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1

Origins and accumulation of organic matter in expanded Albian to Santonian black shale sequences on the  

E-Print Network [OSTI]

Origins and accumulation of organic matter in expanded Albian to Santonian black shale sequences laminated, Cenoma- nian­Santonian black shale sequences contain between 2% and 15% organic carbon about the depositional conditions leading to the black shale accumulations. The low d13 Corg values

Gilli, Adrian

2

Location and Geology Fig 1. The Macasty black shale  

E-Print Network [OSTI]

, Quebec, is organic-rich black shale and hosting oil and gas. It is equivalent to the Ithaca shaleLocation and Geology Fig 1. The Macasty black shale in the Anticosti Island in the Gulf of St. d13C for calcite disseminated in the black shale range from 2.6o to 2.8 / The values are lower

3

Quantification of loss of calcite, pyrite, and organic matter due to weathering of Toarcian black shales and effects on kerogen and bitumen characteristics  

SciTech Connect (OSTI)

Comparison of geochemical data on Posidonia Shale (Early Toarcian) from a shallow unweathered core and from adjacent weathered exposures of the same facies was performed. Results revealed that quantitatively the most affected petrographic constituent is pyrite and that organic matter and carbonate were also altered by weathering. Due to this process of weathering, the bulk composition of organic matter, especially the molecular composition of soluble organic matter and the fluorescence color of organic particles, are changed. Estimates of weathering rates reveal that the annual release of sulfur and organic carbon from black shales may significantly add to anthropogenic pollution.

Littke, R.; Klussmann, U.; Krooss, B.; Leythaeuser, D. (Inst. fuer Erdoel und organische Geochemie, Juelich (West Germany))

1991-11-01T23:59:59.000Z

4

Comparison of organic-rich shales of Pennsylvanian age in Indiana with New Albany Shale  

SciTech Connect (OSTI)

Abundant black organic-rich shales occur in rocks of Pennsylvanian age in southwestern Indiana. They have not been well characterized except for a few thin intervals in small areas, the best example being at the abandoned Mecca Quarry in west-central Indiana. Although these shales are thinner and less widespread than the organic-rich shales of the New Albany Shale (Devonian and Mississippian age) they warrant characterization because of their accessibility during strip mining of underlying coals. Organic-rich shales of Pennsylvanian age contain up to 44% organic carbon and might be considered potential oil shales. Carbon to hydrogen ratios in these shales are similar to those in the New Albany. Relatively high concentrations of certain metals occur in shales of both ages, especially where phosphate is abundant, and sulfur values for both shales range from < 1 to 6%. Sulfur values are much higher for thin pyrite-rich units. Siderite nodules are common in Pennsylvania shales, but little siderite if found in the New Albany. Dolomite, commonly ferroan, and calcite in a variety of forms are the dominant carbonates in the New Albany. Some Pennsylvanian shales may contain large fossils or mica flakes, but such coarse-grained features are uncommon in the New Albany Shale.

Shaffer, N.R.; Leininger, R.K.; Ennis, M.V.

1983-09-01T23:59:59.000Z

5

Evolution of porosity and geochemistry in Marcellus Formation black shale during weathering  

SciTech Connect (OSTI)

Soils developed on the Oatka Creek member of the Marcellus Formation in Huntingdon, Pennsylvania were analyzed to understand the evolution of black shale matrix porosity and the associated changes in elemental and mineralogical composition during infiltration of water into organic-rich shale. Making the reasonable assumption that soil erosion rates are the same as those measured in a nearby location on a less organic-rich shale, we suggest that soil production rates have on average been faster for this black shale compared to the gray shale in similar climate settings. This difference is attributed to differences in composition: both shales are dominantly quartz, illite, and chlorite, but the Oatka Creek member at this location has more organic matter (1.25 wt.% organic carbon in rock fragments recovered from the bottom of the auger cores and nearby outcrops) and accessory pyrite. During weathering, the extremely low-porosity bedrock slowly disaggregates into shale chips with intergranular pores and fractures. Some of these pores are eitherfilled with organic matter or air-filled but remain unconnected, and thus inaccessible to water. Based on weathering bedrock/soil profiles, disintegration is initiated with oxidation of pyrite and organic matter, which increases the overall porosity and most importantly allows water penetration. Water infiltration exposes fresh surface area and thus promotes dissolution of plagioclase and clays. As these dissolution reactions proceed, the porosity in the deepest shale chips recovered from the soil decrease from 9 to 7% while kaolinite and Fe oxyhydroxides precipitate. Eventually, near the land surface, mineral precipitation is outcompeted by dissolution or particle loss of illite and chlorite and porosity in shale chips increases to 20%. As imaged by computed tomographic analysis, weathering causes i) greater porosity, ii) greater average length of connected pores, and iii) a more branched pore network compared to the unweathered sample. This work highlights the impact of shale water O2interactions in near-surface environments: (1) black shale weathering is important for global carbon cycles as previously buried organic matter is quickly oxidized; and (2) black shales weather more quickly than less organic- and sulfide-rich shales, leading to high porosity and mineral surface areas exposed for clay weathering. The fast rates of shale gas exploitation that are ongoing in Pennsylvania, Texas and other regions in the United States may furthermore lead to release of metals to the environment if reactions between water and black shale are accelerated by gas development activities in the subsurface just as they are by low-temperature processes in ourfield study.

Jin, Lixin [University of Texas at El Paso] [University of Texas at El Paso; Ryan, Mathur [Juniata College, Huntingdon] [Juniata College, Huntingdon; Rother, Gernot [ORNL] [ORNL; Cole, David [Ohio State University] [Ohio State University; Bazilevskaya, Ekaterina [Pennsylvania State University, University Park, PA] [Pennsylvania State University, University Park, PA; Williams, Jennifer [Pennsylvania State University] [Pennsylvania State University; Alex, Carone [Pennsylvania State University] [Pennsylvania State University; Brantley, S. L. [Pennsylvania State University, University Park, PA] [Pennsylvania State University, University Park, PA

2013-01-01T23:59:59.000Z

6

Evolution of porosity and geochemistry in Marcellus Formation black shale during weathering  

SciTech Connect (OSTI)

Soils developed on the Oatka Creek member of the Marcellus Formation in Huntingdon, Pennsylvania were analyzed to understand the evolution of black shale matrix porosity and the associated changes in elemental and mineralogical composition during infiltration of water into organic-rich shale. Making the reasonable assumption that soil erosion rates are the same as those measured in a nearby location on a less organic-rich shale, we suggest that soil production rates have on average been faster for this black shale compared to the gray shale in similar climate settings. This difference is attributed to differences in composition: both shales are dominantly quartz, illite, and chlorite, but the Oatka Creek member at this location has more organic matter (1.25 wt% organic carbon in rock fragments recovered from the bottom of the auger cores and nearby outcrops) and accessory pyrite. During weathering, the extremely low-porosity bedrock slowly disaggregates into shale chips with intergranular pores and fractures. Some of these pores are either filled with organic matter or air-filled but remain unconnected, and thus inaccessible to water. Based on weathering bedrock/soil profiles, disintegration is initiated with oxidation of pyrite and organic matter, which increases the overall porosity and most importantly allows water penetration. Water infiltration exposes fresh surface area and thus promotes dissolution of plagioclase and clays. As these dissolution reactions proceed, the porosity in the deepest shale chips recovered from the soil decrease from 9 to 7 % while kaolinite and Fe oxyhydroxides precipitate. Eventually, near the land surface, mineral precipitation is outcompeted by dissolution or particle loss of illite and chlorite and porosity in shale chips increases to 20%. As imaged by computed tomographic analysis, weathering causes i) greater porosity, ii) greater average length of connected pores, and iii) a more branched pore network compared to the unweathered sample. This work highlights the impact of shale-water-O2 interactions in near-surface environments: (1) black shale weathering is important for global carbon cycles as previously buried organic matter is quickly oxidized; and (2) black shales weather more quickly than less organic- and sulfide-rich shales, leading to high porosity and mineral surface areas exposed for clay weathering. The fast rates of shale gas exploitation that are ongoing in Pennsylvania, Texas and other regions in the United States may furthermore lead to release of metals to the environment if reactions between water and black shale are accelerated by gas development activities in the subsurface just as they are by low-temperature processes in our field study.

Jin, Lixin [ORNL; Mathur, Ryan [Juniata College, Huntingdon; Rother, Gernot [ORNL; Cole, David [Ohio State University; Bazilevskaya, Ekaterina [Pennsylvania State University, University Park, PA; Williams, Jennifer [Pennsylvania State University; Carone, Alex [Pennsylvania State University, University Park, PA; Brantley, Susan L [ORNL

2013-01-01T23:59:59.000Z

7

Paleoecology of the Devonian-Mississippian black-shale sequence in eastern Kentucky with an atlas of some common fossils  

SciTech Connect (OSTI)

The Devonian-Mississippian black-shale sequence of eastern North America is a distinctive stratigraphic interval generally characterized by low clastic influx, high organic production in the water column, anaerobic bottom conditions, and the relative absence of fossil evidence for biologic activity. The laminated black shales which constitute most of the black-shale sequence are broken by two major sequences of interbedded greenish-gray, clayey shales which contain bioturbation and pyritized micromorph invertebrates. The black shales contain abundant evidence of life from upper parts of the water column such as fish fossils, conodonts, algae and other phytoplankton; however, there is a lack of evidence of benthic life. The rare brachiopods, crinoids, and molluscs that occur in the black shales were probably epiplanktic. A significant physical distinction between the environment in which the black sediments were deposited and that in which the greenish-gray sediments were deposited was the level of dissolved oxygen. The laminated black shales point to anaerobic conditions and the bioturbated greenish-gray shales suggest dysaerobic to marginally aerobic-dysaerobic conditions. A paleoenvironmental model in which quasi-estuarine circulation compliments and enhances the effect of a stratified water column can account for both depletion of dissolved oxygen in the bottom environments and the absence of oxygen replenishment during black-shale deposition. Periods of abundant clastic influx from fluvial environments to the east probably account for the abundance of clays in the greenish-gray shale as well as the small amounts of oxygen necessary to support the depauparate, opportunistic, benthic faunas found there. These pulses of greenish-gray clastics were short-lived and eventually were replaced by anaerobic conditions and low rates of clastic sedimentation which characterized most of black-shale deposition.

Barron, L.S.; Ettensohn, F.R.

1981-04-01T23:59:59.000Z

8

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

Brandon C. Nuttall

2003-02-10T23:59:59.000Z

9

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

Brandon C. Nuttall

2003-04-28T23:59:59.000Z

10

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

Brandon C. Nuttall

2003-02-11T23:59:59.000Z

11

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2004-01-01T23:59:59.000Z

12

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 percent (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2004-04-01T23:59:59.000Z

13

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2003-10-29T23:59:59.000Z

14

Effects of diagenesis on the Nd-isotopic composition of black shales from the 420 Ma Utica Shale Magnafacies  

E-Print Network [OSTI]

-isotopic ratios were measured in whole rock black shales with different grades of thermal maturity from the Utica/Sm that cannot be explained solely by diagenesis, implying source heterogeneity. Whole rock black shales maturation), which alters the Sm/Nd ratio of the rock, it can be argued that the different components

Basu, Asish R.

15

DISTRIBUTION OF NATURALLY OCCURRING RADIONUCLIDES (U, Th) IN TIMAHDIT'S BLACK SHALE (MOROCCO)  

E-Print Network [OSTI]

focused on the use of Moroccan's black oil shales as the raw materials for production of a new type, 1991). These adsorbents were produced from oil shale, which is abundant in Morocco. The choice

Paris-Sud XI, Université de

16

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2003-07-28T23:59:59.000Z

17

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-04-26T23:59:59.000Z

18

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-07-29T23:59:59.000Z

19

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-01-28T23:59:59.000Z

20

Sulfide-Driven Arsenic Mobilization from Arsenopyrite and Black Shale Pyrite  

SciTech Connect (OSTI)

We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As-1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O2), hypoxic (2% O2, 98% N2), and anoxic (5% H2, 95% N2) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (-1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.

Zhu, W.; Young, L; Yee, N; Serfes, M; Rhine, E; Reinfelder, J

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library are being sampled to collect CO{sub 2} adsorption isotherms. Sidewall core samples have been acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log has been acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 4.62 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 19 scf/ton in less organic-rich zones to more than 86 scf/ton in the Lower Huron Member of the shale. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2004-08-01T23:59:59.000Z

22

Organic and inorganic hazardous waste stabilization using combusted oil shale  

SciTech Connect (OSTI)

A laboratory study was conducted at the Western Research Institute to evaluate the ability of combusted oil shale to stabilize organic and inorganic constituents of hazardous wastes. The oil shale used in the research was a western oil shale retorted in an inclined fluidized-bed reactor. Two combustion temperatures were used, 1550{degrees}F and 1620{degrees}F (843{degrees}C and 882{degrees}C). The five wastes selected for experimentation were an API separator sludge, creosote-contaminated soil, mixed metal oxide/hydroxide waste, metal-plating sludge, and smelter dust. The API separator sludge and creosote-contaminated soil are US EPA-listed hazardous wastes and contain organic contaminants. The mixed metal oxide/hydroxide waste, metal-plating sludge (also an EPA-listed waste), and smelter dust contain high concentrations of heavy metals. The smelter dust and mixed metal oxide/hydroxide waste fail the Toxicity Characteristic Leaching Procedure (TCLP) for cadmium, and the metalplating sludge fails the TCLP for chromium. To evaluate the ability of the combusted oil shales to stabilize the hazardous wastes, mixtures involving varying amounts of each of the shales with each of the hazardous wastes were prepared, allowed to equilibrate, and then leached with deionized, distilled water. The leachates were analyzed for the hazardous constituent(s) of interest.

Sorini, S.S.; Lane, D.C.

1991-04-01T23:59:59.000Z

23

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-01-01T23:59:59.000Z

24

Paper #194973 GEOCHEMICAL CHARACTERIZATION OF THE RESERVOIR HOSTING SHALE-GAS AND OIL in  

E-Print Network [OSTI]

Paper #194973 GEOCHEMICAL CHARACTERIZATION OF THE RESERVOIR HOSTING SHALE-GAS AND OIL a reservoir for shale-gas and oil. We examined organic-rich black shale, known as Macasty shale, of Upper SHALE-GAS AND OIL in THE SUBSURFACE OF ANTICOSTI ISLAND, CANADA Key Words: Provenance, Anticosti Island

25

Intergrated study of the Devonian-age black shales in eastern Ohio. Final report  

SciTech Connect (OSTI)

This integrated study of the Devonian-age shales in eastern Ohio by the Ohio Department of Natural Resources, Division of Geological Survey is part of the Eastern Gas Shales Project sponsored by the US Department of Energy. The six areas of research included in the study are: (1) detailed stratigraphic mapping, (2) detailed structure mapping, (3) mineralogic and petrographic characterization, (4) geochemical characterization, (5) fracture trace and lineament analysis, and (6) a gas-show monitoring program. The data generated by the study provide a basis for assessing the most promising stratigraphic horizons for occurrences of natural gas within the Devonian shale sequence and the most favorable geographic areas of the state for natural gas exploration and should be useful in the planning and design of production-stimulation techniques. Four major radioactive units in the Devonian shale sequence are believed to be important source rocks and reservoir beds for natural gas. In order of potential for development as an unconventional gas resource, they are (1) lower and upper radioactive facies of the Huron Shale Member of the Ohio Shale, (2) upper Olentangy Shale (Rhinestreet facies equivalent), (3) Cleveland Shale Member of the Ohio Shale, and (4) lower Olentangy Shale (Marcellus facies equivalent). These primary exploration targets are recommended on the basis of areal distribution, net thickness of radioactive shale, shows of natural gas, and drilling depth to the radioactive unit. Fracture trends indicate prospective areas for Devonian shale reservoirs. Good geological prospects in the Devonian shales should be located where the fracture trends coincide with thick sequences of organic-rich highly radioactive shale.

Gray, J.D.; Struble, R.A.; Carlton, R.W.; Hodges, D.A.; Honeycutt, F.M.; Kingsbury, R.H.; Knapp, N.F.; Majchszak, F.L.; Stith, D.A.

1982-09-01T23:59:59.000Z

26

Synthesis of organic geochemical data from the Eastern Gas Shales  

SciTech Connect (OSTI)

Over 2400 core and cuttings samples of Upper Devonian shales from wells in the Appalachian, Illinois, and Michigan Basins have been characterized by organic geochemical methods to provide a basis for accelerating the exploitation of this unconventional, gas-rich resource. This work was part of a program initiated to provide industry with criteria for locating the best areas for future drilling and for the development of stimulation methods that will make recovery of the resource economically attractive. The geochemical assessment shows that the shale, in much of the Appalachian, Illinois, and Michigan Basins is source rock that is capable of generating enormous quantities of gas. In some areas the shales are also capable of generating large quantities of oil as well. The limiting factors preventing these sources from realizing most of their potential are their very low permeabilities and the paucity of potential reservoir rocks. This geochemical data synthesis gives direction to future selection of sites for stimulation research projects in the Appalachian Basin by pinpointing those areas where the greatest volumes of gas are contained in the shale matrix. Another accomplishment of the geochemical data synthesis is a new estimate of the total resource of the Appalachian Basin. The new estimate of 2500 TCF is 25 percent greater than the highest previous estimates. This gives greater incentive to government and industry to continue the search for improved stimulation methods, as well as for improved methods for locating the sites where those improved stimulation methods can be most effectively applied.

Zielinski, R.E.; McIver, R.D.

1982-01-01T23:59:59.000Z

27

Transport and reduction of sulfate and immobilization of sulfide in marine black shales  

SciTech Connect (OSTI)

In fine-grained sediments in which the amount of reduced sulfur retained in stable phases substantially exceeds that present initially in pore waters, rates of sulfate reduction may have equaled or exceeded rates of sulfate transport, resulting in enrichment of [sup 34]S in pore waters and reduction products. Abundance and isotopic compositions of reduced sulfur compounds can be used to calculate the extent of sulfide retention and improve reconstructions of carbon-sulfur oxidation-reduction (redox) budgets. The Miocene Monterey Formation and Upper Devonian New Albany Shale represent distinct types of black shales that accumulated under different conditions of sulfate reduction. Our results suggest that the rate of sulfate reduction was controlled largely by mass transport in the Monterey and by the reduction process itself in the New Albany. Sulfide was more efficiently retained in the Monterey; thus each mole of sulfide in the New Albany represents a greater amount of sedimented organic carbon removed during sulfate reduction. 30 refs., 4 figs., 1 tab.

Zaback, D.A.; Pratt, L.M.; Hayes, J.M. (Indiana Univ., Bloomington (United States))

1993-02-01T23:59:59.000Z

28

Oil and Gas CDT Are non-marine organic-rich shales suitable exploration  

E-Print Network [OSTI]

Oil and Gas CDT Are non-marine organic-rich shales suitable exploration targets? The University Hesselbo, University of Exeter http://emps.exeter.ac.uk/csm/staff/sph216 Key Words Shales, depositional environments, diagenesis, sedimentology, geochemistry Overview Shales are of increasing interest not only

Henderson, Gideon

29

Plants of Devonian-Mississippian black shales, eastern interior, USA  

SciTech Connect (OSTI)

Macrofossils of the New Albany shale and equivalents of Late Devonian of Early Mississippian age in the east-central United States are known from three main floras or assemblages. One flora is almost entirely composed of Callixylon logs, slabs, and slivers, presumed to be driftwood permineralized after burial. Callixylon fossils are most abundant in the upper part of the Clegg Creek Member of the New Albany shale (Famennian) and equivalent strata in western New York, Ohio, and contiguous areas, perhaps because these Propymnosperms reached the zenith of their development at that time. A second, and later, flora consists principally of permineralized wood pieces (phosphatized free-wood or concretions) of stems, rachises, petioles, and possibly even mid-veins of pinnules of diverse members of the Lycopsida, Sphenopsida, Cladoxylales, Coenopteridales, Progymnospermae, and Pteridospermae. The principal concentration of these stem and petiolar segments is in the Falling Run Member of Sanderson Formation of the New Albany shale on the west side of the Cincinnati arch in southern Indiana and Kentucky, and in central Kentucky in the low saddle between the Cincinnati arch proper and its southward extension as the Nashville dome. The third type of macrofossil plant assemblage is consituted of Foerstia. These plants are considered to be algal in origin and indicate no clear relationship either to distance from shore or depth of water. The main concentration is in middle and lower New Albany shale and equivalents. It is also found sparingly in West Virginia and Michigan and much farther west (one specimen from the Exshaw shale of Montana).

Cross, A.T.

1983-03-01T23:59:59.000Z

30

Forecasting Gas Production in Organic Shale with the Combined Numerical Simulation of Gas Diffusion in Kerogen, Langmuir Desorption from  

E-Print Network [OSTI]

SPE 159250 Forecasting Gas Production in Organic Shale with the Combined Numerical Simulation algorithm to forecast gas production in organic shale that simultaneously takes into account gas diffusion-than-expected permeability in shale-gas formations, while Langmuir desorption maintains pore pressure. Simulations confirm

Torres-Verdín, Carlos

31

Improved Detection of Bed Boundaries for Petrophysical Evaluation with Well Logs: Applications to Carbonate and Organic-Shale Formations  

E-Print Network [OSTI]

: Applications to Carbonate and Organic-Shale Formations Zoya Heidari, SPE, Texas A&M University and Carlos of well logs acquired in organic shales and carbonates is challenging because of the presence of thin beds acquired in thinly bedded carbonates and in the Haynesville shale-gas formation. Estimates of petrophysical

Torres-Verdín, Carlos

32

ORGANIC GEOCHEMICAL CHARACTERIZATION AND MINERALOGIC PROPERTIES OF MENGEN OIL SHALE (LUTETIAN  

E-Print Network [OSTI]

, lignite, and oil shale sequences. Oil shale deposit has been accumulated in shallow restricted back

unknown authors

33

Coordinated study of the Devonian black shale in the Illinois Basin: Illinois, Indiana, and western Kentucky. Final report  

SciTech Connect (OSTI)

An evaluation of the resource potential of the Devonian shales, called the Eastern Gas Shales Project (EGSP) was begun. A study of the stratigraphy, structure, composition, and gas content of the Devonian shale in the Illinois Basin was undertaken by the State Geological Surveys of Illinois, Indiana, and Kentucky, under contract to the U.S. DOE as a part of the EGSP. Certain additional data were also developed by other research organizations (including Monsanto Research Corporation-Mound Facility and Battelle-Columbus Laboratory) on cores taken from the Illinois Basin. This report, an overview of geological data on the Illinois basin and interpretations of this data resulting from the EGSP, highlights areas of potential interest as exploration targets for possible natural gas resources in the Devonian shale of the basin. The information in this report was compiled during the EGSP from open file data available at the three State Geological surveys and from new data developed on cores taken by the DOE from the basin specifically for the EGSP. The organically richest shale is found in southeastern Illinois and in most of the Indiana and Kentucky portions of the Illinois Basin. The organic-rich shales in the New Albany are thickest near the center of the basin in southeastern Illinois, southwestern Indiana, and adjacent parts of Kentucky portions of the Illinois Basin. The organic-rich shales in the New Albany are thickest near the center of the basin in southeastern Illinois, southwestern Indiana, and adjacent parts of Kentucky. Natural fractures in the shale may aid in collecting gas from a large volume of shale. These fractures may be more abundant and interconnected to a greater degree in the vicinity of major faults. Major faults along the Rough Creek Lineament and Wabash Valley Fault System cross the deeper part of the basin.

Lineback, J.A.

1980-12-31T23:59:59.000Z

34

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

decomposition of kerogen to shale oil and related by~of Oil Shale to Produce Shale Oil and Related Byproducts.Ref. 3). Chemis of Oil Shale Oil shale is a sedimentary

Amy, Gary L.

2013-01-01T23:59:59.000Z

35

Relationship between bitumen maturity and organic facies in Devonian shales from the Appalachian basin  

SciTech Connect (OSTI)

Variation in several bitumen maturity parameters was studied in a core of Devonian shale from the central Appalachian basin. Kerogens in the shales are at maturity levels equivalent to the early stages of oil generation and range in composition from Type III-IV to Type II-III. Maturity parameters based on steranes, terpanes, and n-alkanes exhibit fluctuations that are unrelated to thermal maturity changes in the core. The parameters correlate with one another to a high degree and appear to be directly or indirectly related to the organic facies of the shales. The maturity level indicated by each parameter increases with total organic carbon (TOC) content and hydrogen index value. The greatest variation occurs in rocks with TOC values below 2% and hydrogen index values below 250. The data provide a good opportunity to examine the dependency of bitumen maturity on organic facies, and they highlight a caveat to be considered during interpretation.

Daly, A.R.

1988-01-01T23:59:59.000Z

36

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

from Characterization of Spent Shale s . , , . . . ,4. Preparation of Spent Shale Samples and Procedure forof Particular Types of Spent Shale References Appendix A.

Amy, Gary L.

2013-01-01T23:59:59.000Z

37

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

OF FIGURES Areal extent of oil shale deposits in the Greencommercial in~situ oil shale facility. Possible alternativefor pyrolysis of oil shale Figure 7. Establishment of

Amy, Gary L.

2013-01-01T23:59:59.000Z

38

Petrographic observations suggestive of microbial mats from Rampur Shale and Bijaigarh Shale,  

E-Print Network [OSTI]

Petrographic observations suggestive of microbial mats from Rampur Shale and Bijaigarh Shale observations of two Vindhyan black shales (Rampur Shale of the Semri Group and Bijaigarh Shale of the Kaimur an attempt has been made to highlight possible microbial mat features from two black shale horizons (Rampur

Schieber, Juergen

39

4D imaging of fracturing in organic-rich shales during heating1 Maya Kobchenko1  

E-Print Network [OSTI]

1 4D imaging of fracturing in organic-rich shales during heating1 2 Maya Kobchenko1 , Hamed Panahi1, Ecully CEDEX,9 France.10 5 Idaho National Laboratory, Idaho Falls, USA11 6 Institute for Energy Technology, Kjeller, Norway12 13 #12;2 Abstract14 To better understand the mechanisms of fracture pattern

Boyer, Edmond

40

ORGANIC GEOCHEMISTRY, DEPOSITIONAL ENVIRONMENT AND HYDROCARBON POTENTIAL OF THE TERTIARY OIL SHALE DEPOSITS IN NW ANATOLIA, TURKEY  

E-Print Network [OSTI]

In this study, organic geochemical characteristics and depositional environ-ment of the Tertiary-aged oil shale deposits in Northwest Anatolia have been examined. Oil shales in all the studied areas are typically characterized by high hydrogen index and low oxygen index values. Beypazar?

R. Kara Glbay; S. Korkmaz

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

4D imaging of fracturing in organic-rich shales during heating  

SciTech Connect (OSTI)

To better understand the mechanisms of fracture pattern development and fluid escape in low permeability rocks, we performed time-resolved in situ X-ray tomography imaging to investigate the processes that occur during the slow heating (from 60 to 400 C) of organic-rich Green River shale. At about 350 C cracks nucleated in the sample, and as the temperature continued to increase, these cracks propagated parallel to shale bedding and coalesced, thus cutting across the sample. Thermogravimetry and gas chromatography revealed that the fracturing occurring at {approx}350 C was associated with significant mass loss and release of light hydrocarbons generated by the decomposition of immature organic matter. Kerogen decomposition is thought to cause an internal pressure build up sufficient to form cracks in the shale, thus providing pathways for the outgoing hydrocarbons. We show that a 2D numerical model based on this idea qualitatively reproduces the experimentally observed dynamics of crack nucleation, growth and coalescence, as well as the irregular outlines of the cracks. Our results provide a new description of fracture pattern formation in low permeability shales.

Maya Kobchenko; Hamed Panahi; Franois Renard; Dag K. Dysthe; Anders Malthe-Srenssen; Adriano Mazzini; Julien Scheibert1; Bjrn Jamtveit; Paul Meakin

2011-12-01T23:59:59.000Z

42

Bibliography of the paleontology and paleoecology of the Devonian-Mississippian black-shale sequence in North America  

SciTech Connect (OSTI)

The Devonian-Mississippian black-shale sequence is one of the most prominent and well-known stratigraphic horizons in the Paleozoic of the United States, yet the paleontology and its paleoecologic and paleoenvironmental implications are poorly known. This is in larger part related to the scarcity of fossils preserved in the shale - in terms of both diversity and abundance. Nonetheless, that biota which is preserved is well-known and much described, but there is little synthesis of this data. The first step in such a synthesis is the compilation of an inclusive bibliography such as this one. This bibliography contains 1193 entries covering all the major works dealing with Devonian-Mississippian black-shale paleontology and paleoecology in North America. Articles dealing with areas of peripheral interest, such as paleogeography, paleoclimatology, ocean circulation and chemistry, and modern analogues, are also cited. In the index, the various genera, taxonomic groups, and other general topics are cross-referenced to the cited articles. It is hoped that this compilation will aid in the synthesis of paleontologic and paleoecologic data toward a better understanding of these unique rocks and their role as a source of energy.

Barron, L.S.; Ettensohn, F.R.

1980-06-01T23:59:59.000Z

43

SPECIATION OF TRACE ORGANIC LIGANDS AND INORGANIC AND ORGANOMETALLIC COMPOUNDS IN OIL SHALE PROCESS WATERS  

E-Print Network [OSTI]

organoarsenic compounds in oi.l shale process waters using aPresented at the 13th Oil Shale Symposium, Golden, CO, April~1ETALLIC COMPOUNDS IN OIL SHALE PROCESS WATERS Richard H.

Fish, Richard H.

2013-01-01T23:59:59.000Z

44

SPECIATION OF TRACE ORGANIC LIGANDS AND INORGANIC AND ORGANOMETALLIC COMPOUNDS IN OIL SHALE PROCESS WATERS  

E-Print Network [OSTI]

Presented at the 13th Oil Shale Symposium, Golden, CO, April~1ETALLIC COMPOUNDS IN OIL SHALE PROCESS WATERS Richard H.compounds in the seven oil shale process waters. These

Fish, Richard H.

2013-01-01T23:59:59.000Z

45

A high liquid yield process for retorting various organic materials including oil shale  

DOE Patents [OSTI]

This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer. The reheated acidic catalyst is separated from the mineral matter and again mixed with fresh organic material, to maintain the continuously cyclic process. 2 figs.

Coburn, T.T.

1988-07-26T23:59:59.000Z

46

High liquid yield process for retorting various organic materials including oil shale  

DOE Patents [OSTI]

This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer. The reheated acidic catalyst is separated from the mineral matter and again mixed with fresh organic material, to maintain the continuously cyclic process.

Coburn, Thomas T. (Livermore, CA)

1990-01-01T23:59:59.000Z

47

Identification of organic compounds contained in the bitumen of Chattanooga oil shale  

SciTech Connect (OSTI)

The bitumen of Chattanooga Oil Shale has been extracted with benzene. The benzene-soluble material was separated into acid base and neutral fractions with ion exchange chromatography. This separation scheme has been used extensively to separate the organic material in Green River Oil Shale. The acid fraction was esterified with BF/sub 3//MeOH. A large portion of the acid fraction was not esterified and this material was considered to be phenolic. The bases were separated into two fractions using alumina. The esters, the two base fractions and the total neutral fraction were analyzed using gas chromatography coupled to mass spectrometry. Two series constituting the methyl esters of normal and isoprenoid acids were identified. Several homologous series were indicated in the base fraction. The major components in the neutral fractions were two series constituting normal and isoprenoid alkanes. The analysis scheme apparently does a good job of separating and identifying aliphatic materials.

Mc Gowan, C.W.; Greenwell, B.E.; Markuszewski, R.; Richard, J.J.; Sepaniak, M.J.

1986-09-01T23:59:59.000Z

48

Clarification of C-S relationships of marine black shales using stable isotopic composition of reduced sulfur  

SciTech Connect (OSTI)

Carbon-sulfur relationships are compared for the Miocene Monterey Formation (Santa Maria Basin, California) and the Upper Devonian New Albany Shale (Illinois Basin, Indiana). In both formations, C-S concentrations covary for samples with the lower to more intermediate organic carbon concentrations and become invariant at higher organic carbon concentrations. While the similarity of these relationships in Monterey and New Albany suggest sulfur diagenesis occurred in similar depositional environments, sulfur isotopic data clearly indicate differences in the depositional environments. In the Monterey, the most organic-rich laminated shales are characterized by isotopic enrichment of reduced S and low S ratios and indicate that sulfate reduction occurred under sulfate-limited conditions within the sediments. In the New Albany, organic-rich laminated shales exhibit isotopic depletion of reduced S coupled with low S[sub reduced]/C[sub org] and suggest sulfur diagenesis occurred under euxinic conditions. These data show that in the absence of sulfur isotopic data, misleading conclusions concerning depositional environments can be made when using C-S plots and the traditional interpretations that are associated with these types of plots.

Zaback, D.A.; Pratt, L.M. (Indiana Univ., Bloomington, IN (United States). Dept. of Geological Sciences)

1992-01-01T23:59:59.000Z

49

Lattice Boltzmann prediction of transport properties in reconstructed nanostructures of organic matters in shales  

E-Print Network [OSTI]

Size, morphology and distributions of pores in organic matters of shale matrix are discussed based on high resolution images from experiments in the literature. 150 nanoscale structures of the organic matters are then reconstructed by randomly placing pore spheres with different diameters and overlap tolerances. Effects of porosity, the mean diameter and the overlap tolerance on void space connectivity and pore size distribution are studied. Further, a pore-scale model based on the Lattice Boltzmann method is developed to predict the Knudsen diffusivity and permeability of the reconstructed organic matters. The simulation results show that the mean pore diameter and overlap tolerance significantly affect the transport properties. The predicted Knudsen effective diffusivity is compared with Bruggeman equation and it is found that this equation underestimate the tortuosity. A modified Bruggeman equation is proposed based on the simulation results. The predicted intrinsic permeability is in acceptable agreement ...

Chen, Li; Zhang, Lei; Tao, Wenquan

2014-01-01T23:59:59.000Z

50

Devonian shale gas resource assessment, Illinois basin  

SciTech Connect (OSTI)

In 1980 the National Petroleum Council published a resource appraisal for Devonian shales in the Appalachian, Michigan, and Illinois basins. Their Illinois basin estimate of 86 TCFG in-place has been widely cited but never verified nor revised. The NPC estimate was based on extremely limited canister off-gas data, used a highly simplified volumetric computation, and is not useful for targeting specific areas for gas exploration. In 1994 we collected, digitized, and normalized 187 representative gamma ray-bulk density logs through the New Albany across the entire basin. Formulas were derived from core analyses and methane adsorption isotherms to estimate total organic carbon (r{sup 2}=0.95) and gas content (r{sup 2}=0.79-0.91) from shale bulk density. Total gas in place was then calculated foot-by-foot through each well, assuming normal hydrostatic pressures and assuming the shale is gas saturated at reservoir conditions. The values thus determined are similar to peak gas contents determined by canister off-gassing of fresh cores but are substantially greater than average off-gas values. Greatest error in the methodology is at low reservoir pressures (or at shallow depths), however, the shale is generally thinner in these areas so the impact on the total resource estimate is small. The total New Albany gas in place was determined by integration to be 323 TCFG. Of this, 210 TCF (67%) is in the upper black Grassy Creek Shale, 72 TCF (23%) in the middle black and gray Selmier Shale, and 31 TCF (10%) in the basal black Blocher Shale. Water production concerns suggest that only the Grassy Creek Shale is likely to be commercially exploitable.

Cluff, R.M.; Cluff, S.G.; Murphy, C.M. [Discovery Group, Inc., Denver, CO (United States)

1996-12-31T23:59:59.000Z

51

Devonian shale gas resource assessment, Illinois basin  

SciTech Connect (OSTI)

In 1980 the National Petroleum Council published a resource appraisal for Devonian shales in the Appalachian, Michigan, and Illinois basins. Their Illinois basin estimate of 86 TCFG in-place has been widely cited but never verified nor revised. The NPC estimate was based on extremely limited canister off-gas data, used a highly simplified volumetric computation, and is not useful for targeting specific areas for gas exploration. In 1994 we collected, digitized, and normalized 187 representative gamma ray-bulk density logs through the New Albany across the entire basin. Formulas were derived from core analyses and methane adsorption isotherms to estimate total organic carbon (r[sup 2]=0.95) and gas content (r[sup 2]=0.79-0.91) from shale bulk density. Total gas in place was then calculated foot-by-foot through each well, assuming normal hydrostatic pressures and assuming the shale is gas saturated at reservoir conditions. The values thus determined are similar to peak gas contents determined by canister off-gassing of fresh cores but are substantially greater than average off-gas values. Greatest error in the methodology is at low reservoir pressures (or at shallow depths), however, the shale is generally thinner in these areas so the impact on the total resource estimate is small. The total New Albany gas in place was determined by integration to be 323 TCFG. Of this, 210 TCF (67%) is in the upper black Grassy Creek Shale, 72 TCF (23%) in the middle black and gray Selmier Shale, and 31 TCF (10%) in the basal black Blocher Shale. Water production concerns suggest that only the Grassy Creek Shale is likely to be commercially exploitable.

Cluff, R.M.; Cluff, S.G.; Murphy, C.M. (Discovery Group, Inc., Denver, CO (United States))

1996-01-01T23:59:59.000Z

52

A tale of shales: the relative roles of production, decomposition, and dilution in the accumulation of organic-rich strata,  

E-Print Network [OSTI]

and Paleontology, New York State Museum, The State Education Department, Albany, NY 12230, USA e College of MarineA tale of shales: the relative roles of production, decomposition, and dilution in the accumulation Abstract A new consensus on the processes responsible for organic carbon burial in ancient epeiric seas has

Sageman, Brad

53

Determination of organic inorganic associations of trace elements in New Albany shale kerogen  

SciTech Connect (OSTI)

The inorganic and organic trace element associations in the kerogen isolated from the New Albany shale were studied by analysis of kerogen fractions and a mineral residue obtained using density separations. Elemental mass balance data from these fractions indicate a predominantly inorganic association with pyrite and marcasite for several elements (As, Co, Ga, Mn, Ni, Sb and Se). The degree of inorganic association of these elements was determined by treatment of the mineral residue ({approximately}85% FeS{sub 2}) with dilute HNO{sub 3} to remove pyrite and marcasite. The association of several other elements in minerals which are insoluble in dilute HNO{sub 3} (rutile, zircon, etc.) were also determined. The results of these studies indicate an essentially total organic association for V and approximately 95% organic association for Ni in New Albany kerogen. The determination of organically combined elements is very difficult for those elements which are predominantly concentrated in the mineral fraction. Correction methods based on low temperature ashing, chemical removal of pyrite, and physical methods of separation are compared.

Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

54

UK Oil and Gas Collaborative Doctoral Training Centre (2014 start) Project Title: Are non-marine organic-rich shales suitable exploration targets?  

E-Print Network [OSTI]

UK Oil and Gas Collaborative Doctoral Training Centre (2014 start) Project Title: Are non-marine organic-rich shales suitable exploration targets? (EARTH-15-SR2) Host institution: University of Oxford Supervisor 1: Stuart Robinson Supervisor 2: Steve Hesselbo (University of Exeter) Project description: Shales

Henderson, Gideon

55

OIL SHALE  

E-Print Network [OSTI]

Seyitmer, Himmeto?lu and Hat?lda? oil shale deposits. The results demonstrate that these oil shales are

Fields (in-situ Combustion Approach; M. V. Kk; G. Guner; S. Bagci?

56

Organic-matter preservation in Chattanooga Shale: revised Late Devonian correlations, Kentucky and Tennessee  

SciTech Connect (OSTI)

Continued interest in the carbon-rich shale of Devonian and Mississippian age in Kentucky is reflected by intensive leasing and drilling to evaluate the potential reserves of oil shale. Thicker accumulations of shale suitable for surface extraction lie along the flanks of the Cincinnati arch in both the Illinois and Appalachian basins. The shale tends to thin across the Cincinnati arch by an order of magnitude (100 versus 10 m, 330 versus 33 ft), and individual units disappear entirely. Key beds have been used with mixed success in tracing these changes. Recognition of these key beds in cores provided by a recently completed 70-core drilling program in and near the outcrop is the basis for revising earlier suggested correlations. One key bed, marked by the occurrence of the alga. Foerstia (Protosalvinia), occurs in the lower part of the lower (Huron) member of the Ohio Shale in the Appalachian basin. The Huron Member is overlain by a lithostratigraphic marker, the Three Lick Bed. The Foerstia Zone has been traced in core and outcrop to the upper part of the uppermost (Clegg Creek) member of the New Albany Shale in the Illinois basin. Discovery in this widespread continuous biostratigraphic marker at the top of the upper (Gassaway) member of the Chattanooga Shale near the designated reference section in Dekalb County, Tennessee, suggests that the Three Lick Bed of the Ohio Shales does not correlate with the unit of the Gassaway Member of the Chattanooga Shale as thought. Field relations indicate that the Three Lick Bed is absent by nondeposition, and starved-basin conditions prevailed into Early Mississippian time in this part of Tennessee.

Kepferle, R.C.; Pollock, J.D.; Barron, L.S.

1983-03-01T23:59:59.000Z

57

Rock Physics Characterization of Organic-Rich Shale Formations to Predict Organic Properties  

E-Print Network [OSTI]

rely on to assess the economic potential of these formations are: total organic carbon (TOC), thermal maturity, hydrocarbon saturation, porosity, mineralogy and brittleness. In this thesis, I investigate rock physics models and methods for the possible...

Bush, Brandon

2013-07-29T23:59:59.000Z

58

CONTAMINATION OF GROUNDWATER BY ORGANIC POLLUTANTS LEACHED FROM IN-SITU SPENT SHALE  

E-Print Network [OSTI]

Bureau of Mines (USBM) gas combustion retorting process; (2)th or without recycle gas), combustion conditions exist durTvoe Combustion Inert gas Combustion Inert gas Air gas shale

Amy, Gary L.

2013-01-01T23:59:59.000Z

59

REGIONAL DEPOSITIONAL TRENDS IN THE DEVONIAN GENESEO/BURKET BLACK SHALE BASED ON GAMMA RAY-DENSITY TRENDS.  

E-Print Network [OSTI]

??ABSTRACTGas shales are becoming increasingly important as new technologies are applied to enhance their production of natural gas. The Barnett, the Fayetteville, and the Haynesville (more)

Arnold, LaMichelle

2010-01-01T23:59:59.000Z

60

Distribution and origin of ethyl-branched alkanes in a Cenomanian transgressive shale of the Western Interior  

E-Print Network [OSTI]

Note Distribution and origin of ethyl-branched alkanes in a Cenomanian transgressive shale hydrocarbon fraction of the basal Graneros Shale (Cenomanian, Western Interior Seaway, USA). On the basis rights reserved. Keywords: Monoethylalkanes; Branched alkanes; Black shales; Cenomanian; Graneros Shale

Kenig, Fabien

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Multi-scale Detection of Organic and Inorganic Signatures Provides Insights into Gas Shale Properties and Evolution  

SciTech Connect (OSTI)

Organic geochemical analyses, including solvent extraction or pyrolysis, followed by gas chromatography and mass spectrometry, are generally conducted on bulk gas shale samples to evaluate their source and reservoir properties. While organic petrology has been directed at unravelling the matrix composition and textures of these economically important unconventional resources, their spatial variability in chemistry and structure is still poorly documented at the sub-micrometre scale. Here, a combination of techniques including transmission electron microscopy and a synchrotron-based microscopy tool, scanning transmission X-ray microscopy, have been used to characterize at a multiple length scale an overmature organic-rich calcareous mudstone from northern Germany. We document multi-scale chemical and mineralogical heterogeneities within the sample, from the millimetre down to the nanometre-scale. From the detection of different types of bitumen and authigenic minerals associated with the organic matter, we show that the multi-scale approach used in this study may provide new insights into gaseous hydrocarbon generation/retention processes occurring within gas shales and may shed new light on their thermal history.

Bernard, S.; Horsfield, B; Schultz, H; Schreiber, A; Wirth, R; Thi AnhVu, T; Perssen, F; Konitzer, S; Volk, H; et. al.

2010-01-01T23:59:59.000Z

62

Process for oil shale retorting  

DOE Patents [OSTI]

Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

Jones, John B. (300 Enterprise Bldg., Grand Junction, CO 80501); Kunchal, S. Kumar (300 Enterprise Bldg., Grand Junction, CO 80501)

1981-10-27T23:59:59.000Z

63

Studies of the New Albany Shale (Devonian and Mississippian) and equivalent strata in Indiana  

SciTech Connect (OSTI)

A formation of black carbonaceous shale, later named the New Albany Shale, was first recognized in 1837 and reported in 1839 by David D. Owen. Since then, the New Albany has been the subject of numerous investigations by individuals affiliated with the Indiana Geological Survey and others. The present comprehensive investigation, involves petrology, mineralogy, stratigraphy, geomorphology, organic and inorganic geochemistry, and physical properties. The lower part of the New Albany Shale is late Middle Devonian in age, and the upper part is Early Mississippian in age.

Hasenmueller, N.R.; Woodard, G.S. (eds.)

1981-09-01T23:59:59.000Z

64

New Albany shale group of Illinois  

SciTech Connect (OSTI)

The Illinois basin's New Albany shale group consists of nine formations, with the brownish-black laminated shales being the predominant lithology in southeastern Illinois and nearby parts of Kentucky where the group reaches its maximum thickness of 460 ft. A second depositional center lies in west-central Illinois and southeastern Iowa, where the group is about 300 ft thick and the predominant lithology is bioturbated olive-gray to greenish-gray shale. A northeast-trending area of thin strata (mostly interfingering gray and black shales) separates these two depocenters. The distribution and types of lithofacies in the New Albany suggest that the shale was deposited across a shelf-slope-basin transition in a marine, stratified anoxic basin. The record of depositional events in the shale group could serve as a baseline for interpreting the history of tectonically more complex sequences such as the Appalachian basin's Devonian shales.

Cluff, R.M.; Reinbold, M.L.; Lineback, J.A.

1981-01-01T23:59:59.000Z

65

Stratigraphy and organic petrography of Mississippian and Devonian oil shale at the Means Project, East-Central Kentucky  

SciTech Connect (OSTI)

The Means Oil Shale Project is under consideration for financial assistance by the US Synthetic Fuels Corporation. The project site is located in southern Montgomery County, about 45 miles east of Lexington, Kentucky. In the site area the Devonian Ohio Shale and the Mississippian Sunbury Shale are under study; these oil shales were deposited in the Appalachian Basin. The objective of the Means Project is to mine, using open pit methods, an ore zone which includes the Sunbury and upper Cleveland and which excludes the Bedford interburden. The thick lower grade oil shale below this ore zone renders the higher grade shale at the base of the Huron commercially unattractive. The oil shale at Means has been classified as a marinite, an oil shale containing abundant alginite of marine origin. Lamalginite is the dominant liptinite and comprises small, unicellular alginite with weak to moderate fluorescence at low rank and a distinctive lamellar form. Telalginite, derived from large colonial or thick-walled, unicellular algae, is common in several stratigraphic intervals.

Solomon, B.J.; Hutton, A.C.; Henstridge, D.A.; Ivanac, J.F.

1985-02-01T23:59:59.000Z

66

TethyanMediterranean organic carbon-rich sediments from Mesozoic black shales to sapropels  

E-Print Network [OSTI]

, sapropel Sedimentology (2009) 56, 247266 doi: 10.1111/j.1365-3091.2008.01026.x 2009 The Authors. Journal and in facies. In terms of sedimentology, distinction is often much less straightforward (Spears, 1980

Gilli, Adrian

67

Fracturing controlled primary migration of hydrocarbon fluids during1 heating of organic-rich shales2  

E-Print Network [OSTI]

understand primary migration of16 hydrocarbon fluids in very low permeability source rock. Cracks nucleate.e. the transport of hydrocarbon fluids from extremely low39 permeability source rocks in which they are generated the source rock is42 formed is buried, the organic material is transformed into complex high molecular weight

68

Effects of low temperature preheating on the pyrolysis products from blocks of oil shale.  

E-Print Network [OSTI]

??Oil shale is a sedimentary rock composed of inorganic and organic fractions. The inorganic minerals contained in oil shale include: dolomite, calcite, quartz, i1 lite, (more)

Alston, David W.

1905-01-01T23:59:59.000Z

69

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

from In-Situ Retorting of Oil Shale," Energy and EnvironmentStudies Trace Contaminants in Oil Shale Retort Water M. J.Organic Arsenic Compounds 1n Oil Shale Process Waters R. H.

,

2012-01-01T23:59:59.000Z

70

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

from In-Situ Retorting of Oil Shale," Energy and EnvironmentTrace Contaminants in Oil Shale Retort Water M. J. Kland, A.Organic Arsenic Compounds 1n Oil Shale Process Waters R. H.

,

2012-01-01T23:59:59.000Z

71

A 4D synchrotron X-ray tomography study of the formation of hydrocarbon migration pathways in heated organic-rich shale  

E-Print Network [OSTI]

. Institute for Energy Technology, Kjeller, Norway Abstract Recovery of oil from oil shales and the natural

Boyer, Edmond

72

Production of hydrogen from oil shale  

SciTech Connect (OSTI)

A process for production of hydrogen from oil shale fines by direct introduction of the oil shale fines into a fluidized bed at temperatures about 1200/sup 0/ to about 2000/sup 0/ F. to obtain rapid heating of the oil shale. The bed is fluidized by upward passage of steam and oxygen, the steam introduced in the weight ratio of about 0.1 to about 10 on the basis of the organic carbon content of the oil shale and the oxygen introduced in less than the stoichiometric quantity for complete combustion of the organic carbonaceous kerogen content of the oil shale. Embodiments are disclosed for heat recovery from the spent shale and heat recovery from the spent shale and product gas wherein the complete process and heat recovery is carried out in a single reaction vessel. The process of this invention provides high conversion of organic carbon component of oil shale and high production of hydrogen from shale fines which when used in combination with a conventional oil shale hydroconversion process results in increased overall process efficiency of greater than 15 percent.

Schora, F. C.; Feldkirchner, H. L.; Janka, J. C.

1985-12-24T23:59:59.000Z

73

Gas potential of new Albany shale (Devonian-Mississippian) in the Illinois Basin  

SciTech Connect (OSTI)

A study to update and evaluate publicly available data relating to present and potential gas production from New Albany Shale in the Illinois basin was conducted cooperatively by the Indiana. Illinois, and Kentucky geological surveys (Illinois Basin Consortium), and was partially funded by the Gas Research Institute. Deliverables included a plate of stratigraphic cross sections and six basin-wide maps at a scale of 1:1,000,000. The New Albany Shale is an organic-rich brownish black shale present throughout the Illinois basin. Gas potential of the New Albany Shale may be great because it contains an estimated 86 tcf of natural gas and has produced modest volumes since 1858 from more than 60 fields, mostly in the southeastern part of the basin. Reservoir beds include organic-rich shales of the Grassy Creek (Shale), Clegg Creek, and Blocher (Shale) members. Limited geologic and carbon isotope data indicate that the gas is indigenous and thermogenic. T[sub max] data suggest that the gas generation begins at R[sub o] values of 0.53% and may begin at R[sub 0] values as low as 0.41% in some beds. New Albany Shale reservoirs contain both free gas in open-pore space and gas adsorbed on clay and kerogen surfaces. Natural fracturing is essential for effective reservoir permeability. Fractures are most common near structures such as faults, flexures, and buried carbonate banks. Based on limited data, fractures and joints have preferred orientations of 45-225[degrees] and 135-315[degrees]. Commercial production requires well stimulation to connect the well bore with the natural fracture system and to prop open pressure-sensitive near-borehole fractures. Current stimulations employ hydraulic fracture treatments using nitrogen and foam, with sand as a propping agent.

Comer, J.B.; Hasenmueller, N.R. (Indiana Geological Survey, Bloomington, IN (United States)); Frankie, W.T. (Illinois State Geological Survey, Champaign, IL (United States)); Hamilton-Smith, T. (Kentucky Geological Survey, Lexington, KY (United States))

1993-08-01T23:59:59.000Z

74

Chemical kinetics and oil shale process design  

SciTech Connect (OSTI)

Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

Burnham, A.K.

1993-07-01T23:59:59.000Z

75

A 4D Synchrotron X-Ray-Tomography Study of the Formation of Hydrocarbon- Migration Pathways in Heated Organic-Rich Shale  

SciTech Connect (OSTI)

Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes that have received renewed interest in recent years because of the ever tightening supply of conventional hydrocarbons and the growing production of hydrocarbons from low-permeability tight rocks. Quantitative models for conversion of kerogen into oil and gas and the timing of hydrocarbon generation have been well documented. However, lack of consensus about the kinetics of hydrocarbon formation in source rocks, expulsion timing, and how the resulting hydrocarbons escape from or are retained in the source rocks motivates further investigation. In particular, many mechanisms have been proposed for the transport of hydrocarbons from the rocks in which they are generated into adjacent rocks with higher permeabilities and smaller capillary entry pressures, and a better understanding of this complex process (primary migration) is needed. To characterize these processes, it is imperative to use the latest technological advances. In this study, it is shown how insights into hydrocarbon migration in source rocks can be obtained by using sequential high-resolution synchrotron X-ray tomography. Three-dimensional images of several immature "shale" samples were constructed at resolutions close to 5 um. This is sufficient to resolve the source-rock structure down to the grain level, but very-fine-grained silt particles, clay particles, and colloids cannot be resolved. Samples used in this investigation came from the R-8 unit in the upper part of the Green River shale, which is organic rich, varved, lacustrine marl formed in Eocene Lake Uinta, USA. One Green River shale sample was heated in situ up to 400 degrees C as X-ray-tomography images were recorded. The other samples were scanned before and after heating at 400 degrees C. During the heating phase, the organic matter was decomposed, and gas was released. Gas expulsion from the low-permeability shales was coupled with formation of microcracks. The main technical difficulty was numerical extraction of microcracks that have apertures in the 5- to 30-um range (with 5 um being the resolution limit) from a large 3D volume of X-ray attenuation data. The main goal of the work presented here is to develop a methodology to process these 3D data and image the cracks. This methodology is based on several levels of spatial filtering and automatic recognition of connected domains. Supportive petrographic and thermogravimetric data were an important complement to this study. An investigation of the strain field using 2D image correlation analyses was also performed. As one application of the 4D (space + time) microtomography and the developed workflow, we show that fluid generation was accompanied by crack formation. Under different conditions, in the subsurface, this might provide paths for primary migration.

Hamed Panahi; Paul Meakin; Francois Renard; Maya Kobchenko; Julien Scheibert; Adriano Mazzini; Bjorn Jamtveit; Anders Malthe-Sorenssen; Dag Kristian Dysthe

2013-04-01T23:59:59.000Z

76

Mechanisms of synfuel degradation 1. Effects of organic nitrogen compounds on the stability of a shale derived diesel fuel  

SciTech Connect (OSTI)

A reliable accelerated fuel stability test regimen has been developed and applied to the study of the storage stability of a shale derived diesel fuel marine (DFM). The results of a survey of nitrogen compounds as dopants in a stable shale DFM base fuel indicate that some pyrroles and indoles may play significant roles in storage stability. A complete stability test matrix has been developed for the temperatures of 43, 65 and 80/sup 0/C, for time periods between 4 and 179 days, and for a ten-fold concentration range of a model dopant, 2,5-dimethylpyrrole (DMP). Stability was defined by the amount of total insoluble material (filterable sediment and adherent gum) produced after stress, and also by the amount of titratable peroxide present in the filtrates of stressed fuel samples. A very regular pattern for insolubles formation was found within the test matrix. Deposit formation rates exhibited a first-order dependence on DMP concentration, with an apparent activation energy of 11-12 kcal/mol. The sediment was found to contain 12% nitrogen and 18-20% oxygen irrespective of the stress conditions employed.

Cooney, J.V.; Beal, E.J.; Huzlett, R.N.

1984-01-01T23:59:59.000Z

77

Isotope Biogeochemistry of Diagenesis caused by a Black  

E-Print Network [OSTI]

the coasts of Surinam and French Guyana #12;µ Black shales in Leg 207 sediments and pore water response depth

78

Geologic and geochemical studies of the New Albany Group (Devonian Black Shale) in Illinois to evaluate its characteristics as a source of hydrocarbons. Quarterly progress report, January 1-March 31, 1980  

SciTech Connect (OSTI)

This project is a detailed analysis of the lithology, stratigraphy, and structure of the New Albany Group in Illinois to determine those characteristics of lithology, thickness, regional distribution, vertical and lateral variability, and deformation that are most relevant to the occurrence of hydrocarbons. The mineralogic and petrographic properties of the New Albany Shale in Illinois are characterized. This includes the quantitative and qualitative characterization, by optical and x-ray techniques, of the inorganic mineral constituents, the dispersed organic matter, and the fabric of the shale. Not less than 49 major, minor, and trace elements are determined in 300 to 500 shale samples, which are representative cross sections of the cores taken. Organic and mineral carbon are included; total hydrogen; total sulfur and when that exceeds 0.5%, pyritic and sulfate sulfur. Also, other elements observed during normal routine analysis are reported. The character of off-gases from approximately 10-foot intervals in cores collected in the Illinois Basin is determined. In addition, the relative distribution of hydrocarbons is determined in ten specially prepared core samples, which are the same as those in previous unit. The carbon isotopic composition of methane in off-gases is determined from core samples whenever sufficient methane can be collected. This data is compared to other pertinent data such as gas composition and vitrinite reflectance for the purpose of making interpretations as to the origin and maturity of the gas. Laboratory experiments are performed to study the relative effects and significance of chemical and isotopic fractionation that occurs as gas is released from core samples. Data accumulated can be evaluated to gain a better understanding of the origin, migration, and location of natural gas associated with the shales.

Bergstrom, R.E.; Shimp, N.F.

1980-04-01T23:59:59.000Z

79

3D multi-scale imaging of experimental fracture generation in shale gas reservoirs.  

E-Print Network [OSTI]

in research and shale unconventional reservoirs that will provide you with the skills to enter the oil and gas3D multi-scale imaging of experimental fracture generation in shale gas reservoirs. Supervisory-grained organic carbon-rich rocks (shales) are increasingly being targeted as shale gas "reservoirs". Due

Henderson, Gideon

80

U-012: BlackBerry Enterprise Server Collaboration Service Bug Lets Remote Users Impersonate Intra-organization Messages  

Broader source: Energy.gov [DOE]

A vulnerability was reported in BlackBerry Enterprise Server. A remote user can impersonate another messaging user within the same organization.

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Oil shale pyrolysis: benchscale experimental studies and modeling.  

E-Print Network [OSTI]

??Oil shale is a complex material that is composed of organic matter, mineral matrix and trace amount of bound and/or unbound water. The endothermic decomposition (more)

Tiwari, Pankaj

2012-01-01T23:59:59.000Z

82

Apparatus for distilling shale oil from oil shale  

SciTech Connect (OSTI)

An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

Shishido, T.; Sato, Y.

1984-02-14T23:59:59.000Z

83

Microbial desulfurization of Eastern oil shale: Bioreactor studies  

SciTech Connect (OSTI)

The removal of sulfur from Eastern oil shale (40 microns particle size) slurries in bioreactors by mixed microbial cultures was examined. A mixed culture that is able to remove the organic sulfur from model sulfur compounds presenting coal as well as a mixed culture isolated from oil shale enrichments were evaluated. The cultures were grown in aerobic fed-batch bioreactors where the oil shale served as the source of all nutrients except organic carbon. Glucose was added as an auxiliary carbon source. Microbial growth was monitored by plate counts, the pH was checked periodically, and oil shale samples were analyzed for sulfur content. Results show a 24% reduction in the sulfur content of the oil shale after 14 days. The settling characteristics of the oil shale in the bioreactors were examined in the presence of the microbes. Also, the mixing characteristics of the oil shale in the bioreactors were examined. 10 refs., 6 figs., 5 tabs.

Maka, A.; Akin, C.; Punwani, D.V.; Lau, F.S.; Srivastava, V.J.

1989-01-01T23:59:59.000Z

84

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

temperature, type of shale and oil content of shale iscontent of the shale, and shale oil content of the rock cantemperatures. Lean and Rich Shale Oil shales vary in their

Bellman Jr., R.

2012-01-01T23:59:59.000Z

85

Devonian-Mississippian oil shale resources of Kentucky: a summary  

SciTech Connect (OSTI)

Assessment of the oil shale resources in Kentucky has continued with 75 NX cores available where the oil shale crops out or is overlain by relatively thin cover in the area from Estill County westward to Bullitt County. In this 14 county area, the total black shale section thins across the crest of the Cincinnati arch and changes stratigraphically from that characteristic of the Ohio Shale in Estill County to that of the New Albany Shale in Bullitt County. Despite this stratigraphic transition the two high-carbon zones (greater than 8.0% carbon) can be traced across the arch. As the traverse is followed from the east, the intervening low-carbon zones thin such that at the crest of the arch, there are areas where the entire section of black shale contains more than 8% carbon. Then upon leaving the crest the two high-carbon zones separate again with one remaining at the very top of the section and one in the lower part. In the 14 county area, there are approximately 3.8 x 10/sup 5/ acres of oil shale outcrop and approximately 7.8 x 10/sup 5/ acres underlain by oil shale at relatively shallow depths.

Barron, L.S.; Robl, T.L.; Kung, J.; Obley, J.

1985-02-01T23:59:59.000Z

86

Clay and SHale--2004 18.1 Clay and Shale  

E-Print Network [OSTI]

Clay and SHale--2004 18.1 Clay and Shale By Robert l. Virta Domestic survey data and tables were). Common Clay and Shale.--In 2004, 162 companies produced common clay and shale from approximately 459 pits in 41 States and Puerto Rico. In States not reporting production, common clay and shale probably

87

Adsorption of pyridine by combusted oil shale  

SciTech Connect (OSTI)

Large volumes of solid waste material will be produced during the commercial production of shale oil. An alternative to the disposal of the solid waste product is utilization. One potential use of spent oil shale is for the stabilization of hazardous organic compounds. The objective of this study was to examine the adsorption of pyridine, commonly found in oil shale process water, by spent oil shale. The adsorption of pyridine by fresh and weathered samples of combusted New Albany Shale and Green River Formation oil shale was examined. In general, pyridine adsorption can be classified as L-type and the isotherms modeled with the Langmuir and Freundlich equations. For the combusted New Albany Shale, weathering reduced the predicted pyridine adsorption maximum and increased the amount of pyridine adsorption maximum. The pyridine adsorption isotherms were similar to those mathematically described by empirical models, the reduction in solution concentrations of pyridine was generally less than 10 mg L{sup {minus}1} at an initial concentration of 100 mg L{sup {minus}1}. 31 refs., 3 figs., 3 tabs.

Essington, M.E.; Hart, B.K.

1990-03-01T23:59:59.000Z

88

Eastern shale hydroretorting  

SciTech Connect (OSTI)

The overall objective of the Bench-Scale Unit (BSU) test program was to determine the effects of major process variables on conversion of organic carbon, yields and properties of oil and gas and consumption of hydrogen for hydroretorting of a specific Indiana New Albany shale. A preliminary error-propagation analysis was performed to identify possible improvements in BSU measurements that could lead to better overall material and elemental balances. A list of additional potential sources of uncertainty (primarily due to the operating procedures used) was compiled. Based on the identification of these possible sources of uncertainty, additional equipment was ordered and installed and existing operating procedures and calculation methods were modified. The result was excellent overall material balance closures (100% +/- 1%).

Roberts, M.J.; Feldkirchner, H.L.; Punwani, D.V.; Rex, R.C. Jr.

1984-01-01T23:59:59.000Z

89

Raw shale dissolution as an aid in determining oil shale mineralogy  

SciTech Connect (OSTI)

With an accurate oil shale mineralogy, one can begin to unravel the inorganic and organic aspects of retorting and combustion chemistry. We evaluated three modern elemental analysis procedures (ICP-AES, XRF, and PIXE) with the aim of improving our knowledge of the mineral matrix. A New Albany Shale (Clegg Creek Member) specimen (NA13) and a Mahogany Zone Green River Formation oil shale from Anvil Points (AP24) were the two materials analyzed. These were oil shales that we had used in our pilot retort. We set a modest goal: determination of those materials present at greater than a 1% level with a relative accuracy of {plus_minus}10%. Various total dissolution methods and pre-treatement procedures were examined. The routine ICP-AES method that we adopted had precision and accuracy that exceeded our initial goals. Partial dissolution of carbonate minerals in acetic acid was slow but highly selective. The clay mineral content of both shales was deduced from the time dependence of dissolution in 6N HCl. An Al:K ratio of 3 indicated selective HCl solubility of the clay, illite. Our eastern oil shale from Kentucky was remarkably similar in mineral composition to high-grade-zone New Albany Shale samples from Kentucky, Indiana, and Illinois that others had subjected to careful mineral analysis. A Mahogany Zone Green River Formation oil shale from the Colony Mine had slightly different minor mineral components (relative to AP24) as shown by its gas evolution profile.

Duewer, T.I.; Foster, K.G.; Coburn, T.T.

1991-11-11T23:59:59.000Z

90

Raw shale dissolution as an aid in determining oil shale mineralogy  

SciTech Connect (OSTI)

With an accurate oil shale mineralogy, one can begin to unravel the inorganic and organic aspects of retorting and combustion chemistry. We evaluated three modern elemental analysis procedures (ICP-AES, XRF, and PIXE) with the aim of improving our knowledge of the mineral matrix. A New Albany Shale (Clegg Creek Member) specimen (NA13) and a Mahogany Zone Green River Formation oil shale from Anvil Points (AP24) were the two materials analyzed. These were oil shales that we had used in our pilot retort. We set a modest goal: determination of those materials present at greater than a 1% level with a relative accuracy of {plus minus}10%. Various total dissolution methods and pre-treatement procedures were examined. The routine ICP-AES method that we adopted had precision and accuracy that exceeded our initial goals. Partial dissolution of carbonate minerals in acetic acid was slow but highly selective. The clay mineral content of both shales was deduced from the time dependence of dissolution in 6N HCl. An Al:K ratio of 3 indicated selective HCl solubility of the clay, illite. Our eastern oil shale from Kentucky was remarkably similar in mineral composition to high-grade-zone New Albany Shale samples from Kentucky, Indiana, and Illinois that others had subjected to careful mineral analysis. A Mahogany Zone Green River Formation oil shale from the Colony Mine had slightly different minor mineral components (relative to AP24) as shown by its gas evolution profile.

Duewer, T.I.; Foster, K.G.; Coburn, T.T.

1991-11-11T23:59:59.000Z

91

Oil shale ash-layer thickness and char combustion kinetics  

SciTech Connect (OSTI)

A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

1992-04-15T23:59:59.000Z

92

OIL SHALE DEVELOPMENT IN CHINA  

E-Print Network [OSTI]

In this paper history, current status and forecast of Chinese oil shale indus-try, as well as the characteristics of some typical Chinese oil shales are given.

J. Qian; J. Wang; S. Li

93

Utilization of Estonian oil shale at power plants  

SciTech Connect (OSTI)

Estonian oil shale belongs to the carbonate class and is characterized as a solid fuel with very high mineral matter content (60--70% in dry mass), moderate moisture content (9--12%) and low heating value (LHV 8--10 MJ/kg). Estonian oil shale deposits lie in layers interlacing mineral stratas. The main constituent in mineral stratas is limestone. Organic matter is joined with sandy-clay minerals in shale layers. Estonian oil shale at power plants with total capacity of 3060 MW{sub e} is utilized in pulverized form. Oil shale utilization as fuel, with high calcium oxide and alkali metal content, at power plants is connected with intensive fouling, high temperature corrosion and wear of steam boiler`s heat transfer surfaces. Utilization of Estonian oil shale is also associated with ash residue use in national economy and as absorbent for flue gas desulfurization system.

Ots, A. [Tallin Technical Univ. (Estonia). Thermal Engineering Department

1996-12-31T23:59:59.000Z

94

Los Alamos environmental activities/oil shale effluents  

SciTech Connect (OSTI)

The objectives of this research are to determine the nature, magnitude, and time dependence of the major and trace element releases as functions of the raw shale mineralogy, retorting conditions, and spent shale mineral assemblages. These experimental studies will focus on retorting variable regimes characteristic of most retorting processes. As an adjunct objective, the relation of laboratory results to those obtained from both bench-scale and pilot-scale retorts, when both have been operated under similar retorting conditions, will be defined. The goal is to develop a predictive capability for spent shale chemistry as a function of the raw material feedstock and process parameters. Key accomplishments follow: completed an overview of health, environmental effects, and potential ''show stoppers'' in oil shale development; elucidated the importance of both raw material and process in the identity and behavior of spent shale wastes (Occidental raw and spent shales from the Logan Wash site); completed a balanced factorial design experiment to investigate the influence of shale type, temperature, and atmosphere on spent shale behavior; compared the behavior of spent shales from laboratory experiments with shales generated from MIS retorting by OOSI at Logan Wash, Colorado; completed a study of the partitioning of minerals, inorganics, and organics as a function of particle size in a raw shale from Anvil Points, Colorado; evaluated the application of the Los Alamos nuclear microprobe to the characterization of trace element residences in shale materials; established the use of chemometrics as a major tool for evaluating large data bases in oil shale research and for relating field and laboratory results; conceptualized and evaluated experimentally a multistaged leaching control for abandonment of underground retorts; and coordinated activities with other DOE laboratories, industry laboratories, and universities. 13 refs., 1 fig., 2 tabs.

Peterson, E.J.

1985-01-01T23:59:59.000Z

95

Oil shale technology  

SciTech Connect (OSTI)

Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

1991-01-01T23:59:59.000Z

96

Sulfide, phosphate, and minor element enrichment in the New Albany Shale (Devonian-Mississippian) of southern Indiana  

SciTech Connect (OSTI)

The upper part of the New Albany Shale is divided into three members, which in ascending order are: (1) the Morgan Trail Member, a laminated brownish-black shale; (2) the Camp Run Member, an interbedded brownish-black and greenish-gray shale; and (3) the Clegg Creek Member, also a laminated brownish-black shale. The Morgan Trail and Camp Run Members contain 5 to 6% total organic carbon (TOC) and 2% sulfide sulfur. Isotopic composition of sulfide in these members ranges from -5.0 to -20.0%. C/S plots indicate linear relationships between abundances of these elements characteristic of sediments deposited in a noneuxinic marine environment. The Clegg Creek Member contains 10 to 15% TOC and 2 to 6% sulfide sulfur. Isotopic composition of sulfide ranges from -5.0 to -40.0%. The most negative values are characteristic of syngenetic pyrite formed within an anoxic water column. Abundances of carbon and sulfur are higher and uncorrelated in this member, consistent with deposition in an euxinic environment. Further, DOP (degree of pyritization) values suggest that pyrite formation was generally iron limited throughout Clegg Creek deposition, but sulfur isotopes indicate that syngenetic (water column) pyrite becomes an important component in the sediment only in the upper part of the member. At the top of the Clegg Creek Member a zone of phosphate nodules and trace metal enrichment coincides with maximal TOC values. During euxinic deposition, phosphate and trace metals accumulated below the chemocline due to limited vertical circulation in the water column. Phosphate and trace metals released for organic matter during early diagenesis resulted in precipitation of metal-rich phosphate nodules.

Beier, J.A.

1988-01-01T23:59:59.000Z

97

CLAY AND SHALE--2001 18.1 CLAY AND SHALE  

E-Print Network [OSTI]

operated approximately 633 clay and shale pits or quarries. The largest 20 companies, many with multiple

98

CLAY AND SHALE--2002 18.1 CLAY AND SHALE  

E-Print Network [OSTI]

CLAY AND SHALE--2002 18.1 CLAY AND SHALE By Robert L. Virta Domestic survey data and tables were clay, bentonite, common clay and shale, fire clay, fuller's earth, and kaolin. Ball clays consist of feldspars, biotite, and quartz. Common clay and shale contain illite and chlorite as major components. Fire

99

Oil shale research in China  

SciTech Connect (OSTI)

There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

1989-01-01T23:59:59.000Z

100

Trace elements in oil shale. Progress report, 1979-1980  

SciTech Connect (OSTI)

The purpose of this research program is to understand the potential impact of an oil shale industry on environmental levels of trace contaminants in the region. The program involves a comprehensive study of the sources, release mechanisms, transport, fate, and effects of toxic trace chemicals, principally the trace elements, in an oil shale industry. The overall objective of the program is to evaluate the environmental and health consequences of the release of toxic trace elements by shale and oil production and use. The baseline geochemical survey shows that stable trace elements maps can be constructed for numerous elements and that the trends observed are related to geologic and climatic factors. Shale retorted by above-ground processes tends to be very homogeneous (both in space and in time) in trace element content. Leachate studies show that significant amounts of B, F, and Mo are released from retorted shales and while B and Mo are rapidly flushed out, F is not. On the other hand, As, Se, and most other trace elements are not present in significant quantities. Significant amounts of F and B are also found in leachates of raw shales. Very large concentrations of reduced sulfur species are found in leachates of processed shale. Very high levels of B and Mo are taken up in some plants growing on processed shale with and without soil cover. There is a tendency for some trace elements to associate with specific organic fractions, indicating that organic chelation or complexation may play an important role. Many of the so-called standard methods for analyzing trace elements in oil shale-related materials are inadequate. A sampling manual is being written for the environmental scientist and practicing engineer. A new combination of methods is developed for separating the minerals in oil shale into different density fractions. Microbial investigations have tentatively identified the existence of thiobacilli in oil shale materials such as leachates. (DC)

Chappell, W R

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Lawrence Livermore National Laboratory oil shale project. Quarterly report, April-June 1982  

SciTech Connect (OSTI)

The effect of the proportion of oxidized shale to raw shale, on the heat of combustion of retort product was studied in a fluidized sand bed at 500/sup 0/C. Results show a significant increase in the heat of combustion, produced by the activity of the oxidized shale. The functionality of organic sulfur in various oil shale types is being investigated. An oil shale pyrolyzer for aboveground retorting is being studied in an engineering facility. Thermochemical and experimental equations were developed for the heat of combustion of raw shale. A heat balance was calculated for 24.6 gal/ton Colorado oil shale. The rapid-pyrolysis data was analyzed to determine the best kinetic scheme for retort modeling. Incipient fluidization velocity measurements were made for various crushed oil shale mixtures of different particle sizes. 10 figures, 1 table. (DLC)

Carley, J.F. (ed.)

1982-09-14T23:59:59.000Z

102

Characterization of interim reference shales  

SciTech Connect (OSTI)

Measurements have been made on the chemical and physical properties of two oil shales designated as interim reference oil shales by the Department of Energy. One oil shale is a Green River Formation, Parachute Creek Member, Mahogany Zone Colorado oil shale from the Anvil Points mine and the other is a Clegg Creek Member, New Albany shale from Kentucky. Material balance Fischer assays, kerogen concentrates, carbon aromaticities, thermal properties, and bulk mineralogic properties have been determined for the oil shales. The measured properties of the interim reference shales are comparable to results obtained from previous studies on similar shales. The western interim reference shale has a low carbon aromaticity, high Fischer assay conversion to oil, and a dominant carbonate mineralogy. The eastern interim reference shale has a high carbon aromaticity, low Fischer assay conversion to oil, and a dominant silicate mineralogy. Chemical and physical properties, including ASTM distillations, have been determined for shale oils produced from the interim reference shales. The distillation data were used in conjunction with API correlations to calculate a large number of shale oil properties that are required for computer models such as ASPEN. The experimental determination of many of the shale oil properties was beyond the scope of this study. Therefore, direct comparison between calculated and measured values of many properties could not be made. However, molecular weights of the shale oils were measured. In this case, there was poor agreement between measured molecular weights and those calculated from API and other published correlations. 23 refs., 12 figs., 15 tabs.

Miknis, F.P.; Sullivan, S.; Mason, G.

1986-03-01T23:59:59.000Z

103

Microporomechanical modeling of shale  

E-Print Network [OSTI]

Shale, a common type of sedimentary rock of significance to petroleum and reservoir engineering, has recently emerged as a crucial component in the design of sustainable carbon and nuclear waste storage solutions and as a ...

Ortega, J. Alberto (Jose Alberta Ortega Andrade)

2010-01-01T23:59:59.000Z

104

Production of Shale Oil  

E-Print Network [OSTI]

Intensive pre-project feasibility and engineering studies begun in 1979 have produced an outline plan for development of a major project for production of shale oil from private lands in the Piceance Basin in western Colorado. This outline plan...

Loper, R. D.

1982-01-01T23:59:59.000Z

105

Oil shale as an energy source in Israel  

SciTech Connect (OSTI)

Reserves, characteristics, energetics, chemistry, and technology of Israeli oil shales are described. Oil shale is the only source of energy and the only organic natural resource in Israel. Its reserves of about 12 billion tons will be enough to meet Israel`s requirements for about 80 years. The heating value of the oil shale is 1,150 kcal/kg, oil yield is 6%, and sulfur content of the oil is 5--7%. A method of oil shale processing, providing exhaustive utilization of its energy and chemical potential, developed in the Technion, is described. The principal feature of the method is a two-stage pyrolysis of the oil shale. As a result, gas and aromatic liquids are obtained. The gas may be used for energy production in a high-efficiency power unit, or as a source for chemical synthesis. The liquid products can be an excellent source for production of chemicals.

Fainberg, V.; Hetsroni, G. [Technion-Israel Inst. of Tech., Haifa (Israel)

1996-01-01T23:59:59.000Z

106

January 20, 2011 Marcellus Shale 101  

E-Print Network [OSTI]

. Will oil shale be viable as well? Oil shale will not be economically viable anytime in the near future

Hardy, Christopher R.

107

Carcinogenicity Studies of Estonian Oil Shale Soots  

E-Print Network [OSTI]

determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All

A. Vosamae

108

Distribution and origin of sulfur in Colorado oil shale  

SciTech Connect (OSTI)

The sulfur content of 1,225 samples of Green River oil shale from two core holes in the Piceance Creek Basin, Colorado, ranges from nearly 0 to 4.9 weight percent. In one core hole, the average sulfur content of a sequence of oil shale 555 m thick, which represents nearly the maximum thickness of oil shale in the basin, is 0.76 weight percent. The vertical distribution of sulfur through the oil shale is cyclic. As many as 25 sulfur cycles have lateral continuity and can be traced between the core holes. Most of the sulfur resides in iron sulfides (pyrite, marcasite, and minor. pyrrhotite), and small amounts are organically bound in kerogen. In general, the concentration of sulfur correlates moderately with oil shale yield, but the degree of association ranges from quite high in the upper 90 m of the oil shale sequence to low or none in the leached zone and in illitic oil shale in the lower part of the sequence. Sulfur also correlates moderately with iron in the carbonate oil shale sequence, but no correlation was found in the illitic samples. Sulfide mineralization is believed to have occurred during early and late stages of diagenesis, and after lithification, during development of the leached zone. Significant amounts of iron found in ankeritic dolomite and in illite probably account for the lack of a strong correlation between sulfur and iron.

Dyni, J.R.

1983-04-01T23:59:59.000Z

109

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect (OSTI)

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

110

Chemically assisted in situ recovery of oil shale  

SciTech Connect (OSTI)

The purpose of the research project was to investigate the feasibility of the chemically assisted in situ retort method for recovering shale oil from Colorado oil shale. The chemically assisted in situ procedure uses hydrogen chloride (HCl), steam (H{sub 2}O), and carbon dioxide (CO{sub 2}) at moderate pressure to recovery shale oil from Colorado oil shale at temperatures substantially lower than those required for the thermal decomposition of kerogen. The process had been previously examined under static, reaction-equilibrium conditions, and had been shown to achieve significant shale oil recoveries from powdered oil shale. The purpose of this research project was to determine if these results were applicable to a dynamic experiment, and achieve penetration into and recovery of shale oil from solid oil shale. Much was learned about how to perform these experiments. Corrosion, chemical stability, and temperature stability problems were discovered and overcome. Engineering and design problems were discovered and overcome. High recovery (90% of estimated Fischer Assay) was observed in one experiment. Significant recovery (30% of estimated Fischer Assay) was also observed in another experiment. Minor amounts of freed organics were observed in two more experiments. Penetration and breakthrough of solid cores was observed in six experiments.

Ramierz, W.F.

1993-12-31T23:59:59.000Z

111

Removal of nitrogen and sulfur from oil-shale  

SciTech Connect (OSTI)

This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

Olmstead, W.N.

1986-01-28T23:59:59.000Z

112

GEOL 482/582 Coal/Organic Petrology  

E-Print Network [OSTI]

, hydrocarbons (oil/gas), oil shales, and dispersed organics. · To be able to recognize organic components under

Nickrent, Daniel L.

113

Nineteenth oil shale symposium proceedings  

SciTech Connect (OSTI)

This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

Gary, J.H.

1986-01-01T23:59:59.000Z

114

Oil shale retort apparatus  

DOE Patents [OSTI]

A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

Reeves, Adam A. (Grand Junction, CO); Mast, Earl L. (Norman, OK); Greaves, Melvin J. (Littleton, CO)

1990-01-01T23:59:59.000Z

115

Oil shale: Technology status report  

SciTech Connect (OSTI)

This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

Not Available

1986-10-01T23:59:59.000Z

116

Marcellus Shale Educational Webinar Series  

E-Print Network [OSTI]

#12;Marcellus Shale Litigation and Legislation December 17, 2009 7 . Pennsylvania Oil and Gas Law1 Marcellus Shale Educational Webinar Series October 2009 - March 2010 Penn State Cooperative Extension #12;2 Marcellus Shale Webinar Series Planning Committee · Members ­ Mark Douglass, Jefferson

Boyer, Elizabeth W.

117

Shale Play Industry Transportation Challenges,  

E-Print Network [OSTI]

­ High volume commodi-es flows in and out of shale plays · Sand In....Oil in excess of 50 MMT/Yr. · Life of current Shale Oil & Gas explora-on trend ­ 2012) #12;Shale Play Oil Industry A Look at the Baaken · 2-3 Unit Trains

Minnesota, University of

118

Short-term microbial testing of shale oil materials  

SciTech Connect (OSTI)

Paraho/Sohio Shale Oil was found to be mutagenic in the Ames assay when assayed with the frameshift strain TA98 and incorporating metabolic activation with rat liver homogenates (Aroclor induced S-9). The mutagenic activity was contributed by the organic constituents of the basic and the neutral fractions. Hydrotreatment of the shale oil abolished the mutagenic activity. Results obtained in the yeast assay supported these observations. Refined oil samples from Paraho/Sohio refinery were not mutagenic. The samples rank for their mutagenic activity as coal oils > shale oil > natural petroleum crudes.

Rao, T.K.; Epler, J.L.; Guerin, M.R.; Clark, B.R.

1980-01-01T23:59:59.000Z

119

POTENTIAL USES OF SPENT SHALE IN THE TREATMENT OF OIL SHALE RETORT WATERS  

E-Print Network [OSTI]

study of retorted oil shale," Lawrence Livermore Laboratoryb) using columns of spent shale. REFERENCES Burnham, Alankinetics between and oil-shale residual carbon. 1. co Effect

Fox, J.P.

2013-01-01T23:59:59.000Z

120

Spent Shale Grouting of Abandoned In-Situ Oil Shale Retorts  

E-Print Network [OSTI]

Mineral Reactions in Colorado Oil Shale," Lawrence Livermore1978. of Decomposition of Colorado Oil Shale: II. LivermoreEffects Lawrence of Steam on Oil Shale Retorting: Livermore

Fox, J.P.; Persoff, P.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A 4D synchrotron X-ray tomography study of the formation of hydrocarbon migration pathways in heated organic-rich shale  

E-Print Network [OSTI]

Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes that have received renewed interests in recent years because of the ever tightening supply of conventional hydrocarbons and the growing production of hydrocarbons from low permeability tight rocks. Quantitative models for conversion of kerogen into oil and gas and the timing of hydrocarbon generation have been well documented. However, lack of consensus about the kinetics of hydrocarbon formation in source rocks, expulsion timing and how the resulting hydrocarbons escape from or are retained in the source rocks motivates further investigation. In particular, many mechanisms for the transport of hydrocarbons from the source rocks in which they are generated into adjacent rocks with higher permeabilities and smaller capillary entry pressures have been proposed, and a better understanding of this complex process (primary migration) is needed. To characterize these processes it is imperative to use the ...

Panahi, Hamed; Renard, Francois; Mazzini, Adriano; Scheibert, Julien; Dysthe, Dag Kristian; Jamtveit, Bjorn; Malthe-Srenssen, Anders; Meakin, Paul

2014-01-01T23:59:59.000Z

122

Fractured shale reservoirs: Towards a realistic model  

SciTech Connect (OSTI)

Fractured shale reservoirs are fundamentally unconventional, which is to say that their behavior is qualitatively different from reservoirs characterized by intergranular pore space. Attempts to analyze fractured shale reservoirs are essentially misleading. Reliance on such models can have only negative results for fractured shale oil and gas exploration and development. A realistic model of fractured shale reservoirs begins with the history of the shale as a hydrocarbon source rock. Minimum levels of both kerogen concentration and thermal maturity are required for effective hydrocarbon generation. Hydrocarbon generation results in overpressuring of the shale. At some critical level of repressuring, the shale fractures in the ambient stress field. This primary natural fracture system is fundamental to the future behavior of the fractured shale gas reservoir. The fractures facilitate primary migration of oil and gas out of the shale and into the basin. In this process, all connate water is expelled, leaving the fractured shale oil-wet and saturated with oil and gas. What fluids are eventually produced from the fractured shale depends on the consequent structural and geochemical history. As long as the shale remains hot, oil production may be obtained. (e.g. Bakken Shale, Green River Shale). If the shale is significantly cooled, mainly gas will be produced (e.g. Antrim Shale, Ohio Shale, New Albany Shale). Where secondary natural fracture systems are developed and connect the shale to aquifers or to surface recharge, the fractured shale will also produce water (e.g. Antrim Shale, Indiana New Albany Shale).

Hamilton-Smith, T. [Applied Earth Science, Lexington, KY (United States)

1996-09-01T23:59:59.000Z

123

Solar retorting of oil shale  

DOE Patents [OSTI]

An apparatus and method for retorting oil shale using solar radiation. Oil shale is introduced into a first retorting chamber having a solar focus zone. There the oil shale is exposed to solar radiation and rapidly brought to a predetermined retorting temperature. Once the shale has reached this temperature, it is removed from the solar focus zone and transferred to a second retorting chamber where it is heated. In a second chamber, the oil shale is maintained at the retorting temperature, without direct exposure to solar radiation, until the retorting is complete.

Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

124

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

1983-09-21T23:59:59.000Z

125

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA); Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA)

1985-01-01T23:59:59.000Z

126

Evaluation of Devonian shale potential in Illinois, Indiana, and western Kentucky  

SciTech Connect (OSTI)

Potential natural gas resources in the New Albany Shale of the Illinois basin may be related to five key factors: relative organic content of the shale; relative thickness of the organically-rich shale; thermal maturity as related to depth of burial; presence of natural fractures; and type of organic matter. The shale that is organically richest is in southeastern Illinois and in most of the Indiana and Kentucky portions of the Illinois basin. The shales are thickest (about 400 feet) near the center of the basin in southeastern Illinois, southwestern Indiana, and adjacent parts of Kentucky. The area is deeply buried by younger rocks, and the organic matter has the highest thermal maturity. In addition, natural fault-induced fractures in the shale, which may aid in collecting gas from a larger volume of shale, may be present, since major faults along the Rough Creek Lineament and Wabash Valley Fault System cross the deeper part of the basin. Thus, this area near the basin center where the shale is thickest and rich organically and where fault-induced fractures may be present has the greatest potential for natural-gas resources. The eastern side of the basin, where the shale is organic-rich but thin, may have poor to moderate potential for additional discoveries of small gas fields similar to those found in the past. In western Illinois and the northern part of the basin, the potential is poor, because the organic content of the dominantly greenish-gray shale in this area is low. More exploration will be required to properly evaluate potential resources of natural gas that may exist in the New Albany Shale.

Not Available

1981-01-01T23:59:59.000Z

127

A feasibility study of oil shale fired pulse combustors with applications to oil shale retorting  

SciTech Connect (OSTI)

The results of the experimental investigation performed to determine the feasibility of using pulverized Colorado oil shale to fuel a bench scale pulse combustor reveal that oil shale cannot sustain pulsations when used alone as fuel. Trace amounts of propane mixed with the oil shale enabled the pulsations, however. Up to 80% of the organic material in the oil shale was consumed when it was mixed with propane in the combustor. Beyond the feasibility objectives, the operating conditions of the combustor fuel with propane and mixtures of oil shale and propane were characterized with respect to pulsation amplitude and frequency and the internal combustor wall temperature over fuel lean and fuel rich stoichiometries. Maximum pressure excursions of 12.5 kPa were experienced in the combustor. Pulsation frequencies ranged from 50 to nearly 80 Hz. Cycle resolved laser Doppler anemometry velocities were measured at the tail pipe exit plane. Injecting inert mineral matter (limestone) into the pulse combustor while using propane fuel had only a slight effect on the pulsation frequency for the feed rates tested.

Morris, G.J.; Johnson, E.K.; Zhang, G.Q.; Roach, R.A.

1992-07-01T23:59:59.000Z

128

Availability of soil organic phosphorus and fertilizer phosphorus applied to coastal bermudagrass (cynodon dactylon l.) on Houston black clay  

E-Print Network [OSTI]

) for different tillage-P treatments during 1976. Mean available P (using 1. 4N NH40Ac extract solution) for different tillage-P treatments during 1976. 46 52 54 61 64 69 70 INTRODUCTION A gradual decline in the annual forage production of recently... con- stitutes the. greatest proportion of the total P in many soils. Supak (1969) found that 46/ of the total P in the check p'lot in a Houston Black clay was organic P. Organic Phosphorus Organic P generally constitutes about 25-75K of the total...

Krautmann, Jolly Yang

1978-01-01T23:59:59.000Z

129

Spent Shale Grouting of Abandoned In-Situ Oil Shale Retorts  

E-Print Network [OSTI]

for the grout. SPENT SHALE Oil shale, which is a low-gradeMineral Reactions in Colorado Oil Shale," Lawrence Livermore1978. of Decomposition of Colorado Oil Shale: II. Livermore

Fox, J.P.; Persoff, P.

1980-01-01T23:59:59.000Z

130

In situ method for recovering hydrocarbon from subterranean oil shale deposits  

SciTech Connect (OSTI)

This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

Friedman, R.H.

1987-11-03T23:59:59.000Z

131

Petrology of the Devonian gas-bearing shale along Lake Erie helps explain gas shows  

SciTech Connect (OSTI)

Comprehensive petrologic study of 136 thin sections of the Ohio Shale along Lake Erie, when combined with detailed stratigraphic study, helps explain the occurrence of its gas shows, most of which occur in the silty, greenish-gray, organic poor Chagrin Shale and Three Lick Bed. Both have thicker siltstone laminae and more siltstone beds than other members of the Ohio Shale and both units also contain more clayshales. The source of the gas in the Chagrin Shale and Three Lick Bed of the Ohio Shale is believed to be the bituminous-rich shales of the middle and lower parts of the underlying Huron Member of the Ohio Shale. Eleven petrographic types were recognized and extended descriptions are provided of the major ones - claystones, clayshales, mudshales, and bituminous shales plus laminated and unlaminated siltstones and very minor marlstones and sandstones. In addition three major types of lamination were identified and studied. Thirty-two shale samples were analyzed for organic carbon, whole rock hydrogen and whole rock nitrogen with a Perkin-Elmer 240 Elemental Analyzer and provided the data base for source rock evaluation of the Ohio Shale.

Broadhead, R.F.; Potter, P.E.

1980-11-01T23:59:59.000Z

132

I. Canada EIA/ARI World Shale Gas and Shale Oil Resource Assessment I. CANADA SUMMARY  

E-Print Network [OSTI]

by this resource study. Figure I-1 illustrates certain of the major shale gas and shale oil basins in

unknown authors

133

The twentieth oil shale symposium proceedings  

SciTech Connect (OSTI)

This book contains 20 selections. Some of the titles are: The technical contributions of John Ward Smith in oil shale research; Oil shale rubble fires: ignition and extinguishment; Fragmentation of eastern oil shale for in situ recovery; A study of thermal properties of Chinese oil shale; and Natural invasion of native plants on retorted oil shale.

Gary, J.H.

1987-01-01T23:59:59.000Z

134

Millimeter wave analysis of the dielectric properties of oil shales  

E-Print Network [OSTI]

Natural sedimentation processes give rise to fine layers in shales. If these layers alternate between organic-rich and organic-poor sediments, then the contrast in dielectric properties gives rise to an effective birefringence as the presence of hydrocarbons suppresses the dielectric constant of the host rock. We have measured these effects with a quasioptical millimeter wave setup that is rapid and noncontacting. We find that the strength of this birefringence and the overall dielectric permittivity provide two useful diagnostic of the organic content of oil shales.

John A. Scales; Michael Batzle

2006-06-06T23:59:59.000Z

135

Organic geochemistry and organic petrography  

SciTech Connect (OSTI)

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

136

Shale oil recovery process  

DOE Patents [OSTI]

A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

Zerga, Daniel P. (Concord, CA)

1980-01-01T23:59:59.000Z

137

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

III, "Method of Breaking Shale Oil-Water Emulsion," U. S.and Biological Treatment of Shale Oil Retort Water, DraftPA (1979). H. H. Peters, Shale Oil Waste Water Recovery by

Fox, J.P.

2010-01-01T23:59:59.000Z

138

HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE  

E-Print Network [OSTI]

cement from spent oil shale," Vol. 10, No. 4, p. 54S,Colorado's primary oil shale resource for vertical modifiedSimulated effects of oil-shale development on the hydrology

Mehta, P.K.

2013-01-01T23:59:59.000Z

139

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Corrosion of Oil Shale Retort Component Materials," LBL-

Bellman Jr., R.

2012-01-01T23:59:59.000Z

140

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

III, "Method of Breaking Shale Oil-Water Emulsion," U. S.Waters from Green River Oil Shale," Chem. and Ind. , 1. ,Effluents from In-Situ oil Shale Processing," in Proceedings

Fox, J.P.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

Elevated Temperature Corrosion of Oil Shale Retort Componentin In-Situ Oil Shale Retorts," NACE Corrosion 80, Paper No.6-10, 1981 CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A.

Bellman Jr., R.

2012-01-01T23:59:59.000Z

142

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

is in intimate contact with oil and shale during In in-situin contact with the oil and shale. These methods and othersWaters from Green River Oil Shale," Chem. and Ind. , 1. ,

Fox, J.P.

2010-01-01T23:59:59.000Z

143

Case Study: Shale Bings in Central  

E-Print Network [OSTI]

and oil shale was widespread. The extraction of oil from shales began in the 1850s and developed within the region that the oil-shale bings constitute one of the eight main habi- tats in West Lothian

144

HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE  

E-Print Network [OSTI]

hydraulic cement from spent oil shale," Vol. 10, No. 4, p.J. W. , "Colorado's primary oil shale resource for verticalSimulated effects of oil-shale development on the hydrology

Mehta, P.K.

2013-01-01T23:59:59.000Z

145

WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY  

E-Print Network [OSTI]

Waters from Green River Oil Shale," Chem. and Ind. , 1. ,Effluents from In-Situ oil Shale Processing," in Proceedingsin the Treatment of Oil Shale Retort Waters," in Proceedings

Fox, J.P.

2010-01-01T23:59:59.000Z

146

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Elevated Temperature Corrosion of Oil Shale Retort Component

Bellman Jr., R.

2012-01-01T23:59:59.000Z

147

Australian Shale Gas Assessment Project Reza Rezaee  

E-Print Network [OSTI]

Australian Shale Gas Assessment Project Reza Rezaee Unconventional Gas Research Group, Department of Petroleum Engineering, Curtin University, Australia Shale gas is becoming an important source feet (Tcf) of technically recoverable shale gas resources. Western Australia (WA) alone

148

Apparatus for oil shale retorting  

DOE Patents [OSTI]

A cascading bed retorting process and apparatus in which cold raw crushed shale enters at the middle of a retort column into a mixer stage where it is rapidly mixed with hot recycled shale and thereby heated to pyrolysis temperature. The heated mixture then passes through a pyrolyzer stage where it resides for a sufficient time for complete pyrolysis to occur. The spent shale from the pyrolyzer is recirculated through a burner stage where the residual char is burned to heat the shale which then enters the mixer stage.

Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA); Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA)

1986-01-01T23:59:59.000Z

149

Optimising the Use of Spent Oil Shale.  

E-Print Network [OSTI]

??Worldwide deposits of oil shales are thought to represent ~3 trillion barrels of oil. Jordanian oil shale deposits are extensive and high quality, and could (more)

FOSTER, HELEN,JANE

2014-01-01T23:59:59.000Z

150

Oil shale: The environmental challenges III  

SciTech Connect (OSTI)

This book presents the papers of a symposium whose purpose was to discuss the environmental and socio-economic aspects of oil shale development. Topics considered include oil shale solid waste disposal, modeling spent shale disposal, water management, assessing the effects of oil shale facilities on water quality, wastewater treatment and use at oil shale facilities, potential air emissions from oil shale retorting, the control of air pollutant emissions from oil shale facilities, oil shale air emission control, socioeconomic research, a framework for mitigation agreements, the Garfield County approach to impact mitigation, the relationship of applied industrial hygiene programs and experimental toxicology programs, and industrial hygiene programs.

Petersen, K.K.

1983-01-01T23:59:59.000Z

151

Rock-Fluid Chemistry Impacts on Shale Hydraulic Fracture and Microfracture Growth  

E-Print Network [OSTI]

The role of surface chemical effects in hydraulic fracturing of shale is studied using the results of unconfined compression tests and Brazilian tests on Mancos shale- cored at depths of 20-60 ft. The rock mineralogy, total organic carbon and cation...

Aderibigbe, Aderonke

2012-07-16T23:59:59.000Z

152

Oil Shale, 2012, Vol. 29, No. 1, pp. 1835 ISSN 0208-189X doi: 10.3176/oil.2012.1.03 2012 Estonian Academy Publishers  

E-Print Network [OSTI]

Oil Shale, 2012, Vol. 29, No. 1, pp. 18­35 ISSN 0208-189X doi: 10.3176/oil.2012.1.03 © 2012 have attracted attention because of its organic-rich matter and oil seepage in the rock series that of an average in marine shales. Inter-element correlations suggest that the shale-normalized REE patterns

Lin, Andrew Tien-Shun

153

Devonian oil shale of the eastern United States: a major American energy resource  

SciTech Connect (OSTI)

The eastern Devonian oil shale resource can yield 400 billion (400 X 10/sup 9/) bbl of synthetic oil, if all surface and near-surface shales were strip or deep mined for above-ground hydroretorting. Experimental work, in equipment capable of processing up to 1 ton/h of shale, has confirmed the technical and economic feasibility of aboveground hydroretorting of oil shales. Work done to date on nearly 500 samples from 12 states indicates that the HYTORT Process can give organic carbon recoveries from 2 to 2.5 times those of conventional retorting of the Devonian shales, so that the HYTORT Process yields 25 to 30 gallons per ton on syncrude at many localities, compared with 10 to 15 gallons per ton using Fischer Assay retort methods. Criteria for inclusion of shale in estimates of recoverable resources for the HYTORT Process are: (1) organic carbon of at least 10% by weight; (2) overburden of less than 200 feet (59 meters); (3) volumetric stripping ratios of less than 2.5 to 1; and (4) stratigraphic thickness of 10 feet (3 meters) or more. Resource estimates include: Kentucky (Ohio, New Albany, and Sunbury shales), 190 billion (190 X 10/sup 9/) barrels (bbl); Ohio (Ohio and Sunbury shales), 140 billion bbl; Tennessee (Chattanooga shale), 44 billion bbl; Indiana (New Albany shale), 40 billion bbl; Michigan (Antrim shale), 5 billion bbl; and Alabama (Chattanooga shale), 4 billion bbl. Recoverable resources have not been identified in West Virginia, Georgia, Oklahoma, Illinois, Arkansas, or Missouri outcrops. Co-production of uranium and metals is a possibility in the areas favorable for syncrude production.

Matthews, R.D.; Janka, J.C.; Dennison, J.M.

1980-01-01T23:59:59.000Z

154

Oil shale, tar sands, and related materials  

SciTech Connect (OSTI)

This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

Stauffer, H.C.

1981-01-01T23:59:59.000Z

155

Favorable conditions noted for Australia shale oil  

SciTech Connect (OSTI)

After brief descriptions of the Rundle, Condor, and Stuart/Kerosene Creek oil shale projects in Queensland, the competitive advantages of oil shale development and the state and federal governments' attitudes towards an oil shale industry in Australia are discussed. It is concluded that Australia is the ideal country in which to start an oil shale industry.

Not Available

1986-09-01T23:59:59.000Z

156

Bureau of Land Management Oil Shale Development  

E-Print Network [OSTI]

Bureau of Land Management Oil Shale Development Unconventional Fuels Conference University of Utah May 17, 2011 #12;#12;Domestic Oil Shale Resources Primary oil shale resources in the U.S. are in the Green River Formation in Wyoming, Utah, and Colorado. 72 % of this oil shale resource is on Federal

Utah, University of

157

Fire and explosion hazards of oil shale  

SciTech Connect (OSTI)

The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

Not Available

1989-01-01T23:59:59.000Z

158

2005 Minerals Yearbook CLAY AND SHALE  

E-Print Network [OSTI]

2005 Minerals Yearbook CLAY AND SHALE U.S. Department of the Interior U.S. Geological Survey February 2007 #12;CLAY AND SHALE--2005 18.1 CLAY AND SHALE By Robert L. Virta Domestic survey data at $1.68 billion in 2004 (table 1). Common clay and shale accounted for 59% of the tonnage, and kaolin

159

Oil shale retorting method and apparatus  

SciTech Connect (OSTI)

Disclosed is an improved method and apparatus for the retorting of oil shale and the formation of spent oil shale having improved cementation properties. The improved method comprises passing feed comprising oil shale to a contacting zone wherein the feed oil shale is contacted with heat transfer medium to heat said shale to retorting temperature. The feed oil shale is substantially retorted to form fluid material having heating value and forming partially spent oil shale containing carbonaceous material. At least a portion of the partially spent oil shale is passed to a combustion zone wherein the partially spent oil shale is contacted with oxidizing gas comprising oxygen and steam to substantially combust carbonaceous material forming spent oil shale having improved cementation properties.

York, E.D.

1983-03-22T23:59:59.000Z

160

Carbon sequestration in depleted oil shale deposits  

SciTech Connect (OSTI)

A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

Burnham, Alan K; Carroll, Susan A

2014-12-02T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Oil Shale and Other Unconventional Fuels Activities | Department...  

Broader source: Energy.gov (indexed) [DOE]

Naval Reserves Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on...

162

Workshop on gas potential of New Albany shale held in conjunction with the 1995 Ioga meeting in Evansville, Indiana on March 1, 1995. Topical report  

SciTech Connect (OSTI)

This workshop is intended to provide an overview of the organic lithofacies, organic carbon content, thermal maturity, and gas potential of the Devonian and Mississippian New Albany Shale in the Illinois Basin. In addition, the reservoir characteristics and completion technology for productive organic-rich Devonian shales in the Michigan and Appalachian Basins are also reviewed. Emphasis is being placed on how proven technologies together with appropriate geologic and geochemical information can be used to explore for gas in the New Albany Shale.

NONE

1996-01-01T23:59:59.000Z

163

POTENTIAL USES OF SPENT SHALE IN THE TREATMENT OF OIL SHALE RETORT WATERS  

E-Print Network [OSTI]

pore-volume study of retorted oil shale," Lawrence LivermoreReaction kinetics between and oil-shale residual carbon. 1.Reaction kinetics between and oil-shale residual carbon. 2.

Fox, J.P.

2013-01-01T23:59:59.000Z

164

POTENTIAL USES OF SPENT SHALE IN THE TREATMENT OF OIL SHALE RETORT WATERS  

E-Print Network [OSTI]

pore-volume study of retorted oil shale," Lawrence Livermoreits contact with the oil and shale. The gas condensate, onkinetics between and oil-shale residual carbon. 1. co Effect

Fox, J.P.

2013-01-01T23:59:59.000Z

165

POTENTIAL USES OF SPENT SHALE IN THE TREATMENT OF OIL SHALE RETORT WATERS  

E-Print Network [OSTI]

pore-volume study of retorted oil shale," Lawrence Livermorekinetics between and oil-shale residual carbon. 1. co Effectkinetics between and oil-shale residual carbon. 2. co 2

Fox, J.P.

2013-01-01T23:59:59.000Z

166

Modeling overpressures in sedimentary basins: Consequences for permeability and rheology of shales, and petroleum expulsion efficiency  

SciTech Connect (OSTI)

The prediction of overpressures using Institut Francais du Petrole's 2-D numerical model TEMISPACK is applied to several provinces of the world. In the Paris basin, France, normally pressured Liassic shales are shown to have permeabilities around a microdarcy, independently confirmed by laboratory measurements. In contrast, in the Norway section of the North Sea, Williston Basin, Canada, Gulf Coast, and in the Mahakam delta, observed overpressures of 10-50 MPa are consistently modeled with shale permeabilities around 1-10 nanodarcys. This theoretical value fits well with the lowest permeability measured in compacted shales. For these basins, compaction disequilibrium was found to explain most (>85%) of the overpressures. The only exception was the Williston basin in which overpressures observed in the organic-rich Bakken shales are entirely due to hydrocarbon generation. In Mahakam delta, the rheology of shales is nonlinear, i.e., the strength of shales increases rapidly with death. Consequently, shale compaction cannot be described by the linear behavior often assumed in hydrology. In the absence of fault barriers, numerical simulations and geological evidence suggest that overpressured source rocks have low or very low expulsion efficiency, irrespective of their organic content. However, shales with a permeability on the order of a microdarcy do not hinder petroleum migration.

Burrus, J.; Schneider, F.; Wolf, S. (Institut Francais du Petrole, Rueil-Malmaison (France))

1994-07-01T23:59:59.000Z

167

Comparison of Heating Methods for In-Situ Oil Shale Extraction  

E-Print Network [OSTI]

Oil shales are lamellar, non-porous, impermeable hydrocarbon bearing rocks that contain organic matter called kerogen which, when heated at pyrolysis temperature of approximately 600-800 ?, thermo-chemically decomposes to liberate hydrocarbons...

Hazra, Kaushik Gaurav

2014-04-29T23:59:59.000Z

168

Modern Devonian shale gas search starting in southwestern Indiana  

SciTech Connect (OSTI)

The New Albany shale of southwestern Indiana is a worthwhile exploration and exploitation objective. The technical ability to enhance natural fractures is available, the drilling depths are shallow, long term gas reserves are attractive, markets are available, drilling costs are reasonable, risks are very low, multiple drilling objectives are available, and the return on investment is good. Indiana Geological Survey records are well organized, accessible, and easy to use. The paper describes the New Albany shale play, play size, early exploration, geologic setting, completion techniques, and locating prime areas.

Minihan, E.D.; Buzzard, R.D. (Minihan/Buzzard Consulting Firm, Fort Worth, TX (United States))

1995-02-27T23:59:59.000Z

169

A1. SHALE GAS PRODUCTION GROWTH IN THE UNITED STATES..............................1 A2. VARIABILITY IN SHALE WELL PRODUCTION PERFORMANCE ............................1  

E-Print Network [OSTI]

basin, and of late the Eagle Ford shale located in southwest Texas. Figure A1 illustrates the growth reservoir pressure, total organic content, thermal maturity, porosity, the presence of natural fractures Eagle Ford Marcellus Haynesville Woodford Fayetteville Barnett Figure A1. Growth in natural gas

170

Fractured gas reservoirs in the Devonian shale of the Illinois and Appalachian basins  

SciTech Connect (OSTI)

The Devonian and Lower Mississippian black shale sequence of Kentucky includes the New Albany Shale of Illinois basin and the Ohio Shale of the Appalachian basin. Fractured reservoirs in the Ohio Shale contain a major gas resource, but have not been so prolific in the New Albany Shale. The authors propose two models of fractured shale reservoirs in both the Illinois and the Appalachian basins, to be tested with gas production data. (1) Where reactivated basement faults have propagated to the surface, the lack of an effective seal has prevented the development of overpressure. The resulting fracture system is entirely tectonic is origin, and served mainly as a conduit for gas migration from the basin to the surface. Gas accumulations in such reservoirs typically are small and underpressured. (2) Where basement faults have been reactivated but have not reached the surface, a seal on the fractured reservoir is preserved. In areas where thermal maturity has been adequate, overpressuring due to gas generation resulted in a major extension of the fracture system, as well as enhanced gas compression and adsorption. Such gas accumulations are relatively large. Original overpressuring has been largely lost, due both to natural depletion and to uncontrolled production. The relative thermal immaturity of the Illinois basin accounts for the scarcity of the second type of fractured reservoir and the small magnitude of the New Albany Shale gas resource.

Hamilton-Smith, T.; Walker, D.; Nuttall, B. (Kentucky Geological Survey, Lexington (United States))

1991-08-01T23:59:59.000Z

171

Gasification characteristics and kinetics for an eastern oil shale  

SciTech Connect (OSTI)

Gasification tests of Indiana New Albany oil shale fines have been conducted. Thermobalance test results indicate that over 95% of the organic carbon in the shale can be gasified at 1700{degree}F and 135 psig with 30 minutes residence time under a synthesis gas atmosphere and at 1800{degree}F and 15 psig with 30 minutes residence time under a hydrogen/steam atmosphere. A simple kinetic expression for hydrogen/steam gasification weight loss has been developed. Weight loss has been described as the sum of the weight loss from two independent, simultaneous reaction paths: a rapid (<2 minutes) first order reaction and a slower gasification reaction that can be expressed in terms of the steam/carbon reaction. Work is in progress to study the gasification of other Eastern shales and improve the kinetic description of weight loss.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-04-01T23:59:59.000Z

172

Heat of combustion of Green River oil shale  

SciTech Connect (OSTI)

The authors derive simple equations for estimating the heat of combustion of raw shale by thermochemical estimates and by linear regression of experimental data. They find that the heat can be estimated well by an exothermic term that accounts for the combustion of organic matter and a constant that accounts for pyrite combustion, carbonate decomposition, and glass formation. The net contribution of reactions included in the constant is endothermic for the standard state products of bomb calorimetry. As a sample application, the authors perform an energy balance on a modified Fischer assay of average Green River shale by using one of our formulas for raw shale along with previously derived formulas for pyrolysis products.

Muehlbauer, M.J.; Burnham, A.K.

1984-04-01T23:59:59.000Z

173

CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS  

E-Print Network [OSTI]

recovery Vent gas '\\Raw shale oil Recycled gas compressorThis process produces shale oil, a low BTU gas, and char,Oil Shale Process" in Oil Shale and Tar Sands, J. W. Smith

Persoff, P.

2011-01-01T23:59:59.000Z

174

Gasification kinetics of six eastern shales in steam and synthesis gas atmospheres  

SciTech Connect (OSTI)

Gasification reactivities have been determined for six Eastern shales with conversions described by a model incorporating fast and slow gasification reactions. A simple model, based on Indiana New Albany shale, was developed to describe the fast and slow weight loss as well as the slow sulfur and organic carbon gasification rates. The slow sulfur and organic carbon reactions are described by rate equations that are first order in sulfur and organic carbon and include the steam pressure. Terms in the organic carbon rate expression account for hydrogen and carbon monoxide inhibition of the steam-carbon reaction. The fraction of shale species lost by fast and slow gasification and the rate of slow sulfur gasification are similar (and assumed to be equal) for the six Eastern shales studied. Eastern shale organic carbon reactivities are different and have been described with different kinetic parameters in the slow organic carbon gasification rate equation. The kinetic expressions developed for Eastern shale gasification are valid in steam and steam; synthesis gas mixtures and for residence times of more than 3 minutes. Gasification is described for temperature and pressure ranges of 1144 to 1311 K and 0.20 to 3.55 MPa, respectively.

Rue, D.M.; Lau, F.S. (Institute of Gas Technology, Chicago, IL (USA))

1989-03-01T23:59:59.000Z

175

A feasibility study of oil shale fired pulse combustors with applications to oil shale retorting. Final report  

SciTech Connect (OSTI)

The results of the experimental investigation performed to determine the feasibility of using pulverized Colorado oil shale to fuel a bench scale pulse combustor reveal that oil shale cannot sustain pulsations when used alone as fuel. Trace amounts of propane mixed with the oil shale enabled the pulsations, however. Up to 80% of the organic material in the oil shale was consumed when it was mixed with propane in the combustor. Beyond the feasibility objectives, the operating conditions of the combustor fuel with propane and mixtures of oil shale and propane were characterized with respect to pulsation amplitude and frequency and the internal combustor wall temperature over fuel lean and fuel rich stoichiometries. Maximum pressure excursions of 12.5 kPa were experienced in the combustor. Pulsation frequencies ranged from 50 to nearly 80 Hz. Cycle resolved laser Doppler anemometry velocities were measured at the tail pipe exit plane. Injecting inert mineral matter (limestone) into the pulse combustor while using propane fuel had only a slight effect on the pulsation frequency for the feed rates tested.

Morris, G.J.; Johnson, E.K.; Zhang, G.Q.; Roach, R.A.

1992-07-01T23:59:59.000Z

176

POLYVINYLCHLORIDE WASTE WITH OIL SHALE ASH TO CAPTURE  

E-Print Network [OSTI]

alkaline oil shale ash. Solid heat carrier (Galoter process)-type oil shale retorting units, where the

V. Oja; A. Elenurm; I. Rohtla; E. Tearo; E. Tali

177

Investigation and development of alternative methods for shale oil processing and analysis. Final technical report, October 1979--April 1983  

SciTech Connect (OSTI)

Oil shale, a carbonaceous rock which occurs abundantly in the earth`s crust, has been investigated for many years as an alternate source of fuel oil. The insoluble organic matter contained in such shales is termed {open_quotes}Kerogen{close_quotes} from the Greek meaning oil or oil forming. The kerogen in oil shale breaks down into oil-like products when subjected to conditions simulating destructive distillation. These products have been the subject of extensive investigations by several researchers and many of the constituents of shale oil have been identified. (1) Forsman (2) estimates that the kerogen content of the earth is roughly 3 {times} 10{sup 15} tons as compared to total coal reserves of about 5 {times} 10{sup 12}. Although the current cost per barrel estimate for commercial production of shale oil is higher than that of fossil oil, as our oil reserves continue to dwindle, shale oil technology will become more and more important. When oil shale is heated, kerogen is said to undergo chemical transformation to usable oil in two steps (3): Kerogen (in oil shale) 300-500{degrees}C bitumen. Crude shale oil and other products. The crude shale oil so obtained differs from fossil oil in that: (1) kerogen is thought to have been produced from the aging of plant matter over many years; (2) shale oil has a higher nitrogen content than fossil oil; (3) non-hydrocarbons are present to a much greater extent in shale oil; and (4) the hydrocarbons in shale oil are much more unsaturated than those in fossil oil (petroleum).

Evans, R.A.

1998-06-01T23:59:59.000Z

178

Production Trends of Shale Gas Wells  

E-Print Network [OSTI]

To obtain better well performance and improved production from shale gas reservoirs, it is important to understand the behavior of shale gas wells and to identify different flow regions in them over a period of time. It is also important...

Khan, Waqar A.

2010-01-14T23:59:59.000Z

179

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

Minor elements in oil shale and oil~shale products, LERCmercury to the oil shale, shale oil, and retort water. Thesemercury to spent shale, shale oil, retort water and offgas

Fox, J. P.

2012-01-01T23:59:59.000Z

180

FLUIDIZED BED COMBUSTION UNIT FOR OIL SHALE  

E-Print Network [OSTI]

combustion performance using oil shale as fuel in direct burning process. It is a steel column of 18 cm

M. Hammad; Y. Zurigat; S. Khzai; Z. Hammad; O. Mubydeem

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Oil shale technology. Final report  

SciTech Connect (OSTI)

This collaborative project with industrial participants studied oil shale retorting through an integrated program of fundamental research, mathematical model development and operation of a 4-tonne-per-day solid recirculation oil shale test unit. Quarterly, project personnel presented progress and findings to a Project Guidance Committee consisting of company representatives and DOE program management. We successfully operated the test unit, developed the oil shale process (OSP) mathematical model, evaluated technical plans for process scale up and determined economics for a successful small scale commercial deployment, producing premium motor fuel, specility chemicals along with electricity co-production. In budget negotiations, DOE funding for this three year CRADA was terminated, 17 months prematurely, as of October 1993. Funds to restore the project and continue the partnership have not been secured.

NONE

1995-03-01T23:59:59.000Z

182

Oil shale technology and evironmental aspects  

SciTech Connect (OSTI)

Oil shale processes are a combination of mining, retorting, and upgrading facilities. This work outlines the processing steps and some design considerations required in an oil shale facility. A brief overview of above ground and in situ retorts is presented; 6 retorts are described. The development aspects which the oil shale industry is addressing to protect the environment are presented.

Scinta, J.

1982-01-01T23:59:59.000Z

183

Australian developments in oil shale processing  

SciTech Connect (OSTI)

This study gives some background on Australian oil shale deposits, briefly records some history of oil shale processing in the country and looks at the current status of the various proposals being considered to produce syncrudes from Australian oil shales. 5 refs.

Baker, G.L.

1981-01-01T23:59:59.000Z

184

Burgess Shale: Cambrian Explosion in Full Bloom  

E-Print Network [OSTI]

4 Burgess Shale: Cambrian Explosion in Full Bloom James W. Hagadorn T he middle cambrian burgess shale is one of the world's best-known and best-studied fossil deposits. The story of the discovery in the Burgess Shale Formation of the Canadian Rockies, Charles Walcott discovered a remarkable "phyl- lopod

Hagadorn, Whitey

185

Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations  

SciTech Connect (OSTI)

This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

Zoback, Mark; Kovscek, Anthony; Wilcox, Jennifer

2013-09-30T23:59:59.000Z

186

Methane adsorption on Devonian shales  

E-Print Network [OSTI]

METHANE ADSORPTION ON DEVONIAN SHALES A Thesis by FAN-CHANG LI Submitted to thc Office of Graclua4e Sturiics of texas AgiM Ulllvel'sliy in pari, ial fulfilhuent of t, hc requirements I'or t, hc degree of ii IAS'I'Elf OF SCIL'NCE December... 1992 Major Subject, : Chemical Engineering METHANE ADSORPTION ON DEVONIAN SHALES A Thesis l&y I'AN-CHANC LI Approved as to style and contcut by: A. T. 'vtratson (Chair of Commitl. ee) John C. Slattery (Member) Bruce . Hcrhcrt (Memhcr...

Li, Fan-Chang

1992-01-01T23:59:59.000Z

187

CLAY AND SHALE--2003 18.1 CLAY AND SHALE  

E-Print Network [OSTI]

%), drilling mud (22%), and iron ore pelletizing (15%); for common clay and shale, brick (55%), cement (19 Protection Agency (EPA) finalized its maximum achievable control technology (MACT) regulation/Mg of uncalcined clay or a reduction of 30% in emissions. For new batch kilns, hydrogen fluoride and hydrogen

188

Optical Properties of Mixed Black Carbon, Inorganic and Secondary Organic Aerosols  

SciTech Connect (OSTI)

Summarizes the achievements of the project, which are divided into four areas: 1) Optical properties of secondary organic aerosols; 2) Development and of a polar nephelometer to measure aerosol optical properties and theoretical approaches to several optical analysis problems, 3) Studies on the accuracy of measurements of absorbing carbon by several methods, and 4) Environmental impacts of biodiesel.

Paulson, S E

2012-05-30T23:59:59.000Z

189

Depositional Model of the Marcellus Shale in West Virginia Based on Facies Analysis  

SciTech Connect (OSTI)

A lithologic analysis of well exposed Marcellus outcrops has identified six different facies in West Virginia and neighboring states: (1) light gray calcareous shale, (2) fossiliferous limestone, (3) black calcareous shale, (4) black noncalcareous shale, (5) dark gray noncalcareous shale, and (6) K-bentonite. Close interbedding of these rock types attests to a complex, ever-changing environment on the eastern foreland ramp of the Appalachian Basin. The environmental setting was clearly not a deep trough, permanently anoxic, salinity stratified, sediment starved, and populated exclusively by phytoplanktonthe traditional depositional model. To the contrary, our sedimentary data suggest a rather shallow water depth, intermittent anoxia, normal-marine salinity, a fluctuating input of siliciclastic mud, and faunal communities of low and moderate diversity. Interbedding of the shale and limestone lithofacies as well as the vertical stacking of facies associations is explained most simply by fluctuations in water depth coupled with fluctuations in sediment supply. The sea floor was, at times, immediately below wave base (Facies 1 and 2), around the depth of the thermocline (Facies 2 and 3), or below the thermocline (Facies 4 and 5), relative sea level changing through two sequences of lowstand, transgression, and highstand. Simultaneously the supply of siliciclastic mud was greater at times of lowstand (increased erosion) and highstand (prograding shoreline), and the supply smaller during transgression (sediment stored in distant coastal plain).

Bruner, Kathy

2011-11-14T23:59:59.000Z

190

Hydrotreating of oil from eastern oil shale  

SciTech Connect (OSTI)

Oil shale provides one of the major fossil energy reserves for the United States. The quantity of reserves in oil shale is less than the quantity in coal, but is much greater (by at least an order of magnitude) than the quantity of crude oil reserves. With so much oil potentially available from oil shale, efforts have been made to develop techniques for its utilization. In these efforts, hydrotreating has proved to be an acceptable technique for upgrading raw shale oil to make usuable products. The present work demonstrated the use of the hydrotreating technique for upgrading an oil from Indiana New Albany oil shale.

Scinta, J.; Garner, J.W.

1984-01-01T23:59:59.000Z

191

Jordan ships oil shale to China  

SciTech Connect (OSTI)

Jordan and China have signed an agreement to develop oil shale processing technology that could lead to a 200 ton/day oil shale plant in Jordan. China will process 1200 tons of Jordanian oil shale at its Fu Shun refinery. If tests are successful, China could build the demonstration plant in Jordan's Lajjun region, where the oil shale resource is estimated at 1.3 billion tons. China plans to send a team to Jordan to conduct a plant design study. A Lajjun oil shale complex could produce as much as 50,000 b/d of shale oil. An earlier 500 ton shipment of shale is said to have yielded promising results.

Not Available

1986-12-01T23:59:59.000Z

192

Bakken Shale Oil Production Trends  

E-Print Network [OSTI]

to study this Type of behavior because of scattering data, which leads to erroneous interpretation for the analysis. These production Types, especially Types I and II will give a new type curve matches for shale oil wells above or below the bubble point....

Tran, Tan

2012-07-16T23:59:59.000Z

193

Isothermal pyrolysis and char combustion of oil shales  

SciTech Connect (OSTI)

Yields and rates of hydrocarbons evolved during pyrolysis of oil shales have been measured with improved accuracy. Green River and New Albany oil shales were heated in a fluidized sand bed, and volatile pyrolysis products were transferred to a combustion tube and burned. Resulting H/sub 2/O and CO/sub 2 were detected in real time by mass spectrometry. Residual char was subsequently burned to allow complete C and H balances. Good closure was obtained. Proportions of organic C and H released as pyrolysis products and retained as char were determined. Shale oil loss due to the presence of oxidized shale in the fluidized bed was measured accurately. We find that all of the experimental apparatus that the pyrolysis gas contacts must be near pyrolysis temperature to avoid condensation of heavy oil which subsequently forms coke and secondary products. We observe a faster release of products with all transfer lines 450/degree/C than when they are at 300/degree/C. The current uncertainty in pyrolysis rates is due in part to such difficulties with experimental techniques. 12 refs., 7 figs., 1 tab.

Coburn, T.T.; Taylor, R.W.; Morris, C.J.; Duval, V.

1988-02-03T23:59:59.000Z

194

Focus on the Marcellus Shale By Lisa Sumi  

E-Print Network [OSTI]

Shale Gas: Focus on the Marcellus Shale By Lisa Sumi FOR THE OIL & GAS ACCOUNTABILITY PROJECT on potential oil and gas development in the Marcellus Shale formation in northeastern Pennsylvania · www.ogap.org #12;Shale Gas: Focus on the Marcellus Shale A REPORT COMPILED FOR THE OIL AND GAS

Boyer, Elizabeth W.

195

Conversion characteristics of 10 selected oil shales  

SciTech Connect (OSTI)

The conversion behavior of 10 oil shale from seven foreign and three domestic deposits has been studied by combining solid- and liquid-state nuclear magnetic resonance (NMR) measurements with material balance Fischer assay conversion data. The extent of aromatization of aliphatic carbons was determined. Between zero and 42% of the raw shale aliphatic carbon formed aromatic carbon during Fischer assay. For three of the shales, there was more aromatic carbon in the residue after Fisher assay than in the raw shale. Between 10 and 20% of the raw shale aliphatic carbons ended up as aliphatic carbons on the spent shale. Good correlations were found between the raw shale aliphatic carbon and carbon in the oil and between the raw shale aromatic carbon and aromatic carbon on the spent shale. Simulated distillations and molecular weight determinations were performed on the shale oils. Greater than 50% of the oil consisted of the atmospheric and vacuum gas oil boiling fractions. 14 refs., 15 figs., 1 tab.

Miknis, F.P.

1989-08-01T23:59:59.000Z

196

Sedimentology of gas-bearing Devonian shales of the Appalachian Basin  

SciTech Connect (OSTI)

The Eastern Gas Shales Project (1976-1981) of the US DOE has generated a large amount of information on Devonian shale, especially in the western and central parts of the Appalachian Basin (Morgantown Energy Technology Center, 1980). This report summarizes this information, emphasizing the sedimentology of the shales and how it is related to gas, oil, and uranium. This information is reported in a series of statements each followed by a brief summary of supporting evidence or discussion and, where interpretations differ from our own, we include them. We believe this format is the most efficient way to learn about the gas-bearing Devonian shales of the Appalachian Basin and have organized our statements as follows: paleogeography and basin analysis; lithology and internal stratigraphy; paleontology; mineralogy, petrology, and chemistry; and gas, oil, and uranium.

Potter, P.E.; Maynard, J.B.; Pryor, W.A.

1981-01-01T23:59:59.000Z

197

Western oil shale development: a technology assessment. Volume 8. Health effects of oil shale development  

SciTech Connect (OSTI)

Information on the potential health effects of a developing oil shale industry can be derived from two major sources: (1) the historical experience in foreign countries that have had major industries; and (2) the health effects research that has been conducted in the US in recent years. The information presented here is divided into two major sections: one dealing with the experience in foreign countries and the second dealing with the more recent work associated with current oil shale development in the US. As a result of the study, several observations can be made: (1) most of the current and historical data from foreign countries relate to occupational hazards rather than to impacts on regional populations; (2) neither the historical evidence from other countries nor the results of current research have shown pulmonary neoplasia to be a major concern, however, certain types of exposure, particularly such mixed source exposures as dust/diesel or dust/organic-vapor have not been adequately studied and the lung cancer question is not closed; (3) the industry should be alert to the incidence of skin disease in the industrial setting, however, automated techniques, modern industrial hygiene practices and realistic personal hygiene should greatly reduce the hazards associated with skin contact; and (4) the entire question of regional water contamination and any resultant health hazard has not been adequately addressed. The industrial practice of hydrotreating the crude shale oil will diminish the carcinogenic hazard of the product, however, the quantitative reduction of biological activity is dependent on the degree of hydrotreatment. Both Soviet and American experimentalists have demonstrated a correlation betweed carcinogenicity/toxicity and retorting temperature; the higher temperatures producing the more carcinogenic or toxic products.

Rotariu, G.J.

1982-02-01T23:59:59.000Z

198

Shale Oil Value Enhancement Research  

SciTech Connect (OSTI)

Raw kerogen oil is rich in heteroatom-containing compounds. Heteroatoms, N, S & O, are undesirable as components of a refinery feedstock, but are the basis for product value in agrochemicals, pharmaceuticals, surfactants, solvents, polymers, and a host of industrial materials. An economically viable, technologically feasible process scheme was developed in this research that promises to enhance the economics of oil shale development, both in the US and elsewhere in the world, in particular Estonia. Products will compete in existing markets for products now manufactured by costly synthesis routes. A premium petroleum refinery feedstock is also produced. The technology is now ready for pilot plant engineering studies and is likely to play an important role in developing a US oil shale industry.

James W. Bunger

2006-11-30T23:59:59.000Z

199

Review of Emerging Resources: U.S. Shale Gas and Shale Oil Plays  

Reports and Publications (EIA)

To gain a better understanding of the potential U.S. domestic shale gas and shale oil resources, the Energy Information Administration (EIA) commissioned INTEK, Inc. to develop an assessment of onshore lower 48 states technically recoverable shale gas and shale oil resources. This paper briefly describes the scope, methodology, and key results of the report and discusses the key assumptions that underlie the results.

2011-01-01T23:59:59.000Z

200

Developments in oil shale in 1987  

SciTech Connect (OSTI)

Oil shale development continued at a slow pace in 1987. The continuing interest in this commodity is demonstrated by the 342 oil shale citations added to the US Department of Energy Energy Database during 1987. The Unocal project in Parachute, Colorado, produced 600,000 bbl of synfuel in 1987. An appreciable amount of 1987's activity was associated with the nonsynfuel uses of oil shale. 4 figs., 2 tabs.

Knutson, C.F.; Dana, G.F.; Solti, G.; Qian, J.L.; Ball, F.D.; Hutton, A.C.; Hanna, J.; Russell, P.L.; Piper, E.M.

1988-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE  

E-Print Network [OSTI]

20 to 40% of the oil shale, and explosively rubblizing andCEMENTS FROM SPENT OIL SHALE P.K. Mehta and P. Persoff AprilCement Manufacture from Oil Shale, U.S. Patent 2,904,445,

Mehta, P.K.

2012-01-01T23:59:59.000Z

202

CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS  

E-Print Network [OSTI]

Controls for a Commercial Oil Shale In~try, Vol. I, An En~Mathematical Hodel for In-Situ Shale Retorting," in SecondBriefing on In-Situ Oil Shale Technology, Lawrence Livermore

Persoff, P.

2011-01-01T23:59:59.000Z

203

Control Strategies for Abandoned in situ Oil Shale Retorts  

E-Print Network [OSTI]

Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Water Pollution of Spent Oil Shale Residues, EDB Lea,

Persoff, P.; Fox, J.P.

1979-01-01T23:59:59.000Z

204

CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS  

E-Print Network [OSTI]

Controls for a Commercial Oil Shale In~try, Vol. I, An En~in Second Briefing on In-Situ Oil Shale Technology, LawrenceReactions in Colorado Oil Shale, Lawrence Report UCRL-

Persoff, P.

2011-01-01T23:59:59.000Z

205

INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE  

E-Print Network [OSTI]

CEMENTS FROM SPENT OIL SHALE P.K. Mehta and P. Persoff AprilCement Manufacture from Oil Shale, U.S. Patent 2,904,445,CEMENTS FROM SPENT OIL SHALE P, K, Mehta Civil Engineering

Mehta, P.K.

2012-01-01T23:59:59.000Z

206

INTER-MOUNTAIN BASINS SHALE BADLAND extent exaggerated for display  

E-Print Network [OSTI]

INTER-MOUNTAIN BASINS SHALE BADLAND R.Rondeau extent exaggerated for display ACHNATHERUM HYMENOIDES HERBACEOUS ALLIANCE Achnatherum hymenoides Shale Barren Herbaceous Vegetation ARTEMISIA BIGELOVII SHRUBLAND ALLIANCE Leymus salinus Shale Sparse Vegetation Overview: This widespread ecological system

207

CORROSION OF METALS IN OIL SHALE ENVIRONMENTS  

E-Print Network [OSTI]

at the National Association of Corrosion EngineersConference, Corrosion '81, Toronto, Ontario, Canada,April 6-10, 1981 CORROSION OF METALS IN OIL SHALE

Bellman Jr., R.

2012-01-01T23:59:59.000Z

208

Challenges and strategies of shale gas development.  

E-Print Network [OSTI]

??The objective of this paper is to help new investors and project developers identify the challenges of shale gas E&P and to enlighten them of (more)

Lee, Sunje

2012-01-01T23:59:59.000Z

209

Decline Curve Analysis of Shale Oil Production.  

E-Print Network [OSTI]

?? Production of oil and gas from shale is often described as a revolution to energyproduction in North America. Since the beginning of this century (more)

Lund, Linnea

2014-01-01T23:59:59.000Z

210

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

Minor Elements in Oil Shale and Oil Shale Products. LERCfor Use 1n Oil Shale and Shale Oil. OSRD-32, 1945. Jeris, J.Water coproduced with shale oil and decanted from it is

Farrier, D.S.

2011-01-01T23:59:59.000Z

211

TREATMENT OF MULTIVARIATE ENVIRONMENTAL AND HEALTH PROBLEMS ASSOCIATED WITH OIL SHALE TECHNOLOGY  

E-Print Network [OSTI]

Identified in Oil Shale and Shale Oil. list." 1. Preliminaryrisks of large scale shale oil production are sufficient tofound in oil shale and shale oil by EMIC and ETIC, has

Kland, M.J.

2010-01-01T23:59:59.000Z

212

TREATMENT OF MULTIVARIATE ENVIRONMENTAL AND HEALTH PROBLEMS ASSOCIATED WITH OIL SHALE TECHNOLOGY  

E-Print Network [OSTI]

Chemicals Identified in Oil Shale and Shale Oil. list." 1.of Trace Contaminants in Oil Shale Retort Wa- ters", Am.Trace Contaminants in Oil Shale Retort Waters", in Oil Shale

Kland, M.J.

2010-01-01T23:59:59.000Z

213

Characterization of contaminants in oil shale residuals and the potential for their management to meet environmental quality standards. Final report  

SciTech Connect (OSTI)

Some general aspects of various oil shale processes developed for scale-up to commercial size modular units are described. The overall magnitude of an envisioned commercial shale oil operation and the magnitude of resulting potentially polluting residues in particular solid residues from retorting oil shale and associated operations and wastewater from retort streams and other sources are considered. The potential problems ensuing from self-oxidation of stockpiles of oil shale and from residual carbonaceous retorted oil shale disposed above ground and/or from in situ retorting operations are examined. Some methods for managing self-heating processes are suggested. The most plausible method of avoiding potential self-heating for retorted oil shale is to oxidize as much as possible of the organic carbon present by utilizing a process that will produce low carbon or carbon-free retorted oil shale residues. In the case of unretorted oil shale, the dimensions and shapes of the stockpiles should be designed such that heat build-up is eliminated or kept to a minimum.

Schmidt-Collerus, J.J.

1984-02-01T23:59:59.000Z

214

Characterization of DOE reference oil shales: Mahogany Zone, Parachute Creek Member, Green River Formation Oil Shale, and Clegg Creek Member, New Albany Shale  

SciTech Connect (OSTI)

Measurements have been made on the chemical and physical properties of two oil shales designated as reference oil shales by the Department of Energy. One oil shale is a Green River Formation, Parachute Creek Member, Mahogany Zone Colorado oil shale from the Exxon Colony mine and the other is a Clegg Creek Member, New Albany shale from Kentucky. Material balance Fischer assays, carbon aromaticities, thermal properties, and bulk mineralogic properties have been determined for the oil shales. Kerogen concentrates were prepared from both shales. The measured properties of the reference shales are comparable to results obtained from previous studies on similar shales. The western reference shale has a low carbon aromaticity, high Fischer assay conversion to oil, and a dominant carbonate mineralogy. The eastern reference shale has a high carbon aromaticity, low Fischer assay conversion to oil, and a dominant silicate mineralogy. Chemical and physical properties, including ASTM distillations, have been determined for shale oils produced from the reference shales. The distillation data were used in conjunction with API correlations to calculate a large number of shale oil properties that are required for computer models such as ASPEN. There was poor agreement between measured and calculated molecular weights for the total shale oil produced from each shale. However, measured and calculated molecular weights agreed reasonably well for true boiling point distillate fractions in the temperature range of 204 to 399/sup 0/C (400 to 750/sup 0/F). Similarly, measured and calculated viscosities of the total shale oils were in disagreement, whereas good agreement was obtained on distillate fractions for a boiling range up to 315/sup 0/C (600/sup 0/F). Thermal and dielectric properties were determined for the shales and shale oils. The dielectric properties of the reference shales and shale oils decreased with increasing frequency of the applied frequency. 42 refs., 34 figs., 24 tabs.

Miknis, F. P.; Robertson, R. E.

1987-09-01T23:59:59.000Z

215

Method for forming an in-situ oil shale retort in differing grades of oil shale  

SciTech Connect (OSTI)

An in-situ oil shale retort is formed in a subterranean formation containing oil shale. The formation comprises at least one region of relatively richer oil shale and another region of relatively leaner oil shale. According to one embodiment, formation is excavated from within a retort site for forming at least one void extending horizontally across the retort site, leaving a portion of unfragmented formation including the regions of richer and leaner oil shale adjacent such a void space. A first array of vertical blast holes are drilled in the regions of richer and leaner oil shale, and a second array of blast holes are drilled at least in the region of richer oil shale. Explosive charges are placed in portions of the blast holes in the first and second arrays which extend into the richer oil shale, and separate explosive charges are placed in portions of the blast holes in the first array which extend into the leaner oil shale. This provides an array with a smaller scaled depth of burial (sdob) and closer spacing distance between explosive charges in the richer oil shale than the sdob and spacing distance of the array of explosive charges in the leaner oil shale. The explosive charges are detonated for explosively expanding the regions of richer and leaner oil shale toward the horizontal void for forming a fragmented mass of particles. Upon detonation of the explosive, greater explosive energy is provided collectively by the explosive charges in the richer oil shale, compared with the explosive energy produced by the explosive charges in the leaner oil shale, resulting in comparable fragmentation in both grades of oil shale.

Ricketts, T.E.

1984-04-24T23:59:59.000Z

216

Shale Oil Production Performance from a Stimulated Reservoir Volume.  

E-Print Network [OSTI]

??The horizontal well with multiple transverse fractures has proven to be an effective strategy for shale gas reservoir exploitation. Some operators are successfully producing shale (more)

Chaudhary, Anish Singh

2011-01-01T23:59:59.000Z

217

Secretary of Energy Advisory Board Hosts Conference Call on Shale...  

Office of Environmental Management (EM)

Secretary of Energy Advisory Board Hosts Conference Call on Shale Gas Draft Report Secretary of Energy Advisory Board Hosts Conference Call on Shale Gas Draft Report November 10,...

218

Strategic Significance of Americas Oil Shale Resource  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

II Oil Shale Resources Technology and Economics Office of Deputy Assistant Secretary for Petroleum Reserves Office of Naval Petroleum and Oil Shale Reserves U.S. Department of...

219

Characterization of Gas Shales by X-ray Raman Spectroscopy |...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Drew Pomerantz, Schlumberger Unconventional hydrocarbon resources such as gas shale and oil-bearing shale have emerged recently as economically viable sources of energy,...

220

Impact of Sorption Isotherms on the Simulation of CO2-Enhanced Gas Recovery and Storage Process in Marcellus Shale  

E-Print Network [OSTI]

and kerogen surfaces, very similar to the way methane is stored within coal beds. It has been demonstrated in gassy coals that on average; CO2 is preferentially adsorbed, displacing methane at a ratio of two for one or more. Black shale reservoirs may react similarly and desorb methane in the presence

Mohaghegh, Shahab

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Concentration of oil shale by froth flotation. Monthly technical letter report, June 1-30, 1983  

SciTech Connect (OSTI)

During the month of June we continued with the study of froth flotation of New Albany shale. Because the shale particles were not reduced sufficiently to literate organics and inorganics by the use of 3.8 cm diameter balls (as grinding medium) we used 1.3 cm diameter balls. The smaller diameter balls are more efficient in grinding fine particles. However, the 1.3 cm diameter balls were not effective in grinding the large particles of the feed shale. Hence, we initially used 3.8 cm diameter balls and then 1.3 cm diameter balls. As previously observed, the fractions of organics in the feed shale recovered in the concentrate were very high, in excess of 95%. The grade or fraction of organics in the concentrate increased steadily, indicating increased liberation with increased grinding time. A factor of two increase in the grade was observed at the end of 26 hours of grinding. The Minerals Separation Corporation has completed the dynamic heavy media testing of Tract C-A shales.

Krishnan, G.

1983-10-14T23:59:59.000Z

222

Black carbon in the Gulf of Maine : new insights into inputs and cycling of combustion-derived organic carbon  

E-Print Network [OSTI]

Emissions of black carbon (BC), the soot and char formed during incomplete combustion of fossil and biomass fuels, have increased over the last century and are estimated to be between 8 and 270 Tg BC/yr. BC may affect ...

Flores Cervantes, Dborah Xanat, 1978-

2008-01-01T23:59:59.000Z

223

Carcinogenicity Studies of Estonian Oil Shale Soots  

E-Print Network [OSTI]

Several series of chronic experiments in white mice and white rats were carried out in order to determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All the investigated samples of soot showed a relatively low (from 14 to 1200 ppm) benzo

A. Vosamae

224

Fluidized bed retorting of eastern oil shale  

SciTech Connect (OSTI)

This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of eastern New Albany oil shale. This is the fourth design study conducted by Foster Wheeler; previous design cases employed the following technologies: Fluidized bed rotating/combustion of Colorado Mahogany zone shale. An FCC concept of fluidized bed retorting/combustion of Colorado Mahogany zone shale. Directly heated moving vertical-bed process using Colorado Mahogany zone shale. The conceptual design encompasses a grassroots facility which processes run-of-mine oil shale into a syncrude oil product and dispose of the spent shale solids. The plant has a nominal capacity of 50,000 barrels per day of syncrude product, produced from oil shale feed having a Fischer Assay of 15 gallons per ton. Design of the processing units was based on non-confidential published information and supplemental data from process licensors. Maximum use of process and cost information developed in the previous Foster Wheeler studies was employed. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is detailed by plant section and estimates of the annual operating requirements and costs are provided. In addition, process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed. 12 refs., 17 figs., 52 tabs.

Gaire, R.J.; Mazzella, G.

1989-03-01T23:59:59.000Z

225

Fracture Conductivity of the Eagle Ford Shale  

E-Print Network [OSTI]

such as the Eagle Ford Shale. This work investigates the fracture conductivities of seven Eagle Ford Shale samples collected from an outcrop of facies B. Rough fractures were induced in the samples and laboratory experiments that closely followed the API RP-61...

Guzek, James J

2014-07-25T23:59:59.000Z

226

Thermomechanical properties of selected shales  

SciTech Connect (OSTI)

The experimental work discussed in this report is part of an ongoing program concerning evaluation of sedimentary and other rock types as potential hosts for a geologic repository. The objectives are the development of tools and techniques for repository characterization and performance assessment in a diversity of geohydrologic settings. This phase of the program is a laboratory study that investigates fundamental thermomechanical properties of several different shales. Laboratory experiments are intrinsically related to numerical modeling and in situ field experiments, which together will be used for performance assessment.

Hansen, F.D.; Vogt, T.J.

1987-08-01T23:59:59.000Z

227

LLNL oil shale project review: METC third annual oil shale contractors meeting  

SciTech Connect (OSTI)

The Lawrence Livermore National Laboratory combines laboratory and pilot-scale experimental measurements with mathematical modeling of fundamental chemistry and physics to provide a technical base for evaluating oil shale retorting alternatives. Presented herein are results of four research areas of interest in oil shale process development: Recent Progress in Solid-Recycle Retorting and Related Laboratory and Modeling Studies; Water Generation During Pyrolysis of Oil Shale; Improved Analytical Methods and Measurements of Rapid Pyrolysis Kinetics for Western and Eastern Oil Shale; and Rate of Cracking or Degradation of Oil Vapor In Contact with Oxidized Shale. We describe operating results of a 1 tonne-per-day, continuous-loop, solid-recycle, retort processing both Western And Eastern oil shale. Sulfur chemistry, solid mixing limits, shale cooling tests and catalyst addition are all discussed. Using a triple-quadrupole mass spectrometer, we measure individual species evolution with greater sensitivity and selectivity. Herein we discuss our measurements of water evolution during ramped heating of Western and Eastern oil shale. Using improved analytical techniques, we determine isothermal pyrolysis kinetics for Western and Eastern oil shale, during rapid heating, which are faster than previously thought. Finally, we discuss the rate of cracking of oil vapor in contact with oxidized shale, qualitatively using a sand fluidized bed and quantitatively using a vapor cracking apparatus. 3 refs., 4 figs., 1 tab.

Cena, R.J.; Coburn, T.T.; Taylor, R.W.

1988-01-01T23:59:59.000Z

228

Shale Oil Production Performance from a Stimulated Reservoir Volume  

E-Print Network [OSTI]

.1 Unconventional resources ................................................................................. 1 1.2 Oil shale and shale oil ....................................................................................... 6 1.3 Production from unconventional..., heavy oil, shale gas and shale oil. On the other hand, conventional reservoirs can be produced at economic flow rates and produce economic volumes of oil and gas without large stimulation treatments or any special recovery process. Conventional...

Chaudhary, Anish Singh

2011-10-21T23:59:59.000Z

229

Study of composite cement containing burned oil shale  

E-Print Network [OSTI]

Study of composite cement containing burned oil shale Julien Ston Supervisors : Prof. Karen properties. SCMs can be by-products from various industries or of natural origin, such as shale. Oil shale correctly, give a material with some cementitious properties known as burned oil shale (BOS). This study

Dalang, Robert C.

230

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development  

E-Print Network [OSTI]

Energy Transitions: A Systems Approach Including Marcellus Shale Gas Development A Report Transitions: A Systems Approach Including Marcellus Shale Gas Development Executive Summary In the 21st the Marcellus shale In addition to the specific questions identified for the case of Marcellus shale gas in New

Angenent, Lars T.

231

Morphological Investigations of Fibrogenic Action of Estonian Oil Shale Dust  

E-Print Network [OSTI]

dust produced in the mining and processing of Estonian oil shale is given. Histological examination of

V. A. Kung

232

Geologic and geochemical studies of the New Albany Shale Group (Devonian-Mississippian) in Illinois. Final report  

SciTech Connect (OSTI)

The Illinois State Geological Survey is conducting geological and geochemical investigations to evaluate the potential of New Albany Group shales as a source of hydrocarbons, particularly natural gas. Geological studies include stratigraphy and structure, mineralogic and petrographic characterization; analyses of physical properties; and development of a computer-based resources evaluation system. Geochemical studies include organic carbon content and trace elements; hydrocarbon content and composition; and adsorption/desorption studies of gas through shales. Separate abstracts have been prepared for each task reported.

Bergstrom, R.E.; Shimp, N.F.

1980-06-30T23:59:59.000Z

233

Differential thermal analysis of the reaction properties of raw and retorted oil shale with air  

SciTech Connect (OSTI)

The results of a study to determine the kinetics of combustion of oil shale and its char by using differential thermal analysis are reported. The study indicates that Colorado oil shale and its char combustion rate is the fastest while Fushun oil shale and its char combustion rate is the slowest among the six oil shales used in this work. Oil shale samples used were Fushun oil shale, Maoming oil shale, Huang county oil shale, and Colorado oil shale.

Wang, T.F.

1984-01-01T23:59:59.000Z

234

Oil shale program plan, FY 1989  

SciTech Connect (OSTI)

The oil shale program is directed to the development of advanced technologies for extracting shale oil from the large domestic resources. The overall goal is to foster development of an economically competitive and environmentally acceptable oil shale industry. A series of technology development steps must be taken by DOE, other government agencies and other governments and/or industry to achieve this goal. They include basic and applied R and D, proof-of-concept activities, first-of-a-kind field tests and associated commercial-scale activity. Activities associated with the oil shale program are designed to: Expand the technically recoverable resource base, increase recovery efficiency, reduce capital and operating costs and/or enhance environmental acceptability. In support of the overall program goal, oil shale research has two major technical goals: (1) Technology Base Development. To produce an engineering and scientific information base for industry use in designing and developing oil shale processes with reduced costs and enhanced environmental acceptability and to foster the development of novel oil shale processes and, (2) Environmental Mitigation. To develop a comprehensive data base on pollutant generation and the steps required to mitigate the impacts in a cost-effective manner. This report discusses the above goals. 9 refs., 1 fig., 1 tab.

Not Available

1989-06-01T23:59:59.000Z

235

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect (OSTI)

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

236

Gasification characteristics of eastern oil shale  

SciTech Connect (OSTI)

The Institute of Gas Technology (IGT) is evaluating the gasification characteristics of Eastern oil shales as a part of a cooperative agreement between the US Department of Energy and HYCRUDE Corporation to expand the data base on moving-bed hydroretorting of Eastern oil shales. Gasification of shale fines will improve the overall resource utilization by producing synthesis gas or hydrogen needed for the hydroretorting of oil shale and the upgrading of shale oil. Gasification characteristics of an Indiana New Albany oil shale have been determined over temperature and pressure ranges of 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Carbon conversion of over 95% was achieved within 30 minutes at gasification conditions of 1800/sup 0/F and 15 psig in a hydrogen/steam gas mixture for the Indiana New Albany oil shale. This paper presents the results of the tests conducted in a laboratory-scale batch reactor to obtain reaction rate data and in a continuous mini-bench-scale unit to obtain product yield data. 2 refs., 7 figs., 4 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1986-11-01T23:59:59.000Z

237

Isothermal kinetics of new Albany oil shale  

SciTech Connect (OSTI)

From the development of technologies for the utilization of eastern U.S. oil shales, fluidized bed pyrolysis technology is emerging as one of the most promising in terms of oil yield, operating cost, and capital investment. Bench-scale testing of eastern shales has reached a level where scale-up represents the next logical step in the evolution of this technology. A major consideration in this development and an essential part of any fluidized bed reactor scale-up effort--isothermal kinetics-- has largely been ignored for eastern US shale with the exception of a recent study conducted by Richardson et al. with a Cleveland shale. The method of Richardson et al. was used previously by Wallman et al. with western shale and has been used most recently by Forgac, also with western shale. This method, adopted for the present study, entails injecting a charge of shale into a fluidized bed and monitoring the hydrocarbon products with a flame ionization detector (FID). Advantages of this procedure are that fluidized bed heat-up effects are simulated exactly and real-time kinetics are obtained due to the on-line FID. Other isothermal methods have suffered from heat-up and cool-down effects making it impossible to observe the kinetics at realistic operating temperatures. A major drawback of the FID approach, however, is that no differentiation between oil and gas is possible.

Carter, S.D.

1987-04-01T23:59:59.000Z

238

In situ retorting or oil shale  

SciTech Connect (OSTI)

An improved method of in situ retorting of oil shale wherein a cavern of crushed shale is created within an oil shale deposit, preferably by igniting a powerful explosion within the oil shale deposit, thereby creating a localized area or cavern of rubblized oil shale. Combustion gases are injected into the bottom of this cavern and particulate material, preferably a cracking catalyst, is deposited into a void at the top of the cavern and allowed to trickle down and fill the voids in the rubblized cavern. The oil shale is ignited at the bottom of the cavern and a combustion zone proceeds upwardly while the particulate material is caused by gas flow to percolate downwardly. A fluidized bed of particulate material is thereby formed at the combustion zone providing a controlled, evelny advancing combustion zone. This, in turn, efficiently retorts oil shale, provides increased recovery of hydrocarbon while ismultaneously producing a catalytically cracked volatile, high octane gasoline exiting from the top of the retort.

Hettinger, W.P. Jr.

1984-09-11T23:59:59.000Z

239

Reservoir and stimulation analysis of a Devonian Shale gas field  

E-Print Network [OSTI]

. The Gas Research Institute (GRI) which sponsored this work under GRI Contract No. 5084-213-0980, "Analysis of Eastern Devonian Gas Shales Production Data;" 2. Doug Terry and Joe Petty with Union Drilling, Inc. who showed great interest in this study... and enhance productivity. ~St h The Devonian Shales in the Mason County Field study area can be subdivided using gamma ray logs as follows (in descending order): Upper Devonian Undivided, Huron Shale Member of the Ohio Shale, Java Formation, Angola Shale...

Shaw, James Stanley

1986-01-01T23:59:59.000Z

240

What is shale gas and why is it important?  

Reports and Publications (EIA)

Shale gas refers to natural gas that is trapped within shale formations. Shales are fine-grained sedimentary rocks that can be rich sources of petroleum and natural gas. Over the past decade, the combination of horizontal drilling and hydraulic fracturing has allowed access to large volumes of shale gas that were previously uneconomical to produce. The production of natural gas from shale formations has rejuvenated the natural gas industry in the United States.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Kerogen extraction from subterranean oil shale resources  

DOE Patents [OSTI]

The present invention is directed to methods for extracting a kerogen-based product from subsurface (oil) shale formations, wherein such methods rely on fracturing and/or rubblizing portions of said formations so as to enhance their fluid permeability, and wherein such methods further rely on chemically modifying the shale-bound kerogen so as to render it mobile. The present invention is also directed at systems for implementing at least some of the foregoing methods. Additionally, the present invention is also directed to methods of fracturing and/or rubblizing subsurface shale formations and to methods of chemically modifying kerogen in situ so as to render it mobile.

Looney, Mark Dean (Houston, TX); Lestz, Robert Steven (Missouri City, TX); Hollis, Kirk (Los Alamos, NM); Taylor, Craig (Los Alamos, NM); Kinkead, Scott (Los Alamos, NM); Wigand, Marcus (Los Alamos, NM)

2010-09-07T23:59:59.000Z

242

General screening criteria for shale gas reservoirs and production data analysis of Barnett shale.  

E-Print Network [OSTI]

??Shale gas reservoirs are gaining importance in United States as conventional oil and gas resources are dwindling at a very fast pace. The purpose of (more)

Deshpande, Vaibhav Prakashrao

2009-01-01T23:59:59.000Z

243

Oil shale mining studies and analyses of some potential unconventional uses for oil shale  

SciTech Connect (OSTI)

Engineering studies and literature review performed under this contract have resulted in improved understanding of oil shale mining costs, spent shale disposal costs, and potential unconventional uses for oil shale. Topics discussed include: costs of conventional mining of oil shale; a mining scenario in which a minimal-scale mine, consistent with a niche market industry, was incorporated into a mine design; a discussion on the benefits of mine opening on an accelerated schedule and quantified through discounted cash flow return on investment (DCFROI) modelling; an estimate of the costs of disposal of spent shale underground and on the surface; tabulation of potential increases in resource recovery in conjunction with underground spent shale disposal; the potential uses of oil shale as a sulfur absorbent in electric power generation; the possible use of spent shale as a soil stabilizer for road bases, quantified and evaluated for potential economic impact upon representative oil shale projects; and the feasibility of co-production of electricity and the effect of project-owned and utility-owned power generation facilities were evaluated. 24 refs., 5 figs., 19 tabs.

McCarthy, H.E.; Clayson, R.L.

1989-07-01T23:59:59.000Z

244

Investigation of the effects of heating rate on coking of shale during retorting  

SciTech Connect (OSTI)

The retorting of oil shale distributes organic carbon among three possible products: the liquid product, the noncondensible product, and the residual carbon (coke). The production of coke is detrimental because of the economic effects caused by the loss of organic carbon to this relatively intractable carbon form. Two reference oil shales, a Mahogany zone, Parachute Creek Member, Green River Formation oil shale from Colorado and a Clegg Creek Member, New Albany oil shale from Kentucky, were studied to evaluate the conditions that affect coke production during retorting. The variable that was studied in these experiments was the heating rate during retorting because heating rate has been indicated to have a direct effect on coke production (Burnham and Clarkson 1980). The six heating rates investigated covered the range from 1 to 650/degree/C/h (1.8 to 1169/degree/F/h). The data collected during these experiments were evaluated statistically in order to identify trends. The data for the eastern reference oil shale indicated a decrease in coke formation with increases in the heating rate. The liquid and noncondensible product yields both increased with increasing heating rate. The distribution of products in relation to retort heating rate follows the model suggested by Burnham and Clarkson (1980). Coke production during the retorting of western reference oil shale was found to be constant in relation to heating rate. The liquid product yield increased with increasing heating rate but the trend could not be verified at the 95% confidence level. The coke production observed in these experiments does not follow the prediction of the model. This may indicate that coke formation occurs early in the retorting process and may be limited by the availability of organic materials that form coke. 6 refs., 10 tabs.

Guffey, F.D.; Hunter, D.E.

1988-02-01T23:59:59.000Z

245

Method for retorting oil shale  

DOE Patents [OSTI]

The recovery of oil from oil shale is provided in a fluidized bed by using a fluidizing medium of a binary mixture of carbon dioxide and 5 steam. The mixture with a steam concentration in the range of about 20 to 75 volume percent steam provides an increase in oil yield over that achievable by using a fluidizing gas of carbon dioxide or steam alone when the mixture contains higher steam concentrations. The operating parameters for the fluidized bed retorted are essentially the same as those utilized with other gaseous fluidizing mediums with the significant gain being in the oil yield recovered which is attributable solely to the use of the binary mixture of carbon dioxide and steam. 2 figs.

Shang, Jer-Yu; Lui, A.P.

1985-08-16T23:59:59.000Z

246

JORDANS EXPERIENCE IN OIL SHALE STUDIES EMPLOYING DIFFERENT TECHNOLOGIES  

E-Print Network [OSTI]

Jordans long experience in dealing with oil shale as a source of energy is in-troduced and discussed. Since the 1960s, Jordan has been investigating eco-nomical and environmental methods for utilizing this indigenous natural re-source, which, due to its high organic content, is considered a

M. S. Bsieso

247

Fast Track Reservoir Modeling of Shale Formations in the Appalachian Basin.  

E-Print Network [OSTI]

· Highly organically rich, dark, fine laminated, naturally fractured shale; · Porosity (core measurements ) is from 1 to 5%; · Permeability (core measurements) is in the range of 10-7 to 10-9 md; · Natural fracture was performed in support of the NETL- RUA Authors would like to acknowledge: · NETL/DOE for financially

Mohaghegh, Shahab

248

Multiscale strength homogenization : application to shale nanoindentation  

E-Print Network [OSTI]

Shales are one of the most encountered materials in sedimentary basins. Because of their highly heterogeneous nature, their strength prediction for oil and gas exploitation engineering has long time been an enigma. In this ...

Gathier, Benjamin

2008-01-01T23:59:59.000Z

249

Chemical factors affecting insolubles formation in shale-derived diesel fuel  

SciTech Connect (OSTI)

In an effort to define the stability of shale-derived diesel fuel, the authors have conducted gravimetric accelerated storage stability tests at 43 and 80/sup 0/C using three model nitrogen compounds, 2-methylpyridine, 2,6-dimethylquinoline and dodecahydrocarbazole, as dopants in an otherwise stable shale diesel fuel. Also, information about potential interactive effects has been defined for these three model nitrogen compounds in the stable fuel in the presence of a second model dopant (a hydroperocide, organic acid or base).

Beal, E.J.; Cooney, J.V.; Hazlett, R.N.

1987-04-01T23:59:59.000Z

250

HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE  

SciTech Connect (OSTI)

Low cost material is needed for grouting abandoned retorts. Experimental work has shown that a hydraulic cement can be produced from Lurgi spent shale by mixing it in a 1:1 weight ratio with limestone and heating one hour at 1000C. With 5% added gypsum, strengths up to 25.8 MPa are obtained. This cement could make an economical addition up to about 10% to spent shale grout mixes, or be used in ordinary cement applications.

Mehta, P.K.; Persoff, P.; Fox, J.P.

1980-06-01T23:59:59.000Z

251

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of US Navy jet fuel (JP-5) has been related to the amounts of large n-alkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how the n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30, and 32 ppM in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-01-01T23:59:59.000Z

252

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of U.S. Navy jet fuel (JP-5) has been related to the amounts of large nalkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how th n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30 and 32 ppm in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-02-01T23:59:59.000Z

253

Rock-eval data relating to oil-source potential of shales of New Albany group (Devonian-Mississippian) in Illinois basin  

SciTech Connect (OSTI)

Only limited data on petroleum source rock potential of New Albany Group (Devonian-Mississippian) shales have been reported, with the exception of vitrinite reflectance and some petrographic analyses. The New Albany Group contains the thickest and most widespread continuous black shale beds in the Illinois basin. The New Albany extends from northwestern Illinois to southwestern Indiana and western Kentucky and is thought to have played a major role in petroleum generation throughout the basin. In this study, Rock-Eval pyrolysis was used to measure the petroleum-generative potential and production index of the shale. Seven geochemical logs, based on 143 core samples from across the basin, and a production index map, based on a total of 252 samples (cuttings and cores) in Illinois, were generated. Systematic variations of petroleum-generative potential of the shale were observed. The variations are related to the differences in shale lithofacies, depth, and geographic location. The upper portion of the New Albany - the Hannibal and Saverton Shales - has the lowest oil-generative potential. The Grassy Creek, Sweetland Creek, and other stratigraphically lower shales of the New Albany Group generally have good oil-generative potential. However, samples from the Hicks dome area of extreme southern Illinois are overmature and have no oil-generative potential. Source rocks that have both good oil-generative potential (> 6 kg hydrocarbons per ton of rock) and a higher production index (> 0.09) are generally located at depths of 2,500-5,300 ft.

Chou, Mei-In M.; Dickerson, D.R.; Sargent, M.L. (Illinois State Geological Survey, Champaign (USA))

1988-08-01T23:59:59.000Z

254

Pressurized fluidized-bed hydroretorting of Indiana New Albany shale in batch and continuous units  

SciTech Connect (OSTI)

Work is being conducted at the Institute of Gas Technology (IGT) to develop a pressurized fluidized-bed hydroretorting (PFH) process for the production of oil from Eastern oil shales. The PFH process, using smaller particle sizes than the moving-bed hydroretorting process, offers higher oil yields and greater reactor mass fluxes through higher selectivity of organic carbon to oil and shorter residence times, respectively. Batch PFH tests have been conducted to study the effects of shale preheat time (15 to 30 min) and temperature (25{degree} to 320{degree}C), retorting temperature (450{degree} to 710{degree}C), hydrogen pressure (2.8 to 7.0 MPa), particle size (65 to 330 microns), and residence time (5 to 30 min) on the product yields from Indiana New Albany shale. Oil yield has been found to increase with increasing hydrogen pressure. Results are discussed. 10 refs., 14 figs., 3 tabs.

Roberts, M.J.; Rue, D.M.; Lau, F.S. (Institute of Gas Technology, Chicago, IL (USA)); Roosmagi, C. (USDOE Laramie Energy Technology Center, WY (USA))

1989-01-01T23:59:59.000Z

255

Calorimetric determination of the heat of combustion of spent Green River shale at 978 K  

SciTech Connect (OSTI)

A Calvet-type calorimeter was used to measure heats of combustion of spent Colorado oil shales. For Green River shale, the samples were members of a sink-float series spanning oil yields from 87 to 340 L . tonne/sup -1/. Shale samples (30-200 mg) are dropped into the calorimeter at high temperature, and a peak in the thermopile signal records the total enthalpy change of the sample between room temperature and the final temperature. Duplicate samples from the above sink-float series were first retorted at 773 K and then dropped separately into nitrogen and oxygen at 978 K. The resulting heats are subtracted to give the heat of combustion, and the results are compared to values from classical bomb calorimetry. The agreement shows that the heats of combustion of the organic component are well understood but that question remain on the reactions of the mineral components.

Mraw, S.C.; Keweshan, C.F.

1987-08-01T23:59:59.000Z

256

A naphthenic jet fuel produced from an Australian marine oil shale  

SciTech Connect (OSTI)

CSR Limited holds title to an Authority to Prospect covering the Cretaceous Julia Creek oil shale deposit, located in Queensland, Australia, approximately 600 km inland from the eastern seaboard. The shale is of marine origin, having been deposited as an anaerobic sediment in a restricted epicontinental sea. Algae are the predominant source of organic matter. Resources are estimated at 20 billion barrels of oil, approximately half in shale deposits suitable for open cut mining. Typical oil shale analyses are given. Average oil yields are 70 liters per ton. The oil has several deleterious characteristics which necessitate its upgrading at higher severity than is conventional at existing refineries. Heteroatom levels are in total significantly higher than values for petroleum crudes and the aromaticity and metal content of the oil add to its complexity and unusual nature. Two processing routes have been proposed for this oil - either the production of a syncrude by hydrostabilization of the whole oil, or alternatively, upgrading separate fractions to marketable fuels. Pilot plant studies were carried out to simulate refinery processes options. During these investigations, they were successful in the first Australian production of shale-derived jet and diesel synfuels which met all specifications. In this paper, they present details of the jet fuel production and describe its unusual naphthenic character.

Stephenson, L.C.; Muradian, A. (CSR Ltd., Sydney (Australia)); Fookes, C.J.R.; Atkins, A.R. (CSIRO Div. of Energy Chemistry, Sutherland (Australia)); Batts, B.D. (Macquarie Univ., North Ryde (Australia))

1987-04-01T23:59:59.000Z

257

Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques  

SciTech Connect (OSTI)

Two Pennsylvanian coal samples (Spr326 and Spr879-IN1) and two Upper Devonian-Mississippian shale samples (MM1 and MM3) from the Illinois Basin were studied with regard to their porosity and pore accessibility. Shale samples are early mature stage as indicated by vitrinite reflectance (R{sub o}) values of 0.55% for MM1 and 0.62% for MM3. The coal samples studied are of comparable maturity to the shale samples, having vitrinite reflectance of 0.52% (Spr326) and 0.62% (Spr879-IN1). Gas (N{sub 2} and CO{sub 2}) adsorption and small-angle and ultrasmall-angle neutron scattering techniques (SANS/USANS) were used to understand differences in the porosity characteristics of the samples. The results demonstrate that there is a major difference in mesopore (2-50 nm) size distribution between the coal and shale samples, while there was a close similarity in micropore (<2 nm) size distribution. Micropore and mesopore volumes correlate with organic matter content in the samples. Accessibility of pores in coal is pore-size specific and can vary significantly between coal samples; also, higher accessibility corresponds to higher adsorption capacity. Accessibility of pores in shale samples is low.

Mastalerz, Maria [Indiana Geological Survey; He, Lilin [ORNL; Melnichenko, Yuri B [ORNL; Rupp, John A [ORNL

2012-01-01T23:59:59.000Z

258

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

Minor Elements in Oil Shale and Oil-Shale Products. LERC RIChemistry of Tar Sands and Oil Shale, ACS, New Orleans.Constituent Analysis of Oil Shale and Solvent-Refined Coal

Girvin, D.G.

2011-01-01T23:59:59.000Z

259

INTERCOMPARISON STUDY OF ELEMENTAL ABUNDANCES IN RAW AND SPENT OIL SHALES  

E-Print Network [OSTI]

Minor Elements ~n Oil Shale and Oil-Shale Products. LERC RI-Analytical Chemistry of Oil Shale and Tar Sands. Advan. inH. Meglen. The Analysis of Oil-Shale Materials for Element

Fox, J.P.

2011-01-01T23:59:59.000Z

260

Method for maximizing shale oil recovery from an underground formation  

DOE Patents [OSTI]

A method for maximizing shale oil recovery from an underground oil shale formation which has previously been processed by in situ retorting such that there is provided in the formation a column of substantially intact oil shale intervening between adjacent spent retorts, which method includes the steps of back filling the spent retorts with an aqueous slurry of spent shale. The slurry is permitted to harden into a cement-like substance which stabilizes the spent retorts. Shale oil is then recovered from the intervening column of intact oil shale by retorting the column in situ, the stabilized spent retorts providing support for the newly developed retorts.

Sisemore, Clyde J. (Livermore, CA)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Retorting of oil shale followed by solvent extraction of spent shale: Experiment and kinetic analysis  

SciTech Connect (OSTI)

Samples of El-Lajjun oil shale were thermally decomposed in a laboratory retort system under a slow heating rate (0.07 K/s) up to a maximum temperature of 698--773 K. After decomposition, 0.02 kg of spent shale was extracted by chloroform in a Soxhlet extraction unit for 2 h to investigate the ultimate amount of shale oil that could be produced. The retorting results indicate an increase in the oil yields from 3.24% to 9.77% of oil shale feed with retorting temperature, while the extraction results show a decrease in oil yields from 8.10% to 3.32% of spent shale. The analysis of the data according to the global first-order model for isothermal and nonisothermal conditions shows kinetic parameters close to those reported in literature.

Khraisha, Y.H.

2000-05-01T23:59:59.000Z

262

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

or by refin- ing and using shale Oil Mass balances and oil.shale retorting produces shale oil, mobility factors wereand retort operating shale, shale oil, retorting (LETC) con-

Fox, J. P.

2011-01-01T23:59:59.000Z

263

Assessment of Factors Influencing Effective CO{sub 2} Storage Capacity and Injectivity in Eastern Gas Shales  

SciTech Connect (OSTI)

Building upon advances in technology, production of natural gas from organic-rich shales is rapidly developing as a major hydrocarbon supply option in North America and around the world. The same technology advances that have facilitated this revolution - dense well spacing, horizontal drilling, and hydraulic fracturing - may help to facilitate enhanced gas recovery (EGR) and carbon dioxide (CO{sub 2}) storage in these formations. The potential storage of CO {sub 2} in shales is attracting increasing interest, especially in Appalachian Basin states that have extensive shale deposits, but limited CO{sub 2} storage capacity in conventional reservoirs. The goal of this cooperative research project was to build upon previous and on-going work to assess key factors that could influence effective EGR, CO{sub 2} storage capacity, and injectivity in selected Eastern gas shales, including the Devonian Marcellus Shale, the Devonian Ohio Shale, the Ordovician Utica and Point Pleasant shale and equivalent formations, and the late Devonian-age Antrim Shale. The project had the following objectives: (1) Analyze and synthesize geologic information and reservoir data through collaboration with selected State geological surveys, universities, and oil and gas operators; (2) improve reservoir models to perform reservoir simulations to better understand the shale characteristics that impact EGR, storage capacity and CO{sub 2} injectivity in the targeted shales; (3) Analyze results of a targeted, highly monitored, small-scale CO{sub 2} injection test and incorporate into ongoing characterization and simulation work; (4) Test and model a smart particle early warning concept that can potentially be used to inject water with uniquely labeled particles before the start of CO{sub 2} injection; (5) Identify and evaluate potential constraints to economic CO{sub 2} storage in gas shales, and propose development approaches that overcome these constraints; and (6) Complete new basin-level characterizations for the CO{sub 2} storage capacity and injectivity potential of the targeted eastern shales. In total, these Eastern gas shales cover an area of over 116 million acres, may contain an estimated 6,000 trillion cubic feet (Tcf) of gas in place, and have a maximum theoretical storage capacity of over 600 million metric tons. Not all of this gas in-place will be recoverable, and economics will further limit how much will be economic to produce using EGR techniques with CO{sub 2} injection. Reservoir models were developed and simulations were conducted to characterize the potential for both CO{sub 2} storage and EGR for the target gas shale formations. Based on that, engineering costing and cash flow analyses were used to estimate economic potential based on future natural gas prices and possible financial incentives. The objective was to assume that EGR and CO{sub 2} storage activities would commence consistent with the historical development practices. Alternative CO{sub 2} injection/EGR scenarios were considered and compared to well production without CO{sub 2} injection. These simulations were conducted for specific, defined model areas in each shale gas play. The resulting outputs were estimated recovery per typical well (per 80 acres), and the estimated CO{sub 2} that would be injected and remain in the reservoir (i.e., not produced), and thus ultimately assumed to be stored. The application of this approach aggregated to the entire area of the four shale gas plays concluded that they contain nearly 1,300 Tcf of both primary production and EGR potential, of which an estimated 460 Tcf could be economic to produce with reasonable gas prices and/or modest incentives. This could facilitate the storage of nearly 50 Gt of CO{sub 2} in the Marcellus, Utica, Antrim, and Devonian Ohio shales.

Godec, Michael

2013-06-30T23:59:59.000Z

264

System for utilizing oil shale fines  

DOE Patents [OSTI]

A system is provided for utilizing fines of carbonaceous materials such as particles or pieces of oil shale of about one-half inch or less diameter which are rejected for use in some conventional or prior surface retorting process, which obtains maximum utilization of the energy content of the fines and which produces a waste which is relatively inert and of a size to facilitate disposal. The system includes a cyclone retort (20) which pyrolyzes the fines in the presence of heated gaseous combustion products, the cyclone retort having a first outlet (30) through which vapors can exit that can be cooled to provide oil, and having a second outlet (32) through which spent shale fines are removed. A burner (36) connected to the spent shale outlet of the cyclone retort, burns the spent shale with air, to provide hot combustion products (24) that are carried back to the cyclone retort to supply gaseous combustion products utilized therein. The burner heats the spent shale to a temperature which forms a molten slag, and the molten slag is removed from the burner into a quencher (48) that suddenly cools the molten slag to form granules that are relatively inert and of a size that is convenient to handle for disposal in the ground or in industrial processes.

Harak, Arnold E. (Laramie, WY)

1982-01-01T23:59:59.000Z

265

Shale Gas Production: Potential versus Actual GHG Emissions  

E-Print Network [OSTI]

Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

O'Sullivan, Francis

266

Shale gas production: potential versus actual greenhouse gas emissions  

E-Print Network [OSTI]

Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

OSullivan, Francis Martin

267

Secretary of Energy Advisory Board Subcommittee (SEAB) on Shale...  

Energy Savers [EERE]

(SEAB) on Shale Gas Production Posts Draft Report Secretary of Energy Advisory Board Subcommittee (SEAB) on Shale Gas Production Posts Draft Report November 10, 2011 - 1:12pm...

268

Material invariant properties of shales : nanoindentation and microporoelastic analysis  

E-Print Network [OSTI]

Shales compose the major part of sedimentary rocks and cover most of hydrocarbon bearing reservoirs. Shale materials are probably one of the most complex natural composites, and their mechanical properties are still an ...

Delafargue, A. (Antoine), 1981-

2005-01-01T23:59:59.000Z

269

Burngrange Nos.1 and 2 (oil Shale) Mine, Midlothian  

E-Print Network [OSTI]

BURNGRANGE Nos. I AND 2 (Oil Shale) MINE, MIDLOTHIAN REPORT On the Causes of, and Circumstances attending, the Explosion and Fire which occurred on the 10th January, 1947, at the Burngrange Nos. I and 2 (Oil Shale) ...

Bryan, A. M.

1947-01-01T23:59:59.000Z

270

Can We Accurately Model Fluid Flow in Shale?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2013 00:00 Over 20 trillion cubic meters of natural gas are trapped in shale, but many shale oil and gas producers still use models of underground fluid flow that date back to...

271

Process Design and Integration of Shale Gas to Methanol  

E-Print Network [OSTI]

Recent breakthroughs in horizontal drilling and hydraulic fracturing technology have made huge reservoirs of previously untapped shale gas and shale oil formations available for use. These new resources have already made a significant impact...

Ehlinger, Victoria M.

2013-02-04T23:59:59.000Z

272

Austin E. Quigley Black Box Theater Proposal Form  

E-Print Network [OSTI]

-1- Austin E. Quigley Black Box Theater Proposal Form Sponsoring Organization indicate that you have read the Austin E. Quigley Black Box Theatre Policy and Procedure Guidelines

Hone, James

273

Thermodynamics and kinetics of hydrophobic organic compound sorption in natural sorbents and quantification of black carbon by electron microscopy  

E-Print Network [OSTI]

The sorption behaviors of hydrophobic organic compounds (HOCs) in sediments were investigated using pyrene. Native pyrene desorbed slowly, taking from weeks to months to equilibrate. The end-point data suggested that, at ...

Kuo, Dave Ta Fu, 1978-

2010-01-01T23:59:59.000Z

274

COLLOQUIUM: "The Environmental Footprint of Shale Gas Extraction...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MBG Auditorium COLLOQUIUM: "The Environmental Footprint of Shale Gas Extraction and Hydraulic Fracturing" Professor Robert Jackson Duke University Presentation:...

275

Economics and Politics of Shale Gas in Europe  

E-Print Network [OSTI]

, Asia Pacific JKM) Source: Henry Hub and NBP Bloomberg; JKM - Platts Overall, the US shale gas revolution produced improvements along several key dimensions: 1. Climate change mitigation U.S. CO2 emissions fell by 5.3% between 2010- 2012... entry). 18 References AMION Consulting (2014). Potential Economic Impacts of Shale Gas in the Ocean Gateway. Available at: http://www.igasplc.com/media/10851/ocean- gateway-shale-gas-impact-study.pdf Barteau, M. and S. Kota (2014). Shale...

Chyong, Chi Kong; Reiner, David M.

2015-01-01T23:59:59.000Z

276

Shale Oil and Gas, Frac Sand, and Watershed  

E-Print Network [OSTI]

;Bakken Oil Shale scope · Light, Sweet crude ­ ideal for automotive fuels and mid-size refineries (Midwest

Minnesota, University of

277

1 Pore Scale Analysis of Oil Shale/Sands Pyrolysis  

E-Print Network [OSTI]

quality and volume of pore space that is created when oil shale is pyrolyzed for the purpose of producing

unknown authors

2009-01-01T23:59:59.000Z

278

ON OIL SHALE MINING IN THE ESTONIA DEPOSIT  

E-Print Network [OSTI]

age) cut the Estonian oil shale-kukersite deposits. Two younger groups of structures are typical fault

K. Sokman; V. Kattai; R. Vaher; Y. J. Systra

279

Occurrence of Multiple Fluid Phases Across a Basin, in the Same Shale Gas Formation Eagle Ford Shale Example  

E-Print Network [OSTI]

Shale gas and oil are playing a significant role in US energy independence by reversing declining production trends. Successful exploration and development of the Eagle Ford Shale Play requires reservoir characterization, recognition of fluid...

Tian, Yao

2014-04-29T23:59:59.000Z

280

Oil shale retorting and combustion system  

DOE Patents [OSTI]

The present invention is directed to the extraction of energy values from l shale containing considerable concentrations of calcium carbonate in an efficient manner. The volatiles are separated from the oil shale in a retorting zone of a fluidized bed where the temperature and the concentration of oxygen are maintained at sufficiently low levels so that the volatiles are extracted from the oil shale with minimal combustion of the volatiles and with minimal calcination of the calcium carbonate. These gaseous volatiles and the calcium carbonate flow from the retorting zone into a freeboard combustion zone where the volatiles are burned in the presence of excess air. In this zone the calcination of the calcium carbonate occurs but at the expense of less BTU's than would be required by the calcination reaction in the event both the retorting and combustion steps took place simultaneously. The heat values in the products of combustion are satisfactorily recovered in a suitable heat exchange system.

Pitrolo, Augustine A. (Fairmont, WV); Mei, Joseph S. (Morgantown, WV); Shang, Jerry Y. (Fairfax, VA)

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Red Leaf Resources and the Commercialization of Oil Shale  

E-Print Network [OSTI]

Red Leaf Resources and the Commercialization of Oil Shale #12;About Red Leaf Resources 2006 Company commercial development field activities #12;Highlights Proven, Revolutionary Oil Shale Extraction Process Technology Significant Owned Oil Shale Resource #12;· The executive management team of Red Leaf Resources

Utah, University of

282

Shale Gas and the Environment: Critical Need for a  

E-Print Network [OSTI]

Shale Gas and the Environment: Critical Need for a Government­University­Industry Research Initiative P o l i c y m a k e r G u i d e #12;Shale gas production is increasing at a rapid rate initiative is needed to fill critical gaps in knowledge at the interface of shale gas development

McGaughey, Alan

283

Shale Gas and the Environment: Critical Need for a  

E-Print Network [OSTI]

Shale Gas and the Environment: Critical Need for a Government­University­Industry Research Initiative P O L I C Y M A K E R G U I D E #12;Shale gas production is increasing at a rapid rate initiative is needed to fill critical gaps in knowledge at the interface of shale gas development

McGaughey, Alan

284

SPE-163690-MS Synthetic, Geomechanical Logs for Marcellus Shale  

E-Print Network [OSTI]

SPE-163690-MS Synthetic, Geomechanical Logs for Marcellus Shale M. O. Eshkalak, SPE, S. D of hydrocarbons from the reservoirs, notably shale, is attributed to realizing the key fundamentals of reservoir and mineralogy is crucial in order to identify the "right" pay-zone intervals for shale gas production. Also

Mohaghegh, Shahab

285

2006 Minerals Yearbook ClaY and Shale  

E-Print Network [OSTI]

2006 Minerals Yearbook ClaY and Shale U.S. Department of the Interior U.S. Geological Survey January 2008 #12;Clay and Shale--2006 18.1 The amount of clay sold or used by domestic producers in 2006 in 2005 (table 1). Common clay and shale accounted for 59% of the tonnage, and kaolin accounted for 55

286

Evolution of Marine Invertebrates and the Burgess Shale Fossils  

E-Print Network [OSTI]

Evolution of Marine Invertebrates and the Burgess Shale Fossils Geology 331, Paleontology #12 #12;Burgess Shale Fossils · Most are soft-bodied fossils, a very rare kind of fossilization. · Of today's 32 living phyla, 15 are found in the Burgess Shale. The other 17 are microscopic or too delicate

Kammer, Thomas

287

Paleoecology of the Greater Phyllopod Bed community, Burgess Shale  

E-Print Network [OSTI]

Paleoecology of the Greater Phyllopod Bed community, Burgess Shale Jean-Bernard Caron , Donald A and composition, ecological attributes, and environmental influences for the Middle Cambrian Burgess Shale ecosystems further suggest the Burgess Shale community was probably highly dependent on immigration from

Jackson, Don

288

Development of the Natural Gas Resources in the Marcellus Shale  

E-Print Network [OSTI]

Development of the Natural Gas Resources in the Marcellus Shale New York, Pennsylvania, Virginia for informational purposes only and does not support or oppose development of the Marcellus Shale natural gas information regarding shale gas well development, ancillary facilities asso- ciated with that development

Boyer, Elizabeth W.

289

Risks and Risk Governance in Unconventional Shale Gas Development  

E-Print Network [OSTI]

Risks and Risk Governance in Unconventional Shale Gas Development Mitchell J. Small,*, Paul C, Desert Research Institute, Reno, Nevada 89512, United States 1. INTRODUCTION The recent U.S. shale gas Issue: Understanding the Risks of Unconventional Shale Gas Development Published: July 1, 2014 A broad

Jackson, Robert B.

290

Creation and Impairment of Hydraulic Fracture Conductivity in Shale Formations  

E-Print Network [OSTI]

Multi-stage hydraulic fracturing is the key to the success of many shale gas and shale oil reservoirs. The main objectives of hydraulic fracturing in shale are to create artificial fracture networks that are conductive for oil and gas flow...

Zhang, Junjing

2014-07-10T23:59:59.000Z

291

THE SHALE OIL BOOM: A U.S. PHENOMENON  

E-Print Network [OSTI]

June 2013 THE SHALE OIL BOOM: A U.S. PHENOMENON LEONARDO MAUGERI The Geopolitics of Energy Project material clearly cite the full source: Leonardo Maugeri. "The Shale Oil Boom: A U.S. Phenomenon" Discussion and International Affairs. #12;June 2013 THE SHALE OIL BOOM: A U.S. PHENOMENON LEONARDO MAUGERI The Geopolitics

292

The Public Health Implications of Marcellus Shale Activities  

E-Print Network [OSTI]

INCIDENT #12;#12;#12;Implications of the Gulf Oil Spill to Marcellus Shale Activities - EnvironmentalThe Public Health Implications of Marcellus Shale Activities Bernard D. Goldstein, MD Department using Data.FracTracker.org. #12;Drilling Rig in Rural Upshur County, WV Source: WVSORO, Modern Shale Gas

Jiang, Huiqiang

293

Shale Gas Glossary | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof the Americas |DOE Former Worker/EnergyFracture Fluids Shale GasShale

294

FINGERPRINTING INORGANIC ARSENIC AND ORGANOARSENIC COMPOUNDS IN IN SITU OIL SHALE RETORT AND PROCESS VOTERS USING A LIQUID CHROMATOGRAPH COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR  

E-Print Network [OSTI]

viable is the recovery of shale oil from our substantialdeposits of oil shale (1). Shale oil is recovered from oilproduce~ along with the shale oil, considerable amounts of

Fish, Richard H.

2013-01-01T23:59:59.000Z

295

Fast Track Reservoir Modeling of Shale Formations in the Appalachian Basin. Application to Lower Huron Shale in Eastern Kentucky.  

E-Print Network [OSTI]

SPE 139101 Fast Track Reservoir Modeling of Shale Formations in the Appalachian Basin. Application to Lower Huron Shale in Eastern Kentucky. O. Grujic, S. D. Mohaghegh, SPE, West Virginia University, G Shale in Eastern Kentucky is presented. Unlike conventional reservoir simulation and modeling which

Mohaghegh, Shahab

296

Shale Gas Production Theory and Case Analysis We researched the process of oil recovery and shale gas  

E-Print Network [OSTI]

Shale Gas Production Theory and Case Analysis (Siemens) We researched the process of oil recovery and shale gas recovery and compare the difference between conventional and unconventional gas reservoir and recovery technologies. Then we did theoretical analysis on the shale gas production. According

Ge, Zigang

297

SPENT SHALE AS A CONTROL TECHNOLOGY FOR OIL SHALE RETORT WATER. ANNUAL REPORT FOR PERIOD OCTOBER 1, 1978 - SEPTEMBER 30, 1979.  

E-Print Network [OSTI]

of Control Technology for Shale Oil Wastewaters,~~ inpyrolysized to produce shale oil, gas, a solid referred towaters are co-produced with shale oil and separated from it

Fox, J.P.

2013-01-01T23:59:59.000Z

298

SPENT SHALE AS A CONTROL TECHNOLOGY FOR OIL SHALE RETORT WATER. ANNUAL REPORT FOR PERIOD OCTOBER 1, 1978 - SEPTEMBER 30, 1979.  

E-Print Network [OSTI]

Properties of Spent Shales. Surface Area Measurements.Carbon. Effects. ~~ co 2,and Oil~Shale Partial-pressure andWater from Green River Oil Shale, 11 Chem. Ind. 1, 485 (

Fox, J.P.

2013-01-01T23:59:59.000Z

299

SPENT SHALE AS A CONTROL TECHNOLOGY FOR OIL SHALE RETORT WATER. ANNUAL REPORT FOR PERIOD OCTOBER 1, 1978 - SEPTEMBER 30, 1979.  

E-Print Network [OSTI]

of its contact with the oil and shale, this water can beWater from Green River Oil Shale, 11 Chem. Ind. 1, 485 (Effluents from In-Situ Oil Shale Processing," in Proceedings

Fox, J.P.

2013-01-01T23:59:59.000Z

300

SPENT SHALE AS A CONTROL TECHNOLOGY FOR OIL SHALE RETORT WATER. ANNUAL REPORT FOR PERIOD OCTOBER 1, 1978 - SEPTEMBER 30, 1979.  

E-Print Network [OSTI]

Water from Green River Oil Shale, 11 Chem. Ind. 1, 485 (Effluents from In-Situ Oil Shale Processing," in ProceedingsControl Technology for Oil Shale Retort Water," August 1978.

Fox, J.P.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Organization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat CornellInternships,(SC) Laboratories »OrganicOrganization

302

Studies of New Albany shale in western Kentucky. Final report  

SciTech Connect (OSTI)

The New Albany (Upper Devonian) Shale in western Kentucky can be zoned by using correlative characteristics distinguishable on wire-line logs. Wells drilled through the shale which were logged by various methods provided a basis for zonation of the subsurface members and units of the Grassy Creek, Sweetland Creek, and Blocher. Structure and isopach maps and cross sections were prepared. The Hannibal Shale and Rockford Limestone were found in limited areas; isopach maps were not made for these members. Samples of cuttings from selected wells were studied in order to identify the contact of the shale with underlying and overlying rock units. A well-site examination of cuttings through the shale section was conducted, and the presence of natural gas was observed in the field. The New Albany Shale has the potential for additional commercially marketable natural gas production. Exploratory drilling is needed to evaluate the reservoir characteristics of the New Albany Shale.

Schwalb, H.R.; Norris, R.L.

1980-02-01T23:59:59.000Z

303

Heat of combustion of retorted and burnt Colorado oil shale  

SciTech Connect (OSTI)

Heats of combustion were measured for 12 samples of retorted and 21 samples of burnt Colorado oil shale originating from raw shales with grades that ranged from 13 to 255 cm/sup 3/ of shale oil/kg of oil shale. For the retorted shales, the authors resolve the heat of combustion into exothermic contributions from combustion of carbon residue and iron sulfides and endothermic contributions from carbonate decomposition and glass formation. Eight samples reported in the literature were included in this analysis. Variations in the first three constituents account for over 99% of the variation in the heats of combustion. For the burnt shales, account must also be taken of the partial conversion of iron sulfides to sulfates. Equations are developed for calculating the heat of combustion of retorted and burnt oil shale with a standard error of about 60 J/g. 13 refs.

Burnham, A.K.; Crawford, P.C.; Carley, J.F.

1982-07-01T23:59:59.000Z

304

Heat of combustion of retorted and burnt Colorado oil shale  

SciTech Connect (OSTI)

Heats of combustion were measured for 12 samples of retorted and 21 samples of burnt Colorado oil shale originating from raw shales with grades that ranged from 13 to 255 cm/sup 3/ of shale oil/kg of oil shale. For the retorted shales, the heat of combustion was resolved into exothermic contributions from combustion of carbon residue and iron sulfides and endothermic contributions from carbonate decomposition and glass formation. Eight samples reported in the literature were included in this analysis. Variations in the first three constituents account for over 99% of the variation in the heats of combustion. For the burnt shales, account must also be taken of the partial conversion of iron sulfides to sulfates. Equations are developed for calculating the heat of combustion of retorted and burnt oil shale with a standard error of about 60 J/g.

Burnham, A.K.; Carley, J.F.; Crawford, P.C.

1982-07-01T23:59:59.000Z

305

Soil stabilization using oil-shale solid waste  

SciTech Connect (OSTI)

Oil-shale solid wastes are evaluated for use as soil stabilizers. A laboratory study consisted of the following tests on compacted samples of soil treated with water and spent oil shale: unconfined compressive strength, moisture-density relationships, wet-dry and freeze-thaw durability, and resilient modulus. Significant increases in strength, durability, and resilient modulus were obtained by treating a silty sand with combusted western oil shale. Moderate increases in durability and resilient modulus were obtained by treating a highly plastic clay with combusted western oil shale. Solid waste from eastern oil shale appears to be feasible for soil stabilization only if limestone is added during combustion. Testing methods, results, and recommendations for mix design of spent shale-stabilized pavement subgrades are presented and the mechanisms of spent-shale cementation are discussed.

Turner, J.P. (Univ. of Wyoming, Laramie, WY (United States). Dept. of Civil and Archeological Engineering)

1994-04-01T23:59:59.000Z

306

FLUIDIZED BED COMBUSTION UNIT FOR OIL SHALE  

E-Print Network [OSTI]

A fluidized bed combustion unit has been designed and installed to study the fluidized bed combustion performance using oil shale as fuel in direct burning process. It is a steel column of 18 cm inside diameter and 130 cm height fitted with a perforated plate air distributor of 611 holes, each of 1

M. Hammad; Y. Zurigat; S. Khzai; Z. Hammad; O. Mubydeem

307

Water mist injection in oil shale retorting  

DOE Patents [OSTI]

Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

1980-07-30T23:59:59.000Z

308

Boomtown blues; Oil shale and Exxon's exit  

SciTech Connect (OSTI)

This paper chronicles the social and cultural effects of the recent oil shale boom on the Colorado communities of Rifle, Silt, Parachute, and Grand Junction. The paper is based upon research and oral history interviews conducted throughout Colorado and in Houston and Washington, DC.

Gulliford, A. (Western New Mexico Univ., Silver City, NM (USA))

1989-01-01T23:59:59.000Z

309

Quantifying the Effect of Kerogen on Electrical Resistivity Measurements on Organic-rich Source Rocks  

E-Print Network [OSTI]

conductivity measurements (Rajeshwar et al., 1980) carried out on oil shale samples from the Green River oil shales illustrate the correlation between electrical behavior of organic matter and temperature. Researchers (Meng et al., 2012; Rajeshwar et al...., 1980) observed a pronounced effect of thermal maturity of organic matter and temperature on magnitude of measured electrical conductivity of the oil shale samples. The changes in kerogen network and structure, with increasing temperature and maturity...

Kethireddy, Nikhil Reddy

2013-12-04T23:59:59.000Z

310

Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research  

SciTech Connect (OSTI)

Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

Not Available

1992-01-01T23:59:59.000Z

311

Eastern oil shale research involving the generation of retorted and combusted oil shale solid waste, shale oil collection, and process stream sampling and characterization: Final report  

SciTech Connect (OSTI)

Approximately 518 tons of New Albany oil shale were obtained from the McRae quarry in Clark County, Indiana and shipped to Golden, CO. A portion of the material was processed through a TOSCO II pilot plant retort. About 273 tons of crushed raw shale, 136 tons of retorted shale, 1500 gallons of shale oil, and 10 drums of retort water were shipped to US Department of Energy, Laramie, WY. Process conditions were documented, process streams were sampled and subjected to chemical analysis, and material balance calculations were made. 6 refs., 12 figs., 14 tabs.

Not Available

1989-02-01T23:59:59.000Z

312

Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock  

E-Print Network [OSTI]

of a jurassic opalinum shale, switzerland. Clays and Clay96 1 INTRODUCTION Clay/shale has been considered asand Rupture of Heterogeneous Shale Samples by Using a Non-

Liu, H.H.

2012-01-01T23:59:59.000Z

313

Inorganic geochemistry of Devonian shales in southern West Virginia: geographic and stratigraphic trends  

SciTech Connect (OSTI)

Samples of cuttings from twenty-one wells and a core from a single well in southern West Virginia were analyzed for major and minor elements: silicon, aluminum, iron, magnesium, calcium, sodium, titanium, phosphorus, manganese, sulfur, zinc, and strontium. Stratigraphic and geographic controls on elemental abundances were studied through canonical correlations, factor analyses, and trend surface analyses. The most abundant elements, silicon and aluminum, show gradual trends through the stratigraphic column of most wells, with silicon increasing and aluminum decreasing up-section. Other elements such as calcium, sulfur, and titanium change abruptly in abundance at certain stratigraphic boundaries. Important geographic trends run east-west: for instance, one can see an increase in sulfur and a decrease in titanium to the west; and a decrease in silicon from the east to the central part of the study area, then an increase further west. Although observed vertical trends in detrital minerals and geographic patterns in elemental abundances agree with the accepted view of a prograding delta complex during Late Devonian time, geographically-local, time restricted depositional processes influenced elemental percentages in subsets of the wells and the stratigraphic intervals studied. The black shales of lower Huron age do not represent simply a return of depositional conditions present in the earlier Rhinestreet time; nor do the gray shales of the Ohio Shale represent the same environmental conditions as the Big White Slate.

Hohn, M.E.; Neal, D.W.; Renton, J.J.

1980-04-01T23:59:59.000Z

314

Concentration of oil shale by froth flotation. Monthly technical letter report, May 1-31, 1983  

SciTech Connect (OSTI)

Highlights of findings during May 1983, are briefly summarized. Batches of shale were ground in a 14-inch ball mill. Froth flotation of the ground shales were carried out using pine oil as a frother. Shale used was a high grade eastern shale (New Albany shale). (DMC)

Krishnan, G.

1983-10-14T23:59:59.000Z

315

The chemistry of minerals obtained from the combustion of Jordanian oil shale  

E-Print Network [OSTI]

The chemistry of minerals obtained from the combustion of Jordanian oil shale Awni Y. Al was performed on the spent oil shale (oil shale ash) obtained from the combustion of Jordanian oil shale process, minimal fragmentation was encountered since Jordanian oil shale contains large proportions of ash

Shawabkeh, Reyad A.

316

Two-level, horizontal free face mining system for in situ oil shale retorts  

SciTech Connect (OSTI)

A method is described for forming an in-situ oil shale retort within a retort site in a subterranean formation containing oil shale, such an in-situ oil shale retort containing a fragmented permeable mass of formation particles containing oil shale formed within upper, lower and side boundaries of an in-situ oil shale retort site.

Cha, C.Y.; Ricketts, T.E.

1986-09-16T23:59:59.000Z

317

Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas  

E-Print Network [OSTI]

Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas, desorbtion, tracing, migration Overview The discovery of shale gas in UK Shales demonstrates how important and no doubt will vary from shale to shale. An improved understanding of the controls on gas production from

Henderson, Gideon

318

Water management practices used by Fayetteville shale gas producers.  

SciTech Connect (OSTI)

Water issues continue to play an important role in producing natural gas from shale formations. This report examines water issues relating to shale gas production in the Fayetteville Shale. In particular, the report focuses on how gas producers obtain water supplies used for drilling and hydraulically fracturing wells, how that water is transported to the well sites and stored, and how the wastewater from the wells (flowback and produced water) is managed. Last year, Argonne National Laboratory made a similar evaluation of water issues in the Marcellus Shale (Veil 2010). Gas production in the Marcellus Shale involves at least three states, many oil and gas operators, and multiple wastewater management options. Consequently, Veil (2010) provided extensive information on water. This current study is less complicated for several reasons: (1) gas production in the Fayetteville Shale is somewhat more mature and stable than production in the Marcellus Shale; (2) the Fayetteville Shale underlies a single state (Arkansas); (3) there are only a few gas producers that operate the large majority of the wells in the Fayetteville Shale; (4) much of the water management information relating to the Marcellus Shale also applies to the Fayetteville Shale, therefore, it can be referenced from Veil (2010) rather than being recreated here; and (5) the author has previously published a report on the Fayetteville Shale (Veil 2007) and has helped to develop an informational website on the Fayetteville Shale (Argonne and University of Arkansas 2008), both of these sources, which are relevant to the subject of this report, are cited as references.

Veil, J. A. (Environmental Science Division)

2011-06-03T23:59:59.000Z

319

PAPER NO. rtos-A118 International Conference on Oil Shale: Recent Trends In Oil Shale, 7-9 November 2006, Amman,Jordan WORLD OIL SHALE RETORTING TECHNOLOGIES  

E-Print Network [OSTI]

This paper mainly describes the worlds commercial oil shale retorting technologies, including lump oil shale and particulate oil shale retorting technologies. Fushun Type Retorting, Petrosix Retorting, and Kiviter Retorting are illustrated as the examples of lump oil shale retorting; Galoter

Jialin Qian; Jianqiu Wang

320

Tectonic and flexural significance of Middle Devonian graben-fill sequence in new Albany shale, central Kentucky  

SciTech Connect (OSTI)

The third tectonic phase of the Acadian orogeny began in the late Middle Devonian, and the sedimentary record of that event is largely restricted to the deeper, more proximal portions of the Appalachian foreland and Illinois intercratonic basins. Much of the intervening area, on and near the Cincinnati arch, was uplifted and subjected to erosion by movement on the peripheral bulge accompanying the initiation of the third tectonic phase. However, bulge movement also reactivated basement fault systems in Kentucky and created a series of grabens that were filled with eroded sediments and debris flows from adjacent horsts. Although rarely preserved, a buried Devonian graben along Carpenter Fork in Boyle County, central Kentucky, reveals such a sequence. The graben is bounded by upthrown blocks of Middle Devonian Boyle Dolomite, which also floors the graben. Within the graben a black-shale unit, apparently absent elsewhere, conformably overlies the Boyle and grades upward into debris-flow deposits represented by the Duffin breccia facies of the New Albany Shale. The Duffin contains clasts of the shale, as well as of chert, silicified fossils, and fine to boulder-size dolostone clasts eroded from the Boyle high on the flanks of the graben. The underlying shale also exhibits evidence of penecontemporaneous soft-sediment deformation related to the debris-flow emplacement of Boyle residue in the graben and due to later loading by the Duffin.

Barnett, S.F.; Ettensohn, F.R.; Mellon, C. (Univ. of Kentucky, Lexington (USA))

1989-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Investigation of methane adsorption and its effect on gas transport in shale matrix through microscale and mesoscale simulations  

E-Print Network [OSTI]

Methane adsorption and its effect on fluid flow in shale matrix are investigated through multi-scale simulation scheme by using molecular dynamics (MD) and lattice Boltzmann (LB) methods. Equilibrium MD simulations are conducted to study methane adsorption on the organic and inorganic walls of nanopores in shale matrix with different pore sizes and pressures. Density and pressure distributions within the adsorbed layer and the free gas region are discussed. The illumination of the MD results on larger scale LB simulations is presented. Pressure-dependent thickness of adsorbed layer should be adopted and the transport of adsorbed layer should be properly considered in LB simulations. LB simulations, which are based on a generalized Navier-Stokes equation for flow through low-permeability porous media with slippage, are conducted by taking into consideration the effects of adsorbed layer. It is found that competitive effects of slippage and adsorbed layer exist on the permeability of shale matrix, leading to di...

Li, ZhongZhen; Chen, Li; Kangd, Qinjun; He, Ya-Ling; Tao, Wen-Quan

2015-01-01T23:59:59.000Z

322

Geologic analysis of Devonian Shale cores  

SciTech Connect (OSTI)

Cleveland Cliffs Iron Company was awarded a DOE contract in December 1977 for field retrieval and laboratory analysis of cores from the Devonian shales of the following eleven states: Michigan, Illinois, Indiana, Ohio, New York, Pennsylvania, West Virginia, Maryland, Kentucky, Tennessee and Virginia. The purpose of this project is to explore these areas to determine the amount of natural gas being produced from the Devonian shales. The physical properties testing of the rock specimens were performed under subcontract at Michigan Technological University (MTU). The study also included LANDSAT information, geochemical research, structural sedimentary and tectonic data. Following the introduction, and background of the project this report covers the following: field retrieval procedures; laboratory procedures; geologic analysis (by state); references and appendices. (ATT)

none,

1982-02-01T23:59:59.000Z

323

Plan for addressing issues relating to oil shale plant siting  

SciTech Connect (OSTI)

The Western Research Institute plan for addressing oil shale plant siting methodology calls for identifying the available resources such as oil shale, water, topography and transportation, and human resources. Restrictions on development are addressed: land ownership, land use, water rights, environment, socioeconomics, culture, health and safety, and other institutional restrictions. Descriptions of the technologies for development of oil shale resources are included. The impacts of oil shale development on the environment, socioeconomic structure, water availability, and other conditions are discussed. Finally, the Western Research Institute plan proposes to integrate these topics to develop a flow chart for oil shale plant siting. Western Research Institute has (1) identified relative topics for shale oil plant siting, (2) surveyed both published and unpublished information, and (3) identified data gaps and research needs. 910 refs., 3 figs., 30 tabs.

Noridin, J. S.; Donovan, R.; Trudell, L.; Dean, J.; Blevins, A.; Harrington, L. W.; James, R.; Berdan, G.

1987-09-01T23:59:59.000Z

324

Kansas Shale Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year in Review WYear Jan FebWellheadShale Proved

325

Kentucky Shale Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year in Review WYear JanFeet)CubicShale Proved

326

Montana Shale Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year2per ThousandWellhead+Wellhead PriceperShale Proved

327

Pennsylvania Shale Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-MonthCoalbed Methane(Dollars per ThousandShale

328

Deformation of shale: mechanical properties and indicators of mechanisms  

E-Print Network [OSTI]

Basins, shales of Devonian age are commonly considered reservoir rocks I' or natural gas [Woodward, 1958; Lockett, 1968; Long, 1979; Gonzales and Johnson, 1985], Economic gas production from the Devonian shales of these basins is associated...] and slates [Donath, 1961], may be expected to be weak. Finally, Microstructural studies of deformed shales have been restricted by optical resolution, and the role of crystal plasticity in clays may have been overlooked. Results for the brittle and semi...

Ibanez, William Dayan

1993-01-01T23:59:59.000Z

329

Tensile strengths of problem shales and clays. Master's thesis  

SciTech Connect (OSTI)

The greatest single expense faced by oil companies involved in the exploration for crude oil is that of drilling wells. The most abundant rock drilled is shale. Some of these shales cause wellbore stability problems during the drilling process. These can range from slow rate of penetration and high torque up to stuck pipe and hole abandonment. The mechanical integrity of the shale must be known when the shalers are subjected to drilling fluids to develop an effective drilling plan.

Rechner, F.J.

1990-01-01T23:59:59.000Z

330

Western oil shale conversion using the ROPE copyright process  

SciTech Connect (OSTI)

Western Research Institute (WRI) is continuing to develop the Recycle Oil Pyrolysis and Extraction (ROPE) process to recover liquid hydrocarbon products from oil shale, tar sand, and other solid hydrocarbonaceous materials. The process consists of three major steps: (1) pyrolyzing the hydrocarbonaceous material at a low temperature (T {le} 400{degrees}C) with recycled product oil, (2) completing the pyrolysis of the residue at a higher temperature (T > 400{degrees}C) in the absence of product oil, and (3) combusting the solid residue and pyrolysis gas in an inclined fluidized-bed reactor to produce process heat. Many conventional processes, such as the Paraho and Union processes, do not use oil shale fines (particles smaller than 1.27 cm in diameter). The amount of shale discarded as fines from these processes can be as high as 20% of the total oil shale mined. Research conducted to date suggests that the ROPE process can significantly improve the overall oil recovery from western oil shale by processing the oil shale fines typically discarded by conventional processes. Also, if the oil shale fines are co-processed with shale oil used as the heavy recycle oil, a better quality oil will be produced that can be blended with the original shale oil to make an overall produce that is more acceptable to the refineries and easier to pipeline. Results from tests conducted in a 2-inch process development unit (PDU) and a 6-inch bench-scale unit (BSU) with western oil shale demonstrated a maximum oil yield at temperatures between 700 and 750{degrees}F (371 and 399{degrees}C). Test results also suggest that the ROPE process has a strong potential for recovering oil from oil shale fines, upgrading shale oil, and separating high-nitrogen-content oil for use as an asphalt additive. 6 refs., 10 figs., 11 tabs.

Cha, C.Y.; Fahy, L.J.; Grimes, R.W.

1989-12-01T23:59:59.000Z

331

Research and information needs for management of oil shale development  

SciTech Connect (OSTI)

This report presents information and analysis to assist BLM in clarifying oil shale research needs. It provides technical guidance on research needs in support of their regulatory responsibilities for onshore mineral activities involving oil shale. It provides an assessment of research needed to support the regulatory and managerial role of the BLM as well as others involved in the development of oil shale resources on public and Indian lands in the western United States.

Not Available

1983-05-01T23:59:59.000Z

332

A Strategy for the Abandonment of Modified In-Situ Oil Shale Retorts  

E-Print Network [OSTI]

Effects of steam on oil shale ing: a preliminary laboratoryInstitute to Rio Blanco Oil Shale Project, May 1977. 1~Cement, pozzolan and oil shale chemistry The chemistry of

Fox, J.P.; Persoff, P.; Moody, M.M.; Sisemore, C.J.

1978-01-01T23:59:59.000Z

333

ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER  

E-Print Network [OSTI]

Water co produced with shale oil and decanted from it isWater from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERC

Ossio, E.A.

2011-01-01T23:59:59.000Z

334

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

each of retort water and shale oil, about 10 1 000 standardfrom In-Situ Retorting of Oil Shale," Energy and Environmentanic species present in shale oils process waters, gases,

,

2012-01-01T23:59:59.000Z

335

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

4, 19'70, p. 89. 24. C-b Shale Oil Venture: Hydrology, MinePiles Solid wastes from the shale-oil recovery process alsofrom a Simulated In-Situ Oil Shale Retort, Proceedings of

Fox, J. P.

2011-01-01T23:59:59.000Z

336

Inventory of Shale Formations in the US, Including Geologic, Hydrological, and Mechanical Characteristics  

E-Print Network [OSTI]

enggeo.2013.05.021. CNX/GTI (2008). New Albany ShaleRVSP, New Albany Shale Gas Project, RVSP Seismic Projectisopach maps of the New Albany Shale, Illinois Basin. Figure

Dobson, Patrick

2014-01-01T23:59:59.000Z

337

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale Retort, Proceedings ofthe 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

Fox, J. P.

2011-01-01T23:59:59.000Z

338

ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER  

E-Print Network [OSTI]

Water from Green River Oil Shale, Chemistry and Industry,an In-Situ Produced Oil-Shale Processin g Water, LERC ReportOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

Ossio, E.A.

2011-01-01T23:59:59.000Z

339

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

A. Robb, and T. J. Spedding. Minor Elements in Oil Shale andOil-Shale Products. LERC RI 77-1, 1977. Bertine, K. K. andFrom A Simulated In-Situ Oil Shale Retort. In: Procedings of

Girvin, D.G.

2011-01-01T23:59:59.000Z

340

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

from In-Situ Retorting of Oil Shale," Energy and EnvironmentTrace Contaminants in Oil Shale Retort Water M. J. Kland, A.Arsenic Compounds 1n Oil Shale Process Waters R. H. Fish,

,

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

A. Robb, and T. J. Spedding. Minor Elements in Oil Shale andOil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

Farrier, D.S.

2011-01-01T23:59:59.000Z

342

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,E . 1977; Mercury in Oil Shale from the Mahogany Zone the

Fox, J. P.

2012-01-01T23:59:59.000Z

343

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

Stabilization of Spent Oil Shales, EPA-600/'7-'78- 021, Feb.Impact Analysis for an Oil Shale Complex at Parachute Creek,from a Simulated In-Situ Oil Shale Retort, Proceedings of

Fox, J. P.

2011-01-01T23:59:59.000Z

344

TREATMENT OF MULTIVARIATE ENVIRONMENTAL AND HEALTH PROBLEMS ASSOCIATED WITH OIL SHALE TECHNOLOGY  

E-Print Network [OSTI]

of Trace Contaminants in Oil Shale Retort Wa- ters", Am.LBL-10850. b. and , "Trace Contaminants in Oil Shale RetortWaters", in Oil Shale Research: Characteriza- tion Studies,

Kland, M.J.

2010-01-01T23:59:59.000Z

345

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

from In-Situ Retorting of Oil Shale," Energy and Environmentintimate contact ~lith the oil and shale, Retort waters area Control Technology for Oil Shale Retort Water J. P. Fox,

,

2012-01-01T23:59:59.000Z

346

ANAEROBIC FERMENTATION OF SIMULATED IN-SITU OIL SHALE RETORT WATER  

E-Print Network [OSTI]

Water from Green River Oil Shale, Chemistry and Industry,for an In-Situ Produced Oil-Shale Processin g Water, LERCOf Simulated In-Situ Oil Shale Retort Water B.A. Ossio, J.P.

Ossio, E.A.

2011-01-01T23:59:59.000Z

347

WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale Retort, Proceedingsof the 11th Oil Shale Symposium, 1978. J. W.MB_terial in Green River Oil Shale, U.S. Bur. lvlines Rept.

Fox, J. P.

2011-01-01T23:59:59.000Z

348

A Strategy for the Abandonment of Modified In-Situ Oil Shale Retorts  

E-Print Network [OSTI]

Effects of steam on oil shale ing: a preliminary laboratoryInstitute to Rio Blanco Oil Shale Project, May 1977. 1~OF MODIFIED IN-SITU OIL SHALE RETORTS J. P. Fox and P.

Fox, J.P.; Persoff, P.; Moody, M.M.; Sisemore, C.J.

1978-01-01T23:59:59.000Z

349

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,V. E . 1977; Mercury in Oil Shale from the Mahogany Zone

Fox, J. P.

2012-01-01T23:59:59.000Z

350

Macrurous Decapods from the Bearpaw Shale (Cretaceous: Campanian) of Northeastern Montana  

E-Print Network [OSTI]

Macrurous Decapods from the Bearpaw Shale (Cretaceous: Campanian) of Northeastern Montana Rodney M THE BEARPAW SHALE (CRETACEOUS: CAMPANIAN) OF NORTHEASTERN MONTANA RODNEY M. FELDMANN, GALE A. BISHOP Shale of north- eastern Montana were studied to characterize the occurrence, preservation

Kammer, Thomas

351

Pennsylvania Energy Impacts Assessment Report 1: Marcellus Shale Natural Gas and Wind  

E-Print Network [OSTI]

Pennsylvania Energy Impacts Assessment Report 1: Marcellus Shale Natural Gas and Wind #12;1 Pennsylvania Energy Impacts Assessment Report 1: Marcellus Shale Natural Gas and Wind November 15, 2010 Author.....................................................................................................................3 Marcellus Shale Natural Gas

Boyer, Elizabeth W.

352

Zero Discharge Water Management for Horizontal Shale Gas Well Development  

SciTech Connect (OSTI)

Hydraulic fracturing technology (fracking), coupled with horizontal drilling, has facilitated exploitation of huge natural gas (gas) reserves in the Devonian-age Marcellus Shale Formation (Marcellus) of the Appalachian Basin. The most-efficient technique for stimulating Marcellus gas production involves hydraulic fracturing (injection of a water-based fluid and sand mixture) along a horizontal well bore to create a series of hydraulic fractures in the Marcellus. The hydraulic fractures free the shale-trapped gas, allowing it to flow to the well bore where it is conveyed to pipelines for transport and distribution. The hydraulic fracturing process has two significant effects on the local environment. First, water withdrawals from local sources compete with the water requirements of ecosystems, domestic and recreational users, and/or agricultural and industrial uses. Second, when the injection phase is over, 10 to 30% of the injected water returns to the surface. This water consists of flowback, which occurs between the completion of fracturing and gas production, and produced water, which occurs during gas production. Collectively referred to as returned frac water (RFW), it is highly saline with varying amounts of organic contamination. It can be disposed of, either by injection into an approved underground injection well, or treated to remove contaminants so that the water meets the requirements of either surface release or recycle use. Depending on the characteristics of the RFW and the availability of satisfactory disposal alternatives, disposal can impose serious costs to the operator. In any case, large quantities of water must be transported to and from well locations, contributing to wear and tear on local roadways that were not designed to handle the heavy loads and increased traffic. The search for a way to mitigate the situation and improve the overall efficiency of shale gas production suggested a treatment method that would allow RFW to be used as make-up water for successive fracs. RFW, however, contains dissolved salts, suspended sediment and oils that may interfere with fracking fluids and/or clog fractures. This would lead to impaired well productivity. The major technical constraints to recycling RFW involves: identification of its composition, determination of industry standards for make-up water, and development of techniques to treat RFW to acceptable levels. If large scale RFW recycling becomes feasible, the industry will realize lower transportation and disposal costs, environmental conflicts, and risks of interruption in well development schedules.

Paul Ziemkiewicz; Jennifer Hause; Raymond Lovett; David Locke Harry Johnson; Doug Patchen

2012-03-31T23:59:59.000Z

353

Shale Webinar Series to Start September 13th The Penn State Marcellus Education Team will be offering a new monthly Shale webinar series beginning  

E-Print Network [OSTI]

Shale Webinar Series to Start September 13th The Penn State Marcellus Education Team will be offering a new monthly Shale webinar series beginning Thursday, September 13th from 1:00 to 2:00 PM. Tom the series with an overview of trends and updates on shale development. Tom will provide an analysis of shale

354

Unconventional oil market assessment: ex situ oil shale.  

E-Print Network [OSTI]

??This thesis focused on exploring the economic limitations for the development of western oil shale. The analysis was developed by scaling a known process and (more)

Castro-Dominguez, Bernardo

2010-01-01T23:59:59.000Z

355

Drugs and oil flow through the Eagle Ford Shale.  

E-Print Network [OSTI]

??This report is a work of original reporting which investigates the proliferation of drug use and drug trafficking in the Eagle Ford Shale, a region (more)

Marks, Michael Perry

2014-01-01T23:59:59.000Z

356

Experimental study of mechanisms of improving oil recovery in Shale.  

E-Print Network [OSTI]

??ABSTRACT Extensive laboratory work was done to investigate some of the important mechanisms of improving oil recovery in Shale formations. The objective of this research (more)

Onyenwere, Emmanuel

2012-01-01T23:59:59.000Z

357

INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE  

SciTech Connect (OSTI)

A process for making hydraulic cements from spent oil shale is described in this paper. Inexpensive cement is needed to grout abandoned in-situ retorts of spent shale for subsidence control, mitigation of leaching, and strengthening the retorted mass in order to recover oil from adjacent pillars of raw shale. A hydraulic cement was produced by heating a 1:1 mixture of Lurgi spent shale and CaCO{sub 3} at 1000 C for one hour. This cement would be less expensive than ordinary portland cement and is expected to fulfill the above requirements.

Mehta, P.K.; Persoff, P.

1980-04-01T23:59:59.000Z

358

Secretary of Energy Advisory Board Subcommittee Releases Shale...  

Office of Environmental Management (EM)

environmental management of shale gas, which has rapidly grown to nearly 30 percent of natural gas production in the United States. Increased transparency and a focus on best...

359

,"New York Natural Gas Gross Withdrawals from Shale Gas (Million...  

U.S. Energy Information Administration (EIA) Indexed Site

,,"(202) 586-8800",,,"2262015 9:43:21 AM" "Back to Contents","Data 1: New York Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)"...

360

Outlook for U.S. shale oil and gas  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

2035 2040 Associated with oil Coalbed methane Tight gas Shale gas Alaska Non-associated offshore Non-associated onshore Projections History 2012 Adam Sieminski, IAEEAEA January...

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Strategic Significance of Americas Oil Shale Resource  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Deputy Assistant Secretary for Petroleum Reserves Office of Naval Petroleum and Oil Shale Reserves U.S. Department of Energy Washington, D.C. March 2004 Strategic...

362

Department of Energy, Office of Naval Petroleum & Oil Shale Reserves  

Broader source: Energy.gov (indexed) [DOE]

Items that may be marked "disposrtron not Office of Naval Petroleum & Oil Shale Reserves approved" or "withdrawn" In column 10 4 Nameof Personwith whom to confer 5...

363

Attrition and abrasion models for oil shale process modeling  

SciTech Connect (OSTI)

As oil shale is processed, fine particles, much smaller than the original shale are created. This process is called attrition or more accurately abrasion. In this paper, models of abrasion are presented for oil shale being processed in several unit operations. Two of these unit operations, a fluidized bed and a lift pipe are used in the Lawrence Livermore National Laboratory Hot-Recycle-Solid (HRS) process being developed for the above ground processing of oil shale. In two reports, studies were conducted on the attrition of oil shale in unit operations which are used in the HRS process. Carley reported results for attrition in a lift pipe for oil shale which had been pre-processed either by retorting or by retorting then burning. The second paper, by Taylor and Beavers, reported results for a fluidized bed processing of oil shale. Taylor and Beavers studied raw, retorted, and shale which had been retorted and then burned. In this paper, empirical models are derived, from the experimental studies conducted on oil shale for the process occurring in the HRS process. The derived models are presented along with comparisons with experimental results.

Aldis, D.F.

1991-10-25T23:59:59.000Z

364

Multi-temperature method for high-pressure sorption measurements on moist shales  

SciTech Connect (OSTI)

A simple and effective experimental approach has been developed and tested to study the temperature dependence of high-pressure methane sorption in moist organic-rich shales. This method, denoted as multi-temperature (short multi-T) method, enables measuring multiple isotherms at varying temperatures in a single run. The measurement of individual sorption isotherms at different temperatures takes place in a closed system ensuring that the moisture content remains constant. The multi-T method was successfully tested for methane sorption on an organic-rich shale sample. Excess sorption isotherms for methane were measured at pressures of up to 25 MPa and at temperatures of 318.1 K, 338.1 K, and 348.1 K on dry and moisture-equilibrated samples. The measured isotherms were parameterized with a 3-parameter Langmuir-based excess sorption function, from which thermodynamic sorption parameters (enthalpy and entropy of adsorption) were obtained. Using these, we show that by taking explicitly into account water vapor as molecular species in the gas phase with temperature-dependent water vapor pressure during the experiment, more meaningful results are obtained with respect to thermodynamical considerations. The proposed method can be applied to any adsorbent system (coals, shales, industrial adsorbents) and any supercritical gas (e.g., CH{sub 4}, CO{sub 2}) and is particularly suitable for sorption measurements using the manometric (volumetric) method.

Gasparik, Matus; Ghanizadeh, Amin; Gensterblum, Yves; Krooss, Bernhard M. [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)] [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)

2013-08-15T23:59:59.000Z

365

Regional geological assessment of the Devonian-Mississippian shale sequence of the Appalachian, Illinois, and Michigan basins relative to potential storage/disposal of radioactive wastes  

SciTech Connect (OSTI)

The thick and regionally extensive sequence of shales and associated clastic sedimentary rocks of Late Devonian and Early Mississippian age has been considered among the nonsalt geologies for deep subsurface containment of high-level radioactive wastes. This report examines some of the regional and basin-specific characteristics of the black and associated nonblack shales of this sequence within the Appalachian, Illinois, and Michigan basins of the north-central and eastern United States. Principal areas where the thickness and depth of this shale sequence are sufficient to warrant further evaluation are identified, but no attempt is made to identify specific storage/disposal sites. Also identified are other areas with less promise for further study because of known potential conflicts such as geologic-hydrologic factors, competing subsurface priorities involving mineral resources and groundwater, or other parameters. Data have been compiled for each basin in an effort to indicate thickness, distribution, and depth relationships for the entire shale sequence as well as individual shale units in the sequence. Included as parts of this geologic assessment are isopach, depth information, structure contour, tectonic elements, and energy-resource maps covering the three basins. Summary evaluations are given for each basin as well as an overall general evaluation of the waste storage/disposal potential of the Devonian-Mississippian shale sequence,including recommendations for future studies to more fully characterize the shale sequence for that purpose. Based on data compiled in this cursory investigation, certain rock units have reasonable promise for radioactive waste storage/disposal and do warrant additional study.

Lomenick, T.F.; Gonzales, S.; Johnson, K.S.; Byerly, D.

1983-01-01T23:59:59.000Z

366

Association of trace elements with mineral species in the New Albany oil shale  

SciTech Connect (OSTI)

X-Ray diffraction (XRD), electron microprobe (EMP), scanning electron microscopy (SEM) and neutron activation analysis (NAA) were used to identify mineral species in the New Albany shale and kerogen isolates. Elemental abundances were determined by NAA and distributions of Ni, V, As, and other elements with-in mineral grains were determined by EMP-XRF. Vanadium in the New Albany shale was found to be associated primarily with clay minerals (illite, montmorrillonite). In the New Albany kerogen, Ni and V were shown to be predominantly associated with the organic matrix. Pyrite (and/or marcasite) was shown to occur in two forms, a euhedral variety and as framboidal clusters. The Ni content of the framboidal variety was found to be higher than that of the euhedral pyrite.

Fitzgerald, S.L.; Day, J.W.; Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

367

Current environmental, health, safety, and socioeconomic research activities related to oil shale: draft  

SciTech Connect (OSTI)

This document was prepared for DOE Resource Applications. It provides a compilation of information on current environmental, health, safety and socioeconomic research activities related to oil shale. The information is the most recent available through August 29, 1980. Included are the following: (1) project title; (2) adminstering agency; (3) contractor; (4) project status; (5) funding level; (6) project schedule; (7) deliverable; and (8) key personnel. The data contained in these reports can be used in environmental impact analyses relating oil shale to various incentives given in the Alternative Fuels Bill. The information provided was obtained from computer search printouts, review of respective agency documents and communication with agency personnel. A complete list of references is provided. The sponsoring organizations include the Department of Energy, the Environmental Protection Agency, the Department of Agriculture, and the Department of Interior.

Not Available

1980-09-01T23:59:59.000Z

368

The technology of the New South Wales torbanite : including an introduction on oil shale.  

E-Print Network [OSTI]

??Although the nature of the products of thermal decomposition of oil shale has attracted the attention of both scientist and industrialist, oil shale possibly ranks (more)

Cane, Reginald Frank

1946-01-01T23:59:59.000Z

369

Experimental and simulation study of improved oil recovery in shale formations.  

E-Print Network [OSTI]

??Shale has ultra low permeability and cannot produce without hydraulic fracturing to improve the contact between reservoir matrix with wellbore. In addition, shale production declines (more)

Morsy, Samiha

2014-01-01T23:59:59.000Z

370

TREATMENT OF MULTIVARIATE ENVIRONMENTAL AND HEALTH PROBLEMS ASSOCIATED WITH OIL SHALE TECHNOLOGY  

E-Print Network [OSTI]

Jr. and M. D. Shelby, "Chemicals Identified in Oil Shaleand Shale Oil. list." 1. Preliminary Environmental MutagenTrace Contaminants in Oil Shale Retort Wa- ters", Am. Chern.

Kland, M.J.

2010-01-01T23:59:59.000Z

371

90-day Second Report on Shale Gas Production - Secretary of Energy...  

Broader source: Energy.gov (indexed) [DOE]

90-day Second Report on Shale Gas Production - Secretary of Energy Advisory Board 90-day Second Report on Shale Gas Production - Secretary of Energy Advisory Board Novemeber 18,...

372

Evaluation of EOR Potential by Gas and Water Flooding in Shale Oil Reservoirs.  

E-Print Network [OSTI]

??The demand for oil and natural gas will continue to increase for the foreseeable future; unconventional resources such as tight oil, shale gas, shale oil (more)

Chen, Ke

2013-01-01T23:59:59.000Z

373

Organic geochemistry and correlation of Paleozoic source rocks and Trenton crude oils, Indiana  

SciTech Connect (OSTI)

Shale samples from four cores of the New Albany and Antrim Shales (Devonian) and from six cores of the Maquoketa Group (Ordovician), representing a broad geographic area of Indiana, have been analyzed for total organic carbon, total sulfur, pyrolysis yield (Rock-Eval), bitumen content, and illite crystallinity data. These data indicate that the New Albany, Antrim, and Maquoketa shales contain a sufficient quantity and quality of organic matter to be good petroleum source rocks. Bitumen ratios, Rock-Eval yields, gas chromatography of saturated hydrocarbons, and illite crystallinity data show that the Maquoketa shales have reached a higher level of thermal maturity than the New Albany and Antrim shales. The level of thermal maturity of the Maquoketa shales suggested a maximum burial depth considerably greater than the present depth.

Guthrie, J. (Indiana Geological Survey, Bloomington (USA))

1989-08-01T23:59:59.000Z

374

Economic viability of shale gas production in the Marcellus Shale; indicated by production rates, costs and current natural gas prices.  

E-Print Network [OSTI]

?? The U.S. natural gas industry has changed because of the recent ability to produce natural gas from unconventional shale deposits. One of the largest (more)

Duman, Ryan J.

2012-01-01T23:59:59.000Z

375

Black Holes  

E-Print Network [OSTI]

Lecture notes for a 'Part III' course 'Black Holes' given in DAMTP, Cambridge. The course covers some of the developments in Black Hole physics of the 1960s and 1970s.

P. K. Townsend

1997-07-04T23:59:59.000Z

376

General screening criteria for shale gas reservoirs and production data analysis of Barnett shale  

E-Print Network [OSTI]

Shale gas reservoirs are gaining importance in United States as conventional oil and gas resources are dwindling at a very fast pace. The purpose of this study is twofold. First aim is to help operators with simple screening criteria which can help...

Deshpande, Vaibhav Prakashrao

2009-05-15T23:59:59.000Z

377

Morphological Investigations of Fibrogenic Action of Estonian Oil Shale Dust  

E-Print Network [OSTI]

A review of morphological investigations carried out to clarify the pathogenicity of industrial dust produced in the mining and processing of Estonian oil shale is given. Histological examination of lungs of workers in the oil shale industry taken at necropsies showed that the inhalation of oil

V. A. Kung

378

The Models of Estimating Oil Shale Flows and Price  

E-Print Network [OSTI]

The fast economical growth of Estonia in past years has set us several questions on sustainability of oil shale mining in Estonia. For how long do the oil shale resources last? What are the mining expenditures in the areas of different mining conditions and how do they change in future? Thus, in

Tauno Tammeoja; Aire Vstrik

379

Water's Journey Through the Shale Gas Drilling and  

E-Print Network [OSTI]

Water's Journey Through the Shale Gas Drilling and Production Processes in the Mid-Atlantic Region: Marcellus shale drilling in progress, Beaver Run Reservoir, Westmoreland County. Credit: Robert Donnan. Gas. This publication fo- cuses mostly on Pennsylvania because it has the most Marcellus drilling activity of any state

Lee, Dongwon

380

Market analysis of shale oil co-products. Appendices  

SciTech Connect (OSTI)

Data are presented in these appendices on the marketing and economic potential for soda ash, aluminia, and nahcolite as by-products of shale oil production. Appendices 1 and 2 contain data on the estimated capital and operating cost of an oil shales/mineral co-products recovery facility. Appendix 3 contains the marketing research data.

Not Available

1980-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Beneficiation and hydroretorting of low grade oil shale  

SciTech Connect (OSTI)

A new approach to oil recovery from low grade oil shales has been developed jointly by the Mineral Resources Institute (MRI) of The University of Alabama and the HYCRUDE Corporation. The approach is based on the HYTORT process, which utilized hydrogen gas during the retorting process to enhance oil yields from many types of oil shales. The performance of the HYTORT process is further improved by combining it with MRI's froth flotation process. Taking advantage of differences in the surface properties of the kerogen and the inorganic mineral constituents of the oil shales, the MRI process can reject up to three quarters by weight of relatively kerogen-free inorganic fractions of the oil shale before HYTORT processing. The HYTORT and MRI processes are discussed. Results of tests by each process on oil shales of low to moderate inherent kerogen content are presented. Also discussed are the results of the combined processes on an Indiana New Albany oil shale. By combining the two processes, the raw shale which yielded 12 gallons of oil per ton by Fischer Assay was upgraded by flotation to a product yielding 27 gallons of Fischer Assay oil per ton. HYTORT processing of the beneficiated product recovered 54 gallons of oil per ton, an improvement in oil yield by a factor of 4.5 over the raw shale Fischer Assay.

Tippin, R.B.; Hanna, J.; Janka, J.C.; Rex, R.C. Jr.

1985-02-01T23:59:59.000Z

382

Shale Gas Production: Potential versus Actual GHG Emissions  

E-Print Network [OSTI]

Shale Gas Production: Potential versus Actual GHG Emissions Francis O'Sullivan and Sergey Paltsev, and environmental effects. In turn, the greenhouse gas and atmospheric aerosol assumptions underlying climate://globalchange.mit.edu/ Printed on recycled paper #12;1 Shale Gas Production: Potential versus Actual GHG Emissions Francis O

383

Shale gas production: potential versus actual greenhouse gas emissions*  

E-Print Network [OSTI]

Shale gas production: potential versus actual greenhouse gas emissions* Francis O, monitor and verify greenhouse gas emissions and climatic impacts. This reprint is one of a series intended Environ. Res. Lett. 7 (2012) 044030 (6pp) doi:10.1088/1748-9326/7/4/044030 Shale gas production: potential

384

Physical and mechanical properties of bituminous mixtures containing oil shales  

SciTech Connect (OSTI)

Rutting of bituminous surfaces on the Jordanian highways is a recurring problem. Highway authorities are exploring the use of extracted shale oil and oil shale fillers, which are abundant in Jordan. The main objectives of this research are to investigate the rheological properties of shale oil binders (conventional binder with various percentages of shale oil), in comparison with a conventional binder, and to investigate the ability of mixes to resist deformation. The latter is done by considering three wearing course mixes containing three different samples of oil shale fillers--which contained three different oil percentages--together with a standard mixture containing limestone filler. The Marshall design method and the immersion wheel tracking machine were adopted. It was concluded that the shale oil binders displayed inconsistent physical properties and therefore should be treated before being used. The oil shale fillers have provided mixes with higher ability to resist deformation than the standard mix, as measured by the Marshall quotients and the wheel tracking machine. The higher the percentages of oil in the oil shale fillers, the lower the ability of the mixes to resist deformation.

Katamine, N.M.

2000-04-01T23:59:59.000Z

385

History and some potentials of oil shale cement  

SciTech Connect (OSTI)

The utilization of oil shale as a cement component is discussed. It was investigated in America and Europe during World War I. Additional development occurred in Western Europe, Russia, and China during the 1920s and 1930s. World War II provided further development incentives and a relatively mature technology was in place in Germany, Russia, and China prior to 1980. The utilization of oil shale in cement has taken a number of different paths. One approach has been to utilize the energy in the oil shale as the principal source for the cement plant and to use the combusted shale as a minor constituent of the plant's cement product. A second approach has been to use the combusted shale as a class C or cementitious fly-ash component in portland cement concrete. Other approaches utilizing eastern oil shale have been to use the combusted oil shale with additives as a specialty cement, or to cocombust the oil shale with coal and utilize the sulfur-rich combustion product.

Knutson, C.F.; Smith, R.P.; Russell, B.F. (Idaho National Engineering Lab., Idaho Falls, ID (USA))

1989-01-01T23:59:59.000Z

386

Potential Contaminant Pathways from Hydraulically Fractured Shale to Aquifers  

E-Print Network [OSTI]

that fracking the shale could reduce that transport time to tens or hundreds of years. Conductive faults to reach a new equilibrium reflecting the significant changes caused by fracking the shale, which could for development. Hydraulic fracturing (fracking, the industry term for the operation; Kramer 2011) loosens

387

SPE-139032-PP Field Development Strategies for Bakken Shale Formation  

E-Print Network [OSTI]

SPE-139032-PP Field Development Strategies for Bakken Shale Formation S.Zargari, SPE, S s a ckno wle dgm ent of S PE co p yrig ht. Abstract Bakken shale has been subjected to more attention coupled with advancements in horizontal drilling, increased the interest of oil companies for investment

Mohaghegh, Shahab

388

Bakken shale typifies horizontal drilling success  

SciTech Connect (OSTI)

Given the favorable production response that has been obtained from horizontal drilling in vertical- fractured reservoirs such as the Bakken shale and, more recently, the Austin chalk, industry interest in this technology has mushroomed in the U.S. Indeed, it is difficult to find a good-sized oil company these days that is not involved in a horizontal drilling project or is giving it serious consideration. In response to growing evidence of successful field applications, the realization is dawning on the investment community that horizontal drilling represents a significant technological development with positive implications for both the exploration and production business, and the oilfield services industry.

Leibman, P.R. (Petrie Parkman and Co., Denver, CO (US))

1990-12-01T23:59:59.000Z

389

West Virginia Shale Production (Billion Cubic Feet)  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYearTexas--StateWinterYearFeet)per Thousand(BillionShale Production

390

Natural Gas from Shale | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy HealthCommentsAugustNational ScienceEnergy - Third QuarterNaturalShale

391

Michigan Shale Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year2per Thousand Cubic Feet) Year Jan FebShale

392

Oklahoma Shale Proved Reserves (Billion Cubic Feet)  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-Month WeekReservesYearYear Jan FebperShale Proved

393

New Mexico Shale Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomic team:6-2015(Million Cubic Feet) NewWellheadperShale

394

North Dakota Shale Production (Billion Cubic Feet)  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper Thousand Cubic Feet)3.74 3.92(Dollars perShale

395

NATURAL GAS FROM SHALE: Questions and Answers  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't32Department ofMoving AwayAvailability ofMyChallengesis shale

396

Market analysis of shale oil co-products. Summary report  

SciTech Connect (OSTI)

This study examines the potential for separating, upgrading and marketing sodium mineral co-products together with shale oil production. The co-products investigated are soda ash and alumina which are derived from the minerals nahcolite and dawsonite. Five cases were selected to reflect the variance in mineral and shale oil content in the identified resource. In the five cases examined, oil content of the shale was varied from 20 to 30 gallons per ton. Two sizes of facilities were analyzed for each resource case to determine economies of scale between a 15,000 barrel per day demonstration unit and a 50,000 barrel per day full sized plant. Three separate pieces of analysis were conducted in this study: analysis of manufacturing costs for shale oil and co-products; projection of potential world markets for alumina, soda ash, and nahcolite; and determination of economic viability and market potential for shale co-products.

Not Available

1980-12-01T23:59:59.000Z

397

Oil shale retorting with steam and produced gas  

SciTech Connect (OSTI)

This patent describes a process for retorting oil shale in a vertical retort. It comprises introducing particles of oil shale into the retort, the particles of oil shale having a minimum size such that the particles are retained on a screen having openings 1/4 inch in size; contacting the particles of oil shale with hot gas to heat the particles of oil shale to a state of pyrolysis, thereby producing retort off-gas; removing the off-gas from the retort; cooling the off-gas; removing oil from the cooled off-gas; separating recycle gas from the off-gas, the recycle gas comprising steam and produced gas, the steam being present in amount, by volume, of at least 50% of the recycle gas so as to increase the yield of sand oil; and heating the recycle gas to form the hot gas.

Merrill, L.S. Jr.; Wheaton, L.D.

1991-08-20T23:59:59.000Z

398

Expectations for Oil Shale Production (released in AEO2009)  

Reports and Publications (EIA)

Oil shales are fine-grained sedimentary rocks that contain relatively large amounts of kerogen, which can be converted into liquid and gaseous hydrocarbons (petroleum liquids, natural gas liquids, and methane) by heating the rock, usually in the absence of oxygen, to 650 to 700 degrees Fahrenheit (in situ retorting) or 900 to 950 degrees Fahrenheit (surface retorting). (Oil shale is, strictly speaking, a misnomer in that the rock is not necessarily a shale and contains no crude oil.) The richest U.S. oil shale deposits are located in Northwest Colorado, Northeast Utah, and Southwest Wyoming. Currently, those deposits are the focus of petroleum industry research and potential future production. Among the three states, the richest oil shale deposits are on federal lands in northwest Colorado.

2009-01-01T23:59:59.000Z

399

Beginning of an oil shale industry in Australia  

SciTech Connect (OSTI)

This paper discusses how preparations are being made for the construction and operation of a semi commercial plant to process Australian oil shale. This plant is primarily designed to demonstrate the technical feasibility of processing these shales at low cost. Nevertheless it is expected to generate modest profits even at this demonstration level. This will be the first step in a three staged development of one of the major Australian oil shale deposits which may ultimately provide nearly 10% of Australia's anticipated oil requirements by the end of the century. In turn this development should provide the basis for a full scale oil shale industry in Australia based upon the advantageously disposed oil shale deposits there. New sources of oil are becoming critical since Australian production is declining rapidly while consumption is accelerating.

Wright, B. (Southern Pacific Petroleum NL, 143 Macquarie Street, Sydney (AU))

1989-01-01T23:59:59.000Z

400

Assessment of industry needs for oil shale research and development  

SciTech Connect (OSTI)

Thirty-one industry people were contacted to provide input on oil shale in three subject areas. The first area of discussion dealt with industry's view of the shape of the future oil shale industry; the technology, the costs, the participants, the resources used, etc. It assessed the types and scale of the technologies that will form the industry, and how the US resource will be used. The second subject examined oil shale R D needs and priorities and potential new areas of research. The third area of discussion sought industry comments on what they felt should be the role of the DOE (and in a larger sense the US government) in fostering activities that will lead to a future commercial US oil shale shale industry.

Hackworth, J.H.

1987-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Potential small-scale development of western oil shale  

SciTech Connect (OSTI)

Several studies have been undertaken in an effort to determine ways to enhance development of western oil shale under current market conditions for energy resources. This study includes a review of the commercial potential of western oil shale products and byproducts, a review of retorting processes, an economic evaluation of a small-scale commercial operation, and a description of the environmental requirements of such an operation. Shale oil used as a blend in conventional asphalt appears to have the most potential for entering today's market. Based on present prices for conventional petroleum, other products from oil shale do not appear competitive at this time or will require considerable marketing to establish a position in the marketplace. Other uses for oil shale and spent shale, such as for sulfur sorbtion, power generation, cement, aggregate, and soil stabilization, are limited economically by transportation costs. The three-state area area consisting of Colorado, Utah, and Wyoming seems reasonable for the entry of shale oil-blended asphalt into the commercial market. From a review of retorting technologies and the product characteristics from various retorting processes it was determined that the direct heating Paraho and inclined fluidized-bed processes produce a high proportion of heavy material with a high nitrogen content. The two processes are complementary in that they are each best suited to processing different size ranges of materials. An economic evaluation of a 2000-b/d shale oil facility shows that the operation is potentially viable, if the price obtained for the shale oil residue is in the top range of prices projected for this product. Environmental requirements for building and operating an oil shale processing facility are concerned with permitting, control of emissions and discharges, and monitoring. 62 refs., 6 figs., 10 tabs.

Smith, V.; Renk, R.; Nordin, J.; Chatwin, T.; Harnsberger, M.; Fahy, L.J.; Cha, C.Y.; Smith, E.; Robertson, R.

1989-10-01T23:59:59.000Z

402

C-S-Fe relationships and the isotopic composition of pyrite in the New Albany Shale of the Illinois Basin, USA  

SciTech Connect (OSTI)

The relationship between pyritic sulfur content (S{sub pyr}) and organic carbon content (C{sub org}) of shales analyzed from the New Albany Group depends upon C/{sub org}. For samples of <6 wt.% C{sub org}, S{sub pyr} and C{sub org} are strongly correlated (r = 0.85). For C{sub org}-rich shales (>6 wt.%), no S{sub pyr}-C{sub org} correlation is apparent. The degree of Fe pyritization (DOP) shows similar relationships to C{sub org}. These C-S-Fe relationships suggest that pyrite formation was limited by the availability of metabolizable organic carbon in samples where C{sub org} < 6 wt.% and by the availability of reactive Fe for samples where C{sub org} > 6 wt.%. Apparent sulfur isotope fractionations relative to contemporaneous seawater sulfate ({Delta}{sup 34}S) for pyrite formation average {minus}40 {per thousand} for non-calcareous shales and {minus}25 {per thousand} for calcareous shales. {Delta}{sup 34}S values become smaller with increasing C{sub org}, S{sub pyr}, and DOP for all C{sub org}-poor (<6 wt.%) and some C{sub org}-rich (<6 wt.%) shales. These trends suggest that pyrite formation occurred in a closed system or that instantaneous bacterial fractionation for sulfate reduction decreased in magnitude with increasing organic carbon content. The isotopic trends observed in the New Albany Group are not necessarily representative of other shales having a comparable range of organic carbon content, e.g. Cretaceous shales and mudstones from the western interior of North America. {Delta}{sup 34}S values in the remainder of the C{sub org}-rich New Albany Group shales are relatively large ({minus}38 to {minus}47 {per thousand}) and independent of C{sub org}, S{sub pyr}, and DOP, which suggests that pyrite in these shales formed mostly at or above the sediment-water interface by precipitation from an isotopically uniform reservoir of dissolved H{sub 2}S.

Anderson, T.F.; Kruger, J. (Univ. of Illinois, Urbana (USA)); Raiswell, R. (Leeds Univ. (England))

1987-10-01T23:59:59.000Z

403

Correlations describing the pressurized fluidized-bed hydroretorting carbon conversions of six Eastern oil shales  

SciTech Connect (OSTI)

A set of correlations has been developed to describe the pressurized fluidized-bed hydroretorting carbon conversion of six Eastern oil shales. Laboratory scale fluidized bed and thermogravimetric data were used to relate hydroretorting conditions and organic carbon conversions to oil, gas, and residue. Conversions have been found to depend on temperature, hydrogen pressure, and residence time over the ranges studied of 750 to 865 K, 0 to 7 MPa H{sub 2}, and 0 to 30 minutes, respectively. Gas yield increases with increasing temperature but is independent of changes in hydrogen pressure. Oil yield increases with increasing hydrogen pressure and has different relationships to temperature for the various shales. A single mechanism has been used to describe the carbon conversions of Alabama and Tennessee Chattanooga, Indiana and Kentucky, New Albany, Michigan Antrim, and Ohio Cleveland shales under PFH conditions. The mechanism includes the simultaneous conversion of carbon to gas, oil, and an active carbon species which can form oil or remain as residue carbon. Yields are predicted over the temperature, hydrogen pressure, and residence time ranges used to PFH processing.

Rue, D.M.

1991-01-01T23:59:59.000Z

404

Correlations describing the pressurized fluidized-bed hydroretorting carbon conversions of six Eastern oil shales  

SciTech Connect (OSTI)

A set of correlations has been developed to describe the pressurized fluidized-bed hydroretorting carbon conversion of six Eastern oil shales. Laboratory scale fluidized bed and thermogravimetric data were used to relate hydroretorting conditions and organic carbon conversions to oil, gas, and residue. Conversions have been found to depend on temperature, hydrogen pressure, and residence time over the ranges studied of 750 to 865 K, 0 to 7 MPa H{sub 2}, and 0 to 30 minutes, respectively. Gas yield increases with increasing temperature but is independent of changes in hydrogen pressure. Oil yield increases with increasing hydrogen pressure and has different relationships to temperature for the various shales. A single mechanism has been used to describe the carbon conversions of Alabama and Tennessee Chattanooga, Indiana and Kentucky, New Albany, Michigan Antrim, and Ohio Cleveland shales under PFH conditions. The mechanism includes the simultaneous conversion of carbon to gas, oil, and an active carbon species which can form oil or remain as residue carbon. Yields are predicted over the temperature, hydrogen pressure, and residence time ranges used to PFH processing.

Rue, D.M.

1991-12-31T23:59:59.000Z

405

Environmental research on a modified in situ oil shale task process. Progress report  

SciTech Connect (OSTI)

This report summarizes the progress of the US Department of Energy's Oil Shale Task Force in its research program at the Occidental Oil Shale, Inc. facility at Logan Wash, Colorado. More specifically, the Task Force obtained samples from Retort 3E and Retort 6 and submitted these samples to a variety of analyses. The samples collected included: crude oil (Retort 6); light oil (Retort 6); product water (Retort 6); boiler blowdown (Retort 6); makeup water (Retort 6); mine sump water; groundwater; water from Retorts 1 through 5; retort gas (Retort 6); mine air; mine dust; and spent shale core (Retort 3E). The locations of the sampling points and methods used for collection and storage are discussed in Chapter 2 (Characterization). These samples were then distributed to the various laboratories and universities participating in the Task Force. For convenience in organizing the data, it is useful to group the work into three categories: Characterization, Leaching, and Health Effects. While many samples still have not been analyzed and much of the data remains to be interpreted, there are some preliminary conclusions the Task Force feels will be helpful in defining future needs and establishing priorities. It is important to note that drilling agents other than water were used in the recovery of the core from Retort 3E. These agents have been analyzed (see Table 12 in Chapter 2) for several constituents of interest. As a result some of the analyses of this core sample and leachates must be considered tentative.

Not Available

1980-05-01T23:59:59.000Z

406

Ion chromatographic analysis of oil shale leachates  

SciTech Connect (OSTI)

In the present work an investigation of the use of ion chromatography to determine environmentally significant anions present in oil shale leachates was undertaken. Nadkarni et al. have used ion chromatography to separate and quantify halogen, sulfur and nitrogen species in oil shales after combustion in a Parr bomb. Potts and Potas used ion chromatography to monitor inorganic ions in cooling tower wastewater from coal gasification. Wallace and coworkers have used ion chromatography to determine anions encountered in retort wastewaters. The ions of interest in this work were the ions of sulfur oxides including sulfite (SO{sub 3}{sup 2{minus}}), sulfate (SO{sub 4}{sup 2{minus}}), thiosulfate (S{sub 2}O{sub 3}{sup 2{minus}}), dithionite (S{sub 2}O{sub 4}{sup 2{minus}}), dithionate (S{sub 2}O{sub 6}{sup 2{minus}}), peroxyodisulfate (S{sub 2}O{sub 8}{sup 2{minus}}), and tetrathionate (S{sub 4}O{sub 6}{sup 2{minus}}), and thiocyanate (SCN{sup {minus}}), sulfide (S{sup 2{minus}}) hydrosulfide (HS{sup {minus}}), cyanide (CN{sup {minus}}), thiocyanate (SCN{sup {minus}}), and cyanate (OCN{sup {minus}}). A literature search was completed and a leaching procedure developed. 15 refs., 6 figs., 1 tab.

Butler, N.L.

1990-10-01T23:59:59.000Z

407

A THERMODYNAMICS STUDY ON THE UTILIZATION OF JORDANIAN OIL SHALE IN CEMENT INDUSTRY  

E-Print Network [OSTI]

Oil shale can be utilized in manufacturing the Portland cement. In addition to the utilization of the spent oil shale after combustion, it can also reduce the required temperature for the clinkering reactions. A study on the Jordanian oil shale was performed to maximize the use of oil shale in the

Awni Y. Al-otoom

408

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater  

E-Print Network [OSTI]

Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater Reyad; available online 29 October 2003 Abstract A by-product fly ash from oil shale processing was converted shale; Ash; Zeolite; Cadmium and lead removal 1. Introduction Oil shale exists in Jordan with large

Shawabkeh, Reyad A.

409

Fire and explosion hazards of oil shale. Report of Investigations/1989  

SciTech Connect (OSTI)

This publication presents the results of investigations into the fire and explosion hazards of oil-shale rocks and dust. Three areas were examined: the explosibility and ignitability of oil-shale dust clouds, the fire hazards of oil-shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles.

Not Available

1989-01-01T23:59:59.000Z

410

E-Print Network 3.0 - akinbo shale eastern Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

...29 Eastern Devonian-Mississippian Oil Shale... ... Source: Laughlin, Robert B. - Department of Physics, Stanford University...

411

Potential Economic Impacts of Marcellus Shale in Pennsylvania: Reflections on the Perryman Group Analysis from Texas  

E-Print Network [OSTI]

Potential Economic Impacts of Marcellus Shale in Pennsylvania: Reflections on the Perryman Group The exploration and development of the Marcellus Shale natural gas play has significant potential to affect in the Barnett Shale region of north Texas. The Barnett Shale play is very similar in geology to the Marcellus

Boyer, Elizabeth W.

412

Using Data-Driven Analytics to Assess the Impact of Design Parameters on Production from Shale  

E-Print Network [OSTI]

Shale Esmaili, S., West Virginia University and Mohaghegh, S.D., Intelligent Solution Inc. and West of SPE copyright. Abstract The importance of production from Shale and its impact on the total US energy from Shale assets with different degrees of success. The notion that shale is a "statistical play" may

Mohaghegh, Shahab

413

EXPERIMENT AND NEURAL NETWORK MODEL OF PRIMARY FRAGMENTATION OF OIL SHALE IN FLUIDIZED BED  

E-Print Network [OSTI]

that the fluidized bed temperature is an important factor of primary fragmentation of oil shale, and

Zhigang Cui; Xiangxin Han; Xiumin Jiang; Jianguo Liu

414

Review article Oil and gas wells and their integrity: Implications for shale and  

E-Print Network [OSTI]

Review article Oil and gas wells and their integrity: Implications for shale and unconventional by Elsevier Ltd. 1. Introduction The rapid expansion of shale gas and shale oil exploration and exploitation xxx Keywords: Shale Fracking Integrity Barrier Integrity Wells a b s t r a c t Data from around

Jackson, Robert B.

415

Modeling, History Matching, Forecasting and Analysis of Shale Reservoirs Performance Using Artificial Intelligence  

E-Print Network [OSTI]

matching, forecasting and analyzing oil and gas production in shale reservoirs. In this new approach and analysis of oil and gas production from shale formations. Examples of three case studies in Lower Huron and New Albany shale formations (gas producing) and Bakken Shale (oil producing) is presented

Mohaghegh, Shahab

416

Perform research in process development for hydroretorting of Eastern oil shales: Volume 2, Expansion of the Moving-Bed Hydroretorting Data Base for Eastern oil shales  

SciTech Connect (OSTI)

An extensive data base was developed for six Eastern oil shales: Alabama Chattanooga, Indiana New Albany, Kentucky Sunbury, Michigan Antrim, Ohio Cleveland, and Tennessee Chattanooga shales. The data base included the hydroretorting characteristics of the six shales, as well as the retorting characteristics in the presence of synthesis gas and ionized gas. Shale gasification was also successfully demonstrated. Shale fines (20%) can produce enough hydrogen for the hydroretorting of the remaining 80% of the shale. The amount of fines tolerable in a moving bed was also determined. 16 refs., 59 figs., 43 tabs.

Not Available

1989-11-01T23:59:59.000Z

417

Multi-scale and Integrated Characterization of the Marcellus Shale in the Appalachian Basin: From Microscopes to Mapping  

SciTech Connect (OSTI)

Historic data from the Department of Energy Eastern Gas Shale Project (ESGP) were compiled to develop a database of geochemical analyses, well logs, lithological and natural fracture descriptions from oriented core, and reservoir parameters. The nine EGSP wells were located throughout the Appalachian Basin and intercepted the Marcellus Shale from depths of 750 meters (2500 ft) to 2500 meters (8200 ft). A primary goal of this research is to use these existing data to help construct a geologic framework model of the Marcellus Shale across the basin and link rock properties to gas productivity. In addition to the historic data, x-ray computerized tomography (CT) of entire cores with a voxel resolution of 240mm and optical microscopy to quantify mineral and organic volumes was performed. Porosity and permeability measurements in a high resolution, steady-state flow apparatus are also planned. Earth Vision software was utilized to display and perform volumetric calculations on individual wells, small areas with several horizontal wells, and on a regional basis. The results indicate that the lithologic character of the Marcellus Shale changes across the basin. Gas productivity appears to be influenced by the properties of the organic material and the mineral composition of the rock, local and regional structural features, the current state of in-situ stress, and lithologic controls on the geometry of induced fractures during stimulations. The recoverable gas volume from the Marcellus Shale is variable over the vertical stratigraphic section, as well as laterally across the basin. The results from this study are expected to help improve the assessment of the resource, and help optimize the recovery of natural gas.

Crandall, Dustin; Soeder, Daniel J; McDannell, Kalin T.; Mroz, Thomas

2010-01-01T23:59:59.000Z

418

Fluidized-bed gasification of an eastern oil shale  

SciTech Connect (OSTI)

The current conceptual HYTORT process design for the hydroretorting of oil shales employs moving-bed retorts that utilize shale particles larger than 3 mm. Work at the Institute of Gas Technology (IGT) is in progress to investigate the potential of high-temperature (1100 to 1300 K) fluidized-bed gasification of shale fines (<3 mm size) using steam and oxygen as a technique for more complete utilization of the resource. Synthesis gas produced from fines gasification can be used for making some of the hydrogen needed in the HYTORT process. After completing laboratory-scale batch and continuous gasification tests with several Eastern oil shales, two tests with Indiana New Albany shale were conducted in a 0.2 m diameter fluidized-bed gasification process development unit (PDU). A conceptual gasifier design for 95% carbon conversion was completed. Gasification of 20% of the mined shale can produce the hydrogen required by the HYTORT reactor to retort 80% of the remaining shale. 12 refs., 1 fig., 5 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-01-01T23:59:59.000Z

419

Status of LLNL Hot-Recycled-Solid oil shale retort  

SciTech Connect (OSTI)

We have investigated the technical and economic barriers facing the introduction of an oil shale industry and we have chosen Hot-Recycled-Solid (HRS) oil shale retorting as the primary advanced technology of interest. We are investigating this approach through fundamental research, operation of a 4 tonne-per-day, HRS pilot plant and development of an Oil Shale Process (OSP) mathematical model. Over the last three years, from June 1991 to June 1993, we completed a series of runs (H10--H27) using the 4-TPD pilot plant to demonstrate the technical feasibility of the HRS process and answer key scale-up questions. With our CRADA partners, we seek to further develop the HRS technology, maintain and enhance the knowledge base gained over the past two decades through research and development by Government and industry and determine the follow on steps needed to advance the technology towards commercialization. The LLNL Hot-Recycled-Solid process has the potential to improve existing oil shale technology. It processes oil shale in minutes instead of hours, reducing plant size. It processes all oil shale, including fines rejected by other processes. It provides controls to optimize product quality for different applications. It co-generates electricity to maximize useful energy output. And, it produces negligible SO{sub 2} and NO{sub x} emissions, a non-hazardous waste shale and uses minimal water.

Baldwin, D.E.; Cena, R.J.

1993-12-31T23:59:59.000Z

420

Industrial hygiene aspects of underground oil shale mining  

SciTech Connect (OSTI)

Health hazards associated with underground oil shale mining are summarized in this report. Commercial oil shale mining will be conducted on a very large scale. Conventional mining techniques of drilling, blasting, mucking, loading, scaling, and roof bolting will be employed. Room-and-pillar mining will be utilized in most mines, but mining in support of MIS retorting may also be conducted. Potential health hazards to miners may include exposure to oil shale dusts, diesel exhaust, blasting products, gases released from the oil shale or mine water, noise and vibration, and poor environmental conditions. Mining in support of MIS retorting may in addition include potential exposure to oil shale retort offgases and retort liquid products. Based upon the very limited industrial hygiene surveys and sampling in experimental oil shale mines, it does not appear that oil shale mining will result in special or unique health hazards. Further animal toxicity testing data could result in reassessment if findings are unusual. Sufficient information is available to indicate that controls for dust will be required in most mining activities, ventilation will be necessary to carry away gases and vapors from blasting and diesel equipment, and a combination of engineering controls and personal protection will likely be required for control of noise. Recommendations for future research are included.

Hargis, K.M.; Jackson, J.O.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Evaluation of physical-chemical and biological treatment of shale oil retort water  

SciTech Connect (OSTI)

Bench scale studies were conducted to evaluate conventional physical-chemical and biological treatment processes for removal of pollutants from retort water produced by in situ shale oil recovery methods. Prior to undertaking these studies, very little information had been reported on treatment of retort water. A treatment process train patterned after that generally used throughout the petroleum refining industry was envisioned for application to retort water. The treatment train would consist of processes for removing suspended matter, ammonia, biodegradable organics, and nonbiodegradable or refractory organics. The treatment processes evaluated include anaerobic digestion and activated sludge for removal of biodegradable organics and other oxidizable substances; activated carbon adsorption for removal of nonbiodegradable organics; steam stripping for ammonia removal; and chemical coagulation, sedimentation and filtration for removal of suspended matter. Preliminary cost estimates are provided.

Mercer, B.W.; Mason, M.J.; Spencer, R.R.; Wong, A.L.; Wakamiya, W.

1982-09-01T23:59:59.000Z

422

Oil shale quarterly report, August--December 1990  

SciTech Connect (OSTI)

This paper contains four status reports on the following oil shale research projects: (1) Lawrence Livermore National Laboratory 4-tonne-per-day pilot plant; (2) chemistry and kinetics of New Albany shale flash pyrolysis under Hot-Recycled-Solid (HRS) conditions; (3) modeling of shale oil cracking and coking in the HRS process; and (4) modeling and analysis of particle slip and drag in a lift pipe of the retort for the HRS process. Each project report has been indexed separately for inclusion on the data base. (CK)

Cena, R.

1991-02-15T23:59:59.000Z

423

Characterization of nitrogen compound types in hydrotreated Paraho shale oil  

SciTech Connect (OSTI)

Results from the separation and characterization of nitrogen compound types in hydrotreated Paraho shale oil samples were obtained. Two samples of Paraho shale oil were hydrotreated by Chevron Research Company such that one sample contained about 0.05 wt. percent nitrogen and the other sample contained about 0.10 wt. percent nitrogen. A separation method concentrate specific nitrogen compound types was developed. Characterization of the nitrogen types was accomplished by infrared spectroscopy, mass spectrometry, potentiometric titration, and elemental analysis. The distribution of nitrogen compound types in both samples and in the Paraho crude shale oil is compared.

Holmes, S.A.; Latham, D.R.

1980-10-01T23:59:59.000Z

424

Pyrolysis of shale oil residual fractions  

SciTech Connect (OSTI)

The freezing point of JP-5, the Navy jet fuel, has been related to the n-alkane content, specifically n-hexadecane. In general, jet fuels from shale oil have the highest n-alkanes. The formation of n-alkanes in the jet fuel distillation range can be explained if large n-alkanes are present in the crude oil source. Quantities of large n-alkanes are insufficient, however, to explain the amounts found - up to 37% n-alkanes in the jet fuel range. Other possible precursors to small straight chain molecules are substituted cyclic compounds. Attack in the side chain obviously afford a path to an n-alkane. Aromatic hydrocarbons, esters, acids, amines, and ethers also have the potential to form n-alkanes if an unbranched alkyl chain is present in the molecule. Investigations showed that the best yield of the JP-5 cut comes at different times for the various fractions, but a time in the 60 to 120 min range would appear to be the optimum time for good yield at 450/sup 0/C. The longer time would be preferred with respect to lower potential n-alkane yield. None of the fractions gave n-alkane yields approaching the 37% amount found in the Shale-I JP-5. A temperature different than the 450/sup 0/C used here might affect the conversion percentage. Further the combined saturate, aromatic, and polar fractions may interact under pyrolysis conditions to give higher potential n-alkane yields than the fractions stressed independently.

Hazlett, R.N.; Beal, E.; Vetter, T.; Sonntag, R.; Moniz, W.

1980-01-01T23:59:59.000Z

425

Comparison of Emperical Decline Curve Analysis for Shale Wells  

E-Print Network [OSTI]

This study compares four recently developed decline curve methods and the traditional Arps or Fetkovich approach. The four methods which are empirically formulated for shale and tight gas wells are: 1. Power Law Exponential Decline (PLE). 2...

Kanfar, Mohammed Sami

2013-07-13T23:59:59.000Z

426

90-day Interim Report on Shale Gas Production - Secretary of...  

Broader source: Energy.gov (indexed) [DOE]

reduce the environmental impact and improve the safety of shale gas production. Natural gas is a cornerstone of the U.S. economy, providing a quarter of the country's total...

427

La Revolucin del Shale Gas Profesor: Hugh Rudnick  

E-Print Network [OSTI]

................................ 36 Impacto / Preocupación Ambiental...................................................................................... 38 Impacto Ambiental en los Procesos de Extracción del Shale Gas.................................................................................................................. 11 Impacto en las Reservas Mundiales de Gas y Proyecciones Relevantes

Rudnick, Hugh

428

Economic analysis of shale gas wells in the United States  

E-Print Network [OSTI]

Natural gas produced from shale formations has increased dramatically in the past decade and has altered the oil and gas industry greatly. The use of horizontal drilling and hydraulic fracturing has enabled the production ...

Hammond, Christopher D. (Christopher Daniel)

2013-01-01T23:59:59.000Z

429

Implications of the U.S. Shale Revolution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Implications of the U.S. Shale Revolution For US-Canada Energy Summit October 17, 2014 | Chicago, IL By Adam Sieminski, Administrator U.S. Energy Information Administration 0 5 10...

430

The U.S. Natural Gas and Shale Production Outlook  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Gas and Shale Production Outlook for North American Gas Forum September 29, 2014 by Adam Sieminski, Administrator The U.S. has experienced a rapid increase in natural gas...

431

West Lothian Biodiversity Action Plan: Oil Shale Bings  

E-Print Network [OSTI]

This report establishes the importance of the West Lothian oil-shale bings at both a national (UK) and local (West Lothian) scale, for their contribution to local biodiversity, their historical importance, their education ...

Harvie, Barbra

2005-01-01T23:59:59.000Z

432

Oil shale and coal in intermontane basins of Thailand  

SciTech Connect (OSTI)

The Mae Tip intermontane basin contains Cenozoic oil shales in beds up to 1 m (3.3 ft) thick interbedded with coal and mudstone. The oil shales contain lamosite-type alginite, and give a maximum oil yield of 122 L/MT (29.3 gal/ton). The beds are laterally continuous for at least 1.5 km (1.0 mi), but pass into mudstones toward the basin margin. The oil shales originated when peat swamps close to a steep basin margin were flooded by shallow lakes, allowing algae to replace rooted vegetation. This distinctive oil shale-coal assemblage is known from many small intermontane basins in Thailand, where locally high geothermal gradients suggest potential for hydrocarbons.

Gibling, M.R.; Srisuk, S.; Ukakimaphan, Y.

1985-05-01T23:59:59.000Z

433

Forecasting long-term gas production from shale  

E-Print Network [OSTI]

Oil and natural gas from deep shale formations are transforming the United States economy and its energy outlook. Back in 2005, the US Energy Information Administration published projections of United States natural gas ...

Cueto-Felgueroso, Luis

434

Assessment of Eagle Ford Shale Oil and Gas Resources  

E-Print Network [OSTI]

, and to assess Eagle Ford shale oil and gas reserves, contingent resources, and prospective resources. I first developed a Bayesian methodology to generate probabilistic decline curves using Markov Chain Monte Carlo (MCMC) that can quantify the reserves...

Gong, Xinglai

2013-07-30T23:59:59.000Z

435

STUDY COMMISSIONED BY WEST LOTHIAN COUNCIL OIL-SHALE BINGS  

E-Print Network [OSTI]

#12;STUDY COMMISSIONED BY WEST LOTHIAN COUNCIL OIL-SHALE BINGS Dr Barbra Harvie School of Geo.....................................................................................................3 The birth of the oil industry ...........................................................................................................................3 The impact of oil on society

436

Cyclone oil shale retorting concept. [Use it all retorting process  

SciTech Connect (OSTI)

A new concept for above-ground retorting of oil shale was disclosed by A.E. Harak in US Patent No. 4,340,463, dated July 20, 1982, and assigned to the US Department of Energy. This patent titled System for Utilizing Oil Shale Fines, describes a process wherein oil shale fines of one-half inch diameter and less are pyrolyzed in an entrained-flow reactor using hot gas from a cyclone combustor. Spent shale and supplemental fuel are burned at slagging conditions in this combustor. Because of fines utilization, the designation Use It All Retorting Process (UIARP) has been adopted. A preliminary process engineering design of the UIARP, analytical tests on six samples of raw oil shale, and a preliminary technical and economic evaluation of the process were performed. The results of these investigations are summarized in this report. The patent description is included. It was concluded that such changes as deleting air preheating in the slag quench and replacing the condenser with a quench-oil scrubber are recognized as being essential. The addition of an entrained flow raw shale preheater ahead of the cyclone retort is probably required, but final acceptance is felt to be contingent on some verification that adequate reaction time cannot be obtained with only the cyclone, or possibly some other twin-cyclone configuration. Sufficient raw shale preheating could probably be done more simply in another manner, perhaps in a screw conveyor shale transporting system. Results of the technical and economic evaluations of Jacobs Engineering indicate that further investigation of the UIARP is definitely worthwhile. The projected capital and operating costs are competitive with costs of other processes as long as electric power generation and sales are part of the processing facility.

Harak, A.E.; Little, W.E.; Faulders, C.R.

1984-04-01T23:59:59.000Z

437

Thermal decomposition of Colorado and Kentucky reference oil shales  

SciTech Connect (OSTI)

Isothermal pyrolysis studies have been conducted on a Green River Formation oil shale from Colorado and a New Albany oil shale from Kentucky. The conversion of kerogen to bitumen, oil, gas, and residue products was obtained for different isothermal reaction times in the temperature range of 375/degree/C to 440/degree/C (707/degree/ to 824/degree/F) using a heated sand bath reactor system. Particular attention was paid to the formation of the bitumen intermediate during decomposition of the two shales. The maximum amount of extractable bitumen in the New Albany shale was 14% or less of the original kerogen at any given temperature, indicating that direct conversion of kerogen to oil, gas, and residue products is a major pathway of conversion of this shale during pyrolysis. In contrast, a significant fraction of the Colorado oil shale kerogen was converted to the intermediate bitumen during pyrolysis. The bitumen data imply that the formation of soluble intermediates may depend on original kerogen structure and may be necessary for producing high yields by pyrolysis. 24 refs., 14 figs., 8 tabs.

Miknis, F.P.; Turner, T.F.; Ennen, L.W.; Chong, S.L.; Glaser, R.

1988-06-01T23:59:59.000Z

438

Life-cycle analysis of shale gas and natural gas.  

SciTech Connect (OSTI)

The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M. (Energy Systems); ( EVS)

2012-01-27T23:59:59.000Z

439

Technology experience and economics of oil shale mining in Estonia  

SciTech Connect (OSTI)

The exhaustion of fuel-energy resources became an evident problem of the European continent in the 1960s. Careful utilization of their own reserves of coal, oil, and gas (Germany, France, Spain) and assigned shares of imports of these resources make up the strategy of economic development of the European countries. The expansion of oil shale utilization is the most topical problem. The experience of mining oil shale deposits in Estonia and Russia, in terms of the practice and the economic results, is reviewed in this article. The room-and-pillar method of underground mining and the open-cut technology of clearing the ground ensure the fertility of a soil. The economics of underground and open pit oil shale mines is analyzed in terms of natural, organizational, and technical factors. These analyses are used in the planning and management of oil shale mining enterprises. The perspectives of the oil shale mining industry of Estonia and the economic expediency of multiproduction are examined. Recommendations and guidelines for future industrial utilization of oil shale are given in the summary.

Fraiman, J.; Kuzmiv, I. [Estonian Oil Shale State Co., Jyhvi (Estonia). Scientific Research Center

1995-11-01T23:59:59.000Z

440

Slow Radio-Frequency Processing of Large Oil Shale Volumes to Produce Petroleum-Like Shale Oil  

SciTech Connect (OSTI)

A process is proposed to convert oil shale by radio frequency heating over a period of months to years to create a product similar to natural petroleum. Electrodes would be placed in drill holes, either vertical or horizontal, and a radio frequency chosen so that the penetration depth of the radio waves is of the order of tens to hundreds of meters. A combination of excess volume production and overburden compaction drives the oil and gas from the shale into the drill holes, where it is pumped to the surface. Electrical energy for the process could be provided initially by excess regional capacity, especially off-peak power, which would generate {approx}3 x 10{sup 5} bbl/day of synthetic crude oil, depending on shale grade. The electricity cost, using conservative efficiency assumptions, is $4.70 to $6.30/bbl, depending on grade and heating rate. At steady state, co-produced gas can generate more than half the electric power needed for the process, with the fraction depending on oil shale grade. This would increase production to 7.3 x 10{sup 5} bbl/day for 104 l/Mg shale and 1.6 x 10{sup 6} bbl/day for 146 l/Mg shale using a combination of off-peak power and power from co-produced gas.

Burnham, A K

2003-08-20T23:59:59.000Z

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

retorted and wet with oil, and shale sections 18 through 24V. , 1979, Analysis of oil shale of products and effluents:In- Situ Retorting of Oil Shale in a Controlled- State

Fox, J. P.

2011-01-01T23:59:59.000Z

442

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

V. , 1979, Analysis of oil shale of products and effluents:In- Situ Retorting of Oil Shale in a Controlled- Stateactivation: Archaeometry, oil-shale analysis v. 11, p.

Fox, J. P.

2011-01-01T23:59:59.000Z

443

FreezeFrac Improves the Productivity of Gas Shales S. Enayatpour, E. Van Oort, T. Patzek, University of Texas At Austin  

E-Print Network [OSTI]

to unconventional hydrocarbon reservers such as oil shales, gas shales, tight gas sands, coalbed methane, and gas

Patzek, Tadeusz W.

444

Pressurized fluidized-bed hydroretorting of Eastern oil shales  

SciTech Connect (OSTI)

The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S. (Institute of Gas Technology, Chicago, IL (United States)); Schultz, C.W. (Alabama Univ., University, AL (United States)); Parekh, B.K. (Kentucky Univ., Lexington, KY (United States)); Misra, M. (Nevada Univ., Reno, NV (United States)); Bonner, W.P. (Tennessee Technological Univ., Cookeville, TN (United States))

1992-11-01T23:59:59.000Z

445

WOGOGOB-2004 CONFERENCE MATERIALS. Edited by O. Hints & L. Ainsaar During Kukruse (Caradoc) time, light-brown organ-  

E-Print Network [OSTI]

ic matter forming oil shale interlayers in calcareous sediments accumulated in the Baltoscandian Basin (Nestor & Einasto 1997). The oil shale is composed of almost equal portions of carbonate, and clayey siliciclastic and organic matter. The existence of a rich and diverse normal marine bottom

unknown authors

446

An Application of Sequence Stratigraphy in Modelling Oil Yield Distribution: The Stuart Oil Shale Deposit, Queensland, Australia.  

E-Print Network [OSTI]

??The Stuart Oil Shale Deposit is a major oil shale resource located near Gladstone on the central Queensland coast. It contains an estimated 3.0 billion (more)

Pope, Graham John

2005-01-01T23:59:59.000Z

447

Gasification characteristics and kinetics for an Eastern oil shale  

SciTech Connect (OSTI)

Gasification reactivity of an Eastern oil shale was studied in a three-year research project under a cooperative agreement between the Department of Energy, Morgantown Energy Technology Center, and HYCRUDE Corp. to expand the data base on the hydroretorting of Eastern oil shales. Gasification tests were conducted with the Indiana New Albany oil shale during the first year of the program. A total of six Eastern oil shales are planned to be tested during the program. A laboratory thermobalance and a 2-inch diameter fluidized bed were used to conduct gasification tests with Indiana New Albany oil shale. Temperature and pressure ranges used were 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Fifteen thermobalance tests were made in hydrogen/steam and synthesis gas/steam mixtures. Six fluidized-bed tests were made in the same synthesis gas/steam mixture. Carbon conversions as high as 95% were achieved. Thermobalance test results and a kinetic description of weight loss during hydrogen/steam gasification are presented. 14 refs., 6 figs., 4 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-01-01T23:59:59.000Z

448

Office of Naval Petroleum and Oil Shale Reserves  

E-Print Network [OSTI]

Worldwide supplies of conventional oil will soon reach a peak production rate and begin an irreversible long-term decline. Options to augment liquid fuel supplies in the United States have once again begun to focus on oil shale as long-term source of reliable, affordable, and secure oil. The United States government has long recognized the strategic potential of the nations vast oil shale resources to support national security. President Taft in 1912 established an Office of Naval Petroleum and Oil Shale Reserves and charged that office with ensuring oil for naval military operations. This office continues to oversee the United States strategic interest in oil shale. Americas 2 trillion barrel oil shale resource is recognized as having the same production potential as Canadas tar sands. Tar sand production, initiated in the 1960s, has increased steadily to more than 1 million per barrels/day and is moving toward a near-term goal of 2.5 million barrels per day by 2017. This amount of oil is equivalent to the volume of oil currently imported by the United States from Middle East countries. Tar sands production has enabled Canada to add 174 billion barrels to its recoverable oil reserves, making Canadas proved reserves second only to those of Saudi Arabia.

unknown authors

449

Shale oil recovery systems incorporating ore beneficiation : final report, October 1982  

E-Print Network [OSTI]

This study analyzed the recovery of oil from oil shale by use of proposed systems which incorporate beneficiation of the shale ore (that is, concentration of the kerogen) before the oil-recovery step. The objective was to ...

Weiss, M. A.

1982-01-01T23:59:59.000Z

450

Complex conductivity tensor of anisotropic hydrocarbon-1 bearing shales and mudrocks2  

E-Print Network [OSTI]

to describe seismic and electromagnetic (EM) measurements in these anisotropic54 materials.55 Oil-shale to release their hydrocarbons. Hence, oil shales and58 mudrocks are typically water-wet, single- or dual

Torres-Verdín, Carlos

451

OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

Holes from the Naval Oil Shale Reserve No. 1 R. D. Giauque,all of the known oil and gas reserves in the United States.cores from the Naval Oil Shale Reserve No. 1 were sectioned

,

2012-01-01T23:59:59.000Z

452

The Effect of Proppant Size and Concentration on Hydraulic Fracture Conductivity in Shale Reservoirs  

E-Print Network [OSTI]

Hydraulic fracture conductivity in ultra-low permeability shale reservoirs is directly related to well productivity. The main goal of hydraulic fracturing in shale formations is to create a network of conductive pathways in the rock which increase...

Kamenov, Anton

2013-04-11T23:59:59.000Z

453

Assessing the mechanical microstructure of shale by nanoindentation : the link between mineral composition and mechanical properties  

E-Print Network [OSTI]

Shale is a multi-phase, multi-scale sedimentary rock that makes up 75% of the earth's sedimentary basins and is especially critical in petroleum engineering applications. At macroscopic scales, shales possess a diverse set ...

Bobko, Christopher Philip, 1981-

2008-01-01T23:59:59.000Z

454

INTERCOMPARISON STUDY OF ELEMENTAL ABUNDANCES IN RAW AND SPENT OIL SHALES  

E-Print Network [OSTI]

W. A. Robb, and T. J. Spedding. Minor Elements ~n Oil Shaleand Oil-Shale Products. LERC RI-77/1, 1977. Wildeman, T. R.H. Meglen. The Analysis of Oil-Shale Materials for Element

Fox, J.P.

2011-01-01T23:59:59.000Z

455

E-Print Network 3.0 - antrim shales Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interior U.S. Geological Survey Summary: -5294 Geology and Resources of Some World Oil-Shale Deposits 12;Cover. Left: New Paraho Co. experimental oil... shale retort in the...

456

USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES  

E-Print Network [OSTI]

W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil-Shale Products. LERC RI 77-1, 1977. Bertine, K. K.From A Simulated In-Situ Oil Shale Retort. In: Procedings of

Girvin, D.G.

2011-01-01T23:59:59.000Z

457

E-Print Network 3.0 - albany shale kentucky Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interior U.S. Geological Survey Summary: -5294 Geology and Resources of Some World Oil-Shale Deposits 12;Cover. Left: New Paraho Co. experimental oil... shale retort in the...

458

Examination of eastern oil shale disposal problems - the Hope Creek field study  

SciTech Connect (OSTI)

A field-based study of problems associated with the disposal of processed Eastern oil shale was initiated in mid-1983 at a private research site in Montgomery County, Kentucky. The study (known as the Hope Creek Spent Oil Shale Disposal Project) is designed to provide information on the geotechnical, revegetation/reclamation, and leachate generation and composition characteristics of processed Kentucky oil shales. The study utilizes processed oil shale materials (retorted oil shale and reject raw oil shale fines) obtained from a pilot plant run of Kentucky oil shale using the travelling grate retort technology. Approximately 1000 tons of processed oil shale were returned to Kentucky for the purpose of the study. The study, composed of three components, is described. The effort to date has concentrated on site preparation and the construction and implementation of the field study research facilities. These endeavors are described and the project direction in the future years is defined.

Koppenaal, D.W.; Kruspe, R.R.; Robl, T.L.; Cisler, K.; Allen, D.L.

1985-02-01T23:59:59.000Z

459

Plan and justification for a Proof-of-Concept oil shale facility. Final report  

SciTech Connect (OSTI)

The technology being evaluated is the Modified In-Situ (MIS) retorting process for raw shale oil production, combined with a Circulating Fluidized Bed Combustor (CFBC), for the recovery of energy from the mined shale. (VC)

Not Available

1990-12-01T23:59:59.000Z

460

E-Print Network 3.0 - afforested oil-shale mining Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oil-shale mining Search Powered by Explorit Topic List Advanced Search Sample search results for: afforested oil-shale mining Page: << < 1 2 3 4 5 > >> 1 The chemistry of minerals...

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

INTERLABORATORY, MULTIMETHOD STUDY OF AN IN SITU PRODUCED OIL SHALE PROCESS WATER  

E-Print Network [OSTI]

W. A. Robb, and T. J. Spedding. Minor Elements in Oil Shaleand Oil Shale Products. LERC Rept. of Invest. 77-1, 1977.Significant to In Situ Oil Shale Processing. Quart. Colo.

Farrier, D.S.

2011-01-01T23:59:59.000Z

462

Pressure Transient Analysis and Production Analysis for New Albany Shale Gas Wells  

E-Print Network [OSTI]

and approaches special for estimating rate decline and recovery of shale gas wells were developed. As the strategy of the horizontal well with multiple transverse fractures (MTFHW) was discovered and its significance to economic shale gas production...

Song, Bo

2010-10-12T23:59:59.000Z

463

Evidence of Pressure Dependent Permeability in Long-Term Shale Gas Production and Pressure Transient Responses  

E-Print Network [OSTI]

The current state of shale gas reservoir dynamics demands understanding long-term production, and existing models that address important parameters like fracture half-length, permeability, and stimulated shale volume assume constant permeability...

Vera Rosales, Fabian 1986-

2012-12-11T23:59:59.000Z

464

Plan and justification for a Proof-of-Concept oil shale facility  

SciTech Connect (OSTI)

The technology being evaluated is the Modified In-Situ (MIS) retorting process for raw shale oil production, combined with a Circulating Fluidized Bed Combustor (CFBC), for the recovery of energy from the mined shale. (VC)

Not Available

1990-12-01T23:59:59.000Z

465

TURKISH OIL SHALES POTENTIAL FOR SYNTHETIC CRUDE OIL and CARBON MATERIALS PRODUCTION  

E-Print Network [OSTI]

research activities on solid fuels. In order to make a new start, research work on Turkish oil shales that

Ekrem Ekinci

466

The use of Devonian oil shales in the production of portland cement  

SciTech Connect (OSTI)

The Lafarge Corporation operates a cement plant at Alpena, Michigan in which Antrim shale, a Devonian oil shale, is used as part of the raw material mix. Using this precedent the authors examine the conditions and extent to which spent shale might be utilized in cement production. They conclude that the potential is limited in size and location but could provide substantial benefit to an oil shale operation meeting these criteria.

Schultz, C.W.; Lamont, W.E. [Alabama Univ., University, AL (United States); Daniel, J. [Lafarge Corp., Alpena, MI (United States)

1991-12-31T23:59:59.000Z

467

Cancer Patterns in the Oil Shale Area of the Estonian S.S.R.  

E-Print Network [OSTI]

the Kohtla-Jarve district (oil shale area) there was an excess of stomach and lung cancer. High rates

Maret Purde; Mati Rahu

468

Secure Fuels from Domestic Resources The Continuing Evolution of Americas Oil Shale and Tar  

E-Print Network [OSTI]

domestic oil shale and tar sands industries since the first release and to include profiles of additional

Sands Industries

469

Generic Argillite/Shale Disposal Reference Case  

SciTech Connect (OSTI)

Radioactive waste disposal in a deep subsurface repository hosted in clay/shale/argillite is a subject of widespread interest given the desirable isolation properties, geochemically reduced conditions, and widespread geologic occurrence of this rock type (Hansen 2010; Bianchi et al. 2013). Bianchi et al. (2013) provides a description of diffusion in a clay-hosted repository based on single-phase flow and full saturation using parametric data from documented studies in Europe (e.g., ANDRA 2005). The predominance of diffusive transport and sorption phenomena in this clay media are key attributes to impede radionuclide mobility making clay rock formations target sites for disposal of high-level radioactive waste. The reports by Hansen et al. (2010) and those from numerous studies in clay-hosted underground research laboratories (URLs) in Belgium, France and Switzerland outline the extensive scientific knowledge obtained to assess long-term clay/shale/argillite repository isolation performance of nuclear waste. In the past several years under the UFDC, various kinds of models have been developed for argillite repository to demonstrate the model capability, understand the spatial and temporal alteration of the repository, and evaluate different scenarios. These models include the coupled Thermal-Hydrological-Mechanical (THM) and Thermal-Hydrological-Mechanical-Chemical (THMC) models (e.g. Liu et al. 2013; Rutqvist et al. 2014a, Zheng et al. 2014a) that focus on THMC processes in the Engineered Barrier System (EBS) bentonite and argillite host hock, the large scale hydrogeologic model (Bianchi et al. 2014) that investigates the hydraulic connection between an emplacement drift and surrounding hydrogeological units, and Disposal Systems Evaluation Framework (DSEF) models (Greenberg et al. 2013) that evaluate thermal evolution in the host rock approximated as a thermal conduction process to facilitate the analysis of design options. However, the assumptions and the properties (parameters) used in these models are different, which not only make inter-model comparisons difficult, but also compromise the applicability of the lessons learned from one model to another model. The establishment of a reference case would therefore be helpful to set up a baseline for model development. A generic salt repository reference case was developed in Freeze et al. (2013) and the generic argillite repository reference case is presented in this report. The definition of a reference case requires the characterization of the waste inventory, waste form, waste package, repository layout, EBS backfill, host rock, and biosphere. This report mainly documents the processes in EBS bentonite and host rock that are potentially important for performance assessment and properties that are needed to describe these processes, with brief description other components such as waste inventory, waste form, waste package, repository layout, aquifer, and biosphere. A thorough description of the generic argillite repository reference case will be given in Jov Colon et al. (2014).

Zheng, Liange; Jov& #233; Colon, Carlos; Bianchi, Marco; Birkholzer, Jens

2014-08-08T23:59:59.000Z

470

Evaluation of Devonian-shale potential in Ohio  

SciTech Connect (OSTI)

The purpose of this report is to inform interested oil and gas operators about EGSP results as they pertain to the Devonian gas shales of the Appalachian basin in eastern Ohio. Geologic data and interpretations are summarized, and areas where the accumulation of gas may be large enough to justify commercial production are outlined. Because the data presented in this report are generalized and not suitable for evaluation of specific sites for exploration, the reader should consult the various reports cited for more detail and discussion of the data, concepts, and interpretations presented. A complete list of EGSP sponsored work pertinent to the Devonian shales in Ohio is contained as an appendix to this report. Radioactive shale zones are also mapped.

Not Available

1981-01-01T23:59:59.000Z

471

Wastewater treatment in the oil-shale industry  

SciTech Connect (OSTI)

Because of the stringent state and federal standards governing the discharge of wastes into local waters and the limited water supplies in this area, an oil shale industry will probably reuse process effluents to the maximum extent possible and evaporate the residuals. Therefore, discharge of effluents into surface and ground waters may not be necessary. This paper reviews the subject of wastewater treatment for an oil shale industry and identifies key issues and research priorities that must be resolved before a large-scale commercial industry can be developed. It focuses on treatment of the waters unique to an oil shale industry: retort water, gas condensate, and mine water. Each presents a unique set of challenges.

Fox, J.P.; Phillips, T.E.

1980-08-01T23:59:59.000Z

472

Private Water Well Testing in Areas Impacted by Marcellus Shale Gas Drilling  

E-Print Network [OSTI]

Private Water Well Testing in Areas Impacted by Marcellus Shale Gas Drilling (Updated November 15th in the absence of shale-gas drilling, well owners are strongly encouraged to evaluate their water on a regular review of shale gas drilling in New York State, as well as the most comprehensive collection of data

Manning, Sturt

473

DOE oil shale reference sample bank: Quarterly report, July-September 1987  

SciTech Connect (OSTI)

The DOE Oil Shale Program was restructured in FY84 to implement a 5-year period of basic and applied research in the study of the phenomena involved in oil shale pyrolysis/retorting. The program calls for the study of two reference shales per year for a period of 5 years. Consequently, the program calls for the identification, acquisition, processing, characterization, storage, disbursement, and record keeping for ten reference shales in a period of 5 years. Two FY86 and one FY87 reference shales have been acquired, processed and stored under inert gas. The Eastern shale, designated E86, was obtained from the Clegg Creek Member of the New Albany Shale at a quarry near Louisville, Kentucky in the first quarter of FY86. The FY86 Western Shale was obtained from the Exxon Colony Mine, located near Parachute, Colorado, during the first quarter of FY86. The FY87 Western Shale was obtained from the Tipton Member of the Green River Formation near Rock Springs, Wyoming during the fourth quarter of FY87. Partial distributions of the FY86 shale have been made to DOE and non-DOE contractors. Complete descriptions of the FY87 Western reference shale locale, shale processing procedures and analytical characterization are provided in this report. 7 refs., 6 figs., 1 tab.

Owen, L.B.

1987-09-01T23:59:59.000Z

474

WATER USE IN LCA Life cycle consumptive water use for oil shale development  

E-Print Network [OSTI]

WATER USE IN LCA Life cycle consumptive water use for oil shale development and implications Heidelberg 2013 Abstract Purpose Oil shale is an unconventional petroleum source that can be produced domestically in the USA. Oil shale resources are primarily located in Utah, Wyoming, and Colorado, within

Jaramillo, Paulina

475

Synthesis and characterization of activated carbo-aluminosilicate material from oil shale  

E-Print Network [OSTI]

Synthesis and characterization of activated carbo-aluminosilicate material from oil shale Reyad activated carbo-aluminosilicate materials were prepared from oil shale by chemical activation. The chemical Published by Elsevier Inc. Keywords: Synthesis; Activated carbo-aluminosilicate; Adsorption; Oil shale

Shawabkeh, Reyad A.

476

Lake Level Controlled Sedimentological I Heterogenity of Oil Shale, Upper Green River  

E-Print Network [OSTI]

Chapter 3 Lake Level Controlled Sedimentological 1:'_i 'I I Heterogenity of Oil Shale, Upper Green email: mgani@uno.edu t",. The Green River Formation comprises the world's largest deposit of oil-shale characterization of these lacustrine oil-shale deposits in the subsurface is lacking. This study analyzed ~300 m

Gani, M. Royhan

477

NBER WORKING PAPER SERIES THE HOUSING MARKET IMPACTS OF SHALE GAS DEVELOPMENT  

E-Print Network [OSTI]

NBER WORKING PAPER SERIES THE HOUSING MARKET IMPACTS OF SHALE GAS DEVELOPMENT Lucija Muehlenbachs © notice, is given to the source. #12;The Housing Market Impacts of Shale Gas Development Lucija to control for confounding factors, we recover hedonic estimates of property value impacts from shale gas

Habib, Ayman

478

Lagrangian Relaxation Based Decompositon for Well Scheduling in Shale-gas Systems  

E-Print Network [OSTI]

Lagrangian Relaxation Based Decompositon for Well Scheduling in Shale-gas Systems Brage Rugstad of mid and late-life wells in shale-gas systems. This state of the wells can be prevented by performing. In this paper, we present a Lagrangian relaxation based scheme for shut-in scheduling of distributed shale multi

Grossmann, Ignacio E.

479

Oscillator or Segal-Shale-Weil representation Geometry: Associating the oscillator to symplectic manifolds  

E-Print Network [OSTI]

C -algebras Oscillator or Segal-Shale-Weil representation Geometry: Associating the oscillator or Segal-Shale-Weil representation Geometry: Associating the oscillator to symplectic manifolds Global and (x) = 0 implies x = 0 2 S. Krýsl #12;C -algebras Oscillator or Segal-Shale-Weil representation

Krysl, Svatopluk

480

Strategic Planning, Design and Development of the Shale Gas Supply Chain Network  

E-Print Network [OSTI]

1 Strategic Planning, Design and Development of the Shale Gas Supply Chain Network Diego C. Cafaro1-term planning of the shale gas supply chain is a relevant problem that has not been addressed before Shale gas, supply chain, strategic planning, MINLP, solution algorithm * Corresponding author. Tel.: +1

Grossmann, Ignacio E.

Note: This page contains sample records for the topic "organic black shale" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Numerical Simulation and Multiple Realizations for Sensitivity Study of Shale Gas Reservoir  

E-Print Network [OSTI]

SPE 141058 Numerical Simulation and Multiple Realizations for Sensitivity Study of Shale Gas. The abstract must contain conspicuous acknowledgment of SPE copyright. Abstract Shale gas in the United States the largest conventional gas accumulations in the world. Shale gas success is directly the result

Mohaghegh, Shahab

482

ANALYSIS OF GAS PRODUCTION FROM HYDRAULICALLY FRACTURED WELLS IN THE HAYNESVILLE SHALE USING SCALING METHODS  

E-Print Network [OSTI]

ANALYSIS OF GAS PRODUCTION FROM HYDRAULICALLY FRACTURED WELLS IN THE HAYNESVILLE SHALE USING P. Marder University of Texas at Austin ABSTRACT The Haynesville Shale is one of the largest. The reservoir temperature is also high, up to 3000 F. These pressures are uniquely high among shale gas

Patzek, Tadeusz W.

483

Title: Working Together in Shale Gas Policy Hosts: Todd Cowen, Teresa Jordan and Christine Shoemaker  

E-Print Network [OSTI]

Title: Working Together in Shale Gas Policy Hosts: Todd Cowen, Teresa Jordan and Christine and environmental groups. The Shale Gas Roundtable of the Institute of Politics at the University of Pittsburgh produced a report with several recommendations dealing especially with shale gas research, water use

Angenent, Lars T.

484

Exploring the Environmental Effects of Shale Gas Development in the Chesapeake Bay Watershed  

E-Print Network [OSTI]

Exploring the Environmental Effects of Shale Gas Development in the Chesapeake Bay Watershed STAC Committee). 2013. Exploring the environmental effects of shale gas development in the Chesapeake Bay of shale gas development in the Chesapeake Bay Watershed. The purpose of this workshop was to engage

485

Department of Mechanical Engineering Fall 2010 Geothermal Pressure Reduction Marcellus Shale Production  

E-Print Network [OSTI]

Shale Production Overview (problem and challenges) During the preliminary production stage, Marcellus Shale natural gas wells have a wellhead pressure that exceeds the material limits of typical above understanding of Marcellus Shale natural gas wells and drilling was gathered on-site. Evaluation of (5

Demirel, Melik C.

486

Life Cycle Analysis on Greenhouse Gas (GHG) Emissions of Marcellus Shale Gas Supporting Information  

E-Print Network [OSTI]

Life Cycle Analysis on Greenhouse Gas (GHG) Emissions of Marcellus Shale Gas Supporting Information 1. GHG Emissions Estimation for Production of Marcellus Shale Gas 1.1 Preparation of Well Pad estimate from Columbia University shows the size of a multi-well pad of Marcellus Shale averages 20

Jaramillo, Paulina

487

CLADID CRINOIDS FROM THE LATE KINDERHOOKIAN MEADVILLE SHALE, CUYAHOGA FORMATION OF OHIO  

E-Print Network [OSTI]

CLADID CRINOIDS FROM THE LATE KINDERHOOKIAN MEADVILLE SHALE, CUYAHOGA FORMATION OF OHIO THOMAS W--A total of 17 species of cladid crinoids are documented from the late Kinderhookian Meadville Shale Member Mississippian Meadville Shale at Richfield, Summit County, Ohio were first noted by Hall (1863) and later fully

Kammer, Thomas

488

Permeability of illite-bearing shale: 1. Anisotropy and effects of clay content and loading  

E-Print Network [OSTI]

Permeability of illite-bearing shale: 1. Anisotropy and effects of clay content and loading-rich shale recovered from the Wilcox formation and saturated with 1 M NaCl solution varies from 3 ? 10?22 transport; KEYWORDS: permeability, shale, connected pore space Citation: Kwon, O., A. K. Kronenberg, A. F

Herbert, Bruce

489

Oil and Gas CDT Structural and depositional controls on shale gas resources in  

E-Print Network [OSTI]

Oil and Gas CDT Structural and depositional controls on shale gas resources in the UK), http://www.bgs.ac.uk/staff/profiles/0688.html · Laura Banfield (BP) Key Words Shale gas, Bowland of structural and depositional controls on shale gas potential in the UK with a synthesis of a series

Henderson, Gideon

490

Potential Health Effects of Marcellus Shale Activities: The Need for Public  

E-Print Network [OSTI]

. #12;Implications of the Gulf Oil Spill to Marcellus Shale Activities - Environmental and human health salt (Proprietary) 10.0 - 30.0% #12;Implications of the Gulf Oil Spill to Marcellus Shale ActivitiesPotential Health Effects of Marcellus Shale Activities: The Need for Public Health Surveillance

Sibille, Etienne

491

www.tyndall.ac.uk Shale gas: an updated assessment of  

E-Print Network [OSTI]

, such as oil derived from tar sands. Nevertheless, there are several routes by which shale gas extraction maywww.tyndall.ac.uk Shale gas: an updated assessment of environmental and climate change impacts Summary This report, commissioned by The Co-operative, is an update on our January report, Shale gas

Matthews, Adrian

492

Design of Bulk Railway Terminals for the Shale Oil and Gas Industry C. Tyler Dick1  

E-Print Network [OSTI]

Page 1 Design of Bulk Railway Terminals for the Shale Oil and Gas Industry C. Tyler Dick1 , P.E., M: Railway transportation is playing a key role in the development of many new shale oil and gas reserves in North America. In the rush to develop new shale oil and gas plays, sites for railway transload terminals

Barkan, Christopher P.L.

493

Underground Injection Wells as an Option for Disposal of Shale Gas Wastewaters: Policies & Practicality.  

E-Print Network [OSTI]

environments and are very salty, like the Marcellus shale and other oil and gas formations underlying the areaUnderground Injection Wells as an Option for Disposal of Shale Gas Wastewaters: Policies), Region 3. Marcellus Shale Educational Webinar, February 18, 2010 (Answers provide below by Karen Johnson

Boyer, Elizabeth W.

494

Proceedings of the first thermomechanical workshop for shale  

SciTech Connect (OSTI)

Chapter 2 provides a description of the three federal regulations that pertain to the development of a high-level nuclear waste repository regardless of the rock type. Chapter 3 summarizes the reference shale repository conditions selected for this workshop. A room-and-pillar configuration was considered at an extraction ratio of about 0.25. The depth was assumed to be 700 m. Chapter 4 gives a summary of several case histories that were considered to be valuable in gaining an understanding of some of the design and construction features that might be unique in creating underground openings in shale. Chapter 5 assesses the data and information needs, availability, technology for acquisition, and the research and development necessary for analytical/numerical modeling in heat transfer, fluid flow, and thermomechanics. Chapter 6 assesses data and information needs in the laboratory and considerations associated with shale rock characterization. Chapter 7 assesses the data and information needs, availability, technology for acquisition, and the research and development necessary for field/in situ testing. Chapter 8 presents the consensus of the workshop participants that there is a definite need to advance the state of knowledge concerning the thermomechanical behavior of shales and to gain experience in applying this knowledge to the design of room-and-pillar excavations. Finally, Chapter 9 provides a summary of the research and development needs in the various interacting activities of repository development, including analytical/numerical modeling, laboratory testing, and field/in situ testing. The main conclusion of the workshop was that a need exists for an aggressive program in laboratory, field, numerical modeling, and design studies to provide a thermomechanical, technological base for comparison of shale types and shale regions/areas/sites.

Not Available

1986-03-01T23:59:59.000Z

495

Texas--RRC District 8 Shale Production (Billion Cubic Feet)  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear JanSeparation,(Million Barrels)Shale(MillionShale Production

496

Executive summary. Western oil shale developmet: a technology assessment  

SciTech Connect (OSTI)

The objectives are to review shale oil technologies as a means of supplying domestically produced fuels within environmental, social, economic, and legal/institutional constraints; using available data, analyses, and experienced judgment, to examine the major points of uncertainty regarding potential impacts of oil shale development; to resolve issues where data and analyses are compelling or where conclusions can be reached on judgmental grounds; to specify issues which cannot be resolved on the bases of the data, analyses, and experienced judgment currently available; and when appropriate and feasible, to suggest ways for the removal of existing uncertainties that stand in the way of resolving outstanding issues.

Not Available

1981-11-01T23:59:59.000Z

497

Oil shale research and coordination. Progress report, 1980-1981  

SciTech Connect (OSTI)

Purpose is to evaluate the environmental and health consequences of the release of toxic trace elements by an oil shale industry. Emphasis is on the five elements As, Mo, F, Se, and B. Results of four years' research are summarized and the research results over the past year are reported in this document. Reports by the task force are included as appendices, together with individual papers on various aspects of the subject topic. Separate abstracts were prepared for the eleven individual papers. A progress report on the IWG oil shale risk analysis is included at the end of this document. (DLC)

Chappell, W R

1981-01-01T23:59:59.000Z

498

Eastern gas shales bibliography selected annotations: gas, oil, uranium, etc. Citations in bituminous shales worldwide  

SciTech Connect (OSTI)

This bibliography contains 2702 citations, most of which are annotated. They are arranged by author in numerical order with a geographical index following the listing. The work is international in scope and covers the early geological literature, continuing through 1979 with a few 1980 citations in Addendum II. Addendum I contains a listing of the reports, well logs and symposiums of the Unconventional Gas Recovery Program (UGR) through August 1979. There is an author-subject index for these publications following the listing. The second part of Addendum I is a listing of the UGR maps which also has a subject-author index following the map listing. Addendum II includes several important new titles on the Devonian shale as well as a few older citations which were not found until after the bibliography had been numbered and essentially completed. A geographic index for these citations follows this listing.

Hall, V.S. (comp.)

1980-06-01T23:59:59.000Z

499

Shale-Gas Experience as an Analog for Potential Wellbore Integrity Issues in CO2 Sequestration  

SciTech Connect (OSTI)

Shale-gas development in Pennsylvania since 2003 has resulted in about 19 documented cases of methane migration from the deep subsurface (7,0000) to drinking water aquifers, soils, domestic water wells, and buildings, including one explosion. In all documented cases, the methane leakage was due to inadequate wellbore integrity, possibly aggravated by hydrofracking. The leakage of methane is instructive on the potential for CO{sub 2} leakage from sequestration operations. Although there are important differences between the two systems, both involve migrating, buoyant gas with wells being a primary leakage pathway. The shale-gas experience demonstrates that gas migration from faulty wells can be rapid and can have significant impacts on water quality and human health and safety. Approximately 1.4% of the 2,200 wells drilled into Pennsylvania's Marcellus Formation for shale gas have been implicated in methane leakage. These have resulted in damage to over 30 domestic water supplies and have required significant remediation via well repair and homeowner compensation. The majority of the wellbore integrity problems are a result of over-pressurization of the wells, meaning that high-pressure gas has migrated into an improperly protected wellbore annulus. The pressurized gas leaks from the wellbore into the shallow subsurface, contaminating drinking water or entering structures. The effects are localized to a few thousands of feet to perhaps two-three miles. The degree of mixing between the drinking water and methane is sufficient that significant chemical impacts are created in terms of elevated Fe and Mn and the formation of black precipitates (metal sulfides) as well as effervescing in tap water. Thus it appears likely that leaking CO{sub 2} could also result in deteriorated water quality by a similar mixing process. The problems in Pennsylvania highlight the critical importance of obtaining background data on water quality as well as on problems associated with previous (legacy) oil and gas operations. The great majority of the leakage issues in Pennsylvania are due to improperly abandoned wells, however in the media there is no clear distinction between past and present problems. In any case, significant analytical work is required to attribute differing sources of methane (or CO{sub 2} in the case of sequestration). In Pennsylvania, a relatively lax regulatory environment appears to have contributed to the problem with inadequate oversight of well design and testing to ensure well integrity. New rules were adopted at the end of 2010, and it will be interesting to observe whether methane leakage problems are significantly reduced.

Carey, James W. [Los Alamos National Laboratory; Simpson, Wendy S. [Los Alamos National Laboratory; Ziock, Hans-Joachim [Los Alamos National Laboratory

2011-01-01T23:59:59.000Z

500

A Study of the Dielectric Properties of Dry and Saturated Green River Oil Shale  

SciTech Connect (OSTI)

We measured dielectric permittivity of dry and fluid-saturated Green River oil shale samples over a frequency range of 1 MHz to 1.8 GHz. Dry sample measurements were carried out between room temperature and 146 C, saturated sample measurements were carried out at room temperature. Samples obtained from the Green River formation of Wyoming and from the Anvil Points Mine in Colorado were cored both parallel and perpendicular to layering. The samples, which all had organic richness in the range of 10-45 gal/ton, showed small variations between samples and a relatively small level of anisotropy of the dielectric properties when dry. The real and imaginary part of the relative dielectric permittivity of dry rock was nearly constant over the frequency range observed, with low values for the imaginary part (loss factor). Saturation with de-ionized water and brine greatly increased the values of the real and imaginary parts of the relative permittivity, especially at the lower frequencies. Temperature effects were relatively small, with initial increases in permittivity to about 60 C, followed by slight decreases in permittivity that diminished as temperature increased. Implications of these observations for the in situ electromagnetic, or radio frequency (RF) heating of oil shale to produce oil and gas are discussed.

Sweeney, J; Roberts, J; Harben, P

2007-02-07T23:59:59.000Z