National Library of Energy BETA

Sample records for organic carbon oc

  1. Organic and Elemental Carbon Aerosol Particulates at the Southern Great

    Office of Scientific and Technical Information (OSTI)

    Plains Site Field Campaign Report (Program Document) | SciTech Connect Program Document: Organic and Elemental Carbon Aerosol Particulates at the Southern Great Plains Site Field Campaign Report Citation Details In-Document Search Title: Organic and Elemental Carbon Aerosol Particulates at the Southern Great Plains Site Field Campaign Report The purpose of this study was to measure the organic carbon (OC) and elemental carbon (EC) fractions of PM2.5 particulate matter at the U.S. Department

  2. Quantum yield for carbon monoxide production in the 248 nm photodissociation of carbonyl sulfide (OCS)

    SciTech Connect (OSTI)

    Zhao, Z.; Stickel, R.E.; Wine, P.H. [Georgia Institute of Technology, Atlanta, GA (United States)] [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-03-01

    Tunable diode laser absorption spectroscopy has been coupled with excimer laser flash photolysis to measure the quantum yield for CO production from 248 nm photodissociation of carbonyl sulfide (OCS) relative to the well known quantum yield for CO production from 248 nm photolysis of phosgene (Cl{sub 2}CO). The temporal resolution of the experiments was sufficient to distinguish CO formed directly by photodissociation from that formed by subsequent S({sup 3}P{sub j}) reaction with OCS. Under the experimental conditions employed, CO formation via the fast S({sup 1}D{sub 2})+OCS reaction was minimal. Measurements at 297K and total pressures from 4 to 100 Torr N{sub 2}+N{sub 2}O show the CO yield to be greater than 0.95 and most likely unity. This result suggests that the contribution of OCS as a precursor to the lower stratospheric sulfate aerosol layer is somewhat larger than previously thought. 25 refs., 1 fig., 2 tabs.

  3. ARM - Measurement - Organic Carbon Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsOrganic Carbon Concentration ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send...

  4. Mobility of organic carbon from incineration residues

    SciTech Connect (OSTI)

    Ecke, Holger Svensson, Malin

    2008-07-01

    Dissolved organic carbon (DOC) may affect the transport of pollutants from incineration residues when landfilled or used in geotechnical construction. The leaching of dissolved organic carbon (DOC) from municipal solid waste incineration (MSWI) bottom ash and air pollution control residue (APC) from the incineration of waste wood was investigated. Factors affecting the mobility of DOC were studied in a reduced 2{sup 6-1} experimental design. Controlled factors were treatment with ultrasonic radiation, full carbonation (addition of CO{sub 2} until the pH was stable for 2.5 h), liquid-to-solid (L/S) ratio, pH, leaching temperature and time. Full carbonation, pH and the L/S ratio were the main factors controlling the mobility of DOC in the bottom ash. Approximately 60 weight-% of the total organic carbon (TOC) in the bottom ash was available for leaching in aqueous solutions. The L/S ratio and pH mainly controlled the mobilization of DOC from the APC residue. About 93 weight-% of TOC in the APC residue was, however, not mobilized at all, which might be due to a high content of elemental carbon. Using the European standard EN 13 137 for determination of total organic carbon (TOC) in MSWI residues is inappropriate. The results might be biased due to elemental carbon. It is recommended to develop a TOC method distinguishing between organic and elemental carbon.

  5. Worldwide organic soil carbon and nitrogen data

    SciTech Connect (OSTI)

    Zinke, P.J.; Stangenberger, A.G.; Post, W.M.; Emanual, W.R.; Olson, J.S.

    1986-09-01

    The objective of the research presented in this package was to identify data that could be used to estimate the size of the soil organic carbon pool under relatively undisturbed soil conditions. A subset of the data can be used to estimate amounts of soil carbon storage at equilibrium with natural soil-forming factors. The magnitude of soil properties so defined is a resulting nonequilibrium values for carbon storage. Variation in these values is due to differences in local and geographic soil-forming factors. Therefore, information is included on location, soil nitrogen content, climate, and vegetation along with carbon density and variation.

  6. 2OC | Open Energy Information

    Open Energy Info (EERE)

    OC Jump to: navigation, search Name: 2OC Place: Bath, England, United Kingdom Zip: BA1 7AB Product: Bath-based, geo-pressure energy company. 2OC helps organisations in the UK and...

  7. Soil Organic Carbon Degradation, Barrow, 2013-2014 (Dataset) | Data

    Office of Scientific and Technical Information (OSTI)

    Explorer Data Explorer Search Results Soil Organic Carbon Degradation, Barrow, 2013-2014 Title: Soil Organic Carbon Degradation, Barrow, 2013-2014 This dataset provides information about soil organic carbon decomposition in Barrow soil incubation studies. The soil cores were collected from low-center polygon (Area A) and were incubated in the laboratory at different temperatures for up to 60 days. Transformations of soil organic carbon were characterized by UV and FT-IR, and small organic

  8. OCS National Compendium

    SciTech Connect (OSTI)

    Gould, G.J.; Karpas, R.M.; Slitor, D.L.

    1991-06-01

    The Minerals Management Service's (MMS) Outer Continental Shelf Information Program (OCSIP) is responsible for making available to affected coastal States, local governments, and other interested parties data and information related to the Outer Continental Shelf (OCS) Oil and Gas Program. Since its establishment through Section 26 of the OCS Lands Act (OCSLA) Amendments of 1978, OCSIP has prepared regional summary reports, updates, and indexes on leasing, exploration, development, and production activities to fulfill the mandates of the OCSLA Amendments. The OCSIP receives many requests for out-of-print summary reports, updates, and indexes. The purpose of the OCS National Compendium is to consolidate these historical data and to present the data on an OCS-wide and regional scale. The single-volume approach allows the reader access to historical information and facilitates regional comparisons. The fold-out chart in the front of this publication provides the reader with a timeline (January 1988--November 1990) of events since publication of the last Compendium. Some of the events are directly related to the 5-year Oil and Gas Program, whereas others may or may not have an effect on the program. A predominantly graphic format is used in the report so that the large accumulation of data can be more readily comprehended. In some cases, it is not possible to update information through October 21, 1990, because of the nature of the data. For example, production data normally lags 3 months. 58 figs., 37 tabs.

  9. Optimizing Carbon Nanotube Contacts for Use in Organic Photovoltaics: Preprint

    SciTech Connect (OSTI)

    Barnes, T. M.; Blackburn, J. L.; Tenent, R. C.; Morfa, A.; Heben, M.; Coutts, T. J.

    2008-05-01

    This report describes research on optimizing carbon nanotube networks for use as transparent electrical contacts (TCs) in organic photovoltaics (OPV).

  10. Organic carbon-14 in the Amazon River system

    SciTech Connect (OSTI)

    Hedges, J.I.; Ertel, J.R.; Quay, P.D.; Grootes, P.M.; Richey, J.E.; Devol, A.H.; Farwell, G.W.; Schmidt, F.W.; Salati, E.

    1986-03-07

    Coarse and fine suspended particulate organic materials and dissolved humic and fulvic acids transported by the Amazon River all contain bomb-produced carbon-14, indicating relatively rapid turnover of the parent carbon pools. However, the carbon-14 contents of these coexisting carbon forms are measurably different and may reflect varying degrees of retention by soils in the drainage basin. 20 references, 1 table.

  11. Long-term stability of organic carbon-stimulated chromatereduction in contaminated soils, and its relation to manganese redoxstatus

    SciTech Connect (OSTI)

    Tokunaga, Tetsu K.; Wan, Jiamin; Lanzirotti, Antonio; Sutton,Steve R.; Newville, Matthew; Rao, William

    2007-03-13

    In-situ reduction of toxic Cr(V1) to less hazardous Cr(II1)is becoming a popular strategy for remediating contaminated soils.However, the long term stability of reduced Cr remains to be understood,especially given the common presence of MnfIIIJV) oxides that reoxidizeCr(II1). This 4.6 year laboratory study tracked Cr and Mn redoxtransformations in soils contaminated with Cr(V1) which were then treatedwith different amounts of organic carbon (OC). Changes in Cr and Mnoxidation states within soils were directly and nondestructively measuredusing micro X-ray absorption near edge structure spectroscopy. Chromatereduction was roughly lst-order, and the extent of reduction was enhancedwith higher OC additions. However, significant Cr(||1) reoxidationoccurred in soils exposed to the highest Cr(V1) concentrations (2,560 mgkg"'). Transient Cr(II1) reoxidation up to 420 mg kg1 was measured at 1.1years after OC treatment, followed by further reduction. Chromateconcentrations increased by 220 mg kgm1a t the end of the study (4.6years) in one soil. The causal role that Mn oxidation state had inreoxidizing Cr was supported by trends in Mn K-edge energies. Theseresults provide strong evidence for longterm dependence of soil Croxidation states on balances between OC availability and Mn redoxstatus.

  12. Soil Organic Carbon Degradation, Barrow, 2013-2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gu, Baohua; Yang, Ziming

    2015-03-30

    This dataset provides information about soil organic carbon decomposition in Barrow soil incubation studies. The soil cores were collected from low-center polygon (Area A) and were incubated in the laboratory at different temperatures for up to 60 days. Transformations of soil organic carbon were characterized by UV and FT-IR, and small organic acids in water-soluble carbons were quantified by ion chromatography during the incubation

  13. Soil Organic Carbon Degradation, Barrow, 2013-2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gu, Baohua; Yang, Ziming

    This dataset provides information about soil organic carbon decomposition in Barrow soil incubation studies. The soil cores were collected from low-center polygon (Area A) and were incubated in the laboratory at different temperatures for up to 60 days. Transformations of soil organic carbon were characterized by UV and FT-IR, and small organic acids in water-soluble carbons were quantified by ion chromatography during the incubation

  14. Historical emissions of black and organic carbon aerosol from energy-related combustion, 1850-2000 - article no. GB2018

    SciTech Connect (OSTI)

    Bond, T.C.; Bhardwaj, E.; Dong, R.; Jogani, R.; Jung, S.K.; Roden, C.; Streets, D.G.; Trautmann, N.M.

    2007-05-15

    We present an emission inventory of primary black carbon (BC) and primary organic carbon (OC) aerosols from fossil fuel and biofuel combustion between 1850 and 2000. We reconstruct fossil fuel consumption and represent changes in technology on a national and sectoral basis. Our estimates rely on new estimates of biofuel consumption, and updated emission factors for old technologies. Emissions of black carbon increase almost linearly, totaling about 1000 Gg in 1850, 2200 Gg in 1900, 3000 Gg in 1950, and 4400 Gg in 2000. Primary organic carbon shows a similar pattern, with emissions of 4100 Gg, 5800 Gg, 6700 Gg, and 8700 Gg in 1850, 1900, 1950, and 2000, respectively. Biofuel is responsible for over half of BC emission until about 1890, and dominates energy-related primary OC emission throughout the entire period. Coal contributes the greatest fraction of BC emission between 1880 and 1975, and is overtaken by emissions from biofuel around 1975, and by diesel engines around 1990. Previous work suggests a rapid rise in BC emissions between 1950 and 2000. This work supports a more gradual increase between 1950 and 2000, similar to the increase between 1850 and 1925; implementation of clean technology is a primary reason.

  15. Carbon Dioxide Capture in Metal-Organic Frameworks | Center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Dioxide Capture in Metal-Organic Frameworks Previous Next List Kenji Sumida , David L. Rogow , Jarad A. Mason , Thomas M. McDonald , Eric D. Bloch , Zoey R. Herm , Tae-Hyun...

  16. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic

    Office of Scientific and Technical Information (OSTI)

    Leakage into an Unconfined, Oxidizing Limestone Aquifer (Journal Article) | SciTech Connect Journal Article: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer An important risk at CO2 storage sites is the potential for groundwater quality impacts. As

  17. Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data

    SciTech Connect (OSTI)

    Thomas, James; Decker, David; Patterson, Gary; Peterman, Zell; Mihevc, Todd; Larsen, Jessica; Hershey, Ronald

    2007-06-25

    Groundwater samples in the Yucca Mountain area were collected for chemical and isotopic analyses and measurements of water temperature, pH, specific conductivity, and alkalinity were obtained at the well or spring at the time of sampling. For this project, groundwater samples were analyzed for major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). The U.S. Geological Survey (USGS) performed all the fieldwork on this project including measurement of water chemistry field parameters and sample collection. The major ions dissolved in the groundwater, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) were analyzed by the USGS. All preparation and processing of samples for DOC carbon isotopic analyses and geochemical modeling were performed by the Desert Research Institute (DRI). Analysis of the DOC carbon dioxide gas produced at DRI to obtain carbon-13 and carbon-14 values was conducted at the University of Arizona Accelerator Facility (a NSHE Yucca Mountain project QA qualified contract facility). The major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of DIC were used in geochemical modeling (NETPATH) to determine groundwater sources, flow paths, mixing, and ages. The carbon isotopes of DOC were used to calculate groundwater ages that are independent of DIC model corrected carbon-14 ages. The DIC model corrected carbon-14 calculated ages were used to evaluate groundwater travel times for mixtures of water including water beneath Yucca Mountain. When possible, groundwater travel times were calculated for groundwater flow from beneath Yucca Mountain to down gradient sample sites. DOC carbon-14 groundwater ages were also calculated for groundwaters in the Yucca Mountain area. When possible, groundwater travel times were estimated for groundwater flow from beneath Yucca Mountain to down gradient groundwater sample sites using the DOC calculated groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by the USGS, is the best geochemical program for correcting carbon-14 activities for geochemical r

  18. Organic carbon cycling in landfills: Model for a continuum approach

    SciTech Connect (OSTI)

    Bogner, J.; Lagerkvist, A.

    1997-09-01

    Organic carbon cycling in landfills can be addressed through a continuum model where the end-points are conventional anaerobic digestion of organic waste (short-term analogue) and geologic burial of organic material (long-term analogue). Major variables influencing status include moisture state, temperature, organic carbon loading, nutrient status, and isolation from the surrounding environment. Bioreactor landfills which are engineered for rapid decomposition approach (but cannot fully attain) the anaerobic digester end-point and incur higher unit costs because of their high degree of environmental isolation and control. At the other extreme, uncontrolled land disposal of organic waste materials is similar to geologic burial where organic carbon may be aerobically recycled to atmospheric CO{sub 2}, anaerobically converted to CH{sub 4} and CO{sub 2} during early diagenesis, or maintained as intermediate or recalcitrant forms into geologic time (> 1,000 years) for transformations via kerogen pathways. A family of improved landfill models are needed at several scales (molecular to landscape) which realistically address landfill processes and can be validated with field data.

  19. Geochemistry and sedimentation of organic matter in the Triassic-Liassic carbonate laminated source rocks of the Ragusa basin (Italy)

    SciTech Connect (OSTI)

    Brosse, E.; Loreau, J.P.; Frixa, A.

    1988-08-01

    The Noto and Streppenosa formations of the Ragusa basin (southeastern Sicily) are considered the main source rocks for oil in this area. They display various styles of sedimentation in a generally carbonate context. The organic matter is basically of marine planktonic origin but with some variations, especially in terms of O/C ratio and kinetic behavior. Three main styles of sedimentation occurred within these formations: (1) laminates in a dominantly carbonate rock with thin recurrent interlayers of black shales; (2) alternating layers of marls and limestones, both containing interlayers of black shales and with occasional laminations in the limestones; and (3) silty shales, more or less rich in carbonates (30-70%). The highest petroleum potentials are neither strictly associated with the algal-sedimentary laminites nor with the basinal silty facies but with the black shales interbedded in the different facies or abruptly overlying limestones. In these black shales, oxygen-poor kerogens are dominant. Limestones of the alternated layers are generally organic lean (TOC < 1%), and oxygen-rich kerogens are dominant. The transition from one type of kerogen to the other occurs in the marly layers of the sequence. A tentative integration of both sedimentological and geochemical results is proposed, at the scale of the core, to interpret the respective influence of the depositional pattern and the diagenetic conditions on the content and nature of the kerogen in the source rocks.

  20. Ab initio Carbon Capture in Open-Site Metal Organic Frameworks | Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Ab initio Carbon Capture in Open-Site Metal Organic Frameworks

  1. Ultraviolet photodissociation of OCS: Product energy and angular distributions

    SciTech Connect (OSTI)

    McBane, G. C. [Department of Chemistry, Grand Valley State University, Allendale, Michigan 49401 (United States); Schmidt, J. A.; Johnson, M. S. [Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen O (Denmark); Schinke, R. [Max-Planck-Institut fuer Dynamik und Selbstorganisation (MPIDS), D-37077 Goettingen (Germany)

    2013-03-07

    The ultraviolet photodissociation of carbonyl sulfide (OCS) was studied using three-dimensional potential energy surfaces and both quantum mechanical dynamics calculations and classical trajectory calculations including surface hopping. The transition dipole moment functions used in an earlier study [J. A. Schmidt, M. S. Johnson, G. C. McBane, and R. Schinke, J. Chem. Phys. 137, 054313 (2012)] were improved with more extensive treatment of excited electronic states. The new functions indicate a much larger contribution from the 1 {sup 1}A{sup Double-Prime} state ({sup 1}{Sigma}{sup -} in linear OCS) than was found in the previous work. The new transition dipole functions yield absorption spectra that agree with experimental data just as well as the earlier ones. The previously reported potential energy surfaces were also empirically modified in the region far from linearity. The resulting product state distributions P{sub v,j}, angular anisotropy parameters {beta}(j), and carbon monoxide rotational alignment parameters A{sub 0}{sup (2)}(j) agree reasonably well with the experimental results, while those computed from the earlier transition dipole and potential energy functions do not. The higher-j peak in the bimodal rotational distribution is shown to arise from nonadiabatic transitions from state 2 {sup 1}A{sup Prime} to the OCS ground state late in the dissociation.

  2. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2014-10-30

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon (OC) stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous OC stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global C cycle and the potential vulnerability of the region's soil OC stocks to changing climatic conditions. In this review,more » we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of OC stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this OC to permafrost thaw under a warming climate.« less

  3. Metal-Containing Organic and Carbon Aerogels for Hydrogen Storage

    SciTech Connect (OSTI)

    Satcher, Jr., J H; Baumann, T F; Herberg, J L

    2005-01-10

    This document and the accompanying manuscript summarize the technical accomplishments of our one-year LDRD-ER effort. Hydrogen storage and hydrogen fuel cells are important components of the 2003 Hydrogen Fuel Initiative focused on the reduction of America's dependence on oil. To compete with oil as an energy source, however, one must be able to transport and utilize hydrogen at or above the target set by DOE (6 wt.% H{sub 2}) for the transportation sector. Other than liquid hydrogen, current technology falls well short of this DOE target. As a result, a variety of materials have recently been investigated to address this issue. Carbon nanostructures have received significant attention as hydrogen storage materials due to their low molecular weight, tunable microporosity and high specific surface areas. For example, the National Renewable Energy Laboratory (NREL) achieved 5 to 10 wt.% H{sub 2} storage using metal-doped carbon nanotubes. That study showed that the intimate mix of metal nanoparticles with graphitic carbon resulted in the unanticipated hydrogen adsorption at near ambient conditions. The focus of our LDRD effort was the investigation of metal-doped carbon aerogels (MDCAs) as hydrogen storage materials. In addition to their low mass densities, continuous porosities and high surface areas, these materials are promising candidates for hydrogen storage because MDCAs contain a nanometric mix of metal nanoparticles and graphitic nanostructures. For FY04, our goals were to: (1) prepare a variety of metal-doped CAs (where the metal is cobalt, nickel or iron) at different densities and carbonization temperatures, (2) characterize the microstructure of these materials and (3) initiate hydrogen adsorption/desorption studies to determine H2 storage properties of these materials. Since the start of this effort, we have successfully prepared and characterized Ni- and Co-doped carbon aerogels at different densities and carbonization temperatures. The bulk of this work is described in the attached manuscript entitled 'Formation of Carbon Nanostructures in Cobalt- and Nickel- Doped Carbon Aerogels'. This one-year effort has lead to our incorporation into the DOE Carbon-based Hydrogen Storage Center of Excellence at NREL, with funding from DOE's Energy Efficiency and Renewable Energy (EERE) Program starting in FY05.

  4. Ab-initio Carbon Capture in Open-Site Metal Organic Frameworks...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ab-initio Carbon Capture in Open-Site Metal Organic Frameworks Previous Next List A. Dzubak, L.-C. Lin, J. Kim, J. A. Swisher, R. Poloni, S. N. Maximoff, B. Smit, and L. Gagliardi,...

  5. Metal binding in an aluminum based metal-organic framework for carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dioxide capture | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Metal binding in an aluminum based metal-organic framework for carbon dioxide capture

  6. Origin of particulate organic carbon in the marine atmosphere as indicated by it stable carbon isotopic composition

    SciTech Connect (OSTI)

    Chesselet, R.; Fontugne, M.; Buat-Menard, P.; Ezat, U.; Lambert, C.E.

    1981-04-01

    Organic carbon concentration and isotopic composition were determined in samples of atmospheric particulate matter collected in 1979 at remote marine locations (Enewetak atoll, Sargasso Sea) during the SEAREX (Sea-Air Exchange) program field experiments. Atmospheric Particulate Organic Carbon (POC) concentrations were found to be in the range of 0.3 to 1.2 mg. m/sup -3/, in agreement with previous literature data. The major mass of POC was found on the smallest particles (r<0.5 mm). The /sup 13/C//sup 12/C of the small particles is close to the one expected (d/sup 13/C = 26 +- 2/sup 0///sub infinity/) for atmospheric POC of continental origin. For all the samples analysed so far, it appears that more than 80% of atmospheric POC over remote marine areas is of continental origin. This can be explained either by long-range transport of small sized continental organic aserosols or by the production of POC in the marine atmosphere from a vapor phase organic carbon pool of continental origin. The POC in the large size fraction of marine aerosols (<20% of the total concentration) is likely to have a direct marine origin since its carbon isotopic composition is close to the expected value (d/sup 13/C = -21 +- 2/sup 0///sub 00/) for POC associated with sea-salt droplets transported to the marine atmosphere.

  7. Hydrogenolysis of 6-carbon sugars and other organic compounds

    DOE Patents [OSTI]

    Werpy, Todd A.; Frye, Jr., John G.; Zacher, Alan H.; Miller, Dennis J.

    2005-01-11

    Methods for hydrogenolysis are described which use a Re-containing multimetallic catalyst for hydrogenolysis of both C--O and C--C bonds. Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 6-carbon sugar, sugar alcohol, or glycerol are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol.

  8. Recent advances in carbon dioxide capture with metal-organic frameworks |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Recent advances in carbon dioxide capture with metal-organic frameworks Previous Next List Yangyang Liu, Zhiyong U. Wang, Hong-Cai Zhou, Greenhouse Gas Sci Technol, 2: 239-259, 2012 DOI: 10.1002/ghg.1296 Abstract: Uncontrolled massive release of the primary greenhouse gas carbon dioxide (CO2) into atmosphere from anthropogenic activities poses a big threat and adversely affects our global climate and natural

  9. Substrate and environmental controls on microbial assimilation of soil organic carbon: a framework for Earth System Models

    SciTech Connect (OSTI)

    Xu, Xiaofeng; Schimel, Joshua; Thornton, Peter E; Song, Xia; Yuan, Fengming; Goswami, Santonu

    2014-01-01

    Microbial assimilation of soil organic carbon is one of the fundamental processes of global carbon cycling and it determines the magnitude of microbial biomass in soils. Mechanistic understanding of microbial assimilation of soil organic carbon and its controls is important for to improve Earth system models ability to simulate carbon-climate feedbacks. Although microbial assimilation of soil organic carbon is broadly considered to be an important parameter, it really comprises two separate physiological processes: one-time assimilation efficiency and time-dependent microbial maintenance energy. Representing of these two mechanisms is crucial to more accurately simulate carbon cycling in soils. In this study, a simple modeling framework was developed to evaluate the substrate and environmental controls on microbial assimilation of soil organic carbon using a new term: microbial annual active period (the length of microbes remaining active in one year). Substrate quality has a positive effect on microbial assimilation of soil organic carbon: higher substrate quality (lower C:N ratio) leads to higher ratio of microbial carbon to soil organic carbon and vice versa. Increases in microbial annual active period from zero stimulate microbial assimilation of soil organic carbon; however, when microbial annual active period is longer than an optimal threshold, increasing this period decreases microbial biomass. The simulated ratios of soil microbial biomass to soil organic carbon are reasonably consistent with a recently compiled global dataset at the biome-level. The modeling framework of microbial assimilation of soil organic carbon and its controls developed in this study offers an applicable ways to incorporate microbial contributions to the carbon cycling into Earth system models for simulating carbon-climate feedbacks and to explain global patterns of microbial biomass.

  10. Method and apparatus for regenerating activated carbon containing an adsorbed volatile organic absorbate

    SciTech Connect (OSTI)

    Tiggelbeck, D.D.; Goyak, G.M.

    1993-07-27

    A method is described for regenerating spent activated carbon containing adsorbed volatile organic adsorbate comprising: establishing a confined downwardly moving bed of activated carbon; adding spent carbon to the top of said bed; introducing superheated steam into the bottom of said bed in contact with said carbon; recovering exit gas including predominantly superheated steam and volatilized adsorbate from the top of said bed; circulating a portion of said exit gas through a superheater and compressor to the bottom of said bed; withdrawing a portion of said exit gas through a cooler to condense steam and volatile adsorbate; continuously circulating superheated steam in a closed loop through said downwardly moving bed, said compressor and said superheater; recovering partially regenerated activated carbon containing residual volatile adsorbate from the bottom of said bed.

  11. Optical Properties of Mixed Black Carbon, Inorganic and Secondary Organic Aerosols

    SciTech Connect (OSTI)

    Paulson, S E

    2012-05-30

    Summarizes the achievements of the project, which are divided into four areas: 1) Optical properties of secondary organic aerosols; 2) Development and of a polar nephelometer to measure aerosol optical properties and theoretical approaches to several optical analysis problems, 3) Studies on the accuracy of measurements of absorbing carbon by several methods, and 4) Environmental impacts of biodiesel.

  12. Study on removal of organic sulfur compound by modified activated carbon

    SciTech Connect (OSTI)

    Fan Huiling; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology (China). Research Inst. for Chemical Engineering of Coal

    1997-12-31

    With the price of coal increasing in China, more and more small and medium scale chemical plants are turning to high sulfur coal as the raw material in order to cut cost. However, the major drawback is that the lifetime of the ammonia synthesis catalyst is then reduced greatly because of the high concentration of the sulfur compounds in the synthesis gas, especially organic sulfur, usually CS{sub 2} and COS. The effects of water vapor and experimental temperature on removal of organic sulfur compounds by using a modified activated carbon were studied in this paper. It was found that water vapor had a negative effect on removal of carbon disulfide by activated carbon impregnated with organic amine. The use of activated carbon impregnated with K{sub 2}CO{sub 3} for removal of carbonyl sulfide was also investigated over the temperature range 30--60, the results show a favorable temperature (40) existing for carbonyl sulfide removal. Fixed-bed breakthrough curves for the adsorbent bed were also offered in this paper.

  13. Electrosynthesis of Organic Compounds from Carbon Dioxide Is Catalyzed by a Diversity of Acetogenic Microorganisms

    SciTech Connect (OSTI)

    Nevin, KP; Hensley, SA; Franks, AE; Summers, ZM; Ou, JH; Woodard, TL; Snoeyenbos-West, OL; Lovley, DR

    2011-04-20

    Microbial electrosynthesis, a process in which microorganisms use electrons derived from electrodes to reduce carbon dioxide to multicarbon, extracellular organic compounds, is a potential strategy for capturing electrical energy in carbon-carbon bonds of readily stored and easily distributed products, such as transportation fuels. To date, only one organism, the acetogen Sporomusa ovata, has been shown to be capable of electrosynthesis. The purpose of this study was to determine if a wider range of microorganisms is capable of this process. Several other acetogenic bacteria, including two other Sporomusa species, Clostridium ljungdahlii, Clostridium aceticum, and Moorella thermoacetica, consumed current with the production of organic acids. In general acetate was the primary product, but 2-oxobutyrate and formate also were formed, with 2-oxobutyrate being the predominant identified product of electrosynthesis by C. aceticum. S. sphaeroides, C. ljungdahlii, and M. thermoacetica had high (> 80%) efficiencies of electrons consumed and recovered in identified products. The acetogen Acetobacterium woodii was unable to consume current. These results expand the known range of microorganisms capable of electrosynthesis, providing multiple options for the further optimization of this process.

  14. Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review

    SciTech Connect (OSTI)

    Burant, Aniela; Lowry, Gregory V.; Karamalidis, Athanasios K.

    2013-01-13

    Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oilbrinesc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by cosolvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oilbrinesc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and cosolvency, which will require more experimental data from key classes of organic compounds.

  15. Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review

    SciTech Connect (OSTI)

    Burant, Aniela; Lowry, Gregory V; Karamalidis, Athanasios K

    2012-12-04

    Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oil–brine–sc-CO{sub 2} system under carbon storage conditions. The solubility of pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by co-solvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oil-brine-sc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and co-solvency, which will require more experimental data from key classes of organic compounds.

  16. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  17. Transport of Organic Contaminants Mobilized from Coal through Sandstone Overlying a Geological Carbon Sequestration Reservoir

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Bacon, Diana H.; Shewell, Jesse L.

    2014-02-01

    Column experiments were conducted using a wetted sandstone rock installed in a tri-axial core holder to study the flow and transport of organic compounds mobilized by scCO2 under simulated geologic carbon storage (GCS) conditions. The sandstone rock was collected from a formation overlying a deep saline reservoir at a GCS demonstration site. Rock core effluent pressures were set at 0, 500, or 1000 psig and the core temperature was set at 20 or 50C to simulate the transport to different subsurface depths. The concentrations of the organic compounds in the column effluent and their distribution within the sandstone core were monitored. Results indicate that the mobility though the core sample was much higher for BTEX compounds than for naphthalene. Retention of organic compounds from the vapor phase to the core appeared to be primarily controlled by partitioning from the vapor phase to the aqueous phase. Adsorption to the surfaces of the wetted sandstone was also significant for naphthalene. Reduced temperature and elevated pressure resulted in greater partitioning of the mobilized organic contaminants into the water phase.

  18. Steady state estimation of soil organic carbon using satellite-derived canopy leaf area index

    SciTech Connect (OSTI)

    Fang, Yilin; Liu, Chongxuan; Huang, Maoyi; Li, Hongyi; Leung, Lai-Yung R.

    2014-12-02

    Soil organic carbon (SOC) plays a key role in the global carbon cycle that is important for decadal-to-century climate prediction. Estimation of soil organic carbon stock using model-based methods typically requires spin-up (time marching transient simulation) of the carbon-nitrogen (CN) models by performing hundreds to thousands years long simulations until the carbon-nitrogen pools reach dynamic steady-state. This has become a bottleneck for global modeling and analysis, especially when testing new physical and/or chemical mechanisms and evaluating parameter sensitivity. Here we report a new numerical approach to estimate global soil carbon stock that can avoid the long term spin-up of the CN model. The approach uses canopy leaf area index (LAI) from satellite data and takes advantage of a reaction-based biogeochemical module NGBGC (Next Generation BioGeoChemical Module) that was recently developed and incorporated in version 4 of the Community Land Model (CLM4). Although NGBGC uses the same CN mechanisms as used in CLM4CN, it can be easily configured to run prognostic or steady state simulations. In this approach, monthly LAI from the multi-year Moderate Resolution Imaging Spectroradiometer (MODIS) data was used to calculate potential annual average gross primary production (GPP) and leaf carbon for the period of the atmospheric forcing. The calculated potential annual average GPP and leaf C are then used by NGBGC to calculate the steady-state distributions of carbon and nitrogen in different vegetation and soil pools by solving the steady-state reaction-network in NGBGC using the Newton-Raphson method. The new approach was applied at point and global scales and compared with SOC derived from long spin-up by running NGBGC in prognostic mode, and SOC from the empirical data of the Harmonized World Soil Database (HWSD). The steady-state solution is comparable to the spin-up value when the MODIS LAI is close to the LAI from the spin-up solution, and largely captured the variability of the HWSD SOC across the different dominant plant functional types (PFTs) at global scale. The numerical correlation between the calculated and HWSD SOC was, however, weak at both point and global scales, suggesting that the models used in describing biogeochemical processes in CLM needs improvements and/or HWSD needs updating as suggested by other studies. Besides SOC, the steady state solution also includes all other state variables simulated by a spin-up run, such as NPP, GPP, total vegetation C etc., which makes the developed approach a promising tool to efficiently estimate global SOC distribution and evaluate and compare different aspects simulated by different CN mechanisms in the model.

  19. Steady state estimation of soil organic carbon using satellite-derived canopy leaf area index

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, Yilin; Liu, Chongxuan; Huang, Maoyi; Li, Hongyi; Leung, Lai-Yung R.

    2014-12-02

    Soil organic carbon (SOC) plays a key role in the global carbon cycle that is important for decadal-to-century climate prediction. Estimation of soil organic carbon stock using model-based methods typically requires spin-up (time marching transient simulation) of the carbon-nitrogen (CN) models by performing hundreds to thousands years long simulations until the carbon-nitrogen pools reach dynamic steady-state. This has become a bottleneck for global modeling and analysis, especially when testing new physical and/or chemical mechanisms and evaluating parameter sensitivity. Here we report a new numerical approach to estimate global soil carbon stock that can avoid the long term spin-up of themore » CN model. The approach uses canopy leaf area index (LAI) from satellite data and takes advantage of a reaction-based biogeochemical module NGBGC (Next Generation BioGeoChemical Module) that was recently developed and incorporated in version 4 of the Community Land Model (CLM4). Although NGBGC uses the same CN mechanisms as used in CLM4CN, it can be easily configured to run prognostic or steady state simulations. In this approach, monthly LAI from the multi-year Moderate Resolution Imaging Spectroradiometer (MODIS) data was used to calculate potential annual average gross primary production (GPP) and leaf carbon for the period of the atmospheric forcing. The calculated potential annual average GPP and leaf C are then used by NGBGC to calculate the steady-state distributions of carbon and nitrogen in different vegetation and soil pools by solving the steady-state reaction-network in NGBGC using the Newton-Raphson method. The new approach was applied at point and global scales and compared with SOC derived from long spin-up by running NGBGC in prognostic mode, and SOC from the empirical data of the Harmonized World Soil Database (HWSD). The steady-state solution is comparable to the spin-up value when the MODIS LAI is close to the LAI from the spin-up solution, and largely captured the variability of the HWSD SOC across the different dominant plant functional types (PFTs) at global scale. The numerical correlation between the calculated and HWSD SOC was, however, weak at both point and global scales, suggesting that the models used in describing biogeochemical processes in CLM needs improvements and/or HWSD needs updating as suggested by other studies. Besides SOC, the steady state solution also includes all other state variables simulated by a spin-up run, such as NPP, GPP, total vegetation C etc., which makes the developed approach a promising tool to efficiently estimate global SOC distribution and evaluate and compare different aspects simulated by different CN mechanisms in the model.« less

  20. Effects of solar radiation on organic matter cycling: Formation of carbon monoxide and carbonyl sulfide (Chapter 11). Book chapter

    SciTech Connect (OSTI)

    Zepp, R.G.

    1994-01-01

    The effects of photoinduced processes on carbon cycling and the biospheric emission of two important trace carbon gases--carbon monoxide and carbonyl sulfide--are examined. Both of these gases are likely to play an important role in the biospheric feedbacks that may reinforce or attenuate future changes in climate. Evidence is presented to support the hypothesis that a significant fraction of the global sources of both of these gases derives from the photochemical fragmentation of decayed plant materials and other biogenic organic matter in terrestrial and marine environments.

  1. Photocatalytic and chemical oxidation of organic compounds in supercritical carbon dioxide. Progress report for FY97

    SciTech Connect (OSTI)

    Blake, D.M.; Bryant, D.L.; Reinsch, V.

    1997-09-30

    'The background for the project is briefly reviewed and the work done during the nine months since funding was received is documented. Work began in January, 1997. A post doctoral fellow joined the team in April. The major activities completed this fiscal year were: staffing the project, design of the experimental system, procurement of components, assembly of the system. preparation of the Safe Operating Procedure and ES and H compliance, pressure testing, establishing data collection and storage methodology, and catalyst preparation. Objective The objective of the project is to develop new chemistry for the removal of organic contaminants from supercritical carbon dioxide. This has application in processes used for continuous cleaning and extraction of parts and waste materials. A secondary objective is to increase the fundamental understanding of photocatalytic chemistry. Cleaning and extraction using supercritical carbon dioxide (scCO{sub 2}) can be applied to the solution of a wide range of environmental and pollution prevention problems in the DOE complex. Work is being done that explores scCO{sub 2} in applications ranging from cleaning contaminated soil to cleaning components constructed from plutonium. The rationale for use of scCO{sub 2} are based on the benign nature, availability and low cost, attractive solvent properties, and energy efficient separation of the extracted solute from the solvent by moderate temperature or pressure changes. To date, R and D has focussed on the methods and applications of the extraction steps of the process. Little has been done that addresses methods to polish the scCO{sub 2} for recycle in the cleaning or extraction operations. In many applications it will be desirable to reduce the level of contamination from that which would occur at steady state operation of a process. This proposal addresses chemistry to achieve that. This would be an alternative to removing a fraction of the contaminated scCO{sub 2} for disposal and using makeup scCO{sub 2}. A chemical polishing operation can reduce the release of CO{sub 2} from the process. It can also reduce the consumption of reagents that may be used in the process to enhance extraction and cleaning. A polishing operation will also reduce or avoid formation of an additional waste stream. Photocatalytic and other photochemical oxidation chemistry have not been investigated in scCO{sub 2}. The large base of information for these reactions in water, organic solvents, or air suggest that the chemistry will work in carbon dioxide. There are compelling reasons to believe that the properties of scCO{sub 2} should increase the performance of photocatalytic chemistry over that found in more conventional fluid phases.'

  2. Carbon dioxide effects research and assessment program: flux of organic carbon by rivers to the oceans. [Lead abstract

    SciTech Connect (OSTI)

    1981-04-01

    Separate abstracts were prepared for the 15 papers presented in this workshop report. The state of knowledge about the role of rivers in the transport, storage and oxidation of carbon is the subject of this report. (KRM)

  3. Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols

    SciTech Connect (OSTI)

    Wang, Bingbing; O'Brien, Rachel E.; Kelly, Stephen T.; Shilling, John E.; Moffet, Ryan C.; Gilles, Mary K.; Laskin, Alexander

    2015-05-14

    Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semi-solid SOC from ozonolysis of limonene (LSOC) and ?-pinene (PSOC) with NaCl using a set of complementary micro-spectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the high volatility of HCl. Similar reactions can take place in SOC/NaNO? particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO? from reacted aerosol particles may have important implications for atmospheric chemistry.

  4. Metal-Organic Framework Derived Hierarchically Porous Nitrogen-Doped Carbon Nanostructures as Novel Electrocatalyst for Oxygen Reduction Reaction

    SciTech Connect (OSTI)

    Fu, Shaofang; Zhu, Chengzhou; Zhou, Yazhou; Yang, Guohai; Jeon, Ju Won; Lemmon, John P.; Du, Dan; Nune, Satish K.; Lin, Yuehe

    2015-10-01

    The hierarchically porous nitrogen-doped carbon materials, derived from nitrogen-containing isoreticular metal-organic framework-3 (IRMOF-3) through direct carbonization, exhibited excellent electrocatalytic activity in alkaline solution for oxygen reduction reaction (ORR). This high activity is attributed to the 10 presence of high percentage of quaternary and pyridinic nitrogen, the high surface area as well as good conductivity. When IRMOF-3 was carbonized at 950 C (CIRMOF-3-950), it showed four-electron reduction pathway for ORR and exhibited better stability (about 78.5% current density was maintained) than platinum/carbon (Pt/C) in the current durability test. In addition, CIRMOF-3-950 presented high selectivity to cathode reactions compared to commercial Pt/C.

  5. Low Power, Red, Green and Blue Carbon Nanotube Enabled Vertical Organic Light Emitting Transistors for Active Matrix OLED Displays

    SciTech Connect (OSTI)

    McCarthy, M. A. [University of Florida, Gainesville; Liu, B. [University of Florida, Gainesville; Donoghue, E. P. [University of Florida, Gainesville; Kravchenko, Ivan I [ORNL; Kim, D. Y. [University of Florida, Gainesville; So, Franky [University of Florida, Gainesville; Rinzler, A. G. [University of Florida, Gainesville

    2011-01-01

    Organic semiconductors are potential alternatives to polycrystalline silicon as the semiconductor used in the backplane of active matrix organic light emitting diode displays. Demonstrated here is a light-emitting transistor with an organic channel, operating with low power dissipation at low voltage, and high aperture ratio, in three colors: red, green and blue. The single-wall carbon nanotube network source electrode is responsible for the high level of performance demonstrated. A major benefit enabled by this architecture is the integration of the drive transistor, storage capacitor and light emitter into a single device. Performance comparable to commercialized polycrystalline-silicon TFT driven OLEDs is demonstrated.

  6. Carbon Nanosheets and Nanostructured Electrodes in Organic Photovoltaic Devices: Cooperative Research and Development Final Report, CRADA Number CRD-08-321

    SciTech Connect (OSTI)

    Olson, D.

    2012-04-01

    Carbon nanosheet thin films were employed as nanostructured electrodes in organic solar cells. Due to the nanostructured texture of the carbon nanosheet electrodes, there was an increase in performance over standard ITO electrodes with very thick active layers. ZnO deposited via atomic layer deposition (ALD) was used as a hole blocking layer to provide for carrier selectivity of the carbon nanosheets.

  7. Operational experience of the OC-OTEC experiments at NELH

    SciTech Connect (OSTI)

    Link, H.

    1989-02-01

    The Solar Energy Research Institute, under funding and program direction from the US Department of Energy, has been operating a small-scale test apparatus to investigate key components of open- cycle ocean thermal energy conversion (OC-OTEC). The apparatus started operations in October 1987 and continues to provide valuable information on heat-and mass-transfer processes in evaporators and condensers, gas sorption processes as seawater is depressurized and repressurized, and control and instrumentation characteristics of open-cycle systems. Although other test facilities have been used to study some of these interactions, this is the largest apparatus of its kind to use seawater since Georges Claude's efforts in 1926. The information obtained from experiments conducted in this apparatus is being used to design a larger scale experiment in which a positive net power production is expected to be demonstrated for the first time with OC-OTEC. This paper describes the apparatus, the major tests conducted during its first 18 months of operation, and the experience gained in OC-OTEC system operation. 13 refs., 8 figs.

  8. Operational experience of the OC-OTEC experiments at NELH

    SciTech Connect (OSTI)

    Link, H.

    1989-02-01

    The Solar Energy Research Institute, under funding and program direction from the US Department of Energy, has been operating a small-scale test apparatus to investigate key components of open- cycle ocean thermal energy conversion (OC-OTEC). The apparatus started operations in October 1987 and continues to provide valuable information on heat-and mass-transfer processes in evaporators and condensers, gas sorption processes as seawater is depressurized and repressurized, and control and instrumentation characteristics of open-cycle systems. Although other test facilities have been used to study some of these interactions, this is the largest apparatus of its kind to use seawater since Georges Claude`s efforts in 1926. The information obtained from experiments conducted in this apparatus is being used to design a larger scale experiment in which a positive net power production is expected to be demonstrated for the first time with OC-OTEC. This paper describes the apparatus, the major tests conducted during its first 18 months of operation, and the experience gained in OC-OTEC system operation. 13 refs., 8 figs.

  9. Genomic expansion of Domain Archaea highlights roles for organisms from new phyla in anaerobic carbon cycling

    SciTech Connect (OSTI)

    Castelle, Cindy; Wrighton, Kelly C.; Thomas, Brian C.; Hug, Laura A.; Brown, Christopher T.; Wilkins, Michael J.; Frischkorn, Kyle R.; Tringe, Susannah G.; Singh, Andrea; Markillie, Lye Meng; Taylor, Ronald C.; Williams, Kenneth H.; Banfield, Jillian F.

    2015-03-01

    Domain Archaea is currently represented by one phylum (Euryarchaeota) and two superphyla (TACK and DPANN). However, gene surveys indicate the existence of a vast diversity of uncultivated archaea for which metabolic information is lacking. We sequenced DNA from complex sediment- and groundwater-associated microbial communities sampled prior to and during an acetate biostimulation field experiment to investigate the diversity and physiology of uncultivated subsurface archaea. We sampled 15 genomes that improve resolution of a new phylum within the TACK superphylum and 119 DPANN genomes that highlight a major subdivision within the archaeal domain that separates DPANN from TACK/Euryarchaeota lineages. Within the DPANN superphylum, which lacks any isolated representatives, we defined two new phyla using sequences from 100 newly sampled genomes. The first new phylum, for which we propose the name Woesearchaeota, was defined using 54 new sequences. We reconstructed a complete (finished) genome for an archaeon from this phylum that is only 0.8 Mb in length and lacks almost all core biosynthetic pathways, but has genes encoding enzymes predicted to interact with bacterial cell walls, consistent with a symbiotic lifestyle. The second new phylum, for which we propose the name Pacearchaeota, was defined based on 46 newly sampled archaeal genomes. This phylum includes the first non-methanogen with an intermediate Type II/III RuBisCO. We also reconstructed a complete (1.24 Mb) genome for another DPANN archaeon, a member of the Diapherotrites phylum. Metabolic prediction and transcriptomic data indicate that this organism has a fermentation-based lifestyle. In fact, genomic analyses consistently indicate lack of recognizable pathways for sulfur, nitrogen, methane, oxygen, and metal cycling, and suggest that symbiotic and fermentation-based lifestyles are widespread across the DPANN superphylum. Thus, as for a recently identified superphylum of bacteria with small genomes and no cultivated representatives, the biogeochemical impacts of this major radiation of archaea are primarily through anaerobic carbon and hydrogen cycling.

  10. File:BOEMRE OCS.oil.gas.2007-12.map.pdf | Open Energy Information

    Open Energy Info (EERE)

    OCS.oil.gas.2007-12.map.pdf Jump to: navigation, search File File history File usage Outer Continental Shelf (OCS) Oil & Gas Leasing Program 2007 - 2012 Size of this preview: 700...

  11. Composite Membranes for CO2 Capture: High Performance Metal Organic Frameworks/Polymer Composite Membranes for Carbon Dioxide Capture

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: A team of six faculty members at Georgia Tech are developing an enhanced membrane by fitting metal organic frameworks, compounds that show great promise for improved carbon capture, into hollow fiber membranes. This new material would be highly efficient at removing CO2 from the flue gas produced at coal-fired power plants. The team is analyzing thousands of metal organic frameworks to identify those that are most suitable for carbon capture based both on their ability to allow coal exhaust to pass easily through them and their ability to select CO2 from that exhaust for capture and storage. The most suitable frameworks would be inserted into the walls of the hollow fiber membranes, making the technology readily scalable due to their high surface area. This composite membrane would be highly stable, withstanding the harsh gas environment found in coal exhaust.

  12. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    Office of Scientific and Technical Information (OSTI)

    3 (2014) 4684 - 4707 Energy Procedia GHGT-12 Geochemical impacts of carbon dioxide, brine, trace metal and organic leakage into an unconfined, oxidizing limestone aquifer Diana H. Bacon3'* *, Zhenxue Daib, Liange Zhengc "Pacific Northwest National Laboratory, Richland, Washington, USA bLos Alamos National Laboratory, Los Alamos, New Mexico, USA cLawrence Berkeley National Laboratory, Berkeley, California, USA Abstract An important risk at CO2 storage sites is the potential for groundwater

  13. doe sc arm 14 038 Organic and Elemental Carbon Aerosol Particulate at the SGP_edited_formatted

    Office of Scientific and Technical Information (OSTI)

    8 Organic and Elemental Carbon Aerosol Particulates at the Southern Great Plains Site Field Campaign Report R Cary April 2016 CLIMATE RESEARCH FACILITY DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or

  14. Time dependence in atmospheric carbon inputs from drainage of organic soils

    SciTech Connect (OSTI)

    Rojstaczer, S.; Deverel, S.J. )

    1993-07-09

    The authors report the results of a study in the San Joaquin-Sacramento Delta of CO[sub 2] emission from drained soils relative to the rate of subsidence of the land. Their interest is in quantifying the rate carbon is freed from soils which are being drained, primarily for agricultural purposes, relative to the observed subsidence rates. This information is one of the inputs in the global carbon cycle. It is argued that most subsidence is the result of carbon oxidation. The fact that subsidence rates correlate with carbon dioxide emission rates supports this argument. In this Delta, subsidence rates have been decreasing in recent years, and measurements indicate that present carbon dioxide emission rates are lower than previous estimates by a factor or 3 or 4.

  15. HNF-SD-WM-TI-740, Rev. OC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    84047 HNF-SD-WM-TI-740, Rev. OC Standard Inventories of Chemicals and Radionuclides in Hanford Site Tank Wastes M. J. Kupfer, A. L. Boldt, K. N. Hodgson, L. W. Shelton, B. C. Simpson, and R. A. Watrous (LMHC); M. D. LeClair (SAIC); G. 1. Borsheim (BA); R. T. Winward (MA); B. A. Higley and R. M. Orme (NHC); N. G. Colton (PNNL); S. L. Lambert and D. E. Place (Cogema); and W. W. Schulz (112S) Lockheed Martin Hanford Corporation, Richland, WA 99352 U.S. Department of Energy Contract

  16. Process for producing organic products containing silicon, hydrogen, nitrogen, and carbon by the direct reaction between elemental silicon and organic amines and products formed thereby

    DOE Patents [OSTI]

    Pugar, E.A.; Morgan, P.E.D.

    1988-04-04

    A process is disclosed for producing, at a low temperature, a high purity organic reaction product consisting essentially of silicon, hydrogen, nitrogen, and carbon. The process comprises reacting together a particulate elemental high purity silicon with a high purity reactive amine reactant in a liquid state at a temperature of from about O/degree/C up to about 300/degree/C. A high purity silicon carbide/silicon nitride ceramic product can be formed from this intermediate product, if desired, by heating the intermediate product at a temperature of from about 1200-1700/degree/C for a period from about 15 minutes up to about 2 hours or the organic reaction product may be employed in other chemical uses.

  17. Process for producing organic products containing silicon, hydrogen, nitrogen, and carbon by the direct reaction between elemental silicon and organic amines

    DOE Patents [OSTI]

    Pugar, Eloise A.; Morgan, Peter E. D.

    1990-04-03

    A process is disclosed for producing, at a low temperature, a high purity organic reaction product consisting essentially of silicon, hydrogen, nitrogen, and carbon. The process comprises reacting together a particulate elemental high purity silicon with a high purity reactive amine reactant in a liquid state at a temperature of from about 0.degree. C. up to about 300.degree. C. A high purity silicon carbide/silicon nitride ceramic product can be formed from this intermediate product, if desired, by heating the intermediate product at a temperature of from about 1200.degree.-1700.degree. C. for a period from about 15 minutes up to about 2 hours or the organic reaction product may be employed in other chemical uses.

  18. Scaling impacts on environmental controls and spatial heterogeneity of soil organic carbon stocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mishra, U.; Riley, W. J.

    2015-01-27

    The spatial heterogeneity of land surfaces affects energy, moisture, and greenhouse gas exchanges with the atmosphere. However, representing heterogeneity of terrestrial hydrological and biogeochemical processes in earth system models (ESMs) remains a critical scientific challenge. We report the impact of spatial scaling on environmental controls, spatial structure, and statistical properties of soil organic carbon (SOC) stocks across the US state of Alaska. We used soil profile observations and environmental factors such as topography, climate, land cover types, and surficial geology to predict the SOC stocks at a 50 m spatial scale. These spatially heterogeneous estimates provide a dataset with reasonablemore » fidelity to the observations at a sufficiently high resolution to examine the environmental controls on the spatial structure of SOC stocks. We upscaled both the predicted SOC stocks and environmental variables from finer to coarser spatial scales (s = 100, 200, 500 m, 1, 2, 5, 10 km) and generated various statistical properties of SOC stock estimates. We found different environmental factors to be statistically significant predictors at different spatial scales. Only elevation, temperature, potential evapotranspiration, and scrub land cover types were significant predictors at all scales. The strengths of control (the median value of geographically weighted regression coefficients) of these four environmental variables on SOC stocks decreased with increasing scale and were accurately represented using mathematical functions (R2 = 0.83–0.97). The spatial structure of SOC stocks across Alaska changed with spatial scale. Although the variance (sill) and unstructured variability (nugget) of the calculated variograms of SOC stocks decreased exponentially with scale, the correlation length (range) remained relatively constant across scale. The variance of predicted SOC stocks decreased with spatial scale over the range of 50 to ~ 500 m, and remained constant beyond this scale. The fitted exponential function accounted for 98% of variability in the variance of SOC stocks. We found moderately-accurate linear relationships between mean and higher-order moments of predicted SOC stocks (R2 ~ 0.55–0.63). Current ESMs operate at coarse spatial scales (50–100 km), and are therefore unable to represent environmental controllers and spatial heterogeneity of high-latitude SOC stocks consistent with observations. We conclude that improved understanding of the scaling behavior of environmental controls and statistical properties of SOC stocks can improve ESM land model benchmarking and perhaps allow representation of spatial heterogeneity of biogeochemistry at scales finer than those currently resolved by ESMs.« less

  19. Scaling impacts on environmental controls and spatial heterogeneity of soil organic carbon stocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mishra, U.; Riley, W. J.

    2015-07-02

    The spatial heterogeneity of land surfaces affects energy, moisture, and greenhouse gas exchanges with the atmosphere. However, representing the heterogeneity of terrestrial hydrological and biogeochemical processes in Earth system models (ESMs) remains a critical scientific challenge. We report the impact of spatial scaling on environmental controls, spatial structure, and statistical properties of soil organic carbon (SOC) stocks across the US state of Alaska. We used soil profile observations and environmental factors such as topography, climate, land cover types, and surficial geology to predict the SOC stocks at a 50 m spatial scale. These spatially heterogeneous estimates provide a data setmore » with reasonable fidelity to the observations at a sufficiently high resolution to examine the environmental controls on the spatial structure of SOC stocks. We upscaled both the predicted SOC stocks and environmental variables from finer to coarser spatial scales (s = 100, 200, and 500 m and 1, 2, 5, and 10 km) and generated various statistical properties of SOC stock estimates. We found different environmental factors to be statistically significant predictors at different spatial scales. Only elevation, temperature, potential evapotranspiration, and scrub land cover types were significant predictors at all scales. The strengths of control (the median value of geographically weighted regression coefficients) of these four environmental variables on SOC stocks decreased with increasing scale and were accurately represented using mathematical functions (R2 = 0.83–0.97). The spatial structure of SOC stocks across Alaska changed with spatial scale. Although the variance (sill) and unstructured variability (nugget) of the calculated variograms of SOC stocks decreased exponentially with scale, the correlation length (range) remained relatively constant across scale. The variance of predicted SOC stocks decreased with spatial scale over the range of 50 m to ~ 500 m, and remained constant beyond this scale. The fitted exponential function accounted for 98 % of variability in the variance of SOC stocks. We found moderately accurate linear relationships between mean and higher-order moments of predicted SOC stocks (R2 ∼ 0.55–0.63). Current ESMs operate at coarse spatial scales (50–100 km), and are therefore unable to represent environmental controllers and spatial heterogeneity of high-latitude SOC stocks consistent with observations. We conclude that improved understanding of the scaling behavior of environmental controls and statistical properties of SOC stocks could improve ESM land model benchmarking and perhaps allow representation of spatial heterogeneity of biogeochemistry at scales finer than those currently resolved by ESMs.« less

  20. Regional geology of Georges Bank basin - OCS Sale 42 drilling results

    SciTech Connect (OSTI)

    High, L.R. Jr.

    1985-02-01

    Industry bid aggressively in OCS Sale 42, spending $816 million. Eight wildcats were drilled in 1981-82 to test 5 major plays. All wells were dry; no potential reservoir or source rocks were found. The tectonic-stratigraphic framework of the Georges Bank basin is that of an Atlantic-type plate margin. Two major unconformities divide the section into prerift, synrift, and postrift sequences. The prerift sequence consists of Paleozoic metasediments in basement fault blocks. Synrift sediments consist of Newark Group equivalents: the Argo Salt and the Iroquoi Formation. The postrift sequence consists of Mohican red beds overlain by progradational wedges, with the carbonate Abenaki Formation at the base. The objective in 4 of the 8 wildcats was the Iroquois Formation. Mobil 312-1 and Shell 357-1 were drilled into a seismic anomaly interpreted to be a reef. This structure was found to be a complex carbonate mound. Exxon 975-1 was drilled on a seismic amplitude anomaly variously interpreted to be the result of salt, coal, or porous carbonates. This anomaly proved to be caused by a salt bed. The objective in Shell 410-1R was carbonate banks over a basement horst block. No significant zones of porosity were found. The remaining 4 wildcats were drilled on Abenaki prospects. Mobil 273-1, Tenneco 187-1d, and Conoco 145-1 were drilled for possible carbonate banks over a salt structure. Only thin oolitic grainstone intervals were found. Exxon 133-1 was based on a seismic anomaly interpreted to be a patch reef. This feature was found to be a volcanic cone.

  1. Electrodeposited Manganese Oxides on Three-Dimensional Carbon Nanotube Substrate: Supercapacitive Behaviour in Aqueous and Organic Electrolytes

    SciTech Connect (OSTI)

    Nam,K.W.; Yang,X.

    2009-03-01

    Thin amorphous manganese oxide layers with a thickness of 3-5nm are electrodeposited on a carbon nanotube (CNT) film substrate that has a three-dimensional nanoporous structure (denoted asMnO2/CNT electrode). For the purpose of comparison, manganese oxide films are also electrodeposited on a flat Pt-coated Si wafer substrate (denoted as MnO2 film electrode). The pseudocapacitive properties of the MnO2 film and MnO2/CNT electrodes are examined in both aqueous electrolyte (1.0M KCl) and nonaqueousorganic electrolyte (1.0M LiClO4 in propylene carbonate). While both types of electrode showpseudocapacitive behaviour in the aqueous electrolyte, only the MnO2/CNT electrode does so in the organic electrolyte, due to its high oxide/electrolyte interfacial area and improved electron conduction through the CNT substrate. Compared with the MnO2 film electrode, the MnO2/CNT electrode shows a much higher specific capacitance and better high-rate capability, regardless of the electrolyte used.Use of the organic electrolyte results in a ?6 times higher specific energy compared with that obtained with the aqueous electrolyte, while maintaining a similar specific power. The construction of a threedimensional nanoporous network structure consisting of a thin oxide layer on a CNT film substrate at the nm scale and the use of an organic electrolyte are promising approaches to improving the specific energyof supercapacitors.

  2. An investigation of groundwater organics, soil minerals, and activated carbon on the complexation, adsorption, and separation of technetium-99

    SciTech Connect (OSTI)

    Gu, B.; Dowlen, K.E.

    1996-01-01

    This report summarizes studies on the interactions of technetium-99 (Tc) with different organic compounds and soil minerals under both oxidizing and reducing conditions. The report is divided into four parts and includes (1) effect of natural organic matter (NOM) on the complexation and solubility of Tc, (2) complexation between Tc and trichloroethylene (TCE) in aqueous solutions, (3) adsorption of Tc on soil samples from Paducah Gaseous Diffusion Plant (PGDP), and (4) adsorption and separation of Tc on activated carbon. Various experimental techniques were applied to characterize and identify Tc complexation with organic compounds and TCE, including liquid-liquid extraction, membrane filtration, size exclusion, and gel chromatography. Results indicate, within the experimental error, Tc (as pertechnetate, TcO{sub 4}) did not appear to form complexes with groundwater or natural organic matter under both atmospheric and reducing conditions. However, Tc can form complexes with certain organic compounds or specific functional groups such as salicylate. Tc did not appear to form complexes with TCE in aqueous solution.Both liquid-liquid extraction and high performance liquid chromatography (HPLC) gave no indication Tc was complexed with TCE. The correlations between Tc and TCE concentrations in monitoring wells at PGDP may be a coincidence because TCE was commonly used as a decontamination reagent. Once TCE and Tc entered the groundwater, they behaved similarly because both TcO{sub 4}{sup {minus}} and TCE are poorly adsorbed by soils. An effective remediation technique to remove TcO{sub 4}{sup {minus}} from PGDP contaminated groundwater is needed. One possibility is the use of an activated carbon adsorption technique developed in this study.

  3. Single-walled carbon nanotube transparent conductive films fabricated by reductive dissolution and spray coating for organic photovoltaics

    SciTech Connect (OSTI)

    Ostfeld, Aminy E.; Arias, Ana Claudia; Catheline, Amlie; Ligsay, Kathleen; Kim, Kee-Chan; Fogden, Sin; Chen, Zhihua; Facchetti, Antonio

    2014-12-22

    Solutions of unbundled and unbroken single-walled carbon nanotubes have been prepared using a reductive dissolution process. Transparent conductive films spray-coated from these solutions show a nearly twofold improvement in the ratio of electrical conductivity to optical absorptivity versus those deposited from conventional aqueous dispersions, due to substantial de-aggregation and sizable nanotube lengths. These transparent electrodes have been utilized to fabricate P3HT-PCBM organic solar cells achieving power conversion efficiencies up to 2.3%, comparable to those of solar cells using indium tin oxide transparent electrodes.

  4. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  5. Organic carbon aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, R.W.

    1998-04-28

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes {<=}1000 {angstrom}, and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050 C to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors. 8 figs.

  6. Organic carbon aerogels from the sol-gel polymerization of phenolic-furfural mixtures

    DOE Patents [OSTI]

    Pekala, Richard W.

    1998-04-28

    The sol-gel polymerization of a phenolic-furfural mixture in dilute solution leads to a highly cross-linked network that can be supercritically dried to form a high surface area foam. These porous materials have cell/pore sizes .ltoreq.1000 .ANG., and although they are dark brown in color, they can be classified as a new type of aerogel. The phenolic-furfural aerogel can be pyrolyzed in an inert atmosphere at 1050.degree. C. to produce carbon aerogels. This new aerogel may be used for thermal insulation, chromatographic packing, water filtration, ion-exchange, and carbon electrodes for energy storage devices, such as batteries and double-layer capacitors.

  7. BLM - Instruction Memorandum No. OC-2012-005 | Open Energy Information

    Open Energy Info (EERE)

    BLM - Instruction Memorandum No. OC-2012-005 Abstract This instruction memorandum sets forth procedures and requirements for conducting the FY 2012 Real Property inventory and...

  8. Effect of an organic molecular coating on control over the conductance of carbon nanotube channel

    SciTech Connect (OSTI)

    Bobrinetskiy, I. I.; Emelianov, A. V.; Nevolin, V. K. Romashkin, A. V.

    2014-12-15

    It is shown that the coating of carbon nanotubes with molecules with a constant dipole moment changes the conductance of the tubes due to a variation in the structure of energy levels that participate in charge transport. The IV characteristics of the investigated structures exhibit significant dependence of the channel conductance on the gate potential. The observed memory effect of conductance level can be explained by the rearrangement of polar groups and molecules as a whole in an electric field. The higher the dipole moment per unit length and the weaker the intermolecular interaction, the faster the rearrangement process is.

  9. OC)elRM(o-T/^ DOE/PC/60810-TIO TITLE: Superacid Catalyzed Coal Conversion Chemistry DE86 015045

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OC)elRM(o-T/^ DOE/PC/60810-TIO TITLE: Superacid Catalyzed Coal Conversion Chemistry DE86 015045 PIs(Authors): George A. Olah INSTITUTION/ORGANIZATION UNIVERSITY OF SOUTHERN CALIFORNIA HYDROCARBON RESEARCH INSTITUTE CONTRACT NO.: FINAL TECHNICAL REPORT (213)743-5277 DE-FG22-83PC60810 September 1,1983-September 1,1986 The basis of our studies was a novel, low temperature, mild coal conversion process developed in our laboratory. It involves the use of a superacidic system consisting of HF and BF,

  10. Definition of the Semisubmersible Floating System for Phase II of OC4

    SciTech Connect (OSTI)

    Robertson, A.; Jonkman, J.; Masciola, M.; Song, H.; Goupee, A.; Coulling, A.; Luan, C.

    2014-09-01

    Phase II of the Offshore Code Comparison Collaboration Continuation (OC4) project involved modeling of a semisubmersible floating offshore wind system as shown below. This report documents the specifications of the floating system, which were needed by the OC4 participants for building aero-hydro-servo-elastic models.

  11. Definition of the Floating System for Phase IV of OC3

    SciTech Connect (OSTI)

    Jonkman, J.

    2010-05-01

    Phase IV of the IEA Annex XXIII Offshore Code Comparison Collaboration (OC3) involves the modeling of an offshore floating wind turbine. This report documents the specifications of the floating system, which are needed by the OC3 participants for building aero-hydro-servo-elastic models.

  12. Designer organisms for photosynthetic production of ethanol from carbon dioxide and water

    DOE Patents [OSTI]

    Lee, James Weifu

    2011-07-05

    The present invention provides a revolutionary photosynthetic ethanol production technology based on designer transgenic plants, algae, or plant cells. The designer plants, designer algae, and designer plant cells are created such that the endogenous photosynthesis regulation mechanism is tamed, and the reducing power (NADPH) and energy (ATP) acquired from the photosynthetic water splitting and proton gradient-coupled electron transport process are used for immediate synthesis of ethanol (CH.sub.3CH.sub.2OH) directly from carbon dioxide (CO.sub.2) and water (H.sub.2O). The ethanol production methods of the present invention completely eliminate the problem of recalcitrant lignocellulosics by bypassing the bottleneck problem of the biomass technology. The photosynthetic ethanol-production technology of the present invention is expected to have a much higher solar-to-ethanol energy-conversion efficiency than the current technology and could also help protect the Earth's environment from the dangerous accumulation of CO.sub.2 in the atmosphere.

  13. Classification of Multiple Types of Organic Carbon Composition in Atmospheric Particles by Scanning Transmission X-Ray Microscopy Analysis

    SciTech Connect (OSTI)

    Kilcoyne, Arthur L; Takahama, S.; Gilardoni, S.; Russell, L.M.; Kilcoyne, A.L.D.

    2007-05-16

    A scanning transmission X-ray microscope at the Lawrence Berkeley National Laboratory is used to measure organic functional group abundance and morphology of atmospheric aerosols. We present a summary of spectra, sizes, and shapes observed in 595 particles that were collected and analyzed between 2000 and 2006. These particles ranged between 0.1 and 12 mm and represent aerosols found in a large range of geographical areas, altitudes, and times. They include samples from seven different field campaigns: PELTI, ACE-ASIA, DYCOMS II, Princeton, MILAGRO (urban), MILAGRO (C-130), and INTEX-B. At least 14 different classes of organic particles show different types of spectroscopic signatures. Different particle types are found within the same region while the same particle types are also found in different geographical domains. Particles chemically resembling black carbon, humic-like aerosols, pine ultisol, and secondary or processed aerosol have been identified from functional group abundance and comparison of spectra with those published in the literature.

  14. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  15. Carbonyl sulfide/carbon chemistry: (Final report)

    SciTech Connect (OSTI)

    Hinckley, C.C.; Shiley, R.H.

    1986-10-01

    This study examined the effects of treating isotropic char, coal tar, and coal with carbonyl sulfide, OCS. The substrates were treated with moderate pressures of OCS at 400-550/sup 0/C for several hours. Gas chromatographic analyses showed that the autoclave gases contained CO, CO/sub 2/, H/sub 2/S, and unreacted OCS as the principal components after reaction. The predominant reaction was the decomposition of OCS to CO and S. Sulfur percentages for all of the treated substrates were increased by 10% or more. Polarized light reflectance microscopy showed that anisotropic carbon (mesopase) was present in coal samples treated with sulfur gases. The study demonstrates that OCS is a potent resulfurization agent for all of the substrates examined. Cabonyl sulfide and hydrogen sulfide, included in the study for comparison, facilitate the formation of mesophasic structures in the coal studied. 9 refs., 6 figs., 12 tabs.

  16. Thermoeconomic optimization of OC-OTEC electricity and water production plants

    SciTech Connect (OSTI)

    Block, D.L.; Valenzuela, J.A.

    1985-05-01

    The study on the thermoeconomic evaluation of open-cycle ocean thermal energy conversion (OC-OTEC) objectives were to assess the economic and technical viability of OC-OTEC for the production of electricity and fresh water based on the current state-of-the-art; develop conceptual designs of optimized OC-OTEC plants that produce electricity and fresh water for plant sizes that are economically attractive; and identify the research issues that must be resolved before a commercial plant can be built. Oceanographic data for six potential sites were evaluated and ''generic'' site characteristics were developed. Current and projected prices and requirements for electricity and water at potential sites were obtained. The state-of-the-art of components comprising the OC-OTEC plant was reviewed. The highest performing, least costly, and least technically uncertain design for each component was selected. Component cost and performance models were then developed and integrated into thermoeconomic system models for single- and double-stage OC-OTEC plants that produced electricity and fresh water. A computerized optimization procedure was developed to obtain optimal plant configurations for the production of electricity and fresh water. Small-scale OC-OTEC appears economically and technologically feasible for many potential sites. OC-OTEC may represent a technology with tremendous near-term potential. It is recommended that it be aggressively pursued.

  17. Barrow Black Carbon Source and Impact Study Final Campaign Report

    SciTech Connect (OSTI)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact campaign was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement (ARM) Climate Research Facility site in Barrow, Alaska. The carbonaceous component was characterized by measuring the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the PM, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine PM fractions (PM2.5) and 49 coarse (PM10) PM fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the Barrow Black Carbon Source and Impact (BBCSI) study used standard Tisch “hi-vol” motors that have a known lifetime of approximately 1 month under constant use; this necessitated monthly maintenance, and it is suggested that, for future deployment in the Arctic, the motors be upgraded to industrial blowers. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric PM samples from Barrow, Alaska, from July 2012 to June 2013. Preliminary analysis of the OC and BC concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer. However, the annual OC concentrations had a very different seasonal pattern with the highest concentrations during the summer, lowest concentrations during the fall, and increased concentrations during the winter and spring (Figure 1).

  18. Design and cost study of critical OC-OTEC plant components: Final subcontract report

    SciTech Connect (OSTI)

    Valenzuela, J.A.; Jasinski, T.; Stacey, W.D.; Patel, B.R.; Dolan, F.Y.

    1988-06-01

    During the FY 1983-84, system analysis studies were performed by the Florida Solar Energy Center and Creare Inc. to assess the economic and technological viability of the OC-OTEC concept for producing both electricity and fresh water on a small scale. A major conclusion of the study was that land-based OC-OTEC plants as small as 10 MWe may be economically feasible in island communities if cost credits are taken for the fresh water produced. The present study builds upon and extends the results of that work. Assess the effect of the seasonal variation in the ocean surface water temperature on the performance of OC-OTEC plants; evaluate the technical feasibility of building small scale OC-OTEC plants using existing low pressure steam turbine rotor designs; refine the plant structure model developed during the Phase I study; and develop background information and analyses to evaluate the various alternative strategies for handling noncondensible gases in OC-OTEC plants. Refinements in OC-OTEC plant performance and cost models performed during the present study have reduced the estimated cost of a 10 MW baseline plant from 99 to 72M$. Further cost reduction of 5 to 10M$ is anticipated from the revised structure cost model and the implementation of barometric leg deaeration and hydraulic compression. Therefore, the results from this study reinforce the earlier conclusion that small-scale OC-OTEC plants are competitive at present for the production of electricity and fresh water in the Caribbean and Pacific Islands. OC-OTEC represents a technology with significant potential. We recommend that it be aggressively pursued. 33 refs., 67 figs., 20 tabs.

  19. Analysis of the premitting processes associated with exploration of Federal OCS leases. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    Under contract to the Office of Leasing Policy Development (LPDO), Jack Faucett Associates is currently undertaking the description and analysis of the Outer Continental Shelf (OCS) regulatory process to determine the nature of time delays that affect OCS production of oil and gas. This report represents the results of the first phase of research under this contract, the description and analysis of regulatory activity associated with exploration activities on the Federal OCS. Volume 1 contains the following three sections: (1) study results; (2) Federal regulatory activities during exploration of Federal OCS leases which involved the US Geological Survey, Environmental Protection Agency, US Coast Guard, Corps of Engineers, and National Ocean and Atmospheric Administration; and (3) state regulatory activities during exploration of Federal OCS leases of Alaska, California, Louisiana, Massachusetts, New Jersey, North Carolina, and Texas. Volume II contains appendices of US Geological Survey, Environmental Protection Agency, Coast Guard, Corps of Engineers, the Coastal Zone Management Act, and Alaska. The major causes of delay in the regulatory process governing exploration was summarized in four broad categories: (1) the long and tedious process associated with the Environmental Protection Agency's implementation of the National Pollutant Discharge Elimination System Permit; (2) the lack of mandated time periods for the completion of individual activities in the permitting process; (3) the lack of overall coordination of OCS exploratory regulation; and (4) the inexperience of states, the Federal government and industry relating to the appropriate level of regulation for first-time lease sale areas.

  20. Fossil and Contemporary Fine Carbon Fractions at 12 Rural and Urban Sites in the United States

    SciTech Connect (OSTI)

    Schichtel, B; Malm, W; Bench, G; Fallon, S; McDade, C; Chow, J

    2007-03-01

    Fine particulate matter collected at two urban, four near-urban, and six remote sites throughout the United States were analyzed for total carbon (TC) and radiocarbon ({sup 14}C). Samples were collected at most sites for both a summer and winter season. The radiocarbon was used to partition the TC into fossil and contemporary fractions. On average, contemporary carbon composed about half of the carbon at the urban, {approx}70-97% at near-urban, and 82-100% at remote sites. At Phoenix, Arizona, and Seattle, Washington, one monitor was located within the urban center and one outside to assess the urban excess over background concentrations. During the summer the urban and rural sites had similar contemporary carbon concentrations. However, during the winter the urban sites had more than twice the contemporary carbon measured at the neighboring sites, indicating anthropogenic contributions to the contemporary carbon. The urban fossil carbon was 4-20 times larger than the neighboring rural sites for both seasons. Organic (OC) and elemental carbon (EC) from TOR analysis were available. These and the radiocarbon data were used to estimate characteristic fossil and contemporary EC/TC ratios for the winter and summer seasons. These ratios were applied to carbon data from the Interagency Monitoring of Protected Visual Environments network to estimate the fraction of contemporary carbon at mostly rural sites throughout the United States. In addition, the ratios were used to develop a semiquantitative, lower bound estimate of secondary organic carbon (SOC) contribution to fossil and contemporary carbon. SOC accounted for more than one-third of the fossil and contemporary carbon.

  1. (Use of carbon dioxide in inorganic, organic, and bioorganic reactions, Ginosa, Italy, June 17--28, 1989): Foreign trip report

    SciTech Connect (OSTI)

    Smith, H.B.

    1989-07-14

    The traveler attended the NATO Advanced Study Institute in Ginosa, Italy, and presented an oral summary of his research entitled ''Subtle Structural Perturbations at the Active Site of Rubisco by Concerted Site-Directed Mutagenesis and Chemical Modification.'' Topics of the Institute included the chemical fixation, electrochemical and chemical reduction of carbon dioxide, and enzymatic reactions of carbon dioxide. Discussion of ribulose bisphosphate carboxylase/oxygenase, the enzyme that catalyzes by far most of the earth's yearly carbon dioxide fixation, highlighted ongoing investigations of the enzyme within the Protein Engineering Program of ORNL's Biology Division.

  2. Molecular Characterization of Brown Carbon (BrC) Chromophores in Secondary Organic Aerosol Generated From Photo-Oxidation of Toluene

    SciTech Connect (OSTI)

    Lin, Peng; Liu, Jiumeng; Shilling, John E.; Kathmann, Shawn M.; Laskin, Julia; Laskin, Alexander

    2015-09-28

    Atmospheric Brown carbon (BrC) is a significant contributor to light absorption and climate forcing. However, little is known about a fundamental relationship between the chemical composition of BrC and its optical properties. In this work, light-absorbing secondary organic aerosol (SOA) was generated in the PNNL chamber from toluene photo-oxidation in the presence of NOx (Tol-SOA). Molecular structures of BrC components were examined using nanospray desorption electrospray ionization (nano-DESI) and liquid chromatography (LC) combined with UV/Vis spectroscopy and electrospray ionization (ESI) high-resolution mass spectrometry (HRMS). The chemical composition of BrC chromophores and the light absorption properties of toluene SOA (Tol-SOA) depend strongly on the initial NOx concentration. Specifically, Tol-SOA generated under high-NOx conditions (defined here as initial NOx/toluene of 5/1) appears yellow and mass absorption coefficient of the bulk sample (MACbulk@365nm = 0.78 m2 g-1) is nearly 80 fold higher than that measured for the Tol-SOA sample generated under low-NOx conditions (NOx/toluene < 1/300). Fifteen compounds, most of which are nitrophenols, are identified as major BrC chromophores responsible for the enhanced light absorption of Tol-SOA material produced in the presence of NOx. The integrated absorbance of these fifteen chromophores accounts for 40-60% of the total light absorbance by Tol-SOA at wavelengths between 300 nm and 500 nm. The combination of tandem LC-UV/Vis-ESI/HRMS measurements provides an analytical platform for predictive understanding of light absorption properties by BrC and their relationship to the structure of individual chromophores. General trends in the UV/vis absorption by plausible isomers of the BrC chromophores were evaluated using theoretical chemistry calculations. The molecular-level understanding of BrC chemistry is helpful for better understanding the evolution and behavior of light absorbing aerosols in the atmosphere.

  3. Optical Properties of Moderately-Absorbing Organic and Mixed Organic/Inorganic Particles at Very High Humidities

    SciTech Connect (OSTI)

    Bond, Tami C; Rood, Mark J; Brem, Benjamin T; Mena-Gonzalez, Francisco C; Chen, Yanju

    2012-04-16

    Relative humidity (RH) affects the water content of an aerosol, altering its ability to scatter and absorb light, which is important for aerosol effects on climate and visibility. This project involves in situ measurement and modeling of aerosol optical properties including absorption, scattering and extinction at three visible wavelengths (467, 530, 660 nm), for organic carbon (OC) generated by pyrolysis of biomass, ammonium sulfate and sodium chloride, and their mixtures at controlled RH conditions. Novel components of this project include investigation of: (1) Changes in all three of these optical properties at scanned RH conditions; (2) Optical properties at RH values up to 95%, which are usually extrapolated instead of measured; and (3) Examination of aerosols generated by the pyrolysis of wood, which is representative of primary atmospheric organic carbon, and its mixture with inorganic aerosol. Scattering and extinction values were used to determine light absorption by difference and single scattering albedo values. Extensive instrumentation development and benchmarking with independently measured and modeled values were used to obtain and evaluate these new results. The single scattering albedo value for a dry absorbing polystyrene microsphere benchmark agreed within 0.02 (absolute value) with independently published results at 530 nm. Light absorption by a nigrosin (sample light-absorbing) benchmark increased by a factor of 1.24 +/-0.06 at all wavelengths as RH increased from 38 to 95%. Closure modeling with Mie theory was able to reproduce this increase with the linear volume average (LVA) refractive index mixing rule for this water soluble compound. Absorption by biomass OC aerosol increased by a factor of 2.1 +/- 0.7 and 2.3 +/- 1.2 between 32 and 95% RH at 467 nm and 530 nm, but there was no detectable absorption at 660 nm. Additionally, the spectral dependence of absorption by OC that was observed with filter measurements was confirmed qualitatively in situ at 467 and 530 nm. Closure modeling with the dynamic effective medium approximation (DEMA) refractive index model was able to capture the increasing absorption trend with RH indicating that the droplets were heterogeneously mixed while containing dispersed insoluble absorbing material within those droplets. Seven other refractive index mixing models including LVA did not adequately describe the measurements for OC. Mixing the biomass OC aerosol with select mass fractions of ammonium sulfate ranging from 25 to 36% and sodium chloride ranging from 21 to 30% resulted in an increase in light scattering and extinction with RH and inorganic mass fraction. However, no detectable difference in light absorption behavior in comparison to pure biomass OC was observed. The main finding of this research is a measured increase in absorption with increasing RH, which is currently not represented in radiative transfer models even though biomass burning produces most of the primary OC aerosol in the atmosphere.

  4. Assessing Fossil and New Carbon in Reclaimed Mined Soils

    SciTech Connect (OSTI)

    Rattan Lal; David Ussiri

    2008-09-30

    Soil organic carbon (SOC) pool in the reclaimed minesoils (RMS) is the mixture of coal C originating from mining and reclamation activities and recent plant-derived organic carbon (OC). Accurate estimates of OC pools and sequestration rates in the RMS are limited by lack of standard and cost-effective method for determination of coal-C concentration. The main objective of this project was to develop and test analytical procedures for quantifying pool sizes of coal-derived C in RMS and to partition organic C in RMS into coal-derived and newly deposited SOC fractions. Analysis of soil and coal artificial mixtures indicated that the {Delta}{sup 13}C method developed was very effective in estimating coal C added in the mixtures, especially soils under C4 plants. However, most of the reclaimed sites in Ohio are under C3 plants with range of {Delta}{sup 13}C signal falling within ranges of coal. The wide range of {Delta}{sup 13}C signal observed in minesoils, (i.e. -26 to -30 for plants and -23 to -26 for coal) limits the ability of this approach to be used for southeast Ohio minesoils. This method is applicable for reclaimed prime farm land under long term corn or corn soybean rotation. Chemi-thermal method was very effective in quantifying coal-C fraction in both soil-coal artificial mixtures and minesoils. The recovery of coal-C from the mixture ranged from 93 to 100% of coal. Cross-validation of chemi-thermal method with radiocarbon analysis revealed that chemi-thermal method was as effective as radiocarbon analysis in quantifying coal-C in RMS. Coal C determined after chemi-thermal treatment of samples was highly correlated with coal C concentration calculated by radiocarbon activity (r{sup 2} = 0.95, P < 0.01). Therefore, both radiocarbon activity and chemi-thermal method were effective in estimating coal carbon concentration in reclaimed minesoils of southeast Ohio. Overall, both coal-C and recent OC fraction exhibited high spatial and depth variation, suggesting that approaches used to obtain representative samples in undisturbed soils may not be effective in RMS sites. Analysis of coal-C fraction in RMS indicated that the contribution of coal C to SOC increased with increase in soil depth, accounting for up to 92% of SOC in the sub-soil. Our data indicated that land use and land management practices plays significant role in enhancing SOC sequestration in reclaimed mined lands.

  5. O Oc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... were made to Livermore's change control process to ensure that system changes continue to be properly ... During such travel, the Deputy Secretary is authorized premium class ...

  6. ARM - Measurement - Black carbon concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of carbon in its very absorbing, elemental, non-organic, non-oxide form (e.g. graphite). Categories Aerosols, Atmospheric Carbon Instruments The above measurement is...

  7. OC5 Project Phase I: Validation of Hydrodynamic Loading on a Fixed Cylinder: Preprint

    SciTech Connect (OSTI)

    Robertson, A. N.; Wendt, F. F.; Jonkman, J. M.; Popko, W.; Vorpahl, F.; Stansberg, C. T.; Bachynski, E. E.; Bayati, I.; Beyer, F.; de Vaal, J. B.; Harries, R.; Yamaguchi, A.; Shin, H.; Kim, B.; van der Zee, T.; Bozonnet, P.; Aguilo, B.; Bergua, R.; Qvist, J.; Qijun, W.; Chen, X.; Guerinel, M.; Tu, Y.; Yutong, H.; Li, R.; Bouy, L.

    2015-04-23

    This paper describes work performed during the first half of Phase I of the Offshore Code Comparison Collaboration Continuation, with Correlation project (OC5). OC5 is a project run under the IEA Wind Research Task 30, and is focused on validating the tools used for modeling offshore wind systems. In this first phase, simulated responses from a variety of offshore wind modeling tools were modeling tools were validated against tank test data of a fixed, suspended cylinder (without a wind turbine) that was tested under regular and irregular wave conditions at MARINTEK. The results from this phase include an examination of different approaches one can use for defining and calibrating hydrodynamic coefficients for a model, and the importance of higher-order wave models in accurately modeling the hydrodynamic loads on offshore substructures.

  8. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  9. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J.

    1999-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  10. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J.

    1998-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  11. Barrow Black Carbon Source and Impact Study Final Campaign Report

    SciTech Connect (OSTI)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact (BBCSI) Study was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement site in Barrow, AK. The carbonaceous component was characterized via measurement of the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the particulate matter, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine (PM2.5) and 49 coarse (PM10) particulate matter fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the BBCSI used standard Tisch hi-vol motors which have a known lifetime of ~1 month under constant use; this necessitated monthly maintenance and it is suggested that the motors be upgraded to industrial blowers for future deployment in the Arctic. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric particulate matter samples from Barrow, AK from July 2012 to June 2013. Preliminary analysis of the organic and black carbon concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer.

  12. Effect of warming on the degradation and production of low-molecular-weight labile organic carbon in an Arctic tundra soil

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ziming; Wullschleger, Stan D.; Liang, Liyuan; Graham, David E.; Gu, Baohua

    2016-01-16

    The fate of soil organic carbon (SOC) stored in the Arctic permafrost is a key concern as temperatures continue to rise in the northern hemisphere. Studies and conceptual models suggest that SOC degradation is affected by the composition of SOC, but it is unclear exactly what portions of SOC are vulnerable to rapid breakdown and what mechanisms may be controlling SOC degradation upon permafrost thaw. Here, we examine the dynamic consumption and production of labile SOC in an anoxic incubation experiment using soil samples from the active layer at the Barrow Environmental Observatory, Barrow, Alaska, USA. Free-reducing sugars, alcohols, andmore » low-molecular-weight (LMW) organic acids were analyzed during incubation at either –2 or 8 °C for up to 240 days. Results show that simple sugar and alcohol SOC largely account for the initial rapid release of CO2 and CH4 through anaerobic fermentation, whereas the fermentation products, acetate and formate, are subsequently utilized as primary substrates for methanogenesis. Iron(III) reduction is correlated to acetate production and methanogenesis, suggesting its important role as an electron acceptor in tundra SOC respiration. These observations are further supported in a glucose addition experiment, in which rapid CO2 and CH4 production occurred concurrently with rapid production and consumption of labile organics such as acetate. However, addition of tannic acid, as a more complex organic substrate, showed little influence on the overall production of CO2 and CH4 and organic acids. Together our study shows that LMW labile organics in SOC control the initial rapid release of green-house gases upon warming. We thus present a conceptual framework for the labile SOC transformations and their relations to fermentation, iron reduction and methanogenesis, thereby providing the basis for improved model prediction of climate feedbacks in the Arctic.« less

  13. Thermoeconomic optimizarion of OC-OTEC electricity and water production plants. Final report

    SciTech Connect (OSTI)

    Block, D.L.; Girgis, M.A.; Huggins, J.C.; McCluney, R.; Rotundo, L.; Valenzuela, J.A.; Hutchings, B.J.; Stacy, W.D.; Sam, R.G.; Patel, B.R.

    1984-09-01

    The objectives of this yearlong project were to: (1) assess the economic and technical viability of open-cycle ocean thermal energy conversion of (OC-OTEC) for the production of electricity and/or fresh water based on the current state of the art; (2) develop conceptual designs of optimized OC-OTEC plants that produce electricity and/or fresh water for plant sizes that are economically attractive; and (3) identify the research issues that must be resolved before a commercial plant can be built. Oceanographic data for six potential sites were evaluated and generic site characteristics were developed. The generic site has a 20/sup 0/C temperature differential between the ocean surface and a depth of 1000 m. This temperature differential occurs at a distance of 5 km from shore. Current and projected prices and requirements for electricity and water at potential sites were obtained. The state of the art of components comprising the OC-OTEC plant was reviewed. Design options for each component were identified. The highest performing, least costly, and least technically uncertain design for each component was selected. Component cost and performance models were then developed and integrated into thermoeconomic system models for single- and double-stage OC-OTEC plants that produced electricity and/or fresh water. A computerized optimization procedure was developed to obtain optimal (minimum cost) plant configurations for the production of electricity and/or fresh water. All plant types - floating, moored, shelf-mounted, shallow-water and land-based plants - were evaluated. Based on the state-of-the-art and typical characteristics of potential sites, the primary thrust of the program was directed towards shallow-water and land-based plants. The shallow-water/land-based plant configurations selected had a 5-km long cold-water supply pipe and a 1-km long discharge pipe for the evaporator and condenser.

  14. Heterotrophic Soil Respiration in Warming Experiments: Using Microbial Indicators to Partition Contributions from Labile and Recalcitrant Soil Organic Carbon. Final Report

    SciTech Connect (OSTI)

    Bradford, M A; Melillo, J M; Reynolds, J F; Treseder, K K; Wallenstein, M D

    2010-06-10

    The central objective of the proposed work was to develop a genomic approach (nucleic acid-based) that elucidates the mechanistic basis for the observed impacts of experimental soil warming on forest soil respiration. The need to understand the mechanistic basis arises from the importance of such information for developing effective adaptation strategies for dealing with projected climate change. Specifically, robust predictions of future climate will permit the tailoring of the most effective adaptation efforts. And one of the greatest uncertainties in current global climate models is whether there will be a net loss of carbon from soils to the atmosphere as climate warms. Given that soils contain approximately 2.5 times as much carbon as the atmosphere, a net loss could lead to runaway climate warming. Indeed, most ecosystem models predict that climate warming will stimulate microbial decomposition of soil carbon, producing such a positive feedback to rising global temperatures. Yet the IPCC highlights the uncertainty regarding this projected feedback. The uncertainty arises because although warming-experiments document an initial increase in the loss of carbon from soils, the increase in respiration is short-lived, declining to control levels in a few years. This attenuation could result from changes in microbial physiology with temperature. We explored possible microbial responses to warming using experiments and modeling. Our work advances our understanding of how soil microbial communities and their activities are structured, generating insight into how soil carbon might respond to warming. We show the importance of resource partitioning in structuring microbial communities. Specifically, we quantified the relative abundance of fungal taxa that proliferated following the addition of organic substrates to soil. We added glycine, sucrose, cellulose, lignin, or tannin-protein to soils in conjunction with 3-bromo-deoxyuridine (BrdU), a nucleotide analog. Active microbes absorb BrdU from the soil solution; if they multiply in response to substrate additions, they incorporate the BrdU into their DNA. After allowing soils to incubate, we extracted BrdU-labeled DNA and sequenced the ITS regions of fungal rDNA. Fungal taxa that proliferated following substrate addition were likely using the substrate as a resource for growth. We found that the structure of active fungal communities varied significantly among substrates. The active fungal community under glycine was significantly different from those under other conditions, while the active communities under sucrose and cellulose were marginally different from each other and the control. These results indicate that the overall community structure of active fungi was altered by the addition of glycine, sucrose, and cellulose and implies that some fungal taxa respond to changes in resource availability. The community composition of active fungi is also altered by experimental warming. We found that glycine-users tended to increase under warming, while lignin-, tannin/protein-, and sucrose-users declined. The latter group of substrates requires extracellular enzymes for use, but glycine does not. It is possible that warming selects for fungal species that target, in particular, labile substrates. Linking these changes in microbial communities and resource partitioning to soil carbon dynamics, we find that substrate mineralization rates are, in general, significantly lower in soils exposed to long-term warming. This suggests that microbial use of organic substrates is impaired by warming. Yet effects are dependent on substrate identity. There are fundamental differences in the metabolic capabilities of the communities in the control and warmed soils. These differences might relate to the changes in microbial community composition, which appeared to be associated with groups specialized on different resources. We also find that functional responses indicate temperature acclimation of the microbial community. There are distinct seasonal patterns and to long-term soil warming, with higher-temperature optima for soils exposed to warmer temperatures. To relate these changes within the microbial community to potential positive feedbacks between climate warming and soil respiration, we develop a microbial-enzyme model to simulate the responses of soil carbon to warming. We find that declines in microbial biomass and degradative enzymes can explain the observed attenuation of soil-carbon emissions in response to warming. Specifically, reduced carbon-use efficiency limits the biomass of microbial decomposers and mitigates loss of soil carbon. However, microbial adaptation or a change in microbial communities could lead to an upward adjustment of the efficiency of carbon use, counteracting the decline in microbial biomass and accelerating soil-carbon loss. We conclude that the soil-carbon response to climate warming depends on the efficiency of soil microbes in using carbon.

  15. Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren; Zhao, Dan; Liu, Di -Jia

    2015-08-25

    Fuel cell vehicles, the only all-electric technology with a demonstrated >300 miles per fill travel range, use Pt as the electrode catalyst. The high price of Pt creates a major cost barrier for large-scale implementation of polymer electrolyte membrane fuel cells. Nonprecious metal catalysts (NPMCs) represent attractive low-cost alternatives. However, a significantly lower turnover frequency at the individual catalytic site renders the traditional carbon-supported NPMCs inadequate in reaching the desired performance afforded by Pt. Unconventional catalyst design aiming at maximizing the active site density at much improved mass and charge transports is essential for the next-generation NPMC. We report heremore » a method of preparing highly efficient, nanofibrous NPMC for cathodic oxygen reduction reaction by electrospinning a polymer solution containing ferrous organometallics and zeolitic imidazolate framework followed by thermal activation. The catalyst offers a carbon nanonetwork architecture made of microporous nanofibers decorated by uniformly distributed high-density active sites. In a single-cell test, the membrane electrode containing such a catalyst delivered unprecedented volumetric activities of 3.3 A∙cm-3 at 0.9 V or 450 A∙cm-3 extrapolated at 0.8 V, representing the highest reported value in the literature. Improved fuel cell durability was also observed.« less

  16. Highly efficient nonprecious metal catalyst prepared with metal–organic framework in a continuous carbon nanofibrous network

    SciTech Connect (OSTI)

    Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren; Zhao, Dan; Liu, Di -Jia

    2015-08-25

    Fuel cell vehicles, the only all-electric technology with a demonstrated >300 miles per fill travel range, use Pt as the electrode catalyst. The high price of Pt creates a major cost barrier for large-scale implementation of polymer electrolyte membrane fuel cells. Nonprecious metal catalysts (NPMCs) represent attractive low-cost alternatives. However, a significantly lower turnover frequency at the individual catalytic site renders the traditional carbon-supported NPMCs inadequate in reaching the desired performance afforded by Pt. Unconventional catalyst design aiming at maximizing the active site density at much improved mass and charge transports is essential for the next-generation NPMC. We report here a method of preparing highly efficient, nanofibrous NPMC for cathodic oxygen reduction reaction by electrospinning a polymer solution containing ferrous organometallics and zeolitic imidazolate framework followed by thermal activation. The catalyst offers a carbon nanonetwork architecture made of microporous nanofibers decorated by uniformly distributed high-density active sites. In a single-cell test, the membrane electrode containing such a catalyst delivered unprecedented volumetric activities of 3.3 A∙cm-3 at 0.9 V or 450 A∙cm-3 extrapolated at 0.8 V, representing the highest reported value in the literature. Improved fuel cell durability was also observed.

  17. ARM - Measurement - Total carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total carbon The total concentration of carbon in all its organic and non-organic forms. Categories Aerosols, Atmospheric Carbon Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  18. Building Technologies Program: Tax Deduction Qualified Software- Owens Corning Commercial Energy Calculator (OC-CEC) version 1.1

    Broader source: Energy.gov [DOE]

    Provides required documentation that Owens Corning Commercial Energy Calculator (OC-CEC) version 1.1 meets Internal Revenue Code §179D, Notice 2006-52, dated June 2, 2006, for calculating commercial building energy and power cost savings.

  19. Offshore Code Comparison Collaboration (OC3) for IEA Wind Task 23 Offshore Wind Technology and Deployment

    SciTech Connect (OSTI)

    Jonkman, J.; Musial, W.

    2010-12-01

    This final report for IEA Wind Task 23, Offshore Wind Energy Technology and Deployment, is made up of two separate reports, Subtask 1: Experience with Critical Deployment Issues and Subtask 2: Offshore Code Comparison Collaborative (OC3). Subtask 1 discusses ecological issues and regulation, electrical system integration, external conditions, and key conclusions for Subtask 1. Subtask 2 included here, is the larger of the two volumes and contains five chapters that cover background information and objectives of Subtask 2 and results from each of the four phases of the project.

  20. Coastal energy transportation study, phase ii, volume 1: a study of OCS onshore support bases and coal export terminals

    SciTech Connect (OSTI)

    Cribbins, P.D.

    1981-08-01

    This study concentrates on siting alternatives for on-shore support bases for Outer Continental Shelf (OCS) oil and gas exploration and coal export terminals. Sixteen alternative OCS sites are described, and a parametric analysis is utilized to select the most promising sites. Site-specific recommendations regarding infrastructure requirements and transportation impacts are provided. Eleven alternative coal terminal sites are identified and assessed for their potential impacts.

  1. Analysis of the permitting processes associated with exploration of Federal OCS leases. Final report. Volume II. Appendices

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    Under contract to the Office of Leasing Policy Development (LPDO), Jack Faucett Associates is currently undertaking the description and analysis of the Outer Continental Shelf (OCS) regulatory process to determine the nature of time delays that affect OCS production of oil and gas. This report represents the results of the first phase of research under this contract, the description and analysis of regulatory activity associated with exploration activities on the Federal OCS. Volume 1 contains the following three sections: (1) study results; (2) Federal regulatory activities during exploration of Federal OCS leases which involved the US Geological Survey, Environmental Protection Agency, US Coast Guard, Corps of Engineers, and National Ocean and Atmospheric Administration; and (3) state regulatory activities during exploration of Federal OCS leases of Alaska, California, Louisiana, Massachusetts, New Jersey, North Carolina and Texas. Volume II contains appendices of US Geological Survey, Environmental Protection Agency, Coast Guard, Corps of Engineers, the Coastal Zone Management Act, and Alaska. The major causes of delay in the regulatory process governing exploration was summarized in four broad categories: (1) the long and tedious process associated with the Environmental Protection Agency's implementation of the National Pollutant Discharge Elimination System Permit; (2) thelack of mandated time periods for the completion of individual activities in the permitting process; (3) the lack of overall coordination of OCS exploratory regulation; and (4) the inexperience of states, the Federal government and industry relating to the appropriate level of regulation for first-time lease sale areas.

  2. Desorption Behavior of Carbon Tetrachloride and Chloroform in...

    Office of Scientific and Technical Information (OSTI)

    Behavior of Carbon Tetrachloride and Chloroform in contaminated Low Organic Carbon Aquifer Sediments Citation Details In-Document Search Title: Desorption Behavior of Carbon ...

  3. Substituted copper phthalocyanine/multiwalled carbon nanotubes hybrid material for Cl{sub 2} sensing application

    SciTech Connect (OSTI)

    Sharma, Anshul Kumar, E-mail: dramanmahajan@yahoo.co.in; Saini, Rajan, E-mail: dramanmahajan@yahoo.co.in; Singh, Rajinder, E-mail: dramanmahajan@yahoo.co.in; Mahajan, Aman, E-mail: dramanmahajan@yahoo.co.in; Bedi, R. K., E-mail: dramanmahajan@yahoo.co.in [Material Science Laboratory, Department of Physics, Guru Nanak Dev University, Amritsar-143005 (India); Aswal, D. K. [Technical Physics Division, Bhabha Atomic Research Center, Mumbai-400085 (India)

    2014-04-24

    In this work, hybrid of soluble copper phthalocyanine (CuPcOC{sub 8}) and functionalized multi-walled carbon nanotubes (MWCNTs) has been synthesized. The formation of CuPcOC{sub 8}-MWCNTs hybrid is confirmed by atomic force microscopy, UV-Visible and FTIR spectroscopy. Subsequently, a chemi-resistive sensor is fabricated by drop casting CuPcOC{sub 8}-MWCNTs hybrid onto glass substrate. It has been demonstrated that CuPcOC{sub 8}-MWCNTs hybrid is highly selective towards Cl{sub 2} gas with minimum detection limit of 100 ppb. The response of sensor increases linearly with increase in the concentration of Cl{sub 2} gas. For 2000 ppb of Cl{sub 2}, CuPcOC{sub 8}-MWCNTs hybrid gives a response as large as 53% in 40 seconds.

  4. Effect of Organic Capping Layers over Monodisperse Platinum Nanoparticles upon Activity for Ethylene Hydrogenation and Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Kuhn, John N.; Tsung, Chia-Kuang; Huang, Wenyu; Somorjai, Gabor A.

    2009-03-24

    The influence of oleylamine (OA), trimethyl tetradecyl ammonium bromide (TTAB), and polyvinlypyrrolidone (PVP) capping agents upon the catalytic properties of Pt/silica catalysts was evaluated. Pt nanoparticles that were 1.5 nm in size were synthesized by the same procedure (ethylene glycol reduction under basic conditions) with the various capping agents added afterward for stabilization. Before examining catalytic properties for ethylene hydrogenation and CO oxidation, the Pt NPs were deposited onto mesoporous silica (SBA-15) supports and characterized by transmission electron microscopy (TEM), H{sub 2} chemisorption, and elemental analysis (ICP-MS). PVP- and TTAB-capped Pt yielded mass-normalized reaction rates that decreased with increasing pretreatment temperature, and this trend was attributed to the partial coverage of the Pt surface with decomposition products from the organic capping agent. Once normalized to the Pt surface area, similar intrinsic activities were obtained regardless of the pretreatment temperature, which indicated no influence on the nature of the active sites. Consequently, a chemical probe technique using intrinsic activity for ethylene hydrogenation was demonstrated as an acceptable method for estimating the metallic surface areas of Pt. Amine (OA) capping exhibited a detrimental influence on the catalytic properties as severe deactivation and low activity were observed for ethylene hydrogenation and CO oxidation, respectively. These results were consistent with amine groups being strong poisons for Pt surfaces, and revealed the need to consider the effects of capping agents on the catalytic properties.

  5. Global patterns and controls of soil organic carbon dynamics as simulated by multiple terrestrial biosphere models: Current status and future directions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tian, Hanqin; Lu, Chaoqun; Yang, Jia; Banger, Kamaljit; Huntzinger, Deborah N.; Schwalm, Christopher R.; Michalak, Anna M.; Cook, Robert; Ciais, Philippe; Hayes, Daniel; et al

    2015-06-05

    Soil is the largest organic carbon (C) pool of terrestrial ecosystems, and C loss from soil accounts for a large proportion of land-atmosphere C exchange. Therefore, a small change in soil organic C (SOC) can affect atmospheric carbon dioxide (CO₂) concentration and climate change. In the past decades, a wide variety of studies have been conducted to quantify global SOC stocks and soil C exchange with the atmosphere through site measurements, inventories, and empirical/process-based modeling. However, these estimates are highly uncertain, and identifying major driving forces controlling soil C dynamics remains a key research challenge. This study has compiled century-longmore » (1901–2010) estimates of SOC storage and heterotrophic respiration (Rh) from 10 terrestrial biosphere models (TBMs) in the Multi-scale Synthesis and Terrestrial Model Intercomparison Project and two observation-based data sets. The 10 TBM ensemble shows that global SOC estimate ranges from 425 to 2111 Pg C (1 Pg = 10¹⁵ g) with a median value of 1158 Pg C in 2010. The models estimate a broad range of Rh from 35 to 69 Pg C yr⁻¹ with a median value of 51 Pg C yr⁻¹ during 2001–2010. The largest uncertainty in SOC stocks exists in the 40–65°N latitude whereas the largest cross-model divergence in Rh are in the tropics. The modeled SOC change during 1901–2010 ranges from –70 Pg C to 86 Pg C, but in some models the SOC change has a different sign from the change of total C stock, implying very different contribution of vegetation and soil pools in determining the terrestrial C budget among models. The model ensemble-estimated mean residence time of SOC shows a reduction of 3.4 years over the past century, which accelerate C cycling through the land biosphere. All the models agreed that climate and land use changes decreased SOC stocks, while elevated atmospheric CO₂ and nitrogen deposition over intact ecosystems increased SOC stocks—even though the responses varied significantly among models. Model representations of temperature and moisture sensitivity, nutrient limitation, and land use partially explain the divergent estimates of global SOC stocks and soil C fluxes in this study. In addition, a major source of systematic error in model estimations relates to nonmodeled SOC storage in wetlands and peatlands, as well as to old C storage in deep soil layers.« less

  6. Global patterns and controls of soil organic carbon dynamics as simulated by multiple terrestrial biosphere models: Current status and future directions

    SciTech Connect (OSTI)

    Tian, Hanqin; Lu, Chaoqun; Yang, Jia; Banger, Kamaljit; Huntzinger, Deborah N.; Schwalm, Christopher R.; Michalak, Anna M.; Cook, Robert; Ciais, Philippe; Hayes, Daniel; Huang, Maoyi; Ito, Akihiko; Jain, Atul K.; Lei, Huimin; Mao, Jiafu; Pan, Shufen; Post, Wilfred M.; Peng, Shushi; Poulter, Benjamin; Ren, Wei; Ricciuto, Daniel; Schaefer, Kevin; Shi, Xiaoying; Tao, Bo; Wang, Weile; Wei, Yaxing; Yang, Qichun; Zhang, Bowen; Zeng, Ning

    2015-06-05

    Soil is the largest organic carbon (C) pool of terrestrial ecosystems, and C loss from soil accounts for a large proportion of land-atmosphere C exchange. Therefore, a small change in soil organic C (SOC) can affect atmospheric carbon dioxide (CO₂) concentration and climate change. In the past decades, a wide variety of studies have been conducted to quantify global SOC stocks and soil C exchange with the atmosphere through site measurements, inventories, and empirical/process-based modeling. However, these estimates are highly uncertain, and identifying major driving forces controlling soil C dynamics remains a key research challenge. This study has compiled century-long (1901–2010) estimates of SOC storage and heterotrophic respiration (Rh) from 10 terrestrial biosphere models (TBMs) in the Multi-scale Synthesis and Terrestrial Model Intercomparison Project and two observation-based data sets. The 10 TBM ensemble shows that global SOC estimate ranges from 425 to 2111 Pg C (1 Pg = 10¹⁵ g) with a median value of 1158 Pg C in 2010. The models estimate a broad range of Rh from 35 to 69 Pg C yr⁻¹ with a median value of 51 Pg C yr⁻¹ during 2001–2010. The largest uncertainty in SOC stocks exists in the 40–65°N latitude whereas the largest cross-model divergence in Rh are in the tropics. The modeled SOC change during 1901–2010 ranges from –70 Pg C to 86 Pg C, but in some models the SOC change has a different sign from the change of total C stock, implying very different contribution of vegetation and soil pools in determining the terrestrial C budget among models. The model ensemble-estimated mean residence time of SOC shows a reduction of 3.4 years over the past century, which accelerate C cycling through the land biosphere. All the models agreed that climate and land use changes decreased SOC stocks, while elevated atmospheric CO₂ and nitrogen deposition over intact ecosystems increased SOC stocks—even though the responses varied significantly among models. Model representations of temperature and moisture sensitivity, nutrient limitation, and land use partially explain the divergent estimates of global SOC stocks and soil C fluxes in this study. In addition, a major source of systematic error in model estimations relates to nonmodeled SOC storage in wetlands and peatlands, as well as to old C storage in deep soil layers.

  7. China Low Carbon Platform | Open Energy Information

    Open Energy Info (EERE)

    Low Carbon Platform Jump to: navigation, search Name China Low Carbon Platform AgencyCompany Organization Institute of Development Studies, Climate Change and Development Centre,...

  8. Campus Carbon Calculator | Open Energy Information

    Open Energy Info (EERE)

    Campus Carbon Calculator Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Campus Carbon Calculator AgencyCompany Organization: Clean Air-Cool Planet Phase: Create a...

  9. Forest Carbon Index | Open Energy Information

    Open Energy Info (EERE)

    Forest Carbon Index Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Forest Carbon Index AgencyCompany Organization: Resources for the Future Partner: United Nations...

  10. Common Carbon Metric | Open Energy Information

    Open Energy Info (EERE)

    Common Carbon Metric Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Common Carbon Metric AgencyCompany Organization: United Nations Environment Programme, World...

  11. Validation of Hydrodynamic Load Models Using CFD for the OC4-DeepCwind Semisubmersible: Preprint

    SciTech Connect (OSTI)

    Benitz, M. A.; Schmidt, D. P.; Lackner, M. A.; Stewart, G. M.; Jonkman, J.; Robertson, A.

    2015-03-01

    Computational fluid dynamics (CFD) simulations were carried out on the OC4-DeepCwind semi-submersible to obtain a better understanding of how to set hydrodynamic coefficients for the structure when using an engineering tool such as FAST to model the system. The focus here was on the drag behavior and the effects of the free-surface, free-ends and multi-member arrangement of the semi-submersible structure. These effects are investigated through code-to-code comparisons and flow visualizations. The implications on mean load predictions from engineering tools are addressed. The work presented here suggests that selection of drag coefficients should take into consideration a variety of geometric factors. Furthermore, CFD simulations demonstrate large time-varying loads due to vortex shedding, which FAST's hydrodynamic module, HydroDyn, does not model. The implications of these oscillatory loads on the fatigue life needs to be addressed.

  12. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization Organization

  13. Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide

    DOE Patents [OSTI]

    Friend, Cynthia M; Madix, Robert J; Xu, Bingjun

    2015-01-20

    The invention provides a method for producing organic carbonates via the reaction of alcohols and carbon monoxide with oxygen adsorbed on a metallic gold or gold alloy catalyst.

  14. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  15. Seawater test results of open-cycle ocean thermal energy conversion (OC-OTEC) components

    SciTech Connect (OSTI)

    Zangrando, F.; Bharathan, D.; Link, H. ); Panchal, C.B. )

    1994-01-01

    Key components of open-cycle ocean thermal energy conversion systems--the flash evaporator, mist eliminator, passive predeaerator, two surface condenser stages, and two direct-contact condenser stages--have been tested using seawater. These components operate at lower steam pressures and higher inlet noncondensable gas concentrations than do conventional power plant heat exchangers. The rate of heat exchanged between the evaporator and the condenser is on the order of 1.25MW-thermal, requiring a warm seawater flow of about 0.1 m[sup 3]/s; the cold seawater flow is on the order of half the warm water flow. In addition to characterizing the performance of the various components, the system has produced potable water from condensation of the steam produced in the evaporator. The information obtained in these tests is being used to design a larger scale experiment in which net power production is expected to be demonstrate for the first time using OC-OTEC technology.

  16. Experiments on oxygen desorption from surface warm seawater under open-cycle ocean thermal energy conversion (OC-OTEC) conditions

    SciTech Connect (OSTI)

    Pesaran, A.A.

    1989-12-01

    This paper reports the results of scoping deaeration experiments conducted with warm surface seawater under open-cycle ocean thermal energy conversion (OC-OTEC). Concentrations of dissolved oxygen in seawater at three locations (in the supply water, water leaving a predeaerator, and discharge water from an evaporator) were measured and used to estimate oxygen desorption levels. The results suggest that 7% to 60% of dissolved oxygen in the supply water was desorbed from seawater in the predeaerator for pressures ranging from 9 to 35 kPa. Bubble injection in the upcomer increased the oxygen desorption rate by 20% to 60%. The dependence of oxygen desorption with flow rate could not be determined. The data also indicated that at typical OC-OTEC evaporator pressures when flashing occurred, 75% to 95% of dissolved oxygen was desorbed overall from the warm seawater. The uncertainty in results is larger than one would desire. These uncertainties are attributed to the uncertainties and difficulties in the dissolved oxygen measurements. Methods to improve the measurements for future gas desorption studies for warm surface and cold deep seawater under OC-OTEC conditions are recommended. 14 refs., 5 figs., 2 tabs.

  17. Controllable synthesis and characterization of novel copper-carbon core-shell structured nanoparticles

    SciTech Connect (OSTI)

    Zhai, Jing; Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, No. 15 Beisanhuan Dong Lu, Beijing 100029 ; Tao, Xia; Pu, Yuan; Zeng, Xiao-Fei; Chen, Jian-Feng

    2011-06-15

    Highlights: {yields} We reported a facile, green and cheap hydrothermal method to obtain novel copper-carbon core-shell nanoparticles. {yields} The as-formed particles with controllable size and morphology are antioxidant. {yields} The particles with organic-group-loaded surfaces and protective shells are expected to be applied in fields of medicine, electronics, sensors and lubricant. -- Abstract: A facile hydrothermal method was developed for preparing copper-carbon core-shell structured particles through a reaction at 160 {sup o}C in which glucose, copper sulfate pentahydrate and cetyltrimethylammonium bromide were used as starting materials. The original copper-carbon core-shell structured particles obtained were sized of 100-250 nm. The thickness of carbonaceous shells was controlled ranging from 25 to 100 nm by adjusting the hydrothermal duration time and the concentrations of glucose in the process. Products were characterized with transmission electron microscopy, X-ray diffraction, energy dispersive spectroscopy, Fourier transform infrared spectroscopy. Since no toxic materials were involved in the preparation, particles with stable carbonaceous framework and reactive surface also showed promising applications in medicine, electronics, sensors, lubricant, etc.

  18. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2015-02-05

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region's soil organic carbon (SOC) stocks to changing climatic conditions. Inmore » this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of organic carbon stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this organic carbon to permafrost thaw under a warming climate. Overall, frozen conditions and cryopedogenic processes, such as cryoturbation, have slowed decomposition and enhanced the sequestration of organic carbon in permafrost-affected soils over millennial timescales. Due to the low temperatures, the organic matter in permafrost soils is often less humified than in more temperate soils, making some portion of this stored organic carbon relatively vulnerable to mineralization upon thawing of permafrost.« less

  19. Carbonyl sulfide/carbon chemistry: Interim report, July 1, 1985-February 28, 1986

    SciTech Connect (OSTI)

    Hinckley, C.C.; Shiley, R.H.

    1986-05-01

    This interim report describes work performed during the first eight months of a continuing project, including descriptions of sample preparations and analyses. The objective of the study is to determine the effects of carbonyl sulfide, a product of the carbon monoxide/ethanol desulfurization process, on coal. A coal is first treated with carbon monoxide to reduce pyrite, and is then reacted with OCS and N/sub 2/ under various conditions. OCS is a potent resulfurization agent and appears to affect the formation of mesophase in chars derived from the coal. 8 refs., 1 fig., 8 tabs.

  20. Indonesia-Low Carbon Development Options Study | Open Energy...

    Open Energy Info (EERE)

    Indonesia-Low Carbon Development Options Study Jump to: navigation, search Name Indonesia-ESMAP Low Carbon Country Studies Program AgencyCompany Organization Energy Sector...

  1. China-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name China-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  2. Guyana's Low Carbon Development Strategy | Open Energy Information

    Open Energy Info (EERE)

    Guyana's Low Carbon Development Strategy Jump to: navigation, search Tool Summary Name: Guyana's Low Carbon Development Strategy AgencyCompany Organization: Guyana Office of...

  3. WWF-Country-Specific Low Carbon Plans | Open Energy Information

    Open Energy Info (EERE)

    Country-Specific Low Carbon Plans Jump to: navigation, search Name WWF-Country-Specific Low Carbon Plans AgencyCompany Organization World Wildlife Fund Sector Energy, Land,...

  4. Republic of Macedonia-Low Carbon Growth Country Studies Program...

    Open Energy Info (EERE)

    Low Carbon Growth Country Studies Program Jump to: navigation, search Name Republic of Macedonia-Low Carbon Growth Country Studies Program AgencyCompany Organization Energy...

  5. Kenya-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Kenya-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  6. United Kingdom Low Carbon Transition Plan | Open Energy Information

    Open Energy Info (EERE)

    Low Carbon Transition Plan Jump to: navigation, search Tool Summary LAUNCH TOOL Name: United Kingdom Low Carbon Transition Plan AgencyCompany Organization: United Kingdom...

  7. Stimulating Low-Carbon Vehicle Technologies | Open Energy Information

    Open Energy Info (EERE)

    Stimulating Low-Carbon Vehicle Technologies Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Stimulating Low-Carbon Vehicle Technologies AgencyCompany Organization: ITF...

  8. Turkey-Low Carbon Plan (LCP) | Open Energy Information

    Open Energy Info (EERE)

    Low Carbon Plan (LCP) Jump to: navigation, search Name Turkey-Country Specific Low Carbon Plans (LCP) AgencyCompany Organization World Wildlife Fund Sector Energy Topics...

  9. India-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name India-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  10. Brazil-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Brazil-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  11. Poland-Low Carbon Growth Country Studies Program | Open Energy...

    Open Energy Info (EERE)

    Low Carbon Growth Country Studies Program Jump to: navigation, search Name Poland-Low Carbon Growth Country Studies Program AgencyCompany Organization Energy Sector Management...

  12. Guyana-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Guyana-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  13. EBRD-The Low Carbon Transition | Open Energy Information

    Open Energy Info (EERE)

    The Low Carbon Transition Jump to: navigation, search Tool Summary LAUNCH TOOL Name: EBRD-The Low Carbon Transition AgencyCompany Organization: European Bank for Reconstruction...

  14. Mexico-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Mexico-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  15. Malaysia-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    Malaysia-ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Malaysia-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks,...

  16. A Low Carbon Economic Strategy for Scotland | Open Energy Information

    Open Energy Info (EERE)

    Low Carbon Economic Strategy for Scotland Jump to: navigation, search Name A Low Carbon Economic Strategy for Scotland AgencyCompany Organization Government of Scotland Sector...

  17. Indonesia-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Indonesia-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  18. Egypt-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Egypt-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks, Project...

  19. Ethiopia-ClimateWorks Low Carbon Growth Planning Support | Open...

    Open Energy Info (EERE)

    Ethiopia-ClimateWorks Low Carbon Growth Planning Support Jump to: navigation, search Name Ethiopia-Low Carbon Growth Planning Support AgencyCompany Organization ClimateWorks,...

  20. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube...

  1. Investigation on the Charging Process of Li2O2-Based Air Electrodes in Li-O2 Batteries with Organic Carbonate Electrolytes

    SciTech Connect (OSTI)

    Xu, Wu; Viswanathan, Vilayanur V.; Wang, Deyu; Towne, Silas A.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Zhang, Jiguang

    2011-04-15

    The charge processes of Li-O2 batteries were investigated by analyzing the gas evolution by in situ gas chromatography-mass spectroscopy (GC/MS) technique. The mixture of Li2O2/Fe3O4/Super P carbon/polyvinylidene fluoride (PVDF) was used as the starting air electrode material and 1M LiTFSI in carbonate-based solvents was used as electrolyte. It was found that Li2O2 is reactive to 1-methyl-2-pyrrolidinone and PVDF binder used in the electrode preparation. During the 1st charge (up to 4.6 V), O2 was the main component in the gases released. The amount of O2 measured by GC/MS was consistent with the amount of Li2O2 decomposed in the electrochemical process as measured by the charge capacity, indicative of the good chargeability of Li2O2. However, after the cell was discharged to 2.0 V in O2 atmosphere and re-charged to ~ 4.6 V in the second cycle, CO2 was dominant in the released gases. Further analysis of the discharged air electrode by X-ray diffraction and Fourier transform infrared spectroscopy indicated that lithium-containing carbonate species (lithium alkyl carbonate and/or Li2CO3) were the main reaction products. Therefore, compatible electrolyte and electrodes as well as the electrode preparation procedures need to be developed for long term operation of rechargeable Li-O2 or Li-air batteries.

  2. Evaluation of the carbon content of aerosols from the burn- ing of biomass in the Brazilian Amazon using thermal, op- tical and thermal-optical analysis methods

    SciTech Connect (OSTI)

    Soto-Garcia, Lydia L.; Andreae, Meinrat O.; Andreae, Tracey W.; taxo, Paulo Ar-; Maenhaut, Willy; Kirchstetter, Thomas; Novakov, T.; Chow, Judith C.; Mayol-Bracero, Olga L.

    2011-06-03

    Aerosol samples were collected at a pasture site in the Amazon Basin as part of the project LBA-SMOCC-2002 (Large-Scale Biosphere-Atmosphere Experiment in Amazonia - Smoke Aerosols, Clouds, Rainfall and Climate: Aerosols from Biomass Burning Perturb Global and Regional Climate). Sampling was conducted during the late dry season, when the aerosol composition was dominated by biomass burning emissions, especially in the submicron fraction. A 13-stage Dekati low-pressure impactor (DLPI) was used to collect particles with nominal aerodynamic diameters (D{sub p}) ranging from 0.03 to 0.10 m. Gravimetric analyses of the DLPI substrates and filters were performed to obtain aerosol mass concentrations. The concentrations of total, apparent elemental, and organic carbon (TC, EC{sub a}, and OC) were determined using thermal and thermal-optical analysis (TOA) methods. A light transmission method (LTM) was used to determine the concentration of equivalent black carbon (BC{sub e}) or the absorbing fraction at 880 nm for the size-resolved samples. During the dry period, due to the pervasive presence of fires in the region upwind of the sampling site, concentrations of fine aerosols (D{sub p} < 2.5 {mu}m: average 59.8 {mu}g m{sup -3}) were higher than coarse aerosols (D{sub p} > 2.5 {mu}m: 4.1 {mu}g m{sup -3}). Carbonaceous matter, estimated as the sum of the particulate organic matter (i.e., OC x 1.8) plus BC{sub e}, comprised more than 90% to the total aerosol mass. Concentrations of EC{sub a} (estimated by thermal analysis with a correction for charring) and BCe (estimated by LTM) averaged 5.2 {+-} 1.3 and 3.1 {+-} 0.8 {mu}g m{sup -3}, respectively. The determination of EC was improved by extracting water-soluble organic material from the samples, which reduced the average light absorption {angstrom} exponent of particles in the size range of 0.1 to 1.0 {mu}m from > 2.0 to approximately 1.2. The size-resolved BC{sub e} measured by the LTM showed a clear maximum between 0.4 and 0.6 m in diameter. The concentrations of OC and BC{sub e} varied diurnally during the dry period, and this variation is related to diurnal changes in boundary layer thickness and in fire frequency.

  3. Octahedral core–shell cuprous oxide/carbon with enhanced electrochemical activity and stability as anode for lithium ion batteries

    SciTech Connect (OSTI)

    Xiang, Jiayuan; Chen, Zhewei; Wang, Jianming

    2015-10-15

    Highlights: • Core–shell octahedral Cu{sub 2}O/C is prepared by a one-step method. • Carbon shell is amorphous and uniformly decorated at the Cu{sub 2}O octahedral core. • Core–shell Cu{sub 2}O/C exhibits markedly enhanced capability and reversibility. • Carbon shell provides fast ion/electron transfer channel. • Core–shell structure is stable during cycling. - Abstract: Core–shell Cu{sub 2}O/C octahedrons are synthesized by a simple hydrothermal method with the help of carbonization of glucose, which reduces Cu(II) to Cu(I) at low temperature and further forms carbon shell coating at high temperature. SEM and TEM images indicate that the carbon shell is amorphous with thickness of ∼20 nm wrapping the Cu{sub 2}O octahedral core perfectly. As anode of lithium ion batteries, the core–shell Cu{sub 2}O/C composite exhibits high and stable columbic efficiency (98%) as well as a reversible capacity of 400 mAh g{sup −1} after 80 cycles. The improved electrochemical performance is attributed to the novel core–shell structure, in which the carbon shell reduces the electrode polarization and promotes the charge transfer at active material/electrolyte interface, and also acts as a stabilizer to keep the octahedral structure integrity during discharge–charge processes.

  4. Conceptual design of an open-cycle ocean thermal energy conversion net power-producing experiment (OC-OTEC NPPE)

    SciTech Connect (OSTI)

    Bharathan, D.; Green, H.J.; Link, H.F.; Parsons, B.K.; Parsons, J.M.; Zangrando, F.

    1990-07-01

    This report describes the conceptual design of an experiment to investigate heat and mass transfer and to assess the viability of open-cycle ocean thermal energy conversion (OC-OTEC). The experiment will be developed in two stages, the Heat- and Mass-Transfer Experimental Apparatus (HMTEA) and the Net Power-Producing Experiment (NPPE). The goal for the HMTEA is to test heat exchangers. The goal for the NPPE is to experimentally verify OC-OTEC's feasibility by installing a turbine and testing the power-generating system. The design effort met the goals of both the HMTEA and the NPPE, and duplication of hardware was minimal. The choices made for the design resource water flow rates are consistent with the availability of cold and warm seawater as a result of the seawater systems upgrade carried out by the US Department of Energy (DOE), the state of Hawaii, and the Pacific International Center for High Technology Research. The choices regarding configuration of the system were made based on projected performance, degree of technical risk, schedule, and cost. The cost for the future phase of the design and the development of the HMTEA/NPPE is consistent with the projected future program funding levels. The HMTEA and NPPE were designed cooperatively by PICHTR, Argonne National Laboratory, and Solar Energy Research Institute under the guidance of DOE. The experiment will be located at the DOE's Seacoast Test Facility at the Natural Energy Laboratory of Hawaii, Kailua-Kona, Hawaii. 71 refs., 41 figs., 34 tabs.

  5. Assessment of thermal evolution stages and oil-gas migration of carbonate source rocks of early tertiary in eastern Sichuan, China, by organic inclusion analysis

    SciTech Connect (OSTI)

    Shi Jixi; Li Benchao; Fu Jiamo

    1989-03-01

    The Jialinjiang Formation of early Tertiary in Sichuan, China, is a series of limestone and dolomite sediments deposited in a platform shoal environment. The diagenetic sequence and organic inclusions trapped in minerals of 95 samples from 20 drillings have been studied. At the late diagenetic stage, pale yellow organic inclusions consisted of liquid hydrocarbons disseminated in pore-infiltrating dolomite, and the homogeneous temperature of contemporaneous saline liquid inclusions possessing a low gas-liquid ratio was 86/degree/C. This indicates the evolution of the organic matter had gone over the oil generating threshold and oil formation had initiated. In the limestone formed at the late diagenetic stage, more brown-yellow organic inclusions were scattered and/or developed along with fissures, comprising 60-70% liquid hydrocarbons and 30-40% gaseous hydrocarbons. Contemporaneous saline liquid inclusions with gas-liquid ratios of 5-10% had homogeneous temperatures of 90/degree/-130/degree/C. These findings show that the organic material had entered a high evolution stage and oil migration had taken place on a large scale.

  6. Improving carbon fixation pathways

    SciTech Connect (OSTI)

    Ducat, DC; Silver, PA

    2012-08-01

    A recent resurgence in basic and applied research on photosynthesis has been driven in part by recognition that fulfilling future food and energy requirements will necessitate improvements in crop carbon-fixation efficiencies. Photosynthesis in traditional terrestrial crops is being reexamined in light of molecular strategies employed by photosynthetic microbes to enhance the activity of the Calvin cycle. Synthetic biology is well-situated to provide original approaches for compartmentalizing and enhancing photosynthetic reactions in a species independent manner. Furthermore, the elucidation of alternative carbon-fixation routes distinct from the Calvin cycle raises possibilities that novel pathways and organisms can be utilized to fix atmospheric carbon dioxide into useful materials.

  7. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the

  8. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  9. Carbon Smackdown: Carbon Capture

    SciTech Connect (OSTI)

    Jeffrey Long

    2010-07-12

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  10. ARM - What is the Carbon Cycle?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What is the Carbon Cycle? Oceanic Properties Future Trends Carbon Cycle Balance Destination of Atmospheric Carbon Sources of Atmospheric Carbon The cycling of carbon from the atmosphere to organic compounds and back again not only involves

  11. Carbon and Energy Reporter | Open Energy Information

    Open Energy Info (EERE)

    and Energy Reporter Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon and Energy Reporter AgencyCompany Organization: Johnson Controls Sector: Energy User...

  12. Low Carbon Transition Unit | Open Energy Information

    Open Energy Info (EERE)

    Transition Unit Jump to: navigation, search Name Low Carbon Transition Unit AgencyCompany Organization Danish Government Partner Danish Ministry of Climate, Energy and Buildings;...

  13. Metal-Organic Frameworks with Precisely Designed Interior for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water...

  14. Methods and systems for chemoautotrophic production of organic compounds

    DOE Patents [OSTI]

    Fischer, Curt R.; Che, Austin J.; Shetty, Reshma P.; Kelly, Jason R.

    2013-01-08

    The present disclosure identifies pathways, mechanisms, systems and methods to confer chemoautotrophic production of carbon-based products of interest, such as sugars, alcohols, chemicals, amino acids, polymers, fatty acids and their derivatives, hydrocarbons, isoprenoids, and intermediates thereof, in organisms such that these organisms efficiently convert inorganic carbon to organic carbon-based products of interest using inorganic energy, such as formate, and in particular the use of organisms for the commercial production of various carbon-based products of interest.

  15. The AeroCom evaluation and intercomparison of organic aerosol in global models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tsigaridis, K.; Daskalakis, N.; Kanakidou, M.; Adams, P. J.; Artaxo, P.; Bahadur, R.; Balkanski, Y.; Bauer, S. E.; Bellouin, N.; Benedetti, A.; et al

    2014-10-15

    This paper evaluates the current status of global modeling of the organic aerosol (OA) in the troposphere and analyzes the differences between models as well as between models and observations. Thirty-one global chemistry transport models (CTMs) and general circulation models (GCMs) have participated in this intercomparison, in the framework of AeroCom phase II. The simulation of OA varies greatly between models in terms of the magnitude of primary emissions, secondary OA (SOA) formation, the number of OA species used (2 to 62), the complexity of OA parameterizations (gas-particle partitioning, chemical aging, multiphase chemistry, aerosol microphysics), and the OA physical, chemicalmore » and optical properties. The diversity of the global OA simulation results has increased since earlier AeroCom experiments, mainly due to the increasing complexity of the SOA parameterization in models, and the implementation of new, highly uncertain, OA sources. Diversity of over one order of magnitude exists in the modeled vertical distribution of OA concentrations that deserves a dedicated future study. Furthermore, although the OA / OC ratio depends on OA sources and atmospheric processing, and is important for model evaluation against OA and OC observations, it is resolved only by a few global models. The median global primary OA (POA) source strength is 56 Tg a–1 (range 34–144 Tg a−1) and the median SOA source strength (natural and anthropogenic) is 19 Tg a–1 (range 13–121 Tg a−1). Among the models that take into account the semi-volatile SOA nature, the median source is calculated to be 51 Tg a–1 (range 16–121 Tg a−1), much larger than the median value of the models that calculate SOA in a more simplistic way (19 Tg a–1; range 13–20 Tg a–1, with one model at 37 Tg a−1). The median atmospheric burden of OA is 1.4 Tg (24 models in the range of 0.6–2.0 Tg and 4 between 2.0 and 3.8 Tg), with a median OA lifetime of 5.4 days (range 3.8–9.6 days). In models that reported both OA and sulfate burdens, the median value of the OA/sulfate burden ratio is calculated to be 0.77; 13 models calculate a ratio lower than 1, and 9 models higher than 1. For 26 models that reported OA deposition fluxes, the median wet removal is 70 Tg a–1 (range 28–209 Tg a−1), which is on average 85% of the total OA deposition. Fine aerosol organic carbon (OC) and OA observations from continuous monitoring networks and individual field campaigns have been used for model evaluation. At urban locations, the model–observation comparison indicates missing knowledge on anthropogenic OA sources, both strength and seasonality. The combined model–measurements analysis suggests the existence of increased OA levels during summer due to biogenic SOA formation over large areas of the USA that can be of the same order of magnitude as the POA, even at urban locations, and contribute to the measured urban seasonal pattern. Global models are able to simulate the high secondary character of OA observed in the atmosphere as a result of SOA formation and POA aging, although the amount of OA present in the atmosphere remains largely underestimated, with a mean normalized bias (MNB) equal to –0.62 (–0.51) based on the comparison against OC (OA) urban data of all models at the surface, –0.15 (+0.51) when compared with remote measurements, and –0.30 for marine locations with OC data. The mean temporal correlations across all stations are low when compared with OC (OA) measurements: 0.47 (0.52) for urban stations, 0.39 (0.37) for remote stations, and 0.25 for marine stations with OC data. The combination of high (negative) MNB and higher correlation at urban stations when compared with the low MNB and lower correlation at remote sites suggests that knowledge about the processes that govern aerosol processing, transport and removal, on top of their sources, is important at the remote stations. There is no clear change in model skill with increasing model complexity with regard to OC or OA mass concentration. As a result, the complexity is needed in models in order to distinguish between anthropogenic and natural OA as needed for climate mitigation, and to calculate the impact of OA on climate accurately.« less

  16. Carbon Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Fact Sheet Research Team Members Key Contacts Carbon Storage Carbon capture and storage (CCS) is a key component of the U.S. carbon management portfolio. Numerous studies have shown that CCS can account for up to 55 percent of the emissions reductions needed to stabilize and ultimately reduce atmospheric concentrations of CO2. NETL's Carbon Storage Program is readying CCS technologies for widespread commercial deployment by 2020. The program's goals are: By 2015, develop technologies

  17. Carbon nanotube coatings as chemical absorbers

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Andresen, Brian D.; Alcaraz, Armando

    2004-06-15

    Airborne or aqueous organic compound collection using carbon nanotubes. Exposure of carbon nanotube-coated disks to controlled atmospheres of chemical warefare (CW)-related compounds provide superior extraction and retention efficiencies compared to commercially available airborne organic compound collectors. For example, the carbon nanotube-coated collectors were four (4) times more efficient toward concentrating dimethylmethyl-phosphonate (DMMP), a CW surrogate, than Carboxen, the optimized carbonized polymer for CW-related vapor collections. In addition to DMMP, the carbon nanotube-coated material possesses high collection efficiencies for the CW-related compounds diisopropylaminoethanol (DIEA), and diisopropylmethylphosphonate (DIMP).

  18. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  19. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  20. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  1. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  2. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  3. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  4. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure carbon to be magnetic, but for more than ten years scientists have suspected that carbon can be made to be magnetic by doping it with nonmagnetic materials, changing its order ever so slightly. Years ago, the first x-ray images obtained using the scanning transmission x-ray microscope at ALS Beamline 11.0.2 provided

  5. Japan-NIES Low-Carbon Society Scenarios 2050 | Open Energy Information

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name Japan-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  6. China-NIES Low-Carbon Society Scenarios 2050 | Open Energy Information

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name China-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  7. Thailand-NIES Low-Carbon Society Scenarios 2050 | Open Energy...

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name Thailand-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  8. Malaysia-NIES Low-Carbon Society Scenarios 2050 | Open Energy...

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name Malaysia-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  9. Vietnam-NIES Low-Carbon Society Scenarios 2050 | Open Energy...

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name Vietnam-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  10. India-NIES Low-Carbon Society Scenarios 2050 | Open Energy Information

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name India-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  11. Bangladesh-NIES Low-Carbon Society Scenarios 2050 | Open Energy...

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name Bangladesh-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  12. Indonesia-NIES Low-Carbon Society Scenarios 2050 | Open Energy...

    Open Energy Info (EERE)

    NIES Low-Carbon Society Scenarios 2050 Jump to: navigation, search Name Indonesia-NIES Low-Carbon Society Scenarios 2050 AgencyCompany Organization National Institute for...

  13. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: Characterization, improved calibration, and implications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H.; Chen, Q.; Kessler, S. H.; Massoli, P.; Ruiz, L. Hildebrandt; Fortner, E.; Williams, L. R.; Wilson, K. R.; et al

    2015-01-12

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), and organic mass-to-organic carbon (OM : OC) ratios, and of carbon oxidation state (OS C) for a vastly expanded laboratory data set of multifunctional oxidized OA standards. For the expanded standard data set, the method introduced by Aiken et al. (2008), which uses experimentally measured ionmoreintensities at all ions to determine elemental ratios (referred to here as "Aiken-Explicit"), reproduces known O : C and H : C ratio values within 20% (average absolute value of relative errors) and 12%, respectively. The more commonly used method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions (referred to here as "Aiken-Ambient"), reproduces O : C and H : C of multifunctional oxidized species within 28 and 14% of known values. The values from the latter method are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and especially H2O+ produced from many oxidized species. Combined AMSvacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method uses specific ion fragments as markers to correct for molecular functionality-dependent systematic biases and reproduces known O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C (H : C) values is smaller for theoretical standard mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OS C values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OS C units). This indicates that OS C is a more robust metric of oxidation than O : C, likely since OS C is not affected by hydration or dehydration, either in the atmosphere or during analysis.less

  14. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H.; Chen, Q.; Kessler, S. H.; Massoli, P.; Hildebrandt Ruiz, L.; Fortner, E.; Williams, L. R.; Wilson, K. R.; et al

    2014-07-31

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), organic mass-to-organic carbon (OM : OC), and carbon oxidation state (OSC) for a vastly expanded laboratory dataset of multifunctional oxidized OA standards. For the expanded standard dataset, the "Aiken-Explicit" method (Aiken et al., 2008), which uses experimentally measured ion intensities at all ions to determine elemental ratios, reproduces known molecular O :more » C and H : C ratio values within 20% (average absolute value of relative errors) and 12% respectively. The more commonly used "Aiken-Ambient" method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions, reproduces O : C and H : C of multifunctional oxidized species within 28% and 14% of known values. These values are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and H2O+ produced from many oxidized species. Combined AMS-vacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 °C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 °C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method reduces the systematic biases and reproduces O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C and H : C values is smaller (12% and 4% respectively) for synthetic mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OSC values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OSC units). This indicates that OSC is a more robust metric of oxidation than O : C, likely since OSC is not affected by hydration or dehydration, either in the atmosphere or during analysis.« less

  15. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H.; Chen, Q.; Kessler, S. H.; Massoli, P.; Hildebrandt Ruiz, L.; Fortner, E.; Williams, L. R.; Wilson, K. R.; et al

    2015-01-12

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), and organic mass-to-organic carbon (OM : OC) ratios, and of carbon oxidation state (OS C) for a vastly expanded laboratory data set of multifunctional oxidized OA standards. For the expanded standard data set, the method introduced by Aiken et al. (2008), which uses experimentally measured ion intensities at all ions to determinemore » elemental ratios (referred to here as "Aiken-Explicit"), reproduces known O : C and H : C ratio values within 20% (average absolute value of relative errors) and 12%, respectively. The more commonly used method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions (referred to here as "Aiken-Ambient"), reproduces O : C and H : C of multifunctional oxidized species within 28 and 14% of known values. The values from the latter method are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and especially H2O+ produced from many oxidized species. Combined AMS–vacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 °C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 °C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method uses specific ion fragments as markers to correct for molecular functionality-dependent systematic biases and reproduces known O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C (H : C) values is smaller for theoretical standard mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OS C values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OS C units). This indicates that OS C is a more robust metric of oxidation than O : C, likely since OS C is not affected by hydration or dehydration, either in the atmosphere or during analysis.« less

  16. Palladium-doped Nanoporous Carbon Fibers for Hydrogen Storage

    SciTech Connect (OSTI)

    Gallego, Nidia C; Contescu, Cristian I; Bhat, Vinay V; van Benthem, Klaus; Tekinalp, Halil; Edie, Dan

    2008-01-01

    Pd-free and Pd-containing activated carbon fibers (Pd-ACF) were synthesized from isotropic pitch as a carbon precursor. The source of Pd was a palladium salt that was premixed with pitch before carbonization. Hydrogen adsorption was measured at near-ambient temperatures (5 to 80 oC) and moderate pressures (up to 20 bar). It was found that adsorption on Pd-ACF is always higher than that on corresponding ACF, and in excess of what it would be expected based solely on formation of Pd hydride. This fact can be explained based on the mechanism of hydrogen spillover. It was also found that temperature and pressure have opposite effects on physisorption and spillover. It was hypothesized that a narrow temperature range exists, where the kinetic advantage of H2 spillover in Pd-ACF overlaps synergistically with the thermodynamic advantage of physisorption, thus contributing to enhanced uptakes compared with the Pd-free carbons.

  17. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated

  18. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated

  19. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated

  20. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Species of Cyanobacteria Forms Intracellular Carbonates New Species of Cyanobacteria Forms Intracellular Carbonates Print Wednesday, 30 January 2013 00:00 A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering

  1. New Species of Cyanobacteria Forms Intracellular Carbonates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Species of Cyanobacteria Forms Intracellular Carbonates Print A new species of cyanobacteria-photosynthetic bacteria that occupy a wide array of habitats-was discovered in the Mexican Lake of Alchichica where massive carbonate rocks form. Cyanobacteria have been impacting the global carbon cycle of the Earth for more than 2.3 billion years by assimilating CO2 into organic compounds and triggering calcium carbonate (CaCO3) precipitation. Despite the importance of this cyanobacteria-mediated

  2. Treatment of organic waste

    DOE Patents [OSTI]

    Grantham, LeRoy F.

    1979-01-01

    An organic waste containing at least one element selected from the group consisting of strontium, cesium, iodine and ruthenium is treated to achieve a substantial reduction in the volume of the waste and provide for fixation of the selected element in an inert salt. The method of treatment comprises introducing the organic waste and a source of oxygen into a molten salt bath maintained at an elevated temperature to produce solid and gaseous reaction products. The gaseous reaction products comprise carbon dioxide and water vapor, and the solid reaction products comprise the inorganic ash constituents of the organic waste and the selected element which is retained in the molten salt. The molten salt bath comprises one or more alkali metal carbonates, and may optionally include from 1 to about 25 wt.% of an alkali metal sulfate.

  3. Carbon Dioxide Conversion to Valuable Chemical Products over Composite Catalytic Systems

    SciTech Connect (OSTI)

    Dagle, Robert A.; Hu, Jianli; Jones, Susanne B.; Wilcox, Wayne A.; Frye, John G.; White, J. F.; Jiang, Juyuan; Wang, Yong

    2013-05-01

    Presented is an experimental study on catalytic conversion of carbon dioxide into methanol, ethanol and acetic acid. Catalysts having different catalytic functions were synthesized and combined in different ways to enhance selectivity to desired products. The combined catalyst system possessed the following functions: methanol synthesis, Fischer-Tropsch synthesis, water-gas-shift and hydrogenation. Results showed that the methods of integrating these catalytic functions played important role in achieving desired product selectivity. It was speculated that if methanol synthesis sites were located adjacent to the C-C chain growth sites, the formation rate of C2 oxygenates would be enhanced. The advantage of using high temperature methanol catalyst PdZnAl in the combined catalyst system was demonstrated. In the presence of PdZnAl catalyst, the combined catalyst system was stable at temperature of 380oC. It was observed that, at high temperature, kinetics favored oxygenate formation. Results implied that the process can be intensified by operating at high temperature using Pd-based methanol synthesis catalyst. Steam reforming of the byproduct organics was demonstrated as a means to provide supplemental hydrogen. Preliminary process design, simulation, and economic analysis of the proposed CO2 conversion process were carried out. Economic analysis indicates how ethanol production cost was affected by the price of CO2 and hydrogen.

  4. Recovery of organic acids

    DOE Patents [OSTI]

    Verser, Dan W. (Menlo Park, CA); Eggeman, Timothy J. (Lakewood, CO)

    2011-11-01

    A method is disclosed for the recovery of an organic acid from a dilute salt solution in which the cation of the salt forms an insoluble carbonate salt. A tertiary amine and CO.sub.2 are introduced to the solution to form the insoluble carbonate salt and a complex between the acid and an amine. A water immiscible solvent, such as an alcohol, is added to extract the acid/amine complex from the dilute salt solution to a reaction phase. The reaction phase is continuously dried and a product between the acid and the solvent, such as an ester, is formed.

  5. Recovery of organic acids

    DOE Patents [OSTI]

    Verser, Dan W. (Golden, CO); Eggeman, Timothy J. (Lakewood, CO)

    2009-10-13

    A method is disclosed for the recovery of an organic acid from a dilute salt solution in which the cation of the salt forms an insoluble carbonate salt. A tertiary amine and CO.sub.2 are introduced to the solution to form the insoluble carbonate salt and a complex between the acid and an amine. A water immiscible solvent, such as an alcohol, is added to extract the acid/amine complex from the dilute salt solution to a reaction phase. The reaction phase is continuously dried and a product between the acid and the solvent, such as an ester, is formed.

  6. Indexing Permafrost Soil Organic Matter Degradation Using High-Resolution Mass Spectrometry

    SciTech Connect (OSTI)

    Mann, Benjamin F.; Chen, Hongmei; Herndon, Elizabeth M.; Chu, Rosalie K.; Tolic, Nikola; Portier, Evan F.; Roy Chowdhury, Taniya; Robinson, Errol W.; Callister, Stephen J.; Wullschleger, Stan D.; Graham, David E.; Liang, Liyuan; Gu, Baohua; Hui, Dafeng

    2015-06-12

    Microbial degradation of soil organic matter (SOM) is a key process for terrestrial carbon cycling, although the molecular details of these transformations remain unclear. This study reports the application of ultrahigh resolution mass spectrometry to profile the molecular composition of SOM and its degradation during a simulated warming experiment. A soil sample, collected near Barrow, Alaska, USA, was subjected to a 40-day incubation under anoxic conditions and analyzed before and after the incubation to determine changes of SOM composition. A CHO index based on molecular C, H, and O data was utilized to codify SOM components according to their observed degradation potentials. Compounds with a CHO index score between –1 and 0 in a water-soluble fraction (WSF) demonstrated high degradation potential, with a highest shift of CHO index occurred in the N-containing group of compounds, while similar stoichiometries in a base-soluble fraction (BSF) did not. Additionally, compared with the classical H:C vs O:C van Krevelen diagram, CHO index allowed for direct visualization of the distribution of heteroatoms such as N in the identified SOM compounds. We demonstrate that CHO index is useful not only in characterizing arctic SOM at the molecular level but also enabling quantitative description of SOM degradation, thereby facilitating incorporation of the high resolution MS datasets to future mechanistic models of SOM degradation and prediction of greenhouse gas emissions.

  7. Indexing Permafrost Soil Organic Matter Degradation Using High-Resolution Mass Spectrometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mann, Benjamin F.; Chen, Hongmei; Herndon, Elizabeth M.; Chu, Rosalie K.; Tolic, Nikola; Portier, Evan F.; Roy Chowdhury, Taniya; Robinson, Errol W.; Callister, Stephen J.; Wullschleger, Stan D.; et al

    2015-06-12

    Microbial degradation of soil organic matter (SOM) is a key process for terrestrial carbon cycling, although the molecular details of these transformations remain unclear. This study reports the application of ultrahigh resolution mass spectrometry to profile the molecular composition of SOM and its degradation during a simulated warming experiment. A soil sample, collected near Barrow, Alaska, USA, was subjected to a 40-day incubation under anoxic conditions and analyzed before and after the incubation to determine changes of SOM composition. A CHO index based on molecular C, H, and O data was utilized to codify SOM components according to their observedmore » degradation potentials. Compounds with a CHO index score between –1 and 0 in a water-soluble fraction (WSF) demonstrated high degradation potential, with a highest shift of CHO index occurred in the N-containing group of compounds, while similar stoichiometries in a base-soluble fraction (BSF) did not. Additionally, compared with the classical H:C vs O:C van Krevelen diagram, CHO index allowed for direct visualization of the distribution of heteroatoms such as N in the identified SOM compounds. We demonstrate that CHO index is useful not only in characterizing arctic SOM at the molecular level but also enabling quantitative description of SOM degradation, thereby facilitating incorporation of the high resolution MS datasets to future mechanistic models of SOM degradation and prediction of greenhouse gas emissions.« less

  8. Organic containment separator

    DOE Patents [OSTI]

    Del Mar, Peter

    1995-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube, said solvent capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube is disclosed.

  9. Organic contaminant separator

    DOE Patents [OSTI]

    Mar, Peter D.

    1994-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube, said solvent capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a composite tube including a polymeric base material selected from the group of polyolefins and polyfluorocarbons and particles of a carbon allotrope material adfixed to the inner wall of the polymeric base material, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube is disclosed.

  10. International Carbon Storage Body Praises Department of Energy Projects

    Broader source: Energy.gov [DOE]

    Three U.S. Department of Energy projects have been identified by an international carbon storage organization as an important advancement toward commercialization and large-scale deployment of carbon capture, utilization, and storage technologies.

  11. McKinsey Carbon Supply Curves | Open Energy Information

    Open Energy Info (EERE)

    Carbon Supply Curves Jump to: navigation, search Tool Summary LAUNCH TOOL Name: McKinsey Carbon Supply Curves AgencyCompany Organization: McKinsey and Company Sector: Energy,...

  12. Ukraine-Capacity Building for Low Carbon Growth | Open Energy...

    Open Energy Info (EERE)

    Ukraine-Capacity Building for Low Carbon Growth Jump to: navigation, search Name UNDP-Capacity Building for Low Carbon Growth in Ukraine AgencyCompany Organization United Nations...

  13. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  14. Geoscience Perspectives in Carbon Sequestration - Educational Training and Research Through Classroom, Field, and Laboratory Investigations

    SciTech Connect (OSTI)

    Wronkiewicz, David; Paul, Varum; Abousif, Alsedik; Ryback, Kyle

    2013-09-30

    The most effective mechanism to limit CO{sub 2} release from underground Geologic Carbon Sequestration (GCS) sites over multi-century time scales will be to convert the CO{sub 2} into solid carbonate minerals. This report describes the results from four independent research investigations on carbonate mineralization: 1) Colloidal calcite particles forming in Maramec Spring, Missouri, provide a natural analog to evaluate reactions that may occur in a leaking GCS site. The calcite crystals form as a result of physiochemical changes that occur as the spring water rises from a depth of more than 190'. The resultant pressure decrease induces a loss of CO{sub 2} from the water, rise in pH, lowering of the solubility of Ca{sup 2+} and CO{sub 3}{sup 2-}, and calcite precipitation. Equilibrium modelling of the spring water resulted in a calculated undersaturated state with respect to calcite. The discontinuity between the observed occurrence of calcite and the model result predicting undersaturated conditions can be explained if bicarbonate ions (HCO{sub 3}{sup -}) are directly involved in precipitation process rather than just carbonate ions (CO{sub 3}{sup 2-}). 2) Sedimentary rocks in the Oronto Group of the Midcontinent Rift (MCR) system contain an abundance of labile Ca-, Mg-, and Fe-silicate minerals that will neutralize carbonic acid and provide alkaline earth ions for carbonate mineralization. One of the challenges in using MCR rocks for GCS results from their low porosity and permeability. Oronto Group samples were reacted with both CO{sub 2}-saturated deionized water at 90°C, and a mildly acidic leachant solution in flow-through core-flooding reactor vessels at room temperature. Resulting leachate solutions often exceeded the saturation limit for calcite. Carbonate crystals were also detected in as little as six days of reaction with Oronto Group rocks at 90oC, as well as experiments with forsterite-olivine and augite, both being common minerals this sequence. The Oronto Group samples have poor reservoir rock characteristics, none ever exceeded a permeability value of 2.0 mD even after extensive dissolution of calcite cement during the experiments. The overlying Bayfield Group – Jacobsville Formation sandstones averaged 13.4 ± 4.3% porosity and a single sample tested by core-flooding revealed a permeability of ~340 mD. The high porosity-permeability characteristics of these sandstones will allow them to be used for GCS as a continuous aquifer unit with the overlying Mt. Simon Formation. 3) Anaerobic sulfate reducing bacteria (SRB) can enhance the conversion rate of CO{sub 2} into solid minerals and thereby improve long-term storage. SRB accelerated carbonate mineralization reactions between pCO{sub 2} values of 0.0059 and 14.7 psi. Hydrogen, lactate and formate served as suitable electron donors for SRB metabolism. The use of a {sup 13}CO{sub 2} spiked gas source also produced carbonate minerals with ~53% of the carbon being derived from the gas phase. The sulfate reducing activity of the microbial community was limited, however, at 20 psi pCO{sub 2} and carbonate mineralization did not occur. Inhibition of bacterial metabolism may have resulted from the acidic conditions or CO{sub 2} toxicity. 4) Microbialite communities forming in the high turbidity and hypersaline water of Storrs’ Lake, San Salvador Island, The Bahamas, were investigated for their distribution, mineralogy and microbial diversity. Molecular analysis of the organic mats on the microbialites indicate only a trace amount of cyanobacteria, while anaerobic and photosynthetic non-sulfur bacteria of the phyla Chloroflexi and purple sulfur bacteria of class Gammaproteobacteria were abundant.

  15. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee R. Todd Anderson Program Manager, BER Climate and Environmental Sciences Anjuli Barnzai Program Manager, BER Climate and Environmental...

  16. Systematic Tuning and Multi-Functionalization of Covalent Organic Polymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Enhanced Carbon Capture | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Systematic Tuning and Multi-Functionalization of Covalent Organic Polymers for Enhanced Carbon Capture Slide1 Link to article

  17. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  18. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  19. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  20. Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture Fact Sheet Research Team Members Key Contacts Carbon Capture Research & Development Carbon capture and storage from fossil-based power generation is a critical component of realistic strategies for arresting the rise in atmospheric CO2 concentrations, but capturing substantial amounts of CO2 using current technology would result in a prohibitive rise in the cost of producing energy. The National Energy Technology Laboratory, in collaboration with researchers from regional

  1. Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture Carbon capture involves the separation of CO2 from coal-based power plant flue gas or syngas. Commercially available first-generation CO2 capture technologies are currently being used in various industrial applications. However, in their current state of development, these technologies are not ready for implementation on coal-based power plants because they have not been demonstrated at appropriate scale, require approximately one-third of the plant's steam and power to operate,

  2. India-Options for Low Carbon Development | Open Energy Information

    Open Energy Info (EERE)

    Low Carbon Growth Country Studies Program AgencyCompany Organization Energy Sector Management Assistance Program of the World Bank Sector Energy, Land Focus Area Energy...

  3. Philippines-Low Carbon Plan (LCP) | Open Energy Information

    Open Energy Info (EERE)

    Plan (LCP) Jump to: navigation, search Name Philippines-Low Carbon Plan (LCP) AgencyCompany Organization World Wildlife Fund Sector Energy Topics Background analysis, Low...

  4. Development of the Electricity Carbon Emission Factors for Russia...

    Open Energy Info (EERE)

    Russia Jump to: navigation, search Name Development of the Electricity Carbon Emission Factors for Russia AgencyCompany Organization European Bank for Reconstruction and...

  5. Low Carbon Development: Planning & Modelling Course | Open Energy...

    Open Energy Info (EERE)

    & Modelling Course Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low Carbon Development: Planning & Modelling Course AgencyCompany Organization: World Bank...

  6. Low-Carbon Land Transport Policy Handbook | Open Energy Information

    Open Energy Info (EERE)

    Policy Handbook Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low-Carbon Land Transport Policy Handbook AgencyCompany Organization: Routledge ComplexityEase...

  7. Low Carbon Society (LCS) Database | Open Energy Information

    Open Energy Info (EERE)

    (LCS) Database Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low Carbon Society (LCS) Database AgencyCompany Organization: LCS-RNet Sector: Energy, Land Focus Area:...

  8. Indonesia-Low Carbon Growth Project | Open Energy Information

    Open Energy Info (EERE)

    Growth Project Jump to: navigation, search Name Indonesia Low Carbon Growth Project AgencyCompany Organization United Kingdom Department for International Development Partner...

  9. Low Carbon Growth Plans: A Sectoral Approach to Climate Protection...

    Open Energy Info (EERE)

    to Climate Protection Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low Carbon Growth Plans: A Sectoral Approach to Climate Protection AgencyCompany Organization:...

  10. Low Carbon Society Vision 2050: India | Open Energy Information

    Open Energy Info (EERE)

    Vision 2050: India Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low Carbon Society Vision 2050: India AgencyCompany Organization: National Institute for...

  11. Low Carbon Growth Country Studies Program | Open Energy Information

    Open Energy Info (EERE)

    Country Studies Program Jump to: navigation, search Name Low Carbon Growth Country Studies Program AgencyCompany Organization Energy Sector Management Assistance Program of the...

  12. Low Carbon Economy Index 2010 | Open Energy Information

    Open Energy Info (EERE)

    Economy Index 2010 Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low Carbon Economy Index 2010 AgencyCompany Organization: PricewaterhouseCoopers Sector: Energy,...

  13. Low-Carbon Technology Cooperation in the Climate Regime | Open...

    Open Energy Info (EERE)

    in the Climate Regime Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low-Carbon Technology Cooperation in the Climate Regime AgencyCompany Organization: Energy...

  14. Carbon Value Analysis Tool (CVAT) | Open Energy Information

    Open Energy Info (EERE)

    Value Analysis Tool (CVAT) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Value Analysis Tool (CVAT) AgencyCompany Organization: World Resources Institute...

  15. Carbon Initiative for Development (Ci-Dev) | Open Energy Information

    Open Energy Info (EERE)

    Initiative for Development (Ci-Dev) Jump to: navigation, search Name Carbon Initiative for Development (Ci-Dev) AgencyCompany Organization World Bank Sector Climate Topics...

  16. Low-Carbon Society Development: Towards 2025 in Bangladesh |...

    Open Energy Info (EERE)

    2025 in Bangladesh Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low-Carbon Society Development: Towards 2025 in Bangladesh AgencyCompany Organization: Kyoto...

  17. India-Low Carbon Transport | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name UNEP-Low Carbon Transport in India AgencyCompany Organization United Nations Environment Programme (UNEP) Sector Climate, Energy Focus Area...

  18. Mass production of multi-wall carbon nanotubes by metal dusting process with high yield

    SciTech Connect (OSTI)

    Ghorbani, H.; Rashidi, A.M.; Rastegari, S.; Mirdamadi, S.; Alaei, M.

    2011-05-15

    Research highlights: {yields} Synthesis of carbon nanotubes over Fe-Ni nanoparticles supported alloy 304L. {yields} Production of carbon nanotubes with high yield (700-1000%) and low cost catalyst. {yields} Optimum growth condition is CO/H{sub 2} = 1/1, 100 cm{sup 3}/min, at 620 {sup o}C under long term repetitive thermal cycling. {yields} Possibility of the mass production by metal dusting process with low cost. -- Abstract: Carbon nanotube materials were synthesized over Fe-Ni nanoparticles generated during disintegration of the surface of alloy 304L under metal dusting environment. The metal dusting condition was simulated and optimized through exposing stainless steel samples during long term repetitive thermal cycling in CO/H{sub 2} = 1/1, total gas flow rate 100 cm{sup 3}/min, at 620 {sup o}C for 300 h. After reaction, surface morphology of the samples and also carbonaceous deposition which had grown on sample surfaces were examined by stereoscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Results revealed that multi-wall carbon nanotubes could be formed over nanocatalyst generated on the alloy surface by exploiting metal dusting process. By optimization of reaction parameters the yields of carbon nanotube materials obtained were 700-1000%. Also it has been shown herein that the amount of carbon nanotube materials remarkably increases when the reaction time is extended up to 300 h, indicating a possibility of the mass production by this easy method.

  19. Measurements of gas sorption from seawater and the influence of gas release on open-cycle ocean thermal energy conversion (OC-OTEC) system performance

    SciTech Connect (OSTI)

    Penney, T.R.; Althof, J.A.

    1985-06-01

    The technical community has questioned the validity and cost-effectiveness of open-cycle ocean thermal energy conversion (OC-OTEC) systems because of the unknown effect of noncondensable gas on heat exchanger performance and the power needed to run vacuum equipment to remove this gas. To date, studies of seawater gas desorption have not been prototypical for system level analysis. This study gives preliminary gas desorption data on a vertical spout, direct contact evaporator and multiple condenser geometries. Results indicate that dissolved gas can be substantially removed before the seawater enters the heat exchange process, reducing the uncertainty and effect of inert gas on heat exchanger performance.

  20. Electrochemical and infrared studies of the reduction of organic...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electrochemical and infrared studies of the reduction of organic carbonates Citation Details ... Publication Date: 2001-06-01 OSTI Identifier: 821009 Report ...

  1. Mechanism and Kinetic Modeling of Hydrogenation in The Organic...

    Office of Scientific and Technical Information (OSTI)

    Mechanism and Kinetic Modeling of Hydrogenation in The Organic GetterPd CatalystActivated Carbon Systems Citation Details In-Document Search Title: Mechanism and Kinetic Modeling ...

  2. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About Us Organization Organization Organization OCIO Organizational Chart (Printable) News & Blog CIO Leadership Organization Contact Us

  3. Carbon particles

    DOE Patents [OSTI]

    Hunt, Arlon J.

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  4. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  5. Carbon microtubes

    DOE Patents [OSTI]

    Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2011-06-14

    A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

  6. Molecular Characterization of Organic Aerosol Using Nanospray Desorption/Electrospray Ionization Mass Spectrometry: CalNex 2010 field study

    SciTech Connect (OSTI)

    O'Brien, Rachel E.; Laskin, Alexander; Laskin, Julia; Liu, Shang; Weber, Robin; Russell, Lynn; Goldstein, Allen H.

    2013-04-01

    Aerosol samples from the CalNex 2010 field study were analyzed using high resolution mass spectrometry (HR-MS) coupled to a nanospray-desorption/electrospray ionization (nano-DESI) source. The samples were collected in Bakersfield, CA on June 22-23, 2010. The chemical formulas of over 1300 unique molecular species were detected in the mass range of 50-800 m/z. Our analysis focused on identification of two main groups: compounds containing only carbon, hydrogen, and oxygen (CHO only), and nitrogen-containing organic compounds (NOC). The NOC accounted for 35% (by number) of the compounds observed in the afternoon, and for 59% in the early morning samples. By comparing plausible reactant-product pairs, we propose that over 50% of the NOC in each sample could have been formed through reactions transforming carbonyls into imines. The CHO only compounds were dominant in the afternoon suggesting a photochemical source. The average O:C ratios of all observed compounds were fairly consistent throughout the day, ranging from 0.34 in the early morning to 0.37 at night. We conclude that both photooxidation and ammonia chemistry play important roles in forming the compounds observed in this mixed urban-rural environment.

  7. Organic aerogel microspheres

    DOE Patents [OSTI]

    Mayer, Steven T.; Kong, Fung-Ming; Pekala, Richard W.; Kaschmitter, James L.

    1999-01-01

    Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

  8. Organic aerogel microspheres

    DOE Patents [OSTI]

    Mayer, S.T.; Kong, F.M.; Pekala, R.W.; Kaschmitter, J.L.

    1999-06-01

    Organic aerogel microspheres are disclosed which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonstick gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

  9. Near-ambient X-ray photoemission spectroscopy and kinetic approach to the mechanism of carbon monoxide oxidation over lanthanum substituted cobaltites

    SciTech Connect (OSTI)

    Hueso, J. L.; Martinez-Martinez, D.; Cabalerro, Alfonso; Gonzalez-Elipe, Agustin Rodriguez; Mun, Bongjin Simon; Salmeron, Miquel

    2009-07-31

    We have studied the oxidation of carbon monoxide over a lanthanum substituted perovskite (La0.5Sr0.5CoO3-d) catalyst prepared by spray pyrolysis. Under the assumption of a first-order kinetics mechanism for CO, it has been found that the activation energy barrier of the reaction changes from 80 to 40 kJ mol-1 at a threshold temperature of ca. 320 oC. In situ XPS near-ambient pressure ( 0.2 torr) shows that the gas phase oxygen concentration over the sample decreases sharply at ca. 300 oC. These two observations suggest that the oxidation of CO undergoes a change of mechanism at temperatures higher than 300 oC.

  10. Weathering controls on mechanisms of carbon storage in grassland soils

    SciTech Connect (OSTI)

    Masiello, C.A.; Chadwick, O.A.; Southon, J.; Torn, M.S.; Harden, J.W.

    2004-09-01

    On a sequence of soils developed under similar vegetation, temperature, and precipitation conditions, but with variations in mineralogical properties, we use organic carbon and 14C inventories to examine mineral protection of soil organic carbon. In these soils, 14C data indicate that the creation of slow-cycling carbon can be modeled as occurring through reaction of organic ligands with Al3+ and Fe3+ cations in the upper horizons, followed by sorption to amorphous inorganic Al compounds at depth. Only one of these processes, the chelation of Al3+ and Fe3+ by organic ligands, is linked to large carbon stocks. Organic ligands stabilized by this process traverse the soil column as dissolved organic carbon (both from surface horizons and root exudates). At our moist grassland site, this chelation and transport process is very strongly correlated with the storage and long-term stabilization of soil organic carbon. Our 14C results show that the mechanisms of organic carbon transport and storage at this site follow a classic model previously believed to only be significant in a single soil order (Spodosols), and closely related to the presence of forests. The presence of this process in the grassland Alfisol, Inceptisol, and Mollisol soils of this chronosequence suggests that this process is a more significant control on organic carbon storage than previously thought.

  11. Method for making carbon films

    DOE Patents [OSTI]

    Tan, Ming X.

    1999-01-01

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

  12. Method for making carbon films

    DOE Patents [OSTI]

    Tan, M.X.

    1999-07-29

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area ([approx equal]1000 m[sup 2] /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160 C for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750 C in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750--850 C for between 1--6 hours. 2 figs.

  13. Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search TODO: Add description Related Links List of Companies in Carbon Sector Retrieved from "http:en.openei.orgwindex.php?titleCarbon&oldid271960...

  14. Gas adsorption on metal-organic frameworks

    DOE Patents [OSTI]

    Willis, Richard R.; Low, John J. , Faheem, Syed A.; Benin, Annabelle I.; Snurr, Randall Q.; Yazaydin, Ahmet Ozgur

    2012-07-24

    The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.

  15. Understanding sources of organic aerosol during CalNex-2010 using the CMAQ-VBS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Woody, M. C.; Baker, K. R.; Hayes, P. L.; Jimenez, J. L.; Koo, B.; Pye, H. O. T.

    2015-10-05

    Community Multiscale Air Quality (CMAQ) model simulations utilizing the volatility basis set (VBS) treatment for organic aerosols (CMAQ-VBS) were evaluated against measurements collected at routine monitoring networks (Chemical Speciation Network (CSN) and Interagency Monitoring of Protected Visual Environments (IMPROVE)) and those collected during the 2010 California at the Nexus of Air Quality and Climate Change (CalNex) field campaign to examine important sources of organic aerosol (OA) in southern California. CMAQ-VBS (OA lumped by volatility, semivolatile POA) underpredicted total organic carbon (OC) at CSN (?25.5 % Normalized Median Bias (NMdnB)) and IMPROVE (?63.9 % NMdnB) locations and total OC wasmoreunderpredicted to a greater degree compared to the CMAQ-AE6 (9.9 and ?55.7 % NMdnB, respectively; semi-explicit OA treatment, SOA lumped by parent hydrocarbon, nonvolatile POA). However, comparisons to aerosol mass spectrometer (AMS) measurements collected at Pasadena, CA indicated that CMAQ-VBS better represented the diurnal profile and the primary/secondary split of OA. CMAQ-VBS secondary organic aerosol (SOA) underpredicted the average measured AMS oxygenated organic aerosol (OOA, a surrogate of SOA) concentration by a factor of 5.2 (4.7 ?g m?3 measured vs. 0.9 ?g m?3 modeled), a considerable improvement to CMAQ-AE6 SOA predictions, which were approximately 24 lower than the average AMS OOA concentration. We use two new methods, based on species ratios and on a simplified SOA parameterization from the observations, to apportion the SOA underprediction for CMAQ-VBS to too slow photochemical oxidation (estimated as 1.5 lower than observed at Pasadena using ? log (NOx: NOy)), low intrinsic SOA formation efficiency (low by 1.6 to 2 for Pasadena), and too low emissions or too high dispersion for the Pasadena site (estimated to be 1.6 to 2.3 too low/high). The first and third factors will be similar for CMAQ-AE6, while the intrinsic SOA formation efficiency for that model is estimated to be too low by about 7. For CMAQ-VBS, 90 % of the anthropogenic SOA mass formed was attributed to aged secondary semivolatile vapors (70 % originating from volatile organic compounds (VOCs) and 20 % from intermediate volatility compounds (IVOCs)). From source-apportioned model results, we found most of the CMAQ-VBS modeled POA at the Pasadena CalNex site was attributable to meat cooking emissions (48 %, and consistent with a substantial fraction of cooking OA in the observations), compared to 18 % from gasoline vehicle emissions, 13 % from biomass burning (in the form of residential wood combustion), and 8 % from diesel vehicle emissions. All "other" inventoried emission sources (e.g. industrial/point sources) comprised the final 13 %. The CMAQ-VBS semivolatile POA treatment underpredicted AMS hydrocarbon-like OA (HOA) + cooking-influenced OA (CIOA) at Pasadena by a factor of 1.8 (1.16 ?g m?3 modeled vs. 2.05 ?g m?3 observed) compared to a factor of 1.4 overprediction of POA in CMAQ-AE6, but did well to capture the AMS diurnal profile of HOA and CIOA, with the exception of the midday peak. We estimated that using the National Emission Inventory (NEI) POA emissions without scaling to represent SVOCs underestimates SVOCs by ~1.7.less

  16. Method of stripping metals from organic solvents

    DOE Patents [OSTI]

    Todd, Terry A.; Law, Jack D.; Herbst, R. Scott; Romanovskiy, Valeriy N.; Smirnov, Igor V.; Babain, Vasily A.; Esimantovski, Vyatcheslav M.

    2009-02-24

    A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.

  17. Synthesis of Large Arrays of Well-Aligned Carbon Nanotubes on Glass

    SciTech Connect (OSTI)

    Bush, P. Siegal, M.P.; Huang, Z.P.; Provencio, P.N.; Ren, Z.F.; Wang, J.H.; Xu, J.W.

    1998-11-10

    Free-standing aligned carbon nanotubes have previously been grown above 7000C on mesoporous silica embedded with iron nanoparticles. Here, carbon nanotubes aligned over areas up to several square centimeters were grown on nickel-coated glass below 666oC by plasma-enhanced hot filament chemical vapor deposition. Acetylene (C2H2) gas was used as the carbon source and ammonia (NH3) gas was used as a catalyst and dilution gas. Nanotubes with controllable diameters from 20 to 400 nanometers and lengths from 0.1 to 50 micrometers were obtained. Using this method, large panels of aligned carbon nanotubes can be made under conditions that are suitable for device fabrication.

  18. Detection of Hydrogen Spillover in Palladium-Modified Activated Carbon Fibers During Hydrogen Adsorption

    SciTech Connect (OSTI)

    Contescu, Cristian I; Brown, Craig; Liu, Yun; Bhat, Vinay V; Gallego, Nidia C

    2009-01-01

    Palladium-modified activated carbon fibers (Pd-ACF) are being evaluated for adsorptive hydrogen storage at near-ambient conditions because of their enhanced hydrogen uptake in comparison to Pd-free activated carbon fibers (ACF). The net uptake enhancement (at room temperature and 20 bar) is in excess of the amount corresponding to formation of Pd hydride, and is usually attributed to hydrogen spillover. In this paper, inelastic neutron scattering was used to demonstrate the formation of new C-H bonds in Pd-containing activated carbon fibers after exposure to hydrogen at 20 oC and 1.6 MPa, at the expense of physisorbed H2. This finding is a post-factum proof of the atomic nature of H species formed in presence of a Pd catalyst, and of their subsequent spillover and binding to the carbon support. Chemisorption of hydrogen may explain the reduction in hydrogen uptake from first to second adsorption cycle.

  19. Accelerated life test of the USDOE OC-OTEC experimental system refurbished with magnetic bearings for the 3rd stage vacuum compressor. Final report

    SciTech Connect (OSTI)

    Vega, L.A.

    1997-04-01

    This report documents the accelerated life test (time-to-failure) performed, at the request of DOE, to evaluate the viability of the magnetic bearing system installed in the stage 3 vacuum pump. To this effect the plant was successfully operated for over 500 hours during the period September-November 1996. The first part of this report discusses system performance by deriving subsystem and system performance parameters from a typical record. This is followed by the discussion of the life tests. The instrumentation used to estimate the performance parameters given here is depicted. The third stage pump was operated for 535 hours without incident. It is concluded that magnetic bearings are the preferable choice for the OC-OTEC centrifugal vacuum pumps.

  20. Observation of multiple ionization pathways for OCS in an intense laser field resolved by three-dimensional covariance mapping and visualized by hierarchical ionization topology

    SciTech Connect (OSTI)

    Bryan, W. A.; Newell, W. R.; Sanderson, J. H.; Langley, A. J. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Department of Physics, University of Waterloo, Waterloo, Ontario, N2L 3G1 (Canada); Central Laser Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom)

    2006-11-15

    The two- and three-body Coulomb explosion of carbonyl sulfide (OCS) by 790 nm, 50 fs laser pulses focused to {approx_equal}10{sup 16} W cm{sup -2} has been investigated by the three-dimensional covariance mapping technique. In a triatomic molecule, a single charge state, in this case the trication, has been observed to dissociate into two distinct energy channels. With the aid of a three-dimensional visualization technique to reveal the ionization hierarchy, evidence is presented for the existence of two sets of ionization pathways resulting from these two initial states. While one group of ions can be modeled using a classical enhanced ionization model, the second group, consisting of mainly asymmetric channels, cannot. The results provide clear evidence that an enhanced ionization approach must also be accompanied by an appreciation of the effects of excited ionic states and multielectronic processes.

  1. Comparison of Hydrodynamic Load Predictions Between Engineering Models and Computational Fluid Dynamics for the OC4-DeepCwind Semi-Submersible: Preprint

    SciTech Connect (OSTI)

    Benitz, M. A.; Schmidt, D. P.; Lackner, M. A.; Stewart, G. M.; Jonkman, J.; Robertson, A.

    2014-09-01

    Hydrodynamic loads on the platforms of floating offshore wind turbines are often predicted with computer-aided engineering tools that employ Morison's equation and/or potential-flow theory. This work compares results from one such tool, FAST, NREL's wind turbine computer-aided engineering tool, and the computational fluid dynamics package, OpenFOAM, for the OC4-DeepCwind semi-submersible analyzed in the International Energy Agency Wind Task 30 project. Load predictions from HydroDyn, the offshore hydrodynamics module of FAST, are compared with high-fidelity results from OpenFOAM. HydroDyn uses a combination of Morison's equations and potential flow to predict the hydrodynamic forces on the structure. The implications of the assumptions in HydroDyn are evaluated based on this code-to-code comparison.

  2. Carbon investment funds

    SciTech Connect (OSTI)

    2007-01-15

    The report is a study of the development of funds to invest in the purchase of carbon credits. It takes a look at the growing market for carbon credits, the rise of carbon investment funds, and the current state of carbon investing. Topics covered in the report include: Overview of climate change, greenhouse gases, and the Kyoto Protocols. Analysis of the alternatives for reducing carbon emissions including nitrous oxide reduction, coal mine methane capture and carbon capture and storage; Discussion of the different types of carbon credits; Discussion of the basics of carbon trading; Evaluation of the current status of carbon investing; and Profiles of 37 major carbon investment funds worldwide.

  3. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Nuclear Physics May 26-27, 2011 Ted Barnes DOE Office of Nuclear Physics Yukiko Sekine NERSC Program Manager, DOE Office of Advanced Computational Research Kathy Yelick NERSC Director Richard Gerber NERSC User Services Harvey Wasserman NERSC User Services Last edited: 2016-04-29 11:35:21

  4. Fermilab | About | Organization | Fermilab Organization | Explanation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Symbols Line Organization: sectors, divisions, sections Line Organization Matrix Organization: centers, projects and programs utilizing resources spanning the entire...

  5. Systematic Tuning and Multifunctionalization of Covalent Organic Polymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Enhanced Carbon Capture | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Systematic Tuning and Multifunctionalization of Covalent Organic Polymers for Enhanced Carbon Capture Previous Next List Xiang, Zhonghua; Mercado, Rocio; Huck, Johanna M.; Wang, Hui; Guo, Zhanhu; Wang, Wenchuan; Cao, Dapeng; Haranczyk, Maciej; and Smit, Berend. Systematic Tuning and Multifunctionalization of Covalent Organic Polymers for Enhanced Carbon Capture. J. Amer. Chem.

  6. Nanostructured Electrodes For Organic Bulk Heterojunction Solar Cells:

    Office of Scientific and Technical Information (OSTI)

    Model Study Using Carbon Nanotube Dispersed Polythiophene-fullerene Blend Devices (Journal Article) | SciTech Connect Nanostructured Electrodes For Organic Bulk Heterojunction Solar Cells: Model Study Using Carbon Nanotube Dispersed Polythiophene-fullerene Blend Devices Citation Details In-Document Search Title: Nanostructured Electrodes For Organic Bulk Heterojunction Solar Cells: Model Study Using Carbon Nanotube Dispersed Polythiophene-fullerene Blend Devices We test the feasibility of

  7. Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 4, Organic methods

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    This interim notice covers the following: extractable organic halides in solids, total organic halides, analysis by gas chromatography/Fourier transform-infrared spectroscopy, hexadecane extracts for volatile organic compounds, GC/MS analysis of VOCs, GC/MS analysis of methanol extracts of cryogenic vapor samples, screening of semivolatile organic extracts, GPC cleanup for semivolatiles, sample preparation for GC/MS for semi-VOCs, analysis for pesticides/PCBs by GC with electron capture detection, sample preparation for pesticides/PCBs in water and soil sediment, report preparation, Florisil column cleanup for pesticide/PCBs, silica gel and acid-base partition cleanup of samples for semi-VOCs, concentrate acid wash cleanup, carbon determination in solids using Coulometrics` CO{sub 2} coulometer, determination of total carbon/total organic carbon/total inorganic carbon in radioactive liquids/soils/sludges by hot persulfate method, analysis of solids for carbonates using Coulometrics` Model 5011 coulometer, and soxhlet extraction.

  8. Pre-Combustion Carbon Dioxide Capture by a New Dual Phase Ceramic-Carbonate Membrane Reactor

    SciTech Connect (OSTI)

    Lin, Jerry

    2014-09-30

    This report documents synthesis, characterization and carbon dioxide permeation and separation properties of a new group of ceramic-carbonate dual-phase membranes and results of a laboratory study on their application for water gas shift reaction with carbon dioxide separation. A series of ceramic-carbonate dual phase membranes with various oxygen ionic or mixed ionic and electronic conducting metal oxide materials in disk, tube, symmetric, and asymmetric geometric configurations was developed. These membranes, with the thickness of 10 ?m to 1.5 mm, show CO2 permeance in the range of 0.5-510-7 molm-2s-1Pa-1 in 500-900oC and measured CO2/N2 selectivity of up to 3000. CO2 permeation mechanism and factors that affect CO2 permeation through the dual-phase membranes have been identified. A reliable CO2 permeation model was developed. A robust method was established for the optimization of the microstructures of ceramic-carbonate membranes. The ceramic-carbonate membranes exhibit high stability for high temperature CO2 separations and water gas shift reaction. Water gas shift reaction in the dual-phase membrane reactors was studied by both modeling and experiments. It is found that high temperature syngas water gas shift reaction in tubular ceramic-carbonate dual phase membrane reactor is feasible even without catalyst. The membrane reactor exhibits good CO2 permeation flux, high thermal and chemical stability and high thermal shock resistance. Reaction and separation conditions in the membrane reactor to produce hydrogen of 93% purity and CO2 stream of >95% purity, with 90% CO2 capture have been identified. Integration of the ceramic-carbonate dual-phase membrane reactor with IGCC process for carbon dioxide capture was analyzed. A methodology was developed to identify optimum operation conditions for a membrane tube of given dimensions that would treat coal syngas with targeted performance. The calculation results show that the dual-phase membrane reactor could improve IGCC process efficiency but the cost of the membrane reactor with membranes having current CO2 permeance is high. Further research should be directed towards improving the performance of the membranes and developing cost-effective, scalable methods for fabrication of dual-phase membranes and membrane reactors.

  9. Organic Superconductors

    SciTech Connect (OSTI)

    Charles Mielke

    2009-02-27

    Intense magnetic fields are an essential tool for understanding layered superconductors. Fundamental electronic properties of organic superconductors are revealed in intense (60 tesla) magnetic fields. Properties such as the topology of the Fermi surface and the nature of the superconducting order parameter are revealed. With modest maximum critical temperatures~13K the charge transfer salt organic superconductors prove to be incredibly valuable materials as their electronically clean nature and layered (highly anisotropic) structures yield insights to the high temperature superconductors. Observation of de Haas-van Alphen and Shubnikov-de Haas quantum oscillatory phenomena, magnetic field induced superconductivity and re-entrant superconductivity are some of the physical phenomena observed in the charge transfer organic superconductors. In this talk, I will discuss the nature of organic superconductors and give an overview of the generation of intense magnetic fields; from the 60 tesla millisecond duration to the extreme 1000 tesla microsecond pulsed magnetic fields.

  10. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Advanced Scientific Computing Research An ASCR / NERSC Workshop January 5-6, 2011 Dr. Karen Pao ASCR Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services John Shalf NERSC Advanced Technologies Group Harvey Wasserman NERSC User Services Last edited: 2016-04-29 11:35:22

  11. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee R. Todd Anderson Program Manager, BER Climate and Environmental Sciences Anjuli Barnzai Program Manager, BER Climate and Environmental Sciences Susan Gregurick Program Manager, BER Biological Systems Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services Harvey Wasserman NERSC System Architecture Last edited: 2016-04-29 11:35:21

  12. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Fusion Energy Science August 3-4, 2010 Dr. John Mandrekas Advanced Fusion Simulations; FES HPC Allocations Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services Alice Koniges NERSC Advanced Technologies Harvey Wasserman NERSC User Services Last edited: 2016-04-29 11:35:21

  13. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for High Energy Physics November 12-13, 2009 Amber Boehnlein Division Scientist, Fermi National Accelerator Laboratory, on assignment to DOE Office of HEP. Glen Crawford Program Manager, Research and Technology Division, DOE Office of HEP. Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for Services Richard Gerber NERSC User Services Harvey

  14. Organizing Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organizing Committee Organizing Committee Large Scale Computing and Storage Requirements for Basic Energy Sciences An ASCR / BES / NERSC Workshop February 9-10, 2010 Jim Davenport Program Manager for Theoretical Condensed Material Physics Mark R. Pederson Program Manager for Theoretical and Computational Chemistry Nicholas B. Woodward Program Manager, Geosciences Research Program Yukiko Sekine NERSC Program Manager, ASCR Kathy Yelick NERSC Director Francesca Verdier NERSC Department Head for

  15. Selecting activated carbon for water and wastewater treatability studies

    SciTech Connect (OSTI)

    Zhang, W.; Chang, Q.G.; Liu, W.D.; Li, B.J.; Jiang, W.X.; Fu, L.J.; Ying, W.C.

    2007-10-15

    A series of follow-up investigations were performed to produce data for improving the four-indicator carbon selection method that we developed to identify high-potential activated carbons effective for removing specific organic water pollutants. The carbon's pore structure and surface chemistry are dependent on the raw material and the activation process. Coconut carbons have relatively more small pores than large pores; coal and apricot nutshell/walnut shell fruit carbons have the desirable pore structures for removing adsorbates of all sizes. Chemical activation, excessive activation, and/or thermal reactivation enlarge small pores, resulting in reduced phenol number and higher tannic acid number. Activated carbon's phenol, iodine, methylene blue, and tannic acid numbers are convenient indicators of its surface area and pore volume of pore diameters < 10, 10-15, 15-28, and > 28 angstrom, respectively. The phenol number of a carbon is also a good indicator of its surface acidity of oxygen-containing organic functional groups that affect the adsorptive capacity for aromatic and other small polar organics. The tannic acid number is an indicator of carbon's capacity for large, high-molecular-weight natural organic precursors of disinfection by-products in water treatment. The experimental results for removing nitrobenzene, methyl-tert-butyl ether, 4,4-bisphenol, humic acid, and the organic constituents of a biologically treated coking-plant effluent have demonstrated the effectiveness of this capacity-indicator-based method of carbon selection.

  16. Carbon Capital | Open Energy Information

    Open Energy Info (EERE)

    Capital Jump to: navigation, search Name: Carbon Capital Place: United Kingdom Sector: Carbon Product: Manages a carbon fund specialised in forestry projects References: Carbon...

  17. On carbon footprints and growing energy use

    SciTech Connect (OSTI)

    Oldenburg, C.M.

    2011-06-01

    Could fractional reductions in the carbon footprint of a growing organization lead to a corresponding real reduction in atmospheric CO{sub 2} emissions in the next ten years? Curtis M. Oldenburg, head of the Geologic Carbon Sequestration Program of LBNLs Earth Sciences Division, considers his own organization's carbon footprint and answers this critical question? In addressing the problem of energy-related greenhouse gas (GHG) emissions and climate change, it is essential that we understand which activities are producing GHGs and the scale of emission for each activity, so that reduction efforts can be efficiently targeted. The GHG emissions to the atmosphere of an individual or group are referred to as the carbon footprint. This terminology is entirely appropriate, because 85% of the global marketed energy supply comes from carbon-rich fossil fuel sources whose combustion produces CO{sub 2}, the main GHG causing global climate change. Furthermore, the direct relation between CO2 emissions and fossil fuels as they are used today makes energy consumption a useful proxy for carbon footprint. It would seem to be a simple matter to reduce energy consumption across the board, both individually and collectively, to help reduce our carbon footprints and therefore solve the energyclimate crisis. But just how much can we reduce carbon footprints when broader forces, such as growth in energy use, cause the total footprint to simultaneously expand? In this feature, I present a calculation of the carbon footprint of the Earth Sciences Division (ESD), the division in which I work at Lawrence Berkeley National Laboratory (LBNL), and discuss the potential for reducing this carbon footprint. It will be apparent that in terms of potential future carbon footprint reductions under projections of expected growth, ESD may be thought of as a microcosm of the situation of the world as a whole, in which alternatives to the business-as-usual use of fossil fuels are needed if absolute GHG emission reductions are to be achieved.

  18. STRIPPING OF URANIUM FROM ORGANIC EXTRACTANTS

    DOE Patents [OSTI]

    Crouse, D.J. Jr.

    1962-09-01

    A liquid-liquid extraction method is given for recovering uranium values from uranium-containing solutions. Uranium is removed from a uranium-containing organic solution by contacting said organic solution with an aqueous ammonium carbonate solution substantially saturated in uranium values. A uranium- containing precipitate is thereby formed which is separated from the organic and aqueous phases. Uranium values are recovered from this separated precipitate. (AE C)

  19. Brazil-Pathways to a Low Carbon Economy | Open Energy Information

    Open Energy Info (EERE)

    Pathways to a Low Carbon Economy Jump to: navigation, search Name Pathways to a Low Carbon Economy for Brazil AgencyCompany Organization McKinsey and Company Topics...

  20. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, Ronald Alfred; Lewis, Irwin Charles

    1997-01-01

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (i) an x-ray density of at least 2.00 grams per cubic centimeters, (ii) a closed porosity of no greater than 5%, and (iii) an open porosity of no greater than 47%; and (b) graphite having the following properties: (i) an x-ray density of at least 2.20 grams per cubic centimeters, (ii) a closed porosity of no greater than 5%, and (iii) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counterelectrode.

  1. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1997-10-14

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

  2. Fermilab | About | Organization | Fermilab Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Fermilab Organization Fermilab Org Chart International Relations Office Accelerator Division Accelerator Physics Center CMS Center Core Computing Division ESH&Q FESS Finance Section LBNF Project Far-Site LBNF Project Near-Site LBNF Project Office LBNF Project LCLS-II Project Neutrino Division Office of Communication Office of Integrated Planning and Performance Management Office of Project Support Services Office of the CFO Office of the CIO Office of the CPO PIP-II Project PPD

  3. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B.

    1993-01-01

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  4. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organic Solar Cells | ANSER Center | Argonne-Northwestern National Laboratory Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells

  5. Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Chart Organization Chart Organization Chart Printable PDF Mission Leadership

  6. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  7. Forest Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of carbon is the difference of two large fluxes: photosynthesis and respiration. Carbon fixation by photosynthesis is, to a large extent, a single process with theoretical...

  8. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  9. Autonomous observations of the ocean biological carbon pump

    SciTech Connect (OSTI)

    Bishop, James K.B.

    2009-03-01

    Prediction of the substantial biologically mediated carbon flows in a rapidly changing and acidifying ocean requires model simulations informed by observations of key carbon cycle processes on the appropriate space and time scales. From 2000 to 2004, the National Oceanographic Partnership Program (NOPP) supported the development of the first low-cost fully-autonomous ocean profiling Carbon Explorers that demonstrated that year-round real-time observations of particulate organic carbon (POC) concentration and sedimentation could be achieved in the world's ocean. NOPP also initiated the development of a sensor for particulate inorganic carbon (PIC) suitable for operational deployment across all oceanographic platforms. As a result, PIC profile characterization that once required shipboard sample collection and shipboard or shore based laboratory analysis, is now possible to full ocean depth in real time using a 0.2W sensor operating at 24 Hz. NOPP developments further spawned US DOE support to develop the Carbon Flux Explorer, a free-vehicle capable of following hourly variations of particulate inorganic and organic carbon sedimentation from near surface to kilometer depths for seasons to years and capable of relaying contemporaneous observations via satellite. We have demonstrated the feasibility of real time - low cost carbon observations which are of fundamental value to carbon prediction and when further developed, will lead to a fully enhanced global carbon observatory capable of real time assessment of the ocean carbon sink, a needed constraint for assessment of carbon management policies on a global scale.

  10. Terrestrial Carbon Management Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Terrestrial Carbon Management are organized as Carbon Accumulation with Cropland Management, Carbon Accumulation with Grassland Management, Carbon Loss Following Cultivation, Carbon Accumulation Following Afforestation, and Carbon Sources and Sinks Associated with U.S. Cropland Production.

  11. OC_IC_DIGITAL.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    463-9076 Physical Chemistry Chemical Physics www.rsc.orgpccp Volume 14 | Number 5 | 7 ... RSC Books Defining Chemical Science Content New Series - Coming Soon Polymer Chemistry, ...

  12. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  13. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  14. Synthesis, characterization and properties of carbon nanotubes microspheres from pyrolysis of polypropylene and maleated polypropylene

    SciTech Connect (OSTI)

    Zhang, Junhao; Department of Chemistry, University of Science and Technology of China, Heifei, Anhui 230026 ; Du, Jin; Qian, Yitai; Xiong, Shenglin

    2010-01-15

    Microspheres assembled from carbon nanotubes (MCNTs), with the diameters ranging from 5.5 to 7.5 {mu}m, were synthesized by means of pyrolysis of polypropylene and maleated polypropylene in an autoclave. The characterization of structure and morphology was carried out by X-ray diffractometer (XRD), field-emission scanning electron microscopy (FESEM), (high resolution) transmission electron microscope [(HR)TEM)], selected-area electron diffraction (SAED) and Raman spectrum. As a typical morphology, the possible growth process of MCNTs was also investigated and discussed. The results of nitrogen adsorption-desorption indicate that the Brunauer-Emett-Teller (BET) surface area (140.6 m{sup 2}/g) of the MCNTs obtained at 600 {sup o}C is about twice as that (74.5 m{sup 2}/g) of carbon nanotubes obtained at 700 {sup o}C. The results of catalytic experiment show that MCNTs based catalyst has higher catalytic activity than the carbon nanotubes based catalyst for the preparation of methanol and dimethoxy-ethane by oxidation of dimethyl ether.

  15. Carbon nanotube composite materials

    DOE Patents [OSTI]

    O'Bryan, Gregory; Skinner, Jack L; Vance, Andrew; Yang, Elaine Lai; Zifer, Thomas

    2015-03-24

    A material consisting essentially of a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes dissolved in a solvent. Un-functionalized carbon nanotube concentrations up to 30 wt % and hydroxylated carbon nanotube concentrations up to 40 wt % can be used with even small concentrations of each (less than 2 wt %) useful in producing enhanced conductivity properties of formed thin films.

  16. Carbon Nanotube Based Sensors

    SciTech Connect (OSTI)

    Jiang, Mian; Lin, Yuehe

    2006-11-01

    This review article provides a comprehensive review on sensors and biosensors based on functionalized carbon nanotubes.

  17. Strong and Reversible Binding of Carbon Dioxide in a Green Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strong and Reversible Binding of Carbon Dioxide in a Green Metal-Organic Framework Previous Next List Jeremiah J. Gassensmith, Hiroyasu Furukawa, Ronald A. Smaldone, Ross S....

  18. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  19. CARBON DIOXIDE AS A FEEDSTOCK.

    SciTech Connect (OSTI)

    CREUTZ,C.; FUJITA,E.

    2000-12-09

    This report is an overview on the subject of carbon dioxide as a starting material for organic syntheses of potential commercial interest and the utilization of carbon dioxide as a substrate for fuel production. It draws extensively on literature sources, particularly on the report of a 1999 Workshop on the subject of catalysis in carbon dioxide utilization, but with emphasis on systems of most interest to us. Atmospheric carbon dioxide is an abundant (750 billion tons in atmosphere), but dilute source of carbon (only 0.036 % by volume), so technologies for utilization at the production source are crucial for both sequestration and utilization. Sequestration--such as pumping CO{sub 2} into sea or the earth--is beyond the scope of this report, except where it overlaps utilization, for example in converting CO{sub 2} to polymers. But sequestration dominates current thinking on short term solutions to global warming, as should be clear from reports from this and other workshops. The 3500 million tons estimated to be added to the atmosphere annually at present can be compared to the 110 million tons used to produce chemicals, chiefly urea (75 million tons), salicylic acid, cyclic carbonates and polycarbonates. Increased utilization of CO{sub 2} as a starting material is, however, highly desirable, because it is an inexpensive, non-toxic starting material. There are ongoing efforts to replace phosgene as a starting material. Creation of new materials and markets for them will increase this utilization, producing an increasingly positive, albeit small impact on global CO{sub 2} levels. The other uses of interest are utilization as a solvent and for fuel production and these will be discussed in turn.

  20. Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material

    SciTech Connect (OSTI)

    Meng, Yujie; Yang, Timothy M; Peizhi, Liu; Contescu, Cristian I; Biao, Huang; Siqun, Wang

    2015-01-01

    The synthesis of a sponge-like carbon aerogel from microfibril cellulose (MFC), with high porosity (99%), ultra-low density (0.01 g/cm3), hydrophobic properties (149 static contact angle) and reusability is reported in this paper. The physical properties, internal morphology, thermal properties, and chemical properties of carbon aerogels heat-treated at 700 and 900 oC (Samples C-700 and C-900) were examined. Stabilization and carbonization parameters were optimized in terms of residual carbon yield. The BET surface area of Sample C-700 (521 m2 /g) was significantly higher than of Sample C-950 (149 m2 /g). Graphitic-like domains were observed in C-950. The highest normalized sorption capacity (86 g/g) for paraffin oil was observed in sample C-700. The removal of hydrophilic function groups during carbonization causes carbon aerogel to present highly hydrophobic properties. Carbon aerogel s ability to absorb oil is enhanced by its highly porous 3D network structure with interconnected cellulose nanofibrils.

  1. Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Yujie; Yang, Timothy M; Peizhi, Liu; Contescu, Cristian I; Biao, Huang; Siqun, Wang

    2015-01-01

    The synthesis of a sponge-like carbon aerogel from microfibril cellulose (MFC), with high porosity (99%), ultra-low density (0.01 g/cm3), hydrophobic properties (149 static contact angle) and reusability is reported in this paper. The physical properties, internal morphology, thermal properties, and chemical properties of carbon aerogels heat-treated at 700 and 900 oC (Samples C-700 and C-900) were examined. Stabilization and carbonization parameters were optimized in terms of residual carbon yield. The BET surface area of Sample C-700 (521 m2 /g) was significantly higher than of Sample C-950 (149 m2 /g). Graphitic-like domains were observed in C-950. The highest normalized sorption capacitymore » (86 g/g) for paraffin oil was observed in sample C-700. The removal of hydrophilic function groups during carbonization causes carbon aerogel to present highly hydrophobic properties. Carbon aerogel s ability to absorb oil is enhanced by its highly porous 3D network structure with interconnected cellulose nanofibrils.« less

  2. Method for catalytic destruction of organic materials

    DOE Patents [OSTI]

    Sealock, L.J. Jr.; Baker, E.G.; Elliott, D.C.

    1997-05-20

    A method is disclosed for converting waste organic materials into an innocuous product gas. The method comprises maintaining, in a pressure vessel, in the absence of oxygen, at a temperature of 250 to 500 C and a pressure of at least 50 atmospheres, a fluid organic waste material, water, and a catalyst consisting essentially of reduced nickel in an amount sufficient to catalyze a reaction of the organic waste material to produce an innocuous product gas composed primarily of methane and carbon dioxide. The methane in the product gas may be burned to preheat the organic materials. 7 figs.

  3. Method for catalytic destruction of organic materials

    DOE Patents [OSTI]

    Sealock, Jr., L. John; Baker, Eddie G.; Elliott, Douglas C.

    1997-01-01

    A method is disclosed for converting waste organic materials into an innocuous product gas. The method comprises maintaining, in a pressure vessel, in the absence of oxygen, at a temperature of 250.degree. C. to 500.degree. C. and a pressure of at least 50 atmospheres, a fluid organic waste material, water, and a catalyst consisting essentially of reduced nickel in an amount sufficient to catalyze a reaction of the organic waste material to produce an innocuous product gas composed primarily of methane and carbon dioxide. The methane in the product gas may be burned to preheat the organic materials.

  4. Carbon dioxide capture-related gas adsorption and separation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks Previous Next List Jian-Rong Li, Yuguang Ma, M. Colin McCarthy, Julian Sculley, Jiamei Yu,...

  5. Energy Use and Carbon Emissions: Non-OECD Countries

    Reports and Publications (EIA)

    1994-01-01

    Presents world energy use and carbon emissions patterns, with particular emphasis on the non-OECD (Organization for Economic Cooperation and Development) countries (including the current and former centrally planned economies).

  6. Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalize...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalized Metal-Organic Frameworks Previous Next List D. Wu, T. M. McDonald, Z. Quan, S. V. Ushakov, P. Zhang, J. R....

  7. Method of making molten carbonate fuel cell ceramic matrix tape

    DOE Patents [OSTI]

    Maricle, Donald L.; Putnam, Gary C.; Stewart, Jr., Robert C.

    1984-10-23

    A method of making a thin, flexible, pliable matrix material for a molten carbonate fuel cell is described. The method comprises admixing particles inert in the molten carbonate environment with an organic polymer binder and ceramic particle. The composition is applied to a mold surface and dried, and the formed compliant matrix material removed.

  8. Carbon aerogels: An update on structure, properties, and applications

    SciTech Connect (OSTI)

    Pekala, R.W.; Mayer, S.T.; Kaschmitter, J.L.; Kong, F.M.

    1993-07-01

    Aerogels are unique porous materials whose composition, structure, and properties can be controlled at the nanometer scale. This paper examines the synthesis of organic aerogels and their carbonized derivatives. Carbon aerogels have low electrical resistivity, high surface area, and a tunable pore size. These materials are finding applications as electrodes in double layer capacitors.

  9. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F.

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  10. Acid sorption regeneration process using carbon dioxide

    DOE Patents [OSTI]

    King, C. Judson; Husson, Scott M.

    2001-01-01

    Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent in the presence of carbon dioxide under pressure. The acids are freed from the sorbent phase by a suitable regeneration method, one of which is treating them with an organic alkylamine solution thus forming an alkylamine-carboxylic acid complex which thermally decomposes to the desired carboxylic acid and the alkylamine.

  11. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou; Crespi, Vincent Henry; Louie, Steven Gwon Sheng; Zettl, Alexander Karlwalter

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  12. Modified electrochemical properties of organic quinoxaline via electrolyte

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interactions in propylene carbonate - Joint Center for Energy Storage Research 4, 2015, Research Highlights Modified electrochemical properties of organic quinoxaline via electrolyte interactions in propylene carbonate Theoretical gravimetric capacity of quinoxaline : 410 mAh/g Solubility > 5M in carbonate solvents Scientific Achievement Quinoxalines are highly sensitive to solvent and electrolyte interactions. For example, bare quinoxaline is active in acetonitrile at DFT-predicted

  13. Carbon Film Electrodes For Super Capacitor Applications

    DOE Patents [OSTI]

    Tan, Ming X.

    1999-07-20

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

  14. Metal-Organic Frameworks as Adsorbents for Hydrogen Purification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal-Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture Previous Next List Z. R. Herm, J. A. Swisher, B. Smit, R. Krishna, and J....

  15. Carbon Jungle | Open Energy Information

    Open Energy Info (EERE)

    Jungle Jump to: navigation, search Name: Carbon Jungle Place: El Segundo, California Zip: 90246 Sector: Carbon Product: Carbon Jungle's mission is to decrease CO2 in the atmosphere...

  16. Carbon Connections | Open Energy Information

    Open Energy Info (EERE)

    Connections Jump to: navigation, search Name: Carbon Connections Place: Norfolk, England, United Kingdom Zip: NR4 7TJ Sector: Carbon Product: Carbon Connections links partner...

  17. Asset Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search Name: Asset Carbon Place: United Kingdom Product: UK-based startup looking to invest in CDMJI projects. References: Asset Carbon1 This article...

  18. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About Us » Organization Organization Organization Download Printable PDF PDF icon Organization Chart - Dated: 07/12/2015 Key Resources PMCDP EVMS PARS IIe FPD Resource Center PM Newsletter Forms and Templates Leadership Organization History Contact Us

  19. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B.

    1991-01-01

    A process for making a carbon-carbon composite having a combination of high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizable woven cloth are covered with petroleum or coal tar pitch and pressed at a temperature a few degrees above the softening point of the pitch to form a green laminated composite. The green composite is restrained in a suitable fixture and heated slowly to carbonize the pitch binder. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnation step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3000.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. to 1300.degree. C. at a reduced pressure for approximately one hundred and fifty (150) hours.

  20. Carbon Emissions: Food Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  1. Carbon nanotube nanoelectrode arrays

    DOE Patents [OSTI]

    Ren, Zhifeng; Lin, Yuehe; Yantasee, Wassana; Liu, Guodong; Lu, Fang; Tu, Yi

    2008-11-18

    The present invention relates to microelectode arrays (MEAs), and more particularly to carbon nanotube nanoelectrode arrays (CNT-NEAs) for chemical and biological sensing, and methods of use. A nanoelectrode array includes a carbon nanotube material comprising an array of substantially linear carbon nanotubes each having a proximal end and a distal end, the proximal end of the carbon nanotubes are attached to a catalyst substrate material so as to form the array with a pre-determined site density, wherein the carbon nanotubes are aligned with respect to one another within the array; an electrically insulating layer on the surface of the carbon nanotube material, whereby the distal end of the carbon nanotubes extend beyond the electrically insulating layer; a second adhesive electrically insulating layer on the surface of the electrically insulating layer, whereby the distal end of the carbon nanotubes extend beyond the second adhesive electrically insulating layer; and a metal wire attached to the catalyst substrate material.

  2. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Bearing Trace Gases A critical scientific and policy oriented question is what are the present day sources and sinks of carbon dioxide (CO2) in the natural environment and...

  3. Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage

    SciTech Connect (OSTI)

    Contescu, Cristian I; van Benthem, Klaus; Li, Sa; Bonifacio, Cecile S; Pennycook, Stephen J; Jena, Puru; Gallego, Nidia C

    2011-01-01

    Palladium-modified activated carbon fibers (Pd-ACF) were synthesized by meltspinning, carbonization and activation of an isotropic pitch carbon precursor premixed with an organometallic Pd compound. The hydrogen uptake at 25 oC and 20 bar on Pd- ACF exceeded the expected capacity based solely on Pd hydride formation and hydrogen physisorption on the microporous carbon support. Aberration-corrected scanning transmission electron microscopy (STEM) with sub- ngstrom spatial resolution provided unambiguous identification of isolated Pd atoms occurring in the carbon matrix that coexist with larger Pd particles. First principles calculations revealed that each single Pd atom can form Kubas-type complexes by binding up to three H2 molecules in the pressure range of adsorption measurements. Based on Pd atom concentration determined from STEM images, the contribution of various mechanisms to the excess hydrogen uptake measured experimentally was evaluated. With consideration of Kubas binding as a viable mechanism (along with hydride formation and physisorption to carbon support) the role of hydrogen spillover in this system may be smaller than previously thought.

  4. Doping of carbon foams for use in energy storage devices

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Morrison, R.L.; Kaschmitter, J.L.

    1994-10-25

    A polymeric foam precursor, wetted with phosphoric acid, is pyrolyzed in an inert atmosphere to produce an open-cell doped carbon foam, which is utilized as a lithium intercalation anode in a secondary, organic electrolyte battery. Tests were conducted in a cell containing an organic electrolyte and using lithium metal counter and reference electrodes, with the anode located there between. Results after charge and discharge cycling, for a total of 6 cycles, indicated a substantial increase in the energy storage capability of the phosphorus doped carbon foam relative to the undoped carbon foam, when used as a rechargeable lithium ion battery. 3 figs.

  5. Doping of carbon foams for use in energy storage devices

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Morrison, Robert L. (Modesto, CA); Kaschmitter, James L. (Pleasanton, CA)

    1994-01-01

    A polymeric foam precursor, wetted with phosphoric acid, is pyrolyzed in an inert atmosphere to produce an open-cell doped carbon foam, which is utilized as a lithium intercalation anode in a secondary, organic electrolyte battery. Tests were conducted in a cell containing an organic electrolyte and using lithium metal counter and reference electrodes, with the anode located therebetween. Results after charge and discharge cycling, for a total of 6 cycles, indicated a substantial increase in the energy storage capability of the phosphorus doped carbon foam relative to the undoped carbon foam, when used as a rechargeable lithium ion battery.

  6. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  7. Carbon Sequestration.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concepts Current Sequestration Methods Novel Concepts * Glacial Storage * Biogenic Methane * Mineralization * Waste Streams Recycling * Calcium Carbonate Hydrates Glacial...

  8. Carbon Storage Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Illinois | Department of Energy Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois November 19, 2012 - 12:00pm Addthis Washington, DC - A project important to demonstrating the commercial viability of carbon capture, utilization and storage (CCUS) technology has completed the first year of injecting carbon dioxide (CO2) from an industrial plant at a large-scale test site in

  9. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  10. Nanocomposite fibers and film containing polyolefin and surface-modified carbon nanotubes

    DOE Patents [OSTI]

    Chu,Benjamin (Setauket, NY); Hsiao, Benjamin S. (Setauket, NY)

    2010-01-26

    Methods for modifying carbon nanotubes with organic compounds are disclosed. The modified carbon nanotubes have enhanced compatibility with polyolefins. Nanocomposites of the organo-modified carbon nanotubes and polyolefins can be used to produce both fibers and films having enhanced mechanical and electrical properties, especially the elongation-to-break ratio and the toughness of the fibers and/or films.

  11. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  12. How Carbon Capture Works

    Broader source: Energy.gov [DOE]

    Carbon capture, utilization and storage is a process that captures carbon dioxide emissions from sources like coal-fired power plants and either reuses or stores it so it will not enter the atmosphere. We'll break down the process step by step so you can learn how this technology can help us lower our carbon pollution.

  13. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  14. Tailoring the properties of organic aerogels

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    We have recently succeeded in producing a new class of organic (or carbon) aerogels whose electrical, mechanical, and other properties are superior to those of the metal alkoxides. By tailoring properties to specific applications, we hope to achieve aerogels with even better performance. We have already tested carbon aerogels for use in inertial-confinement fusion targets and are currently studying applications to other technologies, such as battery electrodes, catalyst supports, and gas filters. In several of these applications, the permeability of the carbon aerogels-that is, their resistance to fluid flow-is crucial to their performance. Here, we describe briefly the synthesis of organic aerogels and present the results of our permeability studies.

  15. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  16. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biosecurity, and Health Environmental Microbiology Soil metagenomics and carbon cycling Soil metagenomics and carbon cycling Establishing a foundational understanding...

  17. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  18. Organization Chart - Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LSD Logo About Us People & Organization Research News & Events Safety Internal Resources Organization Chart Departments Scientific Staff Directory Committees Organization Chart...

  19. Method and reaction pathway for selectively oxidizing organic compounds

    DOE Patents [OSTI]

    Camaioni, Donald M.; Lilga, Michael A.

    1998-01-01

    A method of selectively oxidizing an organic compound in a single vessel comprises: a) combining an organic compound, an acid solution in which the organic compound is soluble, a compound containing two oxygen atoms bonded to one another, and a metal ion reducing agent capable of reducing one of such oxygen atoms, and thereby forming a mixture; b) reducing the compound containing the two oxygen atoms by reducing one of such oxygen atoms with the metal ion reducing agent to, 1) oxidize the metal ion reducing agent to a higher valence state, and 2) produce an oxygen containing intermediate capable of oxidizing the organic compound; c) reacting the oxygen containing intermediate with the organic compound to oxidize the organic compound into an oxidized organic intermediate, the oxidized organic intermediate having an oxidized carbon atom; d) reacting the oxidized organic intermediate with the acid counter ion and higher valence state metal ion to bond the acid counter ion to the oxidized carbon atom and thereby produce a quantity of an ester incorporating the organic intermediate and acid counter ion; and e) reacting the oxidized organic intermediate with the higher valence state metal ion and water to produce a quantity of alcohol which is less than the quantity of ester, the acid counter ion incorporated in the ester rendering the carbon atom bonded to the counter ion less reactive with the oxygen containing intermediate in the mixture than is the alcohol with the oxygen containing intermediate.

  20. The Path of Carbon in Photosynthesis XIV.

    DOE R&D Accomplishments [OSTI]

    Calvin, Melvin; Bassham, J. A.; Benson, A. A.; Kawaguchi, S.; Lynch, V. H.; Stepka, W.; Tolbert, N. E.

    1951-06-30

    It seems hardly necessary to repeat to an audience of this kind the importance of the process known as photosynthesis in the interaction and the interdependence of organisms and in the very existence of life as we know it. This process by which green plants are able to capture electromagnetic energy in the form of sunlight and transform it into stored chemical energy in the form of a wide variety of reduced (relative to carbon dioxide) carbon compounds provides the only major source of energy for the maintenance and propagation of all life.

  1. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, H.L.; Filardo, G.

    1990-10-23

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70 C and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution. 1 fig.

  2. Supercritical separation process for complex organic mixtures

    DOE Patents [OSTI]

    Chum, Helena L.; Filardo, Giuseppe

    1990-01-01

    A process is disclosed for separating low molecular weight components from complex aqueous organic mixtures. The process includes preparing a separation solution of supercritical carbon dioxide with an effective amount of an entrainer to modify the solvation power of the supercritical carbon dioxide and extract preselected low molecular weight components. The separation solution is maintained at a temperature of at least about 70.degree. C. and a pressure of at least about 1,500 psi. The separation solution is then contacted with the organic mixtures while maintaining the temperature and pressure as above until the mixtures and solution reach equilibrium to extract the preselected low molecular weight components from the organic mixtures. Finally, the entrainer/extracted components portion of the equilibrium mixture is isolated from the separation solution.

  3. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  4. Investigation of vertical distribution and morphology of indigenous organic matter Sleeping Bear site, Michigan

    SciTech Connect (OSTI)

    West, C.C.; Lyon, W.G.; Ross, D.L.

    1994-11-01

    This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluable organic matter content (that is, humin) as function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes. 56 refs., 9 figs., 2 tabs.

  5. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Wang, Xiqing (Oak Ridge, TN)

    2012-02-14

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  6. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  7. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applications

    SciTech Connect (OSTI)

    Zhang, Pengfei; Qiao, Zhenan; Dai, Sheng

    2015-04-02

    Carbon-based materials are the most popular material types in both fundamental research and industrial applications, partly because of their well-controlled nano-morphologies. In the past two decades, we have witnessed a number of breakthroughs in carbon research: fullerenes, carbon nanotubes, and more recently graphene. Nowadays, carbon nanospheres are attracting more and more attention worldwide due to their excellent performance in various fields: drug delivery, heterogeneous catalysis, encapsulation of support and electrode materials. Actually, spherical carbon is an old material, whereas controlling carbon spheres in the nanometer range is a recent story. In the past 5 years, it has become possible to precisely control the particle size, surface area, pore size, chemical composition, and dispersity of carbon nanospheres. Toward this end, a number of synthetic strategies are emerging, such as hydrothermal carbonization of biomass-based resources, extended Stöber synthesis, and organic–organic self-assembly via different binding methods. In this feature article, we summarize recent routes for carbon nanospheres and briefly touch on their applications to shed light on the potential of this field. Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications of carbon nanostructures in the near future.

  8. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Pengfei; Qiao, Zhenan; Dai, Sheng

    2015-04-02

    Carbon-based materials are the most popular material types in both fundamental research and industrial applications, partly because of their well-controlled nano-morphologies. In the past two decades, we have witnessed a number of breakthroughs in carbon research: fullerenes, carbon nanotubes, and more recently graphene. Nowadays, carbon nanospheres are attracting more and more attention worldwide due to their excellent performance in various fields: drug delivery, heterogeneous catalysis, encapsulation of support and electrode materials. Actually, spherical carbon is an old material, whereas controlling carbon spheres in the nanometer range is a recent story. In the past 5 years, it has become possible tomore » precisely control the particle size, surface area, pore size, chemical composition, and dispersity of carbon nanospheres. Toward this end, a number of synthetic strategies are emerging, such as hydrothermal carbonization of biomass-based resources, extended Stöber synthesis, and organic–organic self-assembly via different binding methods. In this feature article, we summarize recent routes for carbon nanospheres and briefly touch on their applications to shed light on the potential of this field. Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications of carbon nanostructures in the near future.« less

  9. Carbon Dioxide Utilization Summit

    Broader source: Energy.gov [DOE]

    The 6th Carbon Dioxide Utilization Summit will be held in Newark, New Jersey, from Feb. 24–26, 2016. The conference will look at the benefits and challenges of carbon dioxide utilization. Advanced Algal Systems Program Manager Alison Goss Eng and Technology Manager Devinn Lambert will be in attendance. Dr. Goss Eng will be chairing a round table on Fuels and Chemicals during the Carbon Dioxide Utilization: From R&D to Commercialization discussion session.

  10. Activated Carbon Injection

    SciTech Connect (OSTI)

    2014-07-16

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  11. Reinforced Carbon Nanotubes.

    DOE Patents [OSTI]

    Ren, Zhifen; Wen, Jian Guo; Lao, Jing Y.; Li, Wenzhi

    2005-06-28

    The present invention relates generally to reinforced carbon nanotubes, and more particularly to reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

  12. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  13. SOUTHWEST REGIONAL PARTNERSHIP ON CARBON SEQUESTRATION

    SciTech Connect (OSTI)

    Brian McPherson; Rick Allis; Barry Biediger; Joel Brown; Jim Cappa; George Guthrie; Richard Hughes; Eugene Kim; Robert Lee; Dennis Leppin; Charles Mankin; Orman Paananen; Rajesh Pawar; Tarla Peterson; Steve Rauzi; Jerry Stuth; Genevieve Young

    2004-11-01

    The Southwest Partnership Region includes six whole states, including Arizona, Colorado, Kansas, New Mexico, Oklahoma, and Utah, roughly one-third of Texas, and significant portions of adjacent states. The Partnership comprises a large, diverse group of expert organizations and individuals specializing in carbon sequestration science and engineering, as well as public policy and outreach. The main objective of the Southwest Partnership project is to achieve an 18% reduction in carbon intensity by 2012. The Partnership made great progress in this first year. Action plans for possible Phase II carbon sequestration pilot tests in the region are almost finished, including both technical and non-technical aspects necessary for developing and carrying out these pilot tests. All partners in the Partnership are taking an active role in evaluating and ranking optimum sites and technologies for capture and storage of CO{sub 2} in the Southwest Region. We are identifying potential gaps in all aspects of potential sequestration deployment issues.

  14. Significance of Isotopically Labile Organic Hydrogen in Thermal Maturation of Organic Matter

    SciTech Connect (OSTI)

    Arndt Schimmelmann; Maria Mastalerz

    2010-03-30

    Isotopically labile organic hydrogen in fossil fuels occupies chemical positions that participate in isotopic exchange and in chemical reactions during thermal maturation from kerogen to bitumen, oil and gas. Carbon-bound organic hydrogen is isotopically far less exchangeable than hydrogen bound to nitrogen, oxygen, or sulfur. We explore why organic hydrogen isotope ratios express a relationship with organic nitrogen isotope ratios in kerogen at low to moderate maturity. We develop and apply new techniques to utilize organic D/H ratios in organic matter fractions and on a molecular level as tools for exploration for fossil fuels and for paleoenvironmental research. The scope of our samples includes naturally and artificially matured substrates, such as coal, shale, oil and gas.

  15. Challenges for improving estimates of soil organic carbon stored...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    determined, and research efforts that will reduce this discrepancy were identified. Five research challenges for improving empirical assessments of the distribution and potential...

  16. Metal Organic Clathrates for Carbon Dioxide Removal - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials when exposed to an applied potential, light or a magnetic field. Technology Marketing Summary Researchers at Pacific Northwest National Laboratory have developed a...

  17. A versatile metal-organic framework for carbon dioxide capture...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exhibits selective adsorption of CO2 over CH4 and excellent catalytic activity in a tandem one-pot deacetalization-Knoevenagel condensation reaction as a cooperative catalyst....

  18. Influences of Organic Carbon Supply Rate on Uranium Bioreduction...

    Office of Scientific and Technical Information (OSTI)

    provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of this document is also available for sale to...

  19. Worldwide organic soil carbon and nitrogen data (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    A paper copy of this document is also available for sale to the public from the National ... Variation in these values is due to differences in local and geographic soil-forming ...

  20. Organic fuel cells and fuel cell conducting sheets

    DOE Patents [OSTI]

    Masel, Richard I.; Ha, Su; Adams, Brian

    2007-10-16

    A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

  1. Ordered organic-organic multilayer growth

    DOE Patents [OSTI]

    Forrest, Stephen R.; Lunt, Richard R.

    2016-04-05

    An ordered multilayer crystalline organic thin film structure is formed by depositing at least two layers of thin film crystalline organic materials successively wherein the at least two thin film layers are selected to have their surface energies within .+-.50% of each other, and preferably within .+-.15% of each other, whereby every thin film layer within the multilayer crystalline organic thin film structure exhibit a quasi-epitaxial relationship with the adjacent crystalline organic thin film.

  2. Ordered organic-organic multilayer growth

    DOE Patents [OSTI]

    Forrest, Stephen R; Lunt, Richard R

    2015-01-13

    An ordered multilayer crystalline organic thin film structure is formed by depositing at least two layers of thin film crystalline organic materials successively wherein the at least two thin film layers are selected to have their surface energies within .+-.50% of each other, and preferably within .+-.15% of each other, whereby every thin film layer within the multilayer crystalline organic thin film structure exhibit a quasi-epitaxial relationship with the adjacent crystalline organic thin film.

  3. Carbon-Based and Carbon-Supported Heterogeneous Catalysts for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon-Based and Carbon-Supported Heterogeneous Catalysts for the Conversion of Biomass Carbon-based heterogeneous catalysts play a central role in the conversion of biomass to...

  4. Renaissance Carbon Investment Ltd | Open Energy Information

    Open Energy Info (EERE)

    Carbon Investment Ltd Jump to: navigation, search Name: Renaissance Carbon Investment Ltd. Place: Shanghai, China Zip: 200052 Sector: Carbon Product: Renaissance Carbon Investment...

  5. Boston Carbon Corp | Open Energy Information

    Open Energy Info (EERE)

    Carbon Corp Jump to: navigation, search Name: Boston Carbon Corp Place: Carlisle, Massachusetts Zip: 1741 Sector: Carbon Product: Boston Carbon Corporation helps develop clean...

  6. Edgewood Carbon Holdings LLC | Open Energy Information

    Open Energy Info (EERE)

    Edgewood Carbon Holdings LLC Jump to: navigation, search Name: Edgewood Carbon Holdings LLC Place: Cornwall, Vermont Zip: 57530 Sector: Carbon Product: Edgewood Carbon Holdings LLC...

  7. Eon Masdar Integrated Carbon | Open Energy Information

    Open Energy Info (EERE)

    Eon Masdar Integrated Carbon Jump to: navigation, search Name: Eon Masdar Integrated Carbon Place: Germany Sector: Carbon Product: Germany-based carbon emission projects developer....

  8. Using Renewable Energy Purchases to Achieve Institutional Carbon Goals: A Review of Current Practices and Considerations

    SciTech Connect (OSTI)

    Bird, L.; Sumner, J.

    2011-01-01

    With organizations and individuals increasingly interested in accounting for their carbon emissions, greater attention is being placed on how to account for the benefits of various carbon mitigation actions available to consumers and businesses. Generally, organizations can address their own carbon emissions through energy efficiency, fuel switching, on-site renewable energy systems, renewable energy purchased from utilities or in the form of renewable energy certificates (RECs), and carbon offsets. This paper explores the role of green power and carbon offsets in carbon footprinting and the distinctions between the two products. It reviews how leading greenhouse gas (GHG) reporting programs treat green power purchases and discusses key issues regarding how to account for the carbon benefits of renewable energy. It also discusses potential double counting if renewable energy generation is used in multiple markets.

  9. Using Renewable Energy Purchases to Achieve Institutional Carbon Goals. A Review of Current Practices and Considerations

    SciTech Connect (OSTI)

    Bird, Lori; Sumner, Jenny

    2011-01-01

    With organizations and individuals increasingly interested in accounting for their carbon emissions, greater attention is being placed on how to account for the benefits of various carbon mitigation actions available to consumers and businesses. Generally, organizations can address their own carbon emissions through energy efficiency, fuel switching, on-site renewable energy systems, renewable energy purchased from utilities or in the form of renewable energy certificates (RECs), and carbon offsets. This paper explores the role of green power and carbon offsets in carbon footprinting and the distinctions between the two products. It reviews how leading greenhouse gas (GHG) reporting programs treat green power purchases and discusses key issues regarding how to account for the carbon benefits of renewable energy. It also discusses potential double counting if renewable energy generation is used in multiple markets.

  10. Using Renewable Energy Purchases to Achieve Institutional Carbon Goals. A Review of Current Practices and Considerations.

    SciTech Connect (OSTI)

    Bird, Lori; Sumner, Jenny

    2011-01-01

    With organizations and individuals increasingly interested in accounting for their carbon emissions, greater attention is being placed on how to account for the benefits of various carbon mitigation actions available to consumers and businesses. Generally, organizations can address their own carbon emissions through energy efficiency, fuel switching, on-site renewable energy systems, renewable energy purchased from utilities or in the form of renewable energy certificates (RECs), and carbon offsets. This paper explores the role of green power and carbon offsets in carbon "footprinting" and the distinctions between the two products. It reviews how leading greenhouse gas (GHG) reporting programs treat green power purchases and discusses key issues regarding how to account for the carbon benefits of renewable energy. It also discusses potential double counting if renewable energy generation is used in multiple markets.

  11. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-30

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop (see attached agenda). The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed in the second quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO2 concentrations. While no key deliverables were due during the third quarter, progress on other deliverables is noted in the PowerPoint presentations and in this report. A series of meetings held during the second and third quarters have laid the foundations for assessing the issues surrounding carbon sequestration in this region, the need for a holistic approach to meeting energy demands and economic development potential, and the implementation of government programs or a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. A third Partnership meeting has been planned for August 04 in Idaho Falls; a preliminary agenda is attached.

  12. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E.; Moses, William W.

    1991-01-01

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  13. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  14. Long-term soil warming and Carbon Cycle Feedbacks to the Climate System

    SciTech Connect (OSTI)

    Melillo, Jerry M.

    2014-04-30

    The primary objective of the proposed research was to quantify and explain the effects of a sustained in situ 5oC soil temperature increase on net carbon (C) storage in a northeastern deciduous forest ecosystem. The research was done at an established soil warming experiment at the Harvard Forest in central Massachusetts – Barre Woods site established in 2001. In the field, a series of plant and soil measurements were made to quantify changes in C storage in the ecosystem and to provide insights into the possible relationships between C-storage changes and nitrogen (N) cycling changes in the warmed plots. Field measurements included: 1) annual woody increment; 2) litterfall; 3) carbon dioxide (CO2) efflux from the soil surface; 4) root biomass and respiration; 5) microbial biomass; and 6) net N mineralization and net nitrification rates. This research was designed to increase our understanding of how global warming will affect the capacity of temperate forest ecosystems to store C. The work explored how soil warming changes the interactions between the C and N cycles, and how these changes affect land-atmosphere feedbacks. This core research question framed the project – What are the effects of a sustained in situ 5oC soil temperature increase on net carbon (C) storage in a northeastern deciduous forest ecosystem? A second critical question was addressed in this research – What are the effects of a sustained in situ 5{degrees}C soil temperature increase on nitrogen (N) cycling in a northeastern deciduous forest ecosystem?

  15. Carbon Nanotube Nanocomposites, Methods of Making Carbon Nanotube...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    By combining aligned carbon nanotubes with metal oxides, this technology has higher energy density than technologies based solely on carbon nanotubes, while having higher power ...

  16. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title...

  17. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of...

  18. carbon | OpenEI Community

    Open Energy Info (EERE)

    carbon Home Graham7781's picture Submitted by Graham7781(2017) Super contributor 9 January, 2014 - 13:12 Suburbs offset Low Carbon Footprint of major U.S. Cities carbon cities CO2...

  19. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan Capalbo

    2005-12-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I are organized into four areas: (1) Evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; (2) Development of GIS-based reporting framework that links with national networks; (3) Design of an integrated suite of monitoring, measuring, and verification technologies, market-based opportunities for carbon management, and an economic/risk assessment framework; (referred to below as the Advanced Concepts component of the Phase I efforts) and (4) Initiation of a comprehensive education and outreach program. As a result of the Phase I activities, the groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that complements the ongoing DOE research agenda in Carbon Sequestration. The geology of the Big Sky Carbon Sequestration Partnership Region is favorable for the potential sequestration of enormous volume of CO{sub 2}. The United States Geological Survey (USGS 1995) identified 10 geologic provinces and 111 plays in the region. These provinces and plays include both sedimentary rock types characteristic of oil, gas, and coal productions as well as large areas of mafic volcanic rocks. Of the 10 provinces and 111 plays, 1 province and 4 plays are located within Idaho. The remaining 9 provinces and 107 plays are dominated by sedimentary rocks and located in the states of Montana and Wyoming. The potential sequestration capacity of the 9 sedimentary provinces within the region ranges from 25,000 to almost 900,000 million metric tons of CO{sub 2}. Overall every sedimentary formation investigated has significant potential to sequester large amounts of CO{sub 2}. Simulations conducted to evaluate mineral trapping potential of mafic volcanic rock formations located in the Idaho province suggest that supercritical CO{sub 2} is converted to solid carbonate mineral within a few hundred years and permanently entombs the carbon. Although MMV for this rock type may be challenging, a carefully chosen combination of geophysical and geochemical techniques should allow assessment of the fate of CO{sub 2} in deep basalt hosted aquifers. Terrestrial carbon sequestration relies on land management practices and technologies to remove atmospheric CO{sub 2} where it is stored in trees, plants, and soil. This indirect sequestration can be implemented today and is on the front line of voluntary, market-based approaches to reduce CO{sub 2} emissions. Initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil Carbon (C) on rangelands, and forested, agricultural, and reclaimed lands. Rangelands can store up to an additional 0.05 mt C/ha/yr, while the croplands are on average four times that amount. Estimates of technical potential for soil sequestration within the region in cropland are in the range of 2.0 M mt C/yr over 20 year time horizon. This is equivalent to approximately 7.0 M mt CO{sub 2}e/yr. The forestry sinks are well documented, and the potential in the Big Sky region ranges from 9-15 M mt CO{sub 2} equivalent per year. Value-added benefits include enhanced yields, reduced erosion, and increased wildlife habitat. Thus the terrestrial sinks provide a viable, environmentally beneficial, and relatively low cost sink that is available to sequester C in the current time frame. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological and terrestrial sequestration reflect this concern. Research in Phase I has identified and validated best management practices for soil C in the Partnership region, and outlined a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. This is the basis for the integrative analysis that will be undertaken in Phase II to work with industry, state and local governments and with the pilot demonstration projects to quantify the economic costs and risks associated with all opportunities for carbon storage in the Big Sky region. Scientifically sound MMV is critical for public acceptance of these technologies.

  20. Carbone Lorraine | Open Energy Information

    Open Energy Info (EERE)

    Carbone Lorraine Jump to: navigation, search Name: Carbone Lorraine Place: France Product: Paris-based company developing industrial applications and systems for the optimal...

  1. Fossil Energy Research Benefits Carbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    has become a world leader in carbon capture and storage (CCS) science and technology. ... and storing in geologic formations carbon dioxide (CO 2 ) from industrial or power plants. ...

  2. Carbon Capture Research and Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Lawrence Berkeley National Laboratory Research Institute of Innovative Energy Carbon Capture Research and Development Carbon capture and storage from fossil-based power...

  3. Carbon International | Open Energy Information

    Open Energy Info (EERE)

    International Jump to: navigation, search Name: Carbon International Place: London, United Kingdom Zip: NW1 8LH Sector: Carbon Product: London-based energy and communications...

  4. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sensors, and data processing. Fortunately, additional research has proven that etching carbon with sulfuric acid can also make the carbon magnetic, opening the door for...

  5. Kinetics of hydrolysis and oxidation of carbon disulfide by hydrogen peroxide in alkaline medium and application to carbonyl sulfide

    SciTech Connect (OSTI)

    Adewuyi, Y.G.; Carmichael, G.R.

    1987-02-01

    Kinetic studies of the oxidation of carbon disulfide by hydrogen peroxide in alkaline medium were made spectrophotometrically. The reaction of CS/sub 2/ with OH/sup -/ ion was found to be rate controlling and proceeded by the formation of a dithiocarbonate complex. The major reaction product was sulfate with sulfur occurring as colloidal suspensions only at pH values less than 8. The formation of sulfate increased exponentially with time and was also found to be dependent on the rate of hydrolysis of CS/sub 2/. In addition, the production of sulfate showed large induction periods, suggesting either a complex mechanism or formation by secondary reactions. The results obtained for carbon disulfide were extended to carbonyl sulfide (OCS) oxidation in alkaline solutions. The removal of OCS (acid gas) from mixtures of gases by alkaline liquid absorbents (e.g. NaOH) and oxidation of subsequent solutions to sulfate is an important industrial practice. 42 references, 14 figures, 2 tables.

  6. Electrochemical behavior of carbon aerogels derived from different precursors

    SciTech Connect (OSTI)

    Pekala, R.W.; Alviso, C.T.; Nielson, J.K.; Tran, T.D. [Lawrence Livermore National Lab., CA (United States); Reynolds, G.M.; Dresshaus, M.S. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Physics

    1995-04-01

    The ability to tailor the structure and properties of porous carbons has led to their increased use as electrodes in energy storage devices. Our research focuses on the synthesis and characterization of carbon aerogels for use in electrochemical double layer capacitors. Carbon aerogels are formed from the sol-gel polymerization of (1) resorcinol-formaldehyde or (2) phenolic-furfural, followed by supercritical drying from carbon dioxide, and subsequent pyrolysis in an inert atmosphere. These materials can be produced as monoliths, composites, thin films, powders, or microspheres. In all cases, the areogels have an open-cell structure with an ultrafine pore size (<100 nm), high surface area (400-1 100 m{sup 2}/g), and a solid matrix composed of interconnected particles, fibers, or platelets with characteristic dimensions of 10 nm. This paper examines the effects of the carbon precursor and processing conditions on electrochemical performance in aqueous and organic electrolytes.

  7. Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage

    SciTech Connect (OSTI)

    Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

    2010-01-07

    On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (< 1.5 nm) are much more effective in storing hydrogen than larger ones, such that many materials with large total surface areas are sub-par performers. Established that the distribution of pore sizes can be controlled during CDC synthesis, which opens the possibility of developing high performance materials within a common family while targeting widely disparate applications. Examples being actively pursued with other funding sources include methane storage, electrode materials for batteries and supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

  8. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-01-04

    The Big Sky Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts during the first performance period fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first Partnership meeting the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Complementary to the efforts on evaluation of sources and sinks is the development of the Big Sky Partnership Carbon Cyberinfrastructure (BSP-CC) and a GIS Road Map for the Partnership. These efforts will put in place a map-based integrated information management system for our Partnership, with transferability to the national carbon sequestration effort. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but other policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long term viability. A series of meetings held in November and December, 2003, have laid the foundations for assessing the issues surrounding the implementation of a market-based setting for soil C credits. These include the impact of existing local, state, and federal permitting issues for terrestrial based carbon sequestration projects, consistency of final protocols and planning standards with national requirements, and alignments of carbon sequestration projects with existing federal and state cost-share programs. Finally, the education and outreach efforts during this performance period have resulted in a comprehensive plan which serves as a guide for implementing the outreach activities under Phase I. The primary goal of this plan is to increase awareness, understanding, and public acceptance of sequestration efforts and build support for a constituent based network which includes the initial Big Sky Partnership and other local and regional businesses and entities.

  9. FISSION PRODUCT REMOVAL FROM ORGANIC SOLUTIONS

    DOE Patents [OSTI]

    Moore, R.H.

    1960-05-10

    The decontamination of organic solvents from fission products and in particular the treatment of solvents that were used for the extraction of uranium and/or plutonium from aqueous acid solutions of neutron-irradiated uranium are treated. The process broadly comprises heating manganese carbonate in air to a temperature of between 300 and 500 deg C whereby manganese dioxide is formed; mixing the manganese dioxide with the fission product-containing organic solvent to be treated whereby the fission products are precipitated on the manganese dioxide; and separating the fission product-containing manganese dioxide from the solvent.

  10. Adsorption characteristics of benzene on biosolid adsorbent and commercial activated carbons

    SciTech Connect (OSTI)

    Hung-Lung Chiang; Kuo-Hsiung Lin; Chih-Yu Chen; Ching-Guan Choa; Ching-Shyung Hwu; Nina Lai

    2006-05-15

    This study selected biosolids from a petrochemical wastewater treatment plant as the raw material. The sludge was immersed in 0.5-5 M of zinc chloride (ZnCl{sub 2}) solutions and pyrolyzed at different temperatures and times. Results indicated that the 1-M ZnCl{sub 2}-immersed biosolids pyrolyzed at 500{sup o}C for 30 min could be reused and were optimal biosolid adsorbents for benzene adsorption. Pore volume distribution analysis indicated that the mesopore contributed more than the macropore and micropore in the biosolid adsorbent. The benzene adsorption capacity of the biosolid adsorbent was 65 and 55% of the G206 (granular-activated carbon) and BPL (coal-based activated carbon; Calgon, Carbon Corp.) activated carbons, respectively. Data from the adsorption and desorption cycles indicated that the benzene adsorption capacity of the biosolid adsorbent was insignificantly reduced compared with the first-run capacity of the adsorbent; therefore, the biosolid adsorbent could be reused as a commercial adsorbent, although its production cost is high. 18 refs., 9 figs., 3 tabs.

  11. Storing Carbon in Agricultural Soils to Help Head-Off Global Warming and to Combat Desertification

    SciTech Connect (OSTI)

    Rosenberg, Norman J.; Izaurralde, Roberto C.

    2001-12-31

    We know for sure that addition of organic matter to soil increases water-holding capacity, imparts fertility with the addition of nutrients, increases soil aggregation and improves tilth. Depeing on it's type, organic matter contains between 40 and 60% carbon. Using agricultural management practices to increase the amount of organic matter and carbon in soils can be an effective strategy to offset carbon dioxide emissions to the atmosphere as well as to improve the quality of the soil and slow or prevent desertification.

  12. Terrestrial Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Terrestrial Carbon Cycle "Only about half of the CO2 released into the atmosphere by human activities currently resides in the atmosphere, the rest absorbed on land and in the oceans. The period over which the carbon will be sequestered is unclear, and the efficiency of future sinks is unknown." US Carbon Cycle Research Plan "We" desire to be able to predict the future spatial and temporal distribution of sources and sinks of atmospheric CO2 and their interaction (forcing and

  13. IMPACCT: Carbon Capture Technology

    SciTech Connect (OSTI)

    2012-01-01

    IMPACCT Project: IMPACCT’s 15 projects seek to develop technologies for existing coal-fired power plants that will lower the cost of carbon capture. Short for “Innovative Materials and Processes for Advanced Carbon Capture Technologies,” the IMPACCT Project is geared toward minimizing the cost of removing carbon dioxide (CO2) from coal-fired power plant exhaust by developing materials and processes that have never before been considered for this application. Retrofitting coal-fired power plants to capture the CO2 they produce would enable greenhouse gas reductions without forcing these plants to close, shifting away from the inexpensive and abundant U.S. coal supply.

  14. Wetland (peat) Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wetland (peat) Carbon Cycle Methane (CH4) is an important greenhouse gas, twenty times more potent than CO2, but atmospheric concentrations of CH4 under future climate change are uncertain. This is in part because many climate-sensitive ecosystems release both CH4 and carbon dioxide (CO2) and it is unknown how these systems will partition future releases of carbon to the atmosphere. Ecosystem observations of CH4 emissions lack mechanistic links to the processes that govern CH4 efflux: microbial

  15. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-10-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed in the second quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO{sub 2} concentrations. While no key deliverables were due during the third quarter, progress on other deliverables is noted in the PowerPoint presentations and in this report. A series of meetings held during the second and third quarters have laid the foundations for assessing the issues surrounding carbon sequestration in this region, the need for a holistic approach to meeting energy demands and economic development potential, and the implementation of government programs or a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. In the fourth quarter, three deliverables have been completed, some in draft form to be revised and updated to include Wyoming. This is due primarily to some delays in funding to LANL and INEEL and the approval of a supplemental proposal to include Wyoming in much of the GIS data sets, analysis, and related materials. The deliverables are discussed in the following sections and greater details are provided in the materials that are attached to this report. In August 2004, a presentation was made to Pioneer Hi-Bred, discussing the Partnership and the synergies with terrestrial sequestration, agricultural industries, and ongoing, complimentary USDA efforts. The Partnership organized a Carbon session at the INRA 2004 Environmental and Subsurface Science Symposium in September 2004; also in September, a presentation was made to the Wyoming Carbon Sequestration Advisory Committee, followed up with a roundtable discussion.

  16. Metabolic evolution of Escherichia coli strains that produce organic acids

    DOE Patents [OSTI]

    Grabar, Tammy; Gong, Wei; Yocum, R Rogers

    2014-10-28

    This invention relates to the metabolic evolution of a microbial organism previously optimized for producing an organic acid in commercially significant quantities under fermentative conditions using a hexose sugar as sole source of carbon in a minimal mineral medium. As a result of this metabolic evolution, the microbial organism acquires the ability to use pentose sugars derived from cellulosic materials for its growth while retaining the original growth kinetics, the rate of organic acid production and the ability to use hexose sugars as a source of carbon. This invention also discloses the genetic change in the microorganism that confers the ability to use both the hexose and pentose sugars simultaneously in the production of commercially significant quantities of organic acids.

  17. ATK - Supersonic Carbon Capture

    SciTech Connect (OSTI)

    Castrogiovanni, Anthony; Calayag, Bon

    2014-03-05

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  18. Activated carbon aerogels

    SciTech Connect (OSTI)

    Hanzawa, Y.; Kaneko, K. [Chiba Univ. (Japan)] [Chiba Univ. (Japan); Pekala, R.W. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Dresselhaus, M.S. [Massachusetts Inst. of Technology, Cambridge, MA (United States)] [Massachusetts Inst. of Technology, Cambridge, MA (United States)

    1996-12-25

    Activated carbon aerogels were obtained from the CO{sub 2} activation of the carbon aerogels. The adsorption isotherms of nitrogen on activated carbon aerogels at 77 K were measured and analyzed by the high-resolution {alpha}{sub s} plot to evaluate their porosities. The {alpha}{sub s} plot showed an upward deviation from linearity below {alpha}{sub s} = 0.5, suggesting that the presence of micropores becomes more predominant with the extent of the activation. Activation increased noticeably the pore volume and the surface area (the maximum value: 2600 m{sup 2}.g{sup -1}) without change of the basic network structure of primary particles. Activated carbon aerogels had a bimodal pore size distribution of uniform micropores and mesopores. 16 refs., 2 figs., 1 tab.

  19. ATK - Supersonic Carbon Capture

    ScienceCinema (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO); Calayag, Bon (ATK, Program Manager)

    2014-04-11

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  20. Regional Carbon Sequestration Partnerships

    Broader source: Energy.gov [DOE]

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  1. Departmental Organization and Management

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1993-06-10

    Effective immediately, the Departmental organization structure reflected in the chart at Attachment 1 has been approved.

  2. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-01-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. Efforts are underway to showcase the architecture of the GIS framework and initial results for sources and sinks. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies.

  3. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  4. Carbon Capture Simulation Initiative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture Innovation: Making an IMPACCT on Coal Carbon Capture Innovation: Making an IMPACCT on Coal February 16, 2012 - 4:48pm Addthis The ICES team from Alliant Techsystems and ACENT Laboratories (L to R): Fred Gregory, Andy Robertson, Tony Castrogiovanni, Florin Girlea, Vincenzo Verrelli, Bon Calayag, Vladimir Balepin, Kirk Featherstone. | Courtesy of the ICES team. The ICES team from Alliant Techsystems and ACENT Laboratories (L to R): Fred Gregory, Andy Robertson, Tony Castrogiovanni,

  5. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  6. An unusual carbon-carbon bond cleavage reaction during phosphinothricin

    Office of Scientific and Technical Information (OSTI)

    biosynthesis (Journal Article) | SciTech Connect An unusual carbon-carbon bond cleavage reaction during phosphinothricin biosynthesis Citation Details In-Document Search Title: An unusual carbon-carbon bond cleavage reaction during phosphinothricin biosynthesis Natural products containing phosphorus-carbon bonds have found widespread use in medicine and agriculture. One such compound, phosphinothricin tripeptide, contains the unusual amino acid phosphinothricin attached to two alanine

  7. Method for synthesizing carbon nanotubes

    DOE Patents [OSTI]

    Fan, Hongyou

    2012-09-04

    A method for preparing a precursor solution for synthesis of carbon nanomaterials, where a polar solvent is added to at least one block copolymer and at least one carbohydrate compound, and the precursor solution is processed using a self-assembly process and subsequent heating to form nanoporous carbon films, porous carbon nanotubes, and porous carbon nanoparticles.

  8. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng

    2009-03-24

    This chapter summarizes the recent development of carbon nanotube based electrochemical biosensors work at PNNL.

  9. Biosensors Based on Carbon Nanotubes

    SciTech Connect (OSTI)

    Lin, Yuehe; Yantasee, Wassana; Lu, Fang; Wang, Joseph; Musameh, Mustafa; Tu, Yi; Ren, Zhifeng; J. A. Schwarz, C. Contescu, K. Putyera

    2004-04-01

    This invited review article summarizes recent work on biosensor development based on carbon nanotubes

  10. Carbon cycling in western equatorial atlantic sediments: Insights from carbon isotopes

    SciTech Connect (OSTI)

    McNichol, A.P.; McCorkle, D.C.; Martin, W.R.; Berry, J.N.

    1995-12-01

    Sediments from a site on the Ceara Rise in the western equatorial Atlantic Ocean (5{degrees} 17N, 44{degrees}8W) were collected in March 1994 to study the carbon cycle of ocean sediments. Sediments were collected in 3270 m of water, above the calcite saturation horizon ({triangle}CO{sub 3}{sup 2} {approx} 20). Relatively large volumes (20-30 ml) of pore water were extracted from 1-2 cm interval sections of the surface 10 cm of the sediments using both whole core squeezing and centrifugation techniques. The whole core squeezer permits the in-situ or shipboard extraction of large volumes of pore water without sectioning sediment cores. We analyzed the pore water dissolved inorganic carbon ({Sigma}CO{sub 2}) to yield high resolution profiles of concentration, {gamma}{sup 13}C, and {triangle}{sup 14}C at this site. The bottom water values we measured are about 10 {per_thousand} lower than that measured at a nearby site during the GEOSECS Program in 1974. Pore water {gamma}{sup 13}C decreases regularly from a value of 0.75 {per_thousand} in the bottom water to -0.8 {per_thousand} at 11 cm and {triangle}{sup 14}C decreases regularly from -109 {per_thousand} in the bottom water to -180 at 10 cm. The stable isotope results indicate the addition of carbon to the pore water from both the dissolution of CaCO{sub 3} and the oxidation of organic matter. Pore water radiocarbon results indicate that at least one of these carbon sources is quite old. We will use results from isotopic analyses of the sediment organic matter and CaCO{sub 3} to constrain the sediment carbon budget and discuss the implications for oceanic carbon modelling,

  11. WESTCARB Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The West Coast Regional Carbon Sequestration Partnership (known as WESTCARB) was established in Fall 2003. It is one of seven research partnerships co-funded by DOE to characterize regional carbon sequestration opportunities and conduct pilot-scale validation tests. The California Energy Commission manages WESTCARB and is a major co-funder. WESTCARB is characterizing the extent and capacity of geologic formations capable of storing CO2, known as sinks. Results are entered into a geographic information system (GIS) database, along with the location of major CO2-emitting point sources in each of the six WESTCARB states, enabling researchers and the public to gauge the proximity of candidate CO2 storage sites to emission sources and the feasibility of linking them via pipelines. Specifically, the WESTCARB GIS database (also known as the carbon atlas) stores layers of geologic information about potential underground storage sites, such as porosity and nearby fault-lines and aquifers. Researchers use these data, along with interpreted geophysical data and available oil and gas well logs to estimate the region's potential geologic storage capacity. The database also depicts existing pipeline routes and rights-of-way and lands that could be off-limits, which can aid the development of a regional carbon management strategy. The WESTCARB Carbon Atlas, which is accessible to the public, provides a resource for public discourse on practical solutions for regional CO2 management. A key WESTCARB partner, the Utah Automated Geographic Reference Center, has developed data serving procedures to enable the WESTCARB Carbon Atlas to be integrated with those from other regional partnerships, thereby supporting the U.S. Department of Energy's national carbon atlas, NATCARB

  12. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-11-01

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO2 utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research agenda in Carbon Sequestration. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other DOE regional partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound MMV is critical for public acceptance of these technologies. Deliverables for the 7th Quarter reporting period include (1) for the geological efforts: Reports on Technology Needs and Action Plan on the Evaluation of Geological Sinks and Pilot Project Deployment (Deliverables 2 and 3), and Report on the Feasibility of Mineralization Trapping in the Snake River Plain Basin (Deliverable 14); (2) for the terrestrial efforts: Report on the Evaluation of Terrestrial Sinks and a Report of the Best Production Practices for Soil C Sequestration (Deliverables 8 and 15). In addition, the 7th Quarter activities for the Partnership included further development of the proposed activities for the deployment and demonstration phase of the carbon sequestration pilots including geological and terrestrial pilots, expansion of the Partnership to encompass regions and institutions that are complimentary to the steps we have identified, building greater collaborations with industry and stakeholders in the region, contributed to outreach efforts that spanned all partnerships, co-authorship on the Carbon Capture and Separation report, and developed a regional basis to address future energy opportunities in the region. The deliverables and activities are discussed in the following sections and appended to this report. The education and outreach efforts have resulted in a comprehensive plan which serves as a guide for implementing the outreach activities under Phase I. The public website has been expanded and integrated with the GIS carbon atlas. We have made presentations to stakeholders and policy makers including two tribal sequestration workshops, and made connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmentally-friendly energy production. In addition, the Partnership has plans for integration of our outreach efforts with students, especially at the tribal colleges and at the universities involved in our Partnership. This includes collaboration with MSU and with the U.S.-Norway Summer School, extended outreach efforts at LANL and INEEL, and with the student section of the ASME. Finally, the Big Sky Partnership was involved in key meetings and symposium in the 7th quarter including the USDOE Wye Institute Conference on Carbon Sequestration and Capture (April, 2005); the DOE/NETL Fourth Annual Conference on Carbon Capture and Sequestration (May 2005); Coal Power Development Conference (Denver, June 2005) and meetings with our Phase II industry partners and Governor's staff.

  13. Molten carbonate fuel cell cathode with mixed oxide coating

    DOE Patents [OSTI]

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  14. Measurement of carbon capture efficiency and stored carbon leakage

    DOE Patents [OSTI]

    Keeling, Ralph F.; Dubey, Manvendra K.

    2013-01-29

    Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon capture and storage process. Optionally, the data can be used to quantify a carbon dioxide concentration increase at the first location that is attributable to escape of carbon dioxide from the source and to calculate a rate of escape of carbon dioxide from the source by executing a model of gas-phase transport using at least the first carbon dioxide concentration increase. Related systems, methods, and articles of manufacture are also described.

  15. The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functional...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal-Organic Framework Previous Next List N. Planas, A. L. Dzubak, R. Poloni, L.-C. Lin, A. McManus, T. M....

  16. Enhanced carbon dioxide capture upon incorporation ofN,N'-dimethyleth...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced carbon dioxide capture upon incorporation of N,N'-dimethylethylenediamine in the metal-organic framework CuBTTri Previous Next List Thomas M. McDonald, Deanna M....

  17. Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic ... conditions relevant to removal of CO2 from air, and 3.14 mmolg (12.1 wt %) at 0.15 bar ...

  18. Hydrogen storage and carbon dioxide capture in an iron-based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods Previous Next List Kenji Sumida,...

  19. Mixed crystal organic scintillators

    DOE Patents [OSTI]

    Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

    2014-09-16

    A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

  20. Energy level alignment in polymer organic solar cells at donor-acceptor planar junction formed by electrospray vacuum deposition

    SciTech Connect (OSTI)

    Kim, Ji-Hoon; Hong, Jong-Am; Kwon, Dae-Gyeon; Seo, Jaewon; Park, Yongsup

    2014-04-21

    Using ultraviolet photoelectron spectroscopy (UPS), we have measured the energy level offset at the planar interface between poly(3-hexylthiophene) (P3HT) and C{sub 61}-butyric acid methylester (PCBM). Gradual deposition of PCBM onto spin-coated P3HT in high vacuum was made possible by using electrospray vacuum deposition (EVD). The UPS measurement of EVD-prepared planar interface resulted in the energy level offset of 0.91?eV between P3HT HOMO and PCBM LUMO, which is considered as the upper limit of V{sub oc} of the organic photovoltaic cells.

  1. A new family of fluidic precursors for the self-templated synthesis of hierarchical nanoporous carbons

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fulvio, Pasquale F; Hillesheim, Patrick C; Oyola, Yatsandra; Mahurin, Shannon Mark; Veith, Gabriel M; Dai, Sheng

    2013-01-01

    Hierarchical nanoporous nitrogen-doped carbons were prepared from task specific ionic liquids having a bis-imidazolium motif linked with various organic groups. While ethyl chains linking the imidazolium ions afford microporous-mesoporous carbons, long or aromatic groups resulted in microporous samples.

  2. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  3. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  4. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  5. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  6. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  7. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  8. Photoenhanced anaerobic digestion of organic acids

    DOE Patents [OSTI]

    Weaver, Paul F.

    1990-01-01

    A process is described for rapid conversion of organic acids and alcohols anaerobic digesters into hydrogen and carbon dioxide, the optimal precursor substrates for production of methane. The process includes addition of photosynthetic bacteria to the digester and exposure of the bacteria to radiant energy (e.g., solar energy). The process also increases the pH stability of the digester to prevent failure of the digester. Preferred substrates for photosynthetic bacteria are the organic acid and alcohol waste products of fermentative bacteria. In mixed culture with methanogenic bacteria or in defined co-culture with non-aceticlastic methanogenic bacteria, photosynthetic bacteria are capable of facilitating the conversion or organic acids and alcohols into methane with low levels of light energy input.

  9. Aerogels derived from multifunctional organic monomers

    SciTech Connect (OSTI)

    Pekala, R.W.; Alviso, C.T.; Kong, F.M.; Hulsey, S.S.

    1991-09-01

    Traditional inorganic aerogels are mad via the hydrolysis and condensation of metal alkoxides. Recently, we reported the synthesis of organic aerogels based upon the aqueous polycondensation of (1) resorcinol with formaldehyde and (2) melamine with formaldehyde. The former materials can also be pyrolyzed in an inert atmosphere to form vitreous carbon aerogels. In both the inorganic and organic systems, the structure and properties of the dried aerogel are dictated by polymerization conditions. Factors such as pH, reactant ratio, and temperature influence the crosslinking chemistry and growth processes taking place prior to gelation. The ability to tailor the structure and properties of aerogels at the nanometer scale opens up exciting possibilities for these novel materials. This paper addresses the chemistry-structure-property relationships of organic aerogels. 22 refs., 7 figs.

  10. Organic aerogel microspheres and fabrication method therefor

    DOE Patents [OSTI]

    Mayer, Steven T.; Kong, Fung-Ming; Pekala, Richard W.; Kaschmitter, James L.

    1996-01-01

    Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

  11. Organic aerogel microspheres and fabrication method therefor

    DOE Patents [OSTI]

    Mayer, S.T.; Kong, F.M.; Pekala, R.W.; Kaschmitter, J.L.

    1996-04-16

    Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.

  12. Carbon dioxide research plan. A summary

    SciTech Connect (OSTI)

    Trivelpiece, Alvin W.; Koomanoff, F. A.; Suomi, Verner E.

    1983-11-01

    The Department of Energy is the lead federal agency for research related to atmospheric carbon dioxide. Its responsibility is to sponsor a program of relevant research, and to coordinate this research with that of others. As part of its responsibilities, the Department of Energy has prepared a research plan. The plan documented in this Summary delineated the logic, objectives, organization, background and current status of the research activities. The Summary Plan is based on research subplans in four specific areas: global carbon cycle, climate effects, vegetative response and indirect effects. These subplans have emanated from a series of national and international workshops, conferences, and from technical reports. The plans have been peer reviewed by experts in the relevant scientific fields. Their execution is being coordinated between the responsible federal and international government agencies and the involved scientific community.

  13. Carbon-particle generator

    DOE Patents [OSTI]

    Hunt, A.J.

    1982-09-29

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  14. HOLLOW CARBON ARC DISCHARGE

    DOE Patents [OSTI]

    Luce, J.S.

    1960-10-11

    A device is described for producing an energetic, direct current, hollow, carbon-arc discharge in an evacuated container and within a strong magnetic field. Such discharges are particularly useful not only in dissociation and ionization of high energy molecular ion beams, but also in acting as a shield or barrier against the instreaming of lowenergy neutral particles into a plasma formed within the hollow discharge when it is used as a dissociating mechanism for forming the plasma. There is maintained a predetermined ratio of gas particles to carbon particles released from the arc electrodes during operation of the discharge. The carbon particles absorb some of the gas particles and are pumped along and by the discharge out of the device, with the result that smaller diffusion pumps are required than would otherwise be necessary to dispose of the excess gas.

  15. Carbon K-Edge XANES Spectromicroscopy of Natural Graphite

    SciTech Connect (OSTI)

    Brandes,J.; Cody, G.; Rumble, D.; Haberstroh, P.; Wirick, S.; Gelinas, Y.; Morais-Cabral, J.

    2008-01-01

    The black carbon continuum is composed of a series of carbon-rich components derived from combustion or metamorphism and characterized by contrasting environmental behavior and susceptibility to oxidation. In this work, we present a micro-scale density fractionation method that allows isolating the small quantities of soot-like and graphitic material usually found in natural samples. Organic carbon and {delta}{sup 13}C mass balance calculations were used to quantify the relative contributions of the two fractions to thermally-stable organic matter from a series of aquatic sediments. Varying proportions of soot-like and graphitic material were found in these samples, with large variations in {delta}{sup 13}C signatures suggesting important differences in their origin and/or dynamics in the environment.

  16. Tailored semiconducting carbon nanotube networks with enhanced thermoelectric properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Avery, Azure D.; Zhou, Ben H.; Lee, Jounghee; Lee, Eui -Sup; Miller, Elisa M.; Ihly, Rachelle; Wesenberg, Devin; Mistry, Kevin S.; Guillot, Sarah L.; Zink, Barry L.; et al

    2016-04-04

    Thermoelectric power generation, allowing recovery of part of the energy wasted as heat, is emerging as an important component of renewable energy and energy efficiency portfolios. Although inorganic semiconductors have traditionally been employed in thermoelectric applications, organic semiconductors garner increasing attention as versatile thermoelectric materials. Here we present a combined theoretical and experimental study suggesting that semiconducting single-walled carbon nanotubes with carefully controlled chirality distribution and carrier density are capable of large thermoelectric power factors, higher than 340 μW m-1 K-2, comparable to the best-performing conducting polymers and larger than previously observed for carbon nanotube films. Furthermore, we demonstrate thatmore » phonons are the dominant source of thermal conductivity in the networks, and that our carrier doping process significantly reduces the thermal conductivity relative to undoped networks. As a result, these findings provide the scientific underpinning for improved functional organic thermoelectric composites with carbon nanotube inclusions.« less

  17. Carbon Capture and Storage

    SciTech Connect (OSTI)

    Friedmann, S

    2007-10-03

    Carbon capture and sequestration (CCS) is the long-term isolation of carbon dioxide from the atmosphere through physical, chemical, biological, or engineered processes. This includes a range of approaches including soil carbon sequestration (e.g., through no-till farming), terrestrial biomass sequestration (e.g., through planting forests), direct ocean injection of CO{sub 2} either onto the deep seafloor or into the intermediate depths, injection into deep geological formations, or even direct conversion of CO{sub 2} to carbonate minerals. Some of these approaches are considered geoengineering (see the appropriate chapter herein). All are considered in the 2005 special report by the Intergovernmental Panel on Climate Change (IPCC 2005). Of the range of options available, geological carbon sequestration (GCS) appears to be the most actionable and economic option for major greenhouse gas reduction in the next 10-30 years. The basis for this interest includes several factors: (1) The potential capacities are large based on initial estimates. Formal estimates for global storage potential vary substantially, but are likely to be between 800 and 3300 Gt of C (3000 and 10,000 Gt of CO{sub 2}), with significant capacity located reasonably near large point sources of the CO{sub 2}. (2) GCS can begin operations with demonstrated technology. Carbon dioxide has been separated from large point sources for nearly 100 years, and has been injected underground for over 30 years (below). (3) Testing of GCS at intermediate scale is feasible. In the US, Canada, and many industrial countries, large CO{sub 2} sources like power plants and refineries lie near prospective storage sites. These plants could be retrofit today and injection begun (while bearing in mind scientific uncertainties and unknowns). Indeed, some have, and three projects described here provide a great deal of information on the operational needs and field implementation of CCS. Part of this interest comes from several key documents written in the last three years that provide information on the status, economics, technology, and impact of CCS. These are cited throughout this text and identified as key references at the end of this manuscript. When coupled with improvements in energy efficiency, renewable energy supplies, and nuclear power, CCS help dramatically reduce current and future emissions (US CCTP 2005, MIT 2007). If CCS is not available as a carbon management option, it will be much more difficult and much more expensive to stabilize atmospheric CO{sub 2} emissions. Recent estimates put the cost of carbon abatement without CCS to be 30-80% higher that if CCS were to be available (Edmonds et al. 2004).

  18. Organic photosensitive devices

    DOE Patents [OSTI]

    Rand, Barry P; Forrest, Stephen R

    2013-11-26

    The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photosensitive optoelectronic devices having a photoactive organic region containing encapsulated nanoparticles that exhibit plasmon resonances. An enhancement of the incident optical field is achieved via surface plasmon polariton resonances. This enhancement increases the absorption of incident light, leading to a more efficient device.

  19. WEST COAST REGIONAL CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Larry Myer; Terry Surles; Kelly Birkinshaw

    2004-01-01

    The West Coast Regional Carbon Sequestration Partnership is one of seven partnerships which have been established by the US Department of Energy (DOE) to evaluate carbon dioxide capture, transport and sequestration (CT&S) technologies best suited for different regions of the country. The West Coast Region comprises Arizona, California, Nevada, Oregon, Washington, and the North Slope of Alaska. Led by the California Energy Commission, the West Coast Partnership is a consortium of over thirty five organizations, including state natural resource and environmental protection agencies; national labs and universities; private companies working on CO{sub 2} capture, transportation, and storage technologies; utilities; oil and gas companies; nonprofit organizations; and policy/governance coordinating organizations. In an eighteen month Phase I project, the Partnership will evaluate both terrestrial and geologic sequestration options. Work will focus on five major objectives: (1) Collect data to characterize major CO{sub 2} point sources, the transportation options, and the terrestrial and geologic sinks in the region, and compile and organize this data via a geographic information system (GIS) database; (2) Address key issues affecting deployment of CT&S technologies, including storage site permitting and monitoring, injection regulations, and health and environmental risks (3) Conduct public outreach and maintain an open dialogue with stakeholders in CT&S technologies through public meetings, joint research, and education work (4) Integrate and analyze data and information from the above tasks in order to develop supply curves and cost effective, environmentally acceptable sequestration options, both near- and long-term (5) Identify appropriate terrestrial and geologic demonstration projects consistent with the options defined above, and create action plans for their safe and effective implementation A kickoff meeting for the West Coast Partnership was held on Sept 30-Oct.1. Contracts were then put into place with twelve organizations which will carry out the technical work required to meet Partnership objectives.

  20. Photoconversion of gasified organic materials into biologically-degradable plastics

    DOE Patents [OSTI]

    Weaver, P.F.; Pinching Maness.

    1993-10-05

    A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer. 3 figures.

  1. Photoconversion of gasified organic materials into biologically-degradable plastics

    DOE Patents [OSTI]

    Weaver, Paul F.; Maness, Pin-Ching

    1993-01-01

    A process is described for converting organic materials (such as biomass wastes) into a bioplastic suitable for use as a biodegradable plastic. In a preferred embodiment the process involves thermally gasifying the organic material into primarily carbon monoxide and hydrogen, followed by photosynthetic bacterial assimilation of the gases into cell material. The process is ideally suited for waste recycling and for production of useful biodegradable plastic polymer.

  2. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus; Yanagihara, Naohisa; Dyke, James T.; Vemulapalli, Krishna

    1991-09-03

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  3. Carbon-based Supercapacitors Produced by Activation of Graphene

    SciTech Connect (OSTI)

    Y Zhu; S Murali; M Stoller; K Ganesh; W Cai; P Ferreira; A Pirkle; R Wallace; K Cychosz; et al.

    2011-12-31

    Supercapacitors, also called ultracapacitors or electrochemical capacitors, store electrical charge on high-surface-area conducting materials. Their widespread use is limited by their low energy storage density and relatively high effective series resistance. Using chemical activation of exfoliated graphite oxide, we synthesized a porous carbon with a Brunauer-Emmett-Teller surface area of up to 3100 square meters per gram, a high electrical conductivity, and a low oxygen and hydrogen content. This sp{sup 2}-bonded carbon has a continuous three-dimensional network of highly curved, atom-thick walls that form primarily 0.6- to 5-nanometer-width pores. Two-electrode supercapacitor cells constructed with this carbon yielded high values of gravimetric capacitance and energy density with organic and ionic liquid electrolytes. The processes used to make this carbon are readily scalable to industrial levels.

  4. Carbon-Based Supercapacitors Produced by Activation of Graphene

    SciTech Connect (OSTI)

    Zhu, Y.; Su, D.; Murali, S.; Stoller, M.D.; Ganesh, K.J.; Cai, W.; Ferreira, P.J.; Pirkle, A.; Wallace, R.M.; Cychosz, K.A., Thommes, M.; Stach, E.A.; Ruoff, R.S.

    2011-06-24

    Supercapacitors, also called ultracapacitors or electrochemical capacitors, store electrical charge on high-surface-area conducting materials. Their widespread use is limited by their low energy storage density and relatively high effective series resistance. Using chemical activation of exfoliated graphite oxide, we synthesized a porous carbon with a Brunauer-Emmett-Teller surface area of up to 3100 square meters per gram, a high electrical conductivity, and a low oxygen and hydrogen content. This sp{sup 2}-bonded carbon has a continuous three-dimensional network of highly curved, atom-thick walls that form primarily 0.6- to 5-nanometer-width pores. Two-electrode supercapacitor cells constructed with this carbon yielded high values of gravimetric capacitance and energy density with organic and ionic liquid electrolytes. The processes used to make this carbon are readily scalable to industrial levels.

  5. CarbonMicro | Open Energy Information

    Open Energy Info (EERE)

    Place: Irvine, California Zip: CA 92618 Sector: Carbon Product: Carbon Micro Battery Corporation has a unique technology of creating micro and nanoscale carbon...

  6. Carbon Micro Battery LLC | Open Energy Information

    Open Energy Info (EERE)

    Micro Battery LLC Jump to: navigation, search Name: Carbon Micro Battery, LLC Place: California Sector: Carbon Product: Carbon Micro Battery, LLC, technology developer of micro and...

  7. Carbon Solutions Group | Open Energy Information

    Open Energy Info (EERE)

    Solutions Group Jump to: navigation, search Name: Carbon Solutions Group Place: Chicago, Illinois Zip: 60601 Sector: Carbon Product: Carbon Solutions Group collaborates with...

  8. Participatory Carbon Monitoring: Operational Guidance for National...

    Open Energy Info (EERE)

    Participatory Carbon Monitoring: Operational Guidance for National REDD+ Carbon Accounting Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Participatory Carbon...

  9. Arreon Carbon Ltd | Open Energy Information

    Open Energy Info (EERE)

    Arreon Carbon Ltd Jump to: navigation, search Name: Arreon Carbon Ltd Place: Beijing, Beijing Municipality, China Zip: 100022 Sector: Carbon Product: Beijing-based firm that...

  10. GS Carbon Corporation | Open Energy Information

    Open Energy Info (EERE)

    Carbon Corporation Jump to: navigation, search Name: GS Carbon Corporation Place: New York, New York Zip: 10119 Sector: Carbon Product: The company offsets emissions output with...

  11. Carbon Market Brasil Consulting | Open Energy Information

    Open Energy Info (EERE)

    Market Brasil Consulting Jump to: navigation, search Name: Carbon Market Brasil Consulting Place: Sao Paulo, Brazil Zip: 04120-070 Sector: Carbon Product: Brazil-based carbon...

  12. Universal Carbon Credits Limited | Open Energy Information

    Open Energy Info (EERE)

    Universal Carbon Credits Limited Jump to: navigation, search Name: Universal Carbon Credits Limited Place: London, England, United Kingdom Zip: EC3A6DF Sector: Carbon Product:...

  13. Carbon Trust Enterprises Limited | Open Energy Information

    Open Energy Info (EERE)

    Enterprises Limited Jump to: navigation, search Name: Carbon Trust Enterprises Limited Place: London, United Kingdom Zip: WC2A 2AZ Sector: Carbon Product: Carbon Trust Enterprises...

  14. Equinox Carbon Equities LLC | Open Energy Information

    Open Energy Info (EERE)

    Equinox Carbon Equities LLC Jump to: navigation, search Name: Equinox Carbon Equities, LLC Place: Newport Beach, California Zip: 92660 Sector: Carbon Product: Investment firm...

  15. The Social Carbon Company | Open Energy Information

    Open Energy Info (EERE)

    Social Carbon Company Jump to: navigation, search Name: The Social Carbon Company Place: Brasilia, Distrito Federal (Brasilia), Brazil Zip: CEP 70610-440 Sector: Carbon, Services...

  16. Carbon Credit Capital | Open Energy Information

    Open Energy Info (EERE)

    Capital Jump to: navigation, search Name: Carbon Credit Capital Place: New York, New York Zip: 10012 Sector: Carbon, Services Product: Project Advisory Services and Carbon...

  17. The Global Carbon Bank | Open Energy Information

    Open Energy Info (EERE)

    Global Carbon Bank Jump to: navigation, search Name: The Global Carbon Bank Place: Houston, Texas Zip: 77025 Sector: Carbon, Services Product: Houston-based provider of advisory...

  18. Method for production of carbon nanofiber mat or carbon paper

    DOE Patents [OSTI]

    Naskar, Amit K.

    2015-08-04

    Method for the preparation of a non-woven mat or paper made of carbon fibers, the method comprising carbonizing a non-woven mat or paper preform (precursor) comprised of a plurality of bonded sulfonated polyolefin fibers to produce said non-woven mat or paper made of carbon fibers. The preforms and resulting non-woven mat or paper made of carbon fiber, as well as articles and devices containing them, and methods for their use, are also described.

  19. Mediated electrochemical oxidation of organic wastes using a Co(III) mediator in a neutral electrolyte

    DOE Patents [OSTI]

    Balazs, G. Bryan (Livermore, CA); Lewis, Patricia R. (Livermore, CA)

    1999-01-01

    An electrochemical cell with a Co(III) mediator and neutral pH anolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the cobalt mediator oxidizes the organics and insoluble radioactive species and is regenerated at the anode until all organics are converted to carbon dioxide and destroyed. The neutral electrolyte is non-corrosive, and thus extends the lifetime of the cell and its components.

  20. Mediated electrochemical oxidation of organic wastes using a Co(III) mediator in a neutral electrolyte

    DOE Patents [OSTI]

    Balazs, G.B.; Lewis, P.R.

    1999-07-06

    An electrochemical cell with a Co(III) mediator and neutral pH anolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the cobalt mediator oxidizes the organics and insoluble radioactive species and is regenerated at the anode until all organics are converted to carbon dioxide and destroyed. The neutral electrolyte is non-corrosive, and thus extends the lifetime of the cell and its components. 2 figs.

  1. TESTING GUIDELINES FOR TECHNETIUM-99 ABSORPTION ON ACTIVATED CARBON

    SciTech Connect (OSTI)

    BYRNES ME

    2010-09-08

    CH2M HILL Plateau Remediation Company (CHPRC) is currently evaluating the potential use of activated carbon adsorption for removing technetium-99 from groundwater as a treatment method for the Hanford Site's 200 West Area groundwater pump-and-treat system. The current pump-and-treat system design will include an ion-exchange (IX) system for selective removal of technetium-99 from selected wells prior to subsequent treatment of the water in the central treatment system. The IX resin selected for technetium-99 removal is Purolite A530E. The resin service life is estimated to be approximately 66.85 days at the design technetium-99 loading rate, and the spent resin must be replaced because it cannot be regenerated. The resulting operating costs associated with resin replacement every 66.85 days are estimated at $0.98 million/year. Activated carbon pre-treatment is being evaluated as a potential cost-saving measure to offset the high operating costs associated with frequent IX resin replacement. This document is preceded by the Literature Survey of Technetium-99 Groundwater Pre-Treatment Option Using Granular Activated Carbon (SGW-43928), which identified and evaluated prior research related to technetium-99 adsorption on activated carbon. The survey also evaluated potential operating considerations for this treatment approach for the 200 West Area. The preliminary conclusions of the literature survey are as follows: (1) Activated carbon can be used to selectively remove technetium-99 from contaminated groundwater. (2) Technetium-99 adsorption onto activated carbon is expected to vary significantly based on carbon types and operating conditions. For the treatment approach to be viable at the Hanford Site, activated carbon must be capable of achieving a designated minimum technetium-99 uptake. (3) Certain radionuclides known to be present in 200 West Area groundwater are also likely to adsorb onto activated carbon. (4) Organic solvent contaminants of concern (COCs) will load heavily onto activated carbon and should be removed from groundwater upstream of the activated carbon pre-treatment system. Unless removed upstream, the adsorbed loadings of these organic constituents could exceed the land disposal criteria for carbon.

  2. Carbon cloth supported electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA); Ammon, Robert L. (Baldwin both of, PA)

    1982-01-01

    A flow-by anode is disclosed made by preparing a liquid suspension of about to about 18% by weight solids, the solids comprising about 3.5 to about 8% of a powdered catalyst of platinum, palladium, palladium oxide, or mixtures thereof; about 60 to about 76% carbon powder (support) having a particle size less than about 20 m.mu.m and about 20 to about 33% of an inert binder having a particle size of less than about 500 m.mu.m. A sufficient amount of the suspension is poured over a carbon cloth to form a layer of solids about 0.01 to about 0.05 cm thick on the carbon cloth when the electrode is completed. A vacuum was applied to the opposite side of the carbon cloth to remove the liquid and the catalyst layer/cloth assembly is dried and compressed at about 10 to about 50 MPa's. The binder is then sintered in an inert atmosphere to complete the electrode. The electrode is used for the oxidation of sulfur dioxide in a sulfur based hybrid cycle for the decomposition of water.

  3. Carbon-Fuelled Future

    SciTech Connect (OSTI)

    Appel, Aaron M.

    2014-09-12

    Whether due to changes in policy or consumption of available fossil fuels, alternative sources of energy will be required, especially given the rising global energy demand. However, one of the main factors limiting the widespread utilization of renewable energy, such as wind, solar, wave or geothermal, is our ability to store energy. Storage of energy from carbon-neutral sources, such as electricity from solar or wind, can be accomplished through many routes. One approach is to store energy in the form of chemical bonds, as fuels. The conversion of low-energy compounds, such as water and carbon dioxide, to higher energy molecules, such as hydrogen or carbon-based fuels, enables the storage of carbon-neutral energy on a very large scale. The author¹s work in this area is supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  4. Carbon Footprint Calculator

    Broader source: Energy.gov [DOE]

    This calculator estimates the amount of carbon emissions you and members of your household are responsible for. It does not include emissions associated with your work or getting to work if you commute by public transportation. It was developed by IEEE Spectrum magazine.

  5. Carbon smackdown: wind warriors

    ScienceCinema (OSTI)

    Glen Dahlbacka of the Accelerator & Fusion Research Division and Ryan Wiser of the Environmental Energy Technologies Division are the speakers.

    2010-09-01

    July 16. 2010 carbon smackdown summer lecture: learn how Berkeley Lab scientists are developing wind turbines to be used in an urban setting, as well as analyzing what it will take to increase the adoption of wind energy in the U.S.

  6. Microbial production of multi-carbon chemicals and fuels from water and carbon dioxide using electric current

    DOE Patents [OSTI]

    Lovley, Derek R; Nevin, Kelly

    2015-11-03

    The invention provides systems and methods for generating organic compounds using carbon dioxide as a source of carbon and electrical current as an energy source. In one embodiment, a reaction cell is provided having a cathode electrode and an anode electrode that are connected to a source of electrical power, and which are separated by a permeable membrane. A biological film is provided on the cathode. The biological film comprises a bacterium that can accept electrons and that can convert carbon dioxide to a carbon-bearing compound and water in a cathode half-reaction. At the anode, water is decomposed to free molecular oxygen and solvated protons in an anode half-reaction. The half-reactions are driven by the application of electrical current from an external source. Compounds that have been produced include acetate, butanol, 2-oxobutyrate, propanol, ethanol, and formate.

  7. Carbon Trust | Open Energy Information

    Open Energy Info (EERE)

    Trust Jump to: navigation, search Name: Carbon Trust Place: London, Greater London, United Kingdom Zip: EC4A 3BF Sector: Carbon Product: London-based independent company funded by...

  8. Sustainable Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search Name: Sustainable Carbon Place: Sao Paulo, Sao Paulo, Brazil Zip: 04 038 032 Product: Sao Paulo-based joint-venture with CantorCO2e Brazil. The...

  9. Carbon Clear | Open Energy Information

    Open Energy Info (EERE)

    Clear Jump to: navigation, search Name: Carbon Clear Place: United Kingdom Product: UK-based voluntary offset provider. References: Carbon Clear1 This article is a stub. You can...

  10. Boron nitride converted carbon fiber

    DOE Patents [OSTI]

    Rousseas, Michael; Mickelson, William; Zettl, Alexander K.

    2016-04-05

    This disclosure provides systems, methods, and apparatus related to boron nitride converted carbon fiber. In one aspect, a method may include the operations of providing boron oxide and carbon fiber, heating the boron oxide to melt the boron oxide and heating the carbon fiber, mixing a nitrogen-containing gas with boron oxide vapor from molten boron oxide, and converting at least a portion of the carbon fiber to boron nitride.

  11. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  12. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  13. Carbon nanotube array based sensor

    DOE Patents [OSTI]

    Lee, Christopher L.; Noy, Aleksandr; Swierkowski, Stephan P.; Fisher, Karl A.; Woods, Bruce W.

    2005-09-20

    A sensor system comprising a first electrode with an array of carbon nanotubes and a second electrode. The first electrode with an array of carbon nanotubes and the second electrode are positioned to produce an air gap between the first electrode with an array of carbon nanotubes and the second electrode. A measuring device is provided for sensing changes in electrical capacitance between the first electrode with an array of carbon nanotubes and the second electrode.

  14. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil metagenomics and carbon cycling Soil metagenomics and carbon cycling Establishing a foundational understanding of the microbial and ecosystem factors that control carbon cycling to improve climate modeling and carbon management. Get Expertise Principle Investigator Cheryl Kuske Bioscience Division 505 665 4800 Email Get Expertise John Dunbar Bioscience Division Email Get Expertise Chris Yeager Bioscience Division Email Get Expertise Jean Challacombe Bioscience Division Email This

  15. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  16. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  17. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  18. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS finally put to rest doubts about the existence of magnetic carbon.

  19. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to prove that pure carbon can be magnetized have remained unconvincing. However, using a proton beam and an advanced x-ray microscope at the Advanced Light Source, a multinational team of researchers from the SSRL, the University of Leipzig, and the ALS

  20. Single-layer graphene cathodes for organic photovoltaics

    SciTech Connect (OSTI)

    Cox, Marshall P.; Gorodetsky, Alon A.; Kim, Bumjung; Kim, Keun Soo; Jia, Zhang; Kim, Philip; Nuckolls, Colin; Kymissis, Ioannis

    2011-01-01

    A laminated single-layer graphene is demonstrated as a cathode for organic photovoltaicdevices. The measured properties indicate that graphene offers two potential advantages over conventional photovoltaic electrode materials; work function matching via contact doping, and increased power conversion efficiency due to transparency. These findings indicate that flexible, light-weight all carbon solar cells can be constructed using graphene as the cathode material.

  1. Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling

    SciTech Connect (OSTI)

    Boone, Eric J.; Laskin, Alexander; Laskin, Julia; Wirth, Christopher; Shepson, Paul B.; Stirm, Brian H.; Pratt, Kerri A.

    2015-07-21

    Cloud water and below-cloud atmospheric particle samples were collected onboard a research aircraft during the Southern Oxidant and Aerosol Study (SOAS) over a forested region of Alabama in June 2013. The organic molecular composition of the samples was studied to gain insights into the aqueous-phase processing of organic compounds within cloud droplets. High resolution mass spectrometry with nanospray desorption electrospray ionization and direct infusion electrospray ionization were utilized to compare the organic composition of the particle and cloud water samples, respectively. Isoprene and monoterpene-derived organosulfates and oligomers were identified in both the particles and cloud water, showing the significant influence of biogenic volatile organic compound oxidation above the forested region. While the average O:C ratios of the organic compounds were similar between the atmospheric particle and cloud water samples, the chemical composition of these samples was quite different. Specifically, hydrolysis of organosulfates and formation of nitrogen-containing compounds were observed for the cloud water when compared to the atmospheric particle samples, demonstrating that cloud processing changes the composition of organic aerosol.

  2. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2014-12-20

    Four different parameterizations for the formation and evolution of secondary organic aerosol (SOA) are evaluated using a 0-D box model representing the Los Angeles Metropolitan Region during the CalNex 2010 field campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA formed only from the oxidation of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generationmore » oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model-measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model/measurement agreement for mass concentration. When comparing the three parameterizations, the Grieshop et al. (2009) parameterization more accurately reproduces both the SOA mass concentration and oxygen-to-carbon ratio inside the urban area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the parameterizations over-predict urban SOA formation at long photochemical ages (≈ 3 days) compared to observations from multiple sites, which can lead to problems in regional and global modeling. Among the explicitly modeled VOCs, the precursor compounds that contribute the greatest SOA mass are methylbenzenes. Polycyclic aromatic hydrocarbons (PAHs) are less important precursors and contribute less than 4% of the SOA mass. The amounts of SOA mass from diesel vehicles, gasoline vehicles, and cooking emissions are estimated to be 16–27, 35–61, and 19–35%, respectively, depending on the parameterization used, which is consistent with the observed fossil fraction of urban SOA, 71 (±3) %. In-basin biogenic VOCs are predicted to contribute only a few percent to SOA. A regional SOA background of approximately 2.1 μg m−3 is also present due to the long distance transport of highly aged OA. The percentage of SOA from diesel vehicle emissions is the same, within the estimated uncertainty, as reported in previous work that analyzed the weekly cycles in OA concentrations (Bahreini et al., 2012; Hayes et al., 2013). However, the modeling work presented here suggests a strong anthropogenic source of modern carbon in SOA, due to cooking emissions, which was not accounted for in those previous studies. Lastly, this work adapts a simple two-parameter model to predict SOA concentration and O/C from urban emissions. This model successfully predicts SOA concentration, and the optimal parameter combination is very similar to that found for Mexico City. This approach provides a computationally inexpensive method for predicting urban SOA in global and climate models. We estimate pollution SOA to account for 26 Tg yr−1 of SOA globally, or 17% of global SOA, 1/3 of which is likely to be non-fossil.« less

  3. Apparatus for producing carbon-coated nanoparticles and carbon nanospheres

    DOE Patents [OSTI]

    Perry, W. Lee; Weigle, John C.; Phillips, Jonathan

    2015-10-20

    An apparatus for producing carbon-coated nano- or micron-scale particles comprising a container for entraining particles in an aerosol gas, providing an inlet for carbon-containing gas, providing an inlet for plasma gas, a proximate torch for mixing the aerosol gas, the carbon-containing gas, and the plasma gas, bombarding the mixed gases with microwaves, and providing a collection device for gathering the resulting carbon-coated nano- or micron-scale particles. Also disclosed is a method and apparatus for making hollow carbon nano- or micro-scale spheres.

  4. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  5. A Universal Model for Nanoporous Carbon Supercapacitors Applicable to Diverse Pore Regimes, Carbons, and Electrolyte

    SciTech Connect (OSTI)

    Sumpter, Bobby G; Huang, Jingsong; Meunier, Vincent

    2008-01-01

    Supercapacitors, commonly called electric double-layer capacitors (EDLCs), are emerging as a novel type of energy storage device with the potential to substitute batteries in applications requiring high power densities. In response to the latest experimental breakthrough in nanoporous carbon supercapacitors, we propose a heuristic theoretical model that takes pore curvature into account as a replacement for the EDLC model which is based on a traditional parallel-plate capacitor. When the pore size is in the mesopore regime (2-50 nm), counterions enter mesoporous carbons and approach the pore wall to form an electric double-cylinder capacitor (EDCC); in the micropore regime (< 2 nm), solvated/desolvated counterions line up along the pore axis to form an electric wire-in-cylinder capacitor (EWCC). In the macropore regime (> 50 nm) where pores are large enough so that the pore curvature is no longer significant, the EDCC model can be reduced naturally to the EDLC model. We present density functional theory calculations and detailed analyses of available experimental data in various pore regimes, showing the significant effects of pore curvature on the supercapacitor properties of nanoporous carbons. It is shown that the EDCC/EWCC model is universal to carbon supercapacitors with diverse carbon materials including activated carbons, template carbons, and novel carbide-derived carbons, and with diverse electrolytes including organic electrolytes such as tetraethylammonium tetrafluoroborate (TEABF4), tetraethylammonium methyl-sulfonate (TEAMS) in acetonitrile, aqueous H2SO4 and KOH electrolytes, and even ionic liquid electrolyte such as 1-ethyl-3-methylimmidazolium bis(trifluromethane-sulfonyl)imide (EMI-TFSI). The EDCC/EWCC model allows the supercapacitor properties to be correlated with pore size, specific surface area, Debye length, electrolyte concentration and dielectric constant, and solute ion size, and may lend a support for the systematic optimization of the properties of carbon supercapacitors via experiments. On the basis of the insight obtained from the new model, we also discuss the effects of the kinetic solvation/desolvation process, multimodal (versus unimodal) pore size distribution, and exohedral (versus endohedral) capacitors on the electrochemical properties of supercapacitors.

  6. 2e Carbon Access | Open Energy Information

    Open Energy Info (EERE)

    e Carbon Access Jump to: navigation, search Name: 2e Carbon Access Place: New York, New York Zip: 10280 Sector: Carbon Product: 2E Carbon Access is an enterprise focused solely on...

  7. Less Carbon Ltd | Open Energy Information

    Open Energy Info (EERE)

    Less Carbon Ltd Jump to: navigation, search Name: Less Carbon Ltd Place: London, Greater London, United Kingdom Zip: EC3M 4BT Sector: Carbon Product: Less Carbon advises energy...

  8. SGL Carbon AG | Open Energy Information

    Open Energy Info (EERE)

    Carbon AG Jump to: navigation, search Name: SGL Carbon AG Place: Wiesbaden, Hessen, Germany Zip: 65203 Sector: Carbon Product: A Germany-based manufacturer of carbon-based products...

  9. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO₂- absorbing liquid solvent contained within solid, CO₂-permeable, polymer shells. MECS enhance the rate of CO₂ absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO₂ pressures in stripping conditions,more » relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.« less

  10. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    SciTech Connect (OSTI)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions, relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.

  11. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, Peter; Hemberger, Barbara J.

    1991-01-01

    A process of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a polyolefin tube having an internal diameter of from about 0.01 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the tube, (b) passing a solvent through the tube, said solvent capable of separating the adhered organic contaminant from the tube. Further, a chromatographic apparatus for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium, said apparatus including a polyolefin tube having an internal diameter of from about 0.01 to about 2.0 millimeters and being of sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the tube is disclosed.

  12. Organic photosensitive devices

    DOE Patents [OSTI]

    Peumans, Peter; Forrest, Stephen R.

    2013-01-22

    A photoactive device is provided. The device includes a first electrode, a second electrode, and a photoactive region disposed between and electrically connected to the first and second electrodes. The photoactive region further includes an organic donor layer and an organic acceptor layer that form a donor-acceptor heterojunction. The mobility of holes in the organic donor region and the mobility of electrons in the organic acceptor region are different by a factor of at least 100, and more preferably a factor of at least 1000. At least one of the mobility of holes in the organic donor region and the mobility of electrons in the organic acceptor region is greater than 0.001 cm.sup.2/V-sec, and more preferably greater than 1 cm.sup.2/V-sec. The heterojunction may be of various types, including a planar heterojunction, a bulk heterojunction, a mixed heterojunction, and a hybrid planar-mixed heterojunction.

  13. Nano Structured Activated Carbon for Hydrogen Storge. Project Final Technical Report (May 2, 2005-Dec. 31, 2012)

    SciTech Connect (OSTI)

    Cabasso, Israel; Yuan, Youxin

    2013-02-27

    Development of a nanostructured synthetic carbons materials that have been synthesized by thermal-decomposition of aromatic rich polyether such as poly(ether ether ketone) (PEEK) is reported. These polymers based nanostructured carbons efficacious for gas adsorption and storage and have Brunauer-Emmett-Teller (BET) surface area of more than 3000 m2/g, and with average pore diameter of < 2nm. Surface-area, pore characteristics, and other critical variables for selecting porous materials of high gas adsorption capacities are presented. Analysis of the fragments evolved under various carbonization temperatures, and the correlation between the activation and carbonization temperatures provides a mechanistic perspective of the pore evolution during activation. Correlations between gas (N2 and H2) adsorption capacity and porous texture of the materials have been established. The materials possess excellent hydrogen storage properties, with hydrogen storage capacity up to 7.4 wt% (gravimetric) and ~ 45 g H2 L-1 (volumetric) at -196oC and 6.0 MPa.

  14. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  15. The rare crystallographic structure of d(CGCGCG){sub 2}: The natural spermidine molecule bound to the minor groove of left-handed Z-DNA d(CGCGCG){sub 2} at 10 {sup o}C

    SciTech Connect (OSTI)

    Ohishi, Hirofumi . E-mail: ohishi@gly.oups.ac.jp; Tozuka, Yoshitaka; Da-Yang, Zhou; Ishida, Toshimasa; Nakatani, Kazuhiko

    2007-06-22

    Several crystal structure analyses of complexes of synthetic polyamine compounds, including N {sup 1}-(2-(2-aminoethylamino))ethyl)ethane-1,2-diamine PA(222) and N {sup 1}-(2-(2-(2-aminoethylamino)ethylamino)ethyl)ethane-1,2-diamine PA(2222), and left-handed Z-DNA d(CGCGCG){sub 2} have been reported. However, until now, there have been no examples of naturally occurring polyamines bound to the minor groove of the left-handed Z-DNA of d(CGCGCG){sub 2} molecule. We have found that spermidine, a natural polyamine, is connected to the minor groove of left-handed Z-DNA of d(CGCGCG){sub 2} molecule in a crystalline complex grown at 10 {sup o}C. The electron density of the DNA molecule was clear enough to determine that the spermidine was connected in the minor groove of two symmetry related molecules of left-handed Z-DNA d(CGCGCG){sub 2}. This is the first example that a spermidine molecule can form a bridge conformation between two symmetry related molecules of left-handed Z-DNA d(CGCGCG){sub 2} in the minor groove.

  16. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization View Office of Management Organization Chart in PDF format. Office of Resource Management and Planning The Office of Resource Management and Planning provides the leadership and centralized management and direction of the Office of Management (MA) planning, budgeting, financial, human resources, and program execution processes; ensures that these processes are effective, and fully integrated and consistent with the Department-wide processes and requirements.

  17. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, Richard A.; Lambrecht, Richard M.; Bloomer, William D.

    1989-05-02

    Methods and kits for incorporating a radioactive astatine isotope (particularly .sup.211 At) into an organic compound by electrophilic astatodestannylation of organostannanes.

  18. Laboratory Organization Chart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Board Directorate Staff Org Chart Berkeley Lab Organization Chart ESnet Protective Services ETAESDR ETAEAEI ETA Chief Operating Officer Laboratory Council RIIO...

  19. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, R.A.; Lambrecht, R.M.; Bloomer, W.D.

    1989-05-02

    Methods and kits for incorporating a radioactive astatine isotope (particularly [sup 211]At) into an organic compound by electrophilic astatodestannylation of organostannanes. 3 figs.

  20. Bisfuel links - Professional organizations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professional organizations http://portal.acs.org/portal/acs/corg/content" target="_blank">American Chemical Society

  1. Carbon Capture and Storage, 2008

    ScienceCinema (OSTI)

    None

    2010-01-08

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  2. Carbon Capture and Storage, 2008

    SciTech Connect (OSTI)

    2009-03-19

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  3. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-01

    The Big Sky Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts during the second performance period fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed this quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. To date, there has been little research on soil carbon on rangelands, and since rangeland constitutes a major land use in the Big Sky region, this is important in achieving a better understanding of terrestrial sinks. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO{sub 2} concentrations. Progress on other deliverables is noted in the PowerPoint presentations. A series of meetings held during the second quarter have laid the foundations for assessing the issues surrounding the implementation of a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. Finally, the education and outreach efforts have resulted in a comprehensive plan and process which serves as a guide for implementing the outreach activities under Phase I. While we are still working on the public website, we have made many presentations to stakeholders and policy makers, connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmentally-friendly energy production. In addition, we have laid plans for integration of our outreach efforts with the students, especially at the tribal colleges and at the universities involved in our partnership. This includes collaboration with the film and media arts departments at MSU, with outreach efforts at LANL, and with student section of the ASME. Finally, both Pam Tomski, outreach coordinator, and Susan Capalbo, PI for the Big Sky Partnership will be involved in future U.S.-Norway bilaterals in an effort to provide for an exchange of research and students/faculty.

  4. Tropical forest soil microbial communities couple iron and carbon biogeochemistry

    SciTech Connect (OSTI)

    Dubinsky, E.A.; Silver, W.L.; Firestone, M.K.

    2009-10-15

    We report that iron-reducing bacteria are primary mediators of anaerobic carbon oxidation in upland tropical soils spanning a rainfall gradient (3500 - 5000 mm yr-1) in northeast Puerto Rico. The abundant rainfall and high net primary productivity of these tropical forests provide optimal soil habitat for iron-reducing and iron-oxidizing bacteria. Spatially and temporally dynamic redox conditions make iron-transforming microbial communities central to the belowground carbon cycle in these wet tropical forests. The exceedingly high abundance of iron-reducing bacteria (up to 1.2 x 10{sup 9} cells per gram soil) indicated that they possess extensive metabolic capacity to catalyze the reduction of iron minerals. In soils from the higher rainfall sites, measured rates of ferric iron reduction could account for up to 44 % of organic carbon oxidation. Iron reducers appeared to compete with methanogens when labile carbon availability was limited. We found large numbers of bacteria that oxidize reduced iron at sites with high rates of iron reduction and large numbers of iron-reducers. the coexistence of large populations of ironreducing and iron-oxidizing bacteria is evidence for rapid iron cycling between its reduced and oxidized states, and suggests that mutualistic interactions among these bacteria ultimately fuel organic carbon oxidation and inhibit CH4 production in these upland tropical forests.

  5. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, T.L.; Wilson, J.H.

    1993-09-21

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing. 2 figures.

  6. Method and apparatus for destroying organic contaminants in aqueous liquids

    DOE Patents [OSTI]

    Donaldson, Terrence L.; Wilson, James H.

    1993-01-01

    A method and apparatus for destroying organic contaminants, such as trichloroethylene, in aqueous liquids, such as groundwater, utilizing steam stripping integrated with biodegradation. The contaminated aqueous liquid is fed into a steam stripper causing the volatilization of essentially all of the organic contaminants and a portion of the aqueous liquid. The majority of the aqueous liquid is discharged from the steam stripper. The volatilized vapors are then condensed to the liquid phase and introduced into a bioreactor. The bioreactor contains methanotrophic microorganisms which convert the organic contaminants into mainly carbon dioxide. The effluent from the bioreactor is then recycled back to the steam stripper for further processing.

  7. Mechanism and Kinetic Modeling of Hydrogenation in The Organic Getter/Pd

    Office of Scientific and Technical Information (OSTI)

    Catalyst/Activated Carbon Systems (Journal Article) | SciTech Connect Mechanism and Kinetic Modeling of Hydrogenation in The Organic Getter/Pd Catalyst/Activated Carbon Systems Citation Details In-Document Search Title: Mechanism and Kinetic Modeling of Hydrogenation in The Organic Getter/Pd Catalyst/Activated Carbon Systems Authors: Dinh, L N ; Cairns, G A ; Strickland, R ; McLean II, W ; Maxwell, R S Publication Date: 2014-09-25 OSTI Identifier: 1182700 Report Number(s): LLNL-JRNL-662218

  8. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Mica, biotite, muscovite, diopside, tremolite, ultramafic rock, hematite, Ca-Mg-carbonate, calcite, aragonite, dolomite, crystal nucleation,

  9. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, Mohammad; Yuh, Chao-Yi

    1996-01-01

    A carbonate fuel cell matrix comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles.

  10. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  11. Department of Energy Idaho - Organization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Chart Last Updated: 11/14/2011

  12. Applicant Organization: | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Abengoa Bioenergy Biomass of Kansas, LLC Applicant Organization: Broin Companies

  13. Organization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organization Organization The Office of Economic Impact and Diversity is comprised of: The Office of the Director- contact us Office of Minority Business and Economic Development - contact us Office of Minority Education and Community Development - contact us Office of Civil Rights - contact us Office of Diversity and Inclusion - contact us Stay in Touch Get email updates from our office. Subscribe

  14. Organization Charts | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization Charts Jefferson Lab Organizational Chart 12 GeV Project Organization Accelerator Operations, Research & Development Division Chief Operating Officer Chief Financial Officer Information Technology Division & Chief Information Office Engineering Division Environment, Safety, Health & Quality Experimental Nuclear Physics Division Theory Center

  15. Magnetoelectroluminescence of organic heterostructures: Analytical...

    Office of Scientific and Technical Information (OSTI)

    we present an analytical theory of magnetoelectroluminescence for organic semiconductors. ... AND SUPERFLUIDITY organic semiconductors; spintronics Word Cloud More Like ...

  16. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  17. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R.

    2016-05-03

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  18. Center Organization | Center for Energy Efficient Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Organization People People Scientific Advisory Board Center Organization

  19. Carbon Ion Pump for Carbon Dioxide Removal - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Carbon Ion Pump for Carbon Dioxide Removal Lawrence Livermore National Laboratory Contact LLNL About This Technology Technology Marketing Summary The limitation to reducing greenhouse gases in the atmosphere is the expense of stripping carbon dioxide from other combustion gases. Without a cost-effective means of accomplishing this, hydrocarbon resources cannot be used freely. A few power plants currently remove

  20. Geologic Carbon Sequestration and Biosequestration (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    DePaolo, Don [Director, LBNL Earth Sciences Division

    2011-06-08

    Don DePaolo, Director of LBNL's Earth Sciences Division, speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/