National Library of Energy BETA

Sample records for outlet separator high

  1. Determination of the thermodynamic performance of a bottom outlet cyclone steam-water separator for geothermal use 

    E-Print Network [OSTI]

    Chappell, Mark Andrew

    1979-01-01

    and calibration of instrumentation, detailed experimental procedure, significant equations, and a discussion of a throttling- separating calorimeter. BACKGROUND This section provides a brief description of a geothermal BOC steam-water separator and its...DETERMINATION OF THE THERMODYNAMIC PERFORMANCE OF A BOTTOM OUTLET CYCLONE STEAN-MATER SEPARATOR FOR GEOTHERMAL USE A Thesis by Mark Andrew Chappell Submitted to the Graduate College of Texas AEM University in partial fulfillment...

  2. Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes

    SciTech Connect (OSTI)

    Lee O. Nelson

    2011-04-01

    This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

  3. Reactor User Interface Technology Development Roadmaps for a High Temperature Gas-Cooled Reactor Outlet Temperature of 750 degrees C

    SciTech Connect (OSTI)

    Ian Mckirdy

    2010-12-01

    This report evaluates the technology readiness of the interface components that are required to transfer high-temperature heat from a High Temperature Gas-Cooled Reactor (HTGR) to selected industrial applications. This report assumes that the HTGR operates at a reactor outlet temperature of 750°C and provides electricity and/or process heat at 700°C to conventional process applications, including the production of hydrogen.

  4. Pseudo-stationary separation materials for highly parallel separations.

    SciTech Connect (OSTI)

    Singh, Anup K.; Palmer, Christopher

    2005-05-01

    Goal of this study was to develop and characterize novel polymeric materials as pseudostationary phases in electrokinetic chromatography. Fundamental studies have characterized the chromatographic selectivity of the materials as a function of chemical structure and molecular conformation. The selectivities of the polymers has been studied extensively, resulting in a large body of fundamental knowledge regarding the performance and selectivity of polymeric pseudostationary phases. Two polymers have also been used for amino acid and peptide separations, and with laser induced fluorescence detection. The polymers performed well for the separation of derivatized amino acids, and provided some significant differences in selectivity relative to a commonly used micellar pseudostationary phase. The polymers did not perform well for peptide separations. The polymers were compatible with laser induced fluorescence detection, indicating that they should also be compatible with chip-based separations.

  5. Polymer Separators for High Power, High Efficiency Microbial Fuel Cells

    E-Print Network [OSTI]

    1 Polymer Separators for High Power, High Efficiency Microbial Fuel Cells Guang Chen, Bin) was dissolved in 23 g H2O at 90 °C to prepare ~8 wt% transparent viscous polymer solution. To this solution in the water-swollen membranes. MFC reactor construction Anodes were composed of ammonia-treated carbon brushes

  6. High speed flow cytometric separation of viable cells

    DOE Patents [OSTI]

    Sasaki, Dennis T. (Mountain View, CA); Van den Engh, Gerrit J. (Seattle, WA); Buckie, Anne-Marie (Margate, GB)

    1995-01-01

    Hematopoietic cell populations are separated to provide cell sets and subsets as viable cells with high purity and high yields, based on the number of original cells present in the mixture. High-speed flow cytometry is employed using light characteristics of the cells to separate the cells, where high flow speeds are used to reduce the sorting time.

  7. LALP-06-043 MATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHTMATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHT High temperature separation membranes

    E-Print Network [OSTI]

    membrane in a synthesis gas separation requires a membrane that is thermally, chemically, and mechanically MATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHTMATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHT High temperature separation membranes for hydrogen purification and carbon capture K.A. Berchtold, polymer-based membrane separations are less energy intensive, requiring no phase change in the process

  8. Coupling RELAP5-3D and Fluent to analyze a Very High Temperature Reactor (VHTR) outlet plenum 

    E-Print Network [OSTI]

    Anderson, Nolan Alan

    2006-10-30

    The Very High Temperature Reactor (VHTR) system behavior should be predicted during normal operating conditions and during transient conditions. To predict the VHTR system behavior there is an urgent need for development, ...

  9. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  10. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye (Newton, MA)

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  11. Screen bowl centrifuge: a high-efficiency particle size separator

    SciTech Connect (OSTI)

    Mohanty, M.K.; Zhang, B.; Khanna, N.; Palit, A.; Dube, B.

    2008-05-15

    Over the years, screen bowl centrifuges have been widely used for dewatering fine coal in coal preparation plants in the United States and elsewhere. It is generally recognized in the engineering and scientific communities that screen bowl centrifuges provide some degree of particle size separation while dewatering fine coal in a common application. However, the extent of differential partitioning of coarse and fine particles achievable by a screen bowl centrifuge has not been systematically studied in the past. The present investigation was aimed at conducting a parametric study using a statistically designed experimental program to better understand and optimize the size classification performance of a screen bowl centrifuge. A continuously operating screen bowl centrifuge having a bowl diameter of 0.5 m was used for this study at the Illinois Coal Development Park. Three key operating parameters, i.e., feed flow rate, feed solid content and pool depth, were varied to conduct a total of 17 experiments using a three-level factorial test matrix. Some of the best size separation performances achieved in this study may be described as having an imperfection value of 0.13 at an effective separation size (d(50c)) of 38 mu m and an imperfection value of 0.27 at an effective separation size (d(50c)) of 2.8 mu m. Due to an effective separation of ultrafine high ash materials, the ash content of the screen bowl feed was reduced from 22.3% to a minimum of 8.84% with a combustible recovery of 84.1% and an ash rejection of 71.6%. A higher combustible recovery of 92.1% was achieved at a product ash content of 12.5% with a d(50c) of 2.8 mu m and imperfection of 0.27.

  12. Metal-Organic Frameworks for Highly Selective Separations

    SciTech Connect (OSTI)

    Omar M. Yaghi

    2009-09-28

    This grant was focused on the study of metal-organic frameworks with these specific objectives. (1) To examine the use of MOFs with well-defined open metal sites for binding of gases and small organics. (2) To develop a strategy for producing MOFs that combine large pore size with high surface area for their use in gas adsorption and separation of polycyclic organic compounds. (3) To functionalize MOFs for the storage of inert gases such as methane. A brief outline of our progress towards these objectives is presented here as it forms part of the basis for the ideas to be developed under the present proposal.

  13. High Efficiency Solar Power via Separated Photo and Voltaic Pathways

    SciTech Connect (OSTI)

    Michael J. Naughton

    2009-02-17

    This project demonstrates a novel nanostructured solar cell architecture capable of achieving high efficiency levels that is relatively simple and inexpensive to manufacture. The high efficiency will be achieved by the novel structure that separates the path of the photons from the path of the generated charge carriers. In this way, the photon path can be long for maximum light absorption, while the path for carriers can be short for maximum electronic energy harvesting. The combination of maximum light absorption coupled with maximum carrier harvesting is the basis for the expected high efficiency. The project will develop high efficiency solar cell prototypes utilizing this unique nanostructured architecture. The project addresses the fundamental limitation inherent in all current solar cell designs, and which opens a pathway to development for high efficiency solar cells at low cost. Realizing this goal will result in a levelized cost of electricity in the range of 10˘/kWh, which would achieve the long-sought goal of making photovoltaic electricity cost competitive with fossil-fuel generated electricity without any governmental subsidies. This breakthrough would spur the already rapid growth in the photovoltaic industry to an explosive pace, with significant, widespread benefit to the national economy and the nation’s energy security. The initial target of the program is to develop single-junction solar cells using ultrathin amorphous silicon with the performance approaching that of single crystal silicon cells.

  14. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  15. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  16. Intelligent electrical outlet for collective load control

    DOE Patents [OSTI]

    Lentine, Anthony L.; Ford, Justin R.; Spires, Shannon V.; Goldsmith, Steven Y.

    2015-10-27

    Various technologies described herein pertain to an electrical outlet that autonomously manages loads in a microgrid. The electrical outlet can provide autonomous load control in response to variations in electrical power generation supply in the microgrid. The electrical outlet includes a receptacle, a sensor operably coupled to the receptacle, and an actuator configured to selectively actuate the receptacle. The sensor measures electrical parameters at the receptacle. Further, a processor autonomously controls the actuator based at least in part on the electrical parameters measured at the receptacle, electrical parameters from one or more disparate electrical outlets in the microgrid, and a supply of generated electric power in the microgrid at a given time.

  17. Intelligent electrical outlet for collective load control

    DOE Patents [OSTI]

    Lentine, Anthony L; Ford, Justin R; Spires, Shannon V; Goldsmith, Steven Y

    2015-11-05

    Various technologies described herein pertain to an electrical outlet that autonomously manages loads in a microgrid. The electrical outlet can provide autonomous load control in response to variations in electrical power generation supply in the microgrid. The electrical outlet includes a receptacle, a sensor operably coupled to the receptacle, and an actuator configured to selectively actuate the receptacle. The sensor measures electrical parameters at the receptacle. Further, a processor autonomously controls the actuator based at least in part on the electrical parameters measured at the receptacle, electrical parameters from one or more disparate electrical outlets in the microgrid, and a supply of generated electric power in the microgrid at a given time.

  18. Amorphous Alloy Membranes for High Temperature Hydrogen Separation

    SciTech Connect (OSTI)

    Coulter, K

    2013-09-30

    At the beginning of this project, thin film amorphous alloy membranes were considered a nascent but promising new technology for industrial-scale hydrogen gas separations from coal- derived syngas. This project used a combination of theoretical modeling, advanced physical vapor deposition fabricating, and laboratory and gasifier testing to develop amorphous alloy membranes that had the potential to meet Department of Energy (DOE) targets in the testing strategies outlined in the NETL Membrane Test Protocol. The project is complete with Southwest Research Institute® (SwRI®), Georgia Institute of Technology (GT), and Western Research Institute (WRI) having all operated independently and concurrently. GT studied the hydrogen transport properties of several amorphous alloys and found that ZrCu and ZrCuTi were the most promising candidates. GT also evaluated the hydrogen transport properties of V, Nb and Ta membranes coated with different transition-metal carbides (TMCs) (TM = Ti, Hf, Zr) catalytic layers by employing first-principles calculations together with statistical mechanics methods and determined that TiC was the most promising material to provide catalytic hydrogen dissociation. SwRI developed magnetron coating techniques to deposit a range of amorphous alloys onto both porous discs and tubular substrates. Unfortunately none of the amorphous alloys could be deposited without pinhole defects that undermined the selectivity of the membranes. WRI tested the thermal properties of the ZrCu and ZrNi alloys and found that under reducing environments the upper temperature limit of operation without recrystallization is ~250 °C. There were four publications generated from this project with two additional manuscripts in progress and six presentations were made at national and international technical conferences. The combination of the pinhole defects and the lack of high temperature stability make the theoretically identified most promising candidate amorphous alloys unsuitable for application as hydrogen separation membranes in coal fire systems.

  19. The role of high frequencies in convolutive blind source separation of speech signals

    E-Print Network [OSTI]

    Plumbley, Mark

    The role of high frequencies in convolutive blind source separation of speech signals Maria G load of FD-BSS algorithms, we consider here the role of high frequencies in source separation of speech sig- nals. We show that high frequencies are not as important as low frequencies, This work was funded

  20. Soft inertial microfluidics for high throughput separation of bacteria from human blood cells

    E-Print Network [OSTI]

    Wu, Zhigang

    2009-01-01

    Soft inertial microfluidics for high throughput separation1 Introduction Microfluidics has gained significant advancesof mammalian cells using microfluidics 3,4 , there have been

  1. Metal halogen battery system with multiple outlet nozzle for hydrate

    DOE Patents [OSTI]

    Bjorkman, Jr., Harry K. (Birmingham, MI)

    1983-06-21

    A metal halogen battery system, including at least one cell having a positive electrode and a negative electrode contacted by aqueous electrolyte containing the material of said metal and halogen, store means whereby halogen hydrate is formed and stored as part of an aqueous material, means for circulating electrolyte through the cell and to the store means, and conduit means for transmitting halogen gas formed in the cell to a hydrate former whereby the hydrate is formed in association with the store means, said store means being constructed in the form of a container which includes a filter means, said filter means being inoperative to separate the hydrate formed from the electrolyte, said system having, a hydrate former pump means associated with the store means and being operative to intermix halogen gas with aqueous electrolyte to form halogen hydrate, said hydrate former means including, multiple outlet nozzle means connected with the outlet side of said pump means and being operative to minimize plugging, said nozzle means being comprised of at least one divider means which is generally perpendicular to the rotational axes of gears within the pump means, said divider means acting to divide the flow from the pump means into multiple outlet flow paths.

  2. Report on Separate Disposal of Defense High- Level Radioactive Waste

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct.7, 2015Verizon and VerizonCells: S. DEPARTMENTon Separate

  3. Noise Brush: Interactive High Quality Image-Noise Separation Chi-Keung Tang

    E-Print Network [OSTI]

    Wang, Jue

    Noise Brush: Interactive High Quality Image-Noise Separation Jia Chen Chi-Keung Tang The Hong) and a noise layer (bottom) (this example is produced by Noiseware [Imagenomic Inc. 2008]), our system provides the user with a set of easy interactive control to achieve high quality image-noise separation shown in (c

  4. Automatic Identification and Truncation of Boundary Outlets in...

    Office of Scientific and Technical Information (OSTI)

    MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE; ALGORITHMS; IMAGE PROCESSING; LUNGS; MESH GENERATION; AUTOMATION; ARTERIES; CALCULATION METHODS medical imaging; outlets;...

  5. Ion current detector for high pressure ion sources for monitoring separations

    DOE Patents [OSTI]

    Smith, R.D.; Wahl, J.H.; Hofstadler, S.A.

    1996-08-13

    The present invention relates generally to any application involving the monitoring of signal arising from ions produced by electrospray or other high pressure (>100 torr) ion sources. The present invention relates specifically to an apparatus and method for the detection of ions emitted from a capillary electrophoresis (CE) system, liquid chromatography, or other small-scale separation methods. And further, the invention provides a very simple diagnostic as to the quality of the separation and the operation of an electrospray source. 7 figs.

  6. High Temperature Polybenzimidazole Hollow Fiber Membranes for Hydrogen Separation and Carbon Dioxide Capture from Synthesis Gas

    SciTech Connect (OSTI)

    Singh, Rajinder P.; Dahe, Ganpat J.; Dudeck, Kevin W.; Welch, Cynthia F.; Berchtold, Kathryn A.

    2014-12-31

    Sustainable reliance on hydrocarbon feedstocks for energy generation requires CO? separation technology development for energy efficient carbon capture from industrial mixed gas streams. High temperature H? selective glassy polymer membranes are an attractive option for energy efficient H?/CO? separations in advanced power production schemes with integrated carbon capture. They enable high overall process efficiencies by providing energy efficient CO? separations at process relevant operating conditions and correspondingly, minimized parasitic energy losses. Polybenzimidazole (PBI)-based materials have demonstrated commercially attractive H?/CO? separation characteristics and exceptional tolerance to hydrocarbon fuel derived synthesis (syngas) gas operating conditions and chemical environments. To realize a commercially attractive carbon capture technology based on these PBI materials, development of high performance, robust PBI hollow fiber membranes (HFMs) is required. In this work, we discuss outcomes of our recent efforts to demonstrate and optimize the fabrication and performance of PBI HFMs for use in pre-combustion carbon capture schemes. These efforts have resulted in PBI HFMs with commercially attractive fabrication protocols, defect minimized structures, and commercially attractive permselectivity characteristics at IGCC syngas process relevant conditions. The H?/CO? separation performance of these PBI HFMs presented in this document regarding realistic process conditions is greater than that of any other polymeric system reported to-date.

  7. High Temperature Polybenzimidazole Hollow Fiber Membranes for Hydrogen Separation and Carbon Dioxide Capture from Synthesis Gas

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, Rajinder P.; Dahe, Ganpat J.; Dudeck, Kevin W.; Welch, Cynthia F.; Berchtold, Kathryn A.

    2014-12-31

    Sustainable reliance on hydrocarbon feedstocks for energy generation requires CO? separation technology development for energy efficient carbon capture from industrial mixed gas streams. High temperature H? selective glassy polymer membranes are an attractive option for energy efficient H?/CO? separations in advanced power production schemes with integrated carbon capture. They enable high overall process efficiencies by providing energy efficient CO? separations at process relevant operating conditions and correspondingly, minimized parasitic energy losses. Polybenzimidazole (PBI)-based materials have demonstrated commercially attractive H?/CO? separation characteristics and exceptional tolerance to hydrocarbon fuel derived synthesis (syngas) gas operating conditions and chemical environments. To realize a commerciallymore »attractive carbon capture technology based on these PBI materials, development of high performance, robust PBI hollow fiber membranes (HFMs) is required. In this work, we discuss outcomes of our recent efforts to demonstrate and optimize the fabrication and performance of PBI HFMs for use in pre-combustion carbon capture schemes. These efforts have resulted in PBI HFMs with commercially attractive fabrication protocols, defect minimized structures, and commercially attractive permselectivity characteristics at IGCC syngas process relevant conditions. The H?/CO? separation performance of these PBI HFMs presented in this document regarding realistic process conditions is greater than that of any other polymeric system reported to-date.« less

  8. Highly efficient separation of carbon dioxide by a metal-organic framework replete with

    E-Print Network [OSTI]

    Yaghi, Omar M.

    media. carbon dioxide capture dynamic adsorption reticular chemistry Selective removal of CO2 fromHighly efficient separation of carbon dioxide by a metal-organic framework replete with open metal capture of CO2, which is essential for natural gas purifi- cation and CO2 sequestration, has been reported

  9. High-Throughput Genetic Analysis and Combinatorial Chiral Separations Based on Capillary Electrophoresis

    SciTech Connect (OSTI)

    Wenwan Zhong

    2003-08-05

    Capillary electrophoresis (CE) offers many advantages over conventional analytical methods, such as speed, simplicity, high resolution, low cost, and small sample consumption, especially for the separation of enantiomers. However, chiral method developments still can be time consuming and tedious. They designed a comprehensive enantioseparation protocol employing neutral and sulfated cyclodextrins as chiral selectors for common basic, neutral, and acidic compounds with a 96-capillary array system. By using only four judiciously chosen separation buffers, successful enantioseparations were achieved for 49 out of 54 test compounds spanning a large variety of pKs and structures. Therefore, unknown compounds can be screened in this manner to identify optimal enantioselective conditions in just one rn. In addition to superior separation efficiency for small molecules, CE is also the most powerful technique for DNA separations. Using the same multiplexed capillary system with UV absorption detection, the sequence of a short DNA template can be acquired without any dye-labels. Two internal standards were utilized to adjust the migration time variations among capillaries, so that the four electropherograms for the A, T, C, G Sanger reactions can be aligned and base calling can be completed with a high level of confidence. the CE separation of DNA can be applied to study differential gene expression as well. Combined with pattern recognition techniques, small variations among electropherograms obtained by the separation of cDNA fragments produced from the total RNA samples of different human tissues can be revealed. These variations reflect the differences in total RNA expression among tissues. Thus, this Ce-based approach can serve as an alternative to the DNA array techniques in gene expression analysis.

  10. New High Performance Magnet Structures for Bead Based MolecularSeparation

    SciTech Connect (OSTI)

    Humphries, David

    2005-06-01

    New High Performance Magnet Structures for Bead Based Molecular Separation David Humphries Lawrence Berkeley National Laboratory, D.O.E. Joint Genome Institute Abstract High performance Hybrid magnetic separation technology is under continuing development at the D.O.E. Joint Genome Institute and Lawrence Berkeley National Laboratory for general laboratory and high throughput automated applications. This technology has broad applicability for molecular separation in genomics, proteomics and other areas. It s applicability ranges from large and small scale microtiter plate and flow separation processes to single molecule DNA manipulation. It is currently an enabling purification technology for very high throughput production sequencing at the D.O.E. Joint Genome Institute. This technology incorporates hybrid magnetic structures that combine linear permanent magnet material and ferromagnetic material to produce significantly higher fields and gradients than those of currently available commercial devices. These structures incorporate ferromagnetic poles that can be easily shaped to produce complex field distributions for specialized applications. The higher maximum fields and strong gradients of the hybrid structures result in greater holding forces on magnetized targets that are being processed as well as faster extraction. Current development versions of these magnet plates have exhibited fields in excess of 1.0 tesla and gradients approaching 1000.0 tesla/meter. Second generation Hybrid magnet plates have now been developed for both 384 and 96-well applications. This technology is currently being made available to industry through the Tech Transfer Department at Lawrence Berkeley National Laboratory. This work was performed under the auspices of the US Department of Energy's Office of Science, Biological and Environmental Research Program and the by the University of California, Lawrence Livermore National Laboratory under Contract No. W-7405-Eng-48, Lawrence Berkeley National Laboratory under contract No. DE-AC03-6SF00098 and Los Alamos National Laboratory under contract No. W-7405-ENG-36.

  11. Mass balance of Vatnajokull outlet glaciers reconstructed back to 1958

    E-Print Network [OSTI]

    Rasmussen, L.A.

    Mass balance of Vatnaj¨okull outlet glaciers reconstructed back to 1958 L. A. Rasmussen Department seasonal components of mass balance of five Vatnaj¨okull outlet glaciers. Over the period of observations of mass balance between 1991 and 2001, it had percentage r2 rang- ing from 41 to 93 for winter balance bw

  12. Soft inertial microfluidics for high throughput separation of bacteria from human blood cells

    SciTech Connect (OSTI)

    Wu, Zhigang; Willing, Ben; Bjerketorp, Joakim; Jansson, Janet K.; Hjort, Klas

    2009-01-05

    We developed a new approach to separate bacteria from human blood cells based on soft inertial force induced migration with flow defined curved and focused sample flow inside a microfluidic device. This approach relies on a combination of an asymmetrical sheath flow and proper channel geometry to generate a soft inertial force on the sample fluid in the curved and focused sample flow segment to deflect larger particles away while the smaller ones are kept on or near the original flow streamline. The curved and focused sample flow and inertial effect were visualized and verified using a fluorescent dye primed in the device. First the particle behavior was studied in detail using 9.9 and 1.0 {micro}m particles with a polymer-based prototype. The prototype device is compact with an active size of 3 mm{sup 2}. The soft inertial effect and deflection distance were proportional to the fluid Reynolds number (Re) and particle Reynolds number (Re{sub p}), respectively. We successfully demonstrated separation of bacteria (Escherichia coli) from human red blood cells at high cell concentrations (above 10{sup 8}/mL), using a sample flow rate of up to 18 {micro}L/min. This resulted in at least a 300-fold enrichment of bacteria at a wide range of flow rates with a controlled flow spreading. The separated cells were proven to be viable. Proteins from fractions before and after cell separation were analyzed by gel electrophoresis and staining to verify the removal of red blood cell proteins from the bacterial cell fraction. This novel microfluidic process is robust, reproducible, simple to perform, and has a high throughput compared to other cell sorting systems. Microfluidic systems based on these principles could easily be manufactured for clinical laboratory and biomedical applications.

  13. Correlations of Polyimides and Blended Polyimides for High Temperature Gas Separations

    SciTech Connect (OSTI)

    John R. Klaehn; Christopher J. Orme; Thomas A. Luther; Eric S. Peterson; Jagoda M. Urban-Klaehn

    2002-03-01

    High performance polymers are of interest for high temperature gas separations, especially for the sequestration of carbon dioxide. A new family of high performance imide polymers has been identified as a successful membrane capture material. VTEC polyimides possess desired thermal properties (up to 500 °C) along with being robust and flexible even after multiple thermal cycles (up to 400 °C). Polyimides (PI) are excellent materials for high selectivity for smaller kinetic diameter gases such as H2 and CO2; however, they have low fluxes. We blended small amounts of different polymers with VTEC polyimide, which changes the fluxes. Another critical problem when working with glassy polymers is their moisture content. It has been found that water entrapped within the polymer matrix (left over from the solvent, or physisorbed) can also cause the polymer to change dramatically. Additionally presence of molecular water in the polymer’s void volume has been validated through Positron Annihilation Lifetime (PAL) spectroscopy. In this presentation, polymer characterization and gas-separation testing results will be discussed.

  14. Highly concentrated nebular noble gases in porous nanocarbon separates from the Saratov (L4) meteorite

    SciTech Connect (OSTI)

    Amari, Sachiko; Matsuda, Jun-ichi; Stroud, Rhonda M.; Chisholm, Matthew F.

    2013-11-20

    The majority of heavy noble gases (Ar, Kr, and Xe) in primitive meteorites are stored in a poorly understood phase called Q. Although Q is thought to be carbonaceous, the full identity of the phase has remained elusive for almost four decades. In order to better characterize phase Q and, in turn, the early solar nebula, we separated carbon-rich fractions from the Saratov (L4) meteorite. We chose this meteorite because Q is most resistant in thermal alteration among carbonaceous noble gas carriers in meteorites and we hoped that, in this highly metamorphosed meteorite, Q would be present but not diamond: these two phases are very difficult to separate from each other. One of the fractions, AJ, has the highest {sup 132}Xe concentration of 2.1 × 10{sup –6} cm{sup 3} STP g{sup –1}, exceeding any Q-rich fractions that have yet been analyzed. Transmission electron microscopy studies of the fraction AJ and a less Q-rich fraction AI indicate that they both are primarily porous carbon that consists of domains with short-range graphene orders, with variable packing in three dimensions, but no long-range graphitic order. The relative abundance of Xe and C atoms (6:10{sup 9}) in the separates indicates that individual noble gas atoms are associated with only a minor component of the porous carbon, possibly one or more specific arrangements of the nanoparticulate graphene.

  15. Metal-organic and zeolite imidazolate frameworks (MOFs and ZIFs) for highly selective separations

    SciTech Connect (OSTI)

    Omar M. Yaghi

    2012-09-17

    Metal-organic and zeolite imidazolate frameworks (MOFs and ZIFs) have been investigated for the realization as separation media with high selectivity. These structures are held together with strong bonds, making them architecturally, chemically, and thermally stable. Therefore, employing well designed building units, it is possible to discover promising materials for gas and vapor separation. This grant was focused on the study of MOFs and ZIFs with these specific objectives: (i) to develop a strategy for producing MOFs and ZIFs that combine high surface areas with active sites for their use in gas adsorption and separation of small organic compounds, (ii) to introduce active sites in the framework by a post-synthetic modification and metalation of MOFs and ZIFs, and (iii) to design and synthesize MOFs with extremely high surface areas and large pore volumes to accommodate large amounts of guest molecules. By the systematic study, this effort demonstrated how to introduce active functional groups in the frameworks, and this is also the origin of a new strategy, which is termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. One of the solutions to overcome this challenge is an isoreticular expansion of a MOF�������¢����������������s structure. With triangular organic linker and square building units, we demonstrated that MOF-399 has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and it has the highest porosity (94%) and lowest density (0.126 g cm-3) of any MOF reported to date. MOFs are not just low density materials; the guest-free form of MOF-210 demonstrates an ultrahigh porosity, whose BET surface area was estimated to be 6240 m2 g-1 by N2 adsorption measurements.

  16. Experimental Demonstration of Advanced Palladium Membrane Separators for Central High Purity Hydrogen Production

    SciTech Connect (OSTI)

    Sean Emerson; Neal Magdefrau; Susanne Opalka; Ying She; Catherine Thibaud-Erkey; Thoman Vanderspurt; Rhonda Willigan

    2010-06-30

    The overall objectives for this project were to: (1) confirm the high stability and resistance of a PdCu trimetallic alloy to carbon and carbide formation and, in addition, resistance to sulfur, halides, and ammonia; (2) develop a sulfur, halide, and ammonia resistant alloy membrane with a projected hydrogen permeance of 25 m{sup 3}m{sup -2}atm{sup -0.5}h{sup -1} at 400 C and capable of operating at pressures of 12.1 MPa ({approx}120 atm, 1750 psia); and (3) construct and experimentally validate the performance of 0.1 kg/day H{sup 2} PdCu trimetallic alloy membrane separators at feed pressures of 2 MPa (290 psia) in the presence of H{sub 2}S, NH{sub 3}, and HCl. This project successfully increased the technology readiness level of palladium-based metallic membranes for hydrogen separation from coal-biomass gasifier exhaust or similar hydrogen-containing gas streams. The reversible tolerance of palladium-copper (PdCu) alloys was demonstrated for H{sub 2}S concentrations varying from 20 ppmv up to 487 ppmv and NH{sub 3} concentrations up to 9 ppmv. In addition, atomistic modeling validated the resistance of PdCu alloys to carbon formation, irreversible sulfur corrosion, and chlorine attack. The experimental program highlighted two key issues which must be addressed as part of future experimental programs: (1) tube defects and (2) non-membrane materials of construction. Four out of five FCC PdCu separators developed leaks during the course of the experimental program because {approx}10% of the alloy tubes contained a single defect that resulted in a thin, weak point in the tube walls. These defects limited operation of the existing tubes to less than 220 psig. For commercial applications of a PdCu alloy hydrogen separator under high sulfur concentrations, it was determined that stainless steel 316 is not suitable for housing or supporting the device. Testing with sulfur concentrations of 487 {+-} 4 ppmv resulted in severe corrosion of the stainless steel components of the separators. The project identified an experimental methodology for quantifying the impact of gas contaminants on PdCu alloy membrane performance as well as an atomistic modeling approach to screen metal alloys for their resistance to irreversible sulfur corrosion. Initial mathematical descriptions of the effect of species such as CO and H{sub 2}S were developed, but require further experimental work to refine. At the end of the project, an improvement to the experimental approach for acquiring the necessary data for the permeability model was demonstrated in preliminary tests on an enhanced PdCu separator. All of the key DOE 2010 technical targets were met or exceeded except for the hydrogen flux. The highest flux observed for the project, 125 ft{sup 3}ft{sup -2}h{sup -1}, was obtained on a single tube separator with the aforementioned enhanced PdCu separator with a hydrogen feed pressure of 185 psig at 500 C.

  17. Equilibrium separation in a high pressure helium plasma and its application to the determination of temperatures

    SciTech Connect (OSTI)

    Rodero, A.; Garcia, M.C.; Gamero, A. [Universidad de Cordoba (Spain)

    1995-12-31

    The spectroscopy method based on the Boltzmann-plot of emission lines has been usually employed for measuring the excitation temperature (T{sub exc}) in high pressure plasmas. In the present work, it is shown that this method can produce great errors in the temperature determination when equilibrium separation exists. In this way, the suitability of this determination is tested comparing with other alternative methods in a high pressure helium plasma and also studying its separation from the equilibrium situation, via the absolute population measurements of atomic levels and the estimation of its atomic state distribution function (ASDF). We have made this study using a new excitation structure, the axial injection torch (Torche A Injection Axiale or T.I.A.), which produces a high power microwave plasma at atmospheric pressure. The measurements were carried out at the beginning of the flame (the highest line intensity zone) for a 300-900 W power range at 2.45 GHz and 71/min. of helium gas flow.

  18. High-Performance Palladium Based Membrane for Hydrogen Separation and Purification

    SciTech Connect (OSTI)

    Scott Hopkins

    2012-01-31

    The mission of the DOE's Fuel Cell Technologies'�Hydrogen Fuels R&D effort is to research, develop, and validate technologies for producing, storing, and delivering hydrogen in an efficient, clean, safe, reliable, and affordable manner. A key program technical milestone for hydrogen technology readiness is to produce hydrogen from diverse, domestic resources at $2.00-$3.00 per gallon of gasoline equivalent (gge) delivered, untaxed. Low-cost, high-temperature hydrogen separation membranes represent a key enabling technology for small-scale distributed hydrogen production units. Availability of such membranes with high selectivity and high permeability for hydrogen will allow their integration with hydrocarbon reforming and water gas shift reactions, potentially reducing the cost of hydrogen produced. Pd-metal-based dense membranes are known for their excellent hydrogen selectivity and permeability characteristics, however, utilization of these membranes has so far been limited to small scale niche markets for hydrogen purification primarily due to the relatively high cost of Pd-alloy tubes compared to pressure swing adsorption (PSA) units. This project was aimed at development of thin-film Pd-alloy membranes deposited on Pall Corporation's DOE-based AccuSep® porous metal tube substrates to form a composite hydrogen separation membrane for these applications. Pall's composite membrane development addressed the typical limitations of composite structures by developing robust membranes capable of withstanding thermal and mechanical stresses resulting from high temperature (400C), high pressure (400 psi steam methane reformer and 1000 psi coal) operations and thermal cycling involved in conventional hydrogen production. In addition, the Pd-alloy membrane composition was optimized to be able to offer the most stability in the typical synthesis gas environments produced by reforming of natural gas and bio-derived liquid fuels (BILI) validating the technical effectiveness and economic feasibility of the technology demonstrated. Results from this research added technology and product design information that offers the potential to significantly advance the commercial viability of hydrogen production.

  19. Low-rank separated representation surrogates of high-dimensional stochastic functions: Application in Bayesian inference

    SciTech Connect (OSTI)

    Validi, AbdoulAhad, E-mail: validiab@msu.edu

    2014-03-01

    This study introduces a non-intrusive approach in the context of low-rank separated representation to construct a surrogate of high-dimensional stochastic functions, e.g., PDEs/ODEs, in order to decrease the computational cost of Markov Chain Monte Carlo simulations in Bayesian inference. The surrogate model is constructed via a regularized alternative least-square regression with Tikhonov regularization using a roughening matrix computing the gradient of the solution, in conjunction with a perturbation-based error indicator to detect optimal model complexities. The model approximates a vector of a continuous solution at discrete values of a physical variable. The required number of random realizations to achieve a successful approximation linearly depends on the function dimensionality. The computational cost of the model construction is quadratic in the number of random inputs, which potentially tackles the curse of dimensionality in high-dimensional stochastic functions. Furthermore, this vector-valued separated representation-based model, in comparison to the available scalar-valued case, leads to a significant reduction in the cost of approximation by an order of magnitude equal to the vector size. The performance of the method is studied through its application to three numerical examples including a 41-dimensional elliptic PDE and a 21-dimensional cavity flow.

  20. Absence of Static Phase Separation in the High Tc Cuprate YBa2Cu3O6y J. Bobroff,1

    E-Print Network [OSTI]

    Paris-Sud 11, Université de

    Absence of Static Phase Separation in the High Tc Cuprate YBa2Cu3O6y J. Bobroff,1 H. Alloul,1 S out any large static phase separation between underdoped and optimally doped regions in contrast with the one observed by STM in Bi2212 and by NQR in LaSrCuO. This establishes that static electronic phase

  1. Separation of Highly Complex Mixtures by Two-Dimension Liquid Chromatography

    SciTech Connect (OSTI)

    Georges Guiochon

    2009-12-11

    This report summarizes the progress made on the title project during the grant period. We developed a new classification of two-dimensional separations based on the observation that separations can be made in time or in space. Thus, two-dimensional separations can be made in time×time, space×space, space×time, or time×space. The two successive separations must use two different modes of chromatography that afford uncorrelated or weakly correlated patterns of retention factors for the components of the samples analyzed. Our attention was mainly focused on the separation of protein digests, particularly, on those of the digests of myoglobin and bovine serum albumin as model systems and extremely efficient temporal separations were developed. We also designed and constructed new instruments to carry out space×space separations (True Bidimensional Chromatography, HPLC2 or spacial separations) and time×space separations (a new hybrid combination of a temporal and a spacial separation that we designed).

  2. Particle Capture Efficiency in a Multi-Wire Model for High Gradient Magnetic Separation

    E-Print Network [OSTI]

    Eisenträger, Almut; Griffiths, Ian M

    2014-01-01

    High gradient magnetic separation (HGMS) is an efficient way to remove magnetic and paramagnetic particles, such as heavy metals, from waste water. As the suspension flows through a magnetized filter mesh, high magnetic gradients around the wires attract and capture the particles, removing them from the fluid. We model such a system by considering the motion of a paramagnetic tracer particle through a periodic array of magnetized cylinders. We show that there is a critical Mason number (ratio of viscous to magnetic forces) below which the particle is captured irrespective of its initial position in the array. Above this threshold, particle capture is only partially successful and depends on the particle's entry position. We determine the relationship between the critical Mason number and the system geometry using numerical and asymptotic calculations. If a capture efficiency below 100% is sufficient, our results demonstrate how operating the HGMS system above the critical Mason number but with multiple separa...

  3. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  4. High gliding fluid power generation system with fluid component separation and multiple condensers

    SciTech Connect (OSTI)

    Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

    2014-10-14

    An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

  5. Continuous magnetic separator and process

    DOE Patents [OSTI]

    Oder, Robin R. (Export, PA); Jamison, Russell E. (Lower Burrell, PA)

    2008-04-22

    A continuous magnetic separator and process for separating a slurry comprising magnetic particles into a clarified stream and a thickened stream. The separator has a container with a slurry inlet, an overflow outlet for the discharge of the clarified slurry stream, and an underflow outlet for the discharge of a thickened slurry stream. Magnetic particles in the slurry are attracted to, and slide down, magnetic rods within the container. The slurry is thus separated into magnetic concentrate and clarified slurry. Flow control means can be used to control the ratio of the rate of magnetic concentrate to the rate of clarified slurry. Feed control means can be used to control the rate of slurry feed to the slurry inlet.

  6. Method for the separation of high impact polystyrene (HIPS) and acrylonitrile butadiene styrene (ABS) plastics

    DOE Patents [OSTI]

    Jody, Bassam J. (Chicago, IL); Arman, Bayram (Amherst, NY); Karvelas, Dimitrios E. (Downers Grove, IL); Pomykala, Jr., Joseph A. (Crest Hill, IL); Daniels, Edward J. (Oak Lawn, IL)

    1997-01-01

    An improved method is provided for separating acrylonitrile butadiene styrene (ABS) and high impact polystyrene (HIPS) plastics from each other. The ABS and HIPS plastics are shredded to provide a selected particle size. The shredded particles of the ABS and HIPS plastics are applied to a solution having a solution density in a predefined range between 1.055 gm/cm.sup.3 and 1.07 gm/cm.sup.3, a predefined surface tension in a range between 22 dynes/cm to 40 dynes/cm and a pH in the range of 1.77 and 2.05. In accordance with a feature of the invention, the novel method is provided for separating ABS and HIPS, two solid thermoplastics which have similar densities by selectively modifying the effective density of the HIPS using a binary solution with the appropriate properties, such as pH, density and surface tension, such as a solution of acetic acid and water or a quaternary solution having the appropriate density, surface tension, and pH.

  7. Extraction chromatographic separation of promethium from high active waste solutions of Purex origin

    SciTech Connect (OSTI)

    Ramanujam, A.; Achuthan, P.V.; Dhami, P.S.; Gopalakrishnan, V.; Kannan, R.; Mathur, J.N. [Bhabha Atomic Research Centre, Bombay (India)

    1995-03-01

    An extraction chromatographic procedure for the separation of {sup 147}Pm from High Active Waste solutions of Purex process has been developed. Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO) and 2-ethylhexyl-2-ethylhexylphosphonic acid (KSM-17), both sorbed separately on an inert support(chromosorb-102) have been sequentially employed for this purpose. In the CMPO column, the rare earths and the trivalent actinides are sorbed together with uranium, plutonium and traces of few other fission products. The elution of this column with 0.04 M HNO{sub 3} gives an eluate containing trivalent actinides and lanthanides. This solution, after adjusting the pH to 2.0, is used as feed for the second extraction chromatographic column based on KSM-17. All the trivalent metal ions are sorbed on the column leaving the trace impurities in the effluent. Fractional elution of the metal ions from this column is carried out with nitric acid of varying concentrations. At 0.09 M HNO{sub 3}, the pure beta emitting fraction of {sup 147}Pm has been obtained. 16 refs., 3 figs., 2 tabs.

  8. Next Generation Extractants for Cesium Separation from High-Level Waste

    SciTech Connect (OSTI)

    Moyer, Bruce A; Bazelaire, Eve; Bonnesen, Peter V; Custelcean, Radu; Delmau, Laetitia Helene; Ditto, Mary E; Engle, Nancy L; Gorbunova, Maryna; Haverlock, Tamara; Levitskaia, Tatiana G.; Bartsch, Richard A.; Surowiec, Malgorzata A.; Marquez, Manuel; Zhou, Hui

    2006-01-01

    This project seeks a fundamental understanding and major improvement in cesium separation from high-level waste by cesium-selective calixcrown extractants. Systems of particular interest involve novel solvent-extraction systems containing specific members of the calix[4]arene-crown-6 family, alcohol solvating agents, and alkylamines. Questions being addressed bear upon cesium binding strength, extraction selectivity, cesium stripping, and extractant solubility. Enhanced properties in this regard will specifically benefit applied projects funded by the USDOE Office of Environmental Management to clean up sites such as the Savannah River Site (SRS), Hanford, and the Idaho National Environmental and Engineering Laboratory. The most direct beneficiary will be the SRS Salt Processing Project, which has recently identified the Caustic-Side Solvent Extraction (CSSX) process employing a calixcrown as its preferred technology for cesium removal from SRS high-level tank waste. Disposal of high-level waste is horrendously expensive, in large part because the actual radioactive matter in underground waste tanks at various USDOE sites has been diluted over 1000-fold by ordinary inorganic chemicals. To vitrify the entire mass of the high-level waste would be prohibitively expensive. Accordingly, an urgent need has arisen for technologies to remove radionuclides such as {sup 137}Cs from the high-level waste so that the bulk of it may be diverted to cheaper low-level waste forms and cheaper storage. To address this need in part, chemical research at Oak Ridge National Laboratory (ORNL) has focused on calixcrown extractants, molecules that combine a crown ether with a calixarene. This hybrid possesses a cavity that is highly complementary for the Cs{sup +} ion vs. the Na+ ion, making it possible to cleanly separate cesium from wastes that contain 10,000- to 1,000,000-fold higher concentrations of sodium. Previous EMSP results in Project 55087 elucidated the underlying extraction equilibria in cesium nitrate extraction by the calixcrown used in the CSSX process, calix[4]arene-bis(t-octylbenzo-crown-6), designated here as BOBCalixC6 (see structure). This understanding led to key improvements in the development of the CSSX process under the EM Efficient Separations and Crosscutting Program, entailing a method to back-extract or 'strip' cesium from the calixcrown subsequent to cesium extraction from waste. Having this stripping method allowed the cesium to be concentrated in a relatively pure aqueous stream and the extractant to be regenerated for recycle. Closing the cycle then made possible the design of a process flowsheet and successful demonstration through collaboration with Argonne National Laboratory and Savannah River Technology Center under funding from the USDOE Office of Project Completion and Tanks Focus Area. Despite these successes, the CSSX process represents young technology that can benefit substantially from further fundamental inquiry. First, reversibility of the process (stripping efficiency) still presents the greatest potential for problems and the greatest potential for improvement. Second, although the calixcrown extractants for cesium are two orders of magnitude stronger than the next best simple crown ether, a minor fraction of the extractant capacity is utilized. Third, potassium competes significantly with cesium for the calixcrown binding site, an important issue in dealing with Hanford wastes having potassium concentrations as high as 1 M. Fourth, the calixcrown solubility needs to be improved. And finally, the mechanism of extraction must be understood in detail to provide the base of knowledge from which further development of the technology can be rationally made.

  9. Nanoporous, Metal Carbide, Surface Diffusion Membranes for High Temperature Hydrogen Separations

    SciTech Connect (OSTI)

    Way, J.; Wolden, Colin

    2013-09-30

    Colorado School of Mines (CSM) developed high temperature, hydrogen permeable membranes that contain no platinum group metals with the goal of separating hydrogen from gas mixtures representative of gasification of carbon feedstocks such as coal or biomass in order to meet DOE NETL 2015 hydrogen membrane performance targets. We employed a dual synthesis strategy centered on transition metal carbides. In the first approach, novel, high temperature, surface diffusion membranes based on nanoporous Mo{sub 2}C were fabricated on ceramic supports. These were produced in a two step process that consisted of molybdenum oxide deposition followed by thermal carburization. Our best Mo{sub 2}C surface diffusion membrane achieved a pure hydrogen flux of 367 SCFH/ft{sup 2} at a feed pressure of only 20 psig. The highest H{sub 2}/N{sub 2} selectivity obtained with this approach was 4.9. A transport model using “dusty gas” theory was derived to describe the hydrogen transport in the Mo{sub 2}C coated, surface diffusion membranes. The second class of membranes developed were dense metal foils of BCC metals such as vanadium coated with thin (< 60 nm) Mo{sub 2}C catalyst layers. We have fabricated a Mo{sub 2}C/V composite membrane that in pure gas testing delivered a H{sub 2} flux of 238 SCFH/ft{sup 2} at 600 °C and 100 psig, with no detectable He permeance. This exceeds the 2010 DOE Target flux. This flux is 2.8 times that of pure Pd at the same membrane thickness and test conditions and over 79% of the 2015 flux target. In mixed gas testing we achieved a permeate purity of ?99.99%, satisfying the permeate purity milestone, but the hydrogen permeance was low, ~0.2 SCFH/ft{sup 2}.psi. However, during testing of a Mo{sub 2}C coated Pd alloy membrane with DOE 1 feed gas mixture a hydrogen permeance of >2 SCFH/ft{sup 2}.psi was obtained which was stable during the entire test, meeting the permeance associated with the 2010 DOE target flux. Lastly, the Mo{sub 2}C/V composite membranes were shown to be stable for at least 168 hours = one week, including cycling at high temperature and alternating He/H{sub 2} exposure.

  10. Organic-inorganic nanocomposite membranes from highly ordered mesoporous thin films for solubility-based separations 

    E-Print Network [OSTI]

    Yoo, Suk Joon

    2009-05-15

    hydrocarbons from natural gas. Recently, nanocomposites have shown great promise as possible membrane materials for solubility-selective separations. The chemical derivatization of inorganic mesoporous substrates has been explored to synthesize organic...

  11. Highly Selective Membranes For The Separation Of Organic Vapors Using Super-Glassy Polymers

    DOE Patents [OSTI]

    Pinnau, Ingo (Palo Alto, CA); Lokhandwala, Kaaeid (Menlo Park, CA); Nguyen, Phuong (Fremont, CA); Segelke, Scott (Mountain View, CA)

    1997-11-18

    A process for separating hydrocarbon gases of low boiling point, particularly methane, ethane and ethylene, from nitrogen. The process is performed using a membrane made from a super-glassy material. The gases to be separated are mixed with a condensable gas, such as a C.sub.3+ hydrocarbon. In the presence of the condensable gas, improved selectivity for the low-boiling-point hydrocarbon gas over nitrogen is achieved.

  12. Computational identification of a metal organic framework for high selectivity membrane-based CO2/CH4 separations

    E-Print Network [OSTI]

    Nair, Sankar

    CH4/CO2 mixtures with low cost are required. Membranes offer a powerful general approachComputational identification of a metal organic framework for high selectivity membrane-based CO2 for CO2/CH4 mixtures could revolutionize this industrially important separation. We predict using

  13. Separation of americium, curium, and rare earths from high-level wastes by oxalate precipitation: experiments with synthetic waste solutions

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1980-01-01

    The separation of trivalent actinides and rare earths from other fission products in high-level nuclear wastes by oxalate precipitation followed by ion exchange (OPIX) was experimentally investigated using synthetic wastes and a small-scale, continuous-flow oxalic acid precipitation and solid-liquid separation system. Trivalent actinide and rare earth oxalates are relatively insoluble in 0.5 to 1.0 M HNO/sub 3/ whereas other fission product oxalates are not. The continuous-flow system consisted of one or two stirred-tank reactors in series for crystal growth. Oxalic acid and waste solutions were mixed in the first tank, with the product solid-liquid slurry leaving the second tank. Solid-liquid separation was tested by filters and by a gravity settler. The experiments determined the fraction of rare earths precipitated and separated from synthetic waste streams as a function of number of reactors, system temperature, oxalic acid concentration, liquid residence time in the process, power input to the stirred-tank reactors, and method of solid-liquid separation. The crystalline precipitate was characterized with respect to form, size, and chemical composition. These experiments are only the first step in converting a proposed chemical flowsheet into a process flowsheet suitable for large-scale remote operations at high activity levels.

  14. Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment

    SciTech Connect (OSTI)

    Rich Ciora; Paul KT Liu

    2012-06-27

    In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the inorganic membrane field. Further, this newly developed full scale bundle concept can be extended to other thin film inorganic membrane technology (Pd, zeolite, etc), providing a potential commercialization pathway for these membrane materials that demonstrate high potential in a variety of separation applications yet remain a laboratory 'novelty' for lack of a full scale support. Overall, the project has been highly successful and all of the project objectives have been met. We have developed the first of its kind commercial scale carbon molecular sieve membrane and demonstrated its performance in field testing under aggressive operating conditions and in the presence of chemical contaminants that would rapidly destroy alternative organic and inorganic membranes. This innovative membrane permits H{sub 2} recovery from gas streams that up until now have not been successfully treated with membrane or conventional technology. Our end user participant is currently pursuing the field demonstration of this membrane for hydrogen recovery at its refinery site.

  15. Peak picking and the assessment of separation performance in two-dimensional high performance liquid chromatography

    SciTech Connect (OSTI)

    Guiochon, Georges A; Shalliker, R. Andrew

    2010-01-01

    An algorithm was developed for 2DHPLC that automated the process of peak recognition, measuring their retention times, and then subsequently plotting the information in a two-dimensional retention plane. Following the recognition of peaks, the software then performed a series of statistical assessments of the separation performance, measuring for example, correlation between dimensions, peak capacity and the percentage of usage of the separation space. Peak recognition was achieved by interpreting the first and second derivatives of each respective one-dimensional chromatogram to determine the 1D retention times of each solute and then compiling these retention times for each respective fraction 'cut'. Due to the nature of comprehensive 2DHPLC adjacent cut fractions may contain peaks common to more than one cut fraction. The algorithm determined which components were common in adjacent cuts and subsequently calculated the peak maximum profile by interpolating the space between adjacent peaks. This algorithm was applied to the analysis of a two-dimensional separation of an apple flesh extract separated in a first dimension comprising a cyano stationary phase and an aqueous/THF mobile phase as the first dimension and a second dimension comprising C18-Hydro with an aqueous/MeOH mobile phase. A total of 187 peaks were detected.

  16. Apparatus and methods for high resolution separation of sample components on microfabricated channel devices

    DOE Patents [OSTI]

    Mathies, Richard A.; Paegel, Brian; Simpson, Peter C.; Hutt, Lester

    2005-07-05

    Sample component separation apparatus and methods are described. An exemplary sample component separation apparatus includes a separation channel having a turn portion configured to reduce band-broadening caused by passage of a sample through the turn portion. To reduce band broadening caused by passage of a sample through a turn portion, the turn portion may be constructed and arranged to have a sample transport characteristic that is different from the corresponding sample transport characteristic of a substantially straight portion of the separation channel. For example, the turn portion may be configured with an effective channel width that is smaller than the effective channel widths of the substantially straight portion of the separation channel. The actual channel width of the turn portion may be smaller than the channel widths of the substantially straight portion; the effective channel width of the turn portion may be reduced by placing one or more sample transport barriers or constrictions in the turn portion of the channel. Alternatively, the sample velocity through the turn portion may be controlled so as to reduce band broadening. For example, sample transport barriers may be disposed in the turn portion so that sample components of a given band travel through the turn portion at substantially the same effective rate, whereby the band orientation remains substantially aligned along radial directions characteristic of the turn portion. Other a sample transport characteristics, such as electrical resistance or fluid flow resistance, of the turn portion may be adapted to reduce band broadening caused by passage of the sample through the turn portion.

  17. UBC Social Ecological Economic Development Studies (SEEDS) Student Report Moving UBC Food Outlets Beyond Climate Neutral

    E-Print Network [OSTI]

    for waste and energy reduction and the need for policies to assist UBC food outlets to move beyond climateUBC Social Ecological Economic Development Studies (SEEDS) Student Report Moving UBC Food Outlets of a project/report". #12;AGSC 450 2008 Moving UBC Food Outlets Beyond Climate Neutral Group 30 Heather Allyn

  18. Case1: Outlet of the pipe without a bend and a weld Case2: Outlet of the pipe with 90/90 bend and 30 weld

    E-Print Network [OSTI]

    McDonald, Kirk

    1 #12;Case1: Outlet of the pipe without a bend and a weld Case2: Outlet of the pipe with 90°/90° bend and 30° weld 2 #12;3 Y X Z symmetry Velocity Inlet Wall Pressure Outlet Wall Normalized by Djet inlet from pipeflow study with a 30° weld out of bend plan, and with a 90°/90° bend. Mesh: 15M. #12;Hg

  19. A Rubber-Modified Thermoplastic where the Morphology Produced by Phase-Separation Induced by Polymerization Disappears at High Conversions

    E-Print Network [OSTI]

    E. R. Soule; G. E. Elicabe; R. J. J. Williams

    2013-11-21

    An unexpected experimental finding is reported where the primary morphology developed during polymerization-induced phase separation in a rubber-modified thermoplastic disappears at high conversions. This process was evidenced by light scattering (LS) and scanning electron microscopy (SEM) for a particular composition of solutions of polyisobutylene oligomers (PIB) in isobornylmethacrylate (IBoMA), during the free-radical polymerization of the monomer. The primary phase separation produced a dispersion of domains rich in PIB containing significant amounts of the monomer (IBoMA). Polymerization of the monomer in these domains occurred at high overall conversions producing the filling of dispersed domains with a PIBoMA-PIB blend. Under these conditions the final material had the appearance of a homogeneous blend. The process might be adapted to produce new types of rubber-modified thermoplastics where rubber particles are replaced by rubber-rich domains that do not exhibit definite boundaries. Keywords:

  20. Radiation and spin separation of high energy positrons by bent crystal

    SciTech Connect (OSTI)

    Bashmakov, Y.A.

    1995-09-01

    The channeling of ultrahigh energy positrons both in bent and straight crystals can serve as an effective source of hard photons. The presence in the channel of the strong inhomogeneous electrical field gives rise to a number of interesting peculiarities of the motion of the channeling particles. The radiative separation of particles depending on spin orientation with respect to the plane of motion and radiative polarization can make it possible to obtain by means of bent crystals a positron beam with a degree of polarization about 10 to 20{percent}. Because of availability of the ultrahigh energy positron beams such experiments can be carried out nowadays. {copyright} {ital 1995 American Institute of Physics.}

  1. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2001-07-31

    Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H2 separation. These membranes consist of a thin ({approx}1 mm) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H2 separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 4}0 alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

  2. Technologies for Upgrading Light Water Reactor Outlet Temperature

    SciTech Connect (OSTI)

    Daniel S. Wendt; Piyush Sabharwall; Vivek Utgikar

    2013-07-01

    Nuclear energy could potentially be utilized in hybrid energy systems to produce synthetic fuels and feedstocks from indigenous carbon sources such as coal and biomass. First generation nuclear hybrid energy system (NHES) technology will most likely be based on conventional light water reactors (LWRs). However, these LWRs provide thermal energy at temperatures of approximately 300°C, while the desired temperatures for many chemical processes are much higher. In order to realize the benefits of nuclear hybrid energy systems with the current LWR reactor fleets, selection and development of a complimentary temperature upgrading technology is necessary. This paper provides an initial assessment of technologies that may be well suited toward LWR outlet temperature upgrading for powering elevated temperature industrial and chemical processes during periods of off-peak power demand. Chemical heat transformers (CHTs) are a technology with the potential to meet LWR temperature upgrading requirements for NHESs. CHTs utilize chemical heat of reaction to change the temperature at which selected heat sources supply or consume thermal energy. CHTs could directly utilize LWR heat output without intermediate mechanical or electrical power conversion operations and the associated thermodynamic losses. CHT thermal characteristics are determined by selection of the chemical working pair and operating conditions. This paper discusses the chemical working pairs applicable to LWR outlet temperature upgrading and the CHT operating conditions required for providing process heat in NHES applications.

  3. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Bryan, Jeffrey C.; Engle, Nancy L.; Levitskaia, Tatiana G.; Sachleben, Richard A.; Bartsch, Richard A.; Talanov, Vladimir S.; Gibson, Harry W.; Jones, Jason W.

    2001-08-20

    This project seeks a fundamental understanding and major improvement in cesium separation from high-level waste by cesium-selective calixcrown extractants. Systems of particular interest involve novel solvent-extraction systems containing specific members of the calix[4]arene-crown-6 family, alcohol solvating agents, and alkylamines. Questions being addressed bear upon cesium binding strength, extraction selectivity, cesium stripping, and extractant solubility. Enhanced properties in this regard will specifically benefit applied projects funded by the USDOE Office of Environmental Management to clean up sites such as the Savannah River Site (SRS), Hanford, and the Idaho National Environmental and Engineering Laboratory. The most direct beneficiary will be the SRS Salt Processing Project, which has recently identified the Caustic-Side Solvent Extraction (CSSX) process employing a calixcrown as its preferred technology for cesium removal from SRS high-level tank waste.

  4. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Bryan, Jeffrey C.; Engle, Nancy L.; Keever, Tamara J.; Levitskaia, Tatiana G.; Sachleben, Richard A.; Bartsch, Richard A.; Talanov, Vladimir S.; Gibson, Harry W.; Jones, Jason W.; Hay, Benjamin P.

    2002-06-01

    This project seeks a fundamental understanding and major improvement in cesium separation from high-level waste by cesium-selective calixcrown extractants. Systems of particular interest involve novel solvent-extraction systems containing specific members of the calix[4]arene-crown-6 family, alcohol solvating agents, and alkylamines. Questions being addressed bear upon cesium binding strength, extraction selectivity, cesium stripping, and extractant solubility. Enhanced properties in this regard will specifically benefit applied projects funded by the USDOE Office of Environmental Management to clean up sites such as the Savannah River Site (SRS), Hanford, and the Idaho National Environmental and Engineering Laboratory. The most direct beneficiary will be the SRS Salt Processing Project, which has recently identified the Caustic-Side Solvent Extraction (CSSX) process employing a calixcrown as its preferred technology for cesium removal from SRS high-level tank waste.

  5. Preparation and characterization of composite membrane for high temperature gas separation

    SciTech Connect (OSTI)

    Ilias, S.; King, F.G.

    1998-03-26

    A new class of perm-selective inorganic membrane was developed by electroless deposition of palladium thin-film on a microporous {alpha}-alumina ceramic substrate ({phi}39 mm x 2 mm thickness, nominal pore size 150 nm and open porosity {approx} 42 %). The new membrane was characterized by Scanning Electron Micrography (SEM), Energy Dispersive X-ray Analysis (EDX) and conducting permeability experiments with hydrogen, helium, argon and carbon dioxide at temperatures from 473 K to 673 K and feed pressures from 136 kPa to 274 kPa. The results indicate that the membrane has both high permeability and selectivity for hydrogen. The hydrogen transport through the Pd-composite membrane closely followed Sievert's law. A theoretical model is presented to describe the performance of a single-stage permeation process. The model uses a unified mathematical formulation and calculation methods for two flow patterns (cocurrent and countercurrent) with two permeable components and a nonpermeable fraction in the feed and a sweep stream in the permeate. The countercurrent flow pattern is always better than the cocurrent flow pattern with respect to stage cut and membrane area. The effect of flow configuration decreases with increasing membrane selectivity or with decreasing permeate/feed ratio.

  6. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2003-01-01

    For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating procedures for fabrication of thin Pd-Cu composite membranes at any scale.

  7. FINAL SUMMARIZING REPORT on Grant DE-SC0001014 "Separation of Highly Complex Mixtures by Two-dimension Liquid Chromatography"

    SciTech Connect (OSTI)

    Guiochon, Georges

    2013-09-16

    The goal of our research was a fundamental investigation of methods available for the coupling of two separate chromatographic separations that would considerably enhance the individual separation power of each of these two separations. This gain arises from the combination of two independent retention mechanisms, one of them separating the components that coelute on the other column, making possible the separation of many more compounds in a given time. The two separation mechanisms used must be very different. This is possible because many retention mechanisms are available, using different kinds of molecular interactions, hydrophobic or hydrophilic interactions, polar interactions, hydrogen bonding, complex formation, ionic interactions, steric exclusion. Two methods can be used, allowing separations to be performed in space (spreading the bands of sample components on a plate covered with stationary phase layer) or in time (eluting the sample components through a column and detecting the bands leaving the column). Both offer a wide variety of possible combinations and were studied.

  8. Time-separated oscillatory fields for high-precision mass measurements on short-lived Al and Ca nuclides

    E-Print Network [OSTI]

    S. George; G. Audi; B. Blank; K. Blaum; M. Breitenfeldt; U. Hager; F. Herfurth; A. Herlert; A. Kellerbauer; H. -J. Kluge; M. Kretzschmar; D. Lunney; R. Savreux; S. Schwarz; L. Schweikhard; C. Yazidjian

    2008-01-17

    High-precision Penning trap mass measurements on the stable nuclide 27Al as well as on the short-lived radionuclides 26Al and 38,39Ca have been performed by use of radiofrequency excitation with time-separated oscillatory fields, i.e. Ramsey's method, as recently introduced for the excitation of the ion motion in a Penning trap, was applied. A comparison with the conventional method of a single continuous excitation demonstrates its advantage of up to ten times shorter measurements. The new mass values of 26,27Al clarify conflicting data in this specific mass region. In addition, the resulting mass values of the superallowed beta-emitter 38Ca as well as of the groundstate of the beta-emitter 26Al m confirm previous measurements and corresponding theoretical corrections of the ft-values.

  9. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bazelaire, Eve; Bonnesen, Peter V.; Bryan, Jeffrey C.; Delmau, Latitia H.; Engle, Nancy L.; Gorbunova, Maryna G.; Keever, Tamara J.; Levitskaia, Tatiana G.; Sachleben, Richard A.; Tomkins, Bruce A.

    2004-06-30

    General project objectives. This project seeks a fundamental understanding and major improvement in cesium separation from high-level waste by cesium-selective calixcrown extractants. Systems of particular interest involve novel solvent-extraction systems containing specific members of the calix[4]arene-crown-6 family, alcohol solvating agents, and alkylamines. Questions being addressed pertain to cesium binding strength, extraction selectivity, cesium stripping, and extractant solubility. Enhanced properties in this regard will specifically benefit cleanup projects funded by the USDOE Office of Environmental Management to treat and dispose of high-level radioactive wastes currently stored in underground tanks at the Savannah River Site (SRS), the Hanford site, and the Idaho National Environmental and Engineering Laboratory.1 The most direct beneficiary will be the SRS Salt Processing Project, which has recently identified the Caustic-Side Solvent Extraction (CSSX) process employing a calixcrown as its preferred technology for cesium removal from SRS high level tank waste.2 This technology owes its development in part to fundamental results obtained in this program.

  10. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation

    SciTech Connect (OSTI)

    Moyer, Bruce A; Bazelaire, Eve; Bonnesen, Peter V.; Bryan, Jeffrey C.; Delmau, Laetitia H.; Engle, Nancy L.; Gorbunova, Maryna G.; Keever, Tamara J.; Levitskaia, Tatiana G.; Sachleben, Richard A.; Tomkins, Bruce A.; Bartsch, Richard A.; Talanov, Vladimir S.; Gibson, Harry W.; Jones, Jason W.; Hay, Benjamin P.

    2003-09-01

    This project seeks a fundamental understanding and major improvement in cesium separation from high-level waste by cesium-selective calixcrown extractants. Systems of particular interest involve novel solvent-extraction systems containing specific members of the calix[4]arene-crown-6 family, alcohol solvating agents, and alkylamines. Questions being addressed pertain to cesium binding strength, extraction selectivity, cesium stripping, and extractant solubility. Enhanced properties in this regard will specifically benefit cleanup projects funded by the USDOE Office of Environmental Management to treat and dispose of high-level radioactive wastes currently stored in underground tanks at the Savannah River Site (SRS), the Hanford site, and the Idaho National Environmental and Engineering Laboratory.1 The most direct beneficiary will be the SRS Salt Processing Project, which has recently identified the Caustic-Side Solvent Extraction (CSSX) process employing a calixcrown as its preferred technology for cesium removal from SRS high-level tank waste.2 This technology owes its development in part to fundamental results obtained in this program.

  11. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation into Reusable Container Food Outlets

    E-Print Network [OSTI]

    UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation Investigation into Reusable Container Food Outlets The University of British Columbia APSC 261 ­ Technology into operating one of these as a `Bring your own container' (BYOC) outlet, in which students would not be served

  12. Origin of stratified basal ice in outlet glaciers of Vatnaj okull and O rfaj okull, Iceland

    E-Print Network [OSTI]

    Origin of stratified basal ice in outlet glaciers of Vatnaj ¨okull and O¨ rćfaj ¨okull, Iceland, Iceland. Boreas, Vol. 39, pp. 457­470. 10.1111/j.1502-3885.2009.00134.x. ISSN 0300-9483. During the period ice from warm-based outlet glaciers of Vatnaj ¨okull and O¨ rćfaj ¨okull, Iceland, and analysed them

  13. Ultracapacitor separator

    DOE Patents [OSTI]

    Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); LeBlanc, Jr., Oliver Harris (Schenectady, NY)

    2001-03-06

    An ultracapacitor includes two solid, nonporous current collectors, two porous electrodes separating the collectors, a porous separator between the electrodes and an electrolyte occupying the pores in the electrodes and separator. The electrolyte is a polar aprotic organic solvent and a salt. The porous separator comprises a wet laid cellulosic material.

  14. SPATIALLY-SEPARATED ATOMIC LAYER DEPOSITION OF Al2O3, A NEW OPTION FOR HIGH-THROUGHPUT Si SOLAR CELL PASSIVATION

    E-Print Network [OSTI]

    SPATIALLY-SEPARATED ATOMIC LAYER DEPOSITION OF Al2O3, A NEW OPTION FOR HIGH-THROUGHPUT Si SOLAR material for surface passivation of crystalline Si is atomic layer deposited (ALD) Al2O3. However for the development of high-efficiency solar cells. It has been shown that atomic layer deposition (ALD) of Al2O3

  15. Separation of metallic residues from the dissolution of a high-burnup BWR fuel using nitrogen trifluoride

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Buck, Edgar C.; Soderquist, Chuck Z.; Smith, Frances N.; Mausolf, Edward J.; Scheele, Randall D.

    2014-02-10

    Nitrogen trifluoride (NF3) was used to fluorinate the metallic residue from the dissolution of a high burnup, boiling water reactor fuel (?70 MWd/kgU). The metallic residue included the noble metal phase (containing ruthenium, rhodium, palladium, technetium, and molybdenum), and smaller amounts of zirconium, selenium, tellurium, and silver. Exposing the noble metal phase to 10% NF3 in argon between 400 and 550?C, removed molybdenum and technetium near 400?C as their volatile fluorides, and ruthenium near 500?C as its volatile fluoride. The events were thermally and temporally distinct and the conditions specified are a recipe to separate these transition metals from each other and from the noble metal phase nonvolatile residue. Depletion of the volatile fluorides resulted in substantial exothermicity. Thermal excursion behavior was recorded under non-adiabatic, isothermal conditions that typically minimize heat release. Physical characterization of the metallic noble phase and its thermal behavior are consistent with high kinetic velocity reactions encouraged by the nanoparticulate phase or perhaps catalytic influences of the mixed platinum metals with nearly pure phase structure. Post-fluorination, only two phases were present in the residual nonvolatile fraction. These were identified as a nano-crystalline, metallic palladium cubic phase and a hexagonal rhodium trifluoride (RhF3) phase. The two phases were distinct as the sub-µm crystallites of metallic palladium were in contrast to the RhF3 phase, which grew from the parent nano-crystalline noble-metal phase during fluorination, to acicular crystals exceeding 20-µm in length.

  16. Integrated reactor and centrifugal separator and uses thereof

    DOE Patents [OSTI]

    Birdwell, Jr., Joseph F (Knoxville, TN); Jennings, Harold L. (Clinton, TN); McFarlane, Joanna (Oak Ridge, TN); Tsouris, Constantino (Oak Ridge, TN)

    2012-01-17

    An apparatus for providing reaction of fluids and separation of products with increased residence time. The apparatus includes a stationary shell, a rotating hollow cylindrical component disposed in the stationary shell, a residence-time increasing device external to the stationary shell, a standpipe for introducing fluid into an interior cavity of the hollow cylindrical component from the residence-time increasing device, a first outlet in fluid flow communication with the interior cavity of the hollow cylindrical component for a less dense phase fluid, and a second outlet in fluid flow communication with the interior cavity of the hollow cylindrical component for a more dense phase fluid.

  17. Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

    2013-09-02

    Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

  18. Sudden increase in tidal response linked to calving and acceleration at a large Greenland outlet glacier

    E-Print Network [OSTI]

    de Juan, J.; Elosegui, P.; Nettles, M.; Larsen, T. B.; Davis, J. L.; Hamilton, Gordon S.; Stearns, Leigh; Anderson, M. L.; Ekstrom, G.; Ahlstrom, A. P.; Stenseng, L.; Khan, S. A.; Forsberg, R.

    2010-06-23

    [1] Large calving events at Greenland's largest outlet glaciers are associated with glacial earthquakes and near-instantaneous increases in glacier flow speed. At some glaciers and ice streams, flow is also modulated in a regular way by ocean tidal...

  19. A Separate-Queue Multicast Architecture For High-speed Ying Jiang, Mounir Hamdi,and Khaled Ben LetaieP

    E-Print Network [OSTI]

    Hamdi, Mounir

    A Separate-Queue Multicast Architecture For High-speed Routers Ying Jiang, Mounir Hamdi,and Khaled Kong University of Science and Technology Clear Water Bay, Kowloon, Hong Kong Corresponding Author switch, etc.). The frequently-adopted virtual output queued (VOQ)architecture for unicast traffic doesn

  20. A novel magnetically separable TiO2/CoFe2O4 nanofiber with high photocatalytic activity under UVvis light

    E-Print Network [OSTI]

    Gong, Jian Ru

    photocatalytic ability, various morphologies of TiO2 including nanoparticles, nanotubes, nanostructured filmsA novel magnetically separable TiO2/CoFe2O4 nanofiber with high photocatalytic activity under UV pollutants [1,2]. Titanium dioxide (TiO2) is considered as an interesting material and has been widely

  1. Control of Flow Separation in S-ducts via Flow Injection and Suction

    E-Print Network [OSTI]

    Debiasi, Marco

    Control of Flow Separation in S-ducts via Flow Injection and Suction Marco Debiasi1 , Marco Robert as a mean to control the separation of flow in S-duct inlets. The overall goal is to reduce the distortion of the S-duct outlet flow and to improve its pressure recovery by using the least expenditure of energy. We

  2. Separation and Purification and Beta Liquid Scintillation Analysis of Sm-151 in Savannah River Site and Hanford Site DOE High Level Waste

    SciTech Connect (OSTI)

    Dewberry, R.A.

    2001-02-13

    This paper describes development work to obtain a product phase of Sm-151 pure of any other radioactive species so that it can be determined in US Department of Energy high level liquid waste and low level solid waste by liquid scintillation {beta}-spectroscopy. The technique provides separation from {mu}Ci/ml levels of Cs-137, Pu alpha and Pu-241 {beta}-decay activity, and Sr-90/Y-90 activity. The separation technique is also demonstrated to be useful for the determination of Pm-147.

  3. Gas Separation Using Membranes 

    E-Print Network [OSTI]

    Koros, W. J.; Paul, D. R.

    1984-01-01

    Commercial membrane-based gas separator systems based upon high-flux, asymmetric polysulfone hollow fibers were first introduced in 1977 by Monsanto. These systems were packaged in compact modules containing large amounts of permeation surface area...

  4. Gas-separation process

    DOE Patents [OSTI]

    Toy, Lora G. (San Francisco, CA); Pinnau, Ingo (Palo Alto, CA); Baker, Richard W. (Palo Alto, CA)

    1994-01-01

    A process for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material.

  5. CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of raregovAboutRecovery ActToolsForNorthfor Gas SeparationsRelevant

  6. Phase-separated high-temperature-annealed (Ga,Mn)As: A negative charge-transfer-energy material

    E-Print Network [OSTI]

    Moreno, M

    2011-01-01

    The approximate location in the Zaanen-Sawatzky-Allen diagram of the phase-separated (Ga,Mn)As material, consisting of MnAs nanoclusters embedded in GaAs, is determined on the basis of configuration-interaction (CI) cluster-model analysis of their Mn 2p core-level photoemission. The composite material is found to belong to the special class of materials with negative charge-transfer energy (delta). As such, its metallic or insulating/semiconducting behavior depends on the strength of the p-d hybridization (affected by strain) relative to the (size-dependent) p-bandwidth. Whereas internal strain in the embedded clusters counteracts gap opening, a metal-to-semiconductor transition is expected to occur for decreasing cluster size, associated to the opening of a small gap of p-p type (covalent gap). The electronic properties of homogeneous and phase-separated (Ga,Mn)As materials are analyzed, with emphasis on the nature of their metal-insulator transitions.

  7. Centrifugal deterministic lateral displacement separation system

    E-Print Network [OSTI]

    Mingliang Jiang; Aaron D. Mazzeo; German Drazer

    2015-07-22

    This work investigates the migration of spherical particles of different sizes in a centrifuge-driven deterministic lateral displacement (c-DLD) device. Specifically, we use a scaled-up model to study the motion of suspended particles through a square array of cylindrical posts under the action of centrifugation. Experiments show that separation of particles by size is possible depending on the orientation of the driving acceleration with respect to the array of posts (forcing angle). We focus on the fractionation of binary suspensions and measure the separation resolution at the outlet of the device for different forcing angles. We found excellent resolution at intermediate forcing angles, when large particles are locked to move at small migration angles but smaller particles follow the forcing angle more closely. Finally, we show that reducing the initial concentration (number) of particles, approaching the dilute limit of single particles, leads to increased resolution in the separation.

  8. Centrifugal deterministic lateral displacement separation system

    E-Print Network [OSTI]

    Jiang, Mingliang; Drazer, German

    2015-01-01

    This work investigates the migration of spherical particles of different sizes in a centrifuge-driven deterministic lateral displacement (c-DLD) device. Specifically, we use a scaled-up model to study the motion of suspended particles through a square array of cylindrical posts under the action of centrifugation. Experiments show that separation of particles by size is possible depending on the orientation of the driving acceleration with respect to the array of posts (forcing angle). We focus on the fractionation of binary suspensions and measure the separation resolution at the outlet of the device for different forcing angles. We found excellent resolution at intermediate forcing angles, when large particles are locked to move at small migration angles but smaller particles follow the forcing angle more closely. Finally, we show that reducing the initial concentration (number) of particles, approaching the dilute limit of single particles, leads to increased resolution in the separation.

  9. Passive gas separator and accumulator device

    DOE Patents [OSTI]

    Choe, Hwang (Saratoga, CA); Fallas, Thomas T. (Berkeley, CA)

    1994-01-01

    A separation device employing a gas separation filter and swirler vanes for separating gas from a gasliquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use.

  10. Passive gas separator and accumulator device

    DOE Patents [OSTI]

    Choe, H.; Fallas, T.T.

    1994-08-02

    A separation device employing a gas separation filter and swirler vanes for separating gas from a gas-liquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use. 3 figs.

  11. High-Permeance Room-Temperature Ionic-Liquid-Based Membranes for CO2/N-2 Separation

    SciTech Connect (OSTI)

    Zhou, JS; Mok, MM; Cowan, MG; McDanel, WM; Carlisle, TK; Gin, DL; Noble, RD

    2014-12-24

    We have developed and fabricated thin-film composite (TFC) membranes with an active layer consisting of a room-temperature ionic liquid/polymerized (room-temperature ionic liquid) [i.e., (RTIL)/poly(RTIL)] composite material. The resulting membrane has a CO2 permeance of 6100 +/- 400 GPU (where 1 GPU = 10(-6) cm(3)/(cm(2) s cmHg)) and an ideal CO2/N-2 selectivity of 22 +/- 2. This represents a new membrane with state-of-the-art CO2 permeance and good CO2/N-2 selectivity. To our knowledge, this is the first example of a TFC gas separation membrane composed of an RTIL-containing active layer.

  12. ESTIMATION OF OUTLET MASS FLOW FOR A MONO-TUBE CAVITY RECEIVER FOR DIRECT STEAM GENERATION

    E-Print Network [OSTI]

    arrays of parabolic dishes, where each collector contributes steam to a central steam-turbine power blockESTIMATION OF OUTLET MASS FLOW FOR A MONO-TUBE CAVITY RECEIVER FOR DIRECT STEAM GENERATION José This paper presents recent developments on a dynamic model for a mono-tube cavity receiver for direct steam

  13. Quantitative estimates of velocity sensitivity to surface melt variations at a large Greenland outlet glacier

    E-Print Network [OSTI]

    Anderson, M. L.; Nettles, M.; Larsen, T. B.; Hamilton, Gordon S.; Stearns, Leigh

    2011-09-01

    , marine-terminating outlet glaciers that drain the ice sheet. We use a validated model of meltwater input and GPS-derived surface velocities to quantify the sensitivity of glacier flow speed to changes in surface melt at Helheim Glacier during two summer...

  14. On-Line Estimation of Inlet and Outlet Composition in Catalytic Partial Ali Al-Matouq , Tyrone Vincent

    E-Print Network [OSTI]

    Vincent, Tyrone

    On-Line Estimation of Inlet and Outlet Composition in Catalytic Partial Oxidation Ali Al and outlet composition of catalytic partial oxidation (CPOX) of methane over rhodium catalyst using simple experiments are conducted to verify the accuracy of the estimator. Keywords: Catalytic Partial Oxidation

  15. Separation system

    DOE Patents [OSTI]

    Rubin, Leslie S. (Newton, MA)

    1986-01-01

    A separation system for dewatering radioactive waste materials includes a disposal container, drive structure for receiving the container, and means for releasably attaching the container to the drive structure. Separation structure disposed in the container adjacent the inner surface of the side wall structure retains solids while allowing passage of liquids. Inlet port structure in the container top wall is normally closed by first valve structure that is centrifugally actuated to open the inlet port and discharge port structure at the container periphery receives liquid that passes through the separation structure and is normally closed by second valve structure that is centrifugally actuated to open the discharge ports. The container also includes coupling structure for releasable engagement with the centrifugal drive structure. Centrifugal force produced when the container is driven in rotation by the drive structure opens the valve structures, and radioactive waste material introduced into the container through the open inlet port is dewatered, and the waste is compacted. The ports are automatically closed by the valves when the container drum is not subjected to centrifugal force such that containment effectiveness is enhanced and exposure of personnel to radioactive materials is minimized.

  16. EXPERIMENTAL-BASED DISCUSSION FOR THE SEPARATION OF RESIDUAL STRESSES AND COLD WORK IN SHOT PEENED IN718 USING HIGH FREQUENCY EDDY CURRENT SPECTROSCOPY

    SciTech Connect (OSTI)

    Hillmann, S.; Heuer, H.; Robbert, A.; Meyendorf, N. [Fraunhofer Institute for Non-Destructive Testing, Dresden branch of IZFP, Maria-Reiche-Str. 2, 01109 Dresden (Germany); Baron, H.-U.; Bamberg, J. [MTU Aero Engines GmbH, Dachauer Str. 665, 80995 Munich (Germany)

    2010-02-22

    Typical aero engine alloys, such as IN718, can be surface-treated by shot peening to induce near-surface compressive strains. To calculate the remaining operation time for those critical aero engine components, a quantitative nondestructive determination of near-surface strain gradients has to be developed. We have demonstrated in the past, that it is possible to obtain a characteristic depth profile (surface and sub-surface) of the electrical conductivity of shot peened specimen by using high-frequency eddy current techniques. The measured conductivity profile is resulting from residual stresses, cold work, surface roughness, and the microstructure of the material. The objective is to measure residual stresses (separately from other material properties) in such components after a defined life time. It can be assumed, that surface roughness and microstructure remain unchanged in IN718 materials over their lifetime, but cold work and residual stresses can change independently. Consequently, there is a need to clearly separate the information from both material properties of received eddy current conductivity signals in order to obtain specific information related to residual stresses. This paper presents results acquired from different experiments, conducted to separate both effects by using the eddy current technique on shot peened IN718 materials. We present different physical approaches and illustrate the experiments to solve them. In addition, we will demonstrate that there is a need to use additional techniques, for example ultrasonic time-of-flight measurements, to separate the effects of residual stresses from compound (mixed) signals obtained on cold work samples.

  17. Plasma isotope separation methods

    SciTech Connect (OSTI)

    Grossman, M.W. ); Shepp, T.A. )

    1991-12-01

    Isotope separation has many important industrial, medical, and research applications. Large-scale processes have typically utilized complex cascade systems; for example, the gas centrifuge. Alternatively, high single-stage enrichment processes (as in the case of the calutron) are very energy intensive. Plasma-based methods being developed for the past 15 to 20 years have attempted to overcome these two drawbacks. In this review, six major types of isotope separation methods which involve plasma phenomena are discussed. These methods are: plasma centrifuge, AVLIS (atomic vapor laser isotope separation), ion wave, ICR (ion-cyclotron resonance), calutron, and gas discharge. The emphasis of this paper is to describe the plasma phenomena in these major categories. An attempt was made to include enough references so that more detailed study or evaluation of a particular method could readily be pursued. A brief discussion of isotope separation using mass balance concepts is also carried out.

  18. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bazelaire, Eve; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Ditto, Mary E.; Engle, Nancy L.; Gorbunova, Maryna G.; Haverlock, Tamara J.; Levitskaia, Taiana G.; Bartsch, Richard A.; Surowiec, Malgorzata A.; Hui Zhou

    2005-07-06

    This project unites expertise at Oak Ridge National Laboratory (ORNL) and Texas Tech University (TTU, Prof. Richard A. Bartsch) to answer fundamental questions addressing the problem of cesium removal from high-level tank waste. Efforts focus on novel solvent-extraction systems containing calixcrown extractants designed for enhanced cesium binding and release. Exciting results are being obtained in three areas: (1) a new lipophilic cesium extractant with a high solubility in the solvent; (2) new proton-ionizable calixcrowns that both strongly extract cesium and "switch off" when protonated; and (3) an improved solvent system that may be stripped with more than 100-fold greater efficiency. Scientific questions primarily concern how to more effectively reverse extraction, focusing on the use of amino groups and proton-ionizable groups to enable pH-switching. Synthesis is being performed at ORNL (amino calixcrowns) and TTU (proton-ionizable calixcrowns). At ORNL, the extraction behavior is being surveyed to assess the effectiveness of candidate solvent systems, and systematic distribution measurements are under way to obtain a thermodynamic understanding of partitioning and complexation equilibria. Crystal structures obtained at ORNL are revealing the structural details of cesium binding. The overall objective is a significant advance in the predictability and efficiency of cesium extraction from high-level waste in support of potential implementation at U. S. Department of Energy (USDOE) sites.

  19. Next Generation Extractants for Cesium Separation from High-Level Waste: From Fundamental Concepts to Site Implementation

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bazelaire, Eve; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Ditto, Mary E.; Engle, Nancy L.; Gorbunova, Maryna G.; Haverlock, Tamara J.; Levitskaia, Tatiana G.; Bartsch, Richard A.; Surowiec, Malgorzata A.; Zhou, Hui

    2005-07-06

    This project unites expertise at Oak Ridge National Laboratory (ORNL) and Texas Tech University (TTU, Prof. Richard A. Bartsch) to answer fundamental questions addressing the problem of cesium removal from high-level tank waste. Efforts focus on novel solvent-extraction systems containing calixcrown extractants designed for enhanced cesium binding and release. Exciting results are being obtained in three areas: (1) a new lipophilic cesium extractant with a high solubility in the solvent; (2) new proton-ionizable calixcrowns that both strongly extract cesium and ''switch off'' when protonated; and (3) an improved solvent system that may be stripped with more than 100-fold greater efficiency. Scientific questions primarily concern how to more effectively reverse extraction, focusing on the use of amino groups and proton-ionizable groups to enable pH-switching. Synthesis is being performed at ORNL (amino calixcrowns) and TTU (proton-ionizable calixcrowns). At ORNL, the extraction behavior is being surveyed to assess the effectiveness of candidate solvent systems, and systematic distribution measurements are under way to obtain a thermodynamic understanding of partitioning and complexation equilibria. Crystal structures obtained at ORNL are revealing the structural details of cesium binding. The overall objective is a significant advance in the predictability and efficiency of cesium extraction from high-level waste in support of potential implementation at U. S. Department of Energy (USDOE) sites.

  20. Development of the laser isotope separation method (AVLIS) for obtaining weight amounts of highly enriched {sup 150}Nd isotope

    SciTech Connect (OSTI)

    Babichev, A P; Grigoriev, Igor' S; Grigoriev, A I; Dorovskii, A P; D'yachkov, Aleksei B; Kovalevich, S K; Kochetov, V A; Kuznetsov, V A; Labozin, Valerii P; Matrakhov, A V; Mironov, Sergei M; Nikulin, Sergei A; Pesnya, A V; Timofeev, N I; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G

    2005-10-31

    Results obtained at the first stage of development of the experimental technique for obtaining weight amounts of the highly enriched {sup 150}Nd isotope by laser photoionisation are presented. The vaporiser and the laser are designed, and various methods of irradiation of neodymium vapour and extraction of photoions are tested. The product yield {approx}40 mg h{sup -1} for the {approx}60% enrichment and 25 mg h{sup -1} for the {approx}65% enrichment is achieved for a vaporiser of length 27 cm. The cost of constructing the facility for preparing 50 kg of the {sup 150}Nd isotope, intended for determining the neutrino mass, is estimated. This estimate shows that the cost of production can be lowered by a factor of 5-7 compared to the electromagnetic method. (invited paper)

  1. An analysis of the threshold necessary to sustain rural Texas retail outlets 

    E-Print Network [OSTI]

    Adcock, Donna P

    1992-01-01

    activity into and out of them [Shaffer]. When residents go outside of the community to purchase goods, a leakage of economic activity out of that community occurs. By understanding the characteristics of local economies which support specific types... for the merchants [Shaffer]. As identified by Simon, Braschler, Kuehn and Croll, information on these thresholds will help local decisionmakers answer the following questions: ~ What type of retail outlets can this community support? ~ How many firms can...

  2. Gas-separation process

    DOE Patents [OSTI]

    Toy, L.G.; Pinnau, I.; Baker, R.W.

    1994-01-25

    A process is described for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material. 6 figures.

  3. Heat recovery steam generator outlet temperature control system for a combined cycle power plant

    SciTech Connect (OSTI)

    Martens, A.; Myers, G.A.; McCarty, W.L.; Wescott, K.R.

    1986-04-01

    This patent describes a command cycle electrical power plant including: a steam turbine and at least one set comprising a gas turbine, an afterburner and a heat recovery steam generator having an attemperator for supplying from an outlet thereof to the steam turbine superheated steam under steam turbine operating conditions requiring predetermined superheated steam temperature, flow and pressure; with the gas turbine and steam turbine each generating megawatts in accordance with a plant load demand; master control means being provided for controlling the steam turbine and the heat recovery steam generator so as to establish the steam operating conditions; the combination of: first control means responsive to the gas inlet temperature of the heat recovery steam generator and to the plant load demand for controlling the firing of the afterburner; second control means responsive to the superheated steam predetermined temperature and to superheated steam temperature from the outlet for controlling the attemperator between a closed and an open position; the first and second control means being operated concurrently to maintain the superheated steam outlet temperature while controlling the load of the gas turbine independently of the steam turbine operating conditions.

  4. STATUS OF THE DEVELOPMENT OF IN-TANK/AT-TANK SEPARATIONS TECHNOLOGIES FOR FOR HIGH-LEVEL WASTE PROCESSING FOR THE U.S. DEPARTMENT OF ENERGY

    SciTech Connect (OSTI)

    Aaron, G.; Wilmarth, B.

    2011-09-19

    Within the U.S. Department of Energy's (DOE) Office of Technology Innovation and Development, the Office of Waste Processing manages a research and development program related to the treatment and disposition of radioactive waste. At the Savannah River (South Carolina) and Hanford (Washington) Sites, approximately 90 million gallons of waste are distributed among 226 storage tanks (grouped or collocated in 'tank farms'). This waste may be considered to contain mixed and stratified high activity and low activity constituent waste liquids, salts and sludges that are collectively managed as high level waste (HLW). A large majority of these wastes and associated facilities are unique to the DOE, meaning many of the programs to treat these materials are 'first-of-a-kind' and unprecedented in scope and complexity. As a result, the technologies required to disposition these wastes must be developed from basic principles, or require significant re-engineering to adapt to DOE's specific applications. Of particular interest recently, the development of In-tank or At-Tank separation processes have the potential to treat waste with high returns on financial investment. The primary objective associated with In-Tank or At-Tank separation processes is to accelerate waste processing. Insertion of the technologies will (1) maximize available tank space to efficiently support permanent waste disposition including vitrification; (2) treat problematic waste prior to transfer to the primary processing facilities at either site (i.e., Hanford's Waste Treatment and Immobilization Plant (WTP) or Savannah River's Salt Waste Processing Facility (SWPF)); and (3) create a parallel treatment process to shorten the overall treatment duration. This paper will review the status of several of the R&D projects being developed by the U.S. DOE including insertion of the ion exchange (IX) technologies, such as Small Column Ion Exchange (SCIX) at Savannah River. This has the potential to align the salt and sludge processing life cycle, thereby reducing the Defense Waste Processing Facility (DWPF) mission by 7 years. Additionally at the Hanford site, problematic waste streams, such as high boehmite and phosphate wastes, could be treated prior to receipt by WTP and thus dramatically improve the capacity of the facility to process HLW. Treatment of boehmite by continuous sludge leaching (CSL) before receipt by WTP will dramatically reduce the process cycle time for the WTP pretreatment facility, while treatment of phosphate will significantly reduce the number of HLW borosilicate glass canisters produced at the WTP. These and other promising technologies will be discussed.

  5. Fluidic assembly for an ultra-high-speed chromosome flow sorter

    DOE Patents [OSTI]

    Gray, Joe W. (Livermore, CA); Alger, Terry W. (Livermore, CA); Lord, David E. (Livermore, CA)

    1982-01-01

    A fluidic assembly for an ultra-high-speed chromosome flow sorter using a fluid drive system, a nozzle with an orifice having a small ratio of length to diameter, and mechanism for vibrating the nozzle along its axis at high frequencies. The orifice is provided with a sharp edge at its inlet, and a conical section at its outlet for a transition from a short cylindrical aperture of small length to diameter ratio to free space. Sample and sheath fluids in separate low pressure reservoirs are transferred into separate high pressure buffer reservoirs through a valve arrangement which first permit the fluids to be loaded into the buffer reservoirs under low pressure. Once loaded, the buffer reservoirs are subjected to high pressure and valves are operated to permit the buffer reservoirs to be emptied through the nozzle under high pressure. A sensor and decision logic is positioned at the exit of the nozzle, and a charging pulse is applied to the jet when a particle reaches a position further downstream where the droplets are formed. In order to adjust the timing of charge pulses, the distance between the sensing station at the outlet of the nozzle and the droplet breakoff point is determined by stroboscopic illumination of the droplet breakoff region using a laser and a revolving lucite cylinder, and a beam on/off modulator. The breakoff point in the region thus illuminated may then be viewed, using a television monitor.

  6. Designing and Validating Ternary Pd Alloys for Optimum Sulfur/Carbon Resistance in Hydrogen Separation and Carbon Capture Membrane Systems Using High-Throughput Combinatorial Methods

    SciTech Connect (OSTI)

    Lewis, Amanda; Zhao, Hongbin; Hopkins, Scott

    2014-09-30

    This report summarizes the work completed under the U.S. Department of Energy Project Award No.: DE-FE0001181 titled “Designing and Validating Ternary Pd Alloys for Optimum Sulfur/Carbon Resistance in Hydrogen Separation and Carbon Capture Membrane Systems Using High-Throughput Combinatorial Methods.” The project started in October 1, 2009 and was finished September 30, 2014. Pall Corporation worked with Cornell University to sputter and test palladium-based ternary alloys onto silicon wafers to examine many alloys at once. With the specialized equipment at Georgia Institute of Technology that analyzed the wafers for adsorbed carbon and sulfur species six compositions were identified to have resistance to carbon and sulfur species. These compositions were deposited on Pall AccuSep® supports by Colorado School of Mines and then tested in simulated synthetic coal gas at the Pall Corporation. Two of the six alloys were chosen for further investigations based on their performance. Alloy reproducibility and long-term testing of PdAuAg and PdZrAu provided insight to the ability to manufacture these compositions for testing. PdAuAg is the most promising alloy found in this work based on the fabrication reproducibility and resistance to carbon and sulfur. Although PdZrAu had great initial resistance to carbon and sulfur species, the alloy composition has a very narrow range that hindered testing reproducibility.

  7. Separators - Technology review: Ceramic based separators for secondary batteries

    SciTech Connect (OSTI)

    Nestler, Tina; Schmid, Robert; Münchgesang, Wolfram; Bazhenov, Vasilii; Meyer, Dirk C.; Schilm, Jochen; Leisegang, Tilmann

    2014-06-16

    Besides a continuous increase of the worldwide use of electricity, the electric energy storage technology market is a growing sector. At the latest since the German energy transition ('Energiewende') was announced, technological solutions for the storage of renewable energy have been intensively studied. Storage technologies in various forms are commercially available. A widespread technology is the electrochemical cell. Here the cost per kWh, e. g. determined by energy density, production process and cycle life, is of main interest. Commonly, an electrochemical cell consists of an anode and a cathode that are separated by an ion permeable or ion conductive membrane - the separator - as one of the main components. Many applications use polymeric separators whose pores are filled with liquid electrolyte, providing high power densities. However, problems arise from different failure mechanisms during cell operation, which can affect the integrity and functionality of these separators. In the case of excessive heating or mechanical damage, the polymeric separators become an incalculable security risk. Furthermore, the growth of metallic dendrites between the electrodes leads to unwanted short circuits. In order to minimize these risks, temperature stable and non-flammable ceramic particles can be added, forming so-called composite separators. Full ceramic separators, in turn, are currently commercially used only for high-temperature operation systems, due to their comparably low ion conductivity at room temperature. However, as security and lifetime demands increase, these materials turn into focus also for future room temperature applications. Hence, growing research effort is being spent on the improvement of the ion conductivity of these ceramic solid electrolyte materials, acting as separator and electrolyte at the same time. Starting with a short overview of available separator technologies and the separator market, this review focuses on ceramic-based separators. Two prominent examples, the lithium-ion and sodium-sulfur battery, are described to show the current stage of development. New routes are presented as promising technologies for safe and long-life electrochemical storage cells.

  8. Efficient separations & processing crosscutting program

    SciTech Connect (OSTI)

    1996-08-01

    The Efficient Separations and Processing Crosscutting Program (ESP) was created in 1991 to identify, develop, and perfect chemical and physical separations technologies and chemical processes which treat wastes and address environmental problems throughout the DOE complex. The ESP funds several multiyear tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R & D) leading to the demonstration or use of these separations technologies by other organizations within the Department of Energy (DOE), Office of Environmental Management.

  9. Separation science and technology

    SciTech Connect (OSTI)

    Smith, B.F.; Sauer, N.; Chamberlin, R.M.; Gottesfeld, S.; Mattes, B.R.; Li, D.Q.; Swanson, B.

    1998-12-31

    The focus of this project is the demonstration and advancement of membrane-based separation and destruction technologies. The authors are exploring development of membrane systems for gas separations, selective metal ion recovery, and for separation or destruction of hazardous organics. They evaluated existing polymers and polymer formulations for recovery of toxic oxyanionic metals such as chromate and arsenate from selected waste streams and developed second-generation water-soluble polymeric systems for highly selective oxyanion removal and recovery. They optimized the simultaneous removal of radioactive strontium and cesium from aqueous solutions using the new nonhazardous separations agents, and developed recyclable, redox-active extractants that permitted recovery of the radioactive ions into a minimal waste volume. They produced hollow fibers and fabricated prototype hollow-fiber membrane modules for applications to gas separations and the liquid-liquid extraction and recovery of actinides and nuclear materials from process streams. They developed and fabricated cyclodextrin-based microporous materials that selectively absorb organic compounds in an aqueous environment; the resultant products gave pure water with organics at less than 0.05 parts per billion. They developed new, more efficient, membrane-based electrochemical reactors for use in organic destruction in process waste treatment. They addressed the need for advanced oxidation technologies based on molecular-level materials designs that selectively remove or destroy target species. They prepared and characterized surface-modified TiO{sub 2} thin films using different linking approaches to attach ruthenium photosensitizers, and they started the measurement of the photo-degradation products generated using surface modified TiO{sub 2} films in reaction with chlorophenol.

  10. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  11. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

    1988-01-01

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  12. EFFICIENT OXYGEN SEPARATION MEMBRANE

    E-Print Network [OSTI]

    Mucina, Ladislav

    EFFICIENT OXYGEN SEPARATION MEMBRANE Summary of technology Oxygen can be separated from air using a uniquely structured ceramic ion transport membrane for oxygen separation thatshowsremarkablyhighflux © Curtin University 2013 Gas diffusion in conventional membrane Gas diffusion in new membrane New membrane

  13. Innovative Separations Technologies

    SciTech Connect (OSTI)

    J. Tripp; N. Soelberg; R. Wigeland

    2011-05-01

    Reprocessing used nuclear fuel (UNF) is a multi-faceted problem involving chemistry, material properties, and engineering. Technology options are available to meet a variety of processing goals. A decision about which reprocessing method is best depends significantly on the process attributes considered to be a priority. New methods of reprocessing that could provide advantages over the aqueous Plutonium Uranium Reduction Extraction (PUREX) and Uranium Extraction + (UREX+) processes, electrochemical, and other approaches are under investigation in the Fuel Cycle Research and Development (FCR&D) Separations Campaign. In an attempt to develop a revolutionary approach to UNF recycle that may have more favorable characteristics than existing technologies, five innovative separations projects have been initiated. These include: (1) Nitrogen Trifluoride for UNF Processing; (2) Reactive Fluoride Gas (SF6) for UNF Processing; (3) Dry Head-end Nitration Processing; (4) Chlorination Processing of UNF; and (5) Enhanced Oxidation/Chlorination Processing of UNF. This report provides a description of the proposed processes, explores how they fit into the Modified Open Cycle (MOC) and Full Recycle (FR) fuel cycles, and identifies performance differences when compared to 'reference' advanced aqueous and fluoride volatility separations cases. To be able to highlight the key changes to the reference case, general background on advanced aqueous solvent extraction, advanced oxidative processes (e.g., volumetric oxidation, or 'voloxidation,' which is high temperature reaction of oxide UNF with oxygen, or modified using other oxidizing and reducing gases), and fluorination and chlorination processes is provided.

  14. UBC Social Ecological Economic Development Studies (SEEDS) Student Report Assessing the Potential for a Student-run Cooperative Organic Grocery Outlet in UBC's

    E-Print Network [OSTI]

    for a Student-run Cooperative Organic Grocery Outlet in UBC's Student Union Building: The Sustainability of the UBC Food System Collaborative Project III Shannon Buckshaw, Celine Evans, Magdalena Kerner, Young of a project/report". #12;Assessing the Potential for a Student-run Cooperative Organic Grocery Outlet in UBC

  15. Production Pathways and Separation Procedures for High-Diagnostic-Value Activation Species, Fission Products, and Actinides Required for Preparation of Realistic Synthetic Post-Detonation Nuclear Debris

    SciTech Connect (OSTI)

    Faye, S A; Shaughnessy, D A

    2015-08-19

    The objective of this project is to provide a comprehensive study on the production routes and chemical separation requirements for activation products, fission products, and actinides required for the creation of realistic post-detonation surrogate debris. Isotopes that have been prioritized by debris diagnosticians will be examined for their ability to be produced at existing irradiation sources, production rates, and availability of target materials, and chemical separation procedures required to rapidly remove the products from the bulk target matrix for subsequent addition into synthetic debris samples. The characteristics and implications of the irradiation facilities on the isotopes of interest will be addressed in addition to a summary of the isotopes that are already regularly produced.

  16. Long-Gradient Separations Coupled with Selected Reaction Monitoring for Highly Sensitive, Large Scale Targeted Protein Quantification in a Single Analysis

    SciTech Connect (OSTI)

    Shi, Tujin; Fillmore, Thomas L.; Gao, Yuqian; Zhao, Rui; He, Jintang; Schepmoes, Athena A.; Nicora, Carrie D.; Wu, Chaochao; Chambers, Justin L.; Moore, Ronald J.; Kagan, Jacob; Srivastava, Sudhir; Liu, Alvin Y.; Rodland, Karin D.; Liu, Tao; Camp, David G.; Smith, Richard D.; Qian, Weijun

    2013-10-01

    Long-gradient separations coupled to tandem MS were recently demonstrated to provide a deep proteome coverage for global proteomics; however, such long-gradient separations have not been explored for targeted proteomics. Herein, we investigate the potential performance of the long-gradient separations coupled with selected reaction monitoring (LG-SRM) for targeted protein quantification. Direct comparison of LG-SRM (5 h gradient) and conventional LC-SRM (45 min gradient) showed that the long-gradient separations significantly reduced background interference levels and provided an 8- to 100-fold improvement in LOQ for target proteins in human female serum. Based on at least one surrogate peptide per protein, an LOQ of 10 ng/mL was achieved for the two spiked proteins in non-depleted human serum. The LG-SRM detection of seven out of eight endogenous plasma proteins expressed at ng/mL or sub-ng/mL levels in clinical patient sera was also demonstrated. A correlation coefficient of >0.99 was observed for the results of LG-SRM and ELISA measurements for prostate-specific antigen (PSA) in selected patient sera. Further enhancement of LG-SRM sensitivity was achieved by applying front-end IgY14 immunoaffinity depletion. Besides improved sensitivity, LG-SRM offers at least 3 times higher multiplexing capacity than conventional LC-SRM due to ~3-fold increase in average peak widths for a 300-min gradient compared to a 45-min gradient. Therefore, LG-SRM holds great potential for bridging the gap between global and targeted proteomics due to its advantages in both sensitivity and multiplexing capacity.

  17. Smolt Responses to Hydrodynamic Conditions in Forebay Flow Nets of Surface Flow Outlets, 2007

    SciTech Connect (OSTI)

    Johnson, Gary E.; Richmond, Marshall C.; Hedgepeth, J. B.; Ploskey, Gene R.; Anderson, Michael G.; Deng, Zhiqun; Khan, Fenton; Mueller, Robert P.; Rakowski, Cynthia L.; Sather, Nichole K.; Serkowski, John A.; Steinbeck, John R.

    2009-04-01

    This study provides information on juvenile salmonid behaviors at McNary and The Dalles dams that can be used by the USACE, fisheries resource managers, and others to support decisions on long-term measures to enhance fish passage. We researched smolt movements and ambient hydrodynamic conditions using a new approach combining simultaneous acoustic Doppler current profiler (ADCP) and acoustic imaging device (AID) measurements at surface flow outlets (SFO) at McNary and The Dalles dams on the Columbia River during spring and summer 2007. Because swimming effort vectors could be computed from the simultaneous fish and flow data, fish behavior could be categorized as passive, swimming against the flow (positively rheotactic), and swimming with the flow (negatively rheotactic). We present bivariate relationships to provide insight into fish responses to particular hydraulic variables that engineers might consider during SFO design. The data indicate potential for this empirical approach of simultaneous water/fish measurements to lead to SFO design guidelines in the future.

  18. Apparatus for molecular weight separation

    DOE Patents [OSTI]

    Smith, Richard D. (Richland, WA); Liu, Chuanliang (Haverhill, MA)

    2001-01-01

    The present invention relates generally to an apparatus and method for separating high molecular weight molecules from low molecular weight molecules. More specifically, the invention relates to the use of microdialysis for removal of the salt (low molecular weight molecules) from a nucleotide sample (high molecular weight molecules) for ESI-MS analysis. The dialysis or separation performance of the present invention is improved by (1) increasing dialysis temperature thereby increasing desalting efficiency and improving spectrum quality; (2) adding piperidine and imidazole to the dialysis buffer solution and reducing charge states and further increasing detection sensitivity for DNA; (3) using low concentrations (0-2.5 mM NH4OAc) of dialysis buffer and shifting the DNA negative ions to higher charge states, producing a nearly 10-fold increase in detection sensitivity and a slightly decreased desalting efficiency, (4) conducting a two-stage separation or (5) any combination of (1), (2), (3) and (4).

  19. Actinide separations conference

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This report contains the abstracts for 55 presentations given at the fourteenth annual Actinide Separations Conference. (JDL)

  20. Safety shutdown separators

    DOE Patents [OSTI]

    Carlson, Steven Allen; Anakor, Ifenna Kingsley; Farrell, Greg Robert

    2015-06-30

    The present invention pertains to electrochemical cells which comprise (a) an anode; (b) a cathode; (c) a solid porous separator, such as a polyolefin, xerogel, or inorganic oxide separator; and (d) a nonaqueous electrolyte, wherein the separator comprises a porous membrane having a microporous coating comprising polymer particles which have not coalesced to form a continuous film. This microporous coating on the separator acts as a safety shutdown layer that rapidly increases the internal resistivity and shuts the cell down upon heating to an elevated temperature, such as 110.degree. C. Also provided are methods for increasing the safety of an electrochemical cell by utilizing such separators with a safety shutdown layer.

  1. Farm Size in Relation to Market Outlets and Forward Contracts for Major Field Crops and Beef Cattle Texas Rollin Plains. 

    E-Print Network [OSTI]

    Moore, Donald S.; Martin, J. Rod

    1978-01-01

    STATION / Neville P. Clarke, Director The Texas A&M University System 1 College Station, Texas Farm Size in Relation to Market Outlets and Fomd Contracts for Major Field Crops and Beef Cattle, B-1187 Texas Rolling Plains February 1978 Donald S. Moore... and J. Rod Martin* Agricultural producers are continually adjusting to changing marketing channels. Some farmers obviously seek these changes, while others are only later affected by the changing conditions. One example of changing marketing channels...

  2. Next Generation Nuclear Plant Project Technology Development Roadmaps: The Technical Path Forward for 750–800°C Reactor Outlet Temperature

    SciTech Connect (OSTI)

    John Collins

    2009-08-01

    This document presents the NGNP Critical PASSCs and defines their technical maturation path through Technology Development Roadmaps (TDRMs) and their associated Technology Readiness Levels (TRLs). As the critical PASSCs advance through increasing levels of technical maturity, project risk is reduced and the likelihood of within-budget and on-schedule completion is enhanced. The current supplier-generated TRLs and TDRMs for a 750–800°C reactor outlet temperature (ROT) specific to each supplier are collected in Appendix A.

  3. New Electrode Manufacturing Process Equipment: Novel High Energy Density Lithium-Ion Cell Designs via Innovative Manufacturing Process Modules for Cathode and Integrated Separator

    SciTech Connect (OSTI)

    2010-07-01

    BEEST Project: Applied Materials is developing new tools for manufacturing Li-Ion batteries that could dramatically increase their performance. Traditionally, the positive and negative terminals of Li-Ion batteries are mixed with glue-like materials called binders, pressed onto electrodes, and then physically kept apart by winding a polymer mesh material between them called a separator. With the Applied Materials system, many of these manually intensive processes will be replaced by next generation coating technology to apply each component. This process will improve product reliability and performance of the cells at a fraction of the current cost. These novel manufacturing techniques will also increase the energy density of the battery and reduce the size of several of the battery’s components to free up more space within the cell for storage.

  4. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, Richard C. (East Hartford, CT)

    1986-09-02

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  5. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, R.C.

    1984-10-17

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  6. Gas Separations using Ceramic Membranes

    SciTech Connect (OSTI)

    Paul KT Liu

    2005-01-13

    This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

  7. High performance internal reforming unit for high temperature fuel cells

    DOE Patents [OSTI]

    Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  8. Separators for flywheel rotors

    DOE Patents [OSTI]

    Bender, Donald A. (Dublin, CA); Kuklo, Thomas C. (Oakdale, CA)

    1998-01-01

    A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors.

  9. Separators for flywheel rotors

    DOE Patents [OSTI]

    Bender, D.A.; Kuklo, T.C.

    1998-07-07

    A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors. 10 figs.

  10. Substituted polyacetylene separation membrane

    DOE Patents [OSTI]

    Pinnau, Ingo (Palo Alto, CA); Morisato, Atsushi (Tokyo, JP)

    1998-01-13

    A separation membrane useful for gas separation, particularly separation of C.sub.2+ hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula: ##STR1## wherein R.sub.1 is chosen from the group consisting of C.sub.1 -C.sub.4 alkyl and phenyl, and wherein R.sub.2 is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) ›PMP!. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations.

  11. Substituted polyacetylene separation membrane

    DOE Patents [OSTI]

    Pinnau, I.; Morisato, Atsushi

    1998-01-13

    A separation membrane is described which is useful for gas separation, particularly separation of C{sub 2+} hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula shown in the accompanying diagram, wherein R{sub 1} is chosen from the group consisting of C{sub 1}-C{sub 4} alkyl and phenyl, and wherein R{sub 2} is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) [PMP]. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations. 4 figs.

  12. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  13. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  14. Continuous flow separation techniques for microchemical synthesis

    E-Print Network [OSTI]

    Kralj, Jason G

    2006-01-01

    Performing multistep microchemical synthesis requires many techniques from combining micromixers in series to the development of continuous microfluidic separation tools. Safety, high heat and mass transfer rates, and cost ...

  15. Microsystem capillary separations

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Wegeng, Robert S [Richland, WA; Whyatt, Greg A [West Richland, WA; Stenkamp, Victoria S [Richland, WA; Gauglitz, Phillip A [Richland, WA

    2003-12-23

    Laminated, multiphase separators and contactors having wicking structures and gas flow channels are described. Some preferred embodiments are combined with microchannel heat exchange. Integrated systems containing these components are also part of the present invention.

  16. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1996-01-01

    A molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication.

  17. Membrane Separations Research 

    E-Print Network [OSTI]

    Fair, J. R.

    1992-01-01

    been dominated by light gas separations and water purification. During this pioneering period, equipment containing the membrane suIfaces has been developed to a point where failures are minimal and the membranes themselves are sufficiently rugged... of separation technology, especially in the area of gas recovery and purification. The field has grown quite large and the literature is voluminous. There is now a North American Membrane Society and there has been for some years the Journal of Membrane...

  18. Hydrogen separation process

    DOE Patents [OSTI]

    Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

    2011-05-24

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  19. Electokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

    2000-01-01

    A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.

  20. Engineering materials for hydrogen separation

    SciTech Connect (OSTI)

    Moss, T.S.; Dye, R.C.

    1997-02-01

    To address the need for enhanced hydrogen separation techniques using metal membranes, a different fabrication technique was utilized that would overcome these concerns. The objectives for the fabrication were: obtaining a highly clean surface on the refractory foil, forming a palladium coating without subsequent surface contamination, and providing a high degree of purity, crystallinity, and crystallographic orientation. To achieve these objectives, the process of physical vapor deposition was used. Within a high vacuum chamber, both sides of a tantalum or vanadium foil were ion milled to remove the surface oxide and, without ever breaking the vacuum, both sides of the cleaned foil were coated with thin palladium layers. The palladium was deposited using either e-beam evaporation or sputtering. Foils produced by this technique have yielded exceptionally high hydrogen flow rates.

  1. Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration

    SciTech Connect (OSTI)

    Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

    2008-09-30

    The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

  2. Organic Separation Test Results

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

    2014-09-22

    Separable organics have been defined as “those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer” (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be “no visible layer” of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

  3. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1986-01-01

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

  4. Separators for electrochemical cells

    DOE Patents [OSTI]

    Carlson, Steven Allen; Anakor, Ifenna Kingsley

    2014-11-11

    Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

  5. Mesoporous Block Copolymer Battery Separators

    E-Print Network [OSTI]

    Wong, David Tunmin

    2012-01-01

    Xiangyun Song helped me with battery experiments. I want toMesoporous Block Copolymer Battery Separators by DavidMesoporous Block Copolymer Battery Separators by David

  6. Polymide gas separation membranes

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz

    2004-09-14

    Soluble polyamic acid salt (PAAS) precursors comprised of tertiary and quaternary amines, ammonium cations, sulfonium cations, or phosphonium cations, are prepared and fabricated into membranes that are subsequently imidized and converted into rigid-rod polyimide articles, such as membranes with desirable gas separation properties. A method of enhancing solubility of PAAS polymers in alcohols is also disclosed.

  7. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, T.D.

    1996-07-09

    The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

  8. NEAMS safeguards and separations

    SciTech Connect (OSTI)

    Sadasivan, Pratap [Los Alamos National Laboratory; De Paoli, David W [ORNL

    2011-01-25

    This presentation provides a program management update on the Safeguards and Separations Integrated Performance and Safety Code (IPSC) program in the DOE Nuclear Energy Advanced Modeling and Simulation (NEAMS). It provides an overview of FY11 work packages at multiple DOE Labs and includes material on challenge problem definitions for the IPSC effort.

  9. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, Charles L. (Lincoln, MA); He, Bo X. (Newton, MA)

    1990-01-01

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

  10. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, C.L.; He, B.X.

    1990-11-13

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

  11. Membranes for Reverse-Organic Air Separations

    Broader source: Energy.gov [DOE]

    New Membranes Use Reverse Separation to Reduce Pollutant Emissions: Many industrial applications need a process to separate pollutants known as volatile organic compounds (VOCs) from air in order to protect the environment and save energy. One such application is the venting of vapor from underground storage tanks (UST) used in gasoline storage and dispensing. These vapors, which can build up and create high pressure within the UST, contribute to ground-level ozone and smog upon release.

  12. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, R.C.; Kobsa, I.R.

    1994-02-01

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

  13. Advanced Separation Consortium

    SciTech Connect (OSTI)

    NONE

    2006-01-01

    The Center for Advanced Separation Technologies (CAST) was formed in 2001 under the sponsorship of the US Department of Energy to conduct fundamental research in advanced separation and to develop technologies that can be used to produce coal and minerals in an efficient and environmentally acceptable manner. The CAST consortium consists of seven universities - Virginia Tech, West Virginia University, University of Kentucky, Montana Tech, University of Utah, University of Nevada-Reno, and New Mexico Tech. The consortium brings together a broad range of expertise to solve problems facing the US coal industry and the mining sector in general. At present, a total of 60 research projects are under way. The article outlines some of these, on topics including innovative dewatering technologies, removal of mercury and other impurities, and modelling of the flotation process. 1 photo.

  14. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1986-08-15

    The atomic vapor laser isotope separation (AVLIS) process for the enrichment of uranium is evaluated. (AIP)

  15. Performance improvement of Gas-Liquid Cylindrical Cyclone separator using different design for tangential inlet 

    E-Print Network [OSTI]

    Barbuceanu, Nicolae

    2001-01-01

    separators often rely on centrifugal forces to enhance the separation process and are therefore highly dependent on inlet geometry. This paper investigates expanding the operational envelope of a compact Gas-Liquid Cylindrical Cyclone separator through...

  16. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

    1986-01-01

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

  17. Apparatus for electrophoresis separation

    DOE Patents [OSTI]

    Anderson, Norman L. (Willowbrook, IL)

    1978-01-01

    An apparatus is disclosed for simultaneously performing electrophoresis separations on a plurality of slab gels containing samples of protein, protein subunits or nucleic acids. A reservoir of buffer solution is divided into three compartments by two parallel partitions having vertical slots spaced along their length. A sheet of flexible, electrically insulative material is attached to each partition and is provided with vertical slits aligned with the slots. Slab-gel holders are received within the slots with the flexible material folded outwardly as flaps from the slits to overlay portions of the holder surfaces and thereby act as electrical and liquid seals. An elongated, spaghetti-like gel containing a sample of specimen that was previously separated by isoelectric focusing techniques is vertically positioned along a marginal edge portion of the slab gel. On application of an electrical potential between the two outer chambers of buffer solution, a second dimensional electrophoresis separation in accordance with molecular weight occurs as the specimen molecules migrate across the slab gel.

  18. Analysis of Reference Design for Nuclear-Assisted Hydrogen Production at 750°C Reactor Outlet Temperature

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego

    2010-05-01

    The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using a high-temperature gas-cooled reactor (HTGR) to provide the process heat and electricity to drive the electrolysis process. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This report describes the resulting new INL reference design coupled to two alternative HTGR power conversion systems, a Steam Rankine Cycle and a Combined Cycle (a Helium Brayton Cycle with a Steam Rankine Bottoming Cycle). Results of system analyses performed to optimize the design and to determine required plant performance and operating conditions when coupled to the two different power cycles are also presented. A 600 MWt high temperature gas reactor coupled with a Rankine steam power cycle at a thermal efficiency of 44.4% can produce 1.85 kg/s of hydrogen and 14.6 kg/s of oxygen. The same capacity reactor coupled with a combined cycle at a thermal efficiency of 42.5% can produce 1.78 kg/s of hydrogen and 14.0 kg/s of oxygen.

  19. Polymeric battery separators

    SciTech Connect (OSTI)

    Minchak, R. J.; Schenk, W. N.

    1985-06-11

    Configurations of cross-linked or vulcanized amphophilic or quaternized block copolymer of haloalkyl epoxides and hydroxyl terminated alkadiene polymers are useful as battery separators in both primary and secondary batteries, particularly nickel-zinc batteries. The quaternized block copolymers are prepared by polymerizing a haloalkyl epoxide in the presence of a hydroxyl terminated 1,3-alkadiene to form a block copolymer that is then reacted with an amine to form the quaternized or amphophilic block copolymer that is then cured or cross-linked with sulfur, polyamines, metal oxides, organic peroxides and the like.

  20. Cyclic membrane separation process

    DOE Patents [OSTI]

    Nemser, Stuart M.

    2005-05-03

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In the first part of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the second part, the membrane is inoperative while gas pressure rises in the ullage. In one aspect of this invention, a vacuum is drawn in the membrane separation unit thus reducing overall VOC emissions.

  1. Cyclic membrane separation process

    DOE Patents [OSTI]

    Bowser, John

    2004-04-13

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In one of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the other part, the membrane is inoperative while gas pressure rises in the ullage. Ambient air is charged to the membrane separation unit during the latter part of the cycle.

  2. High temperature CO2 perm-selective membranes offer potential for uses in various processes for CO2 separation. Recently, efforts are reported on fabrication of dense ceramic-carbonate dual-phase

    E-Print Network [OSTI]

    separation. Recently, efforts are reported on fabrication of dense ceramic-carbonate dual-phase membranes on transport mechanism demonstrates that gas transport for ceramic- carbonate dual-phase membrane is rate and Characterization of Thin Ceramic-Carbonate Dual-Phase Membranes for Carbon Dioxide Separation Bo Lu Advisor: Jerry

  3. Venous Thoracic Outlet Compression and the Paget-Schroetter Syndrome: A Review and Recommendations for Management

    SciTech Connect (OSTI)

    Thompson, J. F. Winterborn, R. J.; Bays, S.; White, H.; Kinsella, D. C.; Watkinson, A. F.

    2011-10-15

    Paget Schroetter syndrome, or effort thrombosis of the axillosubclavian venous system, is distinct from other forms of upper limb deep vein thrombosis. It occurs in younger patients and often is secondary to competitive sport, music, or strenuous occupation. If untreated, there is a higher incidence of disabling venous hypertension than was previously appreciated. Anticoagulation alone or in combination with thrombolysis leads to a high rate of rethrombosis. We have established a multidisciplinary protocol over 15 years, based on careful patient selection and a combination of lysis, decompressive surgery, and postoperative percutaneous venoplasty. During the past 10 years, a total of 232 decompression procedures have been performed. This article reviews the literature and presents the Exeter Protocol along with practical recommendations for management.

  4. Low pressure hydrocyclone separator

    SciTech Connect (OSTI)

    Flanigan, D.A.; Stolhand, J.E.

    1989-07-04

    This patent describes a method of separating a dispersed phase liquid from a bulk phase liquid of a liquid-liquid mixture, the dispersed phase and bulk phase liquids having different densities. The method comprises the steps of: providing a supply of the liquid-liquid mixture at a first pressure; providing a pump means including means for minimizing degradation of the volumetric means size of droplets of the dispersed phase further including a pump size for maintaining the pump means at substantially near maximum flow rate capacity; pumping the liquid-liquid mixture with at least one pump means to a second pressure such that a differential between the first and second pressures is not substantially greater than a differential pressure at which the pump means begins to substantially degrade the volumetric mean size of droplets of the dispersed phase liquid passing therethrough, the pumping without substantial droplet degradation being achieved by operating the pump means at relatively near its maximum flow rate capacity to substantially reduce on a percentage basis the effect of fluid slippage within the pump means; directing the liquid-liquid mixture from the pump means to a hydrocyclone; and separating a substantial portion of the dispersed phase liquid from the liquid-liquid mixture in the hydrocyclone.

  5. Method for packed column separations and purifications

    DOE Patents [OSTI]

    Holman, David A. (Richland, WA); Bruckner-Lea, Cynthia J. (Richland, WA); Brockman, Fred J. (Kennewick, WA); Chandler, Darrell P. (Richland, WA)

    2006-08-15

    The invention encompasses a method of packing and unpacking a column chamber. A mixture of a fluid and a matrix material are introduced through a column chamber inlet so that the matrix material is packed within a column chamber to form a packed column. The column chamber having the column chamber inlet or first port for receiving the mixture further has an outlet port and an actuator port. The outlet port is partially closed for capturing the matrix material and permitting the fluid to flow therepast by rotating relative one to the other of a rod placed in the actuator port. Further rotation relative one to the other of the rod and the column chamber opens the outlet and permits the matrix material and the fluid to flow therethrough thereby unpacking the matrix material from the column chamber.

  6. Low energy high pressure miniature screw valve

    DOE Patents [OSTI]

    Fischer, Gary J. (Sandia Park, NM); Spletzer, Barry L. (Albuquerque, NM)

    2006-12-12

    A low energy high pressure screw valve having a valve body having an upper portion and a lower portion, said lower portion of said valve body defining an inlet flow passage and an outlet flow passage traversing said valve body to a valve seat, said upper portion of said valve body defining a cavity at said valve seat, a diaphragm restricting flow between said upper portion of said valve body and said lower portion, said diaphragm capable of engaging said valve seat to restrict fluid communication between said inlet passage and said outlet passage, a plunger within said cavity supporting said diaphragm, said plunger being capable of engaging said diaphragm with said valve seat at said inlet and outlet fluid passages, said plunger being in point contact with a drive screw having threads engaged with opposing threads within said upper portion of said valve body such engagement allowing motion of said drive screw within said valve body.

  7. Advanced isotope separation

    SciTech Connect (OSTI)

    Not Available

    1982-05-04

    The Study Group briefly reviewed the technical status of the three Advanced Isotope Separation (AIS) processes. It also reviewed the evaluation work that has been carried out by DOE's Process Evaluation Board (PEB) and the Union Carbide Corporation-Nuclear Division (UCCND). The Study Group briefly reviewed a recent draft assessment made for DOE staff of the nonproliferation implications of the AIS technologies. The staff also very briefly summarized the status of GCEP and Advanced Centrifuge development. The Study Group concluded that: (1) there has not been sufficient progress to provide a firm scientific, technical or economic basis on which to select one of the three competing AIS processes for full-scale engineering development at this time; and (2) however, should budgetary restraints or other factors force such a selection, we believe that the evaluation process that is being carried out by the PEB provides the best basis available for making a decision. The Study Group recommended that: (1) any decisions on AIS processes should include a comparison with gas centrifuge processes, and should not be made independently from the plutonium isotope program; (2) in evaluating the various enrichment processes, all applicable costs (including R and D and sales overhead) and an appropriate discounting approach should be included in order to make comparisons on a private industry basis; (3) if the three AIS programs continue with limited resources, the work should be reoriented to focus only on the most pressing technical problems; and (4) if a decision is made to develop the Atomic Vapor Laser Isotope Separation process, the solid collector option should be pursued in parallel to alleviate the potential program impact of liquid collector thermal control problems.

  8. Method for separating boron isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM)

    1978-01-01

    A method of separating boron isotopes .sup.10 B and .sup.11 B by laser-induced selective excitation and photodissociation of BCl.sub.3 molecules containing a particular boron isotope. The photodissociation products react with an appropriate chemical scavenger and the reaction products may readily be separated from undissociated BCl.sub.3, thus effecting the desired separation of the boron isotopes.

  9. Single Cells as Biosensors for Chemical Separations

    E-Print Network [OSTI]

    Single Cells as Biosensors for Chemical Separations Jason B. Shear,* Harvey A. Fishman, Nancy L. Allbritton,t Delia Garigan, Richard N. Zare,t Richard H. Scheller A biosensor system based on the response sensitivity and selectivity. Biosensors detect chemical species with high selectivity on the basis

  10. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal (Birmingham, AL); Liu, Guohai (Birmingham, AL); Peng, WanWang (Birmingham, AL)

    2010-08-10

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  11. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, P.

    1993-12-28

    A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

  12. Acoustic Telemetry Evaluation of Juvenile Salmonid Passage and Survival at John Day Dam with Emphasis on the Prototype Surface Flow Outlet, 2008

    SciTech Connect (OSTI)

    Weiland, Mark A.; Ploskey, Gene R.; Hughes, James S.; Deng, Zhiqun; Fu, Tao; Monter, Tyrell J.; Johnson, Gary E.; Khan, Fenton; Wilberding, Matthew C.; Cushing, Aaron W.; Zimmerman, Shon A.; Faber, Derrek M.; Durham, Robin E.; Townsend, Richard L.; Skalski, John R.; Kim, Jina; Fischer, Eric S.; Meyer, Matthew M.

    2009-12-01

    The main purpose of the study was to evaluate the performance of Top Spill Weirs installed at two spillbays at John Day Dam and evaluate the effectiveness of these surface flow outlets at attracting juvenile salmon away from the powerhouse and reducing turbine passage. The Juvenile Salmonid Acoustic Telemetry System (JSATS) was used to estimate survival of juvenile salmonids passing the dam and also for calculating performance metrics used to evaluate the efficiency and effectiveness of the dam at passing juvenile salmonids.

  13. Chromatographic Separations of Enantiomers and Underivatized Oligosaccharides

    SciTech Connect (OSTI)

    Ying Liu

    2004-12-19

    My graduate research has focused on separation science and bioanalytical analysis, which emphasized in method development. It includes three major areas: enantiomeric separations using high performance liquid chromatography (HPLC), Super/subcritical fluid chromatography (SFC), and capillary electrophoresis (CE); drug-protein binding behavior studies using CE; and carbohydrate analysis using liquid chromatograph-electrospray ionization mass spectrometry (LC-ESI-MS). Enantiomeric separations continue to be extremely important in the pharmaceutical industry. An in-depth evaluation of the enantiomeric separation capabilities of macrocyclic glycopeptides CSPs with SFC mobile phases was investigated using a set of over 100 chiral compounds. It was found that the macrocyclic based CSPs were able to separate enantiomers of various compounds with different polarities and functionalities. Seventy percent of all separations were achieved in less than 4 min due to the high flow rate (4.0 ml/min) that can be used in SFC. Drug-protein binding is an important process in determining the activity and fate of a drug once it enters the body. Two drug/protein systems have been studied using frontal analysis CE method. More sensitive fluorescence detection was introduced in this assay, which overcame the problem of low sensitivity that is common when using UV detection for drug-protein studies. In addition, the first usage of an argon ion laser with 257 nm beam coupled with CCD camera as a frontal analysis detection method enabled the simultaneous observation of drug fluorescence as well as the protein fluorescence. LC-ESI-MS was used for the separation and characterization of underivatized oligosaccharide mixtures. With the limits of detection as low as 50 picograms, all individual components of oligosaccharide mixtures (up to 11 glucose-units long) were baseline resolved on a Cyclobond I 2000 column and detected using ESI-MS. This system is characterized by high chromatographic resolution, high column stability, and high sensitivity. In addition, this method showed potential usefulness for the sensitive and quick analysis of hydrolysis products of polysaccharides, and for trace level analysis of individual oligosaccharides or oligosaccharide isomers from biological systems.

  14. Separation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Perry, Steven T. (Galloway, OH); Arora, Ravi (Dublin, OH); Qiu, Dongming (Bothell, WA); Lamont, Michael Jay (Hilliard, OH); Burwell, Deanna (Cleveland Heights, OH); Dritz, Terence Andrew (Worthington, OH); McDaniel, Jeffrey S. (Columbus, OH); Rogers, Jr.; William A. (Marysville, OH); Silva, Laura J. (Dublin, OH); Weidert, Daniel J. (Lewis Center, OH); Simmons, Wayne W. (Dublin, OH); Chadwell, G. Bradley (Reynoldsburg, OH)

    2009-03-24

    The disclosed invention relates to a process and apparatus for separating a first fluid from a fluid mixture comprising the first fluid. The process comprises: (A) flowing the fluid mixture into a microchannel separator in contact with a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the first fluid is sorbed by the sorption medium, removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing first fluid from the sorption medium and removing desorbed first fluid from the microchannel separator. The process and apparatus are suitable for separating nitrogen or methane from a fluid mixture comprising nitrogen and methane. The process and apparatus may be used for rejecting nitrogen in the upgrading of sub-quality methane.

  15. Novel, Ceramic Membrane System For Hydrogen Separation

    SciTech Connect (OSTI)

    Elangovan, S.

    2012-12-31

    Separation of hydrogen from coal gas represents one of the most promising ways to produce alternative sources of fuel. Ceramatec, teamed with CoorsTek and Sandia National Laboratories has developed materials technology for a pressure driven, high temperature proton-electron mixed conducting membrane system to remove hydrogen from the syngas. This system separates high purity hydrogen and isolates high pressure CO{sub 2} as the retentate, which is amenable to low cost capture and transport to storage sites. The team demonstrated a highly efficient, pressure-driven hydrogen separation membrane to generate high purity hydrogen from syngas using a novel ceramic-ceramic composite membrane. Recognizing the benefits and limitations of present membrane systems, the all-ceramic system has been developed to address the key technical challenges related to materials performance under actual operating conditions, while retaining the advantages of thermal and process compatibility offered by the ceramic membranes. The feasibility of the concept has already been demonstrated at Ceramatec. This project developed advanced materials composition for potential integration with water gas shift rectors to maximize the hydrogenproduction.

  16. Gas separation membrane module assembly

    DOE Patents [OSTI]

    Wynn, Nicholas P (Palo Alto, CA); Fulton, Donald A. (Fairfield, CA)

    2009-03-31

    A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains a tube sheet that divides the space within the housing into two gas-tight spaces. A permeate collection system within the housing gathers permeate gas from the tubes for discharge from the housing.

  17. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation, and plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the elective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to form an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of dvelopment, cost, advantages and drawbacks of the five processes, (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  18. Laser separation of uranium chosen for scaleup. [Atomic vapor laser isotope separation, molecular laser isotope separation plasma separation process

    SciTech Connect (OSTI)

    Rawls, R.L.

    1982-05-17

    Atomic vapor laser isotope separation (AVLIS) has been selected by the Department of Energy to go into large-scale engineering development and demonstration over two other advanced technologies, molecular laser isotope separation and plasma separation. DOE will continue to support development of another uranium enrichment technology, gas centrifugation. By or around 1990, the most promising gas centrifuge technique will be compared to the further developed AVLIS process, and a selection will be made between the two to replace the current technology, gaseous diffusion. The AVLIS process, plasma separation, and molecular laser isotope separation use the selective absorption of radiation of a particular energy level by the /sup 235/U isotope. The plasma separation process selectively energizes /sup 235/U by ion cyclotron resonance. The AVLIS and molecular laser isotope separation processes both use a carefully tuned laser to excite /sup 235/U isotope selectively. In the AVLIS process, uranium metal feed material is melted and vaporized to from an atomic uranium vapor stream. When this vapor stream passes through the beam of copper vapor lasers, the /sup 235/U atoms absorb the light and become ionized. These ionized atoms are collected by electromagnetic fields while the neutral /sup 238/U atoms pass through the magnetic field and are collected as tailings. The AVLIS process has the potential for significantly reducing the cost of enriching uranium. The status of development, cost, advantages and drawbacks of the five processes (gaseous diffusion, gas centrifugation, AVLIS, molecular laser separation, plasma separation) are discussed. (ATT)

  19. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, Wendy R. (1166 Laurel Loop NE., Albuquerque, NM 87122); Storz, Leonard J. (2215 Ambassador NE., Albuquerque, NM 87112)

    1991-01-01

    An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  20. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, W.R.; Storz, L.J.

    1991-03-26

    An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  1. Three phase downhole separator process

    DOE Patents [OSTI]

    Cognata, Louis John (Baytown, TX)

    2008-06-24

    Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

  2. Vision 2020: 2000 Separations Roadmap

    SciTech Connect (OSTI)

    Adler, Stephen; Beaver, Earl; Bryan, Paul; Robinson, Sharon; Watson, Jack

    2000-01-01

    This report documents the results of four workshops on the technology barriers, research needs, and priorities of the chemical, agricultural, petroleum, and pharmaceutical industries as they relate to separation technologies utilizing adsorbents, crystallization, distillation, extraction, membranes, separative reactors, ion exchange, bioseparations, and dilute solutions.

  3. Aquagel electrode separator for use in batteries and supercapacitors

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1995-03-28

    An electrode separator is described for electrochemical energy storage devices, such as a high energy density capacitor incorporating a variety of carbon foam electrodes. The separator is derived from an aquagel of resorcinol-formaldehyde and related polymers and containing ionically conducting electrolyte in the pores thereof. 9 figures.

  4. Aquagel electrode separator for use in batteries and supercapacitors

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1995-01-01

    An electrode separator for electrochemical energy storage devices, such as a high energy density capacitor incorporating a variety of carbon foam electrodes. The separator is derived from an aquagel of resorcinol-formaldehyde and related polymers and containing ionically conducting electrolyte in the pores thereof.

  5. Microdialysis unit for molecular weight separation

    DOE Patents [OSTI]

    Smith, Richard D. (Richland, WA); Liu, Chuanliang (Richland, WA)

    1999-01-01

    The present invention relates generally to an apparatus and method for separating high molecular weight molecules from low molecular weight molecules. More specifically, the invention relates to the use of microdialysis for removal of the salt (low molecular weight molecules) from a nucleotide sample (high molecular weight molecules) for ESI-MS analysis. The dialysis or separation performance of the present invention is improved by (1) increasing dialysis temperature thereby increasing desalting efficiency and improving spectrum quality; (2) adding piperidine and imidazole to the dialysis buffer solution and reducing charge states and further increasing detection sensitivity for DNA; (3) using low concentrations (0-2.5 mM NH4OAc) of dialysis buffer and shifting the DNA negative ions to higher charge states, producing a nearly 10-fold increase in detection sensitivity and a slightly decreased desalting efficiency, or (4) any combination of (1), (2), and (3).

  6. Robust Polymer Composite Membranes for Hydrogen Separation |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Robust Polymer Composite Membranes for Hydrogen Separation Robust Polymer Composite Membranes for Hydrogen Separation polymercompositemembranes.pdf More Documents & Publications...

  7. Particle separating apparatus and method

    DOE Patents [OSTI]

    Van den Engh, Gerrit J. (Seattle, WA)

    1999-01-01

    A disposable first tube (68) extends axially through, and is detachably connected to, an annular main body (10'). An input piezo electric element (38) is attached to a first end of the tubular main body (10'). A second, sensor piezo electric element (40) is attached to the opposite end of the main body (10'). A nozzle (20') having a nozzle passageway (110) and a discharge opening (112) is detachably secured to an outlet end of the first tube (68). A second tube (102) within the first tube (68) delivers a core liquid to the nozzle passageway (110). A sheath liquid is delivered through a space in the first tube (68) surrounding the second tube (102). The nozzle passageway (110) forms the core and sheath liquids into a small diameter jet stream. Electrical energy is delivered to the input piezo electric element (38), to vibrate the nozzle (20') and break the jet stream into droplets. The sensor element (40) determines the amplitude of vibration at the nozzle (20') and delivers this information to a control circuit that adjusts the electrical energy input to the input piezo electric element (38) for maintaining a desired amplitude of vibration at the nozzle (20'). The frequency of vibration is determined by the length of the main body (10') between the two piezo electric elements (38, 40). The first and second tubes (68, 102) are disposable and are replaced after a use rather than being cleaned and sterilized.

  8. Particle separating apparatus and method

    DOE Patents [OSTI]

    Van den Engh, Gerrit J. (9756 49th Ave. NE., Seattle, WA 98195)

    1998-01-01

    A disposable first tube (68) extends axially through, and is detachably connected to, an annular main body (10'). An input piezo electric element (38) is attached to a first end of the tubular main body (10'). A second, sensor piezo electric element (40) is attached to the opposite end of the main body (10'). A nozzle (20') having a nozzle passageway (110) and a discharge opening (112) is detachably secured to an outlet end of the first tube (68). A second tube (102) within the first tube (68) delivers a core liquid to the nozzle passageway (110). A sheath liquid is delivered through a space in the first tube (68) surrounding the second tube (102). The nozzle passageway (110) forms the core and sheath liquids into a small diameter jet stream. Electrical energy is delivered to the input piezo electric element (38), to vibrate the nozzle (20') and break the jet stream into droplets. The sensor element (40) determines the amplitude of vibration at the nozzle (20') and delivers this information to a control circuit that adjusts the electrical energy input to the input piezo electric element (38) for maintaining a desired amplitude of vibration at the nozzle (20'). The frequency of vibration is determined by the length of the main body (10') between the two piezo electric elements (38, 40). The first and second tubes (68, 102) are disposable and are replaced after a use rather than being cleaned and sterilized.

  9. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  10. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

    1997-01-01

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  11. Activated Carbon Composites for Air Separation

    SciTech Connect (OSTI)

    Contescu, Cristian I [ORNL; Baker, Frederick S [ORNL; Tsouris, Costas [ORNL; McFarlane, Joanna [ORNL

    2008-03-01

    In continuation of the development of composite materials for air separation based on molecular sieving properties and magnetic fields effects, several molecular sieve materials were tested in a flow system, and the effects of temperature, flow conditions, and magnetic fields were investigated. New carbon materials adsorbents, with and without pre-loaded super-paramagnetic nanoparticles of Fe3O4 were synthesized; all materials were packed in chromatographic type columns which were placed between the poles of a high intensity, water-cooled, magnet (1.5 Tesla). In order to verify the existence of magnetodesorption effect, separation tests were conducted by injecting controlled volumes of air in a flow of inert gas, while the magnetic field was switched on and off. Gas composition downstream the column was analyzed by gas chromatography and by mass spectrometry. Under the conditions employed, the tests confirmed that N2 - O2 separation occurred at various degrees, depending on material's intrinsic properties, temperature and flow rate. The effect of magnetic fields, reported previously for static conditions, was not confirmed in the flow system. The best separation was obtained for zeolite 13X at sub-ambient temperatures. Future directions for the project include evaluation of a combined system, comprising carbon and zeolite molecular sieves, and testing the effect of stronger magnetic fields produced by cryogenic magnets.

  12. Fluorine separation and generation device

    DOE Patents [OSTI]

    Jacobson, Craig P. (Moraga, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA); Stefan, Constantin I. (Hayward, CA)

    2010-03-02

    A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

  13. Fluorine separation and generation device

    DOE Patents [OSTI]

    The Regents of the University of California (Oakland, CA)

    2008-12-23

    A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

  14. Fluorine separation and generation device

    DOE Patents [OSTI]

    Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.; Stefan, Constantin I.

    2006-08-15

    A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

  15. Development of an Electrochemical Separator and Compressor

    SciTech Connect (OSTI)

    Trent Molter

    2011-04-28

    Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

  16. Freeze Crystallization: Improving the Energy Efficiency of a Low-Energy Separation Process 

    E-Print Network [OSTI]

    Heist, J. A.

    1981-01-01

    for that process. Freeze crystallization is a high energy efficiency separation process that can be applied to a wide variety of industrial requirements. It is demonstrated here that membrane processes are the only separation technology that can approach freezing...

  17. Experimental study of the effects of wakes on separation in low pressure turbine flow 

    E-Print Network [OSTI]

    O?ztu?rk, Burak

    2003-01-01

    the underlying physics of the inception, onset, and extent of the separation zone. A detailed experimental study on the behavior of the separation zone on the suction surface of a highly loaded LPTblade under periodic unsteady wake flow is presented...

  18. Conjugates of Actinide Chelator-Magnetic Nanoparticles for Used Fuel Separation Technology

    SciTech Connect (OSTI)

    Qiang, You; Paszczynski, Andrzej; Rao, Linfeng

    2011-10-30

    The actinide separation method using magnetic nanoparticles (MNPs) functionalized with actinide specific chelators utilizes the separation capability of ligand and the ease of magnetic separation. This separation method eliminated the need of large quantity organic solutions used in the liquid-liquid extraction process. The MNPs could also be recycled for repeated separation, thus this separation method greatly reduces the generation of secondary waste compared to traditional liquid extraction technology. The high diffusivity of MNPs and the large surface area also facilitate high efficiency of actinide sorption by the ligands. This method could help in solving the nuclear waste remediation problem.

  19. TRITIUM BARRIER MATERIALS AND SEPARATION SYSTEMS FOR THE NGNP

    SciTech Connect (OSTI)

    Sherman, S; Thad Adams, T

    2008-07-17

    Contamination of downstream hydrogen production plants or other users of high-temperature heat is a concern of the Next Generation Nuclear Plant (NGNP) Project. Due to the high operating temperatures of the NGNP (850-900 C outlet temperature), tritium produced in the nuclear reactor can permeate through heat exchangers to reach the hydrogen production plant, where it can become incorporated into process chemicals or the hydrogen product. The concentration limit for tritium in the hydrogen product has not been established, but it is expected that any future limit on tritium concentration will be no higher than the air and water effluent limits established by the NRC and the EPA. A literature survey of tritium permeation barriers, capture systems, and mitigation measures is presented and technologies are identified that may reduce the movement of tritium to the downstream plant. Among tritium permeation barriers, oxide layers produced in-situ may provide the most suitable barriers, though it may be possible to use aluminized surfaces also. For tritium capture systems, the use of getters is recommended, and high-temperature hydride forming materials such as Ti, Zr, and Y are suggested. Tritium may also be converted to HTO in order to capture it on molecular sieves or getter materials. Counter-flow of hydrogen may reduce the flux of tritium through heat exchangers. Recommendations for research and development work are provided.

  20. Engine having a high pressure hydraulic system and low pressure lubricating system

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2000-01-01

    An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

  1. High flux reactor

    DOE Patents [OSTI]

    Lake, James A. (Idaho Falls, ID); Heath, Russell L. (Idaho Falls, ID); Liebenthal, John L. (Idaho Falls, ID); DeBoisblanc, Deslonde R. (Summit, NJ); Leyse, Carl F. (Idaho Falls, ID); Parsons, Kent (Idaho Falls, ID); Ryskamp, John M. (Idaho Falls, ID); Wadkins, Robert P. (Idaho Falls, ID); Harker, Yale D. (Idaho Falls, ID); Fillmore, Gary N. (Idaho Falls, ID); Oh, Chang H. (Idaho Falls, ID)

    1988-01-01

    A high flux reactor is comprised of a core which is divided into two symetric segments housed in a pressure vessel. The core segments include at least one radial fuel plate. The spacing between the plates functions as a coolant flow channel. The core segments are spaced axially apart such that a coolant mixing plenum is formed between them. A channel is provided such that a portion of the coolant bypasses the first core section and goes directly into the mixing plenum. The outlet coolant from the first core segment is mixed with the bypass coolant resulting in a lower inlet temperature to the lower core segment.

  2. Phosphazene membranes for gas separations

    DOE Patents [OSTI]

    Stewart, Frederick F.; Harrup, Mason K.; Orme, Christopher J.; Luther, Thomas A.

    2006-07-11

    A polyphosphazene having a glass transition temperature ("T.sub.g") of approximately -20.degree. C. or less. The polyphosphazene has at least one pendant group attached to a backbone of the polyphosphazene, wherein the pendant group has no halogen atoms. In addition, no aromatic groups are attached to an oxygen atom that is bound to a phosphorus atom of the backbone. The polyphosphazene may have a T.sub.g ranging from approximately -100.degree. C. to approximately -20.degree. C. The polyphosphazene may be selected from the group consisting of poly[bis-3-phenyl-1-propoxy)phosphazene], poly[bis-(2-phenyl-1-ethoxy)phosphazene], poly[bis-(dodecanoxypolyethoxy)-phosphazene], and poly[bis-(2-(2-(2-.omega.-undecylenyloxyethoxy)ethoxy)ethoxy)phosphazene]- . The polyphosphazene may be used in a separation membrane to selectively separate individual gases from a gas mixture, such as to separate polar gases from nonpolar gases in the gas mixture.

  3. Atomic vapor laser isotope separation

    SciTech Connect (OSTI)

    Stern, R.C.; Paisner, J.A.

    1985-11-08

    Atomic vapor laser isotope separation (AVLIS) is a general and powerful technique. A major present application to the enrichment of uranium for light-water power reactor fuel has been under development for over 10 years. In June 1985 the Department of Energy announced the selection of AVLIS as the technology to meet the nation's future need for the internationally competitive production of uranium separative work. The economic basis for this decision is considered, with an indicated of the constraints placed on the process figures of merit and the process laser system. We then trace an atom through a generic AVLIS separator and give examples of the physical steps encountered, the models used to describe the process physics, the fundamental parameters involved, and the role of diagnostic laser measurements.

  4. Noise suppressing capillary separation system

    DOE Patents [OSTI]

    Yeung, Edward S. (Ames, IA); Xue, Yongjun (Norwich, NY)

    1996-07-30

    A noise-suppressing capillary separation system for detecting the real-time presence or concentration of an analyte in a sample is provided. The system contains a capillary separation means through which the analyte is moved, a coherent light source that generates a beam which is split into a reference beam and a sample beam that irradiate the capillary, and a detector for detecting the reference beam and the sample beam light that transmits through the capillary. The laser beam is of a wavelength effective to be absorbed by a chromophore in the capillary. The system includes a noise suppressing system to improve performance and accuracy without signal averaging or multiple scans.

  5. Membrane Separations of Liquid Mixtures 

    E-Print Network [OSTI]

    Lloyd, D. R.

    1985-01-01

    , respectively. 147 A membrane (defined below) can be used to separate gas-phase mixtures and liquid-phase mixtures. This paper deals almost exclusively with the latter - a catagory of separation that includes dissolved and suspended solids in liquids... valuable. I ESL-IE-85-05-27 Proceedings from the Seventh National Industrial Energy Technology Conference, Houston, TX, May 12-15, 1985 The membrane may be a gas [56 L a liquid [57,15], or a solid [11-23]. Solid polymeric membranes,and to a lesser extent...

  6. Energy Conservation Possibilities Using Gas Separating Membranes 

    E-Print Network [OSTI]

    Knieriem, H.; Henis, J. M. S.

    1980-01-01

    The separation of gases using semi permeable membranes is a viable unit operation. A novel composite membrane combined with hollow fiber spinning technology enable Monsanto Co. to offer PRISM (TM); Separators to the industrial market. The separator...

  7. Separation of gas mixtures by thermoacoustic waves.

    SciTech Connect (OSTI)

    Swift, G. W.; Geller, D. A.

    2001-01-01

    Imposing sound on a binary gas mixture in a duct separates the two gases along the acoustic-propagation axis. Mole-fraction differences as large as 10% and separation fluxes as high as 0.001 M-squared c, where M is Mach number and c is sound speed, are easily observed. We describe the accidental discovery of this phenomenon in a helium-xenon mixture, subsequent experiments with a helium-argon mixture, and theoretical developments. The phenomenon occurs because a thin layer of the gas adjacent to the wall is immobilized by viscosity while the rest of the gas moves back and forth with the wave, and the heat capacity of the wall holds this thin layer of the gas at constant temperature while the rest of the gas experiences temperature oscillations due to the wave's oscillating pressure. The oscillating temperature gradient causes the light and heavy atoms in the gas to take turns diffusing into and out of the immobilized layer, so that the oscillating motion of the wave outside the immobilized layer tends to carry light-enriched gas in one direction and heavy-enriched gas in the opposite direction. Experiment and theory are in very good agreement for the initial separation fluxes and the saturation mole-fraction differences.

  8. SEPARATION OF GAS MIXTURES BY THERMOACOUSTIC WAVES

    SciTech Connect (OSTI)

    G.W. SWIFT; D.A. GELLER; P.S. SPOOR

    2001-06-01

    Imposing sound on a binary gas mixture in a duct separates the two gases along the acoustic-propagation axis. Mole-fraction differences as large as 10% and separation fluxes as high as 0.001 M-squared c, where M is Mach number and c is sound speed, are easily observed. We describe the accidental discovery of this phenomenon in a helium-xenon mixture, subsequent experiments with a helium-argon mixture, and theoretical developments. The phenomenon occurs because a thin layer of the gas adjacent to the wall is immobilized by viscosity while the rest of the gas moves back and forth with the wave, and the heat capacity of the wall holds this thin layer of the gas at constant temperature while the rest of the gas experiences temperature oscillations due to the wave's oscillating pressure. The oscillating temperature gradient causes the light and heavy atoms in the gas to take turns diffusing into and out of the immobilized layer, so that the oscillating motion of the wave outside the immobilized layer tends to carry light-enriched gas in one direction and heavy-enriched gas in the opposite direction. Experiment and theory are in very good agreement for the initial separation fluxes and the saturation mole-fraction differences.

  9. 33rd Actinide Separations Conference

    SciTech Connect (OSTI)

    McDonald, L M; Wilk, P A

    2009-05-04

    Welcome to the 33rd Actinide Separations Conference hosted this year by the Lawrence Livermore National Laboratory. This annual conference is centered on the idea of networking and communication with scientists from throughout the United States, Britain, France and Japan who have expertise in nuclear material processing. This conference forum provides an excellent opportunity for bringing together experts in the fields of chemistry, nuclear and chemical engineering, and actinide processing to present and discuss experiences, research results, testing and application of actinide separation processes. The exchange of information that will take place between you, and other subject matter experts from around the nation and across the international boundaries, is a critical tool to assist in solving both national and international problems associated with the processing of nuclear materials used for both defense and energy purposes, as well as for the safe disposition of excess nuclear material. Granlibakken is a dedicated conference facility and training campus that is set up to provide the venue that supports communication between scientists and engineers attending the 33rd Actinide Separations Conference. We believe that you will find that Granlibakken and the Lake Tahoe views provide an atmosphere that is stimulating for fruitful discussions between participants from both government and private industry. We thank the Lawrence Livermore National Laboratory and the United States Department of Energy for their support of this conference. We especially thank you, the participants and subject matter experts, for your involvement in the 33rd Actinide Separations Conference.

  10. Whats Inside: Termination/Separation

    E-Print Network [OSTI]

    had responsibility for biological materi- als, biohazards, infectious substances, select agents andShield Member Handbooks Available Online Admin/Computer Seminars Important Contacts · · · · · · INSIDE HUMAN/or radiological materials and hazardous wastes. Please remember that separation Employment Action (EA) forms

  11. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  12. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  13. Optimization of multigravity separation for recovery of ultrafine coal

    SciTech Connect (OSTI)

    Menendez, M.; Gent, M.; Torano, J.; Diego, I. [University of Oviedo, Oviedo (Spain)

    2007-11-15

    Enhanced gravity separation appears to be one of the most promising methods for processing all types of < 200-{mu}m coal feeds and tailings. Systems based on this technology are reviewed, and the results of investigations based on C900 Multi-Gravity Separator tests conducted to assess the treatment of < 200-{mu}m, extremely difficult-to-wash coal settling pond tailings are presented. Multi-Gravity Separator processing tests of ultra-fine tailings with a high clay particle size content (22.6% < 10 {mu}m and 60.1 % < 40 {mu}m) and a 69.56% ash content show that this material can be effectively treated after desliming (< 10 {mu}m) of clay-size particles to produce a coal with a 20.6% ash at a separator combustible material recovery of 69.3 %. Desliming is shown to be critical in reducing coal ash content and combustible material recovery. Similar improvements are anticipated in the recovery and separation processes for other enhanced gravity separation systems from the desliming of feeds. Although not a conventional form of treating Multi-Gravity Separator data, the existence of well-defined polynomial relationships based on the product of drum shake amplitude and shake frequency relative to product coal recovery, product ash content and yields at varying wash water flows is demonstrated. Low-amplitude and intermediate-to high-frequency bed agitation are shown to produce optimum ash reduction results.

  14. Separating the Minor Actinides Through Advances in Selective Coordination Chemistry

    SciTech Connect (OSTI)

    Lumetta, Gregg J.; Braley, Jenifer C.; Sinkov, Sergey I.; Carter, Jennifer C.

    2012-08-22

    This report describes work conducted at the Pacific Northwest National Laboratory (PNNL) in Fiscal Year (FY) 2012 under the auspices of the Sigma Team for Minor Actinide Separation, funded by the U.S. Department of Energy Office of Nuclear Energy. Researchers at PNNL and Argonne National Laboratory (ANL) are investigating a simplified solvent extraction system for providing a single-step process to separate the minor actinide elements from acidic high-level liquid waste (HLW), including separating the minor actinides from the lanthanide fission products.

  15. Freezing and phase separation of self-propelled disks

    E-Print Network [OSTI]

    Yaouen Fily; Silke Henkes; M. Cristina Marchetti

    2013-09-15

    We study numerically a model of non-aligning self-propelled particles interacting through steric repulsion, which was recently shown to exhibit active phase separation in two dimensions in the absence of any attractive interaction or breaking of the orientational symmetry. We construct a phase diagram in terms of activity and packing fraction and identify three distinct regimes: a homogeneous liquid with anomalous cluster size distribution, a phase-separated state both at high and at low density, and a frozen phase. We provide a physical interpretation of the various regimes and develop scaling arguments for the boundaries separating them.

  16. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  17. Novel devices for analytical-scale isoelectric trapping separations 

    E-Print Network [OSTI]

    Lim, Peniel Jason

    2009-05-15

    of the separation time????????????????????. 37 Figure 22 CE analysis of the cathode compartment as a function of the separation time????????????????????. 38 Figure 23 Concentration of BzS - and BzTMA + in the anode and cathode compartments, respectively...-polyamino compounds known as carrier ampholytes (CA) and placed in between the anode and the cathode [4-5]. Carrier ampholytes have high buffering capacity at their individual isoelectric points and adequate conductivity in the vicinity of their pI to carry...

  18. Engine with hydraulic fuel injection and ABS circuit using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2001-01-01

    An engine system comprises a hydraulically actuated fuel injection system and an ABS circuit connected via a fluid flow passage that provides hydraulic fluid to both the fuel injection system and to the ABS circuit. The hydraulically actuated system includes a high pressure pump. The fluid control passage is in fluid communication with an outlet from the high pressure pump.

  19. Noise suppressing capillary separation system

    DOE Patents [OSTI]

    Yeung, E.S.; Xue, Y.

    1996-07-30

    A noise-suppressing capillary separation system for detecting the real-time presence or concentration of an analyte in a sample is provided. The system contains a capillary separation means through which the analyte is moved, a coherent light source that generates a beam which is split into a reference beam and a sample beam that irradiate the capillary, and a detector for detecting the reference beam and the sample beam light that transmits through the capillary. The laser beam is of a wavelength effective to be absorbed by a chromophore in the capillary. The system includes a noise suppressing system to improve performance and accuracy without signal averaging or multiple scans. 13 figs.

  20. Dispersoid separation method and apparatus

    DOE Patents [OSTI]

    Winsche, Warren E. (Bellport, NY)

    1980-01-01

    Improved separation of heavier material from a dispersoid of gas and heavier material entrained therein is taught by the method of this invention which advantageously uses apparatus embodied in an inertial separator having rotary partition means comprising wall members dividing a housing into a plurality of axially-extending through passages arranged in parallel. Simultaneously with the helical transit of a moving stream of the dispersoid through the parallel arrangement of axially-extending through passages at a constant angular velocity, the heavier material is driven radially to the collecting surfaces of the rotational wall members where it is collected while the wall members are rotating at the same angular velocity as the moving stream. The plurality of wall members not only provides an increased area of collecting surfaces but the positioning of each of the wall members according to the teaching of this invention also results in a shortened time-of-flight to the collecting surfaces.

  1. Four Degrees of Separation, Really

    E-Print Network [OSTI]

    Boldi, Paolo

    2012-01-01

    We recently measured the average distance of users in the Facebook graph, spurring comments in the scientific community as well as in the general press ("Four Degrees of Separation"). A number of interesting criticisms have been made about the meaningfulness, methods and consequences of the experiment we performed. In this paper we want to discuss some methodological aspects that we deem important to underline in the form of answers to the questions we have read in newspapers, magazines, blogs, or heard from colleagues. We indulge in some reflections on the actual meaning of "average distance" and make a number of side observations showing that, yes, 3.74 "degrees of separation" are really few.

  2. Molecular separation method and apparatus

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (3108 Roses Run, Aiken, SC 29803)

    1996-01-01

    A method and apparatus for separating a gaseous mixture of chemically identical but physically different molecules based on their polarities. The gaseous mixture of molecules is introduced in discrete quantities into the proximal end of a porous glass molecular. The molecular sieve is exposed to microwaves to excite the molecules to a higher energy state from a lower energy state, those having a higher dipole moment being excited more than those with a lower energy state. The temperature of the sieve kept cold by a flow of liquid nitrogen through a cooling jacket so that the heat generated by the molecules colliding with the material is transferred away from the material. The molecules thus alternate between a higher energy state and a lower one, with the portion of molecules having the higher dipole moment favored over the others. The former portion can then be extracted separately from the distal end of the molecular sieve.

  3. Convex polytopes and quantum separability

    SciTech Connect (OSTI)

    Holik, F.; Plastino, A.

    2011-12-15

    We advance a perspective of the entanglement issue that appeals to the Schlienz-Mahler measure [Phys. Rev. A 52, 4396 (1995)]. Related to it, we propose a criterium based on the consideration of convex subsets of quantum states. This criterium generalizes a property of product states to convex subsets (of the set of quantum states) that is able to uncover an interesting geometrical property of the separability property.

  4. Method to blend separator powders

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM); Andazola, Arthur H. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM)

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  5. Supported liquid membrane electrochemical separators

    DOE Patents [OSTI]

    Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

    1986-01-01

    Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

  6. Apparatus and method for separating constituents

    DOE Patents [OSTI]

    Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

    1992-01-01

    A centrifugal separator apparatus and method for improving the efficiency of the separation of constituents in a fluid stream. A cyclone separator includes an assembly for separately discharging both constituents through the same end of the separator housing. A rotary separator includes a rotary housing having a baffle disposed therein for minimizing the differential rotational velocities of the constituents in the housing, thereby decreasing turbulence, and increasing efficiency. The intensity of the centrifugal force and the time which the constituents reside within the housing can be independently controlled to improve efficiency of separation.

  7. Anisotropic membranes for gas separation

    DOE Patents [OSTI]

    Gollan, Arye Z. (Newton, MA)

    1987-01-01

    A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.

  8. Anisotropic membranes for gas separation

    DOE Patents [OSTI]

    Gollan, A.Z.

    1987-07-21

    A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7--25 C and then air dried at ambient temperature, typically 10--30 C. 2 figs.

  9. Laser separation of medical isotopes

    SciTech Connect (OSTI)

    Eerkens, J.W.; Puglishi, D.A.; Miller, W.H.

    1996-12-31

    There is an increasing demand for different separated isotopes as feed material for reactor and cyclotron-produced radioisotopes used by a fast-growing radiopharmaceutical industry. One new technology that may meet future demands for medical isotopes is molecular laser isotope separation (MLIS). This method was investigated for the enrichment of uranium in the 1970`s and 1980s by Los Alamos National Laboratory, Isotope Technologies, and others around the world. While South Africa and Japan have continued the development of MLIS for uranium and are testing pilot units, around 1985 the United States dropped the LANL MLIS program in favor of AVLIS (atomic vapor LIS), which uses electron-beam-heated uranium metal vapor. AVLIS appears difficult and expensive to apply to most isotopes of medical interest, however, whereas MLIS technology, which is based on cooled hexafluorides or other gaseous molecules, can be adapted more readily. The attraction of MLIS for radiopharmaceutical firms is that it allows them to operate their own dedicated separators for small-quantity productions of critical medical isotopes, rather than having to depend on large enrichment complexes run by governments, which are only optimal for large-quantity productions. At the University of Missouri, the authors are investigating LIS of molybdenum isotopes using MoF{sub 6}, which behaves in a way similar to UF{sub 6}, studied in the past.

  10. Pulsed CO laser for isotope separation of uranium

    SciTech Connect (OSTI)

    Baranov, Igor Y.; Koptev, Andrey V. [Rocket-Space Technics Department, Baltic State Technical University, 1, 1st Krasnoarmeyskaya st.,St. Petersburg, 190005 (Russian Federation)

    2012-07-30

    This article proposes a technical solution for using a CO laser facility for the industrial separation of uranium used in the production of fuel for nuclear power plants, employing a method of laser isotope separation of uranium with condensation repression in a free jet. The laser operation with nanosecond pulse irradiation can provide an acceptable efficiency in the separating unit and a high efficiency of the laser with the wavelength of 5.3 {mu}m. In the present work we also introduce a calculation model and define the parameters of a mode-locked CO laser with a RF discharge in the supersonic stream. The average pulsed CO laser power of 3 kW is sufficient for efficient industrial isotope separation of uranium in one stage.

  11. 2/1/2014 Micro-Windmills Could Power Cell Phones Without Outlets | PopVulture Entertainment Network http://www.popvltr.com/2014/01/micro-windmills-could-power-cell-phones.html 1/3

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    2/1/2014 Micro-Windmills Could Power Cell Phones Without Outlets | PopVulture Entertainment Network http://www.popvltr.com/2014/01/micro-windmills-could-power-cell-phones.html 1/3 3 weeks ago [http-rao-chiao.php] electrical engineering professor designed a micro-windmill that might render urine-powered phones completely

  12. Clustering of exponentially separating trajectories

    E-Print Network [OSTI]

    M. Wilkinson; B. Mehlig; K. Gustavsson; E. Werner

    2010-01-16

    It might be expected that trajectories for a dynamical system which has no negative Lyapunov exponent (implying exponential growth of small separations will not cluster together. However, clustering can occur such that the density $\\rho(\\Delta x)$ of trajectories within distance $\\Delta x$ of a reference trajectory has a power-law divergence, so that $\\rho(\\Delta x)\\sim \\Delta x^{-\\beta}$ when $\\Delta x$ is sufficiently small, for some $0<\\beta<1$. We demonstrate this effect using a random map in one dimension. We find no evidence for this effect in the chaotic logistic map, and argue that the effect is harder to observe in deterministic maps.

  13. Uranium molecular laser isotope separation

    SciTech Connect (OSTI)

    Jensen, R.J.; Sullivan, A.

    1982-01-01

    The Molecular Laser Isotope Separation program is moving into the engineering phase, and it is possible to determine in some detail the plant cost terms involved in the process economics. A brief description of the MLIS process physics is given as a motivation to the engineering and economics discussion. Much of the plant cost arises from lasers and the overall optical system. In the paper, the authors discuss lasers as operating units and systems, along with temporal multiplexing and Raman shifting. Estimates of plant laser costs are given.

  14. Separation of actinides from lanthanides

    DOE Patents [OSTI]

    Smith, B.F.; Jarvinen, G.D.; Ryan, R.R.

    1988-03-31

    An organic extracting solution and an extraction method useful for separating elements of the actinide series of the periodic table from elements of the lanthanide series, where both are in trivalent form is described. The extracting solution consists of a primary ligand and a secondary ligand, preferably in an organic solvent. The primary ligand is a substituted monothio-1,3-dicarbonyl, which includes a substituted 4-acyl-2-pyrazolin-5-thione, such as 4-benzoyl-2,4- dihydro-5-methyl-2-phenyl-3H-pyrazol-3-thione (BMPPT). The secondary ligand is a substituted phosphine oxide, such as trioctylphosphine oxide (TOPO).

  15. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, A.K.

    1984-09-07

    This disclosure relates to separation of aerosol particles from gas samples withdrawn from within a contained atmosphere, such as containment vessels for nuclear reactors or other process equipment where remote gaseous sampling is required. It is specifically directed to separation of dense aerosols including particles of any size and at high mass loadings and high corrosivity. The United States Government has rights in this invention pursuant to Contract DE-AC06-76FF02170 between the US Department of Energy and Westinghouse Electric Corporation.

  16. Separations and safeguards model integration.

    SciTech Connect (OSTI)

    Cipiti, Benjamin B.; Zinaman, Owen

    2010-09-01

    Research and development of advanced reprocessing plant designs can greatly benefit from the development of a reprocessing plant model capable of transient solvent extraction chemistry. This type of model can be used to optimize the operations of a plant as well as the designs for safeguards, security, and safety. Previous work has integrated a transient solvent extraction simulation module, based on the Solvent Extraction Process Having Interaction Solutes (SEPHIS) code developed at Oak Ridge National Laboratory, with the Separations and Safeguards Performance Model (SSPM) developed at Sandia National Laboratory, as a first step toward creating a more versatile design and evaluation tool. The goal of this work was to strengthen the integration by linking more variables between the two codes. The results from this integrated model show expected operational performance through plant transients. Additionally, ORIGEN source term files were integrated into the SSPM to provide concentrations, radioactivity, neutron emission rate, and thermal power data for various spent fuels. This data was used to generate measurement blocks that can determine the radioactivity, neutron emission rate, or thermal power of any stream or vessel in the plant model. This work examined how the code could be expanded to integrate other separation steps and benchmark the results to other data. Recommendations for future work will be presented.

  17. Supported palladium materials for isotope separation

    SciTech Connect (OSTI)

    Rutherford, W.M.; Ellis, R.E.; Abell, G.C.

    1988-01-21

    Several palladium packing materials were investigated for their suitability for use in the separation of hydrogen isotopes by displacement chromatography. The materials included palladium on Chromosorb and several formulations of palladium on commercially available alpha-alumina-based catalyst supports. All materials showed some degradation upon being subjected to repeated hydriding-dehydriding cycles; however, the degradation did not lead to unacceptably low permeability to gas flow. Dynamic performance of the packings was evaluated by displacement of deuterium with protium at several temperatures and flow rates. Isotopic exchange was generally rapid. However, high surface area packings (greater than 4 m/sup 2//g) yielded transition zones that were initially sharp, but had long ''tails'' at deuterium concentrations below 5%. Best results were obtained with a packing containing 48.2% palladium on Norton catalyst support No. SA5*21 (surface area = 0.33 m/sup 2//g). Improved performance was observed as the displacement temperature was increased to 80/sup 0/C from 22/sup 0/C. The slight decrease in equilibrium separation was more than offset by improved kinetics at the higher temperature. 19 figs., 6 tabs.

  18. Guidelines For Developing Low Energy Separation Processes 

    E-Print Network [OSTI]

    Bojnowski, J. H.; Hanks, D. L.

    1981-01-01

    A large portion of the energy required by the process industry is consumed by separation processes. This paper discusses current engineering techniques that can be used in the development and optimization of low energy separation processes....

  19. Permeable polyaniline articles for gas separation

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Mattes, Benjamin R.

    2004-09-28

    Immersion precipitation of solutions having 15%-30% (w/w) and various molecular weights of the emeraldine base form of polyaniline in polar aprotic solvents are shown to form integrally skinned asymmetric membranes and fibers having skin layers <1 .mu.m thick which exhibit improved rates of gas transport while preserving good selectivity. These membranes can be further transformed by an acid doping process after fabrication to achieve excellent permeation rates and high selectivities for particular gas separations. Prior to the use of concentrated EB solutions, the formation of integrally skinned asymmetric membranes was not possible, since films and fibers made from <5% w/w polyaniline solutions were found to disintegrate during the IP process.

  20. Permeable polyaniline articles for gas separation

    DOE Patents [OSTI]

    Wang, Hsing-Lin (Los Alamos, NM); Mattes, Benjamin R. (Santa Fe, NM)

    2009-07-21

    Immersion precipitation of solutions having 15%-30% (w/w) and various molecular weights of the emeraldine base form of polyaniline in polar aprotic solvents are shown to form integrally skinned asymmetric membranes and fibers having skin layers <1 .mu.m thick which exhibit improved rates of gas transport while preserving good selectivity. These membranes can be further transformed by an acid doping process after fabrication to achieve excellent permeation rates and high selectivities for particular gas separations. Prior to the use of concentrated EB solutions, the formation of integrally skinned asymmetric membranes was not possible, since films and fibers made from <5% w/w polyaniline solutions were found to disintegrate during the IP process.

  1. Laser-isotope-separation technology. [Review; economics

    SciTech Connect (OSTI)

    Jensen, R.J.; Blair, L.S.

    1981-01-01

    The Molecular Laser Isotope Separation (MLIS) process currently under development is discussed as an operative example of the use of lasers for material processing. The MLIS process, which uses infrared and ultraviolet lasers to process uranium hexafluoride (UF/sub 6/) resulting in enriched uranium fuel to be used in electrical-power-producing nuclear reactor, is reviewed. The economics of the MLIS enrichment process is compared with conventional enrichment technique, and the projected availability of MLIS enrichment capability is related to estimated demands for U.S. enrichment service. The lasers required in the Los Alamos MLIS program are discussed in detail, and their performance and operational characteristics are summarized. Finally, the timely development of low-cost, highly efficient ultraviolet and infrared lasers is shownd to be the critical element controlling the ultimate deployment of MLIS uranium enrichment. 8 figures, 7 tables.

  2. Device for hydrogen separation and method

    DOE Patents [OSTI]

    Paglieri, Stephen N. (White Rock, NM); Anderson, Iver E. (Ames, IA); Terpstra, Robert L. (Ames, IA)

    2009-11-03

    A device for hydrogen separation has a porous support and hydrogen separation material on the support. The support is prepared by heat treatment of metal microparticles, preferably of iron-based or nickel-based alloys that also include aluminum and/or yttrium. The hydrogen separation material is then deposited on the support. Preferred hydrogen separation materials include metals such as palladium, alloys, platinum, refractory metals, and alloys.

  3. Olefin separation membrane and process

    DOE Patents [OSTI]

    Pinnau, Ingo (Palo Alto, CA); Toy, Lora G. (San Francisco, CA); Casillas, Carlos (San Jose, CA)

    1997-01-01

    A membrane and process for separating unsaturated hydrocarbons from fluid mixtures. The membrane and process differ from previously known membranes and processes, in that the feed and permeate streams can both be dry, the membrane need not be water or solvent swollen, and the membrane is characterized by a selectivity for an unsaturated hydrocarbon over a saturated hydrocarbon having the same number of carbon atoms of at least about 20, and a pressure-normalized flux of said unsaturated hydrocarbon of at least about 5.times.10.sup.-6 cm.sup.3 (STP)/cm.sup.2 .multidot.s.multidot.cmHg, said flux and selectivity being measured with a gas mixture containing said unsaturated and saturated hydrocarbons, and in a substantially dry environment.

  4. Olefin separation membrane and process

    DOE Patents [OSTI]

    Pinnau, I.; Toy, L.G.; Casillas, C.

    1997-09-23

    A membrane and process are disclosed for separating unsaturated hydrocarbons from fluid mixtures. The membrane and process differ from previously known membranes and processes, in that the feed and permeate streams can both be dry, the membrane need not be water or solvent swollen, and the membrane is characterized by a selectivity for an unsaturated hydrocarbon over a saturated hydrocarbon having the same number of carbon atoms of at least about 20, and a pressure-normalized flux of said unsaturated hydrocarbon of at least about 5{times}10{sup {minus}6}cm{sup 3}(STP)/cm{sup 2}{center_dot}s{center_dot}cmHg, said flux and selectivity being measured with a gas mixture containing said unsaturated and saturated hydrocarbons, and in a substantially dry environment. 4 figs.

  5. Center for Gas Separations Relevant to

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Center for Gas Separations Relevant to Clean Energy Technologies #12;Director Berend Smit Jeffrey, metal-organic framework. © 2013 EFRC Center for Gas Separation Relevant to Clean Energy Technology. All the current separation technology, developed over sixty years ago, requires 25-35% more coal to produce

  6. Center for Gas Separations Relevant to

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Center for Gas Separations Relevant to Clean Energy Technologies #12;Director Berend Smit Jeffrey, metal-organic framework. © 2013 EFRC Center for Gas Separation Relevant to Clean Energy Technology. All Research Center (EFRC) "Center for Gas Separations Relevant to Clean Energy Technologies". Other

  7. Gas separations using ceramic membranes. Final report, September 1988--February 1993

    SciTech Connect (OSTI)

    Lin, C.L.; Wu, J.C.S.; Gallaher, G.R.; Smith, G.W.; Flowers, D.L.; Gerdes, T.E.; Liu, P.K.T.

    1993-02-01

    This study covers a comprehensive evaluation of existing ceramic membranes for high temperature gas separations. Methodology has been established for microporous characterization stability and gas separation efficiency. A mathematical model was developed to predict gas separations with existing membranes. Silica and zeolitic modifications of existing membranes were pursued to enhance its separation efficiency. Some of which demonstrate unique separations properties. Use of the dense-silica membranes for hydrogen enrichment was identified as a promising candidate for future development. In addition, the decomposition of trace ammonia contaminant via a catalytic membrane reactor appears feasible. A further economic analysis is required to assess its commercial viability.

  8. Characterization of Fish Passage Conditions through a Francis Turbine and Regulating Outlet at Cougar Dam, Oregon, Using Sensor Fish, 2009–2010

    SciTech Connect (OSTI)

    Duncan, Joanne P.

    2011-05-23

    Fish passage conditions through a Francis turbine and a regulating outlet (RO) at Cougar Dam on the south fork of the McKenzie River in Oregon were evaluated by Pacific Northwest National Laboratory for the U.S. Army Corps of Engineers, Portland District, using Sensor Fish devices. The objective of the study was to describe and compare passage exposure conditions, identifying potential fish injury regions encountered during passage via specific routes. The RO investigation was performed in December 2009 and the turbine evaluation in January 2010, concurrent with HI-Z balloon-tag studies by Normandeau Associates, Inc. Sensor Fish data were analyzed to estimate 1) exposure conditions, particularly exposure to severe collision, strike, and shear events by passage route sub-regions; 2) differences in passage conditions between passage routes; and 3) relationships to live-fish injury and mortality data estimates. Comparison of the three passage routes evaluated at Cougar Dam indicates that the RO passage route through the 3.7-ft gate opening was relatively the safest route for fish passage under the operating conditions tested; turbine passage was the most deleterious. These observations were supported also by the survival and malady estimates obtained from live-fish testing. Injury rates were highest for turbine passage. Compared to mainstem Columbia River passage routes, none of the Cougar Dam passage routes as tested are safe for juvenile salmonid passage.

  9. Centrifugal separator devices, systems and related methods

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Garn, Troy G. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Macaluso, Lawrence L. (Carson City, NV)

    2012-03-20

    Centrifugal separator devices, systems and related methods are described. More particularly, fluid transfer connections for a centrifugal separator system having support assemblies with a movable member coupled to a connection tube and coupled to a fixed member, such that the movable member is constrained to movement along a fixed path relative to the fixed member are described. Also, centrifugal separator systems including such fluid transfer connections are described. Additionally, methods of installing, removing and/or replacing centrifugal separators from centrifugal separator systems are described.

  10. Advanced Palladium Membrane Scale-up for Hydrogen Separation

    SciTech Connect (OSTI)

    Sean Emerson; Neal Magdefrau; Ying She; Catherine Thibaud-Erkey

    2012-10-31

    The main objective of this project was to construct, test, and demonstrate a Pd-Cu metallic tubular membrane micro-channel separator capable of producing 2 lb day{sup -1} H{sub 2} at â?Ą95% recovery when operating downstream of an actual coal gasifier. A key milestone for the project was to complete a pilot-scale gasifier test by 1 September 2011 and demonstrate the separation of 2 lb day{sup -1} H{sub 2} to verify progress toward the DOEâ??s goals prior to down-selection for larger-scale (â??100 lb day{sup -1}) hydrogen separator development. Three different pilot-scale (â??1.5 ft{sup 2}) separators were evaluated downstream of coal gasifiers during four different tests and the key project milestone was achieved in August 2011, ahead of schedule. During three of those tests, all of the separators demonstrated or exceeded the targeted separation rate of 2 lb day{sup -1} H{sub 2}. The separator design was proved to be leak tight and durable in the presence of gasifier exhaust contaminants at temperatures and pressures up to 500 °C and 500 psia. The contaminants in the coal gasifier syngas for the most part had negligible impact on separator performance, with H{sub 2} partial pressure being the greatest determinant of membrane performance. Carbon monoxide and low levels of H{sub 2}S (<39 ppmv) had no effect on H{sub 2} permeability, in agreement with laboratory experiments. However, higher levels of H{sub 2}S (>100 ppmv) were shown to significantly reduce H{sub 2} separation performance. The presence of trace metals, including mercury and arsenic, appeared to have no effect based on the experimental data. Subscale Pd-Cu coupon tests further quantified the impact of H{sub 2}S on irreversible sulfide formation in the UTRC separators. Conditions that have a thermodynamic driving force to form coke were found to reduce the performance of the separators, presumably by blockage of effective separation area with carbon deposits. However, it was demonstrated that both in situ and ex situ (laboratory) air regeneration at 450 °C could restore separator performance by burning out such deposits. Gasifier testing revealed that high molecular weight hydrocarbons have the potential to retard H2 separation. Unconverted coal tars with carbon numbers greater than 14 have a boiling point such that they can act as a reversible poison to the Pd-Cu membranes even at temperatures above 500 °C. The use of real-time, physics-based, performance models revealed the effect of these coal tars. It is believed that this project provided the first evidence for the impact of coal tars on H{sub 2} separator performance. Final down-selection of candidate alloys for non-membrane materials of construction proceeded by evaluating the alloys in both UTRC laboratory tests and testing downstream of an actual gasifier at the National Carbon Capture Center (NCCC). The overall alloy ratings were calculated by multiplying the projected cost of a 100 lb day{sup -1} H{sub 2} separator outer shell by the projected oxide scale thickness for 5 years of operation. The alloy with the lowest resulting rating parameter was stainless steel 309 (SS-309) followed by stainless steel 310 (SS-310). However, it was noted that approximately half of the alloys showed susceptibility to pitting and localized corrosion. SS-309 was one of the alloys that exhibited heavy localized attack after 2000 hours of laboratory testing. As this localized corrosion can potentially lead to accelerated end of life, it was determined that SS-310 would be the best alloy selection for this application as it does not show signs of localized pitting corrosion.

  11. Process for strontium-82 separation

    DOE Patents [OSTI]

    Heaton, R.C.; Jamriska, D.J. Sr.; Taylor, W.A.

    1992-12-01

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed. 1 fig.

  12. Process for strontium-82 separation

    DOE Patents [OSTI]

    Heaton, Richard C. (Los Alamos, NM); Jamriska, Sr., David J. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM)

    1992-01-01

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed.

  13. Process to remove actinides from soil using magnetic separation

    DOE Patents [OSTI]

    Avens, Larry R. (Los Alamos, NM); Hill, Dallas D. (Los Alamos, NM); Prenger, F. Coyne (Los Alamos, NM); Stewart, Walter F. (Las Cruces, NM); Tolt, Thomas L. (Los Alamos, NM); Worl, Laura A. (Los Alamos, NM)

    1996-01-01

    A process of separating actinide-containing components from an admixture including forming a slurry including actinide-containing components within an admixture, said slurry including a dispersion-promoting surfactant, adjusting the pH of the slurry to within a desired range, and, passing said slurry through a pretreated matrix material, said matrix material adapted to generate high magnetic field gradients upon the application of a strong magnetic field exceeding about 0.1 Tesla whereupon a portion of said actinide-containing components are separated from said slurry and remain adhered upon said matrix material is provided.

  14. Cyclone reactor with internal separation and axial recirculation

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA)

    1989-01-01

    A cyclone combustor apparatus contains a circular partition plate containing a central circular aperture. The partition plate divides the apparatus into a cylindrical precombustor chamber and a combustor chamber. A coal-water slurry is passed axially into the inlet end of the precombustor chamber, and primary air is passed tangentially into said chamber to establish a cyclonic air flow. Combustion products pass through the partition plate aperture and into the combustor chamber. Secondary air may also be passed tangentially into the combustor chamber adjacent the partition plate to maintain the cyclonic flow. Flue gas is passed axially out of the combustor chamber at the outlet end and ash is withdrawn tangentially from the combuston chamber at the outlet end. A first mixture of flue gas and ash may be tangentially withdrawn from the combustor chamber at the outlet end and recirculated to the axial inlet of the precombustor chamber with the coal-water slurry. A second mixture of flue gas and ash may be tangentially withdrawn from the outlet end of the combustor chamber and passed to a heat exchanger for cooling. Cooled second mixture is then recirculated to the axial inlet of the precombustor chamber. In another embodiment a single cyclone combustor chamber is provided with both the recirculation streams of the first mixture and the second mixture.

  15. Cyclone reactor with internal separation and axial recirculation

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.

    1988-07-19

    A cyclone combustor apparatus contains a circular partition plate containing a central circular aperture is described. The partition plate divides the apparatus into a cylindrical precombustor chamber and a combustor chamber. A coal-water slurry is passed axially into the inlet end of the precombustor chamber, and primary air is passed tangentially into said chamber to establish a cyclonic air flow. Combustion products pass through the partition plate aperture and into the combustor chamber. Secondary air may also be passed tangentially into the combustor chamber adjacent the partition plate to maintain the cyclonic flow. Flue gas is passed axially out of the combustor chamber at the outlet end and ash is withdrawn tangentially from the combustor chamber at the outlet end. A first mixture of flue gas and ash may be tangentially withdrawn from the combustor chamber at the outlet end and recirculated to the axial inlet of the precombustor chamber with the coal-water slurry. A second mixture may be tangentially withdrawn from the outlet end and passed to a heat exchanger for cooling. Cooled second mixture is then recirculated to the axial inlet of the precombustor chamber. In another embodiment a single cyclone combustor chamber is provided with both the recirculation streams of the first mixture and the second mixture. 10 figs.

  16. SULFUR HEXAFLUORIDE TREATMENT OF USED NUCLEAR FUEL TO ENHANCE SEPARATIONS

    SciTech Connect (OSTI)

    Gray, J.; Torres, R.; Korinko, P.; Martinez-Rodriguez, M.; Becnel, J.; Garcia-Diaz, B.; Adams, T.

    2012-09-25

    Reactive Gas Recycling (RGR) technology development has been initiated at Savannah River National Laboratory (SRNL), with a stretch-goal to develop a fully dry recycling technology for Used Nuclear Fuel (UNF). This approach is attractive due to the potential of targeted gas-phase treatment steps to reduce footprint and secondary waste volumes associated with separations relying primarily on traditional technologies, so long as the fluorinators employed in the reaction are recycled for use in the reactors or are optimized for conversion of fluorinator reactant. The developed fluorination via SF{sub 6}, similar to the case for other fluorinators such as NF{sub 3}, can be used to address multiple fuel forms and downstream cycles including continued processing for LWR via fluorination or incorporation into a aqueous process (e.g. modified FLUOREX) or for subsequent pyro treatment to be used in advanced gas reactor designs such metal- or gas-cooled reactors. This report details the most recent experimental results on the reaction of SF{sub 6} with various fission product surrogate materials in the form of oxides and metals, including uranium oxides using a high-temperature DTA apparatus capable of temperatures in excess of 1000{deg}C . The experimental results indicate that the majority of the fission products form stable solid fluorides and sulfides, while a subset of the fission products form volatile fluorides such as molybdenum fluoride and niobium fluoride, as predicted thermodynamically. Additional kinetic analysis has been performed on additional fission products. A key result is the verification that SF{sub 6} requires high temperatures for direct fluorination and subsequent volatilization of uranium oxides to UF{sub 6}, and thus is well positioned as a head-end treatment for other separations technologies, such as the volatilization of uranium oxide by NF{sub 3} as reported by colleagues at PNNL, advanced pyrochemical separations or traditional full recycle approaches. Based on current results of the research at SRNL on SF{sub 6} fluoride volatility for UNF separations, SF{sub 6} treatment renders all anticipated volatile fluorides studied to be volatile, and all non-volatile fluorides studied to be non-volatile, with the notable exception of uranium oxides. This offers an excellent opportunity to use this as a head-end separations treatment process because: 1. SF{sub 6} can be used to remove volatile fluorides from a UNF matrix while leaving behind uranium oxides. Therefore an agent such as NF{sub 3} should be able to very cleanly separate a pure UF{sub 6} stream, leaving compounds in the bottoms such as PuF{sub 4}, SrF{sub 2} and CsF after the UNF matrix has been pre-treated with SF{sub 6}. 2. Due to the fact that the uranium oxide is not separated in the volatilization step upon direct contact with SF{sub 6} at moderately high temperatures (? 1000{deg}C), this fluoride approach may be wellsuited for head-end processing for Gen IV reactor designs where the LWR is treated as a fuel stock, and it is not desired to separate the uranium from plutonium, but it is desired to separate many of the volatile fission products. 3. It is likely that removal of the volatile fission products from the uranium oxide should simplify both traditional and next generation pyroprocessing techniques. 4. SF{sub 6} treatment to remove volatile fission products, with or without treatment with additional fluorinators, could be used to simplify the separations of traditional aqueous processes in similar fashion to the FLUOREX process. Further research should be conducted to determine the separations efficiency of a combined SF{sub 6}/NF{sub 3} separations approach which could be used as a stand-alone separations technology or a head-end process.

  17. Compact high resolution isobar separator for study of exotic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have yielded a bunch width of 30 ns at 1% of the peak height (FWHM 9 ns) and a transmission in DC mode of 75 - 80 %. With such bunch parameters, MRPs of the MTOF...

  18. Robust, high temperature-ceramic membranes for gas separation

    DOE Patents [OSTI]

    Berchtold, Kathryn A.; Young, Jennifer S.

    2014-07-29

    A method of making ceramic membranes, and the ceramic membranes so formed, comprising combining a ceramic precursor with an organic or inorganic comonomer, forming the combination as a thin film on a substrate, photopolymerizing the thin film, and pyrolyzing the photopolymerized thin film.

  19. Separator Design for Use in High GVF Multiphase Flow 

    E-Print Network [OSTI]

    Cihak, Daniel

    2012-10-19

    outside forces act on the particle. Figure 3.2 shows the relationship between the effective diameter and gas velocity using a liquid density of 999 kg/m3 and a gas viscosity of 0.183 cP. 𝑣 = ?𝑔 ? 𝐷𝑑 2 ? 𝜌𝑙 18 ? 𝜇𝑔 (3.13) Figure 3....2.3. Second Law of Motion The previous equations assume only drag and gravitational forces acting on the particle and is a good representation of a tee pipe fitting. However, if a particle reaches the standing water before the resultant force had time...

  20. Electrolytes and Separators for High Voltage Li Ion Cells

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. Compact high resolution isobar separator for study of exotic decays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit the following comments responseScienceCommunity

  2. Functionalized High Performance Polymer Membranes for Separation of Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you not find whatGasEnergyfeatureClean

  3. High Performance Composite Membranes for Separation of Carbon Dioxide from

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumps An error occurred. Try| Center

  4. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Christopher E. Hull

    2005-01-20

    The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/Biological Extraction; (4) Modeling and Control; and (5) Environmental Control.

  5. Composite membranes for fluid separations

    DOE Patents [OSTI]

    Blume, Ingo (Hengelo, NL); Peinemann, Klaus-Viktor (Reinbek, DE); Pinnau, Ingo (Austin, TX); Wijmans, Johannes G. (Menlo Park, CA)

    1991-01-01

    A method for designing and making composite membranes having a microporous support membrane coated with a permselective layer. The method involves calculating the minimum thickness of the permselective layer such that the selectivity of the composite membrane is close to the intrinsic selectivity of the permselective layer. The invention also provides high performance membranes with optimized properties.

  6. Inorganic Membranes for Refinery Gas Separations

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to push the performance limits of inorganic membranes for large-scale gas separations in refinery applications.

  7. Liquid phase thermal swing chemical air separation

    DOE Patents [OSTI]

    Erickson, D.C.

    1988-05-24

    A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite. 2 figs.

  8. Centrifugal separators and related devices and methods

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Garn, Troy G. (Idaho Falls, ID); Macaluso, Lawrence L. (Carson City, NV); Todd, Terry A. (Aberdeen, ID)

    2012-03-06

    Centrifugal separators and related methods and devices are described. More particularly, centrifugal separators comprising a first fluid supply fitting configured to deliver fluid into a longitudinal fluid passage of a rotor shaft and a second fluid supply fitting sized and configured to sealingly couple with the first fluid supply fitting are described. Also, centrifugal separator systems comprising a manifold having a drain fitting and a cleaning fluid supply fitting are described, wherein the manifold is coupled to a movable member of a support assembly. Additionally, methods of cleaning centrifugal separators are described.

  9. Advanced Nanostructured Molecular Sieves for Energy Efficient Industrial Separations

    SciTech Connect (OSTI)

    Kunhao Li, Michael Beaver

    2012-01-18

    Due to the very small relative volatility difference between propane and propylene, current propane/propylene separation by distillation requires very tall distillation towers (150-250 theoretical plates) and large reflux ratios (up to 15), which is considered to be the most energy consuming large-scale separation process. Adsorptive separation processes are widely considered to be more energy-efficient alternatives to distillation. However, slow diffusion kinetics/mass transport rate through the adsorbent bed often limits the performance of such processes, so further improvements are possible if intra-particle mass transfer rates can be improved. Rive Technology, Inc. is developing and commercializing its proprietary mesoporous zeolite technology for catalysis and separation. With well-controlled intracrystalline mesoporosity, diffusion kinetics through such mesoporous zeolite based catalysts is much improved relative to conventional zeolites, leading to significantly better product selectivity. This 'proof-of-principle' project (DE-EE0003470) is intended to demonstrate that Rive mesoporous zeolite technology can be extended and applied in adsorptive propane/propylene separation and lead to significant energy saving compared to the current distillation process. In this project, the mesoporous zeolite Y synthesis technology was successfully extended to X and A zeolites that are more relevant to adsorbent applications. Mesoporosity was introduced to zeolite X and A for the first time while maintaining adequate adsorption capacity. Zeolite adsorbents were tested for liquid phase separation performance using a pulse flow test unit and the test results show that the separation selectivity of the mesoporous zeolite adsorbent is much closer to optimal for a Simulated Moving Bed (SMB) separation process and the enhanced mesoporosity lead to >100% increase of overall mass transport rate for propane and propylene. These improvements will significantly improve the performance of an adsorptive separation unit for propane/propylene separation compared with traditional zeolite adsorbents. The enhanced transport will allow for more efficient utilization of a given adsorbent inventory by reducing process cycle time, allowing a faster production rate with a fixed amount of adsorbent or smaller adsorbent inventory at a fixed production rate. Smaller adsorbent inventory would also lead to significant savings in the capital cost due to smaller footprint of the equipment. Energy consumption calculation, based on the pulse test results for rived NaX zeolite adsorbent, of a hypothetical moderate-scale SMB propane/propylene separation plant that processes 6000 BPSD refinery grade propylene (70% propylene) will consume about 60-80% less energy (both re-boiler and condenser duties) compared to a C3 splitter that process the same amount of feed. This energy saving also translates to a reduction of 30,000-35,000 tons of CO2 emission per year at this moderate processing rate. The enhancement of mass transport achievable by introduction of controlled mesoporosity to the zeolite also opens the door for the technology to be applied to several other adsorption separation processes such as the separation of xylene isomers by SMB, small- and large scale production of O2/N2 from air by pressure swing adsorption, the separation of CO2 from natural gas at natural gas wellheads, and the purification of ultra-high purity H2 from the off gas produced by steam-methane-reforming.

  10. Roof Separation Highlights Bolting Priority

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis of Protein Structures Print

  11. Blind Source Separation by Sparse Decomposition

    E-Print Network [OSTI]

    Pearlmutter, Barak

    Blind Source Separation by Sparse Decomposition University of New Mexico Technical Report No. CS99 University of New Mexico Albuquerque, NM 87131 USA July 19, 1999 Abstract The blind source separation problem of M unknown \\independent" sources s(t), possibly corrupted by additive noise #24;(t): x(t) = As

  12. Pattern separation via ellipsoids and conic programming

    E-Print Network [OSTI]

    Glineur, François

    ' & $ % Pattern separation via ellipsoids and conic programming Fran¸cois Glineur 1 of 1 05 ellipsoids and conic programming ' & $ % \\Upsilon \\Sigma \\Xi \\Pi Objective Machine learning ffl Separation problem ffl Classification Mathematical programming ffl Linear programming ffl Interior­point methods ffl

  13. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  14. Separation Report No. 100 Ion Exchange

    E-Print Network [OSTI]

    Lebendiker, Mario

    ). Historically, the challenge for chromatographic resin manufactures has been to introduce a relatively thick ion-exchangeSeparation Report No. 100 TSK-GEL BioAssist® Series Ion Exchange Columns Table of Contents 1. Introduction 2 2. Basic Properties 2 2-1 Ion-Exchange Capacity and Pore Characteristics 2 2-2 Separation

  15. Composite metal membranes for hydrogen separation applications

    SciTech Connect (OSTI)

    Moss, T.S.; Dye, R.C.

    1997-06-01

    A novel multilayer metal membrane has been developed that can be used for the separation of hydrogen from feed streams with near perfect selectivity. The membrane is comprised of very thin layers of fully dense palladium film deposited on both sides of a thin Group V metal foil, ion-milled prior to sputtering of the palladium. Palladium loading are kept low using the thin film deposition technology: 0.0012 grams of palladium per square centimeter of membrane is typically used, although thinner coatings have been employed. This membrane operates at temperatures on the order of 300 C and is capable of high rates of hydrogen flow. Flows are dependent on the pressure differential applied to the membrane, but flows of 105 sccm/cm{sup 2} and higher are regularly observed with differentials below one atmosphere. Long term testing of the membrane for a period in excess of 775 hours under constant conditions showed stable flows and an 85% hydrogen recovery efficiency. A system has been successfully applied to the hydrogen handling system of a proton exchange membrane fuel cell and was tested using a pseudo-reformate feed stream without any degradation in performance.

  16. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J., E-mail: Christoph.Weber@freudenberg-nw.com; Geiger, Sigrid, E-mail: Christoph.Weber@freudenberg-nw.com [Freudenberg Vliesstoffe SE and Co KG, 69465 Weinheim (Germany); Falusi, Sandra; Roth, Michael [Freudenberg Forschungsdienste SE and Co KG, 69465 Weinheim (Germany)

    2014-06-16

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.

  17. Gas separation using ultrasound and light absorption

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    2012-07-31

    An apparatus and method for separating a chosen gas from a mixture of gases having no moving parts and utilizing no chemical processing is described. The separation of particulates from fluid carriers thereof has been observed using ultrasound. In a similar manner, molecular species may be separated from carrier species. It is also known that light-induced drift may separate light-absorbing species from carrier species. Therefore, the combination of temporally pulsed absorption of light with ultrasonic concentration is expected to significantly increase the efficiency of separation by ultrasonic concentration alone. Additionally, breaking the spatial symmetry of a cylindrical acoustic concentrator decreases the spatial distribution of the concentrated particles, and increases the concentration efficiency.

  18. Advanced Aqueous Separation Systems for Actinide Partitioning

    SciTech Connect (OSTI)

    Nash, Kenneth L.; Clark, Sue; Meier, G Patrick; Alexandratos, Spiro; Paine, Robert; Hancock, Robert; Ensor, Dale

    2012-03-21

    One of the most challenging aspects of advanced processing of spent nuclear fuel is the need to isolate transuranium elements from fission product lanthanides. This project expanded the scope of earlier investigations of americium (Am) partitioning from the lanthanides with the synthesis of new separations materials and a centralized focus on radiochemical characterization of the separation systems that could be developed based on these new materials. The primary objective of this program was to explore alternative materials for actinide separations and to link the design of new reagents for actinide separations to characterizations based on actinide chemistry. In the predominant trivalent oxidation state, the chemistry of lanthanides overlaps substantially with that of the trivalent actinides and their mutual separation is quite challenging.

  19. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, Helena L. (Arvada, CO); Filardo, Giuseppe (Palermo, IT)

    1990-01-01

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70.degree. C. and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution.

  20. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, H.L.; Filardo, G.

    1990-10-23

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70 C and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution. 1 fig.

  1. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

    2011-01-25

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  2. Persistence of Gulf Stream separation during the Last Glacial Period: Implications for current separation theories

    E-Print Network [OSTI]

    Lynch-Stieglitz, Jean

    as freely meandering jet in the open ocean. On a basin- wide scale, the Gulf Stream separation latitudePersistence of Gulf Stream separation during the Last Glacial Period: Implications for current at which the Gulf Stream separated from the western boundary of the Atlantic Ocean in the past. The modern

  3. Combined ICR heating antenna for ion separation systems

    SciTech Connect (OSTI)

    Timofeev, A. V. [Russian Research Centre Kurchatov Institute (Russian Federation)

    2011-01-15

    A combination of one- and two-wave antennas (one and two turns of conductors around a plasma cylinder, respectively) is proposed. This combined antenna localizes an RF field within itself. It is shown that spent nuclear fuel processing systems based on ICR heating of nuclear ash by such a combined antenna have high productivity. A theory of the RF field excitation in ICR ion separation systems is presented in a simple and compact form.

  4. An overview of copper-laser development for isotope separation

    SciTech Connect (OSTI)

    Warner, B.E.

    1987-03-13

    We have developed a copper-laser pumped dye-laser system that addresses all of the requirements for atomic vapor laser isotope separation. The requirement for high average power for the laser system has led to the development of copper-laser chains with injection-locked oscillators and multihundred-watt amplifiers. By continuously operating the Laser Demonstration Facility, we gain valuable data for further upgrade and optimization.

  5. Understand the potential of electro-separations

    SciTech Connect (OSTI)

    Byers, C.H. (Oak Ridge National Lab., TN (United States)); Amarnath, A. (Electric Power Research Inst., Palo Alto, CA (United States))

    1995-02-01

    Unit operations to separate and purify chemicals consume over 4 Quads (10[sup 15] Btu) of energy in the US alone each year. They also directly or indirectly generate considerable amounts of emissions. These economic and environmental pressures pose challenges that will require new processing approaches. The authors feel that electro-separations will play a leading role in achieving the efficiency and environmental improvements that will be demanded of the chemical process industries (CPI) in the early 21st Century. In this article, the authors provide an overview of the status of electro-separations. But first, to avoid any confusion, they clarify what they mean by the term electro-separations. Conventionally, it refers only to electrolysis-type technologies, such as electrophoresis, electrokinetics, and electrodialysis. Instead, they propose a broader definition: the use of electricity, or electro-magnetic fields to produce and enhance chemical or physical separation. The definition thus includes such processes as electro- and dielectric filtration, magnetic separation, any process where electric or magnetic fields profoundly affect the transport rate, and numerous other technologies that are now in early development but, with adequate support, may become preeminent separation technologies. The relative significance of this broad palette of technologies to the emerging needs of the CPI is the subject of their ongoing study.

  6. Method of separating thorium from plutonium

    DOE Patents [OSTI]

    Clifton, David G. (Los Alamos, NM); Blum, Thomas W. (Los Alamos, NM)

    1984-01-01

    A method of chemically separating plutonium from thorium. Plutonium and thorium to be separated are dissolved in an aqueous feed solution, preferably as the nitrate salts. The feed solution is acidified and sodium nitrite is added to the solution to adjust the valence of the plutonium to the +4 state. A chloride salt, preferably sodium chloride, is then added to the solution to induce formation of an anionic plutonium chloride complex. The anionic plutonium chloride complex and the thorium in solution are then separated by ion exchange on a strong base anion exchange column.

  7. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  8. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  9. Membrane separation advances in FE hydrogen program

    SciTech Connect (OSTI)

    NONE

    2007-12-31

    Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

  10. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  11. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  12. Dense, layered membranes for hydrogen separation

    DOE Patents [OSTI]

    Roark, Shane E.; MacKay, Richard; Mundschau, Michael V.

    2006-02-21

    This invention provides hydrogen-permeable membranes for separation of hydrogen from hydrogen-containing gases. The membranes are multi-layer having a central hydrogen-permeable layer with one or more catalyst layers, barrier layers, and/or protective layers. The invention also relates to membrane reactors employing the hydrogen-permeable membranes of the invention and to methods for separation of hydrogen from a hydrogen-containing gas using the membranes and reactors. The reactors of this invention can be combined with additional reactor systems for direct use of the separated hydrogen.

  13. Separator plate for a fuel cell

    DOE Patents [OSTI]

    Petri, R.J.; Meek, J.; Bachta, R.P.; Marianowski, L.G.

    1996-04-02

    A separator plate is described for a fuel cell comprising an anode current collector, a cathode current collector and a main plate, the main plate disposed between the anode current collector and the cathode current collector. The anode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the anode side of the separator plate and the cathode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the cathode side of the separator plate. In this manner, the number of components required to manufacture and assemble a fuel cell stack is reduced. 9 figs.

  14. Method of separating thorium from plutonium

    DOE Patents [OSTI]

    Clifton, D.G.; Blum, T.W.

    1984-07-10

    A method is described for chemically separating plutonium from thorium. Plutonium and thorium to be separated are dissolved in an aqueous feed solution, preferably as the nitrate salts. The feed solution is acidified and sodium nitrite is added to the solution to adjust the valence of the plutonium to the +4 state. A chloride salt, preferably sodium chloride, is then added to the solution to induce formation of an anionic plutonium chloride complex. The anionic plutonium chloride complex and the thorium in solution are then separated by ion exchange on a strong base anion exchange column.

  15. Method and Apparatus for separation of heavy and tritiated water

    SciTech Connect (OSTI)

    Lee, Myung, W.

    2000-02-28

    An object of the present invention is to provide a method for separating and recovering hydrogen isotopes that avoids the disadvantages of the prior art, is more simple, and allows for continuous hydrogen isotope separation and recovery. The disclosed invention does not require the use of isotope exchange reaction catalysts and/or hydrogen sulfide gas. The present invention achieves the advantages of the thermal diffusion and the chemical exchange processes. The disclosed invention provides a method for separating and recovering hydrogen isotopes from a fluid containing the hydrogen isotopes by providing counter-current cold and hot streams of the fluid containing the hydrogen isotopes separated by a proton exchange membrane made of thermally insulating and chemically transparent material that allows exchange of heavy and light hydrogen isotopes there through. The heavier isotopes migrate to the cold stream producing a deuterium and tritium-enriched fluid, while lighter isotopes migrate to the hot stream producing a lighter isotope-enriched fluid. The heavy and light isotopes are withdrawn from the cold and hot streams respectively. According to the present invention, the fluid is water or hydrogen gas, and the desired hydrogen isotope species are deuterium and/or tritium. Further, according to the present invention, the streams of said high and low temperature fluids are interconnected at their respective top and bottom ends forming a continuous loop, and a feed stream is provided at an intermediate portion of either hot or cold stream to feed the process.

  16. Surface-Modified Membrane as A Separator for Lithium-Ion Polymer Battery

    E-Print Network [OSTI]

    Kim, Jun Young

    This paper describes the fabrication of novel modified polyethylene (PE) membranes using plasma technology to create high-performance and cost-effective separator membranes for practical applications in lithium-ion polymer ...

  17. Separating Dark Physics from Physical Darkness: Minimalist Modified Gravity vs. Dark Energy

    E-Print Network [OSTI]

    Huterer, Dragan

    2009-01-01

    LBNL- 61880 Separating Dark Physics from Physical Darkness:2 Kavli Institute for Cosmological Physics and Astronomy andOffice of High Energy Physics, of the U.S. Department of

  18. Sulfate Separation by Selective Crystallization of a Urea-Functionalized Metal-Organic Framework

    SciTech Connect (OSTI)

    Custelcean, Radu; Sellin, Vincent; Moyer, Bruce A

    2007-01-01

    Encapsulation of SO{sub 4}{sup 2-} into a Ni coordination framework functionalized with urea anion-binding groups allows selective separation of this strongly hydrophilic anion from a highly competitive aqueous environment.

  19. On-chip multi-dimensional biomolecule separation using multi-layer microfabricated valves

    E-Print Network [OSTI]

    Wang, Ying-Chih, 1977-

    2004-01-01

    Recent proteomics researches require a sensitive, high-speed, and automatic protein separation tool that far exceeds the capability of traditional two dimensional (2D) protein gel electrophoresis. Methods are described to ...

  20. Reduced gravity rankine cycle design and optimization with passive vortex phase separation 

    E-Print Network [OSTI]

    Supak, Kevin Robert

    2009-05-15

    turbo machinery, require kilowatts of power and are untested for high vapor flow conditions. The Interphase Transport Phenomena (ITP) laboratory has developed a low-power, passive microgravity vortex phase separator (MVS) which has already proven...

  1. Protein Separation and Label-Free Detection on Supported Lipid Bilayers 

    E-Print Network [OSTI]

    Liu, Chunming

    2012-10-19

    to focus and separate proteins and lipids into narrow bands from an initially homogeneous mixture. Membrane-associated species were focused into specific positions within the SLB in a highly repeatable fashion. The steady-state focusing positions...

  2. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would suffer from low throughput capacities and high maintenance requirements. In general, surface area-based separators (e.g., shaking tables, magnetic drum separator, electrodynamic separator, etc.) have lower throughput capacities than volume-based separators (e.g., flotation cell, dense-medium bath, cyclones, etc.) by an order of magnitude. Furthermore, the electrodes of the laboratory unit need to be cleaned frequently, creating a high maintenance requirement if it is scaled-up to a commercial unit. The bench-scale continuous TES unit developed at NETL, on the other hand, separates positively and negatively charged particles by splitting the gaseous stream containing these particles in an electric field by means of a flow splitter, so that the oppositely charged particles can be directed into different compartments. This device is fundamentally different from the laboratory unit in that the former is a surface area-based separator, while the latter is a volume-based separator. The bench-scale unit is referred to as an entrained flow separator by the in-house researchers at NETL. Thus, the entrained flow TES unit is a significant improvement over the laboratory unit with regard to throughput capacity. In the present work, the entrained flow separator concept will be utilized for developing a proof-of concept (POC) separator that can be scaled-up to commercial size units. To accomplish this, it is necessary to develop a bench-scale separator that can achieve high Btu recoveries while maintaining the high degree of separation efficiencies. It is the objective of the present investigation to develop an efficient separator by studying the mechanisms of triboelectrification and investigating better ways of separating the charged particles. An important criterion for developing efficient separators is that they not only provide high separation efficiencies but also have high throughput capacities, which are essential ingredients for successful commercialization.

  3. Hybrid Membranes for Light Gas Separations 

    E-Print Network [OSTI]

    Liu, Ting

    2012-07-16

    Membrane separations provide a potentially attractive technology over conventional processes due to their advantages, such as low capital cost and energy consumption. The goal of this thesis is to design hybrid membranes that facilitate specific gas...

  4. Atomic vapor laser isotope separation process

    DOE Patents [OSTI]

    Wyeth, R.W.; Paisner, J.A.; Story, T.

    1990-08-21

    A laser spectroscopy system is utilized in an atomic vapor laser isotope separation process. The system determines spectral components of an atomic vapor utilizing a laser heterodyne technique. 23 figs.

  5. Electrochemically mediated separation for carbon capture

    E-Print Network [OSTI]

    Simeon, Fritz

    Carbon capture technology has been proposed as an effective approach for the mitigation of anthropogenic CO[subscript 2] emissions. Thermal-swing separation technologies based on wet chemical scrubbing show potential for ...

  6. Advanced Membrane Separation Technologies for Energy Recovery

    SciTech Connect (OSTI)

    2009-05-01

    This factsheet describes a research project whose goal is to develop novel materials for use in membrane separation technologies for the recovery of waste energy and water from industrial process streams.

  7. Polarized CMB recovery with sparse component separation

    E-Print Network [OSTI]

    Bobin, Jerome; Starck, Jean-Luc

    2015-01-01

    The polarization modes of the cosmological microwave background are an invaluable source of information for cosmology, and a unique window to probe the energy scale of inflation. Extracting such information from microwave surveys requires disentangling between foreground emissions and the cosmological signal, which boils down to solving a component separation problem. Component separation techniques have been widely studied for the recovery of CMB temperature anisotropies but quite rarely for the polarization modes. In this case, most component separation techniques make use of second-order statistics to discriminate between the various components. More recent methods, which rather emphasize on the sparsity of the components in the wavelet domain, have been shown to provide low-foreground, full-sky estimate of the CMB temperature anisotropies. Building on sparsity, the present paper introduces a new component separation technique dubbed PolGMCA (Polarized Generalized Morphological Component Analysis), which r...

  8. Electrolytic cell. [For separating anolyte and catholyte

    DOE Patents [OSTI]

    Bullock, J.S.; Hale, B.D.

    1984-09-14

    An apparatus is described for the separation of the anolyte and the catholyte during electrolysis. The electrolyte flows through an electrolytic cell between the oppositely charged electrodes. The cell is equipped with a wedge-shaped device, the tapered end being located between the electrodes on the effluent side of the cell. The wedge diverts the flow of the electrolyte to either side of the wedge, substantially separating the anolyte and the catholyte.

  9. Waste Separations and Pretreatment Workshop report

    SciTech Connect (OSTI)

    Cruse, J.M.; Harrington, R.A.; Quadrel, M.J.

    1994-01-01

    This document provides the minutes from the Waste Separations and Pretreatment Workshop sponsored by the Underground Storage Tank-Integrated Demonstration in Salt Lake City, Utah, February 3--5, 1993. The Efficient Separations and Processing-Integrated Program and the Hanford Site Tank Waste Remediation System were joint participants. This document provides the detailed minutes, including responses to questions asked, an attendance list, reproductions of the workshop presentations, and a revised chart showing technology development activities.

  10. SEPARATIONS AND WASTE FORMS CAMPAIGN IMPLEMENTATION PLAN

    SciTech Connect (OSTI)

    Vienna, John D.; Todd, Terry A.; Peterson, Mary E.

    2012-11-26

    This Separations and Waste Forms Campaign Implementation Plan provides summary level detail describing how the Campaign will achieve the objectives set-forth by the Fuel Cycle Reasearch and Development (FCRD) Program. This implementation plan will be maintained as a living document and will be updated as needed in response to changes or progress in separations and waste forms research and the FCRD Program priorities.

  11. QUANTITATIVE EVALUATION OF FIRE SEPARATION AND BARRIERS

    SciTech Connect (OSTI)

    Coutts, D

    2007-04-17

    Fire barriers, and physical separation are key components in managing the fire risk in Nuclear Facilities. The expected performance of these features have often been predicted using rules-of-thumb or expert judgment. These approaches often lack the convincing technical bases that exist when addressing other Nuclear Facility accident events. This paper presents science-based approaches to demonstrate the effectiveness of fire separation methods.

  12. Adsorptive separation of propylene-propane mixtures

    SciTech Connect (OSTI)

    Jaervelin, H.; Fair, J.R. (Univ. of Texas, Austin, TX (United States))

    1993-10-01

    The separation of propylene-propane mixtures is of great commercial importance and is carried out by fractional distillation. It is claimed to be the most energy-intensive distillation practiced in the United States. The purpose of this paper is to describe experimental work that suggests a practical alternative to distillation for separating the C[sub 3] hydrocarbons: adsorption. As studied, the process involves three adsorptive steps: initial separation with molecular sieves with heavy dilution with an inert gas; separation of propylene and propane separately from the inert gas, using activated carbon; and drying of the product streams with any of several available desiccants. The research information presented here deals with the initial step and includes both equilibrium and kinetic data. Isotherms are provided for propylene and propane adsorbed on three zeolites, activated alumina, silica gel, and coconut-based activated carbon. Breakthrough data are provided for both adsorption and regeneration steps for the zeolites, which were found to be superior to the other adsorbents for breakthrough separations. A flow diagram for the complete proposed process is included.

  13. Method for sequential injection of liquid samples for radioisotope separations

    DOE Patents [OSTI]

    Egorov, Oleg B. (Richland, WA); Grate, Jay W. (West Richland, WA); Bray, Lane A. (Richland, WA)

    2000-01-01

    The present invention is a method of separating a short-lived daughter isotope from a longer lived parent isotope, with recovery of the parent isotope for further use. Using a system with a bi-directional pump and one or more valves, a solution of the parent isotope is processed to generate two separate solutions, one of which contains the daughter isotope, from which the parent has been removed with a high decontamination factor, and the other solution contains the recovered parent isotope. The process can be repeated on this solution of the parent isotope. The system with the fluid drive and one or more valves is controlled by a program on a microprocessor executing a series of steps to accomplish the operation. In one approach, the cow solution is passed through a separation medium that selectively retains the desired daughter isotope, while the parent isotope and the matrix pass through the medium. After washing this medium, the daughter is released from the separation medium using another solution. With the automated generator of the present invention, all solution handling steps necessary to perform a daughter/parent radionuclide separation, e.g. Bi-213 from Ac-225 "cow" solution, are performed in a consistent, enclosed, and remotely operated format. Operator exposure and spread of contamination are greatly minimized compared to the manual generator procedure described in U.S. patent application Ser. No. 08/789,973, now U.S. Pat. No. 5,749,042, herein incorporated by reference. Using 16 mCi of Ac-225 there was no detectable external contamination of the instrument components.

  14. Vehicle having hydraulic and power steering systems using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2001-06-22

    A vehicle comprises a plurality of wheels attached to a vehicle housing. Also attached to the vehicle housing is a power steering system, including a fluid flow circuit, which is operably coupled to a number of the wheels. An internal combustion engine attached to the vehicle housing is connected to a hydraulically actuated system that includes a high pressure pump. An outlet of the high pressure pump is in fluid communication with the fluid flow circuit.

  15. A Case for Molecular Recognition in Nuclear Separations: Sulfate Separation from Nuclear Wastes

    SciTech Connect (OSTI)

    Moyer, Bruce A; Custelcean, Radu; Hay, Benjamin; Sessler, Jonathan L.; Bowman-James, Kristin; Day, Victor W.; Kang, S.O.

    2013-01-01

    In this paper, we present the case for molecular-recognition approaches for sulfate removal from radioactive wastes via the use of anion-sequestering systems selective for sulfate, using either liquid liquid extraction or crystallization. Potential benefits of removing sulfate from the waste include improved vitrification of the waste, reduced waste-form volume, and higher waste-form performance, all of which lead to potential cleanup schedule acceleration and cost savings. The need for sulfate removal from radioactive waste, especially legacy tank wastes stored at the Hanford site, is reviewed in detail and primarily relates to the low solubility of sulfate in borosilicate glass. Traditional methods applicable to the separation of sulfate from radioactive wastes are also reviewed, with the finding that currently no technology has been identified and successfully demonstrated to meet this need. Fundamental research in the authors laboratories targeting sulfate as an important representative of the class of oxoanions is based on the hypothesis that designed receptors may provide the needed ability to recognize sulfate under highly competitive conditions, in particular where the nitrate anion concentration is high. Receptors that have been shown to have promising affinity for sulfate, either in extraction or in crystallization experiments, include hexaurea tripods, tetraamide macrocycles, cyclo[8]pyrroles, calixpyrroles, and self-assembled urea-lined cages. Good sulfate selectivity observed in the laboratory provides experimental support for the proposed molecular-recognition approach.

  16. Ce-MXRF: the power of separation with bench top element sensitive detection

    SciTech Connect (OSTI)

    Miller, T. C. (Thomasin C.); Joseph, M. R. (Martha R.); Havrilla, G. J. (George J.)

    2002-01-01

    Capillary electrophoresis (CE) is a proven separation technique that offers highly efficient separation, rapid analysis, and minute sample consumption. When combined with a element specific detection scheme, it can be used for chemical speciation of biologically and environmentally relevant species such as metal containing proteins. In this study, a new tool was developed for separation and elemental detection. Specifically, a simple CE apparatus was constructed using a thin-walled fused Si capillary and interfaced with a bench top micro x-ray fluorescence (MXRF) system. X-ray excitation and detection of the separated sample volumes was performed using an EDAX Eagle II micro x-ray fluorescence system equipped with a Rh target excitation source and a SiLi detector. It was demonstrated that the system could be used for the separation and detection of two metals from one another, specifically Cu{sup 2+} and Co{sup 2+}. Free Co{sup 2+} could also be isolated from Co{sup 2+} bound to cyanocobalamin (Vitamin B-12). Other systems that were explored were the separation of two organics, ferritin from cyanocobalamin as well as the separation of the different Cu and Zn isoforms of metallothinein. CE-MXRF was also used to separate the important serum isoforms of transferrin. Direct comparisons were made between CE-MXRF system and other elemental separation techniques such as CE-PIXE, CE-synchrotron-XRF, and CE-ICPMS.

  17. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  18. Production plant separator system conceptual design

    SciTech Connect (OSTI)

    Ng, E.; Kan, T.

    1994-12-31

    A full conceptual design has been completed for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant capable of producing {approximately}1700 metric tons of enriched uranium per year (MTU/y). This plant is the first step in the deployment of AVLIS enrichment technology, which will provide inexpensive, dependable, and environmentally safe uranium enrichment services to utility customers. Previous issues of the ISAM Semiannual Report describe other major systems in the plant, namely the laser, feed and product systems. This article describes the design of the separator system. The separator system is a a key component in the plant. After the feed conversion system converts uranium trioxide (UO{sub 3}) to a uranium-iron alloy, the alloy enters the separator system. In the separator, and intense electron beam vaporizes uranium metal in a vacuum chamber. In the laser system, fixed-frequency copper-vapor lasers pump tunable dye lasers. These precisely tuned dye lasers then selectively excite and ionize uranium-235 atoms in the vapor stream, leaving the uranium-238 atoms untouched. The photo-ions of uranium-235 are then drawn to an electrically biased collector, producing the enriched product stream. The remaining vapor flows through, producing the depleted tails stream. Both product and tails streams are continuously removed from the separator pod as flowing liquid uranium metal. Withdrawal containers are used to collect separately the enriched and depleted uranium. The enriched product will be converted by fuel fabricators to uranium dioxide (UO{sub 2}) and used to fabricate reactor fuel assemblies for utility customers.

  19. Lined sampling vessel including a filter to separate solids from liquids on exit

    DOE Patents [OSTI]

    Shurtliff, Rodney M. (Idaho Falls, ID); Klingler, Kerry M. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID)

    2001-01-01

    A filtering apparatus has an open canister with an inlet port. A canister lid is provided which includes an outlet port for the passage of fluids from the canister. Liners are also provided which are shaped to fit the interiors of the canister and the lid, with at least the canister liner preferably being flexible. The sample to be filtered is positioned inside the canister liner, with the lid and lid liner being put in place thereafter. A filter element is located between the sample and the outlet port. Seals are formed between the canister liner and lid liner, and around the outlet port to prevent fluid leakage. A pressure differential is created between the canister and the canister liner so that the fluid in the sample is ejected from the outlet port and the canister liner collapses around the retained solids.

  20. Method for separating disparate components in a fluid stream

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID)

    1990-01-01

    The invention provides a method of separating a mixed component waste stream in a centrifugal separator. The mixed component waste stream is introduced into the separator and is centrifugally separated within a spinning rotor. A dual vortex separation occurs due to the phase density differences, with the phases exiting the rotor distinct from one another. In a preferred embodiment, aqueous solutions of organics can be separated with up to 100% efficiency. The relatively more dense water phase is centrifugally separated through a radially outer aperture in the separator, while the relatively less dense organic phase is separated through a radially inner aperture.

  1. Laser Isotope Separation Employing Condensation Repression

    SciTech Connect (OSTI)

    Eerkens, Jeff W.; Miller, William H.

    2004-09-15

    Molecular laser isotope separation (MLIS) techniques using condensation repression (CR) harvesting are reviewed and compared with atomic vapor laser isotope separation (AVLIS), gaseous diffusion (DIF), ultracentrifuges (UCF), and electromagnetic separations (EMS). Two different CR-MLIS or CRISLA (Condensation Repression Isotope Separation by Laser Activation) approaches have been under investigation at the University of Missouri (MU), one involving supersonic super-cooled free jets and dimer formation, and the other subsonic cold-wall condensation. Both employ mixtures of an isotopomer (e.g. {sup i}QF{sub 6}) and a carrier gas, operated at low temperatures and pressures. Present theories of VT relaxation, dimerization, and condensation are found to be unsatisfactory to explain/predict experimental CRISLA results. They were replaced by fundamentally new models that allow ab-initio calculation of isotope enrichments and predictions of condensation parameters for laser-excited and non-excited vapors which are in good agreement with experiment. Because of supersonic speeds, throughputs for free-jet CRISLA are a thousand times higher than cold-wall CRISLA schemes, and thus preferred for large-quantity Uranium enrichments. For small-quantity separations of (radioactive) medical isotopes, the simpler coldwall CRISLA method may be adequate.

  2. Environmental assessment: special isotope separation process selection

    SciTech Connect (OSTI)

    Not Available

    1986-04-01

    This Environmental Assessment (EA) evaluates the differences in potential environmental impacts between two plutonium Special Isotope Separation (SIS) technologies: Atomic Vapor Laser Isotope Separation (AVLIS) and Molecular Laser Isotope Separation (MLIS). Both SIS technologies use PuO/sub 2/ as feed; AVLIS converts feed to plutonium metal and MLIS converts feed to PuF/sub 6/. The AVLIS process uses laser energy to selectively photoionize and electrostatically separate plutonium isotopes from an atomic vapor stream. The MLIS process uses laser energy to selectively disassociate specific isotopes of plutonium in the form of PuF/sub 6/ molecules to create PuF/sub 5/ for collection and further processing. Both processes produce plutonium metal as their product. An evaluation of differences in potential environmental impacts attributed to the construction of an SIS facility, based on either technology, included a comparison of construction materials, land areas required, and the size of the design and construction workforce. The differences in potential environmental impacts from operating an SIS facility were also compared. No large differences in potential environmental impacts would be expected from the use of process chemicals. An AVLIS or an MLIS facility would produce operating effluents that would meet all applicable radiation, chemical, and hazardous waste standards and would be constructed to protect workers, the public and the environment. This EA has not revealed any significant differences in the potential environmental impacts that could occur as a result of deploying either the AVLIS or the MLIS Special Isotope Separation technology.

  3. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  4. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  5. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  6. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  7. Catalytic reactive separation system for energy-efficient production of cumene

    DOE Patents [OSTI]

    Buelna, Genoveva (Nuevo Laredo, MX); Nenoff, Tina M. (Albuquerque, NM)

    2009-07-28

    The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.

  8. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2002-07-01

    Mixed-conducting ceramics have the ability to conduct oxygen with perfect selectivity at elevated temperatures, making them extremely attractive as membrane materials for oxygen separation and membrane reactor applications. While the conductivity of these materials can be quite high at elevated temperatures (typically 800-1000 C), much higher oxygen fluxes, or, alternatively, equivalent fluxes at lower temperatures, could be provided by supported thin or thick film membrane layers. Based on that motivation, the objective of this project was to explore the use of ultrafine aerosol-derived powder of a mixed-conducting ceramic material for fabrication of supported thick-film dense membranes. The project focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} (SCFO) because of the desirable permeability and stability of that material, as reported in the literature. Appropriate conditions to produce the submicron SrCo{sub 0.5}FeO{sub x} powder using aerosol pyrolysis were determined. Porous supports of the same composition were produced by partial sintering of a commercially obtained powder that possessed significantly larger particle size than the aerosol-derived powder. The effects of sintering conditions (temperature, atmosphere) on the porosity and microstructure of the porous discs were studied, and a standard support fabrication procedure was adopted. Subsequently, a variety of paste and slurry formulations were explored utilizing the aerosol-derived SCFO powder. These formulations were applied to the porous SCFO support by a doctor blade or spin coating procedure. Sintering of the supported membrane layer was then conducted, and additional layers were deposited and sintered in some cases. The primary characterization methods were X-ray diffraction and scanning electron microscopy, and room-temperature nitrogen permeation was used to assess defect status of the membranes.We found that non-aqueous paste/slurry formulations incorporating dispersant, plasticizer and binder provided superior cracking resistance compared to simple water, alcohol, or polyethylene glycol (PEG) based formulations. With a formulation employing castor oil as dispersant, isopropyl alcohol/mineral spirits as solvent, polyvinyl butyral as binder, and dibutyl phthalate/PEG as plasticizer, sintered SCFO membrane layers approximately 5 {micro}m thick with no apparent cracks were prepared using spin coating with several coats and sintering cycles. A similar but more viscous formulation applied by doctor blade gave a {approx} 10 {micro}m thick membrane layer in one coat, but with some apparent cracking. We demonstrated that the membrane layer could be densified while retaining porosity in the chemically identical support. This was accomplished by pre-sintering the support in air (1050 C), which coarsened the grain size and provided a relatively stable plate-shaped granular microstructure, followed by membrane layer fabrication with the highly-sinterable aerosol powder. Final densification was conducted by sintering in nitrogen ({approx}1100 C), which provided accelerated sintering rates and led to the desired layered perovskite phase content. In spite of these successes, low-temperature pressure-driven permeation testing with N2 showed that even the best membranes were not sufficiently defect free for high-temperature oxygen permeation testing. The source of these defects were not readily apparent from scanning electron microscopy, though incomplete or nonuniform membrane layer coverage from edge to edge of the support was probably one important factor.

  9. Separation of strontium from fecal matter

    DOE Patents [OSTI]

    Kester, D.K.

    1995-01-03

    A method is presented of separating strontium from a sample of biomass potentially contaminated with various radionuclides. After the sample is reduced, dissociated, and carried on a first precipitate of actinides, the first precipitate is removed to leave a supernate. Next, oxalic acid is added to the supernate to cause a second precipitate of strontium and calcium. Then, after separating the second precipitate, nitric acid is added to the second precipitate to cause a third precipitate of strontium. The calcium remains in solution and is discarded to leave essentially the precipitate of strontium.

  10. Novel Metallic Membranes for Hydrogen Separation

    SciTech Connect (OSTI)

    Dogan, Omer

    2011-02-27

    To reduce dependence on oil and emission of greenhouse gases, hydrogen is favored as an energy carrier for the near future. Hydrogen can be converted to electrical energy utilizing fuel cells and turbines. One way to produce hydrogen is to gasify coal which is abundant in the U.S. The coal gasification produces syngas from which hydrogen is then separated. Designing metallic alloys for hydrogen separation membranes which will work in a syngas environment poses significant challenges. In this presentation, a review of technical targets, metallic membrane development activities at NETL and challenges that are facing the development of new technologies will be given.

  11. Separation of strontium from fecal matter

    DOE Patents [OSTI]

    Kester, Dianne K. (Idaho Falls, ID)

    1995-01-01

    A method of separating strontium from a sample of biomass potentially contaminated with various radionuclides. After the sample is reduced, dissociated, and carried on a first precipitate of actinides, the first precipitate is removed to leave a supernate. Next, oxalic acid is added to the supernate to cause a second precipitate of strontium and calcium. Then, after separating the second precipitate, nitric acid is added to the second precipitate to cause a third precipitate of strontium. The calcium remains in solution and is discarded to leave essentially the precipitate of strontium.

  12. Concentric ring flywheel without expansion separators

    DOE Patents [OSTI]

    Kuklo, T.C.

    1999-08-24

    A concentric ring flywheel wherein the adjacent rings are configured to eliminate the need for differential expansion separators between the adjacent rings. This is accomplished by forming a circumferential step on an outer surface of an inner concentric ring and forming a matching circumferential step on the inner surface of an adjacent outer concentric ring. During operation the circumferential steps allow the rings to differentially expand due to the difference in the radius of the rings without the formation of gaps therebetween, thereby eliminating the need for expansion separators to take up the gaps formed by differential expansion. 3 figs.

  13. Separation of metal ions from aqueous solutions

    DOE Patents [OSTI]

    Almon, Amy C. (Augusta, GA)

    1994-01-01

    A process and apparatus for quantitatively and selectively separating metal ions from mixtures thereof in aqueous solution. The apparatus includes, in combination, a horizontal electrochemical flow cell containing flow bulk electrolyte solution and an aqueous, metal ion-containing solution, the cell containing a metal mesh working electrode, a counter electrode positioned downstream from the working electrode, an independent variable power supply/potentiostat positioned outside of the flow cell and connected to the electrodes, and optionally a detector such as a chromatographic detector, positioned outside the flow cell. This apparatus and its operation has significant application where trace amounts of metal ions are to be separated.

  14. : A Model of Refactoring Physically and Virtually Separated Features

    E-Print Network [OSTI]

    Kaestner, Christian

    for SPLs. We distinguish [26] between implementation approaches that physically separate features (a.k.a that virtually separate features (a.k.a. virtual separation of concerns) by annotating code fragments in a common

  15. A Characterization of a Dual Chambered, Two Phase Separator 

    E-Print Network [OSTI]

    Klein, Casey

    2012-02-14

    separator and is meant to determine the minimum inlet gas flow rate necessary for a stable vortex inside the separator for different separator geometries. A dimensional scaling analysis was done to predict this minimum inlet gas flow rate. Experiments were...

  16. Ruthenium Behavior at Phase Separation of Borosilicate Glass-12259

    SciTech Connect (OSTI)

    Enokida, Youichi [Graduate School of Engineering, Nagoya University, Nagoya, 463-8603 (Japan); Sawada, Kayo [EcoTopia Science Institute, Nagoya University, Nagoya, 463-8603 (Japan)

    2012-07-01

    The Rokkasho reprocessing plant (RRP) located in Aomori, Japan, vitrifies high level waste (HLW) into a borosilicate glass. The HLW is generated from the reprocessing of spent fuel and contains ruthenium (Ru) and other platinum group metals (PGMs). Based on the recent consequences after a huge earthquake that occurred in Japan, a hypothetical blackout was postulated for the RRP to address additional safety analysis requirements. During a prolonged blackout, the borosilicate glass could phase separate due to cooling of the glass in the melter. The Ru present in the glass matrix could migrate into separate phases and impact the durability of the borosilicate glass. The durability of the glass is important for quality assurance and performance assessment of the vitrified HLW. A fundamental study was performed at an independent university to understand the impact of a prolonged blackout. Simulated HLW glasses were prepared for the RRP, and the Ru behavior in phase separated glasses was studied. The simulated HLW glasses contained nonradioactive elements and PGMs. The glass compositions were then altered to enhance the formation of the phase-separated glasses when subjected to thermal treatment at 700 deg. C for 24 hours. The synthesized simulated glasses contained 1.1 % Ru by weight as ruthenium dioxide (RuO{sub 2}). A portion of the RuO{sub 2} formed needle-shaped crystals in the glass specimens. After the thermal treatment, the glass specimen had separated into two phases. One of the two phases was a B{sub 2}O{sub 3} rich phase, and the other phase was a SiO{sub 2} rich phase. The majority of the chemical species in the B{sub 2}O{sub 3} rich phase was leached away with the Material Characterization Center-3 (MCC-3) protocol standardized by the Pacific Northwest National Laboratory using an aqueous low-concentrated nitric acid solution, but the leaching of the Ru fraction was very limited; less than 1% of the original Ru content. The Ru leaching was much less than those of the other elements, and the needle-shaped crystals of RuO{sub 2} were observed in the B{sub 2}O{sub 3} rich phase in the specimen after the leaching test. Another experiment was performed using another glass specimen which had been prepared with the same frits, but used reagent RuO{sub 2} of granular shape at lower content (0.0073% by weight as RuO{sub 2}). The leached fractions of elements for the latter specimen increased to almost the same fraction (more than 10% of the original Ru content) as observed for boron and sodium, when the phase separated glass was leached using the MMC-3 protocol with non-acidic de-ionized water. Based on the results of this study, it was concluded that needle-shaped RuO{sub 2} crystals are contained in the B{sub 2}O{sub 3}-rich phase after phase separation of the borosilicate glass after a hypothetical blackout. The leaching fraction for the needle-shaped RuO{sub 2} present in the phase separated glass is much lower than those for boron or sodium. Ruthenium behavior has been studied for a hypothetical loss of cooling in the liquid fed ceramic melter for high level waste by taking into account the phase separation of borosilicate glass. The needle-shaped crystal of ruthenium dioxide after bi-nodal-type phase separation of the borosilicate glass at 700 deg. C migrated into the B{sub 2}O{sub 3} rich phase, but remained without dissolution by an acidic aqueous solution. Additionally, granular ruthenium dioxide can be a morphological form of ruthenium after bimodal-type phase separation of the vitrified high level waste with borosilicate glass media. After the phase separation of the borosilicate glass, the crystal shape of the ruthenium dioxide is either needle-shaped or granular, and the leachable fraction of ruthenium is relatively much lower than those of major components (boron and sodium) in the vitrified borosilicate glass. The fraction of leached ruthenium increased to almost the same fraction as observed for boron and sodium when the phase-separated glass was leached with ultrapure water. (authors)

  17. Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2001-01-01

    An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

  18. SEPARATIONS Continuous-Flow Process for the Separation of Cesium from

    E-Print Network [OSTI]

    SEPARATIONS Continuous-Flow Process for the Separation of Cesium from Complex Waste Mixtures of tetraphenylborate (TPB) anions to precipitate cesium from the bulk waste, minimizes the exposure time of TPB following with filtration. The recovered solids are dissolved in propylene carbonate, and cesium

  19. Food waste management using an electrostatic separator with corona discharge

    SciTech Connect (OSTI)

    Lai, Koonchun; Teh, Pehchiong; Lim, Sooking

    2015-05-15

    In Malaysia, municipal solid waste contains a high portion of organic matters, typically contributed by food waste. It is estimated that about 45% of the municipal waste are food waste, followed by the non-food waste such as plastics, metals, glass and others. Food waste, while being properly sorted and contamination free from non-food waste, can be reused (e.g. fertiliser) instead of being landfilled. Therefore, recycling of food waste is crucial not only from the view point of waste management, but also with respect to the reduction of resource losses and greenhouse gases emission. A new waste separation process involved food particles, non-food particles and electrostatic discharge was investigated in this study. The empirical results reveal that the corona electrostatic separation is an environmental-friendly way in recovering foods from municipal waste. The efficiency of the separator, under same operating conditions, varies with the particle size of the food and non-food particles. The highest efficiency of 82% is recorded for the particle sizes between 1.5 and 3.0?mm.

  20. Plasmons in spatially separated double-layer graphene nanoribbons

    SciTech Connect (OSTI)

    Bagheri, Mehran, E-mail: mh-bagheri@sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, G. C., Evin, Tehran 19835-63113 (Iran, Islamic Republic of); Bahrami, Mousa [ICFO-Institut de Ciencies Fotoniques, Parc Mediterrani de la Tecnologia, 08860 Castelldefels (Barcelona) (Spain)

    2014-05-07

    Motivated by innovative progresses in designing multi-layer graphene nanostructured materials in the laboratory, we theoretically investigate the Dirac plasmon modes of a spatially separated double-layer graphene nanoribbon system, made up of a vertically offset armchair and metallic graphene nanoribbon pair. We find striking features of the collective excitations in this novel Coulomb correlated system, where both nanoribbons are supposed to be either intrinsic (undoped/ungated) or extrinsic (doped/gated). In the former, it is shown the low-energy acoustical and the high-energy optical plasmon modes are tunable only by the inter-ribbon charge separation. In the later, the aforementioned plasmon branches are modified by the added doping factor. As a result, our model could be useful to examine the existence of a linear Landau-undamped low-energy acoustical plasmon mode tuned via the inter-ribbon charge separation as well as doping. This study might also be utilized for devising novel quantum optical waveguides based on the Coulomb coupled graphene nanoribbons.

  1. Generalized Hyper-Ramsey Resonance with separated oscillating fields

    E-Print Network [OSTI]

    T. Zanon-Willette; V. I. Yudin; A. V. Taichenachev

    2015-07-15

    An exact generalization of the Ramsey transition probability is derived to improve ultra-high precision measurement and quantum state engineering when a particle is subjected to independently-tailored separated oscillating fields. The phase-shift accumulated at the end of the interrogation scheme offering high-level control of quantum states throughout various laser parameters conditions. The Generalized Hyper-Ramsey Resonance based on independent manipulation of interaction time, field amplitude, phase and frequency detuning is presented to increase the performance of next generation of atomic, molecular and nuclear clocks, to upgrade high resolution frequency measurement in Penning trap mass spectrometry and for a better control of light induced frequency shifts in matter wave interferometers or quantum information processing.

  2. Low-Cost, Robust Ceramic Membranes for Gas Separation

    Broader source: Energy.gov [DOE]

    Ceramic membranes offer great potential for industrial gas separation. Without a ceramic membrane, gases must be cooled before separation. Unfortunately, even though ceramic membranes can improve...

  3. New Mexico Natural Gas Wet After Lease Separation, Reserves in...

    U.S. Energy Information Administration (EIA) Indexed Site

    After Lease Separation, Reserves in Nonproducing Reservoirs (Billion Cubic Feet) New Mexico Natural Gas Wet After Lease Separation, Reserves in Nonproducing Reservoirs (Billion...

  4. Haverford Researchers Create Carbon Dioxide-Separating Polymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy...

  5. Graphene as the Ultimate Membrane for Gas Separation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Graphene as the Ultimate Membrane for Gas Separation Graphene as the Ultimate Membrane for Gas Separation GraphenePore.jpg Key Challenges: Investigate the permeability and...

  6. Solid-Liquid Separation of Animal Manure and Wastewater 

    E-Print Network [OSTI]

    Mukhtar, Saqib; Sweeten, John M.; Auvermann, Brent W.

    1999-10-19

    Solid-liquid separation is an alternative treatment for animal manure and process-generated wastewater. This publication explains the techniques, equipment, performance and economics of separators....

  7. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation...

  8. Advances in Hydrogen Isotope Separation Using Thermal Cycling...

    Office of Environmental Management (EM)

    Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Advances in Hydrogen Isotope Separation Using Thermal Cycling Absorption Process (TCAP) Presentation...

  9. Section 3161 Rehiring Preference for Eligible Separated Employees

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Section 3161 rehiring preference, if they are separated as a result of: (1) termination for cause; (2) voluntary separation from employment; (3) the normal completion of a...

  10. Advancement of isotope separation for the production of reference standards

    SciTech Connect (OSTI)

    Jared Horkley; Christopher McGrath; Andrew Edwards; Gaven Knighton; Kevin Carney; Jacob Davies; James Sommers; Jeffrey Giglio

    2012-03-01

    Idaho National Laboratory (INL) operates a mass separator that is currently producing high purity isotopes for use as internal standards for high precision isotope dilution mass spectrometry (IDMS). In 2008, INL began the revival of the vintage 1970’s era instrument. Advancements thus far include the successful upgrading and development of system components such as the vacuum system, power supplies, ion-producing components, and beam detection equipment. Progress has been made in the separation and collection of isotopic species including those of Ar, Kr, Xe, Sr, and Ba. Particular focuses on ion source improvements and developments have proven successful with demonstrated output beam currents of over 10 micro-amps 138Ba and 350nA 134Ba from a natural abundance source charge (approximately 2.4 percent 134Ba). In order to increase production and collection of relatively high quantities (mg levels) of pure isotopes, several advancements have been made in ion source designs, source material introduction, and beam detection and collection. These advancements and future developments will be presented.

  11. Separator-spacer for electrochemical systems

    DOE Patents [OSTI]

    Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Bellows, Richard J. (Westfield, NJ)

    1983-08-02

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  12. Composite hydrogen separation element and module

    DOE Patents [OSTI]

    Edlund, D.J.

    1996-03-12

    There are disclosed improvements in multicomponent composite metal membranes useful for the separation of hydrogen, the improvements comprising the provision of a flexible porous intermediate layer between a support layer and a nonporous hydrogen-permeable coating metal layer, and the provision of a textured coating metal layer. 15 figs.

  13. Zone separator for multiple zone vessels

    DOE Patents [OSTI]

    Jones, John B. (Grand Junction, CO)

    1983-02-01

    A solids-gas contact vessel, having two vertically disposed distinct reaction zones, includes a dynamic seal passing solids from an upper to a lower zone and maintaining a gas seal against the transfer of the separate treating gases from one zone to the other, and including a stream of sealing fluid at the seal.

  14. Shape separation of gold nanorods using centrifugation

    E-Print Network [OSTI]

    Sharma, Vivek

    Shape separation of gold nanorods using centrifugation Vivek Sharmaa,1 , Kyoungweon Parka,2 , and Mohan Srinivasaraoa,b,c,3 aSchool of Polymer Textile and Fiber Engineering, bCenter for Advanced, and approved January 23, 2009 (received for review January 29, 2008) We demonstrate the use of centrifugation

  15. A Formal Framework for Java Separate Compilation

    E-Print Network [OSTI]

    Robbiano, Lorenzo

    A Formal Framework for Java Separate Compilation Davide Ancona, Giovanni Lagorio, and Elena Zucca,lagorio,zuccag@disi.unige.it Abstract. We de#12;ne a formal notion, called compilation schema, allow- ing to specify di#11;erent possibilities for performing the overall process of Java compilation, which includes type-checking of source

  16. Exponential Separation of Information and Communication

    E-Print Network [OSTI]

    Raz, Ran

    Exponential Separation of Information and Communication Anat Ganor Gillat Kol Ran Raz Abstract We show an exponential gap between communication complexity and information complexity, by giving an explicit example for a communication task (relation), with information complexity O(k), and distributional

  17. Composite hydrogen separation element and module

    DOE Patents [OSTI]

    Edlund, David J. (Redmond, OR)

    1996-03-12

    There are disclosed improvements in multicomponent composite metal membranes useful for the separation of hydrogen, the improvements comprising the provision of a flexible porous intermediate layer between a support layer and a nonporous hydrogen-permeable coating metal layer, and the provision of a textured coating metal layer.

  18. Composite hydrogen separation element and module

    DOE Patents [OSTI]

    Edlund, D.J.; Newbold, D.D.; Frost, C.B.

    1997-07-08

    There are disclosed improvements in multicomponent composite metal membranes useful for the separation of hydrogen, the improvements comprising the provision of at least one common-axis hole through all components of the composite membrane and the provision of a gas-tight seal around the periphery of the hole or holes through a coating metal layer of the membrane. 11 figs.

  19. Composite hydrogen separation element and module

    DOE Patents [OSTI]

    Edlund, David J. (Redmond, OR); Newbold, David D. (Bend, OR); Frost, Chester B. (Bend, OR)

    1997-01-01

    There are disclosed improvements in multicomponent composite metal membranes useful for the separation of hydrogen, the improvements comprising the provision of at least one common-axis hole through all components of the composite membrane and the provision of a gas-tight seal around the periphery of the hole or holes through a coating metal layer of the membrane.

  20. Method and apparatus for separating material

    DOE Patents [OSTI]

    Oder, Robin R.; Jamison, Russell E.

    2004-11-23

    An apparatus for sorting particles composed of a mixture of particles with differing physical and chemical characteristics. The apparatus includes a comminutor or a pulverizer for reducing the size of the particles. The apparatus includes a mechanism for separating undesired material from desired material.

  1. Apparatus for centrifugal separation of coal particles

    DOE Patents [OSTI]

    Dickie, William (New Eagle, PA); Cavallaro, Joseph A. (Mt. Keesport, PA); Killmeyer, Richard P. (Pleasant Hills, PA)

    1991-01-01

    A gravimetric cell for centrifugal separation of fine coal by density has a cylindrical body and a butterfly valve or other apparatus for selectively sealing the body radially across the approximate center of the cylinder. A removable top is provided which seals the cylinder in the centrifuge and in unvented areas.

  2. Multi-stage separations based on dielectrophoresis

    DOE Patents [OSTI]

    Mariella, Jr., Raymond P.

    2004-07-13

    A system utilizing multi-stage traps based on dielectrophoresis. Traps with electrodes arranged transverse to the flow and traps with electrodes arranged parallel to the flow with combinations of direct current and alternating voltage are used to trap, concentrate, separate, and/or purify target particles.

  3. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

    1989-01-01

    There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

  4. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

    1989-04-25

    There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

  5. Crosscutting Technology Development at the Center for Advanced Separation Technologies

    SciTech Connect (OSTI)

    Christopher Hull

    2009-10-31

    The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium -- Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno - that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/biological extraction; (4) Modeling and control; and (5) Environmental control. Distribution of funds is handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. The successful projects are listed by category, along with brief abstracts of their aims and objectives.

  6. K-25 Structural Separation and Demolition

    SciTech Connect (OSTI)

    Cater, Frank [Bechtel Jacobs Company, LLC, East Tennessee Technology Park, Post Office Box 4699, Oak Ridge, TN 37831 (United States)

    2008-01-15

    The K-25 building is a former gaseous diffusion plant, built in 1944-1945 as part of the United States Manhattan Project. The structure was the largest structure under one roof, surpassed only by the Pentagon. Together the three wings represent about 17.8 hectare (44 acres) under roof and are generally about 18.3 meters (60 ft.) high on the outside face and approximately 12.2 meters (40 ft.) high on the inside face. The entire structure was built in the shape of a 'U', with a lateral distance of approximately one mile. It was constructed in individual building units with each unit connected using expansion joint-type connection. A single unit is approximately 24.4 meters (80 ft.) across and 122 meters (400 ft.) deep. The northern structure is connected to the eastern and western structures at the upper level floors. The four-level, U-shaped building is a steel-frame structure with corrugated cement-asbestos siding. The cell level is an elevated concrete structure supported by reinforced concrete columns located in the basement, or vault area. The vault area can be accessed at grade level from the outside perimeter. Inside the courtyard, the grade level has been raised to provide entry to the second or cell floor level. An engineering evaluation of the structure was performed to determine the condition of the structure and possibility of unplanned collapse of any portion of the structure. The evaluation included physical inspections, calculations for wind, pre-demolition loads, and evaluation of failure modes. The results of the evaluation have provided guidance for the demolition plan and the development of criteria for protection of personnel performing pre-demolition activities. Challenges include degradation of the structure that necessitated repair, dealing with changes in the code revisions from both the American Concrete Institute (ACI) and the American Institute of Steel Construction (AISC), access to areas of the structure that were not necessarily designed for access, and acceleration of the building degradation due to the pre-demolition activities. When a full building is evaluated, 50 percent of wind and applied forces are dissipated in 3 units and 80 percent is dissipated in 12 units. The forces are basically linear for the first 6 units once the building is opened at the start of demolition. Some column buckling, based on current codes, was noted in the analysis that would have to be mitigated to ensure a controlled demolition. Loading for the removal of the equipment required structural engineering evaluation of the certainty of the load and the application of the load. Corbels are being evaluated through an inspection program and criteria for repair based on current loading and anticipated additional live loads. Access issues continue to be a challenge and have created the need for a significant fall protection program. Other areas of access require different approaches and engineering solutions, sometime considering ultimate strength design versus standard yield stress design. An evaluation of separating a wing into two sections to allow for worker re-entry to perform pre-demolition activities during the demolition off shift was conducted. The evaluation has shown that because of both design and history of the K-25 and K-27 Buildings, significant care and attention is needed to demolish these structures from a structural perspective. When the project schedule issues are overlaid, that may demand workers in other parts of the structure after demolition has begun, the structural issues become severe, demanding exacting analysis and significant controls to ensure the safety of the workers both in and outside the building performing the demolition work.

  7. Method for forming a cell separator for use in bipolar-stack energy storage devices

    DOE Patents [OSTI]

    Mayer, S.T.; Feikert, J.H.; Kaschmitter, J.L.; Pekala, R.W.

    1994-08-09

    An improved multi-cell electrochemical energy storage device, such as a battery, fuel cell, or double layer capacitor using a cell separator which allows cells to be stacked and interconnected with low electrical resistance and high reliability while maximizing packaging efficiency. By adding repeating cells, higher voltages can be obtained. The cell separator is formed by applying an organic adhesive on opposing surfaces of adjacent carbon electrodes or surfaces of aerogel electrodes of a pair of adjacent cells prior to or after pyrolysis thereof to form carbon aerogel electrodes. The cell separator is electronically conductive, but ionically isolating, preventing an electrolytic conduction path between adjacent cells in the stack. 2 figs.

  8. Cell separator for use in bipolar-stack energy storage devices

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Feikert, John H. (Livermore, CA); Kachmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1995-01-01

    An improved multi-cell electrochemical energy storage device, such as a battery, fuel cell, or double layer capacitor using a cell separator which allows cells to be stacked and interconnected with low electrical resistance and high reliability while maximizing packaging efficiency. By adding repeating cells, higher voltages can be obtained. The cell separator is formed by applying an organic adhesive on opposing surfaces of adjacent carbon electrodes or surfaces of aerogel electrodes of a pair of adjacent cells prior to or after pyrolysis thereof to form carbon aerogel electrodes. The cell separator is electronically conductive, but ionically isolating, preventing an electrolytic conduction path between adjacent cells in the stack.

  9. Method for forming a cell separator for use in bipolar-stack energy storage devices

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Feikert, John H. (Livermore, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1994-01-01

    An improved multi-cell electrochemical energy storage device, such as a battery, fuel cell, or double layer capacitor using a cell separator which allows cells to be stacked and interconnected with low electrical resistance and high reliability while maximizing packaging efficiency. By adding repeating cells, higher voltages can be obtained. The cell separator is formed by applying an organic adhesive on opposing surfaces of adjacent carbon electrodes or surfaces of aerogel electrodes of a pair of adjacent cells prior to or after pyrolysis thereof to form carbon aerogel electrodes. The cell separator is electronically conductive, but ionically isolating, preventing an electrolytic conduction path between adjacent cells in the stack.

  10. Charge separation in organic photovoltaic cells

    E-Print Network [OSTI]

    Giazitzidis, Paraskevas; Bisquert, Juan; Vikhrenko, Vyacheslav S

    2014-01-01

    We consider a simple model for the geminate electron-hole separation process in organic photovoltaicssss cells, in order to illustrate the influence of dimensionality of conducting channels on the efficiency of the process. The Miller-Abrahams expression for the transition rates between nearest neighbor sites was used for simulating random walks of the electron in the Coulomb field of the hole. The non-equilibrium kinetic Monte Carlo simulation results qualitatively confirm the equilibrium estimations, although quantitatively the efficiency of the higher dimensional systems is less pronounced. The lifetime of the electron prior to recombination is approximately equal to the lifetime prior to dissociation. Their values indicate that electrons perform long stochastic walks before they are captured by the collector or recombined. The non-equilibrium free energy considerably differs from the equilibrium one. The efficiency of the separation process decreases with increasing the distance to the collector, and this...

  11. Separations by supported liquid membrane cascades

    DOE Patents [OSTI]

    Danesi, P.R.

    1983-09-01

    The invention describes a new separation technique which leads to multi-stage operations by the use of a series (a cascade) of alternated carrier-containing supported-liquid cation exchanger extractant and a liquid anion exchanger extractant (or a neutral extractant) as carrier. The membranes are spaced between alternated aqueous electrolytic solutions of different composition which alternatively provide positively charged extractable species and negatively charged (or zero charged) extractable species, of the chemical species to be separated. The alternated aqueous electrolytic solutions in addition to providing the driving force to the process, simultaneously function as a stripping solution from one type of membrane and as an extraction-promoting solution for the other type of membrane. The aqueous electrolytic solution and the supported liquid membranes are arranged to provide a continuous process.

  12. Two stroke engine exhaust emissions separator

    DOE Patents [OSTI]

    Turner, Terry D. (Ammon, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Raterman, Kevin T. (Idaho Falls, ID)

    2002-01-01

    A separator for substantially resolving at least one component of a process stream, such as from the exhaust of an internal combustion engine. The separator includes a body defining a chamber therein. A nozzle housing is located proximate the chamber. An exhaust inlet is in communication with the nozzle housing and the chamber. A nozzle assembly is positioned in the nozzle housing and includes a nozzle moveable within and relative to the nozzle housing. The nozzle includes at least one passage formed therethrough such that a process stream entering the exhaust inlet connection passes through the passage formed in the nozzle, which imparts a substantially rotational flow to the process stream as it enters the chamber. A positioning member is configured to position the nozzle relative to the nozzle housing in response to changes in process stream pressure to adjust flowrate of said process stream entering into the chamber.

  13. Phase separation and distribution phenomena in a two-dimensional test section

    SciTech Connect (OSTI)

    Bukhari, K.M.

    1985-01-01

    Experiments were performed to simulate the so-called chimney effect in a PWR core after a hypothetical loss-of-coolant accident. The countercurrent two-phase flow conditions expected in such a situation were simulated in two dimensions in an air/water 3' x 3' x 1/2'' test section having two inlets and two outlets. The void fraction distribution in this test section was measured with ..gamma..-ray densitometer. A description of the experimental setup and of the ..gamma..-ray densitometer, along with an error analysis, is presented. The void fraction was measured at 27 locations across the test section for 18 different flow conditions, including: different flow rates, flow qualities and flow splits between the two inlets. These same conditions were then repeated with one quarter inch diameter vertical rods mounted inside the test section to simulate the effect of lateral resistance to the flow due to fuel rods in the reactor core. The measured void fraction distribution is presented in the form of tables, plots, and high speed photographs. It was found that the presence of the rods reduces the degree of recirculation otherwise found in the test section. Also observed were a variety of flow regimes, including regions of pure liquid, pure air, bubbly, slug, and churn-turbulent flows. To mathematically model the multidimensional flow, a computer program, using the finite element method, was developed to solve the two fluid equations.

  14. Power generation method including membrane separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01

    A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

  15. Crosslinked Polybenzimidazole Membrane For Gas Separation

    DOE Patents [OSTI]

    Jorgensen, Betty S. (Jemez Springs, NM); Young, Jennifer S. (Los Alamos, NM); Espinoza, Brent F. (Los Alamos, NM)

    2005-09-20

    A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by layering a solution of polybenzimidazole (PBI) and a,a'dibromo-p-xylene onto a porous support and evaporating solvent. A supported membrane of cross-linked poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole unexpectedly exhibits an enhanced gas permeability compared to the non-cross linked analog at temperatures over 265° C.

  16. Preconcentration and separation of analytes in microchannels

    DOE Patents [OSTI]

    Hatch, Anson (Tracy, CA); Singh, Anup K. (Danville, CA); Herr, Amy E. (Fremont, CA); Throckmorton, Daniel J. (Tracy, CA)

    2010-11-09

    Disclosed herein are methods and devices for preconcentrating and separating analytes such as proteins and polynucleotides in microchannels. As disclosed, at least one size-exclusion polymeric element is adjacent to processing area or an assay area in a microchannel which may be porous polymeric element. The size-exclusion polymeric element may be used to manipulate, e.g. concentrate, analytes in a sample prior to assaying in the assay area.

  17. Phase-separation of miscible liquids in a centrifuge

    E-Print Network [OSTI]

    Yoav Tsori; Ludwik Leibler

    2007-12-18

    We show that a liquid mixture in the thermodynamically stable homogeneous phase can undergo a phase-separation transition when rotated at sufficiently high frequency $\\omega$. This phase-transition is different from the usual case where two liquids are immiscible or where the slow sedimentation process of one component (e.g. a polymer) is accelerated due to centrifugation. For a binary mixture, the main coupling is due to a term $\\propto \\Delta\\rho(\\omega r)^2$, where $\\Delta\\rho$ is the difference between the two liquid densities and $r$ the distance from the rotation axis. Below the critical temperature there is a critical rotation frequency $\\omega_c$, below which smooth density gradients occur. When $\\omega>\\omega_c$, we find a sharp interface between the low density liquid close to the center of the centrifuge and a high density liquid far from the center. These findings may be relevant to various separation processes and to the control of chemical reactions, in particular their kinetics.

  18. UTILITY OF MECHANISTIC MODELS FOR DIRECTING ADVANCED SEPARATIONS RESEARCH & DEVELOPMENT ACTIVITIES: Electrochemically Modulated Separation Example

    SciTech Connect (OSTI)

    Schwantes, Jon M.

    2009-06-01

    The objective for this work was to demonstrate the utility of mechanistic computer models designed to simulate actinide behavior for use in efficiently and effectively directing advanced laboratory R&D activities associated with developing advanced separations methods.

  19. Separations Technology for Clean Water and Energy

    SciTech Connect (OSTI)

    Jarvinen, Gordon D

    2012-06-22

    Providing clean water and energy for about nine billion people on the earth by midcentury is a daunting challenge. Major investments in efficiency of energy and water use and deployment of all economical energy sources will be needed. Separations technology has an important role to play in producing both clean energy and water. Some examples are carbon dioxide capture and sequestration from fossil energy power plants and advanced nuclear fuel cycle scemes. Membrane separations systems are under development to improve the economics of carbon capture that would be required at a huge scale. For nuclear fuel cycles, only the PUREX liquid-liquid extraction process has been deployed on a large scale to recover uranium and plutonium from used fuel. Most current R and D on separations technology for used nuclear fuel focuses on ehhancements to a PUREX-type plant to recover the minor actinides (neptunium, americiu, and curium) and more efficiently disposition the fission products. Are there more efficient routes to recycle the actinides on the horizon? Some new approaches and barriers to development will be briefly reviewed.

  20. Combined current collector and electrode separator

    DOE Patents [OSTI]

    Gerenser, R.J.; Littauer, E.L.

    1983-08-23

    This relates to reactive metal cells wherein there is a cathode and a consumable anode. It is necessary to separate the cathode from the anode so that an electrolyte may constantly flow over the face of the anode opposing the cathode. It has been found that this separator may also beneficially function as a current collector. The combined current collector and separator includes a peripheral supporting frame of which a portion may function as a bus-bar. A plurality of bars or ribs extend in parallel relation across the opening defined by the supporting frame and are electrically connected to the bus-bar portion. It is preferred that each bar or rib have a pointed or line edge which will engage and slightly bite into the associated anode to maintain the bar or rib in electrical contact with the anode. This abstract forms no part of the specification of this application and is not to be construed as limiting the claims of the application. 6 figs.

  1. Multilevel cascade voltage source inverter with separate DC sources

    DOE Patents [OSTI]

    Peng, F.Z.; Lai, J.S.

    1997-06-24

    A multilevel cascade voltage source inverter having separate DC sources is described herein. This inverter is applicable to high voltage, high power applications such as flexible AC transmission systems (FACTS) including static VAR generation (SVG), power line conditioning, series compensation, phase shifting and voltage balancing and fuel cell and photovoltaic utility interface systems. The M-level inverter consists of at least one phase wherein each phase has a plurality of full bridge inverters equipped with an independent DC source. This inverter develops a near sinusoidal approximation voltage waveform with only one switching per cycle as the number of levels, M, is increased. The inverter may have either single-phase or multi-phase embodiments connected in either wye or delta configurations. 15 figs.

  2. Design of Hybrid Distillation-Vapor Membrane Separation Systems. Jose A. Caballero*; Ignacio E. Grossmann **; Majid Keyvani+

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    to explore alternative separation technologies with lower energy consumption. In this work, using in the near future1,2 . Although there are a number of new developments for alternative separation techniques in petrochemical industries. Since this technology is highly energy intensive, there is a strong economic incentive

  3. A New Kind of Column Materials for Gas Chromatographic Hydrogen Isotope Separation

    SciTech Connect (OSTI)

    Hara, M.; Shima, H.; Akamaru, S.; Abe, T.; Matsuyama, M.; Watanabe, K. [Toyama University (Japan)

    2005-07-15

    A new kind of materials that can be applied to a gas chromatographic hydrogen isotope separation system was developed to reduce the amount of Pd-Pt alloy required for making the column and to improve the separation efficiency. Pd and Pt were deposited on {alpha}-Al{sub 2}O{sub 3} powder by using a barrel sputtering system. Prepared sample powder was characterized from surface morphology, element distributions on the surface, composition and crystallinity. The characterization showed that a uniform layer of Pd-Pt alloy with expected composition was formed on Al{sub 2}O{sub 3} particles. The crystallinity, however, was poor, but improved after annealing at 1073 K for 2 hours. The hydrogen absorbing behavior was also improved by the annealing. A separation column was prepared from the annealed powder and was subjected to experiments on hydrogen isotope separation. The column of annealed powder gave considerably good separation efficiency around room temperature, in spite that only 0.35 g of Pd-Pt was used for the column. The amount of Pd-Pt alloy used here should be compared to previous results, where 1.5 g of Pd-Pt powder was required for high separation efficiency. The new material was quite effective to reduce the amount of Pd-Pt alloy without compromising the separation efficiency and can give further improvement.

  4. Application of coal petrography to the evaluation of magnetically separated dry crushed coals

    SciTech Connect (OSTI)

    Harris, L.A.; Hise, E.C.

    1981-01-01

    In the present study the open gradient magnetic separation method has been used to beneficiate the -30 + 100 mesh fraction of two high volatile bituminous coals. The evaluation of the effectiveness of the magnetic separation for cleaning these coals is the subject of this paper. Coal petrography in combination with scanning electron microscopy and x-ray diffractometry were used to characterize the magnetically separated coal fractions. These analyses revealed that the majority of the pyrite and non-pyrite minerals were concentrated in the positive magnetic susceptibility fractions. The bulk of the starting samples (approx. 80 weight percent) were located in the negative magnetic susceptibility fractions and showed significant reductions in pyrite and non-pyritic minerals. The magnetic separation appears to effectively split the samples into relatively clean coal and refuse.

  5. Evaluation of solid-based separation materials for the pretreatment of radioactive wastes

    SciTech Connect (OSTI)

    Lumetta, G.J.; Wagner, M.J.; Wester, D.W.; Morrey, J.R.

    1993-05-01

    Separation science will play an important role in pretreating nuclear wastes stored at various US Department of Energy Sites. The application of separation processes offers potential economic and environmental benefits with regards to remediating these sites. For example, at the Hanford Site, the sizeable volume of radioactive wastes stored in underground tanks could be partitioned into a small volume of high-level waste (HLW) and a relatively large volume of low-level waste (LLW). After waste separation, only the smaller volume of HLW would require costly vitrification and geologic disposal. Furthermore, the quality of the remaining LLW form (e.g., grout) would be improved due to the lower inventory of radionuclides present in the LLW stream. This report investigates extraction chromatography as a possible separation process for Hanford wastes.

  6. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  7. Alternative applications of atomic vapor laser isotope separation technology

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This report was commissioned by the Secretary of Energy. It summarizes the main features of atomic vapor laser isotope separation (AVLIS) technology and subsystems; evaluates applications, beyond those of uranium enrichment, suggested by Lawrence Livermore National Laboratory (LLNL) and a wide range of US industries and individuals; recommends further work on several applications; recommends the provision of facilities for evaluating potential new applications; and recommends the full involvement of end users from the very beginning in the development of any application. Specifically excluded from this report is an evaluation of the main AVLIS missions, uranium enrichment and purification of plutonium for weapons. In evaluating many of the alternative applications, it became clear that industry should play a greater and earlier role in the definition and development of technologies with the Department of Energy (DOE) if the nation is to derive significant commercial benefit. Applications of AVLIS to the separation of alternate (nonuranium) isotopes were considered. The use of {sup 157}Gd as burnable poison in the nuclear fuel cycle, the use {sup 12}C for isotopically pure diamond, and the use of plutonium isotopes for several nonweapons applications are examples of commercially useful products that might be produced at a cost less than the product value. Separations of other isotopes such as the elemental constituents of semiconductors were suggested; it is recommended that proposed applications be tested by using existing supplies to establish their value before more efficient enrichment processes are developed. Some applications are clear, but their production costs are too high, the window of opportunity in the market has passed, or societal constraints (e.g., on reprocessing of reactor fuel) discourage implementation.

  8. Restoring broken entanglement by separable correlations

    E-Print Network [OSTI]

    Gaetana Spedalieri; Stefano Pirandola

    2015-09-04

    We consider two bosonic Gaussian channels whose thermal noise is strong enough to break bipartite entanglement. In this scenario, we show how the presence of separable correlations between the two channels is able to restore the broken entanglement. This reactivation occurs not only in a scheme of direct distribution, where a third party (Charlie) broadcasts entangled states to remote parties (Alice and Bob), but also in a configuration of indirect distribution which is based on entanglement swapping. In both schemes, the amount of entanglement remotely activated can be large enough to be distilled by one-way distillation protocols.

  9. Tripartite non-separability in classical optics

    E-Print Network [OSTI]

    W. F. Balthazar; C. E. R. Souza; D. P. Caetano; E. F. Galvăo; J. A. O. Huguenin; A. Z. Khoury

    2015-11-06

    It is possible to prepare classical optical beams which cannot be characterized by a tensor product of vectors describing each of their degrees of freedom. Here we report the experimental creation of such a non-separable, tripartite GHZ-like state of path, polarization and transverse modes of a classical laser beam. We use a Mach-Zehnder interferometer with an additional mirror and other optical elements to perform measurements that violate Mermin's inequality. This demonstration of a classical optical analogue of tripartite entanglement paves the path to novel optical applications inspired by multipartite quantum information protocols.

  10. Membranes for separation of carbon dioxide

    DOE Patents [OSTI]

    Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY); Willson, Patrick Daniel (Latham, NY); Gao, Yan (Niskayuna, NY)

    2011-03-01

    Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, VO.sub.z, NbO.sub.z, TaO.sub.z, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3 CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3, Li.sub.2HfO.sub.3, A.sup.4N.sup.1.sub.yO.sub.z, Y.sub.xN.sup.1.sub.yO.sub.z, La.sub.xN.sup.1.sub.yO.sub.z, HfN.sup.2.sub.yO.sub.z, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; A.sup.3 is Sr or Ba; A.sup.4 is Mg, Ca, Sr, Ba, Ti or Zr; N.sup.1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N.sup.2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.

  11. Surface selective membranes for carbon dioxide separation

    SciTech Connect (OSTI)

    Luebke, D.R.; Pennline, H.W.; Myers, C.R.

    2005-09-01

    In this study, hybrid membranes have been developed for the selective separation of CO2 from mixtures containing H2. Beginning with commercially available Pall alumina membrane tubes with nominal pore diameter of 5 nm, hybrids were produced by silation with a variety of functionalities designed to facilitate the selective adsorption of CO2 onto the pore surface. The goal is to produce a membrane which can harness the power of surface diffusion to give the selectivity of polymer membranes with the permeance of inorganic membranes.

  12. Fast separation of two trapped ions

    E-Print Network [OSTI]

    M. Palmero; S. Martínez-Garaot; U. G. Poschinger; A. Ruschhaupt; J. G. Muga

    2015-05-19

    We design fast protocols to separate or recombine two ions in a segmented Paul trap. By inverse engineering the time evolution of the trapping potential composed of a harmonic and a quartic term, it is possible to perform these processes in a few microseconds without final excitation. These times are much shorter than the ones reported so far experimentally. The design is based on dynamical invariants and dynamical normal modes. Anharmonicities beyond the harmonic approximation at potential minima are taken into account perturbatively. The stability versus an unknown potential bias is also studied.

  13. Metal oxide membranes for gas separation

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Webster, Elizabeth T. (Madison, WI); Xu, Qunyin (Plainsboro, NJ)

    1994-01-01

    A method for permformation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation.

  14. Metal oxide membranes for gas separation

    DOE Patents [OSTI]

    Anderson, M.A.; Webster, E.T.; Xu, Q.

    1994-08-30

    A method for formation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation. 4 figs.

  15. Protein separations using porous silicon membranes 

    E-Print Network [OSTI]

    Pass, Shannon Marie

    1992-01-01

    ) 61 IX LIST OF TABLES 1. The L9 Orthogonal Array 34 2. Experimental Factors and Levels . 3. Results of Silicon Etching Trials . 35 40 4. Results of Silicon Membrane Separation Experiments 44 5. Results of Single Solute Experiments Using... charge or as the absence of an electron in the crystal structure of silicon. The properties of boron doped siTicon are exploited experimentally by setting up an etch cell in which one surface of the silicon serves as the anode and by using...

  16. Separation process using pervaporation and dephlegmation

    DOE Patents [OSTI]

    Vane, Leland M.; Mairal, Anurag P.; Ng, Alvin; Alvarez, Franklin R.; Baker, Richard W.

    2004-06-29

    A process for treating liquids containing organic compounds and water. The process includes a pervaporation step in conjunction with a dephlegmation step to treat at least a portion of the permeate vapor from the pervaporation step. The process yields a membrane residue stream, a stream enriched in the more volatile component (usually the organic) as the overhead stream from the dephlegmator and a condensate stream enriched in the less volatile component (usually the water) as a bottoms stream from the dephlegmator. Any of these may be the principal product of the process. The membrane separation step may also be performed in the vapor phase, or by membrane distillation.

  17. Involuntary Separation Plan Template | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLforLDRDEnergy Copyrights ASiteasInvoluntary Separation Plan

  18. Super Separator | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect PhotovoltaicsStructureInnovationEnergySuper Separator February 12, 2013 Tweet

  19. Separation Creek Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-bRenewableSMUDSectional ModelofSenerSeparation Creek

  20. Separation Design Group LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-bRenewableSMUDSectional ModelofSenerSeparation

  1. Y-12 electromagnetic separation process wins approval

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLos Alamos verifies largest single and theelectromagnetic separation

  2. A NOVEL CO{sub 2} SEPARATION SYSTEM

    SciTech Connect (OSTI)

    Robert J. Copeland

    2000-08-01

    Because of concern over global climate change, new systems are needed that produce electricity from fossil fuels and emit less CO{sub 2}. The fundamental problem with current systems which recover and concentrate CO{sub 2} from flue gases is the need to separate dilute CO{sub 2} and pressurize it to roughly 35 atm for storage or sequestration. This is an energy intensive process that can reduce plant efficiency by 9-37% and double the cost of electricity. There are two fundamental reasons for the current high costs of power consumption, CO{sub 2} removal, and concentration systems: (1) most disposal, storage and sequestering systems require high pressure CO{sub 2} (at roughly 35 atm). Thus, assuming 90% removal of the CO{sub 2} from a typical atmospheric pressure flue gas that contains 10% CO{sub 2}, the CO{sub 2} is essentially being compressed from 0.01 atm to 35 atm (a pressure ratio of 3,500). This is a very energy intensive process. (2) The absorption-based (amine) separation processes that are used to remove the CO{sub 2} from the flue gas and compress it to 1 atm consume approximately 10 times as much energy as the theoretical work of compression because they are heat driven cycles working over a very low temperature difference. Thus, to avoid the problems of current systems, we need a power cycle in which the CO{sub 2} produced by the oxidation of the fuel is not diluted with a large excess of nitrogen, a power cycle which would allow us to eliminate the very inefficient thermally driven absorption/desorption step. In addition, we would want the CO{sub 2} to be naturally available at high pressure (approximately 3 to 6 atmospheres), which would allow us to greatly reduce the compression ratio between generation and storage (from roughly 3,500 to approximately 8).

  3. Axisymmetrical separator for separating particulate matter from a fluid carrying medium

    DOE Patents [OSTI]

    Linhardt, Hans D. (Newport Beach, CA)

    1984-09-04

    A separator for separating particles carried in a fluid carrying medium is disclosed. The separator includes an elongated duct and associated openings incorporated in a solid body. The duct is axisymmetrical relative to its longitudinal axis, and includes a curved wall portion having a curved cross-section taken along the longitudinal axis. An axisymmetrical opening located downstream of the curved wall portion leads from the duct into an axisymmetrical channel which is substantially radially disposed relative to the longitudinal axis. Continuation of the duct downstream of the opening is a discharge portion which is substantially colinear with the longitudinal axis. In operation, a substantial majority of the fluid carrying medium leaves the duct radially through the opening and channel in a state substantially free of particles. A remaining small portion of the fluid carrying medium and a substantial majority of the particles are channelled into the discharge portion by centrifugal forces arising due to travel of the particles along the curved walls. For industrial scale separation of particles from a fluid carrying medium, such as for the clean-up of stack gases, an array of several hundred to several thousand of the separators is provided.

  4. Evaluation of a New Remote Handling Design for High Throughput Annular Centrifugal Contactors

    SciTech Connect (OSTI)

    David H. Meikrantz; Troy G. Garn; Jack D. Law; Lawrence L. Macaluso

    2009-09-01

    Advanced designs of nuclear fuel recycling plants are expected to include more ambitious goals for aqueous based separations including; higher separations efficiency, high-level waste minimization, and a greater focus on continuous processes to minimize cost and footprint. Therefore, Annular Centrifugal Contactors (ACCs) are destined to play a more important role for such future processing schemes. Previous efforts defined and characterized the performance of commercial 5 cm and 12.5 cm single-stage ACCs in a “cold” environment. The next logical step, the design and evaluation of remote capable pilot scale ACCs in a “hot” or radioactive environment was reported earlier. This report includes the development of remote designs for ACCs that can process the large throughput rates needed in future nuclear fuel recycling plants. Novel designs were developed for the remote interconnection of contactor units, clean-in-place and drain connections, and a new solids removal collection chamber. A three stage, 12.5 cm diameter rotor module has been constructed and evaluated for operational function and remote handling in highly radioactive environments. This design is scalable to commercial CINC ACC models from V-05 to V-20 with total throughput rates ranging from 20 to 650 liters per minute. The V-05R three stage prototype was manufactured by the commercial vendor for ACCs in the U.S., CINC mfg. It employs three standard V-05 clean-in-place (CIP) units modified for remote service and replacement via new methods of connection for solution inlets, outlets, drain and CIP. Hydraulic testing and functional checks were successfully conducted and then the prototype was evaluated for remote handling and maintenance suitability. Removal and replacement of the center position V-05R ACC unit in the three stage prototype was demonstrated using an overhead rail mounted PaR manipulator. This evaluation confirmed the efficacy of this innovative design for interconnecting and cleaning individual stages while retaining the benefits of commercially reliable ACC equipment for remote applications in the nuclear industry. Minor modifications and suggestions for improved manual remote servicing by the remote handling specialists were provided but successful removal and replacement was demonstrated in the first prototype.

  5. Fuel cell separator with compressible sealing flanges

    DOE Patents [OSTI]

    Mientek, A.P.

    1984-03-30

    A separator for separating adjacent fuel cells in a stack of such cells includes a flat, rectangular, gas-impermeable plate disposed between adjacent cells and having two opposite side margins thereof folded back over one side of the plate to form two first seal flanges and having the other side margins thereof folded back over the opposite side of the plate to form two second seal flanges, each of the seal flanges cooperating with the plate to define a channel in which is disposed a resiliently compressible stack of thin metal sheets. The two first seal flanges cooperate with the electrolyte matrix of one of the cells to form a gas-impermeable seal between an electrode of the one cell and one of two reactant gas manifolds. The second seal flanges cooperate with the electrolyte matrix of the other cell for forming a gas-impermeable seal between an electrode of the other cell and the other of the two reactant gas manifolds. The seal flanges cooperate with the associated compressible stacks of sheets for maintaining a spacing between the plate and the electrolyte matrices while accommodating variation of that spacing.

  6. Species separation in inertial confinement fusion fuels

    SciTech Connect (OSTI)

    Bellei, C.; Amendt, P. A.; Wilks, S. C. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Haines, M. G. [Blackett Laboratory, Imperial College, London SW7 2AZ (United Kingdom); Casey, D. T. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Li, C. K.; Petrasso, R. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Welch, D. R. [Voss Scientic, Albuquerque, New Mexico 87108 (United States)

    2013-01-15

    It is shown by means of multi-fluid particle-in-cell simulations that convergence of the spherical shock wave that propagates through the inner gas of inertial confinement fusion-relevant experiments is accompanied by a separation of deuterium (D) and tritium (T) ions across the shock front. Deuterons run ahead of the tritons due to their lower mass and higher charge-to-mass ratio and can reach the center several tens of picoseconds before the tritons. The rising edge of the DD and TT fusion rate is also temporally separated by the same amount, which should be an observable in experiments and would be a direct proof of the 'stratification conjecture' on the shock front [Amendt et al., Phys. Plasmas 18, 056308 (2011)]. Moreover, dephasing of the D and T shock components in terms of density and temperature leads to a degradation of the DT fusion yield as the converging shock first rebounds from the fuel center (shock yield). For the parameters of this study, the second peak in the fusion yield (compression yield) is strongly dependent on the choice of the flux limiter.

  7. Functionalized inorganic membranes for gas separation

    DOE Patents [OSTI]

    Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Molaison, Jennifer Lynn (Marietta, GA); Schick, Louis Andrew ,(Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY)

    2008-07-08

    A porous membrane for separation of carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity. The porous membrane comprises a porous support layer comprising alumina, silica, zirconia or stabilized zirconia; a porous separation layer comprising alumina, silica, zirconia or stabilized zirconia, and a functional layer comprising a ceramic oxide contactable with the fluid stream to preferentially transport carbon dioxide. In particular, the functional layer may be MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3 or a mixture thereof; wherein A is Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; and A.sup.3 is Sr or Ba.

  8. Method and apparatus for separating material

    DOE Patents [OSTI]

    Oder, Robin R.; Jamison, Russell E.

    2006-10-24

    An apparatus for sorting particles composed of a mixture of particles with differing physical and chemical characteristics. The apparatus includes a comminutor, a mechanism for removing particles from the inside of the comminutor which are intermediate in size between the feed to the comminutor and the product of comminution, a mechanism for either discharging particles taken from the comminutor to a reject stream or providing them to a size classification apparatus such as screening, a mechanism for returning the oversize particles to the comminutor or for discharging them to the reject stream, an electric mechanism for separating particles with an electrical force disposed adjacent to a magnet mechanism, a mechanism for providing the particles to the magnet mechanism and the electric mechanism and for providing triboelectric and capacitive charges to the particles, and a mechanism for returning one of the products of electric and magnetic separation to the comminutor while discharging the other to the reject stream. A method for sorting particles composed of a mixture of particles with differing physical and chemical characteristics.

  9. Wetting and phase separation in soft adhesion

    E-Print Network [OSTI]

    K. E. Jensen; R. Sarfati; R. W. Style; R. Boltyanskiy; A. Chakrabarti; M. K. Chaudhury; E. R. Dufresne

    2015-07-22

    In the classic theory of solid adhesion, surface energy drives deformation to increase contact area while bulk elasticity opposes it. Recently, solid surface stress has been shown also to play an important role in opposing deformation of soft materials. This suggests that the contact line in soft adhesion should mimic that of a liquid droplet, with a contact angle determined by surface tensions. Consistent with this hypothesis, we observe a contact angle of a soft silicone substrate on rigid silica spheres that depends on the surface functionalization but not the sphere size. However, to satisfy this wetting condition without a divergent elastic stress, the gel separates from its solvent near the contact line. This creates a four-phase contact zone with two additional contact lines hidden below the surface of the substrate. While the geometries of these contact lines are independent of the size of the sphere, the volume of the phase-separated region is not, but rather depends on the indentation volume. These results indicate that theories of adhesion of soft gels need to account for both the compressibility of the gel network and a non-zero surface stress between the gel and its solvent.

  10. Cu--Pd--M hydrogen separation membranes

    SciTech Connect (OSTI)

    Do{hacek over }an, Omer N; Gao, Michael C; Young, Rongxiang Hu; Tafen, De Nyago

    2013-12-17

    The disclosure provides an H2 separation membrane comprised of an allow having the composition Cu.Sub.(100-x-y)Pd.sub.xM.sub.y, where x is from about 35 to about 50 atomic percent and where y is from greater than 0 to about 20 atomic percent, and where M consists of magnesium, yttrium, aluminum, titanium, lanthanum, or combinations thereof. The M elements act as strong stabilizers for the B2 phase of the allow, and extend the critical temperature of the alloy for a given hydrogen concentration and pressure. Due to the phase stabilization and the greater temperature range over which a B2 phase can be maintained, the allow is well suited for service as a H2 separation membrane, particularly when applicable conditions are established or cycled above about 600.degree. C. over the course of expected operations. In certain embodiments, the B2 phase comprises at least 60 estimated volume percent of the allow at a steady-state temperature of 400.degree. C. The B2 phase stability is experimentally validated through HT-XRD.

  11. Phase Separation in Giant Planets: Inhomogeneous Evolution of Saturn

    E-Print Network [OSTI]

    Jonathan J. Fortney; William B. Hubbard

    2003-05-01

    We present the first models of Jupiter and Saturn to couple their evolution to both a radiative-atmosphere grid and to high-pressure phase diagrams of hydrogen with helium and other admixtures. We find that prior calculated phase diagrams in which Saturn's interior reaches a region of predicted helium immiscibility do not allow enough energy release to prolong Saturn's cooling to its known age and effective temperature. We explore modifications to published phase diagrams that would lead to greater energy release, and propose a modified H-He phase diagram that is physically reasonable, leads to the correct extension of Saturn's cooling, and predicts an atmospheric helium mass fraction Y_atmos = 0.185, in agreement with recent estimates. We also explore the possibility of internal separation of elements heavier than helium, and find that, alternatively, such separation could prolong Saturn's cooling to its known age and effective temperature under a realistic phase diagram and heavy element abundance (in which case Saturn's Y_atmos would be solar but heavier elements would be depleted). In none of these scenarios does Jupiter's interior evolve to any region of helium or heavy-element immiscibility: Jupiter evolves homogeneously to the present day. We discuss the implications of our calculations for Saturn's primordial core mass.

  12. RAPID SEPARATION OF ACTINIDES AND RADIOSTRONTIUM IN VEGETATION SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2010-06-01

    A new rapid method for the determination of actinides and radiostrontium in vegetation samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used in emergency response situations or for routine analysis. The actinides in vegetation method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Alpha emitters are prepared using rare earth microprecipitation for counting by alpha spectrometry. The purified {sup 90}Sr fractions are mounted directly on planchets and counted by gas flow proportional counting. The method showed high chemical recoveries and effective removal of interferences. The actinide and {sup 90}Sr in vegetation sample analysis can be performed in less than 8 h with excellent quality for emergency samples. The rapid fusion technique is a rugged sample digestion method that ensures that any refractory actinide particles or vegetation residue after furnace heating is effectively digested.

  13. Separation of heat and charge currents for boosted thermoelectric conversion

    E-Print Network [OSTI]

    Francesco Mazza; Stefano Valentini; Riccardo Bosisio; Giuliano Benenti; Vittorio Giovannetti; Rosario Fazio; Fabio Taddei

    2015-07-01

    In a multi-terminal device the (electronic) heat and charge currents can follow different paths. In this paper we introduce and analyse a class of multi-terminal devices where this property is pushed to its extreme limits, with charge $and$ heat currents flowing in different reservoirs. After introducing the main characteristics of such $heat-charge$ $current$ $separation$ regime we show how to realise it in a multi-terminal device with normal and superconducting leads. We demonstrate that this regime allows to control independently heat and charge flows and to greatly enhance thermoelectric performances at low temperatures. We analyse in details a three-terminal setup involving a superconducting lead, a normal lead and a voltage probe. For a generic scattering region we show that in the regime of heat-charge current separation both the power factor and the figure of merit $ZT$ are highly increased with respect to a standard two-terminal system. These results are confirmed for the specific case of a system consisting of three coupled quantum dots.

  14. Nonlinear dynamics of three dimensional fluid flow separation

    E-Print Network [OSTI]

    Surana, Amit

    2007-01-01

    Flow separation (the detachment of fluid from a no-slip boundary) is a major cause of performance loss in engineering devices, including diffusers, airfoils and jet engines. The systematic study of flow separation dates ...

  15. Materials and interfaces for catalysis, separation, storage, and environmental applications

    E-Print Network [OSTI]

    Nair, Sankar

    the next generation of catalysts, separation processes, gas and liquid storage technologiesMaterials and interfaces for catalysis, separation, storage, and environmental applications Advanced materials and interfaces (including surfaces, thin films, and membranes) are a key to developing

  16. Feedback control of flow separation using synthetic jets 

    E-Print Network [OSTI]

    Kim, Kihwan

    2006-04-12

    The primary goal of this research is to assess the effect of synthetic jets on flow separation and provide a feedback control strategy for flow separation using synthetic jets. The feedback control synthesis is conducted based upon CFD simulation...

  17. Numerical simulation of flow separation control by oscillatory fluid injection 

    E-Print Network [OSTI]

    Resendiz Rosas, Celerino

    2005-08-29

    In this work, numerical simulations of flow separation control are performed. The sep-aration control technique studied is called 'synthetic jet actuation'. The developed code employs a cell centered finite volume scheme which handles viscous...

  18. Source-Filter Separation for Articulation-to-Speech Synthesis 

    E-Print Network [OSTI]

    Shiga, Yoshinori; King, Simon

    In this paper we examine a method for separating out the vocal-tract filter response from the voice source characteristic using a large articulatory database. The method realises such separation for voiced speech using an ...

  19. Electrochemically-mediated amine regeneration for carbon dioxide separations

    E-Print Network [OSTI]

    Stern, Michael C. (Michael Craig)

    2014-01-01

    This thesis describes a new strategy for carbon dioxide (CO?) separations based on amine sorbents, which are electrochemically-mediated to facilitate the desorption and regeneration steps of the separation cycle. The ...

  20. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  1. Isotope separation and advanced manufacturing technology. Volume 2, No. 2, Semiannual report, April--September 1993

    SciTech Connect (OSTI)

    Kan, Tehmanu; Carpenter, J.

    1993-12-31

    This is the second issue of a semiannual report for the Isotope Separation and Advanced Manufacturing (ISAM) Technology Program at Lawrence Livermore National Laboratory. Primary objectives of the ISAM Program include: the Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) process, and advanced manufacturing technologies which include industrial laser materials processing and new manufacturing technologies for uranium, plutonium, and other strategically important materials in support of DOE and other national applications. Topics included in this issue are: production plant product system conceptual design, development and operation of a solid-state switch for thyratron replacement, high-performance optical components for high average power laser systems, use of diode laser absorption spectroscopy for control of uranium vaporization rates, a two-dimensional time dependent hydrodynamical ion extraction model, and design of a formaldehyde photodissociation process for carbon and oxygen isotope separation.

  2. Chiral electric separation effect in the quark-gluon plasma

    E-Print Network [OSTI]

    Yin Jiang; Xu-Guang Huang; Jinfeng Liao

    2015-02-16

    In this paper we introduce and compute a new transport coefficient for the quark-gluon plasma (QGP) at very high temperature. This new coefficient $\\sigma_{\\chi e}$, the CESE (Chiral Electric Separation Effect) conductivity, quantifies the amount of axial current $\\vec J_A$ that is generated in response to an externally applied electric field $e\\vec E$: $\\vec J_A = \\sigma_{\\chi e} (e\\vec E)$. Starting with rather general argument in the kinetic theory framework, we show how a characteristic structure $\\sigma_{\\chi e}\\propto \\mu \\mu_5$ emerges, which also indicates the CESE as an anomalous transport effect occurring only in a parity-odd environment with nonzero axial charge density $\\mu_5\

  3. Chiral electric separation effect in the quark-gluon plasma

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Yin; Liao, Jinfeng; Huang, Xu-Guang

    2015-02-02

    In this paper we introduce and compute a new transport coefficient for the quark-gluon plasma (QGP) at very high temperature. This new coefficient ??e, the CESE (Chiral Electric Separation Effect) conductivity, quantifies the amount of axial current JA that is generated in response to an externally applied electric field eE: JA=??e(eE). Starting with a rather general argument in the kinetic theory framework, we show how a characteristic structure ??e???5 emerges, which also indicates the CESE as an anomalous transport effect occurring only in a parity-odd environment with nonzero axial charge density ?5 ? 0. Using the Hard-Thermal-Loop framework, the CESEmore »conductivity for the QGP is found to be ??e = (#)TTrfQeQA/g?ln(1/g) ??5/T˛ to the leading-log accuracy with the numerical constant (#) depending on favor content, e.g., (#)=14.5163 for u, d light flavors.« less

  4. Effect of temperature on layer separation by plasma-hydrogenation

    SciTech Connect (OSTI)

    Di, Zengfeng [Los Alamos National Laboratory; Michael, Nastasi A [Los Alamos National Laboratory; Wang, Yongqiang [Los Alamos National Laboratory

    2008-01-01

    We have studied hydrogen diffusion in plasma hydrogenated Si/SiGe/Si heterostructure at different temperatures. At low temperature, intrinsic point defects in the molecular beam epitaxy grown Si capping layer are found to compete with the buried strain SiGe layer for hydrogen trapping. The interaction of hydrogen with point defects affects the hydrogen long-range diffusion, and restricts the amount of hydrogen available for trapping by the SiGe layer. However, hydrogen trapping by the capping layer is attenuated with increasing hydrogenation temperature allowing more hydrogen to be trapped in the strain SiGe layer with subsequent surface blister formation. A potential temperature window for plasma hydrogenation induced layer separation is identified based on the combined considerations of trap-limited diffusion at low temperature and outdiffusion of H{sub 2} molecule together with the dissociation of Si-H bonds inside of H platelet at high temperature.

  5. Chiral electric separation effect in the quark-gluon plasma

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Yin [Indiana Univ., Bloomington, IN (United States); Liao, Jinfeng [Indiana Univ., Bloomington, IN (United States); Brookhaven National Lab., Upton, NY (United States); Huang, Xu-Guang [Fudan Univ., Shanghai (China)

    2015-02-01

    In this paper we introduce and compute a new transport coefficient for the quark-gluon plasma (QGP) at very high temperature. This new coefficient ??e, the CESE (Chiral Electric Separation Effect) conductivity, quantifies the amount of axial current JA that is generated in response to an externally applied electric field eE: JA=??e(eE). Starting with a rather general argument in the kinetic theory framework, we show how a characteristic structure ??e???5 emerges, which also indicates the CESE as an anomalous transport effect occurring only in a parity-odd environment with nonzero axial charge density ?5 ? 0. Using the Hard-Thermal-Loop framework, the CESE conductivity for the QGP is found to be ??e = (#)TTrfQeQA/g?ln(1/g) ??5/T˛ to the leading-log accuracy with the numerical constant (#) depending on favor content, e.g., (#)=14.5163 for u, d light flavors.

  6. Possibility of separation of deuterium from natural hydrogen by a palladium particle bed

    SciTech Connect (OSTI)

    Fukada, Satoshi; Fujiwara, Hiroshi

    1999-08-01

    Deuterium in natural hydrogen can be successfully concentrated by means of frontal chromatography using a Pd particle bed at room temperature. The deuterium concentration at the outlet reaches a maximum immediately after hydrogen breaks through the bed. The outlet concentration curve is correlated to a unified profile based on the plate model regardless of the gaseous flow rate and the inlet deuterium concentration. The height equivalent to a theoretical plate, HETP, decreases from 7.6 to 4.7 mm with an increase of the flow rate from 15 to 87 mL(NTP)/min.

  7. Immobilized fluid membranes for gas separation

    DOE Patents [OSTI]

    Liu, Wei; Canfield, Nathan L; Zhang, Jian; Li, Xiaohong Shari; Zhang, Jiguang

    2014-03-18

    Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.

  8. CENTER FOR ADVANCED SEPARATION TECHNOLOGY (CAST) PROGRAM

    SciTech Connect (OSTI)

    Yoon, Roe-Hoan; Hull, Christopher

    2014-09-30

    The U.S. is the largest producer of mining products in the world. In 2011, U.S. mining operations contributed a total of $232 billion to the nation’s GDP plus $138 billion in labor income. Of this the coal mining industry contributed a total of $97.5 billion to GDP plus $53 billion in labor income. Despite these contributions, the industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations.

  9. Anion separation with metal-organic frameworks

    SciTech Connect (OSTI)

    Custelcean, Radu; Moyer, Bruce A

    2007-01-01

    The application of metal-organic frameworks (MOFs) to anion separations with a special emphasis on anion selectivity is reviewed. The coordination frameworks are classified on the basis of the main interactions to the included anion, from weak and non-specific van der Waals forces to more specific interactions such as coordination to Lewis acid metal centers or hydrogen bonding. The importance of anion solvation phenomena to the observed anion selectivities is highlighted, and strategies for reversing the Hofmeister bias that favors large, less hydrophilic anions, and for obtaining peak selectivities based on shape recognition are delineated. Functionalization of the anion-binding sites in MOFs with strong and directional hydrogen-bonding groups that are complementary to the included anion, combined with organizational rigidity of the coordination framework, appears to be the most promising approach for achieving non-Hofmeister selectivity.

  10. Dialysis membrane for separation on microchips

    DOE Patents [OSTI]

    Singh, Anup K. (San Francisco, CA); Kirby, Brian J. (San Francisco, CA); Shepodd, Timothy J. (Livermore, CA)

    2010-07-13

    Laser-induced phase-separation polymerization of a porous acrylate polymer is used for in-situ fabrication of dialysis membranes inside glass microchannels. A shaped 355 nm laser beam is used to produce a porous polymer membrane with a thickness of about 15 .mu.m, which bonds to the glass microchannel and forms a semi-permeable membrane. Differential permeation through a membrane formed with pentaerythritol triacrylate was observed and quantified by comparing the response of the membrane to fluorescein and fluorescently tagging 200 nm latex microspheres. Differential permeation was observed and quantified by comparing the response to rhodamine 560 and lactalbumin protein in a membrane formed with SPE-methylene bisacrylamide. The porous membranes illustrate the capability for the present technique to integrate sample cleanup into chip-based analysis systems.

  11. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  12. LLRF System for the CEBAF Separator Upgrade

    SciTech Connect (OSTI)

    Plawski, Tomasz E.; Bachimanchi, Ramakrishna; Hovater, J. Curt; Seidman, David J.; Wissmann, Mark J.

    2014-12-01

    The Continuous Electron Beam Accelerator Facility (CEBAF) energy upgrade from 6 GeV to 12 GeV includes the installation of four new 748.5 MHz normal conducting deflecting cavities in the 5th pass extraction region. This system will work together with the existing 499 MHz RF Separator in order to allow simultaneous delivery of the beam to four CEBAF experimental halls. The RF system employs two digital LLRF systems controlling four cavities in a vector sum. Cavity tune information of the individual cavities is also obtained using a multiplexing scheme of the forward and reflected RF signals. In this paper we will present detailed LLRF design and the current status of the CEBAF 748.5/499 MHz beam extraction system.

  13. Marine clathrate mining and sediment separation

    DOE Patents [OSTI]

    Borns, David J. (Albuquerque, NM); Hinkebein, Thomas E. (Albuquerque, NM); Lynch, Richard W. (Albuquerque, NM); Northrop, David A. (Albuquerque, NM)

    2001-01-01

    A method and apparatus for mining of hydrocarbons from a hydrocarbon-containing clathrate such as is found on the ocean floor. The hydrocarbon containing clathrate is disaggregated from sediment by first disrupting clathrate-containing strata using continuous mining means such as a rotary tilling drum, a fluid injector, or a drill. The clathrate-rich portion of sediment thus disrupted from the sea floor strata are carried through the apparatus to regions of relative lower pressure and/or relative higher temperature where the clathrate further dissociates into component hydrocarbons and water. The hydrocarbon is recovered with the assistance of a gas that is injected and buoys the hydrocarbon containing clathrate helping it to rise to regions of lower pressure and temperature where hydrocarbon is released. The sediment separated from the hydrocarbon returns to the ocean floor.

  14. Advanced membrane separation technology for biosolvents. Final CRADA report.

    SciTech Connect (OSTI)

    Snyder, S. W.; Energy Systems

    2010-02-08

    Argonne and Vertec Biosolvents investigated the stability and perfonnance for a number of membrane systems to drive the 'direct process' for pervaporation-assisted esterification to produce lactate esters. As outlined in Figure 1, the target is to produce ammonium lactate by fennentation. After purification and concentration, ammonium lactate is reacted with ethanol to produce the ester. Esterification is a reversible reaction so to drive the reaction forward, the produced ammonia and water must be rapidly separated from the product. The project focused on selecting pervaporation membranes with (1) acid functionality to facilitate ammonia separation and (2) temperature stability to be able to perform that reaction at as high a temperature as possible (Figure 2). Several classes of commercial membrane materials and functionalized membrane materials were surveyed. The most promising materials were evaluated for scale-up to a pre-commercial application. Over 4 million metric tons per year of solvents are consumed in the U.S. for a wide variety of applications. Worldwide the usage exceeds 10 million metric tons per year. Many of these, such as the chlorinated solvents, are environmentally unfriendly; others, such as the ethylene glycol ethers and N Methyl Pyrrolidone (NMP), are toxic or teratogenic, and many other petroleum-derived solvents are coming under increasing regulatory restrictions. High performance, environmentally friendly solvents derived from renewable biological resources have the potential to replace many of the chlorinated and petrochemical derived solvents. Some of these solvents, such as ethyl lactate; d-limonene, soy methyl esters, and blends ofthese, can give excellent price/perfonnance in addition to the environmental and regulatory compliance benefits. Advancement of membrane technologies, particularly those based on pervaporation and electrodialysis, will lead to very efficient, non-waste producing, and economical manufacturing technologies for production of ethyl lactate and other esters.

  15. Alternative separation of exchange and correlation energies in range-separated density-functional perturbation theory

    E-Print Network [OSTI]

    Cornaton, Yann; Jensen, Hans Jřrgen Aa; Fromager, Emmanuel

    2013-01-01

    An alternative separation of short-range exchange and correlation energies is used in the framework of second-order range-separated density-functional perturbation theory. This alternative separation was initially proposed by Toulouse et al. [Theor. Chem. Acc. 114, 305 (2005)] and relies on a long-range interacting wavefunction instead of the non-interacting Kohn-Sham one. When second-order corrections to the density are neglected, the energy expression reduces to a range-separated double-hybrid (RSDH) type of functional, RSDHf, where "f" stands for "full-range integrals" as the regular full-range interaction appears explicitly in the energy expression when expanded in perturbation theory. In contrast to usual RSDH functionals, RSDHf describes the coupling between long- and short-range correlations as an orbital-dependent contribution. Calculations on the first four noble-gas dimers show that this coupling has a significant effect on the potential energy curves in the equilibrium region, improving the accurac...

  16. SEPARATIONS Phase Separation of Liquid Mixtures in the Presence of Surfactants

    E-Print Network [OSTI]

    Vladimirova, Natalia

    and extraction via phase transition is an interesting alternative, because it does not introduce unwanted side the native solvent. Then, the system is brought rapidly into its two-phase region, by changing either its temperature or its com- position, resulting in rapid phase separation. The macroscopic characteristics

  17. Separating Signal from Noise in Global Warming Bert W. Rust

    E-Print Network [OSTI]

    Rust, Bert W.

    Separating Signal from Noise in Global Warming Bert W. Rust Reprinted from the CD Rust, B. W. (2003) "Separating Signal from Noise in Global Warming," Computing Science and Statistics, 35, 263-277. ­ or ­ Rust, B. W. (2003) "Separating Signal from Noise in Global Warming," Computing Science and Statistics, 35

  18. Diesel: Applying Privilege Separation to Database Adrienne Porter Felt

    E-Print Network [OSTI]

    Wagner, David

    Diesel: Applying Privilege Separation to Database Access Adrienne Porter Felt Matthew Finifter Joel to lists, requires prior specific permission. #12;Diesel: Applying Privilege Separation to Database Access and code reviewers. We design and construct a system called Diesel, which implements data separation

  19. A Separate Compilation Extension to Standard ML (Revised and Expanded)

    E-Print Network [OSTI]

    A Separate Compilation Extension to Standard ML (Revised and Expanded) David Swasey Tom Murphy VII separate compilation. The system gives meaning to individual program fragments, called units. Units may (the type of a unit); if so, the units can be compiled separately. Otherwise, they must be com- piled

  20. A Separate Compilation Extension to Standard ML (Revised and Expanded)

    E-Print Network [OSTI]

    A Separate Compilation Extension to Standard ML (Revised and Expanded) David Swasey Tom Murphy VII separate compilation. The system gives meaning to individual program fragments, called units. Units may (the type of a unit); if so, the units can be compiled separately. Otherwise, they must be com­ piled

  1. Energy Efficient Hybrid Separation Processes Angelo Lucia* and Amit Amale

    E-Print Network [OSTI]

    Lucia, Angelo

    Energy Efficient Hybrid Separation Processes Angelo Lucia* and Amit Amale Department of Chemical distillation, adsorption/distillation, and others. In this work, the energy efficiency of hybrid separation the target extract compositions for the extractor and lead to the most energy efficient hybrid separations

  2. Four-port gas separation membrane module assembly

    DOE Patents [OSTI]

    Wynn, Nicholas P. (Redwood City, CA); Fulton, Donald A. (Fairfield, CA); Lokhandwala, Kaaeid A. (Fremont, CA); Kaschemekat, Jurgen (Campbell, CA)

    2010-07-20

    A gas-separation membrane assembly, and a gas-separation process using the assembly. The assembly incorporates multiple gas-separation membranes in an array within a single vessel or housing, and is equipped with two permeate ports, enabling permeate gas to be withdrawn from both ends of the membrane module permeate pipes.

  3. CHEM 8823: Special Topics -Analytical Chemistry (Analytical Separations)

    E-Print Network [OSTI]

    Sherrill, David

    of a variety of modern separation techniques such as gas chromatography (GC), liquid chromatography (LC and membrane separation, etc. Grading: 10 quizzes at the end session of each week except the first and last and isopycnic method Oct 8 ­ 12 field-flow fractionation and membrane separation Oct 15 ­ 19 Chromatography

  4. A representation theorem for stochastic processes with separable covariance functions,

    E-Print Network [OSTI]

    for such a proposal, and shows that all processes with continuous separable covariance functions are second-order identical to the product of second-order uncorrelated processes. It discusses the implications of separable relationship between separable covariance functions and a product form for the underlying process, e

  5. HORTSCIENCE 44(3):770773. 2009. Petroleum Ether Separation

    E-Print Network [OSTI]

    Etxeberria, Edgardo

    HORTSCIENCE 44(3):770­773. 2009. Petroleum Ether Separation and Seedcoat Removal Enhance Seed studied. Petroleum ether separation improved germination by dividing seeds into floaters and sinkers sinkers except for one source of C. cunninghamiana. In sorted hybrid seeds, petroleum ether separation

  6. Electrochemically-Mediated Amine Regeneration for Carbon Dioxide Separations

    E-Print Network [OSTI]

    - 1 - Electrochemically-Mediated Amine Regeneration for Carbon Dioxide Separations by Michael C Students #12;- 2 - Electrochemically-Mediated Amine Regeneration for Carbon Dioxide Separations by Michael This thesis describes a new strategy for carbon dioxide (CO2) separations based on amine sorbents, which

  7. Capillary Electrophoresis Microchips for Separation and Detection of Organophosphate

    E-Print Network [OSTI]

    Chen, Wilfred

    influencing the on-chip separation and detection processes have been optimized. Using a MES buffer (20 mM, pH 5.0) running buffer, a 72-mm-long separation channel, and a separation voltage of 2000 V, baseline. Applicability to spiked river water samples is demon- strated, and the implications for on-site environmental

  8. Industrial Membrane Filtration and Short-bed Fractal Separation Systems for Separating Monomers from Heterogeneous Plant Material

    SciTech Connect (OSTI)

    Kearney, M; Kochergin, V; Hess, R; Foust, T; Herbst, R; Mann, N

    2005-03-31

    Large-scale displacement of petroleum will come from low-cost cellulosic feedstocks such as straw and corn stover crop residues. This project has taken a step toward making this projection a reality by reducing capital and energy costs, the two largest cost factors associated with converting cellulosic biomass to chemicals and fuels. The technology exists for using acid or enzyme hydrolysis processes to convert biomass feedstock (i.e., waste cellulose such as straw, corn stover, and wood) into their base monomeric sugar building blocks, which can, in turn, be processed into chemicals and fuels using a number of innovative fermentation technologies. However, while these processes are technically possible, practical and economic barriers make these processes only marginally feasible or not feasible at all. These barriers are due in part to the complexity and large fixed and recurring capital costs of unit operations including filtration, chromatographic separation, and ion exchange. This project was designed to help remove these barriers by developing and implementing new purification and separation technologies that will reduce the capital costs of the purification and chromatographic separation units by 50% to 70%. The technologies fundamental to these improvements are: (a) highly efficient clarification and purification systems that use screening and membrane filtration to eliminate suspended solids and colloidal material from feed streams and (b) fractal technology based chromatographic separation and ion exchange systems that can substitute for conventional systems but at much smaller size and cost. A non-hazardous ''raw sugar beet juice'' stream (75 to 100 gal/min) was used for prototype testing of these technologies. This raw beet juice stream from the Amalgamated Sugar LLC plant in Twin Falls, Idaho contained abrasive materials and membrane foulants. Its characteristics were representative of an industrial-scale heterogeneous plant extract/hydrolysis stream, and therefore was an ideal model system for developing new separation equipment. Subsequent testing used both synthetic acid hydrolysate and corn stover derived weak acid hydrolysate (NREL produced). A two-phased approach was used for the research and development described in this project. The first level of study involved testing the new concepts at the bench level. The bench-scale evaluations provided fundamental understanding of the processes, building and testing small prototype systems, and determining the efficiency of the novel processes. The second level of study, macro-level, required building larger systems that directly simulated industrial operations and provided validation of performance to minimize financial risk during commercialization. The project goals and scope included: (1) Development of low-capital alternatives to conventional crop-based purification/separation processes; and (2) Development of each process to the point that transition to commercial operation is low risk. The project reporting period was January 2001 to December 2004. This included a one year extension of the project (without additional funding).

  9. Robust Polymer Composite Membranes for Hydrogen Separation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    applications, including the following: * Electricity generation via gas turbines or fuel cells * As a feedstock to produce a range of high-value liquid or gaseous fuels and...

  10. Separations Development and Application Presentation for BETO...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    enzymatic lysis, and combined techniques (e.g., alkali + HPH) Sonication, chemical treatments if high selectivity and sensitive proteins are targets Middelberg, 1995...

  11. High volume fuel vapor release valve

    SciTech Connect (OSTI)

    Gimby, D.R.

    1991-09-03

    This patent describes a fuel vapor release valve for use in a vehicle fuel system. It comprises a valve housing 10 placed in a specific longitudinal orientation, the valve housing 10 defining an interior cavity 22 having an inlet 20 for admitting fuel vapor and an outlet 14 for discharging such fuel vapor; a valve member 24 positioned in the cavity 22 for movement between an outlet 14 opening position and an outlet 14 closing position, the valve member 24 including a cap member 34 having a seat surface 36 for mating with the outlet 14 and an orifice 42 extending through the cap member 34 providing a passageway from the outlet 14 to the cavity 22, the orifice 42 extending through the cap member 34 providing a passageway from the outlet 14 to the cavity 22, the orifice 42 having a lesser radius than the outlet 14; the valve member 24 further including a plug member 30 engaged with the cap member 34 for movement between an orifice 42 opening position and an orifice 42 closing position; and, a valve housing tilt responsive means for moving the valve member 24 to an outlet 14 and orifice 42 closing position in response to tilting of the valve 10 about its longitudinal axis whereby, upon the return of the valve 10 to its specified longitudinal orientation, the plug member 30 first moves to an orifice 42 opening position and the cap member 34 subsequently moves to an outlet 14 opening position.

  12. Improved lithiumsulfur batteries with a conductive coating on the separator to prevent the

    E-Print Network [OSTI]

    Cui, Yi

    Improved lithium­sulfur batteries with a conductive coating on the separator to prevent*ac Lithium­sulfur (Li­S) batteries are highly attractive for future generations of portable electronics novel electrodes and electrolytes have been tested to improve Li­S battery performance. However

  13. Zeolite Membrane Water Vapor Separation for Building Air-Conditioning and Ventilation Systems 

    E-Print Network [OSTI]

    Tanskyi, Oleksandr

    2015-07-17

    -AR0000138 “High-efficiency, on-line membrane air dehumidifier enabling sensible cooling for warm and humid climates”. 2. Naval Facilities Engineering Command (NAVFAC), Pacific Northwest National Laboratory (PNNL), and Advanced Research Projects Agency... Outdoor air PC Polycarbonate PDMS Polydimethylsiloxane PE Polyethylene PES Polyethersulphone PNNL Pacific Northwest National Laboratory PSF Polysulfone PVDF Polyvinylidenefluoride RH Relative humidity SF Separation factor STP Standard conditions...

  14. Authors to whom correspondence should be addressed Fabrication of Metallic Electrodes with Nanometer Separation by Electromigration

    E-Print Network [OSTI]

    McEuen, Paul L.

    affected by electron-electron repulsion and energy-level quantization, and transport experiments can and nanocrystals, as demonstrated here by the transport measurements of individual cadmium selenide (Cd metallic electrodes separated by ~1 nm with high efficiency. These electrodes are ideally suited

  15. SENSING AND SEPARATING BIOMOLECULES AT BIOINTERFACES 

    E-Print Network [OSTI]

    Jung, Hyunsook

    2010-07-14

    measurements and be highly inconvenient to employ. To solve these problems, a simple and highly sensitive technique for detection of protein-ligand binding at biointerfaces has been developed. The method is based upon modulation of the interfacial pH when...

  16. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, D.S.

    1984-02-16

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  17. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, David S. (Naperville, IL); Yao, Neng-Ping (Clarendon Hills, IL)

    1985-01-01

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  18. A study on boundary separation in an idealized ocean model

    E-Print Network [OSTI]

    Düben, Peter D

    2015-01-01

    In numerical ocean models coast lines change the direction from one grid cell to its neighbor and the value for viscosity is set to be as small as possible. Therefore, model simulations are not converged with resolution and boundary separation points differ in essential properties from flow separation in continuous flow fields. In this paper, we investigate the quality of the representation of boundary separation points in global ocean models. To this end, we apply well established criteria for boundary separation within an idealized ocean model setup. We investigate an eddy-resolving as well as a steady test case with idealized and unstructured coast lines in a shallow water model that is based on a finite element discretization method. The results show that well established criteria for separation fail to detect boundary separation points due to an insufficient representation of ocean flows along free-slip boundaries. Along no-slip boundaries, most separation criteria provide adequate results. However, a ve...

  19. Development of an Algal Oil Separation Process 

    E-Print Network [OSTI]

    Samarasinghe, Nalin

    2012-10-19

    Microalgae surpass the lipid productivity of terrestrial plants by several folds. However, due to the high moisture content and rigidity of algal cell walls, extraction of lipids from algae is still a significant technological ...

  20. Conditions for uniqueness of product representations for separable quantum channels and separable quantum states

    SciTech Connect (OSTI)

    Cohen, Scott M.

    2014-06-15

    We give a sufficient condition that an operator sum representation of a separable quantum channel in terms of product operators is the unique product representation for that channel, and then provide examples of such channels for any number of parties. This result has implications for efforts to determine whether or not a given separable channel can be exactly implemented by local operations and classical communication. By the Choi-Jamiolkowski isomorphism, it also translates to a condition for the uniqueness of product state ensembles representing a given quantum state. These ideas follow from considerations concerning whether or not a subspace spanned by a given set of product operators contains at least one additional product operator.

  1. Conditions for uniqueness of product representations for separable quantum channels and separable quantum states

    E-Print Network [OSTI]

    Scott M. Cohen

    2014-05-29

    We give a sufficient condition that an operator sum representation of a separable quantum channel in terms of product operators is the unique product representation for that channel, and then provide examples of such channels for any number of parties. This result has implications for efforts to determine whether or not a given separable channel can be exactly implemented by local operations and classical communication. By the Choi-Jamiolkowski isomorphism, it also translates to a condition for the uniqueness of product state ensembles representing a given quantum state. These ideas follow from considerations concerning whether or not a subspace spanned by a given set of product operators contains at least one additional product operator.

  2. Activated Carbon Composites for Air Separation

    SciTech Connect (OSTI)

    Baker, Frederick S [ORNL; Contescu, Cristian I [ORNL; Tsouris, Costas [ORNL; Burchell, Timothy D [ORNL

    2011-09-01

    Coal-derived synthesis gas is a potential major source of hydrogen for fuel cells. Oxygen-blown coal gasification is an efficient approach to achieving the goal of producing hydrogen from coal, but a cost-effective means of enriching O2 concentration in air is required. A key objective of this project is to assess the utility of a system that exploits porous carbon materials and electrical swing adsorption to produce an O2-enriched air stream for coal gasification. As a complement to O2 and N2 adsorption measurements, CO2 was used as a more sensitive probe molecule for the characterization of molecular sieving effects. To further enhance the potential of activated carbon composite materials for air separation, work was implemented on incorporating a novel twist into the system; namely the addition of a magnetic field to influence O2 adsorption, which is accompanied by a transition between the paramagnetic and diamagnetic states. The preliminary findings in this respect are discussed.

  3. Normal butane/iso-butane separation

    SciTech Connect (OSTI)

    Volles, W.K.; Cusher, N.A.

    1986-08-26

    This patent describes an improved pressure swing adsorption process for the separation of iso-butane from normal butane in an adsorption system having at least three adsorbent beds, each bed of which undergoes, on a cyclic basis and a processing sequence comprising: introducing a feed gas mixture of iso-butane and normal butane at an upper adsorption pressure to the feed end of the bed capable of selectively adsorbing normal butane as the more selectivity adsorbable component of the gas mixture. The iso-butane as the less readily adsorbable component passes through the bed and is discharged from the discharge end. The feed gas introduction is continued as a normal butane adsorption front is formed in the bed and passes through the bed from the feed end and breaks through at the discharge end of the bed, a portion of the iso-butane effluent stream thus discharged being diverted for passage as purge gas to another bed in the system; and countercurrently depressurizing the bed with release of gas from the feed end.

  4. Method and apparatus for biological material separation

    DOE Patents [OSTI]

    Robinson, Donna L.

    2005-05-10

    There has been invented an apparatus comprising a separation barrier for excluding denser cell materials from less dense cell materials after centrifuging of the cells so that selected materials can be withdrawn from the less dense cell materials without inclusion of the denser cell materials or clogging of sampling equipment with denser cell materials. Cells from which selected material is to be withdrawn are centrifuged, either as cells or cells in media. Once the denser cell materials are isolated in a layer by centrifugal force, an invention screen or seive is submerged in the less dense cell material to a level above the layer of denser cell materials to isolate the denser cell materials from the less dense cell materials, preventing mixing of the denser cell materials back into the less dense cell materials when the cells or the cells in media are no longer being centrifuged and to prevent clogging of sampling equipment with denser cell materials. In a particularly useful application of the invention method and apparatus, plasmid DNA can be withdrawn from less dense cell materials without contamination or interference with denser cell materials.

  5. Charge separation in photoredox reactions. Final report

    SciTech Connect (OSTI)

    Kevan, L.

    1993-07-15

    The structural aspects controlling charge separation in molecular photoionization reactions in organized molecular assemblies involving micelles, reverse micelles and vesicles are being studied by optical and electron magnetic resonance techniques including the time domain technique of deuterium electron spin echo modulation (ESEM) and matrix proton electron nuclear double resonance (ENDOR) to measure weak electron-nuclear dipolar interactions. ESEM and matrix ENDOR are particularly well adapted to the study of disordered systems as exemplified by micelles and vesicles. The photoionization yields of alkylphenothiazines in micelles and vesicles have been shown to depend on the alkyl chain length and to correlate with relative distances from the surfactant assembly interface measured by deuterium ESEM and matrix proton ENDOR. The photoionization of alkylmethylviologens versus alkyl chain length has also been studied in vesicles, micelles and reverse micelles. Nitroxide spin probes have been used to study the degree of water penetration into mixed ionic/nonionic poly(ethylene oxide) and cationic/anionic micelles by using ESEM methods and selectively deuterated surfactants. The effect of urea interaction at micellar interfaces on the interface hydration has also been evaluated by studying nitroxide probes with ESEM.

  6. Actinide and lanthanide separation process (ALSEP)

    DOE Patents [OSTI]

    Guelis, Artem V.

    2013-01-15

    The process of the invention is the separation of minor actinides from lanthanides in a fluid mixture comprising, fission products, lanthanides, minor actinides, rare earth elements, nitric acid and water by addition of an organic chelating aid to the fluid; extracting the fluid with a solvent comprising a first extractant, a second extractant and an organic diluent to form an organic extractant stream and an aqueous raffinate. Scrubbing the organic stream with a dicarboxylic acid and a chelating agent to form a scrubber discharge. The scrubber discharge is stripped with a simple buffering agent and a second chelating agent in the pH range of 2.5 to 6.1 to produce actinide and lanthanide streams and spent organic diluents. The first extractant is selected from bis(2-ethylhexyl)hydrogen phosphate (HDEHP) and mono(2-ethylhexyl)2-ethylhexyl phosphonate (HEH(EHP)) and the second extractant is selected from N,N,N,N-tetra-2-ethylhexyl diglycol amide (TEHDGA) and N,N,N',N'-tetraoctyl-3-oxapentanediamide (TODGA).

  7. The Atomic Vapor Laser Isotope Separation Program

    SciTech Connect (OSTI)

    Not Available

    1992-11-09

    This report provides the finding and recommendations on the audit of the Atomic Vapor Laser Isotope Separation (AVLIS) program. The status of the program was assessed to determine whether the Department was achieving objectives stated in its January 1990 Plan for the Demonstration, Transition and Deployment of AVLIS Technology. Through Fiscal Year 1991, the Department had spent about $1.1 billion to develop AVLIS technology. The January 1990 plan provided for AVLIS to be far enough along by September to enable the Department to make a determination of the technical and economic feasibility of deployment. However, the milestones needed to support that determination were not met. An estimated $550 million would be needed to complete AVLIS engineering development and related testing prior to deployment. The earliest possible deployment date has slipped to beyond the year 2000. It is recommended that the Department reassess the requirement for AVLIS in light of program delays and changes that have taken place in the enrichment market since January 1990. Following the reassessment, a decision should be made to either fully support and promote the actions needed to complete AVLIS development or discontinue support for the program entirely. Management`s position is that the Department will successfully complete the AVLIS technology demonstration and that the program should continue until it can be transferred to a Government corporation. Although the auditors recognize that AVLIS may be transferred, there are enough technical and financial uncertainties that a thorough assessment is warranted.

  8. Extraction of protactinium-233 and separation from thermal neutron-irradiated thorium-232 using crown ethers

    SciTech Connect (OSTI)

    Jalhoom, Moayyed G.; Mohammed, Dawood A.; Khalaf, Jumah S.

    2008-07-01

    A new method was developed for the extraction and separation of {sup 233}Pa from thermal neutron-irradiated {sup 232}Th. Solutions of Pa{sup 233} were prepared in LiCI-HCl solutions from which appreciable extraction was obtained using dibenzo-18-crown-6 in 1,2-dichloroethane. The effects of cavity size, substitutions on the crown ring, type of the organic solvent, and temperature on extraction are discussed. Very high separation factors were obtained for the pairs {sup 233}Pa/{sup 232}Th (>105), {sup 233}Pa/{sup 233}U (> 1000), and {sup 232}U/{sup 232}Th (>60). (authors)

  9. Oxygen-permeable ceramic membranes for gas separation

    SciTech Connect (OSTI)

    Balachandran, U.; Ma, B.; Maiya, P.S.; Dusek, J.T.; Mieville, R.L.; Picciolo, J.J.

    1998-02-01

    Mixed-conducting oxides have a wide range of applications, including fuel cells, gas separation systems, sensors, and electrocatalytic equipment. Dense ceramic membranes made of mixed-conducting oxides are particularly attractive for gas separation and methane conversion processes. Membranes made of Sr-Fe-Co oxide, which exhibits high combined electronic and oxygen ionic conductivities, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, i.e., CO + H{sub 2}). The authors have fabricated tubular Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes and tested them (some for more than 1,000 h) in a methane conversion reactor that was operating at 850--950 C. An oxygen permeation flux of {approx} 10 scc/cm{sup 2} {center_dot} min was obtained at 900 C in a tubular membrane with a wall thickness of 0.75 mm. Using a gas-tight electrochemical cell, the authors have also measured the steady-state oxygen permeability of flat Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes as a function of temperature and oxygen partial pressure(pO{sub 2}). Steady-state oxygen permeability increases with increasing temperature and with the difference in pO{sub 2} on the two sides of the membrane. At 900 C, an oxygen permeability of {approx} 2.5 scc/cm{sup 2} {center_dot} min was obtained in a 2.9-mm-thick membrane. This value agrees with that obtained in methane conversion reactor experiments. Current-voltage (I-V) characteristics determined in the gas-tight cell indicate that bulk effect, rather than surface exchange effect, is the main limiting factor for oxygen permeation of {approx} 1-mm-thick Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes at elevated temperatures (> 650 C).

  10. Innovative lasers for uranium isotope separation. [Progress report

    SciTech Connect (OSTI)

    Brake, M.L.; Gilgenbach, R.M.

    1991-06-01

    Copper vapor lasers have important applications to uranium atomic vapor laser isotope separation (AVLIS). The authors have spent the first two years of their project investigating two innovative methods of exciting/pumping copper vapor lasers which have the potential to improve the efficiency and scaling of large laser systems used in uranium isotope separation. Experimental research has focused on the laser discharge kinetics of (1) microwave, and (2) electron beam excitation/pumping of large-volume copper vapor lasers. During the first year, the experiments have been designed and constructed and initial data has been taken. During the second year these experiments have been diagnosed. Highlights of some of the second year results as well as plans for the future include the following: Microwave resonant cavity produced copper vapor plasmas at 2.45 GHz, have been investigated. A CW (0--500 W) signal heats and vaporizes the copper chloride to provide the atomic copper vapor. A pulsed (5 kW, 0.5--5kHz) signal is added to the incoming CW signal via a hybrid mixer to excite the copper states to the laser levels. An enhancement of the visible radiation has been observed during the pulsed pardon of the signal. Electrical probe measurements have been implemented on the system to verify the results of the electromagnetic model formulated last year. Laser gain measurements have been initiated with the use of a commercial copper vapor laser. Measurements of the spatial profile of the emission are also currently being made. The authors plan to increase the amount of pulsed microwave power to the system by implementing a high power magnetron. A laser cavity will be designed and added to this system.

  11. Highly cross-linked nanoporous polymers

    DOE Patents [OSTI]

    Steckle, Jr., Warren P. (Los Alamos, NM); Apen, Paul G. (Los Alamos, NM); Mitchell, Michael A. (Los Alamos, NM)

    1998-01-01

    Condensation polymerization followed by a supercritical extraction step can be used to obtain highly cross-linked nanoporous polymers with high surface area, controlled pore sizes and rigid structural integrity. The invention polymers are useful for applications requiring separation membranes.

  12. Highly cross-linked nanoporous polymers

    DOE Patents [OSTI]

    Steckle, Jr., Warren P. (Los Alamos, NM); Apen, Paul G. (Los Alamos, NM); Mitchell, Michael A. (Los Alamos, NM)

    1997-01-01

    Condensation polymerization followed by a supercritical extraction step can be used to obtain highly cross-linked nanoporous polymers with high surface area, controlled pore sizes and rigid structural integrity. The invention polymers are useful for applications requiring separation membranes.

  13. Device for two-dimensional gas-phase separation and characterization of ion mixtures

    DOE Patents [OSTI]

    Tang, Keqi (Richland, WA); Shvartsburg, Alexandre A. (Richland, WA); Smith, Richard D. (Richland, WA)

    2006-12-12

    The present invention relates to a device for separation and characterization of gas-phase ions. The device incorporates an ion source, a field asymmetric waveform ion mobility spectrometry (FAIMS) analyzer, an ion mobility spectrometry (IMS) drift tube, and an ion detector. In one aspect of the invention, FAIMS operating voltages are electrically floated on top of the IMS drift voltage. In the other aspect, the FAIMS/IMS interface is implemented employing an electrodynamic ion funnel, including in particular an hourglass ion funnel. The present invention improves the efficiency (peak capacity) and sensitivity of gas-phase separations; the online FAIMS/IMS coupling creates a fundamentally novel two-dimensional gas-phase separation technology with high peak capacity, specificity, and exceptional throughput.

  14. Method for enhancing the resolving power of ion mobility separations over a limited mobility range

    DOE Patents [OSTI]

    Shvartsburg, Alexandre A; Tang, Keqi; Smith, Richard D

    2014-09-23

    A method for raising the resolving power, specificity, and peak capacity of conventional ion mobility spectrometry is disclosed. Ions are separated in a dynamic electric field comprising an oscillatory field wave and opposing static field, or at least two counter propagating waves with different parameters (amplitude, profile, frequency, or speed). As the functional dependencies of mean drift velocity on the ion mobility in a wave and static field or in unequal waves differ, only single species is equilibrated while others drift in either direction and are mobility-separated. An ion mobility spectrum over a limited range is then acquired by measuring ion drift times through a fixed distance inside the gas-filled enclosure. The resolving power in the vicinity of equilibrium mobility substantially exceeds that for known traveling-wave or drift-tube IMS separations, with spectra over wider ranges obtainable by stitching multiple segments. The approach also enables low-cutoff, high-cutoff, and bandpass ion mobility filters.

  15. Cell separator for use in bipolar-stack energy storage devices

    DOE Patents [OSTI]

    Mayer, S.T.; Feikert, J.H.; Kachmitter, J.L.; Pekala, R.W.

    1995-02-28

    An improved multi-cell electrochemical energy storage device is described, such as a battery, fuel cell, or double layer capacitor using a cell separator which allows cells to be stacked and interconnected with low electrical resistance and high reliability while maximizing packaging efficiency. By adding repeating cells, higher voltages can be obtained. The cell separator is formed by applying an organic adhesive on opposing surfaces of adjacent carbon electrodes or surfaces of aerogel electrodes of a pair of adjacent cells prior to or after pyrolysis thereof to form carbon aerogel electrodes. The cell separator is electronically conductive, but ionically isolating, preventing an electrolytic conduction path between adjacent cells in the stack. 2 figs.

  16. Integrated acoustic phase separator and multiphase fluid composition monitoring apparatus and method

    DOE Patents [OSTI]

    Sinha, Dipen N

    2014-02-04

    An apparatus and method for down hole gas separation from the multiphase fluid flowing in a wellbore or a pipe, for determining the quantities of the individual components of the liquid and the flow rate of the liquid, and for remixing the component parts of the fluid after which the gas volume may be measured, without affecting the flow stream, are described. Acoustic radiation force is employed to separate gas from the liquid, thereby permitting measurements to be separately made for these two components; the liquid (oil/water) composition is determined from ultrasonic resonances; and the gas volume is determined from capacitance measurements. Since the fluid flows around and through the component parts of the apparatus, there is little pressure difference, and no protection is required from high pressure differentials.

  17. Principal physical problems in laser separation of weighable amounts of a rare ytterbium isotope

    SciTech Connect (OSTI)

    Yakovlenko, Sergei I

    1998-11-30

    A review is provided of the work on laser separation of Yb isotopes, carried out at the Institute of General Physics of the Russian Academy of Sciences and at the 'Lad' Scientific - Production Enterprise during the last 4 - 5 years. The processes of Yb isotope separation by the AVLIS (atomic vapour laser isotope separation) method were investigated both theoretically (by computer simulation) and experimentally. The main topics considered in the review are the ionisation selectivity, the formation of laser beams and of vapour flow in the cavity, and the extraction of ions from a plasma. A facility for producing highly enriched {sup 168}Yb on an industrial scale is described. The rate of production of the enriched ytterbium is now 5 - 10 mg h{sup -1} (over 1 g per month). Commercially viable production of the enriched {sup 168}Yb isotope by the AVLIS method was achieved for the first time anywhere in the world. (review)

  18. Process for separating nitrogen from methane using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

    2007-07-31

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  19. Oil/gas collector/separator for underwater oil leaks

    DOE Patents [OSTI]

    Henning, Carl D. (Livermore, CA)

    1993-01-01

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  20. CO2 Separation Using Thermally Optimized Membranes: A Comprehensive Project Report (2000 - 2007)

    SciTech Connect (OSTI)

    N /A

    2008-03-04

    This is a complete (Fiscal Years 2000–2006) collection of the Idaho National Laboratory’s (INL) research and development contributions to the project, “CO2 Separation Using Thermally Optimized Membranes.” The INL scientific contribution to the project has varied due to the fluctuations in funding from year to year. The focus of the project was polybenzimidazole (PBI) membranes and developing PBI compounds (both substitution and blends) that provide good film formation and gas separation membranes. The underlying problem with PBI is its poor solubility in common solvents. Typically, PBI is dissolved in “aggressive” solvents, like N,N-dimethylacetamide (DMAc) and N methylpyrrolidone (NMP). The INL FY-03 research was directed toward making soluble N-substituted PBI polymers, where INL was very successful. Many different types of modified PBI polymers were synthesized; however, film formation proved to be a big problem with both unsubstituted and N-substituted PBIs. Therefore, INL researchers directed their attention to using plasticizers or additives to make the membranes more stable and workable. During the course of these studies, other high-performance polymers (like polyamides and polyimides) were found to be better materials, which could be used either by themselves or blends with PBI. These alternative high-performance polymers provided the best pathway forward for soluble high-temperature polymers with good stable film formation properties. At present, the VTEC polyimides (product of RBI, Inc.) are the best film formers that exhibit high-temperature resistance. INL’s gas testing results show VTEC polyimides have very good gas selectivities for both H2/CO2 and CO2/CH4. Overall, these high-performance polymers pointed towards new research areas where INL has gained a greater understanding of polymer film formation and gas separation. These studies are making possible a direct approach to stable polymer-based high-temperature gas separation membranes. This report is separated into several sections due to the complexity of the research and the variation with the development of better high-temperature, gas separation membranes. Several fiscal years are combined because the research and development efforts within those areas crossed fiscal year boundaries.

  1. CO2 Separation Using Thermally Optimized Membranes: A Comprehensive Project Report (2000 - 2007)

    SciTech Connect (OSTI)

    J.R. Klaehn; C.J. Orme; E.S. Peterson; T.A. Luther; M.G. Jones; A.K. Wertsching

    2008-03-01

    This is a complete (Fiscal Years 2000–2006) collection of the Idaho National Laboratory’s (INL) research and development contributions to the project, “CO2 Separation Using Thermally Optimized Membranes.” The INL scientific contribution to the project has varied due to the fluctuations in funding from year to year. The focus of the project was polybenzimidazole (PBI) membranes and developing PBI compounds (both substitution and blends) that provide good film formation and gas separation membranes. The underlying problem with PBI is its poor solubility in common solvents. Typically, PBI is dissolved in “aggressive” solvents, like N,N-dimethylacetamide (DMAc) and N methylpyrrolidone (NMP). The INL FY-03 research was directed toward making soluble N-substituted PBI polymers, where INL was very successful. Many different types of modified PBI polymers were synthesized; however, film formation proved to be a big problem with both unsubstituted and N-substituted PBIs. Therefore, INL researchers directed their attention to using plasticizers or additives to make the membranes more stable and workable. During the course of these studies, other high-performance polymers (like polyamides and polyimides) were found to be better materials, which could be used either by themselves or blends with PBI. These alternative high-performance polymers provided the best pathway forward for soluble high-temperature polymers with good stable film formation properties. At present, the VTEC polyimides (product of RBI, Inc.) are the best film formers that exhibit high-temperature resistance. INL’s gas testing results show VTEC polyimides have very good gas selectivities for both H2/CO2 and CO2/CH4. Overall, these high-performance polymers pointed towards new research areas where INL has gained a greater understanding of polymer film formation and gas separation. These studies are making possible a direct approach to stable polymer-based high-temperature gas separation membranes. This report is separated into several sections due to the complexity of the research and the variation with the development of better high-temperature, gas separation membranes. Several fiscal years are combined because the research and development efforts within those areas crossed fiscal year boundaries.

  2. Frontiers in thermoacoustic refrigeration and mixture separation

    E-Print Network [OSTI]

    conversion, which harnesses the oscillations of temperature, heat flux, pressure, and motion in intense sound-transfer and acoustic components and filled with a gas-- typically high-pressure helium. Refrigeration is produced because gas that oscillates through the cold heat exchanger is depressurized adiabatically on the pulse

  3. Gas storage and separation by electric field swing adsorption

    DOE Patents [OSTI]

    Currier, Robert P; Obrey, Stephen J; Devlin, David J; Sansinena, Jose Maria

    2013-05-28

    Gases are stored, separated, and/or concentrated. An electric field is applied across a porous dielectric adsorbent material. A gas component from a gas mixture may be selectively separated inside the energized dielectric. Gas is stored in the energized dielectric for as long as the dielectric is energized. The energized dielectric selectively separates, or concentrates, a gas component of the gas mixture. When the potential is removed, gas from inside the dielectric is released.

  4. Interpolatability distinguishes LOCC from separable von Neumann measurements

    SciTech Connect (OSTI)

    Childs, Andrew M.; Leung, Debbie; Man?inska, Laura; Institute for Quantum Computing, University of Waterloo, Waterloo, Ontario N2L 3G1 ; Ozols, Maris; Institute for Quantum Computing, University of Waterloo, Waterloo, Ontario N2L 3G1; IBM TJ Watson Research Center, Yorktown Heights, New York 10598

    2013-11-15

    Local operations with classical communication (LOCC) and separable operations are two classes of quantum operations that play key roles in the study of quantum entanglement. Separable operations are strictly more powerful than LOCC, but no simple explanation of this phenomenon is known. We show that, in the case of von Neumann measurements, the ability to interpolate measurements is an operational principle that sets apart LOCC and separable operations.

  5. Method for preparing membranes with adjustable separation performance

    DOE Patents [OSTI]

    Peterson, E.S.; Orme, C.J.; Stone, M.L.

    1995-01-31

    Methods for adjustable separation of solutes and solvents involve the combination of the use of a maximally swollen membrane and subsequent vacuum depressurization exerted on the permeate side of that membrane. By adjusting the extent of depressurization it is possible to separate solvent from solutes and solutes from each other. Improved control of separation parameters as well as improved flux rates characterize the present invention. 2 figs.

  6. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid (Menlo Park, CA)

    1997-01-01

    A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

  7. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, K.

    1997-07-15

    A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

  8. Method for preparing membranes with adjustable separation performance

    DOE Patents [OSTI]

    Peterson, Eric S. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Stone, Mark L. (Idaho Falls, ID)

    1995-01-01

    Methods for adjustable separation of solutes and solvents involve the combination of the use of a maximally swollen membrane and subsequent vacuum depressurization exerted on the permeate side of that membrane. By adjusting the extent of depressurization it is possible to separate solvent from solutes and solutes from each other. Improved control of separation parameters as well as improved flux rates characterize the present invention.

  9. The plasma centrifuge: A compact, low cost, stable isotope separator. Phase 2 final technical report, September 15, 1991--September 14, 1995

    SciTech Connect (OSTI)

    Guss, W.

    1996-09-05

    Enriched stable isotopes are required for production of radionuclides as well as for research and diagnostic uses. Science Research Laboratory (SRL) has developed a plasma centrifuge for moderate throughput of enriched stable isotopes, such as {sup 13}C, {sup 17}O, {sup 18}O, and {sup 203}Tl, for medical as well as other applications. Dwindling isotope stocks have restricted the use of enriched isotopes and their associated labeled organic molecules in medical imaging to very few research facilities because of high costs of isotope separation. With the introduction of the plasma centrifuge separator, the cost per separated gram of even rarely occurring isotopes ({le} 1% natural abundance) is potentially many times lower than with other separation technologies (cryogenic distillation and calutrons). The centrifuge is a simple, robust, pulsed electrical discharge device that has successfully demonstrated isotope separation of small (mg) quantities of {sup 26}Mg. Based on the results of the Phase 2 program, modest enhancements to the power supplies and cooling systems, a centrifuge separator will have high repetition rate (60 pps) and high duty cycle (60%) to produce in one month kilogram quantities of highly enriched stable isotopes. The centrifuge may be used in stand-alone operation or could be used as a high-throughput pre-separation stage with calutrons providing the final separation.

  10. Process for the recovery and separation of plastics

    DOE Patents [OSTI]

    Jody, Bassam J.; Daniels, Edward J.; Pomykala Jr., Joseph A.

    2003-07-29

    A method of separating a portion of acrylonitrile-butadiene-styrene (ABS) from a mixture containing ABS and for separating a portion of ABS and polycarbonate (PC) from a mixture of plastics containing ABS and PC is disclosed. The method includes shredding and/or granulating the mixture of plastics containing ABS and PC to provide a selected particle size; sequentially dispersing the shredded mixture of plastics in a series aqueous solutions having different specific gravities and separating the floating fraction until the desired separation is obtained. Surface tension and pH are also variable to be controlled.

  11. Oil/gas separator for installation at burning wells

    DOE Patents [OSTI]

    Alonso, Carol T. (Orinda, CA); Bender, Donald A. (Dublin, CA); Bowman, Barry R. (Livermore, CA); Burnham, Alan K. (Livermore, CA); Chesnut, Dwayne A. (Pleasanton, CA); Comfort, III, William J. (Livermore, CA); Guymon, Lloyd G. (Livermore, CA); Henning, Carl D. (Livermore, CA); Pedersen, Knud B. (Livermore, CA); Sefcik, Joseph A. (Tracy, CA); Smith, Joseph A. (Livermore, CA); Strauch, Mark S. (Livermore, CA)

    1993-01-01

    An oil/gas separator is disclosed that can be utilized to return the burning wells in Kuwait to production. Advantageously, a crane is used to install the separator at a safe distance from the well. The gas from the well is burned off at the site, and the oil is immediately pumped into Kuwait's oil gathering system. Diverters inside the separator prevent the oil jet coming out of the well from reaching the top vents where the gas is burned. The oil falls back down, and is pumped from an annular oil catcher at the bottom of the separator, or from the concrete cellar surrounding the well.

  12. Duct System Flammability and Air Sealing Fire Separation Assemblies...

    Office of Scientific and Technical Information (OSTI)

    Fire Separation Assemblies in the International Residential Code Rudd, A.; Prahl, D. 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; RESIDENTIAL BUILDINGS; AIRTIGHTNESS;...

  13. Novel Application of Air Separation Membranes Reduces NOx Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emissions Technology available for licensing: Selective permeation of gases using an air separation membrane. Can be retrofitted to existing engines Significantly reduces NOx...

  14. Process for separating nitrogen from methane using microchannel...

    Office of Scientific and Technical Information (OSTI)

    from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources. Authors: Tonkovich, Anna Lee 1 ;...

  15. Enhanced separation efficiency of photoinduced charges for antimony...

    Office of Scientific and Technical Information (OSTI)

    Enhanced separation efficiency of photoinduced charges for antimony-doped tin oxide (Sb-SnOsub 2)TiOsub 2 heterojunction semiconductors with varied Sb doping concentration...

  16. Oil/gas separator for installation at burning wells

    DOE Patents [OSTI]

    Alonso, C.T.; Bender, D.A.; Bowman, B.R.; Burnham, A.K.; Chesnut, D.A.; Comfort, W.J. III; Guymon, L.G.; Henning, C.D.; Pedersen, K.B.; Sefcik, J.A.; Smith, J.A.; Strauch, M.S.

    1993-03-09

    An oil/gas separator is disclosed that can be utilized to return the burning wells in Kuwait to production. Advantageously, a crane is used to install the separator at a safe distance from the well. The gas from the well is burned off at the site, and the oil is immediately pumped into Kuwait's oil gathering system. Diverters inside the separator prevent the oil jet coming out of the well from reaching the top vents where the gas is burned. The oil falls back down, and is pumped from an annular oil catcher at the bottom of the separator, or from the concrete cellar surrounding the well.

  17. Fuel cell system with separating structure bonded to electrolyte

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY); Quek, Shu Ching (Clifton Park, NY); Hasz, Wayne Charles (Pownal, VT); Powers, James Daniel (Santa Monica, CA)

    2010-09-28

    A fuel cell assembly comprises a separating structure configured for separating a first reactant and a second reactant wherein the separating structure has an opening therein. The fuel cell assembly further comprises a fuel cell comprising a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes, and a passage configured to introduce the second reactant to the second electrode. The electrolyte is bonded to the separating structure with the first electrode being situated within the opening, and the second electrode being situated within the passage.

  18. Supported Molten Metal Membranes for Hydrogen Separation

    SciTech Connect (OSTI)

    Datta, Ravindra; Ma, Yi Hua; Yen, Pei-Shan; Deveau, Nicholas; Fishtik, Ilie; Mardilovich, Ivan

    2013-09-30

    We describe here our results on the feasibility of a novel dense metal membrane for hydrogen separation: Supported Molten Metal Membrane, or SMMM.1 The goal in this work was to develop these new membranes based on supporting thin films of low-melting, non- precious group metals, e.g., tin (Sn), indium (In), gallium (Ga), or their alloys, to provide a flux and selectivity of hydrogen that rivals the conventional but substantially more expensive palladium (Pd) or Pd alloy membranes, which are susceptible to poisoning by the many species in the coal-derived syngas, and further possess inadequate stability and limited operating temperature range. The novelty of the technology presented numerous challenges during the course of this project, however, mainly in the selection of appropriate supports, and in the fabrication of a stable membrane. While the wetting instability of the SMMM remains an issue, we did develop an adequate understanding of the interaction between molten metal films with porous supports that we were able to find appropriate supports. Thus, our preliminary results indicate that the Ga/SiC SMMM at 550 şC has a permeance that is an order of magnitude higher than that of Pd, and exceeds the 2015 DOE target. To make practical SMM membranes, however, further improving the stability of the molten metal membrane is the next goal. For this, it is important to better understand the change in molten metal surface tension and contact angle as a function of temperature and gas-phase composition. A thermodynamic theory was, thus, developed, that is not only able to explain this change in the liquid-gas surface tension, but also the change in the solid-liquid surface tension as well as the contact angle. This fundamental understanding has allowed us to determine design characteristics to maintain stability in the face of changing gas composition. These designs are being developed. For further progress, it is also important to understand the nature of solution and permeation process in these molten metal membranes. For this, a comprehensive microkinetic model was developed for hydrogen permeation in dense metal membranes, and tested against data for Pd membrane over a broad range of temperatures.3 It is planned to obtain theoretical and experimental estimates of the parameters to corroborate the model against mental results for SMMM.

  19. Practical Timing Analysis of Asynchronous Systems Using Time Separation of Events \\Lambda

    E-Print Network [OSTI]

    Chakraborty, Supratik

    separations between appropriate events. Separations between all rele­ vant pairs of events are computed between appropriate events in the timing constraint graph. Separations between all rele­ vant pairs

  20. No. 2 Distillate Prices - Through Retail Outlets

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6Year JanperGas1.8782.38653