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Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Volatile Organic CompoundsEmissions from Biomass Combustion  

Science Journals Connector (OSTI)

The emissions of Volatile Organic Compounds (VOC) from biomass combustion have been investigated. VOC contribute both to ... 0.5–10 MW. A variety of biomass fuel types and combustion equipment was covered. The su...

Lennart Gustavsson; Mats-Lennart Karlsson

1993-01-01T23:59:59.000Z

2

Opportunities for reducing volatile organic compound emissions in manufacturing office furniture partitions: a feasibility analysis  

Science Journals Connector (OSTI)

A feasibility analysis is reported of reduction opportunities for volatile organic compound (VOC) emissions in manufacturing office furniture partitions. The pollution prevention (P2) methodology as defined by the Ontario Ministry of the Environment ... Keywords: emissions, manufacturing, office furniture, pollution prevention, volatile organic compound

Frank S. Luisser; Marc A. Rosen

2009-02-01T23:59:59.000Z

3

A Tree's Response to Herbivory: Quantification of Biogenic Volatile Organic Compound Emissions  

E-Print Network (OSTI)

A Tree's Response to Herbivory: Quantification of Biogenic Volatile Organic Compound Emissions an abundant source of Secondary Organic Aerosols (SOA). These emissions are known to vary in quantity and composition due to both biogenic and anthropogenic stressors. In this study, BVOC emissions from bristlecone

Collins, Gary S.

4

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 2. Incorporation of Chlorine Emissions  

Science Journals Connector (OSTI)

As part of the State Implementation Plan for attaining the National Ambient Air Quality Standard for ozone, the Texas Commission of Environmental Quality has created a Highly Reactive Volatile Organic Compounds (HRVOC) Emissions Cap and Trade Program for ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; David T. Allen

2007-02-27T23:59:59.000Z

5

Emissions of non-methane organic compounds from a grassland site  

SciTech Connect

A mixture of oxygenated hydrocarbons (OxHCs), isoprene, and monoterpenes was detected in the emissions from a grassland site in the Midwestern United States. A plot dominated by crown vetch (Coronilla varia) and bluegrass (Poa spp.), exhibited a constant decrease in emissions of total non-methane organic compounds (NMOCs) from 580 {mu}g m{sup -2} hr{sup -1} in June 1992 to 150 {mu}g m{sup - 2} hr{sup -1} in October 1992, except for a slight increase in August. Oxygenated hydrocarbons (methanol, acetaldehyde, and acetone) and terpenes (isoprene, limonene, myrcene, {alpha}-pinene, and {beta}- pinene) composed about 90% and 10% of the identified NMOC emissions, respectively. Isoprene represented about 10% of the terpene emissions. Total NMOC emission rates based on vegetative biomass averaged 2.3 {mu}g g{sup -1} hr{sup -1}, with 10% of the identified NMOCs attributed to monoterpenes and the remainder mainly OxHCs. Over the course of the investigation, the relationship between the monoterpene emission rate and the temperature for a single plot was logarithmic and similar to the one between compound vapor pressure and temperature. However, emission rates normalized to temperature decreased throughout the summer and fall, indicating that parameterizations of emission rates from herbaceous plants must include a factor to compensate for environmental conditions such as soil moisture and nutrient deposition, which affect plant phenology and the seasonal pattern of species dominance.

Fukui, Yoshiko; Doskey, P.V.

1996-03-01T23:59:59.000Z

6

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network (OSTI)

Chemistry and Physics Vehicular emission of volatile organicY. , and Huang, Y. S. : Emission factors and characteristicslight-duty vehicle emissions, Environ. Sci. Technol. , 30,

2009-01-01T23:59:59.000Z

7

Online measurements of the emissions of intermediate-volatility and semi-volatile organic compounds from aircraft  

E-Print Network (OSTI)

A detailed understanding of the climate and air quality impacts of aviation requires measurements of the emissions of intermediate-volatility and semi-volatile organic compounds (I/SVOCs) from aircraft. Currently both the ...

Herndon, S. C.

8

Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units  

SciTech Connect

Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors wereevaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature andrelative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using theheating, ventilation and air conditioning (HVAC) systems. Indoor temperatures during sampling ranged from 14o C to 33o C, and relative humidity (RH) varied between 35percentand 74percent. Ventilation rates were increased in some trailers using bathroom fans and vents during some of the sampling events. Ventilation rates measured during some aselection of sampling events varied from 0.14 to 4.3 h-1. Steady state indoor formaldehyde concentrations ranged from 10 mu g-m-3 to 1000 mu g-m-3. The formaldehyde concentrations in the trailers were of toxicological significance. The effects of temperature, humidity and ventilation rates were also studied. A linearregression model was built using log of percentage relative humidity, inverse of temperature (in K-1), and inverse log ACH as continuous independent variables, trailermanufacturer as a categorical independent variable, and log of the chemical emission factors as the dependent variable. The coefficients of inverse temperature, log relativehumidity, log inverse ACH with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. The regression model wasfound to explain about 84percent of the variation in the dependent variable. Most VOC concentrations measured indoors in the Purvis THUs were mostly found to be belowvalues reported in earlier studies by Maddalena et al.,1,2 Hodgson et al.,3 and Hippelein4. Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3. Emissions of phenol were also found to be slightly higher than values reported in earlier studies1,2,3. This study can assist in retrospective formaldehyde exposure assessments of THUs where estimates of the occupants indoor formaldehyde exposures are needed.

Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

2010-10-01T23:59:59.000Z

9

Cold Temperature and Biodiesel Fuel Effects on Speciated Emissions of Volatile Organic Compounds from Diesel Trucks  

Science Journals Connector (OSTI)

Emissions testing was conducted on a chassis dynamometer at two ambient temperatures (?7 and 22 °C) operating on two fuels (ultra low sulfur diesel and 20% soy biodiesel blend) over three driving cycles: cold start, warm start and heavy-duty urban dynamometer driving cycle. ... Different 2007+ aftertreatment technologies involving catalyst regeneration led to significant modifications of VOC emissions that were compound-specific and highly dependent on test conditions. ... However, emissions of other toxic partial combustion products such as carbonyls were not reduced in the modern diesel vehicles tested. ...

Ingrid J. George; Michael D. Hays; Richard Snow; James Faircloth; Barbara J. George; Thomas Long; Richard W. Baldauf

2014-11-13T23:59:59.000Z

10

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. 1. Reactivity Based Trading and Potential for Ozone Hot Spot Formation  

Science Journals Connector (OSTI)

Photochemical Modeling of Emissions Trading of Highly Reactive Volatile Organic Compounds in Houston, Texas. ... (12)?Thompson, T. M.; Wang, L.; Web, A.; McDonald-Buller, E.; Allen, D. T. Photochemical Modeling of the Air Quality Impacts of an Emissions Trading Program for Highly Reactive Volatile Organic Compounds (HRVOCs) in Texas; Air and Waste Management Association Annual Meeting, New Orleans, June, 2006. ...

Linlin Wang; Tammy Thompson; Elena C. McDonald-Buller; Alba Webb; David T. Allen

2007-02-27T23:59:59.000Z

11

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

12

Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results  

SciTech Connect

This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

1990-08-01T23:59:59.000Z

13

Impacts of nitrogen fertilization on volatile organic compound emissions from decomposing plant litter  

E-Print Network (OSTI)

decomposing litter from 12 plant species over 125 days, measuring both CO2 and VOC emissions throughout with C emissions as VOCs ranging from 0% to 88% of C emissions as CO2. Methanol was the dominant VOC was occasionally large enough to account for the increased CO2 emissions on a per unit C basis, suggesting that N

Fierer, Noah

14

Vehicular emission of volatile organic compounds (VOCs) from a tunnel study in Hong Kong  

E-Print Network (OSTI)

ethene toluene n-butane propane i-pentane i-butane propeneethene, toluene, n-butane, propane and i-pentane. These fiveVOCs emitted. The high propane and n-butane emissions were

2009-01-01T23:59:59.000Z

15

Southern California Edison's (SCE) Research Program for Industrial Volatile Organic Compound (VOC) Emissions Control  

E-Print Network (OSTI)

. Applied Utility Systems Rosemead, California Tarrytown, New York Santa Ana, California ABSTRACT SCE has developed and implemented a research program for customer retention through VOC emission control. Following characterization of problematic..., California RON CASCONE Senior Consultant Chem Systems, Inc. Tarrytown, New York JIM REESE Applied Utility Santa Ana, California ABSTRACT SCE has developed and implemented a research program for customer retention through VOC emission control. Following...

Sung, R. D.; Cascone, R.; Reese, J.

16

Temperature dependence of volatile organic compound evaporative emissions from motor vehicles  

E-Print Network (OSTI)

gasoline samples collected at Sacramento area service stations. Vapor-liquid equilibrium relationships were summer 2001. Additional gasoline- related VOC emissions not shown in Figure 1 occur at service stations gasoline permeation through rubber and plastic components of the fuel system. [3] EMFAC [California Air

Silver, Whendee

17

Cancer risks from soil emissions of volatile organic compounds at the Lawrence Livermore National Laboratory  

SciTech Connect

The emission isolation flux chamber (EIFC) methodology was applied to Superfund investigations at the Lawrence Livermore National Laboratory Site 300 to determine if on-site workers were exposed to VOCs volatilizing from the subsurface and what, if any, health risks could be attributed to the inhalation of the VOCs volatilizing from the subsurface. During July and August of 1996, twenty, eighteen, and twenty six VOC soil vapor flux samples were collected in the Building 830, 832, and 854 areas, respectively using EIFCS. The VOC concentrations in the vapor samples were used to calculate soil flux rates which were used as input into an air dispersion model to calculate ambient air exposure-point concentrations. The exposure-point concentrations were compared to EPA Region IX Preliminary Remediation Goals (PRGs). Buildings 830 and 832 exposure-point concentrations were less then the PRGs therefore no cancer risks were calculated. The cancer risks for Building 854 ranged from 1.6 x 10{sup -7} to 2.1 x 10{sup -6}. The resultant inhalation cancer risks were all within the acceptable range, implying that on-site workers were not exposed to VOC vapors volatilizing from the subsurface soil that could have significant cancer risks. Therefore remediation in these areas would not be necessary.

Dibley, V. R., LLNL

1998-02-01T23:59:59.000Z

18

Exhaust emissions of volatile organic compounds of powered two-wheelers: Effect of cold start and vehicle speed. Contribution to greenhouse effect and tropospheric ozone formation  

Science Journals Connector (OSTI)

Abstract Powered two-wheeler (PTW) vehicles complying with recent European type approval standards (stages Euro 2 and Euro 3) were tested on chassis dynamometer in order to measure exhaust emissions of about 25 volatile organic compounds (VOCs) in the range C1–C7, including carcinogenic compounds as benzene and 1,3-butadiene. The fleet consists of a moped (engine capacity ? 50 cm3) and three fuel injection motorcycles of different engine capacities (150, 300 and 400 cm3). Different driving conditions were tested (US FPT cycle, constant speed). Due to the poor control of the combustion and catalyst efficiency, moped is the highest pollutant emitter. In fact, fuel injection strategy and three way catalyst with lambda sensor are able to reduce VOC motorcycles' emission of about one order of magnitude with respect to moped. Cold start effect, that is crucial for the assessment of actual emission of \\{PTWs\\} in urban areas, was significant: 30–51% of extra emission for methane. In the investigated speed range, moped showed a significant maximum of VOC emission factor at minimum speed (10 km/h) and a slightly decreasing trend from 20 to 60 km/h; motorcycles showed on the average a less significant peak at 10 km/h, a minimum at 30–40 km/h and then an increasing trend with a maximum emission factor at 90 km/h. Carcinogenic \\{VOCs\\} show the same pattern of total VOCs. Ozone Formation Potential (OFP) was estimated by using Maximum Incremental Reactivity scale. The greatest contribution to tropospheric ozone formation comes from alkenes group which account for 50–80% to the total OFP. VOC contribution effect on greenhouse effect is negligible with respect to CO2 emitted.

M. Antonietta Costagliola; Fabio Murena; M. Vittoria Prati

2014-01-01T23:59:59.000Z

19

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: Measurement comparison, emission ratios, and source attribution  

SciTech Connect

Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of {approx}2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.

Bon, D.M.; Springston, S.; M.Ulbrich, I.; de Gouw, J. A.; Warneke, C.; Kuster, W. C.; Alexander, M. L.; Baker, A.; Beyersdorf, A. J.; Blake, D.; Fall, R.; Jimenez, J. L., Herndon, S. C.; Huey, L. G.; Knighton, W. B.; Ortega, J.; Vargas, O.

2011-03-16T23:59:59.000Z

20

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

1995-08-29T23:59:59.000Z

22

Field Derived Emission Factors For Formaldehyde and other Volatile Organic  

NLE Websites -- All DOE Office Websites (Extended Search)

Field Derived Emission Factors For Formaldehyde and other Volatile Organic Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units Title Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units Publication Type Report LBNL Report Number LBNL-4083E Year of Publication 2010 Authors Parthasarathy, Srinandini, Randy L. Maddalena, Marion L. Russell, and Michael G. Apte Publisher Lawrence Berkeley National Laboratory City Berkeley Abstract Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors were evaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature and relative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using the

23

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

24

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

25

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

26

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

27

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

28

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

29

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

30

Chlorinated organic compounds in urban river sediments  

SciTech Connect

Among anthropogenic chemicals, many chlorinated organic compounds have been used as insecticides and detected frequently as contaminants in urban river sediments so far. However, the number and total amount of chemicals produced commercially and used are increasing year by year, though each amount of chemicals is not so high. New types of contaminants in the environment may be detected by the use of newly developed chemicals. Chlorinated organic compounds in the urban river sediments around Tokyo and Kyoto, large cities in Japan, were surveyed and recent trends of contaminants were studied. Contaminants of the river sediments in industrial areas had a variety, but PCB (polychlorinated biphenyls) was detected in common in industrial areas. Concentration of PCB related well to the number of factories on both sides of rivers, although the use of PCB was stopped 20 years ago. In domestic areas, Triclosan (5-chloro-2-(2,4-dichlorophenoxy)-phenol) and Triclocarban (3,4,4{prime}-trichlorocarbanilide)(both are contained in soap or shampoo for fungicides), p-dichlorobenzene (insecticides for wears) and TCEP(tris-chloroethyl phosphate) were detected. EOX(extracted organic halogen) in the sediments was 5 to 10 times of chlorinated organic compounds detected by GC/MS. Major part of organic halogen was suggested to be included in chlorinated organics formed by bleaching or sterilization.

Soma, Y.; Shiraishi, H.; Inaba, K. [National Inst. of Environmental Studies, Tsukuba, Ibaraki (Japan)

1995-12-31T23:59:59.000Z

31

Effect of Outside Air Ventilation Rate on Volatile Organic Compound  

NLE Websites -- All DOE Office Websites (Extended Search)

Outside Air Ventilation Rate on Volatile Organic Compound Outside Air Ventilation Rate on Volatile Organic Compound Concentrations in a Call Center Title Effect of Outside Air Ventilation Rate on Volatile Organic Compound Concentrations in a Call Center Publication Type Journal Article Year of Publication 2003 Authors Hodgson, Alfred T., David Faulkner, Douglas P. Sullivan, Dennis L. DiBartolomeo, Marion L. Russell, and William J. Fisk Journal Atmospheric Environment Volume 37 Start Page Chapter Pagination 5517-5528 Abstract A study of the relationship between outside air ventilation rate and concentrations of volatile organic compounds (VOCs) generated indoors was conducted in a call center office building. The building, with two floors and a floor area of 4,600 m2, was located in the San Francisco Bay Area, CA. Ventilation rates were manipulated with the building's four air handling units (AHUs). VOC concentrations in the AHU returns were measured on seven days during a 13-week period. VOC emission factors were determined for individual zones on days when they were operating at near steady-state conditions. The emission factor data were subjected to principal component (PC) analysis to identify groups of co-varying compounds. Potential sources of the PC vectors were ascribed based on information from the literature supporting the associations. Two vectors with high loadings of compounds including formaldehyde, 2,2,4-trimethyl-1,3- pentanediol monoisobutyrate, decamethylcyclopentasiloxane (d5 siloxane), and isoprene likely identified occupant-related sources. One vector likely represented emissions from building materials. Another vector represented emissions of solvents from cleaning products. The relationships between indoor minus outdoor VOC concentrations and ventilation rate were qualitatively examined for eight VOCs. Of these, acetaldehyde and hexanal, which were likely associated with material sources, and d5 siloxane exhibited general trends of higher concentrations at lower ventilation rates. For other compounds, the operation of the building and variations in pollutant generation and removal rates apparently combined to obscure the inverse relationship between VOC concentrations and ventilation. This result emphasizes the importance of utilizing source control measures, in addition to adequate ventilation, to limit concentrations of VOCs of concern in office buildings

32

Organic photosensitive devices using subphthalocyanine compounds  

DOE Patents (OSTI)

An organic photosensitive optoelectronic device, having a donor-acceptor heterojunction of a donor-like material and an acceptor-like material and methods of making such devices is provided. At least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound; and/or the device optionally has at least one of a blocking layer or a charge transport layer, where the blocking layer and/or the charge transport layer includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound.

Rand, Barry (Princeton, NJ); Forrest, Stephen R. (Ann Arbor, MI); Mutolo, Kristin L. (Hollywood, CA); Mayo, Elizabeth (Alhambra, CA); Thompson, Mark E. (Anaheim Hills, CA)

2011-07-05T23:59:59.000Z

33

Abatement of Air Pollution: Control of Sulfur Compound Emissions  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Abatement of Air Pollution: Control of Sulfur Compound Emissions Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These regulations set limits on the sulfur content of allowable fuels (1.0%

34

Hydrogen-Evolving Organic Compounds - Energy Innovation Portal  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Storage Energy Storage Find More Like This Return to Search Hydrogen-Evolving Organic Compounds Los Alamos National Laboratory Contact LANL About This Technology Technology...

35

Modeling Semivolatile Organic Aerosol Mass Emissions from  

E-Print Network (OSTI)

in diluted diesel and wood combustion exhaust are interpreted using a two-component absorptive with dilution of both wood smoke and diesel exhaust can be described by two lumped compounds in roughly equal. Introduction Sources of organic aerosol such as diesel engines and wood stoves emit semivolatile organic

Stanier, Charlie

36

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect

Western Research Institute (WRI) initiated exploratory work towards the development of new field screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of carbon-halogen bonds. Commercially available heated diode and corona discharge leak detectors were procured and evaluated for halogenated VOC response. The units were modified to provide a digital readout of signal related to VOC concentration. Sensor response was evaluated with carbon tetrachloride and tetrachloroethylene (perchloroethylene, PCE), which represent halogenated VOCs with and without double bonds. The response characteristics were determined for the VOCs directly in headspace in Tedlar bag containers. Quantitation limits in air were estimated. Potential interferences from volatile hydrocarbons, such as toluene and heptane, were evaluated. The effect of humidity was studied also. The performance of the new devices was evaluated in the laboratory by spiking soil samples and monitoring headspace for halogenated VOCs. A draft concept of the steps for a new analytical method was outlined. The results of the first year effort show that both devices show potential utility for future analytical method development work towards the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani Jr.; Theresa M. Bomstad

2002-06-01T23:59:59.000Z

37

Presence and Distribution of Organic Wastewater Compounds in Wastewater,  

E-Print Network (OSTI)

Presence and Distribution of Organic Wastewater Compounds in Wastewater, Surface, Ground.W., Meyer, M.T., and Zaugg, S.D., 2004, Presence and distri- bution of organic wastewater compounds in wastewater, surface, ground, and drinking waters, Minnesota, 2000-02: U.S. Geological Survey Scientific

38

Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles  

SciTech Connect

This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

Mohan, S.; Nagarkatti, M. [Trinity Consultants, Inc., Baton Rouge, LA (United States)

1996-12-31T23:59:59.000Z

39

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect

Western Research Institute (WRI) is continuing work toward the development of new screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of halogens. In prior work, the devices were tested for response to carbon tetrachloride, heptane, toluene, and water vapors. In the current work, sensor response was evaluated with sixteen halogenated VOCs relative to carbon tetrachloride. The results show that the response of the various chlorinated VOCs is within an order of magnitude of the response to carbon tetrachloride for each of the sensors. Thus, for field screening a single response factor can be used. Both types of leak detectors are being further modified to provide an on-board LCD signal readout, which is related to VOC concentration. The units will be fully portable and will operate with 115-V line or battery power. Signal background, noise level, and response data on the Bacharach heated diode detector and the TIF corona discharge detector show that when the response curves are plotted against the log of concentration, the plot is linear to the upper limit for the particular unit, with some curvature at lower levels. When response is plotted directly against concentration, the response is linear at the low end and is curved at the high end. The dynamic ranges for carbon tetrachloride of the two devices from the lower detection limit (S/N=2) to signal saturation are 4-850 vapor parts per million (vppm) for the corona discharge unit and 0.01-70 vppm for the heated diode unit. Additional circuit modifications are being made to lower the detection limit and increase the dynamic response range of the corona discharge unit. The results indicate that both devices show potential utility for future analytical method development work toward the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani, Jr.; Theresa M. Bomstad

2003-07-01T23:59:59.000Z

40

Sorption to soil of hydrophobic and ionic organic compounds: measurement and modeling.  

E-Print Network (OSTI)

??The sorption of organic compounds to soil, sediments and dissolved organic matter affects the fate of organic compounds. Given the central role of this process… (more)

Laak, Thomas Laurens ter

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Intake of Toxic and Carcinogenic Volatile Organic Compounds from Secondhand Smoke in Motor Vehicles  

Science Journals Connector (OSTI)

...BR.Measurement of emissions from air pollution sources. 5. C1-C32 organic compounds...Ott W , Klepeis N, Switzer P.Air change rates of motor vehicles and...experimental investigation of tobacco smoke pollution in cars.Nicotine Tob Res 2009...

Gideon St.Helen; Peyton Jacob III; Margaret Peng; Delia A. Dempsey; S. Katharine Hammond; and Neal L. Benowitz

2014-12-01T23:59:59.000Z

42

In situ measurements of gas/particle-phase transitions for atmospheric semivolatile organic compounds  

Science Journals Connector (OSTI)

...abundance, as compared to an ambient run (i.e., gas-phase and particle-phase...carbon number. Because n-alkanes are straight chained, and have very low polarity, they do not enter the particle...Diurnal and seasonal variability of gasoline-related volatile organic compound emissions...

Brent J. Williams; Allen H. Goldstein; Nathan M. Kreisberg; Susanne V. Hering

2010-01-01T23:59:59.000Z

43

Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA  

NLE Websites -- All DOE Office Websites (Extended Search)

Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA Temporary Housing Units Title Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA Temporary Housing Units Publication Type Journal Article Year of Publication 2009 Authors Maddalena, Randy L., Marion L. Russell, Douglas P. Sullivan, and Michael G. Apte Journal Environmental Science and Technology Volume 43 Start Page Chapter Pagination 5626-5632 Publisher Lawrence Berkeley National Laboratory Abstract Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THUVOC and aldehyde emission factors (µg h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehydeconcentrations ranged from 378 µg m-3 (0.31ppm) to 632 µg m-3 (0.52 ppm) in the AM, and from 433 µg m-3 (0.35 ppm) to 926 µg m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography - mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (µg h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and materialspecific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds, formaldehyde was theonly one with toxicological significance at the observed concentrations. Whole THU formaldehyde emissions ranged from 173 to 266 µg m-2 h-1 in the morning and 257 to 347 µg m-2 h-1 in the afternoon. Median formaldehyde emissions in previously studied site-built and manufactured homes were 31 and 45 µg m-2 h-1, respectively. Only one of the composite wood materials that was tested appeared to exceed the HUD formaldehyde emission standard (430 µg/m2 h-1 for particleboard and 130 µg/m2 h-1 for plywood). The high loading factor (materialsurface area divided by THU volume) of composite wood products in the THUs and the low fresh air exchange relative to the material surface area may be responsible for the excessive concentrations observed for some of the VOCs and formaldehyde

44

Microscopic description of neutron emission rates in compound nuclei  

E-Print Network (OSTI)

The neutron emission rates in thermal excited nuclei are conventionally described by statistical models with a phenomenological level density parameter that depends on excitation energies, deformations and mass regions. In the microscopic view of hot nuclei, the neutron emission rates can be determined by the external neutron gas densities without any free parameters. Therefore the microscopic description of thermal neutron emissions is desirable that can impact several understandings such as survival probabilities of superheavy compound nuclei and neutron emissivity in reactors. To describe the neutron emission rates microscopically, the external thermal neutron gases are self-consistently obtained based on the Finite-Temperature Hartree-Fock-Bogoliubov (FT-HFB) approach. The results are compared with the statistical model to explore the connections between the FT-HFB approach and the statistical model. The Skyrme FT-HFB equation is solved by HFB-AX in deformed coordinate spaces. Based on the FT-HFB approach, the thermal properties and external neutron gas are properly described with the self-consistent gas substraction procedure. Then neutron emission rates can be obtained based on the densities of external neutron gases. The thermal statistical properties of $^{238}$U and $^{258}$U are studied in detail in terms of excitation energies. The thermal neutron emission rates in $^{238, 258}$U and superheavy compound nuclei $_{112}^{278}$Cn and $_{114}^{292}$Fl are calculated, which agree well with the statistical model by adopting an excitation-energy-dependent level density parameter. The coordinate-space FT-HFB approach can provide reliable microscopic descriptions of neutron emission rates in hot nuclei, as well as microscopic constraints on the excitation energy dependence of level density parameters for statistical models.

Yi Zhu; Junchen Pei

2014-11-02T23:59:59.000Z

45

Emission Zone Control in Blue Organic Electrophosphorescent Devices...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrophosphorescent Devices Through Chemical Modification of Host Materials . Emission Zone Control in Blue Organic Electrophosphorescent Devices Through Chemical...

46

Dosimeter for monitoring vapors and aerosols of organic compounds  

DOE Patents (OSTI)

A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

Vo-Dinh, T.

1987-07-14T23:59:59.000Z

47

Organic light emitting device having multiple separate emissive layers  

DOE Patents (OSTI)

An organic light emitting device having multiple separate emissive layers is provided. Each emissive layer may define an exciton formation region, allowing exciton formation to occur across the entire emissive region. By aligning the energy levels of each emissive layer with the adjacent emissive layers, exciton formation in each layer may be improved. Devices incorporating multiple emissive layers with multiple exciton formation regions may exhibit improved performance, including internal quantum efficiencies of up to 100%.

Forrest, Stephen R. (Ann Arbor, MI)

2012-03-27T23:59:59.000Z

48

Characteristics of the volatile organic compounds -- Arid Integrated Demonstration Site  

SciTech Connect

The Volatile Organic Compounds -- Arid Integrated Demonstration Program (VOC-Arid ID) is targeted at demonstration and testing of technologies for the evaluation and cleanup of volatile organic compounds and associated contaminants at arid DOE sites. The initial demonstration site is an area of carbon tetrachloride (CCl{sub 4}) contamination located near the center of the Hanford Site. The movement of CCl{sub 4} and other volatile organic contaminants in the subsurface is very complex. The problem at the Hanford Site is further complicated by the concurrent discharge of other waste constituents including acids, lard oil, organic phosphates, and transuranic radionuclides. In addition, the subsurface environment is very complex, with large spatial variabilities in hydraulic properties. A thorough understanding of the problem is essential to the selection of appropriate containment, retrieval, and/or in situ remedial technologies. The effectiveness of remedial technologies depends on knowing where the contaminants are, how they are held up in a given physical and chemical subsurface environment; and knowing the physical, chemical, and microbiological changes that are induced by the various remedial technologies.

Last, G.V.; Lenhard, R.J.; Bjornstad, B.N.; Evans, J.C.; Roberson, K.R.; Spane, F.A.; Amonette, J.E.; Rockhold, M.L.

1991-10-01T23:59:59.000Z

49

Measurement of Passive Uptake Rates for Volatile Organic Compounds on  

NLE Websites -- All DOE Office Websites (Extended Search)

Measurement of Passive Uptake Rates for Volatile Organic Compounds on Measurement of Passive Uptake Rates for Volatile Organic Compounds on Commercial Thermal Desorption Tubes and the Effect of Ozone on Sampling Title Measurement of Passive Uptake Rates for Volatile Organic Compounds on Commercial Thermal Desorption Tubes and the Effect of Ozone on Sampling Publication Type Report LBNL Report Number LBNL-6257E Year of Publication 2013 Authors Maddalena, Randy L., Amanda Parra, Marion L. Russell, and Wen-Yee Lee Publisher Lawrence Berkeley National Laboratory City Berkeley Keywords indoor air quality, Passive Sampling, Uptake Rates, vocs Abstract Diffusive or passive sampling methods using commercially filled axial-sampling thermal desorption tubes are widely used for measuring volatile organic compounds (VOCs) in air. The passive sampling method provides a robust, cost effective way to measure air quality with time-averaged concentrations spanning up to a week or more. Sampling rates for VOCs can be calculated using tube geometry and Fick's Law for ideal diffusion behavior or measured experimentally. There is evidence that uptake rates deviate from ideal and may not be constant over time. Therefore, experimentally measured sampling rates are preferred. In this project, a calibration chamber with a continuous stirred tank reactor design and constant VOC source was combined with active sampling to generate a controlled dynamic calibration environment for passive samplers. The chamber air was augmented with a continuous source of 45 VOCs ranging from pentane to diethyl phthalate representing a variety of chemical classes and physiochemical properties. Both passive and active samples were collected on commercially filled Tenax TA thermal desorption tubes over an 11-day period and used to calculate passive sampling rates. A second experiment was designed to determine the impact of ozone on passive sampling by using the calibration chamber to passively load five terpenes on a set of Tenax tubes and then exposing the tubes to different ozone environments with and without ozone scrubbers attached to the tube inlet. During the sampling rate experiment, the measured diffusive uptake was constant for up to seven days for most of the VOCs tested but deviated from linearity for some of the more volatile compounds between seven and eleven days. In the ozone experiment, both exposed and unexposed tubes showed a similar decline in terpene mass over time indicating back diffusion when uncapped tubes were transferred to a clean environment but there was no indication of significant loss by ozone reaction.

50

Volatile organic compound losses from sewage sludge-amended soils  

SciTech Connect

Volatile organic compounds (VOCs) applied to soil in sludge have been assumed to disappear quickly and completely. The VOC behavior in sludge-amended soils has been studied previously only in laboratory systems where the sludged soil has been spiked with compounds of interest. Behavior in these systems may not necessarily represent compound behavior in field soils to which contaminated sludge is added. A series of laboratory microcosm experiments were designed therefore to investigate the behavior of toluene, ethyl benzene, o-, m-, and p-xylene applied to soil in contaminated sludge, and factors influencing loss processes. The VOC loss from sludge-amended soil was well described by a simple one step pseudo-first-order model but in certain soils was better described by a two step first-order model. Volatilization was the predominant loss process. Rates of loss depended on sludge application rate, method of sludge application, soil properties, and on compound characteristics. Experiments indicated that spiking sludge-amended soils gave a reasonable indication of VOC loss rates from systems amended with contaminated sludge at least over a period of 23 d. The majority of VOCs applied to soils in sludge volatilizes quickly to the atmosphere over a few to 10s of days with a small fraction lost more slowly. Potential for VOC crop uptake, livestock ingestion, and contamination of ground water is low under routine, managed applications of sewage sludge to agricultural land.

Wilson, S.C.; Jones, K.C.

1999-08-01T23:59:59.000Z

51

Process for removing an organic compound from water  

DOE Patents (OSTI)

A process for removing organic compounds from water is disclosed. The process involves gas stripping followed by membrane separation treatment of the stripping gas. The stripping step can be carried out using one or multiple gas strippers and using air or any other gas as stripping gas. The membrane separation step can be carried out using a single-stage membrane unit or a multistage unit. Apparatus for carrying out the process is also disclosed. The process is particularly suited for treatment of contaminated groundwater or industrial wastewater.

Baker, Richard W. (Palo Alto, CA); Kaschemekat, Jurgen (Palo Alto, CA); Wijmans, Johannes G. (Menlo Park, CA); Kamaruddin, Henky D. (San Francisco, CA)

1993-12-28T23:59:59.000Z

52

Real-time monitoring of volatile organic compounds using chemical ionization mass spectroscopy: Final report  

SciTech Connect

Volatile organic compound (VOC) emission to the atmosphere is of great concern to semiconductor manufacturing industries, research laboratories, the public, and regulatory agencies. Some industries are seeking ways to reduce emissions by reducing VOCs at the point of use (or generation). This paper discusses the requirements, design, calibration, and use of a sampling inlet/quadrupole mass spectrometer system for monitoring VOCs in a semiconductor manufacturing production line. The system uses chemical ionization to monitor compounds typically found in the lithography processes used to manufacture semiconductor devices (e.g., acetone, photoresist). The system was designed to be transportable from tool to tool in the production line and to give the operator real-time feedback so the process(es) can be adjusted to minimize VOC emissions. Detection limits ranging from the high ppb range for acetone to the low ppm range fore other lithography chemicals were achieved using chemical ionization mass spectroscopy at a data acquisition rate of approximately 1 mass spectral scan (30 to 200 daltons) per second. A demonstration of exhaust VOC monitoring was performed at a working semiconductor fabrication facility during actual wafer processing.

Thornberg, S.M.; Mowry, C.D.; Keenan, M.R.; Bender, S.F.A. [Sandia National Labs., Albuquerque, NM (United States). Gas Analysis Lab.; Owen, T. [Intel Corp., Rio Rancho, NM (United States)

1997-04-01T23:59:59.000Z

53

Detection of volatile organic compounds using surface enhanced Raman scattering  

SciTech Connect

The authors present the detection of volatile organic compounds directly in their vapor phase by surface-enhanced Raman scattering (SERS) substrates based on lithographically-defined two-dimensional rectangular array of nanopillars. The type of nanopillars is known as the tapered pillars. For the tapered pillars, SERS enhancement arises from the nanofocusing effect due to the sharp tip on top. SERS experiments were carried out on these substrates using various concentrations of toluene vapor. The results show that SERS signal from a toluene vapor concentration of ppm level can be achieved, and the toluene vapor can be detected within minutes of exposing the SERS substrate to the vapor. A simple adsorption model is developed which gives results matching the experimental data. The results also show promising potential for the use of these substrates in environmental monitoring of gases and vapors.

Chang, A S; Maiti, A; Ileri, N; Bora, M; Larson, C C; Britten, J A; Bond, T C

2012-03-22T23:59:59.000Z

54

Neutral-ionic transitions in organic mixed-stack compounds  

SciTech Connect

Torrance et al. have made the interesting observation that several mixed-stack organic compounds undergo transitions from neutral states to ionic states as the temperature or pressure is varied. We examine a simple model of such transitions including Coulomb interaction and hybridization of neutral and ionic states. In the limit of weak hybridization and long-range repulsive interaction between ionic planes, it is proven that there is a complete devil's staircase where the degree of ionicity assumes an infinity of rational values. For attractive interactions between ionic planes, the neutral-ionic transition is shown to be first order for weak hybridization. Comparison with experiment indicates that this situation applies to tetrathiafulvalene (TTF) chloranil. For strong hybridization the transition is continuous but goes through a metallic phase. It is shown, for the first time, that the spectrum of the charge-transfer Hamiltonian contains both a bound spectrum, the observed charge-transfer excitations, and a continuum.

Bruinsma, R.; Bak, P.; Torrance, J.B.

1983-01-01T23:59:59.000Z

55

New Soil Volatile Organic Compound Samplers U S  

NLE Websites -- All DOE Office Websites (Extended Search)

Soil Volatile Organic Soil Volatile Organic Compound Samplers U . S . D e p a r t m e n t o f E n e r g y * O f f i c e o f F o s s i l E n e r g y N a t i o n a l E n e r g y T e c h n o l o g y L a b o r a t o r y Successes AdvAnced ReseARch To support coal and power systems development, NETL's Advanced Research Program conducts a range of pre-competitive research focused on breakthroughs in materials and processes, coal utilization science, sensors and controls, computational energy science, and bioprocessing-opening new avenues to gains in power plant efficiency, reliability, and environmental quality. NETL also sponsors cooperative educational initiatives in University Coal Research, Historically Black Colleges and Universities, and Other Minority Institutions. Accomplishments P Process improvement P Cost reduction P Greater efficiency

56

Identifying Sources of Volatile Organic Compounds and Aldehydes in a High  

NLE Websites -- All DOE Office Websites (Extended Search)

Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building Title Identifying Sources of Volatile Organic Compounds and Aldehydes in a High Performance Building Publication Type Report LBNL Report Number LBNL-3979e Year of Publication 2010 Authors Ortiz, Anna C., Marion L. Russell, Wen-Yee Lee, Michael G. Apte, and Randy L. Maddalena Pagination 29 Date Published 09/2010 Publisher Lawrence Berkeley National Laboratory City Berkeley Abstract The developers of the Paharpur Business Center (PBC) and Software Technology Incubator Park in New Delhi, India offer an environmentally sustainable building with a strong emphasis on energy conservation, waste minimization and superior indoor air quality (IAQ). To achieve the IAQ goal, the building utilizes a series of air cleaning technologies for treating the air entering the building. These technologies include an initial water wash followed by ultraviolet light treatment and biolfiltration using a greenhouse located on the roof and numerous plants distributed throughout the building. Even with the extensive treatment of makeup air and room air in the PBC, a recent study found that the concentrations of common volatile organic compounds and aldehydes appear to rise incrementally as the air passes through the building from the supply to the exhaust. This finding highlights the need to consider the minimization of chemical sources in buildings in combination with the use of advanced air cleaning technologies when seeking to achieve superior IAQ. The goal of this project was to identify potential source materials for indoor chemicals in the PBC. Samples of building materials, including wood paneling (polished and unpolished), drywall, and plastic from a hydroponic drum that was part of the air cleaning system, were collected from the building for testing. All materials were collected from the PBC building and shipped to the Lawrence Berkeley National Laboratory (LBNL) for testing. The materials were pre-conditioned for two different time periods before measuring material and chemical specific emission factors for a range of VOCs and Aldehydes. Of the six materials tested, we found that the highest emitter of formaldehyde was new plywood paneling. Although polish and paint contribute to some VOC emissions, the main influence of the polish was in altering the capacity of the surface to accumulate formaldehyde. Neither the new nor aged polish contributed significantly to formaldehyde emissions. The VOC emission stream (excluding formaldehyde) was composed of up to 18 different chemicals and the total VOC emissions ranged in magnitude from 7 ÎĽg/m2/h (old wood with old polish) to >500 ÎĽg/m2/h (painted drywall). The formaldehyde emissions from drywall and old wood with either new or old polish were ~ 15 ÎĽg/m2/h while the new wood material emitted > 100 ÎĽg/m2/h. However, when the projected surface area of each material in the building was considered, the new wood, old wood and painted drywall material all contributed substantially to the indoor formaldehyde loading while the coatings contributed primarily to the VOCs

57

Hafnium metallocene compounds used as cathode interfacial layers for enhanced electron transfer in organic solar cells  

Science Journals Connector (OSTI)

We have used hafnium metallocene compounds as cathode interfacial layers for organic solar cells [OSCs]. A metallocene compound consists of...6, 6]-phenyl C61 butyric acid methyl ester, bis-(ethylcyclopentadienyl...

Keunhee Park; Seungsik Oh; Donggeun Jung; Heeyeop Chae…

2012-01-01T23:59:59.000Z

58

Microbial Electrosynthesis: Feeding Microbes Electricity To Convert Carbon Dioxide and Water to Multicarbon Extracellular Organic Compounds  

Science Journals Connector (OSTI)

...extracellular organic compounds...directly to the cells with a graphite...dioxide to organic compounds...microbial production of multicarbon...to convert solar energy that...hydrogen production was verified...outlet, but a solar-powered...a) H-cell device for...errors of the organic acid and...

Kelly P. Nevin; Trevor L. Woodard; Ashley E. Franks; Zarath M. Summers; Derek R. Lovley

2010-06-01T23:59:59.000Z

59

Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries  

DOE Patents (OSTI)

A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper (II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the orginal organic compounds, is subsequently blended with high level radioactive sludge and transferred to a virtrification facility for processing into borosilicate glass for long-term storage.

Doherty, Joseph P. (Elkton, MD); Marek, James C. (Augusta, GA)

1989-01-01T23:59:59.000Z

60

Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries  

DOE Patents (OSTI)

A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper(II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the original organic compounds, is subsequently blended with high level radioactive sludge land transferred to a vitrification facility for processing into borosilicate glass for long-term storage. 2 figs., 3 tabs.

Doherty, J.P.; Marek, J.C.

1987-02-25T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

E-Print Network 3.0 - aromatic organic compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

62

Volatile organic compound monitoring by photo acoustic radiometry  

SciTech Connect

Two methods for sampling and analyzing volatile organics in subsurface pore gas were developed for use at the Hazardous Waste Disposal Site at Los Alamos National Laboratory. One is Thermal Desorption Gas Chromatography Mass Spectrometry (TDGCMS), the other is Photoacoustic Radiometry (PAR). Presented here are two years worth of experience and lessons learned as both techniques matured. The sampling technique is equally as important as the analysis method. PAR is a nondispersive infrared technique utilizing band pass filters in the region from 1 to 15 {mu}m. A commercial instrument, the Model 1302 Multigas Analyzer, made by Bruel and Kjaer, was adapted for field use. To use the PAR there must be some a priori knowledge of the constellation of analytes to be measured. The TDGCMS method is sensitive to 50 analytes. Hence TDGCMS is used in an initial survey of the site to determine what compounds are present and at what concentration. Once the major constituents of the soil-gas vapor plume are known the PAR can be configured to monitor for the five analytes of most interest. The PAR can analyse a sample in minutes, while in the field. The PAR is also quite precise in controlled situations.

Sollid, J.E.; Trujillo, V.L.; Limback, S.P.; Woloshun, K.A.

1995-12-01T23:59:59.000Z

63

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET ANALYTE LIST OTHER CHANGES TO VOC MONITORING PROGRAM Page 1 of 21 VOC 3·1: PMR Section 3, Topic 1, Table 1 Recalculated Waste Matrix Code Group Weighting Factors based on the 2004 Compliance Recertification Contact Handled (CH) Transuranic (TRU) Waste Inventory (m 3 ) The new weighting factors appear to be based on CH TRU waste only and do not include remote handled (RH) TRU waste. There was no discussion in the PMR addressing possible differences in Waste Matrix Code Group (WMCG) for RH TRU that could potentially impact the weighting factors. Please provide data characterizing the differences in emissions between the two types of waste, in support of the assertion that modeling data from CH TRU waste adequately

64

Artificial Neural Network Modeling of Surface Tension for Pure Organic Compounds  

Science Journals Connector (OSTI)

Artificial Neural Network Modeling of Surface Tension for Pure Organic Compounds ... This study investigates the applicability of artificial neural networks as an efficient tool for the prediction of pure organic compounds’ surface tensions for a wide range of temperatures. ... The most accurate network among several constructed configurations has one hidden layer with 20 neurons. ...

Aliakbar Roosta; Payam Setoodeh; Abdolhossein Jahanmiri

2011-12-09T23:59:59.000Z

65

Volatile organic chemical emissions from carpets. Final report  

SciTech Connect

The primary objective of this research, was to measure the emission rates of selected individual VOC, including low molecular-weight aldehydes, released by samples of four new carpets that are typical of the major types of carpets used in residences, schools and offices. The carpet samples were collected directly from the manufacturers` mills and packaged to preserve their chemical integrity. The measurements of the concentrations and emission rates of these compounds were made under simulated indoor conditions in a 20-M{sup 3} environmental chamber designed specifically for investigations of VOC. The measurements were conducted over a period of one week following the installation of the carpet samples in the chamber. Duplicate experiments were conducted for one carpet. In addition, the concentrations and emission rates of VOC resulting from the installation of a new carpet in a residence were measured over a period of seven weeks. The stabilities of the week-long ventilation rates and temperatures were one percent relative standard deviation. The four carpets emitted a variety of VOC, 40 of which were positively identified. Eight of these were considered to be dominant. They were (in order of chromatographic retention time) formaldehyde, vinyl acetate, 2,2,4-trimethylpentane (isooctane), 1,2-propanediol (propylene glycol), styrene, 2-ethyl-l-hexanol, 4-phenylcyclohexene (4-PCH), and 2,6 di-tert-butyl-4-methylphenol (BHT). With the exception of formaldehyde, only limited data are available on the toxicity and irritancy of these compounds at low concentrations. Therefore, it is difficult to determine at this time the potential magnitude of the health and comfort effects that may occur among the population from exposures to emissions from new carpets. The concentrations and emission rates of most compounds decreased rapidly over the first 12 h of the experiments.

Hodgson, A.T.; Wooley, J.D.; Daisey, J.M.

1992-04-01T23:59:59.000Z

66

Atmospheric outflow of anthropogenic semivolatile organic compounds from East Asia in Spring 2004  

SciTech Connect

To estimate the emissions of anthropogenic semivolatile organic compounds (SOCs) from East Asia and to identify unique SOC molecular markers in Asian air masses, high-volume air samples were collected on the island of Okinawa, Japan between 22 March and 2 May 2004. Contributions from different source regions (China, Japan, the Koreas, Russia, and ocean/local) were estimated by use of source region impact factors (SRIFs). Elevated concentrations of hexachlorobenzene (HCB), hexachlorcyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs), and particulate-phase polycyclic aromatic hydrocarbons (PAHs) were attributed to air masses from China. A large proportion of the variation in the current-use pesticides, gas-phase PAHs, and polychlorinated biphenyl (PCB) concentrations was explained by meteorology. Chlordanes showed a technical mixture profile and similar concentrations regardless of source region. {alpha}/{gamma} HCH and trans/cis chlordane ratios did not vary significantly with different source regions and had regional averages of 2.5 {+-} 1.0 and 1.2 {+-} 0.3, respectively. Particulate-phase PAH concentrations were significantly correlated (p value {lt} 0.05) with other incomplete combustion byproduct concentrations, including elemental mercury (Hg{sup 0}), CO, NOx{asterisk}, black carbon, submicrometer aerosols, and SO{sub 2}. By use of measured PAH, CO, and black carbon concentrations and estimated CO and black carbon emission inventories, the emission of six carcinogenic particulate-phase PAHs was estimated to be 1518-4179 metric tons/year for Asia and 778-1728 metric tons/year for China, respectively. These results confirm that East Asian outflow contains significant emissions of carcinogenic particulate-phase PAHs. 39 refs., 3 figs.

Toby Primbs; Staci Simonich; David Schmedding; Glenn Wilson; Dan Jaffe; Akinori Takami; Shungo Kato; Shiro Hatakeyama; Yoshizumi Kajii [Oregon State University, Corvallis, OR (United States). Departments of Chemistry and Environmental and Molecular Toxicology

2007-05-15T23:59:59.000Z

67

Volatile Organic Compound Investigation Results, 300 Area, Hanford Site, Washington  

SciTech Connect

Unexpectedly high concentrations of volatile organic compounds (VOC) were discovered while drilling in the unconfined aquifer beneath the Hanford Site’s 300 Area during 2006. The discovery involved an interval of relatively finer-grained sediment within the unconfined aquifer, an interval that is not sampled by routine groundwater monitoring. Although VOC contamination in the unconfined aquifer has been identified and monitored, the concentrations of newly discovered contamination are much higher than encountered previously, with some new results significantly higher than the drinking water standards. The primary contaminant is trichloroethene, with lesser amounts of tetrachloroethene. Both chemicals were used extensively as degreasing agents during the fuels fabrication process. A biological degradation product of these chemicals, 1,2-dichloroethene, was also detected. To further define the nature and extent of this contamination, additional characterization drilling was undertaken during 2007. Four locations were drilled to supplement the information obtained at four locations drilled during the earlier investigation in 2006. The results of the combined drilling indicate that the newly discovered contamination is limited to a relatively finer-grained interval of Ringold Formation sediment within the unconfined aquifer. The extent of this contamination appears to be the area immediately east and south of the former South Process Pond. Samples collected from the finer-grained sediment at locations along the shoreline confirm the presence of the contamination near the groundwater/river interface. Contamination was not detected in river water that flows over the area where the river channel potentially incises the finer-grained interval of aquifer sediment. The source for this contamination is not readily apparent. A search of historical documents and the Hanford Waste Information Data System did not provide definitive clues as to waste disposal operations and/or spills that might have resulted in groundwater contamination in this sediment, although several relatively small accidental releases of VOCs have occurred in the past in the northern portion of the 300 Area. It is likely that large quantities of degreasing solutions were disposed to the North and South Process Ponds during the 1950s and 1960s, and that evidence for them in the upper portion of the unconfined aquifer has been removed because of groundwater movement through the much more transmissive sediment. Also, investigations to date have revealed no evidence to suggest that a dense, non-aqueous phase liquid remains undetected in the subsurface. Potential pathways for contamination to migrate from this finer-grained sediment include groundwater movement through the interval to offshore locations in the Columbia River channel, dispersion out of the finer-grained interval into the overlying transmissive sediment (again, with transport to the riverbed), and potential future withdrawal via water supply wells.

Peterson, Robert E.; Williams, Bruce A.; Smith, Ronald M.

2008-07-07T23:59:59.000Z

68

Methods and systems for chemoautotrophic production of organic compounds  

DOE Patents (OSTI)

The present disclosure identifies pathways, mechanisms, systems and methods to confer chemoautotrophic production of carbon-based products of interest, such as sugars, alcohols, chemicals, amino acids, polymers, fatty acids and their derivatives, hydrocarbons, isoprenoids, and intermediates thereof, in organisms such that these organisms efficiently convert inorganic carbon to organic carbon-based products of interest using inorganic energy, such as formate, and in particular the use of organisms for the commercial production of various carbon-based products of interest.

Fischer, Curt R.; Che, Austin J.; Shetty, Reshma P.; Kelly, Jason R.

2013-01-08T23:59:59.000Z

69

1. PRECONCENTRATION, THERMAL DESORPTION & ANALYSIS OF VOLATILE ORGANIC COMPOUNDS  

E-Print Network (OSTI)

: peltier, liq. N?.. Heated transfer line 2) Desorption & transfer by fastheatlng Cooled & heated trap jas trap. The trap is then quickly heated, under a low flow of hélium, to desorb and inject thé compounds. This highly concentrated plug of sample is transferred via a heated transfer line, to a capillary

Boyer, Edmond

70

Manmade organic compounds in the surface waters of the United States: A review of current understanding  

SciTech Connect

On the basis of their aqueous solubilities, nonionic organic compounds partition themselves between water, dissolved organic matter, particulate organic matter, and the lipid reservoirs of aquatic organisms. Ionized organic compounds can be adsorbed to sediments, thereby reducing their aqueous concentrations. Transformation processes of photolysis, hydrolysis, biodegradation, and volatilization can attenuate organic compounds, and attenuation rates commonly follow a first-order kinetic process. Eight groups of manmade organic compounds are discussed: (1) polychlorinated biphenyls and organochlorine insecticides; (2) carbamate and organophosphorus; (3) herbicides; (4) phenols; (5) halogenated aliphatic and monocyclic aromatic hydrocarbons; (6) phthalate esters; (7) polychlorinated dibenzo-p-dioxins, and (8) polycyclic aromatic hydrocarbons. For each compound group, data pertaining to use, production, and properties are presented and discussed. Process that influence the environmental fate of each group, as determined primarily through laboratory studies, are reviewed, and important fate process are identified. Environmental concentrations of compounds from each group in water, biota, and sediment are given to demonstrate representative values for comparison to concentrations determined during ongoing research. Finally, where sufficient data exist, regional and temporal contamination trends in the US are discussed. 699 refs., 26 figs., 47 tabs.

Smith, J.A.; Witkowski, P.J.; Fusillo, T.V.

1990-01-01T23:59:59.000Z

71

Greenhouse gas emissions from home composting of organic household waste  

SciTech Connect

The emission of greenhouse gases (GHGs) is a potential environmental disadvantage of home composting. Because of a lack of reliable GHG emission data, a comprehensive experimental home composting system was set up. The system consisted of six composting units, and a static flux chamber method was used to measure and quantify the GHG emissions for one year composting of organic household waste (OHW). The average OHW input in the six composting units was 2.6-3.5 kg week{sup -1} and the temperature inside the composting units was in all cases only a few degrees (2-10 {sup o}C) higher than the ambient temperature. The emissions of methane (CH{sub 4}) and nitrous oxide (N{sub 2}O) were quantified as 0.4-4.2 kg CH{sub 4} Mg{sup -1} input wet waste (ww) and 0.30-0.55 kg N{sub 2}O Mg{sup -1} ww, depending on the mixing frequency. This corresponds to emission factors (EFs) (including only CH{sub 4} and N{sub 2}O emissions) of 100-239 kg CO{sub 2}-eq. Mg{sup -1} ww. Composting units exposed to weekly mixing had the highest EFs, whereas the units with no mixing during the entire year had the lowest emissions. In addition to the higher emission from the frequently mixed units, there was also an instant release of CH{sub 4} during mixing which was estimated to 8-12% of the total CH{sub 4} emissions. Experiments with higher loads of OHW (up to 20 kg every fortnight) entailed a higher emission and significantly increased overall EFs (in kg substance per Mg{sup -1} ww). However, the temperature development did not change significantly. The GHG emissions (in kg CO{sub 2}-eq. Mg{sup -1} ww) from home composting of OHW were found to be in the same order of magnitude as for centralised composting plants.

Andersen, J.K., E-mail: jka@env.dtu.d [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark); Boldrin, A.; Christensen, T.H.; Scheutz, C. [Department of Environmental Engineering, Technical University of Denmark, DK-2800, Kongens Lyngby (Denmark)

2010-12-15T23:59:59.000Z

72

Growth Yields of Bacteria on Selected Organic Compounds  

Science Journals Connector (OSTI)

...calculate heats of combustion of an exceedingly...carbohydrates, and hydrocarbons, wehave calculated...9, 10), heats of combustion per available...microbial cells on hydrocarbons. Science...S. 1929. Heats of combustion of organic...

W. R. Mayberry; G. J. Prochazka; W. J. Payne

1967-11-01T23:59:59.000Z

73

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From  

E-Print Network (OSTI)

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2010 William Acree, Jr. Department of Chemistry, University of North Texas, Denton, Texas 76203 James S. Chickosa... Department of Chemistry and Biochemistry

Chickos, James S.

74

Electrospun Polyurethane Fibers for Absorption of Volatile Organic Compounds from Air  

E-Print Network (OSTI)

Electrospun polyurethane fibers for removal of volatile organic compounds (VOC) from air with rapid VOC absorption and desorption have been developed. Polyurethanes based on 4,4-methylenebis(phenylisocyanate) (MDI) and ...

Scholten, Elke

75

Weathered Diesel oil as a sorptive phase for hydrophobic organic compounds in aquifer materials  

E-Print Network (OSTI)

The sorptive properties of weathered diesel oil were investigated by conducting miscible displacement experiments with three hydrophobic organic compounds (HOCs), acenapthene, fluorene, and dibenzothiophene, as tracers in columns containing aquifer...

Hudson, Rondall James

2012-06-07T23:59:59.000Z

76

Measurements of Volatile Organic Compounds Using Proton Transfer Reaction - Mass Spectrometry during the MILAGRO 2006 Campaign  

E-Print Network (OSTI)

Volatile organic compounds (VOCs) were measured by proton transfer reaction – mass spectrometry (PTR-MS) on a rooftop in the urban mixed residential and industrial area North Northeast of downtown Mexico City as part of ...

Fortner, E. C.

77

Control of spider mites on cotton by organic sulphur compounds  

E-Print Network (OSTI)

of two species of spider mites using 8 gallons of spray per acre. . 57 10. Results of laboratory ovicidal tests for control of two species of spider mites using 100 gallons of spray per acre.................................................. 59 11...-volurae sprays in the control of cotton pests has presented the problem of getting enough effective sulphur into these sprays to control the spider mites# A series of tests was conducted to evaluate the toxicity of various sulphur compounds in low...

King, Charles Edward

2013-10-04T23:59:59.000Z

78

Progress in Understanding Low-Temperature Organic Compound Oxidation Using a Jet-Stirred Reactor  

E-Print Network (OSTI)

1 Progress in Understanding Low-Temperature Organic Compound Oxidation Using a Jet-Stirred Reactor Lorraine, CNRS, ENSIC, BP 20451, 1 rue Grandville, 54000 Nancy, France Abstract The jet-stirred reactor compounds that can be found in fuels and biofuels. Such an improvement in understanding requires

79

Supercritical CO2 extraction of organic compounds from soil-water slurries  

E-Print Network (OSTI)

SUPERCRITICAL COi EXTRACTION OF ORGANIC COMPOUNDS FROM SOIL-WATER SLURRIES A Thesis by BRIAN DEAN CARTER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1993 Major Subject: Chemical Engineering SUPERCRITICAL COz FXTRACTION OF ORGANIC COMPOUNDS FROM SOIL-WATER SLURRIES A Thesis by BRIAN DEAN CARTER Submitted to Texas A&M University in partial fulfillment of the requirements...

Carter, Brian Dean

2012-06-07T23:59:59.000Z

80

Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites  

SciTech Connect

Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

2014-05-06T23:59:59.000Z

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81

Clean process to destroy arsenic-containing organic compounds with recovery of arsenic  

DOE Patents (OSTI)

A reduction method is provided for the treatment of arsenic-containing organic compounds with simultaneous recovery of pure arsenic. Arsenic-containing organic compounds include pesticides, herbicides, and chemical warfare agents such as Lewisite. The arsenic-containing compound is decomposed using a reducing agent. Arsine gas may be formed directly by using a hydrogen-rich reducing agent, or a metal arsenide may be formed using a pure metal reducing agent. In the latter case, the arsenide is reacted with an acid to form arsine gas. In either case, the arsine gas is then reduced to elemental arsenic. 1 fig.

Upadhye, R.S.; Wang, F.T.

1996-08-13T23:59:59.000Z

82

Developing carbon-based "organic" compounds for microelectronic applications is a promising, rapidly  

E-Print Network (OSTI)

· Performance and production solutions to electronics, displays, solar cells, white lighting and room lightingDeveloping carbon-based "organic" compounds for microelectronic applications is a promising inorganic materials such as silicon and copper, organic microelectronics are flexible, lighter weight, less

Hayden, Nancy J.

83

Electrosynthesis of Organic Compounds from Carbon Dioxide Is Catalyzed by a Diversity of Acetogenic Microorganisms  

Science Journals Connector (OSTI)

...powered by solar energy is...converted to organic compounds...strategies for the production of fuels...harvesting solar energy...electrodes to cells, has received...microbial fuel cells. Bioresour...microbial production platform...challenges in solar energy utilization...conversion of organic matter to...

Kelly P. Nevin; Sarah A. Hensley; Ashley E. Franks; Zarath M. Summers; Jianhong Ou; Trevor L. Woodard; Oona L. Snoeyenbos-West; Derek R. Lovley

2011-03-04T23:59:59.000Z

84

Intermediate-Volatility Organic Compounds: A Large Source of Secondary Organic Aerosol  

Science Journals Connector (OSTI)

Schauer, J. J.; Kleeman, M. J.; Cass, G. R.; Simoneit, B. R. T.Measurement of emissions from air pollution sources. ... Measurement of Emissions from Air Pollution Sources. ... Schauer, J. J.; Kleeman, M. J.; Cass, G. R.; Simoneit, B. R. T.Measurement of emissions from air pollution sources. ...

Yunliang Zhao; Christopher J. Hennigan; Andrew A. May; Daniel S. Tkacik; Joost A. de Gouw; Jessica B. Gilman; William C. Kuster; Agnes Borbon; Allen L. Robinson

2014-11-06T23:59:59.000Z

85

Microbial transformations of natural organic compounds and radionuclides in subsurface environments  

SciTech Connect

A major national concern in the subsurface disposal of energy wastes is the contamination of ground and surface waters by waste leachates containing radionuclides, toxic metals, and organic compounds. Microorganisms play an important role in the transformation of organic compounds, radionuclides, and toxic metals present in the waste and affect their mobility in subsurface environments. Microbial processes involved in dissolution, mobilization, and immobilization of toxic metals under aerobic and anaerobic conditions are briefly reviewed. Metal complexing agents and several organic acids produced by microbial action affect mobilization of radionuclides and toxic metals in subsurface environments. Information on the persistence of and biodegradation rates of synthetic as well as microbiologically produced complexing agents is scarce but important in determining the mobility of metal organic complexes in subsoils. Several gaps in knowledge in the area of microbial transformation of naturally occurring organics, radionuclides, and toxic metals have been identified, and further basic research has been suggested. 31 refs., 1 fig., 3 tabs.

Francis, A.J.

1985-10-01T23:59:59.000Z

86

Liquid-phase adsorption of organic compounds by granular activated carbon and activated carbon fibers  

SciTech Connect

Liquid-phase adsorption of organic compounds by granular activated carbon (GAC) and activated carbon fibers (ACFs) is investigated. Acetone, isopropyl alcohol (IPA), phenol, and tetrahydrofuran (THF) were employed as the model compounds for the present study. It is observed from the experimental results that adsorption of organic compounds by GAC and ACF is influenced by the BET (Brunauer-Emmett-Teller) surface area of adsorbent and the molecular weight, polarity, and solubility of the adsorbate. The adsorption characteristics of GAC and ACFs were found to differ rather significantly. In terms of the adsorption capacity of organic compounds, the time to reach equilibrium adsorption, and the time for complete desorption, ACFs have been observed to be considerably better than GAC. For the organic compounds tested here, the GAC adsorptions were shown to be represented well by the Langmuir isotherm while the ACF adsorption could be adequately described by the Langmuir or the Freundlich isotherm. Column adsorption tests indicated that the exhausted ACFs can be effectively regenerated by static in situ thermal desorption at 150 C, but the same regeneration conditions do not do as well for the exhausted GAC.

Lin, S.H.; Hsu, F.M. [Yuan Ze Inst. of Tech., Taoyuan (Taiwan, Province of China). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

87

Influence of the magnetic phase transition on secondary ion emission from disordered Ni-Pd compounds of various compositions  

Science Journals Connector (OSTI)

Variations in secondary ion emission (SIE) from polycrystals of ferromagnetic disordered Ni-Pd compounds irradiated by argon ions with energy of 10 keV are studied experimentally. A considerable reduction in Ni+ ...

K. F. Minnebaev; K. A. Tolpin…

2012-05-01T23:59:59.000Z

88

Stripping of organic compounds from wastewater as an auxiliary fuel of regenerative thermal oxidizer  

Science Journals Connector (OSTI)

Organic solvents with different volatilities are widely used in various processes and generate air and water pollution problems. In the cleaning processes of electronics industries, most volatile organic compounds (VOCs) are vented to air pollution control devices while most non-volatile organic solvents dissolve in the cleaning water and become the major sources of COD in wastewater. Discharging a high-COD wastewater stream to wastewater treatment facility often disturbs the treatment performance. A pretreatment of the high-COD wastewater is therefore highly desirable. This study used a packed-bed stripping tower in combination with a regenerative thermal oxidizer to remove the COD in the wastewater from a printed circuit board manufacturing process and to utilize the stripped organic compounds as the auxiliary fuel of the RTO. The experimental results showed that up to 45% of the COD could be removed and 66% of the RTO fuel could be saved by the combined treatment system.

Meng-Wen Chang; Jia-Ming Chern

2009-01-01T23:59:59.000Z

89

Ambient air monitoring for organic compounds, acids, and metals at Los Alamos National Laboratory, January 1991  

SciTech Connect

Los Alamos National Laboratory (LANL) contracted Radian Corporation (Radian) to conduct a short-term, intensive air monitoring program whose goal was to estimate the impact of chemical emissions from LANL on the ambient air environment. A comprehensive emission inventory had identified more than 600 potential air contaminants in LANL's emissions. A subset of specific target chemicals was selected for monitoring: 20 organic vapors, 6 metals and 5 inorganic acid vapors. These were measured at 5 ground level sampling sites around LANL over seven consecutive days in January 1991. The sampling and analytical strategy used a combination of EPA and NIOSH methods modified for ambient air applications.

Williams, C.H. (Radian Corp., Austin, TX (United States)); Eberhart, C.F. (Los Alamos National Lab., NM (United States))

1992-01-01T23:59:59.000Z

90

Ambient air monitoring for organic compounds, acids, and metals at Los Alamos National Laboratory, January 1991  

SciTech Connect

Los Alamos National Laboratory (LANL) contracted Radian Corporation (Radian) to conduct a short-term, intensive air monitoring program whose goal was to estimate the impact of chemical emissions from LANL on the ambient air environment. A comprehensive emission inventory had identified more than 600 potential air contaminants in LANL`s emissions. A subset of specific target chemicals was selected for monitoring: 20 organic vapors, 6 metals and 5 inorganic acid vapors. These were measured at 5 ground level sampling sites around LANL over seven consecutive days in January 1991. The sampling and analytical strategy used a combination of EPA and NIOSH methods modified for ambient air applications.

Williams, C.H. [Radian Corp., Austin, TX (United States); Eberhart, C.F. [Los Alamos National Lab., NM (United States)

1992-10-01T23:59:59.000Z

91

Determination of Migration Parameters for Volatile Organic Compounds in Polyethylene Terephthalate and Nylon 6 by Dynamic Permeation Cell Method  

E-Print Network (OSTI)

Determination of Migration Parameters for Volatile Organic Compounds in Polyethylene Terephthalate, such as low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polypropylene (PP); however

Heller, Barbara

92

Enthalpies of Sublimation of Organic and Organometallic Compounds. James S. Chickosa...  

E-Print Network (OSTI)

Enthalpies of Sublimation of Organic and Organometallic Compounds. 1910­2001 James S. Chickosa... Department of Chemistry, University of Missouri-St. Louis, Saint Louis, Missouri 63121 William E. Acree, Jr.b... Department of Chemistry, University of North Texas, Denton, Texas 76203 Received 22 October 2001; accepted 11

Chickos, James S.

93

Rejection and fate of trace organic compounds (TrOCs) during membrane distillation  

E-Print Network (OSTI)

Rejection and fate of trace organic compounds (TrOCs) during membrane distillation Kaushalya COCs) Direct contact membrane distillation (DCMD) Volatility Fate and transport Hydrophobicity/hydrophilicity a b s t r a c t In this study, we examined the feasibility of membrane distillation (MD) for removing

94

A Critical Review on Studies of Volatile Organic Compound (VOC) Sorption by  

E-Print Network (OSTI)

A Critical Review on Studies of Volatile Organic Compound (VOC) Sorption by Building Materials (RP the pros and cons of existing sorption models, as well as experimental methods. In addition, it summarizes existing sorption data in order to understand the phenomenon of VOC sorption on building materials better

Chen, Qingyan "Yan"

95

ARTIFACT FORMATION IN HIGH VOLUME SAMPLING OF VOC's AND SOLID ORGANIC COMPOUNDS.  

E-Print Network (OSTI)

when sampling polluted air. Purified air containing 180 ppbv ozone seems to destroy PAH according Atmospheriques, Boite 7059, UNIVERSITE PARIS 7, 2, place Jussieu, 75251 PARIS Cedex 05 ABSTRACT Pollutants from well äs solid (SOC's) organic compounds. High volume samplers are commonly used m air quality

Boyer, Edmond

96

Air filters from HVAC systems as possible source of volatile organic compounds (VOC) – laboratory and field assays  

Science Journals Connector (OSTI)

The emission of volatile organic compounds (VOC) from air filters of HVAC systems was to be evaluated. In a first study carbonyl compounds (14 aldehydes and two ketones) were measured by reacting them with 2,4-dinitrophenylhydrazine (DNPH). Analysis was done by HPLC and UV detection. In laboratory experiments pieces of used and unused HVAC filters were incubated in test chambers. Filters to be investigated were taken from a filter bank of a large HVAC system in the centre of Berlin. First results show that – among those compounds – formaldehyde and acetone were found in higher concentrations in the test chambers filled with used filters in comparison to those with unused filters. Parallel field measurements were carried out at the prefilter and main filter banks of the two HVAC systems. Here measurements were carried out simultaneously before and after the filters to investigate whether those aldehydes or ketones arise from the filter material on site. Formaldehyde and acetone significantly increased in concentration after the filters of one HVAC system. In parallel experiments microorganisms were proved to be able to survive on air filters. Therefore, a possible source of formaldehyde and acetone might be microbes.

Hans Schleibinger; Henning Rüden

1999-01-01T23:59:59.000Z

97

Emission and Chemistry of Organic Carbon in the Gas and Aerosol...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Chemistry of Organic Carbon in the Gas and Aerosol Phase at a Sub-Urban Site Near Mexico City in March 2006 During Emission and Chemistry of Organic Carbon in the Gas and...

98

Use of sonication for in-well softening of semivolatile organic compounds. 1997 annual progress report  

SciTech Connect

'This project investigates the in-situ degradation of semivolatile organic compounds (SVOCs) and volatile organic compounds (VOCs) using in-well sonication, in-well vapor stripping, and bioremediation. Pretreating groundwaters with sonication techniques in-situ would form VOCs that can be effectively removed by in-well vapor stripping and bioremediation. The mechanistic studies focus on the coupling of megasonics and ultrasonics to soften (i.e., partially degrade) the SVOCs; oxidative reaction mechanism studies; surface corrosion studies (on the reactor walls/well); enhancement due to addition of oxidants, quantification of the hydroxyl radical formation; identification/quantification of degradation products; volatility/degradability of the treated waters; development of a computer simulation model to describe combined in-well sonication/in-well vapor stripping/bioremediation; systems analysis/economic analysis; large laboratory-scale experiment verification; and field demonstration of the integrated technology. Benefits of this approach include: (1) Remediation is performed in-situ; (2) The treatment systems complement each other; their combination can drastically reduce or remove SVOCs and VOCs; (3) Ability to convert hard-to-degrade organics into more volatile organic compounds; (4) Ability to remove residual VOCs and softened SVOCs through the combined action of in-well vapor stripping and biodegradation; (5) Does not require handling or disposing of water at the ground surface; and (6) Cost-effective and improved efficiency, resulting in shortened clean-up times to remediate a site.'

Peters, R.W.; Manning, J. [Argonne National Lab., IL (US); Hoffman, M.R. [California Inst. of Tech., Pasadena, CA (US); Gorelick, S. [Stanford Univ., CA (US)

1997-01-01T23:59:59.000Z

99

Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries  

DOE Patents (OSTI)

A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacting a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

Mincher, Bruce J. (3705 Creekside Dr., Idaho Falls, ID 83404); Curry, Randy Dale (1104 Merrill Ct., Columbia, MO 65203); Clevenger, Thomas E. (2512 Bluff Blvd., Columbia, MO 65201); Golden, Jeffry (12612 Cedarbrook La., Laurel, MD 20708)

2000-01-01T23:59:59.000Z

100

Soil organic carbon enrichment of dust emissions: magnitude, mechanisms and its implications for  

E-Print Network (OSTI)

Soil organic carbon enrichment of dust emissions: magnitude, mechanisms and its implications of SOC enrichment in dust emissions is necessary to evaluate the impact of wind erosion on the carbon) across landscapes and soil carbon emissions (van Oost et al., 2007). The dust cycle rep- resents

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

On-line Analysis of Organic Compounds in Diesel Exhaust Using a Proton Transfer Reaction Mass Spectrometer (PTR-MS)  

SciTech Connect

Chemical ionization mass spectrometry using H3O+ proton transfer in an ion drift tube (PTR-MS) was used to measure volatile organic compound (VOC) concentrations on-line in diesel engine exhaust as a function on engine load. The purpose of the study was to evaluate the PTR-MS instrument as an analytical tool for diesel engine emissions abatement research. Measured sensitivities determined from gas standards were found to be between 30% and 100% greater than calculated sensitivities. A slight humidity dependent sensitivity was observed for non-polar species, implying that reactions with H+(H2O)2 were important for some organics. The mass spectra of diesel exhaust were complex but displayed a pattern of strong ion signals at 14n+1 (n=3..8) masses, with a relative ion abundance similar to that obtained from electron impact ionization of alkanes. Laboratory experiments verified that C8-C16 n-alkanes and C8-C13 1-alkenes react with H3O+ in dissociative proton transfer reaction resulting in alkyl cation ion products, primarily m/z 41, 43, 57, 71 and 85. Monitoring the sum of these ions signals may be useful for estimating alkane emissions from unburnt diesel fuel. Alkane fragmentation likely simplified the diesel exhaust mass spectrum and reduced potential mass interferences with isobaric aromatic compounds. It is shown that the relative abundances of VOCs changed as a function of engine load. Concentrations of aldehydes and ketones dominated those of aromatic species with formaldehyde and acetaldehyde estimated to be the most abundant VOCs in the PTR-MS mass spectrum at all engine loads. The relative abundances of benzene and toluene increased with engine load indicating their pyrogenic origin. The relative abundance of alkanes, aromatics, aldehydes, and alcohols was broadly consistent with literature publications of diesel exhaust analysis by gas chromatography. About 75% of the organic ion signal could be assigned. On line analysis of diesel exhaust using this technology may be valuable tool for diesel engine emission research.

Jobson, B Tom T.; Alexander, M. Lizabeth; Maupin, Gary D.; Muntean, George G.

2005-08-01T23:59:59.000Z

102

Energy use and greenhouse gas emissions in organic and conventional farming systems in the Netherlands  

Science Journals Connector (OSTI)

Abstract Organic agriculture is often considered to contribute to reducing energy use and greenhouse gas (GHG) emissions, also on a per unit product basis. For energy, this is supported by a large number of studies, but the body of evidence for \\{GHGs\\} is smaller. Dutch agriculture is characterized by relatively intensive land use in both organic and conventional farming, which may affect their performance in terms of energy use and GHG emissions. This paper presents results of a model study on energy use and GHG emissions in Dutch organic and conventional farming systems. Energy use per unit milk in organic dairy is approximately 25% lower than in conventional dairy, while GHG emissions are 5-10% lower. Contrary to dairy farming, energy use and GHG emissions in organic crop production are higher than in conventional crop production. Energy use in organic arable farming is 10-30% and in organic vegetable farming 40-50% higher than in their respective conventional counterparts. GHG emissions in organic arable and vegetable farming are 0-15% and 35-40% higher, respectively. Our results correspond with other studies for dairy farming, but not for crop production. The most likely cause for higher energy use and GHG emissions in Dutch organic crop production is its high intensity level, which is expressed in crop rotations with a large share of high-value crops, relatively high fertiliser inputs and frequent field operations related to weeding.

Jules F.F.P. Bos; Janjo de Haan; Wijnand Sukkel; René L.M. Schils

2014-01-01T23:59:59.000Z

103

Source Signature of Volatile Organic Compounds from Oil and Natural Gas Operations in Northeastern Colorado  

Science Journals Connector (OSTI)

Source Signature of Volatile Organic Compounds from Oil and Natural Gas Operations in Northeastern Colorado ... Only 4% of all samples at BAO had high ROH+VOCO&NG and were from the western sector where the nearest wells are located indicating that they were not the dominant O&NG source at BAO. ... parameters were measured concurrently at a site on the western perimeter of Boulder, Colorado, during Feb., 1991. ...

J. B. Gilman; B. M. Lerner; W. C. Kuster; J. A. de Gouw

2013-01-14T23:59:59.000Z

104

Performance specifications for technology development: Application for characterization of volatile organic compounds in the environment  

SciTech Connect

This report contains information about technology development for the monitoring and remediation of environmental pollution caused by the release of volatile organic compounds. Topics discussed include: performance specification processes, gas chromatography, mass spectrometer, fiber-optic chemical sensors, infrared spectroscopy, Raman spectroscopy, piezoelectric sensors and electrochemical sensors. These methods are analyzed for their cost efficiency, accuracy, and the ability to meet the needs of the customer.

Carpenter, S.E.; Doskey, P.V.; Erickson, M.D.; Lindahl, P.C.

1994-07-01T23:59:59.000Z

105

GLOBAL EMISSIONS INVENTORIES OF ACID-RELATED COMPOUNDS T.E. GRAEDEL t , C.M. BENKOVITZ 2, W.C. KEENE 3, D.S. LEE 4,  

E-Print Network (OSTI)

GLOBAL EMISSIONS INVENTORIES OF ACID-RELATED COMPOUNDS T.E. GRAEDEL t , C.M. BENKOVITZ 2, W, and future rely in part on inventories of emissions constructed on appropriate spatial and temporal scales and the regulatory and policy communities. The production of global emissions inventories is the task of the GlobalEmissions

106

Treatment of biorefractory organic compounds in wool scour effluent by hydroxyl radical oxidation  

Science Journals Connector (OSTI)

Wool scouring effluent that had been treated with chemical flocculation and aerobic biological treatment (Sirolan CFB effluent) was tertiary treated by hydroxyl radical oxidation to remove residual organic compounds. These compounds impart a high chemical oxygen demand of 500–3000 mg/L and dark colour. However, a H2O2/UV process was found to effectively treat the majority of residual compounds, with up to 75% COD, 85% total organic carbon, and 100% removal of colour (T480 nm) achieved. This was despite the effluent being strongly absorbing in the UV region, with a film thickness of 0.21 mm reducing T254 nm by 50%. Treatment was unaffected by pH over the range 3–9. H2O2/UV treatment increased the biodegradability of the effluent (5-day biochemical oxygen demand increased from wool scour effluent of approximately 97.5%. This degree of treatment is sufficient for discharge in many, but not all, circumstances.

Andrew J Poole

2004-01-01T23:59:59.000Z

107

Indoor air pollutants from unvented kerosene heater emissions in mobile homes: studies on particles, semivolatile organics, carbon monoxide, and mutagenicity  

Science Journals Connector (OSTI)

Indoor air pollutants from unvented kerosene heater emissions in mobile homes: studies on particles, semivolatile organics, carbon monoxide, and mutagenicity ...

Judy L. Mumford; Ron W. Williams; Debra B. Walsh; Robert M. Burton; David J. Svendsgaard; Jane C. Chuang; Virginia S. Houk; Joellen Lewtas

1991-10-01T23:59:59.000Z

108

Integrated production of fuel gas and oxygenated organic compounds from synthesis gas  

DOE Patents (OSTI)

An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

Moore, Robert B. (Allentown, PA); Hegarty, William P. (State College, PA); Studer, David W. (Wescosville, PA); Tirados, Edward J. (Easton, PA)

1995-01-01T23:59:59.000Z

109

Enhancing the emission directionality of organic light-emitting diodes by using photonic microstructures  

SciTech Connect

We report microstructured organic light-emitting diodes (OLEDs) with directional emission based on efficient solution-processable europium-OLEDs patterned by solvent assisted microcontact molding. The angle dependence of the light emission is characterized for OLEDs with square-array photonic crystals with periods between 275?nm and 335?nm. The microstructured devices have emission patterns strongly modified from the Lambertian emission of planar OLEDs and can approximately double the emitted power in a desired angle range in both s- and p-polarizations. The modified emission is attributed to light diffracted out of the waveguide modes of the OLEDs.

Zhang, Shuyu; Turnbull, Graham A., E-mail: gat@st-andrews.ac.uk, E-mail: idws@st-andrews.ac.uk; Samuel, Ifor D. W., E-mail: gat@st-andrews.ac.uk, E-mail: idws@st-andrews.ac.uk [Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews, Fife KY16 9SS (United Kingdom)] [Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews, Fife KY16 9SS (United Kingdom)

2013-11-18T23:59:59.000Z

110

Thermodynamics and kinetics of hydrophobic organic compound sorption in natural sorbents and quantification of black carbon by electron microscopy  

E-Print Network (OSTI)

The sorption behaviors of hydrophobic organic compounds (HOCs) in sediments were investigated using pyrene. Native pyrene desorbed slowly, taking from weeks to months to equilibrate. The end-point data suggested that, at ...

Kuo, Dave Ta Fu, 1978-

2010-01-01T23:59:59.000Z

111

Pilot scale test of a produced water-treatment system for initial removal of organic compounds  

SciTech Connect

A pilot-scale test to remove polar and non-polar organics from produced water was performed at a disposal facility in Farmington NM. We used surfactant-modified zeolite (SMZ) adsorbent beds and a membrane bioreactor (MBR) in combination to reduce the organic carbon content of produced water prior to reverse osmosis (RO). Reduction of total influent organic carbon (TOC) to 5 mg/L or less is desirable for efficient RO system operation. Most water disposed at the facility is from coal-bed gas production, with oil production waters intermixed. Up to 20 gal/d of produced water was cycled through two SMZ adsorbent units to remove volatile organic compounds (BTEX, acetone) and semivolatile organic compounds (e.g., napthalene). Output water from the SMZ units was sent to the MBR for removal of the organic acid component of TOC. Removal of inorganic (Mn and Fe oxide) particulates by the SMZ system was observed. The SMZ columns removed up to 40% of the influent TOC (600 mg/L). BTEX concentrations were reduced from the initial input of 70 mg/L to 5 mg/L by the SMZ and to an average of 2 mg/L after the MBR. Removal rates of acetate (input 120-170 mg/L) and TOC (input up to 45 mg/L) were up to 100% and 92%, respectively. The water pH rose from 8.5 to 8.8 following organic acid removal in the MBR; this relatively high pH was likely responsible for observed scaling of the MBR internal membrane. Additional laboratory studies showed the scaling can be reduced by metered addition of acid to reduce the pH. Significantly, organic removal in the MBR was accomplished with a very low biomass concentration of 1 g/L throughout the field trial. An earlier engineering evaluation shows produced water treatment by the SMZ/MBR/RO system would cost from $0.13 to $0.20 per bbl at up to 40 gpm. Current estimated disposal costs for produced water are $1.75 to $4.91 per bbl when transportation costs are included, with even higher rates in some regions. Our results suggest that treatment by an SMZ/MBR/RO system may be a feasible alternative to current methods for produced water treatment and disposal.

Sullivan, Enid J [Los Alamos National Laboratory; Kwon, Soondong [UT-AUSTIN; Katz, Lynn [UT-AUSTIN; Kinney, Kerry [UT-AUSTIN

2008-01-01T23:59:59.000Z

112

Electrocatalytic Materials and Techniques for the Anodic Oxidation of Various Organic Compounds  

SciTech Connect

The focus of this thesis was first to characterize and improve the applicability of Fe(III) and Bi(V) doped PbO{sub 2} film electrodes for use in anodic O-transfer reactions of toxic and waste organic compounds, e.g. phenol, aniline, benzene, and naphthalene. Further, they investigated the use of alternative solution/electrode interfacial excitation techniques to enhance the performance of these electrodes for remediation and electrosynthetic applications. Finally, they have attempted to identify a less toxic metal oxide film that may hold promise for future studies in the electrocatalysis and photoelectrocatalysis of O-transfer reactions using metal oxide film electrodes.

Stephen Everett Treimer

2002-06-27T23:59:59.000Z

113

Solar-Powered Electrochemical Oxidation of Organic Compounds Coupled with the Cathodic Production of Molecular Hydrogen  

Science Journals Connector (OSTI)

Solar-Powered Electrochemical Oxidation of Organic Compounds Coupled with the Cathodic Production of Molecular Hydrogen ... The volume percent of the headspace was calculated assuming that it was directly proportional to the ion current measured by the mass spectrometer and that the transfer of all gases through the membrane and their 70 eV electron ionization cross-sections were approximately equivalent. ... In addition, even if hydrogen is mixed with carbon dioxide, CO2 can be readily removed just by chemical absorption process (e.g., flowing carbon dioxide gas through amine solution), which is a typical CO2 separation process in gas turbine power plants. ...

Hyunwoong Park; Chad D. Vecitis; Michael R. Hoffmann

2008-07-26T23:59:59.000Z

114

Literature review of stabilization/solidification of volatile organic compounds and the implications for Hanford grouts  

SciTech Connect

A literature review was conducted on the stabilization/solidification of volatile organic compounds (VOCs). Based on this literature, it is likely that the limestone-containing grout will not permanently immobilize VOCs and that no presently available additives can guarantee permanent immobilization. The Westinghouse hanford company grout may be fairly effective at retarding aqueous leaching of VOCs, and commercial additives can improve this performance. Significant VOC losses do occur during stabilization/solidification, and the high temperatures of the Westinghouse Hanford Company waste and grout should exacerbate this problem. In fact, these high temperatures raise doubts about the presence of VOCs in the double-shell tanks supernates.

Spence, R.D.; Osborne, S.C.

1993-09-01T23:59:59.000Z

115

Polar and non-polar organic aerosols from large-scale agricultural-waste burning emissions in Northern India: Implications to organic mass-to-organic carbon ratio  

Science Journals Connector (OSTI)

Abstract This study focuses on characteristics of organic aerosols (polar and non-polar) and total organic mass-to-organic carbon ratio (OM/OC) from post-harvest agricultural-waste (paddy- and wheat-residue) burning emissions in Northern India. Aerosol samples from an upwind location (Patiala: 30.2°N, 76.3°E) in the Indo-Gangetic Plain were analyzed for non-polar and polar fractions of organic carbon (OC1 and OC2) and their respective mass (OM1 and OM2). On average, polar organic aerosols (OM2) contribute nearly 85% of the total organic mass (OM) from the paddy- and wheat-residue burning emissions. The water-soluble-OC (WSOC) to OC2 ratio, within the analytical uncertainty, is close to 1 from both paddy- and wheat-residue burning emissions. However, temporal variability and relatively low WSOC/OC2 ratio (Av: 0.67 ± 0.06) is attributed to high moisture content and poor combustion efficiency during paddy-residue burning, indicating significant contribution (?30%) of aromatic carbon to OC2. The OM/OC ratio for non-polar (OM1/OC1 ? 1.2) and polar organic aerosols (OM2/OC2 ? 2.2), hitherto unknown for open agricultural-waste burning emissions, is documented in this study. The total OM/OC ratio is nearly identical, 1.9 ± 0.2 and 1.8 ± 0.2, from paddy- and wheat-residue burning emissions.

Prashant Rajput; M.M. Sarin

2014-01-01T23:59:59.000Z

116

The effect of mean cell residence time on the adsorbability of dissolved organic compounds found in petrochemical wastewaters  

E-Print Network (OSTI)

THF EFFECT OF MEAN CELL RESIDENCE TIME ON THE ADSORBABILITY OF DISSOLVED ORGANIC COMPOUNDS FOUND IN PETROCHEMICAL WASTEWATERS A Thesis by TIMOTHY LURING JOHNSON Submitted to the Graduate College of Texas A&M University ir, Partia. fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1979 Major Subject: Civil Engineering THE EFFECT OF MEAN CELL RESIDENCE TIME ON THE ADSORBABILITY OF DISSOLVED ORGANIC COMPOUNDS FOUND IN PETROCHEMICAL WASTENATERS A Thesis by TIMOTHY LORING...

Johnson, Timothy Loring

2012-06-07T23:59:59.000Z

117

The mobility of water soluble organic compounds in soils from the land application of petroleum waste sludge  

E-Print Network (OSTI)

THE MOBILITY OF WATER SOLUBLE ORGANIC COMPOUNDS IN SOILS FROM THE LAND APPLICATION OF PETROLEUM WASTE SLUDGE A Thesis by GORDON BARCUS EVANS, JR. Submitted to the Graduate College of Texas A&l1 University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE December 1979 Major Subject: Soil Science THE MOBILITY OF WATER SOLUBLE ORGANIC COMPOUNDS IN SOILS FROM THE LAND APPLICATION OF PETROLEUM WASTE SLUDGE A Thesis by GORDON BARCUS EVANS, JR. Approved...

Evans, Gordon Barcus

1979-01-01T23:59:59.000Z

118

Hygroscopicity of Water-Soluble Organic Compounds in Atmospheric Aerosols:? Amino Acids and Biomass Burning Derived Organic Species  

Science Journals Connector (OSTI)

In the hygroscopic measurement, the chemicals were first dissolved in ultrapure water to make stock solutions that were used to generate particles by a piezoelectric droplet generator (Uni-Photon Inc., NY., USA, Model 201). ... Together with the measurements of the hygroscopicity of glucose, glycerol, humic-like substances, and arginine, which have been detected in biomass burning aerosols and found noncrystallizing in single particle measurements (8,9,16,20,28,41), these results suggest that organic species derived from biomass burning may retain water at low RH in the atmosphere. ... (6)?Zhang, Q.; Anastasio, C. Free and combined amino compounds in atmospheric fine particles (PM2.5) and fog waters from Northern California. ...

Man Nin Chan; Man Yee Choi; Nga Lee Ng; Chak K. Chan

2005-02-04T23:59:59.000Z

119

Emissions-critical charge cooling using an organic rankine cycle  

DOE Patents (OSTI)

The disclosure provides a system including a Rankine power cycle cooling subsystem providing emissions-critical charge cooling of an input charge flow. The system includes a boiler fluidly coupled to the input charge flow, an energy conversion device fluidly coupled to the boiler, a condenser fluidly coupled to the energy conversion device, a pump fluidly coupled to the condenser and the boiler, an adjuster that adjusts at least one parameter of the Rankine power cycle subsystem to change a temperature of the input charge exiting the boiler, and a sensor adapted to sense a temperature characteristic of the vaporized input charge. The system includes a controller that can determine a target temperature of the input charge sufficient to meet or exceed predetermined target emissions and cause the adjuster to adjust at least one parameter of the Rankine power cycle to achieve the predetermined target emissions.

Ernst, Timothy C.; Nelson, Christopher R.

2014-07-15T23:59:59.000Z

120

Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of organic carbon emissions  

Science Journals Connector (OSTI)

...the SOA potential of diesel emissions, especially...improve heavy-duty diesel engine performance with postcombustion...attention to gasoline and diesel fuel composition and emissions...carbon. Although total consumption of oil is minor relative...

Drew R. Gentner; Gabriel Isaacman; David R. Worton; Arthur W. H. Chan; Timothy R. Dallmann; Laura Davis; Shang Liu; Douglas A. Day; Lynn M. Russell; Kevin R. Wilson; Robin Weber; Abhinav Guha; Robert A. Harley; Allen H. Goldstein

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Geobacter strains that use alternate organic compounds, methods of making, and methods of use thereof  

DOE Patents (OSTI)

In preferred embodiments, the present invention provides new isolated strains of Geobacter species that are capable of using a carbon source that is selected from C.sub.3 to C.sub.12 organic compounds selected from pyruvate or metabolic precursors of pyruvate as an electron donor in metabolism and in subsequent energy production. In other aspects, other preferred embodiments of the present invention include methods of making such strains and methods of using such strains. In general, the wild type strain of the microorganisms has been shown to be unable to use these C.sub.3 to C.sub.12 organic compounds as electron donors in metabolic steps such as the reduction of metallic ions. The inventive strains of microorganisms are useful improving bioremediation applications, including in situ bioremediation (including uranium bioremediation and halogenated solvent bioremediation), microbial fuel cells, power generation from small and large-scale waste facilities (e.g., biomass waste from dairy, agriculture, food processing, brewery, or vintner industries, etc.) using microbial fuel cells, and other applications of microbial fuel cells, including, but not limited to, improved electrical power supplies for environmental sensors, electronic sensors, and electric vehicles.

Lovley, Derek R; Summers, Zarath Morgan; Haveman, Shelley Annette; Izallalen, Mounir

2013-12-03T23:59:59.000Z

122

Neutron reflectometry reveals the internal structure of organic compounds deposited on aluminum oxide  

Science Journals Connector (OSTI)

Organic carbon (OC) stabilization in soils plays a significant role in the global C cycle, therefore understanding the structure and function of the OC–soil mineral interface is of high importance. To study the interface, films of simple OC compounds and natural organic matter (NOM) were deposited onto a soil mineral analogue (Al2O3) using spin coating and were exposed to humidity. The thickness, density and structure of the films were studied using a depth-sensitive, nano-scale technique of neutron reflectometry. A single homogenous layer was observed when NOM and glucose (GL) were adsorbed onto Al2O3. However, when stearic acid (SA) was added to either NOM or GL, separate layers attributed to SA and either NOM or GL were detected. The formation of distinct, immiscible layers is due to insolubility of SA with NOM and GL. In contrast, GL and NOM are both water-soluble, and therefore soluble with each other, forming a homogenous layer on the mineral surface. Our results suggest that the extent of complex layering formed on the OC–mineral interface may depend on the relative solubility of the compounds.

Melanie Mayes; Sindhu Jagadamma; Haile Ambaye; Loukas Petridis; Valeria Lauter

2013-01-01T23:59:59.000Z

123

Modeling Terrestrial Biogenic Sources of Oxygenated Organic Emissions  

Science Journals Connector (OSTI)

In recent years, oxygenated volatile organic chemicals (OVOCs) likeacetone have been recognized as important atmospheric constituents due to their ability to sequester reactive nitrogen in the form peroxyacetyl nitrate (PAN) and to be a source ...

Christopher Potter; Steven Klooster; David Bubenheim; Hanwant B. Singh; Ranga Myneni

2003-07-01T23:59:59.000Z

124

Diversity of the Volatile Organic Compounds Emitted by 55 Species of Tropical Trees: a Survey in French Guiana  

E-Print Network (OSTI)

in French Guiana Elodie A. Courtois & C. E. Timothy Paine & Pierre-Alain Blandinieres & Didier Stien & Jean, LLC 2009 Abstract Volatile organic compounds (VOCs) are pro- duced by a broad range of organisms, from tropical tree species in a lowland rainforest of French Guiana. We discovered a remarkably high chemical

Chave, JĂ©rĂ´me

125

Thermogravimetric investigation on characteristic of biomass combustion under the effect of organic calcium compounds  

Science Journals Connector (OSTI)

Abstract Experiments were conducted in a thermogravimetric analyzer to investigate thermal behavior of different organic calcium compounds (OCCs) and its blended fuels with three kinds of biomass. The effectiveness of synthesized method for OCC was assessed by the pyrolysis test. Effect of the mole ratio of calcium to sulfur on co-combustion characteristics was studied. Results indicated that preparation method of modified calcium acetate (MCA) had high precision and accuracy. Co-combustion characteristic of \\{OCCs\\} blended with biomass was controlled by OCCs’ additive amount and the content of volatile matter which is mainly composed of small hydrocarbon molecules. Combustion performance indexes for peanut shell and wheat straw impregnated by \\{OCCs\\} were improved, however, an inverse trend was found for rice husk because of lower additive amount of OCCs. The blended fuel show higher combustion performance indexes compared with combustion of individual biomass, and these indexes decrease with increases of Ca/S ratio.

Lihui Zhang; Feng Duan; Yaji Huang

2015-01-01T23:59:59.000Z

126

Selected Values of Heats of Combustion and Heats of Formation of Organic Compounds Containing the Elements C, H, N, O, P, and S.  

Science Journals Connector (OSTI)

Selected values of the heats of combustion and heats of formation of 719 organic compounds are reported here. The data tabulated pertain to compounds containing the elements carbon hydrogen nitrogen oxygen phosphorus and sulfur (CHNOPS). The information is arranged according to classes of compounds and within each class compounds are arranged by empirical formula. The general classes covered are: hydrocarbons alcohols phenols polyols ethers aldehydes ketones acids acid anhydrides esters steroids lactones carbohydrates heterocyclic oxygen compounds amines amides urea derivatives guanidine derivatives amino acids peptides alkaloids heterocyclic nitrogen compounds porphyrins organic sulfur compounds and organic phosphorus compounds. When a selection was made from among several investigators commentary is provided to indicate the choice and usually some relevant data. The number of references cited is 596. An alphabetical compound index is provided which gives the name page number empirical formula and the Wiswesser Line Notation (WLN) for each compound.

Eugene S. Domalski

1972-01-01T23:59:59.000Z

127

Organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends  

E-Print Network (OSTI)

The organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends have been assessed under warmed-up and cold idle conditions. The speciated emissions show that the ...

Kar, Kenneth

128

Organic light-emitting device with a phosphor-sensitized fluorescent emission layer  

DOE Patents (OSTI)

The present invention relates to organic light emitting devices (OLEDs), and more specifically to OLEDS that emit light using a combination of fluorescent emitters and phosphorescent emitters. The emissive region of the devices of the present invention comprise at least one phosphor-sensitized layer which has a combined emission from a phosphorescent emitter and a fluorescent emitter. In preferred embodiments, the invention relates to white-emitting OLEDS (WOLEDs).

Forrest, Stephen (Ann Arbor, MI); Kanno, Hiroshi (Osaka, JP)

2009-08-25T23:59:59.000Z

129

The relation of certain organic phosphorus compounds to blood cholinesterase activity and their value as parasiticides in swine  

E-Print Network (OSTI)

THE RELATION OF CERTAIN ORGANIC PHOSPHORUS COMPOUNDS TO BLOOD CHOLINESTERASE ACTIVITY AND THEIR VALUE AS PARASFIICIDES IN SWINE A Thesis By DELFIN DANCEL de LEON Submitted to the Graduate School of the Agricultural and Mechanical College... of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1960 Major Subject: Animal Husbandry THE RELATION OF CERTAIN ORGANIC PHOSPHORUS CON/EXPOUNDS TO BLOOD CHOLINESTERASE ACTIVITT AND THEIR VALUE...

Leon, Delfin Dancel de

1960-01-01T23:59:59.000Z

130

SPECIATION OF TRACE ORGANIC LIGANDS AND INORGANIC AND ORGANOMETALLIC COMPOUNDS IN OIL SHALE PROCESS WATERS  

E-Print Network (OSTI)

Presented at the 13th Oil Shale Symposium, Golden, CO, April~1ETALLIC COMPOUNDS IN OIL SHALE PROCESS WATERS Richard H.compounds in the seven oil shale process waters. These

Fish, Richard H.

2013-01-01T23:59:59.000Z

131

Gas phase radiolysis and vacuum ultraviolet photolysis of heterocyclic organic compounds. Progress report, Feburary 1, 1979-February 1, 1980  

SciTech Connect

The long-range objective of our research group is to gain a better understanding of the processes by which complex organic molecules react when they absorb large amounts of energy. This progress report describes the results of our recent work in three areas: diradicals derived from heterocyclic compounds; trimethylene diradicals from various sources; and ion-molecule reactions.

Scala, A.A.; Nguyen, D.; Rourke, W.; Caputo, M.

1980-01-01T23:59:59.000Z

132

Scale-up analysis and development of gliding arc discharge facility for volatile organic compounds decomposition  

Science Journals Connector (OSTI)

The influences of inlet gas flow rate and reactor configuration on volatile organic compounds (VOCs) decomposition efficiency in a traditional gliding arc (T-GA) facility are studied based on laboratory experiments and numerical simulation. The ratio of the nozzle diameter and the shortest distance of two electrodes should be maintained in a suitable value range to guarantee the decomposition efficiency, which indicates simply enlarging the nozzle inner diameter is not a proper way to raise the T-GA treatment capacity in a fixed supply voltage condition. A developed gliding arc gas discharge (D-GA) reactor based on a modified gas feed system is proposed: small flow rate air goes through the bottom nozzle to process the GA evolution, and high flow rate contaminated gas goes frontal through the plasma region and decomposes. The performances of D-GA reactor in the decomposition of \\{VOCs\\} with relative high gas flow rate, including decomposition efficiency and specific energy consumption, are better than T-GA reactor. D-GA reactor also avoids the drawbacks of the increases of power system amount and electric power consumption in multi-electrode GA system.

Zheng Bo; Jianhua Yan; Xiaodong Li; Yong Chi; Kefa Cen

2008-01-01T23:59:59.000Z

133

Stable Carbon Isotope Ratios of Phenolic Compounds in Secondary Particulate Organic Matter Formed by Photooxidation of Toluene  

E-Print Network (OSTI)

Compound-specific stable carbon isotope ratios for phenolic compounds in secondary particulate organic matter (POM) formed by photooxidation of toluene were studied. Secondary POM generated by photooxidation of toluene using a continuous-flow reactor and an 8 cubic meter indoor smog chamber was collected, and then extracted with acetonitrile. Eight phenolic compounds were identified in the extracts by a gas chromatograph coupled with a mass spectrometer, and their compound-specific stable carbon isotope ratios were determined by a gas chromatograph coupled with a combustion furnace followed by an isotope ratio mass spectrometer. The majority of the products, including methylnitrophenols and methylnitrocatechols, were isotopically depleted by 5 to 6 permil compared to the initial isotope ratio for toluene, whereas the isotope ratio for 4_nitrophenol remained the same as the initial isotope ratio for toluene. Based on the reaction mechanisms postulated in literature, stable carbon isotope ratios of these produc...

Irei, Satoshi; Huang, Lin; Auld, Janeen; Collin, Fabrice; Hastie, Donald

2014-01-01T23:59:59.000Z

134

Arid site characterization and technology assessment: Volatile Organic Compounds-Arid Integrated Demonstration  

SciTech Connect

The US Department of Energy`s (DOE`s) Volatile Organic Compounds-Arid Integrated Demonstration (VOC-Arid ID) program was initiated in March 1991 to evaluate technologies for all phases of remediation of VOCs in soils and groundwater at DOE arid/semiarid sites. The primary site for field demonstrations under the VOC-Arid ID program is the Hanford Site. The purpose of this report is to describe (1) the bases for technologies currently under evaluation in the VOC-Arid ID program; (2) the types of subsurface contamination at DOE arid/semiarid sites; and (3) the areas of potential common technology interests based on perceived technology needs at other DOE sites. This report was compiled by Pacific Northwest Laboratory in response to DOE`s Office of Technology Development`s mission to carry out an aggressive program to accelerate the development and implementation of new and existing technologies to meet a 30-year goal set by DOE in June 1989 to clean up all of its sites and to bring all sites into compliance with current and future environmental regulations. A key component of this program is the development of technologies that are better, faster, safer, and cheaper than those technologies currently available. Included in this report are an evaluation of technologies currently (fiscal year 1993) being pursued at the Hanford Site under the auspices of the VOC-Arid ID program, an assessment of subsurface contaminants at arid/semiarid sites, a summarization of technologies under consideration at other DOE sites, a discussion of areas of potential common technology interests, and the conclusions. Also included are a summary of the extent of contamination at the DOE arid/semiarid sites under consideration and a bibliography of source documents from which this report was prepared.

Riley, R.G.

1993-06-01T23:59:59.000Z

135

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS: THE NEW X-WAND HVOC SCREENING DEVICE  

SciTech Connect

Western Research Institute (WRI) has developed new methodology and a test kit to screen soil or water samples for halogenated volatile organic compounds (HVOCs) in the field. The technology has been designated the X-Wand{trademark} screening tool. The new device uses a heated diode sensor that is commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. This sensor is selective to halogens. It does not respond to volatile aromatic hydrocarbons, such as those in gasoline, and it is not affected by high humidity. In the current work, the heated diode leak detectors were modified further to provide units with rapid response and enhanced sensitivity. The limit of detection for trichloroethylene TCE in air is 0.1 mg/m{sup 3} (S/N = 2). The response to other HVOCS relative to TCE is similar. Variability between sensors and changes in a particular sensor over time can be compensated for by normalizing sensor readings to a maximum sensor reading at 1,000 mg/m{sup 3} TCE. The soil TCE screening method was expanded to include application to water samples. Assuming complete vaporization, the detection limit for TCE in soil is about 1 ug/kg (ppb) for a 25-g sample in an 8-oz jar. The detection limit for TCE in water is about 1 ug/L (ppb) for a 25-mL sample in an 8-oz jar. This is comparable to quantitation limits of EPA GC/MS laboratory methods. A draft ASTM method for screening TCE contaminated soils using a heated diode sensor was successfully submitted for concurrent main committee and subcommittee balloting in ASTM Committee D 34 on Waste Management. The method was approved as ASTM D 7203-05, Standard Test Method for Screening Trichloroethylene (TCE)-Contaminated Soil Using a Heated Diode Sensor.

John F. Schabron; Susan S. Sorini; Joseph F. Rovani Jr

2006-03-01T23:59:59.000Z

136

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network (OSTI)

mixing ratios and vertical wind speed plotted as a functionPanel: De-trended vertical wind speed (blue) and toluene (between toluene and vertical wind speed. Dashed curve

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

137

Observations of nonmethane organic compounds during ARCTAS - Part 1: Biomass burning emissions and plume enhancements  

E-Print Network (OSTI)

TOGA WAS Isobutane WAS Propane WAS Ethane TOGA WAS ButaneButane i-Butane Propene Propane Ethyne Ethene Ethane globallight alkanes against propane determined using the WAS data,

2011-01-01T23:59:59.000Z

138

Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units  

E-Print Network (OSTI)

Urea Formaldehyde Foam Insulation (UFFI), Consumer Product1972 urea formaldehyde foam insulation (UFFI) caused health

Parthasarathy, Srinandini

2011-01-01T23:59:59.000Z

139

Observations of nonmethane organic compounds during ARCTAS - Part 1: Biomass burning emissions and plume enhancements  

E-Print Network (OSTI)

from smoldering combustion of biomass measured by open-pathorganic species from biomass combustion, J. Geophys. Res. ,Biomass Burning Plume Origin Plume Age, Days a Modified Combustion

2011-01-01T23:59:59.000Z

140

Investigation of Nitro-Organic Compounds in Diesel Engine Exhaust: Final Report, February 2007 - April 2008  

SciTech Connect

The National Renewable Energy Laboratory upgraded its ReFUEL engine and vehicle testing facility to speciate unregulated gas-phase emissions. To complement this capability, the laboratory contracted with the Colorado School of Mines (CSM) to study the effects of soy biodiesel fuel and a diesel particle filter (DPF) on emissions of polycyclic aromatic hydrocarbons (PAH) and nitro-polycyclic aromatic hydrocarbons (NPAH). CSM developed procedures to sample diesel particulate matter (PM) emissions from raw and diluted exhaust, with and without a DPF. They also developed improved procedures for extracting PAH and NPAH from the PM and quantifying them with a gas chromatograph-electron monochromator mass spectrometer. The study found the DPF generally reduced PAH emissions by 1 to 3 orders of magnitude. PAH conversion was lowest for B100, suggesting that PAHs were forming in the DPF. Orders of magnitude reductions were also found for NPAH emissions exiting the DPF.

Dane, J.; Voorhees, K. J.

2010-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Comparing removal of trace organic compounds and assimilable organic carbon (AOC) at advanced and traditional water treatment plants  

Science Journals Connector (OSTI)

Stability of drinking water can be indicated by the assimilable organic carbon (AOC). This AOC value represents the regrowth capacity of microorganisms...254, and AOC) from water, experimental results indicate th...

Jie-Chung Lou; Chung-Yi Lin; Jia-Yun Han…

2012-06-01T23:59:59.000Z

142

Electricity Production from Anaerobic Digestion of Household Organic Waste in Ontario: Techno-Economic and GHG Emission Analyses  

Science Journals Connector (OSTI)

Electricity Production from Anaerobic Digestion of Household Organic Waste in Ontario: Techno-Economic and GHG Emission Analyses ... The life cycle greenhouse gas (GHG) emissions and economics of electricity generation through anaerobic digestion (AD) of household source-separated organic waste (HSSOW) are investigated within the FiT program. ... AD can potentially provide considerable GHG emission reductions (up to 1 t CO2eq/t HSSOW) at relatively low to moderate cost (-$35 to 160/t CO2eq) by displacing fossil electricity and preventing the emission of landfill gas. ...

David Sanscartier; Heather L. MacLean; Bradley Saville

2011-12-14T23:59:59.000Z

143

Isotopic constraints on the sources and associations of organic compounds in marine sediments  

E-Print Network (OSTI)

To provide a new perspective on the fate of both natural organic matter and hydrophobic organic contaminants (HOCs) in marine sediments, we have investigated the relationship between radiocarbon (14C) age and the different ...

White, Helen K

2006-01-01T23:59:59.000Z

144

Development of efficiency-enhanced cogeneration system utilizing high-temperature exhaust-gas from a regenerative thermal oxidizer for waste volatile-organic-compound gases  

Science Journals Connector (OSTI)

We have developed a gas-turbine cogeneration system that makes effective use of the calorific value of the volatile organic compound (VOC) gases exhausted during production processes at a manufacturing plant. The system utilizes the high-temperature exhaust-gas from the regenerative thermal oxidizer (RTO) which is used for incinerating VOC gases. The high-temperature exhaust gas is employed to resuperheat the steam injected into the gasturbine. The steam-injection temperature raised in this way increases the heat input, resulting in the improved efficiency of the gas-turbine. Based on the actual operation of the system, we obtained the following results: • Operation with the steam-injection temperature at 300 °C (45 °C resuperheated from 255 °C) increased the efficiency of the gasturbine by 0.7%. • The system can enhance the efficiency by 1.3% when the steam-injection temperature is elevated to 340 °C (85 °C resuperheated). In this case, up to 6.6 million yen of the total energy cost and 400 tons of carbon dioxide (CO2) emissions can be reduced annually. • A gas-turbine cogeneration and RTO system can reduce energy consumption by 23% and CO2 emission by 30.1% at the plant.

Masaaki Bannai; Akira Houkabe; Masahiko Furukawa; Takao Kashiwagi; Atsushi Akisawa; Takuya Yoshida; Hiroyuki Yamada

2006-01-01T23:59:59.000Z

145

Carbon isotope ratios of organic compound fractions in oceanic suspended particles  

E-Print Network (OSTI)

Radiocarbon evidence of fossil-carbon cycling in sediments1968), Metabolic fractionation of carbon isotopes in marineof particulate organic carbon using bomb 14 C, Nature,

Hwang, Jeomshik; Druffel, Ellen R. M

2006-01-01T23:59:59.000Z

146

Predicted change in global secondary organic aerosol concentrations in response to future climate, emissions, and land use change  

E-Print Network (OSTI)

The sensitivity of secondary organic aerosol (SOA) concentration to changes in climate and emissions is investigated using a coupled global atmosphere-land model driven by the year 2100 IPCC A1B scenario predictions. The ...

Heald, C. L.; Henze, D. K.; Horowitz, L. W.; Feddema, Johannes J.; Lamarque, J. F.; Guenther, A.; Hess, P. G.; Vitt, F.; Seinfeld, J. H.; Goldstein, A. H.; Fung, I.

2008-03-01T23:59:59.000Z

147

Emissions of unintentional persistent organic pollutants from open burning of municipal solid waste from developing countries  

Science Journals Connector (OSTI)

Open burning of waste is the most significant source of polychlorinated dibenzo-para-dioxins and dibenzofurans (PCDD/PCDF) in many national inventories prepared pursuant to the Stockholm Convention on Persistent Organic Pollutants. This is particularly true for developing countries. Emission factors for \\{POPs\\} such as PCDD/PCDF, dioxin-like polychlorinated biphenyls (dl-PCB) and penta- and hexachlorobenzenes (PeCBz/HCB) from open burning of municipal solid waste in China and Mexico are reported herein. Six different waste sources were studied varying from urban-industrial to semi-urban to rural. For PCDD/PCDF, the emission factors to air ranged from 3.0 to 650 ng TEQ kg?1 waste and for dl-PCB from 0.092 to 54 ng TEQ kg?1 waste. Emission factors for PeCBz (17–1200 ng kg?1 waste) and HCB (24–1300 ng kg?1 waste) spanned a wide but similar range. Within the datasets there is no indication of significant waste composition effect on emission factor with the exception of significantly higher Mexico rural samples.

Tingting Zhang; Heidelore Fiedler; Gang Yu; Gustavo Solorzano Ochoa; William F. Carroll Jr.; Brian K. Gullett; Stellan Marklund; Abderrahmane Touati

2011-01-01T23:59:59.000Z

148

Supplemental Information : Secondary Organic Aerosol Production from Modern Diesel Engine Emissions, Shar Samy and1 Barbara Zielinska2  

E-Print Network (OSTI)

Supplemental Information : Secondary Organic Aerosol Production from Modern Diesel Engine Emissions emissions. For more detail on compositional and toxicity changes produced from further29 diesel engine use, including: engine age or total engine lifetime operation,23 differences in the initial in-chamber toluene

Meskhidze, Nicholas

149

The effect of marine isoprene emissions on secondary organic aerosol and ozone formation in the coastal United States  

E-Print Network (OSTI)

The effect of marine isoprene emissions on secondary organic aerosol and ozone formation) in the coastal areas of the continental United States is studied using the U.S. Environmental Protection Agency regional-scale Community Multiscale Air Quality (CMAQ) modeling system. Marine isoprene emission rates

Zhang, Yang

150

Microbial Electrosynthesis: Feeding Microbes Electricity To Convert Carbon Dioxide and Water to Multicarbon Extracellular Organic Compounds  

Science Journals Connector (OSTI)

...Microbiology, University of Massachusetts, Amherst, Massachusetts, USA Citation Nevin, K...attractive strategy to convert solar energy that is harvested intermittently...photosynthesis that might convert solar energy to organic products...

Kelly P. Nevin; Trevor L. Woodard; Ashley E. Franks; Zarath M. Summers; Derek R. Lovley

2010-06-01T23:59:59.000Z

151

Microbial Electrosynthesis: Feeding Microbes Electricity To Convert Carbon Dioxide and Water to Multicarbon Extracellular Organic Compounds  

Science Journals Connector (OSTI)

...photosynthesis that might convert solar energy to organic products more effectively...nature of renewable sources of energy, most notably solar and wind, is leading to a search for strategies to capture the electrical energy produced from these sources in...

Kelly P. Nevin; Trevor L. Woodard; Ashley E. Franks; Zarath M. Summers; Derek R. Lovley

2010-06-01T23:59:59.000Z

152

Removal of organic and inorganic compounds from landfill leachate using reverse osmosis  

Science Journals Connector (OSTI)

The main objective of this work was to evaluate an effectiveness of removing organic and inorganic pollutants from landfill leachate in a long-term reverse osmosis (RO) study. Investigations were carried out...4 ...

I. A. Talalaj

2014-08-01T23:59:59.000Z

153

Radionuclides, Trace Metals, and Organic Compounds in Shells of Native Freshwater Mussels Along the Hanford Reach of the Columbia River: 6000 Years Before Present to Current Times  

SciTech Connect

This report documents concentrations of radionuclides, trace metals, and semivolatile organic compounds measured in shell samples of the western pearl shell mussel collected along the Hanford Reach of the Columbia River.

B. L. Tiller; T. E. Marceau

2006-01-25T23:59:59.000Z

154

Metal organic chemical vapor deposition of 111-v compounds on silicon  

DOE Patents (OSTI)

Expitaxial composite comprising thin films of a Group III-V compound semiconductor such as gallium arsenide (GaAs) or gallium aluminum arsenide (GaAlAs) on single crystal silicon substrates are disclosed. Also disclosed is a process for manufacturing, by chemical deposition from the vapor phase, epitaxial composites as above described, and to semiconductor devices based on such epitaxial composites. The composites have particular utility for use in making light sensitive solid state solar cells.

Vernon, Stanley M. (Wellesley, MA)

1986-01-01T23:59:59.000Z

155

Air emissions inventory for the Idaho National Engineering Laboratory -- 1995 emissions report  

SciTech Connect

This report presents the 1995 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The INEL Air Emission Inventory documents sources and emissions of non-radionuclide pollutants from operations at the INEL. The report describes the emission inventory process and all of the sources at the INEL, and provides non-radionuclide emissions estimates for stationary sources. The air contaminants reported include nitrogen oxides, sulfur oxides, carbon monoxide, volatile organic compounds, particulates, and hazardous air pollutants (HAPs).

NONE

1996-06-01T23:59:59.000Z

156

The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994  

SciTech Connect

In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.

Adams, R.D.

1994-01-01T23:59:59.000Z

157

Correlation between gas-phase and solution-phase reactivities of hydroxyl radicals toward saturated organic compounds  

SciTech Connect

The gas-phase and aqueous-solution-phase reactivities of hydroxyl radicals with a wide variety of organic compounds are compared. When kinetic data are available for the same reaction occurring in both phases, this comparison provides useful information about the reaction mechanism. Through this comparison the authors can demonstrate a linear correlation between the gas/solution-phase OH reactivities for numerous saturated organic compounds. This empirical relationship can be used together with mechanistic information to estimate the OH reactivity in one phase from the measured rate constant in the other. In order to develop and extend the correlation, they have used the flash photolysis resonance fluorescence technique to measure rate constants for the gas-phase reactions of OH radicals with methanol-d/sub 4/, ethanol-d/sub 6/, 2-chloroethanol, 2,2,2-trichloroethanol, 2,2,2-trifluoroethanol, acetone-d/sub 6/, 1,1,1-trifluoroacetone, and 1,2-butylene oxide at 298 K. These results are reported herein.

Wallington, T.J.; Dagaut, P.; Kurylo, M.J.

1988-08-25T23:59:59.000Z

158

Emissions  

Office of Scientific and Technical Information (OSTI)

the extra emissions that are generated from manufacturing the material used to make CNG tanks); they can amount tc more than 2% of the emissions from 32 the fuel production and...

159

Our planet is becoming increasingly polluted with inorganic and organic compounds, primarily as a  

E-Print Network (OSTI)

produced or expected to be present in organ- isms). Many of them are toxic and/or carcinogenic. Sources cleanup in the US, and $25­50 billion per year worldwide (Glass 1999; Tsao 2003). Most remediation that use plants to remove, reduce, degrade, or immobilize environmental pollutants from soil and water

160

"The disintegration of organic compounds by microorganisms is accompanied by the liberation of  

E-Print Network (OSTI)

that of the better- known abiotic hydrogen- and methanol-driven fuel cells. For example, abiotic fuel cells require in a cost-effective manner. Over the past 40 years it has been suggested that microbial fuel cells might convert organic matter into electricity in devices known as microbial fuel cells. However, interest

Lovley, Derek

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Ozone-forming potential of a series of oxygenated organic compounds  

SciTech Connect

An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

162

Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers  

Science Journals Connector (OSTI)

Vapour pressures of methyl propyl, isopropyl methyl, butyl methyl, ethyl propyl, t-butyl methyl, dipropyl, di-isopropyl, di-t-butyl, and decyl methyl ethers were measured at pressures up to 205 kPa. The measured values were fitted by Antoine and by Chebyshev equations, values already published from this laboratory for three aromatic ethers were recomputed uniformly with the present results, and published values for four additional compounds were incorporated in a scheme for correlation of the vapour pressures of ethers. Estimates were made of the vapour pressures of 10 other ethers. Between 5 and 200 kPa the vapour pressures of ethers may be represented by a single equation in which carbon number or an effective carbon number is a parameter. Chebyshev equations are given for interpolation between the upper bounds of the measurements and the critical pressures of 11 ethers for which this property has been previously determined.

D Ambrose; J.H Ellender; C.H.S Sprake; R Townsend

1976-01-01T23:59:59.000Z

163

T E C H N I C A L A D V A N C E Soil organic carbon dust emission: an omitted global  

E-Print Network (OSTI)

T E C H N I C A L A D V A N C E Soil organic carbon dust emission: an omitted global source emission, soil organic carbon Received 16 April 2013 and accepted 21 May 2013 Introduction Uncertainty, Gunnedah, NSW 2380, Australia Abstract Soil erosion redistributes soil organic carbon (SOC) within

164

Single-reactor process for producing liquid-phase organic compounds from biomass  

DOE Patents (OSTI)

Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

Dumesic, James A. (Verona, WI); Simonetti, Dante A. (Middleton, WI); Kunkes, Edward L. (Madison, WI)

2011-12-13T23:59:59.000Z

165

Photocatalytic and chemical oxidation of organic compounds in supercritical carbon dioxide. Progress report for FY97  

SciTech Connect

'The background for the project is briefly reviewed and the work done during the nine months since funding was received is documented. Work began in January, 1997. A post doctoral fellow joined the team in April. The major activities completed this fiscal year were: staffing the project, design of the experimental system, procurement of components, assembly of the system. preparation of the Safe Operating Procedure and ES and H compliance, pressure testing, establishing data collection and storage methodology, and catalyst preparation. Objective The objective of the project is to develop new chemistry for the removal of organic contaminants from supercritical carbon dioxide. This has application in processes used for continuous cleaning and extraction of parts and waste materials. A secondary objective is to increase the fundamental understanding of photocatalytic chemistry. Cleaning and extraction using supercritical carbon dioxide (scCO{sub 2}) can be applied to the solution of a wide range of environmental and pollution prevention problems in the DOE complex. Work is being done that explores scCO{sub 2} in applications ranging from cleaning contaminated soil to cleaning components constructed from plutonium. The rationale for use of scCO{sub 2} are based on the benign nature, availability and low cost, attractive solvent properties, and energy efficient separation of the extracted solute from the solvent by moderate temperature or pressure changes. To date, R and D has focussed on the methods and applications of the extraction steps of the process. Little has been done that addresses methods to polish the scCO{sub 2} for recycle in the cleaning or extraction operations. In many applications it will be desirable to reduce the level of contamination from that which would occur at steady state operation of a process. This proposal addresses chemistry to achieve that. This would be an alternative to removing a fraction of the contaminated scCO{sub 2} for disposal and using makeup scCO{sub 2}. A chemical polishing operation can reduce the release of CO{sub 2} from the process. It can also reduce the consumption of reagents that may be used in the process to enhance extraction and cleaning. A polishing operation will also reduce or avoid formation of an additional waste stream. Photocatalytic and other photochemical oxidation chemistry have not been investigated in scCO{sub 2}. The large base of information for these reactions in water, organic solvents, or air suggest that the chemistry will work in carbon dioxide. There are compelling reasons to believe that the properties of scCO{sub 2} should increase the performance of photocatalytic chemistry over that found in more conventional fluid phases.'

Blake, D.M.; Bryant, D.L.; Reinsch, V.

1997-09-30T23:59:59.000Z

166

Behavior of partially miscible organic compounds in simulated ground water systems  

SciTech Connect

Serious ground water contamination problems result from leaks or spills of organic liquids which are partially miscible in water. Two important categories of these liquids include low molecular weight chlorinated solvents and gasoline. 1,1,1-Trichloroethane (TCA) abiotically degrades in water forming approximately 17-25% 1,1-dichloroethene (1,1-DCE) via an elimination reaction. Brominated analogs of TCA hydrolyze 11-13 times faster than TCA. As the number of bromines increase, the percent of elimination products increases. These geminal trihalides degrade by a unimolecular mechanism (E1/SN1). The rate coefficient for TCA degradation in buffered water at elevated temperature is approximately six times greater than hydrolysis of 1-chloropropane (SN2 mechanism) and more than 100 times greater than 1,1-dichloroethane. In the presence of sodium thiosulfate, the 1-chloropropane degradation rate increased by more than a factor of 100, 1,1-dichloroethane rate by 22 and TCA degradation by approximately two. The range of concentrations for major components of gasoline which partition into water was determined for 65 gasoline samples. Benzene concentrations in the water extracts ranged from 12.3-130 mg/l and toluene concentrations ranged from 23-185 mg/l. Fuel/water partition coefficients of seven major aromatic constituents were measured for 31 gasoline types and showed a standard deviation of 10-30%. These coefficients were highly correlated with the pure component solubilities. Chemometric techniques were applied to 20 peaks measured in the aqueous extracts of the 65 gasolines. Bivariate plots and principal component analyses show selected brands have distinguishing equilibrium concentrations, but complete separation of brands was not observed.

Cline, P.V.

1988-01-01T23:59:59.000Z

167

Polybenzimidazole compounds  

DOE Patents (OSTI)

A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2010-08-10T23:59:59.000Z

168

VOLUME 77, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 4 NOVEMBER 1996 Incommensurate Intermodulation of an Organic Intergrowth Compound  

E-Print Network (OSTI)

Intermodulation of an Organic Intergrowth Compound Observed by Neutron Scattering R. Lefort,1 J. Etrillard,1 B occurs around 160 K. The neutron scattering experiments were performed at

Boyer, Edmond

169

Occurrence and Potential Human-Health Relevance of Volatile Organic Compounds in Drinking Water from Domestic Wells in the United States  

E-Print Network (OSTI)

Occurrence and Potential Human-Health Relevance of Volatile Organic Compounds in Drinking Water from Domestic Wells in the United States *Barbara L. Rowe1 , Patricia L. Toccalino2 , Michael J. Moran1 , John S. Zogorski1 , Curtis V. Price1 1 United States Geological Survey, Road, Rapid City, SD 57702 USA

170

Effects of organic silicon compounds as additives on charge–discharge cycling efficiencies of lithium in nonaqueous electrolytes for rechargeable lithium cells  

Science Journals Connector (OSTI)

Abstract Influence of mixing organic silicon compounds into 1 M (M: mol L?1) LiPF6-ethylene carbonate (EC)/ethylmethyl carbonate (EMC) (mixing volume ratio = 3:7) mixed solvent electrolytes on charge–discharge cycling efficiencies of lithium metal negative electrodes is examined. As organic silicon compounds, polyether-modified siloxanes with polyethylene oxide chains, chlorotrimethylsilane, tetraethoxysilane, cis-tetra [isobutyl (dimethylsiloxy)] cyclotetrasiloxane and cage-type silsesquioxane are investigated. Charge–discharge cycling tests of lithium are galvanostatically carried out using stainless steel working electrodes. Charge–discharge cycling efficiencies of lithium tend to improve by mixing organic silicon compounds. A cage-type silsesquioxane, octaphenyloctasilsesquioxane (Ph8T8) exhibits the highest cycling efficiency of approximately 80% with small mixing amount of 0.02 M Ph8T8. Mechanism of enhancement of lithium cycling efficiencies by mixing organic silicon compounds is considered to be due to the suppression of excess reduction of LiPF6-EC/EMC by lithium and the growth of surface film on lithium.

Ryota Yanagisawa; Hisayuki Endo; Masafumi Unno; Hideyuki Morimoto; Shin-ichi Tobishima

2014-01-01T23:59:59.000Z

171

The conversion of solar energy to the chemical energy of organic compounds is a complex process that includes electron transport and  

E-Print Network (OSTI)

The conversion of solar energy to the chemical energy of organic compounds is a complex process would cause severe problems if special mechanisms did not protect the photosynthetic system from energy or photon units. Irradiance is the amount of energy that falls on a flat sensor of known area per

Ehleringer, Jim

172

Dictionary of Organic Compounds  

Science Journals Connector (OSTI)

... an illustration of the considerable increase in the number of entries, the section from “Carene” to “Carvoxime” has grown from 3Ł to 7 pages. In a work ...

JOHN READ

1943-11-20T23:59:59.000Z

173

Unspeciated organic emissions from combustion sources and their influence on the secondary organic aerosol budget in the United States  

Science Journals Connector (OSTI)

...vehicles, 3 on-road diesel vehicles, and biomass...spanned a wide range of engine and emissions control...gasoline, on-road diesel, and biomass burning...mass formation. In general, more SOA formation...injection, turbocharged diesel engine. This tractor had...

Shantanu H. Jathar; Timothy D. Gordon; Christopher J. Hennigan; Havala O. T. Pye; George Pouliot; Peter J. Adams; Neil M. Donahue; Allen L. Robinson

2014-01-01T23:59:59.000Z

174

ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT  

E-Print Network (OSTI)

Composite Wood Products, California Air Resources Board.in Air and Emission Rates from Wood Products Using a LargeComposite Wood Products, California Air Resources Board.

Maddalena, Randy L.

2008-01-01T23:59:59.000Z

175

The Effect of Compound Structure on the Elemental Responses in Gas Chromatography-Microwave Induced Plasma Atomic Emission Spectrometry  

Science Journals Connector (OSTI)

......Since microwave induced plasma atomic emission spectrometry...pro totype Model SG-2 atmospheric pressure GC-MIP which...The flow of the He plasma supporting gas was maintained...output frequency: 2450 30 MHz output power: 0-200...by J&D Instruments Plasma discharge tube length......

Huang Yieru; Ou Qingyu; Yu Weile

1990-11-01T23:59:59.000Z

176

ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT  

E-Print Network (OSTI)

Urea Formaldehyde Foam Insulation (UFFI), Consumer Productdiisobutyrate Urea Formaldehyde Foam Insulation orexpandable foam insulation Volatile Organic Chemical TMPD-

Maddalena, Randy L.

2008-01-01T23:59:59.000Z

177

High-precision optical measurements of 13C/12C isotope ratios in organic compounds at natural abundance  

Science Journals Connector (OSTI)

High-precision...compounds at natural abundance...catalytic combustor, and an isotopic...challenge to the high-cost and...carbon dioxide gas, using...temperature and pressure from which...of carbon gases . Spectrochim...2008 ) High precision...compounds at natural abundance...catalytic combustor, and...

Richard N. Zare; Douglas S. Kuramoto; Christa Haase; Sze M. Tan; Eric R. Crosson; Nabil M. R. Saad

2009-01-01T23:59:59.000Z

178

Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025  

Energy.gov (U.S. Department of Energy (DOE))

The Environmental Protection Agency finalized Tier 3 emission standards in a rule issued in March 2014. One effect of the rule is a decrease in the combined amount of non-methane organic gases ...

179

Mapping isoprene emissions over North America using formaldehyde column observations from space  

E-Print Network (OSTI)

Mapping isoprene emissions over North America using formaldehyde column observations from space. [1] We present a methodology for deriving emissions of volatile organic compounds (VOC) using space to local VOC emissions, with a spatial smearing that increases with the VOC lifetime. Isoprene

Chance, Kelly

180

MEASUREMENT OF VOC EMISSIONS FROM WOOD REMEDIAL TREATMENT: CHAMBER TESTS AND FIELD EXPERIMENTS  

E-Print Network (OSTI)

products on indoor air quality. The emissions of two wood remedial treatment products (water in real conditions during a roof renovation work in an old building. A petroleum-based solvent product of volatile organic compound (VOC) emissions from building products. Simple models can be applied to emission

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

COLLOIDAL ELECTROLUMINESCENCE: NOVEL ROUTES TO CONTROLLED EMISSION OF ORGANIC LIGHT EMITTING DIODE DEVICES.  

E-Print Network (OSTI)

??In recent years the importance of the organic light emitting diode (OLED) has grown immensely, and the past two decades have seen ongoing and exhaustive… (more)

Huebner, Christopher

2009-01-01T23:59:59.000Z

182

VOCs and formaldehyde emissions from cleaning products and air Ccilia Solal1,*  

E-Print Network (OSTI)

VOCs and formaldehyde emissions from cleaning products and air fresheners CĂ©cilia Solal1: air fresheners, glass cleaners, furniture polishes, toilet products, carpet and floor cleaning Formaldehyde, Volatile organic compounds, Household products, Exposure INTRODUCTION Most indoor air pollutants

Paris-Sud XI, Université de

183

The development of a sensitive method to study volatile organic compounds in gaseous emissions of lung cancer cell lines  

E-Print Network (OSTI)

HCO3 producing excess H+ ions in the medium and therefore a fall in pH. This is seen as a color change. 10 When the confluence has reached 90% the cells are ready to be sub-cultured (Fig 2). 50 % cells in media Thawed... patients with no prior treatment for lung cancer. We have used an alternative method for the spectrometric analysis and quantitation of the selected chemical markers. The pre-concentration method involved a Purge and Trap unit with a thermal desorber...

Maroly, Anupam

2005-08-29T23:59:59.000Z

184

Flux Measurements of Volatile Organic Compounds from an Urban Tower Platform in Houston, Texas: Trends and Tracers  

E-Print Network (OSTI)

and traffic counts except during variable working hours. To assign measured fluxes to local sources, we tested a bulk flux footprint model (Kormann and Meixner model) designed for uniform emission surface areas in this urban, heterogeneous landscape. Tracer...

Hale, Martin C

2014-05-08T23:59:59.000Z

185

Electric Turbo Compounding Technology Update | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Compounding Technology Update Electric Turbo Compounding Technology Update Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

186

Evaluation of an operational method for the estimation of emissions of nitrogen compounds for a group of farms  

Science Journals Connector (OSTI)

The aim of this article is to evaluate a practical method for estimating nitrogen emissions on the scale of a group of farms, to be used in Life Cycle Assessment (LCA). The method rests on the estimation of nitrogen inputs and outputs to calculate the surplus of the annual nitrogen balance on the scale of a farm. The different gaseous nitrogen losses (NH3, NO, N2O, N3) are then estimated for each livestock or cropping system. The leaching losses in the form of NO3 are assumed to correspond to the surplus of the apparent nitrogen balance to which are added the atmospheric depositions, minus the gaseous losses. The feasibility of this method was studied on 24 farms in the Naizin catchment area (Brittany, France). An analysis of the sensitivity of NO3 estimates to different parameters used to calculate gaseous losses was carried out. Lastly the robustness of the NO3 estimates was examined by comparing them with measurements of NO3 collected within this catchment area.

Sylvain Payraudeau; Hayo M.G. Van Der Werf; Francoise Vertes

2006-01-01T23:59:59.000Z

187

Using portable Raman spectrometers for the identification of organic compounds at low temperatures and high altitudes: exobiological applications  

Science Journals Connector (OSTI)

...orbiters carried out infrared thermal mapping of the planet (Kieffer...Poulet et al. 2007). The thermal emission imaging system on...7.4V internal lithium ion battery, allowing practically about...and G. Neugebau1972Infrared thermal experiment-Viking Mars orbiterIcarus...

2010-01-01T23:59:59.000Z

188

Fatty Acids from Lipids of Marine Organisms: Molecular Biodiversity, Roles as Biomarkers, Biologically Active Compounds, and Economical Aspects  

Science Journals Connector (OSTI)

Because of their characteristic living environments, marine organisms produce a variety of lipids. Fatty acids constitute the essential part of triglycerides and wax esters, which are the major components ...

Jean-Pascal Bergé; Gilles Barnathan

2005-01-01T23:59:59.000Z

189

A study on full color organic light emitting diodes with blue common layer under the patterned emission layer  

Science Journals Connector (OSTI)

Abstract Color patterning steps for red, green, and blue emission layers (EMLs) are crucial for the production of full color organic light-emitting diodes (OLEDs). The most common method to form individually patterned \\{EMLs\\} is to use a shadow mask as the key component for patterning. However, most pixel defects are caused by such kinds of patterning steps. Therefore, skipping certain color patterning steps could significantly improve the production yield during the fine metal masking process in the OLED fabrication. A representative example of such approach is the top blue common layer (TBCL) structure with a non-patterned BCL on top of both green and red EMLs. However, this structure could cause blue color mixing in green or red devices. To prevent this effect, we propose a newly devised bottom BCL (BBCL) structure with the BCL that is totally separated from both green and red EMLs. In particular, we utilized 1,4,5,8,9,11-hexaazatriphenylene-hexacarbonitrile interlayer (7 nm) between the underlying BCL and the hole injection layer to completely extinguish blue emission. As a result, both green and red devices with the BBCL structure showed relatively better efficiencies compared to those with the TBCL structure without any color mixing.

Hee Young Shin; Min Chul Suh

2014-01-01T23:59:59.000Z

190

Vehicle Emission Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vehicle Emission Basics Vehicle Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of vehicles powered by internal combustion engines, which include gasoline, diesel, natural gas, and propane vehicles. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs) particulate matter (PM) A number of factors determine the composition of emissions, including the vehicle's fuel, the engine's technology, the vehicle's exhaust aftertreatment system, and how the vehicle operates. Emissions are also produced by fuel evaporation during fueling or even when vehicles are

191

Evaluate Greenhouse Gas Emissions Profile  

Energy.gov (U.S. Department of Energy (DOE))

Evaluating a Federal agency's greenhouse gas (GHG) emissions profile means getting a solid understanding of the organization's largest emission categories, largest emission sources, and its potential for improvement.

192

Mechanisms of synfuel degradation 1. Effects of organic nitrogen compounds on the stability of a shale derived diesel fuel  

SciTech Connect

A reliable accelerated fuel stability test regimen has been developed and applied to the study of the storage stability of a shale derived diesel fuel marine (DFM). The results of a survey of nitrogen compounds as dopants in a stable shale DFM base fuel indicate that some pyrroles and indoles may play significant roles in storage stability. A complete stability test matrix has been developed for the temperatures of 43, 65 and 80/sup 0/C, for time periods between 4 and 179 days, and for a ten-fold concentration range of a model dopant, 2,5-dimethylpyrrole (DMP). Stability was defined by the amount of total insoluble material (filterable sediment and adherent gum) produced after stress, and also by the amount of titratable peroxide present in the filtrates of stressed fuel samples. A very regular pattern for insolubles formation was found within the test matrix. Deposit formation rates exhibited a first-order dependence on DMP concentration, with an apparent activation energy of 11-12 kcal/mol. The sediment was found to contain 12% nitrogen and 18-20% oxygen irrespective of the stress conditions employed.

Cooney, J.V.; Beal, E.J.; Huzlett, R.N.

1984-01-01T23:59:59.000Z

193

A novel Whole Air Sample Profiler (WASP) for the quantification of volatile organic compounds in the boundary layer  

SciTech Connect

The emission and fate of reactive VOCs is of inherent interest to those studying chemical biosphere-atmosphere interactions. In-canopy VOC observations are obtainable using tower-based samplers, but the lack of suitable sampling systems for the full boundary 5 layer has limited the data characterizing the vertical structure of such gases above the canopy height and still in the boundary layer. This is the important region where many reactive VOCs are oxidized or otherwise removed. Here we describe an airborne sampling system designed to collect a vertical profile of air into a 3/800 OD tube 150m in length. The inlet ram air pressure is used to flow sampled air through the 10 tube, which results in a varying flow rate based on aircraft speed and altitude. Since aircraft velocity decreases during ascent, it is necessary to account for the variable flow rate into the tube. This is accomplished using a reference gas that is pulsed into the air stream so that the precise altitude of the collected air can be reconstructed post-collection. The pulsed injections are also used to determine any significant effect 15 from diffusion/mixing within the sampling tube, either during collection or subsequent extraction for gas analysis. This system has been successfully deployed, and we show some measured vertical profiles of isoprene and its oxidation products methacrolein and methyl vinyl ketone from a mixed canopy near Columbia, Missouri.

Mak, J. E.; Su, L.; Guenther, Alex B.; Karl, Thomas G.

2013-10-16T23:59:59.000Z

194

Versatile piezoelectric pulsed molecular beam source for gaseous compounds and organic molecules with femtomole accuracy for UHV and surface science applications  

SciTech Connect

This note describes the construction of a piezoelectric pulsed molecular beam source based upon a design presented in an earlier work [D. Proch and T. Trickl, Rev. Sci. Instrum. 60, 713 (1988)]. The design features significant modifications that permit the determination of the number of molecules in a beam pulse with an accuracy of 1x10{sup 11} molecules per pulse. The 21 cm long plunger-nozzle setup allows the molecules to be brought to any point of the UHV chamber with very high intensity. Furthermore, besides typical gaseous compounds, also smaller organic molecules with a vapor pressure higher than 0.1 mbar at room temperature may serve as feed material. This makes the new design suitable for various applications in chemical and surface science studies.

Schiesser, Alexander; Schaefer, Rolf [Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Technische Universitaet Darmstadt, Petersenstrasse 20, 64287 Darmstadt (Germany)

2009-08-15T23:59:59.000Z

195

Use of solid waste for chemical stabilization: Adsorption isotherms and {sup 13}C solid-state NMR study of hazardous organic compounds sorbed on coal fly ash  

SciTech Connect

Adsorption of hazardous organic compounds on the Dave Johnston plant fly ash is described. Fly ash from Dave Johnston and Laramie River power plants were characterized using elemental, x-ray, and {sup 29}Si NMR; the Dave Johnston (DJ) fly ash had higher quartz contents, while the Laramie River fly ash had more monomeric silicate anions. Adsorption data for hydroaromatics and chlorobenzenes indicate that the adsorption capacity of DJ coal fly ash is much less than that of activated carbon by a factor of >3000; but it is needed to confirm that solid-gas and solid-liquid equilibrium isotherms can indeed be compared. However, for pyridine, pentachlorophenol, naphthalene, and 1,1,2,2-tetrachloroethane, the DJ fly ash appears to adsorb these compounds nearly as well as activated carbon. {sup 13}C NMR was used to study the adsorption of hazardous org. cpds on coal fly ash; the nuclear spin relaxation times often were very long, resulting in long experimental times to obtain a spectrum. Using a jumbo probe, low concentrations of some hazardous org. cpds could be detected; for pentachlorophenol adsorbed onto fly ash, the chemical shift of the phenolic carbon was changed. Use of NMR to study the adsorption needs further study.

Netzel, D.A.; Lane, D.C.; Rovani, J.F.; Cox, J.D.; Clark, J.A.; Miknis, F.P.

1993-09-01T23:59:59.000Z

196

Comparative evaluation of several small mammal species as monitors of heavy metals, radionuclides, and selected organic compounds in the environment  

SciTech Connect

The primary purpose of this study was to evaluate which small mammal species are the best monitors of specific environmental contaminants. The evaluation is based on the published literature and on an analysis of small mammals trapped at several sites on the Oak Ridge National Laboratory (ORNL) Reservation in Oak Ridge, Tennessee. Studies on the uptake of heavy metals, radionuclides, and organic chemicals are reviewed in Chapter II to evaluate several small mammal species for their capacity to serve as sentinels for the presence, accumulation, and effects of various contaminants. Where several species were present at a site, a comparative evaluation was made and species are ranked for their capacity to serve as monitors of specific contaminants. Food chain accumulation and food habits of the species are used to establish a relationship with suitability as a biomonitor. Tissue-specific concentration factors were noted in order to establish target tissues. Life histories, habitat, and food habits are reviewed in order to make generalizations concerning the ability of similar taxa to serve as biomonitor. Finally, the usefulness of several small mammal species as monitors of three contaminants -- benzo(a)pyrene, mercury, and strontium-90 -- present on or near the ORNL facilities was investigated. 133 refs., 5 figs., 20 tabs.

Talmage, S.S. (Tennessee Univ., Knoxville, TN (USA) Oak Ridge National Lab., TN (USA)); Walton, B.T. (Oak Ridge National Lab., TN (USA))

1990-08-01T23:59:59.000Z

197

Organization  

NLE Websites -- All DOE Office Websites (Extended Search)

Organization Print Organization Print 2012-12 org chart A complete ALS organization chart (June 2013) is available in PDF. Appointed and elected members of advisory panels provide guidance to Berkeley Lab and ALS management in developing the ALS scientific and user programs. ALS Staff Photo staff photo thumb Click on the image to see a recent photo of ALS staff in front of the dome. The photo was taken on May 14, 2013. ALS Management and Advisory Team Steve Kevan, Deputy Division Director, Science Michael J. Banda, Deputy Division Director, Operations Robert W. Schoenlein, Senior Staff Scientist, Next Generation Light Source Initiative Janos Kirz, Scientific Advisor Paul Adams, Division Deputy for Biosciences ALS Scientific, Technical, and User Support Groups Accelerator Physics

198

Vehicle Technologies Office: Emission Control R&D  

NLE Websites -- All DOE Office Websites (Extended Search)

Emission Control R&D Emission Control R&D The Vehicle Technologies Office (VTO) supports research and development of aftertreatment technologies to control advanced combustion engine exhaust emissions. All engines that enter the vehicle market must comply with the Environmental Protection Agency's emissions regulations. Harmful pollutants in these emissions include: Carbon monoxide Nitrogen oxides Unburned hydrocarbons Volatile organic compounds (VOCs) Particulate matter The energy required for emission control often reduces vehicle fuel economy and increases vehicle cost. VTO's Emission Control R&D focuses on developing efficient, durable, low-cost emission control systems that complement new combustion strategies while minimizing efficiency losses. VTO often leverages the national laboratories' unique capabilities and facilities to conduct this research.

199

NETL: Emissions Characterization - Adv. Low-NOx Burner Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization of Fine Particulate Emissions using Subcritical Water Characterization of Fine Particulate Emissions using Subcritical Water As part of a Cooperative Agreement with DOE-NETL, the University of North Dakota Energy and Environmental Research Center (EERC) is developing advanced sampling and analysis methodologies for particulate matter that can be used for source apportionment and to assist in health studies. These techniques will be used to determine sources of fine particulate matter in rural states such as North Dakota. One of the primary activities of this effort is the development of a procedure using subcritical water to fractionate organics in air particulates, and test the toxicity of the fractionated organics using various tests. In contrast to inorganic aerosols, which are often well characterized, only ca. 15%–50% of the organic carbonaceous (OC) particulate mass has been characterized. The characterized compounds are almost exclusively nonpolar. The limited knowledge on OC fractions is due to the use of organic solvents which are able to extract only nonpolar or slightly polar organics. Subcritical water has not previously been used to fractionate OC from air particulates, but should have the ability to extract a broad range of polar to low-polarity OC, as well as to provide extracts in a solvent (water) which is directly useful for biological tests. Earlier studies have shown that compounds of different polarities, such as phenols, PAHs, and alkanes, can be sequentially extracted from a petroleum waste sludge by increases in subcritical water temperature.

200

Removal of organic compounds and trace metals from oil sands process-affected water using zero valent iron enhanced by petroleum coke  

Science Journals Connector (OSTI)

Abstract The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of \\{NAs\\} in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the \\{NAs\\} removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the \\{NAs\\} removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox® bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment.

Parastoo Pourrezaei; Alla Alpatova; Kambiz Khosravi; Przemys?aw Drzewicz; Yuan Chen; Pamela Chelme-Ayala; Mohamed Gamal El-Din

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Effects of emission layer doping on the spatial distribution of charge and host recombination rate density in organic light emitting devices: A numerical study  

SciTech Connect

Based on drift-diffusion theory, a numerical model of the doping of a single energy level trap in the emission layer of an organic light emitting device (OLED) was developed, and the effects of doping of this single energy level trap on the distribution of the charge density, the recombination rate density, and the electric field in single- and double-layer OLEDs were studied numerically. The results show that by doping the n-type (p-type) emission layer with single energy electron (hole) traps, the distribution of the recombination rate density can be tuned and shifted, which is useful for improvement of the device performance by reduced electrode quenching or for realization of desirable special functions, e.g., emission spectrum tuning in multiple dye-doped white OLEDs.

Li, Yanli; Zhou, Maoqing; Zheng, Tingcai; Yao, Bo [Institute of Microelectronics, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); Peng, Yingquan, E-mail: yqpeng@lzu.edu.cn [Institute of Microelectronics, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000 (China)

2013-12-28T23:59:59.000Z

202

Chemical Composition of Gas-Phase Organic Carbon Emissions from Motor Vehicles and Implications for Ozone Production  

E-Print Network (OSTI)

gasoline and diesel vehicles via two methods. First we use speciated measurements of exhaust emissions from and comprise 32 ± 2% of gasoline exhaust and 26 ± 1% of diesel exhaust by mass. We calculate and compare ozone production potentials of diesel exhaust, gasoline exhaust, and nontailpipe gasoline emissions. Per mass

Cohen, Ronald C.

203

Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions  

SciTech Connect

In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4{sup ?}-N,N{sup ?}-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N{sup ?})iridium(III) (Ir(2-phq){sub 3}) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2{sup ?}]picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m{sup 2}. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37) as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

Hua, Wang, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Du, Xiaogang [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China) [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Su, Wenming, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Zhang, Dongyu [Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China)] [Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China); Lin, Wenjing [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China) [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China)

2014-02-15T23:59:59.000Z

204

The impact of bark beetle infestations on monoterpene emissions and secondary organic aerosol formation in western North America  

E-Print Network (OSTI)

Over the last decade, extensive beetle outbreaks in western North America have destroyed over 100 000 km2 of forest throughout British Columbia and the western United States. Beetle infestations impact monoterpene emissions ...

Berg, A. R.

205

Speciated Engine-Out Organic Gas Emissions from a PFI-SI Engine Operating on Ethanol/Gasoline Mixtures  

E-Print Network (OSTI)

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the ...

Kar, Kenneth

206

Investigation of pure green-colour emission from inorganic-organic hybrid LEDs based on colloidal CdSe/ZnS quantum dots  

Science Journals Connector (OSTI)

We studied the operation characteristics of inorganic-organic hybrid light emitting devices (HLEDs) that have a green CdSe/ZnS quantum dot (QD) emitting layer (EML) and a 1,3,5-tris(N-phenylbenzimidazol-2-yl)-benzene (TPBi) hole blocking layer (HBL). A series of devices with a different thickness TPBi HBL all showed pure electroluminescence that is consistent with green photoluminescence of colloidal QDs without any colour contamination from organic layers. The best performance, which we attributed to more balanced charge carrier supply to a QD EML and efficient energy transfer from excitions in a TPBi layer to QDs, was observed from the device with a TPBi HBL of 20 nm thickness: the deep green emission with the luminous efficiency of 1.55 cd/A at standard video brightness (200 cd/m˛) and the luminance as large as ~1800 cd/m˛.

Nguyen Huu Tuan; Soonil Lee; Nguyen Nang Dinh

2013-01-01T23:59:59.000Z

207

The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust Emissions and Measurements of Trace gas and Aerosol properties.  

E-Print Network (OSTI)

The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust exhaust experiment It has previously been difficult to identify the emissions of diesel exhaust until reactive with organic compounds such as alkanes which are present in diesel exhaust emissions. The reaction

Collins, Gary S.

208

Comparative Toxicity of Gasoline and Diesel Engine Emissions  

SciTech Connect

Better information on the comparative toxicity of airborne emissions from different types of engines is needed to guide the development of heavy vehicle engine, fuel, lubricant, and exhaust after-treatment technologies, and to place the health hazards of current heavy vehicle emissions in their proper perspective. To help fill this information gap, samples of vehicle exhaust particles and semi-volatile organic compounds (SVOC) were collected and analyzed. The biological activity of the combined particle-SVOC samples is being tested using standardized toxicity assays. This report provides an update on the design of experiments to test the relative toxicity of engine emissions from various sources.

JeanClare Seagrave; Joe L. Mauderly; Barbara Zielinska; John Sagebiel; Kevin Whitney; Doughlas R. Lawson; Michael Gurevich

2000-06-19T23:59:59.000Z

209

A Pilot Study of the Effectiveness of Indoor Plants for Removal of Volatile Organic Compounds in Indoor Air in a Seven-Story Office Building  

SciTech Connect

The Paharpur Business Centre and Software Technology Incubator Park (PBC) is a 7 story, 50,400 ft{sup 2} office building located near Nehru Place in New Delhi India. The occupancy of the building at full normal operations is about 500 people. The building management philosophy embodies innovation in energy efficiency while providing full service and a comfortable, safe, healthy environment to the occupants. Provision of excellent Indoor Air Quality (IAQ) is an expressed goal of the facility, and the management has gone to great lengths to achieve it. This is particularly challenging in New Delhi, where ambient urban pollution levels rank among the worst on the planet. The approach to provide good IAQ in the building includes a range of technical elements: air washing and filtration of ventilation intake air from rooftop air handler, the use of an enclosed rooftop greenhouse with a high density of potted plants as a bio-filtration system, dedicated secondary HVAC/air handling units on each floor with re-circulating high efficiency filtration and UVC treatment of the heat exchanger coils, additional potted plants for bio-filtration on each floor, and a final exhaust via the restrooms located at each floor. The conditioned building exhaust air is passed through an energy recovery wheel and chemisorbent cartridge, transferring some heat to the incoming air to increase the HVAC energy efficiency. The management uses 'green' cleaning products exclusively in the building. Flooring is a combination of stone, tile and 'zero VOC' carpeting. Wood trim and finish appears to be primarily of solid sawn materials, with very little evidence of composite wood products. Furniture is likewise in large proportion constructed from solid wood materials. The overall impression is that of a very clean and well-kept facility. Surfaces are polished to a high sheen, probably with wax products. There was an odor of urinal cake in the restrooms. Smoking is not allowed in the building. The plants used in the rooftop greenhouse and on the floors were made up of a number of species selected for the following functions: daytime metabolic carbon dioxide (CO{sub 2}) absorption, nighttime metabolic CO{sub 2} absorption, and volatile organic compound (VOC) and inorganic gas absorption/removal for air cleaning. The building contains a reported 910 indoor plants. Daytime metabolic species reported by the PBC include Areca Palm, Oxycardium, Rubber Plant, and Ficus alii totaling 188 plants (21%). The single nighttime metabolic species is the Sansevieria with a total of 28 plants (3%). The 'air cleaning' plant species reported by the PBC include the Money Plant, Aglaonema, Dracaena Warneckii, Bamboo Palm, and Raphis Palm with a total of 694 plants (76%). The plants in the greenhouse (Areca Palm, Rubber Plant, Ficus alii, Bamboo Palm, and Raphis Palm) numbering 161 (18%) of those in the building are grown hydroponically, with the room air blown by fan across the plant root zones. The plants on the building floors are grown in pots and are located on floors 1-6. We conducted a one-day monitoring session in the PBC on January 1, 2010. The date of the study was based on availability of the measurement equipment that the researchers had shipped from Lawrence Berkeley National Lab in the U.S.A. The study date was not optimal because a large proportion of the regular building occupants were not present being New Year's Day. An estimated 40 people were present in the building all day during January 1. This being said, the building systems were in normal operations, including the air handlers and other HVAC components. The study was focused primarily on measurements in the Greenhouse and 3rd and 5th floor environments as well as rooftop outdoors. Measurements included a set of volatile organic compounds (VOCs) and aldehydes, with a more limited set of observations of indoor and outdoor particulate and carbon dioxide concentrations. Continuous measurements of Temperature (T) and relative humidity (RH) were made selected indoor and outdoor locations.

Apte, Michael G.; Apte, Joshua S.

2010-04-27T23:59:59.000Z

210

Distinguishing triplet energy transfer and trap-assisted recombination in multi-color organic light-emitting diode with an ultrathin phosphorescent emissive layer  

SciTech Connect

An ultrathin layer of deep-red phosphorescent emitter tris(1-phenylisoquinoline) iridium (III) (Ir(piq){sub 3}) is inserted within different positions of the electron blocking layer fac-tris (1-phenylpyrazolato-N,C{sup 2?})-iridium(III) (Ir(ppz){sub 3}) to distinguish the contribution of the emission from the triplet exciton energy transfer/diffusion from the adjacent blue phosphorescent emitter and the trap-assisted recombination from the narrow band-gap emitter itself. The charge trapping effect of the narrow band-gap deep-red emitter which forms a quantum-well-like structure also plays a role in shaping the electroluminescent characteristics of multi-color organic light-emitting diodes. By accurately controlling the position of the ultrathin sensing layer, it is considerably easy to balance the white emission which is quite challenging for full-color devices with multiple emission zones. There is nearly no energy transfer detectable if 7 nm thick Ir(ppz){sub 3} is inserted between the blue phosphorescent emitter and the ultrathin red emitter.

Xue, Qin, E-mail: xueqin19851202@163.com; Liu, Shouyin [Department of Physical Science and Technology, Central China Normal University, Wuhan 430079 (China); Xie, Guohua; Chen, Ping; Zhao, Yi; Liu, Shiyong [State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China)

2014-03-21T23:59:59.000Z

211

Reducing Emissions of Persistent Organic Pollutants from a Diesel Engine by Fueling with Water-Containing Butanol Diesel Blends  

Science Journals Connector (OSTI)

An increasing energy demand and environmental pollution has motivated a search for bio-fuels, such as bio-diesels(1, 2) and bio-alcohols,(3, 4) that can be used as alternative fuels for diesel engines. ... In general, both bio-diesel and bio-alcohols, such as ethanol and butanol, have the advantages of higher brake thermal efficiency (BTE) and lower emissions of particulate matter (PM), carbon monoxide (CO) and hydrocarbons (HC). ... Diesel Engine and Test Cycle ...

Yu-Cheng Chang; Wen-Jhy Lee; Hsi-Hsien Yang; Lin-Chi Wang; Jau-Huai Lu; Ying I. Tsai; Man-Ting Cheng; Li-Hao Young; Chia-Jui Chiang

2014-04-16T23:59:59.000Z

212

Quantifying the ecosystem-scale emission and deposition fluxes of biogenic volatile organic compounds (BVOC) and their oxidation products above plant canopies  

E-Print Network (OSTI)

covariance plots of vertical wind speed and m/z 127.073 (C 7correlation of vertical wind speed (w) and volume mixingcorrections between vertical wind speed and volume mixing

Park, Jeong-Hoo

2012-01-01T23:59:59.000Z

213

Analysis of C1, C2, and C10 through C33 particle-phase and semi-volatile organic compound emissions from heavy-duty diesel engines  

E-Print Network (OSTI)

from heavy-duty diesel engines Z. Gerald Liu a,*, Devin R. Berg a , Victoria N. Vasys a , Melissa E engines Aftertreatment technology Diesel particulate filter Chemical speciation a b s t r a c t To meet increasingly stringent regulations for diesel engines, technologies such as combustion strategies

Wu, Mingshen

214

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution  

E-Print Network (OSTI)

carbon monoxide (Table 3). Propane, n- butane and i- butaneof vehicle traffic and liquid propane gas (LPG) emissionshicles, the use of liquid propane gas and the production of

2011-01-01T23:59:59.000Z

215

MST: Organizations: Organic Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Adhesive Bonding Adhesive Bonding Composites Encapsulation Materials Characterization Mechanical Testing Molding, Thermoforming, & Compounding Organizations Organic Materials Composite-to-metal adhesive bond Experimental/analytical study of composit-to-metal adhesive bond. The Organic Materials department in the Advanced Manufacturing and Processing Laboratory provides innovative prototype fabrication, full service small lot production, materials technology, processing expertise, and a broad range of organic material characterization and mechanical testing techniques. We encapsulate, we join and bond, we foam, we analyze and image, we build composite structures. We strive to make you, our customers, successful! We partner with you to find the right combination of materials, processing, and fixturing that will result in the highest value

216

The use of radon (Rn-222) and volatile organic compounds in monitoring soil gas to localize NAPL contamination at a gas station in Rio Claro, Săo Paulo State, Brazil  

Science Journals Connector (OSTI)

Abstract This study focuses on the presence of radon (222Rn) and volatile organic compounds (VOCs) in soil gases at a gas station located in the city of Rio Claro, Săo Paulo, Brazil, where a fossil fuel leak occurred. The spatial distribution results show a correlation between 222Rn and VOCs, consistent with the fact that radon gas has a greater chemical affinity with organic phases than with water. This finding demonstrates that the presence of a residual hydrocarbon phase in an aquifer can retain radon, leading to a reduced radon content in the soil gas. The data in this study confirm the results of previous investigations, in which the method used in this study provided a preliminary fingerprint of a contaminated area. Furthermore, the data analysis time is brief, and only simple equipment is required.

E.Q. Barbosa; J.A. Galhardi; D.M. Bonotto

2014-01-01T23:59:59.000Z

217

Complete Detoxification of Short Chain Chlorinated Aliphatic Compounds: Isolation of Halorespiring Organisms and Biochemical Studies of the Dehalogenating Enzyme Systems - Final Report  

SciTech Connect

Work focused on the isolation and characterization of halorespiring populations, and the initial investigation of the dechlorinating enzyme systems. In addition, tools to evaluate the presence/activity to halorespiring populations in the environment were developed. The tools developed in this work (measurements of hydrogen consumption thresholds, molecular probes) are relevant for regulatory agencies in order to facilitate decisions on which bioremediation technology (biostimulation or bioaugmentation) is most promising at a particular site. In addition, a better understanding of the physiology of the halorespiring organisms as well as the biochemistry of the dehalogenating enzyme systems enhances our knowledge of how these organisms can successfully be employed in the bioremediation of contaminated sites.

Tiedje, J.M.

1999-10-01T23:59:59.000Z

218

Characterization of particle- and vapor-phase organic fraction emissions from a heavy-duty diesel engine equipped with a particle trap and regeneration controls  

SciTech Connect

The effects of a ceramic particle trap on the chemical and biological character of the exhaust from a heavy-duty diesel engine have been studied during steady-state operation and during periods of trap regeneration. Phase I of this project involved developing and refining the methods using a Caterpillar 3208 engine, and Phase II involved more detailed experiments with a Cummins LTA10-300 engine, which met Federal 1988 particulate matter standards, and a ceramic particle trap with built-in regeneration controls. During the Phase I experiments, samples wee collected at the Environmental Protection Agency (EPA)* steady-state mode 4 (50% load at intermediate speed). Varying the dilution ratio to obtain a constant filter-face temperature resulted in less variability in total particulate matter (TPM), particle-associated soluble organic fraction (SOF), solids (SOL), and polynuclear aromatic hydrocarbon (PAH) levels than sampling with a constant dilution ratio and allowing filter-face temperature to vary. A modified microsuspension Ames assay detected mutagenicity in the SOF samples, and in the semivolatile organic fraction extracted from XAD-2 resin (XAD-2 resin organic component, XOC) with at least 10 times less sample mass than the standard plate incorporation assay. Measurement techniques for PAH and nitro-PAH in the SOF and XOC also were developed during this portion of the project. For the Phase II work, two EPA steady-state rated speed modes were selected: mode 11 (25% load) and mode 9 (75% load). With or without the trap, filter-face temperatures were kept at 45 degrees +/- 2 degrees C, nitrogen dioxide (NO2) levels less than 5 parts per million (ppm), and sampling times less than 60 minutes. Particle sizes were determined using an electrical aerosol analyzer. Similar sampling methods were used when the trap was regenerated, except that a separate dilution tunnel and sampling system was designed and built to collect all of the regeneration emissions.

Bagley, S.T.; Gratz, L.D.; Leddy, D.G.; Johnson, J.H. (Michigan Technological Univ., Houghton, MI (United States))

1993-07-01T23:59:59.000Z

219

The conformational evolution of elongated polymer solutions tailors the polarization of light-emission from organic nanofibers  

E-Print Network (OSTI)

Polymer fibers are currently exploited in tremendously important technologies. Their innovative properties are mainly determined by the behavior of the polymer macromolecules under the elongation induced by external mechanical or electrostatic forces, characterizing the fiber drawing process. Although enhanced physical properties were observed in polymer fibers produced under strong stretching conditions, studies of the process-induced nanoscale organization of the polymer molecules are not available, and most of fiber properties are still obtained on an empirical basis. Here we reveal the orientational properties of semiflexible polymers in electrospun nanofibers, which allow the polarization properties of active fibers to be finely controlled. Modeling and simulations of the conformational evolution of the polymer chains during electrostatic elongation of semidilute solutions demonstrate that the molecules stretch almost fully within less than 1 mm from jet start, increasing polymer axial orientation at the jet center. The nanoscale mapping of the local dichroism of individual fibers by polarized near-field optical microscopy unveils for the first time the presence of an internal spatial variation of the molecular order, namely the presence of a core with axially aligned molecules and a sheath with almost radially oriented molecules. These results allow important and specific fiber properties to be manipulated and tailored, as here demonstrated for the polarization of emitted light.

Andrea Camposeo; Israel Greenfeld; Francesco Tantussi; Maria Moffa; Francesco Fuso; Maria Allegrini; Eyal Zussman; Dario Pisignano

2014-07-30T23:59:59.000Z

220

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network (OSTI)

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Communication accepte: Healthy Buildings/IAQ'97 Washington DC, septembre 1997Communication accepte: Healthy Buildings/IAQ'97 Washington DC, septembre 1997 DISCRIMINATION OF VOLATILE ORGANIC COMPOUNDS  

E-Print Network (OSTI)

Communication acceptée: Healthy Buildings/IAQ'97 Washington DC, septembre 1997Communication acceptée: Healthy Buildings/IAQ'97 Washington DC, septembre 1997 DISCRIMINATION OF VOLATILE ORGANIC manuscript, published in "4th International Conference on Healthy Buildings'97, Washington : United States

Paris-Sud XI, Université de

222

Semivolatile Organic Compounds (SVOCs) Semivolatile organic compounds (SVOCs) are a group of compounds that includes some  

E-Print Network (OSTI)

) Triclosan Antimicrobial Toothpaste, hand/dish soaps Polychlorinated Biphenyls Heat-transfer fluid Food

Iglesia, Enrique

223

Collaborative Emissions Research at EMSL | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Collaborative Emissions Research at EMSL Collaborative Emissions Research at EMSL EMSL produced this video for the annual congressional science expo organized by the National User...

224

Wildland fire emissions, carbon, and climate: Emission factors Shawn Urbanski  

E-Print Network (OSTI)

Wildland fire emissions, carbon, and climate: Emission factors Shawn Urbanski Missoula Fire burning Greenhouse gases Emission factors a b s t r a c t While the vast majority of carbon emitted wildland fire greenhouse gas and aerosol (organic aerosol (OA) and black carbon (BC)) emission inventories

225

Turbo Compounding: A Technology Whose Time Has Come | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

A Technology Whose Time Has Come Turbo Compounding: A Technology Whose Time Has Come 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters...

226

242-A Evaporator/plutonium uranium extraction (PUREX) effluent treatment facility (ETF) nonradioactive air emission test report  

SciTech Connect

This report shows the methods used to test the stack gas outlet concentration and emission rate of Volatile Organic Compounds as Total Non-Methane Hydrocarbons in parts per million by volume,grams per dry standard cubic meter, and grams per minute from the PUREX ETF stream number G6 on the Hanford Site. Test results are shown in Appendix B.1.

Hill, J.S., Westinghouse Hanford

1996-05-10T23:59:59.000Z

227

Low emission turbo compound engine system  

DOE Patents (OSTI)

A diesel or HHCI engine has an air intake and an exhaust for products of combustion. A pair of turbochargers receive the products of combustion in a series relationship and an exhaust aftertreatment device receive the products of combustion from the downstream turbine. A power turbine receives the output from the exhaust aftertreatment device and an EGR system of the power turbine passes a selected portion of the output to a point upstream of the upstream turbocharger compressor. A device adds fuel to the aftertreatment device to regenerate the particulate filter and the power turbine recoups the additional energy. The power turbine may be used to drive accessories or the prime output of the engine.

Vuk; Carl T. (Denver, IA)

2011-05-31T23:59:59.000Z

228

Characterizing the formation of secondary organic aerosols  

SciTech Connect

Organic aerosol is an important fraction of the fine particulate matter present in the atmosphere. This organic aerosol comes from a variety of sources; primary organic aerosol emitted directly from combustion process, and secondary aerosol formed in the atmosphere from condensable vapors. This secondary organic aerosol (SOA) can result from both anthropogenic and biogenic sources. In rural areas of the United States, organic aerosols can be a significant part of the aerosol load in the atmosphere. However, the extent to which gas-phase biogenic emissions contribute to this organic load is poorly understood. Such an understanding is crucial to properly apportion the effect of anthropogenic emissions in these rural areas that are sometimes dominated by biogenic sources. To help gain insight on the effect of biogenic emissions on particle concentrations in rural areas, we have been conducting a field measurement program at the University of California Blodgett Forest Research Facility. The field location includes has been used to acquire an extensive suite of measurements resulting in a rich data set, containing a combination of aerosol, organic, and nitrogenous species concentration and meteorological data with a long time record. The field location was established in 1997 by Allen Goldstein, a professor in the Department of Environmental Science, Policy and Management at the University of California at Berkeley to study interactions between the biosphere and the atmosphere. The Goldstein group focuses on measurements of concentrations and whole ecosystem biosphere-atmosphere fluxes for volatile organic compounds (VOC's), oxygenated volatile organic compounds (OVOC's), ozone, carbon dioxide, water vapor, and energy. Another important collaborator at the Blodgett field location is Ronald Cohen, a professor in the Chemistry Department at the University of California at Berkeley. At the Blodgett field location, his group his group performs measurements of the concentrations of important gas phase nitrogen compounds. Experiments have been ongoing at the Blodgett field site since the fall of 2000, and have included portions of the summer and fall of 2001, 2002, and 2003. Analysis of both the gas and particle phase data from the year 2000 show that the particle loading at the site correlates with both biogenic precursors emitted in the forest and anthropogenic precursors advected to the site from Sacramento and the Central Valley of California. Thus the particles at the site are affected by biogenic processing of anthropogenic emissions. Size distribution measurements show that the aerosol at the site has a geometric median diameter of approximately 100 nm. On many days, in the early afternoon, growth of nuclei mode particles (<20 nm) is also observed. These growth events tend to occur on days with lower average temperatures, but are observed throughout the summer. Analysis of the size resolved data for these growth events, combined with typical measured terpene emissions, show that the particle mass measured in these nuclei mode particles could come from oxidation products of biogenic emissions, and can serve as a significant route for SOA partitioning into the particle phase. During periods of each year, the effect of emissions for forest fires can be detected at the Blodgett field location. During the summer of 2002 emissions from the Biscuit fire, a large fire located in Southwest Oregon, was detected in the aerosol data. The results show that increases in particle scattering can be directly related to increased black carbon concentration and an appearance of a larger mode in the aerosol size distribution. These results show that emissions from fires can have significant impact on visibility over large distances. The results also reinforce the view that forest fires can be a significant source of black carbon in the atmosphere, which has important climate and visibility. Continuing work with the 2002 data set, particularly the combination of the aerosol and gas phase data, will continue to provide important information o

Lunden, Melissa; Black, Douglas; Brown, Nancy

2004-02-01T23:59:59.000Z

229

Emissions of metals, chromium and nickel species, and organics from municipal waste-water-sludge incinerators. Volume 5. Site 7 test report CEMS evaluation. Final report, 1989-91  

SciTech Connect

The U.S. Environmental Protection Agency (EPA) Office of Water Regulations and Standards (OWRS) has recently revised the risk-based sludge regulations under Section 405d of the Clean Water Act. The revised regulations include a provision for monitoring total hydrocarbon (THC) and/or carbon monoxide (CO) emissions as a surrogate for organic emissions measurements. With the assistance of EPA's Risk Reduction Engineering Laboratory (RREL), OWRS has implemented a research program to investigate the relationship of CO and hydrocarbon emissions and the viability of the monitoring systems used to continuously measure these emissions. The test report presents the results obtained at the Site 7 municipal wastewater treatment facility. The CO and THC emission levels showed good agreement during the test program, i.e., increases in CO are accompanied by increases in THC. The actual correlation coefficients ranged from .73-.93 using one-minute averaged data from six test runs. Comparisons of CO and THC values corrected to 7% oxygen levels do not provide the same measure of correlation (r-values from .11 to .83). Possible explanation of the apparent change in agreement is being investigated further. The report presents uncorrected and corrected emission data in both tabular and graphic formats.

Cone, A.L.; Shanklin, S.A.

1992-03-01T23:59:59.000Z

230

A numerical solution to three-dimensional multiphase transport of volatile organic compounds in unsaturated soils -- with an application to the remedial method of in-situ volatilization. Part I: Theoretical development  

SciTech Connect

Part I of this paper presents the development and application of a numerical model for determining the fate and transport of volatile organic compounds (VOCS) in the unsaturated zone resulting from forced volatilization and gaseous advection-dispersion of organic vapor in a multipartitioned three-dimensional environment. The model allows for single-component transport in the gas and water phases. The hydrocarbon is assumed to be in specific retention and, therefore, immobile. Partitioning of the hydrocarbon between the oil, water, gas, and soil is developed as rate-limited functions that are incorporated into sink/source terms in the transport equations. The code for the model was developed specifically to investigate in-situ volatilization (ISV) remedial strategies, predict the extent of cleanup from information obtained at a limited number of measurement locations, and to help design ISV remedial systems. Application of the model is demonstrated for a hypothetical one-dimensional ISV system. Part II of this paper will present the analysis of an existing ISV system using the full three-dimensional capability of the model.

Filley, T.; Tomasko, D.

1992-04-01T23:59:59.000Z

231

Low emissions diesel fuel  

DOE Patents (OSTI)

A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

Compere, Alicia L. (Knoxville, TN); Griffith, William L. (Oak Ridge, TN); Dorsey, George F. (Farragut, TN); West, Brian H. (Kingston, TN)

1998-01-01T23:59:59.000Z

232

Oxidized organic functional groups in aerosol particles from forest emissions measured at mid-mountain and high- elevation mountain sites in Whistler, BC  

E-Print Network (OSTI)

with fossil fuel combustion and marine emissions (Russell etfuel combustion, and biomass burning (BB). Natural sources include biogenic (from the biosphere), marine (

Schwartz, Rachel E.

2010-01-01T23:59:59.000Z

233

Partitioning of Volatile Organics in Diesel Particulate and Exhaust  

Energy.gov (U.S. Department of Energy (DOE))

Evaluation of how sampling details affect the measurement of volatile organic compounds in diesel exhaust

234

Emissions Inventory Report Summary: Reporting Requirements for the New Mexico Administrative Code, Title 20, Chapter 2, Part 73 (20 NMAC 2.73) for Calendar Year 2001  

SciTech Connect

Los Alamos National Laboratory is subject to annual emissions-reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), Notice of Intent and Emissions Inventory Requirements. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. For calendar year 2001, the Technical Area 3 steam plant was the primary source of criteria air pollutants from the Laboratory, while research and development activities were the primary source of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20.2.72 NMAC. Hazardous air pollutant emissions from chemical use for research and development activities were also reported.

Margorie Stockton

2003-04-01T23:59:59.000Z

235

Microwave plasma conversion of volatile organic compounds  

E-Print Network (OSTI)

MHz; Gerling Laboratory) and a resonant plasma tuner (ASTEX) were used to generate an argon/steam- based plasma at one atmosphere

Ko, Y; Yang, G S; Chang, DPY; Kennedy, Ian M

2003-01-01T23:59:59.000Z

236

Oxidation of Organic Compounds in the Soil.  

E-Print Network (OSTI)

.................... ltudy by Means of Carbon Dioxide Formed 8 ............................... lomparison of . Various Materials 9 ...................................... lffect of Nature of Soil 14 ..................................... Ixidation of Soil Carbon 18... was drawn to take out the carbon dioxide. Althongl~ such experi- ments are well adapted to estimate carbon cliosicle, obviously, such con- ditions do not prevail in the soil, and while it is possible that Wollnp's conclusions may appl~r to the soil uncler...

Fraps, G. S. (George Stronach)

1915-01-01T23:59:59.000Z

237

Indoor Residential Chemical Emissions as Risk Factors for Children's  

NLE Websites -- All DOE Office Websites (Extended Search)

Indoor Residential Chemical Emissions as Risk Factors for Children's Indoor Residential Chemical Emissions as Risk Factors for Children's Respiratory Health Speaker(s): Mark Mendell Date: February 23, 2007 - 12:00pm Location: 90-3122 Most research into the effects of residential indoor air exposures on asthma and allergies has focused on exposures to biologic allergens, moisture and mold, endotoxin, or combustion byproducts. A growing body of research suggests that chemical emissions from common indoor materials and finishes have adverse effects, including increased risk of asthma, allergies, and pulmonary infections. The identified risk factors include specific organic compounds such as formaldehyde, benzene, and phthalates, as well as indoor materials or finishes such as vinyl flooring, carpet, paint, and plastics. This presentation presents a brief review of studies

238

Multivariate analysis of exhaust emissions from heavy-duty diesel fuels  

SciTech Connect

Particulate and gaseous exhaust emission phases from running 10 diesel fuels on two makes of heavy-duty diesel engines were analyzed with respect to 63 chemical descriptors. Measurements for one of the fuels were also made in the presence of an exhaust aftertreatment device. The variables included 28 polycyclic aromatic compounds (PAC), regulated pollutants (CO, HC, NO{sub x}, particles), and 19 other organic and inorganic exhaust emission components. Principal components analysis (PCA) was applied for the statistical exploration of the obtained data. In addition, relationships between chemical (12 variables) and physical (12 variables) parameters of the fuels to the exhaust emissions were derived using partial least squares (PLS) regression. Both PCA and PLS models were derived for the engine makes separately. The PCA showed that the most descriptive exhaust emission factors from these diesel fuels included fluoranthene as a representative of PAC, the regulated pollutants, sulfates, methylated pyrenes, and monoaromatics. Exhaust emissions were significantly decreased in the presence of an exhaust aftertreatment device. Both engine makes exhibited similar patterns of exhaust emissions. Discrepancies were observed for the exhaust emissions of CO{sub 2} and oil-derived soluble organic fractions, owing to differences in engine design. The PLS analysis showed a good correlation of exhaust emission of the regulated pollutants and PAC with the contents of PAC in the fuels and the fuel aromaticity. 41 refs., 6 figs., 6 tabs.

Sjoegren, M.; Ulf, R.; Li, H.; Westerholm, R. [Stockholm Univ. (Sweden)

1996-01-01T23:59:59.000Z

239

Introduction Compound-specific identification, or biomarker analysis,  

E-Print Network (OSTI)

269 Introduction Compound-specific identification, or biomarker analysis, in organic geochemistry cases highlighting subtle yet important details not revealed by bulk analyses alone. For example

Long, Bernard

240

GEIA-ACCENT Emission Data Portal | Open Energy Information  

Open Energy Info (EERE)

GEIA-ACCENT Emission Data Portal GEIA-ACCENT Emission Data Portal Jump to: navigation, search Tool Summary Name: Global Emissions Inventory Activity (GEIA) Agency/Company /Organization: National Aeronautics and Space Administration Sector: Energy, Land Topics: GHG inventory Resource Type: Dataset Website: www.geiacenter.org/ References: Global Emissions Inventory Activity (GEIA)[1] "The GEIA /ACCENT data portal provides gridded emission data; emission data are usually separated into three main categories : anthropogenic emissions, biomass burning emissions, and natural emissions: anthropogenic emissions include emissions from fossil fuel and biofuel consumption, industry and agricultural sources. biomass burning emissions include emissions from forest fires, savannah fires, and sometimes large croplands fires.

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Excitation-emission spectra and fluorescence quantum yields for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Excitation-emission spectra and fluorescence quantum yields for fresh and aged biogenic secondary organic aerosols. Excitation-emission spectra and fluorescence quantum yields for...

242

Numerical simulation of VOC Emissions from Dry Materials , J.S. Zhang2  

E-Print Network (OSTI)

, subfloors), and insulation materials (fiberglass, rigid foam) emit a variety of volatile organic compounds

Chen, Qingyan "Yan"

243

APPENDIX E. AIRNOVA, INC. EMISSION EVALUATION TEST REPORT  

E-Print Network (OSTI)

.6 Specific Volatile Organic Compounds . . . . . . . . . . . . . . . . 27 4.7 Dioxins, Furans, and PCBs)* · Volatile Organic Compounds (VOCs)* · Sulfur Dioxide (SO2)* · Dioxins and Furans · Toxic Metals

Brookhaven National Laboratory

244

Emissions Inventory Report Summary Reporting Requirements for the New Mexico Administrative Code, Title 20, Chapter 2, Part 73 (20 NMAC 2.73) for Calendar Year 1998  

SciTech Connect

Los Alamos National Laboratory (the Laboratory) is subject to emissions reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20 NMAC 2.73), Notice of Intent and Emissions Inventory Requirements. The Laboratory has the potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, and volatile organic compounds. For 1998, combustion products from the industrial sources contributed the greatest amount of criteria air pollutants from the Laboratory. Research and development activities contributed the greatest amount of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20 NMAC 2.72 Construction Permits.

Air Quality Group, ESH-17

1999-09-01T23:59:59.000Z

245

Measurement of chemical emissions under the influence of low-NO{sub x} combustion modifications. Final report  

SciTech Connect

Effect of low-NO{sub x} firing. There was no clear-cut effect on the emission of trace metals or acid gases. The data give marginal evidence for a decreased emission of Cr(VI), which would be a favorable change but is not certain by any means. The effect on aldehydes and ketones cannot be stated because of the loss of samples for baseline conditions; no credible data on these compounds were obtained for baseline conditions. The change in volatile organics appeared to be a reduction in emissions, whereas that for semi-volatiles seemed to be an increase. Inasmuch as low-NO{sub x} firing is sometimes accompanied by large increases in the amount of unburned carbon in the ash, the result for semi-volatiles is more in line with expectation. Effect of the hot-side ESP. As indicated above, the hot-side ESP lowered trace-element emissions to the range roughly from 1 to 5% of the levels found in the inlet gas stream. Not surprisingly, the hot-side ESP had no measurable influence on the emissions of SO{sub x}, HF, and HCl. Quite surprisingly, on the other hand, the ESP seemed to suppress the emission of certain organic substances. Suppression of the emission of formaldehyde is particularly difficult to explain. Presumably, the apparent disappearance of organics in the vapor state may be due in part to chemical changes at the high temperature of the ESP or in the corona regions, where ozone and other high-energy reactants are present. Perhaps chemical destruction was aided in the instance of semi-volatile compounds by relatively long residence times at high temperature while the compounds were adsorbed on ash particles in the hoppers. Effect of the cold-side ESP. Limited data with the cold-side ESP in operation made it difficult to detect any but the most emphatic effect of that ESP. No dramatic effect was seen.

Dismukes, E.B.

1993-10-08T23:59:59.000Z

246

Emissions Trading  

Science Journals Connector (OSTI)

Emissions trading is a comparatively new policy instrument which ... electricity systems in Europe. The development of emissions trading thus represents an innovation in its own...

2009-01-01T23:59:59.000Z

247

Emissions from street vendor cooking devices (charcoal grilling). Final report, January 1998--March 1999  

SciTech Connect

The report discusses a joint US/Mexican program to establish a reliable emissions inventory for street vendor cooking devices (charcoal grilling), a significant source of air pollutants in the Mexicali-Imperial Valley area of Mexico. Emissions from these devices, prevalent in the streets of Mexicali, Mexico, were investigated experimentally by measuring levels of particulate matter, particle size distributions, volatile and semivolatile organic compounds, aldehydes, and oxides of nitrogen and sulfur, emitted when meat is cooked on a grill over a charcoal fire. To investigate the emission rate, both beef and chicken were tested. Furthermore, both meats were marinated with a mixture similar to that used by the street vendors. Some tests were conducted with non-marinated beef for comparison. Two blank runs were performed sampling charcoal fires without meat. Finally, a simple control device, normally used in an exhaust fan to trap grease over a kitchen stove, was evaluated for its effectiveness in reducing emissions.

Lee, S.Y.

1999-06-01T23:59:59.000Z

248

Mixed crystal organic scintillators  

DOE Patents (OSTI)

A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

2014-09-16T23:59:59.000Z

249

Effect of E85 on Tailpipe Emissions from Light-Duty Vehicles  

SciTech Connect

E85, which consists of nominally 85% fuel grade ethanol and 15% gasoline, must be used in flexible-fuel (or 'flexfuel') vehicles (FFVs) that can operate on fuel with an ethanol content of 0-85%. Published studies include measurements of the effect of E85 on tailpipe emissions for Tier 1 and older vehicles. Car manufacturers have also supplied a large body of FFV certification data to the U.S. Environmental Protection Agency, primarily on Tier 2 vehicles. These studies and certification data reveal wide variability in the effects of E85 on emissions from different vehicles. Comparing Tier 1 FFVs running on E85 to similar non-FFVs running on gasoline showed, on average, significant reductions in emissions of oxides of nitrogen (NOx; 54%), non-methane hydrocarbons (NMHCs; 27%), and carbon monoxide (CO; 18%) for E85. Comparing Tier 2 FFVs running on E85 and comparable non-FFVs running on gasoline shows, for E85 on average, a significant reduction in emissions of CO (20%), and no significant effect on emissions of non-methane organic gases (NMOGs). NOx emissions from Tier 2 FFVs averaged approximately 28% less than comparable non-FFVs. However, perhaps because of the wide range of Tier 2 NOx standards, the absolute difference in NOx emissions between Tier 2 FFVs and non-FFVs is not significant (P 0.28). It is interesting that Tier 2 FFVs operating on gasoline produced approximately 13% less NMOGs than non-FFVs operating on gasoline. The data for Tier 1 vehicles show that E85 will cause significant reductions in emissions of benzene and butadiene, and significant increases in emissions of formaldehyde and acetaldehyde, in comparison to emissions from gasoline in both FFVs and non-FFVs. The compound that makes up the largest proportion of organic emissions from E85-fueled FFVs is ethanol.

Yanowitz, J.; McCormick, R. L.

2009-02-01T23:59:59.000Z

250

Small-Chamber Measurements of Chemical-Specific Emission Factors for  

NLE Websites -- All DOE Office Websites (Extended Search)

Small-Chamber Measurements of Chemical-Specific Emission Factors for Small-Chamber Measurements of Chemical-Specific Emission Factors for Drywall Title Small-Chamber Measurements of Chemical-Specific Emission Factors for Drywall Publication Type Report Year of Publication 2010 Authors Maddalena, Randy L., Marion L. Russell, Moya Melody, and Michael G. Apte Publisher Lawrence Berkeley National Laboratory City Berkeley Abstract Imported drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. To support an investigation of those building materials by the Consumer Products Safety Commission (CPSC), Lawrence Berkeley National Laboratory (LBNL) measured chemical-specific emission factors for 30 samples of drywall materials. Emission factors are reported for 75 chemicals and 30 different drywall samples encompassing both domestic and imported stock and incorporating natural, synthetic, or mixed gypsum core material. CPSC supplied all drywall materials. First the drywall samples were isolated and conditioned in dedicated chambers, then they were transferred to small chambers where emission testing was performed. Four sampling and analysis methods were utilized to assess (1) volatile organic compounds, (2) low molecular weight carbonyls, (3) volatile sulfur compounds, and (4) reactive sulfur gases. LBNL developed a new method that combines the use of solid phase microextraction (SPME) with small emission chambers to measure the reactive sulfur gases, then extended that technique to measure the full suite of volatile sulfur compounds. The testing procedure and analysis methods are described in detail herein. Emission factors were measured under a single set of controlled environmental conditions. The results are compared graphically for each method and in detailed tables for use in estimating indoor exposure concentrations

251

Novel amine-based presursor compounds and composite membranes thereof  

DOE Patents (OSTI)

Novel amine-based precursor compounds comprising the condensation products of dialkylenetriamine and alpha, beta-unsaturated acid halides are disclosed, as well as composite membranes containing such compounds, the membranes being useful in RO-type processes for desalination and the removal of low molecular weight organic compounds such as phenols and carboxylic acids.

Lee, Eric K. L. (Wilmington, DE); Tuttle, Mark E. (Bend, OR)

1989-01-01T23:59:59.000Z

252

Sorption of naphthoic acids and quinoline compounds to estuarine sediment  

E-Print Network (OSTI)

Sorption of naphthoic acids and quinoline compounds to estuarine sediment William D. Burgos The sorption of 16 ionizable organic compounds (IOCs) to an estuarine sediment was measured in synthetic were quinoline compounds. The linear sorption distribution coefficient (Kd) was used to correlate

Burgos, William

253

Process for reducing aromatic compounds in ethylenediamine with calcium  

DOE Patents (OSTI)

Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

Benkeser, R.A.; Laugal, J.A.; Rappa, A.

1985-08-06T23:59:59.000Z

254

Stable blue phosphorescent organic light emitting devices  

DOE Patents (OSTI)

Novel combination of materials and device architectures for organic light emitting devices is provided. An organic light emitting device, is provided, having an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer includes a host and a phosphorescent emissive dopant having a peak emissive wavelength less than 500 nm, and a radiative phosphorescent lifetime less than 1 microsecond. Preferably, the phosphorescent emissive dopant includes a ligand having a carbazole group.

Forrest, Stephen R.; Thompson, Mark; Giebink, Noel

2014-08-26T23:59:59.000Z

255

Carbon sinks and emissions trading under the Kyoto Protocol: a legal analysis  

Science Journals Connector (OSTI)

...Saunders Carbon sinks and emissions trading under the Kyoto Protocol: a...the issues of carbon sinks and emissions trading nearly aborted the Kyoto Protocol...third flexibility mechanism, emissions trading, compounded the complexity...

2002-01-01T23:59:59.000Z

256

Emissions Inventory Report Summary for Los Alamos National Laboratory for Calendar Year 2004  

SciTech Connect

Los Alamos National Laboratory (LANL) is subject to annual emissions reporting requirements for regulated air pollutants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), ''Notice of Intent and Emissions Inventory Requirements''. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. Additionally, on April 30, 2004, LANL was issued a Title V Operating Permit from the New Mexico Environment Department, Air Quality Bureau, under 20.2.70 NMAC. This Title V Operating Permit (Permit No. P-100) includes emission limits and operating limits for all regulated sources of air pollution at LANL. The Title V Operating Permit also requires semi-annual emissions reporting for all sources included in the permit. This report summarizes both the annual emissions inventory reporting and the semi-annual emissions reporting for LANL for calendar year 2004. LANL's 2004 emissions are well below the emission limits in the Title V Operating Permit.

M. Stockton

2005-10-01T23:59:59.000Z

257

Reduction of carbon monoxide emissions with regenerative thermal oxidizers  

SciTech Connect

Regenerative thermal oxidizers (RTOs) have been extensively used for the control of volatile organic compound (VOC) emissions from various sources. However, very little information is available on the ability of RTOs to control carbon monoxide (CO) emissions. This paper presents the results of extensive tests conducted on two RTOs to determine their VOC and CO control efficiencies. The inlet gas stream to the RTOs includes VOC and CO concentrations as high as 2,000 ppm and 3,600 ppm, respectfully. The testing demonstrated that both RTOs were capable of controlling greater than 98% of both inlet VOCs and CO. While the destruction efficiencies within the combustion chambers exceeded 99.9%, direct leakage past valves accounted for the lower control efficiencies. The tests indicated that the overall VOC and CO control efficiencies of the RTOs may be limited by valve leakage. The design and permitting of a RTO should include conservative control estimates which account for possible valve leakage.

Firmin, S.M.; Lipke, S.; Baturay, A.

1996-09-01T23:59:59.000Z

258

Mononuclear Organolead Compounds  

Science Journals Connector (OSTI)

Tetraorganolead compounds in general exhibit lower thermal stability and greater reactivity than the corresponding compounds of the lighter Group 14 elements. The thermal stability is strongly dependent on the...

Friedo Huber; Wolfgang Petz

1987-01-01T23:59:59.000Z

259

Partitioning of Volatile Organics in Diesel Particulate and Exhaust...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Exhaust Partitioning of Volatile Organics in Diesel Particulate and Exhaust Evaluation of how sampling details affect the measurement of volatile organic compounds in...

260

Elements & Compounds Atoms (Elements)  

E-Print Network (OSTI)

#12;Elements & Compounds #12;Atoms (Elements) Molecules (Compounds) Cells Elements & Compounds #12;Nucleus Electrons Cloud of negative charge (2 electrons) Fig. 2.5: Simplified model of a Helium (He) Atom He 4.002602 2 Helium Mass Number (~atomic mass) = number of Neutrons + Protons = 4 for Helium Atomic

Frey, Terry

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Emissions Trading  

Science Journals Connector (OSTI)

Emissions trading is a market-based instrument to achieve ... The current international dissemination and intended linking of emissions trading schemes underlines the growing relevance of this ... . There are thr...

Edwin Woerdman

2014-06-01T23:59:59.000Z

262

Emissions Trading  

Science Journals Connector (OSTI)

This chapter covers a series of operations which are essential for the implementation of an efficient emissions trading market on the domestic and international level. An introduction to how a national emissions trading

Dr. Michael See

2001-01-01T23:59:59.000Z

263

Fluorine Speciation Analysis Using Reverse Phase Liquid Chromatography Coupled Off-Line to Continuum Source Molecular Absorption Spectrometry (CS-MAS): Identification and Quantification of Novel Fluorinated Organic Compounds in Environmental and Biological Samples  

Science Journals Connector (OSTI)

(1-4) Perfluorinated compounds (PFCs) are especially well-known for their unusual solubility, being simultaneously hydro- and lipophobic. ... (5, 6) This recognition has triggered a boost in interest in the monitoring of PFCs in water, wildlife and food. ... Chemicals used for AAS modifiers, reported by Gleisner et al.,(17) included gallium nitride (99.9%, ...

Zhiwei Qin; David McNee; Heike Gleisner; Andrea Raab; Kwaku Kyeremeh; Marcel Jaspars; Eva Krupp; Hai Deng; Jörg Feldmann

2012-06-11T23:59:59.000Z

264

Electric Turbo Compounding Technology Update  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Turbo Compounding Technology Update Electric Turbo Compounding Technology Update 15 August, 2007 Carl Vuk 15 August, 2007 Carl Vuk Electric Turbo Compounding Highlights Electric...

265

Low Emissions Aftertreatment and Diesel Emissions Reduction  

SciTech Connect

Detroit Diesel Corporation (DDC) has successfully completed a five-year Low Emissions Aftertreatment and Diesel Emissions Reduction (LEADER) program under a DOE project entitled: ''Research and Development for Compression-Ignition Direct-Injection Engines (CIDI) and Aftertreatment Sub-Systems''. The objectives of the LEADER Program were to: Demonstrate technologies that will achieve future federal Tier 2 emissions targets; and Demonstrate production-viable technical targets for engine out emissions, efficiency, power density, noise, durability, production cost, aftertreatment volume and weight. These objectives were successfully met during the course of the LEADER program The most noteworthy achievements in this program are listed below: (1) Demonstrated Tier 2 Bin 3 emissions target over the FTP75 cycle on a PNGV-mule Neon passenger car, utilizing a CSF + SCR system These aggressive emissions were obtained with no ammonia (NH{sub 3}) slip and a combined fuel economy of 63 miles per gallon, integrating FTP75 and highway fuel economy transient cycle test results. Demonstrated feasibility to achieve Tier 2 Bin 8 emissions levels without active NOx aftertreatment. (2) Demonstrated Tier 2 Bin 3 emissions target over the FTP75 cycle on a light-duty truck utilizing a CSF + SCR system, synergizing efforts with the DOE-DDC DELTA program. This aggressive reduction in tailpipe out emissions was achieved with no ammonia slip and a 41% fuel economy improvement, compared to the equivalent gasoline engine-equipped vehicle. (3) Demonstrated Tier 2 near-Bin 9 emissions compliance on a light-duty truck, without active NOx aftertreatment devices, in synergy with the DOE-DDC DELTA program. (4) Developed and applied advanced combustion technologies such as ''CLEAN Combustion{copyright}'', which yields simultaneous reduction in engine out NOx and PM emissions while also improving engine and aftertreatment integration by providing favorable exhaust species and temperature characteristics. These favorable emissions characteristics were obtained while maintaining performance and fuel economy. These aggressive emissions and performance results were achieved by applying a robust systems technology development methodology. This systems approach benefits substantially from an integrated experimental and analytical approach to technology development, which is one of DDCs core competencies Also, DDC is uniquely positioned to undertake such a systems technology development approach, given its vertically integrated commercial structure within the DaimlerChrysler organization. State-of-the-art analytical tools were developed targeting specific LEADER program objectives and were applied to guide system enhancements and to provide testing directions, resulting in a shortened and efficient development cycle. Application examples include ammonia/NO{sub x} distribution improvement and urea injection controls development, and were key contributors to significantly reduce engine out as well as tailpipe out emissions. Successful cooperation between DDC and Engelhard Corporation, the major subcontractor for the LEADER program and provider of state-of-the-art technologies on various catalysts, was another contributing factor to ensure that both passenger car and LD truck applications achieved Tier 2 Bin 3 emissions levels. Significant technical challenges, which highlight barriers of commercialization of diesel technology for passenger cars and LD truck applications, are presented at the end of this report.

None

2005-05-27T23:59:59.000Z

266

5, 90979126, 2005 VOC emissions from  

E-Print Network (OSTI)

ACPD 5, 9097­9126, 2005 VOC emissions from vegetation pyrolysis J. P. Greenberg et al. Title Page Discussions Volatile organic emissions from the distillation and pyrolysis of vegetation J. P. Greenberg, H is licensed under a Creative Commons License. 9097 #12;ACPD 5, 9097­9126, 2005 VOC emissions from vegetation

Paris-Sud XI, Université de

267

Comparative Toxicity of Combined Particle and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins...

268

Partially fluorinated ionic compounds  

DOE Patents (OSTI)

Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

Han, legal representative, Amy Qi (Hockessin, DE); Yang, Zhen-Yu (Hockessin, DE)

2008-11-25T23:59:59.000Z

269

Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN  

E-Print Network (OSTI)

propene, acetone, benzene, propane and ?-pinene (Table 1).cyanide Acetonitrile Ethane Propane i-Butane n-Butane i-= Ethane Ethane Ethane Ethane Propane Propane Propane ARCTAS

2011-01-01T23:59:59.000Z

270

Chemical Emissions of Residential Materials and Products: Review of  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemical Emissions of Residential Materials and Products: Review of Chemical Emissions of Residential Materials and Products: Review of Available Information Title Chemical Emissions of Residential Materials and Products: Review of Available Information Publication Type Report LBNL Report Number LBNL-3938E Year of Publication 2010 Authors Willem, Henry, and Brett C. Singer Publisher Lawrence Berkeley National Laboratory City Berkeley Keywords resave Abstract This report is prepared in the context of a larger program whose mission is to advance understanding of ventilation and indoor air quality in U.S. homes. A specific objective of this program is to develop the scientific basis ? through controlled experiments, monitoring and analysis ? for health risk-based ventilation standards. Appropriate and adequate ventilation is a basic element of a healthy home. Ventilation provides outdoor air and in the process removes indoor odors and contaminants including potentially unhealthful chemicals emitted by indoor materials, products and activities. Ventilation traditionally was assured to occur via infiltration of outdoor air through cracks and other leakage pathways in the residential building envelope. As building air tightness is improved for energy efficiency, infiltration can be reduced to inadequate levels. This has lead to the development of standards requiring mechanical ventilation. Though nominally intended to ensure acceptable indoor air quality, the standards are not explicitly tied to health risk or pollutant exposure targets. LBNL is currently designing analyses to assess the impact of varying ventilation standards on pollutant concentrations, health risks and energy use. These analyses require information on sources of chemical pollutant emissions, ideally including emission rates and the impact of ventilation on emissions. Some information can be obtained from recent studies that report measurements of various air contaminants and their concentrations in U.S. residences. Another way to obtain this information is the bottom-up approach of collecting and evaluating emissions data from construction and interior materials and common household products. This review contributes to the latter approach by summarizing available information on chemical emissions from new residential products and materials. We review information from the scientific literature and public sources to identify and discuss the databases that provide information on new or low-emission materials and products. The review focuses on the primary chemical or volatile organic compound (VOC) emissions from interior surface materials, furnishings, and some regularly used household products; all of these emissions are amenable to ventilation. Though it is an important and related topic, this review does not consider secondary pollutants that result from reactions of ozone and unsaturated organics bound to or emitted from material surfaces. Semi-volatile organic compounds (SVOCs) have been largely excluded from this review because ventilation generally is not an effective way to control SVOC exposures. Nevertheless, health concerns about exposures to SVOCs emitted from selected materials warrant some discussion.

271

8.08 - Photophysics of Lanthanoid Coordination Compounds  

Science Journals Connector (OSTI)

Abstract In recent years, lanthanoids have become vital components to a wealth of advanced optical materials and related technologies. Sharp visible and near-infrared emissions result in exciting applications in lighting devices (fluorescent lamps and light-emitting diodes/organic light-emitting diodes), displays, telecommunications, lasers, sensors, luminescent bioprobes, or solar energy conversion and photocatalysts, to name a few. Many of these applications are presently based on coordination compounds, so that the field of luminescent lanthanoid complexes with organic ligands has literally exploded during the past two decades and presently more than 500 original articles are published annually on the subject. An exhaustive presentation of these works would require an entire book. Therefore, in this chapter, the focus is more on the basic aspects pertaining to the design of luminescent lanthanoid-containing complexes. After an introduction to lanthanoid spectroscopy, energy transfer processes are presented and analyzed, as well as ways of avoiding nonradiative deactivation through vibrations. Representative examples are detailed but extensive enumeration of data is avoided. Furthermore, the chapter gives some highlights on application to fields as diverse as biosciences, telecommunications, electroluminescent materials, and photovoltaics.

J.-C.G. Bünzli; S.V. Eliseeva

2013-01-01T23:59:59.000Z

272

Nuclear evaporation process with simultaneous multiparticle emission  

E-Print Network (OSTI)

The nuclear evaporation process is reformulated by taking into account simultaneous multiparticle emission from a hot compound nucleus appearing as an intermediate state in many nuclear reaction mechanisms. The simultaneous emission of many particles is particularly relevant for high excitation energy of the compound nucleus.These channels are effectively open in competition with the single particle emissions and fission in this energy regime. Indeed, the inclusion of these channels along the decay evaporating chain shows that the yield of charged particles and occurrence of fission are affected by these multiparticle emission processes of the compounded nucleus, when compared to the single sequential emission results. The effect also shows a qualitative change in the neutron multiplicity of different heavy compound nucleus considered. This should be an important aspect for the study of spallation reaction in Acceleration Driven System (ADS) reactors. The majority of neutrons generated in these reactions come from the evaporation stage of the reaction, the source of neutron for the system. A Monte Carlo simulation is employed to determine the effect of these channels on the particle yield and fission process. The relevance of the simultaneous particle emission with the increasing of excitation energy of the compound nucleus is explicitly shown.

Leonardo P. G. De Assis; Sergio B. Duarte; Bianca M. Santos

2012-08-07T23:59:59.000Z

273

Mitigating greenhouse gas emissions: Voluntary reporting  

SciTech Connect

The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

NONE

1997-10-01T23:59:59.000Z

274

Process for forming a metal compound coating on a substrate  

DOE Patents (OSTI)

A method of coating a substrate with a thin layer of a metal compound by forming a dispersion of an electrophoretically active organic colloid and a precursor of the metal compound in an electrolytic cell in which the substrate is an electrode. Upon application of an electric potential, the electrode is coated with a mixture of the organic colloid and the precursor to the metal compound, and the coated substrate is then heated in the presence of an atmosphere or vacuum to decompose the organic colloid and form a coating of either a combination of metal compound and carbon, or optionally forming a porous metal compound coating by heating to a temperature high enough to chemically react the carbon.

Sharp, Donald J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Wright, Steven A. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

275

Process for forming a metal compound coating on a substrate  

DOE Patents (OSTI)

A method of coating a substrate with a thin layer of a metal compound by forming a dispersion of an electrophoretically active organic colloid and a precursor of the metal compound in an electrolytic cell in which the substrate is an electrode. Upon application of an electric potential, the electrode is coated with a mixture of the organic colloid and the precursor to the metal compound, and the coated substrate is then heated in the presence of an atmosphere or vacuum to decompose the organic colloid and form a coating of either a combination of metal compound and carbon, or optionally forming a porous metal compound coating by heating to a temperature high enough to chemically react the carbon.

Sharp, D.J.; Vernon, M.E.; Wright, S.A.

1988-06-29T23:59:59.000Z

276

Impacts of reducing shipboard NOx? and SOx? emissions on vessel performance  

E-Print Network (OSTI)

The international maritime community has been experiencing tremendous pressures from environmental organizations to reduce the emissions footprint of their vessels. In the last decade, air emissions, including nitrogen ...

Caputo, Ronald J., Jr. (Ronald Joseph)

2010-01-01T23:59:59.000Z

277

Hydrocarbon emissions from industrial release events in the Houston-Galveston area and their impact on ozone formation  

Science Journals Connector (OSTI)

Ambient measurements have shown that ozone formation in the Houston-Galveston area of Texas is frequently much more rapid than in other urban areas. One of the contributing factors is believed to be short-term episodic or “event” emissions from industrial facilities, particularly releases that contain significant mass fractions of highly reactive volatile organic compounds (HRVOCs). In this work, time series analyses are used to compare average annual flow rates for air pollutant emissions with those released during reported emission events. The results indicate that the magnitude and frequency of HRVOC event emissions are an important element in accurately reflecting ozone precursor emission patterns in the Houston-Galveston area, particularly in Harris, Brazoria, Galveston, and Chambers counties. More than 50% of the reported episodic (event) emissions of \\{HRVOCs\\} are ethene and approximately a third are propene; the remainders are isomers of butene and 1,3-butadiene. Most events last less than 24 h. The mass released in an event can vary from a few hundred to more than 100,000 lb, and the dominant type of industrial source is chemical manufacturers (SIC 2869). Daily emissions from a single facility can vary from annual average emissions by multiple orders of magnitude at a frequency of several times a year. Because there are so many facilities in the Houston-Galveston area, HRVOC emission variability of this magnitude can be expected daily, at some time and some location in the Houston-Galveston area. If the emission variability occurs at times and locations where atmospheric conditions are conducive to ozone formation, both ambient data and photochemical modeling indicate that industrial emission events can lead to elevated concentrations of ozone. Specifically, peak, area-wide ozone concentration can be increased by as much as 100 ppb for large HRVOC emission events.

Cynthia Folsom Murphy; David T. Allen

2005-01-01T23:59:59.000Z

278

Control of insects and spider mites by translocated compounds  

E-Print Network (OSTI)

applied to soil could be detected in a bioassay method using Aedes larvae. Schrader (1947a), working in Germany during World War II, prepared several phosphorus and fluorine compounds that were shown to be systemic. These compounds were taken up... ............................ .. . . . 113 Attempts to Isolate a Toxic Principle from Plants Treated with Octamethyl Pyrophosphoramide ? ? ? ? ? ? . . ? 118 RELATIONSHIP BETWEEN CHEMICAL STRUCTURE AND SYSTEMIC ACTIVITY OF ORGANIC PHOSPHORUS COMPOUNDS............... 125 Derivatives...

Ivy, Edward Everett

2013-10-04T23:59:59.000Z

279

Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid Thermoelectrics  

Energy.gov (U.S. Department of Energy (DOE))

Demonstrates self-catalytic schemes for large-scale synthesis of compound semiconductor nanowire powders for inorganic-organic hybrid thermoelectric cells

280

Quantifying VOC emissions for the strategic petroleum reserve.  

SciTech Connect

A very important aspect of the Department of Energy's (DOE's) Strategic Petroleum Reserve (SPR) program is regulatory compliance. One of the regulatory compliance issues deals with limiting the amount of volatile organic compounds (VOCs) that are emitted into the atmosphere from brine wastes when they are discharged to brine holding ponds. The US Environmental Protection Agency (USEPA) has set limits on the amount of VOCs that can be discharged to the atmosphere. Several attempts have been made to quantify the VOC emissions associated with the brine ponds going back to the late 1970's. There are potential issues associated with each of these quantification efforts. Two efforts were made to quantify VOC emissions by analyzing VOC content of brine samples obtained from wells. Efforts to measure air concentrations were mentioned in historical reports but no data have been located to confirm these assertions. A modeling effort was also performed to quantify the VOC emissions. More recently in 2011- 2013, additional brine sampling has been performed to update the VOC emissions estimate. An analysis of the statistical confidence in these results is presented here. Arguably, there are uncertainties associated with each of these efforts. The analysis herein indicates that the upper confidence limit in VOC emissions based on recent brine sampling is very close to the 0.42 ton/MMB limit used historically on the project. Refining this estimate would require considerable investment in additional sampling, analysis, and monitoring. An analysis of the VOC emissions at each site suggests that additional discharges could be made and stay within current regulatory limits.

Knowlton, Robert G.; Lord, David L.

2013-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Organic light emitting device architecture for reducing the number of organic materials  

DOE Patents (OSTI)

An organic light emitting device is provided. The device includes an anode and a cathode. A first emissive layer is disposed between the anode and the cathode. The first emissive layer includes a first non-emitting organic material, which is an organometallic material present in the first emissive layer in a concentration of at least 50 wt %. The first emissive layer also includes a first emitting organic material. A second emissive layer is disposed between the first emissive layer and the cathode, preferably, in direct contact with the first emissive layer. The second emissive material includes a second non-emitting organic material and a second emitting organic material. The first and second non-emitting materials, and the first and second emitting materials, are all different materials. A first non-emissive layer is disposed between the first emissive layer and the anode, and in direct contact with the first emissive layer. The first non- emissive layer comprises the first non-emissive organic material.

D'Andrade, Brian (Westampton, NJ); Esler, James (Levittown, PA)

2011-10-18T23:59:59.000Z

282

Exploratory and Newer Compounds  

Science Journals Connector (OSTI)

In writing a chapter on “Exploratory and Newer Compounds” in a book concerned with anesthesia, the authors feel that it is most important to have a clear idea of the aims of their work. The “Why?” must never b...

T. H. S. Burns; A. Bracken

1972-01-01T23:59:59.000Z

283

Heart testing compound  

DOE Patents (OSTI)

The compound 15-(p-[.sup.125 I]-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, Jr., Furn F. (Oak Ridge, TN); Goodman, Mark M. (Knoxville, TN)

1985-01-01T23:59:59.000Z

284

Heart testing compound  

DOE Patents (OSTI)

The compound 15-(p-(/sup 125/I)-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, F.F. Jr.; Goodman, M.M.

1983-06-29T23:59:59.000Z

285

Chemical Emissions of Residential Materials and Products: Review of Available Information  

SciTech Connect

This report is prepared in the context of a larger program whose mission is to advance understanding of ventilation and indoor air quality in U.S. homes. A specific objective of this program is to develop the scientific basis ? through controlled experiments, monitoring and analysis ? for health risk-based ventilation standards. Appropriate and adequate ventilation is a basic element of a healthy home. Ventilation provides outdoor air and in the process removes indoor odors and contaminants including potentially unhealthful chemicals emitted by indoor materials, products and activities. Ventilation traditionally was assured to occur via infiltration of outdoor air through cracks and other leakage pathways in the residential building envelope. As building air tightness is improved for energy efficiency, infiltration can be reduced to inadequate levels. This has lead to the development of standards requiring mechanical ventilation. Though nominally intended to ensure acceptable indoor air quality, the standards are not explicitly tied to health risk or pollutant exposure targets. LBNL is currently designing analyses to assess the impact of varying ventilation standards on pollutant concentrations, health risks and energy use. These analyses require information on sources of chemical pollutant emissions, ideally including emission rates and the impact of ventilation on emissions. Some information can be obtained from recent studies that report measurements of various air contaminants and their concentrations in U.S. residences. Another way to obtain this information is the bottom-up approach of collecting and evaluating emissions data from construction and interior materials and common household products. This review contributes to the latter approach by summarizing available information on chemical emissions from new residential products and materials. We review information from the scientific literature and public sources to identify and discuss the databases that provide information on new or low-emission materials and products. The review focuses on the primary chemical or volatile organic compound (VOC) emissions from interior surface materials, furnishings, and some regularly used household products; all of these emissions are amenable to ventilation. Though it is an important and related topic, this review does not consider secondary pollutants that result from reactions of ozone and unsaturated organics bound to or emitted from material surfaces. Semi-volatile organic compounds (SVOCs) have been largely excluded from this review because ventilation generally is not an effective way to control SVOC exposures. Nevertheless, health concerns about exposures to SVOCs emitted from selected materials warrant some discussion.

Willem, Henry; Singer, Brett

2010-09-15T23:59:59.000Z

286

E-Print Network 3.0 - aromatic hydrocarbon compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

287

E-Print Network 3.0 - aromatic chemical compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... in burn pits include, but...

288

Laboratory scale studies on gaseous emissions generated by the incineration of an artificial automotive shredder residue presenting a critical composition  

Science Journals Connector (OSTI)

Car manufacturers must eliminate automotive shredder residues (ASR). Two ways of incineration are of interest: at 850°C in municipal waste incinerators or at higher temperatures, above 1100°C in cement plants. These processes reduce the mass and the volume of waste to be disposed of in landfills and energy recovery might be possible. Regulations govern the emission of gaseous effluents to control environmental risk. To determine gaseous effluents from a pilot sacle or an industrial incineration plant, an artificial ASR was made by mixing three representative organic polymers present in the real ASR, namely polyvinylchloride, polyurethane and rubber. This mixture was incinerated at 850 and 1100°C in laboratory experiments and the analyses of the principal gaseous effluents such as carbon oxides, nitrogen oxides, volatile organic compounds, hydrochloric and hydrocyanic acids and sulphur compounds are presented and discussed. Lastly, in order to simulate artificial ASR behaviour, the composition of the combustion gases at equilibrium was calculated using a Gibbs energy minimisation code.

D. Lanoir; G. Trouvé; L. Delfosse

1997-01-01T23:59:59.000Z

289

Organic Vegetable Organic Vegetable  

E-Print Network (OSTI)

marketed separately from conventionally grown produce in order to be profitably sold. Because of the amount of organic material include compost, Purdue University · Cooperative Extension Service · Knowledge to Go

290

Charge Density Wave Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Fisher Research Group Fisher Research Group Layered Chalcogenides 29 February 2008 Controlling the Wave by Brad Plummer, SLAC Communications Stanford University researchers working in part at SSRL have discovered a novel set of properties pertaining to a compound of materials called tritellurides. These compounds, composed of three atoms of tellurium and a single atom of one of the rare earth elements, demonstrate unique electronic properties that can be controlled by altering the temperature of the material. The tritellurides display phenomena known as charge density waves (CDW). In a normal conductive metal, electrons persist in a "sea" wherein they are evenly distributed and equally available, or conductive. A CDW occurs under certain circumstances and causes the electrons to clump together, lowering their availability, and thereby lowering the compound's conductivity. Tellurium, when crystallized into quasi-two-dimensional planes and combined with rare earth elements, produces a material with CDWs that can be manipulated and controlled.

291

IGES GHG Emissions Data | Open Energy Information  

Open Energy Info (EERE)

IGES GHG Emissions Data IGES GHG Emissions Data Jump to: navigation, search Tool Summary LAUNCH TOOL Name: IGES GHG Emissions Data Agency/Company /Organization: Institute for Global Environmental Strategies Sector: Energy Topics: Baseline projection, GHG inventory Resource Type: Dataset Website: www.iges.or.jp/en/cdm/report_kyoto.html References: IGES GHG Emissions Data[1] Summary "IGES GHG Emissions Data is aimed at providing comprehensive, organised information on the GHG emissions from Annex I countries to the UNFCCC in an easy-to-understand way. All information is extracted from the publicly available sources on the UNFCCC web-site and this data will be updated regularly. " References ↑ "IGES GHG Emissions Data" Retrieved from "http://en.openei.org/w/index.php?title=IGES_GHG_Emissions_Data&oldid=383109"

292

Microoptical compound lens  

DOE Patents (OSTI)

An apposition microoptical compound lens comprises a plurality of lenslets arrayed around a segment of a hollow, three-dimensional optical shell. The lenslets collect light from an object and focus the light rays onto the concentric, curved front surface of a coherent fiber bundle. The fiber bundle transports the light rays to a planar detector, forming a plurality of sub-images that can be reconstructed as a full image. The microoptical compound lens can have a small size (millimeters), wide field of view (up to 180.degree.), and adequate resolution for object recognition and tracking.

Sweatt, William C. (Albuquerque, NM); Gill, David D. (Albuquerque, NM)

2007-10-23T23:59:59.000Z

293

Full Useful Life (120,000 miles) Exhaust Emission Performance...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A4 Avant Chevrolet Silverado APBF-DEC Organization DOE, EPA, additive companies, automobile manufacturers, engine manufacturers, energy companies, emission control mfrs.,...

294

Guidelines for Low Emission Land use Planning | Open Energy Informatio...  

Open Energy Info (EERE)

Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Guidelines for Low Emission Land use Planning AgencyCompany Organization: USAID LEAF Sector: Climate, Land...

295

Thailand-Enhancing Capacity for Low Emission Development Strategies...  

Open Energy Info (EERE)

Enhancing Capacity for Low Emission Development Strategies (EC-LEDS) AgencyCompany Organization United States Agency for International Development, United States Environmental...

296

China-Quantifying Emission Reduction Opportunities in Emerging...  

Open Energy Info (EERE)

Economies AgencyCompany Organization Ecofys Sector Energy Topics Background analysis, GHG inventory, Low emission development planning, Pathways analysis Website http:...

297

The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary...  

Open Energy Info (EERE)

search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary Combustion AgencyCompany Organization: World Resources...

298

The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport...  

Open Energy Info (EERE)

search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport or Mobil Sources AgencyCompany Organization: World Resources...

299

South Africa-Quantifying Emission Reduction Opportunities in...  

Open Energy Info (EERE)

Economies AgencyCompany Organization Ecofys Sector Energy Topics Background analysis, GHG inventory, Low emission development planning, Pathways analysis Website http:...

300

Verifying Greenhouse Gas Emissions: Methods to Support International...  

Open Energy Info (EERE)

Greenhouse Gas Emissions: Methods to Support International Climate Agreements AgencyCompany Organization: Board on Atmospheric Sciences and Climate Sector: Energy, Land...

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

South Africa - Greenhouse Gas Emission Baselines and Reduction...  

Open Energy Info (EERE)

Potentials from Buildings Jump to: navigation, search Name South Africa - Greenhouse Gas Emission Baselines and Reduction Potentials from Buildings AgencyCompany Organization...

302

Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation  

Open Energy Info (EERE)

Greenhouse Gas Emissions and Mitigation Greenhouse Gas Emissions and Mitigation Potential in Agriculture Jump to: navigation, search Logo: Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation Potential in Agriculture (MAGHG) Name Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation Potential in Agriculture (MAGHG) Agency/Company /Organization Food and Agriculture Organization of the United Nations Sector Climate, Land Focus Area Agriculture, Greenhouse Gas Topics GHG inventory, Low emission development planning, -LEDS Resource Type Dataset, Technical report Website http://www.fao.org/climatechan References MICCA Website[1] The overall objective of the MAGHG project is to support developing countries assess and report their greenhouse gas (GHG) emissions from

303

Unsaturated macrocyclic carbonyl bridge compounds  

Science Journals Connector (OSTI)

Unsaturated macrocyclic carbonyl bridge compounds ... Catalytic Ring-Closing Metathesis of Doubly Armed, Bridged Bicyclic Sulfones. ...

C. F. H. Allen; J. A. VanAllan

1953-07-01T23:59:59.000Z

304

Measurement of emission fluxes from Technical Area 54, Area G and L. Final report  

SciTech Connect

The emission flux (mass/time-area) of tritiated water from TA-54 was measured to support the characterization of radioactive air emissions from waste sites for the Radioactive Air Emissions Management (RAEM) program and for the Area G Performance Assessment. Measurements were made at over 180 locations during the summers of 1993 and 1994, including randomly selected locations across Area G, three suspected areas of contamination at Area G, and the property surrounding TA-54. The emission fluxes of radon were measured at six locations and volatile organic compounds (VOCs) at 30 locations. Monitoring was performed at each location over a several-hour period using the U.S. EPA flux chamber approach. Separate samples for tritiated water, radon, and VOCs were collected and analyzed in off-site laboratories. The measured tritiated water emission fluxes varied over several orders of magnitude, from background levels of about 3 pCi/m{sup 2}-min to 9.69 x 10{sup 6} pCi/m{sup 2}-min near a disposal shaft. Low levels of tritiated water were found to have migrated into Pajarito Canyon, directly south of Area G. The tritium flux data were used to generate an estimated annual emission rate of 14 Curies/yr for all of Area G, with the majority of this activity being emitted from relatively small areas adjacent to several disposal shafts. The estimated total annual release is less than 1% of the total tritium release from all LANL in 1992 and results in a negligible off-site dose. Based on the limited data available, the average emission flux of radon from Area G is estimated to be 8.1 pCi/m{sup 2}-min. The measured emission fluxes of VOCs were < 100 {mu}g/m{sup 2}-min, which is small compared with fluxes typically measured at hazardous waste landfills. The air quality impacts of these releases were evaluated in a separate report.

Eklund, B. [Radian Corp., Austin, TX (United States)

1995-03-15T23:59:59.000Z

305

Compound floating pivot micromechanisms  

DOE Patents (OSTI)

A new class of tilting micromechanical mechanisms have been developed. These new mechanisms use compound floating pivot structures to attain far greater tilt angles than are practical using other micromechanical techniques. The new mechanisms are also capable of bi-directional tilt about multiple axes.

Garcia, Ernest J. (Albuquerque, NM)

2001-04-24T23:59:59.000Z

306

IPCC Emission Factor Database | Open Energy Information  

Open Energy Info (EERE)

IPCC Emission Factor Database IPCC Emission Factor Database Jump to: navigation, search Tool Summary Name: IPCC Emission Factor Database Agency/Company /Organization: World Meteorological Organization, United Nations Environment Programme Resource Type: Dataset Website: www.ipcc-nggip.iges.or.jp/EFDB/main.php References: IPCC-EFDB[1] About "EFDB is meant to be a recognised library, where users can find emission factors and other parameters with background documentation or technical references that can be used for estimating greenhouse gas emissions and removals. The responsibility of using this information appropriately will always remain with the users themselves." References ↑ "IPCC-EFDB" Retrieved from "http://en.openei.org/w/index.php?title=IPCC_Emission_Factor_Database&oldid=367213"

307

Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 1, Main text  

SciTech Connect

This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO{sub 2}), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO{sub 2}-equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO{sub 2}-equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles.

DeLuchi, M.A. [California Univ., Davis, CA (United States)

1991-11-01T23:59:59.000Z

308

Radon emissions  

Science Journals Connector (OSTI)

... SIR,-Wendy Barnaby (August 28) writes on the problem of radon emission from the tailings of uranium milling in Sweden. This problem would arise from ... that has to be treated. She describes Professor Robert O. Pohl's report that "radon can escape more easily from the broken ground of a mine than from an undisturbed ...

SVEN-ERIC BRUNNSJO

1975-10-09T23:59:59.000Z

309

Gas Emissions FLOODING THE LAND,  

E-Print Network (OSTI)

signif- icant sources of emissions of the greenhouse gases carbon dioxide and, in particular, methane to bacteria breaking down organic matter in the water. Methane, a much more powerful greenhouse gas than coal plants generating the same amounts of power. Dams and their associated reservoirs are globally

Batiste, Oriol

310

Impact of additives for enhanced sulfur dioxide removal on re-emissions of mercury in wet flue gas desulfurization  

Science Journals Connector (OSTI)

Abstract The wet flue gas desulfurization process (FGD) in fossil fired power plants offers the advantage of simultaneously removing SO2 and other water soluble pollutants, such as certain oxidized mercury compounds (Hg2+). In order to maximize SO2 removal efficiency of installed FGD units, organic additives can be utilized. In the context of multi-pollutant control by wet FGD, the effect of formic and adipic acid on redox reactions of dissolved mercury compounds is investigated with a continuously operated lab-scale test-rig. For sulfite ( SO 3 2 - ) concentrations above a certain critical value, their potential as reducing agent leads to rapidly increasing formation and re-emission of elemental mercury (Hg0). Increasing chloride concentration and decreasing pH and slurry temperature have been identified as key factors for depressing Hg0 re-emissions. Both organic additives have a negative impact on Hg-retention and cause increased Hg0 re-emissions in the wet FGD process, with formic acid being the significantly stronger reducing agent. Different pathways of Hg2+ reduction were identified by qualitative interpretation of the pH-dependence and by comparison of activation enthalpies and activation entropies. While the first mechanism proposed identifies SO 3 2 - as reducing agent and is therefore relevant for any FGD process, the second mechanism involves the formate anion, thus being exclusively relevant for \\{FGDs\\} utilizing formic acid as additive.

Barna Heidel; Melanie Hilber; Günter Scheffknecht

2014-01-01T23:59:59.000Z

311

Air toxic emissions from the combustion of coal: Identifying and quantifying hazardous air pollutants from US coals  

SciTech Connect

This report addresses the key air toxic emissions likely to emanate from continued and expanded use of domestic coal. It identifies and quantifies those trace elements specified in the US 1990 Clean Air Act Amendments, by tabulating selected characterization data on various source coals by region, state, and rank. On the basis of measurements by various researchers, this report also identifies those organic compounds likely to be derived from the coal combustion process (although their formation is highly dependent on specific boiler configurations and operating conditions).

Szpunar, C.B.

1992-09-01T23:59:59.000Z

312

Urban Transportation Emission Calculator | Open Energy Information  

Open Energy Info (EERE)

Urban Transportation Emission Calculator Urban Transportation Emission Calculator Jump to: navigation, search Tool Summary Name: Urban Transportation Emission Calculator Agency/Company /Organization: Transport Canada Sector: Energy Focus Area: Transportation Topics: GHG inventory Resource Type: Software/modeling tools User Interface: Website Website: wwwapps.tc.gc.ca/Prog/2/UTEC-CETU/Menu.aspx?lang=eng Cost: Free References: http://wwwapps.tc.gc.ca/Prog/2/UTEC-CETU/Menu.aspx?lang=eng The Urban Transportation Emissions Calculator (UTEC) is a user-friendly tool for estimating annual emissions from personal, commercial, and public transit vehicles. It estimates greenhouse gas (GHG) and criteria air contaminant (CAC) emissions from the operation of vehicles. It also estimates upstream GHG emissions from the production, refining and

313

Polybenzimidazole Compounds, Polymeric Media, and Methods of Post-Polymerization Modifications  

INL has developed a patented process to handle and process polybenzimdazole (PBI) compounds that previously could only be handled in very heavy low vapor pressure organic solvents. With the new process the resulting compounds are modified to provide increased solubility in higher vapor pressure solvents and at significantly greater concentrations. These compounds may be utilized in a wide array of applications where high temperature and polymeric materials are utilized. Compounds made with...

2014-06-11T23:59:59.000Z

314

Science Organizations  

NLE Websites -- All DOE Office Websites (Extended Search)

Organizations Science Organizations National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place...

315

Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of  

E-Print Network (OSTI)

Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed 19, 2012 (received for review July 22, 2012) Emissions from gasoline and diesel vehicles composition, mass distribu- tion, and organic aerosol formation potential of emissions from gasoline

Silver, Whendee

316

Sources of Naphthalene in Diesel Exhaust Emissions  

Science Journals Connector (OSTI)

The sale of diesels now account for 20% of new car sales in the UK compared with just 6% in 1990.1 The increased popularity of diesel cars is in part owing to improved engine performance in terms of power output, greater fuel economy, and an improved public image in terms of noise and pollution levels. ... Diesel engines have greater emissions of particulate material than corresponding spark ignition (SI) engines. ... An understanding of the origin of PAH in diesel exhaust emissions is fundamental if adequate control of the emission of these compounds is to be achieved. ...

M. M. Rhead; R. D. Pemberton

1996-05-21T23:59:59.000Z

318

CHARACTERISTICS Nitrated compounds constitute a  

E-Print Network (OSTI)

compounds. If there is a chance of an explosive reaction, conduct the operation behind a blast shield

Wilcock, William

319

Naming chemical compounds: Calculator drill  

Science Journals Connector (OSTI)

36. Bits and pieces, 13. A calculator can be programmed to drill students on chemical compound naming rules.

David Holdsworth; Evelyn Lacanienta

1983-01-01T23:59:59.000Z

320

Organic Separation Test Results  

SciTech Connect

Separable organics have been defined as “those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer” (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be “no visible layer” of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2014-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Boronated porphyrin compounds  

DOE Patents (OSTI)

A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

Kahl, S.B.; Koo, M.S.

1992-09-22T23:59:59.000Z

322

Boronated porphyrin compounds  

DOE Patents (OSTI)

A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

Kahl, Stephen B. (Portola Valley, CA); Koo, Myoung-Seo (San Francisco, CA)

1992-01-01T23:59:59.000Z

323

Organization | Department of Energy  

Energy Savers (EERE)

About Us Organization Organization Organization Printable PDF News & Blog CIO Leadership Organization Contact Us...

324

Organization | Department of Energy  

Office of Environmental Management (EM)

About Us Organization Organization Organization News Leadership Organization History Careers Contact Us...

325

Synthesis and thermal studies of flexible polyurethane nanocomposite foams obtained using nanoclay modified with flame retardant compound  

Science Journals Connector (OSTI)

This work presents thermal studies of nanocomposites based on the flexible polyurethane (PU) matrix and filled using montmorillonite organically modified with organophosphorus flame retardant compound. Flexibl...

?ukasz Piszczyk; Magdalena Danowska…

2014-11-01T23:59:59.000Z

326

2 Extracting and trapping biogenic 3 volatile organic compounds stored  

E-Print Network (OSTI)

, Subcritical water extraction; UAE, Ultrasound-assisted extraction 36 1. Introduction Plants release

Goldstein, Allen

327

Glossary of Volatile Organic Compounds Ethylbenzene Carbon tetrachloride  

E-Print Network (OSTI)

;Ethylbenzene Ethylbenzene is a colorless, flammable liquid found in natural products such as coal tar and petroleum. It is also found in manufactured products such as inks, insecticides, and paints. Ethylbenzene in the air. In surface water, ethylbenzene breaks down by reacting with other chemicals found naturally

328

The Effect of Organic Compounds in Pot Experiments.  

E-Print Network (OSTI)

SUBSTATIONS P. L. DowNs, President, Temple.. . .. ................... .. .. ... ... . ... .. .. .. .. ... .. .. ... .. ... ... .. . ...... Term expires 1919 CHARLES RoGAN, Vice Preszdenl, Austin...... ... .. .. .. . Term expires 1917 W . P. HoBBY, Beaumont... Secretary CHAS. A. FELKER, Chief Clerk J. H. RoGERS, Inspector W. H. WooD, Inspector T. H. WoLTERS, Inspector S. D. PEARCE, Inspector J. M. ScHAEDEL, Inspector W. M. WICKES, Inspector SUBSTATION NO. 1: Beeville, Bee County E. E .. BINFORD, B. S...

Fraps, G. S.

1915-01-01T23:59:59.000Z

329

Degradation of organic phosphorus compounds in anoxic Baltic Sea ...  

Science Journals Connector (OSTI)

Public Affairs · Join the Policy Action Network · Science Education · Science ... in anoxic Baltic Sea sediments: A 31P nuclear magnetic resonance study. Ahlgren ...

330

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET...  

NLE Websites -- All DOE Office Websites (Extended Search)

to the target list or not, according to proposed language in Permit Attachment N. If a TIC is determined to contribute more than one percent of the risk, then it will be added to...

331

Biodegradation of organic compounds in vadose zone and aquifer sediments.  

Science Journals Connector (OSTI)

...rotary head. Conventional, steam-cleaned, hollow-stem augers...phos- phorus, by using the ignition method (34); total nitrogen...mineral nitrogen, by using steam distillation (22); and exchangeable...substrates. This suggestion is based on the assumption that the affinities...

A Konopka; R Turco

1991-08-01T23:59:59.000Z

332

Nanoparticle Formation of Organic Compounds With Retained Biological Activity  

E-Print Network (OSTI)

of Pediatric, Radiology, Microbiology and Immunology, Stanford University School of Medicine, 318 Campus Drive

Zare, Richard N.

333

Three-Dimensional Simulation of Volatile Organic Compound Mass...  

NLE Websites -- All DOE Office Websites (Extended Search)

simulations using data from the U.S. Department of Energy’s Hanford Site, where carbon tetrachloride is present in a low permeability zone about 30 m above the...

334

CHP Emissions Reduction Estimator | Open Energy Information  

Open Energy Info (EERE)

CHP Emissions Reduction Estimator CHP Emissions Reduction Estimator Jump to: navigation, search Tool Summary LAUNCH TOOL Name: CHP Emissions Reduction Estimator Agency/Company /Organization: United States Environmental Protection Agency Sector: Energy Focus Area: Buildings, Transportation, Industry Topics: GHG inventory, Co-benefits assessment Resource Type: Software/modeling tools User Interface: Spreadsheet Website: www.epa.gov/chp/basic/calculator.html Country: United States UN Region: Northern America CHP Emissions Reduction Estimator Screenshot References: http://www.epa.gov/chp/basic/calculator.html "This Emissions Estimator provides the amount of reduced emissions in terms of pounds of CO2, SO2, and NOX based on input from the User regarding the CHP technology being used. In turn the User will be provided with

335

the International Civil Aviation Organization (ICAO) adopted a resolution that not only accepted a long-term strat-egy for reducing emissions but also excluded language intended to prevent unilateral application of EU legislation  

E-Print Network (OSTI)

of atmospheric pollution, airliners cross many borders and fly through many regula- tory jurisdictions a long-term strat- egy for reducing emissions but also excluded language intended to prevent unilateral-standing disagreement between in- dustrialized and developing countries about preventing climate change. Secondly

Sibille, Etienne

336

Organic light emitting device structure for obtaining chromaticity stability  

DOE Patents (OSTI)

The present invention relates to organic light emitting devices (OLEDs). The devices of the present invention are efficient white or multicolored phosphorescent OLEDs which have a high color stability over a wide range of luminances. The devices of the present invention comprise an emissive region having at least two emissive layers, with each emissive layer comprising a different host and emissive dopant, wherein at least one of the emissive dopants emits by phosphorescence.

Tung, Yeh-Jiun (Princeton, NJ); Ngo, Tan (Levittown, PA)

2007-05-01T23:59:59.000Z

337

DOE Hydrogen Analysis Repository: Emissions Analysis of Electricity Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions Analysis of Electricity Storage with Hydrogen Emissions Analysis of Electricity Storage with Hydrogen Project Summary Full Title: Emissions Analysis of Electricity Storage with Hydrogen Project ID: 269 Principal Investigator: Amgad Elgowainy Brief Description: Argonne National Laboratory examined the potential fuel cycle energy and emissions benefits of integrating hydrogen storage with renewable power generation. ANL also examined the fuel cycle energy use and emissions associated with alternative energy storage systems, including pumped hydro storage (PHS), compressed air energy storage (CAES), and vanadium-redox batteries (VRB). Keywords: Hydrogen; Emissions; Greenhouse gases (GHG); Energy storage; Life cycle analysis Performer Principal Investigator: Amgad Elgowainy Organization: Argonne National Laboratory (ANL)

338

CDM Emission Reductions Calculation Sheet Series | Open Energy Information  

Open Energy Info (EERE)

CDM Emission Reductions Calculation Sheet Series CDM Emission Reductions Calculation Sheet Series Jump to: navigation, search Tool Summary LAUNCH TOOL Name: CDM Emission Reductions Calculation Sheet Series Agency/Company /Organization: Institute for Global Environmental Strategies Sector: Energy, Water Focus Area: Agriculture, Greenhouse Gas Topics: Baseline projection, GHG inventory Resource Type: Online calculator User Interface: Spreadsheet Website: www.iges.or.jp/en/cdm/report_ers.html Cost: Free CDM Emission Reductions Calculation Sheet Series Screenshot References: CDM Emission Reductions Calculation Sheet Series[1] "IGES ERs Calculation Sheet aims at providing a simplified spreadsheet for demonstrating emission reductions based on the approved methodologies corresponding to eligible project activities. The sheet will provide you

339

Quantifying Greenhouse Gas Emissions from Transit | Open Energy Information  

Open Energy Info (EERE)

Quantifying Greenhouse Gas Emissions from Transit Quantifying Greenhouse Gas Emissions from Transit Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Quantifying Greenhouse Gas Emissions from Transit Agency/Company /Organization: American Public Transportation Association Focus Area: GHG Inventory Development Topics: Analysis Tools Resource Type: Reports, Journal Articles, & Tools Website: www.aptastandards.com/Portals/0/SUDS/SUDSPublished/APTA_Climate_Change This Recommended Practice provides guidance to transit agencies for quantifying their greenhouse gas emissions, including both emissions generated by transit and the potential reduction of emissions through efficiency and displacement How to Use This Tool This tool is most helpful when using these strategies: Shift - Change to low-carbon modes

340

Harmonized Emissions Analysis Tool (HEAT) | Open Energy Information  

Open Energy Info (EERE)

Harmonized Emissions Analysis Tool (HEAT) Harmonized Emissions Analysis Tool (HEAT) Jump to: navigation, search Tool Summary Name: Harmonized Emissions Analysis Tool (HEAT) Agency/Company /Organization: Local Governments for Sustainability Sector: Energy, Land Topics: Co-benefits assessment, - Health, GHG inventory, Implementation, Pathways analysis Resource Type: Software/modeling tools User Interface: Website Complexity/Ease of Use: Moderate Website: www.environmenttools.co.uk/directory/tool/name/harmonized-emissions-an Cost: Free Harmonized Emissions Analysis Tool (HEAT) Screenshot References: ICLEI-HEAT[1] Related Tools Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Prospective Outlook on Long-Term Energy Systems (POLES) ICCT Roadmap Model ... further results Find Another Tool

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

On The Importance of Organic Oxygen for Understanding Organic Aerosol  

NLE Websites -- All DOE Office Websites (Extended Search)

On The Importance of Organic Oxygen for Understanding Organic Aerosol On The Importance of Organic Oxygen for Understanding Organic Aerosol Particles Title On The Importance of Organic Oxygen for Understanding Organic Aerosol Particles Publication Type Journal Article Year of Publication 2006 Authors Pang, Yanbo, B. J. Turpin, and Lara A. Gundel Journal Journal of Aerosol Science and Technology Volume 40 Start Page Chapter Pagination 128-133 Abstract This study shows how aerosol organic oxygen data could provide new and independent information about organic aerosol mass, aqueous solubility of organic aerosols, formation of secondary organic aerosol (SOA) and the relative contributions of anthropogenic and biogenic sources. For more than two decades atmospheric aerosol organic mass concentration has usually been estimated by multiplying the measured carbon content by an assumed organic mass (OM)-to-organic carbon (OC ) factor of 1.4. However, this factor can vary from 1.0 to 2.5 depending on location. This great uncertainty about aerosol organic mass limits our understanding of the influence of organic aerosol on climate, visibility and health.New examination of organic aerosol speciation data shows that the oxygen content is the key factor responsible for the observed range in the OM-to-OC factor. When organic oxygen content is excluded, the ratio of non-oxygen organic mass to carbon mass varies very little across different environments (1.12 to 1.14). The non-oxygen-OM-to-non-oxygen OC factor for all studied sites (urban and non-urban) is 1.13± 0.02. The uncertainty becomes an order of magnitude smaller than the uncertainty in the best current estimates of organic mass to organic carbon ratios (1.6± 0.2 for urban and 2.1± 0.2 for non-urban areas). When aerosol organic oxygen data become available, organic aerosol mass can be quite accurately estimated using just OC and organic oxygen (OO) without the need to know whether the aerosol is fresh or aged. In addition, aerosol organic oxygen data will aid prediction of water solubility since compounds with OO-to-OC higher than 0.4 have water solubilities higher than 1g per 100 g water

342

The design of new ligands and transition metal compounds for the oxidation of organic compounds  

E-Print Network (OSTI)

..................................... 2 1.3 Epoxidation of ?,?-unsaturated carboxylic acids with catalytic sodium tungstate and hydrogen peroxide ........................................ 3 1.4 The Sharpless asymmetric epoxidation reaction.............................. 4 1.5... as Jacobsen?s catalyst 1-3 but generally only olefins with cis geometry or trisubstituted olefins are epoxidized in high ee. 6 Scheme 1.5. Salen ligands A crystallographic study of these catalysts provides valuable insight...

Grill, Joseph Michael

2009-06-02T23:59:59.000Z

343

Organizations and Networks | Open Energy Information  

Open Energy Info (EERE)

Organizations and Networks Organizations and Networks (Redirected from Gateway:International/Networks) Jump to: navigation, search Registered Technical and Research Organizations Networks Climate Eval "The website promotes active debate on areas relevant to evaluation of climate change and development evaluation by bringing relevant topics to a peer to peer discussion forum." Coordinated Low Emissions Assistance Network (CLEAN) CLEAN aims to improve communication and coordination by bringing together national and international organizations that are assisting developing countries with preparation and implementation of low greenhouse gas emission plans and strategies. This includes support for technology needs assessments, for low carbon and clean energy development plans, and

344

Generation of low work function, stable compound thin films by laser ablation  

DOE Patents (OSTI)

Generation of low work function, stable compound thin films by laser ablation. Compound thin films with low work function can be synthesized by simultaneously laser ablating silicon, for example, and thermal evaporating an alkali metal into an oxygen environment. For example, the compound thin film may be composed of Si/Cs/O. The work functions of the thin films can be varied by changing the silicon/alkali metal/oxygen ratio. Low work functions of the compound thin films deposited on silicon substrates were confirmed by ultraviolet photoelectron spectroscopy (UPS). The compound thin films are stable up to 500.degree. C. as measured by x-ray photoelectron spectroscopy (XPS). Tests have established that for certain chemical compositions and annealing temperatures of the compound thin films, negative electron affinity (NEA) was detected. The low work function, stable compound thin films can be utilized in solar cells, field emission flat panel displays, electron guns, and cold cathode electron guns.

Dinh, Long N. (Concord, CA); McLean, II, William (Oakland, CA); Balooch, Mehdi (Berkeley, CA); Fehring, Jr., Edward J. (Dublin, CA); Schildbach, Marcus A. (Livermore, CA)

2001-01-01T23:59:59.000Z

345

Source Emissions and Transport  

NLE Websites -- All DOE Office Websites (Extended Search)

electron micrograph image, Lara Gundel with instrumentation electron micrograph image, Lara Gundel with instrumentation Source Emissions and Transport Investigators conduct research here to characterize and better understand the sources of airborne volatile, semi-volatile and particulate organic pollutants in the indoor environment. This research includes studies of the physical and chemical processes that govern indoor air pollutant concentrations and exposures. The motivation is to contribute to the reduction of potential human health effects. Contacts Randy Maddalena RLMaddalena@lbl.gov (510) 486-4924 Mark Mendell MJMendell@lbl.gov (510) 486-5762 Links Pollutant Sources, Dynamics and Chemistry Group Batteries and Fuel Cells Buildings Energy Efficiency Electricity Grid Energy Analysis Energy Technologies Environmental Impacts

346

Chemoprevention by Fruit Phenolic Compounds  

Science Journals Connector (OSTI)

This chapter summarizes available information on the chemopreventive effects of fruit phenolic compounds in various experimental systems. Emphasis is placed on the anticarcinogenic activity of these phenolics ...

Gary D. Stoner PhD; Bruce C. Casto ScD

2004-01-01T23:59:59.000Z

347

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

348

Characterization of the crude oil polar compound extract  

SciTech Connect

This research is designed to determine if there are any naturally occurring constituents in crude oils that can be chemically altered to bring about increased oil production. An extract containing only the polar organic compounds of the crude oil was obtained by using a modification of the ASTM-2007 procedure. Chemical characterization of the polar compounds were carried out using high pressure liquid chromatography (HPLC) and gas chromatography. The HPLC analyses indicated a range of polar organic compound content of 10 crude oils from 1.6% to 12.7%. Wettability determinations show that by adding a small amount of the polar fraction from a crude oil, to a mineral oil, a 40 to 111% change of wettability toward a more oil-wet system will occur, depending on the specific extract used.

Donaldson, E.C.; Crocker, M.E.

1980-10-01T23:59:59.000Z

349

Emissivity Correcting Pyrometry of Semiconductor Growth  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissivity Correcting Pyrometry of Semiconductor Growth Emissivity Correcting Pyrometry of Semiconductor Growth by W. G. Breiland, L. A. Bruskas, A. A. Allerman, and T. W. Hargett Motivation-Temperature is a critical factor in the growth of thin films by either chemical vapor deposition (CVD) or molecular beam epitaxy (MBE). It is particularly important in compound semiconductor growth because one is often challenged to grow materials with specific chemical compositions in order to maintain stringent lattice-matching conditions or to achieve specified bandgap values. Optical pyrometry can be used to measure surface temperatures, but the thin film growth causes significant changes in the emissivity of the surface, leading to severe errors in the pyrometer measurement. To avoid these errors, emissivity changes must be measured and

350

Vehicle Emissions Review - 2011  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emissions Review - 2011 (so far) Tim Johnson October 4, 2011 DOE DEER Conference, Detroit JohnsonTV@Corning.com 2 Summary * California LD criteria emission regs are tightening....

351

Property:Event/Organizer | Open Energy Information  

Open Energy Info (EERE)

Organizer Organizer Jump to: navigation, search Property Name Event/Organizer Property Type String Description The entity or entities responsible for organizing the event. This is typically a person or organization. More than one organizer can be attributed to each event. Pages using the property "Event/Organizer" Showing 25 pages using this property. (previous 25) (next 25) 1 11th Annual Workshop on Greenhouse Gas Emission Trading + International Energy Agency (IEA) + 11th Annual Workshop on Greenhouse Gas Emission Trading Day 2 + International Energy Agency (IEA) + 15th International Business Forum: Low Carbon High Growth - Business Models for a Changing Climate + German Agency for International Cooperation (GIZ) + 18th Africa Partnership Forum + African Partnership Forum +

352

EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

2. Carbon Dioxide Emissions 2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors contributing to the decrease in carbon dioxide emissions in 2009 included an economy in recession with a decrease in gross domestic product of 2.6 percent, a decrease in the energy intensity of the economy of 2.2 percent, and a decrease in the carbon intensity of energy supply of

353

A series of novel metal–organic coordination polymers constructed from the new 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole spacer and aromatic carboxylates: Synthesis, crystal structures, and luminescence properties  

SciTech Connect

Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers, [Zn(L)(1,4-bdc){sub 0.5}] (1), [Zn{sub 1.5}(L)(2,5-pydc)] (2), [Zn(HL)(1,2,4,5-btec){sub 0.5}] (3), and [Cd(HL)(1,2,4,5-btec){sub 0.5}] (4) (1,4-bdc, 1,4-benzenedicarboxylate; 2,5-pydc, 2,5-pyridinedicarboxylate; 1,2,4,5-btec, 1,2,4,5-benzenetetracarboxylate) have been successfully synthesized and analyzed. Compound 1 features the 2D [Zn(L)]{sub n} layers built by ?{sub 3}-L bridging ligands and Zn(II) ions, which are further linked by pillared 1,4-bdc{sup 2?} ligands to form a 2-fold interpenetrating dmc framework. The 3D network of compound 2 can be simplified as a rare 2-nodal (3,6)-connected rtl (rutile) topology. Compound 3 possesses a 2D layer structure which is accomplished by connecting ladder-chains to L ligands. Compound 4 exhibits 2D [Cd(1,2,4,5-btec)] layers with infinite Cd–O–Cd rods and the adjacent 2D networks are further pillared by L with terminal bidentate coordination mode to generate the final 3D structure. The solid-state luminescent studies show that compounds 1–4 display intense fluorescent emissions. - Graphical abstract: Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers have been obtained. All compounds show good luminescence properties at room temperature. Display Omitted - Highlights: • Four Zn(II)/Cd(II)-MOCPs have been successfully prepared with the rigid bifunctional ligand 5-(4-imidazol -1-yl-phenyl) -2H-tetrazole and different aromatic carboxylates mixed ligands. • Compound 2 is a 2-nodal rtl (rutile) net and compound 4 is a binodal (5, 6)-connected net with yav topology. • Compounds 1-4 display intense fluorescent emissions at room temperature.

Sun, Jiayin [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Daojun, E-mail: zhangdj0410@gmail.com [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Wang, Li [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Renchun; Wang, Junjie; Zeng, Ying; Zhan, Jinling [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Xu, Jianing [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Fan, Yong, E-mail: mrfy@jlu.edu.cn [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)

2013-10-15T23:59:59.000Z

354

Emissions Of Greenhouse Gases From Rice Agriculture  

SciTech Connect

This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min × 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

M. Aslam K. Khalil

2009-07-16T23:59:59.000Z

355

Concentrations and Size Distributions of Particulate Matter Emissions...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

& Organic Carbon - PAHs and n-PAHs - Elemental Compounds - Ionic Species - Carbonyls - Dioxins and Furans - Bioassays Sampling System Diluted Exhaust 1 0 11 6 7 8 a 8 b 3 4 BXDX...

356

On-road emission factors of PM pollutants for light-duty vehicles (LDVs) based on urban street driving conditions  

Science Journals Connector (OSTI)

An on-road sampling campaign was conducted on two major surface streets (Wilshire and Sunset Boulevards) in Los Angeles, CA, to characterize PM components including metals, trace elements, and organic species for three PM size fractions (PM10–2.5, PM2.5–0.25, and PM0.25). Fuel-based emission factors (mass of pollutant per kg of fuel) were calculated to assess the emissions profile of a light-duty vehicle (LDV) traffic fleet characterized by stop-and-go driving conditions that are reflective of urban street driving. Emission factors for metals and trace elements were highest in PM10–2.5 while emission factors for \\{PAHs\\} and hopanes and steranes were highest in PM0.25. PM2.5 emission factors were also compared to previous freeway, roadway tunnel, and dynamometer studies based on an LDV fleet to determine how various environments and driving conditions may influence concentrations of PM components. The on-road sampling methodology deployed in the current study captured substantially higher levels of metals and trace elements associated with vehicular abrasion (Fe, Ca, Cu, and Ba) and crustal origins (Mg and Al) than previous LDV studies. The semi-volatile nature of \\{PAHs\\} resulted in higher levels of \\{PAHs\\} in the particulate phase for LDV tunnel studies (Phuleria et al., 2006) and lower levels of \\{PAHs\\} in the particulate phase for freeway studies (Ning et al., 2008). With the exception of a few high molecular weight PAHs, the current study's emission factors were in between the LDV tunnel and LDV freeway studies. In contrast, hopane and sterane emission factors were generally comparable between the current study, the LDV tunnel, and LDV freeway, as expected given the greater atmospheric stability of these organic compounds. Overall, the emission factors from the dynamometer studies for metals, trace elements, and organic species are lower than the current study. Lastly, n-alkanes (C19–C40) were quantified and alkane carbon preference indices (CPIs) were determined to be in the range of 1–2, indicating substantial anthropogenic source contribution for surface streets in Los Angeles.

Winnie Kam; James W. Liacos; James J. Schauer; Ralph J. Delfino; Constantinos Sioutas

2012-01-01T23:59:59.000Z

357

Dilution-based emissions sampling from stationary sources: part 2 - gas-fired combustors compared with other fuel-fired systems  

SciTech Connect

With the recent focus on fine particle matter (PM2.5), new, self- consistent data are needed to characterize emissions from combustion sources. Emissions data for gas-fired combustors are presented, using dilution sampling as the reference. The sampling and analysis of the collected particles in the presence of precursor gases, SO{sub 2}, nitrogen oxide, volatile organic compound, and NH{sub 3} is discussed; the results include data from eight gas fired units, including a dual- fuel institutional boiler and a diesel engine powered electricity generator. These data are compared with results in the literature for heavy-duty diesel vehicles and stationary sources using coal or wood as fuels. The results show that the gas-fired combustors have very low PM2.5 mass emission rates in the range of {approximately}10{sup -4} lb/million Btu (MMBTU) compared with the diesel backup generator with particle filter, with {approximately} 5 x 10{sup -3} lb/MMBTU. Even higher mass emission rates are found in coal-fired systems, with rates of {approximately} 0.07 lb/MMBTU for a bag-filter-controlled pilot unit burning eastern bituminous coal. The characterization of PM2.5 chemical composition from the gas-fired units indicates that much of the measured primary particle mass in PM2.5 samples is organic or elemental carbon and, to a much less extent, sulfate. Metal emissions are low compared with the diesel engines and the coal- or wood-fueled combustors. The metals found in the gas- fired combustor particles are low in concentration. The interpretation of the particulate carbon emissions is complicated by the fact that an approximately equal amount of particulate carbon is found on the particle collector and a backup filter. It is likely that measurement artifacts are positively biasing 'true' particulate carbon emissions results. 49 refs., 1 fig., 12 tabs.

England, G.C.; Watson, J.G.; Chow, J.C.; Zielinska, B.; Chang, M.C.O.; Loos, K.R.; Hidy. G.M. [GE Energy, Santa Ana, CA (United States)

2007-01-15T23:59:59.000Z

358

Version 2 Global Fire Emissions Database Available  

NLE Websites -- All DOE Office Websites (Extended Search)

Global Fire Emissions Database Available Global Fire Emissions Database Available The ORNL DAAC announces the release of the data set "Global Fire Emissions Database, Version 2 (GFEDv2)." This data set, which supersedes and replaces the Global Fire Emissions Database, Version 1 (GFEDv1), consists of 1 degree x 1 degree gridded monthly burned area, fuel loads, combustion completeness, and fire emissions of carbon (C), carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), non-methane hydrocarbons (NMHC), molecular hydrogen (H2), nitrogen oxides (NOx), nitrous oxide (N2O), particulate matter (PM2.5), total particulate matter (TPM), total carbon (TC), organic carbon (OC), and black carbon (BC) for the time period January 1997 - December 2004. For more information or to access this data set, please see the Vegetation

359

Organic Photovoltaics  

Science Journals Connector (OSTI)

Satisfying the world's growing demand for energy is an urgent societal challenge. Organic photovoltaics holds promise as a cost-efficient and environmentally friendly solution.

Kippelen, Bernard

2007-01-01T23:59:59.000Z

360

Enforcing Emissions Trading when Emissions Permits are Bankable  

Science Journals Connector (OSTI)

We propose enforcement strategies for emissions trading programs with bankable emissions permits that guarantee...

John K. Stranlund; Christopher Costello…

2005-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

 COMPOUND-SPECIFIC RADIOCARBON ANALYSES OF PHOSPHOLIPID FATTY ACIDS AND n -ALKANES IN OCEAN SEDIMENTS  

E-Print Network (OSTI)

Monica Basin surface sediment: a model based on compound-ACIDS AND n-ALKANES IN OCEAN SEDIMENTS Ellen R M Druffel 1 •organic matter in ocean sediments from the northeast Pacific

2010-01-01T23:59:59.000Z

362

Compound-Specific Radiocarbon Analyses of Phospholipid Fatty Acids and n-Alkanes in Ocean Sediments  

E-Print Network (OSTI)

Monica Basin surface sediment: a model based on compound-ACIDS AND n-ALKANES IN OCEAN SEDIMENTS Ellen R M Druffel 1 •organic matter in ocean sediments from the northeast Pacific

2010-01-01T23:59:59.000Z

363

Initial-phase optimization for bioremediation of munition compound-contaminated soils.  

Science Journals Connector (OSTI)

...for the first stage of remediation was between 6.5 and...of the first stage of remediation of munition compound-contaminated...bioremediation explosives ground water herbicides Oregon organic...pollutants pollution remediation soil treatment soils...

S B Funk; D J Roberts; D L Crawford; R L Crawford

1993-07-01T23:59:59.000Z

364

E-Print Network 3.0 - americium compounds Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

the Pajarito Canyon Watershed LA-UR-10-1362 1 March 2010 Summary: organic compounds, dioxins, and furans should be added to the analytical suite for each sample (NMED 2009... in...

365

E-Print Network 3.0 - antimony compounds Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

the Pajarito Canyon Watershed LA-UR-10-1362 1 March 2010 Summary: organic compounds, dioxins, and furans should be added to the analytical suite for each sample (NMED 2009......

366

Multiwavelength Thermal Emission  

E-Print Network (OSTI)

Multiwavelength Astronomy NASA #12;Thermal Emission #12;Thermal Emission Non-thermal p-p collisions Optical IR Radio/ Microwave sources of emission massive stars, WHIM, Ly many dust, cool objects-ray ~GeV Gamma-ray ~TeV sources of emission AGN, clusters, SNR, binaries, stars AGN (obscured), shocks

California at Santa Cruz, University of

367

The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions  

E-Print Network (OSTI)

The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1) is a modeling framework for estimating fluxes of biogenic compounds between terrestrial ecosystems and the atmosphere using simple mechanistic ...

Guenther, A. B.

368

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, Michael S. (New Ellenton, SC)

1995-01-01T23:59:59.000Z

369

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired. 5 figs.

Stowell, M.S.

1995-08-22T23:59:59.000Z

370

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1993-01-01T23:59:59.000Z

371

Emissions of greenhouse gases in the United States, 1985--1990  

SciTech Connect

The Earth`s capacity to support life depends on the moderating influences of gases that envelop the planet and warm its surface and protect it from harmful radiation. These gases are referred to as ``greenhouse gases.`` Their warming capacity, called ``the greenhouse effect,`` is essential to maintaining a climate hospitable to all plant, animal, and human life. In recent years, however, there has been increasing concern that human activity may be affecting the intricate balance between the Earth`s absorption of heat from the sun and its capacity to reradiate excess heat back into space. Emissions of greenhouse gases from human activities may be an important mechanism that affects global climate. Thus, research is intensifying to improve our understanding of the role human activities might play in influencing atmospheric concentrations of greenhouse gases. On the basis of scientific findings of the past few decades, the US Government and the international community at large are now taking steps toward stabilizing greenhouse gas emissions. This report contributes to that process. Mandated by Congress this report provides estimates of US emissions of the principal greenhouse gases--carbon dioxide, methane, nitrous oxide, chlorofluorcarbons, carbon monoxide, nitrogen oxides, and nonmethane volatile organic compounds. Estimates are for the period 1985 to 1990. Preliminary estimates for 1991 have also been included, whenever data were available.

Not Available

1993-11-10T23:59:59.000Z

372

UNDP-Low Emission Capacity Building Programme | Open Energy Information  

Open Energy Info (EERE)

Programme Programme Jump to: navigation, search Logo: UNDP-Low Emission Capacity Building Programme Name UNDP-Low Emission Capacity Building Programme Agency/Company /Organization United Nations Development Programme (UNDP), European Union Sector Climate, Energy, Land, Water Topics Low emission development planning Resource Type Training materials Website http://www.undp.org/climatestr References UNDP-Low Emission Capacity Building Programme[1] UNDP-Low Emission Capacity Building Programme Screenshot "This collaborative programme aims to strengthen technical and institutional capacities at the country level, while at the same time facilitating inclusion and coordination of the public and private sector in national initiatives addressing climate change. It does so by utilizing the

373

Global Atmospheric Pollution Forum Air Pollutant Emission Inventory | Open  

Open Energy Info (EERE)

Global Atmospheric Pollution Forum Air Pollutant Emission Inventory Global Atmospheric Pollution Forum Air Pollutant Emission Inventory Jump to: navigation, search Tool Summary Name: Global Atmospheric Pollution (GAP) Forum Air Pollutant Emission Inventory Agency/Company /Organization: BOC foundation, U.S. Environment Protection Agency (EPA) and Swedish International Development Cooperation Agency (SIDA) Complexity/Ease of Use: Moderate Website: sei-international.org/rapidc/gapforum/html/emissions-manual.php Cost: Free Related Tools Global Atmospheric Pollution Forum Air Pollutant Emission Inventory World Induced Technical Change Hybrid (WITCH) Energy Development Index (EDI) ... further results Find Another Tool FIND DEVELOPMENT IMPACTS ASSESSMENT TOOLS A manual that provides formulation of methods and assessment of good

374

UNDP-Low Emission Climate Resilient Development Strategies (LECRDS)  

Open Energy Info (EERE)

UNDP-Low Emission Climate Resilient Development Strategies (LECRDS) UNDP-Low Emission Climate Resilient Development Strategies (LECRDS) Guidance Manuals and Toolkits Jump to: navigation, search Tool Summary LAUNCH TOOL Name: UNDP-Low Emission Climate Resilient Development Strategies (LECRDS) Guidance Manuals and Toolkits Agency/Company /Organization: United Nations Development Programme Sector: Energy, Land, Climate Focus Area: Economic Development, Greenhouse Gas Topics: Finance, GHG inventory, Low emission development planning, Policies/deployment programs, Pathways analysis Resource Type: Guide/manual, Lessons learned/best practices Website: www.undp.org/environment/climatestrategies_toolkits.shtml Cost: Free UNDP-Low Emission Climate Resilient Development Strategies (LECRDS) Guidance Manuals and Toolkits Screenshot

375

Mexico - Greenhouse Gas Emissions Baselines and Reduction Potentials from  

Open Energy Info (EERE)

Greenhouse Gas Emissions Baselines and Reduction Potentials from Greenhouse Gas Emissions Baselines and Reduction Potentials from Buildings Jump to: navigation, search Name Mexico - Greenhouse Gas Emissions Baselines and Reduction Potentials from Buildings Agency/Company /Organization United Nations Environment Programme Sector Energy Focus Area Buildings Topics Baseline projection, GHG inventory, Pathways analysis, Background analysis Resource Type Publications Website http://www.unep.org/sbci/pdfs/ Country Mexico Central America References Greenhouse Emissions Baselines and Reduction Potentials for Buildings[1] Mexico - Greenhouse Gas Emissions Baselines and Reduction Potentials from Buildings Screenshot "This report represents the first comprehensive description of the factors that determine the present and future impacts of residential and commercial

376

CO2 Emissions from Fuel Combustion | Open Energy Information  

Open Energy Info (EERE)

CO2 Emissions from Fuel Combustion CO2 Emissions from Fuel Combustion Jump to: navigation, search Tool Summary Name: CO2 Emissions from Fuel Combustion Agency/Company /Organization: International Energy Agency Sector: Energy Topics: Baseline projection, GHG inventory Resource Type: Dataset, Publications Website: www.iea.org/co2highlights/co2highlights.pdf CO2 Emissions from Fuel Combustion Screenshot References: CO2 Emissions from Fuel Combustion[1] Overview "This annual publication contains: estimates of CO2 emissions by country from 1971 to 2008 selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh CO2 emissions from international marine and aviation bunkers, and other relevant information" Excel Spreadsheet References ↑ "CO2 Emissions from Fuel Combustion"

377

Assess Potential Agency Size Changes that Impact Greenhouse Gas Emissions |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emissions Emissions Assess Potential Agency Size Changes that Impact Greenhouse Gas Emissions October 7, 2013 - 10:12am Addthis Federal agencies should establish planned changes in operations that could have a substantial impact on emissions for each greenhouse gas (GHG) emission source: Buildings Vehicles and mobile equipment Business travel Employee commuting. Such changes could represent either an additional significant hurdle to overcome or a significant reduction in the effort required to drive emissions down-in the absence of any direct GHG mitigation reduction strategies. This will help each organization establish its "business as usual" emission profile in 2020, the year agencies are expected to meet their Scope 1 and 2 and Scope 3 GHG emission-reduction goals.

378

Evaluate Greenhouse Gas Emissions Profile | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emissions Profile Emissions Profile Evaluate Greenhouse Gas Emissions Profile October 7, 2013 - 10:14am Addthis Evaluating a Federal agency's greenhouse gas (GHG) emissions profile means getting a solid understanding of the organization's largest emission categories, largest emission sources, and its potential for improvement: Buildings Vehicles and mobile equipment Business travel Employee commuting. While the data required for annual GHG reporting are sufficient to establish an agency's overall emission inventory, these data are not typically enough information for effectively managing emissions. A detailed, bottom-up assessment can provide the foundation for much more robust Strategic Sustainability Performance Plans. Because detailed analyses of all assets can be time-intensive, strategic planning helps the

379

Crystallographic properties of fertilizer compounds  

SciTech Connect

This bulletin is a compilation of crystallographic data collected at NFERC on 450 fertilizer-related compounds. In TVA's fertilizer R and D program, petrographic examination, XRD, and infrared spectroscopy are combined with conventional chemical analysis methods in identifying the individual compounds that occur in fertilizer materials. This handbook brings together the results of these characterization studies and supplemental crystallographic data from the literature. It is in one-compound-per-page, loose-leaf format, ordered alphabetically by IUPAC name. Indexes provided include IUPAC name, formula, group, alternate formula, synonyms, x-ray data, optical data. Tables are given for solids, compounds in commercial MAP and DAP, and matrix materials in phosphate rock.

Frazier, A.W.; Dillard, E.F.; Thrasher, R.D.; Waerstad, K.R.; Hunter, S.R.; Kohler, J.J.; Scheib, R.M.

1991-02-01T23:59:59.000Z

380

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Detection of chlorinated aromatic compounds  

DOE Patents (OSTI)

A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

Ekechukwu, Amy A. (Augusta, GA)

1996-01-01T23:59:59.000Z

382

Method for digesting a nitro-bearing explosive compound  

DOE Patents (OSTI)

The present invention is a process wherein superoxide radicals from superoxide salt are used to break down the explosive compounds. The process has an excellent reaction rate for degrading explosives, and operates at ambient temperature and atmospheric pressure in aqueous or non-aqueous conditions. Because the superoxide molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The superoxide salt generates reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro-bearing compound.

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

383

Organic geochemistry and organic petrography  

SciTech Connect

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

384

Vietnam-Rapid Assessment of City Emissions (RACE) for Low Carbon...  

Open Energy Info (EERE)

Assessment of City Emissions (RACE) for Low Carbon Cities: Transport and Building Electricity Use AgencyCompany Organization Clean Air Asia, Chreod Ltd. Partner Asian...

385

State Externalities Policy and Carbon Dioxide Emissions: Who Bears the Risks of Future Regulation?  

Science Journals Connector (OSTI)

ITEM...: In January 1991, representatives of 38 state consumer advocacy offices and 17 environmental organizations warned utilities that failures to anticipate future carbon-dioxide-emission cost i...

Ralph Cavanagh; Ashok Gupta; Dan Lashof; Marika Tatsutani

1994-01-01T23:59:59.000Z

386

Undisturbed and disturbed above canopy ponderosa pine emissions: PTR-TOF-MS measurements and MEGAN 2.1 model results  

SciTech Connect

We present the first eddy covariance flux measurements of volatile organic compounds (VOCs) using a proton-transfer-reaction time-of-flight mass-spectrometer (PTR-TOFMS) above a ponderosa pine forest in Colorado, USA. The high mass resolution of the PTR-TOF-MS enabled the identification of chemical sum formulas. During a 30 day measurement period in August and September 2010, 649 different ion mass peaks were detected in the ambient air mass spectrum (including primary ions and mass calibration ompounds). Eddy covariance with the vertical wind speed was calculated for all ion mass peaks. On a typical day, 17 ion mass peaks including protonated parent compounds, their fragments and isotopes as well as VOC-H+-water clusters showed a significant flux with daytime average emissions above a reliable flux threshold of 0.1mgcompoundm?2 h?1. These ion mass peaks could be assigned to seven compound classes. The main flux contributions during daytime (10:00-18:00 LT) are attributed to the sum of 2-methyl-3-buten-2-ol (MBO) and isoprene (50 %), methanol (12%), the sum of acetic acid and glycolaldehyde (10%) and the sum of monoterpenes (10 %). The total MBO+isoprene flux was composed of 10% isoprene and 90% MBO. There was good agreement between the light and temperature dependency of the sum of MBO and isoprene observed for this work and those of earlier studies. The above canopy flux measurements of the sum of MBO and isoprene and the sum of 20 monoterpenes were compared to emissions calculated using the Model of Emissions of Gases and Aerosols from Nature (MEGAN 2.1). The best agreement between MEGAN 2.1 and measurements was reached using emission factors determined from site specific leaf cuvette measurements. While the modelled and measured MBO+isoprene fluxes agree well the emissions of the sum of monoterpenes is underestimated by MEGAN 2.1. This is expected as some factors impacting monoterpene emissions, such as physical damage of needles and branches due to storms, are not included in MEGAN 2.1.

Kaser, L.; Karl, T.; Guenther, Alex B.; Graus, M.; Schnitzhofer, R.; Turnipseed, A.; Fischer, L.; Harley, P.; Madronich, M.; Gochis, David; Keutsch, Frank N.; Hansel, A.

2013-12-09T23:59:59.000Z

387

Nitroaromatic Compounds, from Synthesis to Biodegradation  

Science Journals Connector (OSTI)

...compounds that enter the TCA cycle. Interestingly, expression...and then converted to TCA cycle compounds, with salicylate...nitroaromatic compounds, but several fundamental aspects regarding their biosynthesis...Explosives development and fundamentals of explosives technology...

Kou-San Ju; Rebecca E. Parales

2010-06-01T23:59:59.000Z

388

A Novel New Approach to VOC and HAP Emission Control  

E-Print Network (OSTI)

of real estate. Non-thermal VOHAP (Volatile Organic Hazardous Air Pollutant) emission control devices require additional maintenance. They also require the replacement of costly consumables such as activated carbon or they use large amounts of energy...

McGinness, M.

389

Offsetting China's CO2 Emissions by Soil Carbon Sequestration  

Science Journals Connector (OSTI)

Fossil fuel emissions of carbon (C) in China in 2000 was ... % or more of the antecedent soil organic carbon (SOC) pool.Some of the depleted ... . A crude estimated potential of soil C sequestration in China is 1...

R. Lal

2004-08-01T23:59:59.000Z

390

ARM - Measurement - Organic Carbon Concentration  

NLE Websites -- All DOE Office Websites (Extended Search)

govMeasurementsOrganic Carbon Concentration govMeasurementsOrganic Carbon Concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Organic Carbon Concentration The concentration of carbon bound in organic compounds. Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments ACSM : Aerosol Chemical Speciation Monitor Field Campaign Instruments AEROSCARBON : Aerosol Carbon Analyzer AEROSMASSSPEC : Aerosol Mass Spectrometer Datastreams AOS : Aerosol Observing System Datastreams

391

Method of digesting an explosive nitro compound  

DOE Patents (OSTI)

The present invention is a process wherein bleaching oxidants are used to digest explosive nitro compounds. The process has an excellent reaction rate for digesting explosives and operates under multivariate conditions. Reaction solutions may be aqueous, non-aqueous or a combination thereof, and can also be any pH, but preferably have a pH between 2 and 9. The temperature may be ambient as well as any temperature above which freezing of the solution would occur and below which any degradation of the bleaching oxidant would occur or below which any explosive reaction would be initiated. The pressure may be any pressure, but is preferably ambient or atmospheric, or a pressure above a vapor pressure of the aqueous solution to avoid boiling of the solution. Because the bleaching oxidant molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The bleaching oxidants generate reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro compound.

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

392

compound queries | OpenEI Community  

Open Energy Info (EERE)

Jweers's picture Submitted by Jweers(83) Contributor 16 May, 2013 - 14:22 Multicolor Maps from Compound Queries ask queries compound queries developer Google maps maps...

393

Novel Phosphazene Compounds for Enhancing Electrolyte Stability...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells Novel Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion...

394

Novel Phosphazene Compounds for Enhancing Electrolyte Stability...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Novel Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells Novel Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of...

395

Emission factors for ammonia and particulate matter from broiler Houses  

E-Print Network (OSTI)

of ammonia will probably result in the emission of other odorants (e. g. volatile fatty acids. volatile amines, indole, phenol, sulfur-containing compounds). Ammonia is produced from the microbial breakdown of uric acid in poultry manure. The decomposition... sulfate (Barthelmie and Pryor, 1998). Additionally, ammonia is an odorant and conditions conducive to the production of ammonia will probably result in the emission of other odorants (e. g. volatile fatty acids, volatile amines, indole, phenol, sulfur...

Redwine, Jarah Suzanne

2001-01-01T23:59:59.000Z

396

Supporting Information:1 Contributions of individual reactive biogenic volatile organic compounds to organic2  

E-Print Network (OSTI)

System Laboratory, National Center for22 Atmospheric Research, Boulder, CO USA23 Now at: Air Pollution 8 Université Lille Nord de France, Lille, France16 9 �cole des Mines de Douai, Douai, France17 10

Meskhidze, Nicholas

397

Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications  

DOE Patents (OSTI)

A PBI compound includes imidazole nitrogens at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2-- where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least 5 equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about 15.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2007-08-21T23:59:59.000Z

398

Beyond Tailpipe Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Beyond Tailpipe Emissions Beyond Tailpipe Emissions Greenhouse Gas Emissions for Electric and Plug-In Hybrid Electric Vehicles Driving your vehicle can yield both greenhouse gas (GHG) emissions from your vehicle's tailpipe and GHG emissions related to the production of the fuel used to power your vehicle. For example, activities associated with fuel production such as feedstock extraction, feedstock transport to a processing plant, and conversion of feedstock to motor fuel, as well as distribution of the motor fuel, can all produce GHG emissions. The Fuel Economy and Environment Label provides a Greenhouse Gas Rating, from 1 (worst) to 10 (best), based on the vehicle's tailpipe carbon dioxide emissions only, and this rating does not reflect any GHG emissions associated with fuel production.

399

Emissions from Ships  

Science Journals Connector (OSTI)

...Turbine and Diesel) Engine Exhaust Emission...of relative fuel consumption. For commercial...Marine Diesel Engine and Gas Turbine...Turbine and Diesel) Engine Exhaust Emission...of relative fuel consumption. For commercial...

James J. Corbett; Paul Fischbeck

1997-10-31T23:59:59.000Z

400

Introduction to Emissions Trading  

Science Journals Connector (OSTI)

This chapter constitutes an introduction to emissions trading. First, we detail the latest developments ... Second, we introduce the main characteristics of emissions trading, be it in terms of spatial and...2 al...

Dr. Julien Chevallier

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Organic Tanks Safety Program: Waste aging studies  

SciTech Connect

The underground storage tanks at the Hanford Complex contain wastes generated from many years of plutonium production and recovery processes, and mixed wastes from radiological degradation processes. The chemical changes of the organic materials used in the extraction processes have a direct on several specific safety issues, including potential energy releases from these tanks. This report details the first year`s findings of a study charged with determining how thermal and radiological processes may change the composition of organic compounds disposed to the tank. Their approach relies on literature precedent, experiments with simulated waste, and studies of model reactions. During the past year, efforts have focused on the global reaction kinetics of a simulated waste exposed to {gamma} radiation, the reactions of organic radicals with nitrite ion, and the decomposition reactions of nitro compounds. In experiments with an organic tank non-radioactive simulant, the authors found that gas production is predominantly radiolytically induced. Concurrent with gas generation they observe the disappearance of EDTA, TBP, DBP and hexone. In the absence of radiolysis, the TBP readily saponifies in the basic medium, but decomposition of the other compounds required radiolysis. Key organic intermediates in the model are C-N bonded compounds such as oximes. As discussed in the report, oximes and nitro compounds decompose in strong base to yield aldehydes, ketones and carboxylic acids (from nitriles). Certain aldehydes can react in the absence of radiolysis to form H{sub 2}. Thus, if the pathways are correct, then organic compounds reacting via these pathways are oxidizing to lower energy content. 75 refs.

Camaioni, D.M.; Samuels, W.D.; Lenihan, B.D.; Clauss, S.A.; Wahl, K.L.; Campbell, J.A.

1994-11-01T23:59:59.000Z

402

Organic materials with nonlinear optical properties  

DOE Patents (OSTI)

The present invention is directed to organic materials that have the ability to double or triple the frequency of light that is directed through the materials. Particularly, the present invention is directed to the compound 4-[4-(2R)-2-cyano-7-(4{prime}-pentyloxy-4-biphenylcarbonyloxy)phenylheptylidenephenylcarbonyloxy]benzaldehyde, which can double the frequency of light that is directed through the compound. The invention is also directed to the compound (12-hydroxy-5,7-dodecadiynyl)-4{prime}-[(4{prime}-pentyloxy-4-biphenyl)carbonyloxy]-4-biphenylcarboxylate, and its polymeric form. The polymeric form can triple the frequency of light directed through it. 4 figs.

Stupp, S.I.; Son, S.; Lin, H.C.

1995-05-02T23:59:59.000Z

403

Emission Factors (EMFAC) | Open Energy Information  

Open Energy Info (EERE)

Emission Factors (EMFAC) Emission Factors (EMFAC) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: EMFAC Agency/Company /Organization: California Environmental Protection Agency Sector: Energy Focus Area: Transportation Phase: Determine Baseline Topics: Baseline projection, GHG inventory Resource Type: Software/modeling tools, Online calculator User Interface: Spreadsheet Website: www.arb.ca.gov/msei/onroad/latest_version.htm Country: United States Cost: Free Northern America References: http://www.arb.ca.gov/msei/onroad/latest_version.htm The EMission FACtors (EMFAC) model is used to calculate emission rates from all motor vehicles, such as passenger cars to heavy-duty trucks, operating on highways, freeways and local roads in California. EMFAC2007 is the most recent version of this model.

404

NICKEL SPECIES EMISSION INVENTORY FOR OIL-FIRED BOILERS  

SciTech Connect

Representative duplicate fly ash samples were obtained from the stacks of 400-MW and 385-MW utility boilers (Unit A and Unit B, respectively) using a modified U.S. Environmental Protection Agency (EPA) Method 17 sampling train assembly as they burned .0.9 and 0.3 wt% S residual oils, respectively, during routine power plant operations. Residual oil fly ash (ROFA) samples were analyzed for nickel (Ni) concentrations and speciation using inductively coupled plasma-atomic emission spectroscopy, x-ray absorption fine structure (XAFS) spectroscopy, x-ray diffraction (XRD), and a water-soluble Ni extraction method. ROFA water extraction residues were also analyzed for Ni speciation using XAFS and XRD. Total Ni concentrations in the ROFAs were similar, ranging from 1.3 to 1.5 wt%; however, stack gas Ni concentrations in the Unit A were {approx}990 {micro}g/Nm{sup 3} compared to {approx}620 {micro}g/Nm{sup 3} for Unit B because of the greater residual oil feed rates employed at Unit A to attain higher load (i.e., MW) conditions with a lower heating value oil. Ni speciation analysis results indicate that ROFAs from Unit A contain about 3 wt% NiSO{sub 4} {center_dot} xH{sub 2}O (where x is assumed to be 6 for calculation purposes) and a Ni-containing spinel compound, similar in composition to (Mg,Ni)(Al,Fe){sub 2}O{sub 4}. ROFAs from Unit B contain on average 2.0 wt% NiSO{sub 4} {center_dot} 6H{sub 2}O and 1.1 wt% NiO. XAFS and XRD analyses did not detect any nickel sulfide compounds, including nickel subsulfide (Ni{sub 3}S{sub 2}) (XAFS detection limit is 5% of the total Ni concentration). In addition, XAFS measurements indicated that inorganic sulfate and organic thiophene species account for >97% of the total sulfur in the ROFAs. The presence of NiSO{sub 4} {center_dot} xH{sub 2}O and nickel oxide compound mixtures and lack of carcinogenic Ni{sub 3}S{sub 2} or nickel sulfide compounds (e.g., NiS, NiS{sub 2}) in ROFAs stack-sampled from 400- and 385-MW boilers are contrary to EPA's Ni inhalation cancer risk assessment (''Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units--Final Report to Congress'', February 1998), where it is assumed that the Ni compound mixture emitted from oil-fired utilities is 50% as carcinogenic as Ni{sub 3}S{sub 2}. Apparently, this assumption greatly overestimates the Ni inhalation cancer risk from oil-fired utilities.

Kevin C. Galbreath; Richard L. Schulz; Donald L. Toman; Carolyn M. Nyberg

2004-01-01T23:59:59.000Z

405

NETL - World CO2 Emissions - Projected Trends Tool | Open Energy  

Open Energy Info (EERE)

NETL - World CO2 Emissions - Projected Trends Tool NETL - World CO2 Emissions - Projected Trends Tool Jump to: navigation, search Tool Summary LAUNCH TOOL Name: NETL - World CO2 Emissions - Projected Trends Tool Agency/Company /Organization: National Energy Technology Laboratory Sector: Energy Topics: GHG inventory Resource Type: Software/modeling tools Website: www.netl.doe.gov/energy-analyses/refshelf/results.asp?ptype=Models/Too References: NETL - World CO2 Emissions - Projected Trends Tool [1] NETL - World CO2 Emissions - Projected Trends Tool This interactive tool enables the user to look at both total and power sector CO2 emissions from the use of coal, oil, or natural gas, over the period 1990 to 2030. One can use the tool to compare five of the larger CO2 emitters to each other or to overall world emissions. The data are from the

406

Carbon Dioxide Emissions Associated with Bioenergy and Other Biogenic  

Open Energy Info (EERE)

Carbon Dioxide Emissions Associated with Bioenergy and Other Biogenic Carbon Dioxide Emissions Associated with Bioenergy and Other Biogenic Sources Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Emissions Associated with Bioenergy and Other Biogenic Sources Agency/Company /Organization: United States Environmental Protection Agency Sector: Energy, Climate Focus Area: Biomass, - Biomass Combustion, - Biomass Gasification, - Biomass Pyrolysis, - Biofuels, - Landfill Gas, - Waste to Energy, Greenhouse Gas Phase: Evaluate Options Resource Type: Publications, Guide/manual User Interface: Website Website: www.epa.gov/climatechange/emissions/biogenic_emissions.html Cost: Free References: EPA, 40 CFR Part 60[1] Tailoring Rule[2] Biogenic Emissions[3] The 'EPA Climate Change - Green House Gas Emissions - Carbon Dioxide

407

DOE Hydrogen Analysis Repository: MOVES (Motor Vehicle Emission Simulator)  

NLE Websites -- All DOE Office Websites (Extended Search)

MOVES (Motor Vehicle Emission Simulator) MOVES (Motor Vehicle Emission Simulator) Project Summary Full Title: MOVES (Motor Vehicle Emission Simulator) Previous Title(s): New Generation Mobile Source Emissions Model (NGM) Project ID: 179 Principal Investigator: Margo Oge Brief Description: Estimates emissions for on-road and nonroad sources, multiple pollutants, fine-scale analysis to national inventory estimation. Keywords: Vehicle; transportation; emissions Purpose Estimate emissions for on-road and nonroad sources, cover a broad range of pollutants, and allow multiple scale analysis, from fine-scale analysis to national inventory estimation. When fully implemented MOVES will serve as the replacement for MOBILE. Performer Principal Investigator: Margo Oge Organization: U.S. Environmental Protection Agency

408

The Phosphorus Compounds of Cotton Seed Meal and Wheat Bran.  

E-Print Network (OSTI)

. Phar. & Expt. Therapeutics 1,151) claims that ? the chief poisonous principle of cottonseed meal is a salt of pyrophos- phoric acid.? It has been shown by the writer (Bulletin 146) that the product which these writers thought was inorganic... compound as phytin, but do not report complete analyses of the product. Levine (Biochem. Ztscher. 16, 390) describes a semicrystalline barium salt of an organic phosphorus acid. Yorbrodt (Anzeiger. Akad. Wiss. Krakau, 1910. Series A. 414) separated...

Rather, J. B. (James Burness)

1913-01-01T23:59:59.000Z

409

Regulation of GHG emissions from transportation fuels: Emission quota versus emission intensity standard  

E-Print Network (OSTI)

1 ? ?) and ? respectively. GHG emissions per unit of blend1 ? ?)? i + ?? i Reduction in GHG emissions with respect toSeries Regulation of GHG emissions from transportation 

Rajagopal, Deepak

2010-01-01T23:59:59.000Z

410

The reaction kinetics of gasoline sulfur compounds: Catalytic mechanisms for sulfur reduction  

SciTech Connect

One of the key elements of reformulated gasoline is the reduction of the sulfur compounds produced by fluid catalytic cracking. This paper probes the reaction kinetics of refractory gasoline-range thiophene derivatives (thiophene, tetrahydrothiophene, and alkylthiophenes) in an effort to determine the mechanisms of sulfur compound cracking in the FCC unit. The gasoline-range sulfur compounds were analyzed using gas chromatography with an atomic emission detector. The authors` results show that the FCC catalysts affects the cracking of sulfur compounds through both hydrogen transfer and zeolite pore restriction mechanisms. An experimental FCC catalyst is shown to reduce gasoline sulfur content in the Davidson Circulating Riser (DCR{sup TM}) pilot unit. Model compound tests show that the activity of the catalyst is due to both its catalytic and adsorptive properties. Tetrahydrothiophene, which is produced from thiophenes by hydrogen transfer, is completely removed by the experimental catalyst.

Harding, R.H.; Gatte, R.R.; Albro, T.G.; Wormsbecher, R.F. [W.R. Grace & Co. Conn, Columbia, MD (United States)

1993-12-31T23:59:59.000Z

411

E-Print Network 3.0 - atomic energy organization Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

6. A common trait of simple organic compounds is to have Lewis... in a certain organic molecule absorbs radiation that has a frequency of 6.0 x 1013 s1. a. What... is the...

412

Liquefaction of cellulosic wastes. 6: Oxygen compounds in pyrolytic oil and water fractions  

SciTech Connect

Liquid hydrocarbon oil and water have been produced from the liquefaction of cellulosic matter present in municipal solid wastes. The produced pyrolytic oil and water fraction seemed to be contaminated with considerable amounts of oxygen compounds as compared with fuels derived from a petroleum origin. The oxygen compounds included organic acids (fatty and naphthenic acids), phenols, and carbonyl compounds. These classes of oxygen compounds were extracted selectively from the pyrolytic oils and water using chemical extraction methods. Methyl esters of fatty acids and 2,4-dinitrophenylhydrazones of carbonyl compounds were identified by gas chromatography and thin layer chromatography, respectively. It was suggested that the identified oxygen compounds could be produced from the pyrolysis of volatiles (e.g., levoglucosane, which is the primary product of cellulose depolymerization) via different mechanistic pathways.

Gharieb, H.K.; Faramawy, S.; El-Amrousi, F.A.; El-Sabagh, S.M. [Egyptian Petroleum Research Inst., Cairo (Egypt)

1998-07-01T23:59:59.000Z

413

Volatile compounds from marine algae  

Science Journals Connector (OSTI)

Volatile compounds from marine algae ... Seasonal Variations of Bromophenols in Brown Algae (Padina arborescens, Sargassum siliquastrum, and Lobophora variegata) Collected in Hong Kong ... Seasonal Variations of Bromophenols in Brown Algae (Padina arborescens, Sargassum siliquastrum, and Lobophora variegata) Collected in Hong Kong ...

Richard E. Moore

1977-02-01T23:59:59.000Z

414

Simultaneous multiparticle emissions in hot nuclei evaporation process  

SciTech Connect

This work presents a new mechanism for the evaporation with simultaneous particles emission mechanism in the evaporation chain as new channels opened to high excitation energy regime of the compound nucleus. The probability of multiple simultaneous emissions is determined based on phase space approach. A Monte Carlo simulation is employed to compute the final average yield of emitted particles after the decay chain. The neutron, proton, alpha and fission yields are obtained and compared to the conventional calculation with sequential simple particles emission and the relevance of the different channels in competition is also analyzed.

Santos, B. M. [Instituto de Fisica - Universidade Federal Fluminense Av. Gal. Milton Tavares de Souza, 24210-346 Niteroi. RJ (Brazil); De Assis, L. P.; Duarte, S. B. [Centro Brasileiro de Pesquisas Fisicas - CBPF Rua Dr. Xavier Sigaud 150, 22290-180 Rio de Janeiro. RJ (Brazil)

2013-03-25T23:59:59.000Z

415

U.S. zero emission coal alliance techology  

SciTech Connect

For coal to maintain its major role in supplying the world's energy, eventually all emissions to the atmosphere must be eliminated. Not only must conventional pollutants, like sulfur compounds and dust particles be kept out of the air, but also the far larger quantities of carbon dioxide that result from the combustion of carbon. We present a new technology for coal-based power that generates hydrogen from carbon and water, avoids emissions to the atmosphere, and disposes of the carbon dioxide as inert, solid mineral carbonates. Based on the available resources, coal power is sustainable for centuries. Our zero emission technology makes coal energy as clean as renewable energy.

Lackner, K. S. (Klaus S.); Ziock, H. J. (Hans-Joachim)

2001-01-01T23:59:59.000Z

416

State Emissions Estimates  

Gasoline and Diesel Fuel Update (EIA)

Estimates of state energy-related carbon dioxide emissions Estimates of state energy-related carbon dioxide emissions Because energy-related carbon dioxide (CO 2 ) constitutes over 80 percent of total emissions, the state energy-related CO 2 emission levels provide a good indicator of the relative contribution of individual states to total greenhouse gas emissions. The U.S. Energy Information Administration (EIA) emissions estimates at the state level for energy-related CO 2 are based on data contained in the State Energy Data System (SEDS). 1 The state-level emissions estimates are based on energy consumption data for the following fuel categories: three categories of coal (residential/commercial, industrial, and electric power sector); natural gas; and ten petroleum products including-- asphalt and road oil, aviation gasoline, distillate fuel, jet fuel, kerosene, liquefied petroleum gases

417

In Vitro Genotoxicity of Particulate and Semi-Volatile Organic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30F In Vitro Genotoxicity of Particulate...

418

Pollutant Emissions from Gasoline Combustion. 1. Dependence on Fuel  

E-Print Network (OSTI)

Pollutant Emissions from Gasoline Combustion. 1. Dependence on Fuel Structural Functionalities H O fractions of gasoline fuels, the Utah Surrogate Mechanisms is extended to include submecha- nisms of gasoline surrogate compounds using a set of mechanism generation techniques. The mechanism yields very good

Utah, University of

419

Rapid Assessment of City Emissions (RACE): Case of Batangas City,  

Open Energy Info (EERE)

Rapid Assessment of City Emissions (RACE): Case of Batangas City, Rapid Assessment of City Emissions (RACE): Case of Batangas City, Philippines Jump to: navigation, search Tool Summary Name: Rapid Assessment of City Emissions (RACE): Case of Batangas City, Philippines Agency/Company /Organization: International Resources Group (IRG), Clean Air Asia, Chreod Ltd. Partner: United States Agency for International Development (USAID), Ministry of Planning Sector: Land Focus Area: Buildings, Economic Development, Energy Efficiency, Greenhouse Gas, Land Use, People and Policy, Transportation Topics: Background analysis, Baseline projection, Co-benefits assessment, - Environmental and Biodiversity, GHG inventory, Low emission development planning, -LEDS, Market analysis, Pathways analysis, Policies/deployment programs Resource Type: Case studies/examples

420

South Africa-Promoting Low Emission Urban Development Strategies in  

Open Energy Info (EERE)

South Africa-Promoting Low Emission Urban Development Strategies in South Africa-Promoting Low Emission Urban Development Strategies in Emerging Economy Countries (URBAN-LEDS) Jump to: navigation, search Name South Africa-Promoting Low Emission Urban Development Strategies in Emerging Economy Countries (URBAN-LEDS) Agency/Company /Organization ICLEI - Local Governments for Sustainability, European Commission, UN Habitat Sector Climate, Energy Focus Area Renewable Energy, Buildings, Buildings - Commercial, Buildings - Residential, People and Policy Topics Adaptation, Background analysis, Baseline projection, Low emission development planning, -LEDS, Market analysis, Pathways analysis, Policies/deployment programs Website http://www.iclei.org/fileadmin Program Start 2012 Program End 2015 Country South Africa Southern Africa

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary  

Open Energy Info (EERE)

The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary Combustion Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary Combustion Agency/Company /Organization: World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Buildings, Greenhouse Gas Phase: Determine Baseline, Evaluate Effectiveness and Revise as Needed Resource Type: Software/modeling tools User Interface: Spreadsheet Website: www.ghgprotocol.org/calculation-tools/all-tools Cost: Free References: Stationary Combustion Guidance[1] The Greenhouse Gas Protocol tool for stationary combustion is a free Excel spreadsheet calculator designed to calculate GHG emissions specifically

422

Identification of Low Emissions Agricultural Pathways and Priorities for  

Open Energy Info (EERE)

Identification of Low Emissions Agricultural Pathways and Priorities for Identification of Low Emissions Agricultural Pathways and Priorities for Mitigation in Agricultural Landscapes using Integrated Assessment Modeling and Scenarios Jump to: navigation, search Name Identification of Low Emissions Agricultural Pathways and Priorities for Mitigation in Agricultural Landscapes using Integrated Assessment Modeling and Scenarios Agency/Company /Organization CGIAR's Climate Change, Agriculture and Food Security (CCAFS), Canadian International Development Agency (CIDA), the Danish International Development Agency (DANIDA), the European Union, International Fund for Agricultural Development (IFAD) Partner International Institute for Applied Systems Analysis (IIASA) Sector Land Focus Area Agriculture Topics Background analysis, Baseline projection, Low emission development planning, -LEDS, Pathways analysis, Policies/deployment programs

423

Enhancing Capacity for Low Emission Development Strategies (EC-LEDS)  

Open Energy Info (EERE)

Enhancing Capacity for Low Emission Development Strategies Program Enhancing Capacity for Low Emission Development Strategies Program Agency/Company /Organization United States Agency for International Development, United States Environmental Protection Agency, United States Department of Energy, United States Department of Agriculture, United States Department of State Sector Energy, Land Topics Low emission development planning, -LEDS Program Start 2010 Program End 2014 Country Albania, Bangladesh, Cambodia, Colombia, Costa Rica, Gabon, Georgia, Guatemala, Indonesia, Jamaica, Kazakhstan, Kenya, Republic of Macedonia, Malawi, Malaysia, Mexico, Moldova, Peru, Philippines, Serbia, South Africa, Thailand, Ukraine, Vietnam, Zambia UN Region Southern Asia References Enhancing Capacity for Low Emission Development Strategies Program[1]

424

General Equilibrium Emissions Model (GEEM) | Open Energy Information  

Open Energy Info (EERE)

General Equilibrium Emissions Model (GEEM) General Equilibrium Emissions Model (GEEM) Jump to: navigation, search Tool Summary Name: General Equilibrium Emissions Model (GEEM) Agency/Company /Organization: International Institute for Sustainable Development (IISD) Sector: Climate, Energy Focus Area: Renewable Energy, Non-renewable Energy, Agriculture, Buildings, Economic Development, Energy Efficiency, Forestry, Goods and Materials, Greenhouse Gas, Industry, Offsets and Certificates, Transportation Topics: Background analysis, Baseline projection, GHG inventory, Low emission development planning, Market analysis, Pathways analysis, Policies/deployment programs, Technology characterizations Country: Kenya, Thailand UN Region: Eastern Africa, Caribbean Coordinates: 13.7240216°, 100.5798602°

425

Supporting RBEC Transition to Low-Emission Development | Open Energy  

Open Energy Info (EERE)

RBEC Transition to Low-Emission Development RBEC Transition to Low-Emission Development Jump to: navigation, search Name Supporting RBEC Transition to Low-Emission Development Agency/Company /Organization United Nations Development Programme (UNDP), UNDP Bratislava Regional Center Partner Interministerial committees headed by the national focal point on climate change Sector Climate, Energy Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Greenhouse Gas, Industry, People and Policy, Transportation Topics Background analysis, Baseline projection, Co-benefits assessment, Low emission development planning, -LEDS Website http://europeandcis.undp.org/e Program Start 2010 Program End 2012 Country Kazakhstan, Moldova, Republic of Kosovo, Turkey, Turkmenistan, Uzbekistan

426

Handbook of GC/MS data and information for selected Clean Air Act amendments compounds. Report for January 1992-December 1993  

SciTech Connect

This Handbook presents a compilation of the results of laboratory experiments to test the applicability of GC/MS techniques using EPA methods 8270 and 5041, and the compatibility of the Title III organic compounds with organic solvents. The Handbook contains the following information: (1) Compounds that can and cannot be analyzed; (2) Relative response factors; (3) Chromatograms, reference mass spectra; and (4) Evaluation of compound compatibility for semivolatile organic compounds in isolation. Data and information included in the Handbook are intended to address analytical issues only; sample collection issues are not addressed.

Rice, J.; Bursey, J.T.; McGaughey, J.F.; Merrill, R.G.; Harvan, D.J.

1994-03-01T23:59:59.000Z

427

Solvent-free microwave extraction of bioactive compounds provides a tool for green analytical chemistry  

Science Journals Connector (OSTI)

Abstract We present an overview on solvent-free microwave-extraction techniques of bioactive compounds from natural products. This new technique is based on the concept of green analytical chemistry. It has proved to be an alternative to other techniques with the advantages of reducing extraction times, energy consumption, solvent use and CO2 emissions.

Ying Li; Anne Sylvie Fabiano-Tixier; Maryline Abert Vian; Farid Chemat

2013-01-01T23:59:59.000Z

428

Spatial and Temporal Trends of Perfluorinated Compounds in Beluga Whales (Delphinapterus leucas) from Alaska  

Science Journals Connector (OSTI)

Wildlife from remote locations have been shown to bioaccumulate perfluorinated compounds (PFCs) in their tissues. ... The Chukchi Sea belugas forage in Arctic water between the United States and Russia and based on prevailing wind and ocean currents, these animals may be more reflective of PFCs emissions coming from Asia and Russia. ...

Jessica L. Reiner; Steven G. O’Connell; Amanda J. Moors; John R. Kucklick; Paul R. Becker; Jennifer M. Keller

2011-02-10T23:59:59.000Z

429

The optimisation and exploitation of compound semiconductors will lead to more efficient lighting,  

E-Print Network (OSTI)

The optimisation and exploitation of compound semiconductors will lead to more efficient lighting. This will reduce the consumption of fossil fuels and therefore lower greenhouse gas emissions. Other applications structures. Market and applications · High power electronics. · LED lighting. Licensing and development

Strathclyde, University of

430

Dioxin/furans and Air Pollution Control Dioxins and furans are chlorinated compounds produced during all  

E-Print Network (OSTI)

Dioxin/furans and Air Pollution Control Dioxins and furans are chlorinated compounds produced baghouse. As a result of the new controls, the dioxin/furan emissions of WTE plants in the U (28 million tons of MSW combusted) emit less than six grams TEQ dioxins per year. In comparison

431

On modeling the potential impacts of CO2 sequestration on shallow groundwater: Transport of organics and co-injected H2S by supercritical CO2 to shallow aquifers  

E-Print Network (OSTI)

solvent, and its use to decontaminate soils impacted by hazardous organic compounds is regarded as a “green”

Zheng, L.

2014-01-01T23:59:59.000Z

432

Organizations and Networks | Open Energy Information  

Open Energy Info (EERE)

Jump to: navigation, search Jump to: navigation, search Registered Technical and Research Organizations Networks Climate Eval "The website promotes active debate on areas relevant to evaluation of climate change and development evaluation by bringing relevant topics to a peer to peer discussion forum." Coordinated Low Emissions Assistance Network (CLEAN) CLEAN aims to improve communication and coordination by bringing together national and international organizations that are assisting developing countries with preparation and implementation of low greenhouse gas emission plans and strategies. This includes support for technology needs assessments, for low carbon and clean energy development plans, and for technology roadmaps and deployment programs. Renewable Energy Policy Network for the 21st Century (REN21)

433

Carbon Emissions: Food Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Food Industry Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 6.6% Total First Use of Energy: 1,193 trillion Btu -- Pct. of All Manufacturers: 5.5% Carbon Intensity: 20.44 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 24.4 Net Electricity 9.8 Natural Gas 9.1 Coal 4.2 All Other Sources 1.3 Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998

434

Carbon Emissions: Chemicals Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Chemicals Industry Chemicals Industry Carbon Emissions in the Chemicals Industry The Industry at a Glance, 1994 (SIC Code: 28) Total Energy-Related Emissions: 78.3 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 21.1% -- Nonfuel Emissions: 12.0 MMTC Total First Use of Energy: 5,328 trillion Btu -- Pct. of All Manufacturers: 24.6% Energy Sources Used As Feedstocks: 2,297 trillion Btu -- LPG: 1,365 trillion Btu -- Natural Gas: 674 trillion Btu Carbon Intensity: 14.70 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 78.3 Natural Gas 32.1

435

NETL: Mercury Emissions Control  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Innovations for Existing Plants > Mercury Emissions Control Home > Technologies > Coal & Power Systems > Innovations for Existing Plants > Mercury Emissions Control Innovations for Existing Plants Mercury Emissions Control NETL managed the largest funded research program in the country to develop an in-depth understanding of fossil combustion-based mercury emissions. The program goal was to develop effective control options that would allow generators to comply with regulations. Research focus areas included measurement and characterization of mercury emissions, as well as the development of cost-effective control technologies for the U.S. coal-fired electric generating industry. Control Technologies Field Testing Phase I & II Phase III Novel Concepts APCD Co-benefits Emissions Characterization

436

Carbon Emissions: Paper Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Paper Industry Paper Industry Carbon Emissions in the Paper Industry The Industry at a Glance, 1994 (SIC Code: 26) Total Energy-Related Emissions: 31.6 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 8.5% Total First Use of Energy: 2,665 trillion Btu -- Pct. of All Manufacturers: 12.3% -- Pct. Renewable Energy: 47.7% Carbon Intensity: 11.88 MMTC per quadrillion Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 31.6 Net Electricity 11.0

437

emissions | OpenEI  

Open Energy Info (EERE)

emissions emissions Dataset Summary Description The New Zealand Ministry of Economic Development publishes an annual Energy Outlook, which presents projections of New Zealand's future energy supply, demand, prices and greenhouse gas emissions. The principle aim of these projections is to inform the national energy debate. Included here are the model results for emissions. The spreadsheet provides an interactive tool for selecting which model results to view, and which scenarios to evaluate; full model results for each scenario are also included. Source New Zealand Ministry of Economic Development Date Released Unknown Date Updated December 15th, 2010 (4 years ago) Keywords emissions New Zealand projections Data application/vnd.ms-excel icon 2010 New Zealand emissions outlook (xls, 1.2 MiB)

438

Reducing Diesel Engine Emissions  

NLE Websites -- All DOE Office Websites (Extended Search)

Reducing Reducing Diesel Engine Emissions 2 0 1 0 Green TransporTaTion TechnoloGies Compared to traditional gasoline engines, diesel engines require less maintenance, generate energy more efficiently, and produce less carbon dioxide emissions. But when uncontrolled, diesel engines churn out harmful emissions like particu- late matter (PM) and nitrogen oxides (NO x ). Researchers at Argonne National Laboratory are currently working to develop

439

Development and use of the GREET model to estimate fuel-cycle energy use and emissions of various transportation technologies and fuels  

SciTech Connect

This report documents the development and use of the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The model, developed in a spreadsheet format, estimates the full fuel- cycle emissions and energy use associated with various transportation fuels for light-duty vehicles. The model calculates fuel-cycle emissions of five criteria pollutants (volatile organic compounds, carbon monoxide, nitrogen oxides, sulfur oxides, and particulate matter measuring 10 microns or less) and three greenhouse gases (carbon dioxide, methane, and nitrous oxide). The model also calculates the total fuel-cycle energy consumption, fossil fuel consumption, and petroleum consumption using various transportation fuels. The GREET model includes 17 fuel cycles: petroleum to conventional gasoline, reformulated gasoline, clean diesel, liquefied petroleum gas, and electricity via residual oil; natural gas to compressed natural gas, liquefied petroleum gas, methanol, hydrogen, and electricity; coal to electricity; uranium to electricity; renewable energy (hydrogen, solar energy, and wind) to electricity; corn, woody biomass, and herbaceous biomass to ethanol; and landfill gases to methanol. This report presents fuel-cycle energy use and emissions for a 2000 model-year car powered by each of the fuels that are produced from the primary energy sources considered in the study.

Wang, M.Q.

1996-03-01T23:59:59.000Z

440

4, 227265, 2004 Effect of organic  

E-Print Network (OSTI)

and Physics Discussions Effect of organic compounds on nanoparticle formation in diluted diesel exhaust U. Introduction Exhaust from diesel engines represents an important anthropogenic source of particles in ambient Print Version Interactive Discussion © EGU 2004 Abstract The nucleation of nanoparticles in the exhaust

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Organic chemical contaminants in Biosolids Sally Brown  

E-Print Network (OSTI)

under the general classification "dioxins." Dioxins are one of the well known dangerous organic chemicals. Dioxins had commercial uses, primarily in the pulp and paper industry, but have been outlawed due. There are many types of dioxins. "Dioxin" is actually a general term for a large number of compounds that contain

Brown, Sally

442

AEROBIC BIOTRANSFORMATION OF TOXIC ORGANICS IN WASTEWATER  

E-Print Network (OSTI)

#12;AEROBIC BIOTRANSFORMATION OF TOXIC ORGANICS IN WASTEWATER DOE FRAP 1997-15 Prepared for in both domestic and industrial wastewater. The release of these compounds during wastewater treatment to predict the mass of the VOCs in the wastewater treated by biotransformation and the mass stripped

443

Saving Fuel, Reducing Emissions  

E-Print Network (OSTI)

would in turn lower PHEV fuel costs and make them morestretches from fossil-fuel- powered conventional vehiclesbraking, as do Saving Fuel, Reducing Emissions Making Plug-

Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

2009-01-01T23:59:59.000Z

444

Vehicle Emissions Review - 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vehicle Emissions Review - 2012 Tim Johnson October 16, 2012 2 Environmental Technologies Summary * Regulations - LEVIII finalized, Tier 3? RDE in Europe developing and very...

445

EMSL - emission spectra  

NLE Websites -- All DOE Office Websites (Extended Search)

emission-spectra en Structures and Stabilities of (MgO)n Nanoclusters. http:www.emsl.pnl.govemslwebpublicationsstructures-and-stabilities-mgon-nanoclusters

446

Thermodynamic evaluation of the compounds of gold, silver, and other trace elements formed upon the combustion of brown coal  

Science Journals Connector (OSTI)

The thermodynamically most probable main compounds of Ag, Au, Ge, Se, Sr, U, and ash-forming elements formed upon the combustion of brown coal, which was close in the composition of organic and mineral matter ...

M. Ya. Shpirt; A. A. Lavrinenko; I. N. Kuznetsova…

2013-09-01T23:59:59.000Z

447

Muon-spin spectroscopy of the organometallic spin-1/2 kagome-lattice compound Cu(1,3-benzenedicarboxylate)  

E-Print Network (OSTI)

Using muon-spin resonance, we examine the organometallic hybrid compound Cu(1,3-benzenedicarboxylate) [Cu(1,3-bdc)], which has structurally perfect spin-1/2 copper kagome planes separated by pure organic linkers. This ...

Marcipar, Lital

448

NETL: Emissions Characterization - CMU Emissions Characterization Study  

NLE Websites -- All DOE Office Websites (Extended Search)

Source Emissions Characterization Study Source Emissions Characterization Study The emissions characterization study is being performed in conjunction with the Pittsburgh Air Quality Study [PDF-744KB], a larger effort that includes ambient measurements and atmospheric modeling of the Pittsburgh region. The main objectives of this portion of the study are: To achieve advanced characterization of the PM in the Pittsburgh region. Measurements include the PM size, surface, volume, and mass distribution; chemical composition as a function of size and on a single particle basis; temporal and spatial variability. To obtain accurate current fingerprints of the major primary PM sources in the Pittsburgh region using traditional filter-based sampling and state-of-the-art techniques such as dilution sampling and single particle analysis using mass spectroscopy and LIBS.

449

The POETICs of industrial carbon dioxide emissions in Japan: an urban and institutional extension of the IPAT identity  

Science Journals Connector (OSTI)

This study applies the POETICs framework (population, organization, environment, technology, institutions and culture) to an analysis of industrial carbon dioxide emissions in Japanese cities. The inclusion of in...

Stephan Scholz

2006-09-01T23:59:59.000Z

450

Global Fire Emissions Database, Version 3.1 Published  

NLE Websites -- All DOE Office Websites (Extended Search)

Fire Emissions Database, Version 3.1 Published Fire Emissions Database, Version 3.1 Published The ORNL DAAC is pleased to announce the release of the Global Fire Emissions Database, Version 3.1: Global Fire Emissions Database, Version 3.1. Data set prepared by J.T. Randerson, G.R. van der Werf, L. Giglio, G.J. Collatz, and P.S. Kasibhatla. This data set provides monthly burned area, and monthly and annual fire emissions data from July 1996 to February 2012. Emissions data are available for carbon (C), dry matter (DM), carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), hydrogen (H2), nitrous oxide (N2O), nitrogen oxides (NOx), non-methane hydrocarbons (NMHC), organic carbon (OC), black carbon (BC), particulate matter 2.5 micron (PM2p5), total particulate matter (TPM), and sulfur dioxide (SO2) among others. The C4 fraction of

451

Preparing Low-emission and Climate-Resilient Development Strategies  

Open Energy Info (EERE)

Preparing Low-emission and Climate-Resilient Development Strategies Preparing Low-emission and Climate-Resilient Development Strategies (LECRDS) - Executive Summary Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Preparing Low-Emission and Climate-Resilient Development Strategies (LECRDS) - Executive Summary Agency/Company /Organization: United Nations Development Programme (UNDP) Topics: Low emission development planning Resource Type: Guide/manual Website: www.beta.undp.org/content/undp/en/home/ourwork/environmentandenergy/fo Cost: Free Language: English Preparing Low-Emission and Climate-Resilient Development Strategies (LECRDS) - Executive Summary Screenshot References: Preparing Low-Emission and Climate-Resilient Development Strategies (LECRDS) - Executive Summary[1] This report serves as the Executive Summary to a series of manuals and

452

MOBILE6 Vehicle Emission Modeling Software | Open Energy Information  

Open Energy Info (EERE)

MOBILE6 Vehicle Emission Modeling Software MOBILE6 Vehicle Emission Modeling Software Jump to: navigation, search Tool Summary Name: MOBILE6 Agency/Company /Organization: United States Environmental Protection Agency Sector: Energy Focus Area: Transportation Topics: GHG inventory Resource Type: Software/modeling tools User Interface: Desktop Application Website: www.epa.gov/oms/m6.htm Cost: Free References: http://www.epa.gov/oms/m6.htm MOBILE6 is an emission factor model for predicting gram per mile emissions of Hydrocarbons (HC), Carbon Monoxide (CO), Nitrogen Oxides (NOx), Carbon Dioxide (CO2), Particulate Matter (PM), and toxics from cars, trucks, and motorcycles under various conditions. MOBILE6 is an emission factor model for predicting gram per mile emissions of Hydrocarbons (HC), Carbon Monoxide (CO), Nitrogen Oxides (NOx), Carbon

453

Policies to Reduce Emissions from the Transportation Sector | Open Energy  

Open Energy Info (EERE)

Policies to Reduce Emissions from the Transportation Sector Policies to Reduce Emissions from the Transportation Sector Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Policies to Reduce Emissions from the Transportation Sector Agency/Company /Organization: PEW Center Sector: Climate Focus Area: Transportation, People and Policy Phase: Evaluate Options, Develop Goals, Prepare a Plan Resource Type: Guide/manual User Interface: Other Website: www.pewclimate.org/DDCF-Briefs/Transportation Cost: Free References: Policies To Reduce Emissions From The Transportation Sector[1] Provide an overview of policy tools available to reduce GHG emissions from the transportation sector. Overview Provide an overview of policy tools available to reduce GHG emissions from the transportation sector. Outputs include: General Information

454

Thailand-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Thailand-Low Emissions Asian Development (LEAD) Program Thailand-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Thailand-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Thailand South-Eastern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

455

Cambodia-Lowering Emissions in Asia's Forests (LEAF) | Open Energy  

Open Energy Info (EERE)

Cambodia-Lowering Emissions in Asia's Forests (LEAF) Cambodia-Lowering Emissions in Asia's Forests (LEAF) Jump to: navigation, search Name Cambodia-Lowering Emissions in Asia's Forests (LEAF) Agency/Company /Organization United States Agency for International Development Sector Climate, Land Focus Area Biomass, Forestry Topics GHG inventory, Low emission development planning, -LEDS Resource Type Training materials Website http://www.snvworld.org/en/sec Country Cambodia South-Eastern Asia References LEAF[1] "Lowering Emissions in Asia's Forests (LEAF), supported by USAID/RDMA, aims to strengthen the capacity of target countries to achieve meaningful and sustained reductions in GHG emissions from the forestry-land use sector while assisting them in benefitting from the emerging international REDD+

456

CLEAN-Linking International Instruments to Support Low Emission Planning  

Open Energy Info (EERE)

CLEAN-Linking International Instruments to Support Low Emission Planning CLEAN-Linking International Instruments to Support Low Emission Planning Webinar- TNAs, NAMAs, LEDS and Roadmaps Jump to: navigation, search Tool Summary LAUNCH TOOL Name: CLEAN-Linking International Instruments to Support Low Emission Planning Webinar- TNAs, NAMAs, LEDS and Roadmaps Agency/Company /Organization: National Renewable Energy Laboratory Sector: Energy, Land Topics: Low emission development planning Resource Type: Presentation, Training materials, Video, Webinar Website: en.openei.org/wiki/CLEAN References: CLEAN-Linking International Instruments to Support Low Emission Planning Webinar- TNAs, NAMAs, LEDS and Roadmaps[1] Logo: CLEAN-Linking International Instruments to Support Low Emission Planning Webinar- TNAs, NAMAs, LEDS and Roadmaps

457

Bangladesh-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Bangladesh-Low Emissions Asian Development (LEAD) Program Bangladesh-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Bangladesh-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Bangladesh Southern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

458

Development of the Electricity Carbon Emission Factors for Russia | Open  

Open Energy Info (EERE)

the Electricity Carbon Emission Factors for Russia the Electricity Carbon Emission Factors for Russia Jump to: navigation, search Name Development of the Electricity Carbon Emission Factors for Russia Agency/Company /Organization European Bank for Reconstruction and Development Sector Energy Focus Area Renewable Energy Topics GHG inventory Resource Type Publications Website http://www.lahmeyer.de/fileadm Country Russia Eastern Europe References Development of the Electricity Carbon Emission Factors for Russia[1] References ↑ "Development of the Electricity Carbon Emission Factors for Russia" Retrieved from "http://en.openei.org/w/index.php?title=Development_of_the_Electricity_Carbon_Emission_Factors_for_Russia&oldid=383164" Category: Programs What links here Related changes Special pages

459

MOtor Vehicle Emission Simulator (MOVES) | Open Energy Information  

Open Energy Info (EERE)

MOtor Vehicle Emission Simulator (MOVES) MOtor Vehicle Emission Simulator (MOVES) Jump to: navigation, search Tool Summary Name: MOtor Vehicle Emission Simulator (MOVES) Agency/Company /Organization: U.S. Environmental Protection Agency Focus Area: GHG Inventory Development Topics: Analysis Tools Website: www.epa.gov/otaq/models/moves/index.htm This emission modeling system estimates emissions from mobile sources, including cars, trucks, and motorcycles. The modeling tool covers a broad range of pollutants and allows multiple scale analysis. How to Use This Tool This tool is most helpful when using these strategies: Shift - Change to low-carbon modes Improve - Enhance infrastructure & policies Learn more about the avoid, shift, improve framework for limiting air pollutants and greenhouse gas emissions.

460

Nepal-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Nepal-Low Emissions Asian Development (LEAD) Program Nepal-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Nepal-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Nepal Southern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Vietnam-Lowering Emissions in Asia's Forests (LEAF) | Open Energy  

Open Energy Info (EERE)

Vietnam-Lowering Emissions in Asia's Forests (LEAF) Vietnam-Lowering Emissions in Asia's Forests (LEAF) Jump to: navigation, search Name Vietnam-Lowering Emissions in Asia's Forests (LEAF) Agency/Company /Organization United States Agency for International Development Sector Climate, Land Focus Area Biomass, Forestry Topics GHG inventory, Low emission development planning, -LEDS Resource Type Training materials Website http://www.snvworld.org/en/sec Country Vietnam South-Eastern Asia References LEAF[1] "Lowering Emissions in Asia's Forests (LEAF), supported by USAID/RDMA, aims to strengthen the capacity of target countries to achieve meaningful and sustained reductions in GHG emissions from the forestry-land use sector while assisting them in benefitting from the emerging international REDD+ framework.

462

Lowering Emissions in Asia's Forests (LEAF) | Open Energy Information  

Open Energy Info (EERE)

Lowering Emissions in Asia's Forests (LEAF) Lowering Emissions in Asia's Forests (LEAF) Jump to: navigation, search Name Lowering Emissions in Asia's Forests (LEAF) Agency/Company /Organization United States Agency for International Development Sector Climate, Land Focus Area Biomass, Forestry Topics GHG inventory, Low emission development planning, -LEDS Resource Type Training materials Website http://www.snvworld.org/en/sec Country Cambodia, Laos, Malaysia, Papua New Guinea, Thailand, Vietnam South-Eastern Asia, South-Eastern Asia, South-Eastern Asia, Melanesia, South-Eastern Asia, South-Eastern Asia References LEAF[1] "Lowering Emissions in Asia's Forests (LEAF), supported by USAID/RDMA, aims to strengthen the capacity of target countries to achieve meaningful and sustained reductions in GHG emissions from the forestry-land use sector

463

Vietnam-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Vietnam-Low Emissions Asian Development (LEAD) Program Vietnam-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Vietnam-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Vietnam South-Eastern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

464

Malaysia-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Malaysia-Low Emissions Asian Development (LEAD) Program Malaysia-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Malaysia-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Malaysia South-Eastern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

465

Methodology for Estimating Reductions of GHG Emissions from Mosaic  

Open Energy Info (EERE)

Methodology for Estimating Reductions of GHG Emissions from Mosaic Methodology for Estimating Reductions of GHG Emissions from Mosaic Deforestation Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Methodology for Estimating Reductions of GHG Emissions from Mosaic Deforestation Agency/Company /Organization: World Bank Sector: Land Focus Area: Forestry Topics: Co-benefits assessment, GHG inventory, Resource assessment Resource Type: Publications Website: wbcarbonfinance.org/docs/REDD_Mosaic_Methodology.pdf Methodology for Estimating Reductions of GHG Emissions from Mosaic Deforestation Screenshot References: Methodology for Estimating Reductions of GHG Emissions from Mosaic Deforestation[1] Overview "This methodology is for project activities that reduce emissions of greenhouse gases (GHG) from mosaic deforestation and, where relevant and

466

Thailand-Lowering Emissions in Asia's Forests (LEAF) | Open Energy  

Open Energy Info (EERE)

Thailand-Lowering Emissions in Asia's Forests (LEAF) Thailand-Lowering Emissions in Asia's Forests (LEAF) Jump to: navigation, search Name Thailand-Lowering Emissions in Asia's Forests (LEAF) Agency/Company /Organization United States Agency for International Development Sector Climate, Land Focus Area Biomass, Forestry Topics GHG inventory, Low emission development planning, -LEDS Resource Type Training materials Website http://www.snvworld.org/en/sec Country Thailand South-Eastern Asia References LEAF[1] "Lowering Emissions in Asia's Forests (LEAF), supported by USAID/RDMA, aims to strengthen the capacity of target countries to achieve meaningful and sustained reductions in GHG emissions from the forestry-land use sector while assisting them in benefitting from the emerging international REDD+

467

Selected GHG Emission Supply Curves | Open Energy Information  

Open Energy Info (EERE)

Selected GHG Emission Supply Curves Selected GHG Emission Supply Curves Jump to: navigation, search Tool Summary Name: Selected GHG Emission Supply Curves Agency/Company /Organization: Northwest Power and Conservation Council Sector: Energy Focus Area: Conventional Energy, Energy Efficiency, Renewable Energy, Industry, Transportation, Forestry, Agriculture Topics: GHG inventory, Pathways analysis Resource Type: Dataset, Publications Website: www.nwcouncil.org/energy/grac/20090130_Supply%20Curves_NWPCC_FINAL.pdf Selected GHG Emission Supply Curves Screenshot References: Selected GHG Emission Supply Curves[1] Background "The ECL supply curve model includes data on potential emission reductions for approximately 60 separate technology options. It allows the examination of multiple scenarios involving the inclusion or exclusion of technology

468

Philippines-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Philippines-Low Emissions Asian Development (LEAD) Program Philippines-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Philippines-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Philippines South-Eastern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

469

Laos-Low Emissions Asian Development (LEAD) Program | Open Energy  

Open Energy Info (EERE)

Laos-Low Emissions Asian Development (LEAD) Program Laos-Low Emissions Asian Development (LEAD) Program Jump to: navigation, search Name Laos-Low Emissions Asian Development (LEAD) Program Agency/Company /Organization ICF International, United States Agency for International Development (USAID) Partner USFS, EPA, United States Department of State Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, -LEDS Website http://www.LowEmissionsAsia.or Country Laos South-Eastern Asia References USAID LEAD Program[1] The Low Emissions Asian Development (LEAD) program is a regional US Agency for International Development (USAID) activity that supports developing countries in Asia to achieve long-term, transformative development and accelerate sustainable, climate-resilient economic growth while slowing the

470

Catalysts for Lean Engine Emission Control - Emissions & Emission Controls  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalysts for Lean Engine Emission Control Catalysts for Lean Engine Emission Control Catalysts for controlling NOx from lean engines are studied in great detail at FEERC. Lean NOx Traps (LNTs) and Selective Catalytic Reduction (SCR) are two catalyst technologies of interest. Catalysts are studied from the nanoscale to full scale. On the nanoscale, catalyst powders are analyzed with chemisorptions techniques to determine the active metal surface area where catalysis occurs. Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy is used to observe the chemical reactions occurring on the catalyst surface during catalyst operation. Both powder and coated catalyst samples are analyzed on bench flow reactors in controlled simulated exhaust environments to better characterize the chemical

471

Air Emission Inventory for the INEEL -- 1999 Emission Report  

SciTech Connect

This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

Zohner, Steven K

2000-05-01T23:59:59.000Z

472

IMPACTT5A model : enhancements and modifications since December 1994 - with special reference to the effect of tripled-fuel-economy vehicles on fuel-cycle energy and emissions.  

SciTech Connect

Version 5A of the Integrated Market Penetration and Anticipated Cost of Transportation Technologies (IMPACTT5A) model is a spreadsheet-based set of algorithms that calculates the effects of advanced-technology vehicles on baseline fuel use and emissions. Outputs of this Argonne National Laboratory-developed model include estimates of (1) energy use and emissions attributable to conventional-technology vehicles under a baseline scenario and (2) energy use and emissions attributable to advanced- and conventional-technology vehicles under an alternative market-penetration scenario. Enhancements to IMPACIT made after its initial documentation in December 1994 have enabled it to deal with a wide range of fuel and propulsion system technologies included in Argonne's GREET model in a somewhat modified three-phased approach. Vehicle stocks are still projected in the largely unchanged STOCK module. Vehicle-miles traveled, fuel use, and oil displacement by advanced-technology vehicles are projected in an updated USAGE module. Now, both modules can incorporate vehicle efficiency and fuel share profiles consistent with those of the Partnership for a New Generation of Vehicles. Finally, fuel-cycle emissions of carbon monoxide, volatile organic compounds, nitrogen oxides, toxics, and greenhouse gases are computed in the EMISSIONS module via an interface with the GREET model that was developed specifically to perform such calculations. Because of this interface, results are now more broadly informative than were results from earlier versions of IMPACTT.

Mintz, M. M.; Saricks, C. L.

1999-08-28T23:59:59.000Z

473

Hyperpolarizable compounds and devices fabricated therefrom  

DOE Patents (OSTI)

Substituted compounds having relatively large molecular first order hyperpolarizabilities are provided, along with devices and materials containing them. In general, the compounds bear electron-donating and electron-withdrawing chemical substituents on a polyheterocyclic core. 13 figs.

Therien, M.J.; DiMagno, S.G.

1998-07-21T23:59:59.000Z

474

Bibliography of work on the photocatalytic removal of hazardous compounds from water and air  

SciTech Connect

This is a bibliography of information in the open literature on work that has been done to date on the photocatalytic oxidation of compounds, principally organic compounds. The goal of the listing is removing hazardous oompounds from water or air. It contains lists of substances and literature citations. The bibliography includes information obtained through the middle of 1993 and some selected references for the balance of that year.

Blake, D.M.

1994-05-01T23:59:59.000Z

475

Mitigating Greenhouse Gas Emissions: Voluntary Reporting  

Gasoline and Diesel Fuel Update (EIA)

08(96) 08(96) Distribution Category UC-950 Mitigating Greenhouse Gas Emissions: Voluntary Reporting October 1997 Energy Information Administration Office of Integrated Analysis and Forecasting U.S. Department of Energy Washington, DC 20585 This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should not be construed as advocating or reflecting any policy position of the Department of Energy or of any other organization. For More Information Individuals or members of organizations wishing to report reductions in emissions of greenhouse gases under the auspices of the Voluntary Reporting Program can contact the Energy Information Administration (EIA) at: Voluntary Reporting of Greenhouse Gases Energy Information Administration U.S. Department

476

NETL: IEP - Mercury Emissions Control: Emissions Characterization  

NLE Websites -- All DOE Office Websites (Extended Search)

Control Control Emissions Characterization In anticipation of the 1990 CAAAs, specifically the draft Title III regarding the characterization of potential HAPs from electric steam generating units, DOE initiated a new Air Toxics Program in 1989. The DOE Mercury Measurement and Control Program evolved as a result of the findings from the comprehensive assessment of hazardous air pollutants studies conducted by DOE from 1990 through 1997. DOE, in collaboration with EPRI, performed stack tests at a number of coal-fired power plants (identified on map below) to accurately determine the emission rates of a series of potentially toxic chemicals. These tests had not been conducted previously because of their cost, about $1 million per test, so conventional wisdom on emissions was based on emission factors derived from analyses of coal. In general, actual emissions were found to be about one-tenth previous estimates, due to a high fraction of the pollutants being captured by existing particulate control systems. These data resulted in a decision by EPA that most of these pollutants were not a threat to the environment, and needed no further regulation at power plants. This shielded the coal-fired power industry from major (tens of millions) costs that would have resulted from further controlling these emissions. However, another finding of these studies was that mercury was not effectively controlled in coal-fired utility boiler systems. Moreover, EPA concluded that a plausible link exists between these emissions and adverse health effects. Ineffective control of mercury by existing control technologies resulted from a number of factors, including variation in coal composition and variability in the form of the mercury in flue gases. The volatility of mercury was the main contributor for less removal, as compared to the less volatile trace elements/metals which were being removed at efficiencies over 99% with the fly ash. In addition, it was determined that there was no reliable mercury speciation method to accurately distinguish between the elemental and oxidized forms of mercury in the flue gas. These two forms of mercury respond differently to removal techniques in existing air pollution control devices utilized by the coal-fired utility industry.

477

Organic tanks safety program FY95 waste aging studies  

SciTech Connect

This report gives the second year`s findings of a study of how thermal and radiological processes may change the composition of organic compounds in the underground tanks at Hanford. Efforts were focused on the global reaction kinetics in a simulated waste exposed to {gamma} rays and the reactions of organic radicals with nitrite ion. The gas production is predominantly radiolytic. Decarboxylation of carboxylates is probably an aging pathway. TBP was totaly consumed in almost every run. Radiation clearly accelerated consumption of the other compounds. EDTA is more reactive than citrate. Oximes and possibly organic nitro compounds are key intermediates in the radiolytic redox reactions of organic compounds with nitrate/nitrite. Observations are consistent with organic compounds being progressively degraded to compounds with greater numbers of C-O bonds and fewer C-H and C-C bonds, resulting in an overall lower energy content. If the radwaste tanks are adequately ventilated and continually dosed by radioactivity, their total energy content should have declined. Level of risk depends on how rapidly carboxylate salts of moderate energy content (including EDTA fragments) degrade to low energy oxalate and formate.

Camaioni, D.M.; Samuels, W.D.; Clauss, S.A.; Lenihan, B.D.; Wahl, K.L.; Campbell, J.A.; Shaw, W.J.

1995-09-01T23:59:59.000Z

478

Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes  

DOE Patents (OSTI)

A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

2003-06-03T23:59:59.000Z

479

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

SciTech Connect

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

480

Zirconia coating on stainless steel sheets from organozirconium compounds  

SciTech Connect

The stability and the coating characteristics of a variety of organozirconium compounds have been investigated to coat ZrO/sub 2/ films on stainless steel sheets for the improvement of heat resistance against oxidation. Zirconium tetraoctylate and zirconium tetrakis(acetylacetonate). The authors discuss how the compounds were found to be more stable than zirconium alkoxides in an ambient atmosphere. The ZrO/sub 2/ films from zirconium alkoxides became white and discontinuous when the thickness of the films exceeded about 200 A (20nm). On the other hand, transparent ZrO/sub 2/ films were obtained from zirconium tetraoctylate and zirconium tetrakis(acetylacetonate). The IR spectra of the films showed that the heat treatment at 400{sup 0}C for 5 min produced organic-free ZrO/sub 2/ films. The heat resistance of stainless steel sheets against oxidation was improved by the ZrO/sub 2/ coating, depending on the film thickness.

Izumi, K.; Murakami, M.; Deguchi, T.; Morita, A. (Nisshin Steel Co. Ltd., Tokyo (Japan)); Tohge, N.; Minami, T. (Dept. of Applied Chemistry, Univ. of Osaka Prefecture, Mozu-Umekmachi, Sakai-Shi, Osaka- Fu 591 (JP))

1989-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic compound emissions" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.