National Library of Energy BETA

Sample records for oven emissions inorganic

  1. Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M206 Mechanical Convection Oven The M206 oven is dedicated to CAMD staff use only. M326 Mechanical Convection Oven Located next to the spinners, the M326 oven is availabe to...

  2. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F.; Hofherr, K.

    1995-12-01

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  3. Lesson 9 - Solar Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fridell * Place the oven on a sunny flat surface facing the sun and use masking tape to prop the aluminum flap open. Sunlight should reflect off the flap and into the solar oven...

  4. Making a Solar Oven

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students make solar ovens. Student background information is provided. The expected outcome is that students will learn about solar energy transfer.

  5. Portable oven air circulator

    DOE Patents [OSTI]

    Jorgensen, Jorgen A. (Bloomington, MN); Nygren, Donald W. (Minneapolis, MN)

    1983-01-01

    A portable air circulating apparatus for use in cooking ovens which is used to create air currents in the oven which transfer heat to cooking foodstuffs to promote more rapid and more uniform cooking or baking, the apparatus including a motor, fan blade and housing of metallic materials selected from a class of heat resistant materials.

  6. Combustion and inorganic emissions of ground waste tires

    SciTech Connect (OSTI)

    Levendis, Y.A.; Atal, A.; Steciak, J.

    1995-12-31

    An experimental study was undertaken to assess the combustion characteristics and emissions of SO{sub 2}, NO{sub x} and CO{sub 2} gases from ground waste tires. Results were contrasted with those obtained from burning pulverized coal. Laboratory bench-scale experiments were conducted in a drop-tube, laminar-flow furnace, in air at fuel-lean conditions, at gas temperatures ranging from 1300 K to 1600 K. Two particle size cuts were burned from both materials, 75-90 {mu}m and 180-212 {mu}m. Blends of coal and tire particles, at equal weight ratios, were also burned. Pyrometric and cinematographic observations revealed that the coal particles exhibited distinct volatile and char combustion phases, while tire particles exhibited a distinct primary volatile phase followed by a char combustion phase, which was accompanied by burning of secondary pyrolysis products. SO{sub 2} emissions of burning ground tires increased from 160 to 500 ppm as the temperature increased from 1300 K to 1600 K. Combustion of coal produced SO{sub 2} emissions in the neighborhood of 200-300 ppm (corresponding to 40 to 60 wt% of its sulfur content) independent of the gas temperature. The blend of coal and tire particles (equal mass ratios) exhibited SO{sub 2} values which fell in between the above. NO{sub x} emissions were constant at approximately 175 ppm for tire crumb (corresponding to approximately 45 wt% of its fuel nitrogen content) and 625 ppm for coal (corresponding to 55 wt% of its fuel nitrogen content) in the temperature range studied. CO{sub 2} emissions from tire were 8-9 molar %, while for coal particles they were 5-7 molar %; the upper limits corresponded to approximately 100% combustion efficiency. As a means to reduce the SO{sub 2} emissions, pulverized coal and tire crumb were fluidized together with particles of a calcium bearing sorbent - calcium magnesium acetate (CMA). CMA has been identified as an effective SO{sub 2} scrubbing agent in previous studies.

  7. Inorganic aerosols responses to emission changes in Yangtze River Delta, China

    SciTech Connect (OSTI)

    Dong, Xinyi; Li, Juan; Fu, Joshua S.; Gao, Yang; Huang, Kan; Zhuang, Guoshun

    2014-05-15

    China announced the Chinese National Ambient Air Quality standards (CH-NAAQS) on Feb. 29th, 2012, and PM2.5 is for the very first time included in the standards as a criteria pollutant. In order to probe into PM2.5 pollution over Yangtze River Delta, which is one of the major urban clusters hosting more than 80 million people in China, the integrated MM5/CMAQ modeling system is applied for a full year simulation to examine the PM2.5 concentration and seasonality, and also the inorganic aerosols responses to precursor emission changes. Both simulation and observation demonstrated that, inorganic aerosols have substantial contributions to PM2.5 over YRD, ranging from 37.1% in November to 52.8% in May. Nocturnal production of nitrate (NO3-) through heterogeneous hydrolysis of N2O5 was found significantly contribute to high NO3-concentration throughout the year. We also found that in winter NO3- was even increased under nitrogen oxides (NOx) emission reduction due to higher production of N2O5 from the excessive ozone (O3) introduced by attenuated titration, which further lead to increase of ammonium (NH4+) and sulfate (SO42-), while other seasons showed decrease response of NO3-. Sensitivity responses of NO3- under anthropogenic VOC emission reduction was examined and demonstrated that in urban areas over YRD, NO3- formation was actually VOC sensitive due to the O3-involved nighttime chemistry of N2O5, while a reduction of NOx emission may have counter-intuitive effect by increasing concentrations of inorganic aerosols.

  8. Oven wall panel construction

    DOE Patents [OSTI]

    Ellison, Kenneth; Whike, Alan S.

    1980-04-22

    An oven roof or wall is formed from modular panels, each of which comprises an inner fabric and an outer fabric. Each such fabric is formed with an angle iron framework and somewhat resilient tie-bars or welded at their ends to flanges of the angle irons to maintain the inner and outer frameworks in spaced disposition while minimizing heat transfer by conduction and permitting some degree of relative movement on expansion and contraction of the module components. Suitable thermal insulation is provided within the module. Panels or skins are secured to the fabric frameworks and each such skin is secured to a framework and projects laterally so as slidingly to overlie the adjacent frame member of an adjacent panel in turn to permit relative movement during expansion and contraction.

  9. Ovenized microelectromechanical system (MEMS) resonator

    DOE Patents [OSTI]

    Olsson, Roy H; Wojciechowski, Kenneth; Kim, Bongsang

    2014-03-11

    An ovenized micro-electro-mechanical system (MEMS) resonator including: a substantially thermally isolated mechanical resonator cavity; a mechanical oscillator coupled to the mechanical resonator cavity; and a heating element formed on the mechanical resonator cavity.

  10. Solar Pizza Oven Box k - 6

    Office of Environmental Management (EM)

    Ready to Build? BUILD A PIZZA BOX SOLAR OVEN Background The sun is hot enough to bake food. Here's how to make a simple solar oven that gets hot enough to warm up cookies and other...

  11. A fully integrated oven controlled microelectromechanical oscillator --

    Office of Scientific and Technical Information (OSTI)

    Part I. Design and fabrication (Journal Article) | DOE PAGES - Part I. Design and fabrication This content will become publicly available on June 24, 2016 Title: A fully integrated oven controlled microelectromechanical oscillator -- Part I. Design and fabrication Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift

  12. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  13. Solar Pizza Oven Box k - 6

    Energy Savers [EERE]

    Ready to Build? BUILD A PIZZA BOX SOLAR OVEN Background The sun is hot enough to bake food. Here's how to make a simple solar oven that gets hot enough to warm up cookies and other treats, like s'mores. It won't get really hot, though, so you can't bake things in it and you won't burn yourself when playing with it. Be sure to have an adult help you with this! Materials - One pizza box from a local pizza delivery store. Here's a good excuse to ask your parents to order pizza tonight! - Newspapers

  14. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  15. Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency | Department of Energy Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency This process heating tip sheet recommends using lower flammable limit monitoring equipment to improve oven efficiency. PROCESS HEATING TIP SHEET #11 PDF icon Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency (October 2007) More Documents & Publications Check Burner

  16. Covered Product Category: Commercial Ovens | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ovens Covered Product Category: Commercial Ovens The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial ovens, which is a product category covered by the ENERGY STAR program. Federal laws and requirements mandate that agencies purchase products that are covered by ENERGY STAR or FEMP in all acquisitions that are not specifically exempted by law. Meeting Energy Efficiency Requirements for Commercial Ovens ENERGY STAR sets efficiency requirements for commercial

  17. Multiple delivery cesium oven system for negative ion sources

    SciTech Connect (OSTI)

    Bansal, G.; Bhartiya, S.; Pandya, K.; Bandyopadhyay, M.; Singh, M. J.; Soni, J.; Gahlaut, A.; Parmar, K. G.; Chakraborty, A. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2012-02-15

    Distribution of cesium in large negative ion beam sources to be operational in ITER, is presently based on the use of three or more cesium ovens, which operate simultaneously and are controlled remotely. However, use of multiple Cs ovens simultaneously is likely to pose difficulties in operation and maintenance of the ovens. An alternate method of Cs delivery, based on a single oven distribution system is proposed as one which could reduce the need of simultaneous operation of many ovens. A proof of principle experiment verifying the concept of a multinozzle distributor based Cs oven has been carried out at Institute for Plasma Research. It is also observed that the Cs flux is not controlled by Cs reservoir temperature after few hours of operation but by the temperature of the distributor which starts behaving as a Cs reservoir.

  18. Prolongation technologies for campaign life of tall oven

    SciTech Connect (OSTI)

    Doko, Yoshiji; Saji, Takafumi; Kitayama, Yoshiteru; Yoshida, Shuhei

    1997-12-31

    In Kashima Steel Works, 25-year-old 7-meter-high coke ovens have damage on their walls. However, by using new methods of internal in-situ investigation, ceramic welding for the extended central and upper portions of coke ovens has prolonged the campaign life for over 40 years without large-scale hot repair. In this paper, introduction of these new methods, its application in Kashima and the policy of repairing the tall coke oven are reported.

  19. Solar Oven, Take One: FAIL | Department of Energy

    Energy Savers [EERE]

    Oven, Take One: FAIL Solar Oven, Take One: FAIL June 15, 2011 - 11:56am Addthis Our homemade solar oven. | Courtesy of Moon Choe Our homemade solar oven. | Courtesy of Moon Choe Moon Choe EERE Summer Intern The first time I ever saw solar cookers was on the news in the summer of 2009 (though that would make it their winter, as I was living in Chile at the time), as part of a development project in the north, which is mostly desert. I had no idea solar cookers were so markedly simple in all

  20. Center for Nanophase Materials Sciences (CNMS) - Inorganic Synthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inorganic Synthesis

  1. Build a Pizza Box Solar Oven | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Build a Pizza Box Solar Oven Build a Pizza Box Solar Oven Below is information about the student activity/lesson plan from your search. Grades K-4, 5-8, 9-12 Subject Solar Summary Check out this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven. Curriculum Science, Visual Arts, Language Arts Plan Time One class period Materials One pizza box from a local pizza delivery store, tape, scissors, black construction paper, clear plastic wrap, aluminum foil,

  2. ISSUANCE 2015-07-23: Energy Conservation Program: Energy Conservation Standards for Residential Conventional Ovens

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Residential Conventional Ovens, Comment Period Extension

  3. Container for heat treating materials in microwave ovens

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Farragut, TN); Dykes, Norman L. (Oak Ridge, TN); Kimrey, Jr., Harold D. (Knoxville, TN); Mills, James E. (Knoxville, TN)

    1989-01-01

    The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed of top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achieveable in the oven without the container.

  4. A container for heat treating materials in microwave ovens

    DOE Patents [OSTI]

    Holcombe, C.E.; Dykes, N.L.; Kimrey, H.D. Jr.; Mills, J.E.

    1988-01-26

    The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed to top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation for reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achievable in the oven without the container.

  5. Operating and maintenance benefits of automated oven wall temperature measurement

    SciTech Connect (OSTI)

    Leuchtmann, K.P.; Hinz, D.; Bergbau, D.; Platts, M.

    1997-12-31

    For a very long time and regardless of all shortcomings associated with it, the manual measurement of the heating flue temperature has been the only method of monitoring the temperature prevailing in a coke oven battery and discovering weak points in the heating system. In the course of the last few years a number of automated temperature measuring systems have been developed that are intended to replace or supplement the manual heating flue measurement system. These measuring systems and their advantages/disadvantages are briefly described in this paper. Additionally, operational experience gathered with the oven chamber wall temperature measuring system is discussed in detail.

  6. Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Updates the Social Cost of Carbon | Department of Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon August 21, 2013 - 9:18am Addthis A typical microwave is used to heat food for about 70 hours each year, but continues to use electricity for the remaining 8,690 hours of the year to power the electronic controls and display. On

  7. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  8. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  9. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L.

    1997-12-31

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  10. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  11. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D.

    1997-12-31

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  12. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E.

    1995-12-01

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  13. Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emission intensities and line ratios from a fast neutral helium beam J-W. Ahn a͒ Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA D. Craig, b͒ G. Fiksel, and D. J. Den Hartog Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA and Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, Madison, Wisconsin 53706, USA J. K. Anderson Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA M. G.

  14. Emissions

    Office of Scientific and Technical Information (OSTI)

    Emissions of Greenhouse Gases from the Use of Transportation Fuels and Electricity Volume 1: Main Text ::_:_ii_i!!._i_!!!i_!!_!_!i!ii_!).._i!iiii!!_i!i_!!_iii!i!_ii_iii!!_i!i!ii_!i!!_!!!_ii!!_)i!i_i_i!!ii!i!_!!ii!!i_!i_!iii_!!i!i_i!i!!_!ii_i!i._!ii_i!i!_i!_!!!i!!_!_!!_!_!!!!i_!_!!!i_:``.!ii!!_i_i_i!!!_!_!_ii_i_!_i_i_!!i!i!i!!!ii:!i_i!_ii!_!!ii_! ,qh_...dllri" :._m..41W..- ,,mm,m_ - Centerfor TransportationResearch Argonne NationalLaboratory Operated by lhe University of Chicago, under

  15. New Energy Efficiency Standards for Microwave Ovens to Save Consumers on Energy Bills

    Broader source: Energy.gov [DOE]

    U.S. Energy Secretary Ernest Moniz announced today that the Energy Department has finalized new energy efficiency standards for microwave ovens that will save consumers nearly $3 billion on their energy bills through 2030.

  16. Methods for reduction of charging emissions

    SciTech Connect (OSTI)

    Schuecker, F.J.; Schulte, H.

    1997-12-31

    One of the most critical subjects in coking plants are charging emissions. The paper reviews the systems that have been used over the years to reduce charging emissions. The advantages and disadvantages are summarized for the following systems: Double collecting main with aspiration on both oven sides; Single collecting main with/without aspiration via standpipe, and extraction and cleaning of charging gas on charging car; Single collecting main with aspiration via standpipe and pretreatment of charging gas on the charging car as well as additional stationary exhaust and cleaning of charging gas; Single collecting main with aspiration via single standpipe; and Single collecting main with simultaneous aspiration via two standpipes and a U-tube connecting the oven chamber with the neighboring oven. The paper then briefly discusses prerequisites for reduction of charging emissions.

  17. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  18. ISSUANCE 2016-02-09: Energy Conservation Program: Energy Conservation Standards for Standby Mode and Off Mode for Microwave Ovens; Correction

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Standby Mode and Off Mode for Microwave Ovens; Correction

  19. Nanomaterials: Organic and Inorganic for Next-Generation Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy Nanomaterials: Organic and Inorganic for Next-Generation Diesel Technologies Nanomaterials: Organic and Inorganic for Next-Generation Diesel Technologies 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_vanderwal.pdf More Documents & Publications 21st Century Truck

  20. Supported inorganic membranes

    DOE Patents [OSTI]

    Sehgal, Rakesh; Brinker, Charles Jeffrey

    1998-01-01

    Supported inorganic membranes capable of molecular sieving, and methods for their production, are provided. The subject membranes exhibit high flux and high selectivity. The subject membranes are substantially defect free and less than about 100 nm thick. The pores of the subject membranes have an average critical pore radius of less than about 5 .ANG., and have a narrow pore size distribution. The subject membranes are prepared by coating a porous substrate with a polymeric sol, preferably under conditions of low relative pressure of the liquid constituents of the sol. The coated substrate is dried and calcined to produce the subject supported membrane. Also provided are methods of derivatizing the surface of supported inorganic membranes with metal alkoxides. The subject membranes find use in a variety of applications, such as the separation of constituents of gaseous streams, as catalysts and catalyst supports, and the like.

  1. EERE Success Story-Energy Efficiency Standards for Microwave Ovens Saves

    Office of Environmental Management (EM)

    Consumers Energy and Updates the Social Cost of Carbon | Department of Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon EERE Success Story-Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon August 21, 2013 - 9:18am Addthis A typical microwave is used to heat food for about 70 hours each year, but continues to use electricity for the remaining 8,690 hours of the year to power

  2. Using Coke Oven Gas in a Blast Furnace Saves Over $6 Million Annually at a Steel Mill (U.S. Steel Edgar Thompson Plant)

    SciTech Connect (OSTI)

    2000-12-01

    Like most steel companies, U.S. Steel (USS) had been using coke oven gas (COG), a by-product of coke manufacturing, as a fuel in their coke ovens, boilers, and reheat furnaces.

  3. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  4. ARM - Measurement - Inorganic chemical composition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsInorganic chemical composition ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Inorganic chemical composition The chemical composition of an aerosol, with the exception of those with hydrocarbons, and usually including carbides, oxides of carbon, metallic carbonates, carbon sulfur compounds, and carbon nitrogen compounds. Categories Aerosols Instruments The above measurement is

  5. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  6. A fully integrated oven controlled microelectromechanical oscillator Part II. Characterization and measurement

    SciTech Connect (OSTI)

    Wojciechowski, Kenneth E.; Olsson, Roy H.

    2015-06-24

    Our paper reports the measurement and characterization of a fully integrated oven controlled microelectromechanical oscillator (OCMO). The OCMO takes advantage of high thermal isolation and monolithic integration of both aluminum nitride (AlN) micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. Operation at microscale sizes allows implementation of high thermal resistance platform supports that enable thermal stabilization at very low-power levels when compared with the state-of-the-art oven controlled crystal oscillators. A prototype OCMO has been demonstrated with a measured temperature stability of -1.2 ppb/C, over the commercial temperature range while using tens of milliwatts of supply power and with a volume of 2.3 mm3 (not including the printed circuit board-based thermal control loop). Additionally, due to its small thermal time constant, the thermal compensation loop can maintain stability during fast thermal transients (>10 C/min). This new technology has resulted in a new paradigm in terms of power, size, and warm up time for high thermal stability oscillators.

  7. A fully integrated oven controlled microelectromechanical oscillator -- Part I. Design and fabrication

    SciTech Connect (OSTI)

    Wojciechowski, Kenneth E.; Baker, Michael S.; Clews, Peggy J.; Olsson, Roy H.

    2015-06-24

    Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift and electronic properties (Q, resistance) of both the resonant tank circuit and feedback electronics required to form an electronic oscillator. An OCMO is presented that takes advantage of high thermal isolation and monolithic integration of both micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. This was achieved by developing a processing technique where both silicon-on-insulator complementary metal-oxide-semiconductor (CMOS) circuitry and piezoelectric aluminum nitride, AlN, micromechanical resonators are placed on a suspended platform within a standard CMOS integrated circuit. Operation at microscale sizes achieves high thermal resistances (~10 C/mW), and hence thermal stabilization of the oscillators at very low-power levels when compared with the state-of-the-art ovenized crystal oscillators, OCXO. This constant resistance feedback circuit is presented that incorporates on platform resistive heaters and temperature sensors to both measure and stabilize the platform temperature. Moreover, the limits on temperature stability of the OCMO platform and oscillator frequency imposed by the gain of the constant resistance feedback loop, placement of the heater and temperature sensing resistors, as well as platform radiative and convective heat losses are investigated.

  8. A Fully Integrated Oven Controlled Microelectromechanical OscillatorPart II. Characterization and Measurement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wojciechowski, Kenneth E.; Olsson, Roy H.

    2015-06-24

    Our paper reports the measurement and characterization of a fully integrated oven controlled microelectromechanical oscillator (OCMO). The OCMO takes advantage of high thermal isolation and monolithic integration of both aluminum nitride (AlN) micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. Operation at microscale sizes allows implementation of high thermal resistance platform supports that enable thermal stabilization at very low-power levels when compared with the state-of-the-art oven controlled crystal oscillators. A prototype OCMO has been demonstrated with a measured temperature stability of -1.2 ppb/C, over the commercial temperature range while using tensmoreof milliwatts of supply power and with a volume of 2.3 mm3 (not including the printed circuit board-based thermal control loop). Additionally, due to its small thermal time constant, the thermal compensation loop can maintain stability during fast thermal transients (>10 C/min). This new technology has resulted in a new paradigm in terms of power, size, and warm up time for high thermal stability oscillators.less

  9. A fully integrated oven controlled microelectromechanical oscillator – Part II. Characterization and measurement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wojciechowski, Kenneth E.; Olsson, Roy H.

    2015-06-24

    Our paper reports the measurement and characterization of a fully integrated oven controlled microelectromechanical oscillator (OCMO). The OCMO takes advantage of high thermal isolation and monolithic integration of both aluminum nitride (AlN) micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. Operation at microscale sizes allows implementation of high thermal resistance platform supports that enable thermal stabilization at very low-power levels when compared with the state-of-the-art oven controlled crystal oscillators. A prototype OCMO has been demonstrated with a measured temperature stability of -1.2 ppb/°C, over the commercial temperature range while using tensmore » of milliwatts of supply power and with a volume of 2.3 mm3 (not including the printed circuit board-based thermal control loop). Additionally, due to its small thermal time constant, the thermal compensation loop can maintain stability during fast thermal transients (>10 °C/min). This new technology has resulted in a new paradigm in terms of power, size, and warm up time for high thermal stability oscillators.« less

  10. A fully integrated oven controlled microelectromechanical oscillatorPart I. Design and fabrication

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wojciechowski, Kenneth E.; Baker, Michael S.; Clews, Peggy J.; Olsson, Roy H.

    2015-06-24

    Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift and electronic properties (Q, resistance) of both the resonant tank circuit and feedback electronics required to form an electronic oscillator. An OCMO is presented that takes advantage of high thermal isolation and monolithic integration of both micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. This was achieved by developing a processing technique where both silicon-on-insulator complementary metal-oxide-semiconductor (CMOS) circuitrymoreand piezoelectric aluminum nitride, AlN, micromechanical resonators are placed on a suspended platform within a standard CMOS integrated circuit. Operation at microscale sizes achieves high thermal resistances (~10 C/mW), and hence thermal stabilization of the oscillators at very low-power levels when compared with the state-of-the-art ovenized crystal oscillators, OCXO. This constant resistance feedback circuit is presented that incorporates on platform resistive heaters and temperature sensors to both measure and stabilize the platform temperature. Moreover, the limits on temperature stability of the OCMO platform and oscillator frequency imposed by the gain of the constant resistance feedback loop, placement of the heater and temperature sensing resistors, as well as platform radiative and convective heat losses are investigated.less

  11. System to acquire and monitor operating machinery positions for horizontal coke oven batteries

    SciTech Connect (OSTI)

    Bierbaum, D.; Teschner, W.

    1980-02-26

    In a horizontal coke oven battery with at least one coke receiving device movable along one longitudinal side of the battery and at least one coke driving device movable along an opposite longitudinal side of the battery, an apparatus is disclosed for determining the relative position of the coke receiving device with respect to the coke driving device and for activating the coke driving device when its position corresponds with that of the coke receiving device. A first wheel is mounted on the coke receiving device for rotation with the movement of the coke receiving device, a first angle encoder is connected to the first wheel for producing a first signal corresponding to the location of the first wheel and the position of the coke receiving device along the coke oven, and an input storage in the form of a magnetic disc is connected to the first angle encoder for recording and storing the signal. A second wheel is mounted on the coke driving device for rotation with the movement of the coke driving device and a second angle encoder is connected thereto for producing a second signal which corresponds to the rotation of the second wheel and the position of the coke driving device along the coke oven. A comparator is connected to the second signal encoder for receiving the second signal and a data link is provided between the comparator and the input storage of the coke receiving device so that the first signal from the coke receiving device can be impressed on the comparator. An activator is connected to the comparator for activating the coke driving device when the first signal corresponds to the second signal indicating a corresponding positional relationship between the coke receiving device and the coke driving device.

  12. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J.; Gross, M.

    1995-12-01

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  13. Demonstration of a fuel-saving system for paint-curing ovens

    SciTech Connect (OSTI)

    Jensen, W P

    1980-12-01

    Two curing ovens at Roll Coater, Inc. (the Greenfield, Indiana plant) were retrofitted to save fuel and cost. Included in the fuel conserving retrofit was the design, fabrication, and installation of an afterburner for each of the two ovens, piping their combustion products to each of two commonly housed waste heat boilers before discharge from those units to the atmosphere at about 450 F. Depending on the product being run and the coating applied, natural gas requirements have been reduced by 45 to 65% with operation of the zone incinerators only and by as much as 65 to 85% including the effects of both the zone incineration and heat recovery by means of the afterburners and waste heat boilers. A demonstration program on conversion work at the No. 3 line at Greenfield and results are described in Section 2. Section 3 describes the retrofit design and the system construction. System performance (tests and measurements, qualitative performance, maintenance factors, and economic performance) is described in Section 4. Conclusions and recommendations are summarized.

  14. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  15. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  16. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  17. Chemically stabilized ionomers containing inorganic fillers

    DOE Patents [OSTI]

    Roelofs, Mark Gerrit

    2013-12-31

    Ionomeric polymers that are chemically stabilized and contain inorganic fillers are prepared, and show reduced degradation. The ionomers care useful in membranes and electrochemical cells.

  18. Inorganic Membranes for Refinery Gas Separations

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to push the performance limits of inorganic membranes for large-scale gas separations in refinery applications.

  19. Inorganic dual-layer microporous supported membranes

    DOE Patents [OSTI]

    Brinker, C. Jeffrey; Tsai, Chung-Yi; Lu, Yungfeng

    2003-03-25

    The present invention provides for a dual-layer inorganic microporous membrane capable of molecular sieving, and methods for production of the membranes. The inorganic microporous supported membrane includes a porous substrate which supports a first inorganic porous membrane having an average pore size of less than about 25 .ANG. and a second inorganic porous membrane coating the first inorganic membrane having an average pore size of less than about 6 .ANG.. The dual-layered membrane is produced by contacting the porous substrate with a surfactant-template polymeric sol, resulting in a surfactant sol coated membrane support. The surfactant sol coated membrane support is dried, producing a surfactant-templated polymer-coated substrate which is calcined to produce an intermediate layer surfactant-templated membrane. The intermediate layer surfactant-templated membrane is then contacted with a second polymeric sol producing a polymeric sol coated substrate which is dried producing an inorganic polymeric coated substrate. The inorganic polymeric coated substrate is then calcined producing an inorganic dual-layered microporous supported membrane in accordance with the present invention.

  20. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic...

  1. Multifunctional, Inorganic-Filled Separators for Large Format...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries...

  2. NSF/DOE Thermoelectric Partnership: Inorganic-Organic Hybrid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inorganic-Organic Hybrid Thermoelectrics NSFDOE Thermoelectric Partnership: Inorganic-Organic Hybrid Thermoelectrics 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle...

  3. Inorganic-Organic Hybrid Thermoelectrics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inorganic-Organic Hybrid Thermoelectrics Inorganic-Organic Hybrid Thermoelectrics Large-scale synthesis of inorganic and organic nanomaterials (single-crystalline nanowires and functionalized conducting polymer thin films) together with strategies for large-scale assembly are discussed PDF icon vaddiraju.pdf More Documents & Publications Inorganic-Organic Hybrid Thermoelectrics NSF/DOE Thermoelectric Partnership: Inorganic-Organic Hybrid Thermoelectrics Organic Molecule Functionalized Zn3P2

  4. NSF/DOE Thermoelectric Partnership: Inorganic-Organic Hybrid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectrics | Department of Energy Inorganic-Organic Hybrid Thermoelectrics NSF/DOE Thermoelectric Partnership: Inorganic-Organic Hybrid Thermoelectrics 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace071_vaddiraju_2011_p.pdf More Documents & Publications Inorganic-Organic Hybrid Thermoelectrics Inorganic-Organic Hybrid Thermoelectrics Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid

  5. Crystallization and functionality of inorganic materials

    SciTech Connect (OSTI)

    Xue, Dongfeng, E-mail: dongfeng@ciac.jl.cn [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China); Li, Keyan [School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China)] [School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China); Liu, Jun [Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, 411105 (China)] [Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, 411105 (China); Sun, Congting; Chen, Kunfeng [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China)

    2012-10-15

    In this article, we briefly summarized our recent work on the studies of crystallization and functionality of inorganic materials. On the basis of the chemical bonding theory of single crystal growth, we can quantitatively simulate Cu{sub 2}O crystallization processes in solution system. We also kinetically controlled Cu{sub 2}O crystallization process in the reduction solution route. Lithium ion battery and supercapacitor performances of some oxides such as Co{sub 3}O{sub 4} and MnO{sub 2} were shown to elucidate the important effect of crystallization on functionality of inorganic materials. This work encourages us to create novel functionalities through the study of crystallization of inorganic materials, which warrants more chances in the field of functional materials.

  6. Transformations of inorganic coal constituents in combustion systems

    SciTech Connect (OSTI)

    Helble, J.J.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. ); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. ); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. ); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. (Kentucky Univ., Lexingt

    1992-11-01

    The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles What determines their composition Whether or not particles deposit How combustion conditions, including reactor size, affect these processes remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

  7. Inorganic rechargeable non-aqueous cell

    DOE Patents [OSTI]

    Bowden, William L. (Nashua, NH); Dey, Arabinda N. (Needham, MA)

    1985-05-07

    A totally inorganic non-aqueous rechargeable cell having an alkali or alkaline earth metal anode such as of lithium, a sulfur dioxide containing electrolyte and a discharging metal halide cathode, such as of CuCl.sub.2, CuBr.sub.2 and the like with said metal halide being substantially totally insoluble in SO.sub.2 and admixed with a conductive carbon material.

  8. Hybrid Organic-Inorganic Halide Perovskite Solar Cells | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Hybrid Organic-Inorganic Halide Perovskite Solar Cells Hybrid Organic-Inorganic Halide Perovskite Solar Cells The SunShot Initiative supports research and development projects aimed at increasing the efficiency and lifetime as well as evaluating new materials for hybrid organic-inorganic perovskite solar cells. This field has been dominated by absorber materials based on methylammonium lead halide perovskites. Perovskite solar cells have shown remarkable progress in recent years with

  9. Preparation and screening of crystalline inorganic materials

    DOE Patents [OSTI]

    Schultz, Peter G. (La Jolla, CA); Xiang, Xiaodong (Danville, CA); Goldwasser, Isy (Palo Alto, CA); Brice{hacek over (n)}o, Gabriel (Baldwin Park, CA); Sun, Xiao-Dong (Fremont, CA); Wang, Kai-An (Cupertino, CA)

    2008-10-28

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  10. Combinatorial screening of inorganic and organometallic materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Alameda, CA)

    2002-01-01

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  11. Combinatorial synthesis of inorganic or composite materials

    DOE Patents [OSTI]

    Goldwasser, Isy (Palo Alto, CA); Ross, Debra A. (Mountain Ranch, CA); Schultz, Peter G. (La Jolla, CA); Xiang, Xiao-Dong (Danville, CA); Briceno, Gabriel (Baldwin Park, CA); Sun, Xian-Dong (Fremont, CA); Wang, Kai-An (Cupertino, CA)

    2010-08-03

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials or, alternatively, allowing the components to interact to form at least two different materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, nonbiological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  12. Rapid Field Measurement of Dissolved Inorganic Carbon Based on...

    Office of Scientific and Technical Information (OSTI)

    Dissolved inorganic carbon (DIC) is commonly measured in water and is an important parameter for understanding carbonate equilibrium, carbon cycling, and water-rock interaction. ...

  13. Inorganic-organic composite polymers and methods of making

    DOE Patents [OSTI]

    Josowicz, M.A.; Exarhos, G.J.

    1996-10-29

    The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell. 2 figs.

  14. Inorganic-organic composite polymers and methods of making

    DOE Patents [OSTI]

    Josowicz, Mira A. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

    1996-01-01

    The invention is a composition of an inorganic-organic polymer composite and a method of making it. The inorganic portion of the fundamental polymer composite polymer repeat is a speciated inorganic heterocyclic compound, and the organic portion of the polymer repeat is a cyclic organic radical anion compound having at least two charged sites. The composition of the present invention is made by combining a cyclic organic radical anion compound with a speciated inorganic heterocyclic compound by a nucleophilic substitution thereby forming a polymer of an inorganic-organic composite. The cyclic organic radical anion compound is preferably generated electrochemically. The nucleophilic substitution is alternately carried out chemically or electrochemically. A preferred embodiment of the present invention includes performing the nucleophilic substitution at the cathode of an electrochemical cell.

  15. Sol-gel processing with inorganic metal salt precursors

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2004-10-19

    Methods for sol-gel processing that generally involve mixing together an inorganic metal salt, water, and a water miscible alcohol or other organic solvent, at room temperature with a macromolecular dispersant material, such as hydroxypropyl cellulose (HPC) added. The resulting homogenous solution is incubated at a desired temperature and time to result in a desired product. The methods enable production of high quality sols and gels at lower temperatures than standard methods. The methods enable production of nanosize sols from inorganic metal salts. The methods offer sol-gel processing from inorganic metal salts.

  16. Thermal properties of organic and inorganic aerogels

    SciTech Connect (OSTI)

    Hrubesh, L.W.; Pekala, R.W. (Chemistry and Material Science Department, Lawrence Livermore National Laboratory, Livermore, California 94551-9900 (United States))

    1994-03-01

    Aerogels are open-cell foams that have already been shown to be among the best thermal insulating solid materials known. This paper examines the three major contributions to thermal transport through porous materials; solid, gaseous, and radiative, to identify how to reduce the thermal conductivity of air-filled aerogels. We find that significant improvements in the thermal insulation property of aerogels are possible by; (i) employing materials with a low intrinsic solid conductivity, (ii) reducing the average pore size within aerogels, and (iii) affecting an increase of the infrared extinction in aerogels. Theoretically, polystyrene is the best of the organic materials and zirconia is the best inorganic material to use for the lowest achievable conductivity. Significant reduction of the thermal conductivity for all aerogel varieties is predicted with only a modest decrease of the average pore size. This might be achieved by modifying the sol-gel chemistry leading to aerogels. For example, a thermal resistance value of [ital R]=20 per inch would be possible for an air-filled resorcinol-formaldehyde aerogel at a density of 156 kg/m[sup 3], if the average pore size was less than 35 nm. An equation is included which facilitates the calculation of the optimum density for the minimum total thermal conductivity, for all varieties of aerogels.

  17. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A. P. Evans

    1998-12-03

    McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using the Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species, hydrogen chloride and hydrogen fluoride.

  18. Advanced Emission Control Development Program.

    SciTech Connect (OSTI)

    Evans, A.P.

    1997-12-31

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  19. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A. P. Evans

    1998-12-03

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W?s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  20. Characterization of Dried and Torrefied Arundo Donax Biomass for Inorganic

    Office of Scientific and Technical Information (OSTI)

    Species Prior to Combustion (Technical Report) | SciTech Connect Dried and Torrefied Arundo Donax Biomass for Inorganic Species Prior to Combustion Citation Details In-Document Search Title: Characterization of Dried and Torrefied Arundo Donax Biomass for Inorganic Species Prior to Combustion Portland General Electric (PGE) potentially plans to replace the coal with torrefied Arundo donax for their Boardman coal-fired power plant by 2020. Since there is only a limited amount of experience

  1. Directed Organization of Functional Materials at Inorganic-Macromolecular

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interfaces Alex Noy is the Principal Investigator for Directed Organization of Functional Materials at Inorganic-Macromolecular Interfaces. Directed Organization of Functional Materials at Inorganic-Macromolecular Interfaces Research The purpose of this project is to develop a quantitative physical picture of macromolecular organization and its relationship to function, and to use macromolecular organization to derive new functionality. The project has several major subtasks in addition to

  2. Casting fine grained, fully dense, strong inorganic materials

    DOE Patents [OSTI]

    Brown, Sam W.; Spencer, Larry S.; Phillips, Michael R.

    2015-11-24

    Methods and apparatuses for casting inorganic materials are provided. The inorganic materials include metals, metal alloys, metal hydrides and other materials. Thermal control zones may be established to control the propagation of a freeze front through the casting. Agitation from a mechanical blade or ultrasonic energy may be used to reduce porosity and shrinkage in the casting. After solidification of the casting, the casting apparatus may be used to anneal the cast part.

  3. Heterostructures based on inorganic and organic van der Waals systems

    SciTech Connect (OSTI)

    Lee, Gwan-Hyoung; Lee, Chul-Ho; Zande, Arend M. van der; Han, Minyong; Cui, Xu; Arefe, Ghidewon; Hone, James; Nuckolls, Colin; Heinz, Tony F.; Kim, Philip

    2014-09-01

    The two-dimensional limit of layered materials has recently been realized through the use of van der Waals (vdW) heterostructures composed of weakly interacting layers. In this paper, we describe two different classes of vdW heterostructures: inorganic vdW heterostructures prepared by co-lamination and restacking; and organic-inorganic hetero-epitaxy created by physical vapor deposition of organic molecule crystals on an inorganic vdW substrate. Both types of heterostructures exhibit atomically clean vdW interfaces. Employing such vdW heterostructures, we have demonstrated various novel devices, including graphene/hexagonal boron nitride (hBN) and MoS{sub 2} heterostructures for memory devices; graphene/MoS{sub 2}/WSe{sub 2}/graphene vertical p-n junctions for photovoltaic devices, and organic crystals on hBN with graphene electrodes for high-performance transistors.

  4. Transformations of inorganic coal constituents in combustion systems. Volume 1, sections 1--5: Final report

    SciTech Connect (OSTI)

    Helble, J.J.; Srinivasachar, S.; Wilemski, G.; Boni, A.A.; Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M.; Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L.; Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A.

    1992-11-01

    The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles? What determines their composition? Whether or not particles deposit? How combustion conditions, including reactor size, affect these processes? remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

  5. Survey of electrochemical production of inorganic compounds. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

  6. Inorganic metal oxide/organic polymer nanocomposites and method thereof

    DOE Patents [OSTI]

    Gash, Alexander E.; Satcher, Joe H.; Simpson, Randy

    2004-03-30

    A synthetic method for preparation of hybrid inorganic/organic energetic nanocomposites is disclosed herein. The method employs the use of stable metal inorganic salts and organic solvents as well as an organic polymer with good solubility in the solvent system to produce novel nanocomposite energetic materials. In addition, fuel metal powders (particularly those that are oxophillic) can be incorporated into composition. This material has been characterized by thermal methods, energy-filtered transmission electron microscopy (EFTEM), N.sub.2 adsoprtion/desorption methods, and Fourier-Transform (FT-IR) spectroscopy. According to these characterization methods the organic polymer phase fills the nanopores of the composite material, providing superb mixing of the component phases in the energetic nanocomposite.

  7. Technical support document: Energy efficiency standards for consumer products: Room air conditioners, water heaters, direct heating equipment, mobile home furnaces, kitchen ranges and ovens, pool heaters, fluorescent lamp ballasts and television sets. Volume 1, Methodology

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The Energy Policy and Conservation Act (P.L. 94-163), as amended, establishes energy conservation standards for 12 of the 13 types of consumer products specifically covered by the Act. The legislation requires the Department of Energy (DOE) to consider new or amended standards for these and other types of products at specified times. DOE is currently considering amending standards for seven types of products: water heaters, direct heating equipment, mobile home furnaces, pool heaters, room air conditioners, kitchen ranges and ovens (including microwave ovens), and fluorescent light ballasts and is considering establishing standards for television sets. This Technical Support Document presents the methodology, data, and results from the analysis of the energy and economic impacts of the proposed standards. This volume presents a general description of the analytic approach, including the structure of the major models.

  8. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update (EIA)

    3. Methane Emissions 3.1. Total emissions The major sources of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9 percent higher than the 2008 total of 724 MMTCO2e (Table 17). Methane emissions declined steadily from 1990 to 2001, as emissions from coal mining and landfills fell, then rose from 2002 to 2009 as a result of moderate increases in emissions related to energy,

  9. Low-melting point inorganic nitrate salt heat transfer fluid

    DOE Patents [OSTI]

    Bradshaw, Robert W.; Brosseau, Douglas A.

    2009-09-15

    A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

  10. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, F.K.

    1986-07-29

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process. 4 figs.

  11. Solid state radioluminescent sources: Mixed organic/inorganic hybrids

    SciTech Connect (OSTI)

    Gill, J.T. (EG and G Mound Applied Technologies, Miamisburg, OH (USA)); Renschler, C.L. (Sandia National Labs., Albuquerque, NM (USA)); Shepodd, T.J. (Sandia National Labs., Livermore, CA (USA)); Smith, H.M. (Allied-Signal, Inc., Kansas City, MO (USA))

    1990-01-01

    This concept brings a condensed source of tritium into close proximity with an inorganic phosphor. That source may thus become the equivalent of many atmospheres of tritium gas pressure. If both phosphor and tritium source material are optically clear, then a lamp's brightness may be made to scale with optical path length. Proof of principle of this concept has been demonstrated and will be described. A theoretical treatment is presented for the results here and for results from aerogel experiments. 12 refs., 2 figs., 1 tab.

  12. Engineering the Interface Between Inorganic Materials and Cells

    SciTech Connect (OSTI)

    Schaffer, David

    2014-05-31

    To further optimize cell function in hybrid living materials, it would be advantageous to render mammalian cells responsive to novel orthogonal cues, i.e. signals they would not ordinarily respond to but that can be engineered to feed into defined intracellular signaling pathways. We recently developed an optogenetic method, based on A. thaliana Cry2, for rapid and reversible protein oligomerization in response to blue light. We also demonstrated the ability to use this method to channel the light input into several defined signaling pathways, work that will enhance communication between inorganic devices and living systems.

  13. Coal liquefaction in an inorganic-organic medium

    DOE Patents [OSTI]

    Vermeulen, Theodore (Berkeley, CA); Grens, II, Edward A. (Danville, CA); Holten, Ronald R. (El Cerrito, CA)

    1982-01-01

    Improved process for liquefaction of coal by contacting pulverized coal in an inorganic-organic medium solvent system containing a ZnCl.sub.2 catalyst, a polar solvent with the structure RX where X is one of the elements O, N, S or P, and R is hydrogen or a lower hydrocarbon radical; the solvent system can contain a hydrogen donor solvent (and must when RX is water) which is immiscible in the ZnCl.sub.2 and is a hydroaromatic hydrocarbon, selected from tetralin, dihydrophenanthrene, dihydroanthracene or a hydrogenated coal derived hydroaromatic hydrocarbon distillate fraction.

  14. Air stable organic-inorganic nanoparticles hybrid solar cells

    DOE Patents [OSTI]

    Qian, Lei; Yang, Jihua; Xue, Jiangeng; Holloway, Paul H.

    2015-09-29

    A solar cell includes a low work function cathode, an active layer of an organic-inorganic nanoparticle composite, a ZnO nanoparticle layer situated between and physically contacting the cathode and active layers; and a transparent high work function anode that is a bilayer electrode. The inclusion of the ZnO nanoparticle layer results in a solar cell displaying a conversion efficiency increase and reduces the device degradation rate. Embodiments of the invention are directed to novel ZnO nanoparticles that are advantageous for use as the ZnO nanoparticle layers of the novel solar cells and a method to prepare the ZnO nanoparticles.

  15. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1986-01-01

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  16. Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials

    DOE Patents [OSTI]

    Wang, Yifeng; Miller, Andy; Bryan, Charles R.; Kruichak, Jessica Nicole

    2015-11-17

    Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials are described. For example, a method of capturing and immobilizing radioactive nuclei includes flowing a gas stream through an exhaust apparatus. The exhaust apparatus includes a metal fluorite-based inorganic material. The gas stream includes a radioactive species. The radioactive species is removed from the gas stream by adsorbing the radioactive species to the metal fluorite-based inorganic material of the exhaust apparatus.

  17. Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials

    DOE Patents [OSTI]

    Wang, Yifeng; Miller, Andy; Bryan, Charles R; Kruichar, Jessica Nicole

    2015-04-07

    Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials are described. For example, a method of capturing and immobilizing radioactive nuclei includes flowing a gas stream through an exhaust apparatus. The exhaust apparatus includes a metal fluorite-based inorganic material. The gas stream includes a radioactive species. The radioactive species is removed from the gas stream by adsorbing the radioactive species to the metal fluorite-based inorganic material of the exhaust apparatus.

  18. Rapid Field Measurement of Dissolved Inorganic Carbon Based on CO{sub 2}

    Office of Scientific and Technical Information (OSTI)

    Analysis (Conference) | SciTech Connect SciTech Connect Search Results Conference: Rapid Field Measurement of Dissolved Inorganic Carbon Based on CO{sub 2} Analysis Citation Details In-Document Search Title: Rapid Field Measurement of Dissolved Inorganic Carbon Based on CO{sub 2} Analysis Dissolved inorganic carbon (DIC) is commonly measured in water and is an important parameter for understanding carbonate equilibrium, carbon cycling, and water-rock interaction. While accurate measurements

  19. Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 3, Inorganic instrumental methods

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    The methods cover: C in solutions, F (electrode), elements by atomic emission spectrometry, inorganic anions by ion chromatography, Hg in water/solids/sludges, As, Se, Bi, Pb, data calculations for SST (single shell tank?) samples, Sb, Tl, Ag, Pu, O/M ratio, ignition weight loss, pH value, ammonia (N), Cr(VI), alkalinity, U, C sepn. from soil/sediment/sludge, Pu purif., total N, water, C and S, surface Cl/F, leachable Cl/F, outgassing of Ge detector dewars, gas mixing, gas isotopic analysis, XRF of metals/alloys/compounds, H in Zircaloy, H/O in metals, inpurity extraction, reduced/total Fe in glass, free acid in U/Pu solns, density of solns, Kr/Xe isotopes in FFTF cover gas, H by combustion, MS of Li and Cs isotopes, MS of lanthanide isotopes, GC operation, total Na on filters, XRF spectroscopy QC, multichannel analyzer operation, total cyanide in water/solid/sludge, free cyanide in water/leachate, hydrazine conc., ICP-MS, {sup 99}Tc, U conc./isotopes, microprobe analysis of solids, gas analysis, total cyanide, H/N{sub 2}O in air, and pH in soil.

  20. Screening combinatorial arrays of inorganic materials with spectroscopy or microscopy

    DOE Patents [OSTI]

    Schultz, Peter G.; Xiang, Xiaodong; Goldwasser, Isy

    2004-02-03

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  1. Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    synthesis of compound semiconductor nanowire powders for inorganic-organic hybrid thermoelectric cells PDF icon vaddiraju.pdf More Documents & Publications NSFDOE Thermoelectric...

  2. Polystyrene-poly(vinylphenol) copolymers as compatibilzers for organic-inorganic composites

    SciTech Connect (OSTI)

    Landry, C.J.T.; Coltrain, B.K.; Teegarden, D.M.

    1996-12-31

    Random, graft, and block copolymers of polystyrene (PS) and poly(4-vinylphenol) (PVPh), and PVPh homopolymer are shown to act as compatibilizers for incompatible organic-inorganic composite materials. The VPh component reacts, or interacts strongly with the polymerizing inorganic (titanium or zirconium) alkoxide. The organic components studied were PS, poly(vinyl methyl ether), and poly(styrene-co-acrylonitrile). The use of such compatibilizers provides a means of combining in situ polymerized inorganic oxides and hydrophobic polymers. This is seen as a reduction in the size of the dispersed inorganic phase and results in improved optical and mechanical properties.

  3. Apparatus and method for temperature correction and expanded count rate of inorganic scintillation detectors

    DOE Patents [OSTI]

    Ianakiev, Kiril D.; Hsue, Sin Tao; Browne, Michael C.; Audia, Jeffrey M.

    2006-07-25

    The present invention includes an apparatus and corresponding method for temperature correction and count rate expansion of inorganic scintillation detectors. A temperature sensor is attached to an inorganic scintillation detector. The inorganic scintillation detector, due to interaction with incident radiation, creates light pulse signals. A photoreceiver processes the light pulse signals to current signals. Temperature correction circuitry that uses a fast light component signal, a slow light component signal, and the temperature signal from the temperature sensor to corrected an inorganic scintillation detector signal output and expanded the count rate.

  4. Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid Thermoelectrics

    Broader source: Energy.gov [DOE]

    Demonstrates self-catalytic schemes for large-scale synthesis of compound semiconductor nanowire powders for inorganic-organic hybrid thermoelectric cells

  5. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) bothmore » significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 60–80%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the formation of secondary inorganic aerosols, and led to rapid increase of the PM2.5 concentration.« less

  6. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    SciTech Connect (OSTI)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) both significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 6080%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the formation of secondary inorganic aerosols, and led to rapid increase of the PM2.5 concentration.

  7. Inorganic Metal Oxide/Organic Polymer Nanocomposites And Method Thereof

    DOE Patents [OSTI]

    Gash, Alexander E.; Satcher, Joe H.; Simpson, Randy

    2004-11-16

    A synthetic method for preparation of hybrid inorganic/organic energetic nanocomposites is disclosed herein. The method employs the use of stable metal in organic salts and organic solvents as well as an organic polymer with good solubility in the solvent system to produce novel nanocomposite energetic materials. In addition, fuel metal powders (particularly those that are oxophilic) can be incorporated into composition. This material has been characterized by thermal methods, energy-filtered transmission electron microscopy (EFTEM), N.sub.2 adsoprtion/desorption methods, and Fourier-Transform (FT-IR) spectroscopy. According to these characterization methods the organic polymer phase fills the nanopores of the material, providing superb mixing of the component phases in the energetic nanocomposite.

  8. Inorganic nanotubes and electro-fluidic devices fabricated therefrom

    DOE Patents [OSTI]

    Yang, Peidong (Kensington, CA); Majumdar, Arunava (Orinda, CA); Fan, Rong (Pasadena, CA); Karnik, Rohit (Cambridge, MA)

    2011-03-01

    Nanofluidic devices incorporating inorganic nanotubes fluidly coupled to channels or nanopores for supplying a fluid containing chemical or bio-chemical species are described. In one aspect, two channels are fluidly interconnected with a nanotube. Electrodes on opposing sides of the nanotube establish electrical contact with the fluid therein. A bias current is passed between the electrodes through the fluid, and current changes are detected to ascertain the passage of select molecules, such as DNA, through the nanotube. In another aspect, a gate electrode is located proximal the nanotube between the two electrodes thus forming a nanofluidic transistor. The voltage applied to the gate controls the passage of ionic species through the nanotube selected as either or both ionic polarities. In either of these aspects the nanotube can be modified, or functionalized, to control the selectivity of detection or passage.

  9. Analysis on storage off-gas emissions from woody, herbaceous, and torrefied biomass

    SciTech Connect (OSTI)

    Tumuluru, Jaya Shankar; Lim, C. Jim; Bi, Xiaotao T.; Kuang, Xingya; Melin, Staffan; Yazdanpanah, Fahimeh; Sokhansanj, Shahab

    2015-03-02

    Wood chips, torrefied wood chips, ground switchgrass, and wood pellets were tested for off-gas emissions during storage. Storage canisters with gas-collection ports were used to conduct experiments at room temperature of 20 C and in a laboratory oven set at 40 C. Commercially-produced wood pellets yielded the highest carbon monoxide (CO) emissions at both 20 and 40 C (1600 and 13,000 ppmv), whereas torrefied wood chips emitted the lowest of about <200 and <2000 ppmv. Carbon dioxide (CO?) emissions from wood pellets were 3000 ppmv and 42,000 ppmv, whereas torrefied wood chips registered at about 2000 and 25,000 ppmv, at 20 and 40 C at the end of 11 days of storage. CO emission factors (milligrams per kilogram of biomass) calculated were lowest for ground switchgrass and torrefied wood chips (2.68 and 4.86 mg/kg) whereas wood pellets had the highest CO of about 10.60 mg/kg, respectively, at 40 C after 11 days of storage. In the case of CO?, wood pellets recorded the lowest value of 55.46 mg/kg, whereas switchgrass recorded the highest value of 318.72 mg/kg. This study concludes that CO emission factor is highest for wood pellets, CO? is highest for switchgrass and CH? is negligible for all feedstocks except for wood pellets, which is about 0.374 mg/kg at the end of 11-day storage at 40 C.

  10. OXIDATIVE COUPLING OF METHANE USING INORGANIC MEMBRANE REACTORS

    SciTech Connect (OSTI)

    Dr. Y.H. Ma; Dr. W.R. Moser; Dr. A.G. Dixon; Dr. A.M. Ramachandra; Dr. Y. Lu; C. Binkerd

    1998-04-01

    The objective of this research is to study the oxidative coupling of methane in catalytic inorganic membrane reactors. A specific target is to achieve conversion of methane to C{sub 2} hydrocarbons at very high selectivity and higher yields than in conventional non-porous, co-feed, fixed bed reactors by controlling the oxygen supply through the membrane. A membrane reactor has the advantage of precisely controlling the rate of delivery of oxygen to the catalyst. This facility permits balancing the rate of oxidation and reduction of the catalyst. In addition, membrane reactors minimize the concentration of gas phase oxygen thus reducing non selective gas phase reactions, which are believed to be a main route for the formation of CO{sub x} products. Such gas phase reactions are a cause of decreased selectivity in the oxidative coupling of methane in conventional flow reactors. Membrane reactors could also produce higher product yields by providing better distribution of the reactant gases over the catalyst than the conventional plug flow reactors. Membrane reactor technology also offers the potential for modifying the membranes both to improve catalytic properties as well as to regulate the rate of the permeation/diffusion of reactants through the membrane to minimize by-product generation. Other benefits also exist with membrane reactors, such as the mitigation of thermal hot-spots for highly exothermic reactions such as the oxidative coupling of methane. The application of catalytically active inorganic membranes has potential for drastically increasing the yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity.

  11. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors

  12. Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment

    SciTech Connect (OSTI)

    Rich Ciora; Paul KT Liu

    2012-06-27

    In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the inorganic membrane field. Further, this newly developed full scale bundle concept can be extended to other thin film inorganic membrane technology (Pd, zeolite, etc), providing a potential commercialization pathway for these membrane materials that demonstrate high potential in a variety of separation applications yet remain a laboratory 'novelty' for lack of a full scale support. Overall, the project has been highly successful and all of the project objectives have been met. We have developed the first of its kind commercial scale carbon molecular sieve membrane and demonstrated its performance in field testing under aggressive operating conditions and in the presence of chemical contaminants that would rapidly destroy alternative organic and inorganic membranes. This innovative membrane permits H{sub 2} recovery from gas streams that up until now have not been successfully treated with membrane or conventional technology. Our end user participant is currently pursuing the field demonstration of this membrane for hydrogen recovery at its refinery site.

  13. Organic/inorganic nanocomposites, methods of making, and uses as a permeable reactive barrier

    DOE Patents [OSTI]

    Harrup, Mason K.; Stewart, Frederick F.

    2007-05-15

    Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater. Methods for making nanocomposite materials, PRB systems, and methods of treating groundwater are also disclosed.

  14. Advanced Branching Control and Characterization of Inorganic Semiconducting Nanocrystals

    SciTech Connect (OSTI)

    Hughes, Steven Michael

    2007-12-31

    The ability to finely tune the size and shape of inorganic semiconducting nanocrystals is an area of great interest, as the more control one has, the more applications will be possible for their use. The first two basic shapes develped in nanocrystals were the sphere and the anistropic nanorod. the II_VI materials being used such as Cadmium Selenide (CdSe) and Cadmium Telluride (CdTe), exhibit polytypism, which allows them to form in either the hexagonally packed wurtzite or cubically packed zinc blende crystalline phase. The nanorods are wurtzite with the length of the rod growing along the c-axis. As this grows, stacking faults may form, which are layers of zinc blende in the otherwise wurtzite crystal. Using this polytypism, though, the first generation of branched crystals were developed in the form of the CdTe tetrapod. This is a nanocrystal that nucleates in the zincblend form, creating a tetrahedral core, on which four wurtzite arms are grown. This structure opened up the possibility of even more complex shapes and applications. This disseration investigates the advancement of branching control and further understanding the materials polytypism in the form of the stacking faults in nanorods.

  15. Carbon Emissions: Food Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  16. Project Profile: Heat Transfer and Latent Heat Storage in Inorganic Molten

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Salts for CSP Plants | Department of Energy Heat Transfer and Latent Heat Storage in Inorganic Molten Salts for CSP Plants Project Profile: Heat Transfer and Latent Heat Storage in Inorganic Molten Salts for CSP Plants Terrafore logo Terrafore, under the Thermal Storage FOA, is developing an economically feasible thermal energy storage (TES) system based on phase change materials (PCMs), for CSP plants. Approach This diagram shows how Terrafore is using a molten salt slurry to improve the

  17. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  18. Final Report: No{sub x} Emissions from By Product Fuel Combustion in Steel Making, September 15, 1996 - October 15, 1999

    SciTech Connect (OSTI)

    Pershing, David W.; Lighty, JoAnn S.; Eddings, Eric G.; Cacciatore, David A.

    1999-01-28

    Exhaust gases from the primary operations in the steel making process are almost exclusively utilized as supplemental fuels within the steel plant. These by-product fuels include blast furnace gas (BFG) and coke oven gas (COG) which contain mixtures of H{sub 2}, CO, CH{sub 4} and trace amounts of some heavier hydrocarbons and the impurities NH{sub 3} and HCN. These fuels are burned alone or in combination with natural gas to fire the coke ovens, blast furnace stoves utility boilers and metal working furnaces. The utilization of these by-product fuels reduces the waste gas emissions at the steel mill and reduces the requirements for outside fuel sources. However, as with primary fuel sources, the combustion of these by-product fuel blends does produce hazardous pollutants, in particular nitrogen oxides, and because these are atypical fuel blends of varying composition, the pollutant formation is not well understood. The objective of this research was to develop an understanding of the mechanisms controlling NO{sub x} formation from the combustion of by-product fuels from the steel industry and investigate control and design options to minimize emissions. The minimization strategies investigated were constrained by limits on CO and hydrocarbon emissions, both of which increased under fuel-rich combustion scenarios that resulted in reduced NO{sub x} emissions. Also, the minimization strategies were constrained by the need for reasonable heat generation rates in the furnaces that employ these by-product fuels, so that product steel quality is not adversely affected.

  19. Thermal and chemical degradation of inorganic membrane materials. Final report, August 1992--May 1995

    SciTech Connect (OSTI)

    Damle, A.S.; Krishnan, G.N.; Sanjurjo, A.; Wood, B.J.; Lau, K.H.

    1995-05-01

    SRI International conducted a theoretical and experimental program to evaluate the long-term thermal and chemical degradation of inorganic membranes that are being developed to separate the gaseous products of coal gasification. A variety of developmental efforts are underway, including a number of projects sponsored by the US Department of Energy (DOE), to improve the selectivity and permeability of porous inorganic membranes. DOE is also sponsoring efforts to extend the use of metallic membranes to new applications. Most developmental efforts have focused on hydrogen separation by inorganic membranes, which may be used to maximize hydrogen production from coal gas or to remove H{sub 2}S and NH{sub 3} contaminants via thermal or catalytic decomposition in integrated-gasification combined-cycle (IGCC) systems. Inorganic membranes that have a high separation efficiency and exhibit both thermal and chemical stability would improve the economics of power generation from coal. Membrane materials that have been investigated include glass (silica), alumina, carbon, and metals (Pd and Pt). This report describes inorganic membrane materials, long term membrane exposure tests, membrane permeation tests, coal gasifier exposure tests, conclusions, and recommendations.

  20. Secondary Emission Calorimetry

    SciTech Connect (OSTI)

    Winn, David Roberts

    2015-03-24

    This report describes R&D on a new type of calorimeter using secondary emission to measure the energy of radiation, particularly high energy particles.

  1. Carbon Emissions: Paper Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994...

  2. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.

  3. Exfoliation of self-assembled 2D organic-inorganic perovskite semiconductors

    SciTech Connect (OSTI)

    Niu, Wendy Baumberg, Jeremy J.; Eiden, Anna; Vijaya Prakash, G.

    2014-04-28

    Ultra-thin flakes of 2D organic-inorganic perovskite (C{sub 6}H{sub 9}C{sub 2}H{sub 4}NH{sub 3}){sub 2}PbI{sub 4} are produced using micromechanical exfoliation. Mono- and few-layer areas are identified using optical and atomic force microscopy, with an interlayer spacing of 1.6?nm. Refractive indices extracted from the optical spectra reveal a sample thickness dependence due to the charge transfer between organic and inorganic layers. These measurements demonstrate a clear difference in the exciton properties between bulk (>15 layers) and very thin (<8 layer) regions as a result of the structural rearrangement of organic molecules around the inorganic sheets.

  4. An inorganic capping strategy for the seeded growth of versatile bimetallic nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pei, Yuchen; Maligal-Ganesh, Raghu V.; Xiao, Chaoxian; Goh, Tian -Wei; Brashler, Kyle; Gustafson, Jeffrey A.; Huang, Wenyu

    2015-09-11

    Metal nanostructures have attracted great attention in various fields due to their tunable properties through precisely tailored sizes, compositions and structures. Using mesoporous silica (mSiO2) as the inorganic capping agent and encapsulated Pt nanoparticles as the seeds, we developed a robust seeded growth method to prepare uniform bimetallic nanoparticles encapsulated in mesoporous silica shells (PtM@mSiO2, M = Pd, Rh, Ni and Cu). Unexpectedly, we found that the inorganic silica shell is able to accommodate an eight-fold volume increase in the metallic core by reducing its thickness. The bimetallic nanoparticles encapsulated in mesoporous silica shells showed enhanced catalytic properties and thermalmore » stabilities compared with those prepared with organic capping agents. As a result, this inorganic capping strategy could find a broad application in the synthesis of versatile bimetallic nanostructures with exceptional structural control and enhanced catalytic properties.« less

  5. NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES

    SciTech Connect (OSTI)

    Singer, Brett C.; Apte, Michael G.; Black, Douglas R.; Hotchi, Toshifumi; Lucas, Donald; Lunden, Melissa M.; Mirer, Anna G.; Spears, Michael; Sullivan, Douglas P.

    2009-12-01

    The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel was Northern California line gas with Wobbe number (a measure of fuel energy delivery rate) of 1320-1340; test fuels had Wobbe numbers of roughly 1390 and 1420, and in some cases 1360. No ignition or operational problems were observed during test fuel use. Baseline emissions varied widely across and within burner groups and with burner operational mode. Statistically significant emissions changes were observed for some pollutants on some burners.

  6. The retention time of inorganic mercury in the brain — A systematic review of the evidence

    SciTech Connect (OSTI)

    Rooney, James P.K.

    2014-02-01

    Reports from human case studies indicate a half-life for inorganic mercury in the brain in the order of years—contradicting older radioisotope studies that estimated half-lives in the order of weeks to months in duration. This study systematically reviews available evidence on the retention time of inorganic mercury in humans and primates to better understand this conflicting evidence. A broad search strategy was used to capture 16,539 abstracts on the Pubmed database. Abstracts were screened to include only study types containing relevant information. 131 studies of interest were identified. Only 1 primate study made a numeric estimate for the half-life of inorganic mercury (227–540 days). Eighteen human mercury poisoning cases were followed up long term including autopsy. Brain inorganic mercury concentrations at death were consistent with a half-life of several years or longer. 5 radionucleotide studies were found, one of which estimated head half-life (21 days). This estimate has sometimes been misinterpreted to be equivalent to brain half-life—which ignores several confounding factors including limited radioactive half-life and radioactive decay from surrounding tissues including circulating blood. No autopsy cohort study estimated a half-life for inorganic mercury, although some noted bioaccumulation of brain mercury with age. Modelling studies provided some extreme estimates (69 days vs 22 years). Estimates from modelling studies appear sensitive to model assumptions, however predications based on a long half-life (27.4 years) are consistent with autopsy findings. In summary, shorter estimates of half-life are not supported by evidence from animal studies, human case studies, or modelling studies based on appropriate assumptions. Evidence from such studies point to a half-life of inorganic mercury in human brains of several years to several decades. This finding carries important implications for pharmcokinetic modelling of mercury and potentially for the regulatory toxicology of mercury.

  7. Air Emission Inventory for the INEEL -- 1999 Emission Report

    SciTech Connect (OSTI)

    Zohner, Steven K

    2000-05-01

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  8. Analysis on storage off-gas emissions from woody, herbaceous, and torrefied biomass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, Jaya Shankar; Lim, C. Jim; Bi, Xiaotao T.; Kuang, Xingya; Melin, Staffan; Yazdanpanah, Fahimeh; Sokhansanj, Shahab

    2015-03-02

    Wood chips, torrefied wood chips, ground switchgrass, and wood pellets were tested for off-gas emissions during storage. Storage canisters with gas-collection ports were used to conduct experiments at room temperature of 20 °C and in a laboratory oven set at 40 °C. Commercially-produced wood pellets yielded the highest carbon monoxide (CO) emissions at both 20 and 40 °C (1600 and 13,000 ppmv), whereas torrefied wood chips emitted the lowest of about <200 and <2000 ppmv. Carbon dioxide (CO₂) emissions from wood pellets were 3000 ppmv and 42,000 ppmv, whereas torrefied wood chips registered at about 2000 and 25,000 ppmv, atmore » 20 and 40 °C at the end of 11 days of storage. CO emission factors (milligrams per kilogram of biomass) calculated were lowest for ground switchgrass and torrefied wood chips (2.68 and 4.86 mg/kg) whereas wood pellets had the highest CO of about 10.60 mg/kg, respectively, at 40 °C after 11 days of storage. In the case of CO₂, wood pellets recorded the lowest value of 55.46 mg/kg, whereas switchgrass recorded the highest value of 318.72 mg/kg. This study concludes that CO emission factor is highest for wood pellets, CO₂ is highest for switchgrass and CH₄ is negligible for all feedstocks except for wood pellets, which is about 0.374 mg/kg at the end of 11-day storage at 40 °C.« less

  9. Emission Abatement System

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2003-05-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  10. Fouling of inorganic membrane and flux enhancement in membrane-coupled anaerobic bioreactor

    SciTech Connect (OSTI)

    Yoon, S.H.; Kang, I.J.; Lee, C.H.

    1999-03-01

    The fouling mechanism of an inorganic membrane was studied during the operation of a membrane-coupled anaerobic bioreactor (MCAB) when alcohol distillery wastewater was used as a digester feed. It was observed that the fouling mechanism of an inorganic membrane was significantly different from that of conventional membrane filtration processes. The main foulant was identified to be an inorganic precipitate, struvite (MgNH{sub 4}PO{sub 4}{center_dot}6H{sub 2}O), rather than anaerobic microbial flocs. Struvite appears to be precipitated not only on the membrane surface but also inside the membrane pores. The amount of struvite generated during the bioreaction was estimated to be about 2 g/L alcohol distillery wastewater. The inorganic foulant was not easily removed by general physical cleaning such as depressurization, lumen flushing, and backflushing. Based on these findings, the membrane fouling was alleviated and thus flux was enhanced by adopting a backfeeding mode which has dual purpose of feeding and backflushing with particle-free acidic wastewater used as the feed for anaerobic digestion.

  11. Photon enhanced thermionic emission

    DOE Patents [OSTI]

    Schwede, Jared; Melosh, Nicholas; Shen, Zhixun

    2014-10-07

    Photon Enhanced Thermionic Emission (PETE) is exploited to provide improved efficiency for radiant energy conversion. A hot (greater than 200.degree. C.) semiconductor cathode is illuminated such that it emits electrons. Because the cathode is hot, significantly more electrons are emitted than would be emitted from a room temperature (or colder) cathode under the same illumination conditions. As a result of this increased electron emission, the energy conversion efficiency can be significantly increased relative to a conventional photovoltaic device. In PETE, the cathode electrons can be (and typically are) thermalized with respect to the cathode. As a result, PETE does not rely on emission of non-thermalized electrons, and is significantly easier to implement than hot-carrier emission approaches.

  12. Field emission electron source

    DOE Patents [OSTI]

    Zettl, Alexander Karlwalter (Kensington, CA); Cohen, Marvin Lou (Berkeley, CA)

    2000-01-01

    A novel field emitter material, field emission electron source, and commercially feasible fabrication method is described. The inventive field emission electron source produces reliable electron currents of up to 400 mA/cm.sup.2 at 200 volts. The emitter is robust and the current it produces is not sensitive to variability of vacuum or the distance between the emitter tip and the cathode. The novel emitter has a sharp turn-on near 100 volts.

  13. Combustion and Emissions Modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion and Emissions Modeling This email address is being protected from spambots. You need JavaScript enabled to view it. - Computational Fluid Dynamics Project Leader Background Modern transportation engines are designed to use the available fuel resources efficiently and minimize harmful emissions. Optimization of these designs is based on a wealth of practical design, construction and operating experiences, and use of modern testing facilities and sophisticated analyses of the combustion

  14. A Community Emissions Data System (CEDS) for Historical Emissions

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect SciTech Connect Search Results Conference: A Community Emissions Data System (CEDS) for Historical Emissions Citation Details In-Document Search Title: A Community Emissions Data System (CEDS) for Historical Emissions Historical emission estimates for anthropogenic aerosol and precursor compounds are key data needed for Earth system models, climate models, and atmospheric chemistry and transport models; both for general analysis and assessment and also for

  15. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) Greenhouse Gas Emissions Overview Diagram Notes [a] CO2 emissions related to petroleum consumption (includes 64 MMTCO2 of non-fuel-related emissions). [b] CO2 emissions related to coal consumption (includes 0.3 MMTCO2 of non-fuel-related emissions). [c] CO2 emissions related to natural gas consumption (includes 13 MMTCO2 of

  16. Mechanically flexible organic electroluminescent device with directional light emission

    DOE Patents [OSTI]

    Duggal, Anil Raj; Shiang, Joseph John; Schaepkens, Marc

    2005-05-10

    A mechanically flexible and environmentally stable organic electroluminescent ("EL") device with directional light emission comprises an organic EL member disposed on a flexible substrate, a surface of which is coated with a multilayer barrier coating which includes at least one sublayer of a substantially transparent organic polymer and at least one sublayer of a substantially transparent inorganic material. The device includes a reflective metal layer disposed on the organic EL member opposite to the substrate. The reflective metal layer provides an increased external quantum efficiency of the device. The reflective metal layer and the multilayer barrier coating form a seal around the organic EL member to reduce the degradation of the device due to environmental elements.

  17. Fugitive Emissions | Department of Energy

    Energy Savers [EERE]

    Fugitive Emissions Fugitive Emissions Fugitive emissions refers to the release of greenhouse gases (GHGs) from pressurized systems. The Fugitive Emissions Working Group (FEWG) is a network of scientists, engineers, technicians, and environmental professionals representing more than 20 U.S. Department of Energy (DOE) laboratories, power marketing administrations, program offices, and National Nuclear Security Administration facilities that are working to reduce emissions of high-impact fugitive

  18. Method for reducing CO2, CO, NOX, and SOx emissions

    DOE Patents [OSTI]

    Lee, James Weifu (Oak Ridge, TN); Li, Rongfu (Zhejiang, CH)

    2002-01-01

    Industrial combustion facilities are integrated with greenhouse gas-solidifying fertilizer production reactions so that CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions can be converted prior to emission into carbonate-containing fertilizers, mainly NH.sub.4 HCO.sub.3 and/or (NH.sub.2).sub.2 CO, plus a small fraction of NH.sub.4 NO.sub.3 and (NH.sub.4).sub.2 SO.sub.4. The invention enhances sequestration of CO.sub.2 into soil and the earth subsurface, reduces N0.sub.3.sup.- contamination of surface and groundwater, and stimulates photosynthetic fixation of CO.sub.2 from the atmosphere. The method for converting CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions into fertilizers includes the step of collecting these materials from the emissions of industrial combustion facilities such as fossil fuel-powered energy sources and transporting the emissions to a reactor. In the reactor, the CO.sub.2, CO, N.sub.2, SO.sub.x, and/or NO.sub.x are converted into carbonate-containing fertilizers using H.sub.2, CH.sub.4, or NH.sub.3. The carbonate-containing fertilizers are then applied to soil and green plants to (1) sequester inorganic carbon into soil and subsoil earth layers by enhanced carbonation of groundwater and the earth minerals, (2) reduce the environmental problem of NO.sub.3.sup.- runoff by substituting for ammonium nitrate fertilizer, and (3) stimulate photosynthetic fixation of CO.sub.2 from the atmosphere by the fertilization effect of the carbonate-containing fertilizers.

  19. Elemental and isotopic analysis of inorganic salts by laser desorption ionization mass spectrometry

    SciTech Connect (OSTI)

    Jayasekharan, T.; Sahoo, N. K.

    2013-02-05

    Laser desorption ionization mass spectrometry is applied for the analysis of elements as well as their isotopic composition in different inorganic salts. At very low laser energies the inorganic ions are desorbed and ionized from the thin layer of the sample surface. The naturally occurring isotopes of alkali and silver ions are resolved using time of flight mass spectrometer. Further increase in laser energy shows the appearance of Al, Cr, and Fe ions in the mass spectra. This indicates the penetration laser beam beyond the sample surface leading to the ablation of sample target at higher energies. The simultaneous appearance of atomic ions from the sample target at relatively higher laser energies hampers the unambiguous identification of amino acid residues from the biomolecular ions in MALDI-MS.

  20. 2013 INORGANIC REACTION MECHANISMS GORDON RESEARCH CONFERENCE (MARCH 3-8, 2013 - HOTEL GALVEZ, GALVESTON TX)

    SciTech Connect (OSTI)

    Abu-Omar, Mahdi M.

    2012-12-08

    The 2013 Gordon Conference on Inorganic Reaction Mechanisms will present cutting-edge research on the molecular aspects of inorganic reactions involving elements from throughout the periodic table and state-of-the art techniques that are used in the elucidation of reaction mechanisms. The Conference will feature a wide range of topics, such as homogeneous and heterogeneous catalysis, metallobiochemistry, electron-transfer in energy reactions, polymerization, nitrogen fixation, green chemistry, oxidation, solar conversion, alkane functionalization, organotransition metal chemistry, and computational chemistry. The talks will cover themes of current interest including energy, materials, and bioinorganic chemistry. Sections cover: Electron-Transfer in Energy Reactions; Catalytic Polymerization and Oxidation Chemistry; Kinetics and Spectroscopy of Heterogeneous Catalysts; Metal-Organic Chemistry and its Application in Synthesis; Green Energy Conversion;Organometallic Chemistry and Activation of Small Molecules; Advances in Kinetics Modeling and Green Chemistry; Metals in Biology and Disease; Frontiers in Catalytic Bond Activation and Cleavage.

  1. Inorganic-Organic Molecules and Solids with Nanometer-Sized Pores

    SciTech Connect (OSTI)

    Maverick, Andrew W.

    2011-12-17

    We are constructing porous inorganic-organic hybrid molecules and solids, many of which contain coordinatively unsaturated metal centers. In this work, we use multifunctional ???²-diketone ligands as ?¢????building blocks?¢??? to prepare extended-solid and molecular porous materials that are capable of reacting with a variety of guest molecules.

  2. Composite Organic Radical - Inorganic Hybrid Cathode for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Huang, Qian; Cosimbescu, Lelia; Koech, Phillip K.; Choi, Daiwon; Lemmon, John P.

    2013-07-01

    A new organic radical inorganic hybrid cathode comprised of PTMA/LiFePO4 composite system is developed and reported for the first time. The hybrid cathodes demonstrate high pulse power capability resulting in a significant improvement over the pure PTMA or LiFePO4 cathode which is very promising for transportation and other high pulse power applications that require long cycle life and lower cost.

  3. Characterization and calibration of a viscoelastic simplified potential energy clock model for inorganic glasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chambers, Robert S.; Tandon, Rajan; Stavig, Mark E.

    2015-07-07

    In this study, to analyze the stresses and strains generated during the solidification of glass-forming materials, stress and volume relaxation must be predicted accurately. Although the modeling attributes required to depict physical aging in organic glassy thermosets strongly resemble the structural relaxation in inorganic glasses, the historical modeling approaches have been distinctly different. To determine whether a common constitutive framework can be applied to both classes of materials, the nonlinear viscoelastic simplified potential energy clock (SPEC) model, developed originally for glassy thermosets, was calibrated for the Schott 8061 inorganic glass and used to analyze a number of tests. A practicalmore » methodology for material characterization and model calibration is discussed, and the structural relaxation mechanism is interpreted in the context of SPEC model constitutive equations. SPEC predictions compared to inorganic glass data collected from thermal strain measurements and creep tests demonstrate the ability to achieve engineering accuracy and make the SPEC model feasible for engineering applications involving a much broader class of glassy materials.« less

  4. Characterization and calibration of a viscoelastic simplified potential energy clock model for inorganic glasses

    SciTech Connect (OSTI)

    Chambers, Robert S.; Tandon, Rajan; Stavig, Mark E.

    2015-07-07

    In this study, to analyze the stresses and strains generated during the solidification of glass-forming materials, stress and volume relaxation must be predicted accurately. Although the modeling attributes required to depict physical aging in organic glassy thermosets strongly resemble the structural relaxation in inorganic glasses, the historical modeling approaches have been distinctly different. To determine whether a common constitutive framework can be applied to both classes of materials, the nonlinear viscoelastic simplified potential energy clock (SPEC) model, developed originally for glassy thermosets, was calibrated for the Schott 8061 inorganic glass and used to analyze a number of tests. A practical methodology for material characterization and model calibration is discussed, and the structural relaxation mechanism is interpreted in the context of SPEC model constitutive equations. SPEC predictions compared to inorganic glass data collected from thermal strain measurements and creep tests demonstrate the ability to achieve engineering accuracy and make the SPEC model feasible for engineering applications involving a much broader class of glassy materials.

  5. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    1. Greenhouse Gas Emissions Overview 1.1 Total emissions Total U.S. anthropogenic (human-caused) greenhouse gas emissions in 2009 were 5.8 percent below the 2008 total (Table 1). The decline in total emissions-from 6,983 million metric tons carbon dioxide equivalent (MMTCO2e) in 2008 to 6,576 MMTCO2e in 2009-was the largest since emissions have been tracked over the 1990-2009 time frame. It was largely the result of a 419-MMTCO2e drop in carbon dioxide (CO2) emissions (7.1 percent). There was a

  6. Assessment of the potential for refinery applications of inorganic membrane technology: An identification and screening analysis. Final report

    SciTech Connect (OSTI)

    Johnson, H.E.; Schulman, B.L.

    1993-05-01

    Commercial application of membrane technology in the separation of gas, liquid, and solid streams has grown to a business with worldwide revenues exceeding $1 billion annually. Use of organic membranes for industrial gas separation, particularly in the refining industry, is one of the major growth areas. However, organic membranes based on polymeric separation barriers, are susceptible to damage by liquids, and careful precautions must be taken to retain the system integrity. Researchers are currently developing small pore sized inorganic membranes which may substantially increase the efficiency and economics in selected refinery separation applications. Expected advantages of these advanced inorganic membranes include high permeability, high selectivity, and low manufacturing cost. SFA Pacific conducted a screening analysis to identify applications for inorganic membrane technology in the petroleum refining industry and their potential cost advantages over competing separation systems. Two meetings were held in connection with this project. Copies of Viewgraphs presented by SFA Pacific at these meetings are attached in Appendices A and C. Potential high priority applications and market impacts of advanced inorganic membrane technology in the refining industry are addressed in this report, and include the following areas: Competitive separation technologies; application of those technologies; incentives for inorganic membranes; market benefits and impacts of inorganic membranes.

  7. Supercomputers Take a Cue From Microwave Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for one or a few dedicated functions. "Because the ultimate goal of the embedded market is to maximize battery life, these technologies have always been driven by...

  8. A fully integrated oven controlled microelectromechanical oscillator...

    Office of Scientific and Technical Information (OSTI)

    Authors: Wojciechowski, Kenneth E. 1 ; Baker, Michael S. 1 ; Clews, Peggy J. 1 ; Olsson, Roy H. 1 + Show Author Affiliations Sandia National Lab. (SNL-NM), Albuquerque, NM ...

  9. A fully integrated oven controlled microelectromechanical oscillator...

    Office of Scientific and Technical Information (OSTI)

    Additional Journal Information: Journal Volume: 24; Journal Issue: 6; Journal ID: ISSN 1057-7157 Publisher: IEEE Research Org: Sandia National Laboratories (SNL-NM), Albuquerque, ...

  10. Low emissions diesel fuel

    DOE Patents [OSTI]

    Compere, A.L.; Griffith, W.L.; Dorsey, G.F.; West, B.H.

    1998-05-05

    A method and matter of composition for controlling NO{sub x} emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO{sub x} produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  11. Low emissions diesel fuel

    DOE Patents [OSTI]

    Compere, Alicia L.; Griffith, William L.; Dorsey, George F.; West, Brian H.

    1998-01-01

    A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  12. Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Gaseous Emissions - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  13. Power plant emissions reduction

    DOE Patents [OSTI]

    Anand, Ashok Kumar; Nagarjuna Reddy, Thirumala Reddy

    2015-10-20

    A system for improved emissions performance of a power plant generally includes an exhaust gas recirculation system having an exhaust gas compressor disposed downstream from the combustor, a condensation collection system at least partially disposed upstream from the exhaust gas compressor, and a mixing chamber in fluid communication with the exhaust gas compressor and the condensation collection system, where the mixing chamber is in fluid communication with the combustor.

  14. National Emission Standards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Pollutants Calendar Year 1999 National Emission Standards for Hazardous Air Pollutants Calendar Year 1999 June 2000 June 2000 U.S. Department of Energy Nevada Operations Office Las Vegas, Nevada U.S. Department of Energy Nevada Operations Office Las Vegas, Nevada DOE/NV/11718--442 DOE/NV/11718--442 DISCLAIMER Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement,

  15. GBTL Workshop GHG Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GHG Emissions GBTL Workshop GHG Emissions EERE Presentation of Greenhouse Gas EmissionsResource Potential gbtlworkshopghgemissions.pdf More Documents & Publications GBTL...

  16. Energy-Related Carbon Emissions in Manufacturing

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Energy-Related Carbon Emissions Detailed Energy-Related Carbon Emissions All Industry Groups 1994 emissions Selected Industries Petroleum refining Chemicals Iron & Steel...

  17. Soft x-ray free-electron laser induced damage to inorganic scintillators

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burian, Tomáš; Hájková, Věra; Chalupský, Jaromír; Vyšín, Luděk; Boháček, Pavel; Přeček, Martin; Wild, Jan; Özkan, Cigdem; Coppola, Nicola; Farahani, Shafagh Dastjani; et al

    2015-01-07

    An irreversible response of inorganic scintillators to intense soft x-ray laser radiation was investigated at the FLASH (Free-electron LASer in Hamburg) facility. Three ionic crystals, namely, Ce:YAG (cerium-doped yttrium aluminum garnet), PbWO4 (lead tungstate), and ZnO (zinc oxide), were exposed to single 4.6 nm ultra-short laser pulses of variable pulse energy (up to 12 μJ) under normal incidence conditions with tight focus. Damaged areas produced with various levels of pulse fluences, were analyzed on the surface of irradiated samples using differential interference contrast (DIC) and atomic force microscopy (AFM). The effective beam area of 22.2 ± 2.2 μm2 was determinedmore » by means of the ablation imprints method with the use of poly(methyl methacrylate) - PMMA. Applied to the three inorganic materials, this procedure gave almost the same values of an effective area. The single-shot damage threshold fluence was determined for each of these inorganic materials. The Ce:YAG sample seems to be the most radiation resistant under the given irradiation conditions, its damage threshold was determined to be as high as 660.8 ± 71.2 mJ/cm2. Contrary to that, the PbWO4 sample exhibited the lowest radiation resistance with a threshold fluence of 62.6 ± 11.9 mJ/cm2. The threshold for ZnO was found to be 167.8 ± 30.8 mJ/cm2. Both interaction and material characteristics responsible for the damage threshold difference are discussed in the article.« less

  18. Quantum confinement of zero-dimensional hybrid organic-inorganic polaritons at room temperature

    SciTech Connect (OSTI)

    Nguyen, H. S.; Lafosse, X.; Amo, A.; Bouchoule, S.; Bloch, J.; Abdel-Baki, K.; Lauret, J.-S.; Deleporte, E.

    2014-02-24

    We report on the quantum confinement of zero-dimensional polaritons in perovskite-based microcavity at room temperature. Photoluminescence of discrete polaritonic states is observed for polaritons localized in symmetric sphere-like defects which are spontaneously nucleated on the top dielectric Bragg mirror. The linewidth of these confined states is found much sharper (almost one order of magnitude) than that of photonic modes in the perovskite planar microcavity. Our results show the possibility to study organic-inorganic cavity polaritons in confined microstructure and suggest a fabrication method to realize integrated polaritonic devices operating at room temperature.

  19. Subsurface Monitor for Dissolved Inorganic Carbon at Geological Sequestration Site Phase 1 SBIR Final Report

    SciTech Connect (OSTI)

    Sheng Wu

    2012-08-03

    Phase I research of this SBIR contract has yielded anticipated results and enable us to develop a practical new instrument to measure the Dissolved Inorganic Carbons (DIC) as well as Supercritical (SC) CO2 in underground brine water at higher sensitivity, lower cost, higher frequency and longer period of time for the Monitoring, Verification & Accounting (MVA) of CO2 sequestration as well as Enhanced Oil Recovery (EOR). We show that reduced cost and improved performance are possible; both future and emerging market exist for the proposed new instrument.

  20. Acoustic emission intrusion detector

    DOE Patents [OSTI]

    Carver, Donald W. (Knoxville, TN); Whittaker, Jerry W. (Knoxville, TN)

    1980-01-01

    An intrusion detector is provided for detecting a forcible entry into a secured structure while minimizing false alarms. The detector uses a piezoelectric crystal transducer to sense acoustic emissions. The transducer output is amplified by a selectable gain amplifier to control the sensitivity. The rectified output of the amplifier is applied to a Schmitt trigger circuit having a preselected threshold level to provide amplitude discrimination. Timing circuitry is provided which is activated by successive pulses from the Schmitt trigger which lie within a selected time frame for frequency discrimination. Detected signals having proper amplitude and frequency trigger an alarm within the first complete cycle time of a detected acoustical disturbance signal.

  1. Positron Emission Tomography (PET)

    DOE R&D Accomplishments [OSTI]

    Welch, M. J.

    1990-01-01

    Positron emission tomography (PET) assesses biochemical processes in the living subject, producing images of function rather than form. Using PET, physicians are able to obtain not the anatomical information provided by other medical imaging techniques, but pictures of physiological activity. In metaphoric terms, traditional imaging methods supply a map of the body's roadways, its, anatomy; PET shows the traffic along those paths, its biochemistry. This document discusses the principles of PET, the radiopharmaceuticals in PET, PET research, clinical applications of PET, the cost of PET, training of individuals for PET, the role of the United States Department of Energy in PET, and the futures of PET.

  2. Measurement and Characterization of Unregulated Emissions from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Measurement and Characterization of Unregulated Emissions from Advanced Technologies...

  3. Advanced emissions control development program. Quarterly technical progress report No. 9, October 1--December 31, 1996

    SciTech Connect (OSTI)

    Evans, A.P.

    1996-12-31

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U.S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emission compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emission control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  4. Elastic emission polishing

    SciTech Connect (OSTI)

    Loewenthal, M.; Loseke, K.; Dow, T.A.; Scattergood, R.O.

    1988-12-01

    Elastic emission polishing, also called elastic emission machining (EEM), is a process where a stream of abrasive slurry is used to remove material from a substrate and produce damage free surfaces with controlled surface form. It is a noncontacting method utilizing a thick elasto-hydrodynamic film formed between a soft rotating ball and the workpiece to control the flow of the abrasive. An apparatus was built in the Center, which consists of a stationary spindle, a two-axis table for the workpiece, and a pump to circulate the working fluid. The process is controlled by a programmable computer numerical controller (CNC), which presently can operate the spindle speed and movement of the workpiece in one axis only. This apparatus has been used to determine material removal rates on different material samples as a function of time, utilizing zirconium oxide (ZrO{sub 2}) particles suspended in distilled water as the working fluid. By continuing a study of removal rates the process should become predictable, and thus create a new, effective, yet simple tool for ultra-precision mechanical machining of surfaces.

  5. Zero emission coal

    SciTech Connect (OSTI)

    Ziock, H.; Lackner, K.

    2000-08-01

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  6. Conducting Polymer-Inorganic Nanoparticle (CPIN) Nanoarrays for Battery Applications - Final Technical Report

    SciTech Connect (OSTI)

    Buttry, Daniel A.

    2006-06-27

    Our objective was to develop new, self-assembling conducting polymer-inorganic nanoparticle nanoarrays (CPIN nanoarrays) comprised of nanoparticles of inorganic Li+ insertion compounds that are wired together with oligomeric chains of derivatives of polythiophene. Using these nanoarrays, we developed an understanding of the relationship between structure and electrochemical function for nanostructured materials. Such nanoarrays are expected to have extremely high specific energy and specific power for battery applications due to the unique structural characteristics that derive from the nanoarray. Under this award we developed several synthetic approaches to producing manganese dioxide nanoparticles (NPs). We also developed a layer-by-layer approach for immobilizing these NPs so they could be examined electrochemically. We also developed new synthetic procedures for encapsulating manganese dioxide nanoparticles within spheres of polyethylenedioxythiophene (PEDOT), a conducting polymer with excellent charge-discharge stability. These have a unique manganese dioxide core-PEDOT shell structure. We examined the structures of these systems using transmission electron microscopy, various scanning probe microscopies, and electrochemical measurements. Various technical reports have been submitted that describe the work, including conference presentations, publications and patent applications. These reports are available through http://www.osti.gov, the DOE Energy Link System.

  7. Controlled synthesis of hyper-branched inorganic nanocrystals withrich three-dimensional structures

    SciTech Connect (OSTI)

    Kanaras, Antonios G.; Sonnichsen, Carsten; Liu, Haitao; Alivisatos, A. Paul

    2005-07-27

    Studies of crystal growth kinetics are tightly integrated with advances in the creation of new nanoscale inorganic building blocks and their functional assemblies 1-11. Recent examples include the development of semiconductor nanorods which have potential uses in solar cells 12-17, and the discovery of a light driven process to create noble metal particles with sharp corners that can be used in plasmonics 18,19. In the course of studying basic crystal growth kinetics we developed a process for preparing branched semiconductor nanocrystals such as tetrapods and inorganic dendrimers of precisely controlled generation 20,21. Here we report the discovery of a crystal growth kinetics regime in which a new class of hyper-branched nanocrystals are formed. The shapes range from 'thorny balls', to tree-like ramified structures, to delicate 'spider net'-like particles. These intricate shapes depend crucially on a delicate balance of branching and extension. The multitudes of resulting shapes recall the diverse shapes of snowflakes 22.The three dimensional nature of the branch points here, however, lead to even more complex arrangements than the two dimensionally branched structures observed in ice. These hyper-branched particles not only extend the available three-dimensional shapes in nanoparticle synthesis ,but also provide a tool to study growth kinetics by carefully observing and modeling particle morphology.

  8. Cellular morphology of organic-inorganic hybrid foams based on alkali alumino-silicate matrix

    SciTech Connect (OSTI)

    Verdolotti, Letizia; Capasso, Ilaria; Lavorgna, Marino; Liguori, Barbara; Caputo, Domenico; Iannace, Salvatore

    2014-05-15

    Organic-inorganic hybrid foams based on an alkali alumino-silicate matrix were prepared by using different foaming methods. Initially, the synthesis of an inorganic matrix by using aluminosilicate particles, activated through a sodium silicate solution, was performed at room temperature. Subsequently the viscous paste was foamed by using three different methods. In the first method, gaseous hydrogen produced by the oxidization of Si powder in an alkaline media, was used as blowing agent to generate gas bubbles in the paste. In the second method, the porous structure was generated by mixing the paste with a meringue type of foam previously prepared by whipping, under vigorous stirring, a water solution containing vegetal proteins as surfactants. In the third method, a combination of these two methods was employed. The foamed systems were consolidated for 24 hours at 40C and then characterized by FTIR, X-Ray diffraction, scanning electron microscopy (SEM) and compression tests. Low density foams (?500 Kg/m{sup 3}) with good cellular structure and mechanical properties were obtained by combining the meringue approach with the use of the chemical blowing agent based on Si.

  9. Polymeric media comprising polybenzimidazoles N-substituted with organic-inorganic hybrid moiety

    DOE Patents [OSTI]

    Klaehn, John R. [Idaho Falls, ID; Peterson, Eric S. [Idaho Falls, ID; Wertsching, Alan K. [Idaho Falls, ID; Orme, Christopher J. [Shelley, ID; Luther, Thomas A. [Idaho Falls, ID; Jones, Michael G. [Pocatello, ID

    2009-12-15

    A PBI compound includes imidazole nitrogens at least a portion of which are substituted with an organic-inorganic hybrid moiety may be included in a separator medium. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2-- where R is selected from among methyl, phenyl, vinyl, and allyl. The separatory medium may exhibit an H.sub.2, Ar, N.sub.2, O.sub.2, CH.sub.3, or CO.sub.2 gas permeability greater than the gas permeability of a comparable separatory medium comprising the PBI compound without substitution. The separatory medium may further include an electronically conductive medium and/or ionically conductive medium. The separatory medium may be used as a membrane (semi-permeable, permeable, and non-permeable), a barrier, an ion exhcange media, a filter, a gas chromatography coating (such as stationary phase coating in affinity chromatography), etc.

  10. THE SCENARIOS APPROACH TO ATTENUATION-BASED REMEDIES FOR INORGANIC AND RADIONUCLIDE CONTAMINANTS

    SciTech Connect (OSTI)

    Vangelas, K.; Rysz, M.; Truex, M.; Brady, P.; Newell, C.; Denham, M.

    2011-08-04

    Guidance materials based on use of conceptual model scenarios were developed to assist evaluation and implementation of attenuation-based remedies for groundwater and vadose zones contaminated with inorganic and radionuclide contaminants. The Scenarios approach is intended to complement the comprehensive information provided in the US EPA's Technical Protocol for Monitored Natural Attenuation (MNA) of Inorganic Contaminants by providing additional information on site conceptual models and extending the evaluation to consideration of Enhanced Attenuation approaches. The conceptual models incorporate the notion of reactive facies, defined as units with hydrogeochemical properties that are different from surrounding units and that react with contaminants in distinct ways. The conceptual models also incorporate consideration of biogeochemical gradients, defined as boundaries between different geochemical conditions that have been induced by waste disposal or other natural phenomena. Gradients can change over time when geochemical conditions from one area migrate into another, potentially affecting contaminant mobility. A recognition of gradients allows the attenuation-affecting conditions of a site to be projected into the future. The Scenarios approach provides a stepwise process to identify an appropriate category of conceptual model and refine it for a specific site. Scenario materials provide links to pertinent sections in the EPA technical protocol and present information about contaminant mobility and important controlling mechanism for attenuation-based remedies based on the categories of conceptual models.

  11. A Community Emissions Data System (CEDS) for Historical Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Zhou, Yuyu; Kyle, G. Page; Wang, Hailong; Yu, Hongbin

    2015-04-21

    Historical emission estimates for anthropogenic aerosol and precursor compounds are key data needed for Earth system models, climate models, and atmospheric chemistry and transport models; both for general analysis and assessment and also for model validation through comparisons with observations. Current global emission data sets have a number of shortcomings, including timeliness and transparency. Satellite and other earth-system data are increasingly available in near real-time, but global emission estimates lag by 5-10 years. The CEDS project will construct a data-driven, open source framework to produce annually updated emission estimates. The basic methodologies to be used for this system have been used for SO2 (Smith et al. 2011, Klimont, Smith and Cofala 2013), and are designed to complement existing inventory efforts. The goal of this system is to consistently extend current emission estimates both forward in time to recent years and also back over the entire industrial era. The project will produce improved datasets for global and (potentially) regional model, allow analysis of trends across time, countries, and sectors of emissions and emission factors, and facilitate improved scientific analysis in general. Consistent estimation of uncertainty will be an integral part of this system. This effort will facilitate community evaluation of emissions and further emission-related research more generally.

  12. Fuel Mix and Emissions Disclosure

    Broader source: Energy.gov [DOE]

    Electricity suppliers and electricity companies must also provide a fuel mix report to customers twice annually, within the June and December billing cycles. Emissions information must be disclos...

  13. Biodiesel and Pollutant Emissions (Presentation)

    SciTech Connect (OSTI)

    McCormick, R.; Williams, A.; Ireland, J.; Hayes, B.

    2006-09-28

    Presents the results from three methods of testing--engine, chassis, and PEM--for testing nitrogen oxide (NOx) emissions from B20.

  14. Crystal structure and catalytic properties of three inorganicorganic hybrid constructed from heteropolymolybdate and aminopyridine

    SciTech Connect (OSTI)

    Deng, Qian; Huang, Yilan; Peng, Zhenshan; Dai, Zengjin; Lin, Minru; Cai, Tiejun

    2013-04-15

    Three new organicinorganic hybrid compounds (2-C{sub 5}H{sub 7}N{sub 2}){sub 3}(SiMo{sub 12}O{sub 40})(C{sub 4}H{sub 8}N{sub 4}){sub 0.5}(C{sub 5}H{sub 6}N{sub 2}){sub 2}(H{sub 2}O){sub 2} (1), (3-C{sub 5}H{sub 7}N{sub 2}){sub 8}(SiMo{sub 12}O{sub 40}){sub 2}(C{sub 5}H{sub 7}N{sub 3}){sub 2}(H{sub 8}O{sub 4})(H{sub 2}O){sub 8} (2) and (4-C{sub 5}H{sub 7}N{sub 2}){sub 6}(SiMo{sub 12}O{sub 40}) (3) composed the heteropolymolybdate ?-H{sub 4}SiMo{sub 12}O{sub 40} and the organic substrate 2/3/4-aminopyridine have been hydrothermally synthesized and characterized by routine methods. Compounds 1 and 2 exhibit a three-dimensional supramolecular network via hydrogen bond and ?? stacking interactions. Compound 2 contains a tetramolecular water cluster which consists of four water molecules connected by hydrogen bonds. These compounds exhibit good thermal stability and photoluminescent phenomena. Compounds 1 and 3 are active for catalytic oxidation of methanol in a continuous-flow fixed-bed micro-reactor, when the initial concentration of methanol is 2.75 g m{sup ?3} in air and flow rate is 10 mL min{sup ?1} at 150 C, corresponding to the elimination rate of methanol i.e. 87.7% and 76.8%, respectively. - Three new Keggin type inorganicorganic hybrid frameworks were synthesized. Compounds exhibit an extended three-dimensional supramolecular network. Compounds 1 and 3 have better catalytic activity for eliminating methanol. Highlights: ? Three 3-D Keggin inorganicorganic hybrid frameworks were synthesized. ? The ?? stacking interactions are existed in Compounds 1 and 2. ? Compound 2 contains a tetramolecular water cluster connected by hydrogen bond. ? Compounds 1 and 3 are active in the catalytic oxidation of methanol into CO{sub 2} and H{sub 2}O.

  15. Development of nanostructured and surface modified semiconductors for hybrid organic-inorganic solar cells.

    SciTech Connect (OSTI)

    Hsu, Julia, W. P.

    2008-09-01

    Solar energy conversion is increasingly being recognized as one of the principal ways to meet future energy needs without causing detrimental environmental impact. Hybrid organic-inorganic solar cells (SCs) are attracting particular interest due to the potential for low cost manufacturing and for use in new applications, such as consumer electronics, architectural integration and light-weight sensors. Key materials advantages of these next generation SCs over conventional semiconductor SCs are in design opportunities--since the different functions of the SCs are carried out by different materials, there are greater materials choices for producing optimized structures. In this project, we explore the hybrid organic-inorganic solar cell system that consists of oxide, primarily ZnO, nanostructures as the electron transporter and poly-(3-hexylthiophene) (P3HT) as the light-absorber and hole transporter. It builds on our capabilities in the solution synthesis of nanostructured semiconducting oxide arrays to this photovoltaic (PV) technology. The three challenges in this hybrid material system for solar applications are (1) achieving inorganic nanostructures with critical spacing that matches the exciton diffusion in the polymer, {approx} 10 nm, (2) infiltrating the polymer completely into the dense nanostructure arrays, and (3) optimizing the interfacial properties to facilitate efficient charge transfer. We have gained an understanding and control over growing oriented ZnO nanorods with sub-50 nm diameters and the required rod-to-rod spacing on various substrates. We have developed novel approaches to infiltrate commercially available P3HT in the narrow spacing between ZnO nanorods. Also, we have begun to explore ways to modify the interfacial properties. In addition, we have established device fabrication and testing capabilities at Sandia for prototype devices. Moreover, the control synthesis of ZnO nanorod arrays lead to the development of an efficient anti-reflection coating for multicrystalline Si solar cells. An important component of this project is the collaboration with Dr. Dave Ginley's group at NREL. The NREL efforts, which are funded by NREL's LDRD program, focus on measuring device performance, external quantum efficiency, photoconductance through highly specialized non-contact time-resolved microwave conductivity (TRMC) measurements, and vapor phase deposition of oxide materials. The close collaboration with NREL enables us to enter this competitive field in such short time. Joint publications and presentations have resulted from this fruitful collaboration. To this date, 5 referred journal papers have resulted from this project, with 2 more in preparation. Several invited talks and numerous contributed presentations in international conferences are also noted. Sandia has gained the reputation of being one of forefront research groups on nanostructured hybrid solar cells.

  16. Alternative Fuels Data Center: Propane Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emissions to someone by E-mail Share Alternative Fuels Data Center: Propane Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Propane Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Propane Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Propane Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Propane Vehicle Emissions on Digg Find More places to share Alternative Fuels Data Center: Propane Vehicle Emissions on

  17. Semiconductor nanocrystals covalently bound to solid inorganic surfaces using self-assembled monolayers

    DOE Patents [OSTI]

    Alivisatos, A. Paul (Berkeley, CA); Colvin, Vicki L. (Berkeley, CA)

    1998-01-01

    Methods are described for attaching semiconductor nanocrystals to solid inorganic surfaces, using self-assembled bifunctional organic monolayers as bridge compounds. Two different techniques are presented. One relies on the formation of self-assembled monolayers on these surfaces. When exposed to solutions of nanocrystals, these bridge compounds bind the crystals and anchor them to the surface. The second technique attaches nanocrystals already coated with bridge compounds to the surfaces. Analyses indicate the presence of quantum confined clusters on the surfaces at the nanolayer level. These materials allow electron spectroscopies to be completed on condensed phase clusters, and represent a first step towards synthesis of an organized assembly of clusters. These new products are also disclosed.

  18. Biologically Inspired Synthesis Route to Three-Dimensionally Structured Inorganic Thin Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schwenzer, Birgit; Morse, Daniel E.

    2008-01-01

    Inorganic thin films (hydroxide, oxide, and phosphate materials) that are textured on a submicron scale have been prepared from aqueous metal salt solutions at room temperature using vapor-diffusion catalysis. This generic synthesis approach mimics the essential advantages of the catalytic and structure-directing mechanisms observed for the formation of silica skeletons of marine sponges. Chemical composition, crystallinity, and the three-dimensional morphology of films prepared by this method are extremely sensitive to changes in the synthesis conditions, such as concentrations, reaction times, and the presence and nature of substrate materials. Focusing on different materials systems, the reaction mechanism for the formation ofmore » these thin films and the influence of different reaction parameters on the product are explained.« less

  19. Semiconductor nanocrystals covalently bound to solid inorganic surfaces using self-assembled monolayers

    DOE Patents [OSTI]

    Alivisatos, A.P.; Colvin, V.L.

    1998-05-12

    Methods are described for attaching semiconductor nanocrystals to solid inorganic surfaces, using self-assembled bifunctional organic monolayers as bridge compounds. Two different techniques are presented. One relies on the formation of self-assembled monolayers on these surfaces. When exposed to solutions of nanocrystals, these bridge compounds bind the crystals and anchor them to the surface. The second technique attaches nanocrystals already coated with bridge compounds to the surfaces. Analyses indicate the presence of quantum confined clusters on the surfaces at the nanolayer level. These materials allow electron spectroscopies to be completed on condensed phase clusters, and represent a first step towards synthesis of an organized assembly of clusters. These new products are also disclosed. 10 figs.

  20. Inorganic Corrosion-Inhibitive Pigments for High-Temperature Alkali-activated Well Casing Foam Cement

    SciTech Connect (OSTI)

    Sugama, T.; Pyatina, T.

    2014-11-14

    This study evaluates inorganic pigments for improving carbon steel (CS) brine-corrosion protection by the sodium metasilicate-activated calcium aluminate cement/Fly Ash blend at 300C. Calcium borosilicate (CBS) and zinc phosphate, significantly improved CS corrosion-protection by decreasing cements permeability for corrosive ions and inhibiting anodic corrosion. An amorphous Na2O-Al2O3-SiO2-H2O phase tightly attached to CS surface formed at 300oC in CBS-modified cement pore solution. The corrosion rate of the CS covered with this phase was nearly 4-fold lower than in the case of nonmodified cement pore solution where the major phase formed on the surface of CS was crystalline analcime.

  1. Inorganic Corrosion-Inhibitive Pigments for High-Temperature Alkali-activated Well Casing Foam Cement

    SciTech Connect (OSTI)

    Sugama, T.; Pyatina, T.

    2014-11-01

    This study evaluates inorganic pigments for improving carbon steel (CS) brine-corrosion protection by the sodium metasilicate-activated calcium aluminate cement/Fly Ash blend at 300C. Calcium borosilicate (CBS) and zinc phosphate, significantly improved CS corrosion-protection by decreasing cements permeability for corrosive ions and inhibiting anodic corrosion. An amorphous Na2O-Al2O3-SiO2-H2O phase tightly attached to CS surface formed at 300oC in CBS-modified cement pore solution. The corrosion rate of the CS covered with this phase was nearly 4-fold lower than in the case of nonmodified cement pore solution where the major phase formed on the surface of CS was crystalline analcime.

  2. Improved oxidation resistance of organic/inorganic composite atomic layer deposition coated cellulose nanocrystal aerogels

    SciTech Connect (OSTI)

    Smith, Sean W.; Matthews, David J.; Conley, John F., E-mail: jconley@eecs.oregonstate.edu [School of Electrical Engineering and Computer Science, 1148 Kelley Engineering Center, Oregon State University, Corvallis, Oregon 97331 (United States); Buesch, Christian; Simonsen, John [Department of Wood Science and Engineering, Oregon State University, 119 Richardson Hall, Corvallis, Oregon 97331 (United States)

    2014-07-01

    Cellulose nanocrystal (CNC) aerogels are coated with thin conformal layers of Al{sub 2}O{sub 3} using atomic layer deposition to form hybrid organic/inorganic nanocomposites. Electron probe microanalysis and scanning electron microscopy analysis indicated the Al{sub 2}O{sub 3} penetrated more than 1500??m into the aerogel for extended precursor pulse and exposure/purge times. The measured profile of coated fiber radius versus depth from the aerogel surface agrees well with simulations of precursor penetration depth in modeled aerogel structures. Thermogravimetric analysis shows that Al{sub 2}O{sub 3} coated CNC aerogel nanocomposites do not show significant thermal degradation below 295?C as compared with 175?C for uncoated CNC aerogels, an improvement of over 100?C.

  3. Structural resistance of chemically modified 1-D nanostructured titanates in inorganic acid environment

    SciTech Connect (OSTI)

    Marinkovic, Bojan A.; Fredholm, Yann C.; Morgado, Edisson

    2010-10-15

    Sodium containing one-dimensional nanostructured layered titanates (1-D NSLT) were produced both from commercial anatase powder and Brazilian natural rutile mineral sands by alkali hydrothermal process. The 1-D NSLT were chemically modified with proton, cobalt or iron via ionic exchange and all products were additionally submitted to intensive inorganic acid aging (pH = 0.5) for 28 days. The morphology and crystal structure transformations of chemically modified 1-D NSLT were followed by transmission electron microscopy, powder X-ray diffraction, selected area electron diffraction and energy dispersive spectroscopy. It was found that the original sodium rich 1-D NSLT and cobalt substituted 1-D NSLT were completely converted to rutile nanoparticles, while the protonated form was transformed in a 70%-30% (by weight) anatase-rutile nanoparticles mixture, very similar to that of the well-known TiO{sub 2}-photocatalyst P25 (Degussa). The iron substituted 1-D NSLT presented better acid resistance as 13% of the original structure and morphology remained, the rest being converted in rutile. A significant amount of remaining 1-D NSLT was also observed after the acid treatment of the product obtained from rutile sand. The results showed that phase transformation of NSLT into titanium dioxide polymorph in inorganic acid conditions were controllable by varying the exchanged cations. Finally, the possibility to transform, through acid aging, 1-D NSLT obtained from Brazilian natural rutile sand into TiO{sub 2}-polymorphs was demonstrated for the first time to the best of authors' knowledge, opening path for producing TiO{sub 2}-nanoproducts with different morphologies through a simple process and from a low cost precursor.

  4. Inorganic soil and groundwater chemistry near Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Moore, G.K.

    1995-03-01

    Near-surface soils, boreholes, and sediments near the Paducah Gaseous Diffusion Plant (PGDP) were sampled in 1989-91 as were monitoring wells, TVA wells, and privately-owned wells. Most wells were sampled two or three times. The resulting chemical analyses have been published in previous reports and have been previously described (CH2M HILL 1991, 1992; Clausen et al. 1992). The two reports by CH2M HILL are controversial, however, because, the concentrations of some constituents were reported to exceed background levels or drinking water standards and because both on-site (within the perimeter fence at PGDP) and off-site pollution was reported to have occurred. The groundwater samples upon which these interpretations were based may not be representative, however. The CH2M HILL findings are discussed in the report. The purpose of this report is to characterize the inorganic chemistry of groundwater and soils near PGDP, using data from the CH2M HILL reports (1991, 1992), and to determine whether or not any contamination has occurred. The scope is limited to analysis and interpretation of data in the CH2M HILL reports because previous interpretations of these data may not be valid, because samples were collected in a relatively short period of time at several hundred locations, and because the chemical analyses are nearly complete. Recent water samples from the same wells were not considered because the characterization of inorganic chemistry for groundwater and soil requirements only one representative sample and an accurate analysis from each location.

  5. Generalized local emission tomography

    DOE Patents [OSTI]

    Katsevich, Alexander J. (Los Alamos, NM)

    1998-01-01

    Emission tomography enables locations and values of internal isotope density distributions to be determined from radiation emitted from the whole object. In the method for locating the values of discontinuities, the intensities of radiation emitted from either the whole object or a region of the object containing the discontinuities are inputted to a local tomography function .function..sub..LAMBDA..sup.(.PHI.) to define the location S of the isotope density discontinuity. The asymptotic behavior of .function..sub..LAMBDA..sup.(.PHI.) is determined in a neighborhood of S, and the value for the discontinuity is estimated from the asymptotic behavior of .function..sub..LAMBDA..sup.(.PHI.) knowing pointwise values of the attenuation coefficient within the object. In the method for determining the location of the discontinuity, the intensities of radiation emitted from an object are inputted to a local tomography function .function..sub..LAMBDA..sup.(.PHI.) to define the location S of the density discontinuity and the location .GAMMA. of the attenuation coefficient discontinuity. Pointwise values of the attenuation coefficient within the object need not be known in this case.

  6. Vehicle Emissions Review - 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Vehicle Emissions Review - 2011 Reviews regulatory requirements and general technology approaches for heavy- and light-duty vehicle emissions control - filter technology, new catalysts, NOx control, diesel oxidation catalysts, gasoline particulate filters PDF icon deer11_johnson.pdf More Documents & Publications Vehicle Emissions Review - 2012 Diesel Emission Control Review Review of Emerging Diesel Emissions and Control

  7. Vehicle Emissions Review - 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Vehicle Emissions Review - 2012 Reviews vehicle emission control highlighting representative studies that illustrate the state-of-the-art PDF icon deer12_johnson.pdf More Documents & Publications Diesel Emission Control Review Review of Emerging Diesel Emissions and Control Diesel Emission Control Technology in Review

  8. Diesel Emission Control Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review Diesel Emission Control Review Reviews regulatory requirements and technology approaches for diesel emission control for heavy and light duty applications PDF icon deer10_tjohnson.pdf More Documents & Publications Review of Emerging Diesel Emissions and Control Diesel Emission Control Technology in Review Vehicle Emissions Review - 2012

  9. Advanced Collaborative Emissions Study (ACES)

    SciTech Connect (OSTI)

    Greenbaum, Daniel; Costantini, Maria; Van Erp, Annemoon; Shaikh, Rashid; Bailey, Brent; Tennant, Chris; Khalek, Imad; Mauderly, Joe; McDonald, Jacob; Zielinska, Barbara; Bemis, Jeffrey; Storey, John; Hallberg, Lance; Clark, Nigel

    2013-12-31

    The objective of the Advanced Collaborative Emissions Study (ACES) was to determine before widespread commercial deployment whether or not the new, energy-efficient, heavy duty diesel engines (2007 and 2010 EPA Emissions Standards Compliant) may generate anticipated toxic emissions that could adversely affect the environment and human health. ACES was planned to take place in three phases. In Phase 1, extensive emissions characterization of four production-intent prototype engine and control systems designed to meet 2007 standards for nitrogen oxides (NOx) and particulate matter (PM) was conducted at an existing emissions characterization facility: Southwest Research Institute (SwRI). One of the tested engines was selected (at random, after careful comparison of results) for health testing in Phase 3. In Phase 2, extensive emission characterization of three production-intent prototype engine and control systems meeting the 2010 standards (including more advanced NOx controls to meet the more stringent 2010 NOx standards) was conducted at the same test facility. In Phase 3, one engine/aftertreatment system selected from Phase 1 was further characterized during health effects studies (at an existing inhalation toxicology laboratory: Lovelace Respiratory Research Institute, [LRRI]) to form the basis of the ACES safety assessment. The Department of Energy (DOE) award provided funding for emissions characterization in Phases 1 and 2 as well as exposure characterization in Phase 3. The main health analyses in Phase 3 were funded separately and are not reported here.

  10. Metal tritides helium emission

    SciTech Connect (OSTI)

    Beavis, L.C.

    1980-02-01

    Over the past several years, we have been measuring the release of helium from metal tritides (primarily erbium tritide). We find that qualitatively all tritides of interest to us behave the same. When they are first formed, the helium is released at a low rate that appears to be related to the amount of surface area which has access to the outside of the material (either film or bulk). For example, erbium tritide films initially release about 0.3% of the helium generated. Most tritide films emit helium at about this rate initially. At some later time, which depends upon the amount of helium generated, the parent occluding element and the degree of tritium saturation of the dihydride phase the helium emission changes to a new mode in which it is released at approximately the rate at which it is generated (for example, we measure this value to be approx. = .31 He/Er for ErT/sub 1/./sub 9/ films). If erbium ditritide is saturated beyond 1.9 T/Er, the critical helium/metal ratio decreases. For example, in bulk powders ErT/sub 2/./sub 15/ reaches critical release concentration at approx. = 0.03. Moderate elevation of temperature above room temperature has little impact on the helium release rate. It appears that the process may have approx. = 2 kcal/mol activation energy. The first helium formed is well bound. As the tritide ages, the helium is found in higher energy sites. Similar but less extensive measurements on scandium, titanium, and zirconium tritides are also described. Finally, the thermal desorption of erbium tritides of various ages from 50 days to 3154 days is discussed. Significant helium is desorbed along with the tritium in all but the youngest samples during thermodesorption.

  11. Trading Emissions PLC | Open Energy Information

    Open Energy Info (EERE)

    Trading Emissions PLC Jump to: navigation, search Name: Trading Emissions PLC Place: London, United Kingdom Zip: EC2N 4AW Product: Trading Emissions PLC is an investment fund...

  12. Alternative Fuels Data Center: Biodiesel Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Biodiesel Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Biodiesel Vehicle Emissions on Digg Find More places to share Alternative Fuels Data Center:

  13. Alternative Fuels Data Center: Ethanol Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Ethanol Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Ethanol Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Ethanol Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Ethanol Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Ethanol Vehicle Emissions on Digg Find More places to share Alternative Fuels Data Center: Ethanol Vehicle

  14. Acoustic emission linear pulse holography

    DOE Patents [OSTI]

    Collins, H.D.; Busse, L.J.; Lemon, D.K.

    1983-10-25

    This device relates to the concept of and means for performing Acoustic Emission Linear Pulse Holography, which combines the advantages of linear holographic imaging and Acoustic Emission into a single non-destructive inspection system. This unique system produces a chronological, linear holographic image of a flaw by utilizing the acoustic energy emitted during crack growth. The innovation is the concept of utilizing the crack-generated acoustic emission energy to generate a chronological series of images of a growing crack by applying linear, pulse holographic processing to the acoustic emission data. The process is implemented by placing on a structure an array of piezoelectric sensors (typically 16 or 32 of them) near the defect location. A reference sensor is placed between the defect and the array.

  15. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A.P.Evans; K.E. Redinger; M.J. Holmes

    1998-04-01

    The objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESPS), fabric filters (baghouse), and wet flue gas desulfurization. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate and hydrogen chloride. Following the construction and evaluation of a representative air toxics test facility in Phase I, Phase II focused on the evaluation of mercury and several other air toxics emissions. The AECDP is jointly funded by the United States Department of Energy's Federal Energy Technology Center (DOE), the Ohio Coal Development Office within the Ohio Department of Development (oCDO), and Babcock& Wilcox-a McDermott company (B&W).

  16. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    grasslands 34 Net carbon dioxide sequestration in U.S. urban trees, yard trimmings, and food scraps 35 Emissions of carbon dioxide from biofuelbioenergy use by sector and fuel

  17. Advanced Collaborative Emissions Study (ACES)

    Broader source: Energy.gov [DOE]

    ACES is a cooperative multi-party effort to characterize emissions and possible health effects of new, advanced heavy duty engine and control systems and fuels in the market 2007 - 2010.

  18. emissions | OpenEI Community

    Open Energy Info (EERE)

    cities CO2 emissions OpenEI suburbs US New research from the University of California-Berkeley shows that those who live in cities in the United States have significantly smaller...

  19. Advanced Collaborative Emissions Study (ACES) - Cooperative multi...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    emissions and possible health effects of new advanced heavy ... to 2007 compliant diesel emissions PDF icon ... Tissue Response to Inhaled 2007-Compliant Diesel Exhaust

  20. IGES GHG Emissions Data | Open Energy Information

    Open Energy Info (EERE)

    GHG inventory Resource Type: Dataset Website: www.iges.or.jpencdmreportkyoto.html References: IGES GHG Emissions Data1 Summary "IGES GHG Emissions Data is aimed at...

  1. Characterizing Test Methods and Emissions Reduction Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Test Methods and Emissions Reduction Performance of In-Use Diesel Retrofit Technologies from the National Clean Diesel Campaign Characterizing Test Methods and Emissions Reduction ...

  2. Zero Emissions Leasing LLC | Open Energy Information

    Open Energy Info (EERE)

    Zero Emissions Leasing LLC Jump to: navigation, search Name: Zero Emissions Leasing LLC Place: Honolulu, Hawaii Zip: 96822 Sector: Solar Product: Honolulu-based developer of solar...

  3. Steinbeis Technology Transfer Centre for Emissions Trading |...

    Open Energy Info (EERE)

    Steinbeis Technology Transfer Centre for Emissions Trading Jump to: navigation, search Name: Steinbeis Technology Transfer Centre for Emissions Trading Place: Augsburg, Bavaria,...

  4. IPCC Emission Factor Database | Open Energy Information

    Open Energy Info (EERE)

    Emission Factor Database Jump to: navigation, search Tool Summary LAUNCH TOOL Name: IPCC Emission Factor Database AgencyCompany Organization: World Meteorological Organization,...

  5. How the Carbon Emissions Were Estimated

    U.S. Energy Information Administration (EIA) Indexed Site

    dioxide emissions are the main component of greenhouse gas emissions caused by human activity. Carbon dioxide is emitted mostly as a byproduct of the combustion of fossil fuels...

  6. Low Emissions Asian Development (LEAD) Program - Bangladesh ...

    Open Energy Info (EERE)

    Low Emissions Asian Development (LEAD) Program - Bangladesh Redirect page Jump to: navigation, search REDIRECT Low Emissions Asian Development (LEAD) Program Retrieved from...

  7. Energy-Related Carbon Emissions in Manufacturing

    Reports and Publications (EIA)

    2000-01-01

    Energy-related carbon emissions in manufacturing analysis and issues related to the energy use, energy efficiency, and carbon emission indicators.

  8. The Maritime Administration's Energy and Emissions Program -...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Recent Diesel Engine Emission Mitigation Activities of the ... Emissions Program - Part 1 U.S. Navy Marine Diesel Engines and the Environment - ...

  9. IPCC Special Report on Emissions Scenarios

    Office of Scientific and Technical Information (OSTI)

    IPCC Special Report on Emissions Scenarios Get Javascript Other reports in this collection Special Report on Emissions Scenarios Foreword Preface Summary for policymakers Technical...

  10. Emission Factors (EMFAC) | Open Energy Information

    Open Energy Info (EERE)

    The EMission FACtors (EMFAC) model is used to calculate emission rates from all motor vehicles, such as passenger cars to heavy-duty trucks, operating on highways, freeways...

  11. Kenaf Bast Fibers—Part II: Inorganic Nanoparticle Impregnation for Polymer Composites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Jinshu; Shi, Sheldon Q.; Barnes, H. Michael; Horstemeyer, Mark F.; Wang, Ge

    2011-01-01

    The objective of this study was to investigate an inorganic nanoparticle impregnation (INI) technique to improve the compatibility between kenaf bast fibers and polyolefin matrices. The Scanning Electron Microscopy (SEM) was used to examine the surface morphology of the INI-treated fibers showing that the CaCO 3 nanoparticle crystals grew onto the fiber surface. Energy-dispersive X-ray spectroscopy (EDS) was used to verify the CaCO 3 nanoparticle deposits on the fiber surface. The tension tests of the individual fiber were conducted, and the results showed that the tensile strength of the fibers increased significantly (more than 20%) after the INI treatments.more » Polymer composites were fabricated using the INI-treated fiber as reinforcement and polypropylene (PP) as the matrix. The results showed that the INI treatments improved the compatibility between kenaf fibers and PP matrix. The tensile modulus and tensile strength of the composites reinforced with INI-treated fibers increased by 25.9% and 10.4%, respectively, compared to those reinforced with untreated kenaf fibers.« less

  12. Catalyzed CO.sub.2-transport membrane on high surface area inorganic support

    DOE Patents [OSTI]

    Liu, Wei

    2014-05-06

    Disclosed are membranes and methods for making the same, which membranes provide improved permeability, stability, and cost-effective manufacturability, for separating CO.sub.2 from gas streams such as flue gas streams. High CO.sub.2 permeation flux is achieved by immobilizing an ultra-thin, optionally catalyzed fluid layer onto a meso-porous modification layer on a thin, porous inorganic substrate such as a porous metallic substrate. The CO.sub.2-selective liquid fluid blocks non-selective pores, and allows for selective absorption of CO.sub.2 from gas mixtures such as flue gas mixtures and subsequent transport to the permeation side of the membrane. Carbon dioxide permeance levels are in the order of 1.0.times.10.sup.-6 mol/(m.sup.2sPa) or better. Methods for making such membranes allow commercial scale membrane manufacturing at highly cost-effective rates when compared to conventional commercial-scale CO.sub.2 separation processes and equipment for the same and such membranes are operable on an industrial use scale.

  13. Evaluating Transport and Attenuation of Inorganic Contaminants in the Vadose Zone for Aqueous Waste Disposal Sites

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Tartakovsky, Guzel D.

    2015-09-01

    An approach was developed for evaluating vadose zone transport and attenuation of aqueous wastes containing inorganic (non-volatile) contaminants that were disposed of at the land surface (i.e., directly to the ground in cribs, trenches, tile fields, etc.) and their effect on the underlying groundwater. The approach provides a structured method for estimating transport of contaminants through the vadose zone and the resulting temporal profile of groundwater contaminant concentrations. The intent of the approach is also to provide a means for presenting and explaining the results of the transport analysis in the context of the site-specific waste disposal conditions and site properties, including heterogeneities and other complexities. The document includes considerations related to identifying appropriate monitoring to verify the estimated contaminant transport and associated predictions of groundwater contaminant concentrations. While primarily intended for evaluating contaminant transport under natural attenuation conditions, the approach can also be applied to identify types of, and targets for, mitigation approaches in the vadose zone that would reduce the temporal profile of contaminant concentrations in groundwater, if needed.

  14. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    M. J. Holmes

    1998-12-03

    McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using the Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and hydrogen chloride and hydrogen fluoride.

  15. Surface structures for enhancement of quantum yield in broad spectrum emission nanocrystals

    DOE Patents [OSTI]

    Schreuder, Michael A.; McBride, James R.; Rosenthal, Sandra J.

    2014-07-22

    Disclosed are inorganic nanoparticles comprising a body comprising cadmium and/or zinc crystallized with selenium, sulfur, and/or tellurium; a multiplicity of phosphonic acid ligands comprising at least about 20% of the total surface ligand coverage; wherein the nanocrystal is capable of absorbing energy from a first electromagnetic region and capable of emitting light in a second electromagnetic region, wherein the maximum absorbance wavelength of the first electromagnetic region is different from the maximum emission wavelength of the second electromagnetic region, thereby providing a Stokes shift of at least about 20 nm, wherein the second electromagnetic region comprises an at least about 100 nm wide band of wavelengths, and wherein the nanoparticle exhibits has a quantum yield of at least about 10%. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  16. Emission Market Opportunities for Federal Energy Projects

    SciTech Connect (OSTI)

    Vimmerstedt, L.; Shah, C.

    2005-06-01

    This document assists federal agencies in incorporating emissions market opportunities in their energy projects, including emission reduction credit markets and cap and trade. It looks at how potential emissions costs/revenues can be incorporated into project proposals, how groups can apply for emissions allowances, and how agencies can sell emissions allowances and receive the financial benefit. The fact sheet also outlines how FEMP can provide assistance throughout the process.

  17. Software solutions for emission monitoring

    SciTech Connect (OSTI)

    DeFriez, H.; Schillinger, S.; Seraji, H.

    1996-12-31

    Industry and state and federal environmental regulatory agencies are becoming ever more conciliatory due to the high cost of implementing the Clean Air Act Amendments of 1990 (CAAA) for the operation of Continuous Emissions Monitoring Systems (CEMS). In many cases the modifications do nothing to reduce emissions or even to measure the pollution, but simply let the source owner or operator and the permitting authority agree on a monitoring method and/or program. The EPA methods and standards developed under the Code of Federal Regulations (CFRs) have proven to be extremely costly and burdensome. Now, the USEPA and state agencies are making efforts to assure that emissions data has a strong technical basis to demonstrate compliance with regulations such as Title V.

  18. Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1998 Emissions Report

    SciTech Connect (OSTI)

    S. K. Zohner

    1999-10-01

    This report presents the 1998 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradiological emissions estimates for stationary sources.

  19. Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory - Calendar Year 1999 Emission Report

    SciTech Connect (OSTI)

    Zohner, S.K.

    2000-05-30

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  20. Air emission inventory for the Idaho National Engineering Laboratory: 1994 emissions report

    SciTech Connect (OSTI)

    1995-07-01

    This report Presents the 1994 update of the Air Emission inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources.

  1. Transportable Emissions Testing Laboratory for Alternative Vehicles Emissions Testing

    SciTech Connect (OSTI)

    Clark, Nigel

    2012-01-31

    The overall objective of this project was to perform research to quantify and improve the energy efficiency and the exhaust emissions reduction from advanced technology vehicles using clean, renewable and alternative fuels. Advanced vehicle and alternative fuel fleets were to be identified, and selected vehicles characterized for emissions and efficiency. Target vehicles were to include transit buses, school buses, vocational trucks, delivery trucks, and tractor-trailers. Gaseous species measured were to include carbon monoxide, carbon dioxide, oxides of nitrogen, hydrocarbons, and particulate matter. An objective was to characterize particulate matter more deeply than by mass. Accurate characterization of efficiency and emissions was to be accomplished using a state-of-the-art portable emissions measurement system and an accompanying chassis dynamometer available at West Virginia University. These two units, combined, are termed the Transportable Laboratory. An objective was to load the vehicles in a real-world fashion, using coast down data to establish rolling resistance and wind drag, and to apply the coast down data to the dynamometer control. Test schedules created from actual vehicle operation were to be employed, and a specific objective of the research was to assess the effect of choosing a test schedule which the subject vehicle either cannot follow or can substantially outperform. In addition the vehicle loading objective was to be met better with an improved flywheel system.

  2. Low emission internal combustion engine

    DOE Patents [OSTI]

    Karaba, Albert M.

    1979-01-01

    A low emission, internal combustion compression ignition engine having a cylinder, a piston movable in the cylinder and a pre-combustion chamber communicating with the cylinder near the top thereof and in which low emissions of NO.sub.x are achieved by constructing the pre-combustion chamber to have a volume of between 70% and 85% of the combined pre-chamber and main combustion chamber volume when the piston is at top dead center and by variably controlling the initiation of fuel injection into the pre-combustion chamber.

  3. Inorganic Carbon Isotopes and Chemical Characterization of Watershed Drainages, Barrow, Alaska, 2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Throckmorton, Heather M.; Heikoop, Jeffrey H.; Newman, Brent D.; Wilson, Cathy J.

    Arctic soils contain a large pool of terrestrial C and are of interest due to their potential for releasing significant carbon dioxide (CO2) and methane (CH4) to the atmosphere. Due to substantial landscape heterogeneity, predicting ecosystem-scale CH4 and CO2 production is challenging. This study assessed dissolved inorganic carbon (DIC = Sigma (total) dissolved CO2) and CH4 in watershed drainages in Barrow, Alaska as critical convergent zones of regional geochemistry, substrates, and nutrients. In July and September of 2013, surface waters and saturated subsurface pore waters were collected from 17 drainages. Based on simultaneous DIC and CH4 cycling, we synthesized isotopic and geochemical methods to develop a subsurface CH4 and DIC balance by estimating mechanisms of CH4 and DIC production and transport pathways and oxidation of subsurface CH4. We observed a shift from acetoclastic (July) towards hydrogenotropic (September) methanogenesis at sites located towards the end of major freshwater drainages, adjacent to salty estuarine waters, suggesting an interesting landscape-scale effect on CH4 production mechanism. The majority of subsurface CH4 was transported upward by plant-mediated transport and ebullition, predominantly bypassing the potential for CH4 oxidation. Thus, surprisingly CH4 oxidation only consumed approximately 2.51 +/- 0.82% (July) and 0.79 +/- 0.79% (September) of CH4 produced at the frost table, contributing to less than 0.1% of DIC production. DIC was primarily produced from respiration, with iron and organic matter serving as likely e- acceptors. This work highlights the importance of spatial and temporal variability of CH4 production at the watershed scale, and suggests broad scale investigations are required to build better regional or pan-Arctic representations of CH4 and CO2 production.

  4. Fiber optics spectrochemical emission sensors

    DOE Patents [OSTI]

    Griffin, J.W.; Olsen, K.B.

    1992-02-04

    A method is described of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species. The method uses a probe insertable into the well or tank via a cable and having an electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has an optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited in the fluid in alignment with the light guide axis. Optical emissions are received from the excited chemical species along such axis. 18 figs.

  5. Fission Particle Emission Multiplicity Simulation

    Energy Science and Technology Software Center (OSTI)

    2006-09-27

    Simulates discrete neutron and gamma-ray emission from the fission of heavy nuclei that is either spontaneous or neutron induced. This is a function library that encapsulates the fission physics and is intended to be called Monte Carlo transport code.

  6. Anisotropic Lyman-alpha emission

    SciTech Connect (OSTI)

    Zheng, Zheng; Wallace, Joshua

    2014-10-20

    As a result of resonant scatterings off hydrogen atoms, Ly? emission from star-forming galaxies provides a probe of the (hardly isotropic) neutral gas environment around them. We study the effect of the environmental anisotropy on the observed Ly? emission by performing radiative transfer calculations for models of neutral hydrogen clouds with prescriptions of spatial and kinematic anisotropies. The environmental anisotropy leads to corresponding anisotropy in the Ly? flux and spectral properties and induces correlations among them. The Ly? flux (or observed luminosity) depends on the viewing angle and shows an approximate correlation with the initial Ly? optical depth in the viewing direction relative to those in all other directions. The distribution of Ly? flux from a set of randomly oriented clouds is skewed to high values, providing a natural contribution to the Ly? equivalent width (EW) distribution seen in observation. A narrower EW distribution is found at a larger peak offset of the Ly? line, similar to the trend suggested in observation. The peak offset appears to correlate with the line shape (full width at half-maximum and asymmetry), pointing to a possibility of using Ly? line features alone to determine the systemic redshifts of galaxies. The study suggests that anisotropies in the spatial and kinematic distributions of neutral hydrogen can be an important ingredient in shaping the observed properties of Ly? emission from star-forming galaxies. We discuss the implications of using Ly? emission to probe the circumgalactic and intergalactic environments of galaxies.

  7. Fiber optics spectrochemical emission sensors

    DOE Patents [OSTI]

    Griffin, Jeffrey W. (Kennewick, WA); Olsen, Khris B. (West Richland, WA)

    1992-01-01

    A method of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species uses a probe insertable into the well or tank via a cable and having electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited the fluid in alignment with the light guide axis and optical emissions are received from the excited chemical species along such axis.

  8. Advanced emissions control development program. Quarterly technical progress report {number_sign}4, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Farthing, G.A.

    1995-12-31

    Babcock and Wilcox (B and W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls will likely arise as the US Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendments of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B and W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF will provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. The specific objectives of the project are to: (1) measure and understand the production and partitioning of air toxics species for a variety of steam coals, (2) optimize the air toxics removal performance of conventional flue gas cleanup systems (ESPs, baghouses, scrubbers), (3) develop advanced air toxics emissions control concepts, (4) develop and validate air toxics emissions measurement and monitoring techniques, and (5) establish a comprehensive, self-consistent air toxics data library. Development work is currently concentrated on the capture of mercury, fine particulate, and a variety of inorganic species such as the acid gases (hydrogen chloride, hydrogen fluoride, etc.).

  9. Junction-based field emission structure for field emission display

    DOE Patents [OSTI]

    Dinh, Long N.; Balooch, Mehdi; McLean, II, William; Schildbach, Marcus A.

    2002-01-01

    A junction-based field emission display, wherein the junctions are formed by depositing a semiconducting or dielectric, low work function, negative electron affinity (NEA) silicon-based compound film (SBCF) onto a metal or n-type semiconductor substrate. The SBCF can be doped to become a p-type semiconductor. A small forward bias voltage is applied across the junction so that electron transport is from the substrate into the SBCF region. Upon entering into this NEA region, many electrons are released into the vacuum level above the SBCF surface and accelerated toward a positively biased phosphor screen anode, hence lighting up the phosphor screen for display. To turn off, simply switch off the applied potential across the SBCF/substrate. May be used for field emission flat panel displays.

  10. Heat Transfer and Latent Heat Storage in Inorganic Molten Salts for Concentrating Solar Power Plants

    SciTech Connect (OSTI)

    Mathur, Anoop

    2013-08-14

    A key technological issue facing the success of future Concentrating Solar Thermal Power (CSP) plants is creating an economical Thermal Energy Storage (TES) system. Current TES systems use either sensible heat in fluids such as oil, or molten salts, or use thermal stratification in a dual-media consisting of a solid and a heat-transfer fluid. However, utilizing the heat of fusion in inorganic molten salt mixtures in addition to sensible heat , as in a Phase change material (PCM)-based TES, can significantly increase the energy density of storage requiring less salt and smaller containers. A major issue that is preventing the commercial use of PCM-based TES is that it is difficult to discharge the latent heat stored in the PCM melt. This is because when heat is extracted, the melt solidifies onto the heat exchanger surface decreasing the heat transfer. Even a few millimeters of thickness of solid material on heat transfer surface results in a large drop in heat transfer due to the low thermal conductivity of solid PCM. Thus, to maintain the desired heat rate, the heat exchange area must be large which increases cost. This project demonstrated that the heat transfer coefficient can be increase ten-fold by using forced convection by pumping a hyper-eutectic salt mixture over specially coated heat exchanger tubes. However,only 15% of the latent heat is used against a goal of 40% resulting in a projected cost savings of only 17% against a goal of 30%. Based on the failure mode effect analysis and experience with pumping salt at near freezing point significant care must be used during operation which can increase the operating costs. Therefore, we conclude the savings are marginal to justify using this concept for PCM-TES over a two-tank TES. The report documents the specialty coatings, the composition and morphology of hypereutectic salt mixtures and the results from the experiment conducted with the active heat exchanger along with the lessons learnt during experimentation.

  11. Methane emissions from MBT landfills

    SciTech Connect (OSTI)

    Heyer, K.-U. Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. Methane oxidation in the waste itself and in soil covers. Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (Umweltbundesamt), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 1824 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD) model of the IPCC Guidelines for National Greenhouse Gas Inventories, 2006, was used to estimate the methane emissions from MBT landfills. Due to the calculation made by the authors emissions in the range of 60,000135,000 t CO{sub 2-eq.}/a for all German MBT landfills can be expected. This wide range shows the uncertainties when the here used procedure and the limited available data are applied. It is therefore necessary to generate more data in the future in order to calculate more precise methane emission rates from MBT landfills. This is important for the overall calculation of the climate gas production in Germany which is required once a year by the German Government.

  12. Assessing the nonlinear response of fine particles to precursor emissions: Development and application of an extended response surface modeling technique v1.0

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, B.; Wang, S. X.; Xing, J.; Fu, K.; Fu, J. S.; Jang, C.; Zhu, Y.; Dong, X. Y.; Gao, Y.; Wu, W. J.; et al

    2015-01-30

    An innovative extended response surface modeling technique (ERSM v1.0) is developed to characterize the nonlinear response of fine particles (PM₂̣₅) to large and simultaneous changes of multiple precursor emissions from multiple regions and sectors. The ERSM technique is developed based on the conventional response surface modeling (RSM) technique; it first quantifies the relationship between PM₂̣₅ concentrations and the emissions of gaseous precursors from each single region using the conventional RSM technique, and then assesses the effects of inter-regional transport of PM₂̣₅ and its gaseous precursors on PM₂̣₅ concentrations in the target region. We apply this novel technique with a widelymore » used regional chemical transport model (CTM) over the Yangtze River delta (YRD) region of China, and evaluate the response of PM₂̣₅ and its inorganic components to the emissions of 36 pollutant–region–sector combinations. The predicted PM₂̣₅ concentrations agree well with independent CTM simulations; the correlation coefficients are larger than 0.98 and 0.99, and the mean normalized errors (MNEs) are less than 1 and 2% for January and August, respectively. It is also demonstrated that the ERSM technique could reproduce fairly well the response of PM₂̣₅ to continuous changes of precursor emission levels between zero and 150%. Employing this new technique, we identify the major sources contributing to PM₂̣₅ and its inorganic components in the YRD region. The nonlinearity in the response of PM₂̣₅ to emission changes is characterized and the underlying chemical processes are illustrated.« less

  13. Assessing the nonlinear response of fine particles to precursor emissions: Development and application of an extended response surface modeling technique v1.0

    SciTech Connect (OSTI)

    Zhao, B.; Wang, S. X.; Xing, J.; Fu, K.; Fu, J. S.; Jang, C.; Zhu, Y.; Dong, X. Y.; Gao, Y.; Wu, W. J.; Wang, J. D.; Hao, J. M.

    2015-01-30

    An innovative extended response surface modeling technique (ERSM v1.0) is developed to characterize the nonlinear response of fine particles (PM₂̣₅) to large and simultaneous changes of multiple precursor emissions from multiple regions and sectors. The ERSM technique is developed based on the conventional response surface modeling (RSM) technique; it first quantifies the relationship between PM₂̣₅ concentrations and the emissions of gaseous precursors from each single region using the conventional RSM technique, and then assesses the effects of inter-regional transport of PM₂̣₅ and its gaseous precursors on PM₂̣₅ concentrations in the target region. We apply this novel technique with a widely used regional chemical transport model (CTM) over the Yangtze River delta (YRD) region of China, and evaluate the response of PM₂̣₅ and its inorganic components to the emissions of 36 pollutant–region–sector combinations. The predicted PM₂̣₅ concentrations agree well with independent CTM simulations; the correlation coefficients are larger than 0.98 and 0.99, and the mean normalized errors (MNEs) are less than 1 and 2% for January and August, respectively. It is also demonstrated that the ERSM technique could reproduce fairly well the response of PM₂̣₅ to continuous changes of precursor emission levels between zero and 150%. Employing this new technique, we identify the major sources contributing to PM₂̣₅ and its inorganic components in the YRD region. The nonlinearity in the response of PM₂̣₅ to emission changes is characterized and the underlying chemical processes are illustrated.

  14. ATOMISTIC MODELING OF OIL SHALE KEROGENS AND ASPHALTENES ALONG WITH THEIR INTERACTIONS WITH THE INORGANIC MINERAL MATRIX

    SciTech Connect (OSTI)

    Facelli, Julio; Pugmire, Ronald; Pimienta, Ian

    2011-03-31

    The goal of this project is to obtain and validate three dimensional atomistic models for the organic matter in both oil shales and oil sands. In the case of oil shales the modeling was completed for kerogen, the insoluble portion of the organic matter; for oil sands it was for asphaltenes, a class of molecules found in crude oil. The three dimensional models discussed in this report were developed starting from existing literature two dimensional models. The models developed included one kerogen, based on experimental data on a kerogen isolated from a Green River oil shale, and a set of six representative asphaltenes. Subsequently, the interactions between these organic models and an inorganic matrix was explored in order to gain insight into the chemical nature of this interaction, which could provide vital information in developing efficient methods to remove the organic material from inorganic mineral substrate. The inorganic substrate used to model the interaction was illite, an aluminum silicate oxide clay. In order to obtain the feedback necessary to validate the models, it is necessary to be able to calculate different observable quantities and to show that these observables both reproduce the results of experimental measurements on actual samples as well as that the observables are sensitive to structural differences between models. The observables that were calculated using the models include 13C NMR spectra, the IR vibrational spectra, and the atomic pair wise distribution function; these were chosen as they are among the methods for which both experimental and calculated values can be readily obtained. Where available, comparison was made to experiment results. Finally, molecular dynamic simulations of pyrolysis were completed on the models to gain an understanding into the nature of the decomposition of these materials when heated.

  15. Integrated Emissivity And Temperature Measurement

    DOE Patents [OSTI]

    Poulsen, Peter (Livermore, CA)

    2005-11-08

    A multi-channel spectrometer and a light source are used to measure both the emitted and the reflected light from a surface which is at an elevated temperature relative to its environment. In a first method, the temperature of the surface and emissivity in each wavelength is calculated from a knowledge of the spectrum and the measurement of the incident and reflected light. In the second method, the reflected light is measured from a reference surface having a known reflectivity and the same geometry as the surface of interest and the emitted and the reflected light are measured for the surface of interest. These measurements permit the computation of the emissivity in each channel of the spectrometer and the temperature of the surface of interest.

  16. Effects of Biodiesel on NOx Emissions

    SciTech Connect (OSTI)

    McCormick, R.

    2005-06-01

    A presentation about the effects of biodiesel on nitrogen oxide emissions presented at the ARB Biodiesel Workshop June 8, 2005.

  17. School Bus Emissions Study | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    School Bus Emissions Study School Bus Emissions Study 2003 DEER Conference Presentation: international Truck and Engine Corporation PDF icon deer_2003_slodowske.pdf More Documents & Publications Investigation of the Effects of Fuels and Aftertreatment Devices on the Emission Profiles of Trucks and Buses ARB's Study of Emissions from Diesel and CNG Heavy-duty Transit Buses Diesel Health Impacts & Recent Comparisons to Other Fuels

  18. FUELS; 54 ENVIRONMENTAL SCIENCES; RADIOACTIVE EFFLUENTS; EMISSION...

    Office of Scientific and Technical Information (OSTI)

    SRP radioactive waste releases. Startup through 1959 Ashley, C. 05 NUCLEAR FUELS; 54 ENVIRONMENTAL SCIENCES; RADIOACTIVE EFFLUENTS; EMISSION; ENVIRONMENTAL MATERIALS;...

  19. Biological Air Emissions Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Air Emissions Control Biological Air Emissions Control Innovative Technology Enables Low-Cost, Energy-Efficient Treatment of Industrial Exhaust Streams Air quality standards are becoming more stringent for the U.S. wood products industry. Emissions of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) (including methanol, formaldehyde, acetylaldehyde, and acrolein) during production of wood products must be tightly controlled. Conventional VOCs and HAPs emission

  20. Module: Estimating Historical Emissions from Deforestation |...

    Open Energy Info (EERE)

    Website: www.leafasia.orgtoolstechnical-guidance-series-estimating-historical Cost: Free Language: English Module: Estimating Historical Emissions from Deforestation Screenshot...

  1. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of internal combustion engine vehicles. These vehicles can run on gasoline, diesel, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs) particulate matter (PM) A

  2. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    Contacts This report, Emissions of Greenhouse Gases in the United States 2009, was prepared under the general direction of John Conti, Assistant Administrator for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. General questions concerning the content of this report may be directed to the Office of Communications at 202/586-8800. Technical information concerning the content of the report may be obtained from Perry Lindstrom at 202/586-0934 (email,

  3. Emissions

    Office of Scientific and Technical Information (OSTI)

    ... combined with increased R&D on solar energy production ... and lt,tztstry, Organization for Economic Cooperation ... Journal of the Air ald Waste Managemert Association ...

  4. Comparing Emissions Benefits from Regulating Heavy Vehicle Idling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Benefits from Regulating Heavy Vehicle Idling Comparing Emissions Benefits from Regulating Heavy Vehicle Idling 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  5. Retrofit Diesel Emissions Control System Providing 50% NOxControl...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  6. Attachment C - Summary GHG Emissions Data FINAL | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Summary GHG Emissions Data FINAL Attachment C - Summary GHG Emissions Data FINAL File Attachment C - Summary GHG Emissions Data FINAL More Documents & Publications Attachment C

  7. Attachment C Summary GHG Emissions Data FINAL | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summary GHG Emissions Data FINAL Attachment C Summary GHG Emissions Data FINAL File Attachment-C-Summary-GHG-Emissions-Data-FINAL.xlsx More Documents & Publications Attachment C -

  8. Catalyzing Cooperative Action for Low Emissions Development Agenda...

    Open Energy Info (EERE)

    Emissions Development Agenda Jump to: navigation, search Low Emission Development Strategies Global Partnership Advancing climate-resilient, low-emission development around the...

  9. Advanced Diesel Common Rail Injection System for Future Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Common Rail Injection System for Future Emission Legislation Advanced Diesel Common Rail Injection System for Future Emission Legislation 2004 Diesel Engine Emissions Reduction ...

  10. 2010 Emissions from an Electronics Perspective | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from an Electronics Perspective 2010 Emissions from an Electronics Perspective 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon ...

  11. Energy-Related Carbon Emissions, by Industry, 1994

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Efficiency Page > Energy Energy-Related Carbon Emissions > Total Table Total Energy-Related Carbon Emissions for Manufacturing Industries, 1994 Carbon Emissions (million...

  12. Optimization of an Advanced Passive/Active Diesel Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Diesel Particulate Filters and NO2 Emission Limits Active Diesel Emission Control Technology for Transport Refrigeration Units Active Diesel Emission ...

  13. Rigorous HDD Emissions Capabilities of Shell GTL Fuel | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rigorous HDD Emissions Capabilities of Shell GTL Fuel Rigorous HDD Emissions Capabilities of Shell GTL Fuel 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations...

  14. How Exhaust Emissions Drive Diesel Engine Fuel Efficiency | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    How Exhaust Emissions Drive Diesel Engine Fuel Efficiency How Exhaust Emissions Drive Diesel Engine Fuel Efficiency 2004 Diesel Engine Emissions Reduction (DEER) Conference...

  15. Module: Emission Factors for Deforestation | Open Energy Information

    Open Energy Info (EERE)

    www.leafasia.orgtoolstechnical-guidance-series-emission-factors-defo Cost: Free Language: English Module: Emission Factors for Deforestation Screenshot Logo: Module: Emission...

  16. 2009 LANL radionuclide air emissions report

    SciTech Connect (OSTI)

    Fuehne, David P.

    2010-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2009. This report meets the reporting requirements established in the regulations.

  17. 2010 LANL radionuclide air emissions report /

    SciTech Connect (OSTI)

    Fuehne, David P.

    2011-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2010. This report meets the reporting requirements established in the regulations.

  18. 2008 LANL radionuclide air emissions report

    SciTech Connect (OSTI)

    Fuehne, David P.

    2009-06-01

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2008. This report meets the reporting requirements established in the regulations.

  19. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  20. Emissions Technology Gives Company Clean Win as Energy Innovator

    Broader source: Energy.gov [DOE]

    Umpqua Energy produced an emission control system that can potentially reduce the emissions from vehicles by 90 percent.

  1. Advanced Emissions Control Development Program. Quarterly Technical Progress Report {number_sign}7 for the period: April 1 to June 30, 1996

    SciTech Connect (OSTI)

    Evans, A.P.

    1996-12-31

    Babcock {ampersand} Wilcox (B{ampersand}W) is conducting a five-year project aimed at the development of practical, cost- effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B{ampersand}W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  2. Diesel Emission Control Technology in Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Review Diesel Emission Control Technology in Review Review of light- and heavy-duty diesel emission regulations and state-of-the-art emission control technologies and strategies to meet them. PDF icon deer08_johnson.pdf More Documents & Publications Diesel Emission Control Review Review of Emerging Diesel Emissions and Control Diesel Emission Control in Review

  3. Vehicle Technologies Office: Emission Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Efficiency & Emissions » Vehicle Technologies Office: Emission Control Vehicle Technologies Office: Emission Control The Vehicle Technologies Office (VTO) supports research and development of aftertreatment technologies to control advanced combustion engine exhaust emissions. All engines that enter the vehicle market must comply with the Environmental Protection Agency's emissions regulations. Harmful pollutants in these emissions include: Carbon monoxide Nitrogen oxides Unburned

  4. Field Emission and Nanostructure of Carbon Films

    SciTech Connect (OSTI)

    Merkulov, V.I.; Lowndes, D.H.; Baylor, L.R.

    1999-11-29

    The results of field emission measurements of various forms of carbon films are reported. It is shown that the films nanostructure is a crucial factor determining the field emission properties. In particular, smooth, pulsed-laser deposited amorphous carbon films with both high and low sp3 contents are poor field emitters. This is similar to the results obtained for smooth nanocrystalline, sp2-bonded carbon films. In contrast, carbon films prepared by hot-filament chemical vapor deposition (HE-CVD) exhibit very good field emission properties, including low emission turn-on fields, high emission site density, and excellent durability. HF-CVD carbon films were found to be predominantly sp2-bonded. However, surface morphology studies show that these films are thoroughly nanostructured, which is believed to be responsible for their promising field emission properties.

  5. Emissions trading: principles and practice. 2nd

    SciTech Connect (OSTI)

    Tietenberg, T.H.

    2006-02-15

    The author demonstrates how emissions trading became an attractive alternative to command-and-control policies that would have required the EPA to disallow the opening of new plants in the middle of the recession-burdened 1970s. His examination of the evolution of this system includes, among other applications, the largest multinational trading system ever conceived, the European Union's Greenhouse Gas Emission Trading Scheme (EUETG), and the use of emissions trading in the Kyoto Protocol.

  6. PNNL: About: Air Emissions (Radioactive) Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Emissions (Radioactive) Reports At PNNL, we value the environment and strive to protect it and the public from unacceptable risks resulting from its operations. These reports document PNNL Campus and Marine Science Laboratory (MSL) radionuclide air emissions that result in the highest dose to a member of the public. The reports have been prepared in compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for

  7. Positron Emission Tomography (PET) and Positron Scanning

    Office of Scientific and Technical Information (OSTI)

    Positron Emission Tomography (PET) and Positron Scanning Resources with Additional Information Positron Emission Tomography (PET) Scanner Courtesy Lawrence Berkeley National Laboratory 'Positron Emission Tomography ... [is a medical imaging technique that] can track chemical reactions in living tissues and merges chemistry with biological imaging. Its strength has been in studies of the brain where there has been significant progress in investigations of drug addiction, aging, mental illness,

  8. Fine Structure Studies in Proton Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure Studies in Proton Emission In order to understand the evolution of single particle wave functions and deformations beyond the proton drip line, a program has been initiated to study fine structure decay in proton emission. Fine structure in the proton emission spectrum allows one not only to define low energy states in the daughter, but from a comparison of the proton energies and partial half-lives, enables determination of the composition of the single-particle proton states in the

  9. Milestone Project Demonstrates Innovative Mercury Emissions Reduction

    Office of Environmental Management (EM)

    Technology | Department of Energy Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology January 12, 2010 - 12:00pm Addthis Washington, DC - An innovative technology that could potentially help some coal-based power generation facilities comply with anticipated new mercury emissions standards was successfully demonstrated in a recently concluded milestone project at a Michigan power

  10. PLASMA EMISSION BY WEAK TURBULENCE PROCESSES

    SciTech Connect (OSTI)

    Ziebell, L. F.; Gaelzer, R.; Yoon, P. H.; Pavan, J. E-mail: rudi.gaelzer@ufrgs.br E-mail: joel.pavan@ufpel.edu.br

    2014-11-10

    The plasma emission is the radiation mechanism responsible for solar type II and type III radio bursts. The first theory of plasma emission was put forth in the 1950s, but the rigorous demonstration of the process based upon first principles had been lacking. The present Letter reports the first complete numerical solution of electromagnetic weak turbulence equations. It is shown that the fundamental emission is dominant and unless the beam speed is substantially higher than the electron thermal speed, the harmonic emission is not likely to be generated. The present findings may be useful for validating reduced models and for interpreting particle-in-cell simulations.

  11. Urban Transportation Emission Calculator | Open Energy Information

    Open Energy Info (EERE)

    Calculator (UTEC) is a user-friendly tool for estimating annual emissions from personal, commercial, and public transit vehicles. It estimates greenhouse gas (GHG) and...

  12. Planetary Emissions Management | Open Energy Information

    Open Energy Info (EERE)

    Management Jump to: navigation, search Name: Planetary Emissions Management Place: Cambridge, Massachusetts Sector: Carbon Product: US-based, company offering measurements of...

  13. Measurement and Characterization of Unregulated Emissions from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon ace045storey2011o.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Measurement and Characterization of Unregulated...

  14. The Maritime Administration's Energy and Emissions Program -...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Emissions Program - Part 1 2002 DEER Conference Presentation: Maritime Administration PDF icon 2002deergore1.pdf More Documents & Publications Recent Diesel Engine...

  15. Measurement and Characterization of Unregulated Emissions from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2009 -- Washington D.C. PDF icon ace30storey.pdf More Documents & Publications Measurement and Characterization of Unregulated Emissions from Advanced Technologies Synergies...

  16. Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Breakup Model & Detailed Chemistry Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling using KH-ACT Primary Breakup Model & Detailed Chemistry Poster presented at the ...

  17. Low Emission Development Strategies (LEDS): Technical, Institutional...

    Open Energy Info (EERE)

    Energy, Land Topics: Low emission development planning Resource Type: Publications, Lessons learnedbest practices Website: www.oecd.orgdataoecd325846553489.pdf Low...

  18. Emissions from US waste collection vehicles

    SciTech Connect (OSTI)

    Maimoun, Mousa A.; Reinhart, Debra R.; Gammoh, Fatina T.; McCauley Bush, Pamela

    2013-05-15

    Highlights: ? Life-cycle emissions for alternative fuel technologies. ? Fuel consumption of alternative fuels for waste collection vehicles. ? Actual driving cycle of waste collection vehicles. ? Diesel-fueled waste collection vehicle emissions. - Abstract: This research is an in-depth environmental analysis of potential alternative fuel technologies for waste collection vehicles. Life-cycle emissions, cost, fuel and energy consumption were evaluated for a wide range of fossil and bio-fuel technologies. Emission factors were calculated for a typical waste collection driving cycle as well as constant speed. In brief, natural gas waste collection vehicles (compressed and liquid) fueled with North-American natural gas had 610% higher well-to-wheel (WTW) greenhouse gas (GHG) emissions relative to diesel-fueled vehicles; however the pump-to-wheel (PTW) GHG emissions of natural gas waste collection vehicles averaged 6% less than diesel-fueled vehicles. Landfill gas had about 80% lower WTW GHG emissions relative to diesel. Biodiesel waste collection vehicles had between 12% and 75% lower WTW GHG emissions relative to diesel depending on the fuel source and the blend. In 2011, natural gas waste collection vehicles had the lowest fuel cost per collection vehicle kilometer travel. Finally, the actual driving cycle of waste collection vehicles consists of repetitive stops and starts during waste collection; this generates more emissions than constant speed driving.

  19. Exhaust emission control and diagnostics

    DOE Patents [OSTI]

    Mazur, Christopher John; Upadhyay, Devesh

    2006-11-14

    A diesel engine emission control system uses an upstream oxidation catalyst and a downstream SCR catalyst to reduce NOx in a lean exhaust gas environment. The engine and upstream oxidation catalyst are configured to provide approximately a 1:1 ratio of NO to NO2 entering the downstream catalyst. In this way, the downstream catalyst is insensitive to sulfur contamination, and also has improved overall catalyst NOx conversion efficiency. Degradation of the system is determined when the ratio provided is no longer near the desired 1:1 ratio. This condition is detected using measurements of engine operating conditions such as from a NOx sensor located downstream of the catalysts. Finally, control action to adjust an injected amount of reductant in the exhaust gas based on the actual NO to NO2 ratio upstream of the SCR catalyst and downstream of the oxidation catalyst.

  20. Positron emission tomography wrist detector

    DOE Patents [OSTI]

    Schlyer, David J. (Bellport, NY); O'Connor, Paul (Bellport, NY); Woody, Craig (Setauket, NY); Junnarkar, Sachin Shrirang (Sound Beach, NY); Radeka, Veljko (Bellport, NY); Vaska, Paul (Sound Beach, NY); Pratte, Jean-Francois (Stony Brook, NY)

    2006-08-15

    A method of serially transferring annihilation information in a compact positron emission tomography (PET) scanner includes generating a time signal representing a time-of-occurrence of an annihilation event, generating an address signal representing a channel detecting the annihilation event, and generating a channel signal including the time and address signals. The method also includes generating a composite signal including the channel signal and another similarly generated channel signal concerning another annihilation event. An apparatus that serially transfers annihilation information includes a time signal generator, address signal generator, channel signal generator, and composite signal generator. The time signal is asynchronous and the address signal is synchronous to a clock signal. A PET scanner includes a scintillation array, detection array, front-end array, and a serial encoder. The serial encoders include the time signal generator, address signal generator, channel signal generator, and composite signal generator.

  1. Ammonia Gas Transport and Reactions in Unsaturated Sediments: Implications for Use as an Amendment to Immobilize Inorganic Contaminants

    SciTech Connect (OSTI)

    Zhong, Lirong; Szecsody, James E.; Truex, Michael J.; Williams, Mark D.; Liu, Yuanyuan

    2015-05-01

    Use of gas-phase amendments for in situ remediation of inorganic contaminants in unsaturated sediments of the vadose zone may be advantageous, but there has been limited development and testing of gas remediation technologies. Treatment with ammonia gas has been studied and has a potential for use in treating inorganic contaminants such as uranium because it induces a high pore-water pH causing mineral dissolution and subsequent formation of stable precipitates that decrease the mobility of some contaminants. For field application, knowledge of ammonia transport and the geochemical reactions induced by ammonia is needed. Laboratory studies were conducted to support calculations needed for field treatment design, to quantify advective and diffusive ammonia transport in unsaturated sediments, to evaluate reactions among gas, sediment, and water, and to study reaction-induced pore-water chemistry changes as a function of ammonia delivery conditions. Ammonia gas quickly partitions into sediment pore water and increases pH up to 13.2. Injected ammonia gas front movement can be reasonably predicted by gas flow rate and equilibrium partitioning. The ammonia gas diffusion rate is a function of the water content in the sediment. Measured diffusion front movement was 0.05, 0.03, and 0.02 cm/hr. in sediments with 2.0%, 8.7%, and 13.0% water content, respectively. Sodium, aluminum, and silica pore-water concentrations increase on exposure to ammonia and then decline as aluminosilicates precipitate with declining pH. When uranium is present in the sediment and pore water, up to 85% of the water-leachable uranium was immobilized by ammonia treatment.

  2. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  3. Air Emission Inventory for the Idaho National Engineering Laboratory, 1993 emissions report

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This report presents the 1993 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The purpose of the Air Emission Inventory is to commence the preparation of the permit to operate application for the INEL, as required by the recently promulgated Title V regulations of the Clean Air Act. The report describes the emission inventory process and all of the sources at the INEL and provides emissions estimates for both mobile and stationary sources.

  4. Advanced Emissions Control Development Program. Quarterly Technical Progress Report {number_sign}5 for the period October 1 to December 31, 1995

    SciTech Connect (OSTI)

    Farthing, George A.

    1996-12-31

    Babcock {ampersand} Wilcox (B{ampersand}W) is conducting a five year project aimed at the development of practical, cost- effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls will likely arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendments of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF will provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. The specific objectives of the project are to: (1) measure and understand the production and partitioning of air toxics species for a variety of steam coals, (2) optimize the air toxics removal performance of conventional flue gas cleanup systems (ESPs, baghouses, scrubbers), (3) develop advanced air toxics emissions control concepts, (4) develop and validate air toxics emissions measurement and monitoring techniques, and (5) establish a comprehensive, self-consistent air toxics data library. Development work is currently concentrated on the capture of mercury, fine particulate, and a variety of inorganic species such as the acid gases (hydrogen chloride, hydrogen fluoride, etc.).

  5. Advanced Emissions Control Development Program. Quarterly Technical Progress Report {number_sign}6 for the period: January 1 to March 31, 1996

    SciTech Connect (OSTI)

    Farthing, George A.

    1996-12-31

    Babcock {ampersand} Wilcox (B{ampersand}W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls will likely arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the clean Air Act Amendments of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B{ampersand}W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF will provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. The specific objectives of the project are to: (1) measure and understand the production and partitioning of air toxics species for a variety of steam coals, (2) optimize the air toxics removal performance of conventional flue gas cleanup systems (ESPs, baghouses, scrubbers), (3) develop advanced air toxics emissions control concepts, (4) develop and validate air toxics emissions measurement and monitoring techniques, and (5) establish a comprehensive, self- consistent air toxics data library. Development work is currently concentrated on the capture of mercury, fine particulate, and a variety of inorganic species such as the acid gases (hydrogen chloride, hydrogen fluoride, etc.).

  6. Characterizing toxic emissions from a coal-fired power plant demonstrating the AFGD ICCT Project and a plant utilizing a dry scrubber/baghouse system: Bailly Station Units 7 and 8 and AFGD ICCT Project. Final report. Final report

    SciTech Connect (OSTI)

    Dismukes, E.B.

    1994-10-20

    This report describes results of assessment of the risk of emissions of hazardous air pollutants at one of the electric power stations, Bailly Station, which is also the site of a Clean Coal Technology project demonstrating the Pure Air Advanced Flue Gas Desulfurization process (wet limestone). This station represents the configuration of no NO{sub x} reduction, particulate control with electrostatic precipitators, and SO{sub 2} control with a wet scrubber. The test was conducted September 3--6, 1993. Sixteen trace metals were determined along with 5 major metals. Other inorganic substances and organic compounds were also determined.

  7. Fuel-based motor vehicle emission inventory

    SciTech Connect (OSTI)

    Singer, B.C.; Harley, R.A.

    1996-06-01

    A fuel-based methodology for calculating motor vehicle emission inventories is presented. In the fuel-based method, emission factors are normalized to fuel consumption and expressed as grams of pollutant emitted per gallon of gasoline burned. Fleet-average emission factors are calculated from the measured on-road emissions of a large, random sample of vehicles. Using this method, a fuel-based motor vehicle CO inventory was calculated for the South Coast Air Basin in California for summer 1991. Emission factors were calculated from remote sensing measurements of more than 70,000 in-use vehicles. Results of the study are presented and a conclusion is provided. 40 refs., 4 figs., 6 tabs.

  8. PHOTOSPHERIC EMISSION FROM STRATIFIED JETS

    SciTech Connect (OSTI)

    Ito, Hirotaka; Nagataki, Shigehiro; Ono, Masaomi; Lee, Shiu-Hang; Mao, Jirong; Yamada, Shoichi; Pe'er, Asaf; Mizuta, Akira; Harikae, Seiji

    2013-11-01

    We explore photospheric emissions from stratified two-component jets, wherein a highly relativistic spine outflow is surrounded by a wider and less relativistic sheath outflow. Thermal photons are injected in regions of high optical depth and propagated until the photons escape at the photosphere. Because of the presence of shear in velocity (Lorentz factor) at the boundary of the spine and sheath region, a fraction of the injected photons are accelerated using a Fermi-like acceleration mechanism such that a high-energy power-law tail is formed in the resultant spectrum. We show, in particular, that if a velocity shear with a considerable variance in the bulk Lorentz factor is present, the high-energy part of observed gamma-ray bursts (GRBs) photon spectrum can be explained by this photon acceleration mechanism. We also show that the accelerated photons might also account for the origin of the extra-hard power-law component above the bump of the thermal-like peak seen in some peculiar bursts (e.g., GRB 090510, 090902B, 090926A). We demonstrate that time-integrated spectra can also reproduce the low-energy spectrum of GRBs consistently using a multi-temperature effect when time evolution of the outflow is considered. Last, we show that the empirical E{sub p}-L{sub p} relation can be explained by differences in the outflow properties of individual sources.

  9. Review of Emerging Diesel Emissions and Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emerging Diesel Emissions and Control Review of Emerging Diesel Emissions and Control Criteria pollutant regulatory efforts are focused on Euro VI HD PN limits, and California LEV3 for LD. PDF icon deer09_johnson.pdf More Documents & Publications Diesel Emission Control Review Diesel Emission Control Technology in Review Vehicle Emissions Review - 2012

  10. Fuel Effects on Emissions Control Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Control Technologies Fuel Effects on Emissions Control Technologies 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ft007_sluder_2012_o.pdf More Documents & Publications Fuel Effects on Emissions Control Technologies Fuel Effects on Emissions Control Technologies Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies

  11. SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 | Department

    Energy Savers [EERE]

    of Energy SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 File SUMMARY_GREENHOUSE_GAS_EMISSIONS_DATA_WORKSHEET_JANUARY_2015.xlsx More Documents & Publications Attachment C - Summary GHG Emissions Data FINAL Attachment C Summary GHG Emissions Data FINAL Full Service Leased Space Data Report

  12. Energy Efficiency Standards for Microwave Ovens Saves Consumers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Positive Impact Significant savings to consumer energy bills and reductions in carbon pollution. Locations Nationwide Partners Lawrence Berkeley National Laboratory, Navigant EERE ...

  13. Oven rack having integral lubricious, dry porcelain surface

    SciTech Connect (OSTI)

    Ambrose, Jeffrey A; Mackiewicz-Ludtka, Gail; Sikka, Vinod K; Qu, Jun

    2014-06-03

    A lubricious glass-coated metal cooking article capable of withstanding repeated heating and cooling between room temperature and at least 500.degree. F. without chipping or cracking the glass coating, wherein the glass coating includes about 0.1 to about 20% by weight of a homogeneously distributed dry refractory lubricant material having a particle size less than about 200 .mu.m. The lubricant material is selected from the group consisting of carbon; graphite; boron nitride; cubic boron nitride; molybdenum (FV) sulfide; molybdenum sulfide; molybdenum (IV) selenide; molybdenum selenide, tungsten (IV) sulfide; tungsten disulfide; tungsten sulfide; silicon nitride (Si.sub.3N.sub.4); TiN; TiC; TiCN; TiO.sub.2; TiAlN; CrN; SiC; diamond-like carbon; tungsten carbide (WC); zirconium oxide (ZrO.sub.2); zirconium oxide and 0.1 to 40 weight % aluminum oxide; alumina-zirconia; antimony; antimony oxide; antimony trioxide; and mixtures thereof.

  14. New Energy Efficiency Standards for Microwave Ovens to Save Consumers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    "Appliance efficiency standards represent a huge opportunity to help families save money by saving energy, while still delivering high quality appliances for consumers," said ...

  15. Covered Product Category: Commercial Ovens | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    product is available to meet the functional requirements, or that no such product is life cycle cost-effective for a specific application. Additional information on Federal...

  16. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  17. Methane sources and emissions in Italy

    SciTech Connect (OSTI)

    Guidotti, G.R.; Castagnola, A.M.

    1994-12-31

    Methane emissions in Italy were assessed in the framework of the measures taken to follow out the commitments undertaken at the 1992 U.N. Conference for Environment and Development. Methane emissions of anthropic origin were estimated to be in the range of 1.6 to 2.3 million ton of methane per year. Some of these methane sources (natural gas production, transmission and distribution; rice paddies; managed livestock enteric fermentation and waste; solid waste landfills) are given here particular care as they mainly contribute to the total methane emission budget.

  18. Emission abatement system utilizing particulate traps

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2004-04-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  19. Assessment of the Emissions Behavior of Higher Mileage Class...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Emissions Behavior of Higher Mileage Class-8 Trucks and Engines Assessment of the Emissions Behavior of Higher Mileage Class-8 Trucks and Engines Study of in-use emission ...

  20. Assessment of Health Hazards of Repeated Inhalation of Diesel Emissions,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with Comparisons to Other Source Emissions | Department of Energy Health Hazards of Repeated Inhalation of Diesel Emissions, with Comparisons to Other Source Emissions Assessment of Health Hazards of Repeated Inhalation of Diesel Emissions, with Comparisons to Other Source Emissions 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: National Environmental Respiratory Center PDF icon 2004_deer_mauderly.pdf More Documents & Publications Relationship Between Composition

  1. Organic light emitting device having multiple separate emissive layers

    DOE Patents [OSTI]

    Forrest, Stephen R. (Ann Arbor, MI)

    2012-03-27

    An organic light emitting device having multiple separate emissive layers is provided. Each emissive layer may define an exciton formation region, allowing exciton formation to occur across the entire emissive region. By aligning the energy levels of each emissive layer with the adjacent emissive layers, exciton formation in each layer may be improved. Devices incorporating multiple emissive layers with multiple exciton formation regions may exhibit improved performance, including internal quantum efficiencies of up to 100%.

  2. Diesel and Gasoline Engine Emissions: Characterization of Atmosphere

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Composition and Health Responses to Inhaled Emissions | Department of Energy and Gasoline Engine Emissions: Characterization of Atmosphere Composition and Health Responses to Inhaled Emissions Diesel and Gasoline Engine Emissions: Characterization of Atmosphere Composition and Health Responses to Inhaled Emissions 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_mcdonald.pdf More Documents & Publications The Effect of Changes in Diesel

  3. The Advanced Collaborative Emissions Study Moving Forward with Assessing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Emissions and Health Effects of New Diesel Technology | Department of Energy Moving Forward with Assessing the Emissions and Health Effects of New Diesel Technology The Advanced Collaborative Emissions Study Moving Forward with Assessing the Emissions and Health Effects of New Diesel Technology 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_greenbaum.pdf More Documents & Publications The Advanced Collaborative Emissions Study

  4. Greenhouse Gas Emissions Reduction Benefits of Workplace Charging |

    Office of Environmental Management (EM)

    Department of Energy Greenhouse Gas Emissions Reduction Benefits of Workplace Charging Greenhouse Gas Emissions Reduction Benefits of Workplace Charging Reducing greenhouse gas emissions (GHG) from employees' commutes, also known as Scope 3 emissions, is a top priority for many organizations interested in minimizing their carbon footprint. Scope 3 emissions are indirect GHG emissions from sources not owned or directly controlled by the organization but are related to their activities,

  5. Alternative Fuels Data Center: Natural Gas Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Natural Gas Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Digg Find More places to share Alternative Fuels Data

  6. New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors

    SciTech Connect (OSTI)

    Gash, A E; Tillotson, T M; Satcher Jr, J H; Hrubesh, L W; Simpson, R L

    2000-09-12

    We have developed a new sol-gel route to synthesize several transition and main-group metal oxide aerogels. The approach is straightforward, inexpensive, versatile, and it produces monolithic microporous materials with high surface areas. Specifically, we report the use of epoxides as gelation agents for the sol-gel synthesis of chromia aerogels and xerogels from simple Cr(III) inorganic salts. The dependence of both gel formation and its rate was studied by varying the solvent used, the Cr(III) precursor salt, the epoxide/Cr(III) ratio, as well as the type of epoxide employed. All of these variables were shown to affect the rate of gel formation and provide a convenient control of this parameter. Dried chromia aerogels were characterized by high-resolution transmission electron microscopy (HRTEM) and nitrogen adsorption/desorption analyses, results of which will be presented. Our studies have shown that rigid monolithic gels can be prepared from many different metal ions salts, provided the formal oxidation state of the metal ion is greater than or equal to +3. Conversely, when di-valent transition metal salts are used precipitated solids are the products.

  7. Nanocatalysts for Diesel Engine Emissions Remediation

    SciTech Connect (OSTI)

    2009-05-01

    This factsheet describes a research project whose goal is to develop durable zeolite nanocatalysts with broad temperature operating windows to treat diesel engine emissions, thus enabling diesel engine equipment and vehicles to meet regulatory requirements.

  8. 2014 LANL Radionuclide Air Emissions Report

    SciTech Connect (OSTI)

    Fuehne, David Patrick

    2015-07-21

    This report describes the emissions of airborne radionuclides from operations at Los Alamos National Laboratory (LANL) for calendar year 2014, and the resulting off-site dose from these emissions. This document fulfills the requirements established by the National Emissions Standards for Hazardous Air Pollutants in 40 CFR 61, Subpart H – Emissions of Radionuclides other than Radon from Department of Energy Facilities, commonly referred to as the Radionuclide NESHAP or Rad-NESHAP. Compliance with this regulation and preparation of this document is the responsibility of LANL’s RadNESHAP compliance program, which is part of the Environmental Protection Division. The information in this report is required under the Clean Air Act and is being submitted to the U.S. Environmental Protection Agency (EPA) Region 6.

  9. Evaluation of Partial Oxidation Reformer Emissions

    SciTech Connect (OSTI)

    Unnasch, Stefan; Fable, Scott; Waterland, Larry

    2006-01-06

    In this study, a gasoline fuel processor and an ethanol fuel processor were operated under conditions simulating both startup and normal operation. Emissions were measured before and after the AGB in order to quantify the effectiveness of the burner catalyst in controlling emissions. The emissions sampling system includes CEM for O2, CO2, CO, NOx, and THC. Also, integrated gas samples are collected in evacuated canisters for hydrocarbon speciation analysis via GC. This analysis yields the concentrations of the hydrocarbon species required for the California NMOG calculation. The PM concentration in the anode burner exhaust was measured through the placement of a filter in the exhaust stream. The emissions from vehicles with fully developed on board reformer systems were estimated.

  10. Device for collecting emissions from kerosene heaters

    SciTech Connect (OSTI)

    Gilloti, N.J.

    1984-09-04

    An apparatus for both improving the heat distribution throughout a room from a portable kerosene heater and for collecting undesirable emissions resulting from the burning of the kerosene, includes a base adapted to be mounted on the top of the heater, the base supporting a vertically extending shaft on which is mounted a heat-driven fan formed of either paper or metal, and a disposable disk mounted a spaced distance above the fan on the same shaft, the disk serving as a collector for the undesirable emissions. When the device is placed on an operating kerosene heater, the rising hot air and gases from the heater cause the fan to rotate, which in turn causes emissions from the burning fuel to move upwardly in a more or less cylindrical path. As the products of combustion move upwardly, certain emissions therein such as soot, oily vapors, etc. deposit or condense onto the surface of the spinner and disposable disk.

  11. Variable emissivity laser thermal control system

    DOE Patents [OSTI]

    Milner, Joseph R. (Livermore, CA)

    1994-01-01

    A laser thermal control system for a metal vapor laser maintains the wall mperature of the laser at a desired level by changing the effective emissivity of the water cooling jacket. This capability increases the overall efficiency of the laser.

  12. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP ...

  13. Field Emission Measurements from Niobium Electrodes

    SciTech Connect (OSTI)

    M. BastaniNejad, P.A. Adderley, J. Clark, S. Covert, J. Hansknecht, C. Hernandez-Garcia, R. Mammei, M. Poelker

    2011-03-01

    Increasing the operating voltage of a DC high voltage photogun serves to minimize space charge induced emittance growth and thereby preserve electron beam brightness, however, field emission from the photogun cathode electrode can pose significant problems: constant low level field emission degrades vacuum via electron stimulated desorption which in turn reduces photocathode yield through chemical poisoning and/or ion bombardment and high levels of field emission can damage the ceramic insulator. Niobium electrodes (single crystal, large grain and fine grain) were characterized using a DC high voltage field emission test stand at maximum voltage -225kV and electric field gradient > 10MV/m. Niobium electrodes appear to be superior to diamond-paste polished stainless steel electrodes.

  14. MicroEmissive Displays | Open Energy Information

    Open Energy Info (EERE)

    Edinburgh, United Kingdom Zip: EH9 3JF Product: MicroEmissive Displays makes P-OLED (polymer light emitting diode) displays. Specific interests are head mounted displays and...

  15. Addiction Studies with Positron Emission Tomography

    ScienceCinema (OSTI)

    Joanna Fowler

    2010-01-08

    Brookhaven scientist Joanna Fowler describes Positron Emission Technology (PET) research at BNL which for the past 30 years has focused in the integration of basic research in radiotracer chemistry with the tools of neuroscience to develop new scientific

  16. Exploring Advanced Combustion Regimes for Efficiency and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exploring Advanced Combustion Regimes for Efficiency and Emissions Exploring Advanced Combustion Regimes for Efficiency and Emissions 2003 DEER Conference Presentation: Oak Ridge...

  17. Relationship Between Composition and Toxicity of Engine Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Effect of Changes in Diesel Exhaust ... for the Health Effects of Inhaled Engine Emissions Assessment of Health Hazards of Repeated Inhalation of Diesel Emissions, with ...

  18. An Analytical Approach for Tail-Pipe Emissions Estimation with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Analytical Approach for Tail-Pipe Emissions Estimation with Coupled Engine and Aftertreatment System An Analytical Approach for Tail-Pipe Emissions Estimation with Coupled Engine ...

  19. Ethiopia-National Greenhouse Gas Emissions Baseline Scenarios...

    Open Energy Info (EERE)

    National Greenhouse Gas Emissions Baseline Scenarios: Learning from Experiences in Developing Countries Jump to: navigation, search Name Ethiopia-National Greenhouse Gas Emissions...

  20. Greenhouse Gas Emission Trends and Projections in Europe 2009...

    Open Energy Info (EERE)

    Liechtenstein, Poland and Turkey provided updated information on emission projections and national programmes in 2009." References "Greenhouse Gas Emission Trends and...

  1. The Greenhouse Gas Protocol Initiative: Allocation of Emissions...

    Open Energy Info (EERE)

    for allocation of GHG emissions from a combined heat and power (CHP) plant is a free Excel spreadsheet calculator designed to determine the GHG emissions attributable to the...

  2. MOtor Vehicle Emission Simulator (MOVES) | Open Energy Information

    Open Energy Info (EERE)

    of low-emission development strategies (LEDS). Key Outputs Greenhouse gas and air toxic emissions. How to Use This Tool Training Available Training available at http:...

  3. Urea/Ammonia Distribution Optimization in an SCR Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ammonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis UreaAmmonia Distribution Optimization in an SCR Emission Control System...

  4. EIA Energy Efficiency-Energy Related Greenhouse Gas Emissions...

    U.S. Energy Information Administration (EIA) Indexed Site

    Related Greenhouse Gas Emissions Links Energy Related Greenhouse Gas Emissions Links Posted Date: May 2007 Page Last Modified: September 2010 EIA Links Disclaimer: These pages...

  5. Unregulated Emissions from High-Efficiency Clean Combustion Modes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Poster presentation at...

  6. Future Diesel Engine Thermal Efficiency Improvement andn Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engine Thermal Efficiency Improvement andn Emissions Control Technology Future Diesel Engine Thermal Efficiency Improvement andn Emissions Control Technology 2005 Diesel...

  7. 12TH DIESEL ENGINE-EFFICIENCY AND EMISSIONS RESEARCH CONFERENCE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2TH DIESEL ENGINE-EFFICIENCY AND EMISSIONS RESEARCH CONFERENCE (DEER 2006) PRESENTATIONS 12TH DIESEL ENGINE-EFFICIENCY AND EMISSIONS RESEARCH CONFERENCE (DEER 2006) PRESENTATIONS...

  8. Dilute Clean Diesel Combustion Achieves Low Emissions and High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI Dilute Clean Diesel Combustion Achieves Low Emissions and High...

  9. Asia Carbon Emission Management India Pvt Ltd | Open Energy Informatio...

    Open Energy Info (EERE)

    Asia Carbon Emission Management India Pvt Ltd Jump to: navigation, search Name: Asia Carbon Emission Management India Pvt Ltd Place: Chennai, Tamil Nadu, India Zip: 600 034 Sector:...

  10. Time dependent particle emission from fission products (Conference...

    Office of Scientific and Technical Information (OSTI)

    Time dependent particle emission from fission products Citation Details In-Document Search Title: Time dependent particle emission from fission products You are accessing a...

  11. Directionally-Tailored Infrared Emission. AFRL STTR Program

    SciTech Connect (OSTI)

    Burckel, David Bruce; Peters, David W.; Davids, Paul; Resnick, Paul J.; Clem, Paul G.; Ginn, James; Figueiredo, Pedro; Shelton, David

    2015-10-30

    The purpose of this program is to investigate emissive metamaterials (EMM) as a path to realizing surfaces with directional absorption/emission.

  12. Gateway:Low Emission Development Strategies | Open Energy Information

    Open Energy Info (EERE)

    Gateway Edit History Gateway:Low Emission Development Strategies (Redirected from LEDS) Jump to: navigation, search Leds-Graphics 03.PNG Low Emission Development Strategies...

  13. Gateway:Low Emission Development Strategies | Open Energy Information

    Open Energy Info (EERE)

    Edit History Gateway:Low Emission Development Strategies Jump to: navigation, search Leds-Graphics 03.PNG Low Emission Development Strategies (LEDS) Gateway Hello why do you...

  14. Cascaded emission of linearly polarized single photons from positioned...

    Office of Scientific and Technical Information (OSTI)

    Cascaded emission of linearly polarized single photons from positioned InPGaInP quantum dots Citation Details In-Document Search Title: Cascaded emission of linearly polarized ...

  15. Phase 1 of the Advanced Collaborative Emissions Study (ACES)...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding Phase 1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding ...

  16. Advanced Collaborative Emissions Study (ACES): Phase 2 Status...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    : Phase 2 Status Report Advanced Collaborative Emissions Study (ACES): Phase 2 Status Report Discusses status of ACES, a cooperative multi-party effort to characterize emissions ...

  17. Low-Cost Packaged CHP System with Reduced Emissions - Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Packaged CHP System with Reduced Emissions - Presentation by Cummins Power Generation, June 2011 Low-Cost Packaged CHP System with Reduced Emissions - Presentation by ...

  18. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents...

  19. Performance of Johnson Matthey EGRT? Emission Control System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Performance of Johnson Matthey EGRT Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 2002 DEER Conference Presentation: Johnson Matthey...

  20. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

  1. Performance of Johnson Matthey EGRT? Emission Control System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Performance of Johnson Matthey EGRT Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 2 2002 DEER Conference Presentation: Johnson Matthey...

  2. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    customers the fuel mix of its electricity production and the associated sulfur dioxide, nitrogen oxide, and carbon dioxide emissions emissions, expressed in pounds per 1000...

  3. Cellulosic emissions (kg of pollutant per km2 county area) -...

    Open Energy Info (EERE)

    Cellulosic emissions (kg of pollutant per km2 county area) Data reflects projected air emissions of nitrogen oxides (NOX), ammonia (NH3), carbon monoxide (CO), sulfur oxide (SOX),...

  4. Vehicle Technologies Office Merit Review 2014: Emissions Modeling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Modeling: GREET Life Cycle Analysis Vehicle Technologies Office Merit Review 2014: Emissions Modeling: GREET Life Cycle Analysis Presentation given by Argonne National...

  5. COP 18 Side Event: Advancing Collaborative Action for Low Emissions...

    Open Energy Info (EERE)

    COP 18 Side Event: Advancing Collaborative Action for Low Emissions Development Jump to: navigation, search Low Emission Development Strategies Global Partnership Advancing...

  6. US DRIVE Advanced Combustion and Emission Control Technical Team...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion and Emission Control Technical Team Roadmap US DRIVE Advanced Combustion and Emission Control Technical Team Roadmap The ACEC focuses on advanced engine and ...

  7. International Assistance for Low-Emission Development Planning...

    Open Energy Info (EERE)

    Low-Emission Development Planning: CLEAN Inventory of Activities and Tools-Preliminary Trends Jump to: navigation, search International Assistance for Low-Emission Development...

  8. Evaluating Exhaust Emission Performance of Urban Buses Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis ...

  9. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis ...

  10. Advanced Petroleum-Based fuels - Diesel Emissions Control (APBF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fuels - Diesel Emissions Control (APBF-DEC) Activity Advanced Petroleum-Based fuels - Diesel Emissions Control (APBF-DEC) Activity 2003 DEER Conference Presentation: National...

  11. Development and Deployment of Advanced Emission Controls for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Emission Controls for the Retrofit Market Development and Deployment of Advanced Emission Controls for the Retrofit Market 2003 DEER Conference Presentation: Cleaire...

  12. High Engine Efficiency at 2010 Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Engine Efficiency at 2010 Emissions 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005deernelson.pdf More Documents & ...

  13. Low Temperature Combustion and Diesel Emission Reduction Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Diesel Emission Reduction Research Low Temperature Combustion and Diesel Emission Reduction Research Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. ...

  14. Visualization of UHC Emissions for Low-Temperature Diesel Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    UHC Emissions for Low-Temperature Diesel Engine Combustion Visualization of UHC Emissions for Low-Temperature Diesel Engine Combustion Presentation given at DEER 2006, August ...

  15. Potential Effect of Pollutantn Emissions on Global Warming: First...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Potential Effect of Pollutantn Emissions on Global Warming: First Comparisong Using External Costs on Urban Buses Potential Effect of Pollutantn Emissions on Global Warming: First ...

  16. Review of SCR Technologies for Diesel Emission Control: Euruopean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles French perspective on diesel engines & emissions Potential Effect of Pollutantn Emissions on Global Warming: First ...

  17. Low Emission Asian Development (LEAD) Program | Open Energy Informatio...

    Open Energy Info (EERE)

    Low Emission Asian Development (LEAD) Program Redirect page Jump to: navigation, search REDIRECT Low Emissions Asian Development (LEAD) Program Retrieved from "http:...

  18. An Experimental Study of PM Emission Characteristics of Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Experimental Study of PM Emission Characteristics of Commercial Diesel Engine with Urea-SCR System Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research ...

  19. Regulated Emissions from Diesel and Compressed Natural Gas Transit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Heavy Duty Vehicle In-Use Emission Performance Comparison of Clean Diesel Buses to CNG Buses

  20. Advanced PHEV Engine Systems and Emissions Control Modeling and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PHEV Engine Systems and Emissions Control Modeling and Analysis Advanced PHEV Engine Systems and Emissions Control Modeling and Analysis 2011 DOE Hydrogen and Fuel Cells Program,...

  1. Cold-Start Emissions Control in Hybrid Vehicles Equipped with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Control in Hybrid Vehicles Equipped with a Passive Adsorber for Hydrocarbons and NOx Cold-Start Emissions Control in Hybrid Vehicles Equipped with a Passive Adsorber for ...

  2. Effects of Biomass Fuels on Engine & System Out Emissions for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Fuels on Engine & System Out Emissions for Short Term Endurance Effects of Biomass Fuels on Engine & System Out Emissions for Short Term Endurance Results of an...

  3. Thermal Efficiency Improvement While Meeting Emissions of 2007...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Efficiency Improvement While Meeting Emissions of 2007, 2010 and Beyond 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon...

  4. Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon...

  5. Rapid Assessment of City Emissions (RACE): Case of Batangas City...

    Open Energy Info (EERE)

    Rapid Assessment of City Emissions (RACE): Case of Batangas City, Philippines Jump to: navigation, search Tool Summary Name: Rapid Assessment of City Emissions (RACE): Case of...

  6. Emission Inventories and Projections (Book) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Book: Emission Inventories and Projections Citation Details In-Document Search Title: Emission Inventories and Projections When the Executive Body to the Convention on Long-range...

  7. Updated Spitzer emission spectroscopy of bright transiting hot...

    Office of Scientific and Technical Information (OSTI)

    Updated Spitzer emission spectroscopy of bright transiting hot Jupiter HD 189733b Citation Details In-Document Search Title: Updated Spitzer emission spectroscopy of bright...

  8. Injection System and Engine Strategies for Advanced Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection System and Engine Strategies for Advanced Emission Standards Injection System and Engine Strategies for Advanced Emission Standards Presentation given at DEER 2006, ...

  9. Adaptive Injection Strategies (AIS) for Ultra-low Emissions Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection Strategies (AIS) for Ultra-low Emissions Diesel Engines Adaptive Injection Strategies (AIS) for Ultra-low Emissions Diesel Engines Presentation given at the 2007 Diesel ...

  10. Quality, Performance, and Emission Impacts of Biodiesel Blends...

    Broader source: Energy.gov (indexed) [DOE]

    Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Advanced Petroleum Based Fuels ...

  11. Simplification of Diesel Emission Control System Packaging Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simplification of Diesel Emission Control System Packaging Using SCR Coated on DPF Simplification of Diesel Emission Control System Packaging Using SCR Coated on DPF Study...

  12. Comprehensive Assessment of the Emissions from the Use of Biodiesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comprehensive Assessment of the Emissions from the Use of Biodiesel in California Comprehensive Assessment of the Emissions from the Use of Biodiesel in California Overview of a ...

  13. Modeling of Lean Exhaust Emissions Control Systems | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean Exhaust Emissions Control Systems Modeling of Lean Exhaust Emissions Control Systems 2002 DEER Conference Presentation: National Renewable Energy Laboratory PDF icon...

  14. Los Alamos achieves 20-year low on radioactive air emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its lowest radioactive air emissions rate in 20 years in 2013, according to annual air quality results released recently. Each year, the Laboratory measures air emissions...

  15. Collaborative Lubricating Oil Study on Emissions (CLOSE Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Lung Toxicity and ...

  16. Collaborative Lubricating Oil Study on Emissions (CLOSE Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Vehicle Technologies ...

  17. Collaborative Lubricating Oil Study on Emissions (CLOSE) Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLOSE) Project Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Extensive ... to evaluate relative contributions of fuel and lubricating oil on tailpipe emissions. ...

  18. Update on Diesel Exhaust Emission Control Technology and Regulations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Technology and Regulations Update on Diesel Exhaust Emission Control Technology and Regulations 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation:...

  19. China-Quantifying Emission Reduction Opportunities in Emerging...

    Open Energy Info (EERE)

    Emission Reduction Opportunities in Emerging Economies Jump to: navigation, search Name China-Quantifying Emission Reduction Opportunities in Emerging Economies AgencyCompany...

  20. CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT Citation Details In-Document Search Title: CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE ...

  1. Emission Control Systems and Components for Retrofit and First...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Systems and Components for Retrofit and First-Fit Applications 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Cleaire Advanced Emissions Control ...

  2. UNDP-Low Emission Capacity Building Programme | Open Energy Informatio...

    Open Energy Info (EERE)

    Capacity Building Programme Jump to: navigation, search Logo: UNDP-Low Emission Capacity Building Programme Name UNDP-Low Emission Capacity Building Programme AgencyCompany...

  3. Attaining Tier 2 Emissions Through Diesel Engine and Aftertreatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Attaining Tier 2 Emissions Through Diesel Engine and Aftertreatment Integration - Strategy and Experimental Results Attaining Tier 2 Emissions Through Diesel Engine and...

  4. The Role of Lubricant Additives in Fuel Efficiency and Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricant Additives in Fuel Efficiency and Emission Reductions: Viscosity Effects The Role of Lubricant Additives in Fuel Efficiency and Emission Reductions: Viscosity Effects ...

  5. Ultrabroad stimulated emission from quantum well laser

    SciTech Connect (OSTI)

    Wang, Huolei; Zhou, Xuliang; Yu, Hongyan; Mi, Junping; Wang, Jiaqi; Bian, Jing; Wang, Wei; Pan, Jiaoqing; Ding, Ying; Chen, Weixi

    2014-06-23

    Observation of ultrabroad stimulated emission from a simplex quantum well based laser at the center wavelength of 1.06??m is reported. With increased injection current, spectrum as broad as 38?nm and a pulsed output power of ?50?mW have been measured. The experiments show evidence of an unexplored broad emission regime in the InGaAs/GaAs quantum well material system, which still needs theoretical modeling and further analysis.

  6. Emissions trading - time to get serious

    SciTech Connect (OSTI)

    Vitelli, A.

    2007-11-15

    The Kyoto Protocol's five year compliance period begins in 2008. Industrialized nations around the world have pledged to cut carbon emissions, but the job seems to get harder, not easier, as 2008 approaches. Can market mechanisms make the crucial difference? The article discloses recent initiatives and developments worldwide. It concludes that it is clear that the market is maintaining its central role in fighting climate change and that bringing emissions trading to developing countries and to the US can only reinforce that role.

  7. EPA proposes to control automotive VOC emissions

    SciTech Connect (OSTI)

    Not Available

    1987-09-01

    US Environmental Protection Agency has proposed a vehicle control system for reducing gasoline vapors that can escape into the environment during refueling of motor vehicles. It has also has been proposed that gasoline refiners lower the volatility of commercial fuels in summer to reduce vehicle evaporative emissions. EPA said nationwide emissions of volatile organic compounds (VOC), a major contributor to the formation of urban ozone, could be reduced as much as 10% under the proposed pollution-control measures.

  8. Advanced Collaborative Emissions Study | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Study Advanced Collaborative Emissions Study Reports on Phase 1 testing of new 2007 heavy-duty diesel engines (using a common lubricant) from four manufacturers (Caterpillar, Cummins, Detroit Diesel, and Volvo) has been completed; data being reiviewed to support representative engine selection. Duplicate engine will be prepared and tested for su9itability as backup for the exposure study. PDF icon deer08_tennant.pdf More Documents & Publications Advanced Collaborative Emissions Study (ACES):

  9. Radionuclide Air Emission Report for 2007

    SciTech Connect (OSTI)

    Wahl, Linnea; Wahl, Linnea

    2008-06-13

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) radioactive air emission regulations in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H (EPA 1989). The EPA regulates radionuclide emissions that may be released from stacks or vents on buildings where radionuclide production or use is authorized or that may be emitted as diffuse sources. In 2007, all Berkeley Lab sources were minor stack or building emissions sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]), there were no diffuse emissions, and there were no unplanned emissions. Emissions from minor sources either were measured by sampling or monitoring or were calculated based on quantities received for use or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, Version 3.0, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2007 is 1.2 x 10{sup -2} mrem/yr (1.2 x 10{sup -4} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) EPA dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 3.1 x 10{sup -1} person-rem (3.1 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2007.

  10. Displacing Natural Gas Consumption and Lowering Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion System for Refinery and Chemical Plant Process Heaters ADVANCED MANUFACTURING OFFICE Displacing Natural Gas Consumption and Lowering Emissions By enabling process heaters to utilize opportunity gaseous fuels with a fuel-flexible combustion system, this technol- ogy lowers carbon and nitrogen oxide (NO x ) emissions and reduces energy costs for industry. Introduction The refning and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion

  11. Air Emission Inventory for the Idaho National Engineering Laboratory: 1992 emissions report

    SciTech Connect (OSTI)

    Stirrup, T.S.

    1993-06-01

    This report presents the 1992 Air Emission Inventory for the Idaho National Engineering Laboratory. Originally, this report was in response to the Environmental Oversight and Monitoring Agreement in 1989 between the State of Idaho and the Department of Energy Idaho Field Office, and a request from the Idaho Air Quality Bureau. The current purpose of the Air Emission Inventory is to provide the basis for the preparation of the INEL Permit-to-Operate (PTO) an Air Emission Source Application, as required by the recently promulgated Title V regulations of the Clean Air Act. This report includes emissions calculations from 1989 to 1992. The Air Emission Inventory System, an ORACLE-based database system, maintains the emissions inventory.

  12. The experimental setup of the Interaction in Crystals for Emission of RADiation collaboration at Mainzer Mikrotron: Design, commissioning, and tests

    SciTech Connect (OSTI)

    Lietti, D.; Backe, H.; Lauth, W.; Bagli, E.; Bandiera, L.; Germogli, G.; Guidi, V.; Mazzolari, A.; Berra, A.; Prest, M.; Carturan, S.; De Salvador, D.; Vallazza, E.

    2015-04-15

    Silicon/germanium flat/bent crystals are thin devices able to efficiently deflect charged particle GeV-energy beams up to a few hundreds of ?rad; moreover, high intensity photons can be efficiently produced in the so-called Multi-Volume Reflection (MVR) and Multiple Volume Reflections in One Crystal (MVROC) conditions. In the last years, the research interest in this field has moved to the dynamic studies of light negative leptons in the low energy range: the possibility to deflect negative particles and to produce high intensity ? sources via the coherent interactions with crystals in the sub-GeV energy range has been proved by the ICE-RAD (Interaction in Crystals for Emission of RADiation) Collaboration at the MAinzer MIkrotron (MAMI, Germany). This paper describes the setup used by the ICE-RAD experiment for the crystals characterization (both in terms of deflection and radiation emission properties): a high precision goniometer is used to align the crystals with the incoming beam, while a silicon based profilometer and an inorganic scintillator reconstruct, respectively, the particle position and the photon spectra after the samples. The crystals manufacturing process and their characterization, the silicon profilometer commissioning at the CERN PS T9 beamline, and the commissioning of the whole setup installed at MAMI are presented.

  13. Radionuclide Air Emission Report for 2008

    SciTech Connect (OSTI)

    Wahl, Linnea

    2009-05-21

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) radioactive air emission regulations in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2008, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources include more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2008 is 5.2 x 10{sup -3} mrem/yr (5.2 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.1 x 10{sup -1} person-rem (1.1 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2008.

  14. Radionuclide Air Emission Report for 2009

    SciTech Connect (OSTI)

    Wahl, Linnea

    2010-06-01

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the EPA radioactive air emission regulations in 40CFR61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2009, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources included more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2009 is 7.0 x 10{sup -3} mrem/yr (7.0 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.5 x 10{sup -1} person-rem (1.5 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2009.

  15. Optical Properties of Moderately-Absorbing Organic and Mixed Organic/Inorganic Particles at Very High Humidities

    SciTech Connect (OSTI)

    Bond, Tami C; Rood, Mark J; Brem, Benjamin T; Mena-Gonzalez, Francisco C; Chen, Yanju

    2012-04-16

    Relative humidity (RH) affects the water content of an aerosol, altering its ability to scatter and absorb light, which is important for aerosol effects on climate and visibility. This project involves in situ measurement and modeling of aerosol optical properties including absorption, scattering and extinction at three visible wavelengths (467, 530, 660 nm), for organic carbon (OC) generated by pyrolysis of biomass, ammonium sulfate and sodium chloride, and their mixtures at controlled RH conditions. Novel components of this project include investigation of: (1) Changes in all three of these optical properties at scanned RH conditions; (2) Optical properties at RH values up to 95%, which are usually extrapolated instead of measured; and (3) Examination of aerosols generated by the pyrolysis of wood, which is representative of primary atmospheric organic carbon, and its mixture with inorganic aerosol. Scattering and extinction values were used to determine light absorption by difference and single scattering albedo values. Extensive instrumentation development and benchmarking with independently measured and modeled values were used to obtain and evaluate these new results. The single scattering albedo value for a dry absorbing polystyrene microsphere benchmark agreed within 0.02 (absolute value) with independently published results at 530 nm. Light absorption by a nigrosin (sample light-absorbing) benchmark increased by a factor of 1.24 +/-0.06 at all wavelengths as RH increased from 38 to 95%. Closure modeling with Mie theory was able to reproduce this increase with the linear volume average (LVA) refractive index mixing rule for this water soluble compound. Absorption by biomass OC aerosol increased by a factor of 2.1 +/- 0.7 and 2.3 +/- 1.2 between 32 and 95% RH at 467 nm and 530 nm, but there was no detectable absorption at 660 nm. Additionally, the spectral dependence of absorption by OC that was observed with filter measurements was confirmed qualitatively in situ at 467 and 530 nm. Closure modeling with the dynamic effective medium approximation (DEMA) refractive index model was able to capture the increasing absorption trend with RH indicating that the droplets were heterogeneously mixed while containing dispersed insoluble absorbing material within those droplets. Seven other refractive index mixing models including LVA did not adequately describe the measurements for OC. Mixing the biomass OC aerosol with select mass fractions of ammonium sulfate ranging from 25 to 36% and sodium chloride ranging from 21 to 30% resulted in an increase in light scattering and extinction with RH and inorganic mass fraction. However, no detectable difference in light absorption behavior in comparison to pure biomass OC was observed. The main finding of this research is a measured increase in absorption with increasing RH, which is currently not represented in radiative transfer models even though biomass burning produces most of the primary OC aerosol in the atmosphere.

  16. Mechanism of charge recombination in meso-structured organic-inorganic hybrid perovskite solar cells: A macroscopic perspective

    SciTech Connect (OSTI)

    Yang, Wenchao; Yao, Yao Wu, Chang-Qin

    2015-04-21

    In the currently popular organic-inorganic hybrid perovskite solar cells, the slowness of the charge recombination processes is found to be a key factor for contributing to their high efficiencies and high open circuit voltages, but the underlying recombination mechanism remains unclear. In this work, we investigate the bimolecular recombination (BR) and the trap-assisted monomolecular recombination (MR) in meso-structured perovskite solar cells under steady state working condition, and try to reveal their roles on determining the device performance. Some interfacial effects such as the injection barriers at the selective contacts are examined as well. Based on the macroscopic device modeling, the recombination resistance-voltage (R{sub rec}?V) and the current density-voltage (JV) curves are calculated to characterize the recombination mechanism and describe the device performance, respectively. Through comparison with the impedance spectroscopy extracted R{sub rec} data, it is found that under the typical BR reduction factor and deep trap densities observed in experiments, the MR dominates the charge recombination in the low voltage regime, while the BR dominates in the high voltage regime. The short circuit current and the fill factor could be reduced by the significant MR but the open circuit voltage is generally determined by the BR. The different electron injection barriers at the contact can change the BR rate and induce different patterns for the R{sub rec}V characteristics. For the perovskites of increased band gaps, the R{sub rec}'s are significantly enhanced, corresponding to the high open circuit voltages. Finally, it is revealed that the reduced effective charge mobility due to the transport in electron and hole transporting material makes the R{sub rec} decrease slowly with the increasing voltage, which leads to increased open circuit voltage.

  17. Recent Diesel Engine Emission Mitigation Activities of the Maritime

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Administration Energy Technologies Program | Department of Energy Diesel Engine Emission Mitigation Activities of the Maritime Administration Energy Technologies Program Recent Diesel Engine Emission Mitigation Activities of the Maritime Administration Energy Technologies Program 2003 DEER Conference Presentation: Maritime Administration PDF icon 2003_deer_gore.pdf More Documents & Publications The Maritime Administration's Energy and Emissions Program - Part 2 Reduction of Emissions

  18. Review of Diesel Emission Control Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Emission Control Technology Review of Diesel Emission Control Technology 2002 DEER Conference Presentation: Corning Inc. PDF icon 2002_deer_johnson.pdf More Documents & Publications Diesel Emission Control Technology Review Update on Diesel Exhaust Emission Control Light Duty Diesels in the United States - Some Perspectives

  19. Mass Correlation of Engine Emissions with Spectral Instruments | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Mass Correlation of Engine Emissions with Spectral Instruments Mass Correlation of Engine Emissions with Spectral Instruments 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of Minnesota, Cambustion UK PDF icon 2004_deer_collings.pdf More Documents & Publications Nanoparticle Emissions from Internal Combustion Engines Chemical and Physical Characteristics of Diesel Aerosol California's Efforts for Advancing Ultrafine Particle Number

  20. Combustion Targets for Low Emissions and High Efficiency | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Targets for Low Emissions and High Efficiency Combustion Targets for Low Emissions and High Efficiency 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_ryan.pdf More Documents & Publications Diesel Engine Alternatives An Experimental Investigation of Low Octane Gasoline in Diesel Engines SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline Engines

  1. Update on Diesel Exhaust Emission Control Technology and Regulations |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Control Technology and Regulations Update on Diesel Exhaust Emission Control Technology and Regulations 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Corning PDF icon 2004_deer_johnson2.pdf More Documents & Publications Light Duty Diesels in the United States - Some Perspectives Review of Diesel Emission Control Technology Update on Diesel Exhaust Emission Control

  2. Preparing Low-emission and Climate-Resilient Development Strategies...

    Open Energy Info (EERE)

    contentundpenhomeourworkenvironmentandenergyfo Cost: Free Language: English Preparing Low-Emission and Climate-Resilient Development Strategies (LECRDS) -...

  3. New three-dimensional inorganic frameworks based on the uranophane-type sheet in monoamine templated uranyl-vanadates

    SciTech Connect (OSTI)

    Jouffret, Laurent; Shao Zhenmian

    2010-10-15

    Seven new uranyl vanadates with mono-protonated amine or tetramethylammonium used as structure directing cations, (C{sub 2}NH{sub 8}){sub 2{l_brace}}[(UO{sub 2})(H{sub 2}O)][(UO{sub 2})(VO{sub 4})]{sub 4{r_brace}}.H{sub 2}O (DMetU5V4) (C{sub 2}NH{sub 8}){l_brace}[(UO{sub 2})(H{sub 2}O){sub 2}][(UO{sub 2})(VO{sub 4})]{sub 3{r_brace}}.H{sub 2}O (DMetU4V3), (C{sub 5}NH{sub 6}){sub 2{l_brace}}[(UO{sub 2})(H{sub 2}O)][(UO{sub 2})(VO{sub 4})]{sub 4{r_brace}}.H{sub 2}O (PyrU5V4), (C{sub 3}NH{sub 10}){l_brace}[(UO{sub 2})(H{sub 2}O){sub 2}][(UO{sub 2})(VO{sub 4})]{sub 3{r_brace}}.H{sub 2}O (isoPrU4V3), (N(CH{sub 3}){sub 4}){l_brace}[(UO{sub 2})(H{sub 2}O){sub 2}][(UO{sub 2})(VO{sub 4})]{sub 3{r_brace}}.H{sub 2}O (TMetU4V3), (C{sub 6}NH{sub 14}){l_brace}[(UO{sub 2})(H{sub 2}O){sub 2}][(UO{sub 2})(VO{sub 4})]{sub 3{r_brace}}.H{sub 2}O (CHexU4V3), and (C{sub 4}NH{sub 12}){l_brace}[(UO{sub 2})(H{sub 2}O)][(UO{sub 2})(VO{sub 4})]{sub 3{r_brace}} (TButU4V3) were prepared from mild-hydrothermal reactions using dimethylamine, pyridine, isopropylamine, tetramethylammonium hydroxide, cyclohexylamine and tertiobutylamine, respectively, with uranyl nitrate and vanadium oxide in acidic medium. The structures were solved using single-crystal X-ray diffraction data. The compounds exhibit three-dimensional uranyl-vanadate inorganic frameworks built from uranophane-type uranyl-vanadate layers pillared by uranyl polyhedra with cavities in between occupied by protonated organic moieties. In the uranyl-vanadate layers the orientations of the vanadate tetrahedra give new geometrical isomers leading to unprecedented pillared systems and new inorganic frameworks with U/V=4/3. Crystallographic data: (DMetU5V4) orthorhombic, Cmc2{sub 1} space group, a=15.6276(4), b=14.1341(4), c=13.6040(4) A; (DMetU4V3) monoclinic, P2{sub 1}/n space group, a=10.2312(4), b=13.5661(7), c=17.5291(7) A, {beta}=96.966(2); (PyrU5V4), triclinic, P1 space group, a=9.6981(3), b=9.9966(2), c=10.5523(2) A, {alpha}=117.194(1), {beta}=113.551(1), {gamma}=92.216(1){sup o}; (isoPrU4V3) monoclinic, P2{sub 1}/n space group, a=10.3507(1), b=13.6500(2), c=17.3035(2) A, {beta}=97.551(1){sup o}; (TMetU4V3) orthorhombic, Pbca space group, a=17.1819(2), b=13.6931(1), c=21.4826(2) A; (CHexU4V3), triclinic P-1 space group, a=9.8273(6), b=11.0294(7), c=12.7506(8) A, {alpha}=98.461(3), {beta}=96.437(3), {gamma}=105.955(3){sup o}; (TButU4V3), monoclinic, P2{sub 1}/m space group, a=9.8048(4), b=17.4567(8), c=15.4820(6) A, {beta}=106.103(2). - Graphical abstract: The various type of PBP pillars P2, P3, P4, and P4' in the three-dimensional inorganic frameworks based on the uranophane-type sheet in monoamine templated uranyl-vanadates.

  4. ZERO EMISSION POWER GENERATION TECHNOLOGY DEVELOPMENT

    SciTech Connect (OSTI)

    Ronald Bischoff; Stephen Doyle

    2005-01-20

    Clean Energy Systems (CES) was previously funded by DOE's ''Vision 21'' program. This program provided a proof-of-concept demonstration that CES' novel gas generator (combustor) enabled production of electrical power from fossil fuels without pollution. CES has used current DOE funding for additional design study exercises which established the utility of the CES-cycle for retrofitting existing power plants for zero-emission operations and for incorporation in zero-emission, ''green field'' power plant concepts. DOE funding also helped define the suitability of existing steam turbine designs for use in the CES-cycle and explored the use of aero-derivative turbines for advanced power plant designs. This work is of interest to the California Energy Commission (CEC) and the Norwegian Ministry of Petroleum & Energy. California's air quality districts have significant non-attainment areas in which CES technology can help. CEC is currently funding a CES-cycle technology demonstration near Bakersfield, CA. The Norwegian government is supporting conceptual studies for a proposed 40 MW zero-emission power plant in Stavager, Norway which would use the CES-cycle. The latter project is called Zero-Emission Norwegian Gas (ZENG). In summary, current engineering studies: (1) supported engineering design of plant subsystems applicable for use with CES-cycle zero-emission power plants, and (2) documented the suitability and availability of steam turbines for use in CES-cycle power plants, with particular relevance to the Norwegian ZENG Project.

  5. Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction | Department of Energy Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions Reduction Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_rumsey.pdf More Documents & Publications High Engine Efficiency at 2010 Emissions Integrated Engine and Aftertreatment Technology Roadmap for EPA 2010 Heavy-duty Emissions Regulations Optimization

  6. Progress Update: Creating Mobile Emission Reduction Credits | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Update: Creating Mobile Emission Reduction Credits Progress Update: Creating Mobile Emission Reduction Credits 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Emission Reduction Specialists PDF icon 2004_deer_sloan.pdf More Documents & Publications Creating Mobile Emission Reduction Credits ADEC II Universal SCR Retrofit System for On-road and Off-road Diesel Engines SCR & DPF RETROFITS FOR MOBILE DIESEL ENGINES

  7. Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Emission Control | Department of Energy Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control 2003 DEER Conference Presentation: The Pennsylvania State University PDF icon 2003_deer_boehman.pdf More Documents & Publications Fuel Impacts on Soot Nanostructure and Reactivity Effect of Alternative Fuels on Soot Properties and Regeneration of Diesel Particulate

  8. Creating Mobile Emission Reduction Credits | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Creating Mobile Emission Reduction Credits Creating Mobile Emission Reduction Credits 2002 DEER Conference Presentation: Emission Credit Brokers PDF icon 2002_deer_sloan.pdf More Documents & Publications Progress Update: Creating Mobile Emission Reduction Credits An Experimental Study of PM Emission Characteristics of Commercial Diesel Engine with Urea-SCR System Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel Genset

  9. DOE Emission Control R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Control R&D DOE Emission Control R&D 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_3_howden.pdf More Documents & Publications Overview of DOE Emission Control R&D Overview of DOE Emission Control R&D Overview of DOE Emission Control R&D

  10. Diesel Emission Control in Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Review Diesel Emission Control in Review Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_johnson.pdf More Documents & Publications Update on Diesel Exhaust Emission Control Diesel Emission Control Review Diesel Emission Control Technology Review

  11. Guide to Low-Emission Boiler and Combustion Equipment Selection |

    Office of Environmental Management (EM)

    Department of Energy Low-Emission Boiler and Combustion Equipment Selection Guide to Low-Emission Boiler and Combustion Equipment Selection The guide provides background information about various types of industrial, commercial, and institutional (ICI) boilers along with discussion about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and

  12. Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on

  13. Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Trucks Wisconsin Reduces Emissions With Natural Gas Trucks to someone by E-mail Share Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Facebook Tweet about Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Twitter Bookmark Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Google Bookmark Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Delicious

  14. Light collection device for flame emission detectors

    DOE Patents [OSTI]

    Woodruff, Stephen D. (Morgantown, WV); Logan, Ronald G. (Morgantown, WV); Pineault, Richard L. (Morgantown, WV)

    1990-01-01

    A light collection device for use in a flame emission detection system such as an on-line, real-time alkali concentration process stream monitor is disclosed which comprises a sphere coated on its interior with a highly diffuse reflective paint which is positioned over a flame emission source, and one or more fiber optic cables which transfer the light generated at the interior of the sphere to a detecting device. The diffuse scattering of the light emitted by the flame uniformly distributes the light in the sphere, and the collection efficiency of the device is greater than that obtainable in the prior art. The device of the present invention thus provides enhanced sensitivity and reduces the noise associated with flame emission detectors, and can achieve substantial improvements in alkali detection levels.

  15. Emission Control Systems and Components for Retrofit and First-Fit Applications

    Broader source: Energy.gov [DOE]

    2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Cleaire Advanced Emissions Control

  16. Far-infrared surface emissivity and climate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-03

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

  17. Far-infrared surface emissivity and climate

    SciTech Connect (OSTI)

    Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-03

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 ?m, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.82.0 W m? difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2K, 10 W m?, and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

  18. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  19. Inorganic ion sorbent method

    DOE Patents [OSTI]

    Teter, David M. (Edgewood, NM); Brady, Patrick V. (Albuquerque, NM); Krumhansl, James L. (Albuquerque, NM)

    2007-07-17

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  20. Inorganic ion sorbents

    DOE Patents [OSTI]

    Teter, David M.; Brady, Patrick V.; Krumhansl, James L.

    2006-10-17

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  1. A LIGHT CURVE ANALYSIS OF CLASSICAL NOVAE: FREE-FREE EMISSION VERSUS PHOTOSPHERIC EMISSION

    SciTech Connect (OSTI)

    Hachisu, Izumi; Kato, Mariko E-mail: mariko@educ.cc.keio.ac.jp

    2015-01-10

    We analyzed light curves of seven relatively slower novae, PW Vul, V705 Cas, GQ Mus, RR Pic, V5558 Sgr, HR Del, and V723 Cas, based on an optically thick wind theory of nova outbursts. For fast novae, free-free emission dominates the spectrum in optical bands rather than photospheric emission, and nova optical light curves follow the universal decline law. Faster novae blow stronger winds with larger mass-loss rates. Because the brightness of free-free emission depends directly on the wind mass-loss rate, faster novae show brighter optical maxima. In slower novae, however, we must take into account photospheric emission because of their lower wind mass-loss rates. We calculated three model light curves of free-free emission, photospheric emission, and their sum for various white dwarf (WD) masses with various chemical compositions of their envelopes and fitted reasonably with observational data of optical, near-IR (NIR), and UV bands. From light curve fittings of the seven novae, we estimated their absolute magnitudes, distances, and WD masses. In PW Vul and V705 Cas, free-free emission still dominates the spectrum in the optical and NIR bands. In the very slow novae, RR Pic, V5558 Sgr, HR Del, and V723 Cas, photospheric emission dominates the spectrum rather than free-free emission, which makes a deviation from the universal decline law. We have confirmed that the absolute brightnesses of our model light curves are consistent with the distance moduli of four classical novae with known distances (GK Per, V603 Aql, RR Pic, and DQ Her). We also discussed the reason why the very slow novae are about ∼1 mag brighter than the proposed maximum magnitude versus rate of decline relation.

  2. The influence of interfaces on properties of thin-film inorganic structural isomers containing SnSeNbSe? Subunits

    SciTech Connect (OSTI)

    Alemayehu, Matti B.; Falmbigl, Matthias; Ta, Kim; Johnson, David C.

    2015-08-28

    Inorganic isomers ([SnSe]1+?)m(NbSe?)n([SnSe]1+?)p(NbSe?)q([SnSe]1+?)r(NbSe?)s where m, n, p, q, r, and s are integers and m + p + r = n + q + s = 4 were prepared using the modulated elemental reactant technique. This series of all six possible isomers provides an opportunity to study the influence of interface density on properties while maintaining the same unit cell size and composition. As expected, all six compounds were observed to have the same atomic compositions and an almost c-axis lattice parameter of ?4.90 (5) nm, with a slight trend in the c-axis lattice parameter correlated with the different number of interfaces in the isomers: two, four and six. The structures of the constituents in the ab-plane were independent of one another, confirming the nonepitaxial relationship between them. The temperature dependent electrical resistivities revealed metallic behavior for all the six compounds. Surprisingly, the electrical resistivity at room temperature decreases with increasing number of interfaces. Hall measurements suggest this results from changes in carrier concentration, which increases with increasing thickness of the thickest SnSe block in the isomer. Carrier mobility scales with the thickness of the thickest NbSe? block due to increased interfacial scattering as the NbSe? blocks become thinner. The observed behavior suggests that the two constituents serve different purposes with respect to electrical transport. SnSe acts as a charge donor and NbSe? acts as the charge transport layer. This separation of function suggests that such heterostructures can be designed to optimize performance through choice of constituent, layer thickness, and layer sequence. A simplistic model, which predicts the properties of the complex isomers from a weighted sum of the properties of building blocks, was developed. A theoretical model is needed to predict the optimal compound for specific properties among the many potential compounds that can be prepared.

  3. Exploring Low Emission Lubricants for Diesel Engines

    SciTech Connect (OSTI)

    Perez, J. M.

    2000-07-06

    A workshop to explore the technological issues involved with the removal of sulfur from lubricants and the development of low emission diesel engine oils was held in Scottsdale, Arizona, January 30 through February 1, 2000. It presented an overview of the current technology by means of panel discussions and technical presentations from industry, government, and academia.

  4. Variable emissivity laser thermal control system

    DOE Patents [OSTI]

    Milner, J.R.

    1994-10-25

    A laser thermal control system for a metal vapor laser maintains the wall temperature of the laser at a desired level by changing the effective emissivity of the water cooling jacket. This capability increases the overall efficiency of the laser. 8 figs.

  5. Mitigating Greenhouse Gas Emissions: Voluntary Reporting 1996

    Reports and Publications (EIA)

    1997-01-01

    Presents information on voluntary actions to reduce greenhouse gases or remove such gases from the atmosphere in 1995. It provides an overview of participation in the Voluntary Reporting Program, a perspective on the composition of activities reported, and a review of some key issues in interpreting and evaluating achievements associated with reported emissions mitigation initiatives.

  6. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  7. Plasma emission spectroscopy method of tumor therapy

    DOE Patents [OSTI]

    Fleming, Kevin J. (Albuquerque, NM)

    1997-01-01

    Disclosed are a method and apparatus for performing photon diagnostics using a portable and durable apparatus which incorporates the use of a remote sensing probe in fiberoptic communication with an interferometer or spectrometer. Also disclosed are applications for the apparatus including optically measuring high velocities and analyzing plasma/emission spectral characteristics.

  8. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect (OSTI)

    2005-09-01

    This project focuses on a new technology that reduces NOx emissions while increasing furnace efficiency for both air- and oxygen-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace.

  9. 2007: make or break for emissions trading

    SciTech Connect (OSTI)

    Vitelli, A.

    2006-11-15

    With the Kyoto Protocol's first compliance period beginning in 2008, much of 2007 will be focussed on implementing the institutions needed to ensure the Protocol's effectiveness. The big unknown is whether governments and international bodies can make tough decisions in time to let the emissions market function effectively to reduce greenhouse gases.

  10. Plasma emission spectroscopy method of tumor therapy

    DOE Patents [OSTI]

    Fleming, K.J.

    1997-03-11

    Disclosed are a method and apparatus for performing photon diagnostics using a portable and durable apparatus which incorporates the use of a remote sensing probe in fiberoptic communication with an interferometer or spectrometer. Also disclosed are applications for the apparatus including optically measuring high velocities and analyzing plasma/emission spectral characteristics. 6 figs.

  11. Advanced Instrumentation for Positron Emission Tomography [PET

    DOE R&D Accomplishments [OSTI]

    Derenzo, S. E.; Budinger, T. F.

    1985-04-01

    This paper summarizes the physical processes and medical science goals that underlay modern instrumentation design for Positron Emission Tomography. The paper discusses design factors such as detector material, crystalphototube coupling, shielding geometry, sampling motion, electronics design, time-of-flight, and the interrelationships with quantitative accuracy, spatial resolution, temporal resolution, maximum data rates, and cost.

  12. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  13. China Energy and Emissions Paths to 2030

    SciTech Connect (OSTI)

    Fridley, David; Zheng, Nina; Zhou, Nan; Ke, Jing; Hasanbeigi, Ali; Morrow, Bill; Price, Lynn

    2011-01-14

    After over two decades of staggering economic growth and soaring energy demand, China has started taking serious actions to reduce its economic energy and carbon intensity by setting short and medium-term intensity reduction targets, renewable generation targets and various supporting policies and programs. In better understanding how further policies and actions can be taken to shape China's future energy and emissions trajectory, it is important to first identify where the largest opportunities for efficiency gains and emission reduction lie from sectoral and end-use perspectives. Besides contextualizing China's progress towards reaching the highest possible efficiency levels through the adoption of the most advanced technologies from a bottom-up perspective, the actual economic costs and benefits of adopting efficiency measures are also assessed in this study. This study presents two modeling methodologies that evaluate both the technical and economic potential of raising China's efficiency levels to the technical maximum across sectors and the subsequent carbon and energy emission implications through 2030. The technical savings potential by efficiency measure and remaining gap for improvements are identified by comparing a reference scenario in which China continues the current pace of with a Max Tech scenario in which the highest technically feasible efficiencies and advanced technologies are adopted irrespective of costs. In addition, from an economic perspective, a cost analysis of selected measures in the key industries of cement and iron and steel help quantify the actual costs and benefits of achieving the highest efficiency levels through the development of cost of conserved energy curves for the sectors. The results of this study show that total annual energy savings potential of over one billion tonne of coal equivalent exists beyond the expected reference pathway under Max Tech pathway in 2030. CO2 emissions will also peak earlier under Max Tech, though the 2020s is a likely turning point for both emission trajectories. Both emission pathways must meet all announced and planned policies, targets and non-fossil generation targets, or an even wider efficiency gap will exist. The savings potential under Max Tech varies by sector, but the industrial sector appears to hold the largest energy savings and emission reduction potential. The primary source of savings is from electricity rather than fuel, and electricity savings are magnified by power sector decarbonization through increasing renewable generation and coal generation efficiency improvement. In order to achieve the maximum energy savings and emission reduction potential, efficiency improvements and technology switching must be undertaken across demand sectors as well as in the growing power sector. From an economic perspective, the cost of conserved energy analysis indicates that nearly all measures for the iron and steel and cement industry are cost-effective. All 23 efficiency measures analyzed for the cement industry are cost-effective, with combined CO2 emission reduction potential of 448 Mt CO2. All of the electricity savings measures in the iron and steel industry are cost-effective, but the cost-effective savings potential for fuel savings measures is slightly lower than total technical savings potential. The total potential savings from these measures confirm the magnitude of savings in the scenario models, and illustrate the remaining efficiency gap in the cement and iron and steel industries.

  14. Perspective on the Future Development of Diesel Emission Standards...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Perspective on the Future Development of Diesel Emission Standards in Europe - Euro 5 for LDV, amendment of EURO 5 for HDV Perspective on the Future Development of Diesel Emission...

  15. The Effect of Diesel Fuel Properties on Emissions-Restrained...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Effect of Diesel Fuel Properties on Emissions-Restrained Fuel Economy at Mid-Load Conditions The Effect of Diesel Fuel Properties on Emissions-Restrained Fuel Economy at...

  16. Integrated Assessment of the Energy Savings and Emissions-Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment of the Energy Savings and Emissions-Reduction Potential of CHP, June 1999 Integrated Assessment of the Energy Savings and Emissions-Reduction Potential of CHP, June 1999 ...

  17. Microsoft Word - Energy and Emissions Benefit Table Instructions...

    Broader source: Energy.gov (indexed) [DOE]

    known air emissions from the production site related to the manufacturing process (i.e. NOx from a boiler, emissions from a diesel forklift or volatization of a solvent). If there...

  18. Design of Integrated Laboratory and Heavy-Duty Emissions Testing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design of Integrated Laboratory and Heavy-Duty Emissions Testing Center Both simulated and ... emissions were able to be measured and analyzed using a bench-top adiabatic reactor. ...

  19. HEAVY-DUTY TRUCK EMISSIONS AND FUEL CONSUMPTION SIMULATING REAL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HEAVY-DUTY TRUCK EMISSIONS AND FUEL CONSUMPTION SIMULATING REAL-WORLD DRIVING IN LABORATORY CONDITIONS HEAVY-DUTY TRUCK EMISSIONS AND FUEL CONSUMPTION SIMULATING REAL-WORLD DRIVING ...

  20. Operability and Emissions from a Medium-Duty Fleet Operating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Operability and Emissions from a Medium-Duty Fleet Operating with GTL Fuel and Catalyzed DPFs Operability and Emissions from a Medium-Duty Fleet Operating with GTL Fuel and ...

  1. Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF In reference ...

  2. Future climate change under RCP emission scenarios with GISS...

    Office of Scientific and Technical Information (OSTI)

    Future climate change under RCP emission scenarios with GISS ModelE2 Citation Details In-Document Search Title: Future climate change under RCP emission scenarios with GISS ModelE2 ...

  3. Concentrations and Size Distributions of Particulate Matter Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigation of the Effects of Fuels and Aftertreatment Devices on the Emission Profiles of Trucks and Buses ARB's Study of Emissions from Diesel and CNG Heavy-duty Transit Buses ...

  4. Combustion and Emissions Performance of Dual-Fuel Gasoline and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC on a Multi-Cylinder Light Duty Diesel Engine Combustion and Emissions Performance of Dual-Fuel Gasoline...

  5. The Business of Near Zero Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Business of Near Zero Emissions The Business of Near Zero Emissions PDF icon deer10_charbonneau.pdf More Documents & Publications Advanced Vehicle Electrification Navistar-Driving efficiency with integrated technology Advanced Vehicle Electrification

  6. Formation of nanofilament field emission devices

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Contolini, Robert J. (Lake Oswego, OR); Musket, Ronald G. (Danville, CA); Bernhardt, Anthony F. (Berkeley, CA)

    2000-01-01

    A process for fabricating a nanofilament field emission device. The process enables the formation of high aspect ratio, electroplated nanofilament structure devices for field emission displays wherein a via is formed in a dielectric layer and is self-aligned to a via in the gate metal structure on top of the dielectric layer. The desired diameter of the via in the dielectric layer is on the order of 50-200 nm, with an aspect ratio of 5-10. In one embodiment, after forming the via in the dielectric layer, the gate metal is passivated, after which a plating enhancement layer is deposited in the bottom of the via, where necessary. The nanofilament is then electroplated in the via, followed by removal of the gate passification layer, etch back of the dielectric, and sharpening of the nanofilament. A hard mask layer may be deposited on top of the gate metal and removed following electroplating of the nanofilament.

  7. FETC Programs for Reducing Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Ruether, J.A.

    1998-02-01

    Mark Twain once quipped that everyone talks about the weather but no one does anything about it. With interest in global climate change on the rise, researchers in the fossil-energy sector are feeling the heat to provide new technology to permit continued use of fossil fuels but with reduced emissions of so-called `greenhouse gases.` Three important greenhouse gases, carbon dioxide, methane, and nitrous oxide, are released to the atmosphere in the course of recovering and combusting fossil fuels. Their importance for trapping radiation, called forcing, is in the order given. In this report, we briefly review how greenhouse gases cause forcing and why this has a warming effect on the Earth`s atmosphere. Then we discuss programs underway at FETC that are aimed at reducing emissions of methane and carbon dioxide.

  8. Emissive sensors and devices incorporating these sensors

    DOE Patents [OSTI]

    Swager, Timothy M; Zhang, Shi-Wei

    2013-02-05

    The present invention generally relates to luminescent and/or optically absorbing compositions and/or precursors to those compositions, including solid films incorporating these compositions/precursors, exhibiting increased luminescent lifetimes, quantum yields, enhanced stabilities and/or amplified emissions. The present invention also relates to sensors and methods for sensing analytes through luminescent and/or optically absorbing properties of these compositions and/or precursors. Examples of analytes detectable by the invention include electrophiles, alkylating agents, thionyl halides, and phosphate ester groups including phosphoryl halides, cyanides and thioates such as those found in certain chemical warfare agents. The present invention additionally relates to devices and methods for amplifying emissions, such as those produced using the above-described compositions and/or precursors, by incorporating the composition and/or precursor within a polymer having an energy migration pathway. In some cases, the compositions and/or precursors thereof include a compound capable of undergoing a cyclization reaction.

  9. Electrochemical sharpening of field emission tips

    DOE Patents [OSTI]

    Bernhardt, Anthony F. (Berkeley, CA)

    1999-01-01

    A method for sharpening field emitter tips by electroetching/polishing. In gated field emitters, it is very important to initiate electron emission at the lowest possible voltage and thus the composition of the emitter and the gate, as well as the emitter-gate structure, are important factors. This method of sharpening the emitter tips uses the grid as a counter electrode in electroetching of the emitters, which can produce extremely sharp emitter tips as well as remove asperities and other imperfections in the emitters, each in relation to the specific grid hole in which it resides. This has the effect of making emission more uniform among the emitters as well as lowering the turn-on voltage.

  10. Electrochemical sharpening of field emission tips

    DOE Patents [OSTI]

    Bernhardt, A.F.

    1999-04-06

    A method is disclosed for sharpening field emitter tips by electroetching/polishing. In gated field emitters, it is very important to initiate electron emission at the lowest possible voltage and thus the composition of the emitter and the gate, as well as the emitter-gate structure, are important factors. This method of sharpening the emitter tips uses the grid as a counter electrode in electroetching of the emitters, which can produce extremely sharp emitter tips as well as remove asperities and other imperfections in the emitters, each in relation to the specific grid hole in which it resides. This has the effect of making emission more uniform among the emitters as well as lowering the turn-on voltage. 3 figs.

  11. Integrated field emission array for ion desorption

    DOE Patents [OSTI]

    Resnick, Paul J; Hertz, Kristin L; Holland, Christopher; Chichester, David; Schwoebel, Paul

    2013-09-17

    An integrated field emission array for ion desorption includes an electrically conductive substrate; a dielectric layer lying over the electrically conductive substrate comprising a plurality of laterally separated cavities extending through the dielectric layer; a like plurality of conically-shaped emitter tips on posts, each emitter tip/post disposed concentrically within a laterally separated cavity and electrically contacting the substrate; and a gate electrode structure lying over the dielectric layer, including a like plurality of circular gate apertures, each gate aperture disposed concentrically above an emitter tip/post to provide a like plurality of annular gate electrodes and wherein the lower edge of each annular gate electrode proximate the like emitter tip/post is rounded. Also disclosed herein are methods for fabricating an integrated field emission array.

  12. EIA - Greenhouse Gas Emissions - Table-Figure Notes and Sources

    Gasoline and Diesel Fuel Update (EIA)

    A1. Notes and Sources Tables Chapter 1: Greenhouse gas emissions overview Table 1. U.S. emissions of greenhouse gases, based on global warming potential, 1990-2009: Sources: Emissions: EIA estimates. Data in this table are revised from the data contained in the previous EIA report, Emissions of Greenhouse Gases in the United States 2008, DOE/EIA-0573(2008) (Washington, DC, December 2009). Global warming potentials: Intergovernmental Panel on Climate Change, Climate Change 2007: The Physical

  13. Secretary of Energy Memorandum on DOE Greenhouse Gas Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    including strategies for: reducing greenhouse gas emissions; using water more efficiently; promoting pollution prevention and eliminating waste; constructing high performance ...

  14. New Directions: GEIA's 2020 Vision for Better Air Emissions Information

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect New Directions: GEIA's 2020 Vision for Better Air Emissions Information Citation Details In-Document Search Title: New Directions: GEIA's 2020 Vision for Better Air Emissions Information We are witnessing a crucial change in how we quantify and understand emissions of greenhouse gases and air pollutants, with an increasing demand for science-based transparent emissions information produced by robust community efforts. Today's scientific capabilities, with

  15. Impacts of Biodiesel on Emission Control Devices | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel on Emission Control Devices Impacts of Biodiesel on Emission Control Devices Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_toops2.pdf More Documents & Publications Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies Non-Petroleum-Based Fuels: Effects on

  16. Achieving High Efficiency at 2010 Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Efficiency at 2010 Emissions Achieving High Efficiency at 2010 Emissions Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_nelson.pdf More Documents & Publications High Engine Efficiency at 2010 Emissions Heavy-Duty Truck Engine: 2007 Emissions with Excellent Fuel Economy Exhaust Energy Recovery

  17. Advanced Diesel Common Rail Injection System for Future Emission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Legislation | Department of Energy Common Rail Injection System for Future Emission Legislation Advanced Diesel Common Rail Injection System for Future Emission Legislation 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Robert Bosch GMBH Common Rail System Engineering for PC Diesel Systems PDF icon 2004_deer_busch.pdf More Documents & Publications Injection System and Engine Strategies for Advanced Emission Standards SCR Technologies for NOx Reduction Powertrain

  18. Air Quality/Emissions Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Quality/Emissions Resources Air Quality/Emissions Resources Federal agencies and certain state governments are required to acquire alternative fuel vehicles as part of the Energy Policy Act of 1992, though they are also entitled to choose a petroleum reduction path as an alternative to the mandate. Find air quality/emissions resources below. Emission-Related Information for Heavy Trucks, Buses, and Engines National Clean Diesel Campaign: Sector Programs. Back to Transportation Policies and

  19. Tritium emissions from 200 East Area Double-Shell Tanks

    SciTech Connect (OSTI)

    Bachand, D.D.

    1994-11-28

    This document evaluates the need for tritium sampling of the emissions from the 200 East Area Double Shell Tanks based on the requirements of {open_quotes}National Emission Standards for Hazardous Air Pollutants{close_quotes} (NESHAP). The NESHAP requirements are specified in 40 Code of Federal Regulation (CFR), Part 61, Subpart H; {open_quotes}National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities{close_quotes}.

  20. Relationship Between Composition and Toxicity of Engine Emission Samples |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Emission Samples Relationship Between Composition and Toxicity of Engine Emission Samples 2003 DEER Conference Presentation: Lovelace Respiratory Research Institute PDF icon 2003_deer_mauderly.pdf More Documents & Publications Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Relationship Between

  1. Relationship Between Composition and Toxicity of Engine Emissions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Emissions Relationship Between Composition and Toxicity of Engine Emissions 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Lovelace Respiratory Research Instiitute PDF icon 2004_deer_mcdonald.pdf More Documents & Publications The Effect of Changes in Diesel Exhaust Composition and After-Treatment Technology on Lung Inflammation and Resistance to Viral Infection Components Responsible for the Health Effects of Inhaled Engine Emissions

  2. Retrofit Diesel Emissions Control System Providing 50% NOxControl |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_yee.pdf More Documents & Publications Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions Control

  3. Future Diesel Engine Thermal Efficiency Improvement andn Emissions Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology | Department of Energy Diesel Engine Thermal Efficiency Improvement andn Emissions Control Technology Future Diesel Engine Thermal Efficiency Improvement andn Emissions Control Technology 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_puetz.pdf More Documents & Publications Integrated Engine and Aftertreatment Technology Roadmap for EPA 2010 Heavy-duty Emissions Regulations Model-Based Transient Calibration Optimization

  4. Evaluating Exhaust Emission Performance of Urban Buses Using Transient

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Chassis Dynamometer | Department of Energy Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: VTT Technical Research Centre of Finland PDF icon 2004_deer_erkkila.pdf More Documents & Publications Heavy Duty Vehicle In-Use Emission Performance HEAVY-DUTY TRUCK

  5. Collaborative Lubricating Oil Study on Emissions (CLOSE) Project |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy CLOSE) Project Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Extensive chemical and physical characterization performed on emissions from normal and high emitting light-, medium-, and heavy-duty vehicles to evaluate relative contributions of fuel and lubricating oil on tailpipe emissions. PDF icon deer08_lawson.pdf More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on

  6. Comparing Emissions Benefits from Regulating Heavy Vehicle Idling |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Emissions Benefits from Regulating Heavy Vehicle Idling Comparing Emissions Benefits from Regulating Heavy Vehicle Idling 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_gaines.pdf More Documents & Publications Future Diesel Engine Thermal Efficiency Improvement andn Emissions Control Technology Oil Bypass Filter and Diesel Engine Idling Wear-Rate Evaluations Diesel Trucks - Then and Now

  7. Development and Deployment of Advanced Emission Controls for the Retrofit

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Market | Department of Energy Advanced Emission Controls for the Retrofit Market Development and Deployment of Advanced Emission Controls for the Retrofit Market 2003 DEER Conference Presentation: Cleaire Advanced Emission Controls PDF icon 2003_deer_edgar.pdf More Documents & Publications Emission Control Systems and Components for Retrofit and First-Fit Applications Development and Field Demonstrations of the Low NO2 ACCRT’ System for Retrofit Applications Development and

  8. Thermal Efficiency Improvement While Meeting Emissions of 2007, 2010 and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beyond | Department of Energy Efficiency Improvement While Meeting Emissions of 2007, 2010 and Beyond Thermal Efficiency Improvement While Meeting Emissions of 2007, 2010 and Beyond 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_oladipo.pdf More Documents & Publications Model-Based Transient Calibration Optimization for Next Generation Diesel Engines Future Diesel Engine Thermal Efficiency Improvement andn Emissions Control

  9. System Simulations of Hybrid Electric Vehicles with Focus on Emissions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy System Simulations of Hybrid Electric Vehicles with Focus on Emissions System Simulations of Hybrid Electric Vehicles with Focus on Emissions Comparative simulations of hybrid electric vehicles with gasoline and diesel engines will be conducted with focus on emissions control. PDF icon deer10_gao.pdf More Documents & Publications PHEV Engine and Aftertreatment Model Development Advanced PHEV Engine Systems and Emissions Control Modeling and Analysis PHEV Engine and

  10. 2002 Diesel Engine Emissions Reduction (DEER) Conference Presentations |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2 Diesel Engine Emissions Reduction (DEER) Conference Presentations 2002 Diesel Engine Emissions Reduction (DEER) Conference Presentations August 25-29, 2002 San Diego, California The following documents are available as Adobe Acrobat PDFs. Download Adobe Reader. Session 1: Diesel Engine Emissions Reduction Strategies Session 7: Emissions-Related Technologies and Regulations Session 2: Applied Thermoelectric Generator R&D Session 8: Emerging Diesel Engine Technology

  11. 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 5 Diesel Engine Emissions Reduction (DEER) Conference Presentations 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations August 21-25, 2005 Chicago, Illinois The following documents are available as Adobe Acrobat PDFs. Download Adobe Reader. Plenary Session: A View from the Bridge Technical Session 4: Emission Control Technologies, Part 1 Technical Session 1: Advanced Combustion Technologies Part 1 Poster Session 2: Light-Duty Diesels and Emission

  12. Alternative Fuels Data Center: Petroleum and Emission Reduction Planning

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Tool Tools Printable Version Share this resource Send a link to Alternative Fuels Data Center: Petroleum and Emission Reduction Planning Tool to someone by E-mail Share Alternative Fuels Data Center: Petroleum and Emission Reduction Planning Tool on Facebook Tweet about Alternative Fuels Data Center: Petroleum and Emission Reduction Planning Tool on Twitter Bookmark Alternative Fuels Data Center: Petroleum and Emission Reduction Planning Tool on Google Bookmark Alternative Fuels Data Center:

  13. Alternative Fuels Data Center: Alternative Fuel Vehicles Lower Emissions in

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Columbus, Ohio Alternative Fuel Vehicles Lower Emissions in Columbus, Ohio to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicles Lower Emissions in Columbus, Ohio on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicles Lower Emissions in Columbus, Ohio on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicles Lower Emissions in Columbus, Ohio on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicles

  14. Grid Expansion Planning for Carbon Emissions Reduction

    SciTech Connect (OSTI)

    Bent, Russell W.; Toole, Gasper L.

    2012-07-18

    There is a need to upgrade and expand electric power transmission and generation to meet specified renewable energy targets and simultaneously minimize construction cost and carbon emissions. Some challenges are: (1) Renewable energy sources have variable production capacity; (2) Deficiency of transmission capacity at desirable renewable generation locations; (3) Need to incorporate models of operations into planning studies; and (4) Prevent undesirable operational outcomes such as negative dispatch prices or curtailment of carbon neutral generation.

  15. 2006 LANL Radionuclide Air Emissions Report

    SciTech Connect (OSTI)

    David P. Fuehne

    2007-06-30

    This report describes the impacts from emissions of radionuclides at Los Alamos National Laboratory (LANL) for calendar year 2006. This report fulfills the requirements established by the Radionuclide National Emissions Standards for Hazardous Air Pollutants (Rad-NESHAP). This report is prepared by LANL's Rad-NESHAP compliance team, part of the Environmental Protection Division. The information in this report is required under the Clean Air Act and is being reported to the U.S. Environmental Protection Agency (EPA). The highest effective dose equivalent (EDE) to an off-site member of the public was calculated using procedures specified by the EPA and described in this report. LANL's EDE was 0.47 mrem for 2006. The annual limit established by the EPA is 10 mrem per year. During calendar year 2006, LANL continuously monitored radionuclide emissions at 28 release points, or stacks. The Laboratory estimates emissions from an additional 58 release points using radionuclide usage source terms. Also, LANL uses a network of air samplers around the Laboratory perimeter to monitor ambient airborne levels of radionuclides. To provide data for dispersion modeling and dose assessment, LANL maintains and operates meteorological monitoring systems. From these measurement systems, a comprehensive evaluation is conducted to calculate the EDE for the Laboratory. The EDE is evaluated as any member of the public at any off-site location where there is a residence, school, business, or office. In 2006, this location was the Los Alamos Airport Terminal. The majority of this dose is due to ambient air sampling of plutonium emitted from 2006 clean-up activities at an environmental restoration site (73-002-99; ash pile). Doses reported to the EPA for the past 10 years are shown in Table E1.

  16. High Efficiency Low Emission Refrigeration System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Low Emission Refrigeration System 2014 Building Technologies Office Peer Review Brian Fricke, frickeba@ornl.gov Oak Ridge National Laboratory Project Summary Timeline: Start date: 1 October 2011 Planned end date: 30 September 2016 Key Milestones 1. Evaluate System Design Strategies; March 2013 2. Develop Prototype System; March 2013 3. Fabricate Prototype System; March 2014 Budget: Total DOE $ to date: $700k Total future DOE $: $1,000k Target Market/Audience: The primary market

  17. Atmospheric process evaluation of mobile source emissions

    SciTech Connect (OSTI)

    1995-07-01

    During the past two decades there has been a considerable effort in the US to develop and introduce an alternative to the use of gasoline and conventional diesel fuel for transportation. The primary motives for this effort have been twofold: energy security and improvement in air quality, most notably ozone, or smog. The anticipated improvement in air quality is associated with a decrease in the atmospheric reactivity, and sometimes a decrease in the mass emission rate, of the organic gas and NO{sub x} emissions from alternative fuels when compared to conventional transportation fuels. Quantification of these air quality impacts is a prerequisite to decisions on adopting alternative fuels. The purpose of this report is to present a critical review of the procedures and data base used to assess the impact on ambient air quality of mobile source emissions from alternative and conventional transportation fuels and to make recommendations as to how this process can be improved. Alternative transportation fuels are defined as methanol, ethanol, CNG, LPG, and reformulated gasoline. Most of the discussion centers on light-duty AFVs operating on these fuels. Other advanced transportation technologies and fuels such as hydrogen, electric vehicles, and fuel cells, will not be discussed. However, the issues raised herein can also be applied to these technologies and other classes of vehicles, such as heavy-duty diesels (HDDs). An evaluation of the overall impact of AFVs on society requires consideration of a number of complex issues. It involves the development of new vehicle technology associated with engines, fuel systems, and emission control technology; the implementation of the necessary fuel infrastructure; and an appropriate understanding of the economic, health, safety, and environmental impacts associated with the use of these fuels. This report addresses the steps necessary to properly evaluate the impact of AFVs on ozone air quality.

  18. Greenhouse Gas Emissions and Fuel Use

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gas Emissions and Fuel Use within the Natural Gas Supply Chain - Sankey Diagram Methodology James Bradbury, Zachary Clement, and Adrian Down Office of Energy Policy and Systems Analysis U.S. Department of Energy July, 2015 2 Acknowledgements The authors are grateful for excellent technical reviews and other contributions provided by several individuals. Within the Department of Energy, input was provided by Judi Greenwald, Elke Hodson and Diana Bauer. External reviewers included the

  19. Nanocatalysts for Diesel Engine Emissions Remediation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanocatalysts for Diesel Engine Emissions Remediation Zeolite-Based Nanocatalysts Offer Enhanced Catalyst Performance and Durability Each year, the United States consumes a large volume of petroleum fuel, with more than half of crude oil imported from foreign sources. Diesel engines, which are approximately 30 percent more fuel effcient than gasoline engines, provide one pathway for reducing dependence on imported oil and improving overall energy effciency. The use of improved diesel engines can

  20. Research Challenge 5: Enhanced Spontaneous Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5: Enhanced Spontaneous Emission - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  1. Research Challenge 6: Beyond Spontaneous Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6: Beyond Spontaneous Emission - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  2. Emissions Modeling: GREET Life Cycle Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Modeling: GREET Life Cycle Analysis Michael Wang, Amgad Elgowainy, Jeongwoo Han Argonne National Laboratory The 2014 DOE Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting Washington, DC June 18, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information Project ID: van002 Project Overview  Start: Oct. 1993  End: not applicable (ongoing annual allocation  % complete: 70% (for FY14)  Indicators and

  3. Controlling NOx emission from industrial sources

    SciTech Connect (OSTI)

    Srivastava, R.K.; Nueffer, W.; Grano, D.; Khan, S.; Staudt, J.E.; Jozewicz, W.

    2005-07-01

    A number of regulatory actions focused on reducing NOx emissions from stationary combustion sources have been taken in the United States in the last decade. These actions include the Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, and the NOx SIP Call rulemakings. In addition to these regulations, the recent Interstate Air Quality Rulemaking proposal and other bills in the Congress are focusing on additional reductions of NOx. Industrial combustion sources accounted for about 18016 of NOx emissions in the United States in 2000 and constituted the second largest emitting source category within stationary sources, only behind electric utility sources. Based on these data, reduction of NOx emissions from industrial combustion sources is an important consideration in efforts undertaken to address the environmental concerns associated with NOx. This paper discusses primary and secondary NOx control technologies applicable to various major categories of industrial sources. The sources considered in this paper include large boilers, furnaces and fired heaters, combustion turbines, large IC engines, and cement kilns. For each source category considered in this paper, primary NOx controls are discussed first, followed by a discussion of secondary NOx controls.

  4. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  5. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  6. Trading permanent and temporary carbon emissions credits

    SciTech Connect (OSTI)

    Marland, Gregg; Marland, Eric

    2009-08-01

    In this issue of Climatic Change, Van Kooten (2009) addresses an issue that has bedeviled negotiators since the drafting stage of the Kyoto Protocol. If we accept that increasing withdrawals of carbon dioxide from the atmpshere has the same net impact on the climate system as reducing emissions of carbon dioxide to the atmosphere, how do we design a system that allows trading of one for the other? As van Kooten expresses the challenge: 'The problem is that emissions reduction and carbon sequestration, while opposite sides of the same coin in some sense, are not directly comparable, thereby inhibiting their trade in carbon markets.' He explains: 'The difficulty centers on the length of time that mitigation strategies without CO{sub 2} from entering the atmosphere - the duration problem.' While reducing emissions of CO{sub 2} represents an essentially permanent benefit for the atmosphere, capturing CO{sub 2} that has been produced (whether capture is from the atmosphere or directly from, for example, the exhaust from power plants) there is the challenge of storing the carbon adn the risk that it will yet escape to the atmosphere. Permanent benefit to the atmosphere is often not assured for carbon sequestration activities. This is especially true if the carbon is taken up and stored in the biosphere - e.g. in forest trees or agricultural soils.

  7. Resonant seismic emission of subsurface objects

    SciTech Connect (OSTI)

    Korneev, Valeri A.

    2009-04-15

    Numerical modeling results and field data indicate that some contrasting subsurface objects (such as tunnels, caves, pipes, filled pits, and fluid-filled fractures) are capable of generating durable resonant oscillations after trapping seismic energy. These oscillations consist of surface types of circumferential waves that repeatedly propagate around the object. The resonant emission of such trapped energy occurs primarily in the form of shear body waves that can be detected by remotely placed receivers. Resonant emission reveals itself in the form of sharp resonant peaks for the late parts of the records, when all strong direct and primary reflected waves are gone. These peaks were observed in field data for a buried barrel filled with water, in 2D finite-difference modeling results, and in the exact canonical solution for a fluid-filled sphere. A computed animation for the diffraction of a plane wave upon a low-velocity elastic sphere confirms the generation of resonances by durable surface waves. Resonant emission has characteristic quasi-hyperbolic traveltime patterns on shot gathers. The inversion of these patterns can be performed in the frequency domain after muting the strong direct and primary scattered waves. Subsurface objects can be detected and imaged at a single resonance frequency without an accurate knowledge of source trigger time. The imaging of subsurface objects requires information about the shear velocity distribution in an embedding medium, which can be done interactively during inversion.

  8. PHEV Engine Cold Start Emissions Management | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cold Start Emissions Management PHEV Engine Cold Start Emissions Management Coordination of engine and powertrain supervisory control strategies to minimize cold start emissions PDF icon p-05_chambon.pdf More Documents & Publications PHEV Engine Control and Energy Management Strategy PHEV Engine Control and Energy Management Strategy PHEV Engine Control and Energy Management Strategy

  9. Active Diesel Emission Control Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems Active Diesel Emission Control Systems 2004 Diesel Engine Emissions Reduction (DEER) Conferencen Presentation: RYPOS Active Diesel Emission Control Systems PDF icon 2004_deer_depetrillo.pdf More Documents & Publications RYPOS Trap Field Demonstrations Part 1 RYPOS - An Actively Regenerated DPF that Demonstrates Significant NO2 Reduction RYPOS Trap Field Demonstrations Part 2

  10. Advanced Ceramic Filter For Diesel Emission Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramic Filter For Diesel Emission Control Advanced Ceramic Filter For Diesel Emission Control 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Dow Automotive PDF icon 2004_deer_mao.pdf More Documents & Publications Vehicle Evaluation of Downsized Dow ACM DPF fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate Filters Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters

  11. Update on Diesel Exhaust Emission Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Update on Diesel Exhaust Emission Control 2003 DEER Conference Presentation: Corning, Inc. PDF icon deer_2003_johnson.pdf More Documents & Publications Review of Diesel Emission Control Technology Update on Diesel Exhaust Emission Control Technology and Regulations Light Duty Diesels in the United States - Some Perspectives

  12. Electrochemical NOxSensor for Monitoring Diesel Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy NOxSensor for Monitoring Diesel Emissions Electrochemical NOxSensor for Monitoring Diesel Emissions PDF icon pm_02_glass.pdf More Documents & Publications NOxsensor development Electrochemical NOx Sensors for Monitoring Diesel Emissions NOx Sensor Development

  13. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy myth versus facts about biofuels and greenhouse gas emissions. PDF icon Biofuels & Greenhouse Gas Emissions: Myths versus Facts More Documents & Publications Microsoft Word - 47C468D4-69BA-281F40.doc Biofuels & Greenhouse Gas Emissions: Myths versus Facts

  14. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy myths versus facts of ethanol and greenhouse gas emissions. PDF icon Biofuels & Greenhouse Gas Emissions: Myths versus Facts More Documents & Publications Biofuels & Greenhouse Gas Emissions: Myths versus Facts Microsoft Word - 47C468D4-69BA-281F40.doc

  15. Technology Development for Energy Efficiency and Low Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Energy Efficiency and Low Emissions Technology Development for Energy Efficiency and Low Emissions 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_jwall.pdf More Documents & Publications A View from the Bridge Aftertreatment Modeling Status, Futur Potential, and Application Issues Ten Years of Development Experience with Advanced Light Truck Diesel Engines

  16. On the impact of CO{sub 2} emission-trading on power generation emissions

    SciTech Connect (OSTI)

    Chappin, E.J.L.; Dijkema, G.P.J.

    2009-03-15

    In Europe one of the main policy instruments to meet the Kyoto reduction targets is CO{sub 2} emission-trading (CET), which was implemented as of January 2005. In this system, companies active in specific sectors must be in the possession of CO{sub 2} emission rights to an amount equal to their CO{sub 2} emission. In Europe, electricity generation accounts for one-third of CO{sub 2} emissions. Since the power generation sector has been liberalized, reregulated and privatized in the last decade, around Europe autonomous companies determine the sectors' CO{sub 2} emission. Short-term they adjust their operation, long-term they decide on (dis) investment in power generation facilities and technology selection. An agent-based model is presented to elucidate the effect of CET on the decisions of power companies in an oligopolistic market. Simulations over an extensive scenario-space show that there CET does have an impact. A long-term portfolio shift towards less-CO{sub 2} intensive power generation is observed. However, the effect of CET is relatively small and materializes late. The absolute emissions from power generation rise under most scenarios. This corresponds to the dominant character of current capacity expansion planned in the Netherlands (50%) and in Germany (68%), where companies have announced many new coal based power plants. Coal is the most CO{sub 2} intensive option available and it seems surprising that even after the introduction of CET these capacity expansion plans indicate a preference for coal. Apparently in power generation the economic effect of CO{sub 2} emission-trading is not sufficient to outweigh the economic incentives to choose for coal.

  17. Diesel Passenger Car Technology for Low Emissions and CO2 Compliance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passenger Car Technology for Low Emissions and CO2 Compliance Diesel Passenger Car Technology for Low Emissions and CO2 Compliance Cost effective reduction of legislated emissions...

  18. Exhaust system with emissions storage device and plasma reactor

    DOE Patents [OSTI]

    Hoard, John W. (Livonia, MI)

    1998-01-01

    An exhaust system for a combustion system, comprising a storage device for collecting NO.sub.x, hydrocarbon, or particulate emissions, or mixture of these emissions, and a plasma reactor for destroying the collected emissions is described. After the emission is collected in by the storage device for a period of time, the emission is then destroyed in a non-thermal plasma generated by the plasma reactor. With respect to the direction of flow of the exhaust stream, the storage device must be located before the terminus of the plasma reactor, and it may be located wholly before, overlap with, or be contained within the plasma reactor.

  19. Discussion of ``Comparison of air emissions from waste management facilities``

    SciTech Connect (OSTI)

    1996-12-31

    The analysis of emissions from landfills is questioned. Why are the emissions estimated compared on a peak-year rather that on a life-cycle basis? The authors reply that unlike most traditional air pollutant sources, the annual emissions of landfill gas vary markedly, depending on the pace of MSW decomposition over the years. The peak-year emission rate projected over the landfill`s lifetime is what is compared to regulatory emission thresholds to determine whether Title V permitting, etc. applies.

  20. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    1996-10-01

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.