner) during the quarter included 38 tests with PRB coal. NOx reduction was significantly improved to levels as low as 60-100 ppmv with CO in the range of 35-112 ppmv without any furnace air staging.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-01-31T23:59:59.000Z

222

Ozone and life on the Archaean Earth  

Science Journals Connector (OSTI)

...John Raven Ozone and life on the Archaean Earth Charles S Cockell 1 * John A Raven 2...cockell@open.ac.uk ) 1 Centre for Earth, Planetary, Space and Astronomical Research...column abundance. On the anoxic Archaean Earth, such an ozone screen would not have existed...

2007-01-01T23:59:59.000Z

223

SOx/NOx sorbent and process of use  

DOE Patents (OSTI)

An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

1993-01-19T23:59:59.000Z

224

Defensive Investments and the Demand for Air Quality: Evidence from the NOx Budget Program and Ozone Reductions  

E-Print Network (OSTI)

The economic costs of environmental regulations have been widely debated since the U.S. began to restrict pollution emissions more than four decades ago. Using detailed production data from nearly 1.2 million plant ...

Deschnes, Olivier

2012-07-15T23:59:59.000Z

225

Defensive Investments and the Demand for Air Quality: Evidence from the NOx Budget Program and Ozone Reductions  

E-Print Network (OSTI)

Willingness to pay for air quality is a function of health and the costly defensive investments that contribute to health, but there is little research assessing the empirical importance of defensive investments. The setting ...

Deschnes, Olivier

226

An Analysis of PM and NOx Train Emissions in the Alameda Corridor, CA  

E-Print Network (OSTI)

Environment. Estimation of Nitrogen Dioxide Concentrationsmatter, ozone, nitrogen dioxide and sulfur dioxide - Globalnitrate particles and nitrogen dioxide can reduce visibility

Sangkapichai, Mana; Saphores, Jean-Daniel M; Ritchie, Stephen G.; You, Soyoung Iris; Lee, Gunwoo

2008-01-01T23:59:59.000Z

227

On the NOx production by laboratory electrical discharges and lightning Vernon Cooraya,, Mahbubur Rahman a  

E-Print Network (OSTI)

in estimating the global production of NOx by lightning flashes, including field measurements carried out during influence extrapolation of laboratory data to lightning flashes. Second, an estimation of the NOx yield per lightning flash is made by treating the lightning flash as a composite event consisting of several discharge

Florida, University of

228

Measurements of NOX produced by rocket-triggered lightning M. Rahman,1  

E-Print Network (OSTI)

lightning flashes were triggered using the rocket- and-wire technique at the International Center atmosphere. [3] A direct measurement of the NOX generated by a natural lightning flash is impractical because generated by lightning flashes. Due to a large number of uncertainties involved, the estimates of global NOX

Florida, University of

229

A Novel Technology for the Reduction of NOx on Char by Microwaves  

E-Print Network (OSTI)

of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99...

Buenger, C.; Peterson, E.

230

Improvement of lightning NOx in the TM5 global chemistry transport model  

E-Print Network (OSTI)

, a key greenhouse gas, and for the formation of the hydroxyl28 radical, which removes methane, also a key greenhouse gas. Estimates of the global lightning NOx production vary29 by an order of magnitude interpreting the lighting NOx contribu-36 tion from satellite and aircraft observations of NO2 in comparison

Haak, Hein

231

Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines  

Energy.gov (U.S. Department of Energy (DOE))

Stand-alone urea SCR system was developed for marine diesel engines and showed a 50-percent reduction in NOx.

232

Development of Compact Gaseous Sensors with Internal Reference for Monitoring O2 and NOx in Combustion Environments  

Energy.gov (U.S. Department of Energy (DOE))

Compact sensors have been developed to allow for real-time monitoring of O2 and NOx during combustion.

233

Advanced NOx Emissions Control: Control Technology - Second Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Second Generation Advanced Reburning Second Generation Advanced Reburning General Electric - Energy and Environmental Research Corporation (GE-EER) is carrying out a two Phase research program to develop novel Advanced Reburning (AR) concepts for high efficiency and low cost NOx control from coal-fired utility boilers. AR technologies are based on combination of basic reburning and N-agent/promoter injections. Phase I of the project was successfully completed and EER was selected to continue to develop AR technology during Phase II. Phase I demonstrated that AR technologies are able to provide effective NOx control for coal-fired combustors. Three technologies were originally envisioned for development: AR-Lean, AR-Rich, and Multiple Injection AR (MIAR). Along with these, three additional technologies were identified during the project: reburning plus promoted SNCR; AR-Lean plus promoted SNCR; and AR-Rich plus promoted SNCR. The promoters are sodium salts, in particular sodium carbonate. These AR technologies have different optimum reburn heat input levels and furnace temperature requirements. For full scale application, an optimum technology can be selected on a boiler-specific basis depending on furnace temperature profile and regions of injector access.

234

2004 Conference on Reburning for NOX Control Reburning on Trial  

NLE Websites -- All DOE Office Websites (Extended Search)

2004 Conf. on Reburning for NOx Control Reburning on Trial 2004 Conf. on Reburning for NOx Control Reburning on Trial May 18, 2004 Table of Contents Disclaimer Papers and Presentations Reburning Overview Commercial Reburning Experience Biomass Reburning Other Applications of Reburning Posters Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

235

NETL: PPII - Integration of Low-NOx Burners with an Optimization Plan for  

NLE Websites -- All DOE Office Websites (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for Boiler Combustion [PDF-3.4MB] (June 2006) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Achieving New Source Performance Standards (NSPS) Emission Standards through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion: A DOE Assessment [PDF-1.4MB] (Nov 2006)

236

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbon??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

237

A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine  

E-Print Network (OSTI)

to prevent injury from other pollutants (Manning, 1992). It has been widely reported that ethylenediurea protects plants from ozone foliar injury (Bennett et al. , 1978; Lee et al. , 198 la; Clarke et al. , 1990', Whitaker et al. , 1990; Kostka-Rick... & Manning, 1991; 1992) as well as early senescence due to ozone damage (Temple & Bisessar, 1979; Lee et al. , 1981a; Kostka-Rick et al. , 1991). Ozone pretnaturely ages the leaf, and EDU counteracts these effects by enhancing cellular carbohydrates...

Posey, Karen Lashea

1995-01-01T23:59:59.000Z

238

Low NOx burner retrofits and enhancements for a 518 MW oil and gas fired boiler  

SciTech Connect

Low NOx oil/gas burners originally supplied to Jacksonville Electric Authority, Northside No. 3 .500 MW unit, were based on a duplex air register design with lobed spray oil atomizers providing additional fuel staging. Although the burners could meet the targeted NOx levels of 0.3 and 0.2 lbs/10{sup 6} BTU on oil and gas respectively. There was insufficient margin on these NOx levels to enable continuous low NOx operation to be achieved. Further burner development was undertaken based on improved aerodynamic control within the burner design to give an approximate 25% improvement in NOx emission reduction thus providing an adequate operating margin. This `RoBTAS` (Round Burner with Tilted Air Supply) burner design based on techniques developed successfully for front wall coal firing applications achieved the required NOx reductions in full scale firing demonstrations on both heavy fuel oil and natural gas firing. The paper describes the development work and the subsequent application of the `RoBTAS` burners to the Northside No. 3 boiler. The burner will also be test fired on Orimulsion fuel and thus the comparison between heavy fuel oil firing and Orimulsion firing under ultra low NOx conditions will be made.

King, J.J. [Jacksonville Electric Authority, FL (United States); Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

1995-12-31T23:59:59.000Z

239

Low NOx nozzle tip for a pulverized solid fuel furnace  

DOE Patents (OSTI)

A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

2014-04-22T23:59:59.000Z

240

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. During the current reporting period, BBP's subcontract was modified to reflect changes in the pilot testing program, and the modifications to the gas-fired preheat combustor were completed. The Computational Fluid Dynamics (CFD) modeling approach was defined for the combined PC burner and 3-million Btu/h pilot system. Modeling of the modified gas-fired preheat combustor was also started.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-04-29T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Experimental Studies of Hydroxyl Radical Initiated Tropospheric Oxidation of Unsaturated Hydrocarbons  

E-Print Network (OSTI)

radical, followed by chain propagating radical reactions. Their oxidation is the major source for ground level ozone formation in both rural and urban area and understanding their chemistry is essential for regional air quality modeling. Until recently...

Ghosh, Buddhadeb

2011-10-21T23:59:59.000Z

242

METHANE DE-NOX FOR UTILITY PC BOILERS  

SciTech Connect

The primary focus for the project continues to be on developing a PC PREHEAT system design suitable for use with caking coals and readying the 100 MMBtu/h CBTF for testing with noncaking PRB coal. During the current quarter, twenty-two pilot tests were conducted with Central Appalachian (CA) caking coal. The objective for these tests was to achieve continuous operation of the pilot system at its design coal feed rate of 156 lb/h, without plugging or agglomeration in the combustor. One combustor air distribution method tested achieved continuous operation at 110 lb/hr, and inspection of the combustor afterward indicated that this method has potential to solve the caking problem. The NOx results from the pilot caking coal runs indicate that even greater NOx reduction is possible with CA coal than with the PRB coal tested, to levels near 100 ppmv or lower at 4-6% exit oxygen. It was therefore decided to conduct additional pilot tests of the air distribution method to determine how to incorporate this into a workable CA combustor design. Based on current weather and manpower restrictions at the site, this pilot testing is expected to be started in February. The design for the 100 MMBtu/h unit for PRB testing in the CBTF was completed and fabrication and installation started during the quarter. While significant progress has been made in the installation of the unit, weather and combustor fabrication delays are expected to move the start of large-scale testing with PRB coal into February, which will push the project completion date beyond the current 3/30/04 end date. GTI is in the process of developing a revised project schedule and estimated cost to complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-02-06T23:59:59.000Z

243

METHANE de-NOX for Utility PC Boilers  

SciTech Connect

The primary focus for the project during the quarter was shakedown testing of the large-scale coal preheater prototype in the CBTF with non-caking PRB coal. Additional pilot-scale tests were conducted in the PSCF in support of developing a preheating system design suitable for use with caking coals. Thirty-two additional pilot tests were conducted during the quarter with caking coal. These tests further evaluated the use of the air-bleed and indirect air-cooled liner designs to reduce or eliminate combustor plugging with caking coal. The air-bleed configurations tested used air injection holes perpendicular to the liner's longitudinal axis with the number, size and air flow though the air-bleed holes varied to determine the effect on combustor plugging. The indirect cooling configurations tested included a stainless steel liner with spiral fins in the annular space between the liner and the combustor wall, and a silicon carbide liner without fins. Continuous pilot operation was maintained for up to 30 minutes at a coal feed rate of 50 lb/h with the air-bleed liner. The best result achieved was for the stainless steel indirect air-cooled liner with 20 minutes of continuous operation at 126 lb/h of coal followed by an additional 20 minutes at 150 lb/h. The NOx results from these continue to indicate that even greater NOx reduction is possible with caking coal than with the PRB coal tested. The installation of the large-scale prototype coal preheater for PRB testing in the CBTF was completed and shakedown testing with natural gas and PRB coal started during the quarter. Stable operation of the coal system, combustor and burner were achieved at coal feed rates up to 6000 lb/h (50 MMBtu/h).

Bruce Bryan; Joseph Rabovitser Serguei Nester; Stan Wohadlo

2004-06-30T23:59:59.000Z

244

Influencing factors on NOX emission level during grate conversion of three pelletized energy crops  

Science Journals Connector (OSTI)

Abstract NOX emission behavior of three different pelletized energy crops, a herbaceous one, Brassica carinata, a short rotation coppice, Populus sp., and a blend of them, was assessed during fixed grate conversion. Measurements of NOX emissions were done at combustion conditions that yielded both thermal efficiency and CO emissions according to the European norm (EN 303-5:2012), and results compared to limits established by the Austrian deviations. Based on the experimental data, NOX results fulfilled the Austrian restrictions except during combustion of brassica, which exhibited the highest Fuel-N content. The Fuel-NOX was identified as the main formation mechanism. An opposite relation was determined between the specific NOX emissions and the Fuel-N conversion ratio obtained between the N-rich and the N-lean fuels tested here. The influence of the air supply (amount and distribution) on the NOX formation was also noticeable. In general, a higher proportion of air increased the specific NOX emissions and the Fuel-N conversion ratio. Possibilities to control the NOX emissions level by air staging were rather limited, particularly, during combustion of brassica and the blend because of their peculiarities as ash-rich fuels with high slag formation risk. For attaining an appropriate conversion of these fuels, primary air requirements substantially increased. Due to limitations found during the energy crops conversion, efforts to minimize the level of NOX emissions identified here for the troublesome fuels tested should be mainly focused on attaining both a properly designed air supply system and the grate temperature control as well as on conditioning the Fuel-N content, for instance, by blending.

Maryori Daz-Ramrez; Fernando Sebastin; Javier Royo; Adeline Rezeau

2014-01-01T23:59:59.000Z

245

Geophysics: Ancient Air, Ozone, and Faults  

Science Journals Connector (OSTI)

...col-leagues at he Jet Propulsion Laboratory showing that the postulated reactions do occur under Antarctic stratospheric di-iions. Whether similar reactions accelerate ozone destruion under conditions more typial of the rest of the stratosphere re-mains...

RICHARD A. KERR

1988-01-08T23:59:59.000Z

246

Ozone treatment of biomass to enhance digestibility  

E-Print Network (OSTI)

is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

Almendarez, Maria Elena

2000-01-01T23:59:59.000Z

247

Exergy analysis of combustion characteristics and NOx emissions of a dual-fuel engine  

Science Journals Connector (OSTI)

The combustion characteristics and NOx emissions of compression ignition engines working on a dual fuel mode are investigated numerically and their exergetic efficiencies are determined. The model has been validated with available experimental results. The simulation results show that dual fuel engine combustion and trend of NOx emissions are well predicted by the present model. Parametric study showed improvements in engine performance and an increase in NOx emissions with decreased advanced injection timing of the pilot fuel as well as with increased intake temperature and pilot fuel quantity. The maximum values for energy and exergy are found to be comparable.

Mohamed H. Morsy; Abdelrahman El-Leathy; Arif Hepbasli

2012-01-01T23:59:59.000Z

248

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992  

SciTech Connect

This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

Not Available

1992-12-31T23:59:59.000Z

249

Intercomparison of ozone measurements over Antarctica  

SciTech Connect

Measurements of the abundances of ozone over Antarctic in August and September 1987 obtained during the Airborne Antarctic Ozone Experiment are intercompared. These measurements of ozone concentrations and total column abundance were obtained by three satellite instruments, two IR and one UV column-measuring instruments aboard the DC-8, one in situ DC-8, and two in situ ER-2 instruments, an upward looking lidar aboard the DC-8, and ozonesondes from four sites in Antarctica. Given the natural variability of ozone in the Antarctic and the fact that the data were not truly coincident spatially and temporally, this intercomparison is suitable only for identifying gross disparities among the techniques, rather than confirming the accuracies as rigorously as is normally done in an intercomparison. This paper presents a summary of the ozone data, using the data and accuracies given by the individual investigators in the individual papers in this issue, without any attempt to critically review or evaluate the data. In general, very good agreement (within about 10-20%, limited by natural variability) among the various techniques was found, with no systematic biases detected. These observations confirm the low ozone amounts reported in the Antarctic stratosphere.

Margitan, J.J.; Farmer, C.B.; Toon, G.C. (California Inst. of Tech., Pasadena (United States)); Brothers, G.A. (Chemal, Inc., Wallops Island, VA (United States)); Browell, E.V.; Gregory, G.L.; Hypes, W.; Larsen, J.C.; McCormick, M.P. (NASA Langley Research Center, Hampton, VA (United States)); Cariolle, D. (Centre National de la Recherches Meteorologiques, Toulouse (France)); Coffey, M.T.; Mankin, W. (National Center for Atmospheric Research, Boulder, CO (United States)); Farman, J.C. (British Antarctic Survey, Cambridge (United Kingdom)); Harder, J.W.; Mount, G.H.; Ravishankara, A.R.; Schemeltekopf, A.L.; Tuck, A.F. (NOAA Aeronomy Lab., Boulder, CO (United States)); Hofmann, D.J. (Univ. of Wyoming, Laramie (United States)); Ismail, S.; Kooi, S. (ST Systems, Inc., Hampton, VA (United States)); Jakoubek, R.O.; Proffitt, M.H.; Wahner, A.; Watterson, I. (NOAA Aeronomy Lab., Boulder, CO (United States) Univ. of Colorado, Boulder (United States)); Komhyr, W. (NOAA Air Resources La

1989-11-30T23:59:59.000Z

250

Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives  

SciTech Connect

Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jrmie; Brunner, Gregory; Zhang, Jianshun (Jensen); Fisk, William J.

2011-05-01T23:59:59.000Z

251

Definition: Reduced Sox, Nox, And Pm-2.5 Emissions | Open Energy  

Open Energy Info (EERE)

Sox, Nox, And Pm-2.5 Emissions Sox, Nox, And Pm-2.5 Emissions Jump to: navigation, search Dictionary.png Reduced Sox, Nox, And Pm-2.5 Emissions Functions that provide this benefit can lead to avoided vehicle miles, decrease the amount of central generation needed to their serve load (through reduced electricity consumption, reduced electricity losses, more optimal generation dispatch), and or reduce peak generation. These impacts translate into a reduction in pollutant emissions produced by fossil-based electricity generators and vehicles.[1] Related Terms electricity generation, reduced electricity losses, smart grid References ↑ SmartGrid.gov 'Description of Benefits' An in LikeLike UnlikeLike You like this.Sign Up to see what your friends like. line Glossary Definition Retrieved from "http://en.openei.org/w/index.php?title=Definition:Reduced_Sox,_Nox,_And_Pm-2.5_Emissions&oldid=502508

252

Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine  

SciTech Connect

Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

Not Available

2004-02-01T23:59:59.000Z

253

NH3 generation over commercial Three-Way Catalysts and Lean-NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

formulations and operation for the in-situ generation of NH3, storage on a downstream SCR catalyst, and utilized to reduce the remaining NOx deer12toops.pdf More Documents &...

254

NOx Emissions of Alternative Diesel Fuels:? A Comparative Analysis of Biodiesel and FT Diesel  

Science Journals Connector (OSTI)

This study explores the diesel injection and combustion processes in an effort to better understand the differences in NOx emissions between biodiesel, Fischer?Tropsch (FT) diesel, and their blends with a conventional diesel fuel. Emissions studies were ...

James P. Szybist; Stephen R. Kirby; Andr L. Boehman

2005-05-14T23:59:59.000Z

255

Sulphur Removal Characteristics from a Commercial NOx Storage/Reduction Catalyst.  

E-Print Network (OSTI)

??The ability to effectively remove sulphur from sulphur-poisoned NOx storage/reduction (NSR) catalysts, while minimizing associated fuel penalties and thermal degradation, is important for commercial application (more)

Kisinger, Darren

2009-01-01T23:59:59.000Z

256

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network (OSTI)

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

257

An experimental study on combustion processes and nox emission characteristics of the air-staged burner  

Science Journals Connector (OSTI)

The combustion processes and emission characteristics in air-staged burner...5H5N) is used to investigate the fuel NOX emission characteristics. Experiments are carried out for a wide range of operating condition...

Kook-Young Ahn; Han-Seok Kim; Eun-Seong Cho; Jin-Hyuk Ahn

1999-06-01T23:59:59.000Z

258

Combining Low-Temperature Combustion with Lean-NOx Trap Yields...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Posters 2005deerhuff.pdf More Documents & Publications Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Reductant Utilization in a LNT + SCR...

259

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Jim Parks (parksjeii@ornl.gov), Matt Swartz, Shean Huff, Brian West Oak Ridge National Laboratory...

260

Evaluation of oxides of nitrogen emissions for the purpose of their transient regulation from a direct injection diesel engine  

Science Journals Connector (OSTI)

The concept of defining a regulatory standard for the maximum allowable emissions of oxides of nitrogen (NOx) from a heavy-duty diesel engine on an instantaneous basis is presented. The significance of this concept from a regulatory point of view is the possibility to realise a steady brake specific NOx emissions result independent of the test schedule used. The emissions of oxides of nitrogen from a state-of-the-art direct injection diesel engine have been examined on an integral as well as on an instantaneous basis over the Federal Test Procedure as well as over several other arbitrary transient cycles generated for this study. Three candidate standards of specific NOx emissions have been evaluated on a real-time, continuous basis. These include brake power specific, fuel mass specific, and carbon dioxide mass specific NOx emissions. Retaining the stock engine control module, the carbon dioxide specific emissions of NOx have been shown to be the most uniform, varying only by about 30% of its mean value regardless of the test schedule or engine operation. The instantaneous fuel specific NOx emissions are shown to be relatively less invariant and the least steady are the brake power specific emissions with a coefficient of variation of up to 200%. Advancing injection timing has been shown to have a wide range of authority over the specific emissions of oxides of nitrogen regardless of the units used, when operating at full load in the vicinity of peak torque speeds. The carbon dioxide specific NOx emissions have shown a linear dependence on the power specific emissions, independent of the examined operating conditions. The trade-off between better brake thermal efficiency, lower exhaust gas temperature at advanced timing and lower NOx emissions has also been shown to be independent of the units of the specific standard used.

Yasser Yacoub; Chris Atkinson

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis...

262

OZONE TREATMENT OF SOLUBLE ORGANICS IN PRODUCED WATER (FEAC307)  

SciTech Connect

Oil production is shifting from ''shallow'' wells (0-650 ft water depth) to off-shore, deep-water operations (>2,600 ft.). Production from these operations is now approaching 20%. By 2007, it is projected that as much as 70% of the U.S. oil production will be from deep-water operations. The crude oil from these deep wells is more polar, thus increasing the amount of dissolved hydrocarbons in the produced water. Early data from Gulf of Mexico (GOM) wells indicate that the problem with soluble organics will increase significantly as deep-water production increases. Existing physical/chemical treatment technologies used to remove dispersed oil from produced water will not remove dissolved organics. GOM operations are rapidly moving toward design of high-capacity platforms that will require compact, low-cost, efficient treatment processes to comply with current and future water quality regulations. This project is an extension of previous research to improve the applicability of ozonation and will help address the petroleum industry-wide problem of treating water containing soluble organics. The goal of this project is to maximize oxidation of water-soluble organics during a single-pass operation. The project investigates: (1) oxidant production by electrochemical and sonochemical methods, (2) increasing the mass transfer rate in the reactor by forming microbubbles during ozone injection into the produced water, and (3) using ultraviolet irradiation to enhance the reaction if needed. Industrial collaborators include Chevron, Shell, Phillips, BP Amoco, Statoil, and Marathon Oil through a joint project with the Petroleum Environmental Research Forum (PERF). The research and demonstration program consists of three phases: (1) Laboratory testing in batch reactors to compare effectiveness of organics destruction using corona discharge ozone generation methods with hydrogen peroxide generated sonochemically and to evaluate the enhancement of destruction by UV light and micro-bubble spraying. (2) Continuous-flow studies to determine the efficacy of various contactors, the dependency of organics destruction on process variables, and scale-up issues. (3) Field testing of a prototype system in close collaboration with an industrial partner to generate performance data suitable for scale-up and economic evaluation.

Klasson, KT

2001-03-20T23:59:59.000Z

263

METHANE de-NOX for Utility PC Boilers  

SciTech Connect

During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was continued with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was decided that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, the pilot gas combustor was changed to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Testing with caking coal in the horizontal pilot combustor achieved feed rates up to 126 lb/h, although some deposition and LOI issues remain. Several promising approaches to further improve operation with caking coal were identified. NOx results with caking coal are promising, with NOx as low as 150 ppmv at exit oxygen levels of 4% and higher. The 100 MMBtu/h commercial-scale prototype design is nearing completion. Design of the caking coal version of the unit continues with additional pilot testing in support of this design expected. GTI and RPI are expediting the fabrication of the 100 MMBtu/h PRB unit in order to start testing in early- to mid-December. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) is nearing completion. As of mid-September, this activity was 95% complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2003-09-30T23:59:59.000Z

264

Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology  

E-Print Network (OSTI)

ozone record from Paramaribo, Surinam (6°N, 55°W) (also in SHADOZ) shows a marked contrast to southern tropical ozone because Surinam is often north of the Intertropical Convergence Zone (ITCZ). A more

Thompson, Anne

265

Concentration of ozone in surface air over greater Boston  

E-Print Network (OSTI)

Surface ozone concentrations were measured in the Greater Boston area from November, 1964 to December, 1965. Ozone was monitored continuosly using a Mast microcoulombmetric sensor. A chromium trioxide filter was fitted to ...

Widen, Donald Allen

1966-01-01T23:59:59.000Z

266

Open-path ozone detection by quantum-cascade laser  

Science Journals Connector (OSTI)

Open-path ozone measurements performed by mid-IR differential absorption spectroscopy are reported. Ozone spectrum was taken by fast repetitive sweeping of a quantum-cascade laser wavelength over a spectral featu...

M. Taslakov; V. Simeonov; M. Froidevaux; H. van den Bergh

2006-03-01T23:59:59.000Z

267

Chemistry climate model simulations of1 spring Antarctic ozone  

E-Print Network (OSTI)

013577. 1. Introduction [2] Since its discovery [Farman et al., 1985], the Antarctic ozone hole has been

Wirosoetisno, Djoko

268

Attribution of the Arctic ozone column deficit in March 2011  

E-Print Network (OSTI)

Toronto, Ont. , Canada. Farman, J. C. , B. G. Gardiner, andthe Antarctic ozone hole [Farman et al. , 1985]. [ 13

2012-01-01T23:59:59.000Z

269

Ozone treatment in a closed culture system for Macrobrachium rosenbergii  

E-Print Network (OSTI)

constant flow of air. The Orthotoridine-Manganese Method (OTM) wss employed to measure ozone in solution (APHA, 1976) . Because of the rapid rate of decomposition of ozone in water, it was determined that the production of ozone could not be measured... by introducing into water and then sampling that water for analysis with OTM. Therefore, ozone was introduced directly into a solution of OTM reagent with subsequent changes in color of the reagent, measured on a "B & L Spectronic 70" spectrophotometer, being...

Yamaguchi, Ryoji

1978-01-01T23:59:59.000Z

270

Release of Ammonium and Mercury from NOx Controlled Fly Ash  

SciTech Connect

One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

Schroeder, K.T.; Cardone, C.R.; Kim, A.G

2007-07-01T23:59:59.000Z

271

Failure of ozone and nitrogen dioxide to enhance lung tumor development in hamsters  

SciTech Connect

We tested the hypothesis that the two common oxidant air pollutants, ozone and nitrogen dioxide, modulate the development of respiratory tract tumors in Syrian golden hamsters. The animals received subcutaneous injections of the carcinogen diethylnitrosamine (20 mg/kg) twice a week while being exposed continuously to an atmosphere of 0.8 parts per million (ppm)* of ozone or 15 ppm of nitrogen dioxide. Animals were killed 16 weeks or 24 to 32 weeks after the beginning of the treatment. Ozone delayed the appearance of tracheal tumors and reduced the incidence of tumors in the lung periphery. A suspected neuroendocrine differentiation of those lung tumors could not be established by immunocytochemistry due to overfixation of tissues. On the other hand, ozone seemed to mitigate development of hepatotoxic lesions mediated by diethylnitrosamine. In animals treated with diethylnitrosamine and exposed to nitrogen dioxide, fewer tracheal tumors and no lung tumors were found. Only a few lung tumors were produced in animals treated with diethylnitrosamine and kept in an atmosphere of 65% oxygen. The previously observed neuroendocrine nature of tumors induced by simultaneous exposure to diethylnitrosamine and hyperoxia could not be established because the long fixation of tissues precluded immunocytochemical stains. Animals treated with diethylnitrosamine and kept in filtered air while being housed in wire-mesh cages developed fewer lung tumors than animals given the same treatment and kept on conventional bedding in shoebox cages. Although all inhalants tested are known to produce substantial cell proliferation in the respiratory tract, it was not possible to document whether this would enhance lung tumor development. The role of the two common air pollutants, ozone and nitrogen dioxide, as possible additional risks in the pathogenesis of lung cancer in animals continues to remain uncertain.

Witschi, H.; Breider, M.A.; Schuller, H.M. (Univ. of California, Davis, CA (United States))

1993-09-01T23:59:59.000Z

272

Nitrous oxide (N?O) isotopic composition in the troposphere : instrumentation, observations at Mace Head, Ireland, and regional modeling  

E-Print Network (OSTI)

Nitrous oxide (N?O) is a significant greenhouse gas and main contributor to stratospheric ozone destruction. Surface measurements of N?O mole fractions have been used to attribute source and sink strengths, but large ...

Potter, Katherine Ellison

2011-01-01T23:59:59.000Z

273

Effect of Ventilation Strategies on Residential Ozone Levels  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Ventilation Strategies on Residential Ozone Levels Effect of Ventilation Strategies on Residential Ozone Levels Title Effect of Ventilation Strategies on Residential Ozone Levels Publication Type Journal Article LBNL Report Number LBNL-5889E Year of Publication 2012 Authors Walker, Iain S., and Max H. Sherman Journal Building and Environment Volume 59 Start Page 456 Pagination 456-465 Date Published 01/2013 Keywords ashrae standard 62,2, filtration, infiltration, mechanical ventilation, ozone, simulation Abstract Elevated outdoor ozone levels are associated with adverse health effects. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone of outdoor origin would lower population exposures and might also lead to a reduction in ozone---associated adverse health effects. In most buildings, indoor ozone levels are diminished with respect to outdoor levels to an extent that depends on surface reactions and on the degree to which ozone penetrates the building envelope. Ozone enters buildings from outdoors together with the airflows that are driven by natural and mechanical means, including deliberate ventilation used to reduce concentrations of indoor---generated pollutants. When assessing the effect of deliberate ventilation on occupant health one should consider not only the positive effects on removing pollutants of indoor origin but also the possibility that enhanced ventilation might increase indoor levels of pollutants originating outdoors. This study considers how changes in residential ventilation that are designed to comply with ASHRAE Standard 62.2 might influence indoor levels of ozone. Simulation results show that the building envelope can contribute significantly to filtration of ozone. Consequently, the use of exhaust ventilation systems is predicted to produce lower indoor ozone concentrations than would occur with balanced ventilation systems operating at the same air---exchange rate. We also investigated a strategy for reducing exposure to ozone that would deliberately reduce ventilation rates during times of high outdoor ozone concentration while still meeting daily average ventilation requirements.

274

Utilization of computational fluid dynamics technique in low NOx burner/furnace retrofits  

SciTech Connect

A computational fluid dynamics (CFD) technique has been utilized to provide design guidance for retrofitting low NOx combustion systems and incorporating associated furnace modifications into existing utility boilers. The CFD program utilized is FW-FIRES (Fossil fuel, Water-walled Furnace Integrated Reaction and Emission Simulation) which simulates furnace combustion, heat transfer and pollutant formation based on fundamental principals of mass, momentum and energy conservations. The program models the gas flow field as a three-dimensional turbulent reacting continuum and the particle flow as a series of discrete particle trajectories through the gas continuum. Chemical reaction, heat transfer, and pollutant formation mechanisms are incorporated in the program. FW-FIRES furnace simulation of low NOx combustion system retrofits has been performed for various furnace configurations including front wall-fired, front and real wall-fired, and tangentially-fired furnaces, to determine the effects of burner/furnace modifications on the NOx emission, furnace exit gas temperature, furnace heat absorption, unburned carbon, and furnace wall corrosion. For front wall-fired, and front and real wall-fired furnaces, the NOx emission requirement is met by the use of Foster Wheeler lox NOx burners and overfire air (OFA) staging. Studies of burner and OFA quantify and spacing are conducted to limit NOx emission and unburned carbon to acceptable levels. A major concern in once-through supercritical units with OFA is furnace wall corrosion which is caused by high furnace wall metal temperature and corrosive hydrogen sulfide (H{sub 2}S) created in a reducing atmosphere from part of coal sulfur. The FW-FIRES code is used to minimize this corrosion potential by selecting the proper location and quantity of boundary air. A simulation of tangentially-fired unit, which has been retrofitted with low NOx burners, is used to study the effect of the burner tilt on the furnace exit gas temperature. This paper details the basis and results of several CFD analyses conducted for potential retrofit programs.

Cho, S.M.; Seltzer, A.H.; Ma, J.; Steitz, T.H.; Grusha, J.; Cole, R.W.

1999-07-01T23:59:59.000Z

275

Pilot-Scale Aftertreatment Using Nonthermal Plasma Reduction of Adsorbed NOx in Marine Diesel-Engine Exhaust Gas  

Science Journals Connector (OSTI)

Regulations governing marine diesel engine NOx emissions have recently become more stringent. As it is difficult to fulfill these requirements by combustion improvements alone, effective aftertreatment technologi...

Takuya Kuwahara; Keiichiro Yoshida

2014-01-01T23:59:59.000Z

276

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

models 19 Technical Back-Up Slides 20 Managed by UT-Battelle for the Department of Energy * Step1: NO oxidation * Step2: SS NO x & NH 3 conversions, Parasitic NH 3...

277

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

barriers 16 Technical Back-Up Slides 17 Managed by UT-Battelle for the Department of Energy * Step1: NO oxidation * Step2: SS NO x & NH 3 conversions, Parasitic NH 3...

278

Effects of pulp consistency and mixing intensity on ozone bleaching  

SciTech Connect

Conventional wisdom holds that ozone bleaching is feasible only at low or high pulp consistencies. However, recent research suggests that ozone bleaching at medium consistency is possible under conditions of high-intensity mixing. This article presents experimental results for softwood and hardwood pulps that were ozone-bleached over a range of consistencies (3-40%) and mixing conditions. Ozone was pressurized and delivered by a proprietary automated system. Results indicate that ozone bleaching at medium consistency can be as effective as bleaching at high consistency. Medium-consistency bleaching has the advantage of greater selectivity, resulting in higher pulp viscosity.

Hurst, M.M. (Quantum Technologies, Inc., Twinsburg, OH (United States))

1993-04-01T23:59:59.000Z

279

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

green sheet, (3) smoothing surface by chemically inducing reflow using a solvent,solvents comprised circa 35% of the weight of the feedstock materials for the green

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

280

Satellite constraints of nitrogen oxide (NOx) emissions from India based on OMI observations and WRFChem simulations  

E-Print Network (OSTI)

; Ghude et al., 2008]. Thermal power plants are the largest consumer of coal in India [Garg et al., 2001 and WRFChem simulations Sachin D. Ghude,1,2 Gabriele G. Pfister,2 Chinmay Jena,1 R.J. van der A,3 Louisa K tropospheric NO2 column retrievals over the Indian region, with tropospheric NO2 columns simulated

Haak, Hein

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

the unfired ceramic sample during thermal processing steps.ceramic samples were affixed to 4 silicon handle wafers using the following bonding agents: thermal

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

282

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network (OSTI)

122 Table 22. Equivalent circuit model resistances for NOof the resistance elements of the equivalent circuit offersOver time, the resistance values of the equivalent circuit

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

283

High pressure conversion of \\{NOx\\} and Hg and their capture as aqueous condensates in a laboratory piston-compressor simulating oxy-fuel CO2 compression  

Science Journals Connector (OSTI)

Abstract Oxy-fuel technology for CO2 capture has largely focused on combustion characteristics as a driver towards demonstration. Impurity removal studies typically centre on the how current environmental control units (FGD, SCR, activated carbon beds) operate in oxy-fuel firing. However, it is expected that some removal of \\{NOx\\} and \\{SOx\\} may occur during compression of flue gas through the lead chamber process. Some commercial systems link the capture of mercury to the formation of acid condensates (as a soluble mercury salt). Mercury in compressed flue gas represents a potential corrosion risk in the processing of CO2 from oxy-fuel combustion processes. Gas phase elemental mercury (Hg0) is difficult to remove from the flue gas and the level of cleaning required to prevent corrosion of cryogenic brazed aluminium heat exchangers is uncertain. This work has investigated the behaviour of gaseous Hg0 in pressurised oxy-fuel systems in terms of the potential capture in acidic condensates, interaction with \\{NOx\\} gases and liquid stability on de-pressurisation. The work was undertaken on an adapted laboratory scale three stage axial-piston compressor with gas and liquid sampling at pressures up to 30bar. The main finding was that gaseous Hg0 reacts readily with NO2 formed from NO oxidation at high pressure. This reaction occurred without the presence of water, either water vapour or liquid water, contrary to speculation in the literature. Without NO2, no capture of Hg0 was observed in the compression system. Overall, the capture of mercury during compression occurred as a consequence of high pressure, longer residence time and concentration of NO2. Capture rates of 100% Hg and 7583% \\{NOx\\} were measured from the compressor exit at 30barg.

Rohan Stanger; Timothy Ting; Terry Wall

2014-01-01T23:59:59.000Z

284

METHANE de-NOX for Utility PC Boilers  

SciTech Connect

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

2005-09-30T23:59:59.000Z

285

Coal characterisation for \\{NOx\\} prediction in air-staged combustion of pulverised coals  

Science Journals Connector (OSTI)

A series of world-traded coal samples has been tested using the Imperial College high temperature wire mesh apparatus (HTWM) in order to assess the relationship between high temperature (1600C) char nitrogen content and \\{NOx\\} formation in Hemweg Power Station (in the Netherlands) using deep furnace air staging. A linear relationship between high temperature char nitrogen and \\{NOx\\} formation has been confirmed. These results suggest that high temperature char N content is the main factor limiting \\{NOx\\} emissions with deep air-staged combustion. Char N and (hence apparently deep air-staged NOx) can be predicted with an accuracy of approximately 20% for most coals from the coal proximate and ultimate analysisbut this might not be sufficient for stations operating close to their emission limits. Measuring high temperature char N directly reduces the likely uncertainty in deep air-staged \\{NOx\\} emissions for coals (and most blends) to approximately 10%. Its use should be considered on a routine basis for coal selection on plants employing this technology.

C.K. Man; J.R. Gibbins; J.G. Witkamp; J. Zhang

2005-01-01T23:59:59.000Z

286

NASA reports drop in stratospheric ozone  

Science Journals Connector (OSTI)

NASA reports drop in stratospheric ozone ... "I believe I have that evidence," asserts NASA's Heath, adding: "It's not the proofthat will take much more work. ... Public release of the NASA data analysis is somewhat premature, he says, because the paper has not yet been published. ...

1981-08-24T23:59:59.000Z

287

Nuclear conflict and ozone depletion Quick summary  

E-Print Network (OSTI)

Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

Toohey, Darin W.

288

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in AP-XPS Measures MIEC Oxides in Action AP-XPS Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

289

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3  

E-Print Network (OSTI)

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3 A.Bonfils , Y. Creff for an automotive selective catalytic reduction (SCR) system, for which the feedback is based on a NOx sensor the variety of en- countered technologies, selective catalytic reduction (SCR) is one of the most appealing

290

Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration  

E-Print Network (OSTI)

1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

Boyer, Edmond

291

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission  

E-Print Network (OSTI)

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission Inventories J. David Felix,*, Emily M. Elliott, and Stephanie L. Shaw contributions, prior documentation of 15 N of various NOx emission sources is exceedingly limited

Elliott, Emily M.

292

OZONE PRECURSORS, SOURCE REGIONS, AND O(3) FORMATION DURING THE TEXAQS 2000 STUDY.  

SciTech Connect

The DOE G-1 aircraft made flights on 14 days during the TexAQS 2000 study. On 7 of those days, the aircraft encountered highly localized plumes exhibiting O{sub 3} concentrations in excess of 150 ppb; on some days, peak O{sub 3} concentrations were in excess of 200 ppb. These ozone plumes were rapidly formed with an efficiency (O{sub 3} per NO{sub x} molecule consumed) much higher (7-20) than observed in other urban areas (3-4), and were frequently associated with high concentrations (>20 ppb) of secondary hydrocarbon species such as formaldehyde. Back trajectory analysis showed that the plumes were invariably associated with emissions from one or more of the large industrial complexes clustered about the Houston Ship Channel and Galveston Bay. Very high hydrocarbon reactivities were found in the vicinity of these facilities during morning flights. These hydrocarbon reactivities, in combination with local NO{sub x} emissions, were large enough to support instantaneous O{sub 3} production rates as high as 200 ppb/h. It is hypothesized that the combination of nitrogen oxides and hydrocarbon emissions emanating from this complex of industries provided a potent mixture of chemicals that caused the rapid formation of very high concentrations of ozone which, depending on the prevailing meteorology, could cause exceedance of the NAAQS ozone standard anywhere in the Houston metropolitan area.

DAUM,P.H.; KLEINMAN,L.I.; BRECHTEL,F.; LEE,Y.N.; NUNNERMACKER,L.J.; SPRINGSTON,S.R.; WEINSTEIN-LLOYD,J.

2001-10-01T23:59:59.000Z

293

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III (SAGE III)  

E-Print Network (OSTI)

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas extinction. We retrieve ozone and nitrogen dioxide number densities and aerosol extinction from transmission), Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III

294

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network (OSTI)

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates #12 Satellite observations of ozone and nitrogen dioxide: from retrievals to emission es- timates / by Bas Subject headings: satellite retrieval / nitrogen dioxide / ozone / air pollution / emis- sion estimates

Haak, Hein

295

Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.  

E-Print Network (OSTI)

Ozone Reaction with HVAC Filters Hugo Destaillats, WenhaoOzone Reaction with HVAC Filters Hugo Destaillats 1,3,* ,Ozone Reaction with HVAC Filters Hugo Destaillats 1,3,* ,

Destaillats, Hugo

2012-01-01T23:59:59.000Z

296

Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide  

E-Print Network (OSTI)

Nitrous oxide is an important greenhouse gas and ozone-depleting-substance. Its sources are diffuse and poorly characterized, complicating efforts to understand anthropogenic impacts and develop mitigation policies. Online, ...

Harris, Eliza

297

International aspects of restrictions of ozone-depleting substances  

SciTech Connect

This report summarizes international efforts to protect stratospheric ozone. Also included in this report is a discussion of activities in other countries to meet restrictions in the production and use of ozone-depleting substances. Finally, there is a brief presentation of trade and international competitiveness issues relating to the transition to alternatives for the regulated chlorofluorocarbons (CFCs) and halons. The stratosphere knows no international borders. Just as the impact of reduced stratospheric ozone will be felt internationally, so protection of the ozone layer is properly an international effort. Unilateral action, even by a country that produces and used large quantities of ozone-depleting substances, will not remedy the problem of ozone depletion if other countries do not follow suit. 32 refs., 7 tabs.

McDonald, S.C.

1989-10-01T23:59:59.000Z

298

Ozone chemistry in the smoke from the Kuwait oil fires  

SciTech Connect

Ozone depletion occurred in the core of the plume of smoke from the Kuwait oil fires within 100 km of the fires, primarily in regions where NO{sub x} concentrations were high and ultraviolet flux was near zero. Rapid conversion of NO to NO{sub 2} can explain almost all of the ozone loss. Ozone was produced in diffuse regions of the plume, where the ultraviolet flux was higher than in the core. However, due to the relatively high ratio of nonmethane hydrocarbons to NO{sub x}, ozone production was slow. Since ozone was produced in a much larger volume than it was depleted, the plume as a whole was a source of ozone on a regional scale. 27 refs., 4 figs., 1 tab.

Herring, J.A.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States)

1992-09-20T23:59:59.000Z

299

Ozone Removal by Filters Containing Activated Carbon: A Pilot Study  

SciTech Connect

This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

2009-09-01T23:59:59.000Z

300

Oxidants, Antioxidants and Cell Signaling  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidants, Antioxidants and Cell Signaling Oxidants, Antioxidants and Cell Signaling Speaker(s): Chandan K. Sen Date: February 17, 1998 - 12:00pm Location: 90-3148 Seminar Host/Point of Contact: Richard Sextro Reactive oxygen species represent a common mediator of environmental stress such as during physical exercise, ozone exposure, UV radiation and xenobiotic (pollutant) metabolism. Antioxidant defense systems protect against the ravages of such reactive species. In contrast to the conventional idea that reactive oxygen is mostly a trigger for oxidative damage of biological structures, now we know that low physiologically relevant concentration of reactive oxygen species can regulate a variety of key molecular mechanisms that may be linked with important processes such as immune response, cell-cell adhesion, cell proliferation, inflammation,

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Sensors and Actuators B 118 (2006) 135141 Low temperature indium oxide gas sensors  

E-Print Network (OSTI)

Sensors and Actuators B 118 (2006) 135­141 Low temperature indium oxide gas sensors M. Sucheaa rights reserved. Keywords: Metal oxide thin films; InOx; Gas sensors; Ozone 1. Introduction The interest's attractive for many areas such as transparent electrodes for solar cells and flat panel displays

302

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

303

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

304

AP-XPS Measures MIEC Oxides in Action  

NLE Websites -- All DOE Office Websites (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

305

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect

This is the fifteenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At AEP's Gavin Plant, data from the corrosion probes showed that corrosion rate increased as boiler load was increased. During an outage at the plant, the drop in boiler load, sensor temperature and corrosion rate could all be seen clearly. Restarting the boiler saw a resumption of corrosion activity. This behavior is consistent with previous observations made at a 600MWe utility boiler. More data are currently being examined for magnitudes of corrosion rates and changes in boiler operating conditions. Considerable progress was made this quarter in BYU's laboratory study of catalyst deactivation. Surface sulfation appears to partially suppress NO adsorption when the catalyst is not exposed to NH3; NH3 displaces surface-adsorbed NO on SCR catalysts and surface sulfation increases the amount of adsorbed NH3, as confirmed by both spectroscopy and TPD experiments. However, there is no indication of changes in catalyst activity despite changes in the amount of adsorbed NH3. A monolith test reactor (MTR), completed this quarter, provided the first comparative data for one of the fresh and field-exposed monolith SCR catalysts yet developed in this project. Measurements of activity on one of the field-exposed commercial monolith catalysts do not show significant changes in catalyst activity (within experimental error) as compared to the fresh catalyst. The exposed surface of the sample contains large amounts of Ca and Na, neither of which is present in the fresh sample, even after removal of visibly obvious fouling deposits. However, these fouling compounds do not deactivate the catalyst to the extent that these same poisons do in the deliberately wet-impregnated laboratory-prepared samples (1%V{sub 2}O{sub 5}-9%WO{sub 3}/TiO{sub 2}). At least in this case, the fouling deposits generated by field exposure present little if any chemical deactivation or barrier to mass transfer. During this quarter, the slipstream reactor at Rockport operated for 1000 hours on flue gas. Periodic NO{sub x} reduction measurements were made, showing some decrease in activity relative to fresh catalyst samples. Plans are being made to take the reactor out of service at the Rockport plant and move it to Plant Gadsden. At Gadsden, inlet and outlet ports were installed on Unit 1 for the slipstream reactor during an outage.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-03-31T23:59:59.000Z

306

Ozone heating and the destabilization of traveling waves during summer  

SciTech Connect

The effects of ozone heating on the linear stability of lower stratospheric traveling waves of the summertime, extratropical circulation are examined. Based on coupled equations for the quasigeostrophic potential vorticity and ozone volume mixing ratio, it is shown that the diabatic heating arising from ozone advection can offset the damping due to Newtonian cooling, leading to wave amplification and significant changes in the structure and zonally rectified fluxes of the wave fields in both the lower stratosphere and troposphere. The vertical profile of the zonal mean wind plays a crucial role in determining whether the ozone heating destabilizes eastward and/or westward traveling disturbances.

Nathan, T.R.; Cordero, E.C.; Li, L. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States)

1994-07-01T23:59:59.000Z

307

Effect of Ventilation Strategies on Residential Ozone Levels  

E-Print Network (OSTI)

provided by HVAC system filters, it was assumed filtration from the HVAC system filters brings down HVAC system air leakage and ozone deposition on HAVC system filters.

Walker, Iain S.

2014-01-01T23:59:59.000Z

308

E-Print Network 3.0 - arctic ozone depletion Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

1 Introduction Stratospheric ozone depletion has been one... (Chubachi, 1984; Farman et al., 1985), winter ozone ... Source: Ecole Polytechnique, Centre de mathmatiques...

309

E-Print Network 3.0 - antarctic ozone experiment Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

in the 1980s of anomalously low ozone column abundances over the Antarctic by Farman et al. (1985... ), ozone abundances in the Antarctic ... Source: Ecole Polytechnique,...

310

E-Print Network 3.0 - airborne antarctic ozone Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

in the 1980s of anomalously low ozone column abundances over the Antarctic by Farman et al. (1985... ), ozone abundances in the Antarctic ... Source: Ecole Polytechnique,...

311

E-Print Network 3.0 - ambient ozone levels Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

level ozone. Lesson 2: Ozone Formation... , power plants and industry all emit air pollution that forms ... Source: Royer, Dana - Department of Earth and Environmental Sciences,...

312

Influence of combustion parameters on NOx production in an industrial boiler  

E-Print Network (OSTI)

Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M pollution using a model furnace of an industrial boiler utilizing fuel gas. The importance of this problem is mainly due to its relation to the pollutants produced by large boiler furnaces used widely in thermal

Aldajani, Mansour A.

313

Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)  

E-Print Network (OSTI)

. INTRODUCTION Plasma remediation of exhaust from internal combustion engines, and diesel engines in particular of achieving high E/N electric field/ gas number density are promising in this regard.11 Actual diesel exhaust discharge DBD reactors are being investigated for plasma remediation of NOx from the exhaust of internal

Kushner, Mark

314

tive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and  

E-Print Network (OSTI)

a few sluggish electric vehicles would cause enough traffic slowing that the gasoline- powered fleet Analy- sis article on battery-powered vehicles (Sept. 1996, p. 402A) serves as a useful remindertive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and associated NO.,. emissions

Denver, University of

315

Atmospheric Environment 38 (2004) 27792787 First detection of nitrogen from NOx in tree rings: a 15  

E-Print Network (OSTI)

abies; Air pollution; Dendroecology; Nitrogen deposition; Stable isotopes; Nitrogen dioxide 1Atmospheric Environment 38 (2004) 2779­2787 First detection of nitrogen from NOx in tree rings 2004; accepted 27 February 2004 Abstract Nitrogen isotope analysis (d15 N) of tree rings is potentially

316

Transport of NOx in East Asia identified by satellite and in situ measurements  

E-Print Network (OSTI)

Research Laboratory, Boulder, Colorado, USA, 3 Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, Colorado, USA, 4 School of Earth and Environmental Sciences, Seoul burning, and natural phenomena like lightning, wildfires, and soil microbial activity. NOx play

Park, Rokjin

317

NOx reduction with the use of feedlot biomass as a reburn fuel  

E-Print Network (OSTI)

. Additional air called overfire air (about 20 % of total air) is injected in order to complete combustion. Typically reburn fuel is natural gas (NG). From previous research at TAMU, it was found that firing feedlot biomass (FB) as reburn fuel lowers the NOx...

Goughnour, Paul Gordon

2009-05-15T23:59:59.000Z

318

Latest developments and application of DB Riley's low NOx CCV{reg{underscore}sign} burner technology  

SciTech Connect

Recent developments in DB Riley (DBR) low NOx burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1,500 Controlled Combustion Venturi (CCV{reg{underscore}sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50--70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1,300 MW opposed fired cell type boilers. In DBR's latest version of the CCV{reg{underscore}sign} burner, a second controlled flow air zone was added to enhance NOx control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg{underscore}sign} dual air zone burner in DBR's 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg{underscore}sign} single register burner. The tests results showed that the second air zone enhanced NOx reduction capability by an additional 20% over the single register design. Computational fluid dynamic (DFD) modeling results of the CCV{reg{underscore}sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NOx firing. DBR was recently awarded Phase IV of the Low Emission Boiler System (LEBS) program by the US Department of Energy to build a proof of concept facility representing the next major advancement in pulverized coal burning technology. A key part of winning that award were test results of the CCV{reg{underscore}sign} dual air zone burner with advanced air staging and coal reburning in a 100 million Btu/hr (20 MW) U-fired slagging combustor test facility. These results showed NOx emissions of less than 0.2 lb/million Btu (0.086 g/MJ) while converting the coal ash into an inert, non-leachable solid. This results is an 80% reduction in NOx emissions from currently operating U-fired slagging boilers.

Penterson, C.; Ake, T.

1998-07-01T23:59:59.000Z

319

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS:  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Title Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Publication Type Journal Article Year of Publication 2013 Authors Rosseler, Olivier, Mohamad Sleiman, Nahuel V. Montesinos, Andrey Shavorskiy, Valerie Keller, Nicolas Keller, Marta I. Litter, Hendrik Bluhm, Miquel Salmeron, and Hugo Destaillats Journal J. Phys. Chem. Lett. Volume 4 Start Page 536 Issue 3 Pagination 536-541 Date Published 01/2013 Abstract Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3-, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO3- conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3- in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds.

320

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect

Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

NONE

1995-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Combustion and \\{NOx\\} emissions of biomass-derived syngas under various gasification conditions utilizing oxygen-enriched-air and steam  

Science Journals Connector (OSTI)

The purpose of this study is to investigate the \\{NOx\\} emissions from combustion of syngas derived from gasification of three different biomass feedstock (i.e., pine, mapleoak mixture, and seed corn) at different oxygen-enriched-air and steam conditions. Three different oxygen-enriched-air and steam conditions were tested for each feedstock, thus resulting in nine different sets of syngas. The biomass-derived syngas was burned in an industrial burner that was integrated into the gasification system. The gasifier and burner are rated at 800kW and 879kW thermal, respectively. For each set of biomass-derived syngas, \\{NOx\\} emissions were measured at different burner operating conditions including various heat rates and equivalence ratios using emission analyzers with chemiluminescence technology. All the combustion test conditions are in the lean mixture ranges in order to avoid the peak temperature limitation of both the burner and combustion chamber. Results show that \\{NOx\\} emissions using syngas obtained from woody feedstock decrease almost linearly as the combustion mixture becomes leaner and the heat rate decreases. When compared to natural gas, syngas from both woody feedstock generates higher \\{NOx\\} emissions even when the heat rates are comparable, indicating that fuel \\{NOx\\} formation is highly important in biomass-derived syngas combustion. In contrast to syngas from woody feedstock, syngas from seed corn results in peak \\{NOx\\} emissions before \\{NOx\\} decreases with leaner conditions. The trend is observed for all fuel flow rates and all oxygen-enriched-air and steam conditions of seed corn-derived syngas. Among the three feedstock, seed corn has the highest nitrogen content which yields the highest ammonia concentration in syngas, which, in turn, results in the highest \\{NOx\\} emissions for all test conditions. Overall, the \\{NOx\\} emissions from seed corn-derived syngas combustion are approximately in the range of 450900ppm higher compared to those from wood-derived syngas combustion.

Cuong Van Huynh; Song-Charng Kong

2013-01-01T23:59:59.000Z

322

On the Promoting Effect of Water during NOx Removal over Single-Site Copper in Hydrophobic Silica APD-Aerogels  

Science Journals Connector (OSTI)

Reversibility of the Cu2+/Cu+ redox pair was confirmed in the Cu-aerogel during and after wet redox cycling. ... (1) Popular solutions to selective catalytic reduction of NOx include the use of exhaust hydrocarbon residuals (SCR-HC-deNOx) or ammonia added to the exhaust (SCR-NH3-deNOx) as the reductant; the former technology being suitable for light duty passenger vehicles, whereas the latter is applied to medium or heavy duty vehicles. ... During vehicle use, the converter is exposed to heat, which causes the metal particles to agglomerate and grow, and their overall surface area to decrease. ...

Tina Kristiansen; Karina Mathisen

2014-01-10T23:59:59.000Z

323

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network (OSTI)

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

324

Quantifying Denitrification and Its Effect on Ozone Recovery  

Science Journals Connector (OSTI)

...Effect on Ozone Recovery 10.1126...USA. 3 Atmospheric and Environmental...effects on ozone recovery in a colder and possibly...below the condensation point of...37) [or water vapor (38...5 ppm for water vapor. The atmospheric concentrations...

A. Tabazadeh; M. L. Santee; M. Y. Danilin; H. C. Pumphrey; P. A. Newman; P. J. Hamill; J. L. Mergenthaler

2000-05-26T23:59:59.000Z

325

Massive global ozone loss predicted following regional nuclear conflict  

Science Journals Connector (OSTI)

...particles, which in turn heat the ambient air, causing...Heterogeneous reaction of ozone with hydrocarbon flame soot . Phys Chem Chem Phys...and nonreactive uptake on hydrocarbon soot: HNO 3 , O 3 , and N 2...the reaction of ozone with combustion soot: Implications for reactivity...

Michael J. Mills; Owen B. Toon; Richard P. Turco; Douglas E. Kinnison; Rolando R. Garcia

2008-01-01T23:59:59.000Z

326

Atmospheric Environment 41 (2007) 31513160 Ozone removal by HVAC filters  

E-Print Network (OSTI)

Atmospheric Environment 41 (2007) 3151­3160 Ozone removal by HVAC filters P. Zhao, J.A. Siegel?, R May 2006; accepted 14 June 2006 Abstract Residential and commercial HVAC filters that have been loaded of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial

Siegel, Jeffrey

327

URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA  

E-Print Network (OSTI)

Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

Boyer, Edmond

328

BaO/Al2O3/NiAl(110) Model NOx Storage Materials: the effect of BaO film thickness on the amorphous-to-crystalline Ba(NO3)2 phase transition  

SciTech Connect

The reaction of NO2 with BaO (0.15 2 ML and > 30 ML)/Al2O3(12 ML)/NiAl(110) model NOx storage materials was studied. A thick (~12 ML), ordered Al2O3 film was prepared as the support oxide on a NiAl(110) substrate in order to minimize the effect of the intermixing between the two oxide phases (BaO and Al2O3) on the NOx chemistry of BaO. The growth of a thick alumina film, prepared by atomic oxygen deposition onto NiAl(110), follows a layer-by-layer growth mode and the resulting film is much more stable when exposed to NO2 than the ultra-thin alumina films studied before. The interaction of NO2 with the model NOx storage systems at low coverages of BaO show fundamentally different behaviors from a thick BaO film, as nitrite species form at low exposures of NO2, followed by nitrate formation at high NO2 exposures. In contrast, on the thick BaO layer nitrite-nitrate ion pairs form at 300 K under UHV conditions (PNO2 ~ 1 ? 10-9 Torr). However, at elevated NO2 pressures (? 1 ? 10-5 Torr) the thick BaO film is gradually converted into amorphous Ba(NO3)2 at 300 K. Raising the temperature of the samples with ?BaO > 1 ML after NO2 exposure (in the absence of gas phase NO2) leads to the phase transformation of the amorphous Ba(NO3)2 layer into crystalline Ba(NO3)2 particles in the temperature range of 500 600 K. No phase transformation is observed in samples with ?BaO < 1 ML.

Yi, Cheol-Woo W.; Szanyi, Janos

2009-01-15T23:59:59.000Z

329

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application  

SciTech Connect

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Huang, Shyan C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2002-10-01T23:59:59.000Z

330

Effects of 20002050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone  

E-Print Network (OSTI)

) project major changes in anthro- pogenic emissions of greenhouse gases and ozone precur- sors over the 2Effects of 2000­2050 changes in climate and emissions on global tropospheric ozone and the policy; published 27 September 2008. [1] We use a global chemical transport model (GEOS-Chem) driven by a general

Mickley, Loretta J.

331

An Analysis of the health impacts from PM and NOx emissions resulting from train operations in the Alameda Corridor, CA  

E-Print Network (OSTI)

2009). Estimating PM and NOx Train Emissions in the AlamedaAuthority. Number of Trains Running on the Alameda Corridor.x emissions resulting from train operations in the Alameda

Sangkapichai, Mana; Saphores, Jean-Daniel M; Ogunseitan, Oladele; Ritchie, Stephen G.; You, Soyoung Iris; Lee, Gunwoo

2010-01-01T23:59:59.000Z

332

Heavy-duty diesel vehicle Nox? aftertreatment in 2010 : the infrastructure and compliance challenges of urea-SCR  

E-Print Network (OSTI)

Increasingly stringent heavy-duty vehicle emission regulations are prompting the use of PM and NOx aftertreatment systems in the US, the EU and Japan. In the US, the EPA Highway Diesel Rule, which will be fully implemented ...

Bodek, Kristian M

2008-01-01T23:59:59.000Z

333

Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Adsorber for Hydrocarbons and NOx  

Energy.gov (U.S. Department of Energy (DOE))

Reports results from study of potential for using chemisorbing materials to temporally trap HC and NOx emissions during cold-start of HEVs and PHEVs over transient driving cycles

334

Proceedings: Indoor Air 2005 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON  

E-Print Network (OSTI)

Proceedings: Indoor Air 2005 2118 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON PRIMARY of reactions of ozone on building products and on their emissions in indoor air. For this purpose, 12 building products were exposed to ozone in a dedicated experimental setup. The measured ozone removal rate

Paris-Sud XI, Université de

335

Air Quality Conformity G.C. Sciara  

E-Print Network (OSTI)

) · Nitrogen Dioxide (NO2) · Ozone (O3) ­ Volatile Organic Compounds (VOC) ­ Oxides of Nitrogen (NOX) · Oxides disease · Contributes to 80,000 premature deaths/year in CA #12;U.S. Sources of Oxides of Nitrogen EPA

Handy, Susan L.

336

NOx Emissions Reductions from Implementation of the 2000 IECC/IRC Conservation Code to Residential Construction in Texas  

E-Print Network (OSTI)

.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 To ns - NOx/day (average) Tons - NOX/day (p eak) Apx 2x difference 1:1 2...

Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.

2004-01-01T23:59:59.000Z

337

Application of Taguchi's orthogonal array in reducing the NOx emission of a stationary diesel engine  

Science Journals Connector (OSTI)

The main objective of this investigation is to reduce the NOx emission of a stationary diesel engine with less sacrifice on smoke intensity and brake thermal efficiency (BTE). Fuel injection timing, percentage of EGR and fuel injection pressure are chosen as factors influencing the objective. Three levels were chosen in each factor and design of experiments method was employed to design the experiments. Taguchi's L9 orthogonal array was used to conduct the engine tests with different levels of the chosen factors. Test results were analysed by analysis of variance (ANOVA) method and ANOVA table was formed for each response variable. From the ANOVA table the most influencing factor and also the significance of each factor affecting the NOx emission, smoke intensity and BTE was found out. Response graph was drawn for each response variable to determine the optimum combination of the factor levels. This optimum combination was confirmed experimentally. [Received: November 14, 2010; Accepted: March 17, 2011

S. Saravanan; G. Nagarajan; R. Ramanujam; S. Sampath

2011-01-01T23:59:59.000Z

338

UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS  

SciTech Connect

Potomac Electric Power Company (PEPCo) Class F fly ash is the first material to be worked on in this project. A head sample was taken and a screen analysis performed. Each size fraction was evaluated for LOI content. Table 1 shows the distribution of the as-received material by size and LOI content. From the data, 80% of the as-received material is finer than 400 mesh and the LOI content goes from high at coarse fractions and decreases to a low at the finest size fraction. SEM chemical analysis identified the as-received fly ash to mainly consist of silica (46%), aluminum oxide (21%), and iron in various forms (16%). The high iron content presents an extreme case as compared to other fly ash samples we have evaluated previously. Its effect on product testing applications could identify physical and chemical limitations as product testing progresses. Because of the high iron content, it was realized that magnetic separation would be incorporated into the early part of the pilot plant flowsheet to remove magnetic iron and, hopefully, reduce the total iron content. More analytical data will be presented in the next reporting period.

A.M. HEIN; J.Y. HWANG; M.G. MCKIMPSON; R.C. GREENLUND; X. HUANG

1998-10-01T23:59:59.000Z

339

Gas-Phase Advanced Oxidation for Effective, Efficient in Situ Control of Pollution  

Science Journals Connector (OSTI)

The process uses ozone and UV-C light to produce in situ radicals to oxidize pollution, generating particles that are removed by a filter; ozone is removed using a MnO2 honeycomb catalyst. ... (22, 23) Catalytic and thermal oxidizers can be used effectively for treating high VOC levels (>1 g/m3) but require additional fuel when pollution is below the threshold needed to maintain operating temperature; these methods have relatively high costs for installation, operation, and maintenance. ... (24) Regenerative adsorption and cryotrapping remove VOCs but consume energy and are not suitable for wet gas streams. ...

Matthew S. Johnson; Elna J. K. Nilsson; Erik A. Svensson; Sarka Langer

2014-06-23T23:59:59.000Z

340

Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction with HVAC Filters Title Laboratory Measurement of Secondary Pollutant Yields from Ozone Reaction with HVAC Filters Publication Type Conference Proceedings Year of Publication 2009 Authors Destaillats, Hugo, Wenhao Chen, Michael G. Apte, Nuan Li, Michael Spears, Jérémie Almosni, Jianshun Zheng, and William J. Fisk Conference Name Proceedings of the Healthy Buildings 2009 Conference Conference Location Syracuse, NY Keywords building-related symptoms, hvac filter, ozone, ptr-ms, secondary pollutants Abstract We used Proton Transfer Reaction - Mass Spectrometry (PTR-MS) and conventional sampling methods to monitor and identify trace level organic pollutants formed in heterogeneous reactions between ozone and HVAC filters in real time. Experiments were carried out using a bench-scale flow tube reactor operating with dry air and humidified air (50% RH), at realistically high ozone concentrations (150 ppbv). We explored different filter media (i.e., fiberglass and cotton/polyester blends) and different particle loadings (i.e., clean filter and filters loaded with particles for 3 months at the Lawrence Berkeley National Laboratory and the Port of Oakland, CA). Detailed emission dynamics of very low levels of certain organic pollutants from filter media upon ozone exposure in the presence of moisture have been obtained and analyzed.

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

342

The Solubility of Oxygen and Ozone in Liquids  

Science Journals Connector (OSTI)

This review covers the solubility of oxygen and ozone in liquids as a function of temperature and pressure. Solubility data for individual systems were critically evaluated and recommended or tentative values presented in many cases. The trend of solubilities in homologous series or related solvents is discussed. Liquids include water;seawater; aqueous salt solutions; mixed solvents; hydrocarbons; organic compounds containing oxygen halogen sulfur nitrogen or silicon; olive oil; and human blood. For ozone only its solubility in water is presented. Key words: aqueous solutions; biological fluids; gas solubility; hydrocarbons; mixed solvents; organic solvents; oxygen; ozone;seawater;water.

Rubin Battino; Timothy R. Rettich; Toshihiro Tominaga

1983-01-01T23:59:59.000Z

343

Ozone generation by rock fracture: Earthquake early warning?  

SciTech Connect

We report the production of up to 10 ppm ozone during crushing and grinding of typical terrestrial crust rocks in air, O{sub 2} and CO{sub 2} at atmospheric pressure, but not in helium or nitrogen. Ozone is formed by exoelectrons emitted by high electric fields, resulting from charge separation during fracture. The results suggest that ground level ozone produced by rock fracture, besides its potential health hazard, can be used for early warning in earthquakes and other catastrophes, such as landslides or land shifts in excavation tunnels and underground mines.

Baragiola, Raul A.; Dukes, Catherine A.; Hedges, Dawn [Engineering Physics, University of Virginia, Charlottesville, Virginia 22904 (United States)

2011-11-14T23:59:59.000Z

344

\\{NOx\\} emission characteristics of fluidized bed combustion in atmospheres rich in oxygen and water vapor for high-nitrogen fuel  

Science Journals Connector (OSTI)

Abstract The present study examines the influence of water vapor in combustion atmosphere on \\{NOx\\} emission from oxygen-enriched combustion of air-dried distilled spirit lees and its char in a laboratory fluidized bed of 760mm high and 68mm in inner diameter. Steam was added into the fluidizing gas to vary the vapor content in the combustion atmosphere. At a combustion temperature of 950C and a steam-to-fuel mass ratio (S/F) of 0.5, the presence of water vapor reduced the \\{NOx\\} concentration in the flue gas for low O2 contents (?30vol.%) in the combustion agent but increased the \\{NOx\\} emission for high O2 contents (?40vol.%). The possible causes were clarified for this shift from suppression to promotion of fuel-N conversion into \\{NOx\\} with raising O2 concentration in the combustion agent. Varying temperature from 850C to 1150C resulted in a peak conversion of fuel-N to \\{NOx\\} in the temperature range of 9501050C for all the tested O2 concentrations. Increasing the O2 concentration tended to lower the critical temperature corresponding to such a peak fuel-N conversion. Testing results also suggested that the presence of excessive water vapor in the combustion atmosphere would inhibit the release of fuel-N in the devolatilization stage and promote the formation of some reducing gases. In addition to the anticipated diluting effect, the steam addition also shortened the reaction time for homogeneous and heterogeneous \\{NOx\\} reduction by the reducing gases and char. It is postulated that the formation of OH radicals at high O2 content and high temperature could cause the observed increase in the \\{NOx\\} emission.

Chuanqiang Zhu; Shuyuan Liu; Huan Liu; Juan Yang; Xiaoxing Liu; Guangwen Xu

2015-01-01T23:59:59.000Z

345

The effect of ozone on nicotine desorption from model surfaces:evidence for heterogeneous chemistry  

SciTech Connect

Assessment of secondhand tobacco smoke exposure using nicotine as a tracer or biomarker is affected by sorption of the alkaloid to indoor surfaces and by its long-term re-emission into the gas phase. However, surface chemical interactions of nicotine have not been sufficiently characterized. Here, the reaction of ozone with nicotine sorbed to Teflon and cotton surfaces was investigated in an environmental chamber by monitoring nicotine desorption over a week following equilibration in dry or humid air (65-70 % RH). The Teflon and cotton surfaces had N{sub 2}-BET surface areas of 0.19 and 1.17 m{sup 2} g{sup -1}, and water mass uptakes (at 70 % RH) of 0 and 7.1 % respectively. Compared with dry air baseline levels in the absence of O{sub 3}, gas phase nicotine concentrations decrease, by 2 orders of magnitude for Teflon after 50 h at 20-45 ppb O{sub 3}, and by a factor of 10 for cotton after 100 h with 13-15 ppb O{sub 3}. The ratios of pseudo first-order rate constants for surface reaction (r) to long-term desorption (k) were r/k = 3.5 and 2.0 for Teflon and cotton surfaces, respectively. These results show that surface oxidation was competitive with desorption. Hence, oxidative losses could significantly reduce long-term re-emissions of nicotine from indoor surfaces. Formaldehyde, N-methylformamide, nicotinaldehyde and cotinine were identified as oxidation products, indicating that the pyrrolidinic N was the site of electrophilic attack by O{sub 3}. The presence of water vapor had no effect on the nicotine-O{sub 3} reaction on Teflon surfaces. By contrast, nicotine desorption from cotton in humid air was unaffected by the presence of ozone. These observations are consistent with complete inhibition of ozone-nicotine surface reactions in an aqueous surface film present in cotton but not in Teflon surfaces.

Destaillats, Hugo; Singer, Brett C.; Lee, Sharon K.; Gundel, LaraA.

2005-05-01T23:59:59.000Z

346

The Ozone Dilemma: a reference handbook (Contemporary World Issues Series)  

E-Print Network (OSTI)

Dilemma: a reference handbook By David E. Newton Reviewed byDilemma: a reference handbook (Contemporary World IssuesThe Ozone Dilemma: a reference handbook is targeted at both

Li, Haipeng

1997-01-01T23:59:59.000Z

347

The role of ozone in tracheal cell transformation  

SciTech Connect

This project examined the potential role of ozone as a respiratory carcinogen by characterizing its ability to induce or modulate the preneoplastic transformation of rat tracheal epithelial cells. The chemical reactivity of ozone and the types of damage it can cause suggest that it may have a role in environmental carcinogenesis. Few other studies have examined the direct cytotoxic or transforming effects of ozone after in vivo or in vitro exposure of cells, and no studies have been reported on the comparative effects of ozone on respiratory cells exposed in vivo or in vitro. The induction of early preneoplastic changes in populations of rat tracheal epithelial cells by carcinogens can be detected and quantified in vitro after exposures in vivo or in vitro of tracheal epithelial cells. This cell culture and transformation system was used to characterize the transforming potency of ozone. Tracheal epithelial cells were isolated from Fischer-344/N rats that had been exposed for six hours per day, five days per week for one, two, or four weeks to 0, 0.12, 0.5, or 1.0 parts per million (ppm)* ozone (sea-level equivalents). Cell populations were examined in culture for increases in the frequency of preneoplastic variants. Rats exposed to ozone did not exhibit an increase in the frequency of preneoplastic tracheal cells, although exposed tracheas did exhibit dose-dependent morphological changes. Rat tracheal epithelial cells were given single, 40-minute in vitro exposures to concentrations of ozone that did not result in any detectable decrease in colony-forming efficiency.

Thomassen, D.G.; Harkema, J.R.; Sun, J.D.; Stephens, N.D.; Griffith, W.C. (Inhalation Toxicology Research Institute, Lovelace Biomedical and Environmental Research Institute, Albuquerque, NM (United States))

1992-04-01T23:59:59.000Z

348

Step-coverage simulation for tetraethoxysilane and ozone atmospheric pressure chemical vapor deposition  

SciTech Connect

A simulation model for atmospheric pressure (AP) CVD has bee developed using one-dimensional diffusion and mass conservation equations. The model was applied to trench step-coverage of the tetraethoxysilane (TEOS) and O[sub 3] CVD, in which it was not necessary to consider lateral diffusion because of narrow (and deep) trenches. For nondoped silicate glass (NSG), the step-coverage of a 4.5 aspect ratio trench showed a good fit if a sticking probability of 0.0039 was assumed for the 0.6% ozone (in oxygen) deposition and of 0.0026 for the 6% ozone deposition (both 400 C). The reaction rate constant was compared with the diffusion mass-transfer coefficient, and the reaction proved to be limited by diffusion of the reactant, TEOS, which directly participated in the CVD reaction. For the 2 m/o phosphosilicate glass (PSG) step-coverage, which had a slight overhang, the model matched the obtained results well only when an active growth species with a high sticking probability of 1.0 was added to the growth species of nondoped oxide. This analytical simulation method satisfactorily explains the experimental data.

Fujino, K. (Semiconductor Process Lab., Toyko (Japan)); Egashira, Y.; Shimogaki, Y.; Komiyama, H. (Univ. of Tokyo, (Japan). Dept. of Chemical Engineering)

1993-08-01T23:59:59.000Z

349

Understanding how the North American Monsoon creates an ozone  

E-Print Network (OSTI)

EPA NEI-05 + Mexico NEI · Biogenic emissions: MEGAN ­ online calculation based on T, PAR · Wildfire enhancement over southern US due to convective transport of O3 and its precursors coincident with lightning-produced NOx ­ The location of maximum O3 values is anywhere from northern Mexico to Florida #12;Previous work

350

Development of a control-oriented model to optimise fuel consumption and NOX emissions in a DI Diesel engine  

Science Journals Connector (OSTI)

Abstract This paper describes a predictive NOX and consumption model, which is oriented to control and optimisation of DI Diesel engines. The model applies the Response Surface Methodology following a two-step process: firstly, the relationship between engine inputs (intake charge conditions and injection settings) and some combustion parameters (peak pressure, indicated mean effective pressure and burn angles) is determined; secondly, engine outputs (NOX and consumption) are predicted from the combustion parameters using NOX and mechanical losses models. Splitting the model into two parts allows using either experimental or modelled combustion parameters, thus enhancing the model flexibility. If experimental in-cylinder pressure is used to obtain combustion parameters, the mean error of predicted NOX and consumption are 2% and 6% respectively, with a calculation time of 5.5ms. Using modelled parameters reduces the calculation time to 1.5ms, with a penalty in the accuracy. The model performs well in a multi-objective optimisation, reducing NOX and consumption in different amounts depending on the objective of the optimisation.

S. Molina; C. Guardiola; J. Martn; D. Garca-Sarmiento

2014-01-01T23:59:59.000Z

351

Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides  

E-Print Network (OSTI)

?CO, and H, O are initially present in exhaust stream [57]. .. . . . 42 Fig. 21 Fig. 22 Reaction path diagram for RAPRENOx process [63]. .. . Reduction of nitric oxide as a function of temperature, concentration of oxygen, carbon monoxide, and water... the influence of carbon monoxide [89]. . . . . . . . . 58 Fig. 28 Effect of residence time on the NOxOUT process as a function of temperature, NO(initial)=125ppm, 0-ratio of 4 [90]. .. . . . . . . . . . . . . . . 60 Fig. 29 Ammonia slip as a function...

Gentemann, Alexander M.G.

2001-01-01T23:59:59.000Z

352

Correcting injection pressure maladjustments to reduce NOX emissions by marine diesel engines  

Science Journals Connector (OSTI)

Emissions from the exhausts of marine diesel engines comprises several different gases including NOX. These are currently regulated at the international level under Regulation 13 of ANNEX VI of MARPOL 73/78, but this regulation only applies to new engines and is based on bench tests, for only a single engine designated the parent engine. Here, the need to take measurements from across their whole range and once in operation on board a vessel is examined. This would not only improve assessment of new equipment against the current regulation, but would also detect defects in the functioning of the engine.

C. Vanesa Durn Grados; Zigor Uriondo; Manuel Clemente; Francisco J. Jimnez Espadafor; Juan Moreno Gutirrez

2009-01-01T23:59:59.000Z

353

Technology innovations and experience curves for nitrogen oxides control technologies  

SciTech Connect

This paper reviews the regulatory history for nitrogen oxides (NOx) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO{sub 2}) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. Patent data are used to show that in the cases of Japan, Germany, and the United States, innovations in NOx control technologies did not occur until stringent government regulations were in place, thus 'forcing' innovation. It is demonstrated that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NOx control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to {approximately} 86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale. 38 refs., 10 figs., 3 tabs.

Sonia Yeh; Edward S. Rubin; Margaret R. Taylor; David A. Hounshell [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Risk Management Research Laboratory, Office of Research and Development,

2005-12-15T23:59:59.000Z

354

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials: Preliminary Results and  

E-Print Network (OSTI)

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials air quality. #12;Proceedings of Healthy Buildings 2009 Paper 141 Removing ozone from indoor

Siegel, Jeffrey

355

Apparatus and method for stabilization or oxidation of polymeric materials  

DOE Patents (OSTI)

An apparatus for treating polymeric materials comprises a treatment chamber adapted to maintain a selected atmosphere at a selected temperature; a means for supporting the polymeric material within the chamber; and, a source of ozone-containing gas, which decomposes at the selected temperature yielding at least one reactive oxidative species whereby the polymer is stabilized and cross linked through exposure to the oxidative species in the chamber at the selected temperature. The ozone may be generated by a plasma discharge or by various chemical processes. The apparatus may be configured for either batch-type or continuous-type processing. The apparatus and method are especially useful for preparing polymer fibers, particularly PAN fibers, for later carbonization treatments as well as to make flame-retardant fabrics.

Paulauskas, Felix L. (Knoxville, TN) [Knoxville, TN; Sherman, Daniel M. (Knoxville, TN) [Knoxville, TN

2010-01-19T23:59:59.000Z

356

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents (OSTI)

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

357

Assessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS  

E-Print Network (OSTI)

the formation and transport of nitrogen dioxide, ozone, particulate matter and other species throughout EuropeAssessment of soil nitrogen oxides emissions and implementation in LOTOS-EUROS Date 18 March 2013, climate and nitrogen availability. Nitrogen availability is in turn determined by N-deposition from

Haak, Hein

358

6, 93159349, 2006 Seasonality of O3  

E-Print Network (OSTI)

(nitrogen oxide (NO) + nitrogen dioxide (NO2)=NOx) oxidized to NOz (total reac- tive nitrogen (NOy (EN), defined as the net number of ozone molecules produced per molecule of nitrogen ox- ides.s.l. This dataset is a unique long-term data series of nitrogen levels in the free troposphere over Central Europe

Paris-Sud XI, Université de

359

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

360

E-Print Network 3.0 - atmospheric ozone depletion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

H. U., The ozone distributionin the atmosphere,Can. J. Chem., 52, 1491-1504, 1974. Farman, J. C... , Quasi-biennial modulation of the Antarctic ozone ... Source: Bowman,...

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

E-Print Network 3.0 - arctic ozone hole Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

The discovery of the ozone hole in the Southern Hemi- sphere... (Chubachi, 1984; Farman et al., 1985), winter ozone losses over the Arctic (e.g. Brune et al., 1991... .,...

362

E-Print Network 3.0 - antarctic ozone depletion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

-B and Biosphere." Oecologia 128(1-2): 1-296. (1997). Ozone depletion FAQ Part IV: UV radiation and its effects... -B radiation due to stratospheric ozone depletion on global...

363

E-Print Network 3.0 - acute ozone-induced change Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract Predicting ozone-induced reduction of carbon... a leaf-level model to the whole tree, it is possible to investigate whether the ozone-induced ... Source: Michigan...

364

Interannual Variations of Total Ozone at Northern Midlatitudes Correlated with Stratospheric EP Flux and Potential Vorticity  

Science Journals Connector (OSTI)

At northern midlatitudes over the 19792002 time period, column ozone trends are observed to have maximum negative amplitudes in February and March. Here, the portion of the observed ozone interannual variability and trends during these months ...

L. L. Hood; B. E. Soukharev

2005-10-01T23:59:59.000Z

365

Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone  

E-Print Network (OSTI)

Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated

Barthelat, Francois

366

Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

367

E-Print Network 3.0 - acid regulates ozone-induced Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

ozone-induced Search Powered by Explorit Topic List Advanced Search Sample search results for: acid regulates ozone-induced Page: << < 1 2 3 4 5 > >> 1 Plant Molecular Biology 51:...

368

A delayed effect of ozone fumigation on photosynthesis of Norway spruce  

E-Print Network (OSTI)

A delayed effect of ozone fumigation on photosynthesis of Norway spruce D. Eamus1 A.W. Davis J into the long-lastincl effects of ozone fumiga- tion upon photosynthesis of Norway spruce. Measurements were

Paris-Sud XI, Université de

369

Method for control of NOx emission from combustors using fuel dilution  

DOE Patents (OSTI)

A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

Schefer, Robert W. (Alamo, CA); Keller, Jay O (Oakland, CA)

2007-01-16T23:59:59.000Z

370

Atmospheric Environment 38 (2004) 14251436 A development of ozone abatement strategies for the Grenoble  

E-Print Network (OSTI)

with the time evolution of the ozone isopleths at the maximums locations (south and north west valleys). r 2003

371

Meteorological Simulations of Ozone Episode Case Days during the 1996 Paso del Norte Ozone Study  

SciTech Connect

Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13,1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were petiormed using the HOTMAC mesoscale meteorological model using a 1,2,4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11-13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawirisonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. We found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

1999-02-01T23:59:59.000Z

372

Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Pollution Control Regulations: No.27 - Control of Nitrogen Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe possibilities for exemptions (i.e., for sources which have the potential to emit 50 tons but do not actually reach that level) and Reasonably Available Control

373

Advanced Metal-Oxide based SCR Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

SCR with ammonia as reductant is an effective strategy being utilized to reduce NOx emissions to meet regulated levels.

374

Yields of Secondary Organic Aerosol from Reactions between Ozone and Surface-Adsorbed d-Limonene  

E-Print Network (OSTI)

Yields of Secondary Organic Aerosol from Reactions between Ozone and Surface-Adsorbed d, terpenes can adsorb onto building materials, and Springs et al. (2011) determined that ozone did, in fact, react with terpenes adsorbed to surfaces. The purpose of this work was to determine the yield of ozone

Siegel, Jeffrey

375

PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure  

E-Print Network (OSTI)

-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up1 PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch B.C. Stratton1, R. Knight2, and D.R. Mikkelsen1, A. Blutke3, and J

376

1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.  

E-Print Network (OSTI)

Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

Crambes, Christophe

377

Simulating the Impact of Premixed Charge Compression Ignition on Light-Duty Diesel Fuel Economy and Emissions of Particulates and NOx  

SciTech Connect

We utilize the Powertrain Systems Analysis Toolkit (PSAT) combined with transient engine and aftertreatment component models implemented in Matlab/Simulink to simulate the effect of premixed charge compression ignition (PCCI) on the fuel economy and emissions of light-duty diesel-powered conventional and hybrid electric vehicles (HEVs). Our simulated engine is capable of both conventional diesel combustion (CDC) and premixed charge compression ignition (PCCI) over real transient driving cycles. Our simulated aftertreatment train consists of a diesel oxidation catalyst (DOC), lean NOx trap (LNT), and catalyzed diesel particulate filter (DPF). The results demonstrate that, in the simulated conventional vehicle, PCCI can significantly reduce fuel consumption and emissions by reducing the need for LNT and DPF regeneration. However, the opportunity for PCCI operation in the simulated HEV is limited because the engine typically experiences higher loads and multiple stop-start transients that are outside the allowable PCCI operating range. Thus developing ways of extending the PCCI operating range combined with improved control strategies for engine and emissions control management will be especially important for realizing the potential benefits of PCCI in HEVs.

Gao, Zhiming [ORNL; Daw, C Stuart [ORNL; Wagner, Robert M [ORNL; Edwards, Kevin Dean [ORNL; Smith, David E [ORNL

2013-01-01T23:59:59.000Z

378

Secondary pollutants from ozone reactions with ventilation filters and  

NLE Websites -- All DOE Office Websites (Extended Search)

Secondary pollutants from ozone reactions with ventilation filters and Secondary pollutants from ozone reactions with ventilation filters and degradation of filter media additives Title Secondary pollutants from ozone reactions with ventilation filters and degradation of filter media additives Publication Type Journal Article Year of Publication 2011 Authors Destaillats, Hugo, Wenhao Chen, Michael G. Apte, Nuan Li, Michael Spears, Jérémie Almosni, Gregory Brunner, Jianshun(Jensen) Zhang, and William J. Fisk Journal Atmospheric Environment Volume 45 Start Page 3561 Issue 21 Pagination 3561-3568 Keywords commercial building ventilation & indoor environmental quality group, commercial building ventilation and indoor environmental quality group, energy analysis and environmental impacts department, indoor environment department, indoor environment group

379

Investigation of formaldehyde and acetaldehyde sampling rate and ozone  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigation of formaldehyde and acetaldehyde sampling rate and ozone Investigation of formaldehyde and acetaldehyde sampling rate and ozone interference for passive deployment of Waters Sep-Pak XPoSure samplers Title Investigation of formaldehyde and acetaldehyde sampling rate and ozone interference for passive deployment of Waters Sep-Pak XPoSure samplers Publication Type Journal Article Year of Publication 2013 Authors Mullen, Nasim A., Marion L. Russell, Melissa M. Lunden, and Brett C. Singer Journal Atmospheric Environment Volume 80 Pagination 184-189 Date Published 12/2013 Keywords aldehyde; exposure; indoor air quality; passive sampler; residential Abstract This study investigated formaldehyde and acetaldehyde passive sampling rates and ozone interference for the DNPH-based Waters Sep-Pak XPoSure sampler. Previous studies have shown that ozone interferes with active sampling by this cartridge. Our study included one laboratory and six field experiments conducted in Northern California homes. Passive sampling rates of 1.10 ± 0.09 and 0.86 ± 0.10 mL/min determined for formaldehyde and acetaldehyde are lower than previously reported. In a controlled laboratory experiment there were small, statistically insignificant impacts of subsequent ozone exposure on formaldehyde and acetaldehyde mass passively collected on the samplers. This sampler is inexpensive, easy to deploy and to transport by mail, and has a high sampling capacity when used passively; it is suitable for a wide-range of monitoring applications. However, the passive sampling rate remains in question given the internally consistent, but different results obtained in our study and the previous study.

380

Biofouling control with ozone at the Bergen Generating Station  

SciTech Connect

The results of a study designed to evaluate the effectiveness of ozone as an alternative to chlorine for condenser biofouling control in a once-through cooling system are reported. Tests were conducted at PSE and G's Bergen Generating Station using a pilot-scale condenser system to simulate plant condenser operations. Three model condensers were operated under identical conditions with only the biocide treatment differing. Comparisons of ozone and chlorine were made and the minimum effective levels of each were determined by daily measurements of the heat transfer coefficient across the model condenser tubes and/or the water side pressure drop. Final evaluation was based on the mass of biofouling material collected from the tubewalls. Test results indicate that chlorine is capable of effective biofouling control when applied for 2 hours/day at a level as low as 0.1 mg/l. Ozone, applied on the same schedule, requires 0.5 mg/l for effective control. The results of this study are representative of only the Bergen site. Water quality at each particular site will influence the development of the biofouling organisms, the chemical reactions of the biocides, and therefore, the effectiveness of the treatment methodology. The results suggest that further examination of ozonation for biofouling control is warranted. Although much more costly than chlorine, its effects on indigenous ecosystems may prove ozone to be better suited for application at selected power plants. It must be emphasized, however, that much more information is necessary before ozone can be recommended as an environmentally acceptable alternative to chlorine.

Sugam, R.; Guerra, C.R.; DelMonaco, J.L.; Singletary, J.H.; Sandvik, W.A.

1980-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

N-nitrosamine and N-nitramine Formation from NOx Reactions with Amines during Amine-Based CO2  

E-Print Network (OSTI)

Capture for Post-combustion Carbon Sequestration Background! Generation of electricity and heat from power- combustion carbon sequestration, the capture and underground storage of CO2 from the exhaust gases of power formation from NOx reactions with amines during amine-based carbon dioxide capture for postcombustion carbon

Mitch, William A.

382

Nox reduction with CO over supported Pd catalysts under simulated post Euro-IV diesel exhaust conditions  

Science Journals Connector (OSTI)

The catalytic reduction of NOx with CO over Pd/Al2O3 and Pd/TiO2/Al2O3 under simulated post Euro-IV diesel exhaust conditions was studied. The catalytic activities obtained...2 loadings and total amounts of reduc...

Yinghua Li; Dae-Won Lee; Young-Chul Ko

2008-12-01T23:59:59.000Z

383

Flexible CHP System with Low NOx, CO, and VOC Emissions- Presentation by the Gas Technology Institute (GTI), June 2011  

Energy.gov (U.S. Department of Energy (DOE))

Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011.

384

Implications of near-term coal power plant retirement for SO2 and NOX, and life cycle GHG emissions  

E-Print Network (OSTI)

prices of electricity production Plant type Unit Price Nuclear ($/MWh) 16.51 Wind ($/MWh) 201 Hydro Top SO2 100 430 95 440 100 430 Top NOX 105 350 100 380 105 345 Small, inefficient 125 410 125 405 125) Manitoba Hydro Manitoba Hydro Undertaking # 57 http://www.pub.gov.mb.ca/exhibits/mh-83.pdf. (5) Sotkiewicz

Jaramillo, Paulina

385

Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and  

E-Print Network (OSTI)

combustion, biomass burning and soil emissions Lyatt Jaegle´ ,a Linda Steinberger,a Randall V. Martinbc anthropogenic emissions, mostly resulting from fossil fuel combustion and biomass burning, are superimposed-CHEM chemical transport model. Top-down NOx sources are partitioned among fuel combustion (fossil fuel

Lyatt Jaeglé

386

SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD  

E-Print Network (OSTI)

in the atmosphere. TD-GC-MS ANALYSIS METHODOLOGY A thermal desorption (TD) injection device (M. Ezrin, 1991. Valve Spindle 10. Carrier Gas Inlet 11. Inlet Assembly 12. Injection Port Insert PAH standard Solution, 1ppm, 1µL injection Alkanes Standard Solution, 0.1ppm, 1µL injection FUTURE EXPERIMENTS Verify PM

Holmén, Britt A.

387

Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats  

SciTech Connect

Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: Air pollutants have been associated with increased diabetes in humans. Acute ozone exposure produces profound metabolic alterations in rats. Age influences metabolic risk factors in aging BN rats. Acute metabolic effects are reversible and repeated exposure reduces these effects. Ozone metabolic effects are only slightly exacerbated in geriatric rats.

Bass, V. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Gordon, C.J.; Jarema, K.A.; MacPhail, R.C. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Cascio, W.E. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Phillips, P.M. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Ledbetter, A.D.; Schladweiler, M.C. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Andrews, D. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Miller, D. [Curriculum in Toxicology, University of North Carolina, Chapel Hill, NC (United States); Doerfler, D.L. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Kodavanti, U.P., E-mail: kodavanti.urmila@epa.gov [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

2013-12-15T23:59:59.000Z

388

\\{NOx\\} reduction from a large bore natural gas engine via reformed natural gas prechamber fueling optimization  

Science Journals Connector (OSTI)

Lean combustion is a standard approach used to reduce \\{NOx\\} emissions in large bore (3556cm) stationary natural gas engines. However, at lean operating points, combustion instabilities and misfires give rise to high total hydrocarbon (THC) and carbon monoxide (CO) emissions. To counteract this effect, precombustion chamber (PCC) technology is employed to allow engine operation at an overall lean equivalence ratio while mitigating the rise of THC and CO caused by combustion instability and misfires. A PCC is a small chamber, typically 12% of the clearance volume. A separate fuel line supplies gaseous fuel to the PCC and a standard spark plug ignites the slightly rich mixture (equivalence ratio 1.11.2) in the PCC. The ignited PCC mixture enters the main combustion chamber as a high energy flame jet, igniting the lean mixture in the main chamber. Typically, natural gas fuels both the main chamber and the PCC. In the current research, a mixture of reformed natural gas (syngas) and natural gas fuels the PCC. Syngas is a broad term that refers to a synthetic gaseous fuel. In this case, syngas specifically denotes a mixture of hydrogen, carbon monoxide, nitrogen, and methane generated in a natural gas reformer. Syngas has a faster flame speed and a wider equivalence ratio range of operation than methane. Fueling the PCC with Syngas reduces combustion instabilities and misfires. This extends the overall engine lean limit, enabling further \\{NOx\\} reductions. Research results presented are aimed at quantifying the benefits of syngas PCC fueling. A model is developed to calculate the equivalence ratio in the PCC for different mixtures and flowrates of fuel. An electronic injection valve is used to supply the PCC with syngas. The delivery pressure, injection timing, and flow rate are varied to optimize PCC equivalence ratio. The experimental results show that supplying the PCC with 100% syngas improves combustion stability by 21% compared to natural gas PCC fueling. A comparison at equivalent combustion stability operating points between 100% syngas and natural gas shows an 87% reduction in \\{NOx\\} emissions for 100% syngas PCC fueling compared to natural gas PCC fueling.

Mathew D. Ruter; Daniel B. Olsen; Mark V. Scotto; Mark A. Perna

2012-01-01T23:59:59.000Z

389

Analysis, anaerobic treatment and ozonation of wool scouring wastewater  

SciTech Connect

Wool scouring effluents (WSE) were analyzed by high-resolution gas chromatography-mass spectrometry (HRGC-MS), and then exposed to anaerobic biological treatment using laboratory scale fixed-bed filters. This resulted in a nearly 50% reduction in chemical oxygen demand (COD). Ozonation of the effluent from the biological step led to an even further decrease in total organic carbon (TOC). The fatty acid content of the WSE was affected by both biological treatment and ozonation. Finally, steroids in the WSE underwent reduction reactions when exposed to the anaerobic biological treatment.

Monteverdi, A.; Rindone, B.; Sorlini, C. (Univ. di Milano (Italy)); Andreoni, V. (Univ. di Torino (Italy)); Rozzi, A. (Inst. di Ingegneria Sanitaria del Politechnico di Milano (Italy))

1992-01-01T23:59:59.000Z

390

Effects of Catalysts on Emissions from Heavy-Duty Diesel Retrofits for PM and NOX Control  

Energy.gov (U.S. Department of Energy (DOE))

The more heavily catalyzed and the hotter the exhaust temperature, the more strongly the aftertreatment will oxidize the exhaust.

391

Method for reducing NOx during combustion of coal in a burner  

DOE Patents (OSTI)

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

2008-04-15T23:59:59.000Z

392

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application  

Science Journals Connector (OSTI)

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application ... It has been demonstrated that low current arc discharges are highly nonhomogenous. ... In the second case, which corresponds to the most favorable one, assuming (i) a 100 kW car engine thermal power (i.e., 40 kW mechanical power), (ii) that the plasma will treat only a small fraction of the exhaust gas (typically 3.5%), (iii) that the plasma will operate under a cycling operating mode, and (iv) an 80% efficiency for the onboard production of electricity from the car engine, one can estimate that the electric power needed to run the plasma will be around 2.2% of the engine power only during 12 s every 11 km (6.8 miles), that is, 12 s every 6 min assuming a 110 kmh?1 (68 mph) average car velocity. ...

Alexandre Lebouvier; Franc?ois Fresnet; Fre?de?ric Fabry; Vale?rie Boch; Vandad Rohani; Franc?ois Cauneau; Laurent Fulcheri

2011-02-03T23:59:59.000Z

393

New CoO?SiO2-Sol Pillared Clays as Catalysts for NOx Conversion  

Science Journals Connector (OSTI)

For this purpose, codoped SiO2 sol PILC (CoSi?PILC) is prepared via an organic template route and the interlayer pillar structure is systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), and nitrogen adsorption isotherm measurement, along with a preliminary test on the de-NOx catalytic activity. ... The steady-state selective catalytic reduction of NO with CO over CoSi?PILC catalyst was carried out in an isothermal fixed-bed continuous flow quartz reactor (o.d. ... The elemental composition of CoSi?PILC was analyzed to estimate the pillar content of SiO2 and CoO. ...

Jin-Ho Choy; Hyun Jung; Yang-Su Han; Joo-Byoung Yoon; Yong-Gun Shul; Hyun-Jong Kim

2002-08-20T23:59:59.000Z

394

Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch  

SciTech Connect

The technical feasibility of using an induction-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz and ~11 kVA with an argon/oxygen mixture as the plasma-forming gas. A gaseous oxygen quench formed ozone by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in the reaction chamber was measured by Fourier Transform infrared (FTIR) spectroscopy over a wide range of experimental configurations. The geometry of the quench gas flow, the quench flow velocity, and the quench flow rate played important roles in determining the ozone concentration. The ozone concentration was sensitive to the torch RF power, but was insensitive to the torch gas flow rates. These observations are interpreted within the framework of a simple model of ozone synthesis.

A. Blutke; B.C. Stratton; D.R. Mikkelsen; J. Vavruska; R. Knight

1998-01-01T23:59:59.000Z

395

Nitrogen Oxides in the Nocturnal Boundary Layer: Chemistry of Nitrous Acid (HONO) and the Nitrate Radical (N03)  

SciTech Connect

Summary Chemical processes occurring at night in the lowest part of the urban atmosphere, the so called nocturnal boundary layer (NBL), can influence the composition of the atmosphere during the night as well as the following day. They may impact the budgets of some of the most important pollutants, such as ozone and nitrogen oxides, as well as influence size and composition of particular matter. Few studies have thus far concentrated on the nocturnal chemistry of the urban NBL, most likely due to the strong influence of vertical transport and mixing, which requires the measurement of trace gas profiles instead of simple point observations. Motivated by our lack of observations and understanding of nocturnal chemistry, the focus of this project was the study of the vertical distribution of trace gases and the altitude dependence of nocturnal chemistry under polluted conditions through field observations and modeling studies. The analysis of three field experiments (TEXAQS, Houston, 2000; Phoenix Sunrise Ozone Experiment, 2001; NAPOX, Boston, 2002), two of which were performed in this project, showed that ozone concentrations typically increase with height in the lowest 150m, while NO2 typically decreases. NO3, the dominant nocturnal radical species, showed much higher concentrations in the upper part of the NBL, and was often not present at the ground. With the help of a one-dimensional chemical transport model, developed in this project, we found that the interaction of ground emissions of NOx and hydrocarbons, together with their vertical transport, is responsible for the vertical profiles. The dominant chemical reactions influencing ozone, NO2 and NO3 are the reaction of ozone and NO3 with freshly emitted NO. Sensitivity studies with our model showed that the magnitude of the trace gas gradients depend both on the emission rates and the vertical stability of the NBL. Observations and model analysis clearly show that nocturnal chemistry in urban areas is altitude dependent. Measurements at one altitude, for example at the ground, where most air quality monitoring stations are located, are not representative for the rest of the NBL. Our model also revealed that radical chemistry is, in general, altitude dependent at night. We distinguish three regions: an unreactive, NO rich, ground layer; an upper, O3 and NO3 dominated layer, and a reactive mixing layer, where RO2 radicals are mixed from aloft with NO from the ground. In this reactive layer an active radical chemistry and elevated OH radical levels can be found. The downward transport of N2O5 and HO2NO2, followed by their thermal decay, was also identified as a radical source in this layer. Our observations also gave insight into the formation of HONO in the NBL. Based on our field experiments we were able to show that the NO2 to HONO conversion was relative humidity dependent. While this fact was well known, we found that it is most likely the uptake of HONO onto surfaces which is R.H. dependent, rather than the NO2 to HONO conversion. This finding led to the proposal of a new NO2 to HONO conversion mechanism, which is based on solid physical chemical principles. Noteworthy is also the observation of enhanced NO2 to HONO conversion during a dust storm event in Phoenix. The final activity in our project investigated the influence of the urban canopy, i.e. building walls and surfaces, on nocturnal chemistry. For the first time the surface area of a city was determined based on a Geographical Information System database of the city of Santa Monica. The surface to volume areas found in this study showed that, in the 2 lower part of the NBL, buildings provide a much larger surface area than the aerosol. In addition, buildings take up a considerable amount of the volume near the ground. The expansion of our model and sensitivity studies based on the Santa Monica data revealed that the surface area of buildings considerably influences HONO levels in urban areas. The volume reduction leads to a decrease of O3 and an increase of NO2 near the ground due to the stronger impact o

Jochen Stutz

2005-05-24T23:59:59.000Z

396

Removal of phenol and chlorophenols from water by new ozone generator  

Science Journals Connector (OSTI)

Presence of phenol in river water occasionally disturbs the production of drinking water. Phenol often originated from coal power plants or pesticides. New ozone generator [Kuraica et al., Vacuum, 73 (2004) 705] was used for removal of phenol and chlorophenols from water. The ozone generator was based on coaxial dielectricbarrier-discharge and operated in the air at an atmospheric pressure. Flowing water was one of dielectric layers. Ozone and ozonized water were generated in the same volume of the discharge. This type of ozone generator has considerable advantages in comparison with the classical ones. In this paper five experiments were described, three with bidistilled water and two with different water samples from river Danube. In all cases, 5L of water containing 6mg/L of corresponding phenol was passed once through the ozonizer. The concentration of dissolved ozone in water was 740mg/L. The ozonization lasted 1 h, but the total contact time was up to 94 h. In all cases, before and after the treatment of water with ozone, the concentration of corresponding phenol [Standard Methods for Examination of Water and Wastewater, method 510 B, Chloroform Extraction Method, American Public Health Association, Washington, 1985, p. 558], dissolved and residual ozone [Standard Methods for Examination of Water and Wastewater, Methods 2-41, 2-42 (dissolved ozone) Iodometric Method; method 4-104 (ozone residual) Indigo Colorimetric Method, American Public Health Association, Washington, 1995] were determined by standard methods. In experiments with distilled water most of the phenol was removed during ozonization (89.5%). After 24 and 96 h the percentage of removed phenol increased to 93.3 and 98.9%, respectively. With 4-chlorophenol and 2,4-dichlorophenol, 99.8 and 98.9% of corresponding phenols were removed. In experiments with two different water samples from Danube, the phenol was also mostly removed during ozonization, 76.7 and 80.0%, respectively.

D. Manojlovic; D.R. Ostojic; B.M. Obradovic; M.M. Kuraica; V.D. Krsmanovic; J. Puric

2007-01-01T23:59:59.000Z

397

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

398

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

399

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

400

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer  

E-Print Network (OSTI)

Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 Mainz, Germany M. Oppenheimer (*) Department of Geosciences, Princeton University, Princeton, NJ 08544, USA e-mail: omichael@princeton.edu M. Oppenheimer Woodrow Wilson School of Public and International

Oppenheimer, Michael

402

556 2010 ASHRAE Chemical reactions between ozone and terpenoids can  

E-Print Network (OSTI)

, and air-conditioning (HVAC) system. This investigation models the influence of HVAC systems on SOA influential HVAC parameters are the flow rates through the system,particlefiltrationefficiency,andindoortemperature for the residential and commercial models, as well as ozone removal on used filters for the commercial model

Siegel, Jeffrey

403

International Gathering Plans Ways To Safeguard Atmospheric Ozone  

Science Journals Connector (OSTI)

International Gathering Plans Ways To Safeguard Atmospheric Ozone ... Everyone's for it, as was evidenced in Helsinki recently where senior government officials from more than 80 countries, together with delegates representing many interested groups and organizations, attended a week-long meeting to seek ways of safeguarding it. ...

DERMOT A. O'SULLIVAN

1989-06-26T23:59:59.000Z

404

Ozone Treatments of Fresh Atlantic Cod, Gadus morhua  

E-Print Network (OSTI)

, has made it a useful agent for seawater disin fection (Blogoslawski et aI., 1975; Blogoslawski, 1977 to extend the storage life of many perishable foods by slowing decomposi tion caused by microorganisms. These studies were reviewed by Farquhar and Rice (1982). Storage life extension of fish using ozone was first

405

Massive global ozone loss predicted following regional nuclear conflict  

Science Journals Connector (OSTI)

...The magnitude and duration of the predicted ozone reductions are greater than those calculated in the 1980's for global thermonuclear war scenarios involving yields that exceed the ones we considered by factors of >1000. At the time, global models had...

Michael J. Mills; Owen B. Toon; Richard P. Turco; Douglas E. Kinnison; Rolando R. Garcia

2008-01-01T23:59:59.000Z

406

Metastable oxygen incorporation into thin film NiO by low temperature active oxidation: Influence on hole conduction  

SciTech Connect

The ability to controllably tune cation valence state and resulting electrical conductivity of transition metal-oxides such as NiO is of great interest for a range of solid state electronic and energy devices and more recently in understanding electron correlation phenomena at complex oxide interfaces. Here, we demonstrate that it is possible to enhance electrical conductivity of NiO thin films by one order of magnitude by photoexcitation and three orders of magnitude by ozone treatment at as low as 310 K. The change occurs within nearly 2000 s and, thereafter, reaches a self-limiting value. A surprising difference is seen at 400 K: ultraviolet photon and ozone treatments cause only a marginal reduction in resistance in the first few minutes and, then, the resistance begins to increase and recovers its original value. This unusual reversal is explained by considering metastable incorporation of oxygen in NiO and oxygen equilibration with the environment. Variation in nickel valence state prior to and after photoexcitation and ozone treatment, investigated by x-ray photoelectron spectroscopy, provides mechanistic insights into resistance trends. This study demonstrates photon-assisted and ozone oxidation as effective low temperature routes to tune the electrical properties as well as metastably incorporate oxygen into oxides with direct influence on electrical conduction properties.

Aydogdu, Gulgun H.; Ruzmetov, Dmitry; Ramanathan, Shriram [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States)

2010-12-01T23:59:59.000Z

407

An Experimental Investigation of the Origin of Increased NOx Emissions When Fueling a Heavy-Duty Compression-Ignition Engine with Soy Biodiesel  

Energy.gov (U.S. Department of Energy (DOE))

Optical engine experiments suggest that near stoichiometric charge-gas mixtures in the standing premixed autoignition zone near flame lift-off length explains biodiesel NOx increase under all conditions

408

Pillared smectite modified with carbon and manganese as catalyst for SCR of NOx with NH3. Part I. General characterization and catalyst screening  

Science Journals Connector (OSTI)

Carbon- and manganese-modified zirconia-pillared smectites were prepared, characterized (XRD, BET and pore analysis, XPS) and tested in selective catalytic reduction of NOx with NH3. Both untreated and acidic pre...

Lucjan Chmielarz; Roman Dziembaj; Teresa Grzybek; Jerzy Klinik

409

Development of a dry low-NOx gas turbine combustor for a natural-gas fueled 2MW co-generation system  

SciTech Connect

A dry low-NOx gas turbine combustor has been developed for natural-gas fueled co-generation systems in the power range of 1--4MW. The combustor. called the Double Swirler Combustor, uses the lean premixed combustion to reduce NOx emission. The combustor is characterized by two staged lean premixed combustion with two coaxial annular burners and a simple fuel control system without the complex variable geometry. Substantially low NOx level has been achieved to meet the strict NOx regulation to co-generation systems in Japan. High combustion efficiency has been obtained for a wide operating range. In 1994, Tokyo Gas and Ishikawajima-Harima Heavy Industries initiated a collaborative program to develop a natural-gas fueled low NOx gas turbine engine for new 2MW class co-generation system, named IM270. The Double Swirler Combustor, originally developed by Tokyo Gas, was introduced into the natural gas fueled version of the IM270. Engine test of the first production unit was successfully conducted to confirm substantially low NOx level of less than 15 ppm (O{sub 2} = 16%) with the output power of more than 2MW. Test for the durability and the reliability of the system is being conducted at Tokyo Gas Negishi LNG Terminal in Kanagawa, Japan and successful results have been so far obtained.

Mori, Masaaki; Sato, Hiroshi

1998-07-01T23:59:59.000Z

410

Evaluation of the Impacts of Biodiesel and Second Generation Biofuels on NOx Emissions for CARB Diesel Fuels  

Science Journals Connector (OSTI)

McCormick, R. L.; Graboski, M. S.; Alleman, T. L.; Herring, A. M.; Tyson, K. S.Impact of Biodiesel Source Material and Chemical Structure on Emissions of Criteria Pollutants from a Heavy-Duty Engine Environ. ... McCormick, Robert L.; Graboski, Michael S.; Alleman, Teresa L.; Herring, Andrew M.; Tyson, K. Shaine ... McCormick, R.; Alvarez, J.; Graboski, M.; Tyson, K.Fuel Additive and Blending Approaches to Reducing NOx Emissions from Biodiesel SAE Tech. ...

Maryam Hajbabaei; Kent C. Johnson; Robert A. Okamoto; Alexander Mitchell; Marcie Pullman; Thomas D. Durbin

2012-07-12T23:59:59.000Z

411

NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT  

SciTech Connect

This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. Previous research results have demonstrated that the inhalation of coal/MSS ash particles cause an increase in lung permeability than coal ash particles alone. Elemental analysis of the coal/MSS ash particles showed that Zn was more abundant in these ash particles than the ash particles of coal ash alone.

Jost O.L. Wendt

2003-01-31T23:59:59.000Z

412

Ozonized water generator based on coaxial dielectric-barrier-discharge in air  

Science Journals Connector (OSTI)

A coaxial dielectric-barrier-discharge (DBD) as an ozonized water reactor system has been developed and described. It operates in the air at an atmospheric pressure. In the reactor one of the dielectric layers is flowing water. Ozone and ozonized water are generated in the same volume of the discharge. The ozone production and its dissolution in the water simultaneously occur leading to increases of the reactor efficiency. Filamentary 50Hz DBD has been performed using up to 20kV applied voltage. The obtained ozone concentrations correspond to the values typically suggested for the treatment of potable and wastewater. The efficiency can be further increased by addition of small amount of the oxygen in the DBD device. The periodical time dependence of the dissolved ozone concentration in Danube water is found and discussed.

Milorad M. Kuraica; Bratislav M. Obradovi?; Dragan Manojlovi?; Daliborka R. Ostoji?; Jago Puri?

2004-01-01T23:59:59.000Z

413

Impact of HVAC filter on indoor air quality in terms of ozone removal and carbonyls generation  

Science Journals Connector (OSTI)

Abstract This study aims at detecting ozone removal rates and corresponding carbonyls generated by ozone reaction with HVAC filters from various building, i.e., shopping mall, school, and office building. Studies were conducted in a small-scale environmental chamber. By examining dust properties including organic carbon proportion and specific surface area of dusts adsorbed on filters along with ozone removal rates and carbonyls generation rate, the relationship among dust properties, ozone removal rates, and carbonyls generation was identified. The results indicate a well-defined positive correlation between ozone removal efficiency and carbonyls generation on filters, as well as a positive correlation among the mass of organic carbon on filters, ozone removal efficiency and carbonyls generations.

Chi-Chi Lin; Hsuan-Yu Chen

2014-01-01T23:59:59.000Z

414

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

415

NOx diesel exhaust treatment using a pulsed corona discharge: the pulse repetition rate effect  

Science Journals Connector (OSTI)

The pulsed corona offers real promise for degradation of pollutants in gas and water streams. This paper presents a study of NOx removal from diesel exhaust. Special emphasis is laid on the investigation of the dependence of the NO removal rate and efficiency on the pulse repetition rate (PRR). A nanosecond solid state power supply (45?kV, 60?ns, up to 1?kHz) was used for driving the corona reactor. A Mitsubishi 10?kW 3-cylinder diesel-generator engine with a total volume of 1300?cm3 was used as a source of exhaust gas. At an NO removal rate of 35% the NO removal efficiency was 53?g?kW?1h?1 for PRR = 500?Hz and the initial NO concentration was 375?ppm. A semi-empirical expression for the corona reactor removal efficiency related both to PRR and to the residence time is presented. The removal efficiency decreases with increasing PRR at constant flow rate or constant residence time. This expression demonstrates reasonable agreement between the calculation results and the experimental data.

Y Yankelevich; M Wolf; R Baksht; A Pokryvailo; J Vinogradov; B Rivin; E Sher

2007-01-01T23:59:59.000Z

416

Low NOx Burner Design and Analysis for Conceptual Design of Oxygen-Based PC Boiler  

SciTech Connect

The objective of the low NOx burner design and analysis task of the Conceptual Design of Oxygen-Based PC Boiler study is to optimize the burner design to ensure stable ignition, to provide safe operation, and to minimize pollutant formation. The burners were designed and analyzed using the Fluent computer program. Four burner designs were developed: (1) with no over-fire gas (OFG) and 65% flue gas recycle, (2) with 20% OFG and 65% flue gas recycle, (3) with no OFG and 56% flue gas recycle and (4) with 20% OFG and 56% flue gas recycle. A 3-D Fluent simulation was made of a single wall-fired burner and horizontal portion of the furnace from the wall to the center. Without primary gas swirl, coal burnout was relatively small, due to the low oxygen content of the primary gas stream. Consequently, the burners were modified to include primary gas swirl to bring the coal particles in contact with the secondary gas. An optimal primary gas swirl was chosen to achieve sufficient burnout.

Andrew Seltzer

2005-05-01T23:59:59.000Z

417

Clean Air Interstate Rule (released in AEO2009)  

Reports and Publications (EIA)

Clean Air Interstate Rule (CAIR) is a cap-and-trade program promulgated by the Environmental Protection Agency in 2005, covering 28 eastern U.S. states and the District of Columbia. It was designed to reduce sulfur dioxide (SO2) and nitrogen oxide (NOx) emissions in order to help states meet their National Ambient Air Quality Standards (NAAQS) for ozone and particulate matter (PM2.5) and to further emissions reductions already achieved through the Acid Rain Program and the NOx State Implementation Plan call program. The rule was set to commence in 2009 for seasonal and annual NOx emissions and in 2010 for SO2 emissions.

2009-01-01T23:59:59.000Z

418

Meeting the New Ozone Standard: Challenges and Opportunities  

Energy.gov (U.S. Department of Energy (DOE))

This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

419

*Corresponding author: Email: rainer.volkamer@colorado.edu; British Journal of Environment & Climate Change  

E-Print Network (OSTI)

Senff2,3 and R. Michael Hardesty2,3 1 Department of Chemistry and Biochemistry, University of Colorado gas production. Methodology: Three remote sensing instruments, namely the University of Colorado AMAX; AMAX-DOAS; Fluxes, air pollution; 1. INTRODUCTION Ozone (O3) and nitrogen oxides (NOx=NO+NO2) are trace

420

Impact of Wildfires on Ozone Exceptional Events in the Western U.S.  

Science Journals Connector (OSTI)

Impact of Wildfires on Ozone Exceptional Events in the Western U.S. ... ? National Center for Atmospheric Research, Boulder, Colorado 80307, United States ...

Daniel A. Jaffe; Nicole Wigder; Nicole Downey; Gabriele Pfister; Anne Boynard; Stephen B. Reid

2013-08-27T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives  

E-Print Network (OSTI)

2007. Ozone removal by HVAC filters. Atmospheric Environmentozone reactions on HVAC filters cannot be ignored as aof pollutants from HVAC filters may be degradation of

Destaillats, Hugo

2012-01-01T23:59:59.000Z

422

E-Print Network 3.0 - atmospheric ozone increases Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Environmental Sciences and Ecology ; Geosciences 78 Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive...

423

E-Print Network 3.0 - ameliorate ozone effects Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: students confuse the relationship between the ozone hole and the greenhouse effect, thus confusing... , and to suggest more effective teaching methods. 2....

424

Oxidation catalysts comprising metal exchanged hexaaluminate wherein the metal is Sr, Pd, La, and/or Mn  

DOE Patents (OSTI)

The present invention provides metal-exchanged hexaaluminate catalysts that exhibit good catalytic activity and/or stability at high temperatures for extended periods with retention of activity as combustion catalysts, and more generally as oxidation catalysts, that make them eminently suitable for use in methane combustion, particularly for use in natural gas fired gas turbines. The hexaaluminate catalysts of this invention are of particular interest for methane combustion processes for minimization of the generation of undesired levels (less than about 10 ppm) of NOx species. Metal exchanged hexaaluminate oxidation catalysts are also useful for oxidation of volatile organic compounds (VOC), particularly hydrocarbons. Metal exchanged hexaaluminate oxidation catalysts are further useful for partial oxidation, particularly at high temperatures, of reduced species, particularly hydrocarbons (alkanes and alkenes).

Wickham, David (Boulder, CO); Cook, Ronald (Lakewood, CO)

2008-10-28T23:59:59.000Z

425

Time-Resolved Molecular Characterization of Limonene/Ozone Aerosol using High-Resolution Electrospray Ionization Mass Spectrometry  

SciTech Connect

Molecular composition of limonene/O3 secondary organic aerosol (SOA) was investigated using high-resolution electrospray ionization mass spectrometry (HR-ESI-MS) as a function of reaction time. SOA was generated by ozonation of D-limonene in a reaction chamber and sampled at different time intervals using a cascade impactor. The SOA samples were extracted into acetonitrile and analyzed using a HR-ESI-MS instrument with a resolving power of 100,000 (m/?m). The resulting mass spectra provided detailed information about the extent of oxidation inferred from the O:C ratios, double bond equivalency (DBE) factors, and aromaticity indexes (AI) in hundreds of identified individual SOA species.

Bateman, Adam P.; Nizkorodov, Serguei; Laskin, Julia; Laskin, Alexander

2009-09-09T23:59:59.000Z

426

Why sequence Alkaliphilic sulfur oxidizing bacteria for sulfur pollution  

NLE Websites -- All DOE Office Websites (Extended Search)

Alkaliphilic sulfur oxidizing Alkaliphilic sulfur oxidizing bacteria for sulfur pollution remediation? Burning sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such as air pollution and acid rain, besides contributing to the loss of the ozone layer. One method of managing sulfur compounds released as byproducts from industrial processes is to scrub them out using chemical treatments and activated charcoal beds. A lower-cost solution relies on incorporating alkaliphic sulfur-oxidizing bacteria into biofilters to convert the volatile and toxic compounds into insoluble sulfur for easier removal. Discovered in the last decade, these bacteria have been found to thrive in habitats that span the full pH range. The bacteria could have applications

427

Evaluating the Vertical Distribution of Ozone and Its Relationship to Pollution Events in Air Quality Models Using Satellite Data  

Science Journals Connector (OSTI)

Most regional scale models that are used for air quality forecasts and ozone source attribution do not adequately capture the distribution of ozone in the mid- and upper troposphere, but it is unclear how this...

Jessica L. Neu; Gregory Osterman

2014-01-01T23:59:59.000Z

428

A Comparative Study of Ozone and Ultraviolet Light/Hydrogen Peroxide for Decolorizing Textile Dyeing Waste Water  

E-Print Network (OSTI)

generates free radicals and oxygen as shown below. (2) Figure 2 Laboratory ozone contactor OJ + HOO. ---> HO. + 2 O 2 Color Measurements (3) A Bausch and Lomb color spectrophotometer was used in conjunction with The hydroxyl radicals react with dyes... constants depend on the conditions of the experiment. Conditions affecting rate of color removal with ozone include input rate for ozone, mass transfer efficiency of ozone in the contactor, and concentration of dye. 168 ESL-IE-94-04-39 Proceedings from...

Namboodri, C. G.; Perkins, W. S.; Walsh, W. K.

429

Ground-based zenith sky abundances and in situ gas cross sections for ozone and nitrogen dioxide  

E-Print Network (OSTI)

Ground-based zenith sky abundances and in situ gas cross sections for ozone and nitrogen dioxide, in situ ambient absorption gas cell mea- surements for ozone and nitrogen dioxide, and ground-based zenith for ozone and nitrogen dioxide that are retrieved from measured spectra of the zenith sky

Dirksen, Ruud

430

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10 on the Prev'Air  

E-Print Network (OSTI)

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10'Air operational platform. This platform aims at forecasting maps, on a daily basis, for ozone, nitrogen dioxide models, ozone, nitrogen dioxide, particulate matter, threshold exceedance 1. Introduction1 Operational

Mallet, Vivien

431

Ozone levels in passenger cabins of commercial aircraft on North American  

NLE Websites -- All DOE Office Websites (Extended Search)

Ozone levels in passenger cabins of commercial aircraft on North American Ozone levels in passenger cabins of commercial aircraft on North American and transoceanic routes Title Ozone levels in passenger cabins of commercial aircraft on North American and transoceanic routes Publication Type Journal Article Year of Publication 2008 Authors Bhangar, Seema, Shannon Cowlin, Brett C. Singer, Richard G. Sextro, and William W. Nazaroff Journal Environmental Science and Technology Volume 42 Issue 11 Pagination 3938-43 Abstract Ozone levels in airplane cabins, and factors that influence them, were studied on northern hemisphere commercial passenger flights on domestic U.S., transatlantic, and transpacific routes. Real-time data from 76 flights were collected in 2006-2007 with a battery-powered UV photometric monitor. Sample mean ozone level, peak-hour ozone level, and flight-integrated ozone exposures were highly variable across domestic segments (N = 68), with ranges of 100 ppbv) ozone levels on domestic flights were associated with winter-spring storms that are linked to enhanced exchange between the lower stratosphere and the upper troposphere.

432

Surface ozone background in the United States: Canadian and Mexican pollution influences  

E-Print Network (OSTI)

of anthropogenic emissions from Canada, Mexico, and outside North America on daily maximum 8-hour average ozone Surface ozone Air quality standard Chemical transport model Global model a b s t r a c t We use a global chemical transport model (GEOS-Chem) with 1 ? 1 horizontal resolution to quantify the effects

Park, Rokjin

433

Atmospheric Environment 33 (1999) 1821--1845 The relation between ozone, NO  

E-Print Network (OSTI)

, ozone production efficiency, and removal rates of chemically active species. Use of these methods) chemical regimes. These regimes are associated with the chemistry of odd hydrogen radicals and appear production 1. Introduction The relation between ozone and its two main precur- sors, NO V ("NO

Sillman, Sanford

434

A Laboratory Method For Measuring The Ozone Emission From In-duct Air Cleaners.  

E-Print Network (OSTI)

: Emission rate, HVAC air cleaners, electrostatic precipitators, coronas, standard test method 1 Introduction and to ozone byproducts. Currently there are standards and regulations that limit ozone emissions from portable cleaners (i.e., Viner et al., 1992), are generally exempt from standards and regulations because

Siegel, Jeffrey

435

Can ozone depletion and global warming interact to produce rapid climate change?  

E-Print Network (OSTI)

Can ozone depletion and global warming interact to produce rapid climate change? Dennis L. Hartmann of Climate Change (IPCC) assess- ment of the status of global warming, which reported that winter stratospheric ozone depletion and greenhouse warming are possible. These interactions may be responsible

Limpasuvan, Varavut

436

Stratospheric ozone depletion: a key driver of recent precipitation trends in South Eastern South America  

E-Print Network (OSTI)

. In this paper we focus on South Eastern South America (SESA), a region that has exhibited one of the largest South America 1 Introduction The depletion of ozone in the polar Antarctic strato- sphere (i.e. `theStratospheric ozone depletion: a key driver of recent precipitation trends in South Eastern South

437

Experimental study of reactions between ozone and building products M. Nicolas, O. Ramalho, F. Maupetit*  

E-Print Network (OSTI)

ozone and building products and document their potential impact on indoor air quality. PreliminaryExperimental study of reactions between ozone and building products M. Nicolas, O. Ramalho, F experiments were conducted on four building products: two carpets, a gypsum board and a pine wood board

Paris-Sud XI, Université de

438

Validation of Ozone Monitoring Instrument nitrogen dioxide columns E. A. Celarier,1  

E-Print Network (OSTI)

Validation of Ozone Monitoring Instrument nitrogen dioxide columns E. A. Celarier,1 E. J. Brinksma the standard nitrogen dioxide (NO2) data product (Version 1.0.), which is based on measurements made), Validation of Ozone Monitoring Instrument nitrogen dioxide columns, J. Geophys. Res., 113, D15S15, doi:10

439

Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring Instrument  

E-Print Network (OSTI)

Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring; published 28 August 2008. [1] We present an approach to infer ground-level nitrogen dioxide (NO2), Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring

Martin, Randall

440

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network (OSTI)

Summary Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates be inferred for important trace gases such as ozone (O3) and nitrogen dioxide (NO2). Chemical transport models.11 to 3.79. Total nitrogen dioxide columns can be retrieved from space in the 405­465 nm window

Haak, Hein

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Tropospheric ozone trends at Mauna Loa Observatory tied to decadal climate variability  

E-Print Network (OSTI)

measurements at Mauna Loa Observatory in Hawaii reveal little change in tropospheric ozone levels during spring a suite of chemistry­climate model simulations. We show that the flow of ozone-rich air from Eurasia towards Hawaii during spring weakened in the 2000s as a result of La-Niña-like decadal cooling

442

Isolation and characterization of five ozone-inductible cDNA clones from Atriplax canescens (saltbush)  

E-Print Network (OSTI)

and water deficit were examined, and those cDNAs were sequenced. Clone 012-1, hybridized with three RNA species, is initially induced in response to both ozone and water deficit stress, but is repressed to prolonged ozone and sulfur dioxide exposure. Clone...

No, Eun-Gyu

2012-06-07T23:59:59.000Z

443

Measurements of springtime Antarctic ozone depletion and development of a balloon borne ultraviolet photometer  

SciTech Connect

The research described herein consists of two parts. The first part is a description of the design of a balloon borne ultraviolet photometer to measure ozone and the results of a flight using this instrument. The second part describes modifications made on the standard commercially available electrochemical ozonesonde and the results of some experiments performed both in the laboratory and during stratospheric balloon flights. Using this modified ECC system, 33 successful balloon flights were made at McMurdo Station, Antarctica during the austral spring of 1986 to study the temporal and vertical development of the so-called Antarctic Ozone Hole. Photometric measurements of ozone in the atmosphere can be accomplished by exploiting 253.65 nanometer absorption feature of ozone. Using a single light source and beam splitting optics, matched optical paths can be generated through two absorption cells. The ozonesonde data gave a very clear picture of the development of the Ozone Hole. The results can be summarized as follows: (1) Depletion occurs between about 12 and 20 km. (2) The most efficient region of ozone depletion decreases in altitude with time. Height profiles show subregions where ozone removal is highly efficient. (3) At 18 km, the ozone mixing ratio decays with a half-life of 25 days.

Harder, J.W.

1987-01-01T23:59:59.000Z

444

The Role of Material Porosity on Ozone Uptake for Metakaolin-Concrete Surfaces  

E-Print Network (OSTI)

to a diminished environmental impact, clay may cause increased removal of ozone, an important indoor pollutant velocity, Heterogeneous Chemistry, Construction Materials 1 Introduction Metakaolin-cement systems hold ozone uptake. Cement is an essential component in the building industry used in formulating concrete

Siegel, Jeffrey

445

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion of Silver  

E-Print Network (OSTI)

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion The corrosion of Ag contaminated with NaCl particles in gaseous environments containing humidity and ozone analyzed using a coulometric reduction technique. The atmospheric corrosion of Ag was greatly accelerated

446

Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002  

E-Print Network (OSTI)

Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002 R. D in South Africa are reported for the period 1990 to 1994 and a more recent period, 1998 to 2002, when), Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002, J. Geophys. Res

Thompson, Anne

447

Ensemble-based air quality forecasts: A multimodel approach applied to ozone  

E-Print Network (OSTI)

Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1., and B. Sportisse (2006), Ensemble-based air quality forecasts: A multimodel approach applied to ozone, J, the uncertainty in chem- istry transport models is a major limitation of air quality forecasting. The source

Boyer, Edmond

448

Formation of Ozone and Growth of Aerosols in Young Smoke Plumes from Biomass Burning  

E-Print Network (OSTI)

Physics and Chemistry Abstract The combustion of biomass is a major source of atmospheric trace gasesFormation of Ozone and Growth of Aerosols in Young Smoke Plumes from Biomass Burning by Matthew and Planetary Sciences #12;Formation of Ozone and Growth of Aerosols in Young Smoke Plumes from Biomass Burning

449

Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2  

E-Print Network (OSTI)

1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 and Chemistry EAS 6790 Fall 2006 Home Work Assignment No. 4, Ozone Chemistry Problems 11.8 and 11.9 (sub-part 1 and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

Weber, Rodney

450

Transatlantic transport of pollution and its effects on surface ozone in Europe and North America  

E-Print Network (OSTI)

Transatlantic transport of pollution and its effects on surface ozone in Europe and North America; published 3 July 2002. [1] We examine the transatlantic transport of anthropogenic ozone and its impact Head (Ireland) and Sable Island (Canada) are used to evaluate transatlantic transport in the model

Palmer, Paul

451

Atmospheric Environment 39 (2005) 13731382 A hierarchical Bayesian model to estimate and forecast ozone  

E-Print Network (OSTI)

reserved. Keywords: Statistical model; Space­time models; Air pollution; Ozone; Meteorology 1. Introduction describing the spatial­temporal behavior of ambient air pollutants such as ozone (O3) and particulate matter. Statistical space­time models are useful for illuminating relationships between different air pollutants

Irwin, Mark E.

452

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials  

E-Print Network (OSTI)

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A and unpainted drywall as passive ozone control surfaces in a room-sized laboratory chamber. Mean deposition-50%, resulted in increased reactivity for activated carbon. In our model for a typical house, about 35

Siegel, Jeffrey

453

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

454

Comparative evaluation of effects of ozonated and chlorinated thermal discharges on estuarine and freshwater organisms  

SciTech Connect

As a part of a program at PSE and G designed to examine the feasibility of ozonation as an alternative to chlorination for control of biofouling in once-through cooling systems, the biological effects of ozonated and chlorinated thermal discharges were evaluated with estuarine and freshwater organisms. Mortality at salinities between 0.5 to 2.5 ppt with mummichog and white perch indicated greater toxicity for chlorine while the alewife, spottail shiner, rainbow trout and white perch in freshwater were more sensitive to ozone. Behavioral and physograhic results were consistent with those observed in toxicity studies. Initial cough response and avoidance concentrations of mummicog and white perch in estuarine waters were lower when exposed to chlorine than to ozone. In freshwater, blueback herring, alewife, rainbow trout, spottail shiner, banded killifish, and white perch avoided lower concentrations of ozone than chlorine.

Guerra, C.R.; Sugam, R.; Meldrim, J.W.; Holmstrom, E.R.; Balog, G.E.

1980-08-01T23:59:59.000Z

455

Effects of ozone oxidative preconditioning on radiation-induced organ damage in rats  

Science Journals Connector (OSTI)

......USA). All values are expressed as the mean standard error of mean. Continuous variables were compared with the Kruskal-Wallis test. P values 0.05 were considered statistically significant for all tests. RESULTS Plasma AST and ALT levels......

Fatma Ayca Gultekin; Bekir Hakan Bakkal; Berrak Guven; Ilhan Tasdoven; Sibel Bektas; Murat Can; Mustafa Comert

2013-01-01T23:59:59.000Z

456

Office of FreedomCAR and Vehicle Technologies Health Impacts Program (Poster)  

SciTech Connect

We evaluated day-of-week differences in mean concentrations of ozone precursors [nitric oxide (NO), nitrogen oxides (NOx), volatile organic compounds (VOC) and carbon monoxide (CO)] at monitoring sites in 23 states comprising seven geographic focus areas for the years 1998-2003. We used Wednesdays to represent weekdays and Sundays to represent weekends; we also analyzed Saturdays. Statistical t-tests applied to every monitor showed substantial and statistically significant differences between Wednesday and weekend mean concentrations of ozone precursors in all study areas. At half the sites, nine-hour (6 am through 3 pm) mean concentrations of NO, NOx, and CO declined by at least 65, 49, and 28 percent, respectively, from Wednesdays to Sundays. Large reductions in mean concentrations of ozone precursors on weekends did not reduce mean concentrations of peak ozone significantly, and in many areas, mean peak ozone increased on weekends. Ozone accumulation began earlier on Sundays than on Wednesdays, on average. We also evaluated day-of-week differences in mean concentrations of fine particle and nitrate at available monitoring sites for the same time period and same geographic focus areas. Based on the monitors differences in Wednesday and Sunday means, PM nitrate showed almost negligible weekend decline, despite large NO and NOx declines.

Lawson, D. R.; Eberhardt, J. J.

2006-08-01T23:59:59.000Z

457

Calculation of NOx Emission Reduction from Implementation of the 2000 IECC/IRC Conservation Code in Texas  

E-Print Network (OSTI)

building prototypes, which will be constructed to be representative of the new building construction in Texas. 12 The NAHB characteristics divided the state into east (E), and west (W) divisions: window-to-wall area E=15.28%, W=20.6%, glazing U.... Division (East and West Texas): From NAHB survey data. 17. AFUE (%),SEER and Water Heater Efficiency for 1999 standard and IECC 2000 house are 80%, 11 and 76%, respectively. Table 1: 2002 NOx emissions reductions from implementation of the 2000 IECC...

Turner, W. D.; Yazdani, B.; Im, P.; Verdict, M.; Bryant, J.; Fitzpatrick, T.; Haberl, J. S.; Culp, C.

2003-01-01T23:59:59.000Z

458

Intergrated Nox Emissions Reductions from Energy Efficiency and Renewable Energy (EE/RE) Programs across State Agencies in Texas  

E-Print Network (OSTI)

1 Calculation of Integrated NOx Emissions Reductions from Energy Efficiency and Renewable Energy (EE/RE) Programs across State Agencies in Texas Juan-Carlos Baltazar, Ph.D., P.E.,Jeff S. Haberl, Ph.D., P.E., and Bahman Yazdani, P... on Environmental Quality (TCEQ) from the state-wide energy efficiency and renewable energy programs. These programs include: the impact of code-complaint construction, the Texas Public Utility Commission (PUC), the energy efficiency programs managed by the Texas...

Baltazar, J.C.; Haberl, J.; Yazdani, B.

2014-01-01T23:59:59.000Z

459

Impact of the Driving Cycle on the NOx and Particulate Matter Exhaust Emissions of Diesel Passenger Cars  

Science Journals Connector (OSTI)

Impact of the Driving Cycle on the NOx and Particulate Matter Exhaust Emissions of Diesel Passenger Cars ... The driving cycles used are the New European Driving Cycle (NEDC), the 11 and 15 modes Japanese cycles, and three U.S. driving cycles: Federal Test Procedure (FTP-75), US06, and Highway. ... In general, we can state that a reduction in compression ratio in combination with an advanced boosting system and a fast response of the EGR system with advanced EGR cooling leads to a reduction of the emission level. ...

Efthimios Zervas; George Bikas

2008-02-19T23:59:59.000Z

460

Development of a Low NOx Medium sized Industrial Gas Turbine Operating on Hydrogen-Rich Renewable and Opportunity Fuels  

SciTech Connect

This report presents the accomplishments at the completion of the DOE sponsored project (Contract # DE-FC26-09NT05873) undertaken by Solar Turbines Incorporated. The objective of this 54-month project was to develop a low NOx combustion system for a medium sized industrial gas turbine engine operating on Hydrogen-rich renewable and opportunity Fuels. The work in this project was focused on development of a combustion system sized for 15MW Titan 130 gas turbine engine based on design analysis and rig test results. Although detailed engine evaluation of the complete system is required prior to commercial application, those tasks were beyond the scope of this DOE sponsored project. The project tasks were organized in three stages, Stages 2 through 4. In Stage 2 of this project, Solar Turbines Incorporated characterized the low emission capability of current Titan 130 SoLoNOx fuel injector while operating on a matrix of fuel blends with varying Hydrogen concentration. The mapping in this phase was performed on a fuel injector designed for natural gas operation. Favorable test results were obtained in this phase on emissions and operability. However, the resulting fuel supply pressure needed to operate the engine with the lower Wobbe Index opportunity fuels would require additional gas compression, resulting in parasitic load and reduced thermal efficiency. In Stage 3, Solar characterized the pressure loss in the fuel injector and developed modifications to the fuel injection system through detailed network analysis. In this modification, only the fuel delivery flowpath was modified and the air-side of the injector and the premixing passages were not altered. The modified injector was fabricated and tested and verified to produce similar operability and emissions as the Stage 2 results. In parallel, Solar also fabricated a dual fuel capable injector with the same air-side flowpath to improve commercialization potential. This injector was also test verified to produce 15-ppm NOx capability on high Hydrogen fuels. In Stage 4, Solar fabricated a complete set of injectors and a combustor liner to test the system capability in a full-scale atmospheric rig. Extensive high-pressure single injector rig test results show that 15-ppm NOx guarantee is achievable from 50% to 100% Load with fuel blends containing up to 65% Hydrogen. Because of safety limitations in Solar Test Facility, the atmospheric rig tests were limited to methane-based fuel blends. Further work to validate the durability and installed engine capability would require long-term engine field test.

Srinivasan, Ram

2013-07-31T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Sorption, desorption, and surface oxidative fate of nicotine  

NLE Websites -- All DOE Office Websites (Extended Search)

Sorption, desorption, and surface oxidative fate of nicotine Sorption, desorption, and surface oxidative fate of nicotine Title Sorption, desorption, and surface oxidative fate of nicotine Publication Type Journal Article Year of Publication 2010 Authors Petrick, Lauren M., Hugo Destaillats, I. Zouev, S. Sabach, and Yael Dubowski Journal Phys. Chem. Chem. Phys. Volume 12 Issue 35 Pagination 10356-64 Date Published 09/21/2010 Abstract Nicotine dynamics in an indoor environment can be greatly affected by building parameters (e.g. relative humidity (RH), air exchange rate (AER), and presence of ozone), as well as surface parameters (e.g. surface area (SA) and polarity). To better understand the indoor fate of nicotine, these parameter effects on its sorption, desorption, and oxidation rates were investigated on model indoor surfaces that included fabrics, wallboard paper, and wood materials. Nicotine sorption under dry conditions was enhanced by higher SA and higher polarity of the substrate. Interestingly, nicotine sorption to cotton and nylon was facilitated by increased RH, while sorption to polyester was hindered by it. Desorption was affected by RH, AER, and surface type. Heterogeneous nicotine-ozone reaction was investigated by Fourier transform infrared spectrometry with attenuated total reflection (FTIR-ATR), and revealed a pseudo first-order surface reaction rate of 0.035 +/- 0.015 min(-1) (at [O(3)] = 6 +/- 0.3 x 10(15) molecules cm(-3)) that was partially inhibited at high RH. Extrapolation to a lower ozone level ([O(3)] = 42 ppb) showed oxidation on the order of 10(-5) min(-1) corresponding to a half-life of 1 week. In addition, similar surface products were identified in dry and high RH using gas chromatography-mass spectrometry (GC-MS). However, FTIR analysis revealed different product spectra for these conditions, suggesting additional unidentified products and association with surface water. Knowing the indoor fate of condensed and gas phase nicotine and its oxidation products will provide a better understanding of nicotine's impact on personal exposures as well as overall indoor air quality.

462

Understanding the Synergistic Catalytic Effect between La2O3 and CaO for the CH4 Lean De-NOx Reaction:? Kinetic and Mechanistic Studies  

Science Journals Connector (OSTI)

Department of Chemistry, Heterogeneous Catalysis Laboratory, University of Cyprus, P.O. ... 3-5 Methane is of particular interest as a reductant hydrocarbon species because of the large availability of natural gas, the use of the latter at gas-fired power plants (main stationary NOx polluting source), and the potential to be considered as an alternative to NH3 reductant used in industrial practice (NH3?SCR technology), which faces various problems. ... However, the likelihood for the presence of inactive but exchangeable NOx species with gaseous 15NO cannot be excluded. ...

T. Anastasiadou; L. A. Loukatzikou; C. N. Costa; A. M. Efstathiou

2005-06-28T23:59:59.000Z

463

Analysis of different control strategies for the simultaneous reduction of CO2 and NOx emissions of a diesel hybrid passenger car  

Science Journals Connector (OSTI)

Different control strategies for a diesel parallel hybrid passenger car were evaluated through numerical simulations. Two different control strategies were analysed: the first focused on fuel consumption minimisation, the second on NOx emissions cuts. Each of these goals was addressed through two different methodologies, the first based on a group of heuristic laws, the second focused on the instantaneous minimisation of a cost function that takes into account both the fuel and battery energies. A first assessment of the potential of a diesel hybrid passenger car as far as fuel consumption and NOx emissions reductions are concerned was obtained.

Federico Millo; Carlo V. Ferraro; Luciano Rolando

2012-01-01T23:59:59.000Z

464

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2  

Reports and Publications (EIA)

This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

2001-01-01T23:59:59.000Z

465

AutoGC systems for enhanced ozone monitoring network  

SciTech Connect

In response to a requirement for an on-line, automated ozone-precursor analyzer, a Perkin-Elmer Model ATD-400 Thermal Desorption System was specially adapted for the collection of whole-air samples. The C{sub 2} to n-C{sub 10} hydrocarbons were trapped using Peltier cooling on adsorbents at {minus}30 C. Multidimensional chromatography allowed the C{sub 2} to C{sub 6} fraction to be separated using a porous layer open tubular column while a methyl silicone column separated the C{sub 6} to C{sub 10} fraction. No cryogen was used in the collection or analysis. An air generator equipped for automatic restart and special software allowed the system to recover from power failures. Ozone precursor concentrations were detected over 5000 hours of continuous operation at the 0.1 ppbV level. Area repeatability was less than 10%, with retention time precision over 100 hours of approximately 1%RSD for most compounds. Remote communications allowed chromatography to be monitored and files to be downloaded to a central office. Results were converted to EPA AIRS database format using special conversion software. Data were archived using external Bernoulli disks.

Seeley, I. [Perkin-Elmer Corp., Norwalk, CT (United States)

1995-12-31T23:59:59.000Z

466

INFLUENCE OF ELEVATED OZONE AND CARBON DIOXIDE ON INSECT DENSITIES.  

SciTech Connect

The combustion of fossil fuels is profoundly altering the chemical composition of the atmosphere. Beginning with the Industrial Revolution, the concentration of carbon dioxide in the atmosphere has increased from approximately 280 to 370 {micro}l l{sup -1} in 2004, and it is expected to exceed 550 {micro}l l{sup -1} by 2050. Tropospheric ozone has risen even more rapidly than CO{sub 2} and average summer concentrations in the Northern Hemisphere are expected to continue to increase by 0.5-2.5% per year over the next 30 years. Although elevated CO{sub 2} stimulates photosynthesis and productivity of terrestrial ecosystems, ozone (O{sub 3}) is deleterious. In addition to directly affecting the physiology and productivity of crops, increased concentrations of tropospheric CO{sub 2} and O{sub 3} are predicted to lower the nutritional quality of leaves, which has the potential to increase herbivory as insects eat more to meet their nutritional demands. We tested the hypothesis that changes in tropospheric chemistry affect the relationship between plants and insect herbivores by changing leaf quality. The susceptibility to herbivory of soybean grown in elevated CO{sub 2} or O{sub 3} was examined using free air gas concentration enrichment (SoyFACE). FACE technology has the advantage that plants are cultivated under realistic field conditions with no unwanted alteration of microclimate or artificial constraints on the insect community.

DELUCIA, E.; DERMODY, O.; O'NEILL, B.; ALDEA, M.; HAMILTON, J.; ZANGERL, A.; ROGER, A.; BERENBAUM, M.

2005-01-05T23:59:59.000Z

467

Effect of ozonation on fungal resistance of bamboo and oak flooring materials  

Science Journals Connector (OSTI)

Abstract Lignocellulosic materials are gaining increased interest as renewable sources of building materials. However, chemical and microbiological degradation can occur when lignocellulosic materials are exposed to environmental stressors such as ozone and elevated humidity. In this study, the effects of ozone treatment and solvent extraction on fungal growth rates of bamboo and oak flooring materials were investigated. One set of samples was extracted with a mixture of cyclohexane and ethanol solvents for 72h to remove extractable compounds. Another set of materials was exposed continuously to ozone (2000?Lm?3 or 2000ppbv) for one to five weeks. Solvent-extracted and ozone-treated samples were incubated in closed chambers at 85% or 55% RH and 30C. Incubated samples were removed at regular time intervals for fungal growth evaluation. Ozone treatment caused chemical changes in bamboo and oak, which appeared to reduce bamboo's resistance to fungal attack. Longer ozone exposure led to higher susceptibility to fungal growth. Untreated and ozone-treated oak showed no evidence of fungal growth, suggesting that this material may contain fungi-inhibitory compounds that are not removed by these treatments. Also, a delay in fungal growth on cyclohexane/ethanol-extracted bamboo was observed, probably due to the extraction process removing substances that enhanced fungal growth.

Chi Hoang; Tinh Nguyen; Deborah Stanley; Andrew Persily; Richard L. Corsi

2014-01-01T23:59:59.000Z

468

Simultaneous Removal of NOx and Mercury in Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect

The results of a 18-month investigation to advance the development of a novel Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR), for the simultaneous removal of NO{sub x} and mercury (elemental and oxidized) from flue gases in a single unit operation located downstream of the particulate collectors, are reported. In the proposed LTSCAR, NO{sub x} removal is in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The concomitant capture of mercury in the unit is achieved through the incorporation of a novel chelating adsorbent. As conceptualized, the LTSCAR will be located downstream of the particulate collectors (flue gas temperature 140-160 C) and will be similar in structure to a conventional SCR. That is, it will have 3-4 beds that are loaded with catalyst and adsorbent allowing staged replacement of catalyst and adsorbent as required. Various Mn/TiO{sub 2} SCR catalysts were synthesized and evaluated for their ability to reduce NO at low temperature using CO as the reductant. It has been shown that with a suitably tailored catalyst more than 65% NO conversion with 100% N{sub 2} selectivity can be achieved, even at a high space velocity (SV) of 50,000 h-1 and in the presence of 2 v% H{sub 2}O. Three adsorbents for oxidized mercury were developed in this project with thermal stability in the required range. Based on detailed evaluations of their characteristics, the mercaptopropyltrimethoxysilane (MPTS) adsorbent was found to be most promising for the capture of oxidized mercury. This adsorbent has been shown to be thermally stable to 200 C. Fixed-bed evaluations in the targeted temperature range demonstrated effective removal of oxidized mercury from simulated flue gas at very high capacity ({approx}>58 mg Hg/g adsorbent). Extension of the capability of the adsorbent to elemental mercury capture was pursued with two independent approaches: incorporation of a novel nano-layer on the surface of the chelating mercury adsorbent to achieve in situ oxidation on the adsorbent, and the use of a separate titania-supported manganese oxide catalyst upstream of the oxidized mercury adsorbent. Both approaches met with some success. It was demonstrated that the concept of in situ oxidation on the adsorbent is viable, but the future challenge is to raise the operating capacity beyond the achieved limit of 2.7 mg Hg/g adsorbent. With regard to the manganese dioxide catalyst, elemental mercury was very efficiently oxidized in the absence of sulfur dioxide. Adequate resistance to sulfur dioxide must be incorporated for the approach to be feasible in flue gas. A preliminary benefits analysis of the technology suggests significant potential economic and environmental advantages.

Neville G. Pinto; Panagiotis G. Smirniotis

2006-03-31T23:59:59.000Z

469

Effect of ozone and granular activated coal (GAC) on the bioactivity of drinking water  

SciTech Connect

In this research, the appearance of easily biodegradable organic material in ozonation and granular activated coal (GAC) filtration was studied. The amount of bioactivity was measured by conventional AOC analyses used in two different modes and also using quite a new growth potential (GP) method. GAC filtration without ozone doubled the amount of AOC of the chemically treated surface water, whereas by ozonation with GAC filtration it was possible to halve the amount of the AOC. The measurement of GP was noticeably simpler than measuring AOC, but for wider use more parallel studies are needed for the comparability of the results of the analysis.

Sallanko, J.; Iivari, P.; Heiska, E. [University of Oulu, Oulu (Finland). Water Resources and Environmental Engineering Laboratory

2009-07-01T23:59:59.000Z

470

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

471

Responses measured in the exhaled breath of human volunteers acutely exposed to ozone and diesel exhaust  

Science Journals Connector (OSTI)

Exhaled breath collection is used to identify and monitor inflammatory or oxidative components in breath. Exhaled breath sample collection is noninvasive and would greatly benefit human pollutant exposure research. We demonstrate the efficacy of exhaled breath collection and analysis in two human exposure studies to ozone (O3) and diesel exhaust, respectively. O3 study: we collected exhaled breath (gas phase) from healthy human volunteers (age 1835 years, 12 subjects) immediately before and after exposure to filtered air or 0.4 ppm O3 for 2 h with and without intermittent exercise. Six subjects received antioxidant supplementation for 2 weeks before their O3 exposure, while the remaining six subjects received placebo treatments. We demonstrate increased amounts of non-polar carbonyls exhaled immediately post O3 exposure. The O3-induced increase in exhaled carbonyl concentrations was attenuated in the group receiving antioxidants. Our data demonstrate that exhaled exposure biomarkers can be measured in the breath gas phase in humans exposed to O3. Diesel study: we collected exhaled breath condensate (EBC; liquid phase) from healthy human volunteers (age 1840 years; 10 subjects) immediately before, immediately after and 20 h post filtered air or diesel exhaust (106 9 g m?3) exposure. Clean air and diesel exposures were separated by 3 weeks to 6 months. We obtained reproducible intra-subject EBC volumes and total protein concentrations across our six collection time points. Diesel exposure did not affect either EBC volume or total protein concentrations. Our data demonstrated EBC volume and total protein reproducibility over several months. Volume and total protein concentration may serve as normalizing factors for other EBC constituents.

K Sawyer; J M Samet; A J Ghio; J D Pleil; M C Madden

2008-01-01T23:59:59.000Z

472

Influence of Long-Period Variations of Total Ozone Content on Climate  

NLE Websites -- All DOE Office Websites (Extended Search)

Influence of Long-Period Variations of Total Ozone Content on Climate Influence of Long-Period Variations of Total Ozone Content on Climate Change in Twentieth Century Zuev, V Institute of Atmospheric Optics Zueva, N. Institute of Atmospheric Optics Bondarenko, S Institute of Atmospheric Optics Category: Atmospheric State and Surface It is shown that during long-term total ozone decrease everywhere at middle and high latitudes there takes place the destruction of balance in global carbon cycle first of all due to reduction of photosynthetical СО2 sink in consequence of UV-B radiation stress of vegetable biota. As a result, СО2 concentrations in the atmosphere considerably increase, enhancing the "greenhouse effect." Based on reconstruction of behavior of stratospheric ozone between 1600 and 2000 from dendrochronologic data, it is shown that

473

Climatology and Trends in the Forcing of the Stratospheric Ozone Transport  

E-Print Network (OSTI)

A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer transport equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re- Analysis (ERA-40). In ...

Monier, Erwan

474

The impact of traffic emissions on atmospheric ozone and OH: results from QUANTIFY  

E-Print Network (OSTI)

on the boundary layer. The effect of ship emissions does notfor road. Globally the effect of ship emissions on ozone insouthern hemisphere the effect of ship emissions is among

2009-01-01T23:59:59.000Z

475

Three-dimensional simulations of wintertime ozone variability in the lower stratosphere  

SciTech Connect

The evolution of ozone has been calculated for the winters of 1979 and 1989 using winds derived from the authors stratospheric data assimilation system (STRATAN). The ozone fields calculated using this technique are found to compare well with satellite-measured fields for simulations of 2-3 months. Here the authors present comparisons of model fields with both satellite and sonde measurements to verify that stratospheric transport processes are properly represented by this modeling technique. Attention is focussed on the northern hemisphere middle and high latitudes at the 10-hPa level and below, where transport processes are most important to the ozone distribution. First-order quantities and derived budgets from both the model and satellite data are presented. By sampling the model with a limb-viewing satellite and then Kalman filtering the observations of the model, it is shown that transient subplanetary-scale features that are essential to the ozone budget are missed by the satellite system.

Rood, R.B.; Douglass, A.R.; Kaye, J.A. (NASA Goddard Space Flight Center, Greenbelt, MD (USA)); Geller, M.A.; Yuechen, Chi (State Univ. of New York, Stony Brook (USA)); Allen, D.J.; Larson, E.M.; Nash, E.R.; Nielsen, J.E. (Applied Research Corp., Landover, MD (USA))

1991-03-20T23:59:59.000Z

476

Ultraviolet-ozone-treated PEDOT:PSS as anode buffer layer for organic solar cells  

Science Journals Connector (OSTI)

Ultraviolet-ozone-treated poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS)was used as the anode buffer layer in copper phthalocyanine (CuPc)/fullerene-based solar cells. The power conversion e...

Zisheng Su; Lidan Wang; Yantao Li; Haifeng Zhao; Bei Chu

2012-08-01T23:59:59.000Z

477

An Approach to the Detection of Long-Term Trends in Upper Stratospheric Ozone from Space  

Science Journals Connector (OSTI)

A central problem in the detection of long-term trends in upper stratospheric ozone from orbiting remote sensors involves the separation of instrument drifts from true geophysical changes. Periodic flights of a Solar Backscatter Ultraviolet ...

John E. Frederick; Xufeng Niu; Ernest Hilsenrath

1990-10-01T23:59:59.000Z

478

Ozonation of Mutagenic and Carcinogenic Polyaromatic Amines and Polyaromatic Hydrocarbons in Water  

Science Journals Connector (OSTI)

...Laboratory, Department of Microbiology, University of Notre Dame...Present address: Department of Microbiology, Harvard School of Public...titration method of Saltzman and Gilbert (25). The effective ozone...Saitzman, B. E., and Gilbert, N. lodometric microdetermination...

Gary R. Burleson; Michael J. Caulfield; and Morris Pollard

1979-06-01T23:59:59.000Z

479

Evaluation of a novel ozone generation technique for disinfection of poultry hatchers and processed broiler carcasses  

E-Print Network (OSTI)

When comparing electrochemically generated ozone(03)(2.94.2 wt % inside the (hatcher) and formaldehyde (16 n-A formalin + 7.5 g potassium pertnanganate) for disinfection of Salmonella enteiltidis (SE) contaminated agar plates and typical hatchery...

Ramirez, Gerardo Arturo

1994-01-01T23:59:59.000Z

480

Real-World Studies of Ambient Ozone Formation as a Function of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

-- Washington D.C. ace29lawson.pdf More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Health Impacts Program DOE's...

Note: This page contains sample records for the topic "oxides nox ozone" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Verification of the WRF model during a high ozone event over Houston, TX  

E-Print Network (OSTI)

High ozone values were observed in Houston, TX during August 25 - September 1, 2000. A comparison of WRF data with observations and MM5 data was conducted to determine the WRF model's performance in simulating the meteorological conditions...

Ames, Douglas Seeley

2012-06-07T23:59:59.000Z

482

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

483

Ozone production by nanoporous dielectric barrier glow discharge in atmospheric pressure air  

SciTech Connect

This study is aimed at demonstrating plasma-chemical ozone production based on low temperature atmospheric pressure glow discharge through nanoporous dielectric barriers. The 20 kHz ac driven discharge is formed in air or oxygen gas flowing in the axial direction of the cylindrical plasma reactor containing four parallel aluminum rods covered with nanoporous alumina films. The discharge utilizing nanoporous dielectric barrier is more uniform and more energy efficient in ozone generation than the discharge through smooth-surface dielectric barriers.

Cho, J. H.; Koo, I. G.; Choi, M. Y.; Lee, W. M. [Department of Chemistry and Division of Energy Systems Research, Ajou University, Suwon 443-749 (Korea, Republic of)

2008-03-10T23:59:59.000Z

484

Microsoft Word - 41892_Praxair_Low NOx_Factsheet_Rev 0a_01-09-04.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

FACT SHEET FACT SHEET Revision 0a Jan. 9, 2004 Page 1 of 4 I. PROJECT DESCRIPTION A. Objective: The objective of this project is to design a gas turbine combustor system for new and existing turbines with a combination of air flow management control and fuel composition control to achieve 2 ppm NOx emissions. Since most Integrated Gasification Combined-Cycle (IGCC) systems consider the use of natural gas as an alternative fuel and there is a large infrastructure of existing natural gas based turbines, it is imperative that the combustor design be amenable to operating on both coal derived fuel gas and natural gas. The specific objectives of each phase of this program are: Phase I: Develop conceptual design of turbine combustor with air flow control and fuel

485

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN COFIRING BIOMASS WITH COAL  

SciTech Connect

This is the first Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. The project goals and detailed plans were presented in two project kickoff meetings; one at NETL in Pittsburgh and one in Birmingham, AL at Southern Research Institute. Progress has been made in developing a modeling approach to synthesize the reaction time and temperature distributions that will be produced by computational fluid dynamic models of the pilot-scale combustion furnace and the char burnout and chemical reaction kinetics that will predict NOx emissions and unburned carbon levels in the furnace exhaust. Preparations are under way for the initial pilot-scale combustion experiments.

Larry G. Felix; P. Vann Bush; Stephen Niksa

2001-01-24T23:59:59.000Z

486

A method to extend flamelet manifolds for prediction of NOx and long time scale species with tabulated chemistry  

Science Journals Connector (OSTI)

Numerical simulation is currently used to help design low NOx devices for aircraft engines. In order to improve the prediction of pollutant species, combustion models based on tabulated chemistry have been commonly used in recent years. However, the short time scales of usual flamelet manifolds can lead to errors concerning the NO prediction in post flame area, as shown in this paper. Thus, a new method is proposed to extend the manifold in order to describe the evolution of species with a long characteristic time. This method is tested in the framework of 0D-1D computations. The use of the extended manifold is shown to be necessary to correctly predict the evolution of NO concentration in burnt gases. As an example, the extended and classical manifolds were compared in the framework of 2D simulations of an industrial-like combustor, showing an evident difference on the NO levels predicted in the outlet section.

Aymeric Boucher; Nicolas Bertier; Francis Dupoirieux

2014-01-01T23:59:59.000Z

487

Mechanistic Investigation of Ethanol SCR of NOx over Ag/Al2O3  

SciTech Connect

A 2 wt.% Ag/{gamma}-Al{sub 2}O{sub 3} catalyst was studied for the ethanol selective catalytic reduction of NO{sub x} from 200 to 550 C and space velocities between 30,000 h{sup -1} and 140,000 h{sup -1}. Peak NO{sub x} conversions reached 85% at 400 C, and an activation energy was determined to be 57 kJ/mol with a feed of ethanol to NO{sub x} or HC{sub 1}/NO{sub x} = 3. Up to 80% of the NO is oxidized to NO{sub 2} at 250 C, but overall NO{sub x} conversion is only 15%. Interestingly, ethanol oxidation occurs at much lower temperatures than NO{sub x} reduction; at 250 C, ethanol oxidation is 80% when flowing ethanol + NO + O{sub 2}. This increased reactivity, compared to only 15% when flowing only ethanol + O{sub 2}, combined with the observation that NO is not oxidized to NO{sub 2} in the absence of ethanol illustrates a synergistic relationship between the reactants. To further investigate this chemistry, a series of DRIFTS experiments were performed. To form nitrates/nitrites on the catalysts it was necessary to include ethanol in the feed with NO. These nitrates/nitrites were readily formed when flowing NO{sub 2} over the catalyst. It is proposed that ethanol adsorbs through an ethoxy-intermediate that results in atomic hydrogen on the surface. This hydrogen aids the release of NO{sub 2} from Ag to the gas-phase which, can be subsequently adsorbed at {gamma}-Al{sub 2}O{sub 3} sites away from Ag. The disappearance of these nitrates/nitrites at higher temperatures proceeds in parallel with the increase in NO{sub x} reduction reactivity between 300 and 350 C observed in the kinetic study. It is therefore proposed that the consumption of nitrates is involved in the rate determining step for this reaction.

Johnson, William L [ORNL; Fisher, Galen [University of Michigan; Toops, Todd J [ORNL

2012-01-01T23:59:59.000Z

488

Ozone response of foliage and cells of sensitive and tolerant potato cultivars  

SciTech Connect

The ozone response was contrasted between Cherokee' and Norchip', relatively ozone-sensitive and -tolerant potato cultivars, respectively. Leaf conductance of the two cultivars was determined with a diffusive resistance porometer before, during and after a 3-hour exposure to 0.25 ppm ozone (490 ..mu..g m3). While Cherokee foliage had a higher leaf conductance at the onset of the ozone exposure, conductance of Norchip foliage was too high throughout the experiment to account for relative tolerance of the latter cultivar. Norchip and Cherokee both exhibited abaxial and bifacial necrosis with more numerous lesions on the abaxial surface. Abaxial and bifacial necrosis were characterized by injured spongy, and spongy plus palisade cells, respectively. The percent of injured cell types were the same in both cultivars, but the absolute number of cells injured was greater in Cherokee than Norchip. Two types of cell injury were observed in necrotic lesions. One type of injury was characterized by collapsed, basophilic cells and the other by intact, basophilic cells. The ozone response of isolated leaf protoplasts of the two cultivars was similar. Two types of protoplast injury were observed, one characterized by lysis and the other by reduced staining with fluorescein diacetate. Maximum protoplast response to ozone was observed within the first 5 minutes of a 15 minute exposure. Little additional protoplast response occurred after 10 minutes.

Illman, B.L.

1983-01-01T23:59:59.000Z

489

The evolution of the Brewer-Dobson circulation and the ozone layer during the last three decades.  

E-Print Network (OSTI)

??In 1985 Joseph Farman and his colleagues of the British Antarctic Survey published a paper [Farman et al. 1985] showing that the total ozone content (more)

Oss Castilln, Albert

2014-01-01T23:59:59.000Z

490

Ozone Measurements at Geesthacht (53.4 N, 10.4 E) with an Advanced Raman Lidar  

Science Journals Connector (OSTI)

An advanced Raman lidar, which measures ozone, water vapor, aerosol backscatter, and extinction profiles simoultaneously and independently, has been in routine operation at Geesthacht since February 1995. Results...

Marcus Seiwazi; Jens Reichardt

1997-01-01T23:59:59.000Z

491

Cross-country urban and rural measurements of NOx and SO2. Final report  

SciTech Connect

Total sulfur and oxides of nitrogen measurements, gathered along two long-distance routes across the United States, are presented. Supportive information describing the instrumentation, procedures, moving laboratory, and regional meteorological conditions are provided. Over 300,000 measurements were made. Points consisting of ten-measurement averages have been plotted; they are also presented in a graphic analysis. This analysis consists of frequency distribution plots of segments of the trip, for example, through rural areas and crossing urban developments. These plots provide a means of classification of the degree of pollution present and monitored with this moving laboratory technique. The data were gathered from Denver, Colorado, to Raleigh, North Carolina, in August 1976, and from Los Angeles, California, to Raleigh, North Carolina, in November 1976. In November the laboratory stopped at six rural locations to record time-averaged data, which are also presented.

Langan, L.; Peache, M.A.; Garbarz, J.J.; Baumgardner, R.E.; Stevens, R.K.

1980-01-01T23:59:59.000Z

492

Integrated Dry NOx/SO2 Emissions Control System, A DOE Assessment  

SciTech Connect

The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) Program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment (PPA) of a project selected in CCT Round III, the Integrated Dry NO{sub x}/SO{sub 2} Emissions Control System (IDECS), as described in a Report to Congress (U.S. Department of Energy 1991). The desire to reduce emissions of nitrogen oxides (NO, nitric oxide, and NO{sub 2}, nitrogen dioxide, collectively referred to as NO{sub x}) and sulfur dioxide (SO{sub 2}) by up to 70 percent at a minimum capital expenditure, while limiting waste production to dry solids that can be handled by conventional ash-removal equipment, prompted Public Service Company of Colorado (PSCC) to submit the proposal for the IDECS project. In March 1991, PSCC entered into a cooperative agreement with DOE to conduct the study. The project was sited at PSCC's Arapahoe Steam Electric Generating Station in Denver, Colorado. The purpose of this CCT project was to demonstrate the reduction of NO{sub x} and SO{sub 2} emissions by installing a combination of existing and emerging technologies, which were expected to work synergistically to reduce emissions. The technologies were low-NO{sub x} burners (LNBS), overfire air (OFA), and selective noncatalytic reduction (SNCR) for NO{sub x} reduction; and dry sorbent injection (DSI), both with and without flue-gas humidification (FGH), for SO{sub 2} reduction. DOE provided 50 percent of the total project funding of $26.2 million.

National Energy Technology Laboratory

2001-10-01T23:59:59.000Z

493

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite  

Energy.gov (U.S. Department of Energy (DOE))

Discusses the impact of Na in biodiesel on three emission control devices: the diesel particulate filter, diesel oxidation catalyst, and zeolyte-based SCR catalyst

494

Mixed-Phase Oxide Catalyst Based on Mn-Mullite (Sm, Gd)Mn2O5 for NO Oxidation in Diesel Exhaust  

Science Journals Connector (OSTI)

...efficiency than gasoline engines (1). However...devices to reduce the engine-generated nitrogen...NOx to N 2 under fuel-rich regeneration...NOx-based pollutants, diesel engines also generate black...indicating the consumption of surface...

Weichao Wang; Geoffrey McCool; Neeti Kapur; Guang Yuan; Bin Shan; Matt Nguyen; Uschi M. Graham; Burtron H. Davis; Gary Jacobs; Kyeongjae Cho; Xianghong (Kelly) Hao

2012-08-17T23:59:59.000Z

495

Modeling of formaldehyde and nitrogen oxides from a proposed renewable energy biogas facility in Canada  

Science Journals Connector (OSTI)

The aim of this study was to use the CALPUFF modeling system an effective and reliable atmospheric modeling tool to predict the concentrations of formaldehyde (HCHO) and nitrogen oxides (NOx) released due to the combustion of biogas in the combined heat and power (CHP) engines from the Kawartha renewable energy generation facility at its proposed location in Ontario Canada. In this study HCHO and NOx were selected as the indicator and point source pollutants since they were the most significant products of biogas combustion emitted during the facility's normal operations (production of electricity and heat). The Lambert Conformal Conic projection coordinate system was implemented for the operation of the CALPUFF model. The proposed modeling scheme was coupled with both surface meteorological data (from 00:00 to 23:00) on an hourly basis and 12-h interval-based upper air meteorological data (from 00:00 to 12:00) to simulate the emission of these pollutants for the four seasonal Eastern Time meteorological conditions of winter (January 1113 2013) spring (April 1416 2013) summer (July 1012 2013) and autumn (November 1618 2013). The results from the CALPUFF dispersion model clearly demonstrated that the maximum 1-h average concentrations of both HCHO and NOx emitted from the combustion of biogas (composed of 60% CH4 and 40% CO2) in five CHP engines (operation load?=?100% maximum electricity generation capacity?=?9.8?MW) were found to be within the limits defined by Ontario Regulation 419/05.

2014-01-01T23:59:59.000Z

496

Oxidation of propylene over copper oxide catalysts  

E-Print Network (OSTI)

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

497

Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.  

SciTech Connect

This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

Whitfield, R. G.

1999-03-04T23:59:59.000Z

498

Auto GC system for enhanced ozone monitoring network  

SciTech Connect

A Perkin-Elmer Model ATD-400 Thermal Desorption System was specially adapted for the collection of whole-air samples. The C{sub 2} to n-C{sub 10} hydrocarbons were trapped using Peltier cooling on Carbotrap/Carbosieve adsorbents at {minus}30 C. A Deans switch allowed the C{sub 2} to C{sub 6} fraction to be separated using a porous layer open tubular column while a methyl silicone column separated the C{sub 6} to C{sub 10} fraction. No cryogen was used in the collection or analysis. Ozone precursor concentrations were detected at the 0.1 ppbV level. Area repeatability was less than 10%, with retention time precision over 100 hours of approximately 1% RSD for most compounds. Remote communications allowed chromatography to be monitored and files to be downloaded to a central office. Data in .CSV format was directly assimilated by spreadsheet software for diurnal inspection and customized reporting. Data were achieved using external Bernoulli disks.

Seeley, I.; Tipler, A. [Perkin-Elmer Corp., Norwalk, CT (United States); Broadway, G. [Perkin-Elmer Ltd., Beaconsfield (United Kingdom)

1994-12-31T23:59:59.000Z