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Sample records for oracle java se

  1. U-105:Oracle Java SE Critical Patch Update Advisory

    Broader source: Energy.gov [DOE]

    Multiple vulnerabilities were reported in Oracle Java SE. A remote user can execute arbitrary code on the target system. A remote user can cause denial of service conditions.

  2. V-181: Oracle Java SE Critical Patch Update Advisory - June 2013 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1: Oracle Java SE Critical Patch Update Advisory - June 2013 V-181: Oracle Java SE Critical Patch Update Advisory - June 2013 June 19, 2013 - 1:06am Addthis PROBLEM: Oracle Java SE Critical Patch Update Advisory - June 2013 PLATFORM: Version(s): 5.0 Update 45, 6 Update 45, 7 Update 21; and prior versions ABSTRACT: Multiple vulnerabilities were reported in Oracle Java. REFERENCE LINKS: Oracle Java SE Critical Patch Update June 2013 SecurityTracker Alert ID: 1028679

  3. T-558: Oracle Java SE and Java for Business Critical Patch Update Advisory- February 2011

    Broader source: Energy.gov [DOE]

    This Critical Patch Update contains 21 new security fixes for Oracle Java SE and Java for Business. 19 of these vulnerabilities may be remotely exploitable without authentication, i.e., may be exploited over a network without the need for a username and password.

  4. V-051: Oracle Solaris Java Multiple Vulnerabilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Articles U-191: Oracle Java Multiple Vulnerabilities U-105:Oracle Java SE Critical Patch Update Advisory T-576: Oracle Solaris Adobe Flash Player Multiple Vulnerabilities...

  5. T-641: Oracle Java SE Critical Patch Update Advisory- June 2011

    Office of Energy Efficiency and Renewable Energy (EERE)

    This Critical Patch Update contains 17 new security fixes for Oracle Java SE - 5 apply to client and server deployments of Java SE, 11 apply to client deployments of Java SE only, and 1 applies to server deployments of Java SE only. All of these vulnerabilities may be remotely exploitable without authentication, i.e., may be exploited over a network without the need for a username and password. Oracle CVSS scores assume that a user running a Java applet or Java Web Start application has administrator privileges (typical on Windows). Where the user does not run with administrator privileges (typical on Solaris and Linux), the corresponding CVSS impact scores for Confidentiality, Integrity, and Availability are "Partial" instead of "Complete", and the corresponding CVSS Base score is 7.5 instead of 10 respectively. For issues in Deployment, fixes are only made available for JDK and JRE 6. Users should use the Java Web Start in JRE 6 and the new Java Plug-in introduced in 6 Update 10. CVE-2011-0862, CVE-2011-0873, CVE-2011-0815, CVE-2011-0817, CVE-2011-0863, CVE-2011-0864, CVE-2011-0802, CVE-2011-0814, CVE-2011-0871, CVE-2011-0786, CVE-2011-0788, CVE-2011-0866, CVE-2011-0868, CVE-2011-0872, CVE-2011-0867, CVE-2011-0869, and CVE-2011-0865

  6. U-191: Oracle Java Multiple Vulnerabilities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1: Oracle Java Multiple Vulnerabilities U-191: Oracle Java Multiple Vulnerabilities June 14, 2012 - 7:00am Addthis PROBLEM: Multiple vulnerabilities have been reported in Oracle Java, which can be exploited by malicious local users PLATFORM: Oracle Java JDK 1.7.x / 7.x Oracle Java JRE 1.7.x / 7.x Sun Java JDK 1.5.x Sun Java JDK 1.6.x / 6.x Sun Java JRE 1.4.x Sun Java JRE 1.5.x / 5.x Sun Java JRE 1.6.x / 6.x Sun Java SDK 1.4.x ABSTRACT: The Critical Patch Update for Java SE also includes

  7. V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerabilit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability June 25, 2013 - 12:41am Addthis PROBLEM: ...

  8. V-095: Oracle Java Flaws Let Remote Users Execute Arbitrary Code...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5: Oracle Java Flaws Let Remote Users Execute Arbitrary Code V-095: Oracle Java Flaws Let Remote Users Execute Arbitrary Code February 20, 2013 - 12:38am Addthis PROBLEM: Oracle...

  9. V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 85: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability June 25, 2013 - 12:41am Addthis PROBLEM: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability PLATFORM: Apache OpenOffice SDK 3.x ABSTRACT: Apache has acknowledged a vulnerability in Apache OpenOffice SDK REFERENCE LINKS: Apache OpenOffice Secunia Advisory SA53963 Secunia Advisory SA53846 CVE-2013-1571 IMPACT ASSESSMENT:

  10. V-083: Oracle Java Multiple Vulnerabilities

    Broader source: Energy.gov [DOE]

    A Critical Patch Update is a collection of patches for multiple security vulnerabilities. The Critical Patch Update for Java SE also includes non-security fixes. Critical Patch Updates are cumulative and each advisory describes only the security fixes added since the previous Critical Patch Update and Security Alert.

  11. V-142: Oracle Java Reflection API Flaw Lets Remote Users Execute...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2: Oracle Java Reflection API Flaw Lets Remote Users Execute Arbitrary Code V-142: Oracle Java Reflection API Flaw Lets Remote Users Execute Arbitrary Code April 25, 2013 - 12:14am...

  12. T-561: IBM and Oracle Java Binary Floating-Point Number Conversion Denial of Service Vulnerability

    Broader source: Energy.gov [DOE]

    IBM and Oracle Java products contain a vulnerability that could allow an unauthenticated, remote attacker to cause a denial of service (DoS) condition on a targeted system.

  13. U-014: Oracle Java Runtime Environment (JRE) Multiple Flaws Let...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SDK and JRE 1.4.233 and prior ABSTRACT: A remote user can create a Java applet or Java Web Start application that, when loaded by the target user, will access or modify data or...

  14. U-233: Oracle Database INDEXTYPE CTXSYS.CONTEXT Bug Lets Remote...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Articles U-083:Oracle Critical Patch Update Advisory - January 2012 V-067: Oracle Java Flaw Lets Remote Users Execute Arbitrary Code T-576: Oracle Solaris Adobe Flash Player...

  15. Tomcat, Oracle & XML Web Archive

    Energy Science and Technology Software Center (OSTI)

    2008-01-01

    The TOX (Tomcat Oracle & XML) web archive is a foundation for development of HTTP-based applications using Tomcat (or some other servlet container) and an Oracle RDBMS. Use of TOX requires coding primarily in PL/SQL, JavaScript, and XSLT, but also in HTML, CSS and potentially Java. Coded in Java and PL/SQL itself, TOX provides the foundation for more complex applications to be built.

  16. U-014: Oracle Java Runtime Environment (JRE) Multiple Flaws Let Remote Users Execute Arbitrary Code and Deny Service

    Broader source: Energy.gov [DOE]

    A remote user can create a Java applet or Java Web Start application that, when loaded by the target user, will access or modify data or execute arbitrary code on the target user's system.

  17. Oracle Management Tool Suite

    Energy Science and Technology Software Center (OSTI)

    2007-06-01

    The Oracle Management Tool Suite is used to automatically manage Oracle based systems. This includes startup and shutdown of databases and application servers as well as backup, space management, workload management and log file management.

  18. Java support on genepool: java6 (jdk1.6) will be removed on 08/30/2013;

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    firefox security updates Java support on genepool: java6 (jdk1.6) will be removed on 08/30/2013; firefox security updates Java support on genepool: java6 (jdk1.6) will be removed on 08/30/2013; firefox security updates June 28, 2013 Oracle has stopped releasing free security updates for java6; and thus it will need to be removed from the system in the near future. Do you have code that is using java6? If so, please start testing with java 7. The plan is to completely remove the system

  19. Oracle Financials PIA, Bechtel Jacobs Company, LLC | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oracle Financials PIA, Bechtel Jacobs Company, LLC Oracle Financials PIA, Bechtel Jacobs Company, LLC Oracle Financials PIA, Bechtel Jacobs Company, LLC PDF icon Oracle Financials ...

  20. T-537: Oracle Critical Patch Update Advisory - January 2011 ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    T-537: Oracle Critical Patch Update Advisory - January 2011 January 19, 2011 - 7:11am ... Oracle Critical Update Addthis Related Articles T-537: Oracle Critical Patch Update ...

  1. V-199: Solaris Bugs Let Local Users Gain Root Privileges, Remote...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    recommends applying July Critical Patch Update Addthis Related Articles V-181: Oracle Java SE Critical Patch Update Advisory - June 2013 V-051: Oracle Solaris Java Multiple...

  2. Java XMGR

    SciTech Connect (OSTI)

    Dr. George L. Mesina; Steven P. Miller

    2004-08-01

    The XMGR5 graphing package [1] for drawing RELAP5 [2] plots is being re-written in Java [3]. Java is a robust programming language that is available at no cost for most computer platforms from Sun Microsystems, Inc. XMGR5 is an extension of an XY plotting tool called ACE/gr extended to plot data from several US Nuclear Regulatory Commission (NRC) applications. It is also the most popular graphing package worldwide for making RELAP5 plots. In Section 1, a short review of XMGR5 is given, followed by a brief overview of Java. In Section 2, shortcomings of both tkXMGR [4] and XMGR5 are discussed and the value of converting to Java is given. Details of the conversion to Java are given in Section 3. The progress to date, some conclusions and future work are given in Section 4. Some screen shots of the Java version are shown.

  3. V-136: Oracle Critical Patch Update Advisory - April 2013 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6: Oracle Critical Patch Update Advisory - April 2013 V-136: Oracle Critical Patch Update Advisory - April 2013 April 17, 2013 - 1:46am Addthis PROBLEM: Oracle Critical Patch...

  4. Oracle, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Oracle, Arizona: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 32.6109054, -110.7709348 Show Map Loading map... "minzoom":false,"mappingservi...

  5. U-019: Oracle Critical Patch Update Advisory- October 2011

    Broader source: Energy.gov [DOE]

    October 2011 Critical Patch Update, security vulnerability fixes for proprietary components of Oracle Linux will be announced in Oracle Critical Patch Updates.

  6. V-004: Oracle Critical Patch Update Advisory- October 2012

    Broader source: Energy.gov [DOE]

    October 2012 Critical Patch Update, security vulnerability fixes for proprietary components of Oracle Linux will be announced in Oracle Critical Patch Updates.

  7. Running with Java

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Running with Java Running with Java Workflows that require the Java Virtual Machine will run into a couple of issues when running on Genepool. Java Software installed on Genepool...

  8. Oracle accrual plans from requirements to implementation

    SciTech Connect (OSTI)

    Rivera, Christine K

    2009-01-01

    Implementing any new business software can be an intimidating prospect and this paper is intended to offer some insight in to how to approach this challenge with some fundamental rules for success. Los Alamos National Laboratory (LANL) had undergone an original ERP implementation of HRMS, Oracle Advanced Benefits, Worker Self Service, Manager Self Service, Project Accounting, Financials and PO, and recently completed a project to implement Oracle Payroll, Time and Labor and Accrual Plans. This paper will describe some of the important lessons that can be applied to any implementation as a whole, and then specifically how this knowledge was applied to the design and deployment of Oracle Accrual Plans for LANL. Finally, detail on the functionality available in Oracle Accrual Plans will be described, as well as the detailed setups.that were utilized at LANL.

  9. Oracle Database DBFS Hierarchical Storage Overview

    SciTech Connect (OSTI)

    Rivenes, A

    2011-07-25

    The National Ignition Facility (NIF) at the Lawrence Livermore National Laboratory creates large numbers of images during each shot cycle for the analysis of optics, target inspection and target diagnostics. These images must be readily accessible once they are created and available for the 30 year lifetime of the facility. The Livermore Computing Center (LC) runs a High Performance Storage System (HPSS) that is capable of storing NIF's estimated 1 petabyte of diagnostic images at a fraction of what it would cost NIF to operate its own automated tape library. With Oracle 11g Release 2 database, it is now possible to create an application transparent, hierarchical storage system using the LC's HPSS. Using the Oracle DBMS-LOB and DBMS-DBFS-HS packages a SecureFile LOB can now be archived to storage outside of the database and accessed seamlessly through a DBFS 'link'. NIF has chosen to use this technology to implement a hierarchical store for its image based SecureFile LOBs. Using a modified external store and DBFS links, files are written to and read from a disk 'staging area' using Oracle's backup utility. Database external procedure calls invoke OS based scripts to manage a staging area and the transfer of the backup files between the staging area and the Lab's HPSS.

  10. U-215: Oracle Critical Patch Update Advisory- July 2012

    Broader source: Energy.gov [DOE]

    Critical Patch Updates are the primary means of releasing security fixes for Oracle products to customers with valid support contracts. They are released on the Tuesday closest to the 17th day of January, April, July and October.

  11. U-150: Oracle Critical Patch Update Advisory- April 2012

    Broader source: Energy.gov [DOE]

    Critical Patch Updates are the primary means of releasing security fixes for Oracle products to customers with valid support contracts. They are released on the Tuesday closest to the 17th day of January, April, July and October.

  12. T-672: Oracle Critical Patch Update Advisory- July 2011

    Broader source: Energy.gov [DOE]

    Due to the threat posed by a successful attack, Oracle strongly recommends that customers apply CPU fixes as soon as possible. This Critical Patch Update contains 78 new security fixes across all product families.

  13. Oracle Applications Patch Administration Tool (PAT) Beta Version

    Energy Science and Technology Software Center (OSTI)

    2002-01-04

    PAT is a Patch Administration Tool that provides analysis, tracking, and management of Oracle Application patches. This includes capabilities as outlined below: Patch Analysis & Management Tool Outline of capabilities: Administration Patch Data Maintenance -- track Oracle Application patches applied to what database instance & machine Patch Analysis capture text files (readme.txt and driver files) form comparison detail report comparison detail PL/SQL package comparison detail SQL scripts detail JSP module comparison detail Parse and loadmore » the current applptch.txt (10.7) or load patch data from Oracle Application database patch tables (11i) Display Analysis -- Compare patch to be applied with current Oracle Application installed Appl_top code versions Patch Detail Module comparison detail Analyze and display one Oracle Application module patch. Patch Management -- automatic queue and execution of patches Administration Parameter maintenance -- setting for directory structure of Oracle Application appl_top Validation data maintenance -- machine names and instances to patch Operation Patch Data Maintenance Schedule a patch (queue for later execution) Run a patch (queue for immediate execution) Review the patch logs Patch Management Reports« less

  14. V-189: Oracle VirtualBox 'tracepath' Bug Lets Local Guest Users...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oracle VirtualBox 'tracepath' Bug Lets Local Guest Users Deny Service on the Target Host V-189: Oracle VirtualBox 'tracepath' Bug Lets Local Guest Users Deny Service on the Target...

  15. T-535: Oracle Critical Patch Update- January 2011

    Broader source: Energy.gov [DOE]

    This Critical Patch Update Pre-Release Announcement provides advance information about the Oracle Critical Patch Update for January 2011, which will be released on Tuesday, January 18, 2011. While this Pre-Release Announcement is as accurate as possible at the time of publication, the information it contains may change before publication of the Critical Patch Update Advisory. A Critical Patch Update is a collection of patches for multiple security vulnerabilities. This Critical Patch Update contains 66 new security vulnerability fixes across hundreds of Oracle products. Some of the vulnerabilities addressed in this Critical Patch Update affect multiple products. Due to the threat posed by a successful attack, Oracle strongly recommends that customers apply Critical Patch Update fixes as soon as possible.

  16. Java Vertexing Tools

    SciTech Connect (OSTI)

    Strube, Jan; Graf, Norman; /SLAC

    2006-03-03

    This document describes the implementation of the topological vertex finding algorithm ZVTOP within the org.lcsim reconstruction and analysis framework. At the present date, Java vertexing tools allow users to perform topological vertexing on tracks that have been obtained from a Fast MC simulation. An implementation that will be able to handle fully reconstructed events is being designed from the ground up for longevity and maintainability.

  17. Java support on genepool: java6 (jdk1.6) will be removed on 08...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Java support on genepool: java6 (jdk1.6) will be removed on 08302013; firefox security updates Java support on genepool: java6 (jdk1.6) will be removed on 08302013; firefox...

  18. Java - Dieng Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Java - Dieng Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Java - Dieng Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3...

  19. Java - Kamojang Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Java - Kamojang Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Java - Kamojang Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3...

  20. Java - Darajat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Java - Darajat Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Java - Darajat Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3...

  1. U-234: Oracle MySQL User Login Security Bypass Vulnerability

    Broader source: Energy.gov [DOE]

    Oracle MySQL is prone to a security bypass vulnerability Attackers can exploit this issue to bypass certain security restrictions.

  2. NPDES compliance monitoring report: Oracle Ridge Mine, San Manuel, Arizona. Draft report

    SciTech Connect (OSTI)

    Stevens, J.

    1992-11-03

    This presents the findings of a compliance evaluation inspection of the Oracle Ridge Copper Mine near San Manuel, Arizona, conducted on August 17, 1992. It is part of a series of inspections of uncontrolled discharges of mine drainage.

  3. Jess, the Java expert system shell

    SciTech Connect (OSTI)

    Friedman-Hill, E.J.

    1997-11-01

    This report describes Jess, a clone of the popular CLIPS expert system shell written entirely in Java. Jess supports the development of rule-based expert systems which can be tightly coupled to code written in the powerful, portable Java language. The syntax of the Jess language is discussed, and a comprehensive list of supported functions is presented. A guide to extending Jess by writing Java code is also included.

  4. V-161: IBM Maximo Asset Management Products Java Multiple Vulnerabilities

    Broader source: Energy.gov [DOE]

    Asset and Service Mgmt Products - Potential security exposure when using JavaTM based applications due to vulnerabilities in Java Software Developer Kits.

  5. V-161: IBM Maximo Asset Management Products Java Multiple Vulnerabilit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Articles U-179: IBM Java 7 Multiple Vulnerabilities V-145: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities V-094: IBM Multiple Products Multiple...

  6. V-120: EMC Smarts Network Configuration Manager Java RMI Access...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0: EMC Smarts Network Configuration Manager Java RMI Access Control Flaw Lets Remote Users Gain Full Control V-120: EMC Smarts Network Configuration Manager Java RMI Access Control...

  7. V-145: IBM Tivoli Federated Identity Manager Products Java Multiple...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    V-145: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities April 30, 2013 - 12:09am Addthis PROBLEM: IBM Tivoli Federated Identity Manager Products Java ...

  8. Java Parallel Secure Stream for Grid Computing

    SciTech Connect (OSTI)

    Chen, Jie; Akers, Walter; Chen, Ying; Watson, William

    2001-09-01

    The emergence of high speed wide area networks makes grid computing a reality. However grid applications that need reliable data transfer still have difficulties to achieve optimal TCP performance due to network tuning of TCP window size to improve the bandwidth and to reduce latency on a high speed wide area network. This paper presents a pure Java package called JPARSS (Java Par-allel Secure Stream) that divides data into partitions that are sent over several parallel Java streams simultaneously and allows Java or Web applications to achieve optimal TCP performance in a gird environment without the necessity of tuning the TCP window size. Several experimental results are provided to show that using parallel stream is more effective than tuning TCP window size. In addi-tion X.509 certificate based single sign-on mechanism and SSL based connection establishment are integrated into this package. Finally a few applications using this package will be discussed.

  9. Oracle inequalities for SVMs that are based on random entropy numbers

    SciTech Connect (OSTI)

    Steinwart, Ingo

    2009-01-01

    In this paper we present a new technique for bounding local Rademacher averages of function classes induced by a loss function and a reproducing kernel Hilbert space (RKHS). At the heart of this technique lies the observation that certain expectations of random entropy numbers can be bounded by the eigenvalues of the integral operator associated to the RKHS. We then work out the details of the new technique by establishing two new oracle inequalities for SVMs, which complement and generalize orevious results.

  10. Tool For Editing Structured Query Language Text Within ORACLE Forms Applications

    Energy Science and Technology Software Center (OSTI)

    1991-02-01

    SQTTEXT is an ORACLE SQL*Forms application that allows a programmer to view and edit all the Structured Query Language (SQL) text for a given application on one screen. This application is an outgrowth of the prototyping of an on-line system dictionary for the Worldwide Household Goods Information system for Transportation-Modernization decision support system being prototyped by the Oak Ridge National Laboratory, but it can be applied to all SQL*Forms software development, debugging, and maintenance.

  11. U-245: Critical Java 0-day flaw exploited

    Broader source: Energy.gov [DOE]

    Targeted attacks exploiting a zero-day Java vulnerability to deliver the Poison Ivy RAT onto the unsuspecting victims' machines

  12. The state of the Java universe

    SciTech Connect (OSTI)

    2011-02-08

    Speaker Bio: James Gosling received a B.Sc. in computer science from the University of Calgary, Canada in 1977. He received a Ph.D. in computer science from Carnegie-Mellon University in 1983. The title of his thesis was The Algebraic Manipulation of Constraints. He has built satellite data acquisition systems, a multiprocessor version of UNIX®, several compilers, mail systems, and window managers. He has also built a WYSIWYG text editor, a constraint-based drawing editor, and a text editor called Emacs, for UNIX systems. At Sun his early activity was as lead engineer of the NeWS window system. He did the original design of the Java programming language and implemented its original compiler and virtual machine. He has recently been a contributor to the Real-Time Specification for Java.

  13. The state of the Java universe

    ScienceCinema (OSTI)

    None

    2011-10-06

    Speaker Bio: James Gosling received a B.Sc. in computer science from the University of Calgary, Canada in 1977. He received a Ph.D. in computer science from Carnegie-Mellon University in 1983. The title of his thesis was The Algebraic Manipulation of Constraints. He has built satellite data acquisition systems, a multiprocessor version of UNIX®, several compilers, mail systems, and window managers. He has also built a WYSIWYG text editor, a constraint-based drawing editor, and a text editor called Emacs, for UNIX systems. At Sun his early activity was as lead engineer of the NeWS window system. He did the original design of the Java programming language and implemented its original compiler and virtual machine. He has recently been a contributor to the Real-Time Specification for Java.

  14. V-143: Fresh Java issues being exploited in the wild

    Broader source: Energy.gov [DOE]

    Java issues are being exploited in the wild by exploit kits, with Cool and Redkit specifically being known to use these bugs, and others likely to follow shortly.

  15. V-178: IBM Data Studio Web Console Java Multiple Vulnerabilities

    Broader source: Energy.gov [DOE]

    IBM Data Studio Web Console uses the IBM Java Runtime Environment (JRE) and might be affected by vulnerabilities in the IBM JRE

  16. T-686: IBM Tivoli Integrated Portal Java Double Literal Denial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    this November 2011 IBM Downloads Addthis Related Articles V-145: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities T-694: IBM Tivoli Federated Identity...

  17. V-122: IBM Tivoli Application Dependency Discovery Manager Java...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automation Application Manager Multiple Vulnerabilities V-145: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities T-694: IBM Tivoli Federated Identity...

  18. V-205: IBM Tivoli System Automation for Multiplatforms Java Multiple...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automation Application Manager Multiple Vulnerabilities V-145: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities V-122: IBM Tivoli Application...

  19. Java Expert System Shell Version 6.0

    Energy Science and Technology Software Center (OSTI)

    2002-06-18

    Java Expert Shell System - Jess - is a rule engine and scripting environment written entirely in Sun's Java language, Jess was orginially inspired by the CLIPS expert system shell, but has grown int a complete, distinct JAVA-influenced environment of its own. Using Jess, you can build Java applets and applications that have the capacity to "reason" using knowledge you supply in the form of declarative rules. Jess is surprisingly fast, and for some problemsmore » is faster than CLIPS, in that many Jess scripts are valid CLIPS scripts and vice-versa. Like CLIPS, Jess uses the Rete algorithm to process rules, a very efficient mechanism for solving the difficult many-to-many matching problem. Jess adds many features to CLIPS, including backwards chaining and the ability to manipulate and directly reason about Java objects. Jess is also a powerful Java scripting environment, from which you can create Java objects and call Java methods without compiling any Java Code.« less

  20. Java implementation of Class Association Rule algorithms

    Energy Science and Technology Software Center (OSTI)

    2007-08-30

    Java implementation of three Class Association Rule mining algorithms, NETCAR, CARapriori, and clustering based rule mining. NETCAR algorithm is a novel algorithm developed by Makio Tamura. The algorithm is discussed in a paper: UCRL-JRNL-232466-DRAFT, and would be published in a peer review scientific journal. The software is used to extract combinations of genes relevant with a phenotype from a phylogenetic profile and a phenotype profile. The phylogenetic profiles is represented by a binary matrix andmore » a phenotype profile is represented by a binary vector. The present application of this software will be in genome analysis, however, it could be applied more generally.« less

  1. T-658: Java for Mac OS X 10.6 Update 5 & Java for Mac OS X 10.5 Update 10

    Broader source: Energy.gov [DOE]

    Multiple vulnerabilities exist in Java 1.6.0_24, the most serious of which may allow an untrusted Java applet to execute arbitrary code outside the Java sandbox. Visiting a web page containing a maliciously crafted untrusted Java applet may lead to arbitrary code execution with the privileges of the current user. These issues are addressed by updating to Java version 1.6.0_26.

  2. JPARSS: A Java Parallel Network Package for Grid Computing

    SciTech Connect (OSTI)

    Chen, Jie; Akers, Walter; Chen, Ying; Watson, William

    2002-03-01

    The emergence of high speed wide area networks makes grid computinga reality. However grid applications that need reliable data transfer still have difficulties to achieve optimal TCP performance due to network tuning of TCP window size to improve bandwidth and to reduce latency on a high speed wide area network. This paper presents a Java package called JPARSS (Java Parallel Secure Stream (Socket)) that divides data into partitions that are sent over several parallel Java streams simultaneously and allows Java or Web applications to achieve optimal TCP performance in a grid environment without the necessity of tuning TCP window size. This package enables single sign-on, certificate delegation and secure or plain-text data transfer using several security components based on X.509 certificate and SSL. Several experiments will be presented to show that using Java parallelstreams is more effective than tuning TCP window size. In addition a simple architecture using Web services

  3. V-145: IBM Tivoli Federated Identity Manager Products Java Multiple

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vulnerabilities | Department of Energy 45: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities V-145: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities April 30, 2013 - 12:09am Addthis PROBLEM: IBM Tivoli Federated Identity Manager Products Java Multiple Vulnerabilities PLATFORM: IBM Tivoli Federated Identity Manager versions 6.1, 6.2.0, 6.2.1, and 6.2.2. IBM Tivoli Federated Identity Manager Business Gateway versions 6.1.1, 6.2.0, 6.2.1

  4. Add Java extensions to your wiki: Java applets can bring dynamic functionality to your wiki pages

    SciTech Connect (OSTI)

    Scarberry, Randall E.

    2008-08-12

    Virtually everyone familiar with today’s world wide web has encountered the free online encyclopedia Wikipedia many times. What you may not know is that Wikipedia is driven by an excellent open-source product called MediaWiki which is available to anyone for free. This has led to a proliferation of wiki sites devoted to just about any topic one can imagine. Users of a wiki can add content -- all that is required of them is that they type in their additions into their web browsers using the simple markup language called wikitext. Even better, the developers of wikitext made it extensible. With a little server-side development of your own, you can add your own custom syntax. Users aware of your extensions can then utilize them on their wiki pages with a few simple keystrokes. These extensions can be custom decorations, formatting, web applications, and even instances of the venerable old Java applet. One example of a Java applet extension is the Jmol extension (REF), used to embed a 3-D molecular viewer. This article will walk you through the deployment of a fairly elaborate applet via a MediaWiki extension. By no means exhaustive -- an entire book would be required for that -- it will demonstrate how to give the applet resize handles using using a little Javascript and CSS coding and some popular Javascript libraries. It even describes how a user may customize the extension somewhat using a wiki template. Finally, it explains a rudimentary persistence mechanism which allows applets to save data directly to the wiki pages on which they reside.

  5. StrBioLib: a Java library for development of custom computationalstruc...

    Office of Scientific and Technical Information (OSTI)

    StrBioLib: a Java library for development of custom computationalstructural biology applications Citation Details In-Document Search Title: StrBioLib: a Java library for ...

  6. V-137: Apple Mac OS X update for Java | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7: Apple Mac OS X update for Java V-137: Apple Mac OS X update for Java April 18, 2013 - 6:00am Addthis PROBLEM: Apple Mac OS X update for Java PLATFORM: Mac OS X 10.6, OS X Lion...

  7. V-122: IBM Tivoli Application Dependency Discovery Manager Java Multiple Vulnerabilities

    Broader source: Energy.gov [DOE]

    Multiple security vulnerabilities exist in the Java Runtime Environments (JREs) that can affect the security of IBM Tivoli Application Dependency Discovery Manager

  8. An evaluation of Java's I/O capabilities for high-performance computing.

    SciTech Connect (OSTI)

    Dickens, P. M.; Thakur, R.

    2000-11-10

    Java is quickly becoming the preferred language for writing distributed applications because of its inherent support for programming on distributed platforms. In particular, Java provides compile-time and run-time security, automatic garbage collection, inherent support for multithreading, support for persistent objects and object migration, and portability. Given these significant advantages of Java, there is a growing interest in using Java for high-performance computing applications. To be successful in the high-performance computing domain, however, Java must have the capability to efficiently handle the significant I/O requirements commonly found in high-performance computing applications. While there has been significant research in high-performance I/O using languages such as C, C++, and Fortran, there has been relatively little research into the I/O capabilities of Java. In this paper, we evaluate the I/O capabilities of Java for high-performance computing. We examine several approaches that attempt to provide high-performance I/O--many of which are not obvious at first glance--and investigate their performance in both parallel and multithreaded environments. We also provide suggestions for expanding the I/O capabilities of Java to better support the needs of high-performance computing applications.

  9. JAva GUi for Applied Research (JAGUAR) v 3.0

    Energy Science and Technology Software Center (OSTI)

    2013-09-09

    JAGUAR is a Java software tool for automatically rendering a graphical user interface (GUI) from a structured input specification. It is designed as a plug-in to the Eclipse workbench to enable users to create, edit, and externally execute analysis application input decks and then view the results. JAGUAR serves as a GUI for Sandia's DAKOTA software toolkit for optimization and uncertainty quantification. It will include problem (input deck)set-up, option specification, analysis execution, and results visualization.more » Through the use of wizards, templates, and views, JAGUAR helps uses navigate the complexity of DAKOTA's complete input specification. JAGUAR is implemented in Java, leveraging Eclipse extension points and Eclipse user interface. JAGUAR parses a DAKOTA NIDR input specification and presents the user with linked graphical and plain text representations of problem set-up and option specification for DAKOTA studies. After the data has been input by the user, JAGUAR generates one or more input files for DAKOTA, executes DAKOTA, and captures and interprets the results« less

  10. T-606: Sun Java System Access Manager Lets Remote Users Partially Modify Data and Remote Authenticated Users Partially Access Data

    Broader source: Energy.gov [DOE]

    Sun Java System Access Manager Lets Remote Users Partially Modify Data and Remote Authenticated Users Partially Access Data.

  11. Oracle BI Answers

    Broader source: Energy.gov (indexed) [DOE]

    This presentation by Amgad Elgowainy of Argonne National Laboratory was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop in March 2013. csd_workshop_11_elgowainy.pdf (767.06 KB) More Documents & Publications Hydrogen Delivery Analysis Models Overview of Station Analysis Tools Developed in Support of H2USA Webinar Overview of Station Analysis Tools Developed in Support of H2USA DOE Analysis Related to H2USA Energy

    Approach to optimize single turbocharger

  12. ORACLE-FINANCIALS.pdf

    Energy Savers [EERE]

    OPOWER RFI Response OPOWER RFI Response OPOWER submits these comments to the Department of Energy in response to the recently issued Request for Information on smart grid implementation challenges. In particular, OPOWER writes to comment on the importance of effective customer engagement in smart grid policy making. OPOWER RFI Response (51.98 KB) More Documents & Publications Insights from Smart Meters: The Potential for Peak Hour Savings from Behavior-Based Programs Voices of Experience:

  13. Oracle BI Answers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy.gov/List of Awardees" "Data is as of March 22, 2013" "Program Office Name","Place of Performance State","DOE Project Name","Awardee Name","Place of Performance City","Total Awarded","Total Outlaid","Award Date" "Advanced Research Projects Agency - Energy","AL-ALABAMA","Program Direction - ARPA -E","NASA/GEORGE C MARSHALL SPACE FLIGHT

  14. Solon SE | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Solon SE Place: Berlin, Berlin, Germany Zip: D-12489 Sector: Solar Product: Manufacturer of PV modules and tracking systems, and integrator of solar...

  15. About-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LGRT Conte Buildings The University of Massachusetts Amherst Energy Frontier Research Center (EFRC) - Polymer-Based Materials for Harvesting Solar Energy, PHaSE - was one of 46 ...

  16. V-111: Multiple vulnerabilities have been reported in Puppet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    vulnerable system. SOLUTION: Update to a fixed version. Addthis Related Articles V-090: Adobe Flash Player AIR Multiple Vulnerabilities V-083: Oracle Java Multiple...

  17. Resources-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resources This webpage is provided for legacy archive purposes only, as of 30 April 2015. However, the facilities and resources created under PHaSE (thanks to the support of the U.S. Department of Energy) remain available for their original purpose of investigating organic-based electronic materials. Resources As a national and regional center of excellence for energy research, PHaSE has access to many resources linked from the Department of Energy and the greater UMass Amherst campus, as well

  18. Virginia Tech Selected to Continue Development of Innovative...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... "Turn-Key" Open Source Software Solutions for Energy Management of Small to Medium Sized Buildings (DE-FOA-0000822) V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing ...

  19. JC3 Bulletin Archive | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Login Security module for Drupal June 25, 2013 V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability Apache has acknowledged a vulnerability in Apache...

  20. JC3 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Login Security module for Drupal June 25, 2013 V-185: Apache OpenOffice SDK Oracle Java JavaDoc Spoofing Vulnerability Apache has acknowledged a vulnerability in Apache...

  1. News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News and Highlights Saxony This page shows highlights and news items about PHaSE activities, research achievements, and people; archived items can be accessed by year at the menu to the left. If you have questions about any items, or want to know more, please contact either Tom Russell or D. Venkataraman. Final archive date: 26 April

  2. Barron: Noncompliance Determination (2013-SE-5402) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noncompliance Determination (2013-SE-5402) Barron: Noncompliance Determination (2013-SE-5402) December 17, 2015 DOE issued a Notice of Noncompliance Determination to Barron ...

  3. Shandong Hongtai: Noncompliance Determination (2016-SE-42010...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noncompliance Determination (2016-SE-42010) Shandong Hongtai: Noncompliance Determination (2016-SE-42010) January 6, 2016 DOE issued a Notice of Noncompliance Determination to ...

  4. I2SE | Open Energy Information

    Open Energy Info (EERE)

    I2SE Jump to: navigation, search Name: I2SE Place: Leipzig, Germany Zip: 4103 Sector: Efficiency Product: IT company providing solutions for energy efficiency and data...

  5. SE Project Srl | Open Energy Information

    Open Energy Info (EERE)

    search Name: SE Project Srl Place: San Pietro, Italy Zip: 35010 Sector: Solar Product: Italian manufacturer and supplier of solar modules and solar technology. References: SE...

  6. JANIS 4: An Improved Version of the NEA Java-based Nuclear Data Information System

    SciTech Connect (OSTI)

    Soppera, N. Bossant, M.; Dupont, E.

    2014-06-15

    JANIS is software developed to facilitate the visualization and manipulation of nuclear data, giving access to evaluated data libraries, and to the EXFOR and CINDA databases. It is stand-alone Java software, downloadable from the web and distributed on DVD. Used offline, the system also makes use of an internet connection to access the NEA Data Bank database. It is now also offered as a full web application, only requiring a browser. The features added in the latest version of the software and this new web interface are described.

  7. Identification of earthquakes that generate tsunamis in Java and Nusa Tenggara using rupture duration analysis

    SciTech Connect (OSTI)

    Pribadi, S.; Puspito, N. T.; Yudistira, T.; Afnimar,; Ibrahim, G.; Laksono, B. I.; Adnan, Z.

    2014-09-25

    Java and Nusa Tenggara are the tectonically active of Sunda arc. This study discuss the rupture duration as a manifestation of the power of earthquake-generated tsunami. We use the teleseismic (30 - 90) body waves with high-frequency energy Seismometer is from IRIS network as amount 206 broadband units. We applied the Butterworth high bandpass (1 - 2 Hz) filtered. The arrival and travel times started from wave phase of P - PP which based on Jeffrey Bullens table with TauP program. The results are that the June 2, 1994 Banyuwangi and the July 17, 2006 Pangandaran earthquakes identified as tsunami earthquakes with long rupture duration (To > 100 second), medium magnitude (7.6 < Mw < 7.9) and located near the trench. The others are 4 tsunamigenic earthquakes and 3 inland earthquakes with short rupture duration start from To > 50 second which depend on its magnitude. Those events are located far from the trench.

  8. Li2Se as a Neutron Scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Du, Mao-Hua; Shi, Hongliang; Singh, David J.

    2015-06-23

    We show that Li2Se:Te is a potential neutron scintillator material based on density functional calculations. Li2Se exhibits a number of properties favorable for efficient neutron detection, such as a high Li concentration for neutron absorption, a small effective atomic mass and a low density for reduced sensitivity to background gamma rays, and a small band gap for a high light yield. Our calculations show that Te doping should lead to the formation of deep acceptor complex VLi-TeSe, which can facilitate efficient light emission, similar to the emission activation in Te doped ZnSe.

  9. Oxidation of ultrathin GaSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  10. Oxidation of ultrathin GaSe

    SciTech Connect (OSTI)

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  11. Q Cells SE | Open Energy Information

    Open Energy Info (EERE)

    Name: Q-Cells SE Place: Thalheim, Brandenburg, Germany Zip: 6766 Product: German PV cell manufacturer; also makes strategic venture capital and corporate investments....

  12. Templates-Resources-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    templates 36 inch high by 48 inch wide, landscape poster template with PHaSE acknowledgements (PPT file download) 36 inch high by 48 inch wide, landscape poster template with PHaSE acknowledgements, 12-panel layout (typical pattern used by UMass PSE) (PPT file download) 42 inch high by 48 inch wide, landscape poster template with PHaSE acknowledgements (PPT file download) 36 inch high by 48 inch wide, portrait poster template with PHaSE acknowledgements (PPT file download) 16:9 Slide Templates

  13. The preliminary results: Seismic ambient noise Rayleigh wave tomography around Merapi volcano, central Java, Indonesia

    SciTech Connect (OSTI)

    Trichandi, Rahmantara; Yudistira, Tedi; Nugraha, Andri Dian; Zulhan, Zulfakriza; Saygin, Erdinc

    2015-04-24

    Ambient noise tomography is relatively a new method for imaging the shallow structure of the Earth subsurface. We presents the application of this method to produce a Rayleigh wave group velocity maps around the Merapi Volcano, Central Java. Rayleigh waves group velocity maps were reconstructed from the cross-correlation of ambient noise recorded by the DOMERAPI array which consists 43 broadband seismometers. In the processing stage, we first filtered the observation data to separatethe noise from the signal that dominated by the strong volcanic activities. Next, we cross-correlate the filtered data and stack to obtain the Green’s function for all possible station pairs. Then we carefully picked the peak of each Green’s function to estimate the dispersion trend and appliedMultiple Filter Technique to obtain the dispersion curve. Inter-station group velocity curvesare inverted to produceRayleigh wave group velocity maps for periods 1 to 10 s. The resulted Rayleigh group velocity maps show the interesting features around the Merapi Volcano which generally agree with the previous studies. Merapi-Lawu Anomaly (MLA) is emerged as a relatively low anomaly in our group velocity maps.

  14. SE Drive Technik | Open Energy Information

    Open Energy Info (EERE)

    Drive Technik Jump to: navigation, search Name: SE Drive Technik Place: Bochum, Germany Zip: 44791 Product: Germany-based R&D subsidiary of Indian turbine maker Suzlon. References:...

  15. Facilities-Resources-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Various PHaSE EFRC equipment may be accessed by making arrangments for training and acceptance to the list of registered users. Access to the facility rooms requires a password ...

  16. 2013 Archives-News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Archives Volodimyr Duzhko photo Volodimyr Duzhko promoted to (extension) Assistant Professor of Polymer Science & Engineering. PHaSE is pleased to announce that Facility Director Dr. Volodimyr Duzhko has been promoted to extension Assistant Professor of Polymer Science & Engineering. Volodimyr is a semiconductor physicist with considerable experience in polymer materials. Since joining PHaSE, he has trained over 70 people to use 10 instruments in the Photovoltaic & Optical

  17. A transferable force field for CdS-CdSe-PbS-PbSe solid systems

    SciTech Connect (OSTI)

    Fan, Zhaochuan; Vlugt, Thijs J. H.; Koster, Rik S.; Fang, Changming; Huis, Marijn A. van; Wang, Shuaiwei; Yalcin, Anil O.; Tichelaar, Frans D.; Zandbergen, Henny W.

    2014-12-28

    A transferable force field for the PbSe-CdSe solid system using the partially charged rigid ion model has been successfully developed and was used to study the cation exchange in PbSe-CdSe heteronanocrystals [A. O. Yalcin et al., “Atomic resolution monitoring of cation exchange in CdSe-PbSe heteronanocrystals during epitaxial solid-solid-vapor growth,” Nano Lett. 14, 3661–3667 (2014)]. In this work, we extend this force field by including another two important binary semiconductors, PbS and CdS, and provide detailed information on the validation of this force field. The parameterization combines Bader charge analysis, empirical fitting, and ab initio energy surface fitting. When compared with experimental data and density functional theory calculations, it is shown that a wide range of physical properties of bulk PbS, PbSe, CdS, CdSe, and their mixed phases can be accurately reproduced using this force field. The choice of functional forms and parameterization strategy is demonstrated to be rational and effective. This transferable force field can be used in various studies on II-VI and IV-VI semiconductor materials consisting of CdS, CdSe, PbS, and PbSe. Here, we demonstrate the applicability of the force field model by molecular dynamics simulations whereby transformations are initiated by cation exchange.

  18. 2011 Archives-News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Archives solar cells video clip Solar Cells from Plastics? Mission Possible at the PHaSE energy research center, UMass Amherst!, a YouTube video about work at PHaSE, debuted on 24 March 2011. This video is part of our center's contributions to the Energy Frontier Research Centers Summit & Forum on 25-27 May 2011, which is further described below. Many thanks to Harihara Venkatraman (DV group, ERG 1) and Dr. Emily Pentzer (Emrick group, ERG 1) for starring in the video clip, along with

  19. Anisotropy in CdSe quantum rods

    SciTech Connect (OSTI)

    Li, Liang-shi

    2003-09-01

    The size-dependent optical and electronic properties of semiconductor nanocrystals have drawn much attention in the past decade, and have been very well understood for spherical ones. The advent of the synthetic methods to make rod-like CdSe nanocrystals with wurtzite structure has offered us a new opportunity to study their properties as functions of their shape. This dissertation includes three main parts: synthesis of CdSe nanorods with tightly controlled widths and lengths, their optical and dielectric properties, and their large-scale assembly, all of which are either directly or indirectly caused by the uniaxial crystallographic structure of wurtzite CdSe. The hexagonal wurtzite structure is believed to be the primary reason for the growth of CdSe nanorods. It represents itself in the kinetic stabilization of the rod-like particles over the spherical ones in the presence of phosphonic acids. By varying the composition of the surfactant mixture used for synthesis we have achieved tight control of the widths and lengths of the nanorods. The synthesis of monodisperse CdSe nanorods enables us to systematically study their size-dependent properties. For example, room temperature single particle fluorescence spectroscopy has shown that nanorods emit linearly polarized photoluminescence. Theoretical calculations have shown that it is due to the crossing between the two highest occupied electronic levels with increasing aspect ratio. We also measured the permanent electric dipole moment of the nanorods with transient electric birefringence technique. Experimental results on nanorods with different sizes show that the dipole moment is linear to the particle volume, indicating that it originates from the non-centrosymmetric hexagonal lattice. The elongation of the nanocrystals also results in the anisotropic inter-particle interaction. One of the consequences is the formation of liquid crystalline phases when the nanorods are dispersed in solvent to a high enough

  20. UMass-Resources-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UMass Resources UMass logo The following links provide information about important local (UMass Amherst) campus and departmental offices and resources, including major interdepartmental research centers that pursue work closely akin to research that was initiated or expanded under PHaSE. The last four links go to sites with energy or research news of potential interest to scientists interested in organic electronic materails. Major UMass User Facilities Vice-Chancellor for Research UMass

  1. Organization-About-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Mission Statement (PDF) Organization Contact Us organization This webpage is provided for legacy archive purposes only, as of 30 April 2015. The day to day operations of the University of Massachusetts Amherst PHaSE EFRC are administered by co-directors. Russell is the Samuel Conte Distingushed Professor of Polymer Science and Engineering, with years of previous experience at IBM Research, over 620 publications and 21 patents for polymer chemistry and physics. Lahti has over 29 years at

  2. SE Great Basin Play Fairway Analysis

    SciTech Connect (OSTI)

    Adam Brandt

    2015-11-15

    This submission includes a Na/K geothermometer probability greater than 200 deg C map, as well as two play fairway analysis (PFA) models. The probability map acts as a composite risk segment for the PFA models. The PFA models differ in their application of magnetotelluric conductors as composite risk segments. These PFA models map out the geothermal potential in the region of SE Great Basin, Utah.

  3. 2010 Archives-News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Archives PHaSE welcomes Dr. Lawrence Friedman as our new Managing Director. Larry comes to us with strong backgrounds in both academic and industrial experience. He is well acquainted with UMass Amherst from his time at Bayer Materials Science, where he was much involved in doctoral level recruiting and in academic/industrial liaison work as Head of University Relations. Before this, he was at Polaroid doing work in flims research as a manager and senior scientist. His academic credentials

  4. 2013 Archives-News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Archives PHaSE EFRC work was featured in an MRS-TV video production, UMASS Amherst -- Optimal Design: Interdisciplinary Teamwork from Synthesis to Production, that was highlighted on electronic signage throughout the Fall 2014 Boston Materials Research Society meeting. Major vignettes were shown from Maroudas group, DV group, Emrick group. Both faculty and undergraduates/graduates/postdocs described EFRC work and work being carried out by closely allied groups interested in energy-related

  5. AeroSys: Noncompliance Determination (2010-SE-0302) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noncompliance Determination (2010-SE-0302) AeroSys: Noncompliance Determination (2010-SE-0302) April 13, 2010 DOE issued a Notice of Noncompliance Determination to AeroSys, Inc. ...

  6. SeQuential Pacific Biodiesel LLC | Open Energy Information

    Open Energy Info (EERE)

    Pacific Biodiesel LLC Jump to: navigation, search Name: SeQuential-Pacific Biodiesel LLC Place: Oregon Sector: Biofuels Product: JV between SeQuential Biofuels, Pacific Biodiesel,...

  7. 2009 Archives-News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09 Archives U.S. DOE Announces Energy Frontier Research Centers (08/2009) UMass Amherst EFRC Proposal (08/2009) EFRC Funding Distributed to Successful Centers (08/2009) PHaSE co-director Paul Lahti led off a set of presentations organized by the UMass Amherst Research & Liaison office to meet with a delegation of scientists from various technical research centers of the Gipuzkoa province in the Basque region of northern Spain. The delegation was organized through the Tecnalia Corporation,

  8. 2012 Archives-News-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Archives Tom Russell photo Joint work by Tom Russell, Alex Briseno, and coworkers describes fabrication and a significant degree of device optimization of a low band polymer pDPP/PCBM solar cell, in an article published in Advanced Materials. Photoconversion efficiency up to 5.6% with a fill factor of 60% were obtained. Morphology control based on solvent mixture tuning was critically important for best electrical output. [read more] PHaSE members D. Venkataraman and Tom Russell have edited a

  9. Synthesis and optical study of green light emitting polymer coated CdSe/ZnSe core/shell nanocrystals

    SciTech Connect (OSTI)

    Tripathi, S.K.; Sharma, Mamta

    2013-05-15

    Highlights: ► Synthesis of Polymer coated core CdSe and CdSe/ZnSe core/shell NCs. ► From TEM image, the spherical nature of CdSe and CdSe/ZnSe is obtained. ► Exhibiting green band photoemission peak at 541 nm and 549 nm for CdSe core and CdSe/ZnSe core/shell NCs. ► The shell thickness has been calculated by using superposition of quantum confinement energy model. - Abstract: CdSe/ZnSe Core/Shell NCs dispersed in PVA are synthesized by chemical method at room temperature. This is characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV/Vis spectra and photoluminescence spectroscopy (PL). TEM image shows the spherical nature of CdSe/ZnSe core/shell NCs. The red shift of absorption and emission peak of CdSe/ZnSe core/shell NCs as compared to CdSe core confirmed the formation of core/shell. The superposition of quantum confinement energy model is used for calculation of thickness of ZnSe shell.

  10. SE-MA-NO Electric Coop | Open Energy Information

    Open Energy Info (EERE)

    SE-MA-NO Electric Coop Jump to: navigation, search Name: SE-MA-NO Electric Coop Place: Missouri Phone Number: (417) 924-3291 Website: www.semano.com Facebook: https:...

  11. MgSe/ZnSe/CdSe coupled quantum wells grown on InP substrate with intersubband absorption covering 1.55??m

    SciTech Connect (OSTI)

    Chen, Guopeng; Shen, Aidong; De Jesus, Joel; Tamargo, Maria C.

    2014-12-08

    The authors report the observation of intersubband (ISB) transitions in the optical communication wavelength region in MgSe/ZnSe/CdSe coupled quantum wells (QWs). The coupled QWs were grown on InP substrates by molecular beam epitaxy. By inserting ZnSe layers to compensate the strain, samples with high structural quality were obtained, as indicated by well resolved satellite peaks in high-resolution x-ray diffraction. The observed ISB transition energies agree well with the calculated values.

  12. Goodman Manufacturing: Order (2011-SE-4301) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Goodman Manufacturing: Order (2011-SE-4301) Goodman Manufacturing: Order (2011-SE-4301) March 2, 2012 DOE ordered Goodman Manufacturing Company, L.P., to pay a $14,800 civil penalty after finding Goodman had manufactured and distributed in commerce in the U.S. at least 74 units of commercial package air conditioner basic model CPC180*. Goodman Manufacturing: Order (2011-SE-4301) (131.78 KB) More Documents & Publications Goodman Manufacturing: Proposed Penalty (2011-SE-4301) Goodman

  13. Barron: Order (2013-SE-5402) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2013-SE-5402) Barron: Order (2013-SE-5402) March 22, 2016 DOE ordered Barron Lighting Group, Inc. to pay a $22,849 civil penalty after finding Barron had manufactured and distributed in commerce in the U.S. 429 units of various noncompliant metal halide lamp fixtures. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Barron. Barron: Order (2013-SE-5402) (19.24 KB) More Documents & Publications Barron: Noncompliance Determination (2013-SE-5402)

  14. SE-72/AS-72 generator system based on Se extraction/ As reextraction

    DOE Patents [OSTI]

    Fassbender, Michael Ernst; Ballard, Beau D

    2013-09-10

    The preparation of a .sup.72Se/.sup.72As radioisotope generator involves forming an acidic aqueous solution of an irradiated alkali bromide target such as a NaBr target, oxidizing soluble bromide in the solution to elemental bromine, removing the elemental bromine, evaporating the resulting solution to a residue, removing hydrogen chloride from the residue, forming an acidic aqueous solution of the residue, adding a chelator that selectively forms a chelation complex with selenium, and extracting the chelation complex from the acidic aqueous solution into an organic phase. As the .sup.72Se generates .sup.72As in the organic phase, the .sup.72As may be extracted repeatedly from the organic phase with an aqueous acid solution.

  15. Two-dimensional GaSe/MoSe2 misfit bilayer heterojunctions by van der Waals epitaxy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xufan; Lin, Ming-Wei; Lin, Junhao; Huang, Bing; Puretzky, Alexander A.; Ma, Cheng; Wang, Kai; Zhou, Wu; Pantelides, Sokrates T.; Chi, Miaofang; et al

    2016-04-01

    Two-dimensional (2D) heterostructures hold the promise for future atomically-thin electronics and optoelectronics due to their diverse functionalities. While heterostructures consisting of different transition metal dichacolgenide monolayers with well-matched lattices and novel physical properties have been successfully fabricated via van der Waals (vdW) or edge epitaxy, constructing heterostructures from monolayers of layered semiconductors with large lattice misfits still remains challenging. Here, we report the growth of monolayer GaSe/MoSe2 heterostructures with large lattice misfit by two-step chemical vapor deposition (CVD). Both vertically stacked and lateral heterostructures are demonstrated. The vertically stacked GaSe/MoSe2 heterostructures exhibit vdW epitaxy with well-aligned lattice orientation between themore » two layers, forming an incommensurate vdW heterostructure. However, the lateral heterostructures exhibit no lateral epitaxial alignment at the interface between GaSe and MoSe2 crystalline domains. Instead of a direct lateral connection at the boundary region where the same lattice orientation is observed between GaSe and MoSe2 monolayer domains in lateral GaSe/MoSe2 heterostructures, GaSe monolayers are found to overgrow MoSe2 during CVD, forming a stripe of vertically stacked vdW heterostructure at the crystal interface. Such vertically-stacked vdW GaSe/MoSe2 heterostructures are shown to form p-n junctions with effective transport and separation of photo-generated charge carriers between layers, resulting in a gate-tunable photovoltaic response. In conclusion, these GaSe/MoSe2 vdW heterostructures should have applications as gate-tunable field-effect transistors, photodetectors, and solar cells.« less

  16. Spectral photoresponse of ZnSe/GaAs(001) heterostructures with CdSe ultra-thin quantum well insertions

    SciTech Connect (OSTI)

    Valverde-Chvez, D. A.; Sutara, F.; Hernndez-Caldern, I.

    2014-05-15

    We present a study of the spectral photoresponse (SPR) of ZnSe/GaAs(001) heterostructures for different ZnSe film thickness with and without CdSe ultra-thin quantum well (UTQW) insertions. We observe a significant increase of the SPR of heterostructures containing 3 monolayer thick CdSe UTQW insertions; these results encourage their use in photodetectors and solar cells.

  17. Twinning effect on photoluminescence spectra of ZnSe nanowires

    SciTech Connect (OSTI)

    Xu, Jing; Wang, Chunrui Wu, Binhe; Xu, Xiaofeng; Chen, Xiaoshuang; Oh, Hongseok; Baek, Hyeonjun; Yi, Gyu-Chul

    2014-11-07

    Bandgap engineering in a single material along the axial length of nanowires may be realized by arranging periodic twinning, whose twin plane is vertical to the axial length of nanowires. In this paper, we report the effect of twin on photoluminescence of ZnSe nanowires, which refers to the bandgap of it. The exciton-related emission peaks of transverse twinning ZnSe nanowires manifest a 10-meV-blue-shift in comparison with those of longitudinal twinning ZnSe nanowires. The blue-shift is attributed to quantum confinement effect, which is influenced severely by the proportion of wurtzite ZnSe layers in ZnSe nanowires.

  18. Thermoelectric transport of Se-rich Ag{sub 2}Se in normal phases and phase transitions

    SciTech Connect (OSTI)

    Mi, Wenlong; Lv, Yanhong; Qiu, Pengfei; Shi, Xun E-mail: cld@mail.sic.ac.cn; Chen, Lidong E-mail: cld@mail.sic.ac.cn; Zhang, Tiansong

    2014-03-31

    Small amount of Se atoms are used to tune the carrier concentrations (n{sub H}) and electrical transport in Ag{sub 2}Se. Significant enhancements in power factor and thermoelectric figure of merit (zT) are observed in the compositions of Ag{sub 2}Se{sub 1.06} and Ag{sub 2}Se{sub 1.08}. The excessive Se atoms do not change the intrinsically electron-conducting character in Ag{sub 2}Se. The detailed analysis reveals the experiment optimum carrier concentration in Ag{sub 2}Se is around 5??10{sup 18}?cm{sup ?3}. We also investigate the temperature of maximum zT and the thermoelectric transport during the first order phase transitions using the recently developed measurement system.

  19. Confined lattice dynamics of single and quadruple SnSe bilayers in [(SnSe) 1.04 ] m [MoSe 2 ] n ferecrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Klobes, Benedikt; Hu, Michael Y.; Beekman, Matt; Johnson, David C.; Hermann, Raphaël P.

    2015-11-30

    The Sn specific densities of phonon states in the SnSe subunits of [(SnSe)1.04]m[MoSe2]n ferecrystals with (m,n) = (1,1), (4,1) and in bulk SnSe were derived from nuclear inelastic scattering by the 119Sn M ssbauer resonance. When using different measurement configurations, phonons with polarization parallel and perpendicular to the ferecrystal plane were specifically probed. Vibrational properties and phonon spectral weight are found to strongly depend on the phonon polarization and layer count m. Moreover, a highly peculiar feature of these ferecrystal densities of phonon states is the emergence of rather sharp high energy vibrational modes polarized perpendicular to the ferecrystal plane,more » which contrasts with usual findings in thin layered structures and nanostructured materials in general, and a depletion of modes with a gap appearing between acoustic and high energy modes. The spectral weight of these phonons depends on the overall SnSe content, m, but cannot be unambiguously attributed to SnSe MoSe2 interfaces. Considering the low energy part of lattice dynamics, ferecrystals exhibit rather low average phonon group velocities as compared to the speed of sound in the long wavelength limit. For the (1,1) ferecrystal, this effect is most pronounced for vibrations polarized in the ferecrystal plane. Therefore, an experimental microscopic origin for the vibrational and bonding anisotropy in subunits of ferecrystals is provided.« less

  20. CuInSe/sub 2/-based photoelectrochemical cells: their use in characterization of thin CuInSe/sub 2/ films, and as photovoltaic cells per se

    SciTech Connect (OSTI)

    Cahen, D.; Chen, Y.W.; Ireland, P.J.; Noufi, R.; Turner, J.A.; Rincon, C.; Bachmann, K.J.

    1984-05-01

    Photoelectrochemistry has been employed to characterize the p-CuInSe/sub 2/ component of the CdS/CuInSe/sub 2/ on-metal and a nonaqueous electrolyte containing a redox couple not specifically adsorbed onto the semiconductor, we can test the films for photovoltaic activity and obtain effective electronic properties of them, before CdS deposition, in a nondestructive manner. Electrochemical decomposition of CuInSe/sub 2/ was investigated in acetonitrile solutions to determine the mechanism of decomposition (n and p) in the dark and under illumination. Electrochemical, solution chemical and surface analyses confirmed at the light-assisted decomposition of CuInSe/sub 2/ resulted in metal ions and elemental chalcogen. On the basis of the results from the electrochemical decomposition, and studies on the solid state chemistry of the (Cu/sub 2/Se)/sub x/(In/sub 2/Se/sub 3/)/sub 1-x/ system and surface analyses, the CuInSe/sub 2//polyiodide interface was stabilized and up to 11.7% conversion efficiencies were obtained.

  1. Perlick: Agreement (2010-SE-0109) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Perlick: Agreement (2010-SE-0109) Perlick: Agreement (2010-SE-0109) February 7, 2011 DOE and Perlick Residential & Hospitality Products entered into a Compromise Agreement in which Perlick agreed to pay a $5,000 civil penalty after DOE found that Perlick had manufactured and distributed in commerce in the U.S. model HP72ROO-S, a noncompliant refrigerator. The Compromise Agreement reflected the settlement terms between DOE and Perlick. Perlick: Agreement (2010-SE-0109) (240.67 KB) More

  2. SeQuential Biofuels LLC | Open Energy Information

    Open Energy Info (EERE)

    Biofuels LLC Jump to: navigation, search Name: SeQuential Biofuels LLC Place: Portland, Oregon Zip: 97231 Sector: Biofuels Product: A biofuels marketing and distribution company...

  3. Research Forum Schedule-Research-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Forum Schedule PHaSE Research Fora and Talks This webpage is provided for legacy archive purposes only, as of 30 April 2015.

  4. SE Idaho Load Service Update - June 10, 2015

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SE-Idaho-Load-Service-Update---June-10,-2015 Sign In About | Careers | Contact | Investors | bpa.gov Search Doing Business Expand Doing Business Customer Involvement Expand...

  5. CdSe self-assembled quantum dots with ZnCdMgSe barriers emitting throughout the visible spectrum

    SciTech Connect (OSTI)

    Perez-Paz, M. Noemi; Zhou Xuecong; Munoz, Martin; Lu Hong; Sohel, Mohammad; Tamargo, Maria C.; Jean-Mary, Fleumingue; Akins, Daniel L.

    2004-12-27

    Self-assembled quantum dots of CdSe with ZnCdMgSe barriers have been grown by molecular beam epitaxy on InP substrates. The optical and microstructural properties were investigated using photoluminescence (PL) and atomic force microscopy (AFM) measurements. Control and reproducibility of the quantum dot (QD) size leading to light emission throughout the entire visible spectrum range has been obtained by varying the CdSe deposition time. Longer CdSe deposition times result in a redshift of the PL peaks as a consequence of an increase of QD size. AFM studies demonstrate the presence of QDs in uncapped structures. A comparison of this QD system with CdSe/ZnSe shows that not only the strain but also the chemical properties of the system play an important role in QD formation.

  6. CdSe/ZnSe quantum dot structures grown by molecular beam epitaxy with a CdTe submonolayer stressor

    SciTech Connect (OSTI)

    Sedova, I. V. Lyublinskaya, O. G.; Sorokin, S. V.; Sitnikova, A. A.; Toropov, A. A.; Donatini, F.; Dang, Si Le; Ivanov, S. V.

    2007-11-15

    A procedure for formation of CdSe quantum dots (QDs) in a ZnSe matrix is suggested. The procedure is based on the introduction of a CdTe submonolayer stressor deposited on the matrix surface just before deposition of the material of the QDs. (For CdTe/ZnSe structure, the relative lattice mismatch is {delta}a/a {approx} 14%.) The stressor forms small strained islands at the ZnSe surface, thus producing local fields of high elastic stresses controlling the process of the self-assembling of the QDs. According to the data of transmission electron microscopy, this procedure allows a considerable increase in the surface density of QDs, with a certain decrease in their lateral dimensions (down to 4.5 {+-} 1.5 nm). In the photoluminescence spectra, a noticeable ({approx}150 meV) shift of the peak to longer wavelengths from the position of the reference CdSe/ZnSe QD structure is observed. The shift is due to some transformation of the morphology of the QDs and an increase in the Cd content in the QDs. Comprehensive studies of the nanostructures by recording and analyzing the excitation spectra of photoluminescence, the time-resolved photoluminescence spectra, and the cathodoluminescence spectra show that the emission spectra involve two types of optical transitions, namely, the type-I transitions in the CdSeTe/ZnSe QDs and the type-II transitions caused mainly by the low cadmium content (Zn,Cd)(Se,Te)/ZnSe layer formed between the QDs.

  7. Victory: Order (2015-SE-42033) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2015-SE-42033) Victory: Order (2015-SE-42033) October 27, 2015 DOE ordered Victory Refrigeration to pay a $1,600 civil penalty after finding Victory had manufactured and distributed in commerce in the U.S. at least 8 units of commercial refrigerator-freezer basic model RFS-1D-S1-EW-PT-HD, a noncompliant product. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Victory. Victory: Order (2015-SE-42033) (21.59 KB) More Documents & Publications

  8. Optical Probing of metamagnetic phases in epitaxial EuSe

    SciTech Connect (OSTI)

    Galgano, G. D.; Henriques, A. B.; Bauer, G.; Springholz, G.

    2011-12-23

    EuSe is a wide gap magnetic semiconductors with a potential for applications in proof-of-concept spintronic devices. When the temperature is lowered, EuSe goes through sharp transitions between a variety of magnetic phases and is thus described as metamagnetic. The purpose of the present investigation is to correlate the magnetic order to the sharp dichroic doublet, discovered recently in high quality thin epitaxial layers of EuSe, grown by molecular beam epitaxy. We report detailed measurements of the doublet positions and intensities as a function of magnetic field in low temperatures, covering several magnetic phases.

  9. Bu Sung: Order (2015-SE-42007) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2015-SE-42007) Bu Sung: Order (2015-SE-42007) October 13, 2015 DOE ordered Bu Sung America Corporation to pay a $71,480 civil penalty after finding Bu Sung had manufactured and distributed in commerce in the U.S. at least 361 units of basic model ESRF2, a noncompliant commercial refrigerator-freezer. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Bu Sung. Bu Sung: Order (2015-SE-42007) (123.64 KB) More Documents & Publications Bu Sung:

  10. AHT: Order (2015-SE-42031) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2015-SE-42031) AHT: Order (2015-SE-42031) March 9, 2016 DOE ordered AHT Cooling Systems, Inc. to pay a $179,040 civil penalty after finding AHT had manufactured and distributed in commerce in the U.S. at least 1,032 units of commercial refrigeration equipment model RIO S 68 L F, a noncompliant product. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and AHT. AHT: Order (2015-SE-42031) (66.05 KB) More Documents & Publications AHT: Proposed Penalty

  11. Optical Properties of CdSe Nanoparticle Assemblies

    SciTech Connect (OSTI)

    Huser, T; Gerion, D; Zaitseva, N; Krol, D M; Leon, F R

    2003-11-24

    We report on three-dimensional fluorescence imaging of micron-size faceted crystals precipitated from solutions of CdSe nanocrystals. Such crystals have previously been suggested to be superlattices of CdSe quantum dots [1,2]. Possible applications for these materials include their use in optical and optoelectronic devices. The micron-size crystals were grown by slow evaporation from toluene solutions of CdSe nanocrystals in the range of 3-6 nm, produced by traditional wet-chemistry techniques. By using a confocal microscope with laser illumination, three-dimensional raster-scanning and synchronized hyper-spectral detection, we have generated spatial profiles of the fluorescence emission intensity and spectrum. The fluorescence data of the micro-crystals were compared with spectra of individual nanocrystals obtained from the same solution. The results do not support the assertion that these microcrystals consist of CdSe superlattices.

  12. Synthesis and properties of new CdSe-AgI-As{sub 2}Se{sub 3} chalcogenide glasses

    SciTech Connect (OSTI)

    Kassem, M.; ULCO, LPCA, EAC CNRS 4493 F-59140 Dunkerque ; Le Coq, D.; Fourmentin, M.; Hindle, F.; Bokova, M.; Cuisset, A.; Masselin, P.; Bychkov, E.; ULCO, LPCA, EAC CNRS 4493 F-59140 Dunkerque

    2011-02-15

    Research highlights: {yields} Determination of the glass-forming region in the pseudo-ternary CdSe-AgI-As{sub 2}Se{sub 3} system. {yields} Characterization of macroscopic properties of the new CdSe-AgI-As{sub 2}Se{sub 3} glasses. {yields} Far infrared transmission of chalcogenide glasses. {yields} Characterization of the total conductivity of CdSe-AgI-As{sub 2}Se{sub 3} glasses. -- Abstract: The glass-forming region in the pseudo-ternary CdSe-AgI-As{sub 2}Se{sub 3} system was determined. Measurements including differential scanning calorimetry (DSC), density, and X-ray diffraction were performed. The effect resulting from the addition of CdSe or AgI has been highlighted by examining three series of different base glasses. The characteristic temperatures of the glass samples, including glass transition (T{sub g}), crystallisation (T{sub x}), and melting (T{sub m}) temperatures are reported and used to calculate their {Delta}T = T{sub x} - T{sub g} and their Hruby, H{sub r} = (T{sub x} - T{sub g})/(T{sub m} - T{sub x}), criteria. Evolution of the total electrical conductivity {sigma} and the room temperature conductivity {sigma}{sub 298} was also studied. The terahertz transparency domain in the 50-600 cm{sup -1} region was pointed for different chalcogenide glasses (ChGs) and the potential of the THz spectroscopy was suggested to obtain structural information on ChGs.

  13. Utility: Noncompliance Determination (2016-SE-42003) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noncompliance Determination (2016-SE-42003) Utility: Noncompliance Determination (2016-SE-42003) December 30, 2015 DOE issued a Notice of Noncompliance Determination to Utility Refrigerator finding that commercial refrigeration equipment basic model number PT-R-75-SS-3S-3S-N does not comport with the energy conservation standards. DOE determined the product was noncompliant based on DOE testing. Utility must immediately notify each person (or company) to whom Utility distributed the noncompliant

  14. Victory: Noncompliance Determination (2015-SE-42033) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noncompliance Determination (2015-SE-42033) Victory: Noncompliance Determination (2015-SE-42033) August 18, 2015 DOE issued a Notice of Noncompliance Determination to Victory Refrigeration finding that commercial refrigeration equipment basic model number RFS-1D-S1-EW-PT-HD (including each individual model within the basic model) does not comport with the energy conservation standards. DOE determined the product was noncompliant based on DOE testing. Victory must immediately notify each person

  15. Victory: Proposed Penalty (2015-SE-42033) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proposed Penalty (2015-SE-42033) Victory: Proposed Penalty (2015-SE-42033) September 25, 2015 DOE alleged in a Notice of Proposed Civil Penalty that Victory Refrigeration manufactured and distributed noncompliant commercial refrigerator-freezer model RFS-1D-S1-EW-PT-HD in the U.S. Federal law subjects manufacturers and private labelers to civil penalties if those parties distribute in the U.S. products that do not meet applicable energy conservation standards. This civil penalty notice advises

  16. True: Order (2015-SE-42049) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    True: Order (2015-SE-42049) True: Order (2015-SE-42049) February 4, 2016 DOE ordered True Manufacturing Co., Inc., to pay a $36,400 civil penalty after finding True had manufactured and distributed in commerce in the U.S. 182 units of True commercial refrigerator basic models TCGG-72 and TCGG-72-S, which did not meet the application energy conservation standard. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and True. Federal law subjects manufacturers and

  17. Haier: Compromise Agreement (2011-SE-1428) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compromise Agreement (2011-SE-1428) Haier: Compromise Agreement (2011-SE-1428) April 23, 2013 DOE and Haier America Trading, LLC entered into a Compromise Agreement to resolve a case involving the distribution in commerce of residential freezers that did not meet the applicable energy conservation performance standard. Haier agreed to ensure that no additional units of the noncompliant freezers will be distributed in commerce in the U.S. and not to use the same model numbers in the future.

  18. Bu Sung: Proposed Penalty (2015-SE-42007) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proposed Penalty (2015-SE-42007) Bu Sung: Proposed Penalty (2015-SE-42007) September 29, 2015 DOE alleged in a Notice of Proposed Civil Penalty that Bu Sung America Corporation d/b/a Everest Refrigeration manufactured and distributed noncompliant commercial refrigerator-freezers in the U.S. Federal law subjects manufacturers and private labelers to civil penalties if those parties distribute in the U.S. products that do not meet applicable energy conservation standards. This civil penalty notice

  19. The influence of interfaces on properties of thin-film inorganic structural isomers containing SnSeNbSe? Subunits

    SciTech Connect (OSTI)

    Alemayehu, Matti B.; Falmbigl, Matthias; Ta, Kim; Johnson, David C.

    2015-08-28

    Inorganic isomers ([SnSe]1+?)m(NbSe?)n([SnSe]1+?)p(NbSe?)q([SnSe]1+?)r(NbSe?)s where m, n, p, q, r, and s are integers and m + p + r = n + q + s = 4 were prepared using the modulated elemental reactant technique. This series of all six possible isomers provides an opportunity to study the influence of interface density on properties while maintaining the same unit cell size and composition. As expected, all six compounds were observed to have the same atomic compositions and an almost c-axis lattice parameter of ?4.90 (5) nm, with a slight trend in the c-axis lattice parameter correlated with the different number of interfaces in the isomers: two, four and six. The structures of the constituents in the ab-plane were independent of one another, confirming the nonepitaxial relationship between them. The temperature dependent electrical resistivities revealed metallic behavior for all the six compounds. Surprisingly, the electrical resistivity at room temperature decreases with increasing number of interfaces. Hall measurements suggest this results from changes in carrier concentration, which increases with increasing thickness of the thickest SnSe block in the isomer. Carrier mobility scales with the thickness of the thickest NbSe? block due to increased interfacial scattering as the NbSe? blocks become thinner. The observed behavior suggests that the two constituents serve different purposes with respect to electrical transport. SnSe acts as a charge donor and NbSe? acts as the charge transport layer. This separation of function suggests that such heterostructures can be designed to optimize performance through choice of constituent, layer thickness, and layer sequence. A simplistic model, which predicts the properties of the complex isomers from a weighted sum of the properties of

  20. Heterojunctions of model CdTe/CdSe mixtures

    SciTech Connect (OSTI)

    van Swol, Frank; Zhou, Xiaowang W.; Challa, Sivakumar R.; Martin, James E.

    2015-03-18

    We report on the strain behavior of compound mixtures of model group IIVI semiconductors. We use the StillingerWeber Hamiltonian that we recently introduced, specifically developed to model binary mixtures of group IIVI compounds such as CdTe and CdSe. We also employ molecular dynamics simulations to examine the behavior of thin sheets of material, bilayers of CdTe and CdSe. The lattice mismatch between the two compounds leads to a strong bending of the entire sheet, with about a 0.5 to 1 deflection between neighboring planes. To further analyze bilayer bending, we introduce a simple one-dimensional model and use energy minimization to find the angle of deflection. The analysis is equivalent to a least-squares straight line fit. We consider the effects of bilayers which are asymmetric with respect to the thickness of the CdTe and CdSe parts. We thus learn that the bending can be subdivided into four kinds depending on the compressive/tensile nature of each outer plane of the sheet. We use this approach to directly compare our findings with experimental results on the bending of CdTe/CdSe rods. To reduce the effects of the lattice mismatch we explore diffuse interfaces, where we mix (i.e. alloy) Te and Se, and estimate the strain response.

  1. Heterojunctions of model CdTe/CdSe mixtures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    van Swol, Frank; Zhou, Xiaowang W.; Challa, Sivakumar R.; Martin, James E.

    2015-03-18

    We report on the strain behavior of compound mixtures of model group II-VI semiconductors. We use the Stillinger-Weber Hamiltonian that we recently introduced, specifically developed to model binary mixtures of group II-VI compounds such as CdTe and CdSe. We also employ molecular dynamics simulations to examine the behavior of thin sheets of material, bilayers of CdTe and CdSe. The lattice mismatch between the two compounds leads to a strong bending of the entire sheet, with about a 0.5 to 1° deflection between neighboring planes. To further analyze bilayer bending, we introduce a simple one-dimensional model and use energy minimization tomore » find the angle of deflection. The analysis is equivalent to a least-squares straight line fit. We consider the effects of bilayers which are asymmetric with respect to the thickness of the CdTe and CdSe parts. We thus learn that the bending can be subdivided into four kinds depending on the compressive/tensile nature of each outer plane of the sheet. We use this approach to directly compare our findings with experimental results on the bending of CdTe/CdSe rods. To reduce the effects of the lattice mismatch we explore diffuse interfaces, where we mix (i.e. alloy) Te and Se, and estimate the strain response.« less

  2. Heterojunctions of model CdTe/CdSe mixtures

    SciTech Connect (OSTI)

    van Swol, Frank; Zhou, Xiaowang W.; Challa, Sivakumar R.; Martin, James E.

    2015-03-18

    We report on the strain behavior of compound mixtures of model group II-VI semiconductors. We use the Stillinger-Weber Hamiltonian that we recently introduced, specifically developed to model binary mixtures of group II-VI compounds such as CdTe and CdSe. We also employ molecular dynamics simulations to examine the behavior of thin sheets of material, bilayers of CdTe and CdSe. The lattice mismatch between the two compounds leads to a strong bending of the entire sheet, with about a 0.5 to 1° deflection between neighboring planes. To further analyze bilayer bending, we introduce a simple one-dimensional model and use energy minimization to find the angle of deflection. The analysis is equivalent to a least-squares straight line fit. We consider the effects of bilayers which are asymmetric with respect to the thickness of the CdTe and CdSe parts. We thus learn that the bending can be subdivided into four kinds depending on the compressive/tensile nature of each outer plane of the sheet. We use this approach to directly compare our findings with experimental results on the bending of CdTe/CdSe rods. To reduce the effects of the lattice mismatch we explore diffuse interfaces, where we mix (i.e. alloy) Te and Se, and estimate the strain response.

  3. EMPaSE: an Extensible Multi-Paradigm Simulation Environment

    Energy Science and Technology Software Center (OSTI)

    2010-08-05

    EMPaSE is a hierarchical, extensible, modular modeling environment for developing and running hybrid simulations of sequential-modular, systems dynamics, discrete-event, and agent-based paradigms. It contains two principle components: a multi-paradigm simulation engine and a graphical user interface. EMPaSE models are defined through a hierarchically-defined set of computational modules that define the simulation logic. Inter-module communication occurs through two complimentary systems: pull-based "ports" for general computation patterns and push-based "plugs" for event processing. Entities (i.e. agents) withinmore » the simulation operate within an abstract multi-network environment. The EMPaSE simulation engine is designed around a flexible plug-in architecture, allowing simulations to import computational modules, engine customizations, and interfaces to external applications from independent plug-in libraries. The EMPaSE GUI environment provides an environment for graphically constructing, executing, and debugging EMPaSE models. As with the simulation engine, the GUI is constructed on top of an extensible architecture that supports rapid customization of the user experience through external plug-in libraries.« less

  4. Reverse Monte Carlo simulation of Se{sub 80}Te{sub 20} and Se{sub 80}Te{sub 15}Sb{sub 5} glasses

    SciTech Connect (OSTI)

    Abdel-Baset, A. M.; Rashad, M.; Moharram, A. H.

    2013-12-16

    Two-dimensional Monte Carlo of the total pair distribution functions g(r) is determined for Se{sub 80}Te{sub 20} and Se{sub 80}Te{sub 15}Sb{sub 5} alloys, and then it used to assemble the three-dimensional atomic configurations using the reverse Monte Carlo simulation. The partial pair distribution functions g{sub ij}(r) indicate that the basic structure unit in the Se{sub 80}Te{sub 15}Sb{sub 5} glass is di-antimony tri-selenide units connected together through Se-Se and Se-Te chain. The structure of Se{sub 80}Te{sub 20} alloys is a chain of Se-Te and Se-Se in addition to some rings of Se atoms.

  5. Electrochemical solar cells using CdSe thin film electrodes

    SciTech Connect (OSTI)

    Xiao, Xu-Rui; Tien, H.Ti.

    1983-01-01

    Electrochemical photocells consisting of a CdSe thin film anode and a Pt cathode immersed in 1M Na/sub 2/S-NaOH-S solution have been studied. CdSe thin films were formed on Ti, Cr, Mo, SnO/sub 2/, glassy carbon, and graphite substrates by coating an aqueous mixture of CdSe, ZnCl/sub 2/, and surfactant, subsequently sintering at 400/sup 0/-500/sup 0/C in air. The current-voltage (I-V) relations, output power efficiency, open-circuit voltage, and short-circuit current were measured. Seven percent power conversion efficiency was obtained at 20 mW/cm/sup 2/ light intensity after photoetching. The monochromatic I-V curves were analyzed.

  6. Utility: Order (2016-SE-42003) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SE-42003) Utility: Order (2016-SE-42003) March 1, 2016 DOE ordered Utility Refrigerator to pay a $200 civil penalty after finding Utility manufactured and distributed in commerce in the U.S. 1 unit of a Utility brand commercial refrigerator, model PT-R-75-SS-3S-3S-N. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Utility. Federal law subjects manufacturers and private labelers to civil penalties if those parties distribute in the U.S. products that do

  7. Friedrich: Order (2014-SE-15010) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Order (2014-SE-15010) Friedrich: Order (2014-SE-15010) October 27, 2015 DOE ordered Friedrich Air Conditioning Co. to pay a civil penalty of $1,494,626.25 after finding Friedrich had manufactured and distributed in commerce in the U.S. 8,241 units of Friedrich model SQ10N10, a noncompliant room air conditioner. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Friedrich. Federal law subjects manufacturers and private labelers to civil penalties if those

  8. Excited-State Relaxation in PbSe Quantum Dots

    SciTech Connect (OSTI)

    An, J. M.; Califano, M.; Franceschetti, A.; Zunger, A.

    2008-01-01

    In solids the phonon-assisted, nonradiative decay from high-energy electronic excited states to low-energy electronic excited states is picosecond fast. It was hoped that electron and hole relaxation could be slowed down in quantum dots, due to the unavailability of phonons energy matched to the large energy-level spacings ('phonon-bottleneck'). However, excited-state relaxation was observed to be rather fast ({le}1 ps) in InP, CdSe, and ZnO dots, and explained by an efficient Auger mechanism, whereby the excess energy of electrons is nonradiatively transferred to holes, which can then rapidly decay by phonon emission, by virtue of the densely spaced valence-band levels. The recent emergence of PbSe as a novel quantum-dot material has rekindled the hope for a slow down of excited-state relaxation because hole relaxation was deemed to be ineffective on account of the widely spaced hole levels. The assumption of sparse hole energy levels in PbSe was based on an effective-mass argument based on the light effective mass of the hole. Surprisingly, fast intraband relaxation times of 1-7 ps were observed in PbSe quantum dots and have been considered contradictory with the Auger cooling mechanism because of the assumed sparsity of the hole energy levels. Our pseudopotential calculations, however, do not support the scenario of sparse hole levels in PbSe: Because of the existence of three valence-band maxima in the bulk PbSe band structure, hole energy levels are densely spaced, in contradiction with simple effective-mass models. The remaining question is whether the Auger decay channel is sufficiently fast to account for the fast intraband relaxation. Using the atomistic pseudopotential wave functions of Pb{sub 2046}Se{sub 2117} and Pb{sub 260}Se{sub 249} quantum dots, we explicitly calculated the electron-hole Coulomb integrals and the P {yields} S electron Auger relaxation rate. We find that the Auger mechanism can explain the experimentally observed P {yields} S

  9. Orbitally-driven giant phonon anharmonicity in SnSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Chen W.; Hong, Jiawang; May, Andrew F.; Bansal, Dipanshu; Chi, Songxue; Hong, Tao; Ehlers, Georg; Delaire, Olivier A.

    2015-10-19

    We understand that elementary excitations and their couplings in condensed matter systems is critical to develop better energy-conversion devices. In thermoelectric materials, the heat-to-electricity conversion efficiency is directly improved by suppressing the propagation of phonon quasiparticles responsible for macroscopic thermal transport. The material with the current record for thermoelectric conversion efficiency, SnSe, achieves an ultra-low thermal conductivity, but the mechanism enabling this strong phonon scattering remains largely unknown. Using inelastic neutron scattering measurements and first-principles simulations, we mapped the four-dimensional phonon dispersion surfaces of SnSe, and revealed the origin of ionic-potential anharmonicity responsible for the unique properties of SnSe. Wemore » show that the giant phonon scattering arises from an unstable electronic structure, with orbital interactions leading to a ferroelectric-like lattice instability. Our results provide a microscopic picture connecting electronic structure and phonon anharmonicity in SnSe, and offers precious insights on how electron-phonon and phononphonon interactions may lead to the realization of ultra-low thermal conductivity.« less

  10. Orbitally-driven giant phonon anharmonicity in SnSe

    SciTech Connect (OSTI)

    Li, Chen W.; Hong, Jiawang; May, Andrew F.; Bansal, Dipanshu; Chi, Songxue; Hong, Tao; Ehlers, Georg; Delaire, Olivier A.

    2015-10-19

    We understand that elementary excitations and their couplings in condensed matter systems is critical to develop better energy-conversion devices. In thermoelectric materials, the heat-to-electricity conversion efficiency is directly improved by suppressing the propagation of phonon quasiparticles responsible for macroscopic thermal transport. The material with the current record for thermoelectric conversion efficiency, SnSe, achieves an ultra-low thermal conductivity, but the mechanism enabling this strong phonon scattering remains largely unknown. Using inelastic neutron scattering measurements and first-principles simulations, we mapped the four-dimensional phonon dispersion surfaces of SnSe, and revealed the origin of ionic-potential anharmonicity responsible for the unique properties of SnSe. We show that the giant phonon scattering arises from an unstable electronic structure, with orbital interactions leading to a ferroelectric-like lattice instability. Our results provide a microscopic picture connecting electronic structure and phonon anharmonicity in SnSe, and offers precious insights on how electron-phonon and phononphonon interactions may lead to the realization of ultra-low thermal conductivity.

  11. Giant piezoelectricity of monolayer group IV monochalcogenides: SnSe, SnS, GeSe, and GeS

    SciTech Connect (OSTI)

    Fei, Ruixiang; Yang, Li; Li, Wenbin; Li, Ju

    2015-10-26

    We predict enormous, anisotropic piezoelectric effects in intrinsic monolayer group IV monochalcogenides (MX, M=Sn or Ge, X=Se or S), including SnSe, SnS, GeSe, and GeS. Using first-principle simulations based on the modern theory of polarization, we find that their piezoelectric coefficients are about one to two orders of magnitude larger than those of other 2D materials, such as MoS{sub 2} and GaSe, and bulk quartz and AlN which are widely used in industry. This enhancement is a result of the unique “puckered” C{sub 2v} symmetry and electronic structure of monolayer group IV monochalcogenides. Given the achieved experimental advances in the fabrication of monolayers, their flexible character, and ability to withstand enormous strain, these 2D structures with giant piezoelectric effects may be promising for a broad range of applications such as nano-sized sensors, piezotronics, and energy harvesting in portable electronic devices.

  12. Epitaxial growth of CZT(S,Se) on silicon

    DOE Patents [OSTI]

    Bojarczuk, Nestor A.; Gershon, Talia S.; Guha, Supratik; Shin, Byungha; Zhu, Yu

    2016-03-15

    Techniques for epitaxial growth of CZT(S,Se) materials on Si are provided. In one aspect, a method of forming an epitaxial kesterite material is provided which includes the steps of: selecting a Si substrate based on a crystallographic orientation of the Si substrate; forming an epitaxial oxide interlayer on the Si substrate to enhance wettability of the epitaxial kesterite material on the Si substrate, wherein the epitaxial oxide interlayer is formed from a material that is lattice-matched to Si; and forming the epitaxial kesterite material on a side of the epitaxial oxide interlayer opposite the Si substrate, wherein the epitaxial kesterite material includes Cu, Zn, Sn, and at least one of S and Se, and wherein a crystallographic orientation of the epitaxial kesterite material is based on the crystallographic orientation of the Si substrate. A method of forming an epitaxial kesterite-based photovoltaic device and an epitaxial kesterite-based device are also provided.

  13. American Ref-Fuel of SE CT Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Ref-Fuel of SE CT Biomass Facility Jump to: navigation, search Name American Ref-Fuel of SE CT Biomass Facility Facility American Ref-Fuel of SE CT Sector Biomass Facility Type...

  14. SpacePak: Proposed Penalty (2014-SE-16012) | Department of Energy

    Office of Environmental Management (EM)

    SpacePak: Proposed Penalty (2014-SE-16012) (19.1 KB) More Documents & Publications SpacePak: Noncompliance Determination (2014-SE-16012) SpacePak: Order (2014-SE-16012) Crane: ...

  15. Deformation potentials of CdSe quantum dots

    SciTech Connect (OSTI)

    Li, Jingbo; Wang, Lin-Wang

    2004-06-02

    The size dependent deformation potentials of CdSe quantum dots are studied by first principle and semi-empirical pseudopotentials calculations. They find that the amplitude of the quantum dot deformation potential is only slightly larger than the bulk value, and this increase is mostly caused by the off {Lambda} point deformation potentials in the bulk, which are larger in amplitude than the {Lambda} point deformation potential.

  16. Major UMass User Facilities-Resources-PHaSe-EFRC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major UMass User Facilities TRPL photo Researchers can access the capabilities of the various investigator interested in organic electronic materials, in PHaSE's original participating departments, and other centers and facilities, including the following: Materials Research Science & Engineering Center Center for Hierarchal Manufacturing High Field NMR Facility Mass Spectrometry Facility EPR Facility Keck Nanostructures Laboratory X-ray powder and single crystal diffraction Polymer

  17. Islandaire: Noncompliance Determination (2015-SE-43007) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 7) Islandaire: Noncompliance Determination (2015-SE-43007) February 25, 2016 DOE issued a Notice of Noncompliance Determination to Islandaire, Inc. finding that the Islandaire package terminal air conditioner basic model CPZ-09ANR1-B, which includes models EZ4209B and EZDR09B, does not comport with the applicable energy conservation standards. DOE determined the product was noncompliant based on DOE testing. Islandaire must immediately notify each person (or company) to whom it

  18. Islandaire: Noncompliance Determination (2015-SE-43008) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 8) Islandaire: Noncompliance Determination (2015-SE-43008) February 25, 2016 DOE issued a Notice of Noncompliance Determination to Islandaire, Inc. finding that the Islandaire package terminal air conditioner basic model CPZ-129ANR1-B, which includes model EZDR12B, does not comport with the applicable energy conservation standards. DOE determined the product was noncompliant based on DOE testing. Islandaire must immediately notify each person (or company) to whom it distributed the

  19. Islandaire: Noncompliance Determination (2015-SE-43009) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 9) Islandaire: Noncompliance Determination (2015-SE-43009) February 25, 2016 DOE issued a Notice of Noncompliance Determination to Islandaire, Inc. finding that the Islandaire package terminal air conditioner basic model CPZ-07ANR1-B, which includes model EZDR07B, does not comport with the applicable energy conservation standards. DOE determined the product was noncompliant based on DOE testing. Islandaire must immediately notify each person (or company) to whom it distributed the

  20. Quantum confined acceptors and donors in InSe nanosheets

    SciTech Connect (OSTI)

    Mudd, G. W.; Patan, A. Makarovsky, O.; Eaves, L.; Kudrynskyi, Z. R.; Kovalyuk, Z. D.; Fay, M. W.; Zlyomi, V.; Falko, V.

    2014-12-01

    We report on the radiative recombination of photo-excited carriers bound at native donors and acceptors in exfoliated nanoflakes of nominally undoped rhombohedral ?-polytype InSe. The binding energies of these states are found to increase with the decrease in flake thickness, L. We model their dependence on L using a two-dimensional hydrogenic model for impurities and show that they are strongly sensitive to the position of the impurities within the nanolayer.

  1. Middleware Automated Deployment Utilities - MRW Suite

    SciTech Connect (OSTI)

    Anderson, Mathew; Bowen, Brian; Coles, Dwight; Cleal, Thomas; Quarles, Elliott; Gurule, Kaitlyn; Kagie, Matthew

    2014-09-18

    The Middleware Automated Deployment Utilities consists the these three components: MAD: Utility designed to automate the deployment of java applications to multiple java application servers. The product contains a front end web utility and backend deployment scripts. MAR: Web front end to maintain and update the components inside database. MWR-Encrypt: Web utility to convert a text string to an encrypted string that is used by the Oracle Weblogic application server. The encryption is done using the built in functions if the Oracle Weblogic product and is mainly used to create an encrypted version of a database password.

  2. Middleware Automated Deployment Utilities - MRW Suite

    Energy Science and Technology Software Center (OSTI)

    2014-09-18

    The Middleware Automated Deployment Utilities consists the these three components: MAD: Utility designed to automate the deployment of java applications to multiple java application servers. The product contains a front end web utility and backend deployment scripts. MAR: Web front end to maintain and update the components inside database. MWR-Encrypt: Web utility to convert a text string to an encrypted string that is used by the Oracle Weblogic application server. The encryption is done usingmore » the built in functions if the Oracle Weblogic product and is mainly used to create an encrypted version of a database password.« less

  3. Pressure-dependent Optical Behaviors of Colloidal CdSe Nanoplatelets...

    Office of Scientific and Technical Information (OSTI)

    dependent Optical Behaviors of Colloidal CdSe Nanoplatelets Citation Details In-Document Search Title: Pressure-dependent Optical Behaviors of Colloidal CdSe Nanoplatelets Authors: ...

  4. Bi-Se doped with Cu, p-type semiconductor

    DOE Patents [OSTI]

    Bhattacharya, Raghu Nath; Phok, Sovannary; Parilla, Philip Anthony

    2013-08-20

    A Bi--Se doped with Cu, p-type semiconductor, preferably used as an absorber material in a photovoltaic device. Preferably the semiconductor has at least 20 molar percent Cu. In a preferred embodiment, the semiconductor comprises at least 28 molar percent of Cu. In one embodiment, the semiconductor comprises a molar percentage of Cu and Bi whereby the molar percentage of Cu divided by the molar percentage of Bi is greater than 1.2. In a preferred embodiment, the semiconductor is manufactured as a thin film having a thickness less than 600 nm.

  5. Phonon anharmonicity and negative thermal expansion in SnSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bansal, Dipanshu; Hong, Jiawang; Li, Chen W.; May, Andrew F.; Porter, Wallace; Hu, Michael Y.; Abernathy, Douglas L.; Delaire, Olivier

    2016-08-09

    In this paper, the anharmonic phonon properties of SnSe in the Pnma phase were investigated with a combination of experiments and first-principles simulations. Using inelastic neutron scattering (INS) and nuclear resonant inelastic X-ray scattering (NRIXS), we have measured the phonon dispersions and density of states (DOS) and their temperature dependence, which revealed a strong, inhomogeneous shift and broadening of the spectrum on warming. First-principles simulations were performed to rationalize these measurements, and to explain the previously reported anisotropic thermal expansion, in particular the negative thermal expansion within the Sn-Se bilayers. Including the anisotropic strain dependence of the phonon free energy,more » in addition to the electronic ground state energy, is essential to reproduce the negative thermal expansion. From the phonon DOS obtained with INS and additional calorimetry measurements, we quantify the harmonic, dilational, and anharmonic components of the phonon entropy, heat capacity, and free energy. Finally, the origin of the anharmonic phonon thermodynamics is linked to the electronic structure.« less

  6. Thermodynamic properties of model CdTe/CdSe mixtures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    van Swol, Frank; Zhou, Xiaowang W.; Challa, Sivakumar R.; Martin, James E.

    2015-02-20

    We report on the thermodynamic properties of binary compound mixtures of model groups II–VI semiconductors. We use the recently introduced Stillinger–Weber Hamiltonian to model binary mixtures of CdTe and CdSe. We use molecular dynamics simulations to calculate the volume and enthalpy of mixing as a function of mole fraction. The lattice parameter of the mixture closely follows Vegard's law: a linear relation. This implies that the excess volume is a cubic function of mole fraction. A connection is made with hard sphere models of mixed fcc and zincblende structures. We found that the potential energy exhibits a positive deviation frommore » ideal soluton behaviour; the excess enthalpy is nearly independent of temperatures studied (300 and 533 K) and is well described by a simple cubic function of the mole fraction. Using a regular solution approach (combining non-ideal behaviour for the enthalpy with ideal solution behaviour for the entropy of mixing), we arrive at the Gibbs free energy of the mixture. The Gibbs free energy results indicate that the CdTe and CdSe mixtures exhibit phase separation. The upper consolute temperature is found to be 335 K. Finally, we provide the surface energy as a function of composition. Moreover, it roughly follows ideal solution theory, but with a negative deviation (negative excess surface energy). This indicates that alloying increases the stability, even for nano-particles.« less

  7. Photoluminescence study of the substitution of Cd by Zn during the growth by atomic layer epitaxy of alternate CdSe and ZnSe monolayers

    SciTech Connect (OSTI)

    Hernndez-Caldern, I.; Salcedo-Reyes, J. C.

    2014-05-15

    We present a study of the substitution of Cd atoms by Zn atoms during the growth of alternate ZnSe and CdSe compound monolayers (ML) by atomic layer epitaxy (ALE) as a function of substrate temperature. Samples contained two quantum wells (QWs), each one made of alternate CdSe and ZnSe monolayers with total thickness of 12 ML but different growth parameters. The QWs were studied by low temperature photoluminescence (PL) spectroscopy. We show that the Cd content of underlying CdSe layers is affected by the exposure of the quantum well film to the Zn flux during the growth of ZnSe monolayers. The amount of Cd of the quantum well film decreases with higher exposures to the Zn flux. A brief discussion about the difficulties to grow the Zn{sub 0.5}Cd{sub 0.5}Se ordered alloy (CuAu-I type) by ALE is presented.

  8. Magnetooptical study of CdSe/ZnMnSe semimagnetic quantum-dot ensembles with n-type modulation doping

    SciTech Connect (OSTI)

    Reshina, I. I. Ivanov, S. V.

    2014-12-15

    Magnetic and polarization investigations of the photoluminescence and resonant electron spin-flip Raman scattering in ensembles of self-organized CdSe/ZnMnSe semimagnetic quantum dots with n-type modulation doping are carried out. It is demonstrated that exciton transitions contribute to the photoluminescence band intensity, along with the transitions of trions in the singlet state. In the Hanle-effect measurements, negative circular polarization in zero magnetic field is observed, which is related to the optical orientation of a trion heavy hole. The lifetime and spin-relaxation time of a heavy hole are estimated as ?3 and ?1 ps, respectively. Such short times are assumed to be due to Auger recombination with the excitation of an intrinsic transition in a Mn{sup 2+} ion. Investigations of the photoluminescence-maximum intensity and shift in a longitudinal magnetic field at the ?{sup ?}?{sup +} and ?{sup ?}?{sup ?} polarizations reveal the pronounced spin polarization of electrons. Under resonant excitation conditions, a sharp increase in the photoluminescence-band maximum intensity at ?{sup ?} excitation polarization over the ?{sup +} one is observed. The Raman scattering peak at the electron spin-flip transition is observed upon resonant excitation in a transverse magnetic field in crossed linear polarizations. This peak is shown to be a Brillouin function of a magnetic field.

  9. Synthesis, structural, optical and Raman studies of pure and lanthanum doped ZnSe nanoparticles

    SciTech Connect (OSTI)

    Kumar, Pushpendra; Singh, Jai; Pandey, Mukesh Kumar; Jeyanthi, C.E.; Siddheswaran, R.; Paulraj, M.; Hui, K.N.; Hui, K.S.

    2014-01-01

    Graphical abstract: - Highlights: • Template-free synthesis of ZnSe and ZnSe:La nanoparticles was developed at low temperature 100 °C. • Cubic ZnSe and ZnSe:La nanoparticles were obtained by chemical route. • As-synthesized ZnSe:La nanoparticles showed higher emission intensity than ZnSe nanoparticles. • Band gap (E{sub g}) of ZnSe nanoparticles was bigger than ZnSe nanoparticles due to nanosized effect. - Abstract: In this work, a simple, effective and reproducible chemical synthetic route for the production of high-quality, pure ZnSe nanoparticles (NPs), and lanthanum-doped ZnSe (ZnSe:La) NPs is presented. The wide bandgap, luminescent pure ZnSe and ZnSe:La NPs has been synthesized at a low temperature (100 °C) in a single template-free step. The size and optical bandgap of the NPs was analyzed from powder X-ray diffraction (XRD), UV–visible (UV–vis) spectroscopy, transmission electron microscopy (TEM), and high resolution transmission electron microscopy (HRTEM). A broad photoluminescence (PL) emission across the visible spectrum has been demonstrated by a systematic blue-shift in emission due to the formation of small nanoparticles. Here, contribution to emission intensity from surface states of NPs increases with La doping. TEM data revealed that the average size of ZnSe and ZnSe:La NPs is 14 and 8 nm, respectively. On the other hand, band gap energy E{sub g} of ZnSe and ZnSe:La NPs were found to be 3.59 eV and 3.65 eV, respectively. Results showed that hydrazine hydrate played multiple roles in the formation of ZnSe and ZnSe:La NPs. A possible reaction mechanism for the growth of NPs is also discussed.

  10. The new misfit compound (BiSe){sub 1.15}(TiSe{sub 2}){sub 2} and the role of dimensionality in the Cu{sub x}(BiSe){sub 1+δ}(TiSe{sub 2}){sub n} series

    SciTech Connect (OSTI)

    Trump, Benjamin A.; Livi, Kenneth J.T.; McQueen, Tyrel M.

    2014-01-15

    The synthesis and physical properties of the new misfit compound (BiSe){sub 1.15}(TiSe{sub 2}){sub 2} are reported. Transmission electron microscopy and powder X-ray diffraction show that the structure consists of alternating rock-salt type BiSe layers and hexagonal (TiSe{sub 2}){sub 2} double layers. Resistivity, specific heat, and magnetization measurements show that it has metallic and diamagnetic behaviors. These results are interpreted and discussed in the context of the transition between single-layer (BiSe){sub 1.13}(TiSe{sub 2}), which shows no charge density wave, and infinite-layered (bulk) 1T-TiSe{sub 2}, which undergoes a charge density wave transition at T=202 K. Intercalation with copper, Cu{sub x}(BiSe){sub 1.15}(TiSe{sub 2}){sub 2}, (0≤x≤0.10) is also reported, but unlike Cu{sub x}TiSe{sub 2}, no superconductivity is observed down to T=0.05 K. Thus, the series Cu{sub x}(BiSe){sub 1+δ}(TiSe{sub 2}){sub n} provides an effective approach to elucidate the impact of dimensionality on charge density wave formation and superconductivity. - Graphical abstract: The newly discovered misfit compound (BiSe){sub 1.15}(TiSe{sub 2}){sub 2} shown in the series (BiSe){sub 1+δ}(TiSe{sub 2}){sub n}. Display Omitted - Highlights: • Reports the structure and properties of the new misfit compound (BiSe){sub 1.15}(TiSe{sub 2}){sub 2}. • The structure consists of a rock salt type BiSe layer and a double (TiSe{sub 2}){sub 2} layer. • The n=1, 2 misfits (BiSe){sub 1+δ}(TiSe{sub 2}){sub n} are found not to exhibit CDW transitions. • Evidence is presented that there is likely a low-lying CDW excited state. • The series Cu{sub x}(BiSe){sub 1+δ}(TiSe{sub 2}){sub 2} does not superconduct, unlike Cu{sub x}TiSe{sub 2}.

  11. Detection of a MoSe{sub 2} secondary phase layer in CZTSe by spectroscopic ellipsometry

    SciTech Connect (OSTI)

    Demircioğlu, Özden; Riedel, Ingo; Gütay, Levent; Mousel, Marina; Redinger, Alex; Rey, Germain; Weiss, Thomas; Siebentritt, Susanne

    2015-11-14

    We demonstrate the application of Spectroscopic Ellipsometry (SE) for identification of secondary phase MoSe{sub 2} in polycrystalline Cu{sub 2}ZnSnSe{sub 4} (CZTSe) samples. A MoSe{sub 2} reference sample was analyzed, and its optical constants (ε{sub 1} and ε{sub 2}) were extracted by SE analysis. This dataset was implemented into an optical model for analyzing SE data from a glass/Mo/CZTSe sample containing MoSe{sub 2} at the back side of the absorber. We present results on the n and k values of CZTSe and show the extraction of the thickness of the secondary phase MoSe{sub 2} layer. Raman spectroscopy and scanning electron microscopy were applied to confirm the SE results.

  12. Intersubband absorption in CdSe/Zn{sub x}Cd{sub y}Mg{sub 1-x-y}Se self-assembled quantum dot multilayers

    SciTech Connect (OSTI)

    Shen, A.; Lu, H.; Charles, W.; Yokomizo, I.; Tamargo, M. C.; Franz, K. J.; Gmachl, C.; Zhang, S. K.; Zhou, X.; Alfano, R. R.; Liu, H. C.

    2007-02-12

    The authors report the observation of intersubband absorption in multilayers of CdSe/Zn{sub x}Cd{sub y}Mg{sub 1-x-y}Se self-assembled quantum dots. The samples were grown by molecular beam epitaxy on InP substrates. For samples with the CdSe dot layers doped with Cl and with the deposited CdSe equivalent layer thickness between 5.2 and 6.9 ML, peak absorption between 2.5 and 3.5 {mu}m was observed. These materials are promising for intersubband devices operating in the mid- and near-infrared ranges.

  13. SE Gobe: Papua New Guinea`s second oil development

    SciTech Connect (OSTI)

    Langston, M.V.; McCaul, T.R.; Fitzmorris, R.E.

    1994-12-31

    A reservoir development plan was developed from a detailed geological model of the SE Gobe Iagifu reservoir. This model incorporated sequence stratigraphy and extensive core and log analysis to provide the detailed layering framework for reservoir simulation. Cross-sectional balancing techniques were applied to field derived dip and strike, dipmeter log, and RFT data to obtain a structural model for the reservoir. Cross-sectional, sector and, finally, full field reservoir simulation models were constructed and used by the team to generate a reservoir development and management plan. The simulation models were used to examine the relative merits of vertical, deviated and horizontal wells, well placement, offtake rates, gas compression requirements and pressure maintenance strategies. Due to the uncertainty in the size and shape of the field, development options were considered at each of three reserve levels: proven, probable and possible. The simulation results showed that well rates should be held to less than 8,000 stb/d and that horizontal wells, with a length of at least 700 m, generally out-performed vertical wells. Oil recovery ranged between 34 and 45% of OOIP. The cases offering the best recoveries included both water injection and horizontal wells.

  14. Pulsed laser deposition of Mn doped CdSe quantum dots for improved...

    Office of Scientific and Technical Information (OSTI)

    Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance Citation Details In-Document Search Title: Pulsed laser deposition of Mn doped CdSe ...

  15. Thermal stability and photoconductive properties of photosensors with an alternating multilayer structure of amorphous Se and As{sub x}Se{sub 1−x}

    SciTech Connect (OSTI)

    Yu, Tung-Yuan; Pan, Fu-Ming Chang, Cheng-Yi; Lin, Jian-Siang; Huang, Wen-Hsien

    2015-07-28

    In this study, we fabricated a-Se based photosensors with an alternating multilayer structure of a-Se and As{sub x}Se{sub 1−x} by rotational thermal evaporation deposition. During the deposition of the amorphous As{sub x}Se{sub 1−x} layers, As diffuses into the underlying a-Se component layers, thereby improving the thermal stability of the multilayer photosensor and thus increasing the breakdown electric field. Although the As doping introduces carrier traps in the a-Se layers, the multilayer photosensors demonstrate an effective quantum efficiency comparable to the single-layered a-Se sensor under the blue light illumination but are with a lower dark current density by two orders of magnitude. In addition to the top As{sub x}Se{sub 1−x} layer being functioning as an electron blocking layer, carrier traps present in the multilayer structure may decrease the drift mobility of charge carriers and disturb electric field distribution in the photosensors, thereby suppressing the dark current.

  16. The US/SE Program Offices' FY 2016 Congressional Budget Request |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy The US/SE Program Offices' FY 2016 Congressional Budget Request The US/SE Program Offices' FY 2016 Congressional Budget Request Figure 2.1: The US/SE Program Offices' FY 2016 Congressional Budget Request (SEP, page 19) Figure 2.1: The US/SE Program Offices' FY 2016 Congressional Budget Request (SEP, page 19) The Under Secretary for Science and Energy (US/SE) program offices lead the Department's engagement in transformative science, technology innovation, and market

  17. T-537: Oracle Critical Patch Update Advisory- January 2011

    Broader source: Energy.gov [DOE]

    A Critical Patch Update is a collection of patches for multiple security vulnerabilities. It also includes non-security fixes that are required because of interdependencies by those security patches. Critical Patch Updates are cumulative.

  18. T-605: Oracle Critical Patch Update Advisory- April 2011

    Broader source: Energy.gov [DOE]

    A Critical Patch Update is a collection of patches for multiple security vulnerabilities. It also includes non-security fixes that are required because of interdependencies by those security patches. Critical Patch Updates are cumulative.

  19. Elastic and surface energies: Two key parameters for CdSe quantum dot formation

    SciTech Connect (OSTI)

    Robin, Ivan-Christophe; Andre, Regis; Bougerol, Catherine; Aichele, Thomas; Tatarenko, Serge

    2006-06-05

    The two-dimensional-three-dimensional transition of a strained CdSe layer on (001) ZnSe induced by the use of amorphous selenium is studied. To precisely control the thickness of the CdSe layer, atomic layer epitaxy growth mode is used. Atomic force microscopy and reflection high-energy electron diffraction measurements reveal the formation of CdSe islands when 3 ML (monolayers) of CdSe, corresponding to the critical thickness, are deposited. When only 2.5 ML of CdSe are deposited another relaxation mechanism is observed, leading to the appearance of strong undulations on the surface. For a 3 ML thick CdSe layer, transmission electron microscopy images indicate that the formation of the islands occurs only after the amorphous selenium desorption.

  20. Method of synthesizing and growing copper-indium-diselenide (CuInSe.sub.2) crystals

    DOE Patents [OSTI]

    Ciszek, Theodore F.

    1987-01-01

    A process for preparing CuInSe.sub.2 crystals includes melting a sufficient quantity of B.sub.2 O.sub.3 along with stoichiometric quantities of Cu, In, and Se in a crucible in a high pressure atmosphere of inert gas to encapsulate the CuInSe.sub.2 melt and confine the Se to the crucible. Additional Se in the range of 1.8 to 2.2 percent over the stoichiometric quantity is preferred to make up for small amounts of Se lost in the process. The crystal is grown by inserting a seed crystal through the B.sub.2 O.sub.3 encapsulate into contact with the CuInSe.sub.2 melt and withdrawing the seed upwardly to grow the crystal thereon from the melt.

  1. Method of synthesizing and growing copper-indium-diselenide (CuInSe/sub 2/) crystals

    DOE Patents [OSTI]

    Ciszek, T.F.

    1984-11-29

    A process for preparing CuInSe/sub 2/ crystals includes melting a sufficient quantity of B/sub 2/O/sub 2/ along with stochiometric quantities of Cu, In, and Se in a crucible in a high-pressure atmosphere of inert gas to encapsulate the CuInSe/sub 2/ melt and confine the Se to the crucible. Additional Se in the range of 1.8 to 2.2% over the stochiometric quantity is preferred to make up for small amounts of Se lost in the process. The melt can then be cooled slowly to form the crystal as direct solidification, or the crystal can be grown by inserting a seed crystal through the B/sub 2/O/sub 3/ encapsulate into contact with the CuInSe/sub 2/ melt and withdrawing the seed upwardly to grow the crystal thereon from the melt.

  2. JavaScript Archives - Nercenergy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tips for Understanding the Relationship Between a Web Application and SLAs At the heart of ... Web Application Monitoring - How it Can Help Just because your web app is online, doesn't ...

  3. Electrical properties of In{sub 2}Se{sub 3} single crystals and photosensitivity of Al/In{sub 2}Se{sub 3} Schottky barriers

    SciTech Connect (OSTI)

    Bodnar, I. V.; Ilchuk, G. A.; Petrus', R. Yu.; Rud', V. Yu.; Rud', Yu. V.; Serginov, M.

    2009-09-15

    In{sub 2}Se{sub 3} single crystals {approx}40 mm long and 14 mm in diameter were grown by the Bridgman method. The composition of grown single crystals and their crystal structure were determined. The conductivity ({sigma}) and Hall constant (R) of grown single crystals were measured and the first Schottky barriers Al/n-In{sub 2}Se{sub 3} were fabricated. Rectification and photovoltaic effect were detected in the new structures. Based on the study of the photosensitivity spectra of Al/n-In{sub 2}Se{sub 3} structures, the nature of the interband transitions and band gap of In{sub 2}Se{sub 3} crystals were determined. It was concluded that the new structures can be applied to develop broadband photoconverters of optical radiation.

  4. Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance

    SciTech Connect (OSTI)

    Dai, Qilin; Wang, Wenyong E-mail: jtang2@uwyo.edu; Tang, Jinke E-mail: jtang2@uwyo.edu; Sabio, Erwin M.

    2014-05-05

    In this work, we demonstrate (1) a facile method to prepare Mn doped CdSe quantum dots (QDs) on Zn{sub 2}SnO{sub 4} photoanodes by pulsed laser deposition and (2) improved device performance of quantum dot sensitized solar cells of the Mn doped QDs (CdSe:Mn) compared to the undoped QDs (CdSe). The band diagram of photoanode Zn{sub 2}SnO{sub 4} and sensitizer CdSe:Mn QD is proposed based on the incident-photon-to-electron conversion efficiency (IPCE) data. Mn-modified band structure leads to absorption at longer wavelengths than the undoped CdSe QDs, which is due to the exchange splitting of the CdSe:Mn conduction band by the Mn dopant. Three-fold increase in the IPCE efficiency has also been observed for the Mn doped samples.

  5. PHaSE | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    PHaSE Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers PHaSE Print Text Size: A A A FeedbackShare Page Polymer-Based Materials for Harvesting Solar Energy (PHaSE) Director(s): Thomas P. Russell and Paul M. Lahti Lead Institution: University of Massachusetts, Amherst Years: 2009-2014 Mission: To carry out fundamental photovoltaic-oriented research on the use of

  6. The PHaSE Photovoltaic & Optical Spectroscopy Facility Facility Director: Dr. Volodimyr Duzhko

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ! 32 The PHaSE Photovoltaic & Optical Spectroscopy Facility Facility Director: Dr. Volodimyr Duzhko The central facilities of the DOE-supported Energy Frontier Research Center "Polymer-Based Materials for Harvesting Solar Energy" (PHaSE) are housed in 1305 sq ft of newly renovated space, Rooms B523 and B524 of the Silvio O. Conte National Center for Polymer Research. The renovation was carried out with EFRC PHaSE ARRA funding. These facilities provide the PHaSE members and external

  7. Flow of US/SE Program Funding to National Laboratories (FY 2014 Enacted) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Flow of US/SE Program Funding to National Laboratories (FY 2014 Enacted) Flow of US/SE Program Funding to National Laboratories (FY 2014 Enacted) Figure 4.2: Flow of US/SE Program Funding to National Laboratories—FY 2014 Enacted (SEP, page 157) Figure 4.2: Flow of US/SE Program Funding to National Laboratories-FY 2014 Enacted (SEP, page 157) This figure illustrates the flow of funding to each of 17 DOE National Laboratories from five of the six Under Secretary for

  8. A Novel and Functional Single Layer Sheet of ZnSe (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    A Novel and Functional Single Layer Sheet of ZnSe Citation ... In this Communication, we report a novel singlelayer sheet ... Type: Accepted Manuscript Journal Name: ACS Applied ...

  9. SE HAN FINALIZADO LOS PREPARATIVOS PARA LA CONFERENCIA NACIONAL DE JUSTICIA MEDIOAMBIENTAL Y PROGRAMA DE FORMACIÓN 2013

    Broader source: Energy.gov [DOE]

    La National Environmental Justice Conference, Inc. (Conferencia de Justicia Medioambiental) se prepara para otro exitoso acontecimiento, ya que se aproxima la Conferencia Nacional de Justicia...

  10. Differences in chemical doping matter: Superconductivity in Ti1-xTaxSe2 but not in Ti1-xNbxSe2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Huixia; Zhu, Yimei; Xie, Weiwei; Tao, Jing; Pletikosic, Ivo; Valla, Tonica; Sahasrabudhe, Girija S.; Osterhoudt, Gavin; Sutton, Eric; Burch, Kenneth S.; et al

    2016-02-21

    We report that 1T-TiSe2, an archetypical layered transition metal dichalcogenide, becomes superconducting when Ta is substituted for Ti but not when Nb is substituted for Ti. This is unexpected because Nb and Ta should be chemically equivalent electron donors. Superconductivity emerges near x = 0.02 for Ti1–xTaxSe2, while, for Ti1–xNbxSe2, no superconducting transitions are observed above 0.4 K. The equivalent chemical nature of the dopants is confirmed by X-ray photoelectron spectroscopy. ARPES and Raman scattering studies show similarities and differences between the two systems, but the fundamental reasons why the Nb and Ta dopants yield such different behavior are unknown.more » We present a comparison of the electronic phase diagrams of many electron-doped 1T-TiSe2 systems, showing that they behave quite differently, which may have broad implications in the search for new superconductors. Here, we propose that superconducting Ti0.8Ta0.2Se2 will be suitable for devices and other studies based on exfoliated crystal flakes.« less

  11. Development of a Low Cost Insulated Foil Substrate for Cu(InGaSe)2 Photovoltaics

    SciTech Connect (OSTI)

    ERTEN ESER

    2012-01-22

    The project validated the use of stainless steel flexible substrate coated with silicone-based resin dielectric, developed by Dow Corning Corporation, for Cu(InGa)Se2 based photovoltaics. The projects driving force was the high performance of Cu(InGa)Se2 based photovoltaics coupled with potential cost reduction that could be achieved with dielectric coated SS web substrate.

  12. Ligand-Mediated Modification of the Electronic Structure of CdSe Quantum Dots

    SciTech Connect (OSTI)

    Lee, Jonathan R.; Whitley, Heather D.; Meulenberg, Robert W.; Wolcott, Abraham; Zhang, Jin Z.; Prendergast, Peter; Lovingood, Derek D.; Strouse, Geoffrey F.; Ogitsu, Tadashi; Schwegler, Eric; Terminello, Louis J.; Van Buuren, Tony W.

    2012-05-18

    X-ray absorption spectroscopy and ab initio modeling of the experimental spectra have been used to investigate the effects of surface passivation on the unoccupied electronic states of CdSe quantum dots (QDs). Significant differences are observed in the unoccupied electronic structure of the CdSe QDs, which are shown to arise from variations in specific ligand-surface bonding interactions.

  13. Surface Plasmon Excitation via Au Nanoparticles in CdSe Semiconductor

    SciTech Connect (OSTI)

    Pradhan, A. K.; Konda, R. B.; Mundle, R.; Mustafa, H.; Bamiduro, O.; Roy, U. N.; Cui, Y.; Burger, A.

    2008-10-23

    We present experimental evidence for the large Raman and photoluminescence enhancement in CdSe semiconductor films grown on Si and glass substrates due to excitation of surface plasmon resonances in proximate gold metal nanoparticles deposited on the surface of CdSe film. Heterojunction diodes containing n-CdSe on p-Si semiconductor were fabricated and the surface of the diodes was in situ coated with Au nanoparticles using the ultra-high vacuum pulsed-laser deposition technique. A significant enhancement of the photocurrent was obtained in CdSe/p-Si containing Au nanoparticles on the surface compared to CdSe/p-Si due to the enhanced photo-absorption within the semiconductor by the phenomenon of surface plasmon resonance. These observations suggest a variety of approaches for improving the performance of devices such as photodetectors, photovoltaic, and related devices, including biosensors.

  14. Glass formation and the third harmonic generation of Cu{sub 2}Se–GeSe{sub 2}–As{sub 2}Se{sub 3} glasses

    SciTech Connect (OSTI)

    Reshak, A. H.; Klymovych, O. S.; Zmiy, O. F.; Myronchuk, G. L.; Zamuruyeva, O. V.; Alahmed, Z. A.; Chyský, J.; Bila, Jiri; Kamarudin, H.

    2014-10-14

    We have performed the investigation of the nonlinear optical properties namely the third harmonic generation (THG) of the glass-formation region in the Cu{sub 2}Se–GeSe{sub 2}–As{sub 2}Se{sub 3} system. The samples were synthesized by direct single-temperature method from high-purity elementary substances. We have found that the value of disorder parameter Δ depends on the composition of the glassy alloys. The measurements show that increasing the Cu{sub 2}Se concentration leads to increased slope of the absorption edge, which may be explained by the decrease of the height of random potential relief for the electrons in the tails of the state density which border the band edges. A very sharp increase in the THG at low temperature was observed. Significant enhancement in THG was obtained with decreasing the energy gap, which agreed well with the nonlinear optical susceptibilities obtained from other glasses.

  15. Inherent room temperature ferromagnetism and dopant dependent Raman studies of PbSe, Pb{sub 1−x}Cu{sub x}Se, and Pb{sub 1−x}Ni{sub x}Se

    SciTech Connect (OSTI)

    Gayner, Chhatrasal; Kar, Kamal K.

    2015-03-14

    Polycrystalline lead selenide (PbSe) doped with copper (Cu) and nickel (Ni) was prepared to understand its magnetic behaviour and Raman activity. The processing conditions, influence of dopants (magnetically active and non-active) and their respective compositions on the magnetic properties and Raman active mode were studied. A surprising/anomalous room temperature ferromagnetism (hysteresis loop) is noticed in bulk diamagnetic PbSe, which is found to be natural or inherent characteristic of material, and depends on the crystallite size, dopant, and developed strain due to dopant/defects. The magnetic susceptibility (−1.71 × 10{sup −4} emu/mol Oe) and saturated magnetic susceptibility (−2.74 × 10{sup −4} emu/mol Oe) are found to be higher than the earlier reported value (diamagnetic: −1.0 × 10{sup −4} emu/mol Oe) in bulk PbSe. With increase of Cu concentration (2% to 10%) in PbSe, the saturated magnetic susceptibility decreases from −1.22 × 10{sup −4} to −0.85 × 10{sup −4} emu/mol Oe. Whereas for Ni dopant, the saturated magnetic susceptibility increases to −2.96 × 10{sup −4} emu/mol Oe at 2% Ni doped PbSe. But it further decreases with dopant concentration. In these doped PbSe, the shifting of longitudinal (LO) phonon mode was also studied by the Raman spectroscopy. The shifting of LO mode is found to be dopant dependent, and the frequency shift of LO mode is associated with the induced strain that created by the dopants and vacancies. This asymmetry in LO phonon mode (peak shift and shape) may be due to the intraband electronic transition of dopants. The variation in magnetic susceptibility and Raman shifts are sensitive to crystallite size, nature of dopant, concentration of dopants, and induced strain due to dopants.

  16. Probing the size and environment induced phase transformation in CdSe quantum dots

    SciTech Connect (OSTI)

    Karakoti, Ajay S.; Sanghavi, Shail P.; Nachimuthu, Ponnusamy; Yang, Ping; Thevuthasan, Suntharampillai

    2011-11-17

    The structural and electronic properties of CdSe quantum dots in toluene and drop-casted on Si wafer were investigated by in-situ micro X-ray diffraction, X-ray photoelectron spectroscopy and UV-Vis absorption and emission spectroscopy. The in-situ micro diffraction data show that the CdSe quantum dots capped with TOPO or hexadecylamine (HDA) in toluene exhibit predominantly wurtzite crystal structure, which undergoes a phase transformation to zinc blende crystal structure following drop casting on Si and this phase transition increases with decreasing the size of the CdSe quantum dots. Decreasing the size of quantum dots also increases the Se vacancies that facilitate the phase transformation. The X-ray photoelectron spectra show a systematic increase in the core level binding energies of Cd 3d and Se 3d, the band gap and the Cd/Se ratio as the size of the quantum dots decreases from 6.6nm to 2.1nm. This is attributed to the quantum confinement of CdSe crystallites by the capping ligands in toluene which increases with decreasing the size of the quantum dots. However, drop-casting quantum dots on Si alter the density and arrangement of capping ligands and solvent molecules on the quantum dots which causes significant phase transformation.

  17. Structural phase transitions in Bi2Se3 under high pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Zhenhai; Gu, Genda; Wang, Lin; Hu, Qingyang; Zhao, Jinggeng; Yan, Shuai; Yang, Ke; Sinogeikin, Stanislav; Mao, Ho -kwang

    2015-11-02

    Raman spectroscopy and angle dispersive X-ray diffraction (XRD) experiments of bismuth selenide (Bi2Se3) have been carried out to pressures of 35.6 and 81.2 GPa, respectively, to explore its pressure-induced phase transformation. The experiments indicate that a progressive structural evolution occurs from an ambient rhombohedra phase (Space group (SG): R-3m) to monoclinic phase (SG: C2/m) and eventually to a high pressure body-centered tetragonal phase (SG: I4/mmm). Evidenced by our XRD data up to 81.2 GPa, the Bi2Se3 crystallizes into body-centered tetragonal structures rather than the recently reported disordered body-centered cubic (BCC) phase. Furthermore, first principles theoretical calculations favor the viewpoint thatmore » the I4/mmm phase Bi2Se3 can be stabilized under high pressure (>30 GPa). Remarkably, the Raman spectra of Bi2Se3 from this work (two independent runs) are still Raman active up to ~35 GPa. Furthermore, it is worthy to note that the disordered BCC phase at 27.8 GPa is not observed here. The remarkable difference in atomic radii of Bi and Se in Bi2Se3 may explain why Bi2Se3 shows different structural behavior than isocompounds Bi2Te3 and Sb2Te3.« less

  18. An oleic acid-capped CdSe quantum-dot sensitized solar cell

    SciTech Connect (OSTI)

    Chen Jing; Song, J. L.; Deng, W. Q.; Sun, X. W.; Jiang, C. Y.; Lei, W.; Huang, J. H.; Liu, R. S.

    2009-04-13

    In this letter, we report an oleic acid (OA)-capped CdSe quantum-dot sensitized solar cell (QDSSC) with an improved performance. The TiO{sub 2}/OA-CdSe photoanode in a two-electrode device exhibited a photon-to-current conversion efficiency of 17.5% at 400 nm. At AM1.5G irradiation with 100 mW/cm{sup 2} light intensity, the QDSSCs based on OA-capped CdSe showed a power conversion efficiency of about 1%. The function of OA was to increase QD loading, extend the absorption range and possibly suppress the surface recombination.

  19. Optimal packing size of non-ligated CdSe nanoclusters for microstructure synthesis

    SciTech Connect (OSTI)

    Tefera, Anteneh G.; Mochena, Mogus D.; Johnson, Elijah; Dickerson, James

    2014-09-14

    Structural and electrostatic properties of nanoclusters of CdSe of diameter 1–2 nm are studied with first principle calculations to determine the optimal size for synthesizing microstructures. Based on robustness of the core structure, i.e., the retention of tetrahedral geometry, hexagonal ring structure, and overall wu{sup ¨}rtzite structure to surface relaxations, we conclude that nanoclusters of ~2 nm diameter are the best candidates to form a dense microstructure with minimal interstitial space. Se-terminated surfaces retain a zigzag structure as Se atoms are pulled out and Cd atoms are pulled in due to relaxation, therefore, are best suited for inter-nanocluster formations.

  20. Low-temperature ferromagnetic properties in Co-doped Ag{sub 2}Se nanoparticles

    SciTech Connect (OSTI)

    Yang, Fengxia E-mail: xia9020@hust.edu.cn; Yu, Gen; Han, Chong; Liu, Tingting; Zhang, Duanming; Xia, Zhengcai E-mail: xia9020@hust.edu.cn

    2014-01-06

    β-Ag{sub 2}Se is a topologically nontrivial insulator. The magnetic properties of Co-doped Ag{sub 2}Se nanoparticles with Co concentrations up to 40% were investigated. The cusp of zero-field-cooling magnetization curves and the low-temperature hysteresis loops were observed. With increasing concentration of Co{sup 2+} ions mainly substituting Ag{sub I} sites in the Ag{sub 2}Se structure, the resistivity, Curie temperature T{sub c}, and magnetization increased. At 10 T, a sharp drop of resistance near T{sub c} was detected due to Co dopants. The ferromagnetic behavior in Co-doped Ag{sub 2}Se might result from the intra-layer ferromagnetic coupling and surface spin. This magnetic semiconductor is a promising candidate in electronics and spintronics.

  1. Flow of US/SE Program Funding to National Laboratories (FY 2014 Enacted)

    Broader source: Energy.gov [DOE]

    This figure illustrates the flow of funding to each of 17 DOE National Laboratories from five of the six US/SE program offices. IE does not directly fund program work at the National Laboratories.

  2. Enhanced spontaneous emission of CdSe quantum dots in monolithic II-VI pillar microcavities

    SciTech Connect (OSTI)

    Lohmeyer, H.; Kruse, C.; Sebald, K.; Gutowski, J.; Hommel, D.

    2006-08-28

    The emission properties of CdSe/ZnSe quantum dots in ZnSe-based pillar microcavities are studied. All-epitaxial cavities made of ZnSSe and MgS/ZnCdSe superlattices with a single quantum-dot sheet embedded have been grown by molecular beam epitaxy. Pillar structures with diameters down to 500 nm have been realized by focused-ion-beam etching. A pronounced enhancement of the spontaneous emission rate of quantum dots coupling to the fundamental mode of the cavities is found as evidence for the Purcell effect. The enhancement by a factor of up to 3.8 depends systematically on the pillar diameter and thus on the Purcell factor of the individual pillars.

  3. Thickness-dependent coherent phonon frequency in ultrathin FeSe...

    Office of Scientific and Technical Information (OSTI)

    After optical excitation, we observe periodic modulations of the photoelectron spectrum as a function of pump-probe delay for 1-unit-cell, 3-unit-cell, and 60-unit-cell thick FeSe ...

  4. Phonon properties of BaFe?X? (X=S, Se) spin ladder compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Popovicq, Z. V.; Petrovic, C.; Scepanovic, M.; Lazarevic, N.; Opacic, M.; Radonjic, M. M.; Tanaskovic, D.; Lei, Hechang

    2015-02-27

    We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe?X? (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe?S? (BaFe?Se?) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe?S(Se)? is supported by themorelattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe?Se? below TN=255K leaves a fingerprint both in the A1g and B3g phonon mode linewidth and energy.less

  5. Thermoelectric properties of polycrystalline In4Se3 and In4Te3

    SciTech Connect (OSTI)

    Shi, Xun; Cho, Jung Y; Salvador, James R.; Yang, Jihui; Wang, Hsin

    2010-01-01

    High thermoelectric performance of a single crystal layered compound In{sub 4}Se{sub 3} was reported recently. We present here an electrical and thermal transport property study over a wide temperature range for polycrystalline samples of In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3}. Our data demonstrate that these materials are lightly doped semiconductors, leading to large thermopower and resistivity. Very low thermal conductivity, below 1 W/m K, is observed. The power factors for In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3} are much smaller when compared with state-of-the-art thermoelectric materials. This combined with the very low thermal conductivity results in the maximum ZT value of less than 0.6 at 700 K for In{sub 4}Se{sub 3}.

  6. Super-Poissonian Statistics of Photon Emission from Single CdSe...

    Office of Scientific and Technical Information (OSTI)

    Title: Super-Poissonian Statistics of Photon Emission from Single CdSe-CdS Core-Shell Nanocrystals Coupled to Metal Nanostructures Authors: Park, Young-Shin ; Ghosh, Yagnaseni ; ...

  7. Secretary Chu to Lead Delegation to SE4All, CEM Conferences in...

    Office of Environmental Management (EM)

    leading economies in London for the UN Sustainable Energy for All (SE4All) conference and ... Thursday, April 26, 2012 10:00 a.m. Joint Clean Energy Ministerial and Sustainable Energy ...

  8. Spin excitations in a model of FeSe with orbital ordering (Journal...

    Office of Scientific and Technical Information (OSTI)

    Spin excitations in a model of FeSe with orbital ordering Citation Details In-Document Search This content will become publicly available on December 27, 2016 Title: Spin ...

  9. Spin excitations in a model of FeSe with orbital ordering (Journal...

    Office of Scientific and Technical Information (OSTI)

    DOE PAGES Search Results Publisher's Accepted Manuscript: Spin excitations in a model of FeSe with orbital ordering This content will become publicly available on December 27, 2016 ...

  10. Unique Challenges Accompany Thick-Shell CdSe/nCdS (n > 10) Nanocrystal Synthesis

    SciTech Connect (OSTI)

    Guo, Y; Marchuk, K; Abraham, R; Sampat, S; Abraham, R.; Fang, N; Malko, AV; Vela, J

    2011-12-23

    Thick-shell CdSe/nCdS (n {ge} 10) nanocrystals were recently reported that show remarkably suppressed fluorescence intermittency or 'blinking' at the single-particle level as well as slow rates of Auger decay. Unfortunately, whereas CdSe/nCdS nanocrystal synthesis is well-developed up to n {le} 6 CdS monolayers (MLs), reproducible syntheses for n {ge} 10 MLs are less understood. Known procedures sometimes result in homogeneous CdS nucleation instead of heterogeneous, epitaxial CdS nucleation on CdSe, leading to broad and multimodal particle size distributions. Critically, obtained core/shell sizes are often below those desired. This article describes synthetic conditions specific to thick-shell growth (n {ge} 10 and n {ge} 20 MLs) on both small (sub2 nm) and large (>4.5 nm) CdSe cores. We find added secondary amine and low concentration of CdSe cores and molecular precursors give desired core/shell sizes. Amine-induced, partial etching of CdSe cores results in apparent shell-thicknesses slightly beyond those desired, especially for very-thick shells (n {ge} 20 MLs). Thermal ripening and fast precursor injection lead to undesired homogeneous CdS nucleation and incomplete shell growth. Core/shells derived from small CdSe (1.9 nm) have longer PL lifetimes and more pronounced blinking at single-particle level compared with those derived from large CdSe (4.7 nm). We expect our new synthetic approach will lead to a larger throughput of these materials, increasing their availability for fundamental studies and applications.

  11. Synthesis of CdSe quantum dots for quantum dot sensitized solar cell

    SciTech Connect (OSTI)

    Singh, Neetu Kapoor, Avinashi; Kumar, Vinod; Mehra, R. M.

    2014-04-24

    CdSe Quantum Dots (QDs) of size 0.85 nm were synthesized using chemical route. ZnO based Quantum Dot Sensitized Solar Cell (QDSSC) was fabricated using CdSe QDs as sensitizer. The Pre-synthesized QDs were found to be successfully adsorbed on front ZnO electrode and had potential to replace organic dyes in Dye Sensitized Solar Cells (DSSCs). The efficiency of QDSSC was obtained to be 2.06 % at AM 1.5.

  12. Advanced Precursor Reaction Processing for Cu(InGa)(SeS)2 Solar Cells

    SciTech Connect (OSTI)

    Shafarman, William N.

    2015-10-12

    This project “Advanced Precursor Reaction Processing for Cu(InGa)(SeS)2 Solar Cells”, completed by the Institute of Energy Conversion (IEC) at the University of Delaware in collaboration with the Department of Chemical Engineering at the University of Florida, developed the fundamental understanding and technology to increase module efficiency and improve the manufacturability of Cu(InGa)(SeS)2 films using the precursor reaction approach currently being developed by a number of companies. Key results included: (1) development of a three-step H2Se/Ar/H2S reaction process to control Ga distribution through the film and minimizes back contact MoSe2 formation; (2) Ag-alloying to improve precursor homogeneity by avoiding In phase agglomeration, faster reaction and improved adhesion to allow wider reaction process window; (3) addition of Sb, Bi, and Te interlayers at the Mo/precursor junction to produce more uniform precursor morphology and improve adhesion with reduced void formation in reacted films; (4) a precursor structure containing Se and a reaction process to reduce processing time to 5 minutes and eliminate H2Se usage, thereby increasing throughput and reducing costs. All these results were supported by detailed characterization of the film growth, reaction pathways, thermodynamic assessment and device behavior.

  13. Ultrahigh photo-responsivity and detectivity in multilayer InSe nanosheets phototransistors with broadband response

    SciTech Connect (OSTI)

    Feng, Wei; Wu, Jing-Bin; Li, Xiaoli; Zheng, Wei; Zhou, Xin; Xiao, Kai; Cao, Wenwu; Yang, Bin; Idrobo, Juan-Carlos; Basile, Leonardo; Tian, Weiquan; Tan, PingHeng; Hu, PingAn

    2015-05-20

    In this paper, we demonstrate the strategies and principles for the performance improvement of layered semiconductor based photodetectors using multilayer indium selenide (InSe) as the model material. It is discovered that multiple reflection interference at the interfaces in the phototransistor device leads to a thickness-dependent photo-response, which provides a guideline to improve the performance of layered semiconductor based phototransistors. The responsivity and detectivity of InSe nanosheet phototransistor can be adjustable using applied gate voltage. Our InSe nanosheet phototransistor exhibits ultrahigh responsivity and detectivity. An ultrahigh external photo-responsivity of ~104 A W-1 can be achieved from broad spectra ranging from UV to near infrared wavelength using our InSe nanosheet photodetectors. The detectivity of multilayer InSe devices is ~1012 to 1013 Jones, which surpasses that of the currently exploited InGaAs photodetectors (1011 to 1012 Jones). Finally, this research shows that multilayer InSe nanosheets are promising materials for high performance photodetectors.

  14. Doping SrTiO3 supported FeSe by excess atoms and oxygen vacancies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shanavas, Kavungal Veedu; Singh, David J.

    2015-07-24

    Photoemission studies of FeSe monolayer films on SrTiO3 substrate have shown electronic structures that deviate from pristine FeSe, consistent with heavy electron doping. With the help of first-principles calculations we studied the effect of excess Fe and Se atoms on the monolayer and oxygen vacancies in the substrate in order to understand the reported Fermi surface in this system. We find that both excess Fe and Se atoms prefer the same adsorption site above the bottom Se atoms on the monolayer. The adsorbed Fe is strongly magnetic and contributes electrons to the monolayer, while excess Se hybridizes with the monolayermore » Fe-d states and partially opens a gap just above the Fermi energy. We also find that the two-dimensional electron gas generated by the oxygen vacancies is partly transferred to the monolayer and can potentially suppress the hole pockets around the Γ point. Furthermore, both O vacancies in the SrTiO3 substrate and excess Fe over the monolayer can provide high levels of electron doping.« less

  15. Recrystallization method to selenization of thin-film Cu(In,Ga)Se.sub.2 for semiconductor device applications

    DOE Patents [OSTI]

    Albin, David S.; Carapella, Jeffrey J.; Tuttle, John R.; Contreras, Miguel A.; Gabor, Andrew M.; Noufi, Rommel; Tennant, Andrew L.

    1995-07-25

    A process for fabricating slightly Cu-poor thin-films of Cu(In,Ga)Se.sub.2 on a substrate for semiconductor device applications includes the steps of forming initially a slightly Cu-rich, phase separated, mixture of Cu(In,Ga)Se.sub.2 :Cu.sub.x Se on the substrate in solid form followed by exposure of the Cu(In,Ga)Se.sub.2 :Cu.sub.x Se solid mixture to an overpressure of Se vapor and (In,Ga) vapor for deposition on the Cu(In,Ga)Se.sub.2 :Cu.sub.x Se solid mixture while simultaneously increasing the temperature of the solid mixture toward a recrystallization temperature (about 550.degree. C.) at which Cu(In,Ga)Se.sub.2 is solid and Cu.sub.x Se is liquid. The (In,Ga) flux is terminated while the Se overpressure flux and the recrystallization temperature are maintained to recrystallize the Cu.sub.x Se with the (In, Ga) that was deposited during the temperature transition and with the Se vapor to form the thin-film of slightly Cu-poor Cu.sub.x (In,Ga).sub.y Se.sub.z. The initial Cu-rich, phase separated large grain mixture of Cu(In,Ga)Se.sub.2 :Cu.sub.x Se can be made by sequentially depositing or co-depositing the metal precursors, Cu and (In, Ga), on the substrate at room temperature, ramping up the thin-film temperature in the presence of Se overpressure to a moderate anneal temperature (about 450.degree. C.) and holding that temperature and the Se overpressure for an annealing period. A nonselenizing, low temperature anneal at about 100.degree. C. can also be used to homogenize the precursors on the substrates before the selenizing, moderate temperature anneal.

  16. CdSe/ZnSe quantum dot with a single Mn{sup 2+} ionA new system for a single spin manipulation

    SciTech Connect (OSTI)

    Smole?ski, T.

    2015-03-21

    We present a magneto-optical study of individual self-assembled CdSe/ZnSe quantum dots doped with single Mn{sup 2+} ions. Properties of the studied dots are analyzed analogously to more explored system of Mn-doped CdTe/ZnTe dots. Characteristic sixfold splitting of the neutral exciton emission line as well as its evolution in the magnetic field are described using a spin Hamiltonian model. Dynamics of both exciton recombination and Mn{sup 2+} spin relaxation are extracted from a series of time-resolved experiments. Presence of a single dopant is shown not to affect the average excitonic lifetime measured for a number of nonmagnetic and Mn-doped dots. On the other hand, non-resonant pumping is demonstrated to depolarize the Mn{sup 2+} spin in a quantum dot placed in external magnetic field. This effect is utilized to determine the ion spin relaxation time in the dark.

  17. A comparative transport study of Bi{sub 2}Se{sub 3} and Bi{sub 2}Se{sub 3}/yttrium iron garnet

    SciTech Connect (OSTI)

    Jiang, Zilong; Tang, Chi; Shi, Jing; Katmis, Ferhat; Wei, Peng; Moodera, Jagadeesh S.

    2014-06-02

    Bilayers of 20 quintuple layer Bi{sub 2}Se{sub 3} on 30 nm thick yttrium iron garnet (YIG) have been grown with molecular beam epitaxy in conjunction with pulsed laser deposition. The presence of the ferri-magnetic insulator YIG causes additional scattering to the surface states of the Bi{sub 2}Se{sub 3} topological insulator layer, as indicated by the temperature dependence of the resistivity. From the two-channel analysis of the Hall data, we find that the surface contribution in the bilayer samples is greatly reduced. Furthermore, the weak antilocalization effect from the surface states is clearly suppressed due to the presence of the YIG layer.

  18. Non-H{sub 2}Se, ultra-thin CuInSe{sub 2} devices. Annual subcontract report, November 10, 1992--November 9, 1993

    SciTech Connect (OSTI)

    Delahoy, A.E.; Britt, J.; Faras, F.; Kiss, Z.

    1994-09-01

    This report describes advances made during Phase II (November 10, 1992-November 9, 1993) of a three-phase, cost-shared subcontract whose ultimate goal is the demonstration of thin film CuInSe{sub 2} photovoltaic modules prepared by methods adaptable to safe, high yield, high volume manufacturing. At the end of Phase I, EPV became one of the first groups to clear the 10% efficiency barrier for CIS cells prepared by non-H{sub 2}Se selenization. During Phase II a total area efficiency of 12.5% was achieved for a 1 cm{sup 2} cell. The key achievement of Phase II was the production of square foot CIS modules without the use of H{sub 2}Se. This is seen as a crucial step towards the commercialization of CIS. Using a novel interconnect technology, EPV delivered an 8.0% aperture area efficiency mini-module and a 6.2% aperture area efficiency 720 cm{sub 2} module to NREL. On the processing side, advances were made in precursor formation and the selenization profile, both of which contributed to higher quality CIS. The higher band gap quaternary chalcopyrite material CuIn(S{sub x}, Se{sub 1{minus}X}){sub 2} was prepared and 8% cells were fabricated using this material. Device analysis revealed a correlation between long wavelength quantum efficiency and the CIS Cu/In ratio. Temperature dependent studies highlighted the need for high V{sub OC} devices to minimize the impact of the voltage drop at operating temperature. Numerical modeling of module performance was performed in order to identify the correct ZnO sheet resistance for modules. Efforts in Phase III will focus on increase of module efficiency to 9-10%, initiation of an outdoor testing program, preparation of completely uniform CIS plates using second generation selenization equipment, and exploration of alternative precursors for CIS formation.

  19. Hidden Superlattice in Tl2(SC6H4S) and Tl2(SeC6H4Se) Solved from Powder X-ray Diffraction

    SciTech Connect (OSTI)

    K Stone; D Turner; M Singh; T Vaid; P Stephens

    2011-12-31

    The crystal structures of the isostructural title compounds poly[({mu}-benzene-1,4-dithiolato)dithallium], Tl{sub 2}(SC{sub 6}H{sub 4}S), and poly[({mu}-benzene-1,4-diselenolato)dithallium], Tl{sub 2}(SeC{sub 6}H{sub 4}Se), were solved by simulated annealing from high-resolution synchrotron X-ray powder diffraction. Rietveld refinements of an initial structure with one formula unit per triclinic cell gave satisfactory agreement with the data, but led to a structure with impossibly close non-bonded contacts. A disordered model was proposed to alleviate this problem, but an alternative supercell structure leads to slightly improved agreement with the data. The isostructural superlattice structures were confirmed for both compounds through additional data collection, with substantially better counting statistics, which revealed the presence of very weak superlattice peaks not previously seen. Overall, each structure contains Tl-S or Tl-Se two-dimensional networks, connected by phenylene bridges. The sulfur (or selenium) coordination sphere around each thallium is a highly distorted square pyramid or a 'see-saw' shape, depending upon how many Tl-S or Tl-Se interactions are considered to be bonds. In addition, the two compounds contain pairs of Tl{sup I} ions that interact through a closed-shell 'thallophilic' interaction: in the sulfur compound there are two inequivalent pairs of Tl atoms with Tl-Tl distances of 3.49 and 3.58 {angstrom}, while in the selenium compound those Tl-Tl interactions are at 3.54 and 3.63 {angstrom}.

  20. Persistent photoconductivity in two-dimensional Mo1-xW xSe2–MoSe2 van der Waals heterojunctions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Puretzky, Alexander A.; Basile, Leonardo; Idrobo, Juan Carlos; Rouleau, Christopher M.; Geohegan, David B.; Xiao, Kai; Li, Xufan; Lin, Ming -Wei; Wang, Kei

    2016-02-16

    Van der Waals (vdW) heterojunctions consisting of vertically-stacked individual or multiple layers of two-dimensional (2D) layered semiconductors, especially the transition metal dichalcogenides (TMDs), are fascinating new artificial solids just nanometers-thin that promise novel optoelectronic functionalities due to the sensitivity of their electronic and optical properties to strong quantum confinement and interfacial interactions. Here, monolayers of n-type MoSe2 and p-type Mo1-xW xSe2–MoSe2 are grown by vapor transport methods, then transferred and stamped to form artificial vdW heterostructures with different interlayer orientations. Atomic-resolution Z-contrast electron microscopy and electron diffraction are used to characterize both the individual monolayers and the atomic registry betweenmore » layers in the bilayer vdW heterostructures. These measurements are compared with photoluminescence and low-frequency Raman spectroscopy, which indicates strong interlayer coupling in heterostructures. Remarkably, the heterojunctions exhibit an unprecedented photoconductivity effect that persists at room temperature for several days. This persistent photoconductivity is shown to be tunable by applying a gate bias that equilibrates the charge distribution. Furthermore, these measurements indicate that such ultrathin vdW heterojunctions can function as rewritable optoelectronic switches or memory elements under time-dependent photo-illumination, an effect which appears promising for new monolayer TMDs-based optoelectronic devices applications.« less

  1. Method of fabricating high-efficiency Cu(In,Ga)(Se,S){sub 2} thin films for solar cells

    DOE Patents [OSTI]

    Noufi, R.; Gabor, A.M.; Tuttle, J.R.; Tennant, A.L.; Contreras, M.A.; Albin, D.S.; Carapella, J.J.

    1995-08-15

    A process for producing a slightly Cu-poor thin film of Cu(In,Ga)(Se,S){sub 2} comprises depositing a first layer of (In,Ga){sub x} (Se,S){sub y} followed by depositing just enough Cu+(Se,S) or Cu{sub x} (Se,S) to produce the desired slightly Cu-poor material. In a variation, most, but not all, (about 90 to 99%) of the (In,Ga){sub x} (Se,S){sub y} is deposited first, followed by deposition of all the Cu+(Se,S) or Cu{sub x} (Se,S) to go near stoichiometric, possibly or even preferably slightly Cu-rich, and then in turn followed by deposition of the remainder (about 1 to 10%) of the (In,Ga){sub x} (Se,S){sub y} to end with a slightly Cu-poor composition. In yet another variation, a small portion (about 1 to 10%) of the (In,Ga){sub x} (Se,S){sub y} is first deposited as a seed layer, followed by deposition of all of the Cu+(Se,S) or Cu{sub x} (Se,S) to make a very Cu-rich mixture, and then followed deposition of the remainder of the (In,Ga){sub x} (Se,S){sub y} to go slightly Cu-poor in the final Cu(In,Ga)(Se,S){sub 2} thin film. 5 figs.

  2. Method of fabricating high-efficiency Cu(In,Ga)(SeS).sub.2 thin films for solar cells

    DOE Patents [OSTI]

    Noufi, Rommel; Gabor, Andrew M.; Tuttle, John R.; Tennant, Andrew L.; Contreras, Miguel A.; Albin, David S.; Carapella, Jeffrey J.

    1995-01-01

    A process for producing a slightly Cu-poor thin film of Cu(In,Ga)(Se,S).sub.2 comprises depositing a first layer of (In,Ga).sub.x (Se,S).sub.y followed by depositing just enough Cu+(Se,S) or Cu.sub.x (Se,S) to produce the desired slightly Cu-poor material. In a variation, most, but not all, (about 90 to 99%) of the (In,Ga).sub.x (Se,S).sub.y is deposited first, followed by deposition of all the Cu+(Se,S) or Cu.sub.x (Se,S) to go near stoichiometric, possibly or even preferably slightly Cu-rich, and then in turn followed by deposition of the remainder (about 1 to 10%) of the (In,Ga).sub.x (Se,S).sub.y to end with a slightly Cu-poor composition. In yet another variation, a small portion (about 1 to 10%) of the (In,Ga).sub.x (Se,S).sub.y is first deposited as a seed layer, followed by deposition of all of the Cu+(Se,S) or Cu.sub.x (Se,S) to make a very Cu-rich mixture, and then followed deposition of the remainder of the (In,Ga).sub.x (Se,S).sub.y to go slightly Cu-poor in the final Cu(In,Ga)(Se,S).sub.2 thin film.

  3. Novel Approaches to Wide Bandgap CuInSe2 Based Absorbers

    SciTech Connect (OSTI)

    William N. Shafarman

    2011-04-28

    This project targeted the development of high performance wide bandgap solar cells based on thin film alloys of CuInSe2 to relax constraints on module design and enable tandem solar cell structures. This addressed goals of the Solar Energy Technologies Program for Next Generation PV to develop technology needed for higher thin film module efficiency as a means to reduce costs. Specific objectives of the research project were: 1) to develop the processes and materials required to improve the performance of wide bandgap thin film solar cells based on alloys of CuInSe2, and 2) to provide the fundamental science and engineering basis for the material, electronic, and device properties required to effectively apply these processes and materials to commercial manufacture. CuInSe2-based photovoltaics have established the highest efficiencies of the thin film materials at both the cell and module scales and are actively being scaled up to commercialization. In the highest efficiency cells and modules, the optical bandgap, a function of the CuInSe2-based alloy composition, is relatively low compared to the optimum match to the solar spectrum. Wider bandgap alloys of CuInSe2 produce higher cell voltages which can improve module performance and enable the development of tandem solar cells to boost the overall efficiency. A focus for the project was alloying with silver to form (AgCu)(InGa)Se2 pentenary thin films deposited by elemental co-evaporation which gives the broadest range of control of composition and material properties. This alloy has a lower melting temperature than Ag-free, Cu-based chalcopyrite compounds, which may enable films to be formed with lower defect densities and the (AgCu)(InGa)Se2 films give improved material properties and better device performance with increasing bandgap. A comprehensive characterization of optical, structural, and electronic properties of (AgCu)(InGa)Se2 was completed over the complete compositional range 0 ≤ Ga/(In+Ga) ≤ 1 and

  4. Superconductivity in strong spin orbital coupling compound Sb2Se3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kong, P. P.; Sun, F.; Xing, L. Y.; Zhu, J.; Zhang, S. J.; Li, W. M.; Liu, Q. Q.; Wang, X. C.; Feng, S. M.; Yu, X. H.; et al

    2014-10-20

    Recently, A2B3 type strong spin orbital coupling compounds such as Bi2Te3, Bi2Se3 and Sb2Te3 were theoretically predicated to be topological insulators and demonstrated through experimental efforts. The counterpart compound Sb2Se3 on the other hand was found to be topological trivial, but theoretical studies indicated that the pressure might induce Sb2Se3 into a topological nontrivial state. We report on the discovery of superconductivity in Sb2Se3 single crystal induced via pressure. Our experiments indicated that Sb2Se3 became superconductive at high pressures above 10 GPa proceeded by a pressure induced insulator to metal like transition at ~3 GPa which should be related tomore » the topological quantum transition. The superconducting transition temperature (TC) increased to around 8.0 K with pressure up to 40 GPa while it keeps ambient structure. As a result, high pressure Raman revealed that new modes appeared around 10 GPa and 20 GPa, respectively, which correspond to occurrence of superconductivity and to the change of TC slop as the function of high pressure in conjunction with the evolutions of structural parameters at high pressures.« less

  5. Electronic structure, irreversibility line and magnetoresistance of Cu0.3Bi2Se3 superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hemian, Yi; Gu, Genda; Chen, Chao -Yu; Sun, Xuan; Xie, Zhuo -Jin; Feng, Ya; Liang, Ai -Ji; Peng, Ying -Ying; He, Shao -Long; Zhao, Lin; et al

    2015-06-01

    CuxBi2Se3 is a superconductor that is a potential candidate for topological superconductors. We report our laser-based angle-resolved photoemission measurement on the electronic structure of the CuxBi2Se3 superconductor, and a detailed magneto-resistance measurement in both normal and superconducting states. We find that the topological surface state of the pristine Bi2Se3 topological insulator remains robust after the Cu-intercalation, while the Dirac cone location moves downward due to electron doping. Detailed measurements on the magnetic field-dependence of the resistance in the superconducting state establishes an irreversibility line and gives a value of the upper critical field at zero temperature of ~4000 Oe formore » the Cu0.3Bi2Se3 superconductor with a middle point Tc of 1.9K. The relation between the upper critical field Hc2 and temperature T is different from the usual scaling relation found in cuprates and in other kinds of superconductors. Small positive magneto-resistance is observed in Cu0.3Bi2Se3 superconductors up to room temperature. As a result, these observations provide useful information for further study of this possible candidate for topological superconductors.« less

  6. In-situ surface composition measurements of CuGaSe{sub 2} thin films

    SciTech Connect (OSTI)

    Fons, P.; Yamada, A.; Niki, S.; Oyanagi, H.

    1998-12-31

    Two CuGaSe{sub 2} films were grown by molecular beam epitaxy onto GaAs (001) substrates with varying Cu/Ga flux ratios under Se overpressure conditions. Growth was interrupted at predetermined times and the surface composition was measured using Auger electron spectroscopy after which growth was continued. After growth, the film composition was analyzed using voltage dependent electron microprobe spectroscopy. Film structure and morphology were also analyzed using x-ray diffraction and atomic force microscopy. The film with a Cu/Ga ratio larger than unity showed evidence of surface segregation of a second Cu-rich phase with a Cu/Se composition ratio slightly greater than unity. A second CuGaSe{sub 2} film with a Cu/Ga ratio of less than unity showed no change in surface composition with time and was also consistent with bulk composition measurements. Diffraction measurements indicated a high concentration of twins as well as the presence of domains with mixed c and a axes in the Ga-rich film. The Cu-rich films by contrast were single domain and had a narrower mosaics. High sensitivity scans along the [001] reciprocal axis did not exhibit any new peaks not attributable to either the substrate or the CuGaSe{sub 2} thin film.

  7. Assessment of the SE2-ANL code using EBR-II temperature measurements

    SciTech Connect (OSTI)

    Yang, W.S.; Yacout, A.M.

    1995-01-01

    The SE2-ANL code is a modified version of the SUPERENERGY-2 code [1]. This code is used at Argonne National Laboratory (ANL) to compute the core-wide temperature profiles in Liquid Metal Reactor (LMR) cores. The accuracy of this code has recently been tested by comparing the predicted temperatures with measured values in the Experimental Breeder Reactor R (EBR-II). The detailed temperature distributions in two experimental subassemblies and the mixed mean subassembly outlet temperatures were used in this validation study. The SE2-ANL predictions were found to agree well with measured values. It was also found that SE2-ANL yields results with accuracy comparable to the more detailed COBRA-WC [2] calculations at much lower computational cost.

  8. Role of polycrystallinity in CdTe and CuInSe sub 2 photovoltaic cells

    SciTech Connect (OSTI)

    Sites, J.R. )

    1991-01-01

    The polycrystalline nature of thin-film CdTe and CuInSe{sub 2} solar cells continues to be a major factor in several individual losses that limit overall cell efficiency. This report describes progress in the quantitative separation of these losses, including both measurement and analysis procedures. It also applies these techniques to several individual cells to help document the overall progress with CdTe and CuInSe{sub 2} cells. Notably, CdTe cells from Photon Energy have reduced window photocurrent losses to 1 mA/Cm{sup 2}; those from the University of South Florida have achieved a maximum power voltage of 693 mV; and CuInSe{sub 2} cells from International Solar Electric Technology have shown a hole density as high as 7 {times} 10{sup 16} cm{sup {minus}3}, implying a significant reduction in compensation. 9 refs.

  9. Luminescence of CdSe/ZnS quantum dots infiltrated into an opal matrix

    SciTech Connect (OSTI)

    Gruzintsev, A. N. Emelchenko, G. A.; Masalov, V. M.; Yakimov, E. E.; Barthou, C.; Maitre, A.

    2009-02-15

    The effect of the photonic band gap in the photonic crystal, the synthesized SiO{sub 2} opal with embedded CdSe/ZnS quantum dots, on its luminescence in the visible spectral region is studied. It is shown that the position of the photonic band gap in the luminescence and reflectance spectra for the infiltrated opal depends on the diameter of the constituent nanospheres and on the angle of recording the signal. The optimal conditions for embedding the CdSe/ZnS quantum dots from the solution into the opal matrix are determined. It is found that, for the opal-CdSe/ZnS nanocomposites, the emission intensity decreases and the luminescence decay time increases in the spatial directions, in which the spectral positions of the photonic band gap and the luminescence peak of the quantum dots coincide.

  10. A Novel and Functional Single-Layer Sheet of ZnSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Jia; Sumpter, Bobby G.; Kent, Paul R. C.; Huang, Jingsong

    2014-12-23

    In this Communication, we report a novel singlelayer sheet of ZnSe, with a three-atomic thickness, which demonstrates a strong quantum confinement effect by exhibiting a large blue shift of 2.0 eV in its absorption edge relative to the zinc blende (ZB) bulk phase. Theoretical optical absorbance shows that the largest absorption of this ultrathin single-layer sheet of ZnSe occurs at a wavelength similar to its four-atom-thick doublelayer counterpart but with higher photoabsorption efficiency, suggesting a superior behavior on incident photon-to-current conversion efficiency for solar water splitting, among other potential applications. The results presented herein for ZnSe may be generalized tomore » other group II-VI analogues.« less

  11. Charge-transfer dynamics in multilayered PbS and PbSe quantum dot architectures

    SciTech Connect (OSTI)

    Xu, F.; Ma, X.; Haughn, C. R.; Doty, M. F.; Cloutier, S. G.

    2014-02-03

    We demonstrate control of the charge transfer process in PbS and PbSe quantum dot assemblies. We first demonstrate efficient charge transfer from donor quantum dots to acceptor quantum dots in a multi-layer PbSe cascade structure. Then, we assemble type-I and type-II heterostructures using both PbS and PbSe quantum dots via careful control of the band alignment. In type-I structures, photo-generated carriers are transferred and localized in the smaller bandgap (acceptor) quantum dots, resulting in a significant luminescence enhancement. In contrast, a significant luminescence quenching and shorter emission lifetime confirms an efficient separation of photo-generated carriers in the type-II architecture.

  12. Two-step growth of two-dimensional WSe2/MoSe2 heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gong, Yongji; Lei, Sidong; Lou, Jun; Liu, Zheng; Vajtai, Robert; Zhou, Wu; Ajayan, Pullikel M.; Ye, Gonglan; Li, Bo; He, Yongmin; et al

    2015-08-03

    Two dimensional (2D) materials have attracted great attention due to their unique properties and atomic thickness. Although various 2D materials have been successfully synthesized with different optical and electrical properties, a strategy for fabricating 2D heterostructures must be developed in order to construct more complicated devices for practical applications. Here we demonstrate for the first time a two-step chemical vapor deposition (CVD) method for growing transition-metal dichalcogenide (TMD) heterostructures, where MoSe2 was synthesized first and followed by an epitaxial growth of WSe2 on the edge and on the top surface of MoSe2. Compared to previously reported one-step growth methods, thismore » two-step growth has the capability of spatial and size control of each 2D component, leading to much larger (up to 169 μm) heterostructure size, and cross-contamination can be effectively minimized. Furthermore, this two-step growth produces well-defined 2H and 3R stacking in the WSe2/MoSe2 bilayer regions and much sharper in-plane interfaces than the previously reported MoSe2/WSe2 heterojunctions obtained from one-step growth methods. The resultant heterostructures with WSe2/MoSe2 bilayer and the exposed MoSe2 monolayer display rectification characteristics of a p-n junction, as revealed by optoelectronic tests, and an internal quantum efficiency of 91% when functioning as a photodetector. As a result, a photovoltaic effect without any external gates was observed, showing incident photon to converted electron (IPCE) efficiencies of approximately 0.12%, providing application potential in electronics and energy harvesting.« less

  13. Orbital alignment at the internal interface of arylthiol functionalized CdSe molecular hybrids

    SciTech Connect (OSTI)

    Li, Zhi; Schlaf, Rudy; Mazzio, Katherine A.; Okamoto, Ken; Luscombe, Christine K.

    2015-04-21

    Organic-inorganic nanoparticle molecular hybrid materials are interesting candidates for improving exciton separation in organic solar cells. The orbital alignment at the internal interface of cadmium selenide (ArS-CdSe) hybrid materials functionalized with covalently attached arylthiolate moieties was investigated through X-ray photoemission spectroscopy (XPS) and ultraviolet photoemission spectroscopy (UPS). A physisorbed interface between arylthiol (ArSH) ligands and CdSe nanoparticles was also investigated for comparison. This interface was created via a multi-step thin film deposition procedure in-vacuo, where the surface was characterized after each experimental step. This enabled the direct comparison of ArSH/CdSe interfaces produced via physisorption and ArS-CdSe covalently attached hybrid materials, which rely on a chemical reaction for their synthesis. All material depositions were performed using an electrospray deposition, which enabled the direct injection of solution-originating molecular species into the vacuum system. This method allows XPS and UPS measurements to be performed immediately after deposition without exposure to the atmosphere. Transmission electron microscopy was used to determine the morphology and particle size of the deposited materials. Ultraviolet-visible spectroscopy was used to estimate the optical band gap of the CdSe nanoparticles and the HOMO-LUMO gap of the ArSH ligands. These experiments showed that hybridization via covalent bonds results in an orbital realignment at the ArSH/CdSe interface in comparison to the physisorbed interface. The orbital alignment within the hybrid caused a favorable electron injection barrier, which likely facilitates exciton-dissociation while preventing charge-recombination.

  14. Direct Observation of Energy-Gap Scaling Law in CdSe Quantum Dots with Positrons

    SciTech Connect (OSTI)

    Denison, Arthur Blanchard; Weber, M. H.; Lynn, K. G.; Barbiellini, B.; Sterne, P. A.

    2002-07-01

    CdSe quantum dot samples with sizes in the range of 1.8~6 nm in diameter were examined by positron annihilation spectroscopy. The results were compared to data obtained for single-crystal bulk CdSe. Evidence is provided that the positrons annihilate within the nanospheres. The annihilation line shape shows a smearing at the boundary of the Jones zone proportional to the widening of the band gap due to a reduction in the size of the quantum dots. The data confirm that the change in the band gap is inversely proportional to the square of the quantum dot diameter.

  15. Tuning thermoelectricity in a Bi2Se3 topological insulator via varied film thickness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Minghua; Wang, Zhenyu; Xu, Yong; Huang, Huaqing; Zang, Yunyi; Liu, Chang; Duan, Wenhui; Gan, Zhongxue; Zhang, Shou-Cheng; He, Ke; et al

    2016-01-12

    We report thermoelectric transport studies on Bi2Se3 topological insulator thin films with varied thickness grown by molecular beam epitaxy. We find that the Seebeck coefficient and thermoelectric power factor decrease systematically with the reduction of film thickness. These experimental observations can be explained quantitatively by theoretical calculations based on realistic electronic band structure of the Bi2Se3 thin films. Lastly, this work illustrates the crucial role played by the topological surface states on the thermoelectric transport of topological insulators, and sheds new light on further improvement of their thermoelectric performance.

  16. Potential thermoelectric performance from optimization of hole-doped Bi2Se3

    SciTech Connect (OSTI)

    Parker, David S; Singh, David J

    2011-01-01

    We present an analysis of the potential thermoelectric performance of hole-doped Bi2Se3, which is commonly considered to show inferior room temperature performance when compared to Bi2Te3. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as have been applied to Bi2Te3) the material may show optimized ZT values of unity or more in the 300 - 500 K temperature range and thus be suitable for cooling and moderate temperature waste heat recovery and thermoelectric solar cell applications. Central to this conclusion are the larger band gap and the relatively heavier valence bands of Bi2Se3.

  17. Optical studies of carriers’ vertical transport in the alternately-strained ZnS{sub 0.4}Se{sub 0.6}/CdSe superlattice

    SciTech Connect (OSTI)

    Evropeytsev, E. A. Sorokin, S. V.; Gronin, S. V.; Sedova, I. V.; Klimko, G. V.; Ivanov, S. V.; Toropov, A. A.

    2015-03-15

    We present the results of theoretical modelling and experimental optical studies of the alternatively-strained CdSe/ZnS{sub y}Se{sub 1−y} (y = 0.4) superlattice (SL) with effective band-gap E{sub g}{sup eff} ∼ 2.580 eV and a thickness of ∼300 nm, which was grown by molecular-beam epitaxy on a GaAs substrate. The thicknesses and composition of the layers of the superlattice are determined on the basis of the SL minibands parameters calculated implying both full lattice matching of the SL as a whole to a GaAs substrate and high efficiency of photoexcited carriers transport along the growth axis. Photoluminescence studies of the transport properties of the structure (including a superlattice with one enlarged quantum well) show that the characteristic time of the diffusion of charge carriers at 300 K is shorter than the times defined by recombination processes. Such superlattices seem to be promising for the formation of a wide-gap photoactive region in a multijunction solar cell, which includes both III–V and II–VI compounds.

  18. Ordering mechanism of stacked CdSe/ZnS{sub x}Se{sub 1-x} quantum dots: A combined reciprocal-space and real-space approach

    SciTech Connect (OSTI)

    Schmidt, Th.; Roventa, E.; Clausen, T.; Flege, J. I.; Alexe, G.; Rosenauer, A.; Hommel, D.; Falta, J.; Bernstorff, S.; Kuebel, C.

    2005-11-15

    The vertical and lateral ordering of stacked CdSe quantum dot layers embedded in ZnS{sub x}Se{sub 1-x} has been investigated by means of grazing incidence small angle x-ray scattering and transmission electron microscopy. Different growth parameters have been varied in order to elucidate the mechanisms leading to quantum dot correlation. From the results obtained for different numbers of quantum dot layers, we conclude on a self-organized process which leads to increasing ordering for progressive stacking. The dependence on the spacer layer thickness indicates that strain induced by lattice mismatch drives the ordering process, which starts to break down for too thick spacer layers in a thickness range from 45 to 80 A. Typical quantum dot distances in a range from about 110 to 160 A have been found. A pronounced anisotropy of the quantum dot correlation has been observed, with the strongest ordering along the [110] direction. Since an increased ordering is found with increasing growth temperature, the formation of stacking faults as an additional mechanism for quantum dot alignment can be ruled out.

  19. Enhanced quality thin film Cu(In,Ga)Se.sub.2 for semiconductor device applications by vapor-phase recrystallization

    DOE Patents [OSTI]

    Tuttle, John R.; Contreras, Miguel A.; Noufi, Rommel; Albin, David S.

    1994-01-01

    Enhanced quality thin films of Cu.sub.w (In,Ga.sub.y)Se.sub.z for semiconductor device applications are fabricated by initially forming a Cu-rich, phase-separated compound mixture comprising Cu(In,Ga):Cu.sub.x Se on a substrate to form a large-grain precursor and then converting the excess Cu.sub.x Se to Cu(In,Ga)Se.sub.2 by exposing it to an activity of In and/or Ga, either in vapor In and/or Ga form or in solid (In,Ga).sub.y Se.sub.z. Alternatively, the conversion can be made by sequential deposition of In and/or Ga and Se onto the phase-separated precursor. The conversion process is preferably performed in the temperature range of about 300.degree.-600.degree. C., where the Cu(In,Ga)Se.sub.2 remains solid, while the excess Cu.sub.x Se is in a liquid flux. The characteristic of the resulting Cu.sub.w (In,Ga).sub.y Se.sub.z can be controlled by the temperature. Higher temperatures, such as 500.degree.-600.degree. C., result in a nearly stoichiometric Cu(In,Ga)Se.sub.2, whereas lower temperatures, such as 300.degree.-400.degree. C., result in a more Cu-poor compound, such as the Cu.sub.z (In,Ga).sub.4 Se.sub.7 phase.

  20. Enhanced quality thin film Cu(In,Ga)Se[sub 2] for semiconductor device applications by vapor-phase recrystallization

    DOE Patents [OSTI]

    Tuttle, J.R.; Contreras, M.A.; Noufi, R.; Albin, D.S.

    1994-10-18

    Enhanced quality thin films of Cu[sub w](In,Ga[sub y])Se[sub z] for semiconductor device applications are fabricated by initially forming a Cu-rich, phase-separated compound mixture comprising Cu(In,Ga):Cu[sub x]Se on a substrate to form a large-grain precursor and then converting the excess Cu[sub x]Se to Cu(In,Ga)Se[sub 2] by exposing it to an activity of In and/or Ga, either in vapor In and/or Ga form or in solid (In,Ga)[sub y]Se[sub z]. Alternatively, the conversion can be made by sequential deposition of In and/or Ga and Se onto the phase-separated precursor. The conversion process is preferably performed in the temperature range of about 300--600 C, where the Cu(In,Ga)Se[sub 2] remains solid, while the excess Cu[sub x]Se is in a liquid flux. The characteristic of the resulting Cu[sub w](In,Ga)[sub y]Se[sub z] can be controlled by the temperature. Higher temperatures, such as 500--600 C, result in a nearly stoichiometric Cu(In,Ga)Se[sub 2], whereas lower temperatures, such as 300--400 C, result in a more Cu-poor compound, such as the Cu[sub z](In,Ga)[sub 4]Se[sub 7] phase. 7 figs.

  1. Low-temperature photoluminescence analysis of CdTeSe crystals for radiation-detector applications

    SciTech Connect (OSTI)

    YANG G.; Roy, U. N.; Bolotnikov, A. E.; Cui, Y.; Camarda, G.S.; Hossain, A.; and James, R. B.

    2015-10-05

    Goal: Understanding the changes of material defects in CdTeSe following annealing. Experimental results and discussions: Infrared (IR) transmission microscopy; current-voltage measurements (Highlight: Improvement of resistivity of un-doped crystals after annealing); low-temperature photoluminescence (PL) spectrum of as-grown and annealed samples.

  2. Molecular beam epitaxial growth of Bi{sub 2}Se{sub 3} nanowires and nanoflakes

    SciTech Connect (OSTI)

    Knebl, G. M. Gessler, J. R.; Kamp, M.; Höfling, S.

    2014-09-29

    Topological Insulators are in focus of immense research efforts and rapid scientific progress is obtained in that field. Bi{sub 2}Se{sub 3} has proven to be a topological insulator material that provides a large band gap and a band structure with a single Dirac cone at the Γ-point. This makes Bi{sub 2}Se{sub 3} one of the most promising three dimensional topological insulator materials. While Bi{sub 2}Se{sub 3} nanowires and nanoflakes so far were fabricated with different methods and for different purposes, we here present the first Bi{sub 2}Se{sub 3} nanowires as well as nanoflakes grown by molecular beam epitaxy. The nanostructures were nucleated on pretreated, silicon (100) wafers. Altering the growth conditions nanoflakes could be fabricated instead of nanowires; both with high crystalline quality, confirmed by scanning electron microscopy as well as transmission electron microscopy. These nanostructures have promise for spintronic devices and Majorana fermion observation in contact to superconductor materials.

  3. Stability of S and Se induced reconstructions on GaP(001)(21) surface

    SciTech Connect (OSTI)

    Li , D. F.; Guo, Zhi C.; Xiao, Hai Yan; Zu, Xiaotao T.; Gao, Fei

    2010-10-15

    The structural and electronic properties of S- and Se- passivated GaP(001)(21) surfaces were studied using first-principles simulations. Our calculations showed that the most stable structure consists of a single chalcogen atom (S or Se) in the first crystal layer, which is bonded to two Ga atoms of the second layer, and the third P layer replaced by chalcogen atoms, similar to the passivation of GaAs(001)(21) surface by chalcogen atoms. The structural parameters were determined and the surface band characters and the local density of states were also analyzed. The results showed that the preferable structure has no surface states in the bulk band gap, but the energy band gaps of the S- and Se-adsorbed GaP(001) surfaces are 1.83eV and 1.63eV, respectively. The passivation effects for the S- and Se-adsorbed surfaces are similar to each other.

  4. Manufacturable CuIn(Ga)Se{sub 2}-based solar cells via development of co-sputtered CuInSe{sub 2} absorber layers

    SciTech Connect (OSTI)

    Dr. Ingrid Eisgruber

    1999-03-20

    Yield and reproducibility remain issues in CuIn(Ga)Se{sub 2} (CIGS) photovoltaic module fabrication. While small-area cells (<1 cm{sup 2}) over 18% efficient have been reported, the best large-area manufactured devices (>1 ft{sup 2}) are 11% efficient with about 60% yield. If improvements in large-area manufacturing can accomplish 15% efficiency and 90% yield, the result is a doubling in throughput leading to a reduction in cost per watt of over 50%. The challenge now facing the photovoltaics industry is to bring the efficiencies of small-area cells and large-area industrial modules closer together and to raise manufacturing yields.

  5. Photoluminescence studies of type-II CdSe/CdTe superlattices

    SciTech Connect (OSTI)

    Li Jingjing; Johnson, Shane R.; Wang Shumin; Ding Ding; Ning Cunzheng; Zhang Yonghang; Yin Leijun; Skromme, B. J.; Liu Xinyu; Furdyna, Jacek K.

    2012-08-06

    CdSe/CdTe type-II superlattices grown on GaSb substrates by molecular beam epitaxy are studied using time-resolved and steady-state photoluminescence (PL) spectroscopy at 10 K. The relatively long carrier lifetime of 188 ns observed in time-resolved PL measurements shows good material quality. The steady-state PL peak position exhibits a blue shift with increasing excess carrier concentration. Self-consistent solutions of the Schroedinger and Poisson equations show that this effect can be explained by band bending as a result of the spatial separation of electrons and holes, which is critical confirmation of a strong type-II band edge alignment between CdSe and CdTe.

  6. CdS/PbSe heterojunction for high temperature mid-infrared photovoltaic detector applications

    SciTech Connect (OSTI)

    Weng, Binbin E-mail: shi@ou.edu; Qiu, Jijun; Zhao, Lihua; Chang, Caleb; Shi, Zhisheng E-mail: shi@ou.edu

    2014-03-24

    n-CdS/p-PbSe heterojunction is investigated. A thin CdS film is deposited by chemical bath deposition on top of epitaxial PbSe film by molecular beam epitaxy on Silicon. Current-voltage measurements demonstrate very good junction characteristics with rectifying ratio of ∼178 and ideality factor of 1.79 at 300 K. Detectors made with such structure exhibit mid-infrared spectral photoresponse at room temperature. The peak responsivity R{sub λ} and specific detectivity D{sup *} are 0.055 A/W and 5.482 × 10{sup 8} cm·Hz{sup 1/2}/W at λ = 4.7 μm under zero-bias photovoltaic mode. Temperature-dependent photoresponse measurements show abnormal intensity variation below ∼200 K. Possible reasons for this phenomenon are also discussed.

  7. Record Seebeck coefficient and extremely low thermal conductivity in nanostructured SnSe

    SciTech Connect (OSTI)

    Serrano-Sánchez, F.; Gharsallah, M.; Nemes, N. M.; Mompean, F. J.; Martínez, J. L.; Alonso, J. A.

    2015-02-23

    SnSe has been prepared by arc-melting, as mechanically robust pellets, consisting of highly oriented polycrystals. This material has been characterized by neutron powder diffraction (NPD), scanning electron microscopy, and transport measurements. A microscopic analysis from NPD data demonstrates a quite perfect stoichiometry SnSe{sub 0.98(2)} and a fair amount of anharmonicity of the chemical bonds. The Seebeck coefficient reaches a record maximum value of 668 μV K{sup −1} at 380 K; simultaneously, this highly oriented sample exhibits an extremely low thermal conductivity lower than 0.1 W m{sup −1} K{sup −1} around room temperature, which are two of the main ingredients of good thermoelectric materials. These excellent features exceed the reported values for this semiconducting compound in single crystalline form in the moderate-temperatures region and highlight its possibilities as a potential thermoelectric material.

  8. Algorithmically scalable block preconditioner for fully implicit shallow-water equations in CAM-SE

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lott, P. Aaron; Woodward, Carol S.; Evans, Katherine J.

    2014-10-19

    Performing accurate and efficient numerical simulation of global atmospheric climate models is challenging due to the disparate length and time scales over which physical processes interact. Implicit solvers enable the physical system to be integrated with a time step commensurate with processes being studied. The dominant cost of an implicit time step is the ancillary linear system solves, so we have developed a preconditioner aimed at improving the efficiency of these linear system solves. Our preconditioner is based on an approximate block factorization of the linearized shallow-water equations and has been implemented within the spectral element dynamical core within themore » Community Atmospheric Model (CAM-SE). Furthermore, in this paper we discuss the development and scalability of the preconditioner for a suite of test cases with the implicit shallow-water solver within CAM-SE.« less

  9. Low-cost CuInSe[sub 2] submodule development

    SciTech Connect (OSTI)

    Basol, B.M.; Kapur, V.K.; Halani, A.; Leidholm, C. )

    1992-10-01

    Aim of this project is development and demonstration of processing steps necessary for fabrication of high efficiency CuInSe[sub 2] solar cells and sub-modules by the two-stage technique (also called the selenization method.) During this period, we have optimized the processing parameters of this method and demonstrated CuInSe[sub 2]/CdS/ZnO devices with a 1[endash]4 cm[sup 2] area and up to 12.4% active area efficiency. We have also developed a novel approach for the preparation of Cu/In precursors that improved the stoichiometric and morphological uniformity in these films. We have developed processing steps and tooling for handling up to 1 ft[sup 2] size substrates and as a result of these efforts demonstrated our first monolithically integrated sub-module of 1 ft[sup 2] area. 16 figs, 1 tab, 15 refs.

  10. Algorithmically scalable block preconditioner for fully implicit shallow-water equations in CAM-SE

    SciTech Connect (OSTI)

    Lott, P. Aaron; Woodward, Carol S.; Evans, Katherine J.

    2014-10-19

    Performing accurate and efficient numerical simulation of global atmospheric climate models is challenging due to the disparate length and time scales over which physical processes interact. Implicit solvers enable the physical system to be integrated with a time step commensurate with processes being studied. The dominant cost of an implicit time step is the ancillary linear system solves, so we have developed a preconditioner aimed at improving the efficiency of these linear system solves. Our preconditioner is based on an approximate block factorization of the linearized shallow-water equations and has been implemented within the spectral element dynamical core within the Community Atmospheric Model (CAM-SE). Furthermore, in this paper we discuss the development and scalability of the preconditioner for a suite of test cases with the implicit shallow-water solver within CAM-SE.