National Library of Energy BETA

Sample records for overrun limitation sol

  1. QuantaSol Limited | Open Energy Information

    Open Energy Info (EERE)

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  2. Critical Parameters for Turbulent Transport in the SOL: Mechanism for the L-H Transition and its impact on the H-mode Power Threshold and Density Limit in ITER

    E-Print Network [OSTI]

    Critical Parameters for Turbulent Transport in the SOL: Mechanism for the L-H Transition and its impact on the H-mode Power Threshold and Density Limit in ITER

  3. Procedures for Correcting Cost Overruns on OSP Funds It is the responsibility of the PI to ensure that their sponsored program fund/index is not

    E-Print Network [OSTI]

    Lawrence, Rick L.

    Procedures for Correcting Cost Overruns on OSP Funds It is the responsibility of the PI to ensure that their sponsored program fund/index is not overspent. On occasion expenditures for a particular project may exceed the overdraft condition immediately. The procedure to be followed once a cost overrun or deficit is identified

  4. Limiter

    DOE Patents [OSTI]

    Cohen, S.A.; Hosea, J.C.; Timberlake, J.R.

    1984-10-19

    A limiter with a specially contoured front face is provided. The front face of the limiter (the plasma-side face) is flat with a central indentation. In addition, the limiter shape is cylindrically symmetric so that the limiter can be rotated for greater heat distribution. This limiter shape accommodates the various power scrape-off distances lambda p, which depend on the parallel velocity, V/sub parallel/, of the impacting particles.

  5. Limiter

    DOE Patents [OSTI]

    Cohen, Samuel A. (Hopewell, NJ); Hosea, Joel C. (Princeton, NJ); Timberlake, John R. (Allentown, NJ)

    1986-01-01

    A limiter with a specially contoured front face accommodates the various power scrape-off distances .lambda..sub.p, which depend on the parallel velocity, V.sub..parallel., of the impacting particles. The front face of the limiter (the plasma-side face) is flat with a central indentation. In addition, the limiter shape is cylindrically symmetric so that the limiter can be rotated for greater heat distribution.

  6. DE-SOL-0008448

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia National 1 PAGE 1 OF2Guidance to the1NDE-SOL-0008445I,

  7. Nanocrystal/sol-gel nanocomposites

    DOE Patents [OSTI]

    Petruska, Melissa A. (Los Alamos, NM); Klimov, Victor L. (Los Alamos, NM)

    2007-06-05

    The present invention is directed to solid composites including colloidal nanocrystals within a sol-gel host or matrix and to processes of forming such solid composites. The present invention is further directed to alcohol soluble colloidal nanocrystals useful in formation of sol-gel based solid composites.

  8. Nanocrystal/sol-gel nanocomposites

    DOE Patents [OSTI]

    Petruska, Melissa A. (Los Alamos, NM); Klimov, Victor L. (Los Alamos, NM)

    2012-06-12

    The present invention is directed to solid composites including colloidal nanocrystals within a sol-gel host or matrix and to processes of forming such solid composites. The present invention is further directed to alcohol soluble colloidal nanocrystals useful in formation of sol-gel based solid composites

  9. Sol-gel derived sorbents

    DOE Patents [OSTI]

    Sigman, Michael E.; Dindal, Amy B.

    2003-11-11

    Described is a method for producing copolymerized sol-gel derived sorbent particles for the production of copolymerized sol-gel derived sorbent material. The method for producing copolymerized sol-gel derived sorbent particles comprises adding a basic solution to an aqueous metal alkoxide mixture for a pH.ltoreq.8 to hydrolyze the metal alkoxides. Then, allowing the mixture to react at room temperature for a precalculated period of time for the mixture to undergo an increased in viscosity to obtain a desired pore size and surface area. The copolymerized mixture is then added to an immiscible, nonpolar solvent that has been heated to a sufficient temperature wherein the copolymerized mixture forms a solid upon the addition. The solid is recovered from the mixture, and is ready for use in an active sampling trap or activated for use in a passive sampling trap.

  10. Sol-Gel Deposited Electrochromic Coatings

    E-Print Network [OSTI]

    Ozer, N.

    2010-01-01

    layer, (3) solid electrolyte or ion conductor, (4) ionof inorganic type solid electrolytes [20,21]. An all sol-gel

  11. Hybrid sol-gel optical materials

    DOE Patents [OSTI]

    Zeigler, John M. (Albuquerque, NM)

    1992-01-01

    Hybrid sol-gel materials comprise silicate sols cross-linked with linear polysilane, polygermane, or poly(silane-germane). The sol-gel materials are useful as optical identifiers in tagging and verification applications and, in a different aspect, as stable, visible light transparent non-linear optical materials. Methyl or phenyl silicones, polyaryl sulfides, polyaryl ethers, and rubbery polysilanes may be used in addition to the linear polysilane. The linear polymers cross-link with the sol to form a matrix having high optical transparency, resistance to thermooxidative aging, adherence to a variety of substrates, brittleness, and a resistance to cracking during thermal cycling.

  12. Hybrid sol-gel optical materials

    DOE Patents [OSTI]

    Zeigler, J.M.

    1993-04-20

    Hybrid sol-gel materials comprise silicate sols cross-linked with linear polysilane, polygermane, or poly(silane-germane). The sol-gel materials are useful as optical identifiers in tagging and verification applications and, in a different aspect, as stable, visible light transparent non-linear optical materials. Methyl or phenyl silicones, polyaryl sulfides, polyaryl ethers, and rubbery polysilanes may be used in addition to the linear polysilane. The linear polymers cross-link with the sol to form a matrix having high optical transparency, resistance to thermooxidative aging, adherence to a variety of substrates, brittleness, and a resistance to cracking during thermal cycling.

  13. Hybrid sol-gel optical materials

    DOE Patents [OSTI]

    Zeigler, John M. (Albuquerque, NM)

    1993-01-01

    Hybrid sol-gel materials comprise silicate sols cross-linked with linear polysilane, polygermane, or poly(silane-germane). The sol-gel materials are useful as optical identifiers in tagging and verification applications and, in a different aspect, as stable, visible light transparent non-linear optical materials. Methyl or phenyl silicones, polyaryl sulfides, polyaryl ethers, and rubbery polysilanes may be used in addition to the linear polysilane. The linear polymers cross-link with the sol to form a matrix having high optical transparency, resistance to thermooxidative aging, adherence to a variety of substrates, brittleness, and a resistance to cracking during thermal cycling.

  14. A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel Process Employing Heterometallic Alkoxides A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel...

  15. Plexus Sol | Open Energy Information

    Open Energy Info (EERE)

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  16. AGGIE SOL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s s iof1AGGIE SOL The University of California,

  17. AGGIE SOL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s s iof1AGGIE SOL The University of California,AGGIE

  18. AGGIE SOL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s s iof1AGGIE SOL The University of

  19. AGGIE SOL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment| Department ofApplianceU.S.Departmentthe(Revision 2)EnergyAGGIE SOL

  20. Serie cronolgica de un CME estallando desde el Sol

    E-Print Network [OSTI]

    Christian, Eric

    #12;Serie cronológica de un CME estallando desde el Sol Imagen Compuesta del Sol en luz anaranjado?). Sin embargo, nuestro Sol nos da más que solo una corriente de luz y calor. El Sol nos baña a nosotros y al resto del sistema solar con energía en forma de luz, partículas cargadas eléctricamente y

  1. Sol-gel antireflective coating on plastics

    DOE Patents [OSTI]

    Ashley, C.S.; Reed, S.T.

    1988-01-26

    An antireflection film made from reliquified sol-gel hydrolyzation, condensation polymeric reaction product of a silicon, alkoxides and/or metal alkoxides, or mixtures thereof. The film is particularly useful for coating plastics.

  2. Sol-gel antireflective coating on plastics

    DOE Patents [OSTI]

    Ashley, Carol S. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM)

    1990-01-01

    An antireflection film made from a reliquified sol-gel hydrolyzation, condensation polymeric reaction product of a silicon, alkoxides and/or metal alkoxides, or mixtures thereof. The film is particularly useful for coating plastics.

  3. Sol-gel method for encapsulating molecules

    DOE Patents [OSTI]

    Brinker, C. Jeffrey (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Bhatia, Rimple (Albuquerque, NM); Singh, Anup K. (San Francisco, CA)

    2002-01-01

    A method for encapsulating organic molecules, and in particular, biomolecules using sol-gel chemistry. A silica sol is prepared from an aqueous alkali metal silicate solution, such as a mixture of silicon dioxide and sodium or potassium oxide in water. The pH is adjusted to a suitably low value to stabilize the sol by minimizing the rate of siloxane condensation, thereby allowing storage stability of the sol prior to gelation. The organic molecules, generally in solution, is then added with the organic molecules being encapsulated in the sol matrix. After aging, either a thin film can be prepared or a gel can be formed with the encapsulated molecules. Depending upon the acid used, pH, and other processing conditions, the gelation time can be from one minute up to several days. In the method of the present invention, no alcohols are generated as by-products during the sol-gel and encapsulation steps. The organic molecules can be added at any desired pH value, where the pH value is generally chosen to achieve the desired reactivity of the organic molecules. The method of the present invention thereby presents a sufficiently mild encapsulation method to retain a significant portion of the activity of the biomolecules, compared with the activity of the biomolecules in free solution.

  4. Neutron detector using sol-gel absorber

    DOE Patents [OSTI]

    Hiller, John M. (Oak Ridge, TN); Wallace, Steven A. (Oak Ridge, TN); Dai, Sheng (Knoxville, TN)

    1999-01-01

    An neutron detector composed of fissionable material having ions of lithium, uranium, thorium, plutonium, or neptunium, contained within a glass film fabricated using a sol-gel method combined with a particle detector is disclosed. When the glass film is bombarded with neutrons, the fissionable material emits fission particles and electrons. Prompt emitting activated elements yielding a high energy electron contained within a sol-gel glass film in combination with a particle detector is also disclosed. The emissions resulting from neutron bombardment can then be detected using standard UV and particle detection methods well known in the art, such as microchannel plates, channeltrons, and silicon avalanche photodiodes.

  5. Comparison of effectiveness of sub-slab ventilation systems for indoor radon mitigation: A numerical study; Comparaison a l`aide d`un outil numerique de l`efficacite des systemes de ventilation active du sol limitant la penetration du radon dans l`habitat

    SciTech Connect (OSTI)

    Bonnefous, Y.C. [Ecole Nationale des Travaux Publics de l`Etat, 69 - Vaulx en Velin (France). Lab. Sciences de l`Habitat]|[Lawrence Berkeley Lab., CA (United States); Gadgil, A.J. [Lawrence Berkeley Lab., CA (United States); Allard, F. [Institut National des Sciences Appliquees (INSA), 69 - Villeurbanne (France)

    1992-04-01

    The functioning of an active sub-slab ventilation system (SVS) has been studied successfully with the help of a previously evaluated numerical model. The parameters explored are the permeability of the sub-slab and the gravel placed beneath it, the amplitude of applied pressure at the installation point of the system and the functioning method: depressurization or pressurization. The mechanisms contributing to the success of the two systems are identified. This numerical study shows that the presence of a layer of gravel beneath the sub-slab considerably improves the performance of the SVS. Considered separately from the extremely permeable sub-slabs, the depressurization systems perform better than the pressurization systems. 17 refs. [Francais] Le fonctionnement des Systemes de Ventilation active du Sol (SVS) a ete etudie a l`aide d`un outil numerique precedemment evalue avec succes. Les parametres explores sont les permeabilites du sol et du gravier place sous plancher bas, l`amplitude de la pression appliquee au point d`installation du systeme, et le mode de fonctionnement: Depressurisation ou Pressurisation. Les mecanismes contribuant au succes des deux systemes sont identifies. Cette etude numerique montre que la presence d`une couche de gravier sous plancher bas ameliore de facon considerable les performances des SVS. Mis a part le cas des sols extremement permeables, les systemes de Depressurisation ont de meilleures performances que les systemes de Pressurisation. 17 refs.

  6. Transparent ultralow-density silica aerogels prepared by a two-step sol-gel process

    SciTech Connect (OSTI)

    Tillotson, T.M.; Hrubesh, L.W.

    1991-09-01

    Conventional silica sol-gel chemistry is limited for the production of transparent ultralow-density aerogels because (1) gelation is either slow or unachievable, and (2) even when gelation is achieved, the large pore sizes result in loss of transparency for aerogels <.020 g/cc. We have developed a two-step sol-gel process that circumvents the limitations of the conventional process and allows the formation of ultralow-density gels in a matter of hours. we have found that the gel time is dependent on the catalyst concentration. After supercritical extraction, the aerogels are transparent, uncracked tiles with densities as low as .003 g/cc. 6 figs., 11 refs.

  7. Sol-Gel Manufactured Energetic Materials

    DOE Patents [OSTI]

    Simpson, Randall L. (Livermore, CA); Lee, Ronald S. (Livermore, CA); Tillotson, Thomas M. (Tracy, CA); Hrubesh, Lawrence W. (Pleasanton, CA); Swansiger, Rosalind W. (Livermore, CA); Fox, Glenn A. (Livermore, CA)

    2005-05-17

    Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.

  8. Sol-gel manufactured energetic materials

    DOE Patents [OSTI]

    Simpson, Randall L.; Lee, Ronald S.; Tillotson, Thomas M.; Hrubesh, Lawrence W.; Swansiger, Rosalind W.; Fox, Glenn A.

    2003-12-23

    Sol-gel chemistry is used for the preparation of energetic materials (explosives, propellants and pyrotechnics) with improved homogeneity, and/or which can be cast to near-net shape, and/or made into precision molding powders. The sol-gel method is a synthetic chemical process where reactive monomers are mixed into a solution, polymerization occurs leading to a highly cross-linked three dimensional solid network resulting in a gel. The energetic materials can be incorporated during the formation of the solution or during the gel stage of the process. The composition, pore, and primary particle sizes, gel time, surface areas, and density may be tailored and controlled by the solution chemistry. The gel is then dried using supercritical extraction to produce a highly porous low density aerogel or by controlled slow evaporation to produce a xerogel. Applying stress during the extraction phase can result in high density materials. Thus, the sol-gel method can be used for precision detonator explosive manufacturing as well as producing precision explosives, propellants, and pyrotechnics, along with high power composite energetic materials.

  9. Sandia Energy - Mesa del Sol Project Is Finalist for International...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Security Renewable Energy Energy Surety Mesa del Sol Energy Facilities Grid Integration Partnership News Distribution Grid Integration News & Events Photovoltaic...

  10. Sol-gel processing with inorganic metal salt precursors

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2004-10-19

    Methods for sol-gel processing that generally involve mixing together an inorganic metal salt, water, and a water miscible alcohol or other organic solvent, at room temperature with a macromolecular dispersant material, such as hydroxypropyl cellulose (HPC) added. The resulting homogenous solution is incubated at a desired temperature and time to result in a desired product. The methods enable production of high quality sols and gels at lower temperatures than standard methods. The methods enable production of nanosize sols from inorganic metal salts. The methods offer sol-gel processing from inorganic metal salts.

  11. Documentation EnMetSol 1 Documentation -EnMetSOL

    E-Print Network [OSTI]

    Oldenburg, Carl von Ossietzky Universität

    which provides high quality daylight and solar radiation data for Western and Central Europe. 9th von Ossietzky University of Oldenburg Dr. A. Hammer Date 2014-03-25 #12;Documentation ­ EnMetSol 2 of determining the global radiation at the ground by using data from a geostationary satellite, see [1,2]. We use

  12. SolGen | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North| OpenSolutionSolGen Jump

  13. SolSolution | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery TechnologySocovoltaic Systems Jump to:SoftSuisseSolSolution

  14. SolBeam Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEurope GmbH JumpSlough HeatMccoy Geothermal AreaSolBeam Inc

  15. TiSol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJThin Film Solar Technologies JumpTiSol Jump to: navigation, search

  16. DE-SOL-0008445 Attachment L-4

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia National 1 PAGE 1 OF2Guidance to the1NDE-SOL-0008445

  17. E2SOL LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower VenturesInformation9)askDouble Oak,Durra BuildingCane FuelFuelEE2SOL

  18. Synthesis of Sol-Gel Matrices for Encapsulation of Enzymes Using an Aqueous Route

    SciTech Connect (OSTI)

    Ashley, C.S.; Bhatia, R.B.; Brinker, C.J.; Harris, T.M.

    1998-11-23

    Sol-gel matrices are promising host materials for potential chemical and biosensor applications. Previous studies have focused on modified sol-gel routes using alkoxides for encapsulation of enzymes. However the formation of alcohol as a byproduct during hydrolysis and condensation reactions poses limitations. We report the immobilization of glucose oxidase and peroxidase in silica prepared by an aqueous route which may provide a more favorable environment for the biomolecules. A two step aqueous sol-gel procedure using sodium silicate as the precursor was developed to encapsulate the enzymes and the dye precursor, o-dianisidine. Glucose oxidase catalyzes the oxidation of glucose to give gluconic acid and hydrogen peroxide. Peroxidase then catalyzes the reaction of the dye precursor with hydrogen peroxide to produce a colored product. The kinetics of the coupled enzymatic reactions were monitored by optical spectroscopy and compared to those occurring in tetramethyl orthosilicate (TMOS) derived silica matrices developed by Yamanaka. Enhanced kinetics in the aqueous silicate matrices were related to differences in the host microstructure as elucidated by microstructural comparisons of the corresponding aerogels.

  19. Sol-gel coatings for optoelectronic devices

    SciTech Connect (OSTI)

    Avellaneda, C.O.; Macedo, M.A.; Florentino, A.O.; Aegerter, M.A. [Univ. of Sao Paulo, Sao Carlos (Brazil). Inst. de Fisica e Quimica

    1994-12-31

    Nb{sub 2}O{sub 5} prepared by a sol-gel process in form of coatings and aerogels are new materials which present interesting properties: (a) The coatings present electrochromic properties and exhibit a blue coloration under Li{sup +} insertion with 100% reversible variation of the optical transmission in the visible and near infrared range between 80% and 200% and have a high chemical stability (tested up to 2,000 cycles). (b) They are semiconductor and present a photoelectric effect when illuminating in the UV region ({lambda} < 360 nm). These films are therefore very promising to be used in electrochromic devices, as electrodes for photoelectrochemical purpose and the development of nanocrystalline solar cell. (c) When prepared in aerogel form, the high BET surface area of the powders is a promising asset to use these new materials for catalytic purposes for air pollution control.

  20. Sol-gel processing of energetic materials

    SciTech Connect (OSTI)

    Tillotson, T.M.; Hrubesh, L.H.; Fox, G.L.; Simpson, R.L.; Lee, R.W.; Swansiger, R.W.; Simpson, L.R.

    1997-08-18

    As part of a new materials effort, we are exploring the use of sol- gel chemistry to manufacture energetic materials. Traditional manufacturing of energetic materials involves processing of granular solids. One application is the production of detonators where powders of energetic material and a binder are typically mixed and compacted at high pressure to make pellets. Performance properties are strongly dependent on particle size distribution, surface area of its constituents, homogeneity of the mix, and void volume. The goal is to produce detonators with fast energy release rate the are insensitive to unintended initiation. In this paper, we report results of our early work in this field of research, including the preparation of detonators from xerogel molding powders and aerogels, comparing the material properties with present state-of-the-art technology.

  1. Solar Flare Measurements with STIX and MiSolFA

    E-Print Network [OSTI]

    Casadei, Diego

    2014-01-01

    Solar flares are the most powerful events in the solar system and the brightest sources of X-rays, often associated with emission of particles reaching the Earth and causing geomagnetic storms, giving problems to communication, airplanes and even black-outs. X-rays emitted by accelerated electrons are the most direct probe of solar flare phenomena. The Micro Solar-Flare Apparatus (MiSolFA) is a proposed compact X-ray detector which will address the two biggest issues in solar flare modeling. Dynamic range limitations prevent simultaneous spectroscopy with a single instrument of all X-ray emitting regions of a flare. In addition, most X-ray observations so far are inconsistent with the high anisotropy predicted by the models usually adopted for solar flares. Operated at the same time as the STIX instrument of the ESA Solar Orbiter mission, at the next solar maximum (2020), they will have the unique opportunity to look at the same flare from two different directions: Solar Orbiter gets very close to the Sun wit...

  2. Sol-gel-derived Epitaxial Nanocomposite Thin Films with Large...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sol-gel-derived Epitaxial Nanocomposite Thin Films with Large Sharp Magnetoelectric Effect Home Author: B. Liu, T. Sun, J. He, V. P. Dravid Year: 2010 Abstract: Nanostructures of...

  3. Sol-gel synthesis and characterization of tetra-alkoxysilane and bridged-polysilsesquioxane materials in non-polar solvents

    SciTech Connect (OSTI)

    Yamanaka, S.A.; Martino, A.; Kawola, J.S.; Loy, D.A. [Sandia National Laboratories, Albuquerque, NM (United States)

    1996-10-01

    Although the sol-gel method has widely been used for the encapsulation of molecules in porous glass materials, the variety of dopants has been limited by the solvents used in processing. Polar solvents, such as ethanol, methanol or tetrahydrofuran, are typically added as cosolvents to prevent phase separation between the organic metal alkoxide and water. Non-polar solvents are generally not suitable for sol-gel processing since they are immicible with the aqueous phase. Our study increases the availability of solvents that may be used in sol-gel processing and therefore expands the range of molecules suitable for encapsulation. Here, we report a novel method for preparing both silica sol-gel materials and bridged-polysilsesquioxane materials in a non-polar, hydrocarbon solvent. The method involves the formation of an inverse micelle upon addition of the surfactant, didodecyldimethylammonium bromide, to toluene. The dynamic nature of the micelle allows sol-gel reactions to occur between water (soluble in the polar core of the micelle) and the metal alkoxide precursor (soluble in the solvent phase). Materials prepared by this technique have been characterized by nitrogen sorption porosimetry, SEM, solid state {sup 29}Si NMR, TGA and XRD. Photochemical conversion of technetium fluorides and oxyfluorides is largely uninvestigated. Because technetium was introduced into U.S. uranium enrichment plants, decommissioning and decontamination of these plants will involve technetium fluorides and oxyfluorides. Photochemical conversion of such compounds may facilitate waste minimization and cost avoidance goals during plant clean-up. Photochemical fluorination using ultraviolet photolysis of a mixture of fluorine and oxygen gases is an effective means of converting solid, nonvolatile fluorides of fight actinides, such as U, Np, and Pu, into volatile hexafluorides thereby removing surface radioactive contamination.

  4. Micro-PIXE characterization of interactions between a sol-gel derived bioactive glass and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    - 1 - Micro-PIXE characterization of interactions between a sol-gel derived bioactive glass the different steps of this bioactivity process via a complete micro-PIXE characterization of a sol- gel derived

  5. Environmental Assessment and Metrics for Solar: Case Study of SolFocus Solar Concentrator Systems

    E-Print Network [OSTI]

    Reich-Weiser, Corinne; Dornfeld, David; Horne, Steve

    2008-01-01

    Assumptions Assembly in India Energy Breakdown t to on3. Energy Breakdown for SolFocus Concentrator System. India

  6. Dgradation et transformation d'un compost ptrolier apport des sols battants et effets sur

    E-Print Network [OSTI]

    Boyer, Edmond

    Dégradation et transformation d'un compost pétrolier apporté à des sols battants et effets sur devenir d'un compost pétrolier après incorporation dans le sol et à appré- cier sa valeur d'amendement. L'expérimentation a été effectuée au laboratoire sur 2 sols de texture limoneuse enrichis en compost selon une dose unique

  7. 3rd ITPA SOL and Divertor Topical Group meeting, St. Petersburg, July 2003 ASDEX Upgrade

    E-Print Network [OSTI]

    3rd ITPA SOL and Divertor Topical Group meeting, St. Petersburg, July 2003 ASDEX Upgrade Arne for power balance A. Kallenbach, 3rd ITPA SOL and Divertor Topical Group meeting, St. Petersburg, July 2003 ms spatial resolution 1-2 mm #12;divertor geometries A. Kallenbach, 3rd ITPA SOL and Divertor Topical

  8. Sol-gel matrices for direct colorimetric detection of analytes

    DOE Patents [OSTI]

    Charych, Deborah H. (Albany, CA); Sasaki, Darryl (Albuquerque, NM); Yamanaka, Stacey (Dallas, TX)

    2000-01-01

    The present invention relates to methods and compositions for the direct detection of analytes using color changes that occur in immobilized biopolymeric material in response to selective binding of analytes to their surface. In particular, the present invention provides methods and compositions related to the encapsulation of biopolymeric material into metal oxide glass using the sol-gel method.

  9. MECHANICAL PROPERTY CHARACTERIZATION OF SOL-GEL DERIVED NANOMATERIALS

    E-Print Network [OSTI]

    Brinker, C. Jeffrey

    mechanical behavior of polysilicate aerogels, prepared using the sol-gel process. Two series of materials were prepared, derivatized with silylating agents, processed into coating solutions, and characterized properties of aerogel thin films were characterized. vi #12;Table of Contents Abstract

  10. Sol-gel chemistry by ring-opening polymerization

    SciTech Connect (OSTI)

    RAHIMIAN,KAMYAR; LOY,DOUGLAS A.

    2000-02-07

    Sol-gel processing of materials is plagued by shrinkage during polymerization of the alkoxide monomers and processing (aging and drying) of the resulting gels. The authors have developed a new class of hybrid organic-inorganic materials based on the solventless ring-opening polymerization (ROP) of monomers bearing the 2,2,5,5-tetramethyl-2,5-disilaoxacyclopentyl group, which permits them to drastically reduce shrinkage in sol-gel processed materials. Because the monomers are polymerized through a chain growth mechanism catalyzed by base rather than the step growth mechanism normally used in sol-gel systems, hydrolysis and condensation products are entirely eliminated. Furthermore, since water is not required for hydrolysis, an alcohol solvent is not necessary. Monomers with two disilaoxacyclopentyl groups, separated by a rigid phenylene group or a more flexible alkylene group, were prepared through disilylation of the corresponding diacetylenes, followed by ring closure and hydrogenation. Anionic polymerization of these materials, either neat or with 2,2,5,5-tetramethyl-2,5-disila-1-oxacyclopentane as a copolymer, affords thermally stable transparent gels with no visible shrinkage. These materials provide an easy route to the introduction of sol-gel type materials in encapsulation of microelectronics, which they have successfully demonstrated.

  11. Aero-Sol-Gel (ASG) Reactor For Nano-Powder Synthesis G. Beaucage, J. Hyeon-Lee, D. J. Kohls

    E-Print Network [OSTI]

    Beaucage, Gregory

    Aero-Sol-Gel (ASG) Reactor For Nano-Powder Synthesis G. Beaucage, J. Hyeon-Lee, D. J. Kohls-structured oxides where sol- gel reactions are carried out in aerosol droplets. This aero-sol-gel reactor (ASG-scale structure and high specific surface areas (100 to 700 m2 /g) [1, 2]. This aero-sol- gel reactor (ASG

  12. Sol-gel polymerization of tetraalkoxygermanium and organotrialkoxygermanium monomers

    SciTech Connect (OSTI)

    Baugher, B.M.; Loy, D.A. [Sandia National Labs., Albuquerque, NM (United States). Properties of Organic Materials Dept.

    1996-12-31

    While the sol-gel polymerizations of tetraalkoxy- and organotrialkoxysilanes have been extensively studied, there have been few reports of similar investigations with the analogous tetraalkoxygermanium and organotrialkoxygermanium compounds. Germanium alkoxides have received less attention due, in part to their higher cost, but also their greater reactivity towards hydrolysis and condensation reactions. Germanium oxide materials are potentially interesting because the Ge-O-Ge linkage is labile (compared with the siloxane bond in silica gels and polysilsequioxanes) opening up the possibility of further chemical modification of the polymeric architecture. This may permit hydrolytic reorganization of germanium oxide networks under relatively mild conditions. In this paper, the authors present the results of investigations of the sol-gel polymerizations of tetraethoxygermanium, tetraisopropoxygermanium, and methyltriethoxy-germanium to afford network materials as both xerogels and aerogels.

  13. Synthesis of zirconium oxide nanoparticle by sol-gel technique

    SciTech Connect (OSTI)

    Lim, H. S.; Ahmad, A.; Hamzah, H. [School of Chemical Science and Food Technology, Faculty of Science and Technology, National University of Malaysia, 43600 Bangi (Malaysia)

    2013-11-27

    Zirconium oxide nanoparticle is synthesized using sol-gel technique. Various mole ratio of ammonia solution and nitric acid relative to zirconium propoxide is added in the reaction to study the effect on the crystallinity and particle size on zirconium oxide particle. Zirconium oxide synthesized with nitric acid have the smallest particle size under FESEM image and show the increasing formation of crystalline tetragonal phase under XRD diffractogram.

  14. Solventless sol-gel chemistry through ring-opening polymerization of bridged disilaoxacyclopentanes

    SciTech Connect (OSTI)

    RAHIMIAN,KAMYAR; LOY,DOUGLAS A.

    2000-04-04

    Disilaoxacyclopentanes have proven to be excellent precursors to sol-gel type materials. These materials have shown promise as precursors for encapsulation and microelectronics applications. The polymers are highly crosslinked and are structurally similar to traditional sol-gels, but unlike typical sol-gels they are prepared without the use of solvents and water, they have low VOC's and show little shrinkage during processing.

  15. Reflexiones y alegrías en los 20 años de Sol del Río

    E-Print Network [OSTI]

    Cea, José Roberto

    1993-10-01

    FALL 1993 125 Reflexiones y alegrías en los 20 años de Sol del Río José Roberto Cea En sus inicios, este grupo teatral se llamó Sol del Río 32, ahora es la Compañía Sol del Río. Su fundación fue el 7 de junio de 1973. Han madurado mucho, que la... florecer mejor. Sol del Río ha hecho muchas muy buenas acciones: como mantenerse grupalmente en su trabajo, hacer de este trabajo una profesión de fe y seguridad, lo que les ha permitido hacer espectáculos teatrales que se han mostrado sin rubor alguno...

  16. Arylene-bridged 2,2,5,5-tetramethyl2,5-disila-1-oxacyclopentanes as precursors to non-shrinking polysiloxanes. A new route to sol-gel type polymers

    SciTech Connect (OSTI)

    Rahimian, K.; Loy, D.A.

    1998-11-01

    Sol-gel chemistry has been the focus of much attention in the design and preparation of highly crosslinked polysiloxane gels. Preparation of sol-gel processed silica or polysilesquioxane gels is carried out by the hydrolysis and condensation of alkoxysilyl monomers, usually in the presence of catalytic acid or base and an excess of water. Removal of the alcohol and water byproducts of the condensation reactions, in addition to the alcohol needed to co-dissolve the hydrophobic monomers with water, leads to substantial shrinkage during drying of the resulting gels. This limits the utility of sol-gel processing for applications requiring net-shape casting of artifacts, crack free coatings, or low vaporous organic contaminants (VOCs). It would be advantageous to have a sol-gel process based on an organosilicon monomer that would not require water as a reactant or produce water and alcohol condensation products and still result in siloxane network polymers capable of forming gels. Here, the authors show the synthesis and preparation of a novel sol-gel monomer which can easily be polymerized by ring opening polymerization to give highly crosslinked polysiloxane gels with no condensation byproducts.

  17. Inves Pozo Sol Sociedad Limitada | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13Renewable PowerMismatch |Inves Pozo Sol Sociedad

  18. Novatec BioSol AG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPI VenturesNewSt. Louis, Minnesota: EnergyOhio: EnergyNottingham,Novatec BioSol

  19. PaSol Italia SpA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPIProtectio Program | OpenWisconsin:NewOverPPS EnviroPowered Inc JumpPVMPaSol

  20. DE-SOL-0000332 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet Hanford Advisory Board6/23/2014 Rev. 20 IdahoDE-SOL-0000332

  1. DE-SOL-0003719 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet Hanford Advisory Board6/23/2014 Rev. 20DE-SOL-0003719 -

  2. DE-SOL-0005395 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet Hanford Advisory Board6/23/2014 Rev. 20DE-SOL-0003719

  3. DE-SOL-0006851 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet Hanford Advisory Board6/23/2014 Rev. 20DE-SOL-0003719Site

  4. Consolidated Edison Sol Inc (New Jersey) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar EnergyLawler,CoalConcordia Electric Coop, IncIllinois)Consolidated Edison Sol

  5. I Sol Ventures GmbH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen RiverScoringUtilities Comm JumpImaging JumpSol Ventures

  6. ConSol (Building Industry Research Alliance) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures JumpCommercial Jump(Thompson, 1985)(Laney, 2005)ComvergeConSol

  7. Stress effects in sol-gel derived ferroelectric thin films L. Lian and N. R. Sottosa)

    E-Print Network [OSTI]

    Sottos, Nancy R.

    Stress effects in sol-gel derived ferroelectric thin films L. Lian and N. R. Sottosa) Department 26 August 2003; accepted 19 October 2003 Residual stress development during processing of sol investigates the effects of stress on field-induced polarization switching in ferroelectric Pb Zr0.52Ti0.48)O3

  8. Toroidicity in the Tokamak SOL: Effects on Poloidal Asymmetries, Radial Current and the L-H Transition

    E-Print Network [OSTI]

    Toroidicity in the Tokamak SOL: Effects on Poloidal Asymmetries, Radial Current and the L-H Transition

  9. Optical fiber sensor having a sol-gel fiber core and a method of making

    DOE Patents [OSTI]

    Tao, Shiquan; Jindal, Rajeev; Winstead, Christopher; Singh, Jagdish P.

    2006-06-06

    A simple, economic wet chemical procedure is described for making sol-gel fibers. The sol-gel fibers made from this process are transparent to ultraviolet, visible and near infrared light. Light can be guided in these fibers by using an organic polymer as a fiber cladding. Alternatively, air can be used as a low refractive index medium. The sol-gel fibers have a micro pore structure which allows molecules to diffuse into the fiber core from the surrounding environment. Chemical and biochemical reagents can be doped into the fiber core. The sol-gel fiber can be used as a transducer for constructing an optical fiber sensor. The optical fiber sensor having an active sol-gel fiber core is more sensitive than conventional evanescent wave absorption based optical fiber sensors.

  10. Aero-Sol-Gel Synthesis of Nanostructured Silica Jingyu Hyeon-Lee, Gregory Beaucage,*, and Sotiris E. Pratsinis

    E-Print Network [OSTI]

    Beaucage, Gregory

    Aero-Sol-Gel Synthesis of Nanostructured Silica Powders Jingyu Hyeon-Lee, Gregory Beaucage-temperature aero- sol-gel process. Hydrolysis and condensation of tetraethoxysilane (TEOS) and tetramethoxy- silane, an aero-sol- gel technique for production of powders with extremely high specific surface areas at room

  11. Substituent effects on the sol-gel chemistry of organotrialkoxysilanes

    SciTech Connect (OSTI)

    LOY, DOUGLAS A.; BAUGHER, BRIGITTA M.; BAUGHER, COLLEEN R.; SCHNEIDER, DUANE A.; RAHIMIAN, KAMYAR

    2000-05-09

    Silsesquioxanes have been the subject of intensive study in the past and are becoming important again as a vehicle for introducing organic functionalities into hybrid organic-inorganic materials through sol-gel processing. Depending on the application, the target hybrid material may be required to be a highly cross-linked, insoluble gel or a soluble polymer that can be cast as a thin film or coating. The former has applications such as catalyst supports and separations media; the latter is an economically important method for surface modification or compatiblization for applying adhesives or introducing fillers. Polysilsesquioxanes are readily prepared through the hydrolysis and condensation of organotrialkoxysilanes, though organotriaminosilane and organotrihalosilane monomers can also be used. This paper explores the kinetics of the preparation route.

  12. Mayenite Synthesized Using the Citrate Sol-Gel Method

    SciTech Connect (OSTI)

    Ude, Sabina N [ORNL] [ORNL; Rawn, Claudia J [ORNL] [ORNL; Meisner, Roberta A [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL)] [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Kirkham, Melanie J [ORNL] [ORNL; Jones, Gregory L. [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Payzant, E Andrew [ORNL] [ORNL

    2014-01-01

    A citrate sol-gel method has been used to synthesize mayenite (Ca12Al14O33). X-ray powder diffraction data show that the samples synthesized using the citrate sol-gel method contained CaAl2O4 and CaCO3 along with mayenite when fired ex-situ in air at 800 C but were single phase when fired at 900 C and above. Using high temperature x-ray diffraction, data collected in-situ in air at temperatures of 600 C and below showed only amorphous content; however, data collected at higher temperatures indicated the first phase to crystallize is CaCO3. High temperature x-ray diffraction data collected in 4% H2/96% N2 does not show the presence of CaCO3, and Ca12Al14O33 starts to form around 850 C. In comparison, x-ray powder diffraction data collected ex-situ on samples synthesized using traditional solid-state synthesis shows that single phase was not reached until samples were fired at 1350 C. DTA/TGA data collected either in a nitrogen environment or air on samples synthesized using the citrate gel method suggest the complete decomposition of metastable phases and the formation of mayenite at 900 C, although the phase evolution is very different depending on the environment. Brunauer-Emmett-Teller (BET) measurements showed a slightly higher surface area of 7.4 0.1 m2/g in the citrate gel synthesized samples compared to solid-state synthesized sample with a surface area of 1.61 0.02 m2/g. SEM images show a larger particle size for samples synthesized using the solid-state method compared to those synthesized using the citrate gel method.

  13. Non-Shrinking Sol-Gel Type Polymers by Ring Opening Polymerizations

    SciTech Connect (OSTI)

    Loy, D.A.; Rahimian, K.

    1999-04-05

    We have designed a new class of cyclic siloxane compounds that behave as sol-gel systems when ring open polymerized using a hydroxide base. These monomers polymerize through chain growth polymerization. unlike conventional alkoxysilane sol-gel precursors, to form sol-gel polymers. They do not require solvent or water for polymerization, show no visible shrinkage or cracking during polymerization and are thermally stable. We have successfully utilized these materials in encapsulation of microelectronics. Current efforts are focused toward expanding this family of ROP monomers and optimization of their mechanical properties.

  14. Solventless sol-gel chemistry through ring-opening polymerization of bridged disilaoxacyclopentanes

    SciTech Connect (OSTI)

    RAHIMIAN,KAMYAR; LOY,DOUGLAS A.

    2000-05-01

    Ring-opening polymerization (ROP) of disilaoxacyclopentanes has proven to be an excellent approach to sol-gel type hybrid organic-inorganic materials. These materials have shown promise as precursors for encapsulation and microelectronics applications. The polymers are highly crosslinked and are structurally similar to traditional sol-gels, but unlike typical sol-gels they are prepared by an organic base or Bronsted acid (formic or triflic acid), without the use of solvents and water, they have low VOC's and show little shrinkage during processing.

  15. Transient stress evolution and crystallization in laser-irradiated amorphous titania sol-gel films

    SciTech Connect (OSTI)

    Exarhos, G.J.; Hess, N.J. (Pacific Northwest Lab., Richland, WA (United States)); Wood, S. (Washington State Univ., Pullman, WA (United States). Dept. of Physics)

    1991-10-01

    Amorphous TiO{sub 2} sol-gel films are irreversibly transformed to a crystalline anatase phase when heated to temperatures in excess of 575 K or subjected to intense pulsed or CW laser irradiation. The laser-induced transformation is initiated as a result of impurity absorption and subsequent heating, and results in densification and relative changes in compressive stress of the film. Isothermally annealed films exhibit a decrease in compressive stress as crystallization proceeds while an increase in compressive stress followed by a decrease in stress is observed when crystallization is laser-induced. Raman spectroscopy has been used to characterize the crystallization ingrowth kinetics and is used in this work as a real time probe of both film temperature and localized stress which can be evaluated from shifts in lattice phonon frequencies measured in real time during laser irradiation. The laser not only induces the phase transformation but excites inelastic Raman scattering from which film stress and temperature can be estimated. A second approach for the determination of these parameters requires incorporation of a thin ruby film between the titania and silica substrate. Here, the wavelength shift of the laser-induced ruby fluorescence can be used to quantify interfacial stress; the fluorescence lifetime measurements are used to determine temperature. The advantages and limitations of these techniques for evaluating transient stress and temperature evolution in thin titania films subjected to CW laser irradiation will be discussed.

  16. Structural Modification of Sol-Gel Materials through Retro Diels-Alder Reaction

    SciTech Connect (OSTI)

    SHALTOUT,RAAFAT M.; LOY,DOUGLAS A.; MCCLAIN,MARK D.; PRABAKAR,SHESHASAYANA; GREAVES,JOHN; SHEA,KENNETH J.

    1999-12-08

    Hydrolysis and condensation of organically bridged bis-triethoxysilanes, (EtO){sub 3}Si-R-Si(OEt){sub 3}, results in the formation of three dimensional organic/inorganic hybrid networks (Equation 1). Properties of these materials, including porosity, are dependent on the nature of the bridging group, R. Flexible groups (akylene-spacers longer than five carbons in length) polymerize under acidic conditions to give non-porous materials. Rigid groups (such as arylene-, alkynylene-, or alkenylene) form non-porous, microporous, and macroporous gels. In many cases the pore size distributions are quite narrow. One of the motivations for preparing hybrid organic-inorganic materials is to extend the range of properties available with sol-gel systems by incorporating organic groups into the inorganic network. For example, organically modified silica gels arc either prepared by co-polymerizing an organoalkoxysilane with a silica precursor or surface silylating the inorganic gel. This can serve to increase hydrophobicity or to introduce some reactive organic functionality. However, the type and orientation of these organic functionalities is difficult to control. Furthermore, many organoalkoxysilanes can act to inhibitor even prevent gelation, limiting the final density of organic functionalities. We have devised a new route for preparing highly functionalized pores in hybrid materials using bridging groups that are thermally converted into the desired functionalities after the gel has been obtained. In this paper, we present the preparation and characterization of bridged polysilsesquioxanes with Diels-Alder adducts as the bridging groups from the sol-gel polymerization of monomers 2 and 4. The bridging groups are constructed such that the retro Diela-Alder reaction releases the dienes and leaves the dienophiles as integral parts of the network polymers. In the rigid architecture of a xerogel, this loss of organic functionality should liberate sufficient space to modify the overall porosity. Furthermore, the new porosity will be functionalized with the dienophilic olefin bridging group. We also demonstrate that by changing the type of Diels-Alder adduct used as the bridging group, we can change the temperature at which the retro-Diels-Alder reaction will occur.

  17. Ammonia Sensors Based on Doped-Sol-Gel-Tipped Optical Fibers for Catalyst System Diagnostics

    Broader source: Energy.gov [DOE]

    This work focuses on the development and application of optical fibers sensors tip-coated with sol gels that sequester a transducing material whose optical response is sensitive to NH3.

  18. Environmental Assessment and Metrics for Solar: Case Study of SolFocus Solar Concentrator Systems

    E-Print Network [OSTI]

    Reich-Weiser, Corinne; Dornfeld, David; Horne, Steve

    2008-01-01

    International Journal of LCA, vol. 10, no. 1, pp. 85–94,Life-cycle assessment (LCA) is utilized to analyze SolFocussolar systems. A hybrid LCA method- ology is explained that

  19. The physics and chemistry of semiconductor nanocrystals in sol-gel derived optical microcavities

    E-Print Network [OSTI]

    Chan, Yinthai

    2006-01-01

    The incorporation of semiconductor nanocrystals (NCs) into sol-gel derived matrices presents both novel applications as well as a robust platform in which to investigate the nonlinear optical properties of NCs. This thesis ...

  20. Molecular receptors in metal oxide sol-gel materials prepared via molecular imprinting

    DOE Patents [OSTI]

    Sasaki, Darryl Y. (Albuquerque, NM); Brinker, C. Jeffrey (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Daitch, Charles E. (Charlottesville, VA); Shea, Kenneth J. (Irvine, CA); Rush, Daniel J. (Philadelphia, PA)

    2000-01-01

    A method is provided for molecularly imprinting the surface of a sol-gel material, by forming a solution comprised of a sol-gel material, a solvent, an imprinting molecule, and a functionalizing siloxane monomer of the form Si(OR).sub.3-n X.sub.n, wherein n is an integer between zero and three and X is a functional group capable of reacting with the imprinting molecule, evaporating the solvent, and removing the imprinting molecule to form the molecularly imprinted metal oxide sol-gel material. The use of metal oxide sol-gels allows the material porosity, pore size, density, surface area, hardness, electrostatic charge, polarity, optical density, and surface hydrophobicity to be tailored and be employed as sensors and in catalytic and separations operations.

  1. Fast-wave Power Flow Along SOL Field Lines In NSTX nd The Associated Power Deposition Profile Across The SOL In Front Of The Antenna

    SciTech Connect (OSTI)

    Perkins, Roy

    2013-06-21

    Fast-wave heating and current drive efficiencies can be reduced by a number of processes in the vicinity of the antenna and in the scrape off layer (SOL). On NSTX from around 25% to more than 60% of the high-harmonic fast-wave power can be lost to the SOL regions, and a large part of this lost power flows along SOL magnetic field lines and is deposited in bright spirals on the divertor floor and ceiling. We show that field-line mapping matches the location of heat deposition on the lower divertor, albeit with a portion of the heat outside of the predictions. The field-line mapping can then be used to partially reconstruct the profile of lost fast-wave power at the midplane in front of the antenna, and the losses peak close to the last closed flux surface (LCFS) as well as the antenna. This profile suggests a radial standing-wave pattern formed by fast-wave propagation in the SOL, and this hypothesis will be tested on NSTX-U. Advanced RF codes must reproduce these results so that such codes can be used to understand this edge loss and to minimize RF heat deposition and erosion in the divertor region on ITER.

  2. Characterization of Hafnia Powder Prepared from an Oxychloride Sol Gel

    SciTech Connect (OSTI)

    McGilvery, Catriona M. [Imperial College, London; De Gendt, S [Imperial College, London; Payzant, E Andrew [ORNL; MacKenzie, M [Imperial College, London; Craven, A J [Imperial College, London; McComb, D W [Imperial College, London

    2011-01-01

    Hafnium containing compounds are of great importance to the semiconductor industry as a replacement for Si(O,N) with a high- gate dielectric. Whilst Hf is already being incorporated into working devices1, much is still to be understood about it. Here we investigate the crystallisation processes and chemistry of bulk HfO2 powders which will aid in interpretation of reactions and crystallisation events occurring in thin films used as gate dielectrics. Amorphous HfO2 powder was prepared via a sol-gel route using hafnium oxychloride (HfOCl2 xH2O) as a precursor. The powders were subjected to various heat treatments and analysed using x-ray diffraction (XRD) and thermal analysis techniques. It was found that a large change in the crystallisation pathway occurred when the sample was heated in an inert environment compared with in air. Instead of the expected monoclinic phase (m-HfO2), tetragonal HfO2 (t-HfO2) also formed under these conditions and was observed up to temperatures of ~760 C. The t-HfO2 particles, which are less than 30nm in size, eventually transform into m-HfO2 on further heating. Possible mechanisms for the crystallisation of t-HfO2 are discussed. It is proposed that within this temperature range t-HfO2 is stabilised due to the presence of oxygen vacancies in the inert environment, forming by the reduction of HfIV to HfIII. As the crystal grows in size as the temperature increases there are too few oxygen vacancies left in the structure to continue stabilising the t-HfO2 phase and so transformation to m-HfO2 occurs.

  3. Tantalum-Tungsten Oxide Thermite Composite Prepared by Sol-Gel Synthesis and Spark Plasma Sintering

    SciTech Connect (OSTI)

    Cervantes, O; Kuntz, J; Gash, A; Munir, Z

    2009-02-13

    Energetic composite powders consisting of sol-gel derived nanostructured tungsten oxide were produced with various amounts of micrometer-scale tantalum fuel metal. Such energetic composite powders were ignition tested and results show that the powders are not sensitive to friction, spark and/or impact ignition. Initial consolidation experiments, using the High Pressure Spark Plasma Sintering (HPSPS) technique, on the sol-gel derived nanostructured tungsten oxide produced samples with higher relative density than can be achieved with commercially available tungsten oxide. The sol-gel derived nanostructured tungsten oxide with immobilized tantalum fuel metal (Ta - WO{sub 3}) energetic composite was consolidated to a density of 9.17 g.cm{sup -3} or 93% relative density. In addition those parts were consolidated without significant pre-reaction of the constituents, thus the sample retained its stored chemical energy.

  4. A sol-powder coating technique for fabrication of yttria stabilised zirconia

    SciTech Connect (OSTI)

    Wattanasiriwech, Darunee . E-mail: darunee@mfu.ac.th; Wattanasiriwech, Suthee; Stevens, Ron

    2006-08-10

    Yttria stabilised zirconia has been prepared using a simple sol-powder coating technique. The polymeric yttria sol, which was prepared using 1,3 propanediol as a network modifier, was homogeneously mixed with nanocrystalline zirconia powder and it showed a dual function: as a binder which promoted densification and a phase modifier which stabilised zirconia in the tetragonal and cubic phases. Thermal analysis and X-ray diffraction revealed that the polymeric yttria sol which decomposed at low temperature into yttrium oxide could change the m {sup {yields}} t phase transformation behaviour of the zirconia, possibly due to the small particle size and very high surface area of both yttria and zirconia particles allowing rapid alloying. The sintered samples exhibited three crystalline phases: monoclinic, tetragonal and cubic, in which cubic and tetragonal are the major phases. The weight fractions of the individual phases present in the selected specimens were determined using quantitative Rietveld analysis.

  5. Catalytic Porous Ceramic Prepared In-Situ by Sol-Gelation for Butane-to-Syngas Processing

    E-Print Network [OSTI]

    Daraio, Chiara

    Catalytic Porous Ceramic Prepared In-Situ by Sol-Gelation for Butane-to-Syngas Processing­1859, 2009 Keywords: catalytic porous ceramic, butane-to-syngas processing, catalytic foam, sol-gelation, Rh containing cat- alytic Rh/ceria/zirconia nanoparticles is tested by its catalytic performance for butane

  6. Magnetic resonance as a structural probe of a uranium (VI) sol-gel process

    SciTech Connect (OSTI)

    King, C.M.; Thompson, M.C.; Buchanan, B.R. [Westinghouse Savannah River Co., Aiken, SC (United States); King, R.B. [Georgia Univ., Athens, GA (United States). Dept. of Chemistry; Garber, A.R. [South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry

    1989-12-31

    NMR investigations on the ORNL process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub l2}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-Gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sub 17}0 NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, [(UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}]{sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results show that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an ``intercalation`` cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ ion exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2}[(UO{sub 2}){sub 8}O{sub 4}(OH){sub 10}] {center_dot} 8H{sub 2}0. This compound is the precursor to sintered U0{sub 2} ceramic fuel.

  7. Magnetic resonance as a structural probe of a uranium (VI) sol-gel process

    SciTech Connect (OSTI)

    King, C.M.; Thompson, M.C.; Buchanan, B.R. (Westinghouse Savannah River Co., Aiken, SC (United States)); King, R.B. (Georgia Univ., Athens, GA (United States). Dept. of Chemistry); Garber, A.R. (South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry)

    1989-01-01

    NMR investigations on the ORNL process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub l2}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-Gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sub 17}0 NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, ((UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}){sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results show that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an intercalation'' cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ ion exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2}((UO{sub 2}){sub 8}O{sub 4}(OH){sub 10}) {center dot} 8H{sub 2}0. This compound is the precursor to sintered U0{sub 2} ceramic fuel.

  8. ELM PARTICLE AND ENERGY TRANSPORT IN THE SOL AND DIVERTOR OF DIII-D

    SciTech Connect (OSTI)

    FENSTERMACHER,ME; LEONARD,AW; SNYDER,PB; BOEDO,JA; COLCHIN,RJ; GROEBNER,RJ; GRAY,DS; GROTH,M; HOLLMANN,E; LASNIER,CJ; OSBORNE,TH; PETRIE,TW; RUDAKOV,DL; TAKAHASHI,H; WATKINS,JG; ZENG,L

    2003-04-01

    A271 ELM PARTICLE AND ENERGY TRANSPORT IN THE SOL AND DIVERTOR OF DIII-D. Results from a series of dedicated experiments measuring the effect of particle and energy pulses from Type-I Edge Localized Modes (ELMs) in the DIII-D scrape-off layer (SOL) and divertor are compared with a simple model of ELM propagation in the boundary plasma. The simple model asserts that the propagation of ELM particle and energy perturbations is dominated by ion parallel convection along SOL fields lines and the recovery from the ELM perturbation is determined by recycling physics. Time scales associated with the initial changes of boundary plasma parameters are expected to be on the order of the ion transit time from the outer midplane, where the ELM instability is initiated, to the divertor targets. To test the model, the ion convection velocity is changed in the experiment by varying the plasma density. At moderate to high density, n{sub e}/n{sub Gr} = 0.5-0.8, the delays in the response of the boundary plasma to the midplane ELM pulses, the density dependence of those delays and other observations are consistent with the model. However, at the lowest densities, n{sub e}/n{sub Gr} {approx} 0.35, small delays between the response sin the two divertors, and changes in the response of the pedestal thermal energy to ELM events, indicate that additional factors including electron conduction in the SOL, the pre-ELM condition of the divertor plasma, and the ratio of ELM instability duration to SOL transit time, may be playing a role. The results show that understanding the response of the SOL and divertor plasmas to ELMs, for various pre-ELM conditions, is just as important to predicting the effect of ELM pulses on the target surfaces of future devices as is predicting the characteristics of the ELM perturbation of the core plasma.

  9. Environmental Protection Agency any waste load associated with sol

    E-Print Network [OSTI]

    440--ORE MINING AND DRESSING POINT SOURCE CAT EGORY Subpart A--Iron Ore Subcategory Sec. 440 average mass of TSS in any calendar month shall be 1.7 times the BOD5 limitation deter mined in paragraph.10 Applicability; description of the iron ore subcategory. Pt. 440 440.11 [Reserved] 440.12 Effluent limitations

  10. Sol-gel silica films embedding NIR- emitting Yb-quinolinolate complexes

    SciTech Connect (OSTI)

    Figus, Cristiana, E-mail: cristiana.figus@dsf.unica.it; Quochi, Francesco, E-mail: cristiana.figus@dsf.unica.it; Piana, Giacomo; Saba, Michele; Mura, Andrea; Bongiovanni, Giovanni [Dipartimento di Fisica, University of Cagliari, SS 554 Bivio per Sestu, I-09042, Monserrato-Cagliari (Italy); Artizzu, Flavia [Dipartimento di Fisica, University of Cagliari and Dipartimento di Scienze Chimiche e Geologiche, University of Cagliari, SS 554 Bivio per Sestu, I-09042, Monserrato-Cagliari (Italy); Mercuri, Maria Laura; Serpe, Angela; Deplano, Paola [Dipartimento di Scienze Chimiche e Geologiche, University of Cagliari, SS 554 Bivio per Sestu, I-09042, Monserrato-Cagliari (Italy)

    2014-10-21

    Sol-gel silica thin films embedding an ytterbium quinolinolato complex (YbClQ{sub 4}) have been obtained using different alkoxides. Homogeneous, crack- and defect-free thin films of optical quality have been successfully deposited on glass substrate by dip-coating. The silica thin films have been characterized by time-resolved photoluminescence. The luminescence properties of the YbClQ{sub 4} are preserved in silica films prepared through an optimized sol-gel approach. The excited state lifetime of the lanthanide is comparable to those observed in bulk and longer than the corresponding ones in solution.

  11. Sol immobilization technique: a delicate balance between activity, selectivity and stability for gold catalyst

    SciTech Connect (OSTI)

    Villa, Alberto [Universita di Milano, Italy] [Universita di Milano, Italy; Wang, Di [Fritz Haber Institute of the Max Planck Society, Berlin, Germany] [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Veith, Gabriel M [ORNL] [ORNL; Prati, Laura [Universita di Milano, Italy] [Universita di Milano, Italy

    2013-01-01

    Sol immobilization is a widely used method to prepare gold catalysts. The presence of the protective layer can have a significant influence on catalyst properties by mediating metal-support and reactantmetal interactions. This paper details the effect of a polyvinyl alcohol (PVA) protecting groups on the activity of a supported gold catalysts as well as its selectivity towards glycerol oxidation.

  12. Nanoindentation and adhesion of sol-gel-derived hard coatings on polyester

    E-Print Network [OSTI]

    Cao, Guozhong

    Nanoindentation and adhesion of sol-gel-derived hard coatings on polyester C.M. Chan, G.Z. Cao,a) H coatings on modified polyester substrates. The silica network was modified by incorporating an organic, and mechanical properties of the coatings. Various low-temperature densification techniques were studied

  13. FEATURE ARTICLE Growth of Oxide Nanorod Arrays through Sol Electrophoretic Deposition

    E-Print Network [OSTI]

    Cao, Guozhong

    approaches in sol-gel processing for synthesis of inorganic or inorganic/organic hybrid materials are briefly* Department of Materials Science and Engineering, UniVersity of Washington, Seattle, Washington 98195 Recei, are impor- tant materials for various applications in industry and technol- ogy. This is due to their multi

  14. Multivariate Population Balances via Moment and Monte Carlo Simulation Methods: An Important Sol Reaction Engineering

    E-Print Network [OSTI]

    Multivariate Population Balances via Moment and Monte Carlo Simulation Methods: An Important Sol application of current/future importance, a multivariate description is required, for which the existing, hopefully, motivate a broader attack on important multivariate population balance problems, including those

  15. Europhysics Letters PREPRINT Layering transitions for adsorbing polymers in poor sol-

    E-Print Network [OSTI]

    Rechnitzer, Andrew

    Europhysics Letters PREPRINT Layering transitions for adsorbing polymers in poor sol- vents J, Potts, etc.). PACS. 05.70.fh ­ Thermodynamics. PACS. 61.41.+e ­ Polymers, elastomers, and plastics. Abstract. ­ An infinite hierarchy of layering transitions exists for model polymers in solu- tion under

  16. Investigations of the small-scale thermal behavior of sol-gel thermites.

    SciTech Connect (OSTI)

    Warren, Mial E.; Farrow, Matthew; Tappan, Alexander Smith

    2009-02-01

    Sol-gel thermites, formulated from nanoporous oxides and dispersed fuel particles, may provide materials useful for small-scale, intense thermal sources, but understanding the factors affecting performance is critical prior to use. Work was conducted on understanding the synthesis conditions, thermal treatments, and additives that lead to different performance characteristics in iron oxide sol-gel thermites. Additionally, the safety properties of sol-gel thermites were investigated, especially those related to air sensitivity. Sol-gel thermites were synthesized using a variety of different techniques and there appear to be many viable routes to relatively equivalent thermites. These thermites were subjected to several different thermal treatments under argon in a differential scanning calorimeter, and it was shown that a 65 C hold for up to 200 minutes was effective for the removal of residual solvent, thus preventing boiling during the final thermal activation step. Vacuum-drying prior to this heating was shown to be even more effective at removing residual solvent. The addition of aluminum and molybdenum trioxide (MoO{sub 3}) reduced the total heat release per unit mass upon exposure to air, probably due to a decrease in the amount of reduced iron oxide species in the thermite. For the thermal activation step of heat treatment, three different temperatures were investigated. Thermal activation at 200 C resulted in increased ignition sensitivity over thermal activation at 232 C, and thermal activation at 300 C resulted in non-ignitable material. Non-sol-gel iron oxide did not exhibit any of the air-sensitivity observed in sol-gel iron oxide. In the DSC experiments, no bulk ignition of sol-gel thermites was observed upon exposure to air after thermal activation in argon; however ignition did occur when the material was heated in air after thermal treatment. In larger-scale experiments, up to a few hundred milligrams, no ignition was observed upon exposure to air after thermal activation in vacuum; however ignition by resistively-heated tungsten wire was possible. Thin films of thermite were fabricated using a dispersed mixture of aluminum and iron oxide particles, but ignition and propagation of these films was difficult. The only ignition and propagation observed was in a preheated sample.

  17. Moisture sensor based on evanescent wave light scattering by porous sol-gel silica coating

    DOE Patents [OSTI]

    Tao, Shiquan; Singh, Jagdish P.; Winstead, Christopher B.

    2006-05-02

    An optical fiber moisture sensor that can be used to sense moisture present in gas phase in a wide range of concentrations is provided, as well techniques for making the same. The present invention includes a method that utilizes the light scattering phenomenon which occurs in a porous sol-gel silica by coating an optical fiber core with such silica. Thus, a porous sol-gel silica polymer coated on an optical fiber core forms the transducer of an optical fiber moisture sensor according to an embodiment. The resulting optical fiber sensor of the present invention can be used in various applications, including to sense moisture content in indoor/outdoor air, soil, concrete, and low/high temperature gas streams.

  18. Energy efficiency dynamometer testing at the 1996 American Tour de Sol

    SciTech Connect (OSTI)

    Sluder, S.; Duoba, M.; Buitrago, C.; Leblanc, N.; Larsen, R.

    1996-08-01

    In 1995, the U.S. Department of Energy through Argonne National Laboratory`s Center for Transportation Research sponsored energy efficiency data collection from the student, private, and professional vehicles during the American Tour de Sol. The American Tour de Sol is a multiple-day road rally event run from New York City to Washington, D.C. As part of this efficiency testing, a number of vehicles were tested on a chassis dynamometer utilizing three common drive cycles: the LA-4, the New York City Cycle, and the Highway Fuel Economy Test. The results demonstrate remarkable efficiency increases over a gasoline control vehicle and significant cycle-sensitivity information. Two series hybrid electric vehicles (HEVs) were shown to have fuel efficiencies which were less sensitive to drive cycle than either a gasoline or an electric vehicle.

  19. Characterization of Sol-gel Encapsulated Proteins using Small-angle Neutron Scattering

    SciTech Connect (OSTI)

    Luo, Guangming [ORNL; Zhang, Qiu [ORNL; Del Castillo, Alexis Rae [ORNL; Urban, Volker S [ORNL; O'Neill, Hugh Michael [ORNL

    2009-01-01

    Entrapment of biomolecules in silica-derived sol-gels has grown into a vibrant area of research since it was originally demonstrated. However, accessing the consequences of entrapment on biomolecules and the gel structure remains a major challenge in characterizing these biohybrid materials. We present the first demonstration that it is possible with small-angle neutron scattering (SANS) to study the conformation of dilute proteins that are entrapped in transparent and dense sol-gels. Using deuterium-labeled green fluorescent protein (GFP) and SANS with contrast variation, we demonstrate that the scattering signatures of the sol-gel and the protein can be separated. Analysis of the scattering curves of the sol-gels using a mass-fractal model shows that the size of the colloidal silica particles and the fractal dimensions of the gels were similar in the absence and presence of protein, demonstrating that GFP did not influence the reaction pathway for the formation of the gel. The major structural difference in the gels was that the pore size was increased 2-fold in the presence of the protein. At the contrast match point for silica, the scattering signal from GFP inside the gel became distinguishable over a wide q range. Simulated scattering curves representing a monomer, end-to-end dimer, and parallel dimer of the protein were calculated and compared to the experimental data. Our results show that the most likely structure of GFP is that of an end-to-end dimer. This approach can be readily applied and holds great potential for the structural characterization of complex biohybrid and other materials.

  20. 2005 Tour de Sol: The Sustainable Energy and Transportation Festival and Competition

    SciTech Connect (OSTI)

    Nancy Hazard

    2005-05-07

    This report gives a summary of the 2005Tour de Sol: The Sustainable Energy and Transportation Festival and Competition. It lists our objectives, what we did, and an analysis of how we met our objectives. An 80-page report with a list of verified print, radio and TV media coverage, and copies of selected news clips and web media coverage is available at the NESEA office for review.

  1. Electrophoretically active sol-gel processes to backfill, seal, and/or densify porous, flawed, and/or cracked coatings on electrically conductive material

    DOE Patents [OSTI]

    Panitz, Janda K. (Sandia Park, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Neiser, Richard A. (Albuquerque, NM); Moffatt, William C. (Albuquerque, NM)

    1999-01-01

    Electrophoretically active sol-gel processes to fill, seal, and/or density porous, flawed, and/or cracked coatings on electrically conductive substrates. Such coatings may be dielectrics, ceramics, or semiconductors and, by the present invention, may have deposited onto and into them sol-gel ceramic precursor compounds which are subsequently converted to sol-gel ceramics to yield composite materials with various tailored properties.

  2. Electrophoretically active sol-gel processes to backfill, seal, and/or densify porous, flawed, and/or cracked coatings on electrically conductive material

    DOE Patents [OSTI]

    Panitz, J.K.; Reed, S.T.; Ashley, C.S.; Neiser, R.A.; Moffatt, W.C.

    1999-07-20

    Electrophoretically active sol-gel processes to fill, seal, and/or density porous, flawed, and/or cracked coatings on electrically conductive substrates. Such coatings may be dielectrics, ceramics, or semiconductors and, by the present invention, may have deposited onto and into them sol-gel ceramic precursor compounds which are subsequently converted to sol-gel ceramics to yield composite materials with various tailored properties. 6 figs.

  3. Multi-machine Comparisons of H-mode Separatrix Densities and Edge Profile Behaviour in the ITPA SOL and Divertor Physics Topical Group

    E-Print Network [OSTI]

    Multi-machine Comparisons of H-mode Separatrix Densities and Edge Profile Behaviour in the ITPA SOL and Divertor Physics Topical Group

  4. Integrated Core-SOL-Divertor Modelling for ITER Including Impurity: Effect of Tungsten on Fusion Performance in H-mode and Hybrid Scenario

    E-Print Network [OSTI]

    Integrated Core-SOL-Divertor Modelling for ITER Including Impurity: Effect of Tungsten on Fusion Performance in H-mode and Hybrid Scenario

  5. Role of uranium(VI) in the ThO/sub 2/-UO/sub 3/ sol-gel process

    SciTech Connect (OSTI)

    Tewari, P.H.; Campbell, A.B.

    1980-11-01

    Increases in pH and temperature of U(VI) solutions enhance adsorption of uranium on ThO/sub 2/ through hydrolysis of U(VI) as evidenced by absorption spectra changes of the solution. Sols of ThO/sub 2/-UO/sub 3/ are formed by adsorption of uranium on ThO/sub 2/. At low pH's (approx. pH 3.0), the sols behave as Newtonian fluids but at higher pH's the sols (especially the concentrated ones) transform into thixotropic gels. The increased adsorption of uranium by ThO/sub 2/ and the increased viscosity of the ThO/sub 2/-UO/sub 3/ sols with pH are related. Increased adsorption of uranium produces rod-shaped UO/sub 3/.2H/sub 2/O on the ThO/sub 2/ surface. These UO/sub 3/ nuclei link ThO/sub 2/ particles to form long rodlike particles. With further increased adsorption of uranium at higher pH's (less than or equal to 3.7), the particles crosslink to produce a structured network giving a thixotropic gel. Adsorption, electron microscopic, electrophoetic mobility, X-ray diffraction, and X-ray photoelectron spectroscopic data are presented to explain the role of U(VI) in the sol-gel process. 6 figures, 1 table.

  6. Dielectric function of sol-gel prepared nano-granular zinc oxide by spectroscopic ellipsometry

    SciTech Connect (OSTI)

    Gilliot, Mickaël, E-mail: mickael.gilliot@univ-reims.fr; Hadjadj, Aomar [LISM, Université de Reims Champagne-Ardenne, Reims (France); Eypert, Céline [HORIBA Jobin Yvon S.A.S., Palaiseau (France)

    2013-11-14

    ZnO thin films have been prepared by sol gel and deposited by spin coating. The dielectric function has been determined by spectroscopic ellipsometry. Ellipsometric spectra are inverted by a direct numerical method without using the standard fitting procedures. The obtained dielectric function presents a broad excitonic effect. The dielectric function is studied using Elliot excitonic theory including exciton plus band-to-band Coulomb interactions with standard Lorentzian broadening. A modification of this model dielectric function with independent bound and unbound exciton contributions is empirically proposed to improve modelling of the band gap excitonic peak.

  7. Electroanalytical applications of screen-printable surfactant-induced sol-gel graphite composites

    DOE Patents [OSTI]

    Guadalupe, Ana R. (San Juan, PR); Guo, Yizhu (San Juan, PR)

    2001-05-15

    A process for preparing sol-gel graphite composite electrodes is presented. This process preferably uses the surfactant bis(2-ethylhexyl) sulfosuccinate (AOT) and eliminates the need for a cosolvent, an acidic catalyst, a cellulose binder and a thermal curing step from prior art processes. Fabrication of screen-printed electrodes by this process provides a simple approach for electroanalytical applications in aqueous and nonaqueous solvents. Examples of applications for such composite electrodes produced from this process include biochemical sensors such as disposable, single-use glucose sensors and ligand modified composite sensors for metal ion sensitive sensors.

  8. Performance of electric and hybrid vehicles at the 1995 American Tour de Sol

    SciTech Connect (OSTI)

    Quong, S.; LeBlanc, N.; Buitrago, C.; Duoba, M.; Larsen, R.

    1995-12-31

    Energy consumption and performance data were collected on more than 40 electric and hybrid vehicles during the 1995 American Tour de Sol. At this competition, one electric vehicle drove 229 miles on one charge using nickel metalhydride batteries. The results obtained from the data show that electric vehicle efficiencies reached 9.07 mi./kWh or 70 equivalent mpg of gasoline when compared to the total energy cycle efficiency of electricity and gasoline. A gasoline-fueled 1995 Geo Metro that drove the same route attained 36.4 mpg.

  9. Direct formation of aerogels by sol-gel polymerizations of alkoxysilanes in supercritical carbon dioxide

    SciTech Connect (OSTI)

    Loy, D.A.; Yamanaka, A.; Carpenter, J.P. [Sandia National Labs., Albuquerque, NM (United States); [Univ. of California, Irvine, CA (United States)] [and others

    1997-12-31

    Sol-gel polymerization of alkoxysilanes in supercritical carbon dioxide (SCCD) was used to directly prepare aerogels. Polymerizations of tetramethoxysilane (TMOS) and 1,4-bis(triethoxysilyl)benzene (BESP) were performed by dissolving the monomers and formic acid in supercritical carbon dioxide (SCCD). Monolithic gels were obtained in under 12 hours. The silica and polysilsesquioxane gels were readily dried to afford aerogels by slowly venting the SCCD. The aerogels were high surface area mesoporous materials that were characterized by solid state NMR, SEM, TEM, and gas sorption porosimetry.

  10. Sandia Energy - Mesa del Sol Unveils First Smart Grid in the Nation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis ofSampleLignin-Feasting MicrobeMesa del Sol Unveils First Smart

  11. Journal of Sol-Gel Science and Technology 36, 183195, 2005 c 2005 Springer Science + Business Media, Inc. Manufactured in the United States.

    E-Print Network [OSTI]

    Cao, Guozhong

    of the electrical double-layer surrounding a particle in a colloidal suspension that is responsible for the electrostatic stabilization of a colloid (left), and the electrophoretic motion and process involved in template an electric field to an electrostatically stabilized sol. Nanoclus- ters dispersed in such a sol would develop

  12. Synthesis of palladium-doped silica nanofibers by sol-gel reaction and electrospinning process

    SciTech Connect (OSTI)

    San, Thiam Hui; Daud, Wan Ramli Wan; Kadhum, Abdul Amir Hassan; Mohamad, Abu Bakar; Kamarudin, Siti Kartom; Shyuan, Loh Kee; Majlan, Edy Herianto [Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia and Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

    2012-06-29

    Nanofiber is drawing great attention nowadays with their high surface area per volume and flexibility in surface functionalities that make them favorable as a proton exchange membrane in fuel cell application. In this study, incorporation of palladium nanoparticles in silica nanofibers was prepared by combination of a tetraorthosilane (TEOS) sol-gel reaction with electrospinning process. This method can prevent the nanoparticles from aggregation by direct mixing of palladium nanoparticles in silica sol. The as-produced electrospun fibers were thermally treated to remove poly(vinyl pyrrolidone) (PVP) and condensation of silanol in silica framework. PVP is chosen as fiber shaping agent because of its insulting and capping properties for various metal nanoparticles. Scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and Fourier transform infrared spectroscopy (FTIR) were used to characterize the silica fibers and Pd nanoparticles on the fibers. Spun fibers with average diameter ranged from 100nm to 400nm were obtained at optimum operating condition and distribution of Pd nanoparticles on silica fibers was investigated.

  13. Simulation of tokamak SOL and divertor region including heat flux mitigation by gas puffing

    SciTech Connect (OSTI)

    Park, Jin Woo [Seoul National University, Seoul, S. Korea; Na, Y. S. [Seoul National University, Seoul, S. Korea; Hong, S. H. [National Fusion Research Institute, Daejon, South Korea; Ahn, J.W. [Oak Ridge National Laboratory (ORNL); Kim, D. K. [Agency Def Dev, Taejon, South Korea; Han, Hyunsun [National Fusion Research Institute, Taejon, South Korea; Shim, Seong Bo [Pusan National University, Busan, Korea; Lee, Hae June [Pusan National University, Busan, Korea

    2012-01-01

    Two-dimensional (2D), scrape-off layer (SOL)-divertor transport simulations are performed using the integrated plasma-neutral-impurity code KTRAN developed at Seoul National University. Firstly, the code is applied to reproduce a National Spherical Torus eXperiment (NSTX) discharge by using the prescribed transport coefficients and the boundary conditions obtained from the experiment. The plasma density, the heat flux on the divertor plate, and the D (alpha) emission rate profiles from the numerical simulation are found to follow experimental trends qualitatively. Secondly, predictive simulations are carried out for the baseline operation mode in Korea Superconducting Tokamak Advanced Research (KSTAR) to predict the heat flux on the divertor target plates. The stationary peak heat flux in the KSTAR baseline operation mode is expected to be 6.5 MW/m(2) in the case of an orthogonal divertor. To study the mitigation of the heat flux, we investigated the puffing effects of deuterium and argon gases. The puffing position is assumed to be in front of the strike point at the outer lower divertor plate. In the simulations, mitigation of the peak heat flux at the divertor target plates is found to occur when the gas puffing rate exceeds certain values, similar to 1.0 x 10(20) /s and similar to 5.0 x 10(18) /s for deuterium and argon, respectively. Multi-charged impurity transport is also investigated for both NSTX and KSTAR SOL and divertor regions.

  14. Thio sol-gel process for the synthesis of titanium disulfide

    SciTech Connect (OSTI)

    Sriram, M.A.; Kumta, P.N. (Carnegie Mellon Univ., Pittsburgh, PA (United States). Dept. of Materials Science and Engineering)

    1994-05-01

    Sulfides of transition metals (titanium, molybdenum, vanadium, tungsten, etc.) represent an important class of materials well-known for their catalytic and electrochemical properties. The catalytic properties make them potentially useful in hydrodesulfurization reactions, and their electrochemical response makes them suitable as active cathodes in rechargeable batteries. A thio sol-gel process for the synthesis of titanium disulfide using titanium alkoxide as the metal source is demonstrated. The alkoxide reacts at room temperature with H[sub 2]S to form a precipitate which is a precursor to the sulfide. Through infrared spectroscopy and chemical analysis of the powder and gas chromatographic analysis of the liquid byproducts of the reaction, it is shown that a partially sulfidized alkoxide precursor forms through the displacement of alkoxy groups from the alkoxide by sulfur-bearing thiol groups. This thiolysis reaction is very similar to that which occurs in the case of sol-gel reactions to form oxides. The alkoxy-thiol species then undergo condensation-polymerization by the liberation of H[sub 2]S. When it is heat-treated in H[sub 2]S, this precursor transforms to TiS[sub 2] at [approximately]700 C. Systematic heat treatments have been performed and the formation of TiS[sub 2] has been observed using X-ray diffractometry. The change in the morphology has also been studied using scanning electron microscopy.

  15. Dialkylenecarbonate-Bridged Polysilsesquioxanes. Hybrid Organic Sol-Gels with a Thermally Labile Bridging Group

    SciTech Connect (OSTI)

    Loy, D.A.; Beach, J.V.; Baugher, B.M.; Assink, R.A.; Shea, K.J.; Tran, J.; Small, J.H.

    1999-04-21

    In this paper, we introduce a new approach for altering the properties of bridged polysilsesquioxane xerogels using post-processing modification of the polymeric network. The bridging organic group contains latent functionalities that can be liberated thermally, photochemically, or by chemical means after the gel has been processed to a xerogel. These modifications can produce changes in density, volubility, porosity, and or chemical properties of the material. Since every monomer possesses two latent functional groups, the technique allows for the introduction of high levels of functionality in hybrid organic-inorganic materials. Dialkylenecarbonate-bridged polysilsesquioxane gels were prepared by the sol-gel polymerization of bis(triethoxysilylpropyl)carbonate (1) and bis(triethoxysilylisobutyl)-carbonate (2). Thermal treatment of the resulting non-porous xerogels and aerogels at 300-350 C resulted in quantitative decarboxylation of the dialkylenecarbonate bridging groups to give new hydroxyalkyl and olefinic substituted polysilsesquioxane monolithic xerogels and aerogels that can not be directly prepared through direct sol-gel polymerization of organotrialkoxysilanes.

  16. Communications mensuelles de l'lnstitut International dela Potasse, Berne (Suisse) Science du sol N 5/1981

    E-Print Network [OSTI]

    Sparks, Donald L.

    Communications mensuelles de l'lnstitut International dela Potasse, Berne (Suisse) Section 4 of potassium in sandy soils) D.l.Sparks Professeur-adjoint de chimie-physique du sol, dc!ipartement des publications suivantes: Sparks D.L., Martens D.C., Zelazny L. W.: Plant Uptake and Leaching of applied

  17. PICARD SOL, a new ground-based facility for long-term solar radius measurements: first results

    E-Print Network [OSTI]

    Boyer, Edmond

    PICARD SOL, a new ground-based facility for long-term solar radius measurements: first results M solar radius measured in space and on ground and to better understand and calibrate atmospheric effects observations and corrections for atmospheric refraction, first estimates of the mean solar radius at the five

  18. Dense and optical transparent CdWO4 films by sol-gel processing for scintillation applications

    E-Print Network [OSTI]

    Cao, Guozhong

    using tungstic acid and cadmium nitrate as precursors and hydrogen peroxide as solvent; homogeneous fabrication of dense and optically transparent cadmium tungstate (CWO) films by sol-gel processing, nanostructures, and optical and x-ray scintillation properties are discussed in detail. I. INTRODUCTION Cadmium

  19. Synthesis of Mixed Ceramic MgxZn1-xO Nanofibers via Mg2+ Using Sol-Gel Electrospinning

    E-Print Network [OSTI]

    Khan, Saad A.

    Synthesis of Mixed Ceramic MgxZn1-xO Nanofibers via Mg2+ Doping Using Sol-Gel Electrospinning Yakup the fibers and conversion of ceramic precursors into ceramic nanofibers, and the appearance of a range property, morphology, and porosity of the resulting nonwoven mat. Ceramic electrospun nanofibers

  20. JOURNAL OF MATERIALS SCIENCE LETTERS 21, 2002, 251 255 Organic-inorganic sol-gel coating for corrosion protection

    E-Print Network [OSTI]

    Cao, Guozhong

    JOURNAL OF MATERIALS SCIENCE LETTERS 21, 2002, 251­ 255 Organic-inorganic sol-gel coating or coatings. Through the modification of chemical composition of the coatings, such protec- tive coatings can strength and hydrophobicity. Various organic coatings have been studied for corrosion protection [4

  1. High surface area neodymium phosphate nano particles by modified aqueous sol-gel method

    SciTech Connect (OSTI)

    Sankar, Sasidharan [Materials Division, National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Thiruvananthapuram 695 019, Kerala (India)] [Materials Division, National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Thiruvananthapuram 695 019, Kerala (India); Warrier, Krishna Gopakumar, E-mail: wwarrierkgk@yahoo.co.in [Materials Division, National Institute for Interdisciplinary Science and Technology, Council of Scientific and Industrial Research, Thiruvananthapuram 695 019, Kerala (India); Komban, Rajesh [Institut fuer Chemie, Anorganische Chemie 1, Universitaet Osnabrueck, Barbarastrasse 7, 49069 Osnabrueck (Germany)] [Institut fuer Chemie, Anorganische Chemie 1, Universitaet Osnabrueck, Barbarastrasse 7, 49069 Osnabrueck (Germany)

    2011-12-15

    Graphical abstract: Synthesis of nano rod shaped neodymium phosphate particles with specific surface area as high as 107 m{sup 2} g{sup -1} and particles could be compacted and sintered at as low as 1300 Degree-Sign C to a density of 98.5% (theoretical) with an average grain size of {approx}1 {mu}m. Highlights: Black-Right-Pointing-Pointer Nano size neodymium phosphate is synthesized and characterized using a novel modified aqueous sol gel process. Black-Right-Pointing-Pointer Specific surface area above 100 m{sup 2} g{sup -1} achieved without the addition of any complexing agents. Black-Right-Pointing-Pointer High sintered density reported than the density obtained for powder synthesized through conventional solid state reaction. Black-Right-Pointing-Pointer The particles are nano sized and have rod shape morphology and are retained at higher temperatures. Black-Right-Pointing-Pointer An average grain size of {approx}1 {mu}m obtained for sintered NdPO{sub 4} after thermal etching at 1400 Degree-Sign C. -- Abstract: Synthesis of nano rod shaped neodymium phosphate (NdPO{sub 4}) particles with specific surface area as high as 107 m{sup 2}g{sup -1} and an average length of 50 nm with aspect ratio 5 was achieved using modified sol gel method. Crystallite size calculated from the X-ray diffraction data by applying Scherer equation was 5 nm for the precursor gel after calcination at 400 Degree-Sign C. NdPO{sub 4} was first precipitated from neodymium nitrate solution using phosphoric acid followed by peptization using dilute nitric acid and further gelation in ammonia atmosphere. The calcined gel powders were further characterized by surface area (Brunauer-Emmet-Teller nitrogen adsorption analysis), Transmission electron microscopy, scanning electron microscopy, UV-vis and FT-IR analysis. Transmission electron microscopy confirms the formation of rod like morphology from the sol, gel and the calcined particles in nano size range. These particles could be compacted and sintered at as low as 1300 Degree-Sign C to a density of 98.5% (theoretical) with an average grain size of {approx}1 {mu}m.

  2. Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, R.W.

    1995-12-19

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes{<=}1000{angstrom}, and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050 C to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors. 8 figs.

  3. Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, Richard W. (Pleasant Hill, CA)

    1995-01-01

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes.ltoreq.1000.ANG., and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050.degree. C. to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors.

  4. Organic carbon aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    SciTech Connect (OSTI)

    Pekala, Richard W. (Pleasant Hill, CA)

    1998-04-28

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes .ltoreq.1000 .ANG., and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050.degree. C. to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors.

  5. Organic carbon aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, R.W.

    1998-04-28

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes {<=}1000 {angstrom}, and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050 C to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors. 8 figs.

  6. Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, R.W.

    1996-09-17

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes {<=}1,000{angstrom}, and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1,050 C to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors. 8 figs.

  7. Organic aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, Richard W. (Pleasant Hill, CA)

    1996-01-01

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes .ltoreq.1000.ANG., and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050.degree. C. to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors.

  8. Sol-gel synthesis of hybrid organic-inorganic materials. Hexylene- and phenylene-bridged polysiloxanes

    SciTech Connect (OSTI)

    Loy, D.A.; Jamison, G.M.; Baugher, B.M.; Myers, S.A.; Assink, R.A.; Shea, K.J. [Sandia National Laboratories, Albuquerque, NM (United States)] [Sandia National Laboratories, Albuquerque, NM (United States); [Univ. of California, Irvine, CA (United States)

    1996-03-01

    New highly cross-linked polysiloxanes were prepared by sol-gel polymerization of 1,6-bis(diethoxymethylsilyl)hexane (1) and 1,4-bis(diethoxymethylsilyl)benzene (2). Hydrolysis and condensation of 1 and 2 under acidic and basic conditions with 4 equiv of water led to the rapid formation of hexylene- and phenylene-bridged polysiloxane gels. The dry gels (xerogels) were intractable, insoluble materials that were noticeably hydrophobic, exhibiting no swelling in organic solvents or water. Most of the xerogels were high surface area, mesoporous materials. Hexylene-bridged polysiloxanes prepared under acidic conditions were always nonporous regardless of whether they were processed to afford xerogels or supercritically dried as aerogels. Hexylene-bridged polysiloxanes prepared under basic conditions and all of the phenylene-bridged polysiloxanes were mesoporous with surface areas as high as 1025 m{sup 2}/g. 35 refs., 9 figs., 3 tabs.

  9. Encapsulation of nanoclusters in dried gel materials via an inverse micelle/sol gel synthesis

    SciTech Connect (OSTI)

    Martino, A.; Yamanaka, S.A.; Kawola, J.S.; Showalter, S.K.; Loy, D.A.

    1998-09-29

    A dried gel material sterically entrapping nanoclusters of a catalytically active material and a process to make the material via an inverse micelle/sol-gel synthesis are disclosed. A surfactant is mixed with an apolar solvent to form an inverse micelle solution. A salt of a catalytically active material, such as gold chloride, is added along with a silica gel precursor to the solution to form a mixture. To the mixture are then added a reducing agent for the purpose of reducing the gold in the gold chloride to atomic gold to form the nanoclusters and a condensing agent to form the gel which sterically entraps the nanoclusters. The nanoclusters are normally in the average size range of from 5--10 nm in diameter with a monodisperse size distribution. 1 fig.

  10. Encapsulation of nanoclusters in dried gel materials via an inverse micelle/sol gel synthesis

    SciTech Connect (OSTI)

    Martino, Anthony (Albuquerque, NM); Yamanaka, Stacey A. (Dallas, TX); Kawola, Jeffrey S. (Albuquerque, NM); Showalter, Steven K. (Albuquerque, NM); Loy, Douglas A. (Albuquerque, NM)

    1998-01-01

    A dried gel material sterically entrapping nanoclusters of a catalytically active material and a process to make the material via an inverse micelle/sol-gel synthesis. A surfactant is mixed with an apolar solvent to form an inverse micelle solution. A salt of a catalytically active material, such as gold chloride, is added along with a silica gel precursor to the solution to form a mixture. To the mixture are then added a reducing agent for the purpose of reducing the gold in the gold chloride to atomic gold to form the nanoclusters and a condensing agent to form the gel which sterically entraps the nanoclusters. The nanoclusters are normally in the average size range of from 5-10 nm in diameter with a monodisperse size distribution.

  11. Synthesis and characterization of vinyl-bridged polysilsesquioxane sol-gel materials

    SciTech Connect (OSTI)

    Yamanaka, S.A.; Carpenter, J.P.; McClain, M.D.; Loy, D.A.

    1995-08-01

    Vinyl-bridged polysilsesquioxane gels were formed through the use of sol-gel polymerization methods. Acid- and base-catalyzed samples were prepared from both the pure cis-(l) and pure trans-(2) isomers of 1, 2-bis(triethoxysilyl)ethylene. Gelation times of the two isomers were compared. The trans monomer 2 formed gels within a week while the cis monomer I failed to gel-even after several months. Gelation of 1 could be promoted by the addition of a coordinating metal such as palladium. The resulting cis- and trans- vinyl-bridged polysilsesquioxane gels were then processed either by vacuum drying to afford xerogels or by extracting with supercritical carbon dioxide to afford aerogels. These vinylbridged polysilsesquioxanes were characterized by SEM, nitrogen sorption porosimetry, solid State {sub 29}Si and {sub 13}C NMR and x-ray powder diffraction.

  12. Sol-Clad-Siding and Trans-Lucent-Insulation : curtain wall components for conserving dwelling heat by passive-solar means

    E-Print Network [OSTI]

    Iliesiu, Doru

    1983-01-01

    A prototype for a dwelling heat loss compensator is introduced in this thesis, along with its measured thermal performance and suggestions for its future development. As a heat loss compensator, the Sol-Clad-Siding collects, ...

  13. On the sol-gel synthesis of strontium-titanate thin films and the prospects of their use in electronics

    SciTech Connect (OSTI)

    Sohrabi Anaraki, H.; Gaponenko, N. V., E-mail: nik@nano.bsuir.edu.by; Rudenko, M. V.; Guk, A. F.; Zavadskij, S. M.; Golosov, D. A.; Kolosnitsyn, B. S. [Belarusian State University of Informatics and Radioelectronics (Belarus); Kolos, V. V.; Pyatlitskij, A. N.; Turtsevich, A. S. [Integral Enterprise (Belarus)

    2014-12-15

    Strontium-titanate films obtained by the sol-gel technique are deposited onto silicon and silicon/oxide titanium/platinum substrates. The strontium-titanate phase is detected by the method of X-ray diffraction analysis after heat treatment at temperatures of 750 and 800°C. The thickness of the films obtained by the spin-on method increases from 50 to 250 nm as the number of deposited layers is increased and is accompanied with an increase in the grain size in the films. Prospects of the development of the sol-gel technique for the formation of film components of electronic devices based on SrTiO{sub 3} xerogels are discussed.

  14. Dialkylene carbonate-bridged polysilsesquioxanes. Hybrid organic-inorganic sol-gels with a thermally labile bridging group

    SciTech Connect (OSTI)

    Loy, D.A.; Beach, J.V.; Baugher, B.M.; Assink, R.A.; Shea, K.J.; Tran, J.; Small, J.H.

    1999-11-01

    In this paper, the authors introduce a new approach for altering the properties of bridged polysilsesquioxane xerogels using postprocessing modification of the polymeric network. The bridging organic group contains latent functionalities that can be liberated thermally, photochemically, or chemically after the gel has been processed to a xerogel. These modifications can produce changes in density, solubility, porosity, and or chemical properties of the material. Since every monomer possesses two latent functional groups, the technique allows for the introduction of high levels of functionality in hybrid organic-inorganic materials. Dialkylene carbonate-bridged polysilsesquioxane gels were prepared by the sol-gel polymerization of bis(triethoxysilylpropyl) carbonate and bis(triethoxysilylisobutyl) carbonate. Thermal treatment of the resulting nonporous xerogels and aerogels at 300--350 C resulted in quantitative decarboxylation of the dialkylene carbonate bridging groups to give new hydroxyalkyl and olefinic substituted polysilsesquioxane monolithic xerogels and aerogels that cannot be directly prepared through direct sol-gel polymerization of organotrialkoxysilanes.

  15. ANA and GIS zeolite synthesis directly from alumatrane and silatrane by sol-gel process and microwave technique

    E-Print Network [OSTI]

    Gulari, Erdogan

    ANA and GIS zeolite synthesis directly from alumatrane and silatrane by sol-gel process, Na2O and H2O at 1:0.25:3:410, GIS was synthesized at hydrothermal treatment of 3 h at 110 C, while analcium (ANA) was produced at 130 C for 8 h. GIS obtained had 4.55 mm in size while ANA's size was 9

  16. Structural and optical properties of chromium doped zinc oxide nanoparticles synthesized by sol-gel method

    SciTech Connect (OSTI)

    Naqvi, Syed Mohd. Adnan; Irshad, Kashif; Soleimani, Hassan E-mail: noorhana-yahya@petronas.com.my; Yahya, Noorhana E-mail: noorhana-yahya@petronas.com.my

    2014-10-24

    Nanosized Cr-doped ZnO nano particles were synthesized by facile sol-gel auto combustion method. The structural and optical properties of Cr-doped ZnO nanoparticles have been investigated by XRD and UV-Vis spectroscopy at room temperature for 0% to 8% concentration. X-ray diffraction analysis reveals that the Cr-doped ZnO crystallizes in a single phase polycrystalline nature with wurtzite lattice. With every % of doping, the peaks are shifting scarcely and doping of Cr is possible up to 7%. After that, the last peak vanishes, that signifies its structure is transmuted from 8% doping. The average crystallite size decreases with increase in Cr concentration (i.e. 28.9 nm for 0% to 25.8 nm for 8%). The UV-Vis spectra of the nanoparticles betoken an incrementation in the band gap energy from 3.401, 3.415, 3.431, 3.437,3.453, 3.514,3.521, 3.530 and 3.538 eV respectively, for 0,1, 2, 3, 4, 5, 6, 7 and 8 % doping concentration.

  17. Energy efficiency of electric vehicles at the 1994 American Tour de Sol

    SciTech Connect (OSTI)

    Quong, S.; Duoba, M.; Buitrago, C.; LeBlanc, N.; Larsen, R.

    1994-11-01

    In 1994, the US Department of Energy, through Argonne National Laboratory`s Center for Transportation Research, sponsored energy-efficiency data collection from student, private, and professional electric vehicles during the American Tour de Sol (ATdS). The ATDS is a multiple-day road rally event, from New York City to Philadelphia. During each leg of the event, kilowatt-hour meters measured the efficiency of the electric vehicles (EVs), which averaged from 5.68 to 65.74 km/kWh. In addition to daily energy-usage measurements, some vehicles used a data-acquisition unit to collect second-by-second information. This showed, in one case, that 21% of the total energy was captured in regenerative braking. Some of the vehicles were also tested on a dynamometer for energy-efficiency, acceleration, and steady-state power ratings. This paper also compares the energy efficiency of the vehicles during the road rally to the dynamometer results. In almost all vehicles, there was an increase in energy efficiency when the vehicle was traveling over the road, due to the non-transient duty cycle and efficient driving techniques. The dynamometer testing also showed that some EVs are equal to or better than gasoline vehicles in performance and efficiency.

  18. Synthesis of Yttria-Stabilized Zirconia Aerogels by a Non-Alkoxide Sol-Gel Route

    SciTech Connect (OSTI)

    Chervin, C N; Clapsaddle, B J; Chiu, H W; Gash, A E; Satcher, Jr., J H; Kauzlarich, S M

    2005-02-11

    Homogeneous, nanocrystalline powders of yttria-stabilized zirconia were prepared using a nonalkoxide sol-gel method. Monolithic gels, free of precipitation, were prepared by addition of propylene oxide to aqueous solutions of Zr{sup 4+} and Y{sup 3+} chlorides at room temperature. The gels were dried with supercritical CO{sub 2}(l), resulting in amorphous aerogels that crystallized into cubic stabilized ZrO{sub 2} following calcination at 500 C. The aerogels and resulting crystalline products were characterized using in-situ temperature profile X-ray diffraction, thermal analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption analysis. TEM and N{sub 2} adsorption/desorption analysis of an aerogel indicated a porous network structure with a high surface area (409 m{sup 2}/g). The crystallized yttria-stabilized zirconia maintained high surface area (159 m{sup 2}/g) upon formation of homogeneous, nanoparticles ({approx}10 nm). Ionic conductivity at 1000 C of sintered YSZ (1500 C, 3 hours) prepared by this method, was 0.13 {+-} 0.02 {Omega}{sup -1} cm{sup -1}. Activation energies for the conduction processes from 1000-550 C and 550-400 C, were 0.95 {+-} 0.09 and 1.12 {+-} 0.05 eV, respectively. This is the first reported synthesis and characterization of yttria-stabilized zirconia via an aerogel precursor.

  19. Thickness controlled sol-gel silica films for plasmonic bio-sensing devices

    SciTech Connect (OSTI)

    Figus, Cristiana Quochi, Francesco Artizzu, Flavia Saba, Michele Marongiu, Daniela Mura, Andrea; Bongiovanni, Giovanni; Floris, Francesco; Marabelli, Franco; Patrini, Maddalena; Fornasari, Lucia; Pellacani, Paola; Valsesia, Andrea

    2014-10-21

    Plasmonics has recently received considerable interest due to its potentiality in many fields as well as in nanobio-technology applications. In this regard, various strategies are required for modifying the surfaces of plasmonic nanostructures and to control their optical properties in view of interesting application such as bio-sensing, We report a simple method for depositing silica layers of controlled thickness on planar plasmonic structures. Tetraethoxysilane (TEOS) was used as silica precursor. The control of the silica layer thickness was obtained by optimizing the sol-gel method and dip-coating technique, in particular by properly tuning different parameters such as pH, solvent concentration, and withdrawal speed. The resulting films were characterized via atomic force microscopy (AFM), Fourier-transform (FT) spectroscopy, and spectroscopic ellipsometry (SE). Furthermore, by performing the analysis of surface plasmon resonances before and after the coating of the nanostructures, it was observed that the position of the resonance structures could be properly shifted by finely controlling the silica layer thickness. The effect of silica coating was assessed also in view of sensing applications, due to important advantages, such as surface protection of the plasmonic structure.

  20. Encapsulation of gold nanoclusters in silica materials via an inverse micelle/sol-gel synthesis

    SciTech Connect (OSTI)

    Martino, A.; Kawola, J.S.; Loy, D.A. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Yamanaka, S.A. [Texas Instruments, Dallas, TX (United States)] [Texas Instruments, Dallas, TX (United States)

    1997-02-01

    Nanometer-sized gold particles were encapsulated in the micropores of xerogels and aerogels. The synthesis involves the sequential reduction of a gold salt followed by sol-gel processing in an inverse micelle solution. The inverse micelle solution solubilizes the metal salt and provides a microreactor for the nucleation, growth, and stabilization of the nanometer-sized clusters. Hydrolysis and condensation of an added siloxane precursor produces a wet gel embedding the particles. Characterization of the particle size and composition and the particle growth process was completed with transmission electron microscopy (TEM), electron diffraction, and UV-visible absorption spectrometry. Characterization of the gel surface areas was completed with N{sub 2} porosimetry. Material properties determined as a function of the gel precursor (TEOS vs a prehydrolyzed form of TEOS), the water to gel precursor reaction stoichiometry, and surfactant concentration are discussed in terms of the unique solution chemistry occurring in the microheterogeneous inverse micelle solutions. 73 refs., 7 figs., 1 tab.

  1. Encapsulation of metal nanocluster catalysts in silica materials via an inverse micelle/sol-gel synthesis

    SciTech Connect (OSTI)

    Martino, A.; Kawola, J.S.; Yamanaka, S.A.; Loy, D.A.

    1997-05-01

    Nanometer sized metal particles were encapsulated in the micropores of xerogels and aerogels. The synthesis involves the sequential reduction of a metal salt followed by sol-gel processing in an inverse micelle solution. The inverse micelle solution solubilizes the metal salt and provides a micro-reactor for the nucleation, growth, and stabilization of the nanometer sized clusters. Hydrolysis and condensation of an added siloxane precursor produces a wet gel embedding the particles. Characterization of the particle size and composition and the particle growth process was completed with transmission electron microscopy (TEM), electron diffraction, and UV-visible absorption spectrometry. Characterization of the gel surface areas was completed with N{sub 2} porosimetry. Material properties determined as a function of the gel precursor (TEOS vs. a pre-hydrolyzed form of TEOS), the water to gel precursor reaction stoichiometry, and surfactant concentration are discussed in terms of the unique solution chemistry occurring in the micro-heterogeneous inverse micelle solutions. Finally, catalyst development and catalyst activity of the materials are discussed. 1-hexene hydrogenation was chosen as a model reaction.

  2. Development of carbon-metal oxide supercapacitors from sol-gel derived carbon-ruthenium xerogels

    SciTech Connect (OSTI)

    Lin, C.; Ritter, J.A.; Popov, B.N.

    1999-09-01

    There has been increasing interest in electrochemical capacitors as energy storage systems because of their high power density and long cycle life, compared to battery devices. According to the mechanism of energy storage, there are two types of electrochemical capacitors. One type is based on double layer (dl) formation due to charge separation, and the other type is based on a faradaic process due to redox reactions. Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt% Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic voltammogram for over 2,000 cycles.

  3. Structure and chemistry of sol-gel derived transparent silica aerogel

    SciTech Connect (OSTI)

    Tewari, P.H.; Lofftus, K.D.; Hunt, A.J.

    1985-02-01

    Transparent silica aerogels are being studied because of their excellent thermal insulation properties for window glazing materials. The chemistry of the base catalyzed Si(OC/sub 2/H/sub 5/)/sub 4/ sol-gel process to produce transparent aerogels is presented. The results of a factorial design set of experiments are discussed in which five process parameters are simultaneously varied. The goal of these experiments was to optimize the process conditions and to analyze the importance of various parameters in improving the properties of the aerogel. A novel technique of ambient temperature supercritical drying of alcogels is described. In this process, supercritical drying occurs at less than or equal to40/sup 0/C instead of at greater than or equal to270/sup 0/C and greater than or equal to1700 PSI (12 MPa), by substituting CO/sub 2/ for alcohol in the alcogel. The time of drying is reduced from 2 to 3 days to 8 to 10 hours. It is shown that light scattering, microstructural properties and other characteristics of aerogels produced by this process and by the high temperature supercritical drying are similar.

  4. Quantum Limits of Thermometry

    E-Print Network [OSTI]

    Thomas M. Stace

    2010-06-08

    The precision of typical thermometers consisting of $N$ particles is shot noise limited, improving as $\\sim1/\\sqrt{N}$. For high precision thermometry and thermometric standards this presents an important theoretical noise floor. Here it is demonstrated that thermometry may be mapped onto the problem of phase estimation, and using techniques from optimal phase estimation, it follows that the scaling of the precision of a thermometer may in principle be improved to $\\sim1/N$, representing a Heisenberg limit to thermometry.

  5. Sol-gel synthesis of mesoporous CaCu{sub 3}Ti{sub 4}O{sub 12} thin films and their gas sensing response

    SciTech Connect (OSTI)

    Parra, R., E-mail: rparra@fi.mdp.edu.a [Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA), CONICET-UNMdP, J. B. Justo 4302, B7608FDQ Mar del Plata (Argentina); Savu, R. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Ramajo, L.A.; Ponce, M.A. [Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA), CONICET-UNMdP, J. B. Justo 4302, B7608FDQ Mar del Plata (Argentina); Varela, J.A. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Castro, M.S. [Instituto de Investigaciones en Ciencia y Tecnologia de Materiales (INTEMA), CONICET-UNMdP, J. B. Justo 4302, B7608FDQ Mar del Plata (Argentina); Bueno, P.R. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Joanni, E. [Instituto de Quimica, UNESP, Rua F. Degni s/n, 14800-900 Araraquara, SP (Brazil); Centro de Tecnologia da Informacao Renato Archer, Rodovia Dom Pedro I (SP-65) km 143, 6, 13069-901 Campinas, SP (Brazil)

    2010-06-15

    A new sol-gel synthesis procedure of stable calcium copper titanate (CaCu{sub 3}Ti{sub 4}O{sub 12}-CCTO) precursor sols for the fabrication of porous films was developed. The composition of the sol was selected in order to avoid the precipitation of undesired phases; ethanol was used as solvent, acetic acid as modifier and poly(ethyleneglycol) as a linker agent. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 {sup o}C. The main phase present in the samples, as detected by X-ray diffraction and Raman spectroscopy, was CaCu{sub 3}Ti{sub 4}O{sub 12}. Scanning electron microscopy analysis showed that mesoporous structures, with thicknesses between 200 and 400 nm, were developed as a result of the processing conditions. The films were tested regarding their sensibility towards oxygen and nitrogen at atmospheric pressure using working temperatures from 200 to 290 {sup o}C. The samples exhibited n-type conductivity, high sensitivity and short response times. These characteristics indicate that CCTO mesoporous structures obtained by sol-gel are suitable for application in gas sensing. - Graphical abstract: A sol-gel synthesis procedure toward stable CaCu{sub 3}Ti{sub 4}O{sub 12}-precursor sols avoiding the precipitation of undesired compounds is proposed. Films deposited by spin-coating onto oxidized silicon substrates were annealed at 700 {sup o}C. The thickness varied between 200 and 400 nm depending on sol composition. The films, tested as gas sensors for O{sub 2}, showed n-type conductivity, good sensitivity and short response times.

  6. Electrochromism in sol-gel deposited TiO(sub 2) films

    SciTech Connect (OSTI)

    Bell, J.M.; Barczynska, J.; Evans, L.A.; MacDonald, K.A.; Wang, J.; Green, D.C.; Smith, G.B.

    1994-12-31

    Electrochromism in sol-gel deposited TiO{sub 2} films and films containing TiO{sub 2} and WO{sub 3} has been observed. The films are deposited by dip-coating from a precursor containing titanium isopropoxide in ethanol or titanium propoxide in ethanol, and after deposition the films are heat treated to between 250 C and 300 C. The films do not show any signs of crystallinity. However substantial coloration is observed using Li{sup +} ions in a non-aqueous electrolyte, both in pure TiO{sub 2} films and in mixed metal oxide films (WO{sub 3}:TiO{sub 2}), although the voltage required to produce coloration is different in the two cases. Results will be presented detailing the optical switching and charge transport properties of the films during cyclic voltammetry. These results will be used to compare the performance of the TiO{sub 2} films with other electrochromics. The TiO{sub 2} and mixed metal films all color cathodically, and the colored state is a neutral greyish color for TiO{sub 2}, while the bleached state is transparent and colorless. Results on coloration efficiency and the stability under repeated electrochemical cycling will also be presented. The neutral color of the TiO{sub 2} films and mixed-metal films means that electrochromic windows based on TiO{sub 2} may have significant advantages over WO{sub 3}-based windows. A detailed analysis of the optical properties of the colored state of the films will be presented. The dynamics of coloration for these films is also under investigation, and preliminary results will be presented.

  7. Characterization of nanocrystalline ZnO:Al films by sol-gel spin coating method

    SciTech Connect (OSTI)

    Gareso, P. L. Rauf, N. Juarlin, E.; Sugianto,; Maddu, A.

    2014-09-25

    Nanocrystalline ZnO films doped with aluminium by sol-gel spin coating method have been investigated using optical transmittance UV-Vis and X-ray diffraction (X-RD) measurements. ZnO films were prepared using zinc acetate dehydrate (Zn(CH{sub 3}COO){sub 2}@@‡2H{sub 2}O), ethanol, and diethanolamine (DEA) as a starting material, solvent, and stabilizer, respectively. For doped films, AlCl{sub 3} was added to the mixture. The ZnO:Al films were deposited on a transparent conductive oxide (TCO) substrate using spin coating technique at room temperature with a rate of 3000 rpm in 30 sec. The deposited films were annealed at various temperatures from 400°C to 600°C during 60 minutes. The transmittance UV-Vis measurement results showed that after annealing at 400°C, the energy band gap profile of nanocrystalline ZnO:Al film was a blue shift. This indicated that the band gap of ZnO:Al increased after annealing due to the increase of crystalline size. As the annealing temperature increased the bandgap energy was a constant. In addition to this, there was a small oscillation occurring after annealing compared to the as–grown samples. In the case of X-RD measurements, the crystalinity of the films were amorphous before annealing, and after annealing the crystalinity became enhance. Also, X-RD results showed that structure of nanocrystalline ZnO:Al films were hexagonal polycrystalline with lattice parameters are a = 3.290 Å and c = 5.2531 Å.

  8. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, D.W.; Mattes, B.R.; Koskelo, A.C.; Heeger, A.J.; Robinson, J.M.; Smilowitz, L.B.; Klimov, V.I.; Cha, M.; Sariciftci, N.S.; Hummelen, J.C.

    1998-04-21

    Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO{sub 2}) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400--1,100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes. 5 figs.

  9. Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology

    SciTech Connect (OSTI)

    Shiquan Tao

    2006-12-31

    The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fiber optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.

  10. A case study of cost overruns in a Thai condominium project 

    E-Print Network [OSTI]

    Roachanakanan, Kwanchai

    2005-08-29

    Construction managers confront many problems. Still, this industry plays a vital role in the healthy growth of the economy of many countries throughout the developed and developing world. Effective management of construction projects has been a...

  11. Rethinking construction cost overruns: an artificial neural network approach to construction cost estimation 

    E-Print Network [OSTI]

    Ahiaga-Dagbui, Dominic Doe

    2014-11-27

    The main concern of a construction client is to procure a facility that is able to meet its functional requirements, of the required quality, and delivered within an acceptable budget and timeframe. The cost aspect of ...

  12. renewable sources of power. Demand for fossil fuels surely will overrun supply s

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-Sessions |discussed howCommercialemail notf.IOE/MA-0001 -08 '9g Electric

  13. Dialkylenecarbonate-Bridged Polysilsesquioxanes. Hybrid Organic-Inorganic Sol-Gels with a Thermally Labile Bridging Group

    SciTech Connect (OSTI)

    Assink, Roger A.; Baugher, Brigitta M.; Beach, James V.; Loy, Douglas A.; Shea, Kenneth J.; Small, James H.; Tran, Joseph

    1999-07-20

    In this paper, we introduce a new approach for altering the properties of bridged polysilsesquioxane xerogels using post-processing mobilization of the polymeric network. The bridging organic group contains latent functionalities that can be liberated thermally, photochemically, or by chemical means after the gel has been processed to a xerogel. These modifications can produce changes in density, volubility, porosity, and or chemical properties of the material. Since every monomer possesses two latent functional groups, the technique allows for the introduction of high levels of functionality in hybrid organic-inorganic materials. Dialkylenecarbonate-bridged polysilsesquioxane gels were prepared by the sol-gel polymerization of bis(triethoxysilylpropyl)carbonate (1) and bis(triethoxysilylisobutyl)-carbonate (2). Thermal treatment of the resulting non-porous xerogels and aerogels at 300-350 C resulted in quantitative decarboxylation of the dialkylenecarbonate bridging groups to give new hydroxyalkyl and olefinic substituted polysilsesquioxane monolithic xerogels and aerogels that can not be directly prepared through direct sol-gel polymerization of organotrialkoxysilanes.

  14. Heat treatment effect on the physical properties of cobalt doped TiO{sub 2} sol–gel materials

    SciTech Connect (OSTI)

    Samet, L., E-mail: lolwasamet@gmail.com [Institut Préparatoires aux Etudes d'Ingénieurs d'El-Manar, Université Tunis El Manar, Campus Universitaire, 2092 El Manar (Tunisia); Laboratoire de Photovoltaique de Semi-conducteur et de Nanostructure, Centre de Recherches et des Technologies de l'Energie, Technopole borj cedria, Bp 95, hammamm lif 2050 (Tunisia); Ben Nasseur, J.; Chtourou, R. [Laboratoire de Photovoltaique de Semi-conducteur et de Nanostructure, Centre de Recherches et des Technologies de l'Energie, Technopole borj cedria, Bp 95, hammamm lif 2050 (Tunisia); March, K.; Stephan, O. [Laboratoire de Physique des Solides, UMR 8502 CNRS - Université Paris-Sud, Bât 510, 91405 Orsay cedex (France)

    2013-11-15

    Cobalt doped and undoped TiO{sub 2} powders have been prepared by sol–gel technique and annealed at temperatures ranging from 400 °C to 1000 °C. The effects of annealing temperature on the structural, morphological and optical properties have been characterized by X-ray diffraction, transmission electron microscopy, electron energy-loss spectroscopy and diffuse reflectance spectroscopy. For all doped samples there is a general reduction of the band gap energy, in comparison with undoped samples prepared in the same conditions. More specifically, experimental results indicate that cobalt doping, occurring as Co{sup 2+} ion insertion into the TiO{sub 2} (Ti{sup 4+}) host lattice, inhibits the growth of the crystallites and delays the phase transformation from anatase to rutile. Moreover, at high temperature, a secondary phase (CoTiO{sub 3}) is found to coexist with highly crystalline rutile. These structural characteristics are discussed in relation with the observed general trends for the optical properties. - Highlights: • Cobalt doped and undoped TiO{sub 2} powders have been prepared by sol–gel route. • Doping makes the band gap narrower. • Doping delays the phase transformation from anatase to rutile. • Doping inhibits the growth of the crystallites. • At high annealing temperature a CoTiO{sub 3} phase coexists with highly crystalline rutile.

  15. Electrochemical characterization of thio sol-gel derived titanium sulfide (TiS{sub 2}) powders with unique morphologies

    SciTech Connect (OSTI)

    Sriram, M.A.; Kumta, P.N. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    1996-12-31

    A novel thio sol-gel process utilizing titanium alkoxide as the metal source has been used to synthesize TiS{sub 2} powders exhibiting uniquely different morphologies. The pure alkoxide and its partially modified form using benzene sulfonic acid (BSA) have been reacted with H{sub 2}S to yield a solid precursor. Upon heat treatment in flowing H{sub 2}S the precursors were converted to TiS{sub 2} exhibiting distinctly different morphologies. These powders have been characterized for their chemical stoichiometry (using X-ray diffraction). At the same time the sulfide was also prepared using conventional techniques involving the reaction of the individual elements in a sealed evacuated quartz ampoule at elevated temperatures of 500{degrees}C. The morphologies of both, the thio sol-gel derived and conventionally synthesized powders have been compared using scanning electron microscopy (SEM). Preliminary electrochemical tests were also performed by fabricating test cathodes of these materials and using them in {open_quotes}hockey puck{close_quotes} cells incorporating lithium as both the anode and the reference electrodes. These studies were conducted to analyze the effect of the different morphologies of the synthesized powders on their electrochemical performance.

  16. Optical properties of undoped and Mg doped CuCrO{sub 2} powders synthesized by sol-gel route

    SciTech Connect (OSTI)

    Srinivasan, Radhakrishnan; Bolloju, Satish [Department of Chemistry, BITS Pilani Hyderabad Campus, Jawahar Nagar Village, Shamirpet Mandal, R.R.District, Hyderabad - 500 078 (India)

    2014-01-28

    In this work, CuCrO{sub 2} was synthesized by sol-gel method using citric acid as a gelling agent. The different parameters like ratio of citric acid to metal ions, calcination temperature, and duration were studied. A green colored powder with particle size around 300 nm was formed at the calcination temperature of 800 °C for four hours duration. The increase in temperature has a profound impact on crystallite size and in turn effected the optical properties. Band gap of the obtained CuCrO{sub 2} has varied from 2.3 to 1.7 eV by increasing the temperature from 800 °C to 900 °C. Doping studies were performed by introducing Mg{sup 2+} ion to substitute Cr{sup 3+} in CuCrO{sub 2}. X-ray powder diffraction and SEM studies on 2% Mg doped samples indicated a clear formation of side phases. According to the X-ray powder patterns, the reflections from side phases were increasing with the increase in doping concentrations of Mg from 2 to 5%. The side phases were found to be MgCr{sub 2}O{sub 4} spinel and CuO. The band gap has decreased for doped samples in comparison to undoped one. In this paper, sol-gel synthesis and characterization by Xray powder diffraction, SEM studies and UV-Vis-Diffuse Reflectance spectra are presented.

  17. New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors

    SciTech Connect (OSTI)

    Gash, A E; Tillotson, T M; Satcher Jr, J H; Hrubesh, L W; Simpson, R L

    2000-09-12

    We have developed a new sol-gel route to synthesize several transition and main-group metal oxide aerogels. The approach is straightforward, inexpensive, versatile, and it produces monolithic microporous materials with high surface areas. Specifically, we report the use of epoxides as gelation agents for the sol-gel synthesis of chromia aerogels and xerogels from simple Cr(III) inorganic salts. The dependence of both gel formation and its rate was studied by varying the solvent used, the Cr(III) precursor salt, the epoxide/Cr(III) ratio, as well as the type of epoxide employed. All of these variables were shown to affect the rate of gel formation and provide a convenient control of this parameter. Dried chromia aerogels were characterized by high-resolution transmission electron microscopy (HRTEM) and nitrogen adsorption/desorption analyses, results of which will be presented. Our studies have shown that rigid monolithic gels can be prepared from many different metal ions salts, provided the formal oxidation state of the metal ion is greater than or equal to +3. Conversely, when di-valent transition metal salts are used precipitated solids are the products.

  18. Investigation of hydrolysis and condensation in organically modified sol-gel systems: {sup 29}Si NMR and the INEPT sequence

    SciTech Connect (OSTI)

    Alam, T.M.; Assink, R.A.; Loy, D.A.

    1996-06-01

    The spectral editing properties of the {sup 29}Si NMR INEPT heteronuclear transfer experiment have been utilized for the identification and characterization of hydrolysis and initial condensation products in methyltrimethoxysilane (MTMS) sol-gel materials. {sup 29}Si NMR assignments in MTMS are complicated by a small spectral dispersion ({approximately} 0.5 ppm) and two different {sup 29}Si-{sup 1}H J couplings. By using analytical expressions for the INEPT signal response with multiple heteronuclear J couplings, unambiguous spectral assignments can be made. For this organomethoxysilane the rate of hydrolysis was found to be very rapid and significantly faster than either the water or alcohol producing condensation reactions. The hydrolysis species of both the MTMS monomer and its initial T{sup 1} condensation products follow statistical distributions that can be directly related to the extent of the hydrolysis reactions. The role of the statistical distribution of hydrolysis products on the production and synthetic control of organically modified sol-gels is discussed.

  19. The Limit of Mental Structures

    E-Print Network [OSTI]

    Mandler, George

    2013-01-01

    of constructing such structures. References A cautionaryTHE LIMIT OF MENTAL STRUCTURES Asch, S. E. , & Ebenholtz, S.100. THE LIMIT OF MENTAL STRUCTURES Halford, G. S. , Cowan,

  20. Fault current limiter

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2013-10-08

    A fault current limiter (FCL) includes a series of high permeability posts for collectively define a core for the FCL. A DC coil, for the purposes of saturating a portion of the high permeability posts, surrounds the complete structure outside of an enclosure in the form of a vessel. The vessel contains a dielectric insulation medium. AC coils, for transporting AC current, are wound on insulating formers and electrically interconnected to each other in a manner such that the senses of the magnetic field produced by each AC coil in the corresponding high permeability core are opposing. There are insulation barriers between phases to improve dielectric withstand properties of the dielectric medium.

  1. (Limiting the greenhouse effect)

    SciTech Connect (OSTI)

    Rayner, S.

    1991-01-07

    Traveler attended the Dahlem Research Conference organized by the Freien Universitat, Berlin. The subject of the conference was Limiting the Greenhouse Effect: Options for Controlling Atmospheric CO{sub 2} Accumulation. Like all Dahlem workshops, this was a meeting of scientific experts, although the disciplines represented were broader than usual, ranging across anthropology, economics, international relations, forestry, engineering, and atmospheric chemistry. Participation by scientists from developing countries was limited. The conference was divided into four multidisciplinary working groups. Traveler acted as moderator for Group 3 which examined the question What knowledge is required to tackle the principal social and institutional barriers to reducing CO{sub 2} emissions'' The working rapporteur was Jesse Ausubel of Rockefeller University. Other working groups examined the economic costs, benefits, and technical feasibility of options to reduce emissions per unit of energy service; the options for reducing energy use per unit of GNP; and the significant of linkage between strategies to reduce CO{sub 2} emissions and other goals. Draft reports of the working groups are appended. Overall, the conference identified a number of important research needs in all four areas. It may prove particularly important in bringing the social and institutional research needs relevant to climate change closer to the forefront of the scientific and policy communities than hitherto.

  2. "Infinite energy solutions" Fractal Laplace operator Nonlocal problem & well-posedness Renormalized sol's definition Hints & Proof Renormalized solutions adapted to the

    E-Print Network [OSTI]

    Jeanjean, Louis

    "Infinite energy solutions" Fractal Laplace operator Nonlocal problem & well-posedness Renormalized #12;"Infinite energy solutions" Fractal Laplace operator Nonlocal problem & well-posedness Renormalized sol's definition Hints & Proof Plan of the talk 1 "Infinite energy solutions" for elliptic PDEs 2

  3. Sol-Gel Synthesis of Vanadium Oxide within a Block Copolymer Elsa A. Olivetti, Jong Hak Kim, Donald R. Sadoway, Ayse Asatekin, and Anne M. Mayes*

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    -transparent. Introduction Hybrid organic/inorganic nanocomposite materials are widely being developed for drug delivery,1Sol-Gel Synthesis of Vanadium Oxide within a Block Copolymer Matrix Elsa A. Olivetti, Jong Hak Kim, Donald R. Sadoway, Ayse Asatekin, and Anne M. Mayes* Department of Materials Science and Engineering

  4. Under Review for Publication in ASME J. Solar Energy Engineering SOL-12-1058 Life Estimation of Pressurized-Air Solar-Thermal Receiver Tubes

    E-Print Network [OSTI]

    Cortes, Corinna

    Under Review for Publication in ASME J. Solar Energy Engineering SOL-12-1058 Life Estimation of Pressurized-Air Solar-Thermal Receiver Tubes David K. Fork 1 e-mail: fork@google.com John Fitch e-mail: fitch.ziaei@gmail.com Robert I. Jetter e-mail: bjetter@sbcglobal.net The operational conditions of the solar thermal receiver

  5. Fluctuations in an aging system: absence of effective temperature in the sol-gel transition of a quenched gelatin sample

    E-Print Network [OSTI]

    Antoine Bérut; Artyom Petrosyan; Juan Ruben Gomez-Solano; Sergio Ciliberto

    2015-09-03

    We study the fluctuations of a Brownian micro particle trapped with optical tweezers in a gelatin solution undergoing a fast local temperature quench below the sol-gel transition. Contrary to what was previously reported, we observe no anomalous fluctuations in the particle's position that could be interpreted in terms of an effective temperature. A careful analysis with ensemble averages shows only equilibrium-like properties for the fluctuations, even though the system is clearly aging. We also provide a detailed discussion on possible artifacts that could have been interpreted as an effective temperature, such as the presence of a drift or a mixing in time and ensemble averages in data analysis. These considerations are of general interest when dealing with non-ergodic or non-stationary systems.

  6. Influence of transition metals on the surface acidic properties of titania prepared by sol-gel route

    SciTech Connect (OSTI)

    Shali, N.B. [Department of Applied Chemistry, Cochin University of Science and Technology, Cochin-22, Kerala (India); Sugunan, S. [Department of Applied Chemistry, Cochin University of Science and Technology, Cochin-22, Kerala (India)]. E-mail: ssg@cusat.ac.in

    2007-09-04

    A series of titania catalysts containing chromium, molybdenum as well as tungsten has been prepared by colloidal sol-gel route using metatitanic acid as the precursor. Structural characterization of the prepared catalysts was done with Energy dispersive X-ray analysis, X-ray diffraction, BET surface area and pore volume measurements. The influence of different transition metals like chromium, molybdenum and tungsten on the surface acidic properties of titania is investigated in detail. Two independent methods have been used to study the surface acidity of these catalyst systems: temperature programmed desorption of ammonia which is a measure of total acidity and thermodesorption studies using 2,6-dimethyl pyridine which is a measure of Bronsted acidity. Cumene cracking reaction is carried out over the prepared systems for further characterizing the acidity of the prepared catalysts. Remarkable enhancement in the surface acidity is observed after transition metal incorporation. The catalytic activity of the prepared catalysts was tested towards the dehydrogenation of cyclohexane.

  7. Decision-making in structure solution using Bayesian estimates of map quality: the PHENIX AutoSol wizard

    SciTech Connect (OSTI)

    Terwilliger, Thomas C., E-mail: terwilliger@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Adams, Paul D. [Lawrence Berkeley National Laboratory, One Cyclotron Road, Building 64R0121, Berkeley, CA 94720 (United States); Read, Randy J.; McCoy, Airlie J. [Department of Haematology, University of Cambridge, Cambridge CB2 0XY (United Kingdom); Moriarty, Nigel W.; Grosse-Kunstleve, Ralf W.; Afonine, Pavel V.; Zwart, Peter H. [Lawrence Berkeley National Laboratory, One Cyclotron Road, Building 64R0121, Berkeley, CA 94720 (United States); Hung, Li-Wei [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2009-06-01

    Ten measures of experimental electron-density-map quality are examined and the skewness of electron density is found to be the best indicator of actual map quality. A Bayesian approach to estimating map quality is developed and used in the PHENIX AutoSol wizard to make decisions during automated structure solution. Estimates of the quality of experimental maps are important in many stages of structure determination of macromolecules. Map quality is defined here as the correlation between a map and the corresponding map obtained using phases from the final refined model. Here, ten different measures of experimental map quality were examined using a set of 1359 maps calculated by re-analysis of 246 solved MAD, SAD and MIR data sets. A simple Bayesian approach to estimation of map quality from one or more measures is presented. It was found that a Bayesian estimator based on the skewness of the density values in an electron-density map is the most accurate of the ten individual Bayesian estimators of map quality examined, with a correlation between estimated and actual map quality of 0.90. A combination of the skewness of electron density with the local correlation of r.m.s. density gives a further improvement in estimating map quality, with an overall correlation coefficient of 0.92. The PHENIX AutoSol wizard carries out automated structure solution based on any combination of SAD, MAD, SIR or MIR data sets. The wizard is based on tools from the PHENIX package and uses the Bayesian estimates of map quality described here to choose the highest quality solutions after experimental phasing.

  8. Facile preparation of apatite-type lanthanum silicate by a new water-based sol–gel process

    SciTech Connect (OSTI)

    Yamagata, Chieko, E-mail: yamagata@ipen.br [Nuclear and Energy Research Institute – Instituto de Pesquisas Energéticas e Nucleares – CCTM (Centro de Ciência e Tecnologia de Materiais), São Paulo (Brazil); Elias, Daniel R.; Paiva, Mayara R.S.; Misso, Agatha M.; Castanho, Sonia R.H. Mello [Nuclear and Energy Research Institute – Instituto de Pesquisas Energéticas e Nucleares – CCTM (Centro de Ciência e Tecnologia de Materiais), São Paulo (Brazil)

    2013-06-01

    Highlights: ? We use a Na{sub 2}SiO{sub 3} waste solution as source of Si. ? We present a simple, rapid and low temperature method of lanthanum silicate apatite preparation. ? TEOS, a high cost reagent, was successfully substituted by a cheap price Na{sub 2}SiO{sub 3}, to obtain pure La{sub 9.56}(SiO{sub 4})6O{sub 2.33} lanthanum silicate apatite. - Abstract: In recent years, apatite-type lanthanum silicates ([Ln{sub 10?x}(XO{sub 4})6O{sub 3–1.5x}] (X = Si or Ge)) have been studied for use in SOFC (solid oxide fuel cells), at low temperature (600–800 °C), due to its ionic conductivity which is higher than that of YSZ (Yttrium Stabilized Zirconia) electrolyte. For this reason they are very promising materials as solid electrolyte for SOFCs. Synthesis of functional nanoparticles is a challenge in the nanotechnology. In this work, apatite-type lanthanum silicate nanoparticles were synthesized by a water-based sol–gel process, i.e., sol–gel technique followed by chemical precipitation of lanthanum hydroxide on the gel of the silica. Na{sub 2}SiO{sub 3} waste solution was used as silica source. Spherical aerogel silica was prepared by acid catalyzed reaction, followed by precipitation of lanthanum hydroxide to obtain the precursor of apatite-type lanthanum silicate. Powders of apatite-type lanthanum silicate achieved from the precursor were characterized by thermal analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and specific surface area measurements (BET). The apatite phase was formed at 900 °C.

  9. Structural and electrical properties of the sol-gel prepared Sr{sub 1-x}Er{sub x}SnO{sub 3-{delta}} compounds

    SciTech Connect (OSTI)

    Ouni, S.; Nouri, S. [Unite de Recherche de Chimie des Materiaux et de l'Environnement UR11ES25, ISSBAT, Universite de Tunis ElManar 9, Avenue Dr. Zoheir Safi, 1006 Tunis (Tunisia); Rohlicek, J. [Institute of Physics ASCR, v.v.i, Na Slovance 2, 18221 Prague 8 (Czech Republic); Ben Hassen, R., E-mail: rached.benhassen@fss.rnu.tn [Unite de Recherche de Chimie des Materiaux et de l'Environnement UR11ES25, ISSBAT, Universite de Tunis ElManar 9, Avenue Dr. Zoheir Safi, 1006 Tunis (Tunisia)

    2012-08-15

    Erbium-substituted strontium stannates, with Er content 0{<=}x{<=}0.09, have been prepared by sol-gel method. The solubility limit of Er was found to be about 3%. The influence of temperature and the duration of the calcination, on the confirmation of single phase of Er doped SrSnO{sub 3} were investigated by using X-ray powder diffraction. The distribution of Er{sup 3+} in the crystal structure has been studied. Rietveld refinement of the data revealed that the crystal structure of the representative compound (Sr{sub 0.97}Er{sub 0.03}SnO{sub 3-{delta}}) is orthorhombic perovskite (space group Pbnm). The cell dimensions are: a=5.7152(1) A, b=5.7092(1) A and c=8.0710(2) A. The IR spectroscopy measurements of the samples with x{<=}0.03 were done in a wavelength range 400-2000 cm{sup -1} and confirmed the observed tilting in the SnO{sub 6} octahedra. The transport properties in the system Sr{sub 1-x}Er{sub x}SnO{sub 3-{delta}}, x{<=}0.03, were investigated at high temperature. The Sr{sub 0.97}Er{sub 0.03}SnO{sub 3-{delta}} compound exhibits semiconductive behaviour and the electrical transport mechanism agrees with the non-adiabatic small polaron hopping model between nominal states Sn{sup 4+}/Sn{sup 2+} in the temperature ranges 350-525 and 525-693 K separately. - Graphical abstract: The Sr{sub 0.97}Er{sub 0.03}SnO{sub 3-{delta}} compound exhibits semiconductive behaviour and the electrical transport mechanism agrees with the non-adiabatic small polaron hopping model between nominal states Sn{sup 4+}/Sn{sup 2+}. Highlights: Black-Right-Pointing-Pointer Er showed a maximum solubility of 3 mol% in SrSnO{sub 3} perovskite at 1173 K. Black-Right-Pointing-Pointer SnO{sub 6} octahedra in Sr{sub 1-x}Er{sub x}SnO{sub 3-{delta}} are tilted. Black-Right-Pointing-Pointer The expansion of the cell parameters ascribed to the apparition of Sn{sup 2+} ions. Black-Right-Pointing-Pointer Transport mechanism in Sr{sub 0.97}Er{sub 0.03}SnO{sub 3-{delta}} agrees with the non-adiabatic small polaron hopping model.

  10. COMMENTARY:Limits to adaptation

    SciTech Connect (OSTI)

    Preston, Benjamin L

    2013-01-01

    An actor-centered, risk-based approach to defining limits to social adaptation provides a useful analytic framing for identifying and anticipating these limits and informing debates over society s responses to climate change.

  11. Synthesis of CdS/CdSe core/shell ultra small nanostructures using new microwave assisted ultrasonic sol gel route

    SciTech Connect (OSTI)

    Goswami, Y. C., E-mail: y-goswami@yahoo.com; Kumar, Vijay, E-mail: y-goswami@yahoo.com [School of Physical Sciences, ITM University, Sithouli, Gwalior- 474001 (India); Sharma, Ranjana [Institute of Technology and Management, Sithouli, Gwalior- 474001 (India); Singh, Rajeev [Institute of Information Technology and Management, Sithouli, Gwalior, MP 474001 (India)

    2014-04-24

    Core-shell CdS/CdSe nanostructures have been synthesized by new microwave assisted ultrasonic sol gel route. The solution was obtained by dissolving cadmium acetate and Thiourea in the molar ratio 1:1 in Triethlioamine. The solution was Ultrasonically irradiated by Ultrasonic crystal at 40 Hz for 3 hours at 70°C. The sol was kept for another 24 hours for gel formation. Selenium dioxide was used as a selenium source and added separately. The gel was spin coated on Quartz and Glass slides followed by microwave heat treatment. The samples were characterized by structural morphological and optical characterization. XRD studies confirm the zinc blende phase of the CdS nanoparticles. The mean nanocrystal sizes calculated using Scherrer equation is ?1.2nm. Optical studies show the strong blue shift in the spectra due to very small size of the nanocrystals. TEM and HRTEM confirm the formation of core shell structures.

  12. Fabrication of CeO2 by sol-gel process based on microfluidic technology as an analog preparation of ceramic nuclear fuel microspheres

    E-Print Network [OSTI]

    Ye, Bin; Li, Jiaolong; Zhao, Zichen; Chang, Zhenqi; Serra, Christophe A

    2012-01-01

    Microfluidics integrated with sol-gel processes is introduced in preparing monodispersed MOX nuclear fuel microspheres using nonactive cerium as a surrogate for uranium or plutonium. The detailed information about microfluidic devices and sol-gel processes are provided. The effects of viscosity and flow rate of continuous and dispersed phase on size and size distribution of CeO2 microspheres have been investigated. A comprehensive characterization of the CeO2 microspheres has been conducted, including XRD pattern, SEM, density, size and size distribution. The size of prepared monodisperse particles can be controlled precisely in range of 10{\\mu}m to 1000{\\mu}m and the particle CV is below 3%.

  13. Fabrication of CeO2 by sol-gel process based on microfluidic technology as an analog preparation of ceramic nuclear fuel microspheres

    E-Print Network [OSTI]

    Bin Ye; Jilang Miao; Jiaolong Li; Zichen Zhao; Zhenqi Chang; Christophe A. Serra

    2012-12-15

    Microfluidics integrated with sol-gel processes is introduced in preparing monodispersed MOX nuclear fuel microspheres using nonactive cerium as a surrogate for uranium or plutonium. The detailed information about microfluidic devices and sol-gel processes are provided. The effects of viscosity and flow rate of continuous and dispersed phase on size and size distribution of CeO2 microspheres have been investigated. A comprehensive characterization of the CeO2 microspheres has been conducted, including XRD pattern, SEM, density, size and size distribution. The size of prepared monodisperse particles can be controlled precisely in range of 10{\\mu}m to 1000{\\mu}m and the particle CV is below 3%.

  14. Promote the use of electric and hybrid vehicles through information dissemination & data collection through the NESEA American Tour de Sol. Final project report

    SciTech Connect (OSTI)

    2000-09-12

    A report on information dissemination on alternative fueled vehicles and on efficiency data collected at the NESEA American Tour de Sol is presented. Some of the latest advanced transportation technology vehicles were showcased. Numerous attachments are included, such as the post-event newsletter, press kit, publicity report, results table, technical workshop proceedings, NESEA tour rules and resources, and a paper titled ''Quantifying the fuel use and greenhouse gas reduction potential of electric and hybrid vehicles.''

  15. Tidal Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJThin Film Solar Technologies JumpTiSol Jump to: navigation,

  16. FUEL CASK IMPACT LIMITER VULNERABILITIES

    SciTech Connect (OSTI)

    Leduc, D; Jeffery England, J; Roy Rothermel, R

    2009-02-09

    Cylindrical fuel casks often have impact limiters surrounding just the ends of the cask shaft in a typical 'dumbbell' arrangement. The primary purpose of these impact limiters is to absorb energy to reduce loads on the cask structure during impacts associated with a severe accident. Impact limiters are also credited in many packages with protecting closure seals and maintaining lower peak temperatures during fire events. For this credit to be taken in safety analyses, the impact limiter attachment system must be shown to retain the impact limiter following Normal Conditions of Transport (NCT) and Hypothetical Accident Conditions (HAC) impacts. Large casks are often certified by analysis only because of the costs associated with testing. Therefore, some cask impact limiter attachment systems have not been tested in real impacts. A recent structural analysis of the T-3 Spent Fuel Containment Cask found problems with the design of the impact limiter attachment system. Assumptions in the original Safety Analysis for Packaging (SARP) concerning the loading in the attachment bolts were found to be inaccurate in certain drop orientations. This paper documents the lessons learned and their applicability to impact limiter attachment system designs.

  17. Decision-Making in Structure Solution using Bayesian Estimates of Map Quality: The PHENIX AutoSol Wizard

    SciTech Connect (OSTI)

    Terwilliger, T. C.; Adams, P. D.; Read, R. J.; McCoy, A. J.; Moriarty, Nigel W.; Grosse-Kunstleve, R. W.; Afonine, P. V.; Zwart, P. H.; Hung, L.-W.

    2009-03-01

    Estimates of the quality of experimental maps are important in many stages of structure determination of macromolecules. Map quality is defined here as the correlation between a map and the map calculated based on a final refined model. Here we examine 10 different measures of experimental map quality using a set of 1359 maps calculated by reanalysis of 246 solved MAD, SAD, and MIR datasets. A simple Bayesian approach to estimation of map quality from one or more measures is presented. We find that a Bayesian estimator based on the skew of histograms of electron density is the most accurate of the 10 individual Bayesian estimators of map quality examined, with a correlation between estimated and actual map quality of 0.90. A combination of the skew of electron density with the local correlation of rms density gives a further improvement in estimating map quality, with an overall correlation coefficient of 0.92. The PHENIX AutoSol Wizard carries out automated structure solution based on any combination of SAD, MAD, SIR, or MIR datasets. The Wizard is based on tools from the PHENIX package and uses the Bayesian estimates of map quality described here to choose the highest-quality solutions after experimental phasing.

  18. Effects of lithium doping on microstructure, electrical properties, and chemical bonds of sol-gel derived NKN thin films

    SciTech Connect (OSTI)

    Lin, Chun-Cheng; Chen, Chan-Ching; Weng, Chung-Ming; Chu, Sheng-Yuan; Tsai, Cheng-Che

    2015-02-28

    Highly (100/110) oriented lead-free Li{sub x}(Na{sub 0.5}K{sub 0.5}){sub 1?x}NbO{sub 3} (LNKN, x?=?0, 0.02, 0.04, and 0.06) thin films are fabricated on Pt/Ti/SiO{sub 2}/Si substrates via a sol-gel processing method. The lithium (Li) dopants modify the microstructure and chemical bonds of the LNKN films, and therefore improve their electrical properties. The optimal values of the remnant polarization (P{sub r}?=?14.3??C/cm{sup 2}), piezoelectric coefficient (d{sub 33}?=?48.1?pm/V), and leakage current (<10{sup ?5} A/cm{sup 2}) are obtained for a lithium addition of x?=?0.04 (i.e., 4 at.?%). The observation results suggest that the superior electrical properties are the result of an improved crystallization, a larger grain size, and a smoother surface morphology. It is shown that the ion transport mechanism is dominated by an Ohmic behavior under low electric fields and the Poole-Frenkel emission effect under high electric fields.

  19. Encapsulation of biomaterials in porous glass-like matrices prepared via an aqueous colloidal sol-gel process

    DOE Patents [OSTI]

    Liu, Dean-Mo (Richmond, CA); Chen, I-Wei (Swarthmore, PA)

    2001-01-01

    The present invention provides a process for the encapsulation of biologically important proteins into transparent, porous silica matrices by an alcohol-free, aqueous, colloidal sol-gel process, and to the biological materials encapsulated thereby. The process is exemplified by studies involving encapsulated cytochrome c, catalase, myoglobin, and hemoglobin, although non-proteinaceous biomaterials, such as active DNA or RNA fragments, cells or even tissues, may also be encapsulated in accordance with the present methods. Conformation, and hence activity of the biomaterial, is successfully retained after encapsulation as demonstrated by optical characterization of the molecules, even after long-term storage. The retained conformation of the biomaterial is strongly correlated to both the rate of gelation and the subsequent drying speed of the encapsulatng matrix. Moreover, in accordance with this process, gelation is accelerated by the use of a higher colloidal solid concentration and a lower synthesis pH than conventional methods, thereby enhancing structural stability and retained conformation of the biomaterials. Thus, the invention also provides a remarkable improvement in retaining the biological activity of the encapsulated biomaterial, as compared with those involved in conventional alkoxide-based processes. It further provides new methods for the quantitative and qualitative detection of test substances that are reactive to, or catalyzed by, the active, encapsulated biological materials.

  20. Lesson 8 Infinite Limits and One-sided Limits

    E-Print Network [OSTI]

    2013-09-06

    Sep 6, 2013 ... long-term behavior. A common model for the population of a species in an area is the logistic model: Lesson 8 Infinite Limits and One-sided ...

  1. Nuclear Structure at the Limits

    SciTech Connect (OSTI)

    Nazarewicz, W.

    1998-01-12

    One of the frontiers of today?s nuclear science is the ?journey to the limits? of atomic charge and nuclear mass, of neutron-to-proton ratio, and of angular momentum. The tour to the limits is not only a quest for new, exciting phenomena, but the new data are expected, as well, to bring qualitatively new information about the fundamental properties of the nucleonic many-body system, the nature of the nuclear interaction, and nucleonic correlations at various energy-distance scales. In this series of lectures, current developments in nuclear structure at the limits are discussed from a theoretical perspective, mainly concentrating on medium-mass and heavy nuclei.

  2. Nuclear Structure at the Limits

    SciTech Connect (OSTI)

    Nazarewicz, Witold

    1997-12-31

    One of the frontiers of today`s nuclear science is the ``journey to the limits``: of atomic charge and nuclear mass, of neutron-to-proton ratio, and of angular momentum. The tour to the limits is not only a quest for new, exciting phenomena but the new data are expected, as well, to bring qualitatively new information about the fundamental properties of the nucleonic many-body system, the nature of the nuclear interaction, and nucleonic correlations at various energy-distance scales. In this talk, current developments in nuclear structure at the limits are discussed from a theoretical perspective.

  3. Generalized Geometric Quantum Speed Limits

    E-Print Network [OSTI]

    Diego Paiva Pires; Marco Cianciaruso; Lucas C. Céleri; Gerardo Adesso; Diogo O. Soares-Pinto

    2015-09-30

    The attempt to gain a theoretical understanding of the concept of time in quantum mechanics has triggered significant progress towards the search for faster and more efficient quantum technologies. One of such advances consists in the interpretation of the time-energy uncertainty relations as lower bounds for the minimal evolution time between two distinguishable states of a quantum system, also known as quantum speed limits. We investigate how the non uniqueness of a bona fide measure of distinguishability defined on the quantum state space affects the quantum speed limits and can be exploited in order to derive improved bounds. Specifically, we establish an infinite family of quantum speed limits valid for unitary and nonunitary evolutions, based on an elegant information geometric formalism. Our work unifies and generalizes existing results on quantum speed limits, and provides instances of novel bounds which are tighter than any established one based on the conventional quantum Fisher information. We illustrate our findings with relevant examples, clarifying the role of classical populations versus quantum coherences in the determination and saturation of the speed limits. Our results can find applications in the optimization and control of quantum technologies such as quantum computation and metrology, and might provide new insights in fundamental investigations of quantum thermodynamics.

  4. Synthesis of BiSrCa(Y)CuO superconductor from the sol-gel method and the effect of Y substitution

    SciTech Connect (OSTI)

    Menassel, S.; Mosbah, M-F.; Altintas, S. P.; Varilci, A.; Bouaicha, F. [Universite Mentouri. Laboratoire Couches Minces et Interfaces. Route de Ain el Bey - 25017 Constantine (Algeria); Abant Izzet Baysal University. Department of Physics. 14280 Bolu. (Turkey)

    2012-09-06

    Superconducting Bi{sub 2}Sr{sub 2}Ca{sub 1-x}Y{sub x}Cu{sub 2}O{sub 8} ceramics samples have been prepared by Sol-Gel methods using citrate process. The influences of the conditions of preparation of oxide powder compound on structural and superconducting properties have been investigated by X ray diffraction (XRD), Scanning Electron Microscopy (SEM) equipped with EDS. The critical transition temperatures Tc have been determined by resistivity versus temperature measurements. Cell parameters samples were calculated from XRD patterns. The polyacryl amide gel makes the citrate process easier, more rapid and affords the possibility of synthesis of high quality oxide powders.

  5. Self-organized micro-holes on titania based sol-gel films under continuous direct writing with a continuous wave ultraviolet laser

    SciTech Connect (OSTI)

    Bakhti, S.; Destouches, N.; Gamet, E.; Reynaud, S. [University of Lyon, F. 42023 Saint-Etienne (France) [University of Lyon, F. 42023 Saint-Etienne (France); CNRS, UMR 5516, Laboratoire Hubert Curien, 18 Rue Pr. Lauras F-42000 Saint-Etienne (France); University of Saint-Etienne, Jean Monnet, F-42000 Saint-Etienne (France); Balan, L. [Institut de Sciences des Materiaux de Mulhouse, CNRS UMR 7361, Universite de Haute Alsace, 15 rue Jean Starcky, 68057 Mulhouse (France)] [Institut de Sciences des Materiaux de Mulhouse, CNRS UMR 7361, Universite de Haute Alsace, 15 rue Jean Starcky, 68057 Mulhouse (France)

    2013-05-27

    The microstructuring of titania based sol-gel films is investigated by direct writing with a continuous wave ultraviolet laser beam emitting at 244 nm. Depending on the exposure conditions, the films exhibit a volume expansion, a volume shrinkage, a self-shaped delamination, or are damaged. This paper is mainly focused on the regime where spontaneous local delamination occurs, which corresponds to a narrow range of laser irradiances and writing speeds. In this regime, self-organized round-shape micro-holes opened on the substrate are generated.

  6. Factory capacity limits Machine dependencies

    E-Print Network [OSTI]

    Foley, Simon

    Factory capacity limits Machine dependencies Employee scheduling Raw material availability Other internal operations (and also possibly the actions of other suppliers that supply raw materials) and at an international workshop at the multi-agent conference (AAMAS'06). Manufacturer Customer demand Penalties for non

  7. Sol–gel auto combustion synthesis of CoFe{sub 2}O{sub 4}/1-methyl-2-pyrrolidone nanocomposite with ethylene glycol: Its magnetic characterization

    SciTech Connect (OSTI)

    Topkaya, R.; Kurtan, U.; Junejo, Y.; Baykal, A.

    2013-09-01

    Graphical abstract: - Highlights: • CoFe{sub 2}O{sub 4} was generated by sol–gel autocombustion using 1-methyl-2-pyrrolidone and ethylene glycol. • The presence of spin-disordered surface layer on magnetic core was established. • A linear dependence of the coercivity on temperature was fitted to Kneller's law. - Abstract: Magnetic nanoparticles were generated by sol–gel auto combustion synthesis of metal salts in the presence of 1-methyl-2-pyrrolidone, a functional solvent and ethylene glycol as usual solvent. The average crystallite size was obtained by using line profile fitting as 11 ± 5 nm. The saturation magnetization value decreases with usage of the ethylene glycol in synthesis. The observed exchange bias effect further confirms the existence of the magnetically ordered core surrounded by spin-disordered surface layer and the ethylene glycol. Square-root temperature dependence of coercivity can be fitted to Kneller's law in the temperature range of 10–400 K. The reduced remanent magnetization values lower than the theoretical value of 0.5 for non-interacting single domain particles indicate the CoFe{sub 2}O{sub 4}-1-methyl-2-pyrrolidone nanocomposite to have uniaxial anisotropy instead of the expected cubic anisotropy according to the Stoner–Wohlfarth model.

  8. Sol–gel auto-combustion synthesis of PVP/CoFe{sub 2}O{sub 4} nanocomposite and its magnetic characterization

    SciTech Connect (OSTI)

    Kurtan, U.; Topkaya, R.; Baykal, A.

    2013-11-15

    Graphical abstract: - Highlights: • The Poly(vinyl pyrrolidone) (PVP) was used as a surface capping agent. • PVP/CoFe{sub 2}O{sub 4} nanocomposite was synthesized by a sol-gel auto-combustion method. • The existence of the spin-disordered surface layer was established. - Abstract: Poly(vinyl pyrrolidone)/CoFe{sub 2}O{sub 4} nanocomposite has been fabricated by a sol–gel auto-combustion method. Poly(vinyl pyrrolidone) was used as a reducing agent as well as a surface capping agent to prevent particle aggregation and stabilize the particles. The average crystallite size estimated from X-ray line profile fitting was found to be 20 ± 7 nm. The high field irreversibility and unsaturated magnetization behaviours indicate the presence of the core–shell structure in the sample. The exchange bias effect observed at 10 K suggests the existence of the magnetically aligned core surrounded by spin-disordered surface layer. The reduced remanent magnetization value of 0.6 at 10 K (higher than the theoretical value of 0.5) shows the PVP/CoFe{sub 2}O{sub 4} nanocomposite to have cubic magnetocrystalline anisotropy according to the Stoner–Wohlfarth model.

  9. Effect of cerium on structure modifications of a hybrid sol–gel coating, its mechanical properties and anti-corrosion behavior

    SciTech Connect (OSTI)

    Cambon, Jean-Baptiste, E-mail: cambon@chimie.ups-tlse.fr [Institut Carnot CIRIMAT, Université de Toulouse, UMR CNRS 5085, 118 Route de Narbonne, 31062 Toulouse Cedex 9 (France)] [Institut Carnot CIRIMAT, Université de Toulouse, UMR CNRS 5085, 118 Route de Narbonne, 31062 Toulouse Cedex 9 (France); Esteban, Julien; Ansart, Florence; Bonino, Jean-Pierre; Turq, Viviane [Institut Carnot CIRIMAT, Université de Toulouse, UMR CNRS 5085, 118 Route de Narbonne, 31062 Toulouse Cedex 9 (France)] [Institut Carnot CIRIMAT, Université de Toulouse, UMR CNRS 5085, 118 Route de Narbonne, 31062 Toulouse Cedex 9 (France); Santagneli, S.H.; Santilli, C.V.; Pulcinelli, S.H. [Departamento F?sico-Química, Instituto de Química, Universidade Estadual Paulista, UNESP, CP 355, 14801-970 Araraquara, SP (Brazil)] [Departamento F?sico-Química, Instituto de Química, Universidade Estadual Paulista, UNESP, CP 355, 14801-970 Araraquara, SP (Brazil)

    2012-11-15

    Highlights: ? New sol–gel routes to replace chromates for corrosion protection of aluminum. ? Effect of cerium concentration on the microstructure of xerogel. ? Electrochemical and mechanical performances of hybrid coating with different cerium contents. ? Good correlation between the different results with an optimal cerium content of 0.01 M. -- Abstract: An organic–inorganic hybrid coating was developed to improve the corrosion resistance of the aluminum alloy AA 2024-T3. Organic and inorganic coatings derived from glycidoxypropyl-trimethoxysilane (GPTMS) and aluminum tri-sec-butoxide Al(O{sup s}Bu){sub 3}, with different cerium contents, were deposited onto aluminum by dip-coating process. Corrosion resistance and mechanical properties were investigated by electrochemical impedance measurements and nano-indentation respectively. An optimal cerium concentration of 0.01 M was evidenced. To correlate and explain the hybrid coating performances in relation to the cerium content, NMR experiments were performed. It has been shown that when the cerium concentration in the hybrid is higher than 0.01 M there are important modifications in the hybrid structure that account for the mechanical properties and anti-corrosion behavior of the sol–gel coating.

  10. Methods for and products of processing nanostructure nitride, carbonitride and oxycarbonitride electrode power materials by utilizing sol gel technology for supercapacitor applications

    DOE Patents [OSTI]

    Huang, Yuhong (West Hills, CA); Wei, Oiang (West Hills, CA); Chu, Chung-tse (Chatsworth, CA); Zheng, Haixing (Oak Park, CA)

    2001-01-01

    Metal nitride, carbonitride, and oxycarbonitride powder with high surface area (up to 150 m.sup.2 /g) is prepared by using sol-gel process. The metal organic precursor, alkoxides or amides, is synthesized firstly. The metal organic precursor is modified by using unhydrolyzable organic ligands or templates. A wet gel is formed then by hydrolysis and condensation process. The solvent in the wet gel is then be removed supercritically to form porous amorphous hydroxide. This porous hydroxide materials is sintered to 725.degree. C. under the ammonia flow and porous nitride powder is formed. The other way to obtain high surface area nitride, carbonitride, and oxycarbonitride powder is to pyrolyze polymerized templated metal amides aerogel in an inert atmosphere. The electrochemical capacitors are prepared by using sol-gel prepared nitride, carbonitride, and oxycarbonitride powder. Two methods are used to assemble the capacitors. Electrode is formed either by pressing the mixture of nitride powder and binder to a foil, or by depositing electrode coating onto metal current collector. The binder or coating is converted into a continuous network of electrode material after thermal treatment to provide enhanced energy and power density. Liquid electrolyte is soaked into porous electrode. The electrochemical capacitor assembly further has a porous separator layer between two electrodes/electrolyte and forming a unit cell.

  11. Photocatalytic degradation of gaseous toluene over TiO{sub 2}-SiO{sub 2} composite nanotubes synthesized by sol-gel with template technique

    SciTech Connect (OSTI)

    Zou, Xuejun [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China)] [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China); Li, Xinyong, E-mail: xyli@dlut.edu.cn [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China) [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China); Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Qu, Zhenping; Zhao, Qidong; Shi, Yong; Chen, Yongying [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China)] [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China); Tade, Moses [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Liu, Shaomin, E-mail: shaomin.liu@curtin.edu.au [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)

    2012-02-15

    Graphical abstract: TiO{sub 2}-SiO{sub 2} nanotubes (b) were fabricated by sol-gel method using ZnO nanowires (a) as template. Highlights: Black-Right-Pointing-Pointer A simple method to prepare TiO{sub 2}-SiO{sub 2} nanotubes for photocatalytic toluene removal. Black-Right-Pointing-Pointer The TiO{sub 2}-SiO{sub 2} nanotubes have a small blue shift and higher absorption intensity. Black-Right-Pointing-Pointer The TiO{sub 2}-SiO{sub 2} nanotubes have an enhanced photoactivity in degrading gaseous toluene. -- Abstract: TiO{sub 2}-SiO{sub 2} composite nanotubes were successfully synthesized by a facile sol-gel technique utilizing ZnO nanowires as template. The nanotubes were well characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, N{sub 2} adsorption-desorption analysis and UV-vis diffuse reflectance spectroscopy. The nanotubular TiO{sub 2}-SiO{sub 2} composite photocatalysts showed diameter of 300-325 nm, fine mesoporous structure and high specific surface area. The results indicated that the degradation efficiency of gaseous toluene could get 65% after 4 h reaction using the TiO{sub 2}-SiO{sub 2} composite as the photocatalyst under UV light illumination, which was higher than that of P25.

  12. Sol–gel synthesis of SnO{sub 2}–MgO nanoparticles and their photocatalytic activity towards methylene blue degradation

    SciTech Connect (OSTI)

    Bayal, Nisha; Jeevanandam, P.

    2013-10-15

    Graphical abstract: - Highlights: • A simple sol–gel method for the synthesis of SnO{sub 2}–MgO nanoparticles is reported. • Band gap of SnO{sub 2} can be tuned by varying the magnesium content in SnO{sub 2}–MgO. • SnO{sub 2}–MgO shows good photocatalytic activity towards degradation of methylene blue. - Abstract: SnO{sub 2}–MgO mixed metal oxide nanoparticles were prepared by a simple sol–gel method. The nanoparticles were characterized by power X-ray diffraction, scanning electron microscopy coupled with energy dispersive X-ray analysis, transmission electron microscopy and UV–vis diffuse reflectance spectroscopy. The XRD results indicate the formation of mixed metal oxide nanoparticles and also a decrease of SnO{sub 2} crystallite size in the mixed metal oxide nanoparticles with increasing magnesium oxide content. The reflectance spectroscopy results show a blue shift of the band gap of SnO{sub 2} in the mixed metal oxide nanoparticles. The photocatalytic activity of the SnO{sub 2}–MgO nanoparticles was tested using the photodegradation of aqueous methylene blue in the presence of sunlight. The results indicate that the mixed metal oxide nanoparticles possess higher efficiency for the photodegradation of methylene blue compared to pure SnO{sub 2} nanoparticles.

  13. Axions - Motivation, limits and searches

    E-Print Network [OSTI]

    Georg G. Raffelt

    2006-11-09

    The axion solution of the strong CP problem provides a number of possible windows to physics beyond the standard model, notably in the form of searches for solar axions and for galactic axion dark matter, but in a broader context also inspires searches for axion-like particles in pure laboratory experiments. We briefly review the motivation for axions, astrophysical limits, their possible cosmological role, and current searches for axions and axion-like particles.

  14. Fundamental Limits to Cellular Sensing

    E-Print Network [OSTI]

    Pieter Rein ten Wolde; Nils B. Becker; Thomas E. Ouldridge; A. Mugler

    2015-05-25

    In recent years experiments have demonstrated that living cells can measure low chemical concentrations with high precision, and much progress has been made in understanding what sets the fundamental limit to the precision of chemical sensing. Chemical concentration measurements start with the binding of ligand molecules to receptor proteins, which is an inherently noisy process, especially at low concentrations. The signaling networks that transmit the information on the ligand concentration from the receptors into the cell have to filter this noise extrinsic to the cell as much as possible. These networks, however, are also stochastic in nature, which means that they will also add noise to the transmitted signal. In this review, we will first discuss how the diffusive transport and binding of ligand to the receptor sets the receptor correlation time, and then how downstream signaling pathways integrate the noise in the receptor state; we will discuss how the number of receptors, the receptor correlation time, and the effective integration time together set a fundamental limit on the precision of sensing. We then discuss how cells can remove the receptor noise while simultaneously suppressing the intrinsic noise in the signaling network. We describe why this mechanism of time integration requires three classes of resources---receptors and their integration time, readout molecules, energy---and how each resource class sets a fundamental sensing limit. We also briefly discuss the scheme of maximum-likelihood estimation, the role of receptor cooperativity, and how cellular copy protocols differ from canonical copy protocols typically considered in the computational literature, explaining why cellular sensing systems can never reach the Landauer limit on the optimal trade-off between accuracy and energetic cost.

  15. United Biofuels Private Limited | Open Energy Information

    Open Energy Info (EERE)

    United Biofuels Private Limited Jump to: navigation, search Name: United Biofuels Private Limited Place: Tamil Nadu, India Sector: Biomass Product: India-based owner and operator...

  16. DE-SOL-0001379

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate CharacterizationTBD1379 TABLE

  17. DE-SOL-0003641

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate

  18. DE-SOL-0005388

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate12/21/2012 000001 3 1

  19. DE-SOL-0005395

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate12/21/2012 000001 3 15395

  20. DE-SOL-0005388

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    needed for in-depth understanding and analysis of the energy-economic system of the United States, conventional and advanced energy technologies, and energy-related...

  1. DE-SOL-0008448

    National Nuclear Security Administration (NNSA)

    Deterence and Detection, "Design, Integration, Construction, Communication and Engineering 2" Acquisition Letter of Commitment to Accept Key Personnel Position. This letter...

  2. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    corrected in amendment 000002. 12. Question 12: RFP Reference: Section L-13 (a) The Internet NNSS website Reading Room, Labor Agreements Question: Will the government release all...

  3. DE-SOL-0005982

    National Nuclear Security Administration (NNSA)

    2 EQUIPMENT - HANDHELD COMPUTER - WIRELESS WHEEL LOAD SYSTEM 1 EQUIPMENT - HEAT STRESS MONITOR 5 EQUIPMENT - HOIST - PORTABLE 1 EQUIPMENT - HOMOGENIZER 1 EQUIPMENT - HPGI 1...

  4. DE-SOL-0008448

    National Nuclear Security Administration (NNSA)

    offeror shall submit evidence to substantiate the authority of the person signing the offer and submit in Volume I of the proposal. CERTIFICATE I, ...

  5. DE-SOL-0005395

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cross-cutting support to ORD R&D activities. CLIN 1 comprises the following work functions: A. Research Services. Although any of the functions of Research Services may take...

  6. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    and effect . 11132015 Signature on File ITEM NO. SUPPLIESSERVICES QUANTITY UNIT UNIT PRICE AMOUNT NAME OF OFFEROR OR CONTRACTOR 2 2 CONTINUATION SHEET REFERENCE NO. OF DOCUMENT...

  7. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    and effect . 12102015 Signature on File ITEM NO. SUPPLIESSERVICES QUANTITY UNIT UNIT PRICE AMOUNT NAME OF OFFEROR OR CONTRACTOR 2 3 CONTINUATION SHEET REFERENCE NO. OF DOCUMENT...

  8. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReporteeo | National/%2A en Office of CounterterrorismEvents0/2015

  9. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReporteeo | National/%2A en Office of

  10. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReporteeo | National/%2A en Office ofAmendment 000002 1 Questions

  11. DE-SOL-0008418

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReporteeo | National/%2A en Office ofAmendment 000002 1

  12. DE-SOL-0008448

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia National 1 PAGE 1 OF2Guidance to

  13. DE-SOL-0008449

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia National 1 PAGE 1 OF2Guidance to [Submit in Volume II,

  14. Hudol Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources JumpNewTexas: Energy Resources Jump to:Huber Heights,Hudol Limited

  15. Novacem Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg, Oregon: EnergyNongqishiCleanAlinca AgricolaNovacem Limited

  16. Hestiun Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen River PowerHeckert BXTHengyuanUmweltHestiun Limited Jump

  17. Plaxica Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly SmartDB-2, Blue MountainSchool DistrictPlaxica Limited Jump to:

  18. Dose Limits | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8,Department of2 Federal Register / Vol.DollarDorm RoomLimits

  19. Energy-limited escape revised

    E-Print Network [OSTI]

    Salz, M; Czesla, S; Schmitt, J H M M

    2015-01-01

    Gas planets in close proximity to their host stars experience photoevaporative mass loss. The energy-limited escape concept is generally used to derive estimates for the planetary mass-loss rates. Our photoionization hydrodynamics simulations of the thermospheres of hot gas planets show that the energy-limited escape concept is valid only for planets with a gravitational potential lower than $\\log_\\mathrm{10}\\left( -\\Phi_{\\mathrm{G}}\\right) < 13.11~$erg$\\,$g$^{-1}$ because in these planets the radiative energy input is efficiently used to drive the planetary wind. Massive and compact planets with $\\log_\\mathrm{10}\\left( -\\Phi_{\\mathrm{G}}\\right) \\gtrsim 13.6~$erg$\\,$g$^{-1}$ exhibit more tightly bound atmospheres in which the complete radiative energy input is re-emitted through hydrogen Ly$\\alpha$ and free-free emission. These planets therefore host hydrodynamically stable thermospheres. Between these two extremes the strength of the planetary winds rapidly declines as a result of a decreasing heating eff...

  20. Tau-neutrino mass limit

    E-Print Network [OSTI]

    Baringer, Philip S.

    1987-05-01

    was supported in part by the U.S. Depart- ment of Energy under Contracts Nos. W-31-109-Eng-38, DE-AC02-76ER011 12, DE-AC03-76S F000998, DE- AC02-76ER01428, and DE-AC02-84ER40125. This ex- periment was made possible by the support provided by the SLAC PEP staff... articles is followed, and page proofs are sent to authors. Tau-neutrino mass limit S. Abachi, P. Baringer, B. G. Bylsma, R. De Bonte, D. Koltick, F. J. Loeffler, E. H. Low, R. L. McIlwain, D. H. Miller, C. R. Ng, L. K. Rangan, and E. I. Shibata Purdue...

  1. Physics of the Shannon Limits

    E-Print Network [OSTI]

    Merhav, Neri

    2009-01-01

    We provide a simple physical interpretation, in the context of the second law of thermodynamics, to the information inequality (a.k.a. the Gibbs' inequality, which is also equivalent to the log-sum inequality), asserting that the relative entropy between two probability distributions cannot be negative. Since this inequality stands at the basis of the data processing theorem (DPT), and the DPT in turn is at the heart of most, if not all, proofs of converse theorems in Shannon theory, it is observed that conceptually, the roots of fundamental limits of Information Theory can actually be attributed to the laws of physics, in particular, to the second law of thermodynamics, and at least indirectly, also to the law of energy conservation. By the same token, in the other direction: one can view the second law as stemming from information-theoretic principles.

  2. The limits of filopodium stability

    E-Print Network [OSTI]

    Sander Pronk; Phillip L. Geissler; Daniel A. Fletcher

    2008-03-03

    Filopodia are long, finger-like membrane tubes supported by cytoskeletal filaments. Their shape is determined by the stiffness of the actin filament bundles found inside them and by the interplay between the surface tension and bending rigidity of the membrane. Although one might expect the Euler buckling instability to limit the length of filopodia, we show through simple energetic considerations that this is in general not the case. By further analyzing the statics of filaments inside membrane tubes, and through computer simulations that capture membrane and filament fluctuations, we show under which conditions filopodia of arbitrary lengths are stable. We discuss several in vitro experiments where this kind of stability has already been observed. Furthermore, we predict that the filaments in long, stable filopodia adopt a helical shape.

  3. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, Daniel M.; Rosen, Robert S.

    2005-04-19

    A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.

  4. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, D.M.; Rosen, R.S.

    1998-06-30

    A cartridge primer is described which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML`s would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers. 10 figs.

  5. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Rosen, Robert S. (San Ramon, CA)

    1998-01-01

    A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.

  6. Mg{sub x}Zn{sub 1-x}O (x = 0-1) films fabricated by sol-gel spin coating

    SciTech Connect (OSTI)

    Caglar, Mujdat [Department of Physics, Faculty of Science, Anadolu University, 26470 Eskisehir (Turkey)] [Department of Physics, Faculty of Science, Anadolu University, 26470 Eskisehir (Turkey); Wu, Junshu; Li, Keyan [Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)] [Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China); Caglar, Yasemin; Ilican, Saliha [Department of Physics, Faculty of Science, Anadolu University, 26470 Eskisehir (Turkey)] [Department of Physics, Faculty of Science, Anadolu University, 26470 Eskisehir (Turkey); Xue, Dongfeng, E-mail: dfxue@chem.dlut.edu.cn [Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)] [Department of Materials Science and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012 (China)

    2010-03-15

    Mg{sub x}Zn{sub 1-x}O films were deposited onto the glass substrate by a sol-gel spin coating method. The drying and annealing temperatures were 300 and 500 {sup o}C in air. As x varies from 0 to 1, it was observed that the crystal structure is changed from wurtzite ZnO to cubic MgO. The morphology characterizations of these films were observed by scanning electron microscope. The randomly oriented hexagonal nanorods were gown on the glass surface when x = 0 and 0.25, which became disappeared with increasing Mg contents. The optical properties of these films were investigated by room-temperature photoluminescence (PL) and UV-vis absorption spectra, which show that the optical band gap and photoluminescence in the visible and UV regions can be ideally tuned by varying the Mg contents in the Mg{sub x}Zn{sub 1-x}O alloy films.

  7. Effects of diethanolamine on sol–gel–processed Cu{sub 2}ZnSnS{sub 4} photovoltaic absorber thin films

    SciTech Connect (OSTI)

    Kahraman, S. Çetinkaya, S.; Çetinkara, H.A.; Güder, H.S.

    2014-02-01

    Highlights: • DEA content significantly affected the crystal structure and the phase purity. • The films’ crystallite sizes increased with increasing DEA content. • Two different impurity levels were found for each film via R-T characteristics. • Under different illuminations, the n-Si/CZTS exhibited good photo-response. • The light on/off current ratios confirmed the photo-sensitivity of the junction. - Abstract: As a promising solar absorber, the Cu{sub 2}ZnSnS{sub 4} compound has been popular recently for the production of green and economical thin-film solar cells owing to the abundancy and non-toxicity of all the constituents. In this study, we have produced Cu{sub 2}ZnSnS{sub 4} films via the sol–gel technique. As a stabilizer, the effects of the diethanolamine on the properties of the films were investigated. The amount of diethanolamine significantly affected the crystal structure, crystallite sizes and phase purity of the films. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of phase-pure CZTS films. It was found that the film produced by using 2 ml of diethanolamine in sol exhibited pure CZTS phase, compact and dense morphology and enhanced photo-sensitivity. Light on/off current ratio of the n-Si/Cu{sub 2}ZnSnS{sub 4} junction was found to be 47 under 100 mW/cm{sup 2} of illumination. Electrical activation energies of the films were investigated and the variations were attributed to delocalized phonon states generating from the presence of other phases and lattice defects.

  8. Shear wall ultimate drift limits

    SciTech Connect (OSTI)

    Duffey, T.A.; Goldman, A.; Farrar, C.R.

    1994-04-01

    Drift limits for reinforced-concrete shear walls are investigated by reviewing the open literature for appropriate experimental data. Drift values at ultimate are determined for walls with aspect ratios ranging up to a maximum of 3.53 and undergoing different types of lateral loading (cyclic static, monotonic static, and dynamic). Based on the geometry of actual nuclear power plant structures exclusive of containments and concerns regarding their response during seismic (i.e.,cyclic) loading, data are obtained from pertinent references for which the wall aspect ratio is less than or equal to approximately 1, and for which testing is cyclic in nature (typically displacement controlled). In particular, lateral deflections at ultimate load, and at points in the softening region beyond ultimate for which the load has dropped to 90, 80, 70, 60, and 50 percent of its ultimate value, are obtained and converted to drift information. The statistical nature of the data is also investigated. These data are shown to be lognormally distributed, and an analysis of variance is performed. The use of statistics to estimate Probability of Failure for a shear wall structure is illustrated.

  9. Neural substrates of cognitive capacity limitations

    E-Print Network [OSTI]

    Buschman, Tim

    Cognition has a severely limited capacity: Adult humans can retain only about four items “in mind”. This limitation is fundamental to human brain function: Individual capacity is highly correlated with intelligence measures ...

  10. Graduate Program Time Limits and Work Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time Limits and Work Schedules Graduate Program Time Limits and Work Schedules Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive...

  11. FUNDAMENTAL PERFORMANCE LIMITS OF WIRELESS SENSOR NETWORKS

    E-Print Network [OSTI]

    Li, Baochun

    FUNDAMENTAL PERFORMANCE LIMITS OF WIRELESS SENSOR NETWORKS ZHIHUA HU, BAOCHUN LI Abstract. Understanding the fundamental performance limits of wireless sensor networks is critical towards. In addition to presenting the general results with respect to the maximum sustainable throughput of wireless

  12. Primordial magnetic field limits from cosmological data

    SciTech Connect (OSTI)

    Kahniashvili, Tina [McWilliams Center for Cosmology and Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Department of Physics, Laurentian University, Ramsey Lake Road, Sudbury, Ontario P3E 2C (Canada); Abastumani Astrophysical Observatory, Ilia State University, 2A Kazbegi Ave, Tbilisi, GE-0160 (Georgia); Tevzadze, Alexander G. [Abastumani Astrophysical Observatory, Ilia State University, 2A Kazbegi Ave, Tbilisi, GE-0160 (Georgia); Faculty of Exact and Natural Sciences, Tbilisi State University, 1 Chavchavadze Avenue, Tbilisi, GE-0128 (Georgia); Sethi, Shiv K. [McWilliams Center for Cosmology and Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Raman Research Institute, Sadashivanagar, Bangalore 560080 (India); Pandey, Kanhaiya [Raman Research Institute, Sadashivanagar, Bangalore 560080 (India); Ratra, Bharat [Department of Physics, Kansas State University, 116 Cardwell Hall, Manhattan, Kansas 66506 (United States)

    2010-10-15

    We study limits on a primordial magnetic field arising from cosmological data, including that from big bang nucleosynthesis, cosmic microwave background polarization plane Faraday rotation limits, and large-scale structure formation. We show that the physically relevant quantity is the value of the effective magnetic field, and limits on it are independent of how the magnetic field was generated.

  13. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, J.R.

    1997-02-04

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  14. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL)

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  15. Economic Growth, Physical Limits and Liveability

    E-Print Network [OSTI]

    Economic Growth, Physical Limits and Liveability: Can Metro Vancouver Achieve all Three? by Jeremy of Thesis: Economic Growth, Physical Limits and Liveability: Can Metro Vancouver Achieve all Three. The Local Energy scenario adds a local energy limit. For each scenario I assume continuous economic

  16. Optical sensing elements for nitrogen dioxide (NO.sub.2) gas detection, a sol-gel method for making the sensing elements and fiber optic sensors incorporating nitrogen dioxide gas optical sensing elements

    DOE Patents [OSTI]

    Mechery, Shelly John (Mississippi State, MS); Singh, Jagdish P. (Starkville, MS)

    2007-07-03

    A sensing element, a method of making a sensing element, and a fiber optic sensor incorporating the sensing element are described. The sensor can be used for the quantitative detection of NO.sub.2 in a mixture of gases. The sensing element can be made by incorporating a diazotizing reagent which reacts with nitrous ions to produce a diazo compound and a coupling reagent which couples with the diazo compound to produce an azo dye into a sol and allowing the sol to form an optically transparent gel. The sensing element changes color in the presence of NO.sub.2 gas. The temporal response of the absorption spectrum at various NO.sub.2 concentrations has also been recorded and analyzed. Sensors having different design configurations are described. The sensing element can detect NO.sub.2 gas at levels of parts per billion.

  17. 1 0 N J I T M A G A Z I N E | F A L L 2 0 0 8 At the edge in solAr reseArch

    E-Print Network [OSTI]

    Bieber, Michael

    1 0 N J I T M A G A Z I N E | F A L L 2 0 0 8 At the edge in solAr reseArch The cool, calm water. But that's where NJIT operates one of the world's foremost solar- research facilities, on a narrow causeway jutting a thousand feet into the lake. Big Bear Solar Observatory (BBSO) has produced a wealth of data

  18. Time_Limit_Extension_Form.docx | Revised: 10/13/2014 Time Limit Extension Request Form

    E-Print Network [OSTI]

    Meyers, Steven D.

    Time_Limit_Extension_Form.docx | Revised: 10/13/2014 Time Limit Extension Request Form OFFICE on your request. PURPOSE The Time Limit Extension may be filed when a student nears the end of the time limitation for completion of the requirements for their degree but needs more time to complete the degree

  19. Basic category theory -Limits Gouter des doctorants

    E-Print Network [OSTI]

    Doyen, Laurent

    Basic category theory - Limits Gouter des doctorants Jérémy Dubut LSV, ENS Cachan Friday, 3rd April, 2015 Jérémy Dubut (LSV, ENS Cachan) Basic category theory - Limits Friday, 3rd April, 2015 1 / 8 #12 not necessarily exist Jérémy Dubut (LSV, ENS Cachan) Basic category theory - Limits Friday, 3rd April, 2015 2 / 8

  20. Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon...

    Office of Scientific and Technical Information (OSTI)

    Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint Bolen, M. L.; Grover, S.; Teplin, C. W.; Bobela, D.; Branz, H. M.; Stradins, P. 08 HYDROGEN; 14...

  1. Synthesis, characterization and application of sol-gel derived mesoporous TiO{sub 2} nanoparticles for dye-sensitized solar cells

    SciTech Connect (OSTI)

    Khan, M. Alam; Shaheer Akhtar, M.; Yang, O-Bong [School of Semiconductor and Chemical Engineering, Chonbuk National University, Dukjin Dong, Dukjingu, Jeon-ju (Korea, Republic of)

    2010-12-15

    Nanocrystalline mesoporous titania of anatase crystal phase were prepared by sol-gel route by varying calcination (400 C and 600 C) conditions, and the photo-electrochemical properties were investigated for dye-sensitized solar cell applications. The TTIP precursor in n-heptane solvent with ratio of water to TTIP (5:1) was found to be effective substrate for the working electrodes. The overall conversion efficiency of 7.59% was achieved under 1 sun irradiation with open circuit voltage of 0.77 V, current density of 17.00 mA/cm{sup 2} and FF of 51.12. The high efficiency of the 400 C calcined sample were attributed to its mesopores, high BET surface area (80.1 m{sup 2}/g) and large pore volume of prepared titania substrate which provide better surface for the absorption of dye, improves light harvesting efficiency and better charge injection. The prepared samples were characterized by XRD, small angle XRD, FE-SEM, TEM, IPCE, I-V curve, BET surface area and BJH plot techniques. (author)

  2. Annealing effects on structural, electrical and optical properties of antimony-tinoxide thin films deposited by sol gel dip coating technique

    SciTech Connect (OSTI)

    Lekshmy, S. Sujatha, E-mail: jolly2jolly@gmail.com; Anitha, V. S., E-mail: jolly2jolly@gmail.com; Berlin, I. John, E-mail: jolly2jolly@gmail.com; Joy, K., E-mail: jolly2jolly@gmail.com [Thin film Laboratory, Post Graduate and Research Department of Physics, Mar Ivanios College, Thiruvananthapuram 695 015 (India)

    2014-01-28

    Antimony-doped tin dioxide possess interesting physical and chemical properties. These properties have a wide range of applications such as catalysis and optoelectronic devices. In the present study, antimony-doped tin oxide (SnO2:Sb) thin films were deposited on the quartz substrates by sol-gel dip coating technique. The films were annealed at temperatures 350°C, 550°C and 850°C in air for 2 hours. The structure and surface morphologies were observed by X-ray diffraction (XRD) and Scanning electron microscopy (SEM). XRD patterns shows tetragonal structure for the SnO2:Sb films annealed at different temperatures. Crystallite size increased from 6 to 14 nm as annealing temperature increased from 350°C to 850°C. SEM studies reveals crack free and smooth surface for all the films. The grains are found to be homogenously distributed for films annealed at higher temperature. The electrical conductivity of the films annealed at 350°C and 550°C decreased and increased for the films annealed at 850°C. The optical properties of the films were investigated in the UV-visible-NIR region (200-900 nm) using UV spectra. The transmittance of the films decreased for films annealed at higher temperature. The optical energy band gap values (4.13 eV-4.83 eV) increased with the increase in annealing temperature.

  3. Limiting Emission Angle for Improved Solar Cell

    E-Print Network [OSTI]

    Limiting Emission Angle for Improved Solar Cell Performance While direct light enters a solar cell will explore the potential benefits to limiting the emission angles of realistic solar cells, with efficiencies cooling, waste heat recovery and solar electricity generation, low values of the thermoelectric figure

  4. Self-triggering superconducting fault current limiter

    DOE Patents [OSTI]

    Yuan, Xing (Albany, NY); Tekletsadik, Kasegn (Rexford, NY)

    2008-10-21

    A modular and scaleable Matrix Fault Current Limiter (MFCL) that functions as a "variable impedance" device in an electric power network, using components made of superconducting and non-superconducting electrically conductive materials. The matrix fault current limiter comprises a fault current limiter module that includes a superconductor which is electrically coupled in parallel with a trigger coil, wherein the trigger coil is magnetically coupled to the superconductor. The current surge doing a fault within the electrical power network will cause the superconductor to transition to its resistive state and also generate a uniform magnetic field in the trigger coil and simultaneously limit the voltage developed across the superconductor. This results in fast and uniform quenching of the superconductors, significantly reduces the burnout risk associated with non-uniformity often existing within the volume of superconductor materials. The fault current limiter modules may be electrically coupled together to form various "n" (rows).times."m" (columns) matrix configurations.

  5. Predetermining acceptable noise limits in EXAFS spectra in the limit of stochastic noise

    E-Print Network [OSTI]

    Hu, Yung-Jin

    2010-01-01

    Predetermining acceptable noise limits of EXAFS spectrain the limit of stochastic noise Yung-Jin Hu 1 and Corwin H.The e?ect of stochastic noise on Extended X-ray Absorption

  6. Limit of light coupling into solar cells

    E-Print Network [OSTI]

    Naqavi, A; Ballif, C; Scharf, T; Herzig, H P

    2013-01-01

    We introduce a limit for the strength of coupling light into the modes of solar cells. This limit depends on both a cell's thickness and its modal properties. For a cell with refractive index n and thickness d, we obtain a maximal coupling rate of 2c*sqrt(n^2-1)/d where c is speed of light. Our method can be used in the design of solar cells and in calculating their efficiency limits; besides, it can be applied to a broad variety of resonant phenomena and devices.

  7. Decoupling limits in multi-sector supergravities

    SciTech Connect (OSTI)

    Achúcarro, Ana; Hardeman, Sjoerd; Schalm, Koenraad; Aalst, Ted van der [Instituut-Lorentz for Theoretical Physics, Universiteit Leiden, Niels Bohrweg 2, Leiden (Netherlands); Oberreuter, Johannes M., E-mail: achucar@lorentz.leidenuniv.nl, E-mail: j.m.oberreuter@uva.nl, E-mail: kschalm@lorentz.leidenuniv.nl, E-mail: vdaalst@lorentz.leidenuniv.nl [Instituut voor Theoretische Fysica, Universiteit van Amsterdam, Science Park 904, Amsterdam (Netherlands)

    2013-03-01

    Conventional approaches to cosmology in supergravity assume the existence of multiple sectors that only communicate gravitationally. In principle these sectors decouple in the limit M{sub pl}??. In practice such a limit is delicate: for generic supergravities, where sectors are combined by adding their Kähler functions, the separate superpotentials must contain non-vanishing vacuum expectation values supplementing the naïve global superpotential. We show that this requires non-canonical scaling in the naïve supergravity superpotential couplings to recover independent sectors of globally supersymmetric field theory in the decoupling limit M{sub pl} ? ?.

  8. PP-206 Frontera Generation Limited Partnership | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PP-206 Frontera Generation Limited Partnership PP-206 Frontera Generation Limited Partnership Presidential permit authorizing Frontera Generation Limited Partnership to construct,...

  9. Representation of Limited Rights Data and Restricted Computer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data...

  10. Climate Prediction: The Limits of Ocean Models

    E-Print Network [OSTI]

    Stone, Peter H.

    We identify three major areas of ignorance which limit predictability in current ocean GCMs. One is the very crude representation of subgrid-scale mixing processes. These processes are parameterized with coefficients whose ...

  11. Performance limits of axial turbomachine stages

    E-Print Network [OSTI]

    Hall, David Kenneth

    2011-01-01

    This thesis assesses the limits of stage efficiency for axial compressor and turbine stages. A stage model is developed, consisting of a specified geometry and a surface velocity distribution with turbulent boundary layers. ...

  12. Infinite volume limit for the dipole gas

    E-Print Network [OSTI]

    J. Dimock

    2009-04-28

    We consider a classical dipole gas in with low activity and show that the pressure has a limit as the volume goes to infinity. The result is obtained by a renormalization group analysis of the model.

  13. Quantum Cryptography Approaching the Classical Limit

    E-Print Network [OSTI]

    Weedbrook, Christian

    We consider the security of continuous-variable quantum cryptography as we approach the classical limit, i.e., when the unknown preparation noise at the sender’s station becomes significantly noisy or thermal (even by as ...

  14. Some Fundamental Limitations for Cognitive Radio

    E-Print Network [OSTI]

    Sahai, Anant

    ' & $ % Some Fundamental Limitations for Cognitive Radio Anant Sahai Wireless Foundations, UCB EECS program November 1 at BWRC Cognitive Radio Workshop #12;' & $ % Outline 1. Why cognitive radios? 2 November 1 at BWRC Cognitive Radio Workshop #12;' & $ % Apparent spectrum allocations · Traditional

  15. Physical limits on cellular directional mechanosensing

    E-Print Network [OSTI]

    Bouffanais, Roland

    Many eukaryotic cells are able to perform directional mechanosensing by directly measuring minute spatial differences in the mechanical stress on their membranes. Here, we explore the limits of a single mechanosensitive ...

  16. Window in the dark matter exclusion limits

    SciTech Connect (OSTI)

    Zaharijas, Gabrijela; Farrar, Glennys R. [Center for Cosmology and Particle Physics, New York University, New York, New York 10003 (United States)

    2005-10-15

    We consider the cross section limits for light dark matter cadnidates (m=0.4 to 10 GeV). We calculate the interaction of dark matter in the crust above underground dark matter detectors and find that in the intermediate cross section range, the energy loss of dark matter is sufficient to fall below the energy threshold of current underground experiments. This implies the existence of a window in the dark matter exclusion limits in the micro-barn range.

  17. Inequality design limits in optimal aerodynamic shapes 

    E-Print Network [OSTI]

    Seaman, Charles Knight

    1968-01-01

    INEQUALITY DESIGN LIMITS IN OPTIMAL AERODYNAMIC SHAPES A Thesis By CHARLES KNIGHT SEAMAN Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1968... Major Subject: Aerospace Engineering INEQUALITY DESIGN LIMITS IN OPTIMAL AERODYNAMIC SHAPES A Thesis By CHARLES KNIGHT SEAMAN Approved as to style and content by: (Chairman of Committee) (Head of Department) (Member) (Member) May 1968...

  18. Meso-porous ?-Fe{sub 2}O{sub 3} thin films synthesized via the sol-gel process for light-driven water oxidation

    SciTech Connect (OSTI)

    Hamd, Wael; Laberty-Robert, Christel; Sanchez, Clement [Laboratoire de Chimie de la Matiere Condensee de Paris-UMR 7574, Universite Paris 6, College de France, 11 place Marcelin Berthelot 75005, Paris, (France); Cobo, Saioa; Fize, Jennifer; Artero, Vincent [Laboratoire de Chimie et Biologie des Metaux, Universite Grenoble 1, CNRS, CEA, 17 rue des Martyrs 38054, Grenoble Cedex 9, (France); Baldinozzi, Gianguido [SPMS, MFE, CNRS-Ecole Centrale Paris et CEA, DEN, DMN, 91191 Gif-sur-Yvette, (France); Schwartz, Wilfrid; Reymermier, Maryse; Pereira, Alexandre [CEA Institut Liten, DTNM/L2CE, 17 rue des Martyrs 38054, Grenoble Cedex 9, (France); Fontecave, Marc [Laboratoire de Chimie et Biologie des Metaux, Universite Grenoble 1, CNRS, CEA, 17 rue des Martyrs 38054, Grenoble Cedex 9, (France); SPMS, MFE, CNRS-Ecole Centrale Paris et CEA, DEN, DMN, 91191 Gif-sur-Yvette, (France)

    2012-07-01

    This work reports a facile and cost-effective method for synthesizing photoactive ?-Fe{sub 2}O{sub 3} films as well as their performances when used as photoanodes for water oxidation. Transparent ?-Fe{sub 2}O{sub 3} meso-porous films were fabricated by template-directed sol-gel chemistry coupled with the dip-coating approach, followed by annealing at various temperatures from 350 degrees C to 750 degrees C in air. ?-Fe{sub 2}O{sub 3} films were characterized by X-ray diffraction, XPS, FE-SEM and electrochemical measurements. The photoelectrochemical performance of ?-Fe{sub 2}O{sub 3} photoanodes was characterized and optimized through the deposition of Co-based co-catalysts via different methods (impregnation, electro-deposition and photo-electro-deposition). Interestingly, the resulting hematite films heat-treated at relatively low temperature (500 degrees C), and therefore devoid of any extrinsic dopant, achieve light-driven water oxidation under near-to-neutral (pH = 8) aqueous conditions after decoration with a Co catalyst. The onset potential is 0.75 V vs. the reversible hydrogen electrode (RHE), thus corresponding to 450 mV light-induced under potential, although modest photocurrent density values (40 ?Acm{sup -2}) are obtained below 1.23 V vs. RHE. These new materials with a very large interfacial area in contact with the electrolyte and allowing for a high loading of water oxidation catalysts open new avenues for the optimization of photo-electrochemical water splitting. (authors)

  19. Synthesis and Characterization of Self-assembled c-axis Oriented Bi2Sr3Co2Oy Thin Films by the Sol gel Method

    SciTech Connect (OSTI)

    Lei H.; Zhu, X.; Tang, X.; Shi, D.; Jian, H.; Yeoh, W.K.; Zhao, B.; Yang, J.; Li, Q.; Zheng, R.; Dou, S.; Sun, Y.

    2011-08-18

    Bi{sub 2}Sr{sub 3}Co{sub 2}Oy thin films are prepared on SrTiO{sub 3} (100), (110) and (111) single crystal substrates using the sol-gel method. All the thin films are c-axis oriented regardless of the orientation of the substrate suggesting self-assembled c-axis orientation, and X-ray photoelectron spectroscopy results give evidence of coexistence of Co{sup 3+} and Co{sup 2+} ions in the derived films. Transmission electronic microscopy observations reveal that all samples are c-axis oriented with no obvious differences for different samples, and the c-axis lattice constant is determined as 15 {angstrom} suggesting the misfit structure. A phenomenological thermodynamic phase diagram for self-assembled c-axis orientation is established for misfit cobaltate-based films using chemical solution deposition. All samples behave like semiconductors due to the coexistence of Co{sup 3+}/Co{sup 2+} ions, and the resistivity at 350 K is 47, 39 and 17 m{Omega} cm for the thin films on SrTiO{sub 3} (100), (110) and (111), respectively, whereas the Seebeck coefficient at 300 K is 97, 89 and 77 {micro}V K{sup -1}. The successful attainment of Bi{sub 2}Sr{sub 3}Co{sub 2}O{sub y} thin films with self-assembled c-axis orientation will provide an effective prototype for investigation of growth mechanisms in complex oxide thin films with a misfit structure.

  20. Cyclization phenomena in the sol-gel polymerization of {alpha},{omega}-bis(triethoxysilyl)alkanes and incorporation of the cyclic structures into network silsesquioxane polymers

    SciTech Connect (OSTI)

    Loy, D.A.; Carpenter, J.P.; Alam, T.M.; Shaltout, R. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Dorhout, P.K. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Chemistry] [Colorado State Univ., Fort Collins, CO (United States). Dept. of Chemistry; Greaves, J.; Shea, K.J. [Univ. of California, Irvine, CA (United States). Dept. of Chemistry] [Univ. of California, Irvine, CA (United States). Dept. of Chemistry; Small, J.H. [Los Alamos National Lab., NM (United States). Polymers and Coatings Group] [Los Alamos National Lab., NM (United States). Polymers and Coatings Group

    1999-06-16

    Intramolecular cyclizations during acid-catalyzed sol-gel polymerizations of {alpha},{omega}-bis(triethoxysilyl)alkanes substantially lengthen gel times for monomers with ethylene (1), propylene (2), and butylene (3) bridging groups. These cyclization reactions were found, using mass spectrometry and {sup 29}Si NMR spectroscopy, to lead preferentially to monomeric and dimeric products based on six- and seven-membered disilsesquioxane rings. 1,2-Bis(triethoxysilyl)ethane (1) reacts under acidic conditions to give a bicyclic dimer (5) that is composed of two annelated seven-membered rings. Under the same conditions, 1,3-bis(triethoxysilyl)propane (2), 1,4-bis(triethoxysilyl)butane (3), and Z-1,4-bis(triethoxysilyl)but-2-ene (10) undergo an intramolecular condensation reaction to give the six- and seven-membered cyclic disilsesquioxanes 6, 7, and 11. Subsequently, these cyclic monomers slowly react to form the tricyclic dimers 8, 9, and 12. With NaOH as polymerization catalyst, these cyclic silsesquioxanes readily reacted to afford gels that were shown by CP MAS {sup 29}Si NMR and infrared spectroscopies to retain some cyclic structures. Comparison of the porosity and microstructure of xerogels prepared from the cyclic monomers 6 and 7 with those of gels prepared directly from their acyclic precursors 2 and 3 indicates that the final pore structure of the xerogels is markedly dependent on the nature of the precursor. In addition, despite the fact that the monomeric cyclic disilsesquioxane species cannot be isolated from 1--3 under basic conditions due to their rapid rate of gelation, spectroscopic techniques also detected the presence of the cyclic structures in the resulting polymeric gels.

  1. Cyclization Phenomena in the Sol-Gel Polymerization of a,w-Bis(triethoxysilyl)alkanes and Incorporation of the Cyclic Structures into Network Silsesquioxane Polymers

    SciTech Connect (OSTI)

    Alam, T.M.; Carpenter, J.P.; Dorhout, P.K.; Greaves, J.; Loy, D.A.; Shaltout, R.; Shea, K.J.; Small, J.H.

    1999-01-04

    Intramolecular cyclizations during acid-catalyzed, sol-gel polymerizations of ct,co- bis(tietioxysilyl)aWmes substintidly lengtien gelties formonomers witietiylene- (l), propylene- (2), and butylene-(3)-bridging groups. These cyclizations reactions were found, using mass spectrometry and %i NMR spectroscopy, to lead preferentially to monomeric and dimeric products based on six and seven membered disilsesquioxane rings. 1,2- Bis(triethoxysilyl)ethane (1) reacts under acidic conditions to give a bicyclic drier (5) that is composed of two annelated seven membered rings. Under the same conditions, 1,3- bis(triethoxysilyl)propane (2), 1,4-bis(triethoxysilyl)butane (3), and z-1,4- bis(triethoxysilyl)but-2-ene (10) undergo an intramolecular condensation reaction to give the six membemd and seven membered cyclic disilsesquioxanes 6, 7, and 11. Subsequently, these cyclic monomers slowly react to form the tricyclic dirners 8,9 and 12. With NaOH as polymerization catalyst these cyclic silsesquioxanes readily ~aeted to afford gels that were shown by CP MAS z%i NMR and infr=d spectroscopes to retain some cyclic structures. Comparison of the porosity and microstructwe of xerogels prepared from the cyclic monomers 6 and 7 with gels prepared directly from their acyclic precursors 2 and 3, indicate that the final pore structure of the xerogels is markedly dependent on the nature of the precursor. In addition, despite the fact that the monomeric cyclic disilsesquioxane species can not be isolated from 1-3 under basic conditions due to their rapid rate of gelation, spectroscopic techniques also detected the presence of the cyclic structures in the resulting polymeric gels.

  2. Purchasing Department PCard Update Form Change Cardholder Limits

    E-Print Network [OSTI]

    Clayton, Dale H.

    : _____________________________ Current Monthly (Cycle) Limit:______________________________ Requested PCard Limits Requested Single Purchase Limit: ___________________________ Requested Monthly (Cycle) Limit) __________________________________________________________________________________________________ University of Utah Purchasing Department | 1901 E South Campus Drive, Room 151 | SLC UT 84112 Phone: 801

  3. A brightness exceeding simulated Langmuir limit

    SciTech Connect (OSTI)

    Nakasuji, Mamoru

    2013-08-15

    When an excitation of the first lens determines a beam is parallel beam, a brightness that is 100 times higher than Langmuir limit is measured experimentally, where Langmuir limits are estimated using a simulated axial cathode current density which is simulated based on a measured emission current. The measured brightness is comparable to Langmuir limit, when the lens excitation is such that an image position is slightly shorter than a lens position. Previously measured values of brightness for cathode apical radii of curvature 20, 60, 120, 240, and 480 ?m were 8.7, 5.3, 3.3, 2.4, and 3.9 times higher than their corresponding Langmuir limits, respectively, in this experiment, the lens excitation was such that the lens and the image positions were 180 mm and 400 mm, respectively. From these measured brightness for three different lens excitation conditions, it is concluded that the brightness depends on the first lens excitation. For the electron gun operated in a space charge limited condition, some of the electrons emitted from the cathode are returned to the cathode without having crossed a virtual cathode. Therefore, method that assumes a Langmuir limit defining method using a Maxwellian distribution of electron velocities may need to be revised. For the condition in which the values of the exceeding the Langmuir limit are measured, the simulated trajectories of electrons that are emitted from the cathode do not cross the optical axis at the crossover, thus the law of sines may not be valid for high brightness electron beam systems.

  4. The characteristic of carbon-coated LiFePO{sub 4} as cathode material for lithium ion battery synthesized by sol-gel process in one step heating and varied pH

    SciTech Connect (OSTI)

    Triwibowo, J.; Yuniarti, E.; Suharyadi, E.

    2014-09-25

    This research has been done on the synthesis of carbon coated LiFePO{sub 4} through sol-gel process. Carbon layer serves for improving electronic conductivity, while the variation of pH in the sol-gel process is intended to obtain the morphology of the material that may improve battery performance. LiFePO{sub 4}/C precursors are Li{sub 2}CO{sub 3}, NH{sub 4}H{sub 2}PO{sub 4} and FeC{sub 2}O{sub 4}.H{sub 2}O and citric acid. In the synthesis process, consisting of a colloidal suspension FeC{sub 2}O{sub 4}.H{sub 2}O and distilled water mixed with a colloidal suspension consisting of NH{sub 4}H{sub 2}PO{sub 4}, Li{sub 2}CO{sub 3}, and distilled water. Variations addition of citric acid is used to control the pH of the gel formed by mixing two colloidal suspensions. Sol in this study had a pH of 5, 5.4 and 5.8. The obtained wet gel is further dried in the oven and then sintered at a temperature 700°C for 10 hours. The resulting material is further characterized by XRD to determine the phases formed. The resulting powder morphology is observed through SEM. Specific surface area of the powder was tested by BET, while the electronic conductivity characterized with EIS.

  5. Defining coiled tubing limits -- A new approach

    SciTech Connect (OSTI)

    Newman, K.R.; Sathuvalli, U.B.; Stone, L.R.; Wolhart, S.

    1996-12-31

    The burst, collapse and axial load operating limits for Coiled Tubing (CT) are currently established using the Von Mises incipient yield criterion. This criterion has historically been used to calculate the limits for oil country tubular goods (OCTG). The limits according to this criterion are based on the point at which the pipe material reaches a load state in which it begins to yield. Because of the bending that occurs when the CT is spooled on and off the reel, and when it is bent over the guide arch, the CT is already far beyond the yield point before it enters a well. Thus, this criterion does not really apply to CT. This paper describes a research project currently in progress. The purpose of this project is to define a new set of CT limits based on criteria other than incipient yield. This new approach to setting CT operating limits takes into account the internal residual stresses in the CT which are a consequence of repeated bending cycles and the accompanying change in material properties.

  6. Fundamental limitations for quantum and nano thermodynamics

    E-Print Network [OSTI]

    Micha? Horodecki; Jonathan Oppenheim

    2014-10-25

    The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when quantum effects become important. Applying results from quantum information theory we construct a theory of thermodynamics in these limits. We derive general criteria for thermodynamical state transformations, and as special cases, find two free energies: one that quantifies the deterministically extractable work from a small system in contact with a heat bath, and the other that quantifies the reverse process. We find that there are fundamental limitations on work extraction from nonequilibrium states, owing to finite size effects and quantum coherences. This implies that thermodynamical transitions are generically irreversible at this scale. As one application of these methods, we analyse the efficiency of small heat engines and find that they are irreversible during the adiabatic stages of the cycle.

  7. Multiple soft limits of cosmological correlation functions

    SciTech Connect (OSTI)

    Joyce, Austin; Khoury, Justin; Simonovi?, Marko E-mail: jkhoury@sas.upenn.edu

    2015-01-01

    We derive novel identities satisfied by inflationary correlation functions in the limit where two external momenta are taken to be small. We derive these statements in two ways: using background-wave arguments and as Ward identities following from the fixed-time path integral. Interestingly, these identities allow us to constrain some of the O(q{sup 2}) components of the soft limit, in contrast to their single-soft analogues. We provide several nontrivial checks of our identities both in the context of resonant non-Gaussianities and in small sound speed models. Additionally, we extend the relation at lowest order in external momenta to arbitrarily many soft legs, and comment on the many-soft extension at higher orders in the soft momentum. Finally, we consider how higher soft limits lead to identities satisfied by correlation functions in large-scale structure.

  8. ON COMPUTING UPPER LIMITS TO SOURCE INTENSITIES

    SciTech Connect (OSTI)

    Kashyap, Vinay L.; Siemiginowska, Aneta [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Van Dyk, David A.; Xu Jin [Department of Statistics, University of California, Irvine, CA 92697-1250 (United States); Connors, Alanna [Eureka Scientific, 2452 Delmer Street, Suite 100, Oakland, CA 94602-3017 (United States); Freeman, Peter E. [Department of Statistics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213 (United States); Zezas, Andreas, E-mail: vkashyap@cfa.harvard.ed, E-mail: asiemiginowska@cfa.harvard.ed, E-mail: dvd@ics.uci.ed, E-mail: jinx@ics.uci.ed, E-mail: aconnors@eurekabayes.co, E-mail: pfreeman@cmu.ed, E-mail: azezas@cfa.harvard.ed [Physics Department, University of Crete, P.O. Box 2208, GR-710 03, Heraklion, Crete (Greece)

    2010-08-10

    A common problem in astrophysics is determining how bright a source could be and still not be detected in an observation. Despite the simplicity with which the problem can be stated, the solution involves complicated statistical issues that require careful analysis. In contrast to the more familiar confidence bound, this concept has never been formally analyzed, leading to a great variety of often ad hoc solutions. Here we formulate and describe the problem in a self-consistent manner. Detection significance is usually defined by the acceptable proportion of false positives (background fluctuations that are claimed as detections, or Type I error), and we invoke the complementary concept of false negatives (real sources that go undetected, or Type II error), based on the statistical power of a test, to compute an upper limit to the detectable source intensity. To determine the minimum intensity that a source must have for it to be detected, we first define a detection threshold and then compute the probabilities of detecting sources of various intensities at the given threshold. The intensity that corresponds to the specified Type II error probability defines that minimum intensity and is identified as the upper limit. Thus, an upper limit is a characteristic of the detection procedure rather than the strength of any particular source. It should not be confused with confidence intervals or other estimates of source intensity. This is particularly important given the large number of catalogs that are being generated from increasingly sensitive surveys. We discuss, with examples, the differences between these upper limits and confidence bounds. Both measures are useful quantities that should be reported in order to extract the most science from catalogs, though they answer different statistical questions: an upper bound describes an inference range on the source intensity, while an upper limit calibrates the detection process. We provide a recipe for computing upper limits that applies to all detection algorithms.

  9. Redshift-space limits of bound structures

    E-Print Network [OSTI]

    Rolando Dünner; Andreas Reisenegger; Andrés Meza; Pablo A. Araya; Hernán Quintana

    2007-02-26

    An exponentially expanding Universe, possibly governed by a cosmological constant, forces gravitationally bound structures to become more and more isolated, eventually becoming causally disconnected from each other and forming so-called "island universes". This new scenario reformulates the question about which will be the largest structures that will remain gravitationally bound, together with requiring a systematic tool that can be used to recognize the limits and mass of these structures from observational data, namely redshift surveys of galaxies. Here we present a method, based on the spherical collapse model and N-body simulations, by which we can estimate the limits of bound structures as observed in redshift space. The method is based on a theoretical criterion presented in a previous paper that determines the mean density contrast that a spherical shell must have in order to be marginally bound to the massive structure within it. Understanding the kinematics of the system, we translated the real-space limiting conditions of this "critical" shell to redshift space, producing a projected velocity envelope that only depends on the density profile of the structure. From it we created a redshift-space version of the density contrast that we called "density estimator", which can be calibrated from N-body simulations for a reasonable projected velocity envelope template, and used to estimate the limits and mass of a structure only from its redshift-space coordinates.

  10. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    NA

    2004-11-22

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this modeling activity is to predict dissolved concentrations or solubility limits for 14 elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) important to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are in the form of tabulated functions with pH and log (line integral) CO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. The output data from this report are fundamental inputs for Total System Performance Assessment for the License Application (TSPA-LA) to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for all of the actinides. These models cover broad ranges of environmental conditions so that they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  11. Limiting Abnormal Mold Growth in Buildings 

    E-Print Network [OSTI]

    Graham, C. W.

    2002-01-01

    in wood, or rusting and corrosion of metals. Abnormal mold or fungal growth, then, can create major problems for building owners. Moisture is the key factor that building designers and owners can manage in order to limit mold growth. This paper introduces...

  12. Flexible moldable conductive current-limiting materials

    DOE Patents [OSTI]

    Shea, John Joseph (Pittsburgh, PA); Djordjevic, Miomir B. (Milwaukee, WI); Hanna, William Kingston (Pittsburgh, PA)

    2002-01-01

    A current limiting PTC device (10) has two electrodes (14) with a thin film of electric conducting polymer material (20) disposed between the electrodes, the polymer material (20) having superior flexibility and short circuit performance, where the polymer material contains short chain aliphatic diepoxide, conductive filler particles, curing agent, and, preferably, a minor amount of bisphenol A epoxy resin.

  13. THE LANDAUER LIMIT AND THERMODYNAMICS OF

    E-Print Network [OSTI]

    Baez, John

    THE LANDAUER LIMIT AND THERMODYNAMICS OF BIOLOGICAL SYSTEMS David H. Wolpert Santa Fe Institute1 v2 b) h 2R vv1 v2 c) h vv1 v2 R Thermodynamic cost to erase a bit - the minimal amount of entropy be thermodynamically reversible ... but if it is applied to known data, it is thermodynamically irreversible." #12;HEAT

  14. Efficiency Limitations for -Protocols for Group Homomorphisms

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Efficiency Limitations for -Protocols for Group Homomorphisms (Full Version) Endre Bangerter1 , Jan stephan.krenn@bfh.ch Abstract. Efficient zero-knowledge proofs of knowledge for group ho- momorphisms be performed very efficiently within groups of known order, for hidden order groups the respective proofs

  15. LIMITED SUBMISSION Obama-Singh 21st

    E-Print Network [OSTI]

    Finley Jr., Russell L.

    -secondary educational institutions, in the thematic areas of energy; sustainable development; climate changeLIMITED SUBMISSION Obama-Singh 21st Century Knowledge Initiative (OSI) US-India Institutional for the support of projects through the Obama-Singh 21st Century Knowledge Initiative (OSI). Announced by the U.S

  16. More "Circle Limit III" Patterns Douglas Dunham

    E-Print Network [OSTI]

    Dunham, Doug

    of the four. In Circle Limit III, four fish meet at right fin tips, three fish meet at left fin tips, and three fish meet at their noses. In this paper, we show patterns with other numbers of fish that meet none but "through traffic" #12;series, and all the fish belonging to one series have the same colour

  17. Extending the Upper Temperature Limit for Life

    E-Print Network [OSTI]

    Lovley, Derek

    ) un- der N2-CO2 (80:20) in sealed culture tubes that con- tained formate (10 mM) as the electron donor that permit strain 121 to grow at such high temperatures are unknown. It is gen- erally assumed that the upperExtending the Upper Temperature Limit for Life Kazem Kashefi and Derek R. Lovley* The upper

  18. Jerk Limited Input Shapers Tarunraj Singh

    E-Print Network [OSTI]

    Singh, Tarunraj

    ACC04 Jerk Limited Input Shapers Tarunraj Singh tsingh@eng.buffalo.edu State University of New York with the impulse sequence. Singh and Vadali [8] proposed a technique to design time-delay filters whose performance and Watanabe [11], multi-hump input shapers by Singhose et al., minimax filters by Singh [12], user specified

  19. Jerk Limited Input Shapers Tarunraj Singh

    E-Print Network [OSTI]

    Singh, Tarunraj

    Jerk Limited Input Shapers Tarunraj Singh Department of Mechanical and Aerospace Engineering SUNY. Singh and Vadali 5 pro- posed a technique to design time-delay filters whose performance was identical and Watanabe 6 , multi-hump input shapers by Singhose et al., minimax filters by Singh 7 , user specified time

  20. Antenna factorization in strongly ordered limits

    SciTech Connect (OSTI)

    Kosower, David A.

    2005-02-15

    When energies or angles of gluons emitted in a gauge-theory process are small and strongly ordered, the emission factorizes in a simple way to all orders in perturbation theory. I show how to unify the various strongly ordered soft, mixed soft-collinear, and collinear limits using antenna factorization amplitudes, which are generalizations of the Catani-Seymour dipole factorization function.

  1. Dose Limit Philosophies Implemented at the

    E-Print Network [OSTI]

    McDonald, Kirk

    Motor Target in Center-cut Position Figure Credit: Adam Carroll EDM Machining Map Specimen Map #12 is an administrative tool used to limit the risk of component failure originating from radiation-induced changes of gadolinium coating on the moderator poison plates ­ Concern: Loss of resolution and performance

  2. Extremal Limits of Rotating Black Holes

    E-Print Network [OSTI]

    Laura Andrianopoli; Riccardo D'Auria; Antonio Gallerati; Mario Trigiante

    2013-05-30

    We consider non-extremal, stationary, axion-dilaton solutions to ungauged symmetric supergravity models, obtained by Harrison transformations of the non-extremal Kerr solution. We define a general algebraic procedure, which can be viewed as an Inonu-Wigner contraction of the Noether charge matrix associated with the effective D=3 sigma-model description of the solution, yielding, through different singular limits, the known BPS and non-BPS extremal black holes (which include the under-rotating non-BPS one). The non-extremal black hole can thus be thought of as "interpolating" among these limit-solutions. The algebraic procedure that we define generalizes the known Rasheed-Larsen limit which yielded, in the Kaluza-Klein theory, the first instance of under-rotating extremal solution. As an example of our general result, we discuss in detail the non-extremal solution in the T^3-model, with either (q_0, p^1) or (p^0, q_1) charges switched on, and its singular limits. Such solutions, computed in D=3 through the solution-generating technique, is completely described in terms of D=4 fields, which include the fully integrated vector fields.

  3. Limit-Induced Stable Limit Cycles in Power Patel Bhageerath Reddy Ian A. Hiskens

    E-Print Network [OSTI]

    place bounds on the divergent behaviour of states. This paper explores the situation where generator a high value. However it is well known that as KA increases, a Hopf bifurcation may occur at a critical/PSS/exciter model of Figure 1. The PSS output VP SS is limited by clipping limits, whilst the field voltage Efd

  4. Synthesis, characterization of double perovskite Ca{sub 2}MSbO{sub 6} (M = Dy, Fe, Cr, Al) materials via sol–gel auto-combustion and their catalytic properties

    SciTech Connect (OSTI)

    Feraru, S.; Samoila, P.; Borhan, A.I.; Ignat, M.; Iordan, A.R.; Palamaru, M.N.

    2013-10-15

    Double perovskite-type oxide Ca{sub 2}MSbO{sub 6} materials, where M = Dy, Fe, Cr, and Al, were prepared by using the sol–gel auto-combustion method. The role of different B-site cations on their synthesis, structures, morphologies and catalytic properties was investigated. The progress of double-perovskite type structure formation and the disappearance of the organic phases were monitored by infrared absorption spectroscopy (FTIR). Double perovskite oxide structures were evaluated using X-ray diffraction (XRD), while the microstructure of obtained compounds was studied using scanning electron microscopy (SEM). Also, BET surface areas were measured at the liquid nitrogen temperature by nitrogen adsorption. Catalytic properties of the obtained compounds were evaluated by test reaction of hydrogen peroxide decomposition. - Highlights: • Ca{sub 2}MSbO{sub 6} double perovskites were obtained by sol–gel auto-combustion method. • Ca{sub 2}MSbO{sub 6} (M = Dy, Fe, Cr and Al) as catalysts in H{sub 2}O{sub 2} decomposition • Strong relationship between particles' shape, BET area and catalytic performance • Ca{sub 2}FeSbO{sub 6} spherical grains show superior catalytic activity.

  5. Quantum Limits of Measurements and Uncertainty Principle

    E-Print Network [OSTI]

    Masanao Ozawa

    2015-05-19

    In this paper, we show how the Robertson uncertainty relation gives certain intrinsic quantum limits of measurements in the most general and rigorous mathematical treatment. A general lower bound for the product of the root-mean-square measurement errors arising in joint measurements of noncommuting observables is established. We give a rigorous condition for holding of the standard quantum limit (SQL) for repeated measurements, and prove that if a measuring instrument has no larger root-mean-square preparational error than the root-mean-square measurement errors then it obeys the SQL. As shown previously, we can even construct many linear models of position measurement which circumvent this condition for the SQL.

  6. Polymer Quantum Mechanics and its Continuum Limit

    E-Print Network [OSTI]

    Alejandro Corichi; Tatjana Vukasinac; Jose A. Zapata

    2007-08-22

    A rather non-standard quantum representation of the canonical commutation relations of quantum mechanics systems, known as the polymer representation has gained some attention in recent years, due to its possible relation with Planck scale physics. In particular, this approach has been followed in a symmetric sector of loop quantum gravity known as loop quantum cosmology. Here we explore different aspects of the relation between the ordinary Schroedinger theory and the polymer description. The paper has two parts. In the first one, we derive the polymer quantum mechanics starting from the ordinary Schroedinger theory and show that the polymer description arises as an appropriate limit. In the second part we consider the continuum limit of this theory, namely, the reverse process in which one starts from the discrete theory and tries to recover back the ordinary Schroedinger quantum mechanics. We consider several examples of interest, including the harmonic oscillator, the free particle and a simple cosmological model.

  7. Toxicity Data to Determine Refrigerant Concentration Limits

    SciTech Connect (OSTI)

    Calm, James M.

    2000-09-30

    This report reviews toxicity data, identifies sources for them, and presents resulting exposure limits for refrigerants for consideration by qualified parties in developing safety guides, standards, codes, and regulations. It outlines a method to calculate an acute toxicity exposure limit (ATEL) and from it a recommended refrigerant concentration limit (RCL) for emergency exposures. The report focuses on acute toxicity with particular attention to lethality, cardiac sensitization, anesthetic and central nervous system effects, and other escape-impairing effects. It addresses R-11, R-12, R-22, R-23, R-113, R-114, R-116, R-123, R-124, R-125, R-134, R-134a, R-E134, R-141b, R-142b, R-143a, R-152a, R-218, R-227ea, R-236fa, R-245ca, R-245fa, R-290, R-500, R-502, R-600a, R-717, and R-744. It summarizes additional data for R-14, R-115, R-170 (ethane), R-C318, R-600 (n-butane), and R-1270 (propylene) to enable calculation of limits for blends incorporating them. The report summarizes the data a nd related safety information, including classifications and flammability data. It also presents a series of tables with proposed ATEL and RCL concentrations-in dimensionless form and the latter also in both metric (SI) and inch-pound (IP) units of measure-for both the cited refrigerants and 66 zerotropic and azeotropic blends. They include common refrigerants, such as R-404A, R-407C, R-410A, and R-507A, as well as others in commercial or developmental status. Appendices provide profiles for the cited single-compound refrigerants and for R-500 and R-502 as well as narrative toxicity summaries for common refrigerants. The report includes an extensive set of references.

  8. Limited English Proficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterFinancialInvesting in Minority Banks InvestingLabLighting andLimited

  9. Means for limiting and ameliorating electrode shorting

    DOE Patents [OSTI]

    Van Konynenburg, Richard A. (Livermore, CA); Farmer, Joseph C. (Tracy, CA)

    1999-01-01

    A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  10. Means for limiting and ameliorating electrode shorting

    SciTech Connect (OSTI)

    Konynenburg, R.A. van; Farmer, J.C.

    1999-11-09

    A fuse and filter arrangement is described for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  11. Quantum nonlocality with arbitrary limited detection efficiency

    E-Print Network [OSTI]

    Gilles Pütz; Nicolas Gisin

    2015-07-17

    The demonstration and use of nonlocality, as defined by Bell's theorem, rely strongly on dealing with non-detection events due to losses and detector inefficiencies. Otherwise, the so-called detection loophole could be exploited. The only way to avoid this is to have detection efficiencies that are above a certain threshold. We introduce the intermediate assumption of limited detection efficiency, e.g. in each run of the experiment the overall detection efficiency is lower bounded by $\\eta_{min} > 0$. Hence, in an adversarial scenario, the adversaries have arbitrary large but not full control over the inefficiencies. We analyze the set of possible correlations that fulfil Limited Detection Locality (LDL) and show that they necessarily satisfy some linear Bell-like inequalities. We prove that quantum theory predicts violation of one of these inequalities for all $\\eta_{min} > 0$. Hence, nonlocality can be demonstrated with arbitrarily small limited detection efficiencies. Finally we propose a generalized scheme that uses this characterization to deal with detection inefficiencies, which interpolates between the two usual schemes, postselection and outcome assignment.

  12. Multivariate Central Limit Theorem in Quantum Dynamics

    E-Print Network [OSTI]

    Simon Buchholz; Chiara Saffirio; Benjamin Schlein

    2013-09-06

    We consider the time evolution of $N$ bosons in the mean field regime for factorized initial data. In the limit of large $N$, the many body evolution can be approximated by the non-linear Hartree equation. In this paper we are interested in the fluctuations around the Hartree dynamics. We choose $k$ self-adjoint one-particle operators $O_1, \\dots, O_k$ on $L^2 (\\R^3)$, and we average their action over the $N$-particles. We show that, for every fixed $t \\in \\R$, expectations of products of functions of the averaged observables approach, as $N \\to \\infty$, expectations with respect to a complex Gaussian measure, whose covariance matrix can be expressed in terms of a Bogoliubov transformation describing the dynamics of quantum fluctuations around the mean field Hartree evolution. If the operators $O_1, \\dots, O_k$ commute, the Gaussian measure is real and positive, and we recover a "classical" multivariate central limit theorem. All our results give explicit bounds on the rate of the convergence (we obtain therefore Berry-Ess{\\'e}en type central limit theorems).

  13. DE-SOL-0003641 001

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate12/21/2012 000001 3 1 13. THIS

  14. Sol Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North| Open

  15. Sol Solution | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North| OpenSolution Jump to:

  16. Sol rios | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North| OpenSolution Jumprios

  17. Big Sol - Facilities - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits & InspectionsBeryllium and ChronicBestBeyond theBid-ListBig

  18. AGGIE SOL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment| Department ofApplianceU.S.Departmentthe(Revision 2)EnergyAGGIE

  19. AGGIE SOL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment of EnergyResearchers atDay 12: Drive5Leadership at PNNL

  20. Sandia Energy - Mesa del Sol

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II)Geothermal Energy &Water Power&

  1. Karnataka Power Corporation Limited and National Thermal Power...

    Open Energy Info (EERE)

    Karnataka Power Corporation Limited and National Thermal Power Corporation JV Jump to: navigation, search Name: Karnataka Power Corporation Limited and National Thermal Power...

  2. (Expired) Nationwide Limited Public Interest Waiver for LED Lighting...

    Energy Savers [EERE]

    (Expired) Nationwide Limited Public Interest Waiver for LED Lighting and HVAC Units: February 11, 2010 (Expired) Nationwide Limited Public Interest Waiver for LED Lighting and HVAC...

  3. Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolyte Fuel Cell Lifetime Limitations: The Role of Electrocatalyst Degradation Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role of Electrocatalyst Degradation...

  4. Assessing Galaxy Limiting Magnitudes in Large Optical Surveys...

    Office of Scientific and Technical Information (OSTI)

    Assessing Galaxy Limiting Magnitudes in Large Optical Surveys Citation Details In-Document Search Title: Assessing Galaxy Limiting Magnitudes in Large Optical Surveys Authors:...

  5. 16 unit limit All undergraduates are limited to 16 unit enrollment 6/4

    E-Print Network [OSTI]

    Su, Xiao

    16 unit limit All undergraduates are limited to 16 unit enrollment 6/4 7/31. Graduating seniors may enroll in up to 18 units 8/1 8/11Graduating seniors may enroll in up to 18 units 8/18/11. Graduating Undergraduates = Excess Unit petitions for graduating seniors will be available 8/19/6. d d d d d

  6. Low velocity limits of cold atom clocks

    E-Print Network [OSTI]

    J. Muñoz; I. Lizuain; J. G. Muga

    2009-09-08

    Fundamental low-energy limits to the accuracy of quantum clock and stopwatch models in which the clock hand motion is activated by the presence of a particle in a region of space have been studied in the past, but their relevance for actual atomic clocks had not been assessed. In this work we address the effect of slow atomic quantum motion on Rabi and Ramsey resonance fringe patterns, as a perturbation of the results based on classical atomic motion. We find the dependence of the fractional error of the corresponding atomic clocks on the atomic velocity and interaction parameters.

  7. Heavy baryons in the large Nc limit

    E-Print Network [OSTI]

    Albertus, C; Fernando, I P; Goity, J L

    2015-01-01

    It is shown that in the large Nc limit heavy baryon masses can be estimated quantitatively in a 1/Nc expansion using the Hartree approximation. The results are compared with available lattice calculations for different values of the ratio between the square root of the string tension and the heavy quark mass tension independent of Nc. Using a potential adjusted to agree with the one obtained in lattice QCD, a variational analysis of the ground state spin averaged baryon mass is performed using Gaussian Hartree wave functions. Relativistic corrections through the quark kinetic energy are included. The results provide good estimates for the first sub-leading in 1/Nc corrections.

  8. Heavy baryons in the large Nc limit

    E-Print Network [OSTI]

    C. Albertus; E. Ruiz Arriola; I. P. Fernando; J. L. Goity

    2015-07-16

    It is shown that in the large Nc limit heavy baryon masses can be estimated quantitatively in a 1/Nc expansion using the Hartree approximation. The results are compared with available lattice calculations for different values of the ratio between the square root of the string tension and the heavy quark mass tension independent of Nc. Using a potential adjusted to agree with the one obtained in lattice QCD, a variational analysis of the ground state spin averaged baryon mass is performed using Gaussian Hartree wave functions. Relativistic corrections through the quark kinetic energy are included. The results provide good estimates for the first sub-leading in 1/Nc corrections.

  9. Limits in high efficiency quantum frequency conversion

    E-Print Network [OSTI]

    Nicolás Quesada; J. E. Sipe

    2015-08-13

    Frequency conversion is an enabling process in many quantum information protocols. In this letter we study fundamental limits to high efficiency frequency conversion imposed by time ordering corrections. Using the Magnus expansion, we argue that these corrections, which are usually considered detrimental, can be used to increase the efficiency of conversion under certain circumstances. The corrections induce a nonlinear behaviour in the probability of upconversion as a function of the pump intensity, significantly modifying the sinusoidal Rabi oscillations that are otherwise expected. Finally, by using a simple scaling argument, we explain why cascaded frequency conversion devices attenuate time ordering corrections, allowing the construction of near ideal quantum pulse gates.

  10. Energy Systems Limited ESL | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH JumpEllenville, NewLtd EILEnergy DatadataCentreCo LtdEnergyLimited ESL

  11. Renewable Fuels Limited RFL | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, New York: Energy ResourcesProducts LLC JumpTechSupply LtdLimited

  12. Bharat Renewable Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC Jump to:Greece:BajoBelpower Srl JumpOpenRenewable Energy Limited

  13. Castle European Estates Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation, search Name:InformationEstates Limited

  14. Lead Hero Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EAInvervar HydroElectricColorado:EnergyLaorLaunchLea CountyHero Limited

  15. United Group Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (Utility Company) JumpGTZ Climate OrientedUnionUnited ElectricLimited Jump

  16. Urenco Limited UK | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (Utility Company) JumpGTZ ClimateFeedUrat Rear Banner JiheUrenco Limited

  17. Carbon Limiting Technologies | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,Cammack Village, Arkansas:Fund for Spanish Firms FC2E JumpLimiting

  18. Carnegie Wave Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,Cammack Village, Arkansas:Fund forCarnegie Wave Energy Limited Jump to:

  19. Biodiesel Energy Trading Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin: EnergyYorkColoradoBelcherCarbonAlgeneBioLogical CapitalLimited

  20. Zebec Biogas Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (UtilityMichigan) JumpZhuyuan Electric Development CoZebec Biogas Limited

  1. Catamount Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy Electricals Ltd BHEL JumpCMNA Power JumpWindSLCastellwindLimited

  2. Clipper Windpower Europe Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy Electricals Ltd BHELEurope Limited Jump to: navigation, search

  3. Crionaig Power Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy Electricals Ltd BHELEurope Limited JumpAGGraefe KGCrionaig Power

  4. GenDrive Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy ElectricalsFTL SolarGate Solar Jump to:GenDrive Limited Jump to:

  5. Graduate Program Time Limits and Work Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUsefulJorgeAtl anta,GraduateTime Limits and Work

  6. Ionic Liquid and Silica Sol-Gel Composite Materials Doped with N,N,N ',N '-tetra(n-octyl)diglycolamide for Extraction of La3+ and Ba2+

    SciTech Connect (OSTI)

    Bell, Jason R [ORNL; Dai, Sheng [ORNL; Yu, Bo [ORNL; Luo, Huimin [ORNL

    2012-01-01

    Sol-gel processed silica materials which incorporated ionic liquids and tetraoctyldiglycolamide (TODGA) were prepared and used for extraction of La3+ and Ba2+ from aqueous solution. Imidazolium-based ionic liquids, 1-alkyl-3-methylimidazolium bis(trifluoromethane)sulfonimide ([Cnmim][NTf2]) were entrapped in the monolithic composite sorbents. Extraction efficiency was found to be dependent upon both the volume of IL used in the silica matrix, and the alkyl chain length of the IL cation. The silica composite sorbent containing [C8mim][NTf2] exhibited the best extraction efficiency for La3+ and the best separation factor for La3+ / Ba 2+. The results were analyzed by both Langmuir and Freundlich adsorption isotherm models, and the Freundlich model was found to give better fit.

  7. Remotely replaceable tokamak plasma limiter tiles

    DOE Patents [OSTI]

    Tsuo, Simon (Lakewood, CO), Langford, Alison A. (Boulder, CO)

    1989-01-01

    U-shaped limiter tiles placed end-to-end over a pair of parallel runners secured to a wall have two rods which engage L-shaped slots in the runners. The short receiving legs of the L-shaped slots are perpendicular to the wall and open away from the wall, while long retaining legs are parallel to and adjacent the wall. A sliding bar between the runners has grooves with clips to retain the rods pressed into receiving legs of the L-shaped slots in the runners. Sliding the bar in the direction of retaining legs of the L-shaped slots latches the tiles in place over the runners. Resilient contact strips between the parallel arms of the U-shaped tiles and the wall assure thermal and electrical contact with the wall.

  8. Thermal-noise-limited underground interferometer CLIO

    E-Print Network [OSTI]

    Kazuhiro Agatsuma; Koji Arai; Masa-Katsu Fujimoto; Seiji Kawamura; Kazuaki Kuroda; Osamu Miyakawa; Shinji Miyoki; Masatake Ohashi; Toshikazu Suzuki; Ryutaro Takahashi; Daisuke Tatsumi; Souichi Telada; Takashi Uchiyama; Kazuhiro Yamamoto; CLIO collaborators

    2010-01-29

    We report on the current status of CLIO (Cryogenic Laser Interferometer Observatory), which is a prototype interferometer for LCGT (Large Scale Cryogenic Gravitational-Wave Telescope). LCGT is a Japanese next-generation interferometric gravitational wave detector featuring the use of cryogenic mirrors and a quiet underground site. The main purpose of CLIO is to demonstrate a reduction of the mirror thermal noise by cooling the sapphire mirrors. CLIO is located in an underground site of the Kamioka mine, 1000 m deep from the mountain top, to verify its advantages. After a few years of commissioning work, we have achieved a thermal-noise-limited sensitivity at room temperature. One of the main results of noise hunting was the elimination of thermal noise caused by a conductive coil-holder coupled with a pendulum through magnets.

  9. Unitary limit in crossed Andreev transport

    E-Print Network [OSTI]

    I. A. Sadovskyy; G. B. Lesovik; V. M. Vinokur

    2015-04-10

    Crossed Andreev reflection splitting a Cooper pair into the metal through spatially separated terminals as two spin and energy entangled electrons is one of the most promising approaches to generation of entangled electron pairs. However, while the conventional (local) Andreev reflection occurs with the probability of unity, the probability of crossed Andreev reflection is significantly suppressed. We propose a one-dimensional model capturing main features of the hybrid normal metal-superconductor setups used in experiments, which allows to achieve a unitary limit of crossed Andreev transport, i.e. splitting of Cooper pairs with the 100% efficiency. We calculate and analyze electron-to-hole transmission probability, differential conductance, and cross-correlations of currents passing through different terminals thus putting the ideas of maximum possible outcome on a firm analytical basis.

  10. Self field triggered superconducting fault current limiter

    DOE Patents [OSTI]

    Tekletsadik, Kasegn D. (Rexford, NY)

    2008-02-19

    A superconducting fault current limiter array with a plurality of superconductor elements arranged in a meanding array having an even number of supconductors parallel to each other and arranged in a plane that is parallel to an odd number of the plurality of superconductors, where the odd number of supconductors are parallel to each other and arranged in a plane that is parallel to the even number of the plurality of superconductors, when viewed from a top view. The even number of superconductors are coupled at the upper end to the upper end of the odd number of superconductors. A plurality of lower shunt coils each coupled to the lower end of each of the even number of superconductors and a plurality of upper shunt coils each coupled to the upper end of each of the odd number of superconductors so as to generate a generally orthoganal uniform magnetic field during quenching using only the magenetic field generated by the superconductors.

  11. Various factors affect coiled tubing limits

    SciTech Connect (OSTI)

    Yang, Y.S.

    1996-01-15

    Safety and reliability remain the primary concerns in coiled tubing operations. Factors affecting safety and reliability include corrosion, flexural bending, internal (or external) pressure and tension (or compression), and mechanical damage due to improper use. Such limits as coiled tubing fatigue, collapse, and buckling need to be understood to avoid disaster. With increased use of coiled tubing, operators will gain more experience. But at the same time, with further research and development of coiled tubing, the manufacturing quality will be improved and fatigue, collapse, and buckling models will become more mature, and eventually standard specifications will be available. This paper reviews the uses of coiled tubing and current research on mechanical behavior of said tubing. It also discusses several models used to help predict fatigue and failure levels.

  12. Mean Field Limits in Strongly Confined Systems

    E-Print Network [OSTI]

    Johannes von Keler

    2014-12-10

    We consider the dynamics of $N$ interacting bosons in three dimensions which are strongly confined in one or two directions. We analyze the two cases where the interaction potential $w$ is rescaled by either $N^{-1}w(\\cdot)$ or $a^{3\\theta-1}w(a^\\theta \\cdot)$ and choose the initial wavefunction to be close to a product wavefunction. For both scalings we prove that in the mean field limit $N\\rightarrow \\infty $ the dynamics of the $N$-particle system are described by a nonlinear equation in one or two dimensions. In the case of the scaling $N^{-1}w(\\cdot)$ this equation is the Hartree equation and for the scaling $a^{3\\theta-1}w(a^\\theta \\cdot) $ the nonlinear Schr\\"odinger equation. In both cases we obtain explicit bounds for the rate of convergence of the $N$-particle dynamics to the one-particle dynamics.

  13. Neutral depletion and the helicon density limit

    SciTech Connect (OSTI)

    Magee, R. M.; Galante, M. E.; Carr, J. Jr.; Lusk, G.; McCarren, D. W.; Scime, E. E.

    2013-12-15

    It is straightforward to create fully ionized plasmas with modest rf power in a helicon. It is difficult, however, to create plasmas with density >10{sup 20} m{sup ?3}, because neutral depletion leads to a lack of fuel. In order to address this density limit, we present fast (1 MHz), time-resolved measurements of the neutral density at and downstream from the rf antenna in krypton helicon plasmas. At the start of the discharge, the neutral density underneath the antenna is reduced to 1% of its initial value in 15 ?s. The ionization rate inferred from these data implies that the electron temperature near the antenna is much higher than the electron temperature measured downstream. Neutral density measurements made downstream from the antenna show much slower depletion, requiring 14 ms to decrease by a factor of 1/e. Furthermore, the downstream depletion appears to be due to neutral pumping rather than ionization.

  14. Authorized limits for Fernald copper ingots

    SciTech Connect (OSTI)

    Frink, N.; Kamboj, S.; Hensley, J.; Chen, S. Y.

    1997-09-01

    This development document contains data and analysis to support the approval of authorized limits for the unrestricted release of 59 t of copper ingots containing residual radioactive material from the U.S. Department of Energy (DOE) Fernald Environmental Management Project (FEMP). The analysis presented in this document comply with the requirements of DOE Order 5400.5, {open_quotes}Radiation Protection of the Public and the Environment,{close_quotes} as well as the requirements of the proposed promulgation of this order as 10 CFR Part 834. The document was developed following the step-by-step process described in the Draft Handbook for Controlling Release for Reuse or Recycle Property Containing Residual Radioactive Material.

  15. Challenging packaging limits and infectivity of phage ?

    E-Print Network [OSTI]

    Elmar Nurmemmedov; Martin Castelnovo; Elizabeth Medina; Carlos Enrique Catalano; Alex Evilevitch

    2011-11-09

    The terminase motors of bacteriophages have been shown to be among the strongest active machines in the biomolecular world, being able to package several tens of kilobase pairs of viral genome into a capsid within minutes. Yet these motors are hindered at the end of the packaging process by the progressive build-up of a force resisting packaging associated with already packaged DNA. In this experimental work, we raise the issue of what sets the upper limit on the length of the genome that can be packaged by the terminase motor of phage {\\lambda} and still yield infectious virions, and the conditions under which this can be efficiently performed. Using a packaging strategy developed in our laboratory of building phage {\\lambda} from scratch, together with plaque assay monitoring, we have been able to show that the terminase motor of phage {\\lambda} is able to produce infectious particles with up to 110% of the wild-type (WT) {\\lambda}-DNA length. However, the phage production rate, and thus the infectivity, decreased exponentially with increasing DNA length, and was a factor of 103 lower for the 110% {\\lambda}-DNA phage. Interestingly, our in vitro strategy was still efficient in fully packaging phages with DNA lengths as high as 114% of the WT length, but these viruses were unable to infect bacterial cells efficiently. Further, we demonstrated that the phage production rate is modulated by the presence of multivalent ionic species. The biological consequences of these finding are discussed.

  16. Flow reversal power limit for the HFBR

    SciTech Connect (OSTI)

    Cheng, L.Y.; Tichler, P.R.

    1997-01-01

    The High Flux Beam Reactor (HFBR) is a pressurized heavy water moderated and cooled research reactor that began operation at 40 MW. The reactor was subsequently upgraded to 60 MW and operated at that level for several years. The reactor undergoes a buoyancy-driven reversal of flow in the reactor core following certain postulated accidents. Questions which were raised about the afterheat removal capability during the flow reversal transition led to a reactor shutdown and subsequent resumption of operation at a reduced power of 30 MW. An experimental and analytical program to address these questions is described in this report. The experiments were single channel flow reversal tests under a range of conditions. The analytical phase involved simulations of the tests to benchmark the physical models and development of a criterion for dryout. The criterion is then used in simulations of reactor accidents to determine a safe operating power level. It is concluded that the limit on the HFBR operating power with respect to the issue of flow reversal is in excess of 60 MW. Direct use of the experimental results and an understanding of the governing phenomenology supports this conclusion.

  17. The ultimate downscaling limit of FETs.

    SciTech Connect (OSTI)

    Mamaluy, Denis; Gao, Xujiao; Tierney, Brian David

    2014-10-01

    We created a highly efficient, universal 3D quant um transport simulator. We demonstrated that the simulator scales linearly - both with the problem size (N) and number of CPUs, which presents an important break-through in the field of computational nanoelectronics. It allowed us, for the first time, to accurately simulate and optim ize a large number of realistic nanodevices in a much shorter time, when compared to other methods/codes such as RGF[~N 2.333 ]/KNIT, KWANT, and QTBM[~N 3 ]/NEMO5. In order to determine the best-in-class for different beyond-CMOS paradigms, we performed rigorous device optimization for high-performance logic devices at 6-, 5- and 4-nm gate lengths. We have discovered that there exists a fundamental down-scaling limit for CMOS technology and other Field-Effect Transistors (FETs). We have found that, at room temperatures, all FETs, irre spective of their channel material, will start experiencing unacceptable level of thermally induced errors around 5-nm gate lengths.

  18. The limits of the nuclear landscape

    SciTech Connect (OSTI)

    Nazarewicz, Witold; Erler, J.; Birge, N.; Kortelainen, E. M.; Olsen, E.; Perhac, A.; Stoitsov, M.

    2012-01-01

    In 2011, 100 new nuclides were discovered1. They joined the approximately 3,000 stable and radioactive nuclides that either occur naturally on Earth or are synthesized in the laboratory2,3. Every atomic nucleus, characterized by a specific number of protons and neutrons, occupies a spot on the chart of nuclides, which is bounded by drip lines indicating the values of neutron and proton number at which nuclear binding ends. The placement of the neutron drip line for the heavier elements is based on theoretical predictions using extreme extrapolations, and so is uncertain. However, it is not known how uncertain it is or how many protons and neutrons can be bound in a nucleus. Here we estimate these limits of the nuclear landscape and provide statistical and systematic uncertainties for our predictions. We use nuclear density functional theory, several Skyrme interactions and high-performance computing, and find that the number of bound nuclides with between 2 and 120 protons is around 7,000. We find that extrapolations for drip-line positions and selected nuclear properties, including neutron separation energies relevant to astrophysical processes, are very consistent between the models used.

  19. Weak Quenched Limiting Distributions for One-dimensional RWRE

    E-Print Network [OSTI]

    Jonathon Peterson

    2010-09-12

    Sep 13, 2010 ... Ladder locations {?n} defined by ?0 = 0, ?n := inf{i > ?n?1 : V(i) < V(?n?1)} .... Weak quenched limits. Proofs. Heuristics of Quenched Limit Laws.

  20. Diesel Particulate Filters and NO2 Emission Limits | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters and NO2 Emission Limits Diesel Particulate Filters and NO2 Emission Limits EPAs New air quality standards for NO2 will impact future DPF designs deer09ibrahim.pdf More...

  1. Overcoming the far-field diffraction limit via absorbance modulation

    E-Print Network [OSTI]

    Tsai, Hsin-Yu Sidney

    2011-01-01

    Diffraction limits the resolution of far-field lithography and imaging to about half of the wavelength, which greatly limits the capability of optical techniques. The proposed technique with absorbance modulation aims to ...

  2. Limited success of heat treatments for curing HLB affected trees

    E-Print Network [OSTI]

    Lopes, S. A.; Luiz, F. Q.B.F.; Fassini, C. G.; Oliveira, H. T.; Oliveira, S. L.A.

    2014-01-01

    Limited success of heat treatments for curing HLB affectedthe lack of success of the heat treatments against HLB. 3rd

  3. Does Superstring Theory Have a Conformally Invariant Limit?

    E-Print Network [OSTI]

    John H. Schwarz

    2000-08-01

    This talk describes a proposal, due to Hull, for a conformally invariant limit of superstring theory in six dimensions.

  4. One-dimensional long-range diffusion-limited aggregation III -- The limit aggregate

    E-Print Network [OSTI]

    Gideon Amir

    2015-04-06

    In this paper we study the structure of the limit aggregate $A_\\infty = \\bigcup_{n\\geq 0} A_n$ of the one-dimensional long range diffusion limited aggregation process defined in [AABK09]. We show (under some regularity conditions) that for walks with finite third moment $A_\\infty$ has renewal structure and positive density, while for walks with finite variance the renewal structure no longer exists and $A_\\infty$ has 0 density. We define a tree structure on the aggregates and show some results on the degrees and number of ends of these random trees. We introduce a new "harmonic competition" model where different colours compete for harmonic measure, and show how the tree structure is related to coexistence in this model.

  5. Limited Electricity Generation Supply and Limited Natural Gas Supply Cases (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01

    Development of U.S. energy resources and the permitting and construction of large energy facilities have become increasingly difficult over the past 20 years, and they could become even more difficult in the future. Growing public concern about global warming and CO2 emissions also casts doubt on future consumption of fossil fuels -- particularly coal, which releases the largest amount of CO2 per unit of energy produced. Even without regulations to limit greenhouse gas emissions in the United States, the investment community may already be limiting the future use of some energy options. In addition, there is considerable uncertainty about the future availability of, and access to, both domestic and foreign natural gas resources.

  6. Scaling Limits of Two-Dimensional Percolation: an Overview

    E-Print Network [OSTI]

    Federico Camia

    2008-10-06

    We present a review of the recent progress on percolation scaling limits in two dimensions. In particular, we will consider the convergence of critical crossing probabilities to Cardy's formula and of the critical exploration path to chordal SLE(6), the full scaling limit of critical cluster boundaries, and near-critical scaling limits.

  7. Salary Limitation on Grants, Cooperative Agreements, and Contracts

    E-Print Network [OSTI]

    Salary Limitation on Grants, Cooperative Agreements, and Contracts Notice Number: NOT-OD-08-035 Key://www.nih.gov) This notice provides updated information regarding the salary limitation for NIH grant and cooperative). On February 22, 2007 NIH published Fiscal Year (FY) 2007 information on the salary limitation in the NIH Guide

  8. A Subject-Delegated Decryption Scheme with "Tightly" Limited Authority

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    A Subject-Delegated Decryption Scheme with "Tightly" Limited Authority Lihua Wang1 , Takeshi@cs.tsukuba.ac.jp Abstract. In this paper, we present a new proxy cryptosystem named subject-delegated decryption scheme subjects. The advantage of our scheme is that the proxy authorities are tightly limited ("Tightly" Limited

  9. Finding the Lower Stellar Mass Limit Observationally Justin Cantrell

    E-Print Network [OSTI]

    Wiita, Paul J.

    saying: "1. Objects with true masses below the limiting mass for thermonuclear fusion of deuterium masses above the limiting mass for thermonuclear fusion of deuterium are "brown dwarfs", no matter how below the limiting mass for thermonuclear fusion of deuterium are not "planets", but are "sub

  10. MFR PAPER 1152 An Empirical Study of Limited Entry

    E-Print Network [OSTI]

    MFR PAPER 1152 An Empirical Study of Limited Entry in Alaska's Salmon Fisheries JAMES E. OWERS to a point where the marginal cost ofan additional unit of fishing effort just equals the revenue it produces both before and after passing limited entry legislation in 1973 strongly suggests that, first, limited

  11. An alternative approach to achieving water quality-based limits

    SciTech Connect (OSTI)

    Hart, C.M.; Graeser, W.C.

    1995-12-01

    Since May 1982, members of the Iron and Steel Industry have been required to meet effluent limits based on Best Available Technology (BAT) for a process water discharge to receiving stream. US Steel Clairton Works has been successful in meeting these limits in the last three years; however, the current regulatory thrust is toward more stringent limits based on water quality. In cases of smaller streams such as the receiving stream for Clairton Works` process outfall, these limits can be very rigid. This paper will discuss the alternative approaches investigated to meet the new more stringent limits including the solution chosen.

  12. 679.24 Gear Limitations 50 CFR 679b24.docx 679.24 Gear Limitations Page 1 of 5

    E-Print Network [OSTI]

    § 679.24 Gear Limitations 50 CFR 679b24.docx § 679.24 Gear Limitations Page 1 of 5 Updated May 5, 2014 § 679.24 Gear limitations. Regulations pertaining to vessel and gear markings are set forth to § 300.62 of chapter III of this title. (a) Marking of hook-and-line, longline pot, and pot-and-line gear

  13. 1Design limits and solutions for very large wind turbines Design limits and solutions for very large wind turbines

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    #12;#12;1Design limits and solutions for very large wind turbines UpWind Design limits and solutions for very large wind turbines A 20 MW turbine is feasible March 2011 Supported by: #12;March 20112 Photo:Nordex #12;3Design limits and solutions for very large wind turbines Contents 1. UpWind: Summary

  14. 2014 Headquarters Facilities Master Security Plan- Chapter 2, Limited Areas, Vault-Type Rooms and Temporary Limited Areas

    Broader source: Energy.gov [DOE]

    2014 Headquarters Facilities Master Security Plan - Chapter 2, Limited Areas, Vault-Type Rooms and Temporary Limited Areas Describes DOE Headquarters procedures for establishing, maintaining, and deactivating Limited Areas and Vault-Type Rooms and protecting the classified information handled within those Areas.

  15. Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} nanoparticles dispersed in a SiO{sub 2} matrix synthesized by sol-gel processing

    SciTech Connect (OSTI)

    Pozo Lopez, G.; Condo, A.M.; Instituto Balseiro, Universidad Nacional de Cuyo, Av. Bustillo 9500, 8400, San Carlos de Bariloche; Consejo Nacional de Investigaciones Cientificas y Tecnicas ; Urreta, S.E.; Silvetti, S.P.; Aguirre, M. del C.; Instituto de Fisica Enrique Gaviola - CONICET

    2012-12-15

    (Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4})x/(SiO{sub 2})(100 - x) (x = 5, 20 and 50 wt.%) nanocomposites are synthesized by a sol-gel method using tetraethylorthosilicate (TEOS) and metallic nitrates as precursors, and by further annealing the powders for 1 h at 1273 K. X-ray diffraction (XRD), transmission electron microscopy (TEM), room temperature vibrating sample magnetometry (VSM) and SQUID measurements are employed for structural, morphological and magnetic sample characterization. For all the concentrations analyzed, the powder nanocomposites actually consist of spinel NiZn ferrite nanoparticles, dispersed in an amorphous silica matrix. TEM studies reveal different particle size distributions and particle morphologies for the three ferrite contents. The 20 wt.%-NiZn ferrite samples consist of nearly spherical nanoparticles, of about 8 nm, mainly superparamagnetic, well-dispersed in the amorphous silica matrix, while the 5 wt.%-NiZn ferrite samples exhibit a bimodal particle size distribution (5 and 30 nm) of single-domain nanoparticles embedded in the silica. In the 50 wt.%-NiZn ferrite samples, two particle families are observed: small round superparamagnetic nanoparticles of about 8 nm embedded in the amorphous silica matrix and large, non-spherical, ferrimagnetic ones, forming agglomerates outside the matrix. In all the synthesized samples, thickness fringes are observed inside some of the ferrite nanoparticles in dark field images. This contrast is explained using the theory of electron diffraction in a weak beam dark field (WBDF) condition and considering spherical ferrite nanoparticles. A large range of tailored magnetic properties varying the fraction, dispersion and mean size of the ferrimagnetic NiZn ferrite particles is obtained. Room temperature saturation magnetization values are found in the range 3.0-30.4 Am{sup 2}/kg for the different concentration samples. Coercivity values, between 1.9 and 7.6 mT, are more than 50% higher than those measured in powders of pure stoichiometric NiZn ferrite nanoparticles and somewhat higher than those reported for similar NiZn ferrite/SiO{sub 2} nanocomposites also synthesized by sol-gel processes. A correlation between the nanocomposite microstructure and the observed magnetic properties is established. - Highlights: Black-Right-Pointing-Pointer NiZn ferrite/SiO{sub 2} nanocomposites are successfully synthesized by a sol-gel route. Black-Right-Pointing-Pointer Depending on the NiZn ferrite content single or bimodal size distributions result. Black-Right-Pointing-Pointer Coercivity (1.9-7.6 mT) is 50% higher than in stoichiometric NiZn ferrite powders. Black-Right-Pointing-Pointer Microstructure and magnetic properties are correlated.

  16. Towards Exploring Fundamental Limits of System-Specific Cryptanalysis Within Limited Attack Classes: Application to ABSG

    E-Print Network [OSTI]

    Altug, Yucel

    2008-01-01

    A new approach on cryptanalysis is proposed where the goal is to explore the fundamental limits of a specific class of attacks against a particular cryptosystem. As a first step, the approach is applied on ABSG, which is an LFSR-based stream cipher where irregular decimation techniques are utilized. Consequently, under some mild assumptions, which are common in cryptanalysis, the tight lower bounds on the algorithmic complexity of successful Query-Based Key-Recovery attacks are derived for two different setups of practical interest. The proofs rely on the concept of ``typicality'' of information theory.

  17. Predetermining acceptable noise limits in EXAFS spectra in the limit of stochastic noise

    SciTech Connect (OSTI)

    Hu, Yung-Jin; Booth, Corwin H

    2009-12-14

    EXAFS measurements are used to probe a variety of experimental systems, but excel at elucidating local structure in samples which have slight disorder or no long-range crystalline order. Of special interest to the authors is the use of EXAFS in understanding the molecular-level binding structure and characteristics of actinides on the surface of environmental minerals and model mineral analogs. In environmental systems the element of interest can be on the order of 10-7% by weight of the total sample. Obviously such samples would be impossible to measure using EXAFS techniques. It is therefore essential to increase the concentration of the element of interest while still preserving a sample's ability to represent environmental conditions. Under such low concentration limits it is expected that the collected data is countrate, or stochastically limited. This condition occurs as we approach the signal-to-noise (S/N) limit of the technique where the random noise of the measurement process dominates over possible systematic errors. When stochastic error is expected to dominate systematic error, it is possible to predict, with the use of simulations, the ability of model fits to tolerate a certain level of stochastic noise. Elsewhere in these proceedings, we discuss how to tell when systematic errors dominate in measured EXAFS spectrum. Here, we outline a technique for determining the number of EXAFS scans necessary to test the relevance of a given structural model. Appropriate stochastic noise levels are determined for each point in r-space by collecting data on a real system. These noise levels are then applied to EXAFS simulations using a test model. In this way, all significant systematic error sources are eliminated in the simulated data. The structural model is then fit to the simulated data, decreasing the noise and increasing the k-range of the fit until the veracity of the model passes an F-test. This paper outlines a method of testing model systems in EXAFS fitting before measurements are conducted to determine the quality of measured data required for fitting of a particular model system with statistical confidence. It is important to reiterate that the calculated {alpha}surface in figure 1 is only applicable to the particular model presented in this paper. Furthermore, this procedure only takes into account stochastic noise; consequentially any confidence levels calculated should be viewed as upper limits to the confidence levels in systems which also contain a significant amount of systematic noise.

  18. Upper limits on gravitational wave emission from 78 radio pulsars

    E-Print Network [OSTI]

    The LIGO Scientific Collaboration; B. Abbott; M. Kramer; A. G. Lyne

    2007-10-12

    We present upper limits on the gravitational wave emission from 78 radio pulsars based on data from the third and fourth science runs of the LIGO and GEO600 gravitational wave detectors. The data from both runs have been combined coherently to maximise sensitivity. For the first time pulsars within binary (or multiple) systems have been included in the search by taking into account the signal modulation due to their orbits. Our upper limits are therefore the first measured for 56 of these pulsars. For the remaining 22, our results improve on previous upper limits by up to a factor of 10. For example, our tightest upper limit on the gravitational strain is 2.6e-25 for PSRJ1603-7202, and the equatorial ellipticity of PSRJ2124-3358 is less than 10^{-6}. Furthermore, our strain upper limit for the Crab pulsar is only 2.2 times greater than the fiducial spin-down limit.

  19. On the no-gravity limit of gravity

    E-Print Network [OSTI]

    J. Kowalski-Glikman; M. Szczachor

    2012-12-21

    We argue that Relative Locality may arise in the no gravity $G\\rightarrow0$ limit of gravity. In this limit gravity becomes a topological field theory of the BF type that, after coupling to particles, may effectively deform its dynamics. We briefly discuss another no gravity limit with a self dual ground state as well as the topological ultra strong $G\\rightarrow\\infty$ one.

  20. Structural and dielectric/ferroelectric properties of (La{sub 1-x}Nd{sub x}){sub 2}Ti{sub 2}O{sub 7} synthesized by sol-gel route

    SciTech Connect (OSTI)

    Shao Zhenmian; Saitzek, Sebastien; Roussel, Pascal; Mentre, Olivier; Prihor Gheorghiu, Felicia; Mitoseriu, Liliana; Desfeux, Rachel

    2010-07-15

    A series of compounds with the general formula (La{sub 1-x}Nd{sub x}){sub 2}Ti{sub 2}O{sub 7} (0.0{<=}x{<=}1.0) has been prepared by the sol-gel method. The decomposition of the gel was characterized by thermo-gravimetric analysis coupled to mass spectrometry, indicating the reaction is achieved above 850 {sup o}C. The lattice parameters versus x show an expected decrease in the a and b parameters while c and the {beta} angle remain almost unchanged with respect to the monoclinic symmetry conserved for the full solid solution. Dielectric, piezoelectric and ferroelectric properties were measured on the entire series. - Graphical abstract: XRD patterns of (La{sub 1-x}Nd{sub x}){sub 2}Ti{sub 2}O{sub 7} powders for various x values. The (hkl) peaks positions (with h and k{ne}0) change with x values while the (00l) peaks positions remain unaffected.

  1. Critical Issues in NPH Categorization and Limit State Selection...

    Office of Environmental Management (EM)

    and the public. This step also includes defining what constitutes failure (e.g., for seismic design, determination of a Limit State associated with SSC failure) * Step 2:...

  2. Recovery Efficiency, False Negative Rate, and Limit of Detection...

    Office of Scientific and Technical Information (OSTI)

    Recovery Efficiency, False Negative Rate, and Limit of Detection Performance of a Validated Macrofoam-Swab Sampling Method with Low Surface Concentrations of Two Bacillus anthracis...

  3. Experimental Evidence for Self-Limiting Reactive Flow through...

    Office of Scientific and Technical Information (OSTI)

    Experimental Evidence for Self-Limiting Reactive Flow through a Fractured Cement Core: Implications for Time-Dependent Wellbore Leakage Citation Details In-Document Search Title:...

  4. Call for emission limits heats debate on global warming

    SciTech Connect (OSTI)

    Singer, S.F.

    1997-08-01

    Emission limits on carbon dioxide is recommended by an Intergovernmental Panel in a discussion on global warming. (AIP) {copyright} {ital 1997 American Institute of Physics.}

  5. Anisotropic Fermi Surface and Quantum Limit Transport in High...

    Office of Scientific and Technical Information (OSTI)

    Anisotropic Fermi Surface and Quantum Limit Transport in High Mobility Three-Dimensional Dirac Semimetal Cd 3 As 2 Citation Details In-Document Search Title: Anisotropic Fermi...

  6. Jordan cells in logarithmic limits of conformal field theory

    E-Print Network [OSTI]

    Jorgen Rasmussen

    2006-11-25

    It is discussed how a limiting procedure of conformal field theories may result in logarithmic conformal field theories with Jordan cells of arbitrary rank. This extends our work on rank-two Jordan cells. We also consider the limits of certain three-point functions and find that they are compatible with known results. The general construction is illustrated by logarithmic limits of (unitary) minimal models in conformal field theory. Characters of quasi-rational representations are found to emerge as the limits of the associated irreducible Virasoro characters.

  7. Resource Limits and Conversion Efficiency with Implications for Climate Change

    E-Print Network [OSTI]

    Croft, Gregory Donald

    2009-01-01

    in resource limits declined with oil prices after 1985, butthe surge in oil prices since 1999 has elevated Hubbertfavored. Along with higher oil prices has come a discussion

  8. Articulated limiter blade for a tokamak fusion reactor

    DOE Patents [OSTI]

    Doll, D.W.

    1982-10-21

    A limiter blade for a large tokomak fusion reactor includes three articulated blade sections for enabling the limiter blade to be adjusted for plasmas of different sizes. Each blade section is formed of a rigid backing plate carrying graphite tiles coated with titanium carbide, and the limiter blade forms a generally elliptic contour in both the poloidal and toroidal directions to uniformly distribute the heat flow to the blade. The limiter blade includes a central blade section movable along the major radius of the vacuum vessel, and upper and lower pivotal blade sections which may be pivoted by linear actuators having rollers held to the back surface of the pivotal blade sections.

  9. Articulated limiter blade for a tokamak fusion reactor

    DOE Patents [OSTI]

    Doll, David W. (San Diego, CA)

    1985-01-01

    A limiter blade for a large tokomak fusion reactor includes three articulated blade sections for enabling the limiter blade to be adjusted for plasmas of different sizes. Each blade section is formed of a rigid backing plate carrying graphite tiles coated with titanium carbide, and the limiter blade forms a generally elliptic contour in both the poloidal and toroidal directions to uniformly distribute the heat flow to the blade. The limiter blade includes a central blade section movable along the major radius of the vacuum vessel, and upper and lower pivotal blade sections which may be pivoted by linear actuators having rollers held to the back surface of the pivotal blade sections.

  10. Headquarters Facilities Master Security Plan - Chapter 2, Limited...

    Energy Savers [EERE]

    and Temporary Limited Areas This chapter covers the establishment, maintenance, and termination of areas within HQ buildings where classified activities take place. It covers the...

  11. COLD BUBBLE FORMATION DURING TOKAMAK DENSITY LIMIT DISRUPTIONS

    E-Print Network [OSTI]

    Howard, John

    COLD BUBBLE FORMATION DURING TOKAMAK DENSITY LIMIT DISRUPTIONS J. HOWARD, M. PERSSON* Plasma Research Laboratory, Research School of Physical Sciences, Australian National University, Canberra

  12. Comments on Emergency Order to Resume Limited Operation at the...

    Office of Environmental Management (EM)

    Operation at the Potomac River Generating Station, Alexandria, VA from the Chesapeake Climate Action Network. Comments on Emergency Order to Resume Limited Operation at the...

  13. Parameterized post-Newtonian limit of Horndeski's gravity theory

    E-Print Network [OSTI]

    Manuel Hohmann

    2015-08-20

    We present a recent result on the parameterized post-Newtonian (PPN) limit of Horndeski's gravity theory and its consistency with solar system observations.

  14. Massive gravity as a limit of bimetric gravity

    E-Print Network [OSTI]

    Martin-Moruno, Prado; Visser, Matt

    2013-01-01

    Massive gravity may be viewed as a suitable limit of bimetric gravity. The limiting procedure can lead to an interesting interplay between the "background" and "foreground" metrics in a cosmological context. The fact that in bimetric theories one always has two sets of metric equations of motion continues to have an effect even in the massive gravity limit. Thus, solutions of bimetric gravity in the limit of vanishing kinetic term are also solutions of massive gravity, but the contrary statement is not necessarily true.

  15. Stainless steel 304 cladding mechanical properties and limitations...

    Office of Scientific and Technical Information (OSTI)

    mechanical properties and limitations during steady state operation of U-ZrH TRIGA type fuel. Citation Details In-Document Search Title: Stainless steel 304 cladding mechanical...

  16. Conditions for diffusion-limited and reaction-limited recombination in nanostructured solar cells

    SciTech Connect (OSTI)

    Ansari-Rad, Mehdi; Department of Physics, University of Shahrood, Shahrood ; Anta, Juan A.; Arzi, Ezatollah

    2014-04-07

    The performance of Dye-sensitized solar cells (DSC) and related devices made of nanostructured semiconductors relies on a good charge separation, which in turn is achieved by favoring charge transport against recombination. Although both processes occur at very different time scales, hence ensuring good charge separation, in certain cases the kinetics of transport and recombination can be connected, either in a direct or an indirect way. In this work, the connection between electron transport and recombination in nanostructured solar cells is studied both theoretically and by Monte Carlo simulation. Calculations using the Multiple-Trapping model and a realistic trap distribution for nanostructured TiO{sub 2} show that for attempt-to-jump frequencies higher than 10{sup 11}–10{sup 13} Hz, the system adopts a reaction limited (RL) regime, with a lifetime which is effectively independent from the speed of the electrons in the transport level. For frequencies lower than those, and depending on the concentration of recombination centers in the material, the system enters a diffusion-limited regime (DL), where the lifetime increases if the speed of free electrons decreases. In general, the conditions for RL or DL recombination depend critically on the time scale difference between recombination kinetics and free-electron transport. Hence, if the former is too rapid with respect to the latter, the system is in the DL regime and total thermalization of carriers is not possible. In the opposite situation, a RL regime arises. Numerical data available in the literature, and the behavior of the lifetime with respect to (1) density of recombination centers and (2) probability of recombination at a given center, suggest that a typical DSC in operation stays in the RL regime with complete thermalization, although a transition to the DL regime may occur for electrolytes or hole conductors where recombination is especially rapid or where there is a larger dispersion of energies of electron acceptors.

  17. BIOMASS FOR HYDROGEN AND OTHER TRANSPORT FUELS -POTENTIALS, LIMITATIONS & COSTS

    E-Print Network [OSTI]

    BIOMASS FOR HYDROGEN AND OTHER TRANSPORT FUELS - POTENTIALS, LIMITATIONS & COSTS Senior scientist - "Towards Hydrogen Society" ·biomass resources - potentials, limits ·biomass carbon cycle ·biomass for hydrogen - as compared to other H2- sources and to other biomass paths #12;BIOMASS - THE CARBON CYCLE

  18. LIMITS TO CBA IN UK AND EUROPEAN ENVIRONMENTAL POLICY

    E-Print Network [OSTI]

    Bateman, Ian J.

    LIMITS TO CBA IN UK AND EUROPEAN ENVIRONMENTAL POLICY: RETROSPECTS & FUTURE PROSPECTS by R.K. Turner CSERGE Working Paper EDM 06-17 #12;Limits to CBA in UK and European Environmental Policy the contemporary debate and the now long standing role of CBA in UK and European environmental policy appraisal

  19. Broadcasting with a Battery Limited Energy Harvesting Rechargeable Transmitter

    E-Print Network [OSTI]

    Ulukus, Sennur

    . The proposed algorithm uses directional water-filling repetitively. I. INTRODUCTION Energy harvestingBroadcasting with a Battery Limited Energy Harvesting Rechargeable Transmitter Omur Ozel1 , Jing with a battery limited energy harvesting trans- mitter in a two-user AWGN broadcast channel. The transmitter has

  20. Cooling at the quantum limit and RF refrigeration

    E-Print Network [OSTI]

    Fominov, Yakov

    Cooling at the quantum limit and RF refrigeration Jukka Pekola Low Temperature Laboratory, Helsinki (electromagnetic) heat transport Cooling at the quantum limit: experiments RF refrigeration in a single as a refrigerator Optimum cooling power is reached at V 2/e: Cooling power of a NIS junction: Temperature TN

  1. Dynamic Limit Growth Indices in Discrete Time Tomasz R. Bielecki

    E-Print Network [OSTI]

    Heller, Barbara

    Dynamic Limit Growth Indices in Discrete Time Tomasz R. Bielecki 1 bielecki@iit.edu Igor Cialenco 1, Illinois Institute of Technology, Chicago, 60616 IL, USA 2 Institute of Mathematics, Jagiellonian propose a new class of mappings, called Dynamic Limit Growth Indices, that are designed to measure

  2. Limited Sectoral Trading between the EU ETS and China

    E-Print Network [OSTI]

    Limited Sectoral Trading between the EU ETS and China Claire Gavard, Niven Winchester and Sergey established research centers at MIT: the Center for Global Change Science (CGCS) and the Center for Energy://globalchange.mit.edu/ Printed on recycled paper #12;1 Limited Sectoral Trading between the EU ETS and China Claire Gavard

  3. Limits on the thermoacoustic detectability of electric and magnetic charges

    SciTech Connect (OSTI)

    Akerlof, C.W.

    1982-09-01

    The energy loss is estimated for a slow magnetic monopole traveling through a conductor. The thermoacoustic signal derived from this process is compared to the acoustic phonon fluctuation pressure. The results show that single-monopole detectability is strongly limited by thermal noise. These calculations also imply severe limits for the detectability of charged-particle cascades.

  4. Limited Flooding Protocol for Mobile Ad hoc Networks Mieso Denko

    E-Print Network [OSTI]

    Goddard, Wayne

    Limited Flooding Protocol for Mobile Ad hoc Networks Mieso Denko Department of Computing propose a multipath routing protocol called Limited Flooding. The protocol is fully reactive and does not entail the compu- tation of routing tables. It uses the basic features of flooding but restricts packet

  5. Broadcasting with a Battery Limited Energy Harvesting Rechargeable Transmitter

    E-Print Network [OSTI]

    Ulukus, Sennur

    ) at the transmitter at random instants. The battery at the transmitter has a finite storage capacity, hence energy mayBroadcasting with a Battery Limited Energy Harvesting Rechargeable Transmitter Omur Ozel1 , Jing with a battery limited energy harvesting trans- mitter in a two-user AWGN broadcast channel. The transmitter has

  6. Dynamic Query Optimization under Access Limitations and Dependencies

    E-Print Network [OSTI]

    Calvanese, Diego

    : Unlike relational tables in a database, data sources on the Web typically can only be accessed in limited ways. In particular, some of the source fields may be required as input and thus need to be mandatorily filled in order to access the source. Answering queries over sources with access limitations is a complex

  7. COGARCH as a continuous-time limit of Jan Kallsen

    E-Print Network [OSTI]

    Kallsen, Jan

    of a sequence of GARCH(1,1) processes. As a by-product we derive the infinitesimal generator of the bivariate. Key words: GARCH, continuous time, limit theorem, Markov process, generator Mathematics SubjectCOGARCH as a continuous-time limit of GARCH(1,1) Jan Kallsen Bernhard Vesenmayer Abstract COGARCH

  8. On the ChapmanJouguet Limit for a Combustion Model

    E-Print Network [OSTI]

    On the Chapman­Jouguet Limit for a Combustion Model Bernard Hanouzet \\Lambda , Roberto Natalini y and Alberto Tesei z Abstract We study the limiting behaviour of solutions to a simple model for combustion detonations and deflagrations with respect to the reaction rate. Key words and phrases: combustion

  9. CMC Markets Stockbroking Limited Financial Services Guide (FSG)

    E-Print Network [OSTI]

    Peters, Richard

    and responsibility of CMC Markets Stockbroking when it provides retail clients with the financial services describedCMC Markets Stockbroking Limited Financial Services Guide (FSG) 1 October 2013 AFSL No. 246381 and ABN 69 081 002 851 #12;Table of Contents CMC Markets Stockbroking Limited | Financial Services Guide 2

  10. Energy Harvesting Communications with Energy and Data Storage Limitations

    E-Print Network [OSTI]

    Yener, Aylin

    Energy Harvesting Communications with Energy and Data Storage Limitations Burak Varan Aylin Yener time minimization problem with finite data and energy storage. The communication set up in [10] does limited energy and data storage. The data transmission policies allow the transmitter to drop some

  11. One-level limit order books with sparsity and memory

    E-Print Network [OSTI]

    2014-10-17

    Oct 17, 2014 ... Keywords and phrases: Limit Order Book Modeling, Price Process Formation, Long-run Price Process ... In recent years, the study of continuous double auction trading ... By nature, the market orders are matched with limit orders at the .... LOB features, some of which are relevant for trading and intraday.

  12. Aalborg Universitet Switching speed limitations of high power IGBT modules

    E-Print Network [OSTI]

    Munk-Nielsen, Stig

    of the total power loss. Therefore, by design, it is critical that switching losses are reduced to a minimumAalborg Universitet Switching speed limitations of high power IGBT modules Incau, Bogdan Ioan.aau.dk on: november 29, 2015 #12;Switching speed limitations of high power IGBT modules Bogdan Ioan Incau

  13. Optical limiting device and method of preparation thereof

    DOE Patents [OSTI]

    Wang, Hsing-Lin (Los Alamos, NM); Xu, Su (Santa Clara, CA); McBranch, Duncan W. (Santa Fe, NM)

    2003-01-01

    Optical limiting device and method of preparation thereof. The optical limiting device includes a transparent substrate and at least one homogeneous layer of an RSA material in polyvinylbutyral attached to the substrate. The device may be produced by preparing a solution of an RSA material, preferably a metallophthalocyanine complex, and a solution of polyvinylbutyral, and then mixing the two solutions together to remove air bubbles. The resulting solution is layered onto the substrate and the solvent is evaporated. The method can be used to produce a dual tandem optical limiting device.

  14. The multicomponent 2D Toda hierarchy: dispersionless limit

    E-Print Network [OSTI]

    Manuel Manas; Luis Martinez Alonso

    2009-04-21

    The factorization problem of the multi-component 2D Toda hierarchy is used to analyze the dispersionless limit of this hierarchy. A dispersive version of the Whitham hierarchy defined in terms of scalar Lax and Orlov--Schulman operators is introduced and the corresponding additional symmetries and string equations are discussed. Then, it is shown how KP and Toda pictures of the dispersionless Whitham hierarchy emerge in the dispersionless limit. Moreover, the additional symmetries and string equations for the dispersive Whitham hierarchy are studied in this limit.

  15. PP-85-2 Boliden Westmin (Canada) Limited | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    85-2 Boliden Westmin (Canada) Limited PP-85-2 Boliden Westmin (Canada) Limited Presidential Permit authorizing Boliden Westmin (Canada) Limited to construct, operate and maintain...

  16. Beating the Landauer's limit by trading energy with uncertainty

    E-Print Network [OSTI]

    Gammaitoni, Luca

    2011-01-01

    According to the International Technology Roadmap for Semiconductors in the next 10-15 years the limits imposed by the physics of switch operation will be the major roadblock for future scaling of the CMOS technology. Among these limits the most fundamental is represented by the so-called Shannon-von Neumann-Landauer limit that sets a lower bound to the minimum heat dissipated per bit erasing operation. Here we show that in a nanoscale switch, operated at finite temperature T, this limit can be beaten by trading the dissipated energy with the uncertainty in the distinguishability of switch logic states. We establish a general relation between the minimum required energy and the maximum error rate in the switch operation and briefly discuss the potential applications in the design of future switches.

  17. Framework for the determination of yield limits In pharmaceutical operations

    E-Print Network [OSTI]

    Liow, Yuh Han John

    2010-01-01

    The manufacturing production of active pharmaceutical ingredients often involve a series of processing stages in which yield limits are prescribed to ensure that the target yield has been achieved for a batch and that the ...

  18. Fourth generation quark mass limits in CKM-element space

    E-Print Network [OSTI]

    Christian J. Flacco; Daniel Whiteson; Matthew Kelly

    2011-01-25

    We present a reanalysis of CDF data to extend limits on individual fourth-generation quark masses from particular flavor-mixing rates to the entire space of possible mixing values. Measurements from CDF have set individual limits on masses, $m_{b'}$ and $m_{t'}$, at the level of $335$--$385$ GeV assuming specific and favorable flavor-mixing rates. We consider the space of possible values for the mixing rates and find that the CDF data imply limits of $290$ GeV and greater over a wide range of mixing scenarios. We also analyze the limits from the perspective of a four-generation CKM matrix. We find that present experimental constraints on CKM elements do not suggest further constraints on fourth-generation quark masses.

  19. Limitation Date and Time Total Wind SCE Plus CSGI Reserves...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Limitation Date and Time Total Wind SCE Plus CSGI Reserves Deployed Reserves Held Reserves Deployed Percent 1182015 3:00 718 -1092 -1100 -99% 262015 12:14 925 -1096 -1100 -99%...

  20. Limitations on area compression of beams from pierce guns

    SciTech Connect (OSTI)

    Yakovlev, V.P.; Nezhevenko, O.A. [Omega-P Inc., 202008 Yale Station, New Haven, Connecticut 06520-2008 (United States)

    1999-05-01

    An important limitation for rf sources such as klystrons and magnicons, designed for 10{close_quote}s of MW power outputs at cm-wavelengths, is the transverse electron beam size. Cathode current density limits require high beam area compressions to obtain small transverse beam areas for fixed currents. This paper discusses the limitations to high beam area compression, namely geometrical aberrations and thermal spread in transverse velocities. Compensation can oftentimes be introduced for aberrations, but thermal velocity spread presents a fundamental limitation. Examples where subtle compensation strategies were employed are discussed for three guns with 100 MW beam power, and area compressions greater than 2000:1. Two of these guns have already been built. A clear determination of effective cathode temperature has yet to be found experimentally, but possible means to measure it are discussed. {copyright} {ital 1999 American Institute of Physics.}

  1. ORIGINAL PAPER Wet hibernacula promote inoculative freezing and limit

    E-Print Network [OSTI]

    Lee Jr., Richard E.

    ORIGINAL PAPER Wet hibernacula promote inoculative freezing and limit the potential Peninsula. Although overwintering larvae have the physiological potential to survive by freezing or cryopro- tective dehydration, use of the latter strategy may be con- strained by inoculative freezing within

  2. An experimental investigation of the countercurrent flow limitation 

    E-Print Network [OSTI]

    Solmos, Matthew Aaron

    2008-10-10

    A new correlation for the prediction of the Countercurrent Flow Limitation (CCFL) in a large diameter tube with a falling water lm is proposed. Dierent from previous correlations, it predicts the onset of ooding by ...

  3. Fundamentals of PV Efficiency: Limits for Light Absorption

    E-Print Network [OSTI]

    M. Ryyan Khan; Xufeng Wang; Muhammad A. Alam

    2012-12-13

    A simple thermodynamic argument related to a (weakly absorbing) finite dielectric slab illuminated by sunlight- originally suggested by Yablonovich- leads to the conclusion that the absorption in a dielectric can at best be increased by a factor 4n2. Therefore, the absorption in these materials is always imperfect; the Shockley-Queisser limit can be achieved only asymptotically. In this paper, we make the connection between the degradation in efficiency and the Yablonovich limit explicit and re-derive the 4n2 limit by intuitive geometrical arguments based on Snell's law and elementary rules of probability. Remarkably, the re-derivation suggests strategies of breaking the traditional limit and improving PV efficiency by enhanced light absorption.

  4. Iron limitation and the role of Siderophores in marine Synechococcus

    E-Print Network [OSTI]

    Rivers, Adam R. (Adam Reid)

    2009-01-01

    Marine cyanobacteria in the genus Synechococcus are widely distributed and contribute significantly to global primary productivity. In many parts of the ocean their growth is limited by a lack of iron, an essential nutrient ...

  5. Pedestrian Only Area University visitors' car parks (limited access)

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Campus Map Pedestrian Only Area Car Parks University visitors' car parks (limited access) Other university car parks Public multi-storey car park Lawns Free City Bus Stop ST. GEORGE'S FIELD WOODHOUSE LAN E

  6. Standard Quantum Limit for Probing Mechanical Energy Quantization

    E-Print Network [OSTI]

    Corbitt, Thomas R.

    We derive a standard quantum limit for probing mechanical energy quantization in a class of systems with mechanical modes parametrically coupled to external degrees of freedom. To resolve a single mechanical quantum, it ...

  7. On the density limit in the helicon plasma sources

    SciTech Connect (OSTI)

    Kotelnikov, Igor A.

    2014-12-15

    Existence of the density limit in the helicon plasma sources is revisited. The low- and high-frequency regimes of a helicon plasma source operation are distinguished. In the low-frequency regime with ?limit is deduced from the Golant-Stix criterion of the accessibility of the lower hybrid resonance. In the high-frequency case, ?>?(?{sub ci}?{sub ce}), an appropriate limit is given by the Shamrai-Taranov criterion. Both these criteria are closely related to the phenomenon of the coalescence of the helicon wave with the Trivelpiece-Gould mode. We draw a conclusion that the derived density limits are not currently achieved in existing devices, perhaps, because of high energy cost of gas ionization.

  8. Impacts of a conspicuity treatment on speed limit compliance 

    E-Print Network [OSTI]

    Garg, Roma

    2007-09-17

    In reduced speed zones, where no other cues indicate the need to slow down, drivers sometimes fail to notice the standard Speed Limit sign and may be speeding inadvertently. To help reduce inadvertent speeding, a red ...

  9. Nonlinear analysis of store-induced limit cycle oscillations 

    E-Print Network [OSTI]

    Thompson, David Eugene

    2001-01-01

    Flight tests of modern high-performance fighter aircraft reveal that when these aircraft are carrying certain configurations of underwing stores, the aircraft will encounter a limit cycle oscillation at speeds much lower than those predicted...

  10. Fundamental limits to the optical response of lossy media

    E-Print Network [OSTI]

    Miller, Owen D; Reid, M T Homer; Hsu, Chia Wei; DeLacy, Brendan G; Joannopoulos, John D; Solja?i?, Marin; Johnson, Steven G

    2015-01-01

    At visible and infrared frequencies, metals show tantalizing promise for strong subwavelength resonances, but material loss typically dampens the response. We derive fundamental limits to the optical response of lossy media, bounding the largest enhancements possible given intrinsic material losses. Through basic conservation-of-energy principles, we derive limits to per-volume absorption and scattering rates, and to local-density-of-states enhancements that represent the power radiated or expended by a dipole near a material body. We provide examples of structures that approach our limits, and also specific frequency ranges at which common structures fall orders of magnitudes short. Underlying the limits is a simple metric, $|\\chi|^2 / \\operatorname{Im} \\chi$ for a material with susceptibility $\\chi$, that enables broad technological evaluation of lossy media across optical frequencies.

  11. Inherent limitations and current status of the unresolved resonance treatment

    SciTech Connect (OSTI)

    Hwang, R.N.

    1984-01-01

    The two general methods for representing the behavior of the unresolved resonances and the limitations of these methods are discussed. Possible solutions to the problem are considered. 17 references. (WHK)

  12. 2006 Nature Publishing Group Robust Salmonella metabolism limits

    E-Print Network [OSTI]

    Cai, Long

    © 2006 Nature Publishing Group Robust Salmonella metabolism limits possibilities for new validation is largely lacking. Here we have obtained in vivo information about over 700 Salmonella enterica enzymes from network analysis of mutant phenotypes, genome comparisons and Salmonella proteomes from

  13. Radial limits of holomorphic functions on the ball 

    E-Print Network [OSTI]

    Fulkerson, Michael C

    2008-10-10

    In this dissertation, we consider various aspects of the boundary behavior of holomorphic functions of several complex variables. In dimension one, a characterization of the radial limit zero sets of nonconstant holomorphic functions on the disc has...

  14. Limited development as a tool for agricultural preservation in Massachusetts

    E-Print Network [OSTI]

    Tuttle, William D. (William Davis)

    1988-01-01

    Limited development offers the hope of turning market development pressure which threatens open land into a means for financing its protection. In theory, the profit from developing a small portion of a parcel can be used ...

  15. Diameter-bandwidth product limitation of isolated-object cloaking

    E-Print Network [OSTI]

    Joannopoulos, John D.

    We show that cloaking of isolated objects using transformation-based cloaks is subject to a diameter-bandwidth product limitation: as the size of the object increases, the bandwidth of good (small-cross-section) cloaking ...

  16. Adsorbed Polymer and NOM Limits Adhesion and Toxicity of Nano

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Adsorbed Polymer and NOM Limits Adhesion and Toxicity of Nano Scale Zerovalent Iron to E. coli Z H. Here we assess the effect that adsorbed synthetic polymers and natural organic matter

  17. Flood control reservoir operations for conditions of limited storage capacity 

    E-Print Network [OSTI]

    Rivera Ramirez, Hector David

    2005-02-17

    -1 FLOOD CONTROL RESERVOIR OPERATIONS FOR CONDITIONS OF LIMITED STORAGE CAPACITY A Dissertation by HECTOR DAVID RIVERA RAMIREZ Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY December 2004 Major Subject: Civil Engineering FLOOD CONTROL RESERVOIR OPERATIONS FOR CONDITIONS OF LIMITED STORAGE CAPACITY A Dissertation by HECTOR DAVID RIVERA...

  18. A Window in the Dark Matter Exclusion Limits

    E-Print Network [OSTI]

    Gabrijela Zaharijas; Glennys R. Farrar

    2005-06-28

    We consider the cross section limits for light dark matter candidates ($m=0.4$ to 10 GeV). We calculate the interaction of dark matter in the crust above underground dark matter detectors and find that in the intermediate cross section range, the energy loss of dark matter is sufficient to fall below the energy threshold of current underground experiments. This implies the existence of a window in the dark matter exclusion limits in the micro-barn range.

  19. Validity and limitations of gas-drive relative permeability measurement 

    E-Print Network [OSTI]

    Gupta, Anand Kumar

    1971-01-01

    VALIDITY AND LIMITATIONS OF GAS-DRIVE RELA TI VE PERMEABILITY MEASUREMEN T A Thesis by ANAND KUMAR GUPTA Submitted to the Graduate College of Texas ARM University in partial fulfillxnent of the requirement for the degree of MASTER Ok SCIENCE... August, 1971 Major Subject: Petroleum Engineering VALIDITY AND LIMITATIONS OF GAS-DRIVE RELATIVE PERMEABILITY MEASUREMENT A Thesis by ANAND KUMAR GUPTA Approved as to style and content by: ( airman of Committee) ber) Head of Department) (Member...

  20. SHOCK EMERGENCE IN SUPERNOVAE: LIMITING CASES AND ACCURATE APPROXIMATIONS

    SciTech Connect (OSTI)

    Ro, Stephen; Matzner, Christopher D.

    2013-08-10

    We examine the dynamics of accelerating normal shocks in stratified planar atmospheres, providing accurate fitting formulae for the scaling index relating shock velocity to the initial density and for the post-shock acceleration factor as functions of the polytropic and adiabatic indices which parameterize the problem. In the limit of a uniform initial atmosphere, there are analytical formulae for these quantities. In the opposite limit of a very steep density gradient, the solutions match the outcome of shock acceleration in exponential atmospheres.

  1. Adjustable direct current and pulsed circuit fault current limiter

    DOE Patents [OSTI]

    Boenig, Heinrich J.; Schillig, Josef B.

    2003-09-23

    A fault current limiting system for direct current circuits and for pulsed power circuit. In the circuits, a current source biases a diode that is in series with the circuits' transmission line. If fault current in a circuit exceeds current from the current source biasing the diode open, the diode will cease conducting and route the fault current through the current source and an inductor. This limits the rate of rise and the peak value of the fault current.

  2. Toroidal midplane neutral beam armor and plasma limiter

    DOE Patents [OSTI]

    Kugel, Henry W. (Somerset, NJ); Hand, Jr, Samuel W. (Hopewell Township, Mercer County, NJ); Ksayian, Haig (Titusville, NJ)

    1986-01-01

    For use in a tokamak fusion reactor having a midplane magnetic coil on the inner wall of an evacuated toriodal chamber within which a neutral beam heated, fusing plasma is magnetically confined, a neutral beam armor shield and plasma limiter is provided on the inner wall of the toroidal chamber to shield the midplane coil from neutral beam shine-thru and plasma deposition. The armor shield/plasma limiter forms a semicircular enclosure around the midplane coil with the outer surface of the armor shield/plasma limiter shaped to match, as closely as practical, the inner limiting magnetic flux surface of the toroidally confined, indented, bean-shaped plasma. The armor shield/plasma limiter includes a plurality of semicircular graphite plates each having a pair of coupled upper and lower sections with each plate positioned in intimate contact with an adjacent plate on each side thereof so as to form a closed, planar structure around the entire outer periphery of the circular midplane coil. The upper and lower plate sections are adapted for coupling to heat sensing thermocouples and to a circulating water conduit system for cooling the armor shield/plasma limiter.The inner center portion of each graphite plate is adapted to receive and enclose a section of a circular diagnostic magnetic flux loop so as to minimize the power from the plasma confinement chamber incident upon the flux loop.

  3. ARM: Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Yan Shi; Laura Riihimaki

    1994-01-07

    Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

  4. Hydraulic limitation not declining nitrogen availability causes the age-related photosynthetic decline in loblolly

    E-Print Network [OSTI]

    DeLucia, Evan H.

    Hydraulic limitation not declining nitrogen availability causes the age-related photosynthetic capacity and thus decreases GPP with increasing age; and (2) hydraulic limitations increasingly induce conservative with age. We conclude that hydraulic limitation increasingly limits the photosyn- thetic rates

  5. ARM: Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Yan Shi; Laura Riihimaki

    Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

  6. Dr. Z's Math251 Handout #14.2 [Limits and Continuity] By Doron Zeilberger

    E-Print Network [OSTI]

    Zeilberger, Doron

    that there are "differ- enet limits for different lines" and hence the limit itself definitely does not exist. Alas

  7. Upper limit map of a background of gravitational waves

    E-Print Network [OSTI]

    Abbott, B; Adhikari, R; Agresti, J; Ajith, P; Allen, B; Amin, R; Anderson, S B; Anderson, W G; Arain, M; Araya, M; Armandula, H; Ashley, M; Aston, S; Aufmuth, P; Aulbert, C; Babak, S; Ballmer, S; Bantilan, H; Barish, B C; Barker, C; Barker, D; Barr, B; Barriga, P; Barton, M A; Bayer, K; Belczynski, K; Betzwieser, J; Beyersdorf, P T; Bhawal, B; Bilenko, I A; Billingsley, G; Biswas, R; Black, E; Blackburn, K; Blackburn, L; Blair, D; Bland, B; Bogenstahl, J; Bogue, L; Bork, R; Boschi, V; Bose, S; Brady, P R; Braginsky, V B; Brau, J E; Brinkmann, M; Brooks, A; Brown, D A; Bullington, A; Bunkowski, A; Buonanno, A; Burmeister, O; Busby, D; Byer, R L; Cadonati, L; Cagnoli, G; Camp, J B; Cannizzo, J; Cannon, K; Cantley, C A; Cao, J; Cardenas, L; Casey, M M; Castaldi, G; Cepeda, C; Chalkey, E; Charlton, P; Chatterji, S; Chelkowski, S; Chen, Y; Chiadini, F; Chin, D; Chin, E; Chow, J; Christensen, N; Clark, J; Cochrane, P; Cokelaer, T; Colacino, C N; Coldwell, R; Conte, R; Cook, D; Corbitt, T; Coward, D; Coyne, D; Creighton, J D E; Creighton, T D; Croce, R P; Crooks, D R M; Cruise, A M; Cumming, A; Dalrymple, J; D'Ambrosio, E; Danzmann, K; Davies, G; De Bra, D; Degallaix, J; Degree, M; Demma, T; Dergachev, V; Desai, S; DeSalvo, R; Dhurandhar, S V; Díaz, M; Dickson, J; Di Credico, A; Diederichs, G; Dietz, A; Doomes, E E; Drever, R W P; Dumas, J C; Dupuis, R J; Dwyer, J G; Ehrens, P; Espinoza, E; Etzel, T; Evans, M; Evans, T; Fairhurst, S; Fan, Y; Fazi, D; Fejer, M M; Finn, L S; Fiumara, V; Fotopoulos, N; Franzen, A; Franzen, K Y; Freise, A; Frey, R; Fricke, T; Fritschel, P; Frolov, V V; Fyffe, M; Galdi, V; Garofoli, J; Gholami, I; Giaime, J A; Giampanis, S; Giardina, K D; Goda, K; Goetz, E; Goggin, L; González, G; Gossler, S; Grant, A; Gras, S; Gray, C; Gray, M; Greenhalgh, J; Gretarsson, A M; Grosso, R; Grote, H; Grünewald, S; Günther, M; Gustafson, R; Hage, B; Hammer, D; Hanna, C; Hanson, J; Harms, J; Harry, G; Harstad, E; Hayler, T; Heefner, J; Heng, I S; Heptonstall, A; Heurs, M; Hewitson, M; Hild, S; Hirose, E; Hoak, D; Hosken, D; Hough, J; Howell, E; Hoyland, D; Huttner, S H; Ingram, D; Innerhofer, E; Ito, M; Itoh, Y; Ivanov, A; Jackrel, D; Johnson, B; Johnson, W W; Jones, D I; Jones, G; Jones, R; Ju, L; Kalmus, Peter Ignaz Paul; Kalogera, V; Kasprzyk, D; Katsavounidis, E; Kawabe, K; Kawamura, S; Kawazoe, F; Kells, W; Keppel, D G; Khalili, F Ya; Kim, C; King, P; Kissel, J S; Klimenko, S; Kokeyama, K; Kondrashov, V; Kopparapu, R K; Kozak, D; Krishnan, B; Kwee, P; Lam, P K; Landry, M; Lantz, B; Lazzarini, A; Lee, B; Lei, M; Leiner, J; Leonhardt, V; Leonor, I; Libbrecht, K; Lindquist, P; Lockerbie, N A; Longo, M; Lormand, M; Lubinski, M; Luck, H; Machenschalk, B; MacInnis, M; Mageswaran, M; Mailand, K; Malec, M; Mandic, V; Marano, S; Marka, S; Markowitz, J; Maros, E; Martin, I; Marx, J N; Mason, K; Matone, L; Matta, V; Mavalvala, N; McCarthy, R; McClelland, D E; McGuire, S C; McHugh, M; McKenzie, K; McNabb, J W C; McWilliams, S; Meier, T; Melissinos, A C; Mendell, G; Mercer, R A; Meshkov, S; Messaritaki, E; Messenger, C J; Meyers, D; Mikhailov, E; Mitra, S; Mitrofanov, V P; Mitselmakher, G; Mittleman, R; Miyakawa, O; Mohanty, S; Moreno, G; Mossavi, K; Mow Lowry, C; Moylan, A; Mudge, D; Müller, G; Mukherjee, S; Muller-Ebhardt, H; Munch, J; Murray, P; Myers, E; Myers, J; Newton, G; Nishizawa, A; Numata, K; O'Reilly, B; O'Shaughnessy, R; Ottaway, D J; Overmier, H; Owen, B J; Pan, Y; Papa, M A; Parameshwaraiah, V; Patel, P; Pedraza, M; Penn, S; Pierro, V; Pinto, I M; Pitkin, M; Pletsch, H; Plissi, M V; Postiglione, F; Prix, R; Quetschke, V; Raab, F; Rabeling, D; Radkins, H; Rahkola, R; Rainer, N; Rakhmanov, M; Ray-Majumder, S; Re, V; Rehbein, H; Reid, S; Reitze, D H; Ribichini, L; Riesen, R; Riles, K; Rivera, B; Robertson, N A; Robinson, C; Robinson, E L; Roddy, S; Rodríguez, A; Rogan, A M; Rollins, J; Romano, J D; Romie, J; Route, R; Rowan, S; Rüdiger, A; Ruet, L; Russell, P; Ryan, K; Sakata, S; Samidi, M; Sancho de la Jordana, L; Sandberg, V; Sannibale, V; Saraf, S; Sarin, P; Sathyaprakash, B S; Sato, S; Saulson, P R; Savage, R; Savov, P; Schediwy, S; Schilling, R; Schnabel, R; Schofield, R; Schutz, B F; Schwinberg, P; Scott, S M; Searle, A C; Sears, B; Seifert, F; Sellers, D; Sengupta, A S; Shawhan, P; Shoemaker, D H; Sibley, A; Sidles, J A; Siemens, X; Sigg, D; Sinha, S; Sintes, A M; Slagmolen, B; Slutsky, J; Smith, J R; Smith, M R; Somiya, K; Strain, K A; Strom, D M; Stuver, A; Summerscales, T Z; Sun, K X; Sung, M; Sutton, P J; Takahashi, H; Tanner, D B; Tarallo, M; Taylor, R; Thacker, J; Thorne, K A; Thorne, K S; Thüring, A; Tokmakov, K V; Torres, C; Torrie, C; Traylor, G; Trias, M; Tyler, W; Ugolini, D W; Ungarelli, C; Urbanek, K; Vahlbruch, H; Vallisneri, M; Van Den Broeck, C; Varvella, M; Vass, S; Vecchio, A; Veitch, J; Veitch, P; Villar, A; Vorvick, C; Vyachanin, S P; Waldman, S J; Wallace, L

    2007-01-01

    We searched for an anisotropic background of gravitational waves using data from the LIGO S4 science run and a method that is optimized for point sources. This is appropriate if, for example, the gravitational wave background is dominated by a small number of distinct astrophysical sources. No signal was seen. Upper limit maps were produced assuming two different power laws for the source strain power spectrum. For an f^-3 power law and using the 50 Hz to 1.8 kHz band the upper limits on the source strain power spectrum vary between 1.2e-48 Hz^-1 (100 Hz/f)^3 and 1.2e-47 Hz^-1 (100 Hz /f)^3, depending on the position in the sky. Similarly, in the case of constant strain power spectrum, the upper limits vary between 8.5e-49 Hz^-1 and 6.1e-48 Hz^-1. As a side product a limit on an isotropic background of gravitational waves was also obtained. All limits are at the 90% confidence level. Finally, as an application, we focused on the direction of Sco-X1, the closest low-mass X-ray binary. We compare the upper limi...

  8. A Keplerian Limit to Static Spherical Spacetimes in Curvature Coordinates

    E-Print Network [OSTI]

    Tyler J. Lemmon; Antonio R. Mondragon

    2008-09-04

    The problem of a test body in the Schwarzschild geometry is investigated in a Keplerian limit. Beginning with the Schwarzschild metric, a solution to the limited case of approximately elliptical (Keplerian) motion is derived in terms of trigonometric functions. This solution is similar in form to that derived from Newtonian mechanics, and includes first-order corrections describing three effects due to general relativity: precession; reduced radial coordinate; and increased eccentricity. The quantitative prediction of increased eccentricity may provide an additional observational test of general relativity. By analogy with Keplerian orbits, approximate orbital energy parameters are defined in terms of a relativistic eccentricity, providing first-order corrections to Newtonian energies for elliptical orbits. The first-order relativistic equation of orbit is demonstrated to be a limiting case of a very accurate self-consistent solution. This self-consistent solution is supported by exact numerical solutions to the Schwarzschild geometry, displaying remarkable agreement. A more detailed energy parameterization is investigated using the relativistic eccentricity together with the apsides derived from the relativistic effective potential in support of the approximate energy parameters defined using only first-order corrections. The methods and approximations describing this Keplerian limit are applied to more general static spherically-symmetric geometries. Specifically, equations of orbit and energy parameters are also derived in this Keplerian limit for the Reissner-Nordstr\\"{o}m and Schwarzschild-de Sitter metrics.

  9. Continuum Limits for Critical Percolation and Other Stochastic Geometric Models

    E-Print Network [OSTI]

    Michael Aizenman

    1998-06-06

    The talk presented at ICMP 97 focused on the scaling limits of critical percolation models, and some other systems whose salient features can be described by collections of random lines. In the scaling limit we keep track of features seen on the macroscopic scale, in situations where the short--distance scale at which the system's basic variables are defined is taken to zero. Among the challenging questions are the construction of the limit, and the explanation of some of the emergent properties, in particular the behavior under conformal maps as discussed in [LPS 94]. A descriptive account of the project, and some related open problems, is found in ref. [A] and in [AB] (joint work with A. Burchard) where tools are developed for establishing a curve--regularity condition which plays a key role in the construction of the limit. The formulation of the scaling limit as a random Web measure permits to formulate the question of uniqueness of measure(s) describing systems of random curves satisfying the conditions of independence, Euclidean invariance, and regularity. The uniqueness question remains open; progress on it could shed light on the purported universality of critical behavior and the apparent conformal invariance of the critical measures. The random Web yields also another perspective on some of the equations of conformal field theory which have appeared in this context, such as the equation proposed by J. Cardy [C].

  10. The Bogoliubov free energy functional II. The dilute limit

    E-Print Network [OSTI]

    Marcin Napiórkowski; Robin Reuvers; Jan Philip Solovej

    2015-11-18

    We analyse the canonical Bogoliubov free energy functional at low temperatures in the dilute limit. We prove existence of a first order phase transition and, in the limit $a_0\\to a$, we determine the critical temperature to be $T_{\\rm{c}}=T_{\\rm{fc}}(1+1.49(\\rho^{1/3}a))$ to leading order. Here, $T_{\\rm{fc}}$ is the critical temperature of the free Bose gas, $\\rho$ is the density of the gas, $a$ is the scattering length of the pair-interaction potential $V$, and $a_0=(8\\pi)^{-1}\\widehat{V}(0)$ its first order approximation. We also prove asymptotic expansions for the free energy. In particular, we recover the Lee-Huang-Yang formula in the limit $a_0\\to a$.

  11. Optical limiting effects in nanostructured silicon carbide thin films

    SciTech Connect (OSTI)

    Borshch, A A; Starkov, V N; Volkov, V I; Rudenko, V I; Boyarchuk, A Yu; Semenov, A V

    2013-12-31

    We present the results of experiments on the interaction of nanosecond laser radiation at 532 and 1064 nm with nanostructured silicon carbide thin films of different polytypes. We have found the effect of optical intensity limiting at both wavelengths. The intensity of optical limiting at ? = 532 nm (I{sub cl} ? 10{sup 6} W cm{sup -2}) is shown to be an order of magnitude less than that at ? = 1064 nm (I{sub cl} ? 10{sup 7} W cm{sup -2}). We discuss the nature of the nonlinearity, leading to the optical limiting effect. We have proposed a method for determining the amount of linear and two-photon absorption in material media. (nonlinear optical phenomena)

  12. NEW LIMITS ON GAMMA-RAY EMISSION FROM GALAXY CLUSTERS

    SciTech Connect (OSTI)

    Griffin, Rhiannon D.; Dai, Xinyu; Kochanek, Christopher S. E-mail: xdai@ou.edu

    2014-11-01

    Galaxy clusters are predicted to produce ?-rays through cosmic ray interactions and/or dark matter annihilation, potentially detectable by the Fermi Large Area Telescope (Fermi-LAT). We present a new, independent stacking analysis of Fermi-LAT photon count maps using the 78 richest nearby clusters (z < 0.12) from the Two Micron All Sky Survey cluster catalog. We obtain the lowest limit on the photon flux to date, 2.3 × 10{sup –11} photons cm{sup –2} s{sup –1} (95% confidence) per cluster in the 0.8-100 GeV band, which corresponds to a luminosity limit of 3.5 × 10{sup 44} photons s{sup –1}. We also constrain the emission limits in a range of narrower energy bands. Scaling to recent cosmic ray acceleration and ?-ray emission models, we find that cosmic rays represent a negligible contribution to the intra-cluster energy density and gas pressure.

  13. More on the renormalization group limit cycle in QCD

    SciTech Connect (OSTI)

    Evgeny Epelbaum; Hans-Werner Hammer; Ulf-G. Meissner; Andreas Nogga

    2006-02-26

    We present a detailed study of the recently conjectured infrared renormalization group limit cycle in QCD using chiral effective field theory. We show that small increases in the up and down quark masses, corresponding to a pion mass around 200 MeV, can move QCD to the critical renormalization group trajectory for an infrared limit cycle in the three-nucleon system. At the critical values of the quark masses, the binding energies of the deuteron and its spin-singlet partner are tuned to zero and the triton has infinitely many excited states with an accumulation point at the three-nucleon threshold. At next-to-leading order in the chiral counting, we find three parameter sets where this effect occurs. For one of them, we study the structure of the three-nucleon system using both chiral and contact effective field theories in detail. Furthermore, we calculate the influence of the limit cycle on scattering observables.

  14. A New Limit on the Flux of Cosmic Antihelium

    E-Print Network [OSTI]

    Saeki, T; Orito, S; Ormes, J F; Imori, M; Kimbell, B L; Makida, Y; Matsumoto, H; Matsunaga, H; Mitchell, J; Motoki, M; Nishimura, J; Nozaki, M; Otoba, M; Sanuki, T; Streitmatter, R E; Suzuki, J; Tanaka, K; Ueda, I; Yajima, N; Yamagami, T; Yamamoto, A; Yoshida, T; Yoshimura, K

    1998-01-01

    A very sensitive search for cosmic-ray antihelium was performed using data obtained from three scientific flights of BESS magnetic rigidity spectrometer. We have not observed any antihelium; this places a model-independent upper limit (95 % C.L.) on the antihelium flux of 6*10**(-4) m**(-2)sr**(-1)s**(-1) at the top of the atmosphere in the rigidity region 1 to 16 GV, after correcting for the estimated interaction loss of antihelium in the air and in the instrument. The corresponding upper limit on the Hebar/He flux ratio is 3.1*10**(-6), 30 times more stringent than the limits obtained in similar rigidity regions with magnetic spectrometers previous to BESS.

  15. A New Limit on the Flux of Cosmic Antihelium

    E-Print Network [OSTI]

    T. Saeki; K. Anraku; S. Orito; J. Ormes; M. Imori; B. Kimbell; Y. Makida; H. Matsumoto; H. Matsunaga; J. Mitchell; M. Motoki; J. Nishimura; M. Nozaki; M. Otoba; T. Sanuki; R. Streitmatter; J. Suzuki; K. Tanaka; I. Ueda; N. Yajima; T. Yamagami; A. Yamamoto; T. Yoshida; K. Yoshimura

    1997-10-21

    A very sensitive search for cosmic-ray antihelium was performed using data obtained from three scientific flights of BESS magnetic rigidity spectrometer. We have not observed any antihelium; this places a model-independent upper limit (95 % C.L.) on the antihelium flux of 6*10**(-4) m**(-2)sr**(-1)s**(-1) at the top of the atmosphere in the rigidity region 1 to 16 GV, after correcting for the estimated interaction loss of antihelium in the air and in the instrument. The corresponding upper limit on the Hebar/He flux ratio is 3.1*10**(-6), 30 times more stringent than the limits obtained in similar rigidity regions with magnetic spectrometers previous to BESS.

  16. The Weak-Coupling Limit of Simplicial Quantum Gravity

    E-Print Network [OSTI]

    G. Thorleifsson; P. Bialas; B. Petersson

    1998-12-23

    In the weak-coupling limit, kappa_0 going to infinity, the partition function of simplicial quantum gravity is dominated by an ensemble of triangulations with the ratio N_0/N_D close to the upper kinematic limit. For a combinatorial triangulation of the D--sphere this limit is 1/D. Defining an ensemble of maximal triangulations, i.e. triangulations that have the maximal possible number of vertices for a given volume, we investigate the properties of this ensemble in three dimensions using both Monte Carlo simulations and a strong-coupling expansion of the partition function, both for pure simplicial gravity and a with a suitable modified measure. For the latter we observe a continuous phase transition to a crinkled phase and we investigate the fractal properties of this phase.

  17. New experimental limits on the alpha decays of lead isotopes

    E-Print Network [OSTI]

    J. W. Beeman; F. Bellini; L. Cardani; N. Casali; S. Di Domizio; E. Fiorini; L. Gironi; S. S. Nagorny; S. Nisi; F. Orio; L. Pattavina; G. Pessina; G. Piperno; S. Pirro; E. Previtali; C. Rusconi; C. Tomei; M. Vignati

    2012-12-12

    For the first time a PbWO4 crystal was grown using ancient Roman lead and it was run as a cryogenic detector. Thanks to the simultaneous and independent read-out of heat and scintillation light, the detector was able to discriminate beta/gamma interactions with respect to alpha particles down to low energies. New more stringent limits on the alpha decays of the lead isotopes are presented. In particular a limit of T_{1/2} > 1.4*10^20 y at a 90% C.L. was evaluated for the alpha decay of 204Pb to 200Hg.

  18. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally measured extinction limits at different mixture conditions. To extend the study to a commercial fuel, the flame extinction limit for Birmingham natural gas (a blend of 95% methane, 5% ethane and 5% nitrogen) was experimentally determined and was found to be 3.62% fuel in the air-fuel mixture.

  19. Developing the Theory of Flux Limits from $?$-Ray Cascades

    E-Print Network [OSTI]

    John A. Cairns

    2007-05-18

    Dark matter annihilation and other processes may precipitate a flux of diffuse ultra-high energy $\\gamma$-rays. These $\\gamma$-rays may be observable in present day experiments which observe diffuse fluxes at the GeV scale. Yet the universe is presently opaque to $\\gamma$-rays above 10 TeV. It is generally assumed that cascade radiation is observable at all high energies, however the disparity in energy from production to observation has important consequences for theoretical flux limits. We detail the physics of cascade radiation development and consider the influence of energy and redshift scale on arbitrary flux limits that result from electromagnetic cascade.

  20. A nonlinear Ramsey interferometer operating beyond the Heisenberg limit

    E-Print Network [OSTI]

    S. Choi; B. Sundaram

    2007-09-24

    We show that a dynamically evolving two-mode Bose-Einstein condensate (TBEC) with an adiabatic, time-varying Raman coupling maps exactly onto a nonlinear Ramsey interferometer that includes a nonlinear medium. Assuming a realistic quantum state for the TBEC, namely the SU(2) coherent spin state, we find that the measurement uncertainty of the ``path-difference'' phase shift scales as the standard quantum limit (1/N^{1/2}) where N is the number of atoms, while that for the interatomic scattering strength scales as 1/N^{7/5}, overcoming the Heisenberg limit of 1/N.

  1. 2015 Chevron North Sea Limited Chevron University Partnership

    E-Print Network [OSTI]

    Painter, Kevin

    of the crude oil and natural gas industry, including exploration and production, manufacturing, marketing Limited Overview The University Partnership Program, or UPP, is a global program developed in conjunction of the Chevron Europe, Eurasia and Middle East Exploration and Production Operating Company, one of four

  2. High voltage fault current limiter having immersed phase coils

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2014-04-22

    A fault current limiter including: a ferromagnetic circuit formed from a ferromagnetic material and including at least a first limb, and a second limb; a saturation mechanism surrounding a limb for magnetically saturating the ferromagnetic material; a phase coil wound around a second limb; a dielectric fluid surrounding the phase coil; a gaseous atmosphere surrounding the saturation mechanism.

  3. Fault current limiter with shield and adjacent cores

    DOE Patents [OSTI]

    Darmann, Francis Anthony; Moriconi, Franco; Hodge, Eoin Patrick

    2013-10-22

    In a fault current limiter (FCL) of a saturated core type having at least one coil wound around a high permeability material, a method of suppressing the time derivative of the fault current at the zero current point includes the following step: utilizing an electromagnetic screen or shield around the AC coil to suppress the time derivative current levels during zero current conditions.

  4. Compressive Video Classification for Decision Systems with Limited Resources

    E-Print Network [OSTI]

    Tsakalides, Panagiotis

    by the introduction of efficient computational models is video classification. With the advent of digital TVCompressive Video Classification for Decision Systems with Limited Resources George Tzagkarakis}@ics.forth.gr Abstract--In this paper, we address the problem of video classification from a set of compressed features

  5. Quenched Limit Laws for Transient, One-Dimensional RWRE

    E-Print Network [OSTI]

    Jonathon Peterson

    2008-04-06

    Apr 8, 2008 ... Ladder locations {?n} defined by ?0 = 0, ?n := inf{i > ?n?1 : V(i) < V(?n?1)} ... Heuristics of Quenched Limit Laws. T?n = n. ? i=1. (T?i ? T?i?1 ).

  6. Performance Analysis of Stochastic Network Coverage with Limited ...

    E-Print Network [OSTI]

    2009-10-30

    exact matching of the sensor's coverage profile with the region's threat profile. ... port [4] states that the main decision of where to place a limited amount of ..... We indicate the condition ... analysis needs to be modified with some care. Our main.

  7. On the practical limits to substitution Robert U. Ayres

    E-Print Network [OSTI]

    . Keywords: Weak sustainability Strong sustainability Substitution Resources Technology 1. Introduction to assume­basical- ly for convenience­that every technology can be improved upon and every barrier can "Limits to Growth (Meadows, 1972). The Solow paper "The economics or resources, or the resources

  8. Anelastic Limits for Euler Type Systems Didier Bresch

    E-Print Network [OSTI]

    Métivier, Guy

    the acoustic wave disappears in a pure pressure term for the limit equation. The decoupling also occurs acoustic waves. The first example studied in this paper enters this category: it is a shallow-water type in infinite domains where the fast acoustic waves are rapidly dispersed at infinity and therefore have no time

  9. The infinite interface limit of multiple-region relaxed magnetohydrodynamics

    E-Print Network [OSTI]

    Hudson, Stuart

    with mobile dust grains Phys. Plasmas 20, 032102 (2013) On the formation of m=1, n=1 density snakes Phys. Plasmas 20, 032504 (2013) The effect of emissive biased limiter on the magnetohydrodynamic modes in the IR subject to AIP license or copyright; see http://pop.aip.org/about/rights_and_permissions #12;The infinite

  10. The limit of strength and toughness of steel

    SciTech Connect (OSTI)

    Guo, Zhen

    2001-12-17

    The ideal structural steel combines high strength with high fracture toughness. This dissertation discusses the governing principles of strength and toughness, along with the approaches that can be used to improve these properties and the inherent limits to how strong and tough a steel can be.

  11. Introduction Regeneration of Mediterranean pines is limited by

    E-Print Network [OSTI]

    Herrera, Carlos M.

    Introduction Regeneration of Mediterranean pines is limited by factors acting at different stages Variación del peso y del tiempo de emergencia de las semillas, y crecimiento de las plántulas en una de las semillas y el crecimiento de las plántulas se investigaron en una población de Pinus nigra

  12. Annual and Aggregate Loan Limits 2011-12 Stafford Loans

    E-Print Network [OSTI]

    Dennett, Daniel

    Annual and Aggregate Loan Limits 2011-12 Stafford Loans Medical students 1st year 2nd year 3rd year 4th year Aggregate Subsidized Stafford (maximum amount shown; amount is lower if student has less if annual costs are lower) $34,222 + difference between $8,500 and actual subsidized loan for academic year

  13. Central Limit Theorems for Empirical Processes Based on Stochastic Processes 

    E-Print Network [OSTI]

    Yang, Yuping

    2013-08-13

    ) = n^(?1/2 )Sigma[1_(Y i(t)¬<=y) – P(Yi(t) <= y)] from i=1 to n, t ? E, y ? R. In the case of independent identically distributed samples (that is {Yi(t) : i ? N} are iid), Kuelbs et al. (2013) proved a Central Limit Theorem for ?_n(t, y) for a large...

  14. Service limit state resistance factors for drilled shafts

    E-Print Network [OSTI]

    Misra, Anil; Roberts, L. A.

    2009-01-01

    The analysis of bored piles, or drilled shafts, at the service limit state is important when foundation settlements are critical to the operation of a structure. The t–z method is a widely used soil–structure interaction model for the analysis...

  15. LIMITED POWER BURSTS IN DISTRIBUTED MODELS OF NUCLEAR REACTORS

    E-Print Network [OSTI]

    Bazhenov, Maxim

    LIMITED POWER BURSTS IN DISTRIBUTED MODELS OF NUCLEAR REACTORS M. V. Bazhenov and E. F. Sabaev UDC employed for analyzing reactor dynamics. Equations of this type are used for analyzing the stability of the reactor power, etc. Among these problems the question of the boundedness of reactor power bursts

  16. Intra-Aggregate Mass Transport-Limited Bioavailability of

    E-Print Network [OSTI]

    Shor, Leslie McCabe

    hydrocarbons (PAHs) are a class of common sediment contaminants characterized by low aqueous solubilityIntra-Aggregate Mass Transport-Limited Bioavailability of Polycyclic Aromatic Hydrocarbons mathematical model was developed to describe sediment-pore water partitioning and rapid aqueous-phase diffusion

  17. Fundamental limit of nanophotonic light trapping in solar cells

    E-Print Network [OSTI]

    Fan, Shanhui

    Fundamental limit of nanophotonic light trapping in solar cells Zongfu Yu1 , Aaswath Raman and is becoming increasingly urgent for current solar cell research. The standard theory of light trapping-generation solar cells. The ultimate success of photovoltaic (PV) cell technology requires great advancements

  18. Upper Limits from Counting Experiments with Multiple Pipelines

    E-Print Network [OSTI]

    Patrick J. Sutton

    2010-04-07

    In counting experiments, one can set an upper limit on the rate of a Poisson process based on a count of the number of events observed due to the process. In some experiments, one makes several counts of the number of events, using different instruments, different event detection algorithms, or observations over multiple time intervals. We demonstrate how to generalize the classical frequentist upper limit calculation to the case where multiple counts of events are made over one or more time intervals using several (not necessarily independent) procedures. We show how different choices of the rank ordering of possible outcomes in the space of counts correspond to applying different levels of significance to the various measurements. We propose an ordering that is matched to the sensitivity of the different measurement procedures and show that in typical cases it gives stronger upper limits than other choices. As an example, we show how this method can be applied to searches for gravitational-wave bursts, where multiple burst-detection algorithms analyse the same data set, and demonstrate how a single combined upper limit can be set on the gravitational-wave burst rate.

  19. THEORETICAL INTERPRETATION OF FETCH LIMITED WINDDRIVEN SEA OBSERVATIONS

    E-Print Network [OSTI]

    Zakharov, Vladimir

    is characterized by a constant (in space and time) offshore wind at a normal angle to the straight coastline. Under article. At larger values of the wind fetch, appropriate for open ocean conditions when the advectionTHEORETICAL INTERPRETATION OF FETCH LIMITED WIND­DRIVEN SEA OBSERVATIONS V.E. Zakharov Department

  20. On Aspects of Holographic Thermal QCD in the MQGP Limit

    E-Print Network [OSTI]

    Aalok Misra; Karunava Sil

    2015-10-28

    Some Physics (obtaining lattice-compatible deconfinement temperature, some transport coefficients and Einstein's relation) and Mathematics (torsion classes and supersymmetry) issues pertaining to the delocalized SYZ type IIA mirror of [1] and its M theory uplift in the MQGP limit of [2], are discussed.

  1. ILP and TLP in Shared Memory Applications: A Limit Study 

    E-Print Network [OSTI]

    Fatehi, Ehsan

    2015-04-28

    CMP design. In the first part we introduce DotSim, a trace-driven toolkit designed to explore the limits of instruction and thread-level scaling and identify microarchitectural bottlenecks in multi-threaded applications. DotSim constructs...

  2. L'tude des dangers : contenu, limites, et spcificits franaises

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    L'étude des dangers : contenu, limites, et spécificités françaises Régis Farret INERIS (Institut aujourd'hui de présenter par le menu ce qu'est une étude de dangers 4, mais de prendre un peu de recul pour exposer la méthode d'analyse des risques qu'est l'étude de dangers et de montrer les

  3. Bioenergy Chances and Limits German National Academy of Sciences Leopoldina

    E-Print Network [OSTI]

    Roegner, Matthias

    clean renewable energy carrier; its oxidation for production of heat or electricity yields water (H2 O on the electrolysis of wa- ter. Large-scale production usually relies on costly high-pressure and high to have a promising future but is currently limited by costs that are about ten times higher than those

  4. Solar panels are cost intensive, have limitations with respect to

    E-Print Network [OSTI]

    Langendoen, Koen

    Solar panels are cost intensive, have limitations with respect to where they can be integrated of the window, integrated in the window frames, strip-shaped CIGS PV solar cells convert the light the CIGS PV solar cells in the form of strips at the edges of the window in the window frame. These solar

  5. HYBRID LIMIT CYCLES AND HYBRID POINCARE-BENDIXSON

    E-Print Network [OSTI]

    Johansson, Karl Henrik

    HYBRID LIMIT CYCLES AND HYBRID POINCAR´E-BENDIXSON Slobodan N. Simi´c Department of Electrical regular hybrid systems with no branching (Simi´c et al., 2000a). The first one provides a condition for asymptotic stability of hybrid closed orbits in terms of contraction-expansion rates of resets and flows

  6. Robust Utility Maximization with Limited Downside Risk in Incomplete Markets

    E-Print Network [OSTI]

    Weber, Stefan

    Robust Utility Maximization with Limited Downside Risk in Incomplete Markets Anne Gundel Humboldt) in an incomplete market. Downside risk is constrained by a robust version of utility-based shortfall risk. We-dimensional analogue of f-divergences which generalize the notion of relative entropy. Key words: Robust utility

  7. Why Software Developers Should Support a New, Limited Patent

    E-Print Network [OSTI]

    Hollaar, Lee A.

    Why Software Developers Should Support a New, Limited Patent Lee A. Hollaar Professor, School Patent Conference, Brussels, 15-16 May 2007. The latest version of this paper, as well as the paper on which it is based, can be found at http://digital-law-online.info/papers/lah/mini-patent.htm Comments

  8. Fault current limiter and alternating current circuit breaker

    DOE Patents [OSTI]

    Boenig, H.J.

    1998-03-10

    A solid-state circuit breaker and current limiter are disclosed for a load served by an alternating current source having a source impedance, the solid-state circuit breaker and current limiter comprising a thyristor bridge interposed between the alternating current source and the load, the thyristor bridge having four thyristor legs and four nodes, with a first node connected to the alternating current source, and a second node connected to the load. A coil is connected from a third node to a fourth node, the coil having an impedance of a value calculated to limit the current flowing therethrough to a predetermined value. Control means are connected to the thyristor legs for limiting the alternating current flow to the load under fault conditions to a predetermined level, and for gating the thyristor bridge under fault conditions to quickly reduce alternating current flowing therethrough to zero and thereafter to maintain the thyristor bridge in an electrically open condition preventing the alternating current from flowing therethrough for a predetermined period of time. 9 figs.

  9. Fault current limiter and alternating current circuit breaker

    DOE Patents [OSTI]

    Boenig, Heinrich J. (Los Alamos, NM)

    1998-01-01

    A solid-state circuit breaker and current limiter for a load served by an alternating current source having a source impedance, the solid-state circuit breaker and current limiter comprising a thyristor bridge interposed between the alternating current source and the load, the thyristor bridge having four thyristor legs and four nodes, with a first node connected to the alternating current source, and a second node connected to the load. A coil is connected from a third node to a fourth node, the coil having an impedance of a value calculated to limit the current flowing therethrough to a predetermined value. Control means are connected to the thyristor legs for limiting the alternating current flow to the load under fault conditions to a predetermined level, and for gating the thyristor bridge under fault conditions to quickly reduce alternating current flowing therethrough to zero and thereafter to maintain the thyristor bridge in an electrically open condition preventing the alternating current from flowing therethrough for a predetermined period of time.

  10. The Omega-Infinity Limit of Single Spikes

    E-Print Network [OSTI]

    Minos Axenides; Emmanuel Floratos; Georgios Linardopoulos

    2015-11-11

    A new infinite-size limit of strings in RxS2 is presented. The limit is obtained from single spike strings by letting their angular velocity omega become infinite. We derive the energy-momenta relation of omega-infinity single spikes as their linear velocity v-->1 and their angular momentum J-->1. Generally, the v-->1, J-->1 limit of single spikes is singular and has to be excluded from the spectrum and be studied separately. We discover that the dispersion relation of omega-infinity single spikes contains logarithms in the limit J-->1. This result is somewhat surprising, since the logarithmic behavior in the string spectra is typically associated with their motion in non-compact spaces such as AdS. Omega-infinity single spikes seem to completely cover the surface of the 2-sphere they occupy, so that they may essentially be viewed as some sort of "brany strings". A proof of the sphere-filling property of omega-infinity single spikes is given in the appendix.

  11. The Omega-Infinity Limit of Single Spikes

    E-Print Network [OSTI]

    Axenides, Minos; Linardopoulos, Georgios

    2015-01-01

    A new infinite-size limit of strings in RxS2 is presented. The limit is obtained from single spike strings by letting their angular velocity omega become infinite. We derive the energy-momenta relation of omega-infinity single spikes as their linear velocity v-->1 and their angular momentum J-->1. Generally, the v-->1, J-->1 limit of single spikes is singular and has to be excluded from the spectrum and be studied separately. We discover that the dispersion relation of omega-infinity single spikes contains logarithms in the limit J-->1. This result is somewhat surprising, since the logarithmic behavior in the string spectra is typically associated with their motion in non-compact spaces such as AdS. Omega-infinity single spikes seem to completely cover the surface of the 2-sphere they occupy, so that they may essentially be viewed as some sort of "brany strings". A proof of the sphere-filling property of omega-infinity single spikes is given in the appendix.

  12. TimeAsymptotic Limit of Solutions of a Combustion Problem

    E-Print Network [OSTI]

    Ferguson, Thomas S.

    Time­Asymptotic Limit of Solutions of a Combustion Problem Tong Li Department of Mathematics University of California, Los Angeles Department of Mathematics University of Iowa Abstract. A combustion, 35B50, 76L05, 76J10. 1 Introduction We consider the combustion problem u t + ( 1 2 u 2 \\Gamma qz) x

  13. Data Integrity Limitations in Highly Secure Systems Cynthia E. Irvine

    E-Print Network [OSTI]

    Irvine, Cynthia E.

    or destruction." [14] A person who has integrity is identified as being one who acts based on a setData Integrity Limitations in Highly Secure Systems Cynthia E. Irvine Department of Computer that is higher in integrity than the integrity level of the COTS components. 1 Introduction Data integrity

  14. Effects of Quantum Confinement on the Doping Limit of Semiconductor

    E-Print Network [OSTI]

    Wu, Junqiao

    . The magnitude of this effect in a given material is found to be determined by two material properties of semiconductor nanostructures in terms of their fundamental material parameters. Doping limits in various bulk are generated in semiconductor materials in response to extrinsic doping so as to pull EF back toward EFS

  15. UNCERTAINTY MEASURES AND LIMITING DISTRIBUTIONS FOR FILAMENT ESTIMATION

    E-Print Network [OSTI]

    UNCERTAINTY MEASURES AND LIMITING DISTRIBUTIONS FOR FILAMENT ESTIMATION By Yen-Chi Chen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 1. Introduction. A filament is a one-dimensional, smooth, connected structure embedded in a multi-dimensional space. Filaments arise in many applications. For example, matter in the universe tends to concentrate

  16. One-level limit order books with sparsity and memory

    E-Print Network [OSTI]

    2014-10-17

    Oct 17, 2014 ... risk management. ... Let us start by describing Cont and Larrard's framework for the dynamics of the level I of the book. ..... of right-continuous functions with left limits, D, equipped with the Skorohod topology (see, e.g., Whitt.

  17. Uranium Reduction in Sediments under Diffusion-Limited Transport of

    E-Print Network [OSTI]

    Hazen, Terry

    Uranium Reduction in Sediments under Diffusion-Limited Transport of Organic Carbon T E T S U K, Chicago, Illinois 60637 Costly disposal of uranium (U) contaminated sediments is motivating research. Introduction Uranium (U) is an important subsurface contaminant at sites associated with its mining

  18. The Family of "Circle Limit III" Escher Patterns Douglas Dunham

    E-Print Network [OSTI]

    Dunham, Doug

    consider the third one of this sequence, Circle Limit III -- a pattern of fish, to be the most beautiful. In this woodcut, four fish meet at right fin tips, three fish meet at left fin tips, and three fish meet at their noses. The backbones of the fish are aligned along white circular arcs. Fish on one arc are the same

  19. ORIGINAL PAPER Confidence levels for tsunami-inundation limits

    E-Print Network [OSTI]

    Goldfinger, Chris

    ORIGINAL PAPER Confidence levels for tsunami-inundation limits in northern Oregon inferred from / Accepted: 25 August 2009 Ó Springer Science+Business Media B.V. 2009 Abstract To explore the local tsunami coseismic deformations for simulation of tsunami inundation at Cannon Beach, Oregon. Maximum A brief summary

  20. NORTHWESTERN UNIVERSITY -OFFICE OF RESEARCH DEVELOPMENT Limited Submission Funding Opportunity

    E-Print Network [OSTI]

    Chisholm, Rex L.

    , including areas as cognitive science and neuroscience, clean energy, and food security, as well as other information to support policy-making decisions and establishing spinoff companies, license agreements or other. LIMIT ON NUMBER OF PROPOSALS PER ORGANIZATION A single organization may submit a maximum of three

  1. Exploring the limit of metazoan thermal tolerance via comparative proteomics

    E-Print Network [OSTI]

    Girguis, Peter R.

    around hydrothermal vents are highly variable, ranging from near freezing up to 3008C. Never- theless transport chain enable pronounced thermotolerance. Ultimately, oxidative stress may be the key factor instability [2], and limitations in gas transport have all been implicated as possible modes of physiological

  2. Risk-Limiting Dispatch for Integrating Renewable Power Ram Rajagopal

    E-Print Network [OSTI]

    Varaiya, Pravin

    clean energy. California's goal is 33% by 2020. The goals are promoted by `renewable portfolio standardsRisk-Limiting Dispatch for Integrating Renewable Power Ram Rajagopal Stanford Univ ramr-stage, stochastic de- cision problem. At each stage, the system operator (SO) purchases forward energy and reserve

  3. Turbulence, Transport and the Density Limit in Magnetic Fusion Experiments

    E-Print Network [OSTI]

    Greenwald, Martin

    Program) 3 Magnetic Confinement Takes advantage of the motion of charged particles in a magnetic field) · In toroidal devices, plasma is confined by Poloidal magnetic fields #12;DESPITE THE CHALLENGES, PROGRESS HAS AND MAGNETIC CONFINEMENT· · · · THE DENSITY LIMIT PROBLEM INTERLUDE ON TRANSPORT AND TURBULENCE TOWARDS

  4. Perturbation analysis of entrainment in a micromechanical limit cycle oscillator

    E-Print Network [OSTI]

    Rand, Richard H.

    Perturbation analysis of entrainment in a micromechanical limit cycle oscillator Manoj Pandey with experiments. Details of the slow flow behavior explain how and where transitions into and out of entrainment; MEMS; Bifurcation; Perturbation 1. Introduction Entrainment is the phenomenon in which freely

  5. CONFIDENCE LIMITS FOR POPULATION PROJECTIONS WHEN VITAL RATES VARY RANDOMLY

    E-Print Network [OSTI]

    CONFIDENCE LIMITS FOR POPULATION PROJECTIONS WHEN VITAL RATES VARY RANDOMLY TIM GERRODE, age distribution, and vital rates are known (e.g., Leslie 1945; Keyfitz 1968). Such population rates are available. However, there is uncertainty in such projections. First, we rarely know vital

  6. Torque limit of PM motors for field-weakening region operation

    DOE Patents [OSTI]

    Royak, Semyon (Beachwood, OH); Harbaugh, Mark M. (Richfield, OH)

    2012-02-14

    The invention includes a motor controller and technique for controlling a permanent magnet motor. In accordance with one aspect of the present technique, a permanent magnet motor is controlled by receiving a torque command, determining a physical torque limit based on a stator frequency, determining a theoretical torque limit based on a maximum available voltage and motor inductance ratio, and limiting the torque command to the smaller of the physical torque limit and the theoretical torque limit. Receiving the torque command may include normalizing the torque command to obtain a normalized torque command, determining the physical torque limit may include determining a normalized physical torque limit, determining a theoretical torque limit may include determining a normalized theoretical torque limit, and limiting the torque command may include limiting the normalized torque command to the smaller of the normalized physical torque limit and the normalized theoretical torque limit.

  7. DE-SOL-0003641 Amendment 002

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate12/21/2012 000001 3 1 13.

  8. DE-SOL-0003641 Amendment 003

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 Gas Hydrate12/21/2012 000001 3 1 13.3641

  9. Sol-Gel Deposited Electrochromic Coatings

    E-Print Network [OSTI]

    Ozer, N.

    2010-01-01

    Deposited Electrochromic Coatings Nilgun Ozer and Carl M.the Optical Interference Coatings Topical Meeting, Tucson,Deposited Electrochromic Coatings Nilgun Ozer and Carl M.

  10. DE-SOL-0008449 REPORTING REQUIREMENTS CHECKLIST

    National Nuclear Security Administration (NNSA)

    Independence Avenue SW Washington DC 20585 E. Task order project support Appendix A: Web-Based Reporting System Requirements Web-Based Reporting System Requirements 1....

  11. DE-SOL-0008445 Attachment L-4

    National Nuclear Security Administration (NNSA)

    4. Contract Value: Initial Amount Current or Final Amount* Estimated Cost Fixed Price FeeProfit Total Value *Should reflect any contract value increases...

  12. ENERGIA DEL SOL Ts = 5780 K

    E-Print Network [OSTI]

    Batiste, Oriol

    es basa la conversi´o de la radiaci´o solar en calor. #12;TRANSFER`ENCIA DE CALOR PER RADIACI´O Llei a utilitzar-la. Conversi´o en calor Conversi´o directa en electricitat Tractarem primer els principis en que

  13. Sol Voltaics AB | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North| OpenSolution Jump

  14. SolFocus | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North| OpenSolution

  15. Pro Sol Energia SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPIProtectio1975)Energy Technology JumpWilliam County,| OpenEIPrismIntegris

  16. Consolidated Edison Sol Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar EnergyLawler,CoalConcordia Electric Coop, IncIllinois)Consolidated

  17. Sociedade do Sol Sosol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery Technology CoWanpingSilveiraSmallSmarrSnapping

  18. Sol e Suisse AG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery TechnologySocovoltaic Systems Jump to:SoftSuisse AG Jump to:

  19. Sol3g SL | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery TechnologySocovoltaic Systems Jump to:SoftSuisse AG Jump

  20. SolFocus Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery TechnologySocovoltaic Systems Jump to:SoftSuisse AG