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Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Nitrogen Oxides (NOx), Why and How They are Controlled  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air Quality EPA 456/F-99-006R Air Quality EPA 456/F-99-006R Environmental Protection Planning and Standards November 1999 Agency Research Triangle Park, NC 27711 Air EPA-456/F-99-006R November 1999 Nitrogen Oxides (NOx), Why and How They Are Controlled Prepared by Clean Air Technology Center (MD-12) Information Transfer and Program Integration Division Office of Air Quality Planning and Standards U.S. Environmental Protection Agency Research Triangle Park, North Carolina 27711 ii DISCLAIMER This report has been reviewed by the Information Transfer and Program Integration Division of the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency and approved for publication. Approval does not signify that the contents of this report reflect the views and policies of the U.S. Environmental Protection Agency. Mention of trade

2

Reducing NOx in Fired Heaters and Boilers  

E-Print Network [OSTI]

-6, 2000 Reducing NOx in Fired Heaters Air Pollution Control and Boilers Keeping the environment clean Presented by Ashutosh Garg Furnace Improvements Low cost solutions for fired heaters Trace compounds ? Nitric oxides ? Carbon monoxide ? Sulfur... it is essential to estimate accurately baseline NOx emissions. ? This will establish each units current compliance status. ? Emissions ? Current excess air level ? Carbon monoxide ? Combustibles ? NOx corrected to 3% 02 314 ESL-IE-00-04-46 Proceedings...

Garg, A.

3

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10li.pdf More Documents & Publications Lean NOx Trap...

4

NOx | OpenEI  

Open Energy Info (EERE)

NOx NOx Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx SO2 sulfur dioxide emissions

5

Modeling Species Inhibition of NO oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbate’s storage in the SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2010-09-15T23:59:59.000Z

6

Modeling Species Inhibition of NO Oxidation in Urea-SCR Catalysts for Diesel Engine NOx Control  

SciTech Connect (OSTI)

Urea-selective catalytic reduction (SCR) catalysts are regarded as the leading NOx aftertreatment technology to meet the 2010 NOx emission standards for on-highway vehicles running on heavy-duty diesel engines. However, issues such as low NOx conversion at low temperature conditions still exist due to various factors, including incomplete urea thermolysis, inhibition of SCR reactions by hydrocarbons and H2O. We have observed a noticeable reduction in the standard SCR reaction efficiency at low temperature with increasing water content. We observed a similar effect when hydrocarbons are present in the stream. This effect is absent under fast SCR conditions where NO ~ NO2 in the feed gas. As a first step in understanding the effects of such inhibition on SCR reaction steps, kinetic models that predict the inhibition behavior of H2O and hydrocarbons on NO oxidation are presented in the paper. A one-dimensional SCR model was developed based on conservation of species equations and was coded as a C-language S-function and implemented in Matlab/Simulink environment. NO oxidation and NO2 dissociation kinetics were defined as a function of the respective adsorbate’s storage in the Fe-zeolite SCR catalyst. The corresponding kinetic models were then validated on temperature ramp tests that showed good match with the test data. Such inhibition models will improve the accuracy of model based control design for integrated DPF-SCR aftertreatment systems.

Devarakonda, Maruthi N.; Tonkyn, Russell G.; Tran, Diana N.; Lee, Jong H.; Herling, Darrell R.

2011-04-20T23:59:59.000Z

7

16 - Ultra-low nitrogen oxides (NOx) emissions combustion in gas turbine systems  

Science Journals Connector (OSTI)

Abstract: The historical development of gas turbine low \\{NOx\\} combustion from the pioneering NASA work in the early 1970s to the present generation of ultra-low \\{NOx\\} industrial gas turbine combustors is reviewed. The principles of operation of single digit ultra-low \\{NOx\\} gas turbine combustion for industrial applications are outlined. The review shows the potential has been demonstrated by several investigators using different flame stabilizers for \\{NOx\\} to be reduced to 1 ppm at 1700 K, 2 ppm at 1800 K and 3–4 ppm at 1900 K with no influence of operating pressure and with a practical operating flame stability margin. Under these conditions it is shown that no thermal \\{NOx\\} should occur and all the \\{NOx\\} is formed by the prompt \\{NOx\\} mechanisms. The elimination of thermal \\{NOx\\} makes the \\{NOx\\} emissions independent of residence time or reference velocity and independent of pressure. Also there is no influence of air inlet temperature for the same flame temperature. Where legislation requires emissions to be as low as can be achieved, emissions below 4 ppm in production engines are current technology and this review shows the potential to get even lower than this in the future.

G.E. Andrews

2013-01-01T23:59:59.000Z

8

Pillared smectite modified with carbon and manganese as catalyst for SCR of NOx with NH3. Part I. General characterization and catalyst screening  

Science Journals Connector (OSTI)

Carbon- and manganese-modified zirconia-pillared smectites were prepared, characterized (XRD, BET and pore analysis, XPS) and tested in selective catalytic reduction of NOx with NH3. Both untreated and acidic pre...

Lucjan Chmielarz; Roman Dziembaj; Teresa Grzybek; Jerzy Klinik…

9

Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts  

Broader source: Energy.gov [DOE]

Presents latest progress in the development of a new type of lean NOx trapping catalyst based on heterogenous composite nanowires, which could potentially be used in gasoline and diesel engines.

10

Assessment of Oxidation in Carbon Foam  

E-Print Network [OSTI]

Carbon foams exhibit numerous unique properties which are attractive for light weight applications such as aircraft and spacecraft as a tailorable material. Carbon foams, when exposed to air, oxidize at temperatures as low as 500-600 degrees Celsius...

Lee, Seung Min

2010-07-14T23:59:59.000Z

11

JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System  

SciTech Connect (OSTI)

Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

Scott Tolbert; Steven Benson

2008-02-29T23:59:59.000Z

12

ORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation  

E-Print Network [OSTI]

). Methylotrophs and iron oxidizers were also active in plume waters and expressed key proteins for methane by bacteria (especially, alpha-, gamma- and epsilon-proteobacteria) that likely participate in the oxidationORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation at a biogeochemical hot spot in the dark

Hansell, Dennis

13

Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...

14

Why sequence carbon monoxide oxidizing thermophiles?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon monoxide oxidizing thermophiles? carbon monoxide oxidizing thermophiles? Many microbes that use carbon monoxide as an energy source are found in high temperature environments such as geothermal areas. Researchers think that these carboxydotrophs may be involved in reducing potentially toxic carbon monoxide hotspots by combine with water to form hydrogen, carbon dioxide and acetate, which are in turn used for thermophilic energy conservation and carbon sequestration mechanisms. The project focuses on sequencing two closely related microbes, one of which is Carboxydothermus hydrogenformans. A strain of C. hydrogenformans has been grown in hydrogen-enriched synthesis gas (syngas), which contains a mix of hydrogen and carbon monoxide. Researchers are interested in sequencing both microbial strains to track the genome's evolution and

15

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network [OSTI]

for Application in Solid Oxide Fuel Cells", (DoctoralImpedance of Solid Oxide Fuel Cell LSM/YSZ CompositeCathode materials of solid oxide fuel cells: a review”, J

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

16

DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN COFIRING BIOMASS WITH COAL  

SciTech Connect (OSTI)

This is the first Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. The project goals and detailed plans were presented in two project kickoff meetings; one at NETL in Pittsburgh and one in Birmingham, AL at Southern Research Institute. Progress has been made in developing a modeling approach to synthesize the reaction time and temperature distributions that will be produced by computational fluid dynamic models of the pilot-scale combustion furnace and the char burnout and chemical reaction kinetics that will predict NOx emissions and unburned carbon levels in the furnace exhaust. Preparations are under way for the initial pilot-scale combustion experiments.

Larry G. Felix; P. Vann Bush; Stephen Niksa

2001-01-24T23:59:59.000Z

17

Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Vehicle Technologies Office Merit Review 2014: Advanced Oxidation &...

18

Thief Carbon Catalyst for Oxidation of Mercury in Effluent Stream  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Catalyst for Oxidation of Mercury in Effluent Carbon Catalyst for Oxidation of Mercury in Effluent Stream Contact NETL Technology Transfer Group techtransfer@netl.doe.gov January 2012 Significance * Oxidizes heavy metal contaminants, especially mercury, in gas streams * Uses partially combusted coal ("Thief" carbon) * Yields an inexpensive catalyst * Cheap enough to be a disposable catalyst * Cuts long-term costs * Simultaneously addresses oxidation and adsorption issues Applications * Any process requiring removal of heavy

19

NETL: Advanced NOx Emissions Control: Control Technology - Model for NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Model for NOx Emissions in Biomass Cofiring Model for NOx Emissions in Biomass Cofiring Southern Research Institute is developing a validated tool or methodology to accurately and confidently design and optimize biomass-cofiring systems for full-scale utility boilers to produce the lowest NOX emissions and the least unburned carbon. The computer model will be validated through an extensive set of tests at the 6 MMBtu/hr pilot combustor in the Southern Company/Southern Research Institute Combustion Research Facility. Full-scale demonstration testing can be compared to the model for further validation. The project is designed to balance the development of a systematic and expansive database detailing the effects of cofiring parameters on NOx formation with the complementary modeling effort that will yield a capability to predict, and therefore optimize, NOx reductions by the selection of those parameters. The database of biomass cofiring results will be developed through an extensive set of pilot-scale tests at the Southern Company/Southern Research Institute Combustion Research Facility. The testing in this program will monitor NOx, LOI, and other emissions over a broad domain of biomass composition, coal quality, and cofiring injection configurations to quantify the dependence of NOx formation and LOI on these parameters. This database of cofiring cases will characterize an extensive suite of emissions and combustion properties for each of the fuel and injection configuration combinations tested.

20

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...  

Broader source: Energy.gov (indexed) [DOE]

NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation...

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Atmospheric Oxidation of Coal at Moderate Temperatures. Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals.  

Science Journals Connector (OSTI)

Atmospheric Oxidation of Coal at Moderate Temperatures. ... Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals. ...

L Schmidt; J Elder; J Davis

1940-01-01T23:59:59.000Z

22

Field Demonstration of 0.2 Grams Per Horsepower-Hour (g/bhp-hr) Oxides of Nitrogen (NOx) Natural  

E-Print Network [OSTI]

: · Reducing health and environmental impacts from air pollution, and greenhouse gas emissions related pollution and greenhouse gas emissions beyond applicable standards, and that benefit natural gas ratepayers of nitrogen (NOx) emission standard of 0.20 g/bhp-hr for heavy duty engines to reduce levels of this critical

23

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO 2 : Implications for inversion analyses  

E-Print Network [OSTI]

Influence of reduced carbon emissions and oxidation on thedescription of reduced carbon emission and oxidationInfluence of reduced carbon emissions and oxidation on the

Suntharalingam, Parvadha; Randerson, James T; Krakauer, Nir; Logan, Jennifer A; Jacob, Daniel J

2005-01-01T23:59:59.000Z

24

A Return Stroke NOx Production Model  

Science Journals Connector (OSTI)

A model is introduced for estimating the nitrogen oxides (NOx = NO + NO2) production from a lightning return stroke channel. A realistic Modified Transmission Line Model return stroke current is assumed to propagate vertically upward along a ...

William J. Koshak; Richard J. Solakiewicz; Harold S. Peterson

25

Production of Carbon from Carbon Dioxide with Iron Oxides and High-Temperature Solar Energy  

Science Journals Connector (OSTI)

Production of Carbon from Carbon Dioxide with Iron Oxides and High-Temperature Solar Energy ... 2 Since it is the major oxidation product from all hydrocarbon combustion processes, its presence permeates nearly every sector of the world economy. ... Thus, CO2 recycling and utilization seems to be a fundamental task from both an ecological and economical point of view. ...

K. Ehrensberger; R. Palumbo; C. Larson; A. Steinfeld

1997-03-03T23:59:59.000Z

26

Thief carbon catalyst for oxidation of mercury in effluent stream  

DOE Patents [OSTI]

A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2011-12-06T23:59:59.000Z

27

UV-light enhanced oxidation of carbon nanotubes M. Grujicica,*  

E-Print Network [OSTI]

the activation energy for molecular-oxygen chemisorption to a nanotube, increases the adsorption energyUV-light enhanced oxidation of carbon nanotubes M. Grujicica,* , G. Caoa , A.M. Raob , T.M. Trittb) calculations of the interactions between selected semiconducting and metallic single-walled carbon nanotubes

Grujicic, Mica

28

Kinetic model of catalytic oxidation of carbon monoxide on nickel  

SciTech Connect (OSTI)

A mechanism is proposed for describing the previous disclosed multiplicity of equilibrium states in the oxidation of carbon monoxide on metallic nickel. In contrast to the known mechanism for oxidation of CO on platinum metals it includes a nonlinear stage of carbon monoxide adsorption and a linear stage of oxygen adsorption. A kinetic model has been obtained and stage velocity constants have been found, providing a basis for obtaining a quantitative agreement between the calculated and experimental relations between the reaction velocity and the reagent concentrations. Opinions are stated in relation to the causes for evolution of the CO oxidation reaction from platinum metals to nickel.

Pyatnitskii, Yu.I.; Ostapyuk, V.A.

1986-07-01T23:59:59.000Z

29

Oxidation resistant carbon-carbon composites: the effect of temperature dependent matrix material properties on laminate response  

E-Print Network [OSTI]

on the thermomechanical response of oxidation resistan two dimensional, externally coated, 8 harness satin weave carbon-carbon laminatcs. This research focuses on developing a through-the-thickness or out-of-plane finite element representation of an oxidation resistant... on the thermomechanical response of oxidation resistan two dimensional, externally coated, 8 harness satin weave carbon-carbon laminatcs. This research focuses on developing a through-the-thickness or out-of-plane finite element representation of an oxidation resistant...

Romine, Paul Richard

2012-06-07T23:59:59.000Z

30

Atmospheric pressure gas plasma-induced colorectal cancer cell death is mediated by Nox2–ASK1 apoptosis pathways and oxidative stress is mitigated by Srx–Nrf2 anti-oxidant system  

Science Journals Connector (OSTI)

Abstract Atmospheric pressure gas plasma (AGP) generates reactive oxygen species (ROS) that induce apoptosis in cultured cancer cells. The majority of cancer cells develop a ROS-scavenging anti-oxidant system regulated by Nrf2, which confers resistance to ROS-mediated cancer cell death. Generation of ROS is involved in the AGP-induced cancer cell death of several colorectal cancer cells (Caco2, HCT116 and SW480) by activation of ASK1-mediated apoptosis signaling pathway without affecting control cells (human colonic sub-epithelial myofibroblasts; CO18, human fetal lung fibroblast; MRC5 and fetal human colon; FHC). However, the identity of an oxidase participating in AGP-induced cancer cell death is unknown. Here, we report that AGP up-regulates the expression of Nox2 (NADPH oxidase) to produce ROS. RNA interference designed to target Nox2 effectively inhibits the AGP-induced ROS production and cancer cell death. In some cases both colorectal cancer HT29 and control cells showed resistance to AGP treatment. Compared to AGP-sensitive Caco2 cells, HT29 cells show a higher basal level of the anti-oxidant system transcriptional regulator Nrf2 and its target protein sulfiredoxin (Srx) which are involved in cellular redox homeostasis. Silencing of both Nrf2 and Srx sensitized HT29 cells, leads to ROS overproduction and decreased cell viability. This indicates that in HT29 cells, Nrf2/Srx axis is a protective factor against AGP-induced oxidative stress. The inhibition of Nrf2/Srx signaling should be considered as a central target in drug-resistant colorectal cancer treatments.

Musarat Ishaq; Margaret D.M. Evans; Kostya (Ken) Ostrikov

2014-01-01T23:59:59.000Z

31

Black Carbon in the Soil Carbon Cycle: Is it an Oxidation Resistant End-Product?  

E-Print Network [OSTI]

for different materials and combustion temperatures. It is less than 1% for thermally altered biomass at combusBlack Carbon in the Soil Carbon Cycle: Is it an Oxidation Resistant End-Product? Simone resistant product of incomplete combustion, and consists out of a range of combustion products such as char

Fischlin, Andreas

32

Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites  

Science Journals Connector (OSTI)

Carbon nanotube (CNT) aerogels are used as scaffolds for the sol-gel deposition of various oxide coatings (SiO2, SnO2 or TiO2). ... In each case, the deposited oxide appears to form a uniform coating on the surfaces of aerogel ligaments. ...

Marcus A. Worsley; Sergei O. Kucheyev; Joshua D. Kuntz; Tammy Y. Olson; T. Yong-Jin Han; Alex V. Hamza; Joe H. Satcher, Jr.; Theodore F. Baumann

2011-05-26T23:59:59.000Z

33

Thermo-Oxidation of Tokamak Carbon Dust  

SciTech Connect (OSTI)

The oxidation of dust and flakes collected from the DIII-D tokamak, and various commercial dust specimens, has been measured at 350 ºC and 2.0 kPa O2 pressure. Following an initial small mass loss, most of the commercial dust specimens showed very little effect due to O2 exposure. Similarly, dust collected from underneath DIII-D tiles, which is thought to comprise largely Grafoil™ particulates, also showed little susceptibility to oxidation at this temperature. However, oxidation of the dust collected from tile surfaces has led to ~ 18% mass loss after 8 hours; thereafter, little change in mass was observed. This suggests that the surface dust includes some components of different composition and/or structure – possibly fragments of codeposited layers. The oxidation of codeposit flakes scraped form DIII-D upper divertor tiles showed an initial 25% loss in mass due to heating in vacuum, and the gradual loss of 30-38% mass during the subsequent 24 hours exposure to O2. This behavior is significantly different from that observed for the oxidation of thinner DIII-D codeposit specimens which were still adhered to tile surfaces, and this is thought to be related to the low deuterium content (D/C ~ 0.03 – 0.04) of the flakes.

J.W. Davis; B.W.N. Fitzpatrick; J.P. Sharpe; A.A. Haasz

2008-04-01T23:59:59.000Z

34

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx Reduction Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx...

35

Low NOx combustion system for heavy oil  

SciTech Connect (OSTI)

As a result of the increasing demand for white oil as one of countermeasures for pollution control and as a fuel for motor vehicle, coupled with the increasing import of heavy crude oil, heavy oils such as asphalt and distillation residue have become surplus in Japan. It is difficult by the conventional low NOx technology to control the NOx emission from the industrial small and medium capacity boilers, which use heavy oil as their fuels. The authors have been developing and improving NOx control technologies for boilers such as low NOx burners, two-stage combustion methods and so on. They have developed a new combustion system for heavy oil, which generates less NOx and soot than conventional systems, by applying the knowledge, obtained in the course of their development of Coal Partial Combustor (CPC). The conventional low NOx combustion method for oil firing boilers has been developed based on decreasing the flame temperature and delaying the combustion reaction. In the system, however, the heavy oil shall be combusted in the intense reducing atmosphere at the high flame temperature between 1,500 C and 1,600 C, and then the combustions gas shall be cooled and oxidized by two-stage combustion air. With this system, NOx emission can be suppressed below 100ppm (converted as O{sub 2}=4%).

Kurata, Chikatoshi; Sasaki, Hideki

1999-07-01T23:59:59.000Z

36

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect (OSTI)

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

37

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network [OSTI]

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

38

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

39

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

40

Adsorption and decomposition of triclosan by activated carbons, manganese oxides, and their composite materials from aqueous solution.  

E-Print Network [OSTI]

??This research investigates the use of activated carbon (AC) and manganese oxides as adsorbents and oxidizing agents to adsorb and oxidize triclosan, a compound which… (more)

Fang, Sheng

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Fe Promoted NOx Storage Materials: Structural Properties and NOx Uptake  

Science Journals Connector (OSTI)

According to the European Union regulations (EURO VI),(2) by the end of 2014, diesel passenger cars will be subject to a 3-fold decrease in NOx emissions from 0.25 to 0.08 g km?1. ... Barium oxide crystallizes in the rock salt structure, and the first order Raman scattering is symmetry forbidden(32, 33) However, broad and weak bands within 350?500 cm?1 due to the lattice modes of the defective BaO domains can still be visible via Raman spectroscopy (see for instance, Figure 3 in the Supporting Information). ...

Emine Kayhan; Stanislava M. Andonova; Go?ksu S. S?entu?rk; Charles C. Chusuei; Emrah Ozensoy

2009-12-11T23:59:59.000Z

42

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

43

Experimental investigation of the thermal and diluent effects of EGR components on combustion and \\{NOx\\} emissions of a turbocharged natural gas SI engine  

Science Journals Connector (OSTI)

Abstract Exhaust gas recirculation (EGR) is one of effective measures used in natural gas (NG) engines to reduce nitrogen oxides (NOx) emissions. Each component of EGR gases can exert different effects on NG combustion and \\{NOx\\} formation rates, such as thermal effect, diluent effect, and chemical effect. In this study, the thermal and diluent effects of the main components of EGR gases, including carbon dioxide (CO2) and nitrogen (N2), were experimentally investigated. The experiments were arranged based on an electronically controlled heavy-duty natural gas spark-ignition (SI) engine with multi-point injection and 6-cylinder. In order to define the diluent effect of EGR components, argon (Ar) was introduced to the test, for its low and unchangeable specific heat capacity under different temperatures. The results showed that the contribution of the diluent effect on \\{NOx\\} reductions was 50–60% and 41–53% for N2 and CO2 respectively, and the relevant contribution of the thermal effect was 40–50% and 47–59% respectively. CO2 had greater effects on NG combustion and \\{NOx\\} formation rates than N2 at the same dilution ratio. Increasing Ar improved the thermal efficiency due to the higher specific heat ratio provided. Meanwhile, \\{NOx\\} emissions were found to be decreased with increasing DR as a result of the diluent effect of Ar on combustion and \\{NOx\\} formations.

Weifeng Li; Zhongchang Liu; Zhongshu Wang; Yun Xu

2014-01-01T23:59:59.000Z

44

Transparent and Conductive Carbon Nanotube Multilayer Thin Films Suitable as an Indium Tin Oxide Replacement  

E-Print Network [OSTI]

Transparent electrodes made from metal oxides suffer from poor flexibility and durability. Highly transparent and electrically conductive thin films based on carbon nanotubes (CNTs) were assembled as a potential indium tin oxide (ITO) replacement...

Park, Yong Tae

2012-07-16T23:59:59.000Z

45

CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING  

E-Print Network [OSTI]

CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING in strategies for climate protection. 1. Introduction Carbon sequestration has been highlighted recently concentration of carbon dioxide (CO2) in the atmo- sphere include sequestering carbon (C) in soils

46

Oxidative enzymatic response of white-rot fungi to single-walled carbon nanotubes  

E-Print Network [OSTI]

Oxidative enzymatic response of white-rot fungi to single-walled carbon nanotubes Timothy D. Berry-walled carbon nanotubes (SWCNT) are becoming increasingly prevalent in manufacturing, there is little knowledge. Introduction Single-walled carbon nanotubes (SWCNTs), formed from single- atom thick sheets of carbon wound

Blanchette, Robert A.

47

Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program  

Broader source: Energy.gov (indexed) [DOE]

41 - Nox Budget Trading 41 - Nox Budget Trading Program (Rhode Island) Air Pollution Control Regulations: No. 41 - Nox Budget Trading Program (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These regulations apply to units that serve generators with a nameplate capacity greater than 15 MWe and sell any amount of electricity, as well as to units that have a maximum

48

Synthesis of Co oxide doped carbon aerogel catalyst and catalytic performance in heterogeneous oxidation of phenol in water  

Science Journals Connector (OSTI)

Co oxide doped carbon aerogel (Co/CA) was prepared, characterised by several techniques, and tested for heterogeneous oxidation of phenol in aqueous solution using oxone as an oxidant. For a comparison, homogeneous oxidation of phenol in Co2+/oxone was also investigated. It was found that homogeneous oxidation of phenol using Co2+/oxone was more effective than Co2+/H2O2 and homogeneous oxidation was faster than heterogeneous Co/CA–oxone. Heterogeneous oxidation of phenol in Co/CA–oxone system followed first order kinetics and the activation energy of the heterogeneous system was estimated to be 62.9 kJ/mol. Several factors influencing phenol degradation in the heterogeneous oxidation were studied. Co/CA loading played a more important role in phenol degradation than oxone concentration, and the presence of other organics in solution resulted in a lower phenol oxidation.

Yasnessya Hardjono; Hongqi Sun; Huyong Tian; C.E. Buckley; Shaobin Wang

2011-01-01T23:59:59.000Z

49

Total oxidation of carbon monoxide and methane over transition metal-fluorite oxide composite catalysts. I. Catalyst composition and activity  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the total oxidation of carbon monoxide and methane was prepared by combining fluorite oxides with active transition metals. The fluorite oxides, such as ceria and zirconia, are oxygen-ion-conducting materials having catalytic properties usually at high temperatures. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of these oxides. The contact of the two types of materials gave rise to a high active oxidation catalyst. At a space velocity of about 42,000 h{sup {minus}1}, complete carbon monoxide oxidation in air occurred at room temperature on the Au{sub 0.05}[Ce(La)]{sub 0.95}L{sub x} catalyst and at ca. 100{degrees}C on Cu-Ce-O composite catalysts. At the same space velocity, total oxidation of methane on the Cu-Ce-O catalyst doped with La{sub 2}O{sub 3} or SrO took place at ca. 550{degrees}C. The specific carbon monoxide oxidation activity of the Cu-Ce-O catalyst was several orders of magnitude higher than that of conventional copper-based catalysts and comparable or superior to platinum catalysts. This type of composite catalyst also showed excellent resistance to water vapor poisoning. The enhanced catalyst activity and stability resulted from strong interaction of the transition metal and fluorite oxide materials. 44 refs., 14 figs., 5 tabs.

Liu, W.; Flytzani-Stephanopoulos, F. [Tufts Univ., Medford, MA (United States)] [Tufts Univ., Medford, MA (United States)

1995-05-01T23:59:59.000Z

50

Standard Test Method for Thermal Oxidative Resistance of Carbon Fibers  

E-Print Network [OSTI]

1.1 This test method covers the apparatus and procedure for the determination of the weight loss of carbon fibers, exposed to ambient hot air, as a means of characterizing their oxidative resistance. 1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units which are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard information, see Section 8.

American Society for Testing and Materials. Philadelphia

1982-01-01T23:59:59.000Z

51

Reduction of carbon monoxide emissions with regenerative thermal oxidizers  

SciTech Connect (OSTI)

Regenerative thermal oxidizers (RTOs) have been extensively used for the control of volatile organic compound (VOC) emissions from various sources. However, very little information is available on the ability of RTOs to control carbon monoxide (CO) emissions. This paper presents the results of extensive tests conducted on two RTOs to determine their VOC and CO control efficiencies. The inlet gas stream to the RTOs includes VOC and CO concentrations as high as 2,000 ppm and 3,600 ppm, respectfully. The testing demonstrated that both RTOs were capable of controlling greater than 98% of both inlet VOCs and CO. While the destruction efficiencies within the combustion chambers exceeded 99.9%, direct leakage past valves accounted for the lower control efficiencies. The tests indicated that the overall VOC and CO control efficiencies of the RTOs may be limited by valve leakage. The design and permitting of a RTO should include conservative control estimates which account for possible valve leakage.

Firmin, S.M.; Lipke, S.; Baturay, A.

1996-09-01T23:59:59.000Z

52

NOx Reduction from Biodiesel Fuels  

Science Journals Connector (OSTI)

NOx Reduction from Biodiesel Fuels ... NOx emissions appear to be different for biodiesels from different feedstocks. ... For the suite of biodiesels prepared from nearly pure fatty acids, all biodiesel fuels produced higher NOx than certification diesel with the following exceptions:? methyl palmitate, methyl laurate, ethyl stearate, and the ethyl ester of hydrogenated soybean oil. ...

Sandun Fernando; Chris Hall; Saroj Jha

2005-11-19T23:59:59.000Z

53

Carbon Monoxide Oxidation by Bacteria Associated with the Roots of Freshwater Macrophytes  

Science Journals Connector (OSTI)

...consumption and production of atmospheric carbon monoxide by...the consumption of atmospheric carbon monoxide by...rapid oxidation of atmospheric CO to CO2 by soils...D. Influence of water table on carbon dioxide...rice fields and biogas generators: CH4, N2O, CO...

Jeremy J. Rich; G. M. King

1998-12-01T23:59:59.000Z

54

Enhanced Combustion Low NOx Pulverized Coal Burner  

SciTech Connect (OSTI)

For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

2007-06-30T23:59:59.000Z

55

Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992  

SciTech Connect (OSTI)

This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

Not Available

1992-12-31T23:59:59.000Z

56

Understanding the Distributed Intra-Catalyst Impact of Sulfation on Water Gas Shift in a Lean NOx Trap Catalyst  

Broader source: Energy.gov [DOE]

The Lean NOx Trap catalyst is an aftertreatment technology for abatement of nitrogen-oxide emissions from lean-burn vehicle engines.

57

Reduction of NOx emission on NiCrAl-Titanium Oxide coated direct injection diesel engine fuelled with radish (Raphanus sativus) biodiesel  

Science Journals Connector (OSTI)

The main aim of this study is the experimental investigation of single cylinder DI diesel engine with and without coating. Diesel and radish (Raphanus sativus) oil Methyl Ester are used as fuels and the results are compared to find the effect of biodiesel in a thermal barrier coating engine. For this purpose engine cylinder head valves and piston crown are coated with 100??m of nickel-chrome-aluminium bond coat and 450??m of TiO2 by the plasma spray method. Radish oil methyl ester is produced by the transesterification process method. From the experimental investigation slight increase in specific fuel consumption in thermal barrier coating engine is observed when compared with the uncoated engine whereas NOx HC Smoke and CO emissions decreased with coated engine for all test fuels used in the coated engine when compared with that of the uncoated engine.

V. Ravikumar; D. Senthilkumar

2013-01-01T23:59:59.000Z

58

In situ ion exchange preparation of Pt/carbon nanotubes electrode: Effect of two-step oxidation of carbon nanotubes  

SciTech Connect (OSTI)

Multi-walled carbon nanotubes (MWNTs) supported Pt electrode is prepared by in-situ ion exchange method. X-ray photoelectron spectroscopy (XPS) confirms that compared with the only electrochemical oxidation or chemical oxidation treatment, more carboxylic acid groups are produced on the surface of MWNTs treated by dual-oxidation, which involves both electrochemical oxidation and chemical oxidation. Transmission electron microscopy (TEM) shows that Pt nanoparticles deposited via in-situ ion exchange are highly dispersed on the MWNTs surface. Electrochemical measurements show that the resultant Pt/MWNTs electrode treated by dual-oxidation exhibits the largest electrochemical surface area and the highest activity for oxygen reduction reaction (ORR) among the investigated electrodes. This can be attributed to the fact that dual-oxidation treatment produces more carboxylic acid groups at the electroactive sites on MWNTs surface, which results in loading more Pt nanoparticles in the following ion exchange process.

Zhang, Sheng; Shao, Yuyan; Gao, Yunzhi; Chen, Guangyu; Lin, Yuehe; Yin, Geping

2011-12-01T23:59:59.000Z

59

Basic solutions to carbon/carbon oxidation: Science and technology. Final report, 15 April 1993--14 April 1998  

SciTech Connect (OSTI)

The goal of this study was to gain a fundamental understanding of the role of boron in carbon oxidation. Boron-doped carbons were synthesized via CVD, ion implantation and high temperature doping are subsequently characterized. It was found that high temperature doped HOPG carbons were ideal for oxidation studies because their surface could be reproduced, their surface structures were determined and they were able to be characterized by XPS, AFM and SEM. The direct analysis of the chemical structures and atomic arrangements in boron- doped carbon or carbon surfaces by these techniques was critical in determining the effect of boron on carbon oxidation. XPS was utilized in this work to determine the local bonding environment of boron in carbon before an after oxidation. It was necessary to obtain an accurate calibration of the B1s binding energy scale which was accomplished by obtaining photoemission spectra of boron-doped carbons with known structures (local boron bonding environments), such as boron oxide, boron carbide, triphenylboroxine, tourmaline, boric acid, danburite and high temperature boron-doped graphite. All of the aforementioned standards contain boron in a unique bonding environment and thus their spectra formulated a complete conversion of B1s binding energies to boron chemical environments which has not been reported in the past. It was clearly established that a chemical shift for substitutional boron in graphite exists at 186.5 eV with a FWHM of 1.2. The chemical structures of the boron in the standards were related to the binding energy using a Pauling charge distribution model and a modification of the Sanderson electronegativity method. This approach was used to determine whether the B1s binding energy would change depending upon the specific location of boron in the graphite or graphite surface.

Harrison, I.R.; Chung, T.; Pantano, C.; Radovic, L.; Thrower, P.

1998-04-14T23:59:59.000Z

60

Evaluation of oxides of nitrogen emissions for the purpose of their transient regulation from a direct injection diesel engine  

Science Journals Connector (OSTI)

The concept of defining a regulatory standard for the maximum allowable emissions of oxides of nitrogen (NOx) from a heavy-duty diesel engine on an instantaneous basis is presented. The significance of this concept from a regulatory point of view is the possibility to realise a steady brake specific NOx emissions result independent of the test schedule used. The emissions of oxides of nitrogen from a state-of-the-art direct injection diesel engine have been examined on an integral as well as on an instantaneous basis over the Federal Test Procedure as well as over several other arbitrary transient cycles generated for this study. Three candidate standards of specific NOx emissions have been evaluated on a real-time, continuous basis. These include brake power specific, fuel mass specific, and carbon dioxide mass specific NOx emissions. Retaining the stock engine control module, the carbon dioxide specific emissions of NOx have been shown to be the most uniform, varying only by about 30% of its mean value regardless of the test schedule or engine operation. The instantaneous fuel specific NOx emissions are shown to be relatively less invariant and the least steady are the brake power specific emissions with a coefficient of variation of up to 200%. Advancing injection timing has been shown to have a wide range of authority over the specific emissions of oxides of nitrogen regardless of the units used, when operating at full load in the vicinity of peak torque speeds. The carbon dioxide specific NOx emissions have shown a linear dependence on the power specific emissions, independent of the examined operating conditions. The trade-off between better brake thermal efficiency, lower exhaust gas temperature at advanced timing and lower NOx emissions has also been shown to be independent of the units of the specific standard used.

Yasser Yacoub; Chris Atkinson

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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61

A method for carbon oxide concentration evaluation in high-temperature combustion processes  

Science Journals Connector (OSTI)

A method for evaluating carbon oxide concentration in high-temperature combustion processes is presented. The paper offers an optimizing control problem for fuel combustion process using a stabilizing regulatory controller, which affects the fuel/air ...

K. E. Arystanbaev, A. T. Apsemetov

2014-04-01T23:59:59.000Z

62

A method for carbon oxide concentration evaluation in high-temperature combustion processes  

Science Journals Connector (OSTI)

A method for evaluating carbon oxide concentration in high-temperature combustion processes is presented. The paper offers an optimizing control problem for fuel combustion process using a stabilizing regulatory ...

K. E. Arystanbaev; A. T. Apsemetov

2014-04-01T23:59:59.000Z

63

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25 bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

64

Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz  

E-Print Network [OSTI]

potential than emissions in the United States to perturb the global oxidizing power of the atmosphere. #12% of NOx concentrations in the lower and middle troposphere throughout the extratropical northern of the ocean. Sources in the United States are found to contribute about half of the fossil fuel NOx over

Jacob, Daniel J.

65

Measurement and Characterization of NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects...

66

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product  

E-Print Network [OSTI]

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I and angular distributions of CO2 produced by CO oxidation on Rh 111 have been measured as a function a fundamental and a practical point of view. CO2 formation serves as a model recombina- tion reaction

Sibener, Steven

67

NETL: Advanced NOx Emissions Control: Control Technology - NOx Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emissions from Multi-Burners Emissions from Multi-Burners The University of Utah working with Reaction Engineering International and Brigham Young University is investigating a project that consists of integrated experimental, theoretical and computational modeling efforts. The primary objective is to evaluate NOx formation/destruction processes as they occur in multi-burner arrays, a geometry almost always utilized in utility practice. Most controlled experimental work examining NOx has been conducted on single burners. The range of potential intra-burner interactions are likely to provide added degrees of freedom for reducing NOx. The resultant findings may allow existing utilities to arrange fuel and air distribution to minimize NOx. In new applications, orientation of individual burners within an array may also be altered to reduce NOx. Comprehensive combustion codes will be modified to incorporate the latest submodels of nitrogen release and heterogeneous chemistry. Comparison of pilot scale experiments and simulations will be utilized to validate/develop theory.

68

Oxidative Degradation of Trichloroethylene Adsorbed on Active Carbons: Use of Microwave Energy  

E-Print Network [OSTI]

OXIDATIVE DEGRADATION OF TRICHLOROETHYLENE ADSORBED ON ACTIVE CARBONS: USE OF MICROWAVE ENERGY R. VARMA, S. P. NANDI, D. CLEAVELAND, K. M. MYLES, D. R. VISSERS, AND P. A. NELSON Chemist Chemical Technology Division Argonne National... Laboratory Argonne, Illinois ABSTRACT Trichloroethylene (TCE) adsorbed on different types of active carbons was exposed to a dry and moist air stream in the presence of 2.45 GHz micro wave radiation. Active carbon beds were used becauae they absorb...

Varma, R.; Nandi, S. P.; Cleaveland, D.; Myles, K. M.; Vissers, D. R.; Nelson, P. A.

69

Carbon contamination and oxidation of Au surfaces under extreme ultraviolet radiation: An x-ray photoelectron spectroscopy study  

E-Print Network [OSTI]

Carbon contamination and oxidation of Au surfaces under extreme ultraviolet radiation: An x 2012) Extreme ultraviolet (EUV) radiation-induced carbon contamination and oxidation of Au surfaces modification during EUV exposure. XPS analysis showed that total carbon contamination (C 1s peak

Harilal, S. S.

70

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2: Implications for inversion analyses  

E-Print Network [OSTI]

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2 carbon emissions. We used TransCom3 annual mean simulations from three transport models to evaluate carbon emission and oxidation processes in deriving inversion estimates of CO2 surface fluxes. Citation

Krakauer, Nir Y.

71

Compact Potentiometric NOx Sensor | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Potentiometric NOx Sensor Compact Potentiometric NOx Sensor 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

72

9, 11231155, 2009 Lightning NOx  

E-Print Network [OSTI]

of lightning intensities. By im-20 posing an updated lightning NO production value of 520 mol NO/Flash, weACPD 9, 1123­1155, 2009 Lightning NOx emissions over the USA investigated using TES L. Jourdain et to the corresponding final paper in ACP if available. Lightning NOx emissions over the USA investigated using TES, NLDN

73

Natural Oxidation of Black Carbon in Soils: Changes in Molecular...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon in Soils: Changes in Molecular Form and Surface Charge along a Climosequence. Abstract: The aim of this work was to investigate changes in molecular form and surface...

74

Nox1 and Nox4 enzymes are persistently elevated in human hepatocytes producing infectious hepatitis C virus  

E-Print Network [OSTI]

location of NOX4 and NOX1 enzymes by cell fractionation. 6.13. Proposed role of hepatocyte NOX enzymes in HCV-inducedMERCED Nox1 and Nox4 enzymes are persistently elevated in

Reyes de Mochel, Nabora Soledad

2009-01-01T23:59:59.000Z

75

Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. lm04paulauskas.pdf More Documents & Publications Advanced Oxidation & Stabilization of...

76

Recent trends in the microwave-assisted synthesis of metal oxide nanoparticles supported on carbon nanotubes and their applications  

Science Journals Connector (OSTI)

The study of coating carbon nanotubes with metal/oxides nanoparticles is now becoming a promising and challenging area of research. To optimize the use of carbon nanotubes in various applications, it is necessary to attach functional groups or other ...

Sarah C. Motshekga; Sreejarani K. Pillai; Suprakas Sinha Ray; Kalala Jalama; Rui. W. M. Krause

2012-01-01T23:59:59.000Z

77

Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms  

E-Print Network [OSTI]

Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

Martin, Katherine C.

2007-01-01T23:59:59.000Z

78

Reduction of iron-oxide-carbon composites: part I. Estimation of the rate constants  

SciTech Connect (OSTI)

A new ironmaking concept using iron-oxide-carbon composite pellets has been proposed, which involves the combination of a rotary hearth furnace (RHF) and an iron bath smelter. This part of the research focuses on studying the two primary chemical kinetic steps. Efforts have been made to experimentally measure the kinetics of the carbon gasification by CO{sub 2} and wustite reduction by CO by isolating them from the influence of heat- and mass-transport steps. A combined reaction model was used to interpret the experimental data and determine the rate constants. Results showed that the reduction is likely to be influenced by the chemical kinetics of both carbon oxidation and wustite reduction at the temperatures of interest. Devolatilized wood-charcoal was observed to be a far more reactive form of carbon in comparison to coal-char. Sintering of the iron-oxide at the high temperatures of interest was found to exert a considerable influence on the reactivity of wustite by virtue of altering the internal pore surface area available for the reaction. Sintering was found to be predominant for highly porous oxides and less of an influence on the denser ores. It was found using an indirect measurement technique that the rate constants for wustite reduction were higher for the porous iron-oxide than dense hematite ore at higher temperatures (> 1423 K). Such an indirect mode of measurement was used to minimize the influence of sintering of the porous oxide at these temperatures.

Halder, S.; Fruehan, R.J. [Praxair Inc., Tonawanda, NY (United States). Technological Center

2008-12-15T23:59:59.000Z

79

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

80

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Metal catalyzed copolymerization processes involving carbon oxides as substrates  

E-Print Network [OSTI]

backbone and electron donating tert-butyl groups in the phenolate rings. This catalyst was used to investigate the effect of altering the nature of the cocatalyst and its concentration. The coupling of carbon monoxide and aziridines has been shown...

Phelps, Andrea Lee

2005-11-01T23:59:59.000Z

82

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, First quarter 1991  

SciTech Connect (OSTI)

This project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 (LS-2) located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This quarterly update provides a description of the flow modeling study. This modeling effort centers on evaluating the in-furnace flow and mixing phenomena for the various low NOx firing systems being demonstrated at LS-2. Testing on the 1/12 scale model of the LS-2 boiler and the 1/6 scale model of the overfire air ductwork was completed. The test matrix included an analysis of the overfire air ductwork and three different boiler configurations. This report also contains results from the Phase 1 baseline tests. Data from the diagnostic, performance, and verification tests are presented. In addition, NOx emissions data and unit load profiles collected during long-term testing are reported. At the full load condition, the baseline NOx emission level at LS-2 is 0.62 lb/mBtu.

Not Available

1991-12-31T23:59:59.000Z

83

Graphene Oxide as an Electrophile for Carbon Nucleophiles  

E-Print Network [OSTI]

The covalent, surface functionalization of graphene oxide with the malononitrile anion has been demonstrated. Once installed, these surface-bound “molecular lynchpins” can be chemically modified to increase the solubility ...

Swager, Timothy Manning

84

Oxidation of Carbon Monoxide in Cell Extracts of Pseudomonas carboxydovorans  

Science Journals Connector (OSTI)

...Winzer. 1932. Uber die Bildung von Essigsaure bei der biologischen Umsetzung von Kohlenoxyd und Kohlensaure mit Wasserstoff zu Methan. Biochem. Z. 245:2-12. 9. Fuchs, G., G. Andress, and R. K. Thauer. 1975. CO- oxidation by anaerobic...

Ortwin Meyer; Hans G. Schlegel

1979-02-01T23:59:59.000Z

85

180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Technical progress report, Third quarter 1992  

SciTech Connect (OSTI)

The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving 50% NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level 1 long-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

Not Available

1992-12-31T23:59:59.000Z

86

Preparation and oxidation resistance of mullite/SiC coating for carbon materials at 1150 °C  

Science Journals Connector (OSTI)

To protect carbon materials from oxidation, mullite/SiC coatings were prepared on graphite by chemical vapor reaction (CVR) and slurry sintering. The XRD analyses show that the phase of the outer-layer coating is composed of SiO2 and mullite, and the inner-layer coating is mainly composed of ?-SiC. The anti-oxidation behavior of the coating and the Rockwell hardness (HRB) of the coating after oxidation were investigated. The oxidation test shows that the as-prepared multi-layer coating exhibits excellent anti-oxidation and thermal shock resistance at high temperature. After oxidation at 1150 °C for 109 h and thermal shock cycling between 1150 °C and room temperature for 12 times, the mass gain of the coated sample is 0.085%. Meanwhile, the indentation tests also demonstrate that the as-prepared coating has good bonding ability between the layers.

Xin YANG; Zhe-an SU; Qi-zhong HUANG; Li-yuan CHAI

2012-01-01T23:59:59.000Z

87

The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NOx) Emissions From Coal-Fired Boilers Demonstration Project: A DOE Assessment  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 2 The Advanced Tangentially Fired Combustion Techniques for the Reduction of Nitrogen Oxides (NO ) Emissions From Coal-Fired Boilers X Demonstration Project: A DOE Assessment March 2000 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

88

Flow reactor experiments on the selective non-catalytic removal of nitrogen oxides  

E-Print Network [OSTI]

?CO, and H, O are initially present in exhaust stream [57]. .. . . . 42 Fig. 21 Fig. 22 Reaction path diagram for RAPRENOx process [63]. .. . Reduction of nitric oxide as a function of temperature, concentration of oxygen, carbon monoxide, and water... the influence of carbon monoxide [89]. . . . . . . . . 58 Fig. 28 Effect of residence time on the NOxOUT process as a function of temperature, NO(initial)=125ppm, 0-ratio of 4 [90]. .. . . . . . . . . . . . . . . 60 Fig. 29 Ammonia slip as a function...

Gentemann, Alexander M.G.

2001-01-01T23:59:59.000Z

89

NOx Sensor Development  

Broader source: Energy.gov (indexed) [DOE]

zirconia (PSZ) for better mechanical properties * (bottom) Dense LSM (Strontium-doped lanthanum manganite oxide) with yttria fully- stabilized zirconia (YSZ) for...

90

NETL: Advanced NOx Emissions Control: Control Technology - Optimized Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optimized Fuel Injector Design Optimized Fuel Injector Design This project includes fundamental research and engineering development of low NOx burners and reburning fuel injectors. The team of Reaction Engineering International (REI), the University of Utah, Brown University and DB Riley, Inc., will develop fundamental information on low NOx burners. The work has two phases. In the first phase, the University of Utah will examine two-phase mixing and near-field behavior of coal injectors using a 15-million Btu/hr bench-scale furnace, Brown University will examine char deactivation and effectiveness of reburning, and REI will develop a comprehensive burner model using the data produced by the University of Utah and Brown University. In the second phase, an optimized injector design will be tested at the 100-million Btu/hr Riley Coal Burner Test Facility. It is anticipated that this work will provide improved hardware designs and computer simulation models for reduced NOx emissions and minimized carbon loss.

91

Preparation of activated carbon from date pits: Effect of the activation agent and liquid phase oxidation  

Science Journals Connector (OSTI)

Two series of activated carbons have been prepared from date pits; series C, using carbon dioxide as activating agent, and series S, prepared by activation with steam under the same experimental conditions. The obtained samples were oxidized with nitric acid in order to introduce more oxygen surface groups. The surface area and porosity of the parent and oxidized activated carbons were studied by N2 adsorption at 77 K and CO2 adsorption at 273 K. The oxygen surface complexes were characterized by temperature-programmed decomposition (TPD). The results show that carbon dioxide and steam activations produce microporous carbons with an increasing amount of CO evolving groups when increasing the burn-off. On the other hand, oxidation with nitric acid increases the amount of CO and CO2 evolved by the decomposition of surface oxygen groups, this increase being related to the development of porosity in the carbon with the degree of activation and to the activating agent used (CO2 versus steam).

Meriem Belhachemi; Rachel V.R.A. Rios; Fatima Addoun; Joaquín Silvestre-Albero; Antonio Sepúlveda-Escribano; Francisco Rodríguez-Reinoso

2009-01-01T23:59:59.000Z

92

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transient Dynamometer Testing of a Single Leg NOx Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single Leg NOx Adsorber...

93

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Development of Chemical Kinetic Models for Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps...

94

EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire  

Broader source: Energy.gov (indexed) [DOE]

472: Commercial Demonstration fo the Low Nox Burner/Separated 472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas EA-1472: Commercial Demonstration fo the Low Nox Burner/Separated Over-Fire Air (LNB/SOFA) Integration System Emission Reduction Technology, Holcolm Station, Sunflower Electric Power Corporation Finnety County, Kansas SUMMARY The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas.

95

Transformation of carbon monoxide dimer surface structures on yttrium oxide modified by silver  

SciTech Connect (OSTI)

It has been established that introducing ions of silver(II) in yttrium(III) oxide leads to the formation of a significant concentration of a paramagnetic dimer species (CO)/sub 2/-in the course of the adsorption of carbon monoxide, and that these dimers exhibit high thermal stability and reactivity. Reactions are proposed for the formation of the dimer species (CO)/sub 2//sup 2 -/ and (CO)/sub 2//sup -/ on the surface of the Ag/Y/sub 2/O/sub 3/ catalyst that involve the reduction of the anion vacancies and a change in the oxidation state of the silver ions. Modifying the yttrium oxide with ionic silver leads to a marked decrease in the strength of the oxidative ability of the surface of the catalyst for CO, while the nature of the active sites of the yttrium oxide, which adsorbs CO in three forms, remains unchanged.

Vydrin, S.N.; Bobolev, A.V.; Loginov, A.Yu.

1987-09-10T23:59:59.000Z

96

Adaptable Silicon–Carbon Nanocables Sandwiched between Reduced Graphene Oxide Sheets as Lithium Ion Battery Anodes  

Science Journals Connector (OSTI)

Adaptable Silicon–Carbon Nanocables Sandwiched between Reduced Graphene Oxide Sheets as Lithium Ion Battery Anodes ... Despite rapidly growing interest in the application of graphene in lithium ion batteries, the interaction of the graphene with lithium ions and electrolyte species during electrochemical cycling is not fully understood. ...

Bin Wang; Xianglong Li; Xianfeng Zhang; Bin Luo; Meihua Jin; Minghui Liang; Shadi A. Dayeh; S. T. Picraux; Linjie Zhi

2013-01-02T23:59:59.000Z

97

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux and  

E-Print Network [OSTI]

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux significant sink that regulates methane flux from sediments into the oceans and atmosphere. Here we examine mesophilic to thermophilic AOM in hydro- thermal sediments recovered from the Middle Valley vent field

Girguis, Peter R.

98

Carbon Nanotube/Manganese Oxide Ultrathin Film Electrodes for Electrochemical Capacitors  

Science Journals Connector (OSTI)

Multiwall carbon nanotube (MWNT)/manganese oxide (MnO2) nanocomposite ultrathin film electrodes have been created via redox deposition of MnO2 on layer-by-layer (LbL)-assembled MWNT films. We demonstrate that these LbL-assembled MWNT (LbL-MWNT)/MnO2 thin ...

Seung Woo Lee; Junhyung Kim; Shuo Chen; Paula T. Hammond; Yang Shao-Horn

2010-06-16T23:59:59.000Z

99

Oxidation of carbon fiber surfaces for use as reinforcement in high-temperature cementitious material systems  

DOE Patents [OSTI]

The interfacial bond characteristics between carbon fiber and a cement matrix, in high temperature fiber-reinforced cementitious composite systems, can be improved by the oxidative treatment of the fiber surfaces. Compositions and the process for producing the compositions are disclosed. 2 figs.

Sugama, Toshifumi.

1990-05-22T23:59:59.000Z

100

Oxidation of carbon fiber surfaces for use as reinforcement in high-temperature cementitious material systems  

DOE Patents [OSTI]

The interfacial bond characteristics between carbon fiber and a cement matrix, in high temperature fiber-reinforced cementitious composite systems, can be improved by the oxidative treatment of the fiber surfaces. Compositions and the process for producing the compositions are disclosed.

Sugama, Toshifumi (Mastic Beach, NY)

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Control of NOx by combustion process modifications  

E-Print Network [OSTI]

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

102

The effect of inhibitors on material and mechanical properties of oxidized carbon-carbon composites  

E-Print Network [OSTI]

oscillator techniques (PUCOT). An analytical diffusion model is developed to predict composite degradation for given exposure conditions, and these results are compared with the experimental data generated. Oxidation specimens are trimmed from a single C...

Elliott, Charles Howard

2012-06-07T23:59:59.000Z

103

N-nitrosamine and N-nitramine Formation from NOx Reactions with Amines during Amine-Based CO2  

E-Print Network [OSTI]

Capture for Post-combustion Carbon Sequestration Background! Generation of electricity and heat from power- combustion carbon sequestration, the capture and underground storage of CO2 from the exhaust gases of power formation from NOx reactions with amines during amine-based carbon dioxide capture for postcombustion carbon

Mitch, William A.

104

Infrared spectroscopic study of the adsorption of carbon monoxide on silica-supported copper oxide  

SciTech Connect (OSTI)

Adsorption of carbon monoxide at room temperature (0.1 to 50 Torr) on silica-supported copper oxide was studied by infrared spectroscopy. Catalysts were prepared by deposition-precipitation or impregnation. After calcination two types of adsorbed CO were identified showing absorption bands at 2136 +- 3 and 2204 +- 1 cm/sup -1/, which are ascribed to CO adsorbed on copper(II) oxide and on isolated copper(II) ions in the silica surface, respectively. Reduction and reoxidation removed the band at 2204 cm/sup -1/ with all samples and raised the intensity of the 2136-cm/sup -1/ band with the precipitated catalysts but not with the impregnation catalyst. Evidence is brought forward that the isolated copper ions are mobilized during reduction and generate new copper (oxide) surface. The change in background transmission of the samples could be used to obtain further information about the interaction of O/sub 2/ and CO with copper oxide.

De Jong, K.P.; Geus, J.W.; Joziasse, J.

1980-10-01T23:59:59.000Z

105

Electro-catalytic oxidation device for removing carbon from a fuel reformate  

DOE Patents [OSTI]

An electro-catalytic oxidation device (ECOD) for the removal of contaminates, preferably carbonaceous materials, from an influent comprising an ECOD anode, an ECOD cathode, and an ECOD electrolyte. The ECOD anode is at a temperature whereby the contaminate collects on the surface of the ECOD anode as a buildup. The ECOD anode is electrically connected to the ECOD cathode, which consumes the buildup producing electricity and carbon dioxide. The ECOD anode is porous and chemically active to the electro-catalytic oxidation of the contaminate. The ECOD cathode is exposed to oxygen, and made of a material which promotes the electro-chemical reduction of oxygen to oxidized ions. The ECOD electrolyte is non-permeable to gas, electrically insulating and a conductor to oxidized. The ECOD anode is connected to the fuel reformer and the fuel cell. The ECOD electrolyte is between and in ionic contact with the ECOD anode and the ECOD cathode.

Liu, Di-Jia (Naperville, IL)

2010-02-23T23:59:59.000Z

106

Using carbon adsorbents for removing nitrogen oxides and sulphur oxides from flue gases  

Science Journals Connector (OSTI)

The use of carbon adsorbents in industrial power engineering outside Russia is briefly reviewed and the results of our own experimental investigations, made in the laboratory and at a pilot commercial installation, are given. The proposal to use the described device in a KE-25-24-C industrial boiler is outlined.

A.I. Blokhin; A.N. Nikitin; A.O. Gabibov

2003-01-01T23:59:59.000Z

107

NETL: Advanced NOx Emissions Control: Control Technology - ALTA for Cyclone  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers Full-Scale Demonstration of ALTA NOx Control for Cyclone-Fired Boilers The primary goal of this project was to evaluate a technology called advanced layered technology application (ALTA) as a means to achieve NOx emissions below 0.15 lb/MMBtu in a cyclone boiler. Reaction Engineering International (REI) conducted field testing and combustion modeling to refine the process design, define the optimum technology parameters, and assess system performance. The ALTA NOx control technology combines deep staging from overfire air, rich reagent injection (RRI), and selective non-catalytic reduction (SNCR). Field testing was conducted during May-June 2005 at AmerenUE's Sioux Station Unit 1, a 500 MW cyclone boiler unit that typically burns an 80/20 blend of Powder River Basin subbituminous coal and Illinois No. 6 bituminous coal. Parametric testing was also conducted with 60/40 and 0/100 blends. The testing also evaluated process impacts on balance-of-plant issues such as the amount of unburned carbon in the ash, slag tapping, waterwall corrosion, ammonia slip, and heat distribution.

108

A Ni-Fe Layered Double Hydroxide-Carbon Nanotube Complex for Water Oxidation  

E-Print Network [OSTI]

Highly active, durable and cost-effective electrocatalysts for water oxidation to evolve oxygen gas hold a key to a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel iron layered double hydroxide nanoplates on mildly oxidized multi-walled carbon nanotubes. Incorporation of Fe into the nickel hydroxide induced the formation of NiFe-layered double hydroxide. The nanoplates were covalently attached to a network of nanotubes, affording excellent electrical wiring to the nanoplates. The ultra-thin Ni-Fe layered double hydroxide nanoplates/carbon nanotube complex was found to exhibit unusually high electro-catalytic activity and stability for oxygen evolution and outperformed commercial precious metal Ir catalysts.

Gong, Ming; Wang, Hailiang; Liang, Yongye; Wu, Justin Zachary; Zhou, Jigang; Wang, Jian; Regier, Tom; Wei, Fei; Dai, Hongjie

2013-01-01T23:59:59.000Z

109

Structure and Oxidation Activity Correlations for Carbon Blacks and Diesel Soot  

Science Journals Connector (OSTI)

This work focuses on a comprehensive investigation of structure–activity relationships for a diesel engine soot sample (Corning) and 10 commercially available carbon black samples. ... Su and colleagues used high-resolution transmission electron microscopy (HRTEM) and thermogravimetric analysis (TGA) to study the relation between the microstructure and oxidation behavior of soot from exhausts of different heavy-duty diesel engines and discovered the microstructure-controlled oxidation behavior of diesel soot. ... FE-SEM images (see Figure S1 of the Supporting Information) of some carbon blacks (Monarch 1400, Monarch 280, and Printex-U) and diesel soot-1 show the agglomerates, which are composed of their fundamental units called primary particles. ...

Lakshitha Pahalagedara; Hom Sharma; Chung-Hao Kuo; Saminda Dharmarathna; Ameya Joshi; Steven L. Suib; Ashish B. Mhadeshwar

2012-10-11T23:59:59.000Z

110

The removal of uranium(VI) from aqueous solution by graphene oxide–carbon nanotubes hybrid aerogels  

Science Journals Connector (OSTI)

Novel graphene oxide–carbon nanotubes (GO–CNTs) hybrid aerogels were fabricated via a freeze-drying method ... solutions of GO and CNTs. The resulting aerogels were characterized by scanning electron microscopy, ...

Zexing Gu; Yun Wang; Jun Tang; Jijun Yang…

2014-11-01T23:59:59.000Z

111

A comparative study of polyethylene oxide/nanoclay composite preparation via supercritical carbon dioxide and melt processing  

Science Journals Connector (OSTI)

The efficacy of supercritical carbon dioxide (ScCO2...) treatment compared with conventional melt processing methods in preparing nanoclay composites from poly(ethylene oxide) (PEO)...2 processing yielded more ho...

Gordon Armstrong; Keith Fortune

2007-10-01T23:59:59.000Z

112

Emissions of carbon dioxide, methane and nitrous oxide from soil receiving urban wastewater for maize (Zea mays L.) cultivation  

Science Journals Connector (OSTI)

We investigated how amending maize with wastewater at 120 kg N ha?1 affected crop growth, soil characteristics and emissions of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) compared to plants ferti...

Fabián Fernández-Luqueño; Verónica Reyes-Varela…

2010-06-01T23:59:59.000Z

113

Carbon dioxide adsorbents containing magnesium oxide suitable for use at high temperatures  

DOE Patents [OSTI]

Adsorption of carbon dioxide from gas streams at temperatures in the range of 300 to 500.degree. C. is carried out with a solid adsorbent containing magnesium oxide, preferably promoted with an alkali metal carbonate or bicarbonate so that the atomic ratio of alkali metal to magnesium is in the range of 0.006 to 2.60. Preferred adsorbents are made from the precipitate formed on addition of alkali metal and carbonate ions to an aqueous solution of a magnesium salt. Atomic ratios of alkali metal to magnesium can be adjusted by washing the precipitate with water. Low surface area adsorbents can be made by dehydration and CO.sub.2 removal of magnesium hydroxycarbonate, with or without alkali metal promotion. The process is especially valuable in pressure swing adsorption operations.

Mayorga, Steven Gerard (Allentown, PA); Weigel, Scott Jeffrey (Allentown, PA); Gaffney, Thomas Richard (Allentown, PA); Brzozowski, Jeffrey Richard (Macungie, PA)

2001-01-01T23:59:59.000Z

114

The cycling and oxidation pathways of organic carbon in a shallow estuary along the Texas Gulf Coast  

SciTech Connect (OSTI)

The cycling and oxidation pathways of organic carbon were investigated at a single shallow water estuarine site in Trinity Bay, Texas, the uppermost lobe of Galveston Bay, during November 2000. Radio-isotopes were used to estimate sediment mixing and accumulation rates, and benthic chamber and pore water measurements were used to determine sediment-water exchange fluxes of oxygen, nutrients and metals, and infer carbon oxidation rates.

Warnken, Kent W.; Santschi, Peter H.; Roberts, Kimberly A.; Gill, Gary A.

2007-08-08T23:59:59.000Z

115

Inkjet printed ambipolar transistors and inverters based on carbon nanotube/zinc tin oxide heterostructures  

SciTech Connect (OSTI)

We report ambipolar field-effect transistors (FETs) consisting of inkjet printed semiconductor bilayer heterostructures utilizing semiconducting single-walled carbon nanotubes (SWCNTs) and amorphous zinc tin oxide (ZTO). The bilayer structure allows for electron transport to occur principally in the amorphous oxide layer and hole transport to occur exclusively in the SWCNT layer. This results in balanced electron and hole mobilities exceeding 2 cm{sup 2} V{sup ?1} s{sup ?1} at low operating voltages (<5?V) in air. We further show that the SWCNT-ZTO hybrid ambipolar FETs can be integrated into functional inverter circuits that display high peak gain (>10). This work provides a pathway for realizing solution processable, inkjet printable, large area electronic devices, and systems based on SWCNT-amorphous oxide heterostructures.

Kim, Bongjun; Jang, Seonpil; Dodabalapur, Ananth, E-mail: ananth.dodabalapur@engr.utexas.edu [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States); Department of Electrical and Computer Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Geier, Michael L.; Prabhumirashi, Pradyumna L. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Hersam, Mark C. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Department of Chemistry, Northwestern University, Evanston, Illinois 60208 (United States); Department of Medicine, Northwestern University, Evanston, Illinois 60208 (United States)

2014-02-10T23:59:59.000Z

116

NETL: News Release - DOE Selects Five NOx-Control Projects to Combat Acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

November 5, 2004 November 5, 2004 DOE Selects Five NOx-Control Projects to Combat Acid Rain and Smog Industry Partners to Focus on Reducing Emissions While Cutting Energy Costs PITTSBURGH, PA - Continuing efforts to cut acid rain and smog-producing nitrogen oxides (NOx) have prompted the U.S. Department of Energy to partner with industry experts to develop advanced NOx-control technologies. With the selection of five new NOx-control projects, the Energy Department continues as a leader in developing advanced technologies to achieve environmental compliance for the nation's fleet of coal-fired power plants. Although today's NOx-control workhorses, such as low-NOx burners and selective catalytic reduction (SCR), have been successfully deployed to address existing regulations, proposed regulations will require deeper cuts in NOx emissions, at a greater number of generating facilities. Many of the smaller affected plants will not be able to cost-effectively use today's technologies; these are the focus of the advanced technologies selected in this announcement.

117

Advanced furnace air staging and burner modifications for ultra-low NOx firing systems  

SciTech Connect (OSTI)

Overfire air is an effective means to reduce NOx emissions from coal fired furnaces. The current range of overfire air usage on wall-fired boilers in the US is in the range of 10 to 20%. In most cases this is enough to achieve current Title IV NOx reduction requirements. Future applications are likely to go beyond 20% Overfire Air to reduce NOx further for lower investment and operating costs of SCR retrofits. Summer ozone reduction requires NOx emissions of 0.15 lb/MBtu. Currently, industry is exploring the conditions under which this goal is attainable. The paper discussed the approach to achieve ultra-low NOx emissions by using advanced furnace air staging. It describes the unique approach of redesigning the burner to maintain low NOx burner performance when the overfire air system is added or increased in capacity. The impact on furnace corrosion and unburned carbon losses are presented. A case study is used to show the effects of overfire air both on emissions and unburned carbon.

McCarthy, K.; Laux, S.; Grusha, J.

1999-07-01T23:59:59.000Z

118

Carbon Diffusion and Clustering in SiGeC Layers Under Thermal Oxidation D. De Salvador1  

E-Print Network [OSTI]

in order to distinguish the pure thermal effects from those produced by the I injection under oxidationCarbon Diffusion and Clustering in SiGeC Layers Under Thermal Oxidation D. De Salvador1 , E to the formation and growth of C containing precipitates which are promoted by the I injection and act as a sink

119

Electro-oxidized Epitaxial Graphene Channel Field-Effect Transistors with Single-Walled Carbon Nanotube Thin Film  

E-Print Network [OSTI]

Electro-oxidized Epitaxial Graphene Channel Field-Effect Transistors with Single-Walled Carbon on the electronic properties of epitaxial graphene (EG) grown on silicon carbide substrates; we demonstrate the introduction of the reaction medium into the graphene galleries during electro-oxidation. The device

120

Mechanisms of carbon nanotube-induced toxicity: Focus on oxidative stress  

SciTech Connect (OSTI)

Nanotechnologies are emerging as highly promising technologies in many sectors in the society. However, the increasing use of engineered nanomaterials also raises concerns about inadvertent exposure to these materials and the potential for adverse effects on human health and the environment. Despite several years of intensive investigations, a common paradigm for the understanding of nanoparticle-induced toxicity remains to be firmly established. Here, the so-called oxidative stress paradigm is scrutinized. Does oxidative stress represent a secondary event resulting inevitably from disruption of biochemical processes and the demise of the cell, or a specific, non-random event that plays a role in the induction of cellular damage e.g. apoptosis? The answer to this question will have important ramifications for the development of strategies for mitigation of adverse effects of nanoparticles. Recent examples of global lipidomics studies of nanoparticle-induced tissue damage are discussed along with proteomics and transcriptomics approaches to achieve a comprehensive understanding of the complex and interrelated molecular changes in cells and tissues exposed to nanoparticles. We also discuss instances of non-oxidative stress-mediated cellular damage resulting from direct physical interference of nanomaterials with cellular structures. -- Highlights: ? CNT induced non-random oxidative stress associated with apoptosis. ? Non-oxidative mechanisms for cellular toxicity of carbon nanotubes. ? Biodegradation of CNT by cells of innate immune system. ? “Omics”-based biomarkers of CNT exposures.

Shvedova, Anna A., E-mail: ats1@cdc.gov [Pathology and Physiology Research Branch, Health Effects Laboratory Division, National Institute for Occupational Safety and Health, University of Rome “Tor Vergata”, Rome (Italy); Department of Physiology and Pharmacology, West Virginia University, Morgantown, WV, University of Rome “Tor Vergata”, Rome (Italy); Pietroiusti, Antonio [Department of Biopathology, University of Rome “Tor Vergata”, Rome (Italy)] [Department of Biopathology, University of Rome “Tor Vergata”, Rome (Italy); Fadeel, Bengt [Division of Molecular Toxicology, Institute of Environmental Medicine, Karolinska Institutet, Stockholm (Sweden) [Division of Molecular Toxicology, Institute of Environmental Medicine, Karolinska Institutet, Stockholm (Sweden); Department of Environmental and Occupational Health, University of Pittsburgh, Pittsburgh, PA (United States); Kagan, Valerian E. [Department of Environmental and Occupational Health, University of Pittsburgh, Pittsburgh, PA (United States)] [Department of Environmental and Occupational Health, University of Pittsburgh, Pittsburgh, PA (United States)

2012-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Reduction of iron-oxide-carbon composites: part III. Shrinkage of composite pellets during reduction  

SciTech Connect (OSTI)

This article involves the evaluation of the volume change of iron-oxide-carbon composite pellets and its implications on reduction kinetics under conditions prevalent in a rotary hearth furnace (RHF) that were simulated in the laboratory. The pellets, in general, were found to shrink considerably during the reduction due to the loss of carbon and oxygen from the system, sintering of the iron-oxide, and formation of a molten slag phase at localized regions inside the pellets due to the presence of binder and coal/wood-charcoal ash at the reduction temperatures. One of the shortcomings of the RHF ironmaking process has been the inability to use multiple layers of composite pellets because of the impediment in heat transport to the lower layers of a multilayer bed. However, pellet shrinkage was found to have a strong effect on the reduction kinetics by virtue of enhancing the external heat transport to the lower layers. The volume change of the different kinds of composite pellets was studied as a function of reduction temperature and time. The estimation of the change in the amount of external heat transport with varying pellet sizes for a particular layer of a multilayer bed was obtained by conducting heat-transfer tests using inert low-carbon steel spheres. It was found that if the pellets of the top layer of the bed shrink by 30 pct, the external heat transfer to the second layer increases by nearly 6 times.

Halder, S.; Fruehan, R.J. [Praxair Inc., Tonawanda, NY (United States). Praxair Technological Center

2008-12-15T23:59:59.000Z

122

Investigation of coal char-slag transition during oxidation: effect of temperature and residual carbon  

SciTech Connect (OSTI)

The transition of coal char to molten slag at high conversion was studied for a bituminous coal using a laminar entrained-flow reactor under oxidizing conditions. Post-oxidized char particles were analyzed by various techniques including loss-on-ignition, gas adsorption analysis, and scanning electron microscopy to determine carbon content, internal surface area and pore size distribution, and char morphology, respectively. These analyses provide information concerning the effect of temperature and residual carbon on the transition from porous char to molten slag. Results showed that, at temperatures above the ash flow temperature, the transition from porous char to molten slag occurred at about 90% conversion for the coal used in this study. No transition occurred at temperatures below the ash flow temperature. This finding explains previous observations that there is a coal-dependent critical carbon conversion at which the ash stickiness increases dramatically. This result also indicates that surface area can be used as a criterion for determining the critical conversion of the transition. In addition, it was found that the randomly overlapping pore model cannot be directly applied to predict the surface area evolution of char particles during the transition without considering the reopening of closed micropores during the initial reaction and the ash fusion effect. 33 refs., 9 figs., 2 tabs.

Suhui Li; Kevin J. Whitty [University of Utah, Salt Lake City, UT (United States). Institute for Clean and Secure Energy

2009-04-15T23:59:59.000Z

123

NETL: Advanced NOx Emissions Control: Control Technology - Ultra Low-NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultra Low NOx Integrated System Ultra Low NOx Integrated System TFS 2000(tm) Low NOx Firing System Project Summary: ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important,

124

LOW NOx EMISSIONS IN A FUEL FLEXIBLE GAS TURBINE  

SciTech Connect (OSTI)

In alignment with Vision 21 goals, a study is presented here on the technical and economic potential for developing a gas turbine combustor that is capable of generating less that 2 ppm NOx emissions, firing on either coal synthesis gas or natural gas, and being implemented on new and existing systems. The proposed solution involves controlling the quantity of H2 contained in the fuel. The presence of H2 leads to increased flame stability such that the combustor can be operated at lower temperatures and produce less thermal NOx. Coal gas composition would be modified using a water gas shift converter, and natural gas units would implement a catalytic partial oxidation (CPOX) reactor to convert part of the natural gas feed to a syngas before fed back into the combustor. While both systems demonstrated technical merit, the economics involved in implementing such a system are marginal at best. Therefore, Praxair has decided not to pursue the technology any further at this time.

Raymond Drnevich; James Meagher; Vasilis Papavassiliou; Troy Raybold; Peter Stuttaford; Leonard Switzer; Lee Rosen

2004-08-01T23:59:59.000Z

125

CLEERS Activities: Diesel Soot Filter Characterization & NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Control Fundamentals CLEERS Activities: Diesel Soot Filter Characterization & NOx Control Fundamentals 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit...

126

Electroless Deposition of Conformal Nanoscale Iron Oxide on Carbon Nanoarchitectures for Electrochemical Charge Storage  

Science Journals Connector (OSTI)

iron oxide; electrochemical capacitor; battery; charge storage; pseudocapacitance; aerogel ... To retain the through-connected aperiodic pore structure of the native carbon nanofoam and to avoid build-up of thick FeOx coatings on the exterior of the nanofoam, it is imperative to identify deposition conditions where the FeOx precursor, in this case K2FeO4, reacts preferentially with the carbon until the resulting FeOx coating passivates the surface to further reaction, while also minimizing extraneous reactions in solution that may result in FeOx precipitates and/or thick exterior coatings. ... As would be expected for incorporation of FeOx coatings within the bare carbon nanofoam interior, the mean pore size and total pore volume decreased with longer FeOx deposition times (and concomitant higher FeOx weight loadings), as shown in Table 1 and Figure 4B. Pore-size distribution plots generated from the isotherm data show that the width of the pores gradually shifts to smaller sizes with increasing FeOx content, yet even the 40-h FeOx-coated carbon nanofoam retains a through-connected pore network, with pore sizes ranging from ca. 3?15 nm. ...

Megan B. Sassin; Azzam N. Mansour; Katherine A. Pettigrew; Debra R. Rolison; Jeffrey W. Long

2010-07-19T23:59:59.000Z

127

Mixed Fuel Strategy for Carbon Deposition Mitigation in Solid Oxide Fuel Cells at Intermediate Temperatures  

Science Journals Connector (OSTI)

Mixed Fuel Strategy for Carbon Deposition Mitigation in Solid Oxide Fuel Cells at Intermediate Temperatures ... (1-4) Although the concept of SOFCs was first reported more than one century ago,(5) major technological advances in cell materials, reactor configuration, operation mode, and balance of plant system integration and optimization were realized in the last 20–30 years only. ... The hybrid start-up process is optimized with respect to a specific setup as an example, but is of general nature and utility to similar systems. ...

Chao Su; Yubo Chen; Wei Wang; Ran Ran; Zongping Shao; João C. Diniz da Costa; Shaomin Liu

2014-05-23T23:59:59.000Z

128

Efficient catalytic wet oxidation of phenol using iron acetylacetonate complexes anchored on carbon nanofibres  

Science Journals Connector (OSTI)

Iron acetylacetonate complexes anchored on oxidized carbon nanofibres (CNFs) were prepared by a three steps procedure: (i) oxidation of commercial \\{CNFs\\} by treatment with HNO3, (ii) synthesis of acetylacetonate (acac) functional groups on the oxidized \\{CNFs\\} surfaces (acac/CNFs) and (iii) iron ions complexation on the acac sites of the \\{CNFs\\} (Fe-acac/CNFs). The surface groups exposed on the functionalized \\{CNFs\\} were characterized by using attenuated total reflectance Fourier transform infrared spectroscopy, temperature programmed desorption, thermogravimetric analysis and X-ray photoelectron spectroscopy. The functionalized \\{CNFs\\} and the iron complexes anchored on the \\{CNFs\\} were tested as heterogeneous catalysts for the wet oxidation of phenol with pure oxygen. Complete phenol conversion and high mineralization values were achieved with fresh and reused Fe-acac/CNFs catalysts, which demonstrate the improved stability of the catalysts under the phenol degradation reaction conditions. Furthermore these conditions are comparatively mild, typically 413 K of reaction temperature and 2.0 MPa of oxygen pressure.

M. Soria-Sánchez; A. Maroto-Valiente; J. Álvarez-Rodríguez; I. Rodríguez-Ramos; A. Guerrero-Ruíz

2009-01-01T23:59:59.000Z

129

NETL: Advanced NOx Emissions Control: Control Technology - NOx Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Control Options and Integration Control Options and Integration Reaction Engineering International (REI) is optimizing the performance of, and reduce the technical risks associated with the combined application of low-NOx firing systems (LNFS) and post combustion controls through modeling, bench-scale testing, and field verification. Teaming with REI are the University of Utah and Brown University. During this two-year effort, REI will assess real-time monitoring equipment to evaluate waterwall wastage, soot formation, and burner stoichiometry, demonstrate analysis techniques to improve LNFS in combination with reburning/SNCR, assess selective catalytic reduction catalyst life, and develop UBC/fly ash separation processes. The REI program will be applicable to coal-fired boilers currently in use in the United States, including corner-, wall-, turbo-, and cyclone-fired units. However, the primary target of the research will be cyclone boilers, which are high NOx producing units and represent about 20% of the U.S. generating capacity. The results will also be applicable to all U.S. coals. The research will be divided into four key components:

130

Recovery of iron, carbon and zinc from steel plant waste oxides using the AISI-DOE postcombustion smelting technology  

SciTech Connect (OSTI)

This report describes a process to recover steel plant waste oxides to be used in the production of hot metal. The process flowsheet used at the pilot plant. Coal/coke breeze and iron ore pellets/waste oxides are charged into the smelting reactor. The waste oxides are either agglomerated into briquettes (1 inch) using a binder or micro-agglomerated into pellets (1/4 inch) without the use of a binder. The iron oxides dissolve in the slag and are reduced by carbon to produce molten iron. The gangue oxides present in the raw materials report to the slag. Coal charged to the smelter is both the fuel as well as the reductant. Carbon present in the waste oxides is also used as the fuel/reductant resulting in a decrease in the coal requirement. Oxygen is top blown through a central, water-cooled, dual circuit lance. Nitrogen is injected through tuyeres at the bottom of the reactor for stirring purposes. The hot metal and slag produced in the smelting reactor are tapped at regular intervals through a single taphole using a mudgun and drill system. The energy requirements of the process are provided by (i) the combustion of carbon to carbon monoxide, referred to as primary combustion and (ii) the combustion of CO and H{sub 2} to CO{sub 2} and H{sub 2}O, known as postcombustion.

Sarma, B. [Praxair, Inc., Tarrytown, NY (United States); Downing, K.B. [Fluor Daniel, Greenville, SC (United States); Aukrust, E.

1996-09-01T23:59:59.000Z

131

Transmural Catalysis - High Efficiency Catalyst Systems for NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation...

132

SCR Technologies for NOx Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technologies for NOx Reduction SCR Technologies for NOx Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deerhesser.pdf More...

133

An Improvement of Diesel PM and NOx Reduction System | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Development on simultaneous reduction system of NOx and PM from a diesel engine An Improvement of Diesel PM and NOx Reduction System New Diesel Emissions...

134

Development on simultaneous reduction system of NOx and PM from...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications An Improvement of Diesel PM and NOx Reduction System An Improvement of Diesel PM and NOx Reduction System EPA Mobile Source Rule Update...

135

Passive Catalytic Approach to Low Temperature NOx Emission Abatement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

136

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Three-Dimensional Composite Nanostructures for Lean NOx Emission Control 2010 DOE Vehicle Technologies and...

137

Effect of Biodiesel Blends on NOx Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Blends on NOx Emissions Effect of Biodiesel Blends on NOx Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

138

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor...

139

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells...

140

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Modeling the Regeneration Chemistry of Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored...

142

Electrochemical NOxSensor for Monitoring Diesel Emissions | Department...  

Broader source: Energy.gov (indexed) [DOE]

Diesel Emissions Electrochemical NOxSensor for Monitoring Diesel Emissions pm02glass.pdf More Documents & Publications Electrochemical NOx Sensor for Monitoring Diesel...

143

Field emission effects of nitrogenated carbon nanotubes on chlorination and oxidation  

SciTech Connect (OSTI)

With reference to our recent reports [Appl. Phys. Lett. 90, 192107 (2007); Appl. Phys. Lett. 91, 202102 (2007)] about the electronic structure of chlorine treated and oxygen-plasma treated nitrogenated carbon nanotubes (N-CNTs), here we studied the electron field emission effects on chlorination (N-CNT:Cl) and oxidation (N-CNT:O) of N-CNT. A high current density (J) of 15.0 mA/cm{sup 2} has been achieved on chlorination, whereas low J of 0.0052 mA/cm{sup 2} is observed on oxidation compared to J=1.3 mA/cm{sup 2} for untreated N-CNT at an applied electric field E{sub A} of {approx}1.9 V/{mu}m. The turn-on electric field (E{sub TO}) was {approx}0.875. The 1.25 V/{mu}m was achieved for N-CNT:Cl and N-CNT:O, respectively, with respect to E{sub TO}=1.0 V/{mu}m for untreated one. These findings are due to the formation of different bonds with carbon and nitrogen in the N-CNT during the process of chlorine (oxygen)-plasma treatment by the charge transfer, or else that changes the density of free charge carriers and hence enhances (reduces) the field emission properties of N-CNTs:Cl (N-CNTs:O)

Ray, S. C.; Palnitkar, U.; Pao, C. W.; Tsai, H. M.; Pong, W. F.; Lin, I-N. [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China); Papakonstantinou, P. [NRI, School of Electrical and Mechanical Engineering, University of Ulster at Jordanstown, Newtownabbey, County Antrim BT37OQB, Northern Ireland (United Kingdom); Ganguly, Abhijit; Chen, L. C. [Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan (China); Chen, K. H. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China)

2008-09-15T23:59:59.000Z

144

Interaction of copper oxides with reaction medium in heterogeneous catalytic oxidation of carbon monoxide by molecular oxygen. IV. IR spectroscopic study of carbon monoxide interaction with copper oxide surface  

SciTech Connect (OSTI)

An IR spectroscopic study has been made of the interaction of CO with CuO prepared in different ways, and the interaction of O/sub 2/ with carbon monoxide preadsorbed on CuO. A number of Cu/sup +/CO surface complexes have been detected (2114-2148 cm/sup -1/) with a heat of adsorption about 79.5-180 kJ/mole. From an analysis of the nature of these complexes, we have evaluated the processes taking place on the CuO surface when it interacts with CO and have compared the properties of massive CuO with those of CuO on oxide supports. The data are interpreted on the assumption that extended defects - dislocations - exist and play an important role, determining to a considerable degree the properties of the massive CuO in the reaction of CO oxidation.

Lokhov, Y.A.; Popovskii, V.V.; Sadykov, V.A.; Tikhov, S.F.

1985-08-01T23:59:59.000Z

145

Influences of Organic Carbon Supply Rate on Uranium Bioreduction in Initially Oxidizing, Contaminated Sediment  

SciTech Connect (OSTI)

Remediation of uranium (U) contaminated sediments through in-situ stimulation of bioreduction to insoluble UO{sub 2} is a potential treatment strategy under active investigation. Previously, we found that newly reduced U(IV) can be reoxidized under reducing conditions sustained by a continuous supply of organic carbon (OC) because of residual reactive Fe(III) and enhanced U(VI) solubility through complexation with carbonate generated through OC oxidation. That finding motivated this investigation directed at identifying a range of OC supply rates that is optimal for establishing U bioreduction and immobilization in initially oxidizing sediments. The effects of OC supply rate, from 0 to 580 mmol OC (kg sediment){sup -1} year{sup -1}, and OC form (lactate and acetate) on U bioreduction were tested in flow-through columns containing U-contaminated sediments. An intermediate supply rate on the order of 150 mmol OC (kg sediment){sup -1} year{sup -1} was determined to be most effective at immobilizing U. At lower OC supply rates, U bioreduction was not achieved, and U(VI) solubility was enhanced by complexation with carbonate (from OC oxidation). At the highest OC supply rate, resulting highly carbonate-enriched solutions also supported elevated levels of U(VI), even though strongly reducing conditions were established. Lactate and acetate were found to have very similar geochemical impacts on effluent U concentrations (and other measured chemical species), when compared at equivalent OC supply rates. While the catalysts of U(VI) reduction to U(IV) are presumably bacteria, the composition of the bacterial community, the Fe reducing community, and the sulfate reducing community had no direct relationship with effluent U concentrations. The OC supply rate has competing effects of driving reduction of U(VI) to low solubility U(IV) solids, as well as causing formation of highly soluble U(VI)-carbonato complexes. These offsetting influences will require careful control of OC supply rates in order to optimize bioreduction-based U stabilization.

Tokunaga, Tetsu K.; Wan, Jiamin; Kim, Yongman; Daly, Rebecca A.; Brodie, Eoin L.; Hazen, Terry C.; Herman, Don; Firestone, Mary K.

2008-06-10T23:59:59.000Z

146

IEP - Advanced NOx Emissions Control: Regulatory Drivers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEP - Advanced NOx Emissions Control Regulatory Drivers Regulatory Drivers for Existing Coal-Fired Power Plants Regulatory and legislative requirements have predominantly driven the need to develop NOx control technologies for existing coal-fired power plants. The first driver was the Title IV acid rain program, established through the 1990 Clean Air Act Amendments (CAAA). This program included a two-phase strategy to reduce NOx emissions from coal-fired power plants – Phase I started January 1, 1996 and Phase II started January 1, 2000. The Title IV NOx program was implemented through unit-specific NOx emission rate limits ranging from 0.40 to 0.86 lb/MMBtu depending on the type of boiler/burner configuration and based on application of LNB technology.

147

Utilization of computational fluid dynamics technique in low NOx burner/furnace retrofits  

SciTech Connect (OSTI)

A computational fluid dynamics (CFD) technique has been utilized to provide design guidance for retrofitting low NOx combustion systems and incorporating associated furnace modifications into existing utility boilers. The CFD program utilized is FW-FIRES (Fossil fuel, Water-walled Furnace Integrated Reaction and Emission Simulation) which simulates furnace combustion, heat transfer and pollutant formation based on fundamental principals of mass, momentum and energy conservations. The program models the gas flow field as a three-dimensional turbulent reacting continuum and the particle flow as a series of discrete particle trajectories through the gas continuum. Chemical reaction, heat transfer, and pollutant formation mechanisms are incorporated in the program. FW-FIRES furnace simulation of low NOx combustion system retrofits has been performed for various furnace configurations including front wall-fired, front and real wall-fired, and tangentially-fired furnaces, to determine the effects of burner/furnace modifications on the NOx emission, furnace exit gas temperature, furnace heat absorption, unburned carbon, and furnace wall corrosion. For front wall-fired, and front and real wall-fired furnaces, the NOx emission requirement is met by the use of Foster Wheeler lox NOx burners and overfire air (OFA) staging. Studies of burner and OFA quantify and spacing are conducted to limit NOx emission and unburned carbon to acceptable levels. A major concern in once-through supercritical units with OFA is furnace wall corrosion which is caused by high furnace wall metal temperature and corrosive hydrogen sulfide (H{sub 2}S) created in a reducing atmosphere from part of coal sulfur. The FW-FIRES code is used to minimize this corrosion potential by selecting the proper location and quantity of boundary air. A simulation of tangentially-fired unit, which has been retrofitted with low NOx burners, is used to study the effect of the burner tilt on the furnace exit gas temperature. This paper details the basis and results of several CFD analyses conducted for potential retrofit programs.

Cho, S.M.; Seltzer, A.H.; Ma, J.; Steitz, T.H.; Grusha, J.; Cole, R.W.

1999-07-01T23:59:59.000Z

148

Poly(ethylene oxide) Crystallization in Single Walled Carbon Nanotube Based Nanocomposites: Kinetics and Structural Consequences  

SciTech Connect (OSTI)

The overall isothermal crystallization behavior of poly(ethylene oxide) (PEO) in single walled carbon nanotube (SWNT) based nanocomposites is studied with a focus on growth kinetics and morphological evolution of PEO using differential scanning calorimetry and in-situ small angle x-ray scattering measurements respectively. The characteristic time for crystallization of PEO increases due to the presence of lithium dodecyl sulfate (LDS) stabilized carbon nanotubes. Further, analysis of crystallization data using the Lauritzen-Hoffman regime theory of crystal growth shows the PEO chains stiffen in presence of LDS with an increased energy barrier associated with the nucleation and crystal growth, and the nanotubes further act as a barrier to chain transport or enhance the efficacy of the LDS action. The energy penalty and diffusional barrier to chain transport in the nanocomposites disrupt the crystalline PEO helical conformation. This destabilization leads to preferential growth of local nuclei resulting in formation of thinner crystal lamellae and suggests that the crystallization kinetics is strongly affected by the nucleation and crystal growth events. This study is particularly interesting considering the suppression of the PEO crystallinity in presence of small fraction of Lithium ion based surfactant and carbon nanotubes.

T Chatterjee; A Lorenzo; R Krishnamoorti

2011-12-31T23:59:59.000Z

149

Effect of Carbon Deposition on the Oxidation Rate of Copper/Bentonite in the Chemical Looping Process  

SciTech Connect (OSTI)

The presented work is part of the Industrial Carbon Management Initiative (ICMI) on the development of metal oxide oxygen carriers for use in the chemical looping combustion process. An oxygen carrier, CuO/bentonite (60:40%), was reacted with methane gas and then oxidized in air. The change in weight and reaction gas concentrations were measured using a thermogravimetric analyzer (TGA) equipped with a real-time gas analyzer. The reduction–oxidation cycle was conducted within the temperature range of 750–900 °C for 10 cycles, using 20, 50, and100% CH{sub 4} concentrations in N{sub 2} for the reduction segment and dry air for the oxidation segment. Several analysis methods were evaluated to fit the oxidation of reduced CuO (i.e., Cu) data over the complete conversion range with suitable rate expressions derived from existing models for oxidation, including the shrinking core model (diffusion and reaction control), first- and second-order reaction rates, parallel and series reaction mechanisms, and Johnson–Mehl–Avrami (JMA) rate. The best agreement between the experimental data and the models of the Cu oxidation was accomplished using the JMA model. The reactivity of the oxygen carrier during the oxidation reactions was affected by the CH{sub 4} concentration as well as the temperature. The rate of fractional uptake of oxygen onto the carrier decreased as the temperature increased, contrary to expectations and indicative that the mechanism is changing during the test. Analysis of the exit gas provided evidence of carbon deposition on the reduced sorbent particle and resulted in the CO{sub 2} product upon oxidation. The oxidation of this carbon releases significant heat that is capable of changing the particle morphology (Zhu, Y.; Mimura, K.; Isshiki, M. Oxid. Met. 2004, 62, 207?222). On the basis of experimental results, the overall reaction process in the fuel reactor may be considered to consist of the decomposition of CH{sub 4} into C and H{sub 2} and reduction of CuO/bentonite by the resulting H{sub 2} and the parallel reaction of CH{sub 4} with CuO/bentonite. The extent of carbon deposition in the carrier particle increased with an increasing temperature and CH{sub 4} concentration. This deposited carbon not only leads to CO{sub 2} release from the oxidation reactor but, more importantly, causes degredation of the carrier capacity and its reactivity.

Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani

2012-11-01T23:59:59.000Z

150

carbon footprinting | OpenEI  

Open Energy Info (EERE)

footprinting footprinting Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides NOx

151

REAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS  

E-Print Network [OSTI]

are International. b DOC = Diesel Oxidation Catalyst; DPF = Diesel Particulate Filter; EGR = Exhaust GasREAL-WORLD EFFICACY OF HEAVY DUTY DIESEL TRUCK NOX AND PM EMISSIONS CONTROLS Gurdas Sandhu H 26-28, 2012 #12;2 Objectives 1. Quantify inter-run variability in exhaust emission rates 2. Assess

Frey, H. Christopher

152

Recovery of manganese oxides from spent alkaline and zinc–carbon batteries. An application as catalysts for VOCs elimination  

SciTech Connect (OSTI)

Highlights: • Manganese oxides were synthesized using spent batteries as raw materials. • Spent alkaline and zinc–carbon size AA batteries were used. • A biohydrometallurgical process was employed to bio-lixiviate batteries. • Manganese oxides were active in the oxidation of VOCs (ethanol and heptane). - Abstract: Manganese, in the form of oxide, was recovered from spent alkaline and zinc–carbon batteries employing a biohydrometallurgy process, using a pilot plant consisting in: an air-lift bioreactor (containing an acid-reducing medium produced by an Acidithiobacillus thiooxidans bacteria immobilized on elemental sulfur); a leaching reactor (were battery powder is mixed with the acid-reducing medium) and a recovery reactor. Two different manganese oxides were recovered from the leachate liquor: one of them by electrolysis (EMO) and the other by a chemical precipitation with KMnO{sub 4} solution (CMO). The non-leached solid residue was also studied (RMO). The solids were compared with a MnO{sub x} synthesized in our laboratory. The characterization by XRD, FTIR and XPS reveal the presence of Mn{sub 2}O{sub 3} in the EMO and the CMO samples, together with some Mn{sup 4+} cations. In the solid not extracted by acidic leaching (RMO) the main phase detected was Mn{sub 3}O{sub 4}. The catalytic performance of the oxides was studied in the complete oxidation of ethanol and heptane. Complete conversion of ethanol occurs at 200 °C, while heptane requires more than 400 °C. The CMO has the highest oxide selectivity to CO{sub 2}. The results show that manganese oxides obtained using spent alkaline and zinc–carbon batteries as raw materials, have an interesting performance as catalysts for elimination of VOCs.

Gallegos, María V., E-mail: plapimu@yahoo.com.ar [Pla.Pi.Mu-Planta Piloto Multipropósito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Falco, Lorena R., E-mail: mlfalco@quimica.unlp.edu.ar [Pla.Pi.Mu-Planta Piloto Multipropósito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Peluso, Miguel A., E-mail: apelu@quimica.unlp.edu.ar [Centro de Investigación y Desarrollo en Ciencias Aplicadas, “Dr. J. Ronco” CINDECA (CONICET CCT La Plata), 47 N°257, La Plata, Buenos Aires (Argentina); Sambeth, Jorge E., E-mail: sambeth@quimica.unlp.edu.ar [Centro de Investigación y Desarrollo en Ciencias Aplicadas, “Dr. J. Ronco” CINDECA (CONICET CCT La Plata), 47 N°257, La Plata, Buenos Aires (Argentina); Thomas, Horacio J. [Pla.Pi.Mu-Planta Piloto Multipropósito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina)

2013-06-15T23:59:59.000Z

153

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect (OSTI)

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

154

Magnesium oxide nanoparticles on green activated carbon as efficient CO{sub 2} adsorbent  

SciTech Connect (OSTI)

This study was focused on carbon dioxide (CO{sub 2}) adsorption ability using Magnesium oxide (MgO) nanoparticles and MgO nanoparticles supported activated carbon based bamboo (BAC). The suitability of MgO as a good CO{sub 2} adsorbent was clarified using Thermodynamic considerations (Gibbs-Helmholtz relationship). The ?H and ?G of this reaction were ? 117.5 kJ?mol{sup ?1} and ? 65.4 kJ?mol{sup ?1}, respectively, at standard condition (298 K and 1 atm). The complete characterization of these adsorbent were conducted by using BET, XRD, FTIR, TEM and TPD?CO{sub 2}. The surface areas for MgO nanoparticles and MgO nanoparticles supported BAC were 297.1 m{sup 2}/g and 702.5 m{sup 2}/g, respectively. The MgO nanoparticles supported BAC shown better physical and chemical adsorption ability with 39.8 cm{sup 3}/g and 6.5 mmol/g, respectively. The combination of MgO nanoparticle and BAC which previously prepared by chemical method can reduce CO{sub 2} emissions as well as better CO{sub 2} adsorption behavior. Overall, our results indicate that nanoparticles of MgO on BAC posses unique surface chemistry and their high surface reactivity coupled with high surface area allowed them to approach the goal as an efficient CO{sub 2} adsorbent.

Wan Isahak, Wan Nor Roslam; Ramli, Zatil Amali Che; Mohamed Hisham, Mohamed Wahab; Yarmo, Mohd Ambar [Low Carbon Economy (LCE) Research Group, School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

155

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

156

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the October 1 to December 31, 2003 time period.

S. Wu

2003-12-31T23:59:59.000Z

157

Electrochemical NOx Sensors for Monitoring Diesel Emissions  

Broader source: Energy.gov [DOE]

A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs

158

Carbon dioxide fixation by Metallosphaera yellowstonensis and acidothermophilic iron-oxidizing microbial communities from Yellowstone National Park  

SciTech Connect (OSTI)

The fixation of inorganic carbon (as carbon dioxide) has been documented in all three domains of life and results in the biosynthesis of a diverse suite of organic compounds that support the growth of heterotrophic organisms. The primary aim of this study was to assess the importance of carbon dioxide fixation in high-temperature Fe(III)-oxide mat communities and in pure cultures of one of the dominant Fe(II)-oxidizing organisms (Metallosphaera yellowstonensis strain MK1) present in situ. Protein-encoding genes of the complete 3-hydroxypropionate/4-hydroxybutyrate (3-HP/4-HB) carbon fixation pathway were identified in pure-cultures of M. yellowstonensis strain MK1. Metagenome sequencing from the same environments also revealed genes for the 3-HP/4-HB pathway belonging to M. yellowstonensis populations, as well as genes for a complete reductive TCA cycle from Hydrogenobaculum spp. (Aquificales). Stable isotope (13CO2) labeling was used to measure the fixation of CO2 by M. yellowstonensis strain MK1, and in ex situ assays containing live Fe(III)-oxide microbial mats. Results showed that M. yellowstonensis strain MK1 fixes CO2 via the 3-HP/4-HB pathway with a fractionation factor of ~ 2.5 ‰. Direct analysis of the 13C composition of dissolved inorganic C (DIC), dissolved organic C (DOC), landscape C and microbial mat C showed that mat C is comprised of both DIC and non-DIC sources. The estimated contribution of DIC carbon to biomass C (> ~ 35%) is reasonably consistent with the relative abundance of known chemolithoautotrophs and corresponding CO2 fixation pathways detected in metagenome sequence. The significance of DIC as a major source of carbon for Fe-oxide mat communities provides a foundation for examining microbial interactions in these systems that are dependent on the activity of autotrophic organisms such as Hydrogenobaculum and Metallosphaera spp.

Jennings, Ryan; Whitmore, Laura M.; Moran, James J.; Kreuzer, Helen W.; Inskeep, William P.

2014-05-01T23:59:59.000Z

159

Carbon microspheres from ethanol at low temperature: Fabrication, characterization and their use as an electrocatalyst support for methanol oxidation  

SciTech Connect (OSTI)

Highlights: ? Carbon microbeads were prepared by the carbonization of ethanol at low temperature. ? The low temperature carbonization of ethanol was catalyzed by iodine. ? Carbon microbeads can serve as ideal candidate for catalyst supports. -- Abstract: Carbon microspheres (CMSs) with a diameter range of 2–3 ?m were prepared by the iodine-catalyzed carbonization of ethanol at low temperatures by solvothermal synthesis. The reaction time, concentrations of reactants, temperatures, different alcohols as carbon precursors and reaction environments were systematically altered to determine the optimal synthesis conditions. The size and shape were characterized by scanning and transmission electron microscopy and their structure was characterized by X-ray powder diffraction and Raman spectroscopy. Energy dispersive X-ray spectroscopy, Fourier transform infrared and X-ray photoelectron spectroscopy showed that abundant oxygen-containing functional groups remain on the surface of the carbon spheres. The formation mechanism involves iodine promotion of the oxidation of ethanol, which results in formation of the CMSs. The specific activity of the CMS-supported Pt catalyst is higher than that of a commercial Pt catalyst from E-TEK or the unsupported Pt catalyst.

Lian, Suoyuan [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China) [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); School of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034 (China); Ming, Hai; Huang, Hui [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Kang, Zhenhui, E-mail: zhkang@suda.edu.cn [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Liu, Yang [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)

2012-11-15T23:59:59.000Z

160

Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels  

SciTech Connect (OSTI)

This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

2013-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

2006-06-30T23:59:59.000Z

162

Block copolymer-templated iron oxide nanoparticles for bimodal growth of multi-walled carbon nanotubes  

E-Print Network [OSTI]

Since their discovery carbon nanotubes (CNTs) have sparked great interest due to their exceptional mechanical, electrical, and thermal properties. These properties make carbon nanotubes desirable for numerous applications ...

Yazzie, Kyle E

2008-01-01T23:59:59.000Z

163

High pressure conversion of \\{NOx\\} and Hg and their capture as aqueous condensates in a laboratory piston-compressor simulating oxy-fuel CO2 compression  

Science Journals Connector (OSTI)

Abstract Oxy-fuel technology for CO2 capture has largely focused on combustion characteristics as a driver towards demonstration. Impurity removal studies typically centre on the how current environmental control units (FGD, SCR, activated carbon beds) operate in oxy-fuel firing. However, it is expected that some removal of \\{NOx\\} and \\{SOx\\} may occur during compression of flue gas through the lead chamber process. Some commercial systems link the capture of mercury to the formation of acid condensates (as a soluble mercury salt). Mercury in compressed flue gas represents a potential corrosion risk in the processing of CO2 from oxy-fuel combustion processes. Gas phase elemental mercury (Hg0) is difficult to remove from the flue gas and the level of cleaning required to prevent corrosion of cryogenic brazed aluminium heat exchangers is uncertain. This work has investigated the behaviour of gaseous Hg0 in pressurised oxy-fuel systems in terms of the potential capture in acidic condensates, interaction with \\{NOx\\} gases and liquid stability on de-pressurisation. The work was undertaken on an adapted laboratory scale three stage axial-piston compressor with gas and liquid sampling at pressures up to 30 bar. The main finding was that gaseous Hg0 reacts readily with NO2 formed from NO oxidation at high pressure. This reaction occurred without the presence of water, either water vapour or liquid water, contrary to speculation in the literature. Without NO2, no capture of Hg0 was observed in the compression system. Overall, the capture of mercury during compression occurred as a consequence of high pressure, longer residence time and concentration of NO2. Capture rates of 100% Hg and 75–83% \\{NOx\\} were measured from the compressor exit at 30 bar g.

Rohan Stanger; Timothy Ting; Terry Wall

2014-01-01T23:59:59.000Z

164

Structural basis of the oxidative activation of the carboxysomal [gamma]-carbonic anhydrase, CcmM  

SciTech Connect (OSTI)

Cyanobacterial RuBisCO is sequestered in large, icosahedral, protein-bounded microcompartments called carboxysomes. Bicarbonate is pumped into the cytosol, diffuses into the carboxysome through small pores in its shell, and is then converted to CO{sub 2} by carbonic anhydrase (CA) prior to fixation. Paradoxically, many {beta}-cyanobacteria, including Thermosynechococcus elongatus BP-1, lack the conventional carboxysomal {beta}-CA, ccaA. The N-terminal domain of the carboxysomal protein CcmM is homologous to {gamma}-CA from Methanosarcina thermophila (Cam) but recombinant CcmM derived from ccaA-containing cyanobacteria show no CA activity. We demonstrate here that either full length CcmM from T. elongatus, or a construct truncated after 209 residues (CcmM209), is active as a CA - the first catalytically active bacterial {gamma}-CA reported. The 2.0 {angstrom} structure of CcmM209 reveals a trimeric, left-handed {beta}-helix structure that closely resembles Cam, except that residues 198-207 form a third {alpha}-helix stabilized by an essential Cys194-Cys200 disulfide bond. Deleting residues 194-209 (CcmM193) results in an inactive protein whose 1.1 {angstrom} structure shows disordering of the N- and C-termini, and reorganization of the trimeric interface and active site. Under reducing conditions, CcmM209 is similarly partially disordered and inactive as a CA. CcmM protein in fresh E. coli cell extracts is inactive, implying that the cellular reducing machinery can reduce and inactivate CcmM, while diamide, a thiol oxidizing agent, activates the enzyme. Thus, like membrane-bound eukaryotic cellular compartments, the {beta}-carboxysome appears to be able to maintain an oxidizing interior by precluding the entry of thioredoxin and other endogenous reducing agents.

Peña, Kerry L.; Castel, Stephane E.; de Araujo, Charlotte; Espie, George S.; Kimber, Matthew S. (Guelph); (Toronto)

2010-04-26T23:59:59.000Z

165

NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS  

SciTech Connect (OSTI)

This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

2001-10-10T23:59:59.000Z

166

Amperometric Biosensors Based on Carbon Paste Electrodes Modified with Nanostructured Mixed-valence Manganese Oxides and Glucose Oxidase  

SciTech Connect (OSTI)

Nanostructured multivalent manganese oxides octahedral molecular sieve (OMS), including cryptomelane-type manganese oxides and todorokite-type manganese oxides, were synthesized and evaluated for chemical sensing and biosensing at low operating potential. Both cryptomelane-type manganese oxides and todorokite-type manganese oxides are nanofibrous crystals with sub-nanometer open tunnels that provide a unique property for sensing applications. The electrochemical and electrocatalytic performance of OMS for the oxidation of H2O2 have been compared. Both cryptomelane-type manganese oxides and todorokite-type manganese oxides can be used to fabricate sensitive H2O2 sensors. Amperometric glucose biosensors are constructed by bulk modification of carbon paste electrodes (CPEs) with glucose oxidase as a biocomponent and nanostructured OMS as a mediator. A Nafion thin film was applied as an immobilization/encapsulation and protective layer. The biosensors were evaluated as an amperometric glucose detector at phosphate buffer solution with a pH 7.4 at an operating potential of 0.3 V (vs. Ag/AgCl). The biosensor is characterized by a well-reproducible amperometric response, linear signal-to-glucose concentration range up to 3.5 mM and 1.75 mM, and detection limits (S/N = 3) of 0.1 mM and 0.05 mM for todorokite-type manganese oxide and cryptomelane-type manganese oxide modified electrodes, respectively. The biosensors based on OMS exhibit considerable good reproducibility and stability, and the construction and renewal are simple and inexpensive.

Cui, Xiaoli; Liu, Guodong; Lin, Yuehe

2005-06-01T23:59:59.000Z

167

Photocatalytic and chemical oxidation of organic compounds in supercritical carbon dioxide. Progress report for FY97  

SciTech Connect (OSTI)

'The background for the project is briefly reviewed and the work done during the nine months since funding was received is documented. Work began in January, 1997. A post doctoral fellow joined the team in April. The major activities completed this fiscal year were: staffing the project, design of the experimental system, procurement of components, assembly of the system. preparation of the Safe Operating Procedure and ES and H compliance, pressure testing, establishing data collection and storage methodology, and catalyst preparation. Objective The objective of the project is to develop new chemistry for the removal of organic contaminants from supercritical carbon dioxide. This has application in processes used for continuous cleaning and extraction of parts and waste materials. A secondary objective is to increase the fundamental understanding of photocatalytic chemistry. Cleaning and extraction using supercritical carbon dioxide (scCO{sub 2}) can be applied to the solution of a wide range of environmental and pollution prevention problems in the DOE complex. Work is being done that explores scCO{sub 2} in applications ranging from cleaning contaminated soil to cleaning components constructed from plutonium. The rationale for use of scCO{sub 2} are based on the benign nature, availability and low cost, attractive solvent properties, and energy efficient separation of the extracted solute from the solvent by moderate temperature or pressure changes. To date, R and D has focussed on the methods and applications of the extraction steps of the process. Little has been done that addresses methods to polish the scCO{sub 2} for recycle in the cleaning or extraction operations. In many applications it will be desirable to reduce the level of contamination from that which would occur at steady state operation of a process. This proposal addresses chemistry to achieve that. This would be an alternative to removing a fraction of the contaminated scCO{sub 2} for disposal and using makeup scCO{sub 2}. A chemical polishing operation can reduce the release of CO{sub 2} from the process. It can also reduce the consumption of reagents that may be used in the process to enhance extraction and cleaning. A polishing operation will also reduce or avoid formation of an additional waste stream. Photocatalytic and other photochemical oxidation chemistry have not been investigated in scCO{sub 2}. The large base of information for these reactions in water, organic solvents, or air suggest that the chemistry will work in carbon dioxide. There are compelling reasons to believe that the properties of scCO{sub 2} should increase the performance of photocatalytic chemistry over that found in more conventional fluid phases.'

Blake, D.M.; Bryant, D.L.; Reinsch, V.

1997-09-30T23:59:59.000Z

168

Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide  

SciTech Connect (OSTI)

The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

1988-11-10T23:59:59.000Z

169

Comparative electron paramagnetic resonance investigation of reduced graphene oxide and carbon nanotubes with different chemical functionalities for quantum dot attachment  

SciTech Connect (OSTI)

Electron paramagnetic resonance (EPR) spectroscopy has been applied to different chemically treated reduced graphene oxide (rGO) and multiwalled carbon nanotubes (CNTs). A narrow EPR signal is visible at g?=?2.0029 in both GO and CNT-Oxide from carbon-related dangling bonds. EPR signals became broader and of lower intensity after oxygen-containing functionalities were reduced and partially transformed into thiol groups to obtain thiol-functionalized reduced GO (TrGO) and thiol-functionalized CNT (CNT-SH), respectively. Additionally, EPR investigation of CdSe quantum dot-TrGO hybrid material reveals complete quenching of the TrGO EPR signal due to direct chemical attachment and electronic coupling. Our work confirms that EPR is a suitable tool to detect spin density changes in different functionalized nanocarbon materials and can contribute to improved understanding of electronic coupling effects in nanocarbon-nanoparticle hybrid nano-composites promising for various electronic and optoelectronic applications.

Pham, Chuyen V.; Krueger, Michael, E-mail: michael.krueger@fmf.uni-freiburg.de, E-mail: emre.erdem@physchem.uni-freiburg.de; Eck, Michael [Freiburg Materials Research Center (FMF), University of Freiburg, Stefan-Meier-Str. 21, 79104 Freiburg (Germany); Department of Microsystems Engineering (IMTEK), University of Freiburg, Georges-Köhler-Allee 103, 79110 Freiburg (Germany); Weber, Stefan; Erdem, Emre, E-mail: michael.krueger@fmf.uni-freiburg.de, E-mail: emre.erdem@physchem.uni-freiburg.de [Institute of Physical Chemistry, University of Freiburg, Albertstr. 21, 79104 Freiburg (Germany)

2014-03-31T23:59:59.000Z

170

Cobalt Carbonate/ and Cobalt Oxide/Graphene Aerogel Composite Anodes for High Performance Li-Ion Batteries  

Science Journals Connector (OSTI)

Cobalt Carbonate/ and Cobalt Oxide/Graphene Aerogel Composite Anodes for High Performance Li-Ion Batteries ... (1, 2) Commercial LIBs use graphite as the anode material with a low theoretical specific capacity of 372 mAh g–1, necessitating extensive research to develop substitute anode materials with higher energy/power densities for high performance LIBs to satisfy demanding applications like electric vehicles. ...

Mohammad Akbari Garakani; Sara Abouali; Biao Zhang; Curtis Alton Takagi; Zheng-Long Xu; Jian-qiu Huang; Jiaqiang Huang; Jang-Kyo Kim

2014-10-15T23:59:59.000Z

171

Advanced NOx Emissions Control: Control Technology - Second Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Second Generation Advanced Reburning Second Generation Advanced Reburning General Electric - Energy and Environmental Research Corporation (GE-EER) is carrying out a two Phase research program to develop novel Advanced Reburning (AR) concepts for high efficiency and low cost NOx control from coal-fired utility boilers. AR technologies are based on combination of basic reburning and N-agent/promoter injections. Phase I of the project was successfully completed and EER was selected to continue to develop AR technology during Phase II. Phase I demonstrated that AR technologies are able to provide effective NOx control for coal-fired combustors. Three technologies were originally envisioned for development: AR-Lean, AR-Rich, and Multiple Injection AR (MIAR). Along with these, three additional technologies were identified during the project: reburning plus promoted SNCR; AR-Lean plus promoted SNCR; and AR-Rich plus promoted SNCR. The promoters are sodium salts, in particular sodium carbonate. These AR technologies have different optimum reburn heat input levels and furnace temperature requirements. For full scale application, an optimum technology can be selected on a boiler-specific basis depending on furnace temperature profile and regions of injector access.

172

Controlling NOx to Obtain Offsets or Meet Compliance  

E-Print Network [OSTI]

monitored and regu lated a number of pollutants: lead, carbon monoxide, oxides of sulfur, oxides of nitrogen, ozone and PM-lO. The Clean Air Act Amendments increased the focus on these pollutants, mandating the reductions to specified limits. Title I...

Mincy, J. E.

173

Ammonia Sensor for SCR NOX Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sensor for SCR NOX Reduction Ammonia Sensor for SCR NOX Reduction Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,...

174

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Broader source: Energy.gov [DOE]

Results show that a series of dual layer catalysts with a bottom layer of LNT catalyst and a top layer of SCR catalyst can carry out coupled ammonia generation and NOx reduction, achieving high NOx conversion with minimal ammonia slip

175

A Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture  

E-Print Network [OSTI]

looping is selected as the model cycle because of its suitability for solar-driven carbon dioxide captureA Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture Lindsey Yue and Wojciech Lipi´nski, The Australian

176

Measuring the Kinetics of the Reduction of Iron Oxide with Carbon Monoxide in a Fluidized Bed  

Science Journals Connector (OSTI)

Combusting a solid fuel in the presence of a metal oxide rather than air, chemical looping combustion, generates CO2suitable for sequestration and the reduced metal. For the case of iron, the reduced oxide can be...

C. D. Bohnt; J. P. Cleeton; C. M. Miiller…

2010-01-01T23:59:59.000Z

177

NETL: Advanced NOx Emissions Control: Control Technology - Methane de-NOx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

METHANE de-NOx® METHANE de-NOx® The Gas Technology Institute (GTI) is teaming with the All-Russian Thermal Engineering Institute and DB Riley to develop a pulverized-coal (PC)-combustion system that is an extension of IGT's METHANE de-NOx® technology. The technology is composed of a novel PC burner design using natural gas fired coal preheating developed and demonstrated in Russia, LNBs with internal combustion staging, and additional natural gas injection with overfire air. The coal is preheated at elevated temperatures (up to 1500oF) in oxygen deficient conditions prior to combustion. Coal preheat releases fuel-bound nitrogen together with volatiles present in the coal. These conditions promote the conversion of fuel-bound nitrogen to molecular nitrogen rather than to NOx.

178

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers. Quarterly report No. 5, July--September 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

179

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions  

Science Journals Connector (OSTI)

Implications of Near-Term Coal Power Plant Retirement for SO2 and NOX and Life Cycle GHG Emissions ... Life cycle GHG emissions were found to decrease by less than 4% in almost all scenarios modeled. ... Resulting changes in fuel use, life cycle greenhouse gas (GHG) emissions, and emissions of sulfur and nitrogen oxides are estimated. ...

Aranya Venkatesh; Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

2012-08-13T23:59:59.000Z

180

Mass Balance of Gaseous and Particulate Products from ?-Pinene/O3/Air in the Absence of Light and ?-Pinene/NOx/Air in the Presence of Natural Sunlight  

Science Journals Connector (OSTI)

The gas and particle phase products from the reaction of ?-pinene with the atmospheric oxidants O3 and OH radicals in the presence of NOx were investigated using both gas chromatography-mass spectrometry (GC-MS) ...

M. Jaoui; R. M. Kamens

2003-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Carbon-based Fuel Cell  

SciTech Connect (OSTI)

The direct use of coal in the solid oxide fuel cell to generate electricity is an innovative concept for power generation. The C-fuel cell (carbon-based fuel cell) could offer significant advantages: (1) minimization of NOx emissions due to its operating temperature range of 700-1000 C, (2) high overall efficiency because of the direct conversion of coal to CO{sub 2}, and (3) the production of a nearly pure CO{sub 2} exhaust stream for the direct CO{sub 2} sequestration. The objective of this project is to determine the technical feasibility of using a highly active anode catalyst in a solid oxide fuel for the direct electrochemical oxidation of coal to produce electricity. Results of this study showed that the electric power generation from Ohio No 5 coal (Lower Kittanning) Seam, Mahoning County, is higher than those of coal gas and pure methane on a solid oxide fuel cell assembly with a promoted metal anode catalyst at 950 C. Further study is needed to test the long term activity, selectivity, and stability of anode catalysts.

Steven S. C. Chuang

2005-08-31T23:59:59.000Z

182

Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity  

SciTech Connect (OSTI)

Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

2012-10-01T23:59:59.000Z

183

Molten Metal Anodes for Direct Carbon-Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??The aim of this thesis was to enable the direct utilization of solid carbonaceous fuels like coal and biomass, in solid oxide fuel cells (SOFC).… (more)

Jayakumar, Abhimanyu

2012-01-01T23:59:59.000Z

184

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper  

Science Journals Connector (OSTI)

... were used without further purification. Electrolyte solutions were prepared with deionized water (Ricca Chemical, ASTM Type I). Preparation of oxide-derived Cu 1

Christina W. Li; Jim Ciston; Matthew W. Kanan

2014-04-09T23:59:59.000Z

185

Effects of carbon nanotubes and graphene oxide absorbers on the noise of mode-locked fiber lasers  

E-Print Network [OSTI]

Phase noise is very important for the ultrafast pulse application in telecommunication, ultrafast diagnose, material science, and biology. In this paper, two types of carbon nano-materials, single-wall carbon nanotube and graphene oxide, are investigated for noise suppression in ultrafast photonics. Various properties of the wall-paper SAs, such as saturable intensity, optical absorption and degree of purity, are found to be key factors determining the phase noise of the ultrafast pulses. A reduced-noise femtosecond fiber laser is experimentally demonstrated by optimizing the above parameters of carbon material based SAs. The phase noise reduction more than 10 dB at 10 kHz can be obtained in the experiments. To our knowledge, this is the first time that the relationship between different carbon material based SAs and the phase noise of mode-locked lasers has been investigated. This work will pave the way to get a high-quality ultrashort pulse in passively mode-locked fiber lasers.

Li, Xiaohui; Yu, Xuechao; Wang, Yonggang; Wang, Yishan; Meng, Bo; Tang, Yulong; Yu, Xia; Zhang, Ying; Sun, Zhipei; Shum, Perry Ping; Wang, Qi Jie

2014-01-01T23:59:59.000Z

186

Surface analysis of Zircaloy-2 implanted with carbon before and after oxidation in air at 500 °C  

Science Journals Connector (OSTI)

Zircaloy-2 specimens were implanted with carbon ions in the fluence range from 1 × 1016 to 1 × 1018 ions/cm2, using a MEVVA source at an extraction voltage of 40 kV at a maximum temperature of 380 °C. The valences and depth profiles of elements in the implanted surface of Zircaloy-2 were analyzed by X-ray photoelectron spectroscopy and Auger electron spectroscopy, respectively. Scanning electron microscopy was used to examine the micro-morphology of samples. The color of the oxidized samples was checked with an optical scanner. Glancing-angle X-ray diffraction at 0.3° incident angles was employed to examine the phase transformations of implanted samples before and after oxidation in the air at 500 °C for 2 h. Before oxidation, at fluences less than 5 × 1016 ions/cm2, hexagonal zirconia (H-ZrO0.35) was present. At a fluence of 1 × 1017 ions/cm2, rhombohedral zirconia (R-Zr3O) appeared. When the fluence reached 1 × 1018 ions/cm2, cubic zirconium carbide was produced. There are many pits, both deep and shallow, in the sample surfaces, both prior to oxidation and after oxidation. Oxidation in the air at 500 °C gave rise to black surfaces on all samples. The X-ray diffraction results showed that monoclinic and tetragonal zirconia were present in the surface of as-received sample. For implanted samples, monoclinic and tetragonal zirconia are still present, while cubic zirconium carbide is produced at all fluences. The presence of ZrC is attributed to the high-temperature, long-time (2 h) exposure.

D.Q. Peng; X.D. Bai; F. Pan; H. Sun; B.S. Chen

2006-01-01T23:59:59.000Z

187

Pd modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to FDCA  

SciTech Connect (OSTI)

We show that the modification of a gold/carbon catalyst with Pt or Pd produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). This finding is a significant advance over current conversion technology because of the technological importance of FDCA. Indeed, FDCA has been identified as one of twelve potential building blocks for the production of value added chemicals derived from biosources.1 FDCA is a potential replacement source of terephthalic acid, the monomer presently used for the production of polyethylene terephthalate (PET) and derived from hydrocarbon sources.2

Villa, Alberto [Universita di Milano, Italy; Schiavoni, Marco [University of Milan and INFN, Milano, Italy; Campisi, Sebastiano [University of Milan and INFN, Milano, Italy; Veith, Gabriel M [ORNL; Prati, Laura [Universita di Milano, Italy

2013-01-01T23:59:59.000Z

188

High surface area, electrically conductive nanocarbon-supported metal oxide  

DOE Patents [OSTI]

A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.

Worsley, Marcus A; Han, Thomas Yong-Jin; Kuntz, Joshua D; Cervanted, Octavio; Gash, Alexander E; Baumann, Theodore F; Satcher, Jr., Joe H

2014-03-04T23:59:59.000Z

189

Dissociation and oxidation of carbon monoxide over Rh/Al sub 2 O sub 3 catalysts  

SciTech Connect (OSTI)

The activity of Rh/Al{sub 2}O{sub 3} catalysts for CO oxidation was investigated by transient isotopic pulse experiments using packed-bed reactor. This transient experimental scheme revealed significant CO dissociation activity during CO oxidation over Rh/Al{sub 2}O{sub 3} catalysts. Results indicate that the oxidation of CO proceeds via dissociative oxidation by its own oxygen as well as via direct oxidation by gas-phase oxygen on well-dispersed Rh/Al{sub 2}O{sub 3} catalysts. The rate of CO dissociation is on the same order of magnitude as the rate of CO oxidation; under steady-state conditions at 300{degree}C, the rate of CO dissociation is approximately half that of direct oxidation. Differences in CO dissociation activity between single-crystal Rh surfaces and well-dispersed supported Rh particles are explained in terms of the molecular bonding and adsorption characteristics on these two different surfaces. The importance of CO dissociation kinetics in the overall CO oxidation activity of Rh/Al{sub 2}O{sub 3} catalysts is further discussed in view of the reaction lightoff behavior.

Cho, Byong K.; Stock, C.J. (General Motors Research Labs., Warren, MI (USA))

1989-05-01T23:59:59.000Z

190

A decoupled approach for NOx–N2O 3-D CFD modeling in CFB plants  

Science Journals Connector (OSTI)

Abstract In this study, a 3D CFD model for the formation of \\{NOx\\} and N2O in a lignite fired 1.2 MWth CFB pilot plant is developed. The decoupled approach (decoupled from combustion simulation) is tested for the minimization of computational cost. As combustion simulation is prerequired, this was achieved through a simplified 3-D CFD combustion model. The developed model is then applied to the pilot-scale 1.2 MWth CFB plant and validated against experimental data. As concerns the NOx–N2O model, an extensive literature review is also carried out for the incorporation of the appropriate reactions network and respective reaction rates expressions. Results show that homogenous reactions are favoured on the lower section of the bed, due to the abundance of fuel devolatilization products. On the other hand, on the upper section, heterogeneous reactions govern nitric oxide formation/reduction. It is found that for the lignite examined in this work, HCN is released in negligible amounts during char combustion. The proposed and validated CFD model for \\{NOx\\} and N2O, is capable of examining the effect of different operational parameters and coal properties on the overall nitric oxides emissions from a CFB combustor, with low computational cost and without the additional expenses for pilot-scale experiments.

A. Nikolopoulos; I. Malgarinos; N. Nikolopoulos; P. Grammelis; S. Karrelas; E. Kakaras

2014-01-01T23:59:59.000Z

191

Conductivity measurements of molten metal oxides and their evaluation in a Direct Carbon Fuel Cell (DCFC)  

E-Print Network [OSTI]

ABSTRACT Since Direct Carbon Fuel Cell (DCFC) technology is in a beginning stage, emphasis should be laid on addressing the fundamental aspects. A molten electrolyte is required to facilitate ionic contact between solid ...

Yarlagadda, Venkata Raviteja

2011-09-08T23:59:59.000Z

192

Modeling Seasonal Variations in Carbon Dioxide and Nitrous Oxide in the Vadose Zone  

Science Journals Connector (OSTI)

...temperature, and soil atmosphere composition were being monitored was specifically...and CEL pools were predominant in the composition of the maize residue and were mainly...also taken into account. agriculture agrochemicals Avignon France Cambisols CANTIS carbon...

P. Cannavo; F. Lafolie; B. Nicolardot; P. Renault

193

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

194

Carbon Nanotubes from Oxide Solid Solution: A Way to Composite Powders, Composite Materials and Isolated Nanotubes  

Science Journals Connector (OSTI)

We have demonstrated the ability to prepare CNTS-metal-oxide powders that contain enormous amounts of CNTs..., most of which are SWNTs or small MWNTs with internal and external diameters in the 0.5-5 nm range. Th...

Christophe Laurent; Alain Peigney; Emmanuel Flahaut…

2002-01-01T23:59:59.000Z

195

Synthesis of zinc oxide particles coated multiwalled carbon nanotubes: Dielectric properties, electromagnetic interference shielding and microwave absorption  

SciTech Connect (OSTI)

Graphical abstract: A resistor–capacitor model could well describe the relationships between the structure and the dielectric properties, electromagnetic interference shielding and microwave-absorption of the composites in the frequency range of 2–18 GHz. The resonant behavior associated with the multiwalled carbon nanotubes/zinc oxide (MWCNTs/ZnO) interface greatly broadens the absorption band. Highlights: ? ZnO-immobilized on multiwalled carbon nanotubes (MWCNTs/ZnO) have resonant behavior. ? A resistor–capacitor model describes the relation between the structure and properties. ? The composite with 40 wt% MWCNTs/ZnO has good electromagnetic interference shielding. ? Two different types of absorption peaks are found in the MWCNTs/ZnO composites. ? The existence of MWCNTs/ZnO interface broadens the absorption band. -- Abstract: Zinc oxide (ZnO) nanoparticles were coated on the surfaces of multiwalled carbon nanotubes (MWCNTs). High resolution transmission electron microscopy images show that the wurtzite ZnO immobilized on the MWCNTs is single-crystalline with a preferential [0 0 0 2] growth direction. A capacitor was generated by the interface of ZnO and MWCNTs, and a resistor–capacitor model could well describe the relationships between the structure and the dielectric properties, electromagnetic interference shielding and microwave-absorption of the composites in the frequency range of 2–18 GHz. The network built by ZnO-immobilized MWCNTs could contribute to the improvement of electrical properties. Resonant peaks associated with the capacitor formed by the interface were observed in the microwave absorption spectra, which suggest that reflection–loss peaks greatly broadens the absorption bandwidth.

Song, Wei-Li [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Cao, Mao-Sheng, E-mail: caomaosheng@bit.edu.cn [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Wen, Bo; Hou, Zhi-Ling; Cheng, Jin [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Yuan, Jie, E-mail: yuanjie4000@sina.com [School of Information Engineering, Central University for Nationality, Beijing 100081 (China)] [School of Information Engineering, Central University for Nationality, Beijing 100081 (China)

2012-07-15T23:59:59.000Z

196

Synthetic zeolites and other microporous oxide molecular sieves  

Science Journals Connector (OSTI)

...Many variations on the process cycle were developed to improve efficiency...NOx ) emitted from lean-burn diesel engines. Many catalyst developers...hydrocarbon oxidation in conventional diesel engines and NOx reduction...reduction and system durability. General Motors achieved 50,000-mile-aged...

John D. Sherman

1999-01-01T23:59:59.000Z

197

Nanocrystalline {001} TiO2/carbon aerogel electrode with high surface area and enhanced photoelectrocatalytic oxidation capacity  

Science Journals Connector (OSTI)

Abstract Aiming at further developing the application of the highly reactive {001} TiO2 in photoelectrocatalytic oxidation, which is limited by the powder form, micron-size and low surface area, a nanocrystalline {001} TiO2/carbon aerogel (CA) photoelectrode was fabricated via a facile hydrothermal method. Nano-sized (50 nm) anatase {001} TiO2 was successfully grown on a CA substrate. The obtained photoelectrode endowed high surface area (537 m2 g?1) and enhanced photoelectrocatalytic oxidation performance. Under UV light illumination, the largest photocurrent density is obtained on 50 nm {001} TiO2 (5.58 mA cm?2), compared to 150 nm (4.17 mA cm?2), 1 ?m (2.83 mA cm?2) {001} TiO2, indicating that an obvious enhancement in photoelectrocatalytic oxidation activity was achieved when crystalline size reached nanometer scale. A high methylene blue removal of 93% was obtained on 50 nm {001} TiO2/CA, and the rate constant reached 8.46 × 10?3 min?1, which was twice as that of P25/CA and around twenty times that of 50 nm{001} TiO2/FTO.

Ya-nan Zhang; Yefei Jin; Xiaofeng Huang; Huijie Shi; Guohua Zhao; Hongying Zhao

2014-01-01T23:59:59.000Z

198

Lower Freezing DEF For Higher NOx Reduction Attainment  

Broader source: Energy.gov [DOE]

NOx emissions data from bench-scale experiments and Class III truck operated using a low freezing point diesel exhaust fluid

199

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA:...

200

Unique Catalyst System for NOx Reduction in Diesel Exhaust |...  

Broader source: Energy.gov (indexed) [DOE]

More Documents & Publications Noxtechs PAC System Development and Demonstration Plasma Assisted Catalysis System for NOx Reduction Clean Diesel Engine Component Improvement...

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Two Catalyst Formulations - One Solution for NOx After-treatment...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Two Catalyst Formulations - One Solution for NOx After-treatment Systems Low-temperature SCR combined with standard high-temperature SCR catalyst formulation in one system provides...

202

Measurement and Characterization of Lean NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

for the Department of Energy Purpose of Work: Enable efficient lean engine market penetration by meeting emission regulations with aftertreatment * Research of Lean NOx...

203

Enhanced High and Low Temperature Performance of NOx Reduction...  

Broader source: Energy.gov (indexed) [DOE]

and Low Temperature Performance of NOx Reduction Materials 2013 DOE AMR Review This presentation does not contain any proprietary, confidential, or otherwise restricted...

204

NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

205

H2-Assisted NOx Traps: Test Cell Results Vehicle Installations  

Broader source: Energy.gov (indexed) [DOE]

Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

206

Investigation of Aging Mechanisms in Lean NOx Traps | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland. merit08johnson.pdf More Documents & Publications Investigation of Aging Mechanisms in Lean NOx Traps...

207

Fuel Processor Enabled NOx Adsorber Aftertreatment System for...  

Broader source: Energy.gov (indexed) [DOE]

for Diesel Engine Emissions Control R. Dalla Betta, D. Sheridan, J. Cizeron Catalytica Energy Systems Inc. Mountain View, California 2 Outline Why use a fuel processor for NOx...

208

Status of APBF-DEC NOx Adsorber/DPF Projects  

Broader source: Energy.gov (indexed) [DOE]

* Examine other fuel properties 6 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Each platform will determine effects of fuel properties on: * NOx and PM reduction...

209

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

210

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Emission Control Catalysts Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts...

211

Three-Dimensional Composite Nanostructures for Lean NOx Emission...  

Broader source: Energy.gov (indexed) [DOE]

Nanowire Lean NOx Emission Control Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts Three-Dimensional Composite Nanostructures for Lean...

212

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Broader source: Energy.gov [DOE]

Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

213

Rapid Aging Protocols for Diesel Aftertreatment Devices: NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Aftertreatment (Agreement 13415) Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by LeanRich Cycling Impacts of Biodiesel on Emission Control Devices...

214

Nitrogen oxide emissions from a kraft recovery furnace  

SciTech Connect (OSTI)

Nitrogen Oxide (NOx) emissions from a rebuilt kraft recovery furnace slightly exceeded the specified limit of 1.1 lb/ton (0.55 kg/metric ton) of black-liquor solids. Mill trials were undertaken to determine whether NOx emissions could be minimized by modifying furnace operation. NOx emissions increased when secondary air was shifted to tertiary ports. NOx emissions fell when the amounts of primary and total air were decreased, but this increased emissions of other pollutants. After demonstrating that best operation of the furnace could not meet the permit with an emissions limit that matched the furnace's performance at best operation.

Prouty, A.L.; Stuart, R.C. (James River Corp., Camas, WA (United States)); Caron, A.L. (NCASI West Coast Regional Office, Corvallis, OR (United States))

1993-01-01T23:59:59.000Z

215

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined...  

Broader source: Energy.gov (indexed) [DOE]

Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Transient Dynamometer Testing of a Single-Leg NOX Adsorber...

216

Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline Engine Equipped with a Lean-NOx Trap Fuel Consumption and NOx Trade-offs on a Port-Fuel-Injected SI Gasoline...

217

Development of Land Use Regression Models for elemental, organic carbon, PAH and hopanes/steranes in 10 ESCAPE/TRANSPHORM European study areas  

Science Journals Connector (OSTI)

Land use regression (LUR) models have been used to model concentrations of mainly traffic related air pollutants (nitrogen oxides (NOx), particulate matter (PM) mass or absorbance). ...

Aleksandra Jedynska; Gerard Hoek; Meng Wang; Marloes Eeftens; Josef Cyrys; Menno Keuken; Christophe Ampe; Rob Beelen; Giulia Cesaroni; Francesco Forastiere; Marta Cirach; Kees de Hoogh; Audrey De Nazelle; Wenche Nystad; Christophe Declercq; Kirsten Thorup Eriksen; Konstantina Dimakopoulou; Timo Lanki; Kees Meliefste; Mark J Nieuwenhuijsen; Tarja Yli-Tuomi; Ole Raaschou-Nielsen; Bert Brunekreef; Ingeborg Kooter

2014-10-15T23:59:59.000Z

218

Metal oxide coating on first mirror in fusion reactor with carbon wall  

Science Journals Connector (OSTI)

Abstract The lifetime of diagnostic equipment in a fusion reactor is typically very short. The first mirror used to reflect optical signals for diagnostics plays a crucial role in the reactor, and it is highly important to develop a more durable first mirror which can survive in the hostile environment. In this work, by conducting electron beam deposition on molybdenum substrates, metallic oxide mirrors are prepared and studied in the simulated environment. The multi-layered metal oxide mirror exhibits much higher reflectivity than the original molybdenum one and the in situ technique to monitor the performance of the first mirror is developed and described.

Xirui Hou; Zhengwei Wu; Paul K. Chu

2014-01-01T23:59:59.000Z

219

Growth Mechanisms of Vertically-aligned Carbon, Boron Nitride, and Zinc Oxide Nanotubes  

SciTech Connect (OSTI)

Nanotubes are one-dimensional nanomaterials with all atoms located near the surface. This article provides a brief review on the possible growth mechanisms of a series of inorganic nanotubes, in particular, vertically-aligned (VA) carbon nanotubes (CNTs), boron nitride nanotubes (BNNTs), and ZnO nanotubes (ZnO NTs).

Yap, Yoke Khin [Department of Physics, Michigan Technological University, 118 Fisher Hall, 1400 Townsend Drive, Houghton, MI 49931 (United States)

2009-07-07T23:59:59.000Z

220

Oxidation State Optimization for Maximum Efficiency of NOx Adsorber Catalysts  

Broader source: Energy.gov [DOE]

Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions -...

222

Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity...  

Broader source: Energy.gov (indexed) [DOE]

NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011 Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2011...

223

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application  

SciTech Connect (OSTI)

Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

Fang, Howard L.; Huang, Shyan C.; Yu, Robert C. (Cummins, Inc.); Wan, C. Z. (Engelhard Corp.); Howden, Ken (U.S. Dept. of Energy)

2002-10-01T23:59:59.000Z

224

Remarkable catalytic activity of cobalt tetraphenylporphyrin modified on a titania for the oxidation of carbon monoxide below room temperature  

SciTech Connect (OSTI)

CoTPP on TiO/sub 2/-120s modified at 250 /sup 0/C under vacuum catalytically oxidized carbon monoxide rapidly with oxygen even at -79/sup 0/C. Its catalytic activity was incomparably higher than that of commercial Hopcalite. Comparison of its catalytic performance with those of the same catalyst or different TiO/sub 2/ supporting catalyst both evacuated at 200 /sup 0/C revealed unique features of the present catalyst in terms of its oxygen adsorption, the poisoning of adsorbed oxygen, and the insolubility of the complex in benzene. Both significant structural modification of the complex and its strong interaction with properly dehydrated TiO/sub 2/-120s brought about by evacuation at 250 /sup 0/C may induce such extraordinary activity. 14 references, 4 figures, 5 tables.

Mochida, I.; Iwai, Y.; Kamo, T.; Fujitsu, H.

1985-12-05T23:59:59.000Z

225

Graphite coated with manganese oxide/multiwall carbon nanotubes composites as anodes in marine benthic microbial fuel cells  

Science Journals Connector (OSTI)

Abstract Improving anode performance is of great significance to scale up benthic microbial fuel cells (BMFCs) for its marine application to drive oceanography instruments. In this study, manganese oxide (MnO2)/multiwall carbon nanotubes (MWCNTs) composites are prepared to be as novel anodes in the \\{BMFCs\\} via a direct redox reaction between permanganate ions (MnO4?) and MWCNTs. The results indicate that the MnO2/MWCNTs anode has a better wettability, greater kinetic activity and higher power density than that of the plain graphite (PG) anode. It is noted that the MnO2 (50% weight percent)/MWCNTs anode shows the highest electrochemical performance among them and will be a promising material for improving bioelectricity production of the BMFCs. Finally, a synergistic mechanism of electron transfer shuttle of Mn ions and their redox reactions in the interface between modified anode and bacteria biofilm are proposed to explain its excellent electrochemical performance.

Yubin Fu; Jian Yu; Yelong Zhang; Yao Meng

2014-01-01T23:59:59.000Z

226

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines  

SciTech Connect (OSTI)

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL; Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

227

Ultra-Low NOx Advanced Vortex Combustor  

SciTech Connect (OSTI)

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Edmonds, R.G. (Ramgen Power Systems, Inc., Bellevue, WA); Steele, R.C. (Ramgen Power Systems, Inc., Bellevue, WA); Williams, J.T. (Ramgen Power Systems, Inc., Bellevue, WA); Straub, D.L.; Casleton, K.H.; Bining, Avtar (California Energy Commission, Sacramento, CA)

2006-05-01T23:59:59.000Z

228

ULTRA-LOW NOX ADVANCED VORTEX COMBUSTOR  

SciTech Connect (OSTI)

An ultra lean-premixed Advanced Vortex Combustor (AVC) has been developed and tested. The natural gas fueled AVC was tested at the U.S. Department of Energy’s National Energy Technology Laboratory (USDOE NETL) test facility in Morgantown (WV). All testing was performed at elevated pressures and inlet temperatures and at lean fuel-air ratios representative of industrial gas turbines. The improved AVC design exhibited simultaneous NOx/CO/UHC emissions of 4/4/0 ppmv (all emissions are at 15% O2 dry). The design also achieved less than 3 ppmv NOx with combustion efficiencies in excess of 99.5%. The design demonstrated tremendous acoustic dynamic stability over a wide range of operating conditions which potentially makes this approach significantly more attractive than other lean premixed combustion approaches. In addition, a pressure drop of 1.75% was measured which is significantly lower than conventional gas turbine combustors. Potentially, this lower pressure drop characteristic of the AVC concept translates into overall gas turbine cycle efficiency improvements of up to one full percentage point. The relatively high velocities and low pressure drops achievable with this technology make the AVC approach an attractive alternative for syngas fuel applications.

Ryan G. Edmonds; Robert C. Steele; Joseph T. Williams; Douglas L. Straub; Kent H. Casleton; Avtar Bining

2006-05-01T23:59:59.000Z

229

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

230

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

231

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Low-NOx Burner Emissions Characterization Advanced Low-NOx Burner Emissions Characterization The goal of this work is to develop a comprehensive, high-quality database characterizing PM2.5 emissions from utility plants firing high sulfur coals. The specific objectives are to: 1) develop and test an ultra low-NOx pulverized coal burner for plug-in retrofit applications without boiler wall tube modifications, 2) assess the impact of low-NOx PC burner operation on NOx and PM2.5 emissions, and 3) provide high-quality data to ensure that future PM2.5 regulations are based on good scientific information. The work will be performed in the Clean Environment Development Facility (CEDF), a 100 million Btu/hr near-full-scale facility located at the Alliance Research Center. Related Papers and Publications:

232

Carbon nanomaterial produced by microwave exfoliation of graphite oxide: new insights.  

SciTech Connect (OSTI)

We present detailed characterization of graphene-like material obtained through microwave stimulated exfoliation of graphite oxide (GO). Properties of this material were studied by multiple techniques including, among others, X-ray photoelectron spectroscopy, mass-spectroscopy, infrared and Raman spectroscopy, scanning electron microscopy and broadband dielectric spectroscopy. Specific surface area and volume of microwave exfoliated graphite oxide reached 600 m2 g1 and 6 cm3 g1, respectively. It is shown that during such an explosive reduction process the sample emits CO2, CO and H2O and, in some cases, SO2 gases. The resulting reduced material exhibits IR spectra similar to that of graphite and a dc-conductivity of 0.12 S cm1.

Shulga, Y.M. [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia] [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia; Baskakov, S.A. [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia] [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia; Knerelman, E.I. [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia] [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia; Davidova, G.I. [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia] [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia; Badamshina, E.R. [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia] [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia; Shulga, N. Yu. [National University of Science and Technology MISiS, Moscow, Russia] [National University of Science and Technology MISiS, Moscow, Russia; Skryleva, E.A. [National University of Science and Technology MISiS, Moscow, Russia] [National University of Science and Technology MISiS, Moscow, Russia; Agapov, Alexander L [ORNL] [ORNL; Voylov, Dmitry N [ORNL] [ORNL; Sokolov, Alexei P [ORNL] [ORNL; Martynenko, V.M. [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia] [Institute of Problems of Chemical Physics, Russian Ac. Sci, Chernogolovka, Russia

2014-01-01T23:59:59.000Z

233

New Modified-Multiwall Carbon Nanotubes Paste Electrode for Electrocatalytic Oxidation and Determination of Hydrazine Using Square Wave Voltammetry  

Science Journals Connector (OSTI)

The applications of p-aminophenol as a suitable mediator, as a sensitive and selective voltammetric sensor for the determination of hydrazine using a square wave voltammetric method were described. The modified multiwall carbon nanotubes paste electrode exhibited a good electrocatalytic activity for the oxidation of hydrazine at pH = 7.0. The catalytic oxidation peak currents showed a linear dependence of the peaks current to the hydrazine concentrations in the range of 0.5–175 ?mol/L with a correlation coefficient of 0.9975. The detection limit (S/N = 3) was estimated to be 0.3 ?mol/L of hydrazine. The relative standard deviations for 0.7 and 5.0 ?mol/L hydrazine were 1.7 and 1.1%, respectively. The modified electrode showed good sensitivity and selectivity. The diffusion coefficient (D = 9.5 × 10?4 cm2/s) and the kinetic parameters such as the electron transfer coefficient (? = 0.7) of hydrazine at the surface of the modified electrode were determined using electrochemical approaches. The electrode was successfully applied for the determination of hydrazine in real samples with satisfactory results.

Ali A. ENSAFI; Mahsa LOTFI; Hassan KARIMI-MALEH

2012-01-01T23:59:59.000Z

234

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

SciTech Connect (OSTI)

Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

2005-06-01T23:59:59.000Z

235

E-Print Network 3.0 - acid oxidation held Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Calcium oxide Water Carbon (activated) Calcium... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ,...

236

E-Print Network 3.0 - acid oxidation defects-remaining Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Calcium oxide Water Carbon (activated) Calcium... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ,...

237

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

238

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

239

Flexible CHP System with Low NOx, CO and VOC Emissions- Fact Sheet, 2014  

Broader source: Energy.gov [DOE]

Utilizing Supplemental Ultra-Low-NOx Burner Technology to Meet Emissions Standards and Improve System Efficiency

240

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

FTIR study of carbon monoxide oxidation and scrambling at room temperature over copper supported on ZnO and TiO{sub 2} No. 1  

SciTech Connect (OSTI)

An FTIR and quadrupole mass spectroscopic study of CO adsorption and oxidation with {sup 16}O{sub 2} and {sup 18}O{sub 2} on copper supported on ZnO and TiO{sub 2} is presented. The experimental results indicate that CO is adsorbed on the metallic particles dispersed on both oxides on two kinds of sites, on the normal terrace sites and on sites at the borderline of the particles. Moreover, on titania, a band at 2126 cm{sup -1}, assigned to CO adsorbed on isolated Cu atoms and/or on two-dimensional small clusters, is detected. A frequency shift of the bands of CO adsorbed on the metallic particles observed in the CO-O{sub 2} coadsorption experiments and the occurrence of a scrambling reaction between CO and {sup 18}O{sub 2} reveal that on all these samples, there are metallic sites which are able to adsorb at the same time oxygen atoms and carbon monoxide. Carbon dioxide and carbonate-like species are formed: the asymmetric stretching frequencies of CO{sub 2} and the quadrupole mass spectroscopic analysis reveal that with {sup 18}O{sub 2}, different isotopic molecular CO{sub 2}`s are formed, while the carbonate-like species have the same frequencies of those produced in {sup 16}O{sub 2}. Moreover, these species are completely lacking in the absence of oxygen in the gas phase. The experimental results indicate the there are, on these samples, two independent pathways for the CO oxidation, a direct oxidation of CO at the surface of the metallic particles and an induced oxidation with the surface lattice oxygen species of the supports. 46 refs., 8 figs.

Baccuzzi, F.; Chiorino, A. [Universita di Torino (Italy)] [Universita di Torino (Italy)

1996-02-29T23:59:59.000Z

242

Asymmetric deposition of manganese oxide in single walled carbon nanotube films as electrodes for flexible high frequency response electrochemical capacitors  

Science Journals Connector (OSTI)

Manganese oxide (MnO2) is a promising pseudocapacitive electrode material because of its high capacitance, abundant resource, low-cost, and environmental friendliness. However, its poor electrical and ionic conductivities and low stability hinder applications. Forming MnO2 nanocomposites with high surface area porous metal, carbon materials, or conducting polymers is a possible solution. In this work, we have developed a facile and scalable asymmetric in situ deposition method to incorporate MnO2 nanoparticles in conductive single walled carbon nanotube (SWCNT) films. The high porosity of vacuum filtrated SWCNT films accommodates pseudocapacitive MnO2 nanoparticles without sacrificing the mechanical flexibility and electrochemical stability of SWCNT films. We exposed one side of SWCNT films to acidic potassium permanganate (KMnO4) solution. The infiltrated \\{KMnO4\\} solution partially etches \\{SWCNTs\\} to create abundant mesopores, which ensure electrolyte ions efficiently access deposited MnO2. Meanwhile, the remaining SWCNT network serves as excellent current collectors. The electrochemical performance of the SWCNT–MnO2 composite electrodes depends on the porosity of SWCNT films, pH, and concentration of \\{KMnO4\\} solution, deposition temperature and time. Our optimized two-electrode electrochemical capacitor, with 1 M Na2SO4 in water as electrolyte, showed a superior performance with specific capacitance of 529.8 F g?1, energy density of 73.6 Wh kg?1, power density of 14.6 kW kg?1, excellent capacitance retention (99.9%) after 2000 charge and discharge cycles, and one of the highest reported frequency responses (knee frequency at 1318 Hz). The high performance flexible electrochemical capacitors have broad applications in portable electronics and electrical vehicles, especially when high frequency response is desired.

Jianmin Shen; Andong Liu; Yu Tu; Hong Wang; Rongrong Jiang; Jie Ouyang; Yuan Chen

2012-01-01T23:59:59.000Z

243

Functionality of Commercial NOx Storage-Reduction Catalysts and...  

Broader source: Energy.gov (indexed) [DOE]

N.A. Ottinger, J.A. Pihl, T.J. Toops, C. Finney, M. Lance, C. Stuart Daw, "Types, Spatial Distribution, Stability, and Performance Impact of Sulfur on a Lean NOx Trap...

244

Reducing NOx emissions using the humid air motor concept  

Science Journals Connector (OSTI)

The use of water to prevent NOx...formation during the combustion process is well known. The H.A.M. system (Humid Air Motor) is an original and promising solution compared ... . This system involves evaporating l...

Emmanuel Riom; Lars-Ola Larsson; Ulf Hagström

2002-05-01T23:59:59.000Z

245

Enhanced High Temperature Performance of NOx Storage/Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ace026peden2010o.pdf More Documents & Publications Mechanisms of Sulfur Poisoning of NOx Adsorber (LNT) Materials...

246

Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration  

SciTech Connect (OSTI)

Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

Choi, Jae-Soon [ORNL] [ORNL; Prikhodko, Vitaly Y [ORNL] [ORNL; Partridge Jr, William P [ORNL] [ORNL; Parks, II, James E [ORNL; Norman, Kevin M [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL; Chambon, Paul H [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL

2010-01-01T23:59:59.000Z

247

Reducing fishing vessel fuel consumption and NOX emissions  

Science Journals Connector (OSTI)

There is a growing concern with the impact of marine operations on the environment. This requires reducing fuel consumption and vessel pollution during operation. On-board computers and satellite communications will enable the operator to reduce fuel consumption and NOX emissions during vessel operations. This paper presents the results of a study on this problem and how such an on-board system could be implemented to reduce fuel consumption and engine NOX emissions.

Robert Latorre

2001-01-01T23:59:59.000Z

248

Group effects on fuel NOx emissisons from coal  

E-Print Network [OSTI]

GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1991 Major Subject: Mechanical Engineering GROUP EFFECTS ON FUEL NOX EMISSIONS FROM COAL A Thesis by ANAND ANAKKARA VADAKKATH Approved ss to style and content by: K. Annamalai (Chair of Committee) Cr, R. Laster (Member) J. Wagne (Member...

Vadakkath, Anand Anakkara

2012-06-07T23:59:59.000Z

249

SYNGAS PRODUCTION VIA HIGH-TEMPERATURE CO-ELECTROLYSIS OF STEAM AND CARBON DIOXIDE IN A SOLID-OXIDE STACK  

SciTech Connect (OSTI)

This paper presents results of recent experiments conducted at the INL studying coelectrolysis of steam and carbon dioxide in a 10-cell high-temperature solid-oxide electrolysis stack. Coelectrolysis is complicated by the fact that the reverse shift reaction occurs concurrently with the electrolytic reduction reactions. All reactions must be properly accounted for when evaluating results. Electrochemical performance of the stack was evaluated over a range of temperatures, compositions, and flow rates. The apparatus used for these tests is heavily instrumented, with precision mass-flow controllers, on-line dewpoint and CO2 sensors, and numerous pressure and temperature measurement stations. It also includes a gas chromatograph for analyzing outlet gas compositions. Comparisons of measured compositions to predictions obtained from a chemical equilibrium co-electrolysis model are presented, along with corresponding polarization curves. Results indicate excellent agreement between predicted and measured outlet compositions. Coelectrolysis significantly increases the yield of syngas over the reverse water gas shift reaction equilibrium composition. The process appears to be a promising technique for large-scale syngas production.

Carl M. Stoots; James E. O'Brien; Joseph J. Hartvigsen

2007-06-01T23:59:59.000Z

250

Relation between surface adsorption states and emf in a solid electrolyte concentration cell during carbon monoxide oxidation on platinum studied by local current measurement  

SciTech Connect (OSTI)

The importance of measuring adsorption during surface catalysis has been emphasized often. This is true for the oxidation of carbon monoxide on a platinum surface. Surface adsorption states during the reaction under steady states can be learned from electromotive force (emf) measurement with appropriate assumptions. Two mechanisms for emf generation have been proposed, one is that only oxygen activity generates emf, the other is that both oxygen and CO adsorption generates emf.

Okamoto, H.; Kawamura, G.; Kudo, T.

1984-04-01T23:59:59.000Z

251

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

SciTech Connect (OSTI)

Uses for structured catalytic supports, such as ceramic straight-channel monoliths and ceramic foams, have been established for a long time. One of the most prominent examples is the washcoated ceramic monolith as a three-way catalytic converter for gasoline-powered automobiles. A distinct alternative to the ceramic monolith is the metal foam, with potential use in fuel cell-powered automobiles. The metal foams are characterized by their pores per inch (ppi) and density ({rho}). In previous research, using 5 wt% platinum (Pt) and 0.5 wt% iron (Fe) catalysts, washcoated metal foams, 5.08 cm in length and 2.54 cm in diameter, of both varying and similar ppi and {rho} were tested for their activity (X{sub CO}) and selectivity (S{sub CO}) on a CO preferential oxidation (PROX) reaction in the presence of a H{sub 2}-rich gas stream. The variances in these metal foams' activity and selectivity were much larger than expected. Other structured supports with 5 wt% Pt, 0-1 wt% Fe weight loading were also examined. A theory for this phenomenon states that even though these structured supports have a similar nominal catalyst weight loading, only a certain percentage of the Pt/Fe catalyst is exposed on the surface as an active site for CO adsorption. We will use two techniques, pulse chemisorption and temperature programmed desorption (TPD), to characterize our structured supports. Active metal count, metal dispersion, and other calculations will help clarify the causes for the activity and selectivity variations between the supports. Results on ceramic monoliths show that a higher Fe loading yields a lower dispersion, potentially because of Fe inhibition of the Pt surface for CO adsorption. This theory is used to explain the reason for activity and selectivity differences for varying ppi and {rho} metal foams; less active and selective metal foams have a lower Fe loading, which justifies their higher metal dispersion. Data on the CO desorption temperature and average metal crystallite size for TPD are also collected.

Paul Chin; George W. Roberts; James J. Spivey

2003-12-31T23:59:59.000Z

252

Evaluation of autotrophic growth of ammonia-oxidizers associated with granular activated carbon used for drinking water purification by DNA-stable isotope probing  

Science Journals Connector (OSTI)

Abstract Nitrification is an important biological function of granular activated carbon (GAC) used in advanced drinking water purification processes. Newly discovered ammonia-oxidizing archaea (AOA) have challenged the traditional understanding of ammonia oxidation, which considered ammonia-oxidizing bacteria (AOB) as the sole ammonia-oxidizers. Previous studies demonstrated the predominance of AOA on GAC, but the contributions of AOA and AOB to ammonia oxidation remain unclear. In the present study, DNA-stable isotope probing (DNA-SIP) was used to investigate the autotrophic growth of AOA and AOB associated with GAC at two different ammonium concentrations (0.14 mg N/L and 1.4 mg N/L). GAC samples collected from three full-scale drinking water purification plants in Tokyo, Japan, had different abundance of AOA and AOB. These samples were fed continuously with ammonium and 13C-bicarbonate for 14 days. The DNA-SIP analysis demonstrated that only AOA assimilated 13C-bicarbonate at low ammonium concentration, whereas AOA and AOB exhibited autotrophic growth at high ammonium concentration. This indicates that a lower ammonium concentration is preferable for AOA growth. Since AOA could not grow without ammonium, their autotrophic growth was coupled with ammonia oxidation. Overall, our results point towards an important role of AOA in nitrification in GAC filters treating low concentration of ammonium.

Jia Niu; Ikuro Kasuga; Futoshi Kurisu; Hiroaki Furumai; Takaaki Shigeeda

2013-01-01T23:59:59.000Z

253

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

254

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

255

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the sixteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. During an unplanned outage, damage occurred to the electrochemical noise corrosion probes installed at the AEP Gavin plant; testing is expected to resume in August. The KEMCOP corrosion coupons were not affected by the unplanned outage; the coupons were removed and sent for analysis. BYU conducted a series of tests before the ISSR lab was relocated. Ammonia adsorption experiments provided clear evidence of the types of acidic sites present on catalyst surfaces. Data collected this quarter indicate that surface sulfation decreases Lewis acid site concentrations for all catalysts thus far studied, confirming that catalytic activity under commercial coal-based SCR conditions occurs primarily on Br{o}nsted acid sites and would be susceptible to basic impurities such as alkali and alkaline earth oxides, chlorides, and sulfates. SCR activity tests based on MS analysis showed that increasing sulfation generally increases NO reduction activity for both 0% and 1% vanadia catalysts. During this quarter, the slipstream reactor at Rockport operated for 720 hours on flue gas. Catalyst exposure time reached 4500 hours since installation. The reactor is out of service at the Rockport plant and plans are being made to move it to the Gadsden Plant. At Gadsden, modifications have begun in preparation for installation of the slipstream reactor next quarter.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-06-30T23:59:59.000Z

256

UV-vis spectroscopy of iodine adsorbed on alkali-metal-modified zeolite catalysts for addition of carbon dioxide to ethylene oxide  

SciTech Connect (OSTI)

The basicity of alkali-metal-exchange (Na, K, Cs) zeolites X and Y was probed by UV-vis diffuse reflectance spectroscopy of adsorbed iodine. The observed blue shift in the visible absorption spectrum of adsorbed iodine, compared to gaseous iodine, correlated well with the negative charge on the framework oxygen atoms calculated from the Sanderson electronegativity equalization principle. The blue shifts associated with iodine adsorbed on classical catalytic supports like silica, alumina, and magnesia suggest that the iodine adsorption technique for probing basicity is applicable to a wide variety of solids. Iodine was also adsorbed on X and Y zeolites containing occluded cesium oxide formed by decomposition of impregnated cesium acetate. However, the iodine appeared to irreversibly react on these strongly basic samples, possibly forming an adsorbed triiodide ions. As a complement to the adsorption studies, the activity of alkali-metal-containing zeolites for the base-catalyzed formation of ethylene carbonate from ethylene oxide and carbon dioxide was investigated. Among the ion-exchanged zeolites, the cesium form of zeolite X exhibited the highest activity for ethylene carbonate formation. The catalytic activity of a zeolite containing occluded cesium was even higher than that of a cesium-exchanged zeolite. The presence of water adsorbed in zeolite pores promoted the rate of ethylene carbonate formation for both cesium-exchanged and cesium-impregnated zeolite X.

Doskocil, E.J.; Bordawekar, S.V.; Kaye, B.G.; Davis, R.J. [Univ. of Virginia, Charlottesville, VA (United States). Dept. of Chemical Engineering] [Univ. of Virginia, Charlottesville, VA (United States). Dept. of Chemical Engineering

1999-07-29T23:59:59.000Z

257

Regenerative catalytic oxidation  

SciTech Connect (OSTI)

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

258

Infrared spectroscopic studies of carbon monoxide adsorbed on a series of silica-supported copper catalysts in different oxidation states  

SciTech Connect (OSTI)

Infrared spectroscopy has been used to study the adsorption of carbon monoxide (358-493 K, 0.1-20 kPa) on four copper-on-silica (2-10 wt% Cu) catalysts prepared by the ion-exchange technique. The measurements are made for each sample in three different states: unreduced (predominantly Cu{sup 2+}), and reduced (Cu{sup 0}), and partially reoxidized in nitrous oxide (Cu{sup +}). On unreduced samples, a major absorption band between 2127 and 2132 cm{sup {minus}1} due to CO adsorbed on small CuO particles and a weak band at 2199 cm{sup {minus}1} due to CO on isolated Cu{sup 2+} ions incorporated in the silica surface have been identified. The former adsorption obeys a Langmuir isotherm with a heat of adsorption of 29 kJ/mol independent of CuO particle size and surface coverage. After catalyst reduction, the major absorption band lies between 2090 and 2113 cm{sup {minus}1} and arises from CO linearly bound to very small (1- to 5-nm) copper metal clusters. The observed frequency shifts indicate the presence of steps and terraces similar to low index Cu planes in very small particles (1- to 2-nm), and the presence of similar higher index Cu planes on larger clusters (2- to 5-nm). The absorption is described by a Freundlich isotherm with the heat of CO adsorption decreasing with coverage from 50 to 22 kJ/mol on bigger particles but more constant (27 to 22 kJ/mol) on small particles. A surface copper/CO atomic ratio increasing from 5 to 12 is established at equilibrium saturation between 358 and 493 K using extinction coefficients determined in this study. In the reduced catalysts, a weakly adsorbed ({Delta}H{sub a} = {minus}20 kJ/mol) species assigned to CO bound to isolated Cu{sup +} ions is also found and absorbs at 2175 cm{sup {minus}1}. The frequency of this band does not vary with catalyst loading and is not affected by reoxidation of the catalyst in nitrous oxide.

Kohler, M.A.; Wainwright, M.S.; Trimm, D.L.; Cant, N.W. (Macquarie Univ., New South Wales (Australia) Univ. of South Wales (Australia))

1989-05-01T23:59:59.000Z

259

Method of making a catalytic metal oxide selective for the conversion of a gas and a coating system for the selective oxidation of hydrocarbons and carbon monoxide  

SciTech Connect (OSTI)

A method is described of making a catalytic metal oxide selective to catalyzing the conversion of given gas species, comprising: intimately supporting a solid film of catalytic metal oxide on an electrically conducting material, said film having an exposed outer surface spaced no greater than 1,000 angstroms from said conducting material and said conducting material being matched to the composition of said oxide to change the electron state of the exposed outer surface to promote a reaction between given gas species and said oxide, said metal oxide being selected from the group consisting of TiO[sub 2], SnO[sub 2], FeO, SrTiO[sub 3], and CoO, and said conducting material being selected from the group consisting of Au, Pt, TiN, Pd, Rh, Ni, and Co.

Logothetis, E.M.; Soltis, R.E.

1993-07-20T23:59:59.000Z

260

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Effects of diesel-water emulsion combustion on diesel engine NOx emissions. Final report, 1 January 1998--1 May 1999  

SciTech Connect (OSTI)

This study examines the effects of combusting a mixture of diesel fuel, water, and surfactant on the nitrogen oxides (NOx) emissions from a compression ignition diesel engine. Extensive previous research in the literature has attributed the observed reduction of nitrogen oxide emissions to a suppression of flame temperature due to quenching effects from the water, thereby reducing thermal NOx formation. The report highlights the relevant theory, operation, and design parameters of diesel internal combustion engines. Experimental procedures conducted using a Detroit Diesel 4-cylinder diesel engine are discussed. Results from testing diesel fuel with varying ratios of water balanced with a surfactant to stabilize the emulsion are presented and discussed. The data shows significant NOx emission reduction with up to 45 percent water, by volume, in the fuel. These results are correlated with thermodynamic first law and equilibrium combustion products analyses to estimate the adiabatic flame temperature of the standard fuel and fuel-water emulsion cases. Results indicate that thermal NOx is indeed reduced by quenching and flame temperature suppression, confirming reports in the literature. Recommendations are given for further studies, including improving the fuel-water emulsion and considerations for long-term testing.

Canfield, A.C.

1999-05-01T23:59:59.000Z

262

NETL: Advanced NOx Emissions Control: Control Technology - SCNR Field  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SNCR Field Demonstration SNCR Field Demonstration American Electric Power (AEP), in conjunction with the U.S. Department of Energy, FuelTech, the Ohio Coal Development Office, and fourteen EPRI member utilities, performed a full-scale demonstration of a urea-based Selective Non-Catalytic Reduction (SNCR) system at Cardinal Unit 1. Cardinal Unit 1 is a 600MWe opposed-wall dry bottom pulverized coal-fired boiler that began service in 1967. This unit burns eastern bituminous high-sulfur coal, (3.72%S). This unit was retrofitted with low NOx burners (LNB's) during its scheduled fall 1998 outage and the SNCR system was installed concurrently. SNCR is a post-combustion NOx control process developed to reduce NOx emissions from fossil-fuel combustion systems. SNCR processes involve the injection of a chemical containing nitrogen into the combustion products, where the temperature is in the range of 1600°F - 2200°F (870°C - 1205°C). In this temperature range, the chemical reacts selectively with NOx in the presence of oxygen, forming primarily nitrogen and water. Although a number of chemicals have been investigated and implemented for SNCR NOx reduction, urea and ammonia have been most widely used for full-scale applications.

263

High surface area silicon carbide-coated carbon aerogel  

SciTech Connect (OSTI)

A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust. Carbon aerogels can be coated with sol-gel silica and the silica can be converted to silicone carbide, improved the thermal stability of the carbon aerogel.

Worsley, Marcus A; Kuntz, Joshua D; Baumann, Theodore F; Satcher, Jr, Joe H

2014-01-14T23:59:59.000Z

264

SCReaming for Low NOx - SCR for the Light Duty Market | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

SCReaming for Low NOx - SCR for the Light Duty Market SCReaming for Low NOx - SCR for the Light Duty Market Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan....

265

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer...

266

Safe and compact ammonia storage/delivery systems for SCR-DeNOX...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

267

Development of a Stand-Alone Urea-SCR System for NOx Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines Stand-alone urea SCR...

268

Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study 2003 DEER Conference Presentation: Oak Ridge...

269

Initial Results of the DeNOx SCR System by Urea Injection in...  

Broader source: Energy.gov (indexed) [DOE]

Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus 2005 Diesel Engine Emissions...

270

The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst  

Broader source: Energy.gov [DOE]

Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost

271

Industry-Utility Collaborative Efforts to Address Environmental Concerns- Dispatching for Localized NOx Reduction  

E-Print Network [OSTI]

these objectives. The approach involves dispatching NOx-producing equipment (e.g., boilers and gas turbines) to achieve minimum NOx production during ozone alert periods and purchasing supplemental power under a special tariff to replace any loss in self...

Hamilton, D. E.; Helmick, R. W.; Lambert, W. J.

272

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Broader source: Energy.gov (indexed) [DOE]

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given...

273

NOx formation by steam injection using detailed chemical kinetics  

Science Journals Connector (OSTI)

In order to improve thermal efficiency of gas turbine system and better control NOx emission, the injection of steam into a gas turbine combustor has been employed. This study has used both chemical equilibrium calculations and the counterflow diffusion flame calculations of methane-air flame aiming at the elucidation of the NOx reduction mechanism due to the steam injection. The influence of the equivalence ratios, the amount of steam and method of injection, the influence of the temperature of the preheated air and fuel has been also investigated. In this study, the GRI-Mech was employed for modelling the chemical reactions.

H. Yamashita; D. Zhao; S.N. Danov; T. Furuhata; N. Arai

2001-01-01T23:59:59.000Z

274

Aeroderivative Gas Turbines Can Meet Stringent NOx Control Requirements  

E-Print Network [OSTI]

for controlling NOx emissions will be discussed. Steam injection has a very favorable effect on engine performance raising both the power output and efficiency. As an example, full steam injection in the GE LM5000 gas turbine :tncreases the power output from... methods for reducing the NOx levels of the LM2500 and LM5000 engines. These engines are aircraft-derivative turbine engines, which are used in a variety of industrial applications. Efforts have been concentrated on the use of water or steam injection...

Keller, S. C.; Studniarz, J. J.

275

Modified carbon-fiber material as a low-temperature catalyst for the oxidation of CO to CO/sub 2/  

SciTech Connect (OSTI)

The authors used a carbon-fiber material (CFM) as the base and study, the preparation structure, and properties of metal-carbon catalysts derived from this material. Cobalt, copper, manganese, chromium, nickel, and iron compounds supported on a nontextured CFM were used. Tables give the conditions for preparation of adsorption-active CFM containing Co, Mn, Ni, Cr, and Fe compounds as the active component. Another table shows that all the samples of adsorption-active CFM (with the exception of the iron-containing CFM) have catalytic activity. Other tables indicate that the activity of the synthesized catalysts depends significantly on the means of preparation. The authors report a new adsorption-active CFM having high catalytic activity for the oxidation of CO to CO/sub 2/.

Morozova, A.A.

1986-01-01T23:59:59.000Z

276

New materials for intermediate-temperature solid oxide fuel cells to be powered by carbon- and sulfur-containing fuels.  

E-Print Network [OSTI]

??Unlike polymer electrolyte fuel cells, solid-oxide fuel cells (SOFCs) have the potential to use a wide variety of fuels, including hydrocarbons and gasified coal or… (more)

Yang, Lei

2011-01-01T23:59:59.000Z

277

1.5 V battery driven reduced graphene oxide–silver nanostructure coated carbon foam (rGO–Ag–CF) for the purification of drinking water  

Science Journals Connector (OSTI)

A porous carbon foam (CF) electrode modified with a reduced graphene oxide–Ag (rGO–Ag) nanocomposite has been fabricated to purify water. It can perform as an antibacterial device by killing pathogenic microbes with the aid of a 1.5 V battery, with very little power consumption. The device is recycled ten times with good performance for long term usage. It is shown that the device may be implemented as a fast water purifier to deactivate the pathogens in drinking water.

Surender Kumar; Somnath Ghosh; N Munichandraiah; H N Vasan

2013-01-01T23:59:59.000Z

278

Adsorption of Ni(II) on oxidized multi-walled carbon nanotubes: Effect of contact time, pH, foreign ions and PAA  

Science Journals Connector (OSTI)

The adsorption of Ni(II) on oxidized multi-walled carbon nanotubes (MWCNTs) as a function of contact time, pH and foreign ions in the absence and presence of polyacrylic acid (PAA) was studied using batch technique. The results indicated that adsorption of Ni(II) on oxidized \\{MWCNTs\\} increased from zero to ?99% at pH 2–9, and then maintained the high level with increasing pH. Kinetic data showed that the adsorption process achieved equilibrium within 2 h and experimental data were fitted well by the pseudo-second-order equation. A positive effect of PAA on Ni(II) adsorption was found at pH  8. The effect of addition sequences of PAA/Ni(II) on the adsorption of Ni(II) to PAA–MWCNT hybrids were also studied. The results indicated that the adsorption of Ni(II) was influenced by addition sequences obviously. The adsorption of Ni(II) on oxidized \\{MWCNTs\\} may be mainly attributed to surface complexation and ion exchange. Oxidized \\{MWCNTs\\} are suitable material in the solidification and pre-concentration of Ni(II) from aqueous solutions.

Shitong Yang; Jiaxing Li; Dadong Shao; Jun Hu; Xiangke Wang

2009-01-01T23:59:59.000Z

279

NOx, SO{sub 3} in the spotlight at NETL's 2006 Environmental Controls conference  

SciTech Connect (OSTI)

As emissions caps drop, technological solutions must become increasingly effective and efficient. Researchers, equipment vendors, and plant operators are exploring alternatives to SCR and SNCR, with a view to reducing the overall costs of NOx reduction. They have also achieved 95% to 99% removal of SO{sub 3}, with no visible plume opacity. These topics were discussed at ECC 2006. The first conference session focussed on selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) control of nitrogen oxide emissions; the second session addressed the related issue of reducing stack emissions and flue gas concentrations of sulfur trioxide. The article summarises many papers presented. Summaries and/or full versions of all the papers mentioned, and others, are posted at www.netl.doe.gov/publications/proceedings/06/ecc/index.html. 2 figs.

Mann, A.N.; Makovsky, L.E.; Sarkus, T.A. [Technology and Management Services Inc. (United States)

2007-02-15T23:59:59.000Z

280

The Chemistry of the Thermal DeNOx Process: A Review of the Technology's Possible Application to control of NOx from Diesel Engines  

SciTech Connect (OSTI)

This paper presents a review of the Thermal DeNOx process with respect to its application to control of NOx emissions from diesel engines. The chemistry of the process is discussed first in empirical and then theoretical terms. Based on this discussion the possibilities of applying the process to controlling NOx emissions from diesel engines is considered. Two options are examined, modifying the requirements of the chemistry of the Thermal DeNOx process to suit the conditions provided by diesel engines and modifying the engines to provide the conditions required by the process chemistry. While the former examination did not reveal any promising opportunities, the latter did. Turbocharged diesel engine systems in which the turbocharger is a net producer of power seem capable of providing the conditions necessary for NOx reduction via the Thermal DeNOx reaction.

Lyon, Richard

2001-08-05T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Lean NOx Reduction with Dual Layer LNT/SCR Catalysts  

Broader source: Energy.gov (indexed) [DOE]

Roles of ceria in LNT SCR: I ncreases NOx storage & NO conversion at low tem perature P rom otes W GS reaction Conditions: Lean: 500 ppm NO, 5% O 2 ; 60s Rich: 2.5% H 2 ; 5s X H2...

282

\\{NOx\\} reduction from a large bore natural gas engine via reformed natural gas prechamber fueling optimization  

Science Journals Connector (OSTI)

Lean combustion is a standard approach used to reduce \\{NOx\\} emissions in large bore (35–56 cm) stationary natural gas engines. However, at lean operating points, combustion instabilities and misfires give rise to high total hydrocarbon (THC) and carbon monoxide (CO) emissions. To counteract this effect, precombustion chamber (PCC) technology is employed to allow engine operation at an overall lean equivalence ratio while mitigating the rise of THC and CO caused by combustion instability and misfires. A PCC is a small chamber, typically 1–2% of the clearance volume. A separate fuel line supplies gaseous fuel to the PCC and a standard spark plug ignites the slightly rich mixture (equivalence ratio 1.1–1.2) in the PCC. The ignited PCC mixture enters the main combustion chamber as a high energy flame jet, igniting the lean mixture in the main chamber. Typically, natural gas fuels both the main chamber and the PCC. In the current research, a mixture of reformed natural gas (syngas) and natural gas fuels the PCC. Syngas is a broad term that refers to a synthetic gaseous fuel. In this case, syngas specifically denotes a mixture of hydrogen, carbon monoxide, nitrogen, and methane generated in a natural gas reformer. Syngas has a faster flame speed and a wider equivalence ratio range of operation than methane. Fueling the PCC with Syngas reduces combustion instabilities and misfires. This extends the overall engine lean limit, enabling further \\{NOx\\} reductions. Research results presented are aimed at quantifying the benefits of syngas PCC fueling. A model is developed to calculate the equivalence ratio in the PCC for different mixtures and flowrates of fuel. An electronic injection valve is used to supply the PCC with syngas. The delivery pressure, injection timing, and flow rate are varied to optimize PCC equivalence ratio. The experimental results show that supplying the PCC with 100% syngas improves combustion stability by 21% compared to natural gas PCC fueling. A comparison at equivalent combustion stability operating points between 100% syngas and natural gas shows an 87% reduction in \\{NOx\\} emissions for 100% syngas PCC fueling compared to natural gas PCC fueling.

Mathew D. Ruter; Daniel B. Olsen; Mark V. Scotto; Mark A. Perna

2012-01-01T23:59:59.000Z

283

Effect of metal oxide and oxygen on the growth of single-walled carbon nanotubes by electric arc discharge  

Science Journals Connector (OSTI)

The effect of oxygen on the growth of single-walled carbon nanotubes was studied with Ni–Co alloy powder as catalyst under helium atmosphere of 500 Torr by electric arc discharge. The oxygen included in nickel or...

Delong He; Yongning Liu; Tingkai Zhao; Jiewu Zhu…

2008-03-01T23:59:59.000Z

284

Sorption, Dilation, and Partial Molar Volumes of Carbon Dioxide and Ethane in Cross-Linked Poly(ethylene oxide)  

Science Journals Connector (OSTI)

First, carbon dioxide is a common impurity in natural gas that must be removed for heating value improvement. ... A database of PMV values for these two gases in liquids and rubbery polymers was constructed, and a correlation between PMV and solubility parameter was observed, so the chemical structure of the polymer can influence the PMV of the sorbed gas. ... Cylinders of ethane (99% purity) and carbon dioxide (99.999% purity) were purchased from Airgas Southwest Inc. (Corpus Christi, TX). ...

Cláudio P. Ribeiro, Jr.; Benny D. Freeman

2008-11-07T23:59:59.000Z

285

Wear Behavior of Plasma-Sprayed Carbon Nanotube-Reinforced Aluminum Oxide Coating in Marine and High-Temperature Environments  

Science Journals Connector (OSTI)

Plasma-sprayed aluminum oxide (Al2O3) coatings offer excellent wear resistance, corrosion resistance, heat, and thermal...1-6...). These coatings have to operate under severe conditions, such as high load, high s...

Anup Kumar Keshri; Arvind Agarwal

2011-12-01T23:59:59.000Z

286

STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH  

SciTech Connect (OSTI)

The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; the effect of various low-NOx firing modes on ash properties and adsorptivity; and the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. This first project period, experiments were carried out to better understand the fundamental nature of the ozonation effect on ash. Carbon surfaces were characterized by surfactant adsorption, and by X-ray Photoelectron Spectroscopy before and after oxidation, both by air at 440 C and by ozone at room temperature. The results strongly suggest that the beneficial effect of ozonation is in large part due to chemical modification of the carbon surfaces.

Robert Hurt; Eric Suuberg; John Veranth

2001-12-26T23:59:59.000Z

287

Elementary Steps and Site Requirements for NOx Adsorption and Oxidation on Metal and Oxide Surfaces  

E-Print Network [OSTI]

Ed. ), CRC Handbook of Chemistry and Physics, 89 th ed. ,Haynes, CRC Handbook of Chemistry and Physics, 91st Edition,Haynes, CRC Handbook of Chemistry and Physics, 91st Edition,

Weiss, Brian M.

2010-01-01T23:59:59.000Z

288

Enhanced rate capability of LiMn0.9Mg0.1PO4 nanoplates by reduced graphene oxide/carbon double coating for Li-ion batteries  

E-Print Network [OSTI]

March 2014 Available online 12 March 2014 Keywords: Li-ion battery LiMnPO4 Reduced graphene oxide ChargeEnhanced rate capability of LiMn0.9Mg0.1PO4 nanoplates by reduced graphene oxide/carbon double coating for Li-ion batteries Sungun Wi a , Jaewon Kim a , Seunghoon Nam a , Joonhyeon Kang a , Sangheon

Park, Byungwoo

289

Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615  

SciTech Connect (OSTI)

Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

Wayland, B.B.

2009-08-31T23:59:59.000Z

290

DOE/EA-1472: Finding of No Significant Impact for the Commercial Demonstration of the Low NOx Burner/Separated Over-Fire Air Integration System Emission Reduction Technology (03/11/03)  

Broader source: Energy.gov (indexed) [DOE]

IMPACT IMPACT COMMERCIAL DEMONSRATION OF THE LOW NOx BURNER/SEPARATED OVER- FIRE AIR (LNB/SOFA) INTEGRATON SYSTEM EMISSION REDUCTION TECHNOLOGY HOLCOMB STATION SUNFLOWER ELECTRIC POWER CORPORATION FINNEY COUNTY, KANSAS AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), to analyze the potential impacts of the commercial application of the Low-NOx Burner/Separated Over-Fire Air (LNB/SOFA) integration system to achieve nitrogen oxide (NOx) emissions reduction at Sunflower's Holcomb Unit No. 1 (Holcomb Station), located near Garden City, in Finney County, Kansas. The Holcomb Station would be modified in three distinct phases to demonstrate the synergistic effect of layering NO,

291

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control  

Science Journals Connector (OSTI)

Diesel Aftertreatment Modeling:? A Systems Approach to NOx Control ... Despite these challenges, the proposed system was able to make several advances:? (1) meeting the T2B5 CO, HC, and PM standards; (2) quantifying the ability to meet T2B5 NOx levels with a more durable DOC and a rapid warm-up strategy to heat the exhaust, especially during the initial cold-start portion of the Federal Test Procedure (FTP) drive cycle. ... The remainder of this work is organized as follows:? The formulation, calibration, and validation of the DOC and SCR models are presented in section 2. The DOC and SCR models are combined for an analysis of the AT system as a whole in section 3. The final section of the article summarizes the results and offers some general conclusions. ...

Santhoji R. Katare; Joseph E. Patterson; Paul M. Laing

2007-03-16T23:59:59.000Z

292

Low Temperature Deposition of Metal Oxide Thin Films in Supercritical Carbon Dioxide using Metal-organic Precursors  

E-Print Network [OSTI]

and are driven by the energy provided by a heated substrate. Both these vacuum-based techniques require in the precursor adsorption, oxidation and by-product desorption. [5] Use of solvation energy may provide a viable. Pressurized CO2 was delivered using an ISCO 260D syringe pump through a high- pressure manifold. Resistive

Gougousi, Theodosia

293

Influence of operating conditions and coal properties on \\{NOx\\} and N2O emissions in pressurized fluidized bed combustion of subbituminous coals  

Science Journals Connector (OSTI)

This experimental study is aimed at finding effects of operating conditions in PFBC on nitrogen oxide emissions for subbituminous coals differing in ash content/composition, combustion/gasification reactivities and in particle size distribution. The experiments have been done on a smaller laboratory apparatus with ID=8 cm. The effects of operating pressure (0.1–1 MPa), temperature of the fluidized bed (800–900 °C), freeboard temperature and oxygen concentration (3–10 vol.%) on the nitrogen oxides emissions are relatively complex, coupled with temperature of burning coal particles. The coal ash content/composition (esp. CaO and Fe2O3) and fly ash freeboard concentration play an important role in formation/destruction chemistry of both NO and N2O. The \\{NOx\\} emissions decrease with increasing operating pressure at the same volumetric oxygen concentration and temperature. Temperature, volatile content, reactivities of coals and ash composition are the most important factors for N2O emissions. The N2O emissions are either almost constant or can exhibit a maximum at increasing operating pressure. Influence of increasing oxygen concentration on \\{NOx\\} and N2O emissions is more pronounced at lower operating pressures, esp. for the less reactive, medium ash coal. The particle size distribution of the coal (influence of coal dust) can cause characteristic changes in \\{NOx\\} and N2O emissions in PFBC, esp. at lower combustion temperatures (800–840 °C). The emission changes are dependent on ash properties/composition.

Karel Svoboda; Michael Poho?elý

2004-01-01T23:59:59.000Z

294

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard  

Gasoline and Diesel Fuel Update (EIA)

3 3 ERRATA Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: Sulfur Dioxide, Nitrogen Oxides, Carbon Dioxide, and Mercury and a Renewable Portfolio Standard July 2001 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Contacts This report was prepared by the Office of Integrated Analysis and Forecasting, Energy Information Adminis- tration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler @eia.doe.gov), Director of the Office of Integrated Analysis and Forecasting, Scott B. Sitzer (202/586-2308,

295

Three Dimensional CFD Model of a Planar Solid Oxide Electrolysis Cell for Co-Electrolysis of Steam and Carbon-Dioxide  

SciTech Connect (OSTI)

A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE). A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. An experimental study is also being performed at the INL to assess the SOE. Model results provide detailed profiles of temperature, Nernst potential, operating potential, anode-side gas composition, cathode-side gas composition, current density and syn-gas production over a range of stack operating conditions. Typical results of current density versus cell potential, cell current versus H2 and CO production, temperature, and voltage potential are all presented within this paper. Plots of mole fraction of CO2, CO, H2, H2O, O2, are presented. Currently there is strong interest in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. This process takes the carbon-neutral approach where the amount of CO2 in the atmosphere does not increase. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen. In the mean time, with the price of oil currently over $70 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis or thermochemical processes, using high-temperature nuclear process heat. In order to achieve competitive efficiencies, both processes require high-temperature operation (~850°C). High-temperature electrolytic CO2 and water splitting supported by nuclear process heat and electricity has the potential to produce syn-gas with an overall system efficiency near those of the thermochemical processes. Specifically, a high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to

G. Hawkes; J. O'Brien; C. Stoots; S. Herring; R. Jones

2006-11-01T23:59:59.000Z

296

Exhaust-catalyst development for methanol-fueled vehicles. II. Synergism between palladium and silver in methanol and carbon monoxide oxidation over an alumina-supported palladium-silver catalyst  

SciTech Connect (OSTI)

Methanol and carbon monoxide oxidation were examined over 0.01 Pd, 5% Ag, and 0.01% Pd/5% Ag catalysts - all supported on ..gamma..-alumina. The bimetallic catalyst showed greater CO and CH/sub 3/OH oxidation activity than either of the single-component catalysts; moreover, the Pd and Ag interacted synergistically in the bimetallic catalyst to produce greater CO and CH/sub 3/OH oxidation rates and lower yields of methanol partial oxidation products than expected from a mixture of the single-component catalysts. Temperature-programmed oxidation experiments and reactivity experiments involving changes in O/sub 2/ partial pressure both provided evidence that the Pd-Ag synergism results from Pd promoting the rate of O/sub 2/ adsorption and reaction with CO and CH/sub 3/OH on Ag. The data also indicate that virtually all of the Pd in the bimetallic catalyst is present in Pd-Ag crystallites.

McCabe, R.W.; Mitchell, P.J.

1987-02-01T23:59:59.000Z

297

BASIC ENGINEERING RESEARCH FOR D&D OF R REACTOR STORAGE POND SLUDGE: ELECTROKINETICS, CARBON DIOXIDE EXTRACTION, AND SUPERCRITICAL WATER OXIDATION  

SciTech Connect (OSTI)

Large quantities of mixed low level waste (MLLW) that fall under the Toxic Substances Control Act (TSCA) exist and will continue to be generated during D&D operations at DOE sites across the country. Currently, the volume of these wastes is approximately 23,500 m3, and the majority of these wastes (i.e., almost 19,000 m3) consist of PCBs and PCB-contaminated materials. Further, additional PCB-contaminated waste will be generated during D&D operations in the future. The standard process for destruction of this waste is incineration, which generates secondary waste that must be disposed, and the TSCA incinerator at Oak Ridge has an uncertain future. Beyond incineration, no proposed process for the recovery and/or destruction of these persistent pollutants has emerged as the preferred choice for DOE cleanup. The main objective of the project was to investigate and develop a deeper understanding of the thermodynamic and kinetic reactions involved in the extraction and destruction of polychlorinated biphenyls (PCBs) from low-level mixed waste solid matrices in order to provide data that would permit the design of a combined-cycle extraction/destruction process. The specific research objectives were to investigate benign dense-fluid extraction with either carbon dioxide (USC) or hot water (CU), followed by destruction of the extracted PCBs via either electrochemical (USC) or hydrothermal (CU) oxidation. Two key advantages of the process are that it isolates and concentrates the PCBs from the solid matrices (thereby reducing waste volume greatly and removing the remaining low-level mixed waste from TSCA control), and little, if any, secondary solvent or solid wastes are generated. This project was a collaborative effort involving the University of South Carolina (USC), Clemson University (CU), and Westinghouse Savannah River Company (WSRC) (including the Savannah River Technology Center, Facilities Decommissioning Division and Regulatory Compliance). T he project was directed and coordinated by the South Carolina Universities Research and Education Foundation (SCUREF), a consortium of the four public research universities in South Carolina. The original plan was to investigate two PCB extraction processes (supercritical carbon dioxide and hot, pressurized water) and two PCB destruction processes (electrochemical oxidation and hydrothermal oxidation). However, at approximately the mid-point of the three year project, it was decided to focus on the more promising extraction process (supercritical carbon dioxide) and the more promising destruction process (supercritical water oxidation). This decision was taken because the investigation of two processes simultaneously by each university was stretching resources too thin, and because the electrochemical oxidation process needed more concentrated research before it would be ready for application to PCB destruction. The solid matrix chosen for experimental work was Toxi-dry, a commonly used adsorbent made from plant material that is used in cleanup of spills and/or liquid solvents. The Toxi-dry was supplied by the research team member from the Facilities Decommissioning Division, WSRC. This adsorbent is a major component of job control waste.

Matthews, Michael A.; Bruce,David; Davis,Thomas; Thies, Mark; Weidner, John; White, Ralph

2001-12-31T23:59:59.000Z

298

Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1  

SciTech Connect (OSTI)

The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite sorption sites proving to be of secondary importance. The Groundwater Geochemistry ROM was developed using nonlinear regression to fit the response surface with a quadratic polynomial. The goodness of fit was excellent for the CO2 flux to the atmosphere, and very good for predicting the volumes of groundwater exceeding the pH, TDS, As, Cd and Pb threshold values.

Bacon, Diana H.

2013-03-31T23:59:59.000Z

299

Dispersion toughened silicon carbon ceramics  

DOE Patents [OSTI]

Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

Wei, G.C.

1984-01-01T23:59:59.000Z

300

Catalytic oxidation of carbon monoxide over Ir/SiO/sub 2/. An in situ infrared and kinetic study  

SciTech Connect (OSTI)

The oxidation of CO on a highly dispersed Ir/SiO/sub 2/ catalyst has been studied both in a Pyrex microreactor and by using an in situ infrared cell-reactor. Multiple steady states obtained under conditions of increasing and decreasing CO partial pressure were observed to lead to reaction rate hysteresis. The area under the hysteresis loop is strongly dependent on reaction temperature. This is explained by invoking competitive adsorption between CO and O/sub 2/ as a function of temperature. Self-sustained oscillations were obtained when certain conditions of partial pressure and temperature were met. Quantitative estimates of fluctuations in surface coverage and temperature during these oscillations were 10% and 3K, respectively. CO islands of reactivity were not observed under the conditions of this study. The presence of higher oxidation states of IR could not be unequivocally determined by using infrared spectroscopy. 29 references, 8 figures, 2 tables.

Saymeh, R.A.; Gonzalez, R.D.

1986-02-13T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Chelating agent assisted heat treatment of carbon supported cobalt oxide nanoparticle for use as cathode catalyst of polymer electrolyte membrane fuel cell (PEMFC)  

Science Journals Connector (OSTI)

Cobalt-based catalysts for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) have been successfully incorporated cobalt oxide (Co3O4) onto Vulcan XC-72 carbon powder by thermal decomposition of Co–ethylenediamine complex (ethylenediamine, NH2CH2CH2NH2, denoted en) at 850 °C. The catalysts were prepared by adsorbing the cobalt complexes [Co(en)(H2O)4]3+, [Co(en)2(H2O)2]3+ and [Co(en)3]3+ on commercial XC-72 carbon black supports, loading amount of Co with respect to carbon black was about 2%, the resulting materials have been pyrolyzed under nitrogen atmosphere to create CoOx/C catalysts, donated as E1, E2, and E3, respectively. The composite materials were characterized using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS). Chemical compositions of prepared catalysts were determined using inductively-coupled plasma-atomic emission spectroscopy (ICP-AES). The catalytic activities for ORR have been analyzed by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). The electrocatalytic activity for oxygen reduction of E2 is superior to that of E1 and E3. Membrane electrode assemblies (MEAs) containing the synthesized CoOx/C cathode catalysts were fabricated and evaluated by single cell tests. The E2 cathode performed better than that of E1 and E3 cathode. This can be attributed to the enhanced activity for ORR, in agreement with the composition of the catalyst that CoO co-existed with Co3O4. The maximum power density 73 mW cm?2 was obtained at 0.3 V with a current density of 240 mA cm?2 for E2 and the normalized power density of E2 is larger than that that of commercial 20 wt.% Pt/C-ETEK.

Chia-Hung Huang; Shyh-Jiun Liu; Weng-Sing Hwang

2011-01-01T23:59:59.000Z

302

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

303

High-Throughput Program for the Discovery of NOx Reduction Catalysts...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2004deerblint.pdf More Documents & Publications WA02042GENERALMOTORSPOWERTRAINDIVWaiverofDomestic.pdf Heavy-Duty NOx Emissions Control: Reformer-Assisted vs....

304

Boosted HCCI for High Power without Engine Knock, and with Ultra-Low NOX Emissions  

Broader source: Energy.gov [DOE]

Advanced engines using HCCI or HCCI-like combustion can provide both high efficiencies and very low emissions of NOX and PM

305

Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...  

Broader source: Energy.gov (indexed) [DOE]

Combustion and Lean NOx Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment....

306

E-Print Network 3.0 - aluminosilicates nox reduction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

RELATIONSHIP BETWEEN Summary: Non-Catalytic Reduction SNCR NOx control throughout the United States and Canada. They correspond... explain why mass balances are not an appro...

307

Flexible CHP System with Low NOx, CO and VOC Emissions | Department...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Flexible CHP System with Low NOx, CO and VOC Emissions Introduction A combined heat and power (CHP) system can be a financially attractive energy option for many...

308

Reduce NOx and Improve Energy Efficiency, Software Tools for Industry, Industrial Technologies Program (ITP) (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes how the Industrial Technologies Program NOx and Energy Assessment Tool (NxEAT) can help petroleum refining and chemical plants improve energy efficiency.

Not Available

2008-12-01T23:59:59.000Z

309

Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning  

Broader source: Energy.gov [DOE]

Presents the reliationship between Pt particle size and NOx storage performance over model catalysts. Novel reaction protocol designed to decouple effects of thermal deactivation and incomplete desulfation.

310

E-Print Network 3.0 - a-induced oxidative liver Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tect rats... . Evaluation of oxidative stress during apoptosis and necrosis caused by carbon tetrachloride in rat liver... oxide in acute liver injury induced by carbon...

311

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network [OSTI]

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

312

Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2  

Reports and Publications (EIA)

This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

2001-01-01T23:59:59.000Z

313

E-Print Network 3.0 - ammonium carbonate leaching Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

all oxidizing agents Chlorates ammonium salts... compounds, fulminic acid Sodium carbon tetrachloride, carbon dioxide, water Sodium nitrite ammonium nitrate... , calcium...

314

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb per million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. A revised subcontract was executed with BBP to reflect changes in the pilot testing program. Modeling activities were continued to develop and verify revised design approaches for both the Preheat gas combustor and PC burner. Reactivation of the pilot test system was then begun with BBP personnel. During the previous reporting period, reactivation of the pilot test system was completed with the modified Preheat gas combustor. Following shakedown of the modified gas combustor alone, a series of successful tests of the new combustor with PRB coal using the original PC burner were completed. NOx at the furnace exit was reduced significantly with the modified gas combustor, to as low as 150 ppm with only 36 ppm CO (both corrected to 3% O2). Concurrent with testing, GTI and BBP collaborated on development of two modified designs for the PC burner optimized to fire preheated char and pyrolysis products from the Preheat gas combustor. During the current reporting period, one of the two modified PC burner designs was fabricated and installed in the pilot test facility. Testing of the modified pilot system (modified gas combustor and modified PC burner) during the quarter included 38 tests with PRB coal. NOx reduction was significantly improved to levels as low as 60-100 ppmv with CO in the range of 35-112 ppmv without any furnace air staging.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-01-31T23:59:59.000Z

315

Development and Field-Scale Optimization of a Honeycomb Zeolite Rotor Concentrator/Recuperative Oxidizer for the Abatement of Volatile Organic Carbons from Semiconductor Industry  

Science Journals Connector (OSTI)

Also the developed rotor performance’s was evaluated in the field; (2) Direct Fired Thermal Oxidizer (DFTO), Recuperative Oxidizer (RO), Regenerative Thermal Oxidizer (RTO) and Regenerative Catalytic oxidizer (RCO) are the available incinerators and the RO was selected as the oxidizer in this work; (3) The overall performance of the developed rotor/oxidizer was explored in a field scale under varying conditions; (4) The energy saving strategy was fulfilled by reducing heat loss from the oxidizer and recovering heat from the exhaust gas. ... The available types of oxidizers include Direct Fired Thermal Oxidizer (DFTO), Recuperative Oxidizer (RO), Regenerative Thermal Oxidizer (RTO) and Regenerative Catalytic oxidizer (RCO). ... cost models were derived for recuperative thermal (TO) and regenerative thermal oxidizers (RTO). ...

Ji Yang; Yufeng Chen; Limei Cao; Yuling Guo; Jinping Jia

2011-11-17T23:59:59.000Z

316

SOx/NOx sorbent and process of use  

DOE Patents [OSTI]

An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

1993-01-19T23:59:59.000Z

317

An infrared spectroscopy study of carbon monoxide adsorption on. alpha. -chromia surfaces: Probing oxidation states of coordinatively unsaturated surface cations  

SciTech Connect (OSTI)

CO adsorption on thermoevacuated, H{sub 2}-reduced and O{sub 2}-treated {alpha}-chromia surfaces was studied by IR spectroscopy in the temperature range 77-298 K. Coordinatively unsaturated (cus) Cr{sup 3+} cation sites, probably in 3-coordinate and to a much lesser extent 5-coordinate states, are the adsorption sites on H{sub 2}-reduced {alpha}-Cr{sub 2}O{sub 3}. The surface containing excess oxygen also exposes cus Cr{sup 4+} and Cr{sup 5+} sites. An empirical procedure is described which permits the determination of oxidation state and coordination number of the cus surface sites. This procedure is based on a correlation between C-O stretching frequency and electric field strength exerted by the cation. The latter is calculated from Pauling's strength of the electrostatic bond and effective ionic radii, both of which take the cation coordination into account.

Zaki, M.I.; Knoezinger, H. (Universitaet Muenchen (West Germany))

1989-10-01T23:59:59.000Z

318

On the NOx production by laboratory electrical discharges and lightning Vernon Cooraya,, Mahbubur Rahman a  

E-Print Network [OSTI]

in estimating the global production of NOx by lightning flashes, including field measurements carried out during influence extrapolation of laboratory data to lightning flashes. Second, an estimation of the NOx yield per lightning flash is made by treating the lightning flash as a composite event consisting of several discharge

Florida, University of

319

Measurements of NOX produced by rocket-triggered lightning M. Rahman,1  

E-Print Network [OSTI]

lightning flashes were triggered using the rocket- and-wire technique at the International Center atmosphere. [3] A direct measurement of the NOX generated by a natural lightning flash is impractical because generated by lightning flashes. Due to a large number of uncertainties involved, the estimates of global NOX

Florida, University of

320

A Novel Technology for the Reduction of NOx on Char by Microwaves  

E-Print Network [OSTI]

of these applications. The technology is directed at NOx reduction but may also address other pollutants like SO2. The technology employees char, a heat treated and devolitilized form of coal, to adsorb NOx from the flue (or waste) gas. Adsorption of greater than 99...

Buenger, C.; Peterson, E.

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Improvement of lightning NOx in the TM5 global chemistry transport model  

E-Print Network [OSTI]

, a key greenhouse gas, and for the formation of the hydroxyl28 radical, which removes methane, also a key greenhouse gas. Estimates of the global lightning NOx production vary29 by an order of magnitude interpreting the lighting NOx contribu-36 tion from satellite and aircraft observations of NO2 in comparison

Haak, Hein

322

Development of a Stand-Alone Urea-SCR System for NOx Reduction in Marine Diesel Engines  

Broader source: Energy.gov [DOE]

Stand-alone urea SCR system was developed for marine diesel engines and showed a 50-percent reduction in NOx.

323

Development of Compact Gaseous Sensors with Internal Reference for Monitoring O2 and NOx in Combustion Environments  

Broader source: Energy.gov [DOE]

Compact sensors have been developed to allow for real-time monitoring of O2 and NOx during combustion.

324

2004 Conference on Reburning for NOX Control Reburning on Trial  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2004 Conf. on Reburning for NOx Control Reburning on Trial 2004 Conf. on Reburning for NOx Control Reburning on Trial May 18, 2004 Table of Contents Disclaimer Papers and Presentations Reburning Overview Commercial Reburning Experience Biomass Reburning Other Applications of Reburning Posters Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

325

NETL: PPII - Integration of Low-NOx Burners with an Optimization Plan for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion - Project Brief [PDF-72KB] Sunflower Electric Power Corp., Garden City, Finney County, KS PROJECT FACT SHEET Achieving New Source Performance Standards (NSPS) Through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion [PDF-260KB] (Oct 2008) PROGRAM PUBLICATIONS Final Report Achieving NSPS Emission Standards Through Integration of Low NOx Burners with an Optimization Plan for Boiler Combustion [PDF-3.4MB] (June 2006) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Achieving New Source Performance Standards (NSPS) Emission Standards through Integration of Low-NOx Burners with an Optimization Plan for Boiler Combustion: A DOE Assessment [PDF-1.4MB] (Nov 2006)

326

Reduction of iron-oxide-carbon composites: part II. Rates of reduction of composite pellets in a rotary hearth furnace simulator  

SciTech Connect (OSTI)

A new ironmaking concept is being proposed that involves the combination of a rotary hearth furnace (RHF) with an iron-bath smelter. The RHF makes use of iron-oxide-carbon composite pellets as the charge material and the final product is direct-reduced iron (DRI) in the solid or molten state. This part of the research includes the development of a reactor that simulated the heat transfer in an RHF. The external heat-transport and high heating rates were simulated by means of infrared (IR) emitting lamps. The reaction rates were measured by analyzing the off-gas and computing both the amount of CO and CO{sub 2} generated and the degree of reduction. The reduction times were found to be comparable to the residence times observed in industrial RHFs. Both artificial ferric oxide (PAH) and naturally occurring hematite and taconite ores were used as the sources of iron oxide. Coal char and devolatilized wood charcoal were the reductants. Wood charcoal appeared to be a faster reductant than coal char. However, in the PAH-containing pellets, the reverse was found to be true because of heat-transfer limitations. For the same type of reductant, hematite-containing pellets were observed to reduce faster than taconite-containing pellets because of the development of internal porosity due to cracking and fissure formation during the Fe2O{sub 3}-to-Fe3O{sub 4} transition. This is, however, absent during the reduction of taconite, which is primarily Fe3O{sub 4}. The PAH-wood-charcoal pellets were found to undergo a significant amount of swelling at low-temperature conditions, which impeded the external heat transport to the lower layers. If the average degree of reduction targeted in an RHF is reduced from 95 to approximately 70 pct by coupling the RHF with a bath smelter, the productivity of the RHF can be enhanced 1.5 to 2 times. The use of a two- or three-layer bed was found to be superior to that of a single layer, for higher productivities.

Halder, S.; Fruehan, R.J. [Praxair Inc., Tonawanda, NY (United States). Praxair Technological Center

2008-12-15T23:59:59.000Z

327

Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries  

DOE Patents [OSTI]

A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li.sub.1+xNi.sub..alpha.Co.sub..beta.Mn.sub..gamma.M'.sub..delta.O.sub.yF- .sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the .alpha. between 0 and 1, the .beta. between 0 and 1, the .gamma. between 0 and 2, the .delta. between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.

Kang, Sun-Ho (Naperville, IL); Amine, Khalil (Downers Grove, IL)

2008-10-14T23:59:59.000Z

328

Effectiveness of Diesel Oxidation Catalyst in Reducing HC and CO Emissions from Reactivity Controlled Compression Ignition  

SciTech Connect (OSTI)

Reactivity Controlled Compression Ignition (RCCI) has been shown to allow for diesel-like or better brake thermal efficiency with significant reductions in nitrogen oxide (NOX) particulate matter (PM) emissions. Hydrocarbon (HC) and carbon monoxide (CO) emission levels, on the other hand, are similar to those of port fuel injected gasoline engines. The higher HC and CO emissions combined with the lower exhaust temperatures with RCCI operation present a challenge for current exhaust aftertreatments. The reduction of HC and CO emissions in a lean environment is typically achieved with an oxidation catalyst. In this work, several diesel oxidation catalysts (DOC) with different precious metal loadings were evaluated for effectiveness to control HC and CO emissions from RCCI combustion in a light-duty multi-cylinder engine operating on gasoline and diesel fuels. Each catalyst was evaluated in a steady-state engine operation with temperatures ranging from 160 to 260 C. A shift to a higher light-off temperature was observed during the RCCI operation. In addition to the steady-state experiments, the performances of the DOCs were evaluated during multi-mode engine operation by switching from diesel-like combustion at higher exhaust temperature and low HC/CO emissions to RCCI combustion at lower temperature and higher HC/CO emissions. High CO and HC emissions from RCCI generated an exotherm keeping the catalyst above the light-off temperature.

Prikhodko, Vitaly Y [ORNL; Curran, Scott [ORNL; Parks, II, James E [ORNL; Wagner, Robert M [ORNL

2013-01-01T23:59:59.000Z

329

Basic Engineering Research for D and D of R Reactor Storage Pond Sludge: Electrokinetics, Carbon Dioxide Extraction, and Supercritical Water Oxidation  

SciTech Connect (OSTI)

Large quantities of mixed low level waste (MLLW) that fall under the Toxic Substances Control Act (TSCA) exist and will continue to be generated during D and D operations at DOE sites across the country. The standard process for destruction of MLLW is incineration, which has an uncertain future. The extraction and destruction of PCBs from MLLW was the subject of this research Supercritical Fluid Extraction (SFE) with carbon dioxide with 5% ethanol as cosolvent and Supercritical Waster Oxidation (SCWO) were the processes studied in depth. The solid matrix for experimental extraction studies was Toxi-dry, a commonly used absorbent made from plant material. PCB surrogates were 1.2,4-trichlorobenzene (TCB) and 2-chlorobiphenyl (2CBP). Extraction pressures of 2,000 and 4,000 psi and temperatures of 40 and 80 C were studied. Higher extraction efficiencies were observed with cosolvent and at high temperature, but pressure little effect. SCWO treatment of the treatment of the PCB surrogates resulted in their destruction below detection limits.

Michael A. Matthews; David A. Bruce,; Thomas A. Davis; Mark C. Thies; John W. Weidner; Ralph E. White

2002-04-01T23:59:59.000Z

330

Basic Engineering Research for D&D of R. Reactor Storage Pond Sludge: Electrokinetics, Carbon Dioxide Extraction, and Supercritical Water Oxidation  

SciTech Connect (OSTI)

Collaborating researchers at the University of South Carolina (USC), Clemson University (CU), and the Savannah River Site (SRS) are investigating the fundamentals of a combined extraction and destruction process for the decontamination and decommissioning (D&D) of PCB-contaminated materials as found at DOE sites. Currently, the volume of PCBs and PCB contaminated wastes at DOE sites nationwide is approximately 19,000 m3. While there are a number of existing and proposed processes for the recovery and/or destruction of these persistent 4 pollutants, none has emerged as the preferred choice. Therefore, this research focuses on combining novel processes to solve the problem. The research objectives are to investigate benign dense-fluid extraction with either carbon dioxide (USC) or hot water (CU), followed by destruction of the extracted PCBs via either electrochemical (USC) or hydrothermal (CU) oxidation. Based on the results of these investigations, a combined extraction and destruction process that incorporates the most successful elements of the various processes will be recommended for application to contaminated DOE sites.

Hamilton, Edward A.; Bruce, David A.; Oji, Lawrence; White, Ralph E.; Matthews, Michael A.; Thies, Mark C.

1999-06-01T23:59:59.000Z

331

Diesel Particulate Oxidation Model: Combined Effects of Fixed...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research...

332

Low NOx burner retrofits and enhancements for a 518 MW oil and gas fired boiler  

SciTech Connect (OSTI)

Low NOx oil/gas burners originally supplied to Jacksonville Electric Authority, Northside No. 3 .500 MW unit, were based on a duplex air register design with lobed spray oil atomizers providing additional fuel staging. Although the burners could meet the targeted NOx levels of 0.3 and 0.2 lbs/10{sup 6} BTU on oil and gas respectively. There was insufficient margin on these NOx levels to enable continuous low NOx operation to be achieved. Further burner development was undertaken based on improved aerodynamic control within the burner design to give an approximate 25% improvement in NOx emission reduction thus providing an adequate operating margin. This `RoBTAS` (Round Burner with Tilted Air Supply) burner design based on techniques developed successfully for front wall coal firing applications achieved the required NOx reductions in full scale firing demonstrations on both heavy fuel oil and natural gas firing. The paper describes the development work and the subsequent application of the `RoBTAS` burners to the Northside No. 3 boiler. The burner will also be test fired on Orimulsion fuel and thus the comparison between heavy fuel oil firing and Orimulsion firing under ultra low NOx conditions will be made.

King, J.J. [Jacksonville Electric Authority, FL (United States); Allen, J.W.; Beal, P.R. [International Combustion Ltd., Derby (United Kingdom). Rolls-Royce Industrial Power Group

1995-12-31T23:59:59.000Z

333

Low NOx nozzle tip for a pulverized solid fuel furnace  

DOE Patents [OSTI]

A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

2014-04-22T23:59:59.000Z

334

METHANE de-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The project seeks to develop and validate a new pulverized coal combustion system to reduce utility PC boiler NOx emissions to 0.15 lb/million Btu or less without post-combustion flue gas cleaning. Work during previous reporting periods completed the design, installation, shakedown and initial PRB coal testing of a 3-million Btu/h pilot system at BBP's Pilot-Scale Combustion Facility (PSCF) in Worcester, MA. Based on these results, modifications to the gas-fired preheat combustor and PC burner were defined, along with a modified testing plan and schedule. During the current reporting period, BBP's subcontract was modified to reflect changes in the pilot testing program, and the modifications to the gas-fired preheat combustor were completed. The Computational Fluid Dynamics (CFD) modeling approach was defined for the combined PC burner and 3-million Btu/h pilot system. Modeling of the modified gas-fired preheat combustor was also started.

Joseph Rabovitser; Bruce Bryan; Serguei Nester; Stan Wohadlo

2002-04-29T23:59:59.000Z

335

METHANE DE-NOX FOR UTILITY PC BOILERS  

SciTech Connect (OSTI)

The primary focus for the project continues to be on developing a PC PREHEAT system design suitable for use with caking coals and readying the 100 MMBtu/h CBTF for testing with noncaking PRB coal. During the current quarter, twenty-two pilot tests were conducted with Central Appalachian (CA) caking coal. The objective for these tests was to achieve continuous operation of the pilot system at its design coal feed rate of 156 lb/h, without plugging or agglomeration in the combustor. One combustor air distribution method tested achieved continuous operation at 110 lb/hr, and inspection of the combustor afterward indicated that this method has potential to solve the caking problem. The NOx results from the pilot caking coal runs indicate that even greater NOx reduction is possible with CA coal than with the PRB coal tested, to levels near 100 ppmv or lower at 4-6% exit oxygen. It was therefore decided to conduct additional pilot tests of the air distribution method to determine how to incorporate this into a workable CA combustor design. Based on current weather and manpower restrictions at the site, this pilot testing is expected to be started in February. The design for the 100 MMBtu/h unit for PRB testing in the CBTF was completed and fabrication and installation started during the quarter. While significant progress has been made in the installation of the unit, weather and combustor fabrication delays are expected to move the start of large-scale testing with PRB coal into February, which will push the project completion date beyond the current 3/30/04 end date. GTI is in the process of developing a revised project schedule and estimated cost to complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2004-02-06T23:59:59.000Z

336

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The primary focus for the project during the quarter was shakedown testing of the large-scale coal preheater prototype in the CBTF with non-caking PRB coal. Additional pilot-scale tests were conducted in the PSCF in support of developing a preheating system design suitable for use with caking coals. Thirty-two additional pilot tests were conducted during the quarter with caking coal. These tests further evaluated the use of the air-bleed and indirect air-cooled liner designs to reduce or eliminate combustor plugging with caking coal. The air-bleed configurations tested used air injection holes perpendicular to the liner's longitudinal axis with the number, size and air flow though the air-bleed holes varied to determine the effect on combustor plugging. The indirect cooling configurations tested included a stainless steel liner with spiral fins in the annular space between the liner and the combustor wall, and a silicon carbide liner without fins. Continuous pilot operation was maintained for up to 30 minutes at a coal feed rate of 50 lb/h with the air-bleed liner. The best result achieved was for the stainless steel indirect air-cooled liner with 20 minutes of continuous operation at 126 lb/h of coal followed by an additional 20 minutes at 150 lb/h. The NOx results from these continue to indicate that even greater NOx reduction is possible with caking coal than with the PRB coal tested. The installation of the large-scale prototype coal preheater for PRB testing in the CBTF was completed and shakedown testing with natural gas and PRB coal started during the quarter. Stable operation of the coal system, combustor and burner were achieved at coal feed rates up to 6000 lb/h (50 MMBtu/h).

Bruce Bryan; Joseph Rabovitser Serguei Nester; Stan Wohadlo

2004-06-30T23:59:59.000Z

337

Influencing factors on NOX emission level during grate conversion of three pelletized energy crops  

Science Journals Connector (OSTI)

Abstract NOX emission behavior of three different pelletized energy crops, a herbaceous one, Brassica carinata, a short rotation coppice, Populus sp., and a blend of them, was assessed during fixed grate conversion. Measurements of NOX emissions were done at combustion conditions that yielded both thermal efficiency and CO emissions according to the European norm (EN 303-5:2012), and results compared to limits established by the Austrian deviations. Based on the experimental data, NOX results fulfilled the Austrian restrictions except during combustion of brassica, which exhibited the highest Fuel-N content. The Fuel-NOX was identified as the main formation mechanism. An opposite relation was determined between the specific NOX emissions and the Fuel-N conversion ratio obtained between the N-rich and the N-lean fuels tested here. The influence of the air supply (amount and distribution) on the NOX formation was also noticeable. In general, a higher proportion of air increased the specific NOX emissions and the Fuel-N conversion ratio. Possibilities to control the NOX emissions level by air staging were rather limited, particularly, during combustion of brassica and the blend because of their peculiarities as ash-rich fuels with high slag formation risk. For attaining an appropriate conversion of these fuels, primary air requirements substantially increased. Due to limitations found during the energy crops conversion, efforts to minimize the level of NOX emissions identified here for the troublesome fuels tested should be mainly focused on attaining both a properly designed air supply system and the grate temperature control as well as on conditioning the Fuel-N content, for instance, by blending.

Maryori Díaz-Ramírez; Fernando Sebastián; Javier Royo; Adeline Rezeau

2014-01-01T23:59:59.000Z

338

Shifting primary energy source and NOx emission location with plug-in hybrid vehicles  

Science Journals Connector (OSTI)

Plug-in hybrid vehicles (PHEVs) present an interesting technological opportunity for using non-fossil primary energy in light duty passenger vehicles, with the associated potential for reducing air pollutant and greenhouse gas emissions, to the extent that the electric power grid is fed by non-fossil sources. This perspective, accompanying the article by Thompson et al (2011) in this issue, will touch on two other studies that are directly related: the Argonne study (Elgowainy et al 2010) and a PhD thesis from Utrecht (van Vliet 2010). Thompson et al (2011) have examined air quality effects in a case where the grid is predominantly fossil fed. They estimate a reduction of 7.42 tons/day of NOx from motor vehicles as a result of substituting electric VMTs for 20% of the light duty gasoline vehicle miles traveled. To estimate the impact of this reduction on air quality they also consider the increases in NOx emissions due to the increased load on electricity generating units. The NOx emission increases are estimated as 4.0, 5.5 and 6.3 tons for the Convenience, Battery and Night charging scenarios respectively. The net reductions are thus in the 1.1–3.4 tons/day range. The air quality modelling results presented show that the air quality impact from a ground-level ozone perspective is favorable overall, and while the effect is stronger in some localities, the difference between the three scenarios is small. This is quite significant and suggests that localization of the NOx emissions to point sources has a more pronounced effect than the absolute reductions achieved. Furthermore it demonstrates that localization of NOx emissions to electricity generating units by using PHEVs in vehicle traffic has beneficial effects for air quality not only by minimizing direct human exposure to motor vehicle emissions, but also due to reduced exposure to secondary pollutants (i.e. ozone). In an electric power grid with a smaller share of fossil fired generating units, the beneficial effects would be more pronounced. In such a case, it would also be possible to realize reductions in greenhouse gas emissions. The significance of the electric power generation mix for plug-in hybrid vehicles and battery electric vehicles is a key aspect of Argonne National Laboratories' well-to-wheel study which focuses on petroleum use and greenhouse gas emissions (Elgowainy et al 2010). The study evaluates possible reductions in petroleum use and GHG emissions in the electric power systems in four major regions of the United States as well as the US average generation mix, using Argonne's GREET life-cycle analysis model. Two PHEV designs are investigated through a Powertrain System Analysis Toolkit (PSAT) model: the power-split configuration (e.g. the current Toyota Prius model with Hymotion conversion), and a future series configuration where the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle. Since the petroleum share is small in the electricity generation mix for most regions in the United States, it is possible to achieve significant reductions in petroleum use by PHEVs. However, GHG reduction is another story. In one of the cases in the study, PHEVs in the charge depleting mode and recharging from a mix with a large share of coal generation (e.g., Illinois marginal mix) produce GHG emissions comparable to those of baseline gasoline internal combustion engine vehicles (with a range from ?15% to +10%) but significantly higher than those of gasoline hybrid electric vehicles (with a range from +20% to +60%). In what is called the unconstrained charging scenario where investments in new generation capacity with high efficiency and low carbon intensity are envisaged, it becomes possible to achieve significant reductions in both petroleum use and GHG emissions. In a PhD dissertation at Utrecht University, van Vliet (2010) presents a comprehensive analysis of alternatives to gasoline and diesel by looking at various fuel and vehicle technologies. Three chapters are of particular interest from the

Deniz Karman

2011-01-01T23:59:59.000Z

339

Exergy analysis of combustion characteristics and NOx emissions of a dual-fuel engine  

Science Journals Connector (OSTI)

The combustion characteristics and NOx emissions of compression ignition engines working on a dual fuel mode are investigated numerically and their exergetic efficiencies are determined. The model has been validated with available experimental results. The simulation results show that dual fuel engine combustion and trend of NOx emissions are well predicted by the present model. Parametric study showed improvements in engine performance and an increase in NOx emissions with decreased advanced injection timing of the pilot fuel as well as with increased intake temperature and pilot fuel quantity. The maximum values for energy and exergy are found to be comparable.

Mohamed H. Morsy; Abdelrahman El-Leathy; Arif Hepbasli

2012-01-01T23:59:59.000Z

340

Definition: Reduced Sox, Nox, And Pm-2.5 Emissions | Open Energy  

Open Energy Info (EERE)

Sox, Nox, And Pm-2.5 Emissions Sox, Nox, And Pm-2.5 Emissions Jump to: navigation, search Dictionary.png Reduced Sox, Nox, And Pm-2.5 Emissions Functions that provide this benefit can lead to avoided vehicle miles, decrease the amount of central generation needed to their serve load (through reduced electricity consumption, reduced electricity losses, more optimal generation dispatch), and or reduce peak generation. These impacts translate into a reduction in pollutant emissions produced by fossil-based electricity generators and vehicles.[1] Related Terms electricity generation, reduced electricity losses, smart grid References ↑ SmartGrid.gov 'Description of Benefits' An in LikeLike UnlikeLike You like this.Sign Up to see what your friends like. line Glossary Definition Retrieved from "http://en.openei.org/w/index.php?title=Definition:Reduced_Sox,_Nox,_And_Pm-2.5_Emissions&oldid=502508

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine  

SciTech Connect (OSTI)

Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

Not Available

2004-02-01T23:59:59.000Z

342

NH3 generation over commercial Three-Way Catalysts and Lean-NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

formulations and operation for the in-situ generation of NH3, storage on a downstream SCR catalyst, and utilized to reduce the remaining NOx deer12toops.pdf More Documents &...

343

NOx Emissions of Alternative Diesel Fuels:? A Comparative Analysis of Biodiesel and FT Diesel  

Science Journals Connector (OSTI)

This study explores the diesel injection and combustion processes in an effort to better understand the differences in NOx emissions between biodiesel, Fischer?Tropsch (FT) diesel, and their blends with a conventional diesel fuel. Emissions studies were ...

James P. Szybist; Stephen R. Kirby; André L. Boehman

2005-05-14T23:59:59.000Z

344

Sulphur Removal Characteristics from a Commercial NOx Storage/Reduction Catalyst.  

E-Print Network [OSTI]

??The ability to effectively remove sulphur from sulphur-poisoned NOx storage/reduction (NSR) catalysts, while minimizing associated fuel penalties and thermal degradation, is important for commercial application… (more)

Kisinger, Darren

2009-01-01T23:59:59.000Z

345

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network [OSTI]

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

346

An experimental study on combustion processes and nox emission characteristics of the air-staged burner  

Science Journals Connector (OSTI)

The combustion processes and emission characteristics in air-staged burner...5H5N) is used to investigate the fuel NOX emission characteristics. Experiments are carried out for a wide range of operating condition...

Kook-Young Ahn; Han-Seok Kim; Eun-Seong Cho; Jin-Hyuk Ahn…

1999-06-01T23:59:59.000Z

347

Combining Low-Temperature Combustion with Lean-NOx Trap Yields...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Posters 2005deerhuff.pdf More Documents & Publications Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Reductant Utilization in a LNT + SCR...

348

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...  

Broader source: Energy.gov (indexed) [DOE]

Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Jim Parks (parksjeii@ornl.gov), Matt Swartz, Shean Huff, Brian West Oak Ridge National Laboratory...

349

Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis...

350

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network [OSTI]

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% ...

Grenfell, J L; Patzer, B; Rauer, H; Segura, A; Stadelmann, A; Stracke, B; Titz, R; Von Paris, P; Grenfell, John Lee; Griessmeier, Jean-Mathias; Patzer, Beate; Rauer, Heike; Segura, Antigona; Stadelmann, Anja; Stracke, Barbara; Titz, Ruth; Paris, Philip von

2007-01-01T23:59:59.000Z

351

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

During the current quarter, pilot-scale testing with the modified air nozzle version of the PC burner was completed with PRB coal at the Riley Power Inc. (RPI) test facility. A total of 8 different burner configurations were tested utilizing various burner air nozzle arrangements in place of the burner air channels. It was found that with the arrangements tested, a stable flame could not be maintained at coal feed rates above 100 lb/h. While it is felt that the air nozzle approach can ultimately be used effectively, in the interest of holding to the current project schedule it was decided to proceed with the balance of the project using the air channel design. The pilot-scale PC burner was therefore restored to the air-channel configuration and benchmark testing with PRB coal to confirmed previous operating results. A series of tests was then conducted with PRB and West Virginia caking coal to evaluate modifications to the gas combustor configuration and operation for improved performance with caking coal. Continuous operation was achieved with caking coal up to 50 lb/h vs. the full load target of 150 lb/h. Impingement and deposition of partially devolatilized coal occurred at various points within the combustor when the caking coal feed was increased above 50 lb/h. The 100 MMBtu/h commercial-scale prototype design was continued with coal burner design input from both RPI and VTI. Based on typical burner installation layout considerations, it was decided that the preheat combustor should be oriented horizontally on the axial centerline of the coal burner. Accordingly, the pilot gas combustor was changed to this orientation so that the pilot results with caking coal will be directly applicable to the preferred 100 MMBtu design. Testing with caking coal in the horizontal pilot combustor achieved feed rates up to 126 lb/h, although some deposition and LOI issues remain. Several promising approaches to further improve operation with caking coal were identified. NOx results with caking coal are promising, with NOx as low as 150 ppmv at exit oxygen levels of 4% and higher. The 100 MMBtu/h commercial-scale prototype design is nearing completion. Design of the caking coal version of the unit continues with additional pilot testing in support of this design expected. GTI and RPI are expediting the fabrication of the 100 MMBtu/h PRB unit in order to start testing in early- to mid-December. Inspection and repair of the 100 MMBtu/h Coal Burner Test Facility (CBTF) is nearing completion. As of mid-September, this activity was 95% complete.

Bruce Bryan; Joseph Rabovitser; Serguei Nester; Stan Wohadlo

2003-09-30T23:59:59.000Z

352

Nitrogen Oxide Emission Statements (Ohio) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) Nitrogen Oxide Emission Statements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter of the law establishes that the Ohio Environmental Protection Agency requires any facility that emits 25 tons or more of NOx and/or 25 tons or more of VOC during the calendar year and is located in a county designated as nonattainment for the National Ambient Air Quality Standards for ozone submit emission statements. Any facility that is located in a county described above is exempt from these requirements. If NOx

353

Advanced NOx Emissions Control: Control Technology - Second Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems In Situ Device for Real-Time Catalyst Deactivation Measurements in Full-Scale SCR Systems To support trends in the electric generating industry of moving from seasonal to year-round operation of Selective Catalytic Reduction (SCR) for control of NOx and mercury, as well as extending the time between generating unit outages, Fossil Energy Research Corporation (FERCo) is developing technology to determine SCR catalyst activity and remaining life without requiring an outage to obtain and analyze catalyst samples. FERCo intends to use SCR catalyst performance results measured with their in situ device at Alabama PowerÂ’s Plant Gorgas during the 2005 and 2006 ozone seasons, along with EPRIÂ’s CatReactTM catalyst management software, to demonstrate the value of real-time activity measurements with respect to the optimization of catalyst replacement strategy. Southern Company and the Electric Power Research Institute are co-funding the project.

354

Release of Ammonium and Mercury from NOx Controlled Fly Ash  

SciTech Connect (OSTI)

One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

Schroeder, K.T.; Cardone, C.R.; Kim, A.G

2007-07-01T23:59:59.000Z

355

Pilot-Scale Aftertreatment Using Nonthermal Plasma Reduction of Adsorbed NOx in Marine Diesel-Engine Exhaust Gas  

Science Journals Connector (OSTI)

Regulations governing marine diesel engine NOx emissions have recently become more stringent. As it is difficult to fulfill these requirements by combustion improvements alone, effective aftertreatment technologi...

Takuya Kuwahara; Keiichiro Yoshida…

2014-01-01T23:59:59.000Z

356

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

models 19 Technical Back-Up Slides 20 Managed by UT-Battelle for the Department of Energy * Step1: NO oxidation * Step2: SS NO x & NH 3 conversions, Parasitic NH 3...

357

Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...  

Broader source: Energy.gov (indexed) [DOE]

barriers 16 Technical Back-Up Slides 17 Managed by UT-Battelle for the Department of Energy * Step1: NO oxidation * Step2: SS NO x & NH 3 conversions, Parasitic NH 3...

358

Reinforced Carbon Nanotubes.  

DOE Patents [OSTI]

The present invention relates generally to reinforced carbon nanotubes, and more particularly to reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

Ren, Zhifen (Newton, MA); Wen, Jian Guo (Newton, MA); Lao, Jing Y. (Chestnut Hill, MA); Li, Wenzhi (Brookline, MA)

2005-06-28T23:59:59.000Z

359

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network [OSTI]

green sheet, (3) smoothing surface by chemically inducing reflow using a solvent,solvents comprised circa 35% of the weight of the feedstock materials for the green

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

360

Satellite constraints of nitrogen oxide (NOx) emissions from India based on OMI observations and WRFChem simulations  

E-Print Network [OSTI]

; Ghude et al., 2008]. Thermal power plants are the largest consumer of coal in India [Garg et al., 2001 and WRFChem simulations Sachin D. Ghude,1,2 Gabriele G. Pfister,2 Chinmay Jena,1 R.J. van der A,3 Louisa K tropospheric NO2 column retrievals over the Indian region, with tropospheric NO2 columns simulated

Haak, Hein

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network [OSTI]

the unfired ceramic sample during thermal processing steps.ceramic samples were affixed to 4” silicon “handle” wafers using the following bonding agents: thermal

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

362

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network [OSTI]

122 Table 22. Equivalent circuit model resistances for NOof the resistance elements of the equivalent circuit offersOver time, the resistance values of the equivalent circuit

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

363

METHANE de-NOX for Utility PC Boilers  

SciTech Connect (OSTI)

The overall project objective is the development and validation of an innovative combustion system, based on a novel coal preheating concept prior to combustion, that can reduce NO{sub x} emissions to 0.15 lb/million Btu or less on utility pulverized coal (PC) boilers. This NO{sub x} reduction should be achieved without loss of boiler efficiency or operating stability, and at more than 25% lower levelized cost than state-of-the-art SCR technology. A further objective is to ready technology for full-scale commercial deployment to meet the market demand for NO{sub x} reduction technologies. Over half of the electric power generated in the U.S. is produced by coal combustion, and more than 80% of these units utilize PC combustion technology. Conventional measures for NOx reduction in PC combustion processes rely on combustion and post-combustion modifications. A variety of combustion-based NO{sub x} reduction technologies are in use today, including low-NO{sub x} burners (LNBs), flue gas recirculation (FGR), air staging, and natural gas or other fuel reburning. Selective non-catalytic reduction (SNCR) and selective catalytic reduction (SCR) are post-combustion techniques. NO{sub x} reduction effectiveness from these technologies ranges from 30 to 60% and up to 90-93% for SCR. Typically, older wall-fired PC burner units produce NO{sub x} emissions in the range of 0.8-1.6 lb/million Btu. Low-NO{sub x} burner systems, using combinations of fuel staging within the burner and air staging by introduction of overfire air in the boiler, can reduce NO{sub x} emissions by 50-60%. This approach alone is not sufficient to meet the desired 0.15 lb/million Btu NO{sub x} standard with a range of coals and boiler loads. Furthermore, the heavy reliance on overfire air can lead to increased slagging and corrosion in furnaces, particularly with higher-sulfur coals, when LNBs are operated at sub-stoichiometric conditions to reduce fuel-derived NOx in the flame. Therefore, it is desirable to minimize the need for overfire air by maximizing NO{sub x} reduction in the burner. The proposed combustion concept aims to greatly reduce NO{sub x} emissions by incorporating a novel modification to conventional or low-NO{sub x} PC burners using gas-fired coal preheating to destroy NO{sub x} precursors and prevent NO{sub x} formation. A concentrated PC stream enters the burner, where flue gas from natural gas combustion is used to heat the PC up to about 1500 F prior to coal combustion. Secondary fuel consumption for preheating is estimated to be 3 to 5% of the boiler heat input. This thermal pretreatment releases coal volatiles, including fuel-bound nitrogen compounds into oxygen-deficient atmosphere, which converts the coal-derived nitrogen compounds to molecular N{sub 2} rather than NO. Design, installation, shakedown, and testing on Powder River Basin (PRB) coal at a 3-million Btu/h pilot system at RPI's (Riley Power, Inc.) pilot-scale combustion facility (PSCF) in Worcester, MA demonstrated that the PC PREHEAT process has a significant effect on final O{sub x} formation in the coal burner. Modifications to both the pilot system gas-fired combustor and the PC burner led to NO{sub x} reduction with PRB coal to levels below 0.15 lb/million Btu with CO in the range of 35-112 ppmv without any furnace air staging.

Bruce Bryan; Serguei Nester; Joseph Rabovitser; Stan Wohadlo

2005-09-30T23:59:59.000Z

364

Carbon Fiber Pilot Plant and Research Facilities  

Broader source: Energy.gov (indexed) [DOE]

from PAN, lignin, polyolefin, pitch, and rayon precursors * Low-temperature carbonization furnace designed to accommodate an oxidizing atmosphere * Expansion slot to enable the...

365

Coal characterisation for \\{NOx\\} prediction in air-staged combustion of pulverised coals  

Science Journals Connector (OSTI)

A series of world-traded coal samples has been tested using the Imperial College high temperature wire mesh apparatus (HTWM) in order to assess the relationship between high temperature (1600°C) char nitrogen content and \\{NOx\\} formation in Hemweg Power Station (in the Netherlands) using deep furnace air staging. A linear relationship between high temperature char nitrogen and \\{NOx\\} formation has been confirmed. These results suggest that high temperature char N content is the main factor limiting \\{NOx\\} emissions with deep air-staged combustion. Char N and (hence apparently deep air-staged NOx) can be predicted with an accuracy of approximately ±20% for most coals from the coal proximate and ultimate analysis—but this might not be sufficient for stations operating close to their emission limits. Measuring high temperature char N directly reduces the likely uncertainty in deep air-staged \\{NOx\\} emissions for coals (and most blends) to approximately ±10%. Its use should be considered on a routine basis for coal selection on plants employing this technology.

C.K. Man; J.R. Gibbins; J.G. Witkamp; J. Zhang

2005-01-01T23:59:59.000Z

366

Protective effects of pulmonary epithelial lining fluid on oxidative stress and DNA single-strand breaks caused by ultrafine carbon black, ferrous sulphate and organic extract of diesel exhaust particles  

SciTech Connect (OSTI)

Pulmonary epithelial lining fluid (ELF) is the first substance to make contact with inhaled particulate matter (PM) and interacts chemically with PM components. The objective of this study was to determine the role of ELF in oxidative stress, DNA damage and the production of proinflammatory cytokines following physicochemical exposure to PM. Ultrafine carbon black (ufCB, 15 nm; a model carbonaceous core), ferrous sulphate (FeSO{sub 4}; a model transition metal) and a diesel exhaust particle (DEP) extract (a model organic compound) were used to examine the acellular oxidative potential of synthetic ELF and non-ELF systems. We compared the effects of exposure to ufCB, FeSO{sub 4} and DEP extract on human alveolar epithelial Type II (A549) cells to determine the levels of oxidative stress, DNA single-strand breaks and interleukin-8 (IL-8) production in ELF and non-ELF systems. The effects of ufCB and FeSO{sub 4} on the acellular oxidative potential, cellular oxidative stress and DNA single-strand breakage were mitigated significantly by the addition of ELF, whereas there was no decrease following treatment with the DEP extract. There was no significant effect on IL-8 production following exposure to samples that were suspended in ELF/non-ELF systems. The results of the present study indicate that ELF plays an important role in the initial defence against PM in the pulmonary environment. Experimental components, such as ufCB and FeSO{sub 4}, induced the production of oxidative stress and led to DNA single-strand breaks, which were moderately prevented by the addition of ELF. These findings suggest that ELF plays a protective role against PM-driven oxidative stress and DNA damage. -- Highlights: ? To determine the role of ELF in ROS, DNA damage and IL-8 after exposure to PM. ? ufCB, FeSO{sub 4} and DEP extract were used to examine the protective effects of ELF. ? PM-driven oxidative stress and DNA single-strand breakage were mitigated by ELF. ? The findings suggest that ELF has a protective role against PM. ? The synthetic ELF system could reduce the use of animals in PM-driven ROS testing.

Chuang, Hsiao-Chi [School of Respiratory Therapy, College of Medicine, Taipei Medical University, Taipei, Taiwan (China) [School of Respiratory Therapy, College of Medicine, Taipei Medical University, Taipei, Taiwan (China); Division of Pulmonary Medicine, Department of Internal Medicine, Shuang Ho Hospital, Taipei Medical University, Taipei, Taiwan (China); Cheng, Yi-Ling; Lei, Yu-Chen [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China)] [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Chang, Hui-Hsien [Institute of Environmental Health, College of Public Health, National Taiwan University, Taipei, Taiwan (China)] [Institute of Environmental Health, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Cheng, Tsun-Jen, E-mail: tcheng@ntu.edu.tw [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China) [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Department of Public Health, College of Public Health, National Taiwan University, Taipei, Taiwan (China)

2013-02-01T23:59:59.000Z

367

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in AP-XPS Measures MIEC Oxides in Action AP-XPS Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

368

Fuel saving, carbon dioxide emission avoidance, and syngas production by tri-reforming of flue gases from coal- and gas-fired power stations, and by the carbothermic reduction of iron oxide  

Science Journals Connector (OSTI)

Flue gases from coal, gas, or oil-fired power stations, as well as from several heavy industries, such as the production of iron, lime and cement, are major anthropogenic sources of global CO2 emissions. The newly proposed process for syngas production based on the tri-reforming of such flue gases with natural gas could be an important route for CO2 emission avoidance. In addition, by combining the carbothermic reduction of iron oxide with the partial oxidation of the carbon source, an overall thermoneutral process can be designed for the co-production of iron and syngas rich in CO. Water-gas shift (WGS) of CO to H2 enables the production of useful syngas. The reaction process heat, or the conditions for thermoneutrality, are derived by thermochemical equilibrium calculations. The thermodynamic constraints are determined for the production of syngas suitable for methanol, hydrogen, or ammonia synthesis. The environmental and economic consequences are assessed for large-scale commercial production of these chemical commodities. Preliminary evaluations with natural gas, coke, or coal as carbon source indicate that such combined processes should be economically competitive, as well as promising significant fuel saving and CO2 emission avoidance. The production of ammonia in the above processes seems particularly attractive, as it consumes the nitrogen in the flue gases.

M. Halmann; A. Steinfeld

2006-01-01T23:59:59.000Z

369

The carbon footprint analysis of wastewater treatment plants and nitrous oxide emissions from full-scale biological nitrogen removal processes in Spain  

E-Print Network [OSTI]

This thesis presents a general model for the carbon footprint analysis of advanced wastewater treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ...

Xu, Xin, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

370

Thermodynamic Analysis of the Possibility of Hydrogen Production by Oxidation of n-Butane, n-Pentane, and Carbon by Oxygen-Containing Nitrogen Compounds  

Science Journals Connector (OSTI)

A thermodynamic analysis is performed to study the reactions of hydrogen production by oxidation of hydrocarbons of natural gas ... analysis suggests the possibility of developing a new hydrogen production method

A. M. Alekseev; Z. V. Komova; L. L. Klinova…

2003-07-01T23:59:59.000Z

371

Synthesis of carbon coated Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/reduced graphene oxide composite for high-performance lithium ion batteries  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Carbon coated LVP nanoparticles strongly anchored on rGO surface are prepared. ? LVP@C/rGO exhibits high electrical conductivity. ? LVP@C/rGO shows excellent cycleability and rate capability between 3.0 and 4.8 V. -- Abstract: The carbon coated Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/reduced graphene oxide (LVP@C/rGO) composite is successfully synthesized by a conventional solid-state reaction, which is easily scaled up. LVP grains coated with a thin layer (?8 nm) of carbon are adhered to the surface of the rGO layer and/or enwrapped into the rGO sheets, which can facilitate the fast charge transfer within the whole electrode and to the current collector. As a cathode material, the LVP@C/rGO electrode delivers an initial discharge capacity of 177 mAh g{sup ?1} at 0.5 C with capacity retention of 96% during the 50th cycle in a wide voltage range of 3.0–4.8 V. A superior rate capability is also achieved, e.g., exhibiting a discharge capacity of 96 mAh g{sup ?1} at a high C rate of 10 C.

Wu, Keliang, E-mail: linxin66@126.com [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China)] [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China); Yang, Jinpeng [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China)] [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China)

2013-02-15T23:59:59.000Z

372

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3  

E-Print Network [OSTI]

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3 A.Bonfils , Y. Creff for an automotive selective catalytic reduction (SCR) system, for which the feedback is based on a NOx sensor the variety of en- countered technologies, selective catalytic reduction (SCR) is one of the most appealing

373

Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration  

E-Print Network [OSTI]

1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

Boyer, Edmond

374

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission  

E-Print Network [OSTI]

Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission Inventories J. David Felix,*, Emily M. Elliott, and Stephanie L. Shaw contributions, prior documentation of 15 N of various NOx emission sources is exceedingly limited

Elliott, Emily M.

375

Sustainability Assessment of Coal-Fired Power Plants with Carbon Capture and Storage  

SciTech Connect (OSTI)

Carbon capture and sequestration (CCS) has the ability to dramatically reduce carbon dioxide (CO2) emissions from power production. Most studies find the potential for 70 to 80 percent reductions in CO2 emissions on a life-cycle basis, depending on the technology. Because of this potential, utilities and policymakers are considering the wide-spread implementation of CCS technology on new and existing coal plants to dramatically curb greenhouse gas (GHG) emissions from the power generation sector. However, the implementation of CCS systems will have many other social, economic, and environmental impacts beyond curbing GHG emissions that must be considered to achieve sustainable energy generation. For example, emissions of nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM) are also important environmental concerns for coal-fired power plants. For example, several studies have shown that eutrophication is expected to double and acidification would increase due to increases in NOx emissions for a coal plant with CCS provided by monoethanolamine (MEA) scrubbing. Potential for human health risks is also expected to increase due to increased heavy metals in water from increased coal mining and MEA hazardous waste, although there is currently not enough information to relate this potential to actual realized health impacts. In addition to environmental and human health impacts, supply chain impacts and other social, economic, or strategic impacts will be important to consider. A thorough review of the literature for life-cycle analyses of power generation processes using CCS technology via the MEA absorption process, and other energy generation technologies as applicable, yielded large variability in methods and core metrics. Nonetheless, a few key areas of impact for CCS were developed from the studies that we reviewed. These are: the impact of MEA generation on increased eutrophication and acidification from ammonia emissions and increased toxicity from MEA production and the impact of increased coal use including the increased generation of NOx from combustion and transportation, impacts of increased mining of coal and limestone, and the disposal of toxic fly ash and boiler ash waste streams. Overall, the implementing CCS technology could contribute to a dramatic decrease in global GHG emissions, while most other environmental and human health impact categories increase only slightly on a global scale. However, the impacts on human toxicity and ecotoxicity have not been studied as extensively and could have more severe impacts on a regional or local scale. More research is needed to draw strong conclusions with respect to the specific relative impact of different CCS technologies. Specifically, a more robust data set that disaggregates data in terms of component processes and treats a more comprehensive set of environmental impacts categories from a life-cycle perspective is needed. In addition, the current LCA framework lacks the required temporal and spatial scales to determine the risk of environmental impact from carbon sequestration. Appropriate factors to use when assessing the risk of water acidification (groundwater/oceans/aquifers depending on sequestration site), risk of increased human toxicity impact from large accidental releases from pipeline or wells, and the legal and public policy risk associated with licensing CO2 sequestration sites are also not currently addressed. In addition to identifying potential environmental, social, or risk-related issues that could impede the large-scale deployment of CCS, performing LCA-based studies on energy generation technologies can suggest places to focus our efforts to achieve technically feasible, economically viable, and environmentally conscious energy generation technologies for maximum impact.

Widder, Sarah H.; Butner, R. Scott; Elliott, Michael L.; Freeman, Charles J.

2011-11-30T23:59:59.000Z

376

Smog Check II Evaluation California Inspection and  

E-Print Network [OSTI]

National Ambient Air Quality Standards NO Nitrogen Oxide NO2 Nitrogen Dioxide NOx Nitrogen Oxides RAP Assistance Program CHP California Highway Patrol CO Carbon Monoxide CO2 Carbon Dioxide DMV California

Denver, University of

377

Geological sequestration of carbon dioxide by hydrous carbonate formation in steelmaking slag .  

E-Print Network [OSTI]

??"The formation of carbonate solids from the alkaline earth oxide phases in steelmaking slag was investigated in dry and aqueous conditions as a vehicle for… (more)

Rawlins, C. Hank, 1968-

2008-01-01T23:59:59.000Z

378

E-Print Network 3.0 - accumulation involving oxidative Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

active phase. For example, thin metal oxide films have been... oxidation of carbon monoxide. Here, we present operando X-ray diffraction experiments on a palladium surface... ,...

379

E-Print Network 3.0 - amperometric nitric oxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

behavioral... Ref. Neurotransmitters and related compounds Nitric oxide (nitrite) Carbon fiber End-channelInt 8... been studied by microchip CEEC is nitric oxide (NO). NO...

380

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite  

E-Print Network [OSTI]

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite · C-C supplied in two forms · T300: C-C composite containing continuous PAN T300 fibers · SWB: Chopped Fiber Composite containing SWB fibers Crush strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine

Rollins, Andrew M.

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Layer-By-Layer Assembled Hybrid Film of Carbon Nanotubes/Iron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

By-Layer Assembled Hybrid Film of Carbon NanotubesIron Oxide Nanocrystals for Reagentless Electrochemical Detection of Layer-By-Layer Assembled Hybrid Film of Carbon Nanotubes...

382

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

383

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

384

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

385

NOx Control Options and Integration for US Coal Fired Boilers  

SciTech Connect (OSTI)

This is the fifteenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. At AEP's Gavin Plant, data from the corrosion probes showed that corrosion rate increased as boiler load was increased. During an outage at the plant, the drop in boiler load, sensor temperature and corrosion rate could all be seen clearly. Restarting the boiler saw a resumption of corrosion activity. This behavior is consistent with previous observations made at a 600MWe utility boiler. More data are currently being examined for magnitudes of corrosion rates and changes in boiler operating conditions. Considerable progress was made this quarter in BYU's laboratory study of catalyst deactivation. Surface sulfation appears to partially suppress NO adsorption when the catalyst is not exposed to NH3; NH3 displaces surface-adsorbed NO on SCR catalysts and surface sulfation increases the amount of adsorbed NH3, as confirmed by both spectroscopy and TPD experiments. However, there is no indication of changes in catalyst activity despite changes in the amount of adsorbed NH3. A monolith test reactor (MTR), completed this quarter, provided the first comparative data for one of the fresh and field-exposed monolith SCR catalysts yet developed in this project. Measurements of activity on one of the field-exposed commercial monolith catalysts do not show significant changes in catalyst activity (within experimental error) as compared to the fresh catalyst. The exposed surface of the sample contains large amounts of Ca and Na, neither of which is present in the fresh sample, even after removal of visibly obvious fouling deposits. However, these fouling compounds do not deactivate the catalyst to the extent that these same poisons do in the deliberately wet-impregnated laboratory-prepared samples (1%V{sub 2}O{sub 5}-9%WO{sub 3}/TiO{sub 2}). At least in this case, the fouling deposits generated by field exposure present little if any chemical deactivation or barrier to mass transfer. During this quarter, the slipstream reactor at Rockport operated for 1000 hours on flue gas. Periodic NO{sub x} reduction measurements were made, showing some decrease in activity relative to fresh catalyst samples. Plans are being made to take the reactor out of service at the Rockport plant and move it to Plant Gadsden. At Gadsden, inlet and outlet ports were installed on Unit 1 for the slipstream reactor during an outage.

Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

2004-03-31T23:59:59.000Z

386

Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes**  

E-Print Network [OSTI]

to the intrinsic material properties of carbon, functionalized films can be produced through chemical modification fabrication method capable of producing large area (%100 s cm2 ) submicrometer porous carbon films. In our methodology. The palladium-modified electrodes exhibit a catalytic response for methanol oxidation

New Mexico, University of

387

Influence of combustion parameters on NOx production in an industrial boiler  

E-Print Network [OSTI]

Influence of combustion parameters on NOx production in an industrial boiler M.A. Habib a,*, M pollution using a model furnace of an industrial boiler utilizing fuel gas. The importance of this problem is mainly due to its relation to the pollutants produced by large boiler furnaces used widely in thermal

Aldajani, Mansour A.

388

Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)  

E-Print Network [OSTI]

. INTRODUCTION Plasma remediation of exhaust from internal combustion engines, and diesel engines in particular of achieving high E/N electric field/ gas number density are promising in this regard.11 Actual diesel exhaust discharge DBD reactors are being investigated for plasma remediation of NOx from the exhaust of internal

Kushner, Mark

389

tive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and  

E-Print Network [OSTI]

a few sluggish electric vehicles would cause enough traffic slowing that the gasoline- powered fleet Analy- sis article on battery-powered vehicles (Sept. 1996, p. 402A) serves as a useful remindertive emissions from EVs (e.g., power plant NOx) and GPVs (tailpipe and associated NO.,. emissions

Denver, University of

390

Observation of NOx enhancement and ozone depletion in the Northern and Southern  

E-Print Network [OSTI]

Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, and H. Fischer Institut fu¨r Meteorologie und Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, H. Fischer, and C. H. Jackman (2005), Observation of NOx

Jackman, Charles H.

391

Atmospheric Environment 38 (2004) 27792787 First detection of nitrogen from NOx in tree rings: a 15  

E-Print Network [OSTI]

abies; Air pollution; Dendroecology; Nitrogen deposition; Stable isotopes; Nitrogen dioxide 1Atmospheric Environment 38 (2004) 2779­2787 First detection of nitrogen from NOx in tree rings 2004; accepted 27 February 2004 Abstract Nitrogen isotope analysis (d15 N) of tree rings is potentially

392

Transport of NOx in East Asia identified by satellite and in situ measurements  

E-Print Network [OSTI]

Research Laboratory, Boulder, Colorado, USA, 3 Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, Colorado, USA, 4 School of Earth and Environmental Sciences, Seoul burning, and natural phenomena like lightning, wildfires, and soil microbial activity. NOx play

Park, Rokjin

393

NOx reduction with the use of feedlot biomass as a reburn fuel  

E-Print Network [OSTI]

. Additional air called overfire air (about 20 % of total air) is injected in order to complete combustion. Typically reburn fuel is natural gas (NG). From previous research at TAMU, it was found that firing feedlot biomass (FB) as reburn fuel lowers the NOx...

Goughnour, Paul Gordon

2009-05-15T23:59:59.000Z

394

Quantification of substitutional carbon loss from Si0.998C0.002 due to silicon self-interstitial injection during oxidation  

E-Print Network [OSTI]

of crystalline silicon. The Si1 xCx layer was grown at 550 °C and 10 Torr using 50 sccm of a disilane mixture 10% disilane in hydrogen and 20 sccm of methylsilane 1% methylsilane in hydrogen as the silicon and carbon

395

Preparation of carbon-coated iron oxide nanoparticles dispersed on graphene sheets and applications as advanced anode materials for lithium-ion batteries  

Science Journals Connector (OSTI)

We report a novel chemical vapor deposition (CVD) based strategy to synthesize carbon-coated Fe2O3 nanoparticles dispersed on graphene sheets (Fe2O3@C@G). Graphene sheets with high surface area and aspect...2O3.....

Huilong Fei; Zhiwei Peng; Lei Li; Yang Yang; Wei Lu; Errol L. G. Samuel…

2014-04-01T23:59:59.000Z

396

Biomarker Response to Galactic Cosmic Ray-Induced NOx and the Methane Greenhouse Effect in the Atmosphere of an Earthlike Planet Orbiting an M-Dwarf Star  

E-Print Network [OSTI]

Planets orbiting in the habitable zone (HZ) of M-Dwarf stars are subject to high levels of galactic cosmic rays (GCRs) which produce nitrogen oxides in earthlike atmospheres. We investigate to what extent this NOx may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources) . Our model results suggest that such signals are robust, changing in the M-star world atmospheric column by up to 20% due to the GCR NOx effects compared to an M-star run without GCR effects and can therefore survive at least the effects of galactic cosmic rays. We have not however investigated stellar cosmic rays here. CH4 levels are about 10 times higher than on the Earth related to a lowering in hydroxyl (OH) in response to changes in UV. The increase is less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on the Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M-star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M-star world differs considerably compared with the Earth.

John Lee Grenfell; Jean-Mathias Griessmeier; Beate Patzer; Heike Rauer; Antigona Segura; Anja Stadelmann; Barbara Stracke; Ruth Titz; Philip von Paris

2007-02-23T23:59:59.000Z

397

Latest developments and application of DB Riley's low NOx CCV{reg{underscore}sign} burner technology  

SciTech Connect (OSTI)

Recent developments in DB Riley (DBR) low NOx burner technology and the application of this technology in coal fired utility boilers are discussed. Since the promulgation of the Clean Air Act Amendment in 1990, DBR has sold nearly 1,500 Controlled Combustion Venturi (CCV{reg{underscore}sign}) burners on pulverized coal fired utility boilers reducing NOx emissions 50--70% from uncontrolled levels. This technology has been retrofitted on boiler designs ranging in size and type from 50 MW front wall fired boilers to 1,300 MW opposed fired cell type boilers. In DBR's latest version of the CCV{reg{underscore}sign} burner, a second controlled flow air zone was added to enhance NOx control capability. Other developments included improved burner air flow measurement accuracy and several mechanical design upgrades such as new coal spreader designs for 3 year wear life. Test results of the CCV{reg{underscore}sign} dual air zone burner in DBR's 100 million Btu/hr (29 MW) coal burner test facility are presented. In the test program, coals from four utility boiler sites were fired to provide a range of coal properties. A baseline high volatile bituminous coal was also fired to provide a comparison with 1992 test data for the CCV{reg{underscore}sign} single register burner. The tests results showed that the second air zone enhanced NOx reduction capability by an additional 20% over the single register design. Computational fluid dynamic (DFD) modeling results of the CCV{reg{underscore}sign} dual air zone burner are also presented showing near field mixing patterns conducive to low NOx firing. DBR was recently awarded Phase IV of the Low Emission Boiler System (LEBS) program by the US Department of Energy to build a proof of concept facility representing the next major advancement in pulverized coal burning technology. A key part of winning that award were test results of the CCV{reg{underscore}sign} dual air zone burner with advanced air staging and coal reburning in a 100 million Btu/hr (20 MW) U-fired slagging combustor test facility. These results showed NOx emissions of less than 0.2 lb/million Btu (0.086 g/MJ) while converting the coal ash into an inert, non-leachable solid. This results is an 80% reduction in NOx emissions from currently operating U-fired slagging boilers.

Penterson, C.; Ake, T.

1998-07-01T23:59:59.000Z

398

Carbon and oxygen isotope halos in the host limestone, El Mochito Zn-Pb-(Ag) skarn massive sulfide-oxide deposit, Honduras  

Science Journals Connector (OSTI)

...sulfide-oxide deposit, Honduras Rodrigo Vazquez Torsten W. Vennemann...deposit, Honduras Vazquez Rodrigo Author University of Michigan...Valanginian Barriasien Todos Santos Fm, Upper Jurassic Middle...Yojoa Nueva Main I 4000 Todos Santos Fm. Faults 6000 8000 10000...

Rodrigo Vazquez; Torsten W. Vennemann; Stephen E. Kesler; Norman Russell

399

Oxidative Degradation of Monoethanolamine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

400

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Title Chemistry of NOx on TiO2 surfaces studied by ambient pressure XPS: products, effect of UV irradiation, water and coadsorbed K+ Publication Type Journal Article Year of Publication 2013 Authors Rosseler, Olivier, Mohamad Sleiman, Nahuel V. Montesinos, Andrey Shavorskiy, Valerie Keller, Nicolas Keller, Marta I. Litter, Hendrik Bluhm, Miquel Salmeron, and Hugo Destaillats Journal J. Phys. Chem. Lett. Volume 4 Start Page 536 Issue 3 Pagination 536-541 Date Published 01/2013 Abstract Self-cleaning surfaces containing TiO2 nanoparticles have been postulated to efficiently remove NOx from the atmosphere. However, UV irradiation of NOx adsorbed on TiO2 also was shown to form harmful gas-phase byproducts such as HONO and N2O that may limit their depolluting potential. Ambient pressure XPS was used to study surface and gas-phase species formed during adsorption of NO2 on TiO2 and subsequent UV irradiation at λ = 365 nm. It is shown here that NO3-, adsorbed on TiO2 as a byproduct of NO2 disproportionation, was quantitatively converted to surface NO2 and other reduced nitrogenated species under UV irradiation in the absence of moisture. When water vapor was present, a faster NO3- conversion occurred, leading to a net loss of surface-bound nitrogenated species. Strongly adsorbed NO3- in the vicinity of coadsorbed K+ cations was stable under UV light, leading to an efficient capture of nitrogenated compounds.

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

NONE

1995-09-01T23:59:59.000Z

402

Reduction of Metal Oxides by Microwave Heating of Multi-walled...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reduction of Metal Oxides by Microwave Heating of Multi-walled Carbon Nanotubes Microwave heating of a metal oxide in the presence of multi-walled carbon nanotubes may result in...

403

Combustion and \\{NOx\\} emissions of biomass-derived syngas under various gasification conditions utilizing oxygen-enriched-air and steam  

Science Journals Connector (OSTI)

The purpose of this study is to investigate the \\{NOx\\} emissions from combustion of syngas derived from gasification of three different biomass feedstock (i.e., pine, maple–oak mixture, and seed corn) at different oxygen-enriched-air and steam conditions. Three different oxygen-enriched-air and steam conditions were tested for each feedstock, thus resulting in nine different sets of syngas. The biomass-derived syngas was burned in an industrial burner that was integrated into the gasification system. The gasifier and burner are rated at 800 kW and 879 kW thermal, respectively. For each set of biomass-derived syngas, \\{NOx\\} emissions were measured at different burner operating conditions including various heat rates and equivalence ratios using emission analyzers with chemiluminescence technology. All the combustion test conditions are in the lean mixture ranges in order to avoid the peak temperature limitation of both the burner and combustion chamber. Results show that \\{NOx\\} emissions using syngas obtained from woody feedstock decrease almost linearly as the combustion mixture becomes leaner and the heat rate decreases. When compared to natural gas, syngas from both woody feedstock generates higher \\{NOx\\} emissions even when the heat rates are comparable, indicating that fuel \\{NOx\\} formation is highly important in biomass-derived syngas combustion. In contrast to syngas from woody feedstock, syngas from seed corn results in peak \\{NOx\\} emissions before \\{NOx\\} decreases with leaner conditions. The trend is observed for all fuel flow rates and all oxygen-enriched-air and steam conditions of seed corn-derived syngas. Among the three feedstock, seed corn has the highest nitrogen content which yields the highest ammonia concentration in syngas, which, in turn, results in the highest \\{NOx\\} emissions for all test conditions. Overall, the \\{NOx\\} emissions from seed corn-derived syngas combustion are approximately in the range of 450–900 ppm higher compared to those from wood-derived syngas combustion.

Cuong Van Huynh; Song-Charng Kong

2013-01-01T23:59:59.000Z

404

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

405

On the Promoting Effect of Water during NOx Removal over Single-Site Copper in Hydrophobic Silica APD-Aerogels  

Science Journals Connector (OSTI)

Reversibility of the Cu2+/Cu+ redox pair was confirmed in the Cu-aerogel during and after wet redox cycling. ... (1) Popular solutions to selective catalytic reduction of NOx include the use of exhaust hydrocarbon residuals (SCR-HC-deNOx) or ammonia added to the exhaust (SCR-NH3-deNOx) as the reductant; the former technology being suitable for light duty passenger vehicles, whereas the latter is applied to medium or heavy duty vehicles. ... During vehicle use, the converter is exposed to heat, which causes the metal particles to agglomerate and grow, and their overall surface area to decrease. ...

Tina Kristiansen; Karina Mathisen

2014-01-10T23:59:59.000Z

406

Spatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic composition of atmospheric nitrate  

E-Print Network [OSTI]

exchange between gas-phase precursors and variability in reactive nitrogen sources. These findings product of NOx in the atmosphere. Due to its exceptionally high solubility in water, nitrate is rapidly deSpatial and diurnal variability in reactive nitrogen oxide chemistry as reflected in the isotopic

407

ZIRCONIA-BASED MIXED POTENTIAL CARBON MONOXIDE/HYDROCARBON SENSORS WITH LANTHANUM MAGNESIUM OXIDE, AND TERBIUM-DOPED YTTRIUM STABILIZED ZIRCONIA ELECTRODES  

SciTech Connect (OSTI)

We have investigated the performance of dual metal oxide electrode mixed potential sensors in an engine-out, dynamometer environment. Sensors were fabricated by sputtering thin films of LaMnO{sub 3} and Tb-doped YSZ onto YSZ electrolyte. Au gauze held onto the metal oxide thin films with Au ink was used for current collection. The exhaust gas from a 4.8L, V8 engine operated in open loop, steady-state mode around stoichiometry at 1500 RPM and 50 Nm. The sensor showed a stable EMF response (with no hysteresis) to varying concentrations of total exhaust gas HC content. The sensor response was measured at 620 and 670 C and shows temperature behavior characteristic of mixed potential-type sensors. The results of these engine-dynamometer tests are encouraging; however, the limitations associated with Au current collection present the biggest impediment to automotive use.

E. L. BROSHA; R. MUKUNDAN; ET AL

2000-10-01T23:59:59.000Z

408

Flue Gas Purification Utilizing SOx/NOx Reactions During Compressin of CO2 Derived from Oxyfuel Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flue Gas Purification Flue Gas Purification Utilizing SO X /NO X Reactions During Compression of CO 2 Derived from Oxyfuel Combustion Background Oxy-combustion in a pulverized coal-fired power station produces a raw carbon dioxide (CO 2 ) product containing contaminants such as water vapor, oxygen, nitrogen, and argon from impurities in the oxygen used and any air leakage into the system. Acid gases are also produced as combustion products, such as sulfur oxides (SO

409

E-Print Network 3.0 - ammonium hydrogen carbonate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-Partial list Chemical Incompatibilities Summary: hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... Ammonium...

410

BaO/Al2O3/NiAl(110) Model NOx Storage Materials: the effect of BaO film thickness on the amorphous-to-crystalline Ba(NO3)2 phase transition  

SciTech Connect (OSTI)

The reaction of NO2 with BaO (0.15 – 2 ML and > 30 ML)/Al2O3(12 ML)/NiAl(110) model NOx storage materials was studied. A thick (~12 ML), ordered Al2O3 film was prepared as the support oxide on a NiAl(110) substrate in order to minimize the effect of the intermixing between the two oxide phases (BaO and Al2O3) on the NOx chemistry of BaO. The growth of a thick alumina film, prepared by atomic oxygen deposition onto NiAl(110), follows a layer-by-layer growth mode and the resulting film is much more stable when exposed to NO2 than the ultra-thin alumina films studied before. The interaction of NO2 with the model NOx storage systems at low coverages of BaO show fundamentally different behaviors from a thick BaO film, as nitrite species form at low exposures of NO2, followed by nitrate formation at high NO2 exposures. In contrast, on the thick BaO layer nitrite-nitrate ion pairs form at 300 K under UHV conditions (PNO2 ~ 1 ? 10-9 Torr). However, at elevated NO2 pressures (? 1 ? 10-5 Torr) the thick BaO film is gradually converted into amorphous Ba(NO3)2 at 300 K. Raising the temperature of the samples with ?BaO > 1 ML after NO2 exposure (in the absence of gas phase NO2) leads to the phase transformation of the amorphous Ba(NO3)2 layer into crystalline Ba(NO3)2 particles in the temperature range of 500 – 600 K. No phase transformation is observed in samples with ?BaO < 1 ML.

Yi, Cheol-Woo W.; Szanyi, Janos

2009-01-15T23:59:59.000Z

411

Simultaneous Removal of NOx and Mercury in Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect (OSTI)

The results of a 18-month investigation to advance the development of a novel Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR), for the simultaneous removal of NO{sub x} and mercury (elemental and oxidized) from flue gases in a single unit operation located downstream of the particulate collectors, are reported. In the proposed LTSCAR, NO{sub x} removal is in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The concomitant capture of mercury in the unit is achieved through the incorporation of a novel chelating adsorbent. As conceptualized, the LTSCAR will be located downstream of the particulate collectors (flue gas temperature 140-160 C) and will be similar in structure to a conventional SCR. That is, it will have 3-4 beds that are loaded with catalyst and adsorbent allowing staged replacement of catalyst and adsorbent as required. Various Mn/TiO{sub 2} SCR catalysts were synthesized and evaluated for their ability to reduce NO at low temperature using CO as the reductant. It has been shown that with a suitably tailored catalyst more than 65% NO conversion with 100% N{sub 2} selectivity can be achieved, even at a high space velocity (SV) of 50,000 h-1 and in the presence of 2 v% H{sub 2}O. Three adsorbents for oxidized mercury were developed in this project with thermal stability in the required range. Based on detailed evaluations of their characteristics, the mercaptopropyltrimethoxysilane (MPTS) adsorbent was found to be most promising for the capture of oxidized mercury. This adsorbent has been shown to be thermally stable to 200 C. Fixed-bed evaluations in the targeted temperature range demonstrated effective removal of oxidized mercury from simulated flue gas at very high capacity ({approx}>58 mg Hg/g adsorbent). Extension of the capability of the adsorbent to elemental mercury capture was pursued with two independent approaches: incorporation of a novel nano-layer on the surface of the chelating mercury adsorbent to achieve in situ oxidation on the adsorbent, and the use of a separate titania-supported manganese oxide catalyst upstream of the oxidized mercury adsorbent. Both approaches met with some success. It was demonstrated that the concept of in situ oxidation on the adsorbent is viable, but the future challenge is to raise the operating capacity beyond the achieved limit of 2.7 mg Hg/g adsorbent. With regard to the manganese dioxide catalyst, elemental mercury was very efficiently oxidized in the absence of sulfur dioxide. Adequate resistance to sulfur dioxide must be incorporated for the approach to be feasible in flue gas. A preliminary benefits analysis of the technology suggests significant potential economic and environmental advantages.

Neville G. Pinto; Panagiotis G. Smirniotis

2006-03-31T23:59:59.000Z

412

An Analysis of the health impacts from PM and NOx emissions resulting from train operations in the Alameda Corridor, CA  

E-Print Network [OSTI]

2009). Estimating PM and NOx Train Emissions in the AlamedaAuthority. Number of Trains Running on the Alameda Corridor.x emissions resulting from train operations in the Alameda

Sangkapichai, Mana; Saphores, Jean-Daniel M; Ogunseitan, Oladele; Ritchie, Stephen G.; You, Soyoung Iris; Lee, Gunwoo

2010-01-01T23:59:59.000Z

413

Heavy-duty diesel vehicle Nox? aftertreatment in 2010 : the infrastructure and compliance challenges of urea-SCR  

E-Print Network [OSTI]

Increasingly stringent heavy-duty vehicle emission regulations are prompting the use of PM and NOx aftertreatment systems in the US, the EU and Japan. In the US, the EPA Highway Diesel Rule, which will be fully implemented ...

Bodek, Kristian M

2008-01-01T23:59:59.000Z

414

Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Adsorber for Hydrocarbons and NOx  

Broader source: Energy.gov [DOE]

Reports results from study of potential for using chemisorbing materials to temporally trap HC and NOx emissions during cold-start of HEVs and PHEVs over transient driving cycles

415

Comparative study of the reactions of metal oxides and carbonates with H{sub 2}S and SO{sub 2}. Final technical report, September 1990--February 1994  

SciTech Connect (OSTI)

The primary objective of this project had been the investigation of the effects of pore structure on the capacity of porous metal oxides for removal of gaseous pollutants from flue gases of power plants (SO{sub 2}) and hot coal gas (primarily H{sub 2}S). Porous calcines obtained from natural precursors (limestones and dolomites) and sorbents based on zinc oxide were used as model systems in our experimental studies, which included reactivity evolution experiments and pore structure characterization using a variety of methods. The key idea behind this project was to appropriately exploit the differences of the sulfidation and sulfation reactions (for instance, different molar volumes of solid products) to elucidate the dependence of the sorptive capacity of a porous sorbent on its physical microstructure. In order to be able to proceed faster and more productively on the analysis of the above defined problem, it was decided to employ in our studies solids whose reaction with SO{sub 2} (limestone calcines) or H{sub 2}S (sorbents based on zinc oxide) had been investigated in detail in past studies by our research group. Reactivity vs time or conversion vs time studies were conducted using thermogravimetry and fixed-bed and fluidized-bed reactors. The pore structure of partially reacted samples collected at selected time instants or conversion levels was analyzed by gas adsorption and mercury porosimetry. For better characterization of the pore structure of the solid samples, we also carried out intraparticle diffusivity measurements by the peak-broadening (chromatographic) method, using a system developed for this purpose in our laboratory. In the context of this part of the project, we also conducted a detailed theoretical investigation of the measurement of effective diffusivities in porous solids using the diffusion-cell method.

Sotirchos, S.V.

1994-03-01T23:59:59.000Z

416

Fly ash carbon passivation  

DOE Patents [OSTI]

A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

La Count, Robert B; Baltrus, John P; Kern, Douglas G

2013-05-14T23:59:59.000Z

417

NOx Emissions Reductions from Implementation of the 2000 IECC/IRC Conservation Code to Residential Construction in Texas  

E-Print Network [OSTI]

.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.0000 0.0500 0.1000 0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 To ns - NOx/day (average) Tons - NOX/day (p eak) Apx 2x difference 1:1 2...

Haberl, J. S.; Im, P.; Culp, C.; Yazdani, B.; Fitzpatrick, T.

2004-01-01T23:59:59.000Z

418

The catalytic oxidation of propylene: investigation of catalyst activity.  

E-Print Network [OSTI]

- thur oxidation resulted in the formation oi' dioxymsthylperoxides acetalde- hydes formic aoids carbon monoxide, carbon dioxide~ hydrogen and water, &t temperatures above 500 degrees Centigrade the polymer1sation of eth- ylene became significant... that water vapor exerted a catalytio effeot on the oxidation of ethylene, while carbon dioxide showed no aooelerating effeot. Davis (ll) observed that water vapor possessed a oatalytio ei'- feet on ths oxidation of olefins. Thompson and Hinshslwood (SS...

Woodham, John Frank

1953-01-01T23:59:59.000Z

419

Application of Taguchi's orthogonal array in reducing the NOx emission of a stationary diesel engine  

Science Journals Connector (OSTI)

The main objective of this investigation is to reduce the NOx emission of a stationary diesel engine with less sacrifice on smoke intensity and brake thermal efficiency (BTE). Fuel injection timing, percentage of EGR and fuel injection pressure are chosen as factors influencing the objective. Three levels were chosen in each factor and design of experiments method was employed to design the experiments. Taguchi's L9 orthogonal array was used to conduct the engine tests with different levels of the chosen factors. Test results were analysed by analysis of variance (ANOVA) method and ANOVA table was formed for each response variable. From the ANOVA table the most influencing factor and also the significance of each factor affecting the NOx emission, smoke intensity and BTE was found out. Response graph was drawn for each response variable to determine the optimum combination of the factor levels. This optimum combination was confirmed experimentally. [Received: November 14, 2010; Accepted: March 17, 2011

S. Saravanan; G. Nagarajan; R. Ramanujam; S. Sampath

2011-01-01T23:59:59.000Z

420

Low NOx firing technology of Mitsubishi Heavy Industries  

SciTech Connect (OSTI)

This paper presents super low NO{sub x} combustion technologies successfully developed by MHI (Mitsubishi Heavy Industries, Ltd.) and its use in practice. PM (Pollution Minimum) burners directly reduce NO{sub x} from the burners themselves and MACT (Mitsubishi Advanced Combustion Technology) system, an in-furnace NO{sub x} removal system, reduces NO{sub x} generated from the main burners within the boiler. These firing systems are applicable to coal, oil, gas and also to other exotic fuels like Orimulsion or CWM (Coal Water Mixture). MRS (Mitsubishi Rotary Separator) mills minimizes unburnt carbon with its reliable ultra-fine grinding of coal and hence contribute to low NO{sub x}. These technologies have been applied in various combinations to 227 boilers for both new installation and retrofit jobs. Large 1,000 MWe oil or gas fired boilers and 700 MWe coal fired boilers have been put into commercial use, and a 1,000 MWe coal fired boiler is under commissioning. The technologies have been applied to small sized boilers for industrial use as well. All the delivered systems have been working both domestic and overseas to the customers` satisfaction.

Kaneko, Shozo; Tokuda, Kimishiro; Sato, Susumu [Mitsubishi Heavy Industries, Yokohama (Japan)

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS  

SciTech Connect (OSTI)

Potomac Electric Power Company (PEPCo) Class F fly ash is the first material to be worked on in this project. A head sample was taken and a screen analysis performed. Each size fraction was evaluated for LOI content. Table 1 shows the distribution of the as-received material by size and LOI content. From the data, 80% of the as-received material is finer than 400 mesh and the LOI content goes from high at coarse fractions and decreases to a low at the finest size fraction. SEM chemical analysis identified the as-received fly ash to mainly consist of silica (46%), aluminum oxide (21%), and iron in various forms (16%). The high iron content presents an extreme case as compared to other fly ash samples we have evaluated previously. Its effect on product testing applications could identify physical and chemical limitations as product testing progresses. Because of the high iron content, it was realized that magnetic separation would be incorporated into the early part of the pilot plant flowsheet to remove magnetic iron and, hopefully, reduce the total iron content. More analytical data will be presented in the next reporting period.

A.M. HEIN; J.Y. HWANG; M.G. MCKIMPSON; R.C. GREENLUND; X. HUANG

1998-10-01T23:59:59.000Z

422

Scaffolding Carbon Nanotubes into Single-Molecule Circuitry  

E-Print Network [OSTI]

carbon nanotubes as single-molecule biosensors. Nano Lett.1990). S.N. Xie: Single-molecule approach to enzymology.improvements to the single molecule oxidation of carbon

Collins, Philip G

2008-01-01T23:59:59.000Z

423

Quantum-chemical investigation of the interaction of nitrogen and carbon monoxide molecules with the Lewis acid sites of aluminium oxide  

SciTech Connect (OSTI)

Within the framework of the cluster approximation, using covalent and ionic models of Lewis acid sites of aluminumoxide, their electronic structure, as well as that of complexes of nitrogen and carbon monoxide molecules with them, was calculated. It was shown that the Lewis acid sites, representing a truncated tetrahedron, exhibit stronger electron-acceptor properties than the corresponding sites in the form of a truncated octahedron. For both molecules, the linear form of adsorption is energetically more profitable than the T-shaped form. The results obtained by the nonempirical SCF MO LCAO method in the STO-3GF basis and by semiempirical methods in CNDO/2 and INDO approximatations, are qualitatively the same.

Senchenya, I.N.; Chuvylkin, N.D.; Kazanskii, V.B.

1986-11-01T23:59:59.000Z

424

Synthesis of graphene oxide nanosheet: A novel glucose sensor based on nickel-graphene oxide composite film  

Science Journals Connector (OSTI)

The graphene oxide (GO) nanosheets were produced by ... IR). An electrochemical sensor based on Ni/graphene (GR) composite film was developed by...2+ into the graphene oxide film modified glassy carbon electrode ...

Fereshteh Chekin; Samira Bagheri…

2014-11-01T23:59:59.000Z

425

Carbon sequestration  

Science Journals Connector (OSTI)

...Leaver and Howard Dalton Carbon sequestration Rattan Lal * * ( lal.1...and biotic technologies. Carbon sequestration implies transfer of atmospheric...and biomass burning. 3. Carbon sequestration Emission rates from fossil...

2008-01-01T23:59:59.000Z

426

Carbon Sequestration  

Science Journals Connector (OSTI)

Carbon sequestration” refers to a portfolio of activities for ... capture, separation and storage or reuse of carbon or CO2. Carbon sequestration technologies encompass both the prevention of CO2 emissions into ...

Robert L. Kane MS; Daniel E. Klein MBA

2005-01-01T23:59:59.000Z

427

Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

particle. When used as an electrocatalyst for the oxidation of fuel at a fuel cell anode, this structure exhibits low platinum loading and elevated tolerance to carbon...

428

Crystallographic Snapshots of Cyanide- and Water-Bound C-Clusters from Bifunctional Carbon Monoxide Dehydrogenase/Acetyl-CoA Synthase  

E-Print Network [OSTI]

Nickel-containing carbon monoxide dehydrogenases (CODHs) reversibly catalyze the oxidation of carbon monoxide to carbon dioxide and are of vital importance in the global carbon cycle. The unusual catalytic CODH C-cluster ...

Kung, Yan

429

\\{NOx\\} emission characteristics of fluidized bed combustion in atmospheres rich in oxygen and water vapor for high-nitrogen fuel  

Science Journals Connector (OSTI)

Abstract The present study examines the influence of water vapor in combustion atmosphere on \\{NOx\\} emission from oxygen-enriched combustion of air-dried distilled spirit lees and its char in a laboratory fluidized bed of 760 mm high and 68 mm in inner diameter. Steam was added into the fluidizing gas to vary the vapor content in the combustion atmosphere. At a combustion temperature of 950 °C and a steam-to-fuel mass ratio (S/F) of 0.5, the presence of water vapor reduced the \\{NOx\\} concentration in the flue gas for low O2 contents (?30 vol.%) in the combustion agent but increased the \\{NOx\\} emission for high O2 contents (?40 vol.%). The possible causes were clarified for this shift from suppression to promotion of fuel-N conversion into \\{NOx\\} with raising O2 concentration in the combustion agent. Varying temperature from 850 °C to 1150 °C resulted in a peak conversion of fuel-N to \\{NOx\\} in the temperature range of 950–1050 °C for all the tested O2 concentrations. Increasing the O2 concentration tended to lower the critical temperature corresponding to such a peak fuel-N conversion. Testing results also suggested that the presence of excessive water vapor in the combustion atmosphere would inhibit the release of fuel-N in the devolatilization stage and promote the formation of some reducing gases. In addition to the anticipated diluting effect, the steam addition also shortened the reaction time for homogeneous and heterogeneous \\{NOx\\} reduction by the reducing gases and char. It is postulated that the formation of OH radicals at high O2 content and high temperature could cause the observed increase in the \\{NOx\\} emission.

Chuanqiang Zhu; Shuyuan Liu; Huan Liu; Juan Yang; Xiaoxing Liu; Guangwen Xu

2015-01-01T23:59:59.000Z

430

Carbon Smackdown: Carbon Capture  

SciTech Connect (OSTI)

In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

Jeffrey Long

2010-07-12T23:59:59.000Z

431

Investigation of the Local Structure of Graphene Oxide  

SciTech Connect (OSTI)

A study of the local structure of graphene oxide is presented. Graphene oxide is understood to be partially oxidized graphene. Absorption peaks corresponding to interlayer states suggest the presence of pristine graphitic nanoislands in graphene oxide. Site-projected partial density of states of carbon atoms bonded to oxygen atoms suggests that the broadening of the peak due to interlayer states in the carbon K-edge spectrum of graphene oxide is predominantly due to formation of epoxide linkages. Density functional theory suggests that multilayers of graphene oxide are linked by peroxide-like linkages.

S Saxena; T Tyson; E Negusse

2011-12-31T23:59:59.000Z

432

Development of a control-oriented model to optimise fuel consumption and NOX emissions in a DI Diesel engine  

Science Journals Connector (OSTI)

Abstract This paper describes a predictive NOX and consumption model, which is oriented to control and optimisation of DI Diesel engines. The model applies the Response Surface Methodology following a two-step process: firstly, the relationship between engine inputs (intake charge conditions and injection settings) and some combustion parameters (peak pressure, indicated mean effective pressure and burn angles) is determined; secondly, engine outputs (NOX and consumption) are predicted from the combustion parameters using NOX and mechanical losses models. Splitting the model into two parts allows using either experimental or modelled combustion parameters, thus enhancing the model flexibility. If experimental in-cylinder pressure is used to obtain combustion parameters, the mean error of predicted NOX and consumption are 2% and 6% respectively, with a calculation time of 5.5 ms. Using modelled parameters reduces the calculation time to 1.5 ms, with a penalty in the accuracy. The model performs well in a multi-objective optimisation, reducing NOX and consumption in different amounts depending on the objective of the optimisation.

S. Molina; C. Guardiola; J. Martín; D. García-Sarmiento

2014-01-01T23:59:59.000Z

433

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

434

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

435

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

436

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

437

Correcting injection pressure maladjustments to reduce NOX emissions by marine diesel engines  

Science Journals Connector (OSTI)

Emissions from the exhausts of marine diesel engines comprises several different gases including NOX. These are currently regulated at the international level under Regulation 13 of ANNEX VI of MARPOL 73/78, but this regulation only applies to new engines and is based on bench tests, for only a single engine designated the “parent engine”. Here, the need to take measurements from across their whole range and once in operation on board a vessel is examined. This would not only improve assessment of new equipment against the current regulation, but would also detect defects in the functioning of the engine.

C. Vanesa Durán Grados; Zigor Uriondo; Manuel Clemente; Francisco J. Jiménez Espadafor; Juan Moreno Gutiérrez

2009-01-01T23:59:59.000Z

438

Technology innovations and experience curves for nitrogen oxides control technologies  

SciTech Connect (OSTI)

This paper reviews the regulatory history for nitrogen oxides (NOx) pollutant emissions from stationary sources, primarily in coal-fired power plants. Nitrogen dioxide (NO{sub 2}) is one of the six criteria pollutants regulated by the 1970 Clean Air Act where National Ambient Air Quality Standards were established to protect public health and welfare. Patent data are used to show that in the cases of Japan, Germany, and the United States, innovations in NOx control technologies did not occur until stringent government regulations were in place, thus 'forcing' innovation. It is demonstrated that reductions in the capital and operation and maintenance (O&M) costs of new generations of high-efficiency NOx control technologies, selective catalytic reduction (SCR), are consistently associated with the increasing adoption of the control technology: the so-called learning-by-doing phenomena. The results show that as cumulative world coal-fired SCR capacity doubles, capital costs decline to {approximately} 86% and O&M costs to 58% of their original values. The observed changes in SCR technology reflect the impact of technological advance as well as other factors, such as market competition and economies of scale. 38 refs., 10 figs., 3 tabs.

Sonia Yeh; Edward S. Rubin; Margaret R. Taylor; David A. Hounshell [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). National Risk Management Research Laboratory, Office of Research and Development,

2005-12-15T23:59:59.000Z

439

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents [OSTI]

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

440

Carbon dioxide capture process with regenerable sorbents  

DOE Patents [OSTI]

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

442

Iron-Doped Carbon Aerogels:? Novel Porous Substrates for Direct Growth of Carbon Nanotubes  

Science Journals Connector (OSTI)

We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel?carbon nanotube composites. ... 33 Since these oxidized species were not detected in the XRD spectra for these materials, the oxides were likely present as surface coatings on the small clusters of reduced iron species that form during pyrolysis. ... These nanoparticles are difficult to detect by XPS because they are coated by a thin C layer and migrate into the C matrix. ...

Stephen A. Steiner; III; Theodore F. Baumann; Jing Kong; Joe H. Satcher, Jr.; Mildred S. Dresselhaus

2007-03-24T23:59:59.000Z

443

Method for control of NOx emission from combustors using fuel dilution  

DOE Patents [OSTI]

A method of controlling NOx emission from combustors. The method involves the controlled addition of a diluent such as nitrogen or water vapor, to a base fuel to reduce the flame temperature, thereby reducing NOx production. At the same time, a gas capable of enhancing flame stability and improving low temperature combustion characteristics, such as hydrogen, is added to the fuel mixture. The base fuel can be natural gas for use in industrial and power generation gas turbines and other burners. However, the method described herein is equally applicable to other common fuels such as coal gas, biomass-derived fuels and other common hydrocarbon fuels. The unique combustion characteristics associated with the use of hydrogen, particularly faster flame speed, higher reaction rates, and increased resistance to fluid-mechanical strain, alter the burner combustion characteristics sufficiently to allow operation at the desired lower temperature conditions resulting from diluent addition, without the onset of unstable combustion that can arise at lower combustor operating temperatures.

Schefer, Robert W. (Alamo, CA); Keller, Jay O (Oakland, CA)

2007-01-16T23:59:59.000Z

444

Carbon Conference  

Science Journals Connector (OSTI)

Carbon Conference ... The Fourth Hienninl Conference on Carbon will be held at the University of Buffalo, June 15 to 19. ... The Pittsburgh Section's coal technology group will meet in the conference room at Mellon Institute, Pittsburgh, June ... ...

1959-06-01T23:59:59.000Z

445

Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide  

Broader source: Energy.gov (indexed) [DOE]

Air Pollution Control Regulations: No.27 - Control of Nitrogen Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) Air Pollution Control Regulations: No.27 - Control of Nitrogen Oxide Emissions (Rhode Island) < Back Eligibility Commercial Industrial Investor-Owned Utility Municipal/Public Utility Rural Electric Cooperative Utility Program Info State Rhode Island Program Type Environmental Regulations Provider Department of Environmental Management These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe possibilities for exemptions (i.e., for sources which have the potential to emit 50 tons but do not actually reach that level) and Reasonably Available Control

446

Advanced Metal-Oxide based SCR Catalysts  

Broader source: Energy.gov [DOE]

SCR with ammonia as reductant is an effective strategy being utilized to reduce NOx emissions to meet regulated levels.

447

Gasdynamic lasers utilizing carbon gasification  

Science Journals Connector (OSTI)

A theoretical investigation was made of the influence of the processes of carbon gasification by combustion products and oxidants on the chemical composition of the active medium and the energy characteristics of a gasdynamic CO2 laser. Conditions were found under which the stored energy of the active medium was greater than 100 J/g.

A S Biryukov; V M Marchenko; A M Prokhorov

1985-01-01T23:59:59.000Z

448

Simulating the Impact of Premixed Charge Compression Ignition on Light-Duty Diesel Fuel Economy and Emissions of Particulates and NOx  

SciTech Connect (OSTI)

We utilize the Powertrain Systems Analysis Toolkit (PSAT) combined with transient engine and aftertreatment component models implemented in Matlab/Simulink to simulate the effect of premixed charge compression ignition (PCCI) on the fuel economy and emissions of light-duty diesel-powered conventional and hybrid electric vehicles (HEVs). Our simulated engine is capable of both conventional diesel combustion (CDC) and premixed charge compression ignition (PCCI) over real transient driving cycles. Our simulated aftertreatment train consists of a diesel oxidation catalyst (DOC), lean NOx trap (LNT), and catalyzed diesel particulate filter (DPF). The results demonstrate that, in the simulated conventional vehicle, PCCI can significantly reduce fuel consumption and emissions by reducing the need for LNT and DPF regeneration. However, the opportunity for PCCI operation in the simulated HEV is limited because the engine typically experiences higher loads and multiple stop-start transients that are outside the allowable PCCI operating range. Thus developing ways of extending the PCCI operating range combined with improved control strategies for engine and emissions control management will be especially important for realizing the potential benefits of PCCI in HEVs.

Gao, Zhiming [ORNL; Daw, C Stuart [ORNL; Wagner, Robert M [ORNL; Edwards, Kevin Dean [ORNL; Smith, David E [ORNL

2013-01-01T23:59:59.000Z

449

Transition metal-promoted oxygen ion conductors as oxidation catalyst  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the complete oxidation of carbon monoxide and hydrocarbons was prepared by combining oxygen ion conducting materials with active transition metals. The oxygen ion conductors used were typical fluorite-type oxides, such as ceria, zirconia, and others. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of oxygen ion conductors. The intimate contact of the two kinds of materials gave rise to a highly active oxidation catalyst. On Cu-Ce-O composite catalysts, 95% of carbon monoxide was oxidized by air at {approximately} 100 C. Complete methane oxidation on the same catalyst took place at {approximately} 550 C. When the stoichiometric amount of sulfur dioxide was sued to oxidize carbon monoxide, 96% of sulfur dioxide was reduced to elemental sulfur at temperatures above 460 C with 99% of sulfur dioxide conversion. This type of composite catalyst also showed excellent resistance to water poisoning.

Liu, W.; Sarofim, A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

1994-12-31T23:59:59.000Z

450

Carbon Cycle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Cycle Carbon Cycle Latest Global Carbon Budget Estimates Including CDIAC Estimates Terrestrial Carbon Management Data Sets and Analyses Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2011) Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Monthly Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature (2012) Monthly Fossil-Fuel CO2 Emissions: Isomass (δ 13C) of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) AmeriFlux - Terrestrial Carbon Dioxide, Water Vapor, and Energy Balance Measurements Estimates of Monthly CO2 Emissions and Associated 13C/12C Values

451

Carbon Isotopes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Trace Gases » Carbon Isotopes Atmospheric Trace Gases » Carbon Isotopes Carbon Isotopes Gateway Pages to Isotopes Data Modern Records of Carbon and Oxygen Isotopes in Atmospheric Carbon Dioxide and Carbon-13 in Methane 800,000 Deuterium Record and Shorter Records of Various Isotopic Species from Ice Cores Carbon-13 13C in CO Measurements from Niwot Ridge, Colorado and Montana de Oro, California (Tyler) 13C in CO2 NOAA/CMDL Flask Network (White and Vaughn) CSIRO GASLAB Flask Network (Allison, Francey, and Krummel) CSIRO in situ measurements at Cape Grim, Tasmania (Francey and Allison) Scripps Institution of Oceanography (Keeling et al.) 13C in CH4 NOAA/CMDL Flask Network (Miller and White) Northern & Southern Hemisphere Sites (Quay and Stutsman) Northern & Southern Hemisphere Sites (Stevens)

452

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES  

E-Print Network [OSTI]

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES A DISSERTATION SUBMITTED;ABSTRACT Autotrophic ammonia oxidation has been documented for the first time in deep- sea hydrothermal autotrophic ammonia oxidation at ~ 91 nM d-1 , and potentially produces de novo organic carbon at a rate (0

Luther, Douglas S.

453

Nox reduction with CO over supported Pd catalysts under simulated post Euro-IV diesel exhaust conditions  

Science Journals Connector (OSTI)

The catalytic reduction of NOx with CO over Pd/Al2O3 and Pd/TiO2/Al2O3 under simulated post Euro-IV diesel exhaust conditions was studied. The catalytic activities obtained...2 loadings and total amounts of reduc...

Yinghua Li; Dae-Won Lee; Young-Chul Ko…

2008-12-01T23:59:59.000Z

454

Flexible CHP System with Low NOx, CO, and VOC Emissions- Presentation by the Gas Technology Institute (GTI), June 2011  

Broader source: Energy.gov [DOE]

Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011.

455

Implications of near-term coal power plant retirement for SO2 and NOX, and life cycle GHG emissions  

E-Print Network [OSTI]

prices of electricity production Plant type Unit Price Nuclear ($/MWh) 16.51 Wind ($/MWh) 201 Hydro Top SO2 100 430 95 440 100 430 Top NOX 105 350 100 380 105 345 Small, inefficient 125 410 125 405 125) Manitoba Hydro Manitoba Hydro Undertaking # 57 http://www.pub.gov.mb.ca/exhibits/mh-83.pdf. (5) Sotkiewicz

Jaramillo, Paulina

456

Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and  

E-Print Network [OSTI]

combustion, biomass burning and soil emissions Lyatt Jaegle´ ,a Linda Steinberger,a Randall V. Martinbc anthropogenic emissions, mostly resulting from fossil fuel combustion and biomass burning, are superimposed-CHEM chemical transport model. Top-down NOx sources are partitioned among fuel combustion (fossil fuel

Lyatt Jaeglé

457

Abatement of Air Pollution: The Clean Air Interstate Rule (CAIR) Nitrogen Oxides (Nox) Ozone Season Trading Program (Connecticut)  

Broader source: Energy.gov [DOE]

These regulations may apply to fossil-fuel fired emission units, and describe nitrogen emission allocations that owners of such units must meet. The regulations also contain provisions for...

458

SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD  

E-Print Network [OSTI]

in the atmosphere. TD-GC-MS ANALYSIS METHODOLOGY A thermal desorption (TD) injection device (M. Ezrin, 1991. Valve Spindle 10. Carrier Gas Inlet 11. Inlet Assembly 12. Injection Port Insert PAH standard Solution, 1ppm, 1µL injection Alkanes Standard Solution, 0.1ppm, 1µL injection FUTURE EXPERIMENTS Verify PM

Holmén, Britt A.

459

Carbon and carbon monoxide hydrogenation on nickel: support effects  

SciTech Connect (OSTI)

Hydrogenation of carbon, deposited on nickel catalysts by CO disproportionation, was investigated by temperature-programmed surface reaction (TPSR) for four oxide supports, alumina (Al/sub 2/O/sub 3/), silica (SiO/sub 2/), titanium oxide (TiO/sub 2/), and SiO/sub 2/.Al/sub 2/O/sub 3/. The rate of carbon monoxide hydrogenation was measured by temperature-programmed reaction (TPR) for comparison. The rate of carbon hydrogenation to methane was found to be independent of the support and an average activation energy of 42 kJ/mol was estimated. In contrast, the rate of carbon monoxide hydrogenation was very sensitive to the catalyst support. Nickel (Ni) supported on TiO/sub 2/ exhibited the highest specific activity, and two distinct sites for methanation were observed on Ni/TiO/sub 2/ and Ni/Al/sub 2/O/sub 3/. The lowest specific activities were observed for Ni/SiO/sub 2/ and Ni/SiO/sub 2/.Al/sub 2/O/sub 3/. For all catalysts, carbon hydrogenation occurred at a lower temperature than carbon monoxide hydrogenation. For both TPR and TPSR, small amounts of ethane were formed and at a lower temperature than methane. The amount of less-active, ..beta..-carbon observed in TPSR experiments was very small on all catalysts. These results indicate that at high coverages, carbon hydrogenation does not depend on the support, and thus it is not rate-determining for CO hydrogenation in excess hydrogen. The support is also shown to change the specific rate of carbon monoxide methanation; activity differences seen in steady-state experiments are not just due to differences in site densities. 5 figures, 5 tables.

Ozdogan, S.Z.; Gochis, P.D.; Falconer, J.L.

1983-10-01T23:59:59.000Z

460

Effects of Catalysts on Emissions from Heavy-Duty Diesel Retrofits for PM and NOX Control  

Broader source: Energy.gov [DOE]

The more heavily catalyzed and the hotter the exhaust temperature, the more strongly the aftertreatment will oxidize the exhaust.

Note: This page contains sample records for the topic "oxides nox carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Method for reducing NOx during combustion of coal in a burner  

DOE Patents [OSTI]

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

2008-04-15T23:59:59.000Z

462

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application  

Science Journals Connector (OSTI)

Exhaust Gas Fuel Reforming of Diesel Fuel by Nonthermal Arc Discharge for NOx Trap Regeneration Application ... It has been demonstrated that low current arc discharges are highly nonhomogenous. ... In the second case, which corresponds to the most favorable one, assuming (i) a 100 kW car engine thermal power (i.e., 40 kW mechanical power), (ii) that the plasma will treat only a small fraction of the exhaust gas (typically 3.5%), (iii) that the plasma will operate under a cycling operating mode, and (iv) an 80% efficiency for the onboard production of electricity from the car engine, one can estimate that the electric power needed to run the plasma will be around 2.2% of the engine power only during 12 s every 11 km (6.8 miles), that is, 12 s every 6 min assuming a 110 km·h?1 (68 mph) average car velocity. ...

Alexandre Lebouvier; Franc?ois Fresnet; Fre?de?ric Fabry; Vale?rie Boch; Vandad Rohani; Franc?ois Cauneau; Laurent Fulcheri

2011-02-03T23:59:59.000Z

463

New CoO?SiO2-Sol Pillared Clays as Catalysts for NOx Conversion  

Science Journals Connector (OSTI)

For this purpose, codoped SiO2 sol PILC (CoSi?PILC) is prepared via an organic template route and the interlayer pillar structure is systematically investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), and nitrogen adsorption isotherm measurement, along with a preliminary test on the de-NOx catalytic activity. ... The steady-state selective catalytic reduction of NO with CO over CoSi?PILC catalyst was carried out in an isothermal fixed-bed continuous flow quartz reactor (o.d. ... The elemental composition of CoSi?PILC was analyzed to estimate the pillar content of SiO2 and CoO. ...

Jin-Ho Choy; Hyun Jung; Yang-Su Han; Joo-Byoung Yoon; Yong-Gun Shul; Hyun-Jong Kim

2002-08-20T23:59:59.000Z

464

Policy Brief October 2014  

E-Print Network [OSTI]

Standard) for electricity generation, reduced fuel carbon intensity (Low Carbon Fuel Standard), improvement by each AB 32 sector or sub-sector for total particulate matter (PM), particulate elemental carbon (EC), particulate organic carbon (OC), oxides of nitrogen (NOx), oxides of sulfur (SOx), reactive organic gases (ROG

California at Davis, University of

465

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

466

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

467

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

468

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

469

Magnetic properties of carbon-coated, ferromagnetic nanoparticles produced by a carbon-arc method  

E-Print Network [OSTI]

to generate carbon-coated transition metal (TM) and TM-carbide nanocrystallites. The magnetic nanocrystallites report here on the synthesis and separation of carbon-coated ferromagnetic transition metal (TM) and TM of transition metal oxide (TM=Fe, Co, and Ni) powder and a combination of graphite powder and graphite cement

McHenry, Michael E.

470

Carbon Nanotubes.  

E-Print Network [OSTI]

?? Carbon nanotubes have extraordinary mechanical, electrical, thermal andoptical properties. They are harder than diamond yet exible, have betterelectrical conductor than copper, but can also… (more)

Fredriksson, Tore

2014-01-01T23:59:59.000Z