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Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Removal of trace olefins from aromatic hydrocarbons  

SciTech Connect (OSTI)

A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

Sachtler, J.W.A.; Barger, P.T.

1989-01-03T23:59:59.000Z

2

Recovering hydrocarbons from hydrocarbon-containing vapors  

DOE Patents [OSTI]

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

1980-09-30T23:59:59.000Z

3

Increased olefins production via recovery of refinery gas hydrocarbons  

SciTech Connect (OSTI)

In the process of catalytically cracking heavy petroleum fractions to make gasoline and light fuel oil, by-product waste gases are also generated. The waste gases, normally used as fuel, are themselves rich sources of ethylene, propylene and other light hydrocarbons which can be recovered inexpensively via a cryogenic dephlegmator process. This gas separation technique is exploited in a system, in operation since spring of 1987, which reclaims C/sub 2/+ hydrocarbons from a refinery gas. The reclamation process bolsters production in a nearby ethylene plant. Causing no disruption of ethylene plant operations, the cryogenic hydrocarbon recovery system functions smoothly with existing systems. The dephlegmation unit operation melds distillation and heat transfer processes in a single easily-controlled step which boosts the hydrocarbon purity and recovery above the levels profitably achievable with conventional cryogenic separation techniques. Very attractive operating economics follow from high purity, high recovery, and high energy efficiency. This paper discusses process concepts, economic benefits, plant operation, and early performance results.

Bernhard, D.P.; Rowles, H.C.; Moss, J.A.; Pickering, J.L. Jr.

1988-01-01T23:59:59.000Z

4

Process for recovering hydrocarbons from a hydrocarbon-bearing formation  

SciTech Connect (OSTI)

A method is described for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

Alston, R.B.; Braden, W.B.; Flournoy, K.H.

1980-03-11T23:59:59.000Z

5

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

6

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

7

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

8

The methanol-to-hydrocarbons reaction : Influence of acid strength on the mechanism of olefin formation.  

E-Print Network [OSTI]

??The methanol-to-hydrocarbons (MTH) reaction is a flexible alternative step in the upgrading of natural gas, coal or biomass. By tuning the catalyst and process conditions,… (more)

Erichsen, Marius Westgård

2010-01-01T23:59:59.000Z

9

In situ method for recovering hydrocarbon from subterranean oil shale deposits  

SciTech Connect (OSTI)

This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

Friedman, R.H.

1987-11-03T23:59:59.000Z

10

Olefin recovery via chemical absorption  

SciTech Connect (OSTI)

The recovery of fight olefins in petrochemical plants has generally been accomplished through cryogenic distillation, a process which is very capital and energy intensive. In an effort to simplify the recovery process and reduce its cost, BP Chemicals has developed a chemical absorption technology based on an aqueous silver nitrate solution. Stone & Webster is now marketing, licensing, and engineering the technology. The process is commercially ready for recovering olefins from olefin derivative plant vent gases, such as vents from polyethylene, polypropylene, ethylene oxide, and synthetic ethanol units. The process can also be used to debottleneck C{sub 2} or C{sub 3} splinters, or to improve olefin product purity. This paper presents the olefin recovery imp technology, discusses its applications, and presents economics for the recovery of ethylene and propylene.

Barchas, R. [Stone & Webster Engineering Corporation, Houston, TX (United States)

1998-06-01T23:59:59.000Z

11

Process for recovering uranium from waste hydrocarbon oils containing the same. [Uranium contaminated lubricating oils from gaseous diffusion compressors  

DOE Patents [OSTI]

The invention is a process for the recovery of uranium from uranium-bearing hydrocarbon oils containing carboxylic acid as a degradation product. In one aspect, the invention comprises providing an emulsion of water and the oil, heating the same to a temperature effecting conversion of the emulsion to an organic phase and to an acidic aqueous phase containing uranium carboxylate, and recovering the uranium from the aqueous phase. The process is effective, simple and comparatively inexpensive. It avoids the use of toxic reagents and the formation of undesirable intermediates.

Conrad, M.C.; Getz, P.A.; Hickman, J.E.; Payne, L.D.

1982-06-29T23:59:59.000Z

12

Process feasibility of DME to olefin conversion  

SciTech Connect (OSTI)

The production of hydrocarbons via a synthetic route has been extensively studied by Mobil through its methanol based Methanol-to-Gasoline (MTG) process. An alternative approach using dimethyl ether (DME) has been developed by the University of Akron -- UA/EPRI DME-to-Hydrocarbons Process. The process feasibility of the production of hydrocarbons from DME has been illustrated in a bench scale, fluidized bed reactor using ZSM-5 type catalyst. In an effort to satisfy the growing demand for olefins as an intermediate chemical feedstocks a mechanistic/kinetic study was developed. The synthesis of olefins has been studied in packed bed micro-reactor using ZSM-5 catalyst. Experimental work has given details of reaction kinetics and mechanism in the conversion of DME to olefins. DME concentration weight hourly space velocity (WHSV), as well as reactor temperature and pressure were investigated in the study. This work was used as a precursor to the production of olefins/hydrocarbons from DME in a fluidized bed reactor. Product gas analysis was performed using an external GC standard method.

Tartamella, T.L.; Fullerton, K.L.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

13

Copolymer SAFT modeling of phase behavior in hydrocarbon-chain solutions: Alkane oligomers, polyethylene, poly(ethylene-co-olefin-1), polystyrene, and poly(ethylene-co-styrene)  

SciTech Connect (OSTI)

The copolymer SAFT equation of state is found to represent phase transitions in the normal-alkane and methyl-alkane solutions in methane, ethane, propane, and n-hexane, the polyethylene and poly(ethylene-co-olefin-1) solutions in propane, and the polystyrene solutions in n-butane. The pure-solute parameters are all estimated on the basis of the molecular weight and structure only, and the one temperature-independent and system-independent (within each class of solutes) binary parameter is set equal to a constant. The segment energy of the methyl branches is found to be around 160 K, which is lower than the corresponding backbone energy, while the segment energy of the benzene branches is found to be around 222 K for polystyrene, which is higher than the corresponding backbone energy. The alkyl branches are found to promote the polymer miscibility while the benzene branches are found to inhibit the polymer miscibility in propane.

Pan, C.; Radosz, M. [Louisiana State Univ., Baton Rouge, LA (United States)] [Louisiana State Univ., Baton Rouge, LA (United States)

1998-08-01T23:59:59.000Z

14

FIELD DEMONSTRATION OF A MEMBRANE PROCESS TO RECOVER HEAVY HYDROCARBONS AND TO REMOVE WATER FROM NATURAL GAS  

SciTech Connect (OSTI)

The objective of this project is to design, construct and field demonstrate a 3-MMscfd membrane system to recover natural gas liquids (NGL) and remove water from raw natural gas. An extended field test to demonstrate system performance under real-world conditions is required to convince industry users of the efficiency and reliability of the process. The system will be designed and fabricated by Membrane Technology and Research, Inc. (MTR) and then installed and operated at British Petroleum (BP)-Amoco's Pascagoula, MS plant. The Gas Research Institute will partially support the field demonstration and BP-Amoco will help install the unit and provide onsite operators and utilities. The gas processed by the membrane system will meet pipeline specifications for dewpoint and Btu value and can be delivered without further treatment to the pipeline. Based on data from prior membrane module tests, the process is likely to be significantly less expensive than glycol dehydration followed by propane refrigeration, the principal competitive technology. At the end of this demonstration project the process will be ready for commercialization. The route to commercialization will be developed during this project and may involve collaboration with other companies already servicing the natural gas processing industry.

K.A. Lokhandwala; T. Hofmann; J. Kaschemekat; C. Bailey; M. Jacobs; R. Baker; Membrane Group

2000-04-04T23:59:59.000Z

15

FIELD DEMONSTRATION OF A MEMBRANE PROCESS TO RECOVER HEAVY HYDROCARBONS AND TO REMOVE WATER FROM NATURAL GAS  

SciTech Connect (OSTI)

The objective of this project is to design, construct and field demonstrate a 3-MMscfd membrane system to recover natural gas liquids (NGL) and remove water from raw natural gas. An extended field test to demonstrate system performance under real-world conditions is required to convince industry users of the efficiency and reliability of the process. The system will be designed and fabricated by Membrane Technology and Research, Inc. (MTR) and then installed and operated at British Petroleum (BP)-Amoco's Pascagoula, MS plant. The Gas Research Institute will partially support the field demonstration and BP-Amoco will help install the unit and provide onsite operators and utilities. The gas processed by the membrane system will meet pipeline specifications for dewpoint and Btu value and can be delivered without further treatment to the pipeline. Based on data from prior membrane module tests, the process is likely to be significantly less expensive than glycol dehydration followed by propane refrigeration, the principal competitive technology. At the end of this demonstration project the process will be ready for commercialization. The route to commercialization will be developed during this project and may involve collaboration with other companies already servicing the natural gas processing industry.

R. Baker; T. Hofmann; J. Kaschemekat; K.A. Lokhandwala; Membrane Group; Module Group; Systems Group

2001-01-11T23:59:59.000Z

16

Selective olefin recovery  

SciTech Connect (OSTI)

This report presents the results of the outstanding studies on olefin product purities, pyridine recovery, and absorber offgas utilization. Other reports issued since the May 2 technical review meeting in Grangemouth evaluated the impact of the new VLE data on the solution stripping operation and the olefin loadings in the lean and rich solutions. This report completes the bulk of Stone & Webster`s engineering development of the absorber/stripper process for Phase I. The final feasibility study report (to be issued in August) will present an updated design and economics.

NONE

1996-07-01T23:59:59.000Z

17

DME-to-olefin process over ZSM-5 catalyst  

SciTech Connect (OSTI)

The production of hydrocarbons via a synthetic route has been extensively studied by Mobil in its MTG process. The focus of much of this research was centered on gasoline range hydrocarbons from a methanol feedstock. Since its development, a novel, more efficient hydrocarbon synthesis process has been developed by the University of Akron using dimethyl ether; namely UA/EPRI DME-to-Hydrocarbon process (DTG). The DTG process has many distinct advantages over Mobil`s methanol based MTG process. Key features of the DTG process include enhanced per-pass conversion and volumetric productivity, lower heat duties, extended catalyst life, and higher selectivity to hydrocarbons. Product distributions for the DTG process are similar to the MTG process. In an effort to satisfy the industries growing need for olefins, it became necessary to determine which set of operating parameters affected the olefinic fraction of the product gas. Product distributions were determined for various levels of DUE weight hourly space velocity, as well as reactor temperature and pressure. The experimental investigation took place in a fixed bed micro-reactor. Capable of holding 1--15 g catalyst, the fixed bed was designed to obtain kinetic/mechanistic data for hydrocarbon production. Product gas analysis was performed using an external GC standard method.

Lee, S.; Sardesai, A.; Tartamella, T.L. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

18

Energy Management in Olefins Units  

E-Print Network [OSTI]

to the point where waste heat from pyrolysis generates more than enough steam to power the olefins unit recovery section. Furthermore, incorporating gas turbine driven electrical generators or process compressors adds to the utility export potential of the unit...

Wells, T. A.

1982-01-01T23:59:59.000Z

19

Stereospecific olefin polymerization catalysts  

DOE Patents [OSTI]

A metallocene catalyst system is described for the polymerization of {alpha}-olefins to yield stereospecific polymers including syndiotactic, and isotactic polymers. The catalyst system includes a metal and a ligand of the formula shown wherein: R{sup 1}, R{sup 2}, and R{sup 3} are independently selected from the group consisting of hydrogen, C{sub 1} to C{sub 10} alkyl, 5 to 7 membered cycloalkyl, which in turn may have from 1 to 3 C{sub 1} to C{sub 10} alkyls as a substituent, C{sub 6} to C{sub 15} aryl or arylalkyl in which two adjacent radicals may together stand for cyclic groups having 4 to 15 carbon atoms which in turn may be substituted, or Si(R{sup 8}){sub 3} where R{sup 8} is selected from the group consisting of C{sub 1} to C{sub 10} alkyl, C{sub 6} to C{sub 15} aryl or C{sub 3} to C{sub 10} cycloalkyl; R{sup 4} and R{sup 6} are substituents both having van der Waals radii larger than the van der Waals radii of groups R{sup 1} and R{sup 3}; R{sup 5} is a substituent having a van der Waals radius less than about the van der Waals radius of a methyl group; E{sup 1}, E{sup 2} are independently selected from the group consisting of Si(R{sup 9}){sub 2}, Si(R{sup 9}){sub 2}--Si(R{sup 9}){sub 2}, Ge(R{sup 9}){sub 2}, Sn(R{sup 9}){sub 2}, C(R{sup 9}){sub 2}, C(R{sup 9}){sub 2}--C(R{sup 9}){sub 2}, where R{sup 9} is C{sub 1} to C{sub 10} alkyl, C{sub 6} to C{sub 15} aryl or C{sub 3} to C{sub 10} cycloalkyl; and the ligand may have C{sub S} or C{sub 1}-symmetry. Preferred metals are selected from the group consisting of group III, group IV, group V or lanthanide group elements. The catalysts are used to prepare stereoregular polymers including polypropylene from {alpha}-olefin monomers.

Bercaw, J.E.; Herzog, T.A.

1998-01-13T23:59:59.000Z

20

Stereospecific olefin polymerization catalysts  

DOE Patents [OSTI]

A metallocene catalyst system for the polymerization of .alpha.-olefins to yield stereospecific polymers including syndiotactic, and isotactic polymers. The catalyst system includes a metal and a ligand of the formula ##STR1## wherein: R.sup.1, R.sup.2, and R.sup.3 are independently selected from the group consisting of hydrogen, C.sub.1 to C.sub.10 alkyl, 5 to 7 membered cycloalkyl, which in turn may have from 1 to 3 C.sub.1 to C.sub.10 alkyls as a substituent, C.sub.6 to C.sub.15 aryl or arylalkyl in which two adjacent radicals may together stand for cyclic groups having 4 to 15 carbon atoms which in turn may be substituted, or Si(R.sup.8).sub.3 where R.sup.8 is selected from the group consisting of C.sub.1 to C.sub.10 alkyl, C.sub.6 to C.sub.15 aryl or C.sub.3 to C.sub.10 cycloalkyl; R.sup.4 and R.sup.6 are substituents both having van der Waals radii larger than the van der Waals radii of groups R.sup.1 and R.sup.3 ; R.sup.5 is a substituent having a van der Waals radius less than about the van der Waals radius of a methyl group; E.sup.1, E.sup.2 are independently selected from the group consisting of Si(R.sup.9).sub.2, Si(R.sup.9).sub.2 --Si(R.sup.9).sub.2, Ge(R.sup.9).sub.2, Sn(R.sup.9).sub.2, C(R.sup.9).sub.2, C(R.sup.9).sub.2 --C(R.sup.9).sub.2, where R.sup.9 is C.sub.1 to C.sub.10 alkyl, C.sub.6 to C.sub.15 aryl or C.sub.3 to C.sub.10 cycloalkyl; and the ligand may have C.sub.S or C.sub.1 -symmetry. Preferred metals are selected from the group consisting of group III, group IV, group V or lanthanide group elements. The catalysts are used to prepare stereoregular polymers including polypropylene from .alpha.-olefin monomers.

Bercaw, John E. (Pasadena, CA); Herzog, Timothy A. (Pasadena, CA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Selective olefin recovery  

SciTech Connect (OSTI)

This interim report has been prepared as a followup to the January 1996 JDAG meeting. The report presents the results of various studies which evaluate the impact of process design changes on the overall SOR economics for cracked gas olefin recovery. The changes were made to either complete portions of the design that were missing or overlooked, or to improve and/or optimize the SOR process. A grass-roots propane-feed 350,000 MTA plant with a conventional recovery system was adopted as the study basis, and was compared with SOR systems of various sizes up to 350,000 MTA. This approach was taken to determine if SOR plants could be competitive with larger plants utilizing conventional recovery systems. Second phase KG expansion by 50,000-150,000 MTA ethylene was reexamined in view of the SOR process optimization. As was done in Stone & Webster`s December 1995 study, an SOR system was compared with an ARS expansion.

NONE

1996-04-01T23:59:59.000Z

22

Olefin Metathesis of Renewable Platform Chemicals  

Science Journals Connector (OSTI)

Olefinic double bonds are often found in the structure of natural compounds. This makes olefin metathesis a powerful tool for their transformation into valuable renewable platform chemicals and, in some cases, di...

Lucas Montero de Espinosa; Michael A. R. Meier

2012-01-01T23:59:59.000Z

23

Structure H hydrate phase equilibria of paraffins, naphthalenes, and olefins with methane  

SciTech Connect (OSTI)

Initial phase equilibrium data are reported for 10 methane + liquid hydrocarbon systems forming structure H hydrates in the pressure range of 1--6 MPa. Four-phase equilibrium conditions were measured for each system, with paraffinic, naphthenic, and olefinic liquid hydrocarbons filling the large cage of structure H, and methane stabilizing the two smaller cages present in the hydrate. Many of these liquid hydrocarbons constitute a small fraction of crude oils and condensates, and the high stability and relative ease of formation of structure H suggest a possible impact of these hydrates upon hydrocarbon facilities.

Mehta, A.P.; Sloan, E.D. Jr. (Colorado School of Mines, Golden, CO (United States))

1994-10-01T23:59:59.000Z

24

Fluid-bed studies of olefin production from methanol  

SciTech Connect (OSTI)

With newly developed technology, conversion of methanol to hydrocarbons represents the final link in the production of premium transportation fuels from coal or natural gas. The methanol-to-gasoline (MTG) process has been developed. The more readily scaled fixed-bed version is the heart of the New Zealand Gas-to-gasoline complex, which will produce 14,000 BPD high octane gasoline from 120 million SCFD gas. The fluid-bed version of the process, which is also available for commercial license, has a higher thermal efficiency and possesses substantial yield and octane advantages over the fixed-bed. Successful scale-up was completed in 1984 in a 100 BPD semi-works plant near Cologne, West Germany. The project funded jointly by the U.S. and German governments and an industrial consortium comprised of Mobil; Union Rheinsche Braunkohlen Kraftstoff, AG; and Uhde, GmbH. The 100 BPD MTG project was extended recently to demonstrate a related fluid bed process for selective conversion of methanol to light olefins (MTO). The products of the MTO reaction make an excellent feed to the commercially available Mobile-Olefins-to-Gasoline-and-Distillate process (MOGD) which selectively converts olefins to premium transportation fuels . A schematic of the combined processes is shown. Total liquid fuels production is typically greater than 90 wt% of hydrocarbon in the feed. Distillate/gasoline product ratios from the plant can be adjusted over a wide range to meet seasonal demands. This paper describes the initial scale-up of the MTO process from a micro-fluid-bed reactor (1-10 grams of catalyst) to a large pilot unit (10-25 kilograms of catalyst).

Socha, R.F.; Chang, C.D.; Gould, R.M.; Kane, S.E.; Avidan, A.A.

1986-03-01T23:59:59.000Z

25

Catalyst-Assisted Production of Olefins from Natural Gas Liquids...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing, April 2013 Catalyst-Assisted Production of Olefins from Natural Gas...

26

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

27

Determination of Hydrocarbons Types and Oxygenates in Motor Gasoline: A Comparative Study by Different Analytical Techniques  

Science Journals Connector (OSTI)

Various standard and published methods based on chromatographic and spectroscopic techniques are routinely used for hydrocarbon types (aromatics, olefins, oxygenates, etc.) in gasoline range fuel products for the assessment of product quality monitoring (...

V. Bansal; G. J. Krishna; A. P. Singh; A. K. Gupta; A. S. Sarpal

2007-12-04T23:59:59.000Z

28

Hydrogen transfer in transformations of olefin and thiophene compounds for the refining of gasoline fractions  

Science Journals Connector (OSTI)

Abstract Hydrogen transfer reactions in the transformations of mixtures of model hydrocarbons (hydrogen donors and acceptors) on zeolite catalysts were studied. Hydrogen donors were represented by various classes of hydrocarbons, and acceptors—by unsaturated (olefin) and thiophene compounds. The [H]-donor activity series of hydrocarbons was revealed. Strong differences in the transformation pathways of 1-hexene and 1-octene under the conditions of catalytic refining were demonstrated. A new method for the refining of low-rank gasoline fractions was proposed. The method is based on the hydrogen transfer reactions between hydrogen donor hydrocarbons and hydrogen acceptor hydrocarbons, which proceed without molecular hydrogen. The proposed method allows the simultaneous removal of sulfur (more than 95%) and unsaturated (more than 90%) compounds.

Oleg V. Potapenko; Vladimir P. Doronin; Tatyana P. Sorokina; Vladimir A. Likholobov

2014-01-01T23:59:59.000Z

29

An Olefin Unit's Energy Audit and Implementation  

E-Print Network [OSTI]

-year $44 million capital program which resulted from the Audit. Reorganization of the Olefin unit technical staff to complete the energy conservation program is covered. Several techniques being used to insure operator and maintenance commitment to energy...

Buehler, J. H.

1979-01-01T23:59:59.000Z

30

Preparation of synthetic hydrocarbon lubricants  

SciTech Connect (OSTI)

A process is described for preparing synthetic lubricating materials which process comprises: (a) reacting (i) at least a portion of a reaction product of the liquid phase oligomerization of propylene, butylene or mixtures thereof containing a C/sub 6/ olefin component, (ii) a linear olefin reactant having an average carbon number ranging from about 10 to about 18 in the presence of a catalyst, (b) separating from the reaction mixture of (a) hydrocarbons which distill at a temperature above about 660/sup 0/ F. (316/sup 0/ C.), and (c) hydrogenating the reaction product of (b) by contact with hydrogen with or without a catalyst at a temperature ranging from about 25/sup 0/ C. to about 300/sup 0/ C.

Johnson, T.H.

1986-10-07T23:59:59.000Z

31

Energy Conservation in Existing Olefins Plants  

E-Print Network [OSTI]

The manufacture of olefins in a modern steam cracking plant consumes a great deal of energy. Depending upon the feedstock, between 6000 and 12000 BTU per pound of ethylene produced is required. In older designs, those designed prior to the first...

DeHaan, S.

1983-01-01T23:59:59.000Z

32

Homogeneous catalysts for stereoregular olefin polymerization  

DOE Patents [OSTI]

The synthesis, and use as precatalysts of chiral organozirconium complexes for olefin polymerization are disclosed, having the structure (C[sub 5]R[prime][sub 4[minus]x]R*[sub x])-A-(C[sub 5]R[double prime][sub 4[minus]y]R[prime][double prime][sub y])-M-Q[sub p], where x and y represent the number of unsubstituted locations on the cyclopentadienyl ring; R[prime], R[double prime], R[prime][double prime], and R* represent substituted and unsubstituted alkyl groups having 1--30 carbon atoms and R* is a chiral ligand; A is a fragment containing a Group 13, 14, 15, or 16 element of the Periodic Table; M is a Group 3, 4, or 5 metal of the Periodic Table; and Q is a hydrocarbyl radical, or halogen radical, with 3 [<=] p [<=] 0. Related complexes may be prepared by alkylation of the corresponding dichlorides. In the presence of methylalumoxane or triarylborane cocatalysts, these complexes form cation-like'' species which are highly active for olefin polymerization. In combination with a Lewis acid cocatalyst, propylene or other [alpha]-olefin polymerization can be effected with very high efficiency and isospecificity. 1 fig.

Marks, T.J.; Eisen, M.S.; Giardello, M.A.

1994-07-19T23:59:59.000Z

33

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents [OSTI]

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

34

Catalyst-Assisted Production of Olefins from Natural Gas Liquids...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing New Process Produces Ethylene More Efficiently and Reduces Coke...

35

A Well-Defined, Silica-Supported Tungsten Imido Alkylidene Olefin Metathesis Catalyst  

E-Print Network [OSTI]

olefin metathesis catalyst. Bouchra Rhers, a Alain Salameh,active propene metathesis catalyst, which can achieve 16000W-based olefin metathesis catalyst through the reaction of [

2006-01-01T23:59:59.000Z

36

Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process  

Science Journals Connector (OSTI)

Abstract Olefins are one of the most important oil derivatives widely used in industry. To reduce the dependence of olefins industry on oil, China is increasing the production of olefins from alternative energy resources, especially from coal. This study is concerned with the opportunities and obstacles of coal-to-olefins development, and focuses on making an overall techno-economic analysis of a coal-to-olefins plant with the capacity of 0.7 Mt/a olefins. Comparison is made with a 1.5 Mt/a oil-to-olefins plant based on three criteria including energy efficiency, capital investment, and product cost. It was found that the coal-based olefins process show prominent advantage in product cost because of the low price of its feedstock. However, it suffers from the limitations of higher capital investment, lower energy efficiency, and higher emissions. The effects of production scale, raw material price, and carbon tax were varied for the two production routes, and thus the operational regions were found for the coal-to-olefins process to be competitive.

Dong Xiang; Yu Qian; Yi Man; Siyu Yang

2014-01-01T23:59:59.000Z

37

Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide  

DOE Patents [OSTI]

A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

Rathke, J.W.; Klingler, R.J.

1993-03-30T23:59:59.000Z

38

Highly Z-Selective Metathesis Homocoupling of Terminal Olefins  

E-Print Network [OSTI]

Mo and W MonoAryloxide-Pyrrolide (MAP) olefin metathesis catalysts can couple terminal olefins to give as high as >98% Z-products in moderate to high yields with as little as 0.2% catalyst. Results are reported for 1-hexene, ...

Jiang, Annie J.

39

Thermochemistry for Hydrocarbon Intermediates Chemisorbed on Metal Surfaces: CHn-m(CH3)m with n ) 1, 2, 3 and m e n on Pt, Ir,  

E-Print Network [OSTI]

for hydrocarbons on metal surfaces similar to the Benson scheme so useful for gas-phase hydrocarbons. This is used-bond isomerization of olefins, (3) dehydrogenation and dehydro- isomerization to aromatics, (4) isomerization processes. Although molecular orbital and valence bond theories have helped explain the nature of reactivity

Goddard III, William A.

40

A generalized viscosity equation for pure heavy hydrocarbons  

SciTech Connect (OSTI)

This paper presents a method for the correlation and prediction of the viscosity of pure heavy hydrocarbons listed in API Research Project 42. The 273 heavy hydrocarbons in the database include branched/unbranched paraffins and olefins together with a variety of complex nonfused/fused aromatic and naphthenic compounds. A generalized one-parameter viscosity-temperature equation, log ({mu} + 0.8) = 100(0.01T){sup b}, is proposed (overall AAD {lt} 7-10%) for all heavy hydrocarbons in the database. For each hydrocarbon, an optimum value of parameter b is provided. It is shown that parameter b varies linearly with the logarithm of molar mass as well as the inverse of boiling temperature (at 10 mmHg). This important observation leads to the development of a predictive method for the liquid-phase viscosity of pure heavy hydrocarbons.

Mehrotra, A.K. (Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta T2N 1N4 (CA))

1991-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Process for using preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect (OSTI)

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream, wherein a need exists for recovering to any selected degree and at extremely high recoveries a selected hydrocarbon component and heavier hydrocarbons. The hydrocarbons are within the group consisting of ethane, propane, butane, and pentane without the need simultaneously to recover hydrocarbons lighter than the selected hydrocarbon component from the hydrocarbon gas stream, The improvement of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent is described here. The method provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100%.

Mehra, Y.R.

1986-10-14T23:59:59.000Z

42

Zwitterionic Group VIII transition metal initiators supported by olefin ligands  

DOE Patents [OSTI]

A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.

Bazan, Guillermo C. (Goleta, CA); Chen, Yaofeng (Shanghai, CN)

2011-10-25T23:59:59.000Z

43

ExxonMobil Olefins Plant Projects, Maintenance and Optimizations  

E-Print Network [OSTI]

are endothermic and there are drastic differences in temperature and pressure across the process Quench & Heat Recovery Steam Cracker Furnace Compression Refrigeration Fractionation Cracked Products ProductsFeed Fuel 60% 35% 5% Ethylene Plant Energy Consumption...ExxonMobil Olefins Plant Projects, Maintenance and Optimizations Matt Neely Utilities Coordinator ExxonMobil Baytown Olefins Plant 2014 IETC May 21, 2014 ESL-IE-14-05-02 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New...

Neely, M. M.

2014-01-01T23:59:59.000Z

44

Biological enhancement of hydrocarbon extraction  

DOE Patents [OSTI]

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

45

Ionic liquids for separation of olefin-paraffin mixtures  

DOE Patents [OSTI]

The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

2013-09-17T23:59:59.000Z

46

Ionic liquids for separation of olefin-paraffin mixtures  

DOE Patents [OSTI]

The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

2014-07-15T23:59:59.000Z

47

Low Severity Coal Liquefaction Promoted by Cyclic Olefins  

SciTech Connect (OSTI)

The development of the donor solvent technology for coal liquefaction has drawn a good deal of attention over the last three decades. The search for better hydrogen donors led investigators to a class of compounds known as cyclic olefins. Cyclic olefins are analogues of the conventional hydroaromatic donor species but do not contain aromatic rings. The cyclic olefins are highly reactive compounds which readily release their hydrogen at temperatures of 200 C or higher. Considerable effort has been o expended toward understanding the process of hydrogen donation. Most of this work was conducted in bomb reactors, with product analysis being carried out after the reaction was complete. Efforts directed towards fundamental studies of these reactions in situ are rare. The current work employs a high temperature and high pressure infrared cell to monitor in situ the concentrations of reactants and products during hydrogen release from hydrogen donor compounds.

Christine W. Curtis

1998-04-09T23:59:59.000Z

48

Composition of paraffinic and naphthenic hydrocarbons in petroleum asphalts  

SciTech Connect (OSTI)

Uses a combination of chromatographic, chemical, and spectroscopic methods to determine the composition of the paraffinic and naphthenic hydrocarbons recovered from asphalts. Monitors the completeness of separation of the hydrocarbons from the aromatics on the basis of UV spectra. Finds that in the mixture of adduct-forming hydrocarbons, along with the n-paraffins there were admixtures of isoparaffins and longchain alkylnaphthenes. Concludes that a comparison of the structural-group composition of the asphalt fractions from the different crudes shows that there are only slight differences in the structure of the paraffinic/naphthenic hydrocarbons present in these asphalts, particularly with regard to those hydrocarbons that do not react with urea.

Botvin'eva, A.M.; Dubkova, R.V.; Shkredova, N.A.

1982-11-01T23:59:59.000Z

49

FINAL TECHNICAL REPORT Synthetic, Structural and Mechanistic Investigations of Olefin Polymerization Catalyzed by Early Transition Metal Compounds  

SciTech Connect (OSTI)

The goal of this project is to develop new catalysts and provide understanding of ligand effects on catalyst composition in order to guide development of superior catalyst systems for polymerization of olefins. Our group is designing and synthesizing new “LX2”,“pincer” type ligands and complexing early transition metals to afford precatalysts. In a collaboration with Hans Brintzinger from the University of Konstanz, we are also examining the structures of the components of catalyst systems obtained from reaction of zirconocene dichlorides with aluminum alkyls and aluminum hydrides. Such systems are currently used commercially to produce polyolefins, but the nature of the active and dormant species as well as the mechanisms of their interconversions are not understood. New information on catalyst design and performance may lead to new types of polymers and/or new chemical transformations between hydrocarbons and transition metal centers, ultimately contributing to the development of catalytic reactions for the production of fuels, commodity and polymeric materials.

Bercaw, John E. [California Institute of Technology

2014-05-23T23:59:59.000Z

50

Catalysts and process for liquid hydrocarbon fuel production  

DOE Patents [OSTI]

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

White, Mark G; Liu, Shetian

2014-12-09T23:59:59.000Z

51

Recovering Plastics from Retired Vehicles  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shredded plastic materials recovered Shredded plastic materials recovered from retired cars and trucks can be used to manufacture new vehicle parts and other plastic products. Left: Items from shredder residue, recovered polyethylene and polypropylene, and a knee bolster manufactured from recovered plastics. Right: Argonne's froth flotation pilot plant. Background For years vehicle manufacturers have been designing and building new cars and trucks with the goal that structural materials in ELVs will be recycled, reducing the flow of material into the solid-waste stream. At the same time, automakers must ensure that the design materials selected for their ability to be recycled do not impair the safety, reliability, and performance of the completed vehicle. In the United States between 12 and 15 million vehicles reach

52

Methanol conversion to higher hydrocarbons  

SciTech Connect (OSTI)

Several indirect options exist for producing chemicals and transportation fuels from coal, natural gas, or biomass. All involve an initial conversion step to synthesis gas (CO and H{sub 2}). Presently, there are two commercial technologies for converting syngas to liquids: Fischer-Tropsch, which yields a range of aliphatic hydrocarbons with molecular weights determined by Schulz-Flory kinetics, and methanol synthesis. Mobil`s diversity of technology for methanol conversion gives the methanol synthesis route flexibility for production of either gasoline, distillate or chemicals. Mobil`s ZSM-5 catalyst is the key in several processes for producing chemicals and transportation fuels from methanol: MTO for light olefins, MTG for gasoline, MOGD for distillates. The MTG process has been commercialized in New Zealand since 1985, producing one-third of the country`s gasoline supply, while MTO and MOGD have been developed and demonstrated at greater than 100 BPD scale. This paper will discuss recent work in understanding methanol conversion chemistry and the various options for its use.

Tabak, S.A. [Mobil Research and Development Corp., Princeton, NJ (United States). Central Research Lab.

1994-12-31T23:59:59.000Z

53

Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis  

DOE Patents [OSTI]

This invention relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by a selected olefin metathesis catalyst. In one embodiment of the invention, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting an olefinic substrate comprised of at least one internal olefin with ethylene, in the presence of a metathesis catalyst, wherein the catalyst is present in an amount that is less than about 1000 ppm relative to the olefinic substrate, and wherein the metathesis catalyst has the structure of formula (II) ##STR00001## wherein the various substituents are as defined herein. The invention has utility, for example, in the fields of catalysis, organic synthesis, and industrial chemistry.

Schrodi, Yann (Agoura Hills, CA)

2011-11-29T23:59:59.000Z

54

Low severity coal liquefaction promoted by cyclic olefins  

SciTech Connect (OSTI)

Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

Curtis, C.W.

1992-07-27T23:59:59.000Z

55

Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction  

Science Journals Connector (OSTI)

A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction.

Emamzadah, S.

2009-08-06T23:59:59.000Z

56

Carbon molecular sieve hollow fiber membranes for olefin/paraffin separations.  

E-Print Network [OSTI]

??Olefin/paraffin separation is a large potential market for membrane applications. Carbon molecular sieve membranes (CMS) are promising for this application due to the intrinsically high… (more)

Xu, Liren

2013-01-01T23:59:59.000Z

57

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

58

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

59

Naphthenic hydrocarbons  

SciTech Connect (OSTI)

An important type of naphthenic hydrocarbons is the monocyclic type, (k/sub 2/, 0, 0). In this instance the number of carbon atoms, n = k/sub 2/, and a formula, C/sub n/H/sub 2n/, can be written where H/C = 2. The value n can vary from 2 to infinity. In the case of n = 2, it is ethylene (I) (2-membered cyclic ring); n = 3, cyclopropane (II) (3-membered cyclic ring); n = 4, cyclobutane (III) (4-membered cyclic ring); etc. If the monocyclic naphthenic is planar, then the bond angle theta can be expressed as theta = (1 - 2/n)..pi.. where n is the number of carbon atoms. However, the tetrahedron angle of the carbon atom being phi = cos/sup -1/ (- 1/3).

Yen, T.F.; Kuo, J.F.; Chilingarian, G.V.

1987-01-01T23:59:59.000Z

60

Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures  

E-Print Network [OSTI]

Monoaryloxide–pyrrolide (MAP) complexes of molybdenum were employed for the selective ethenolysis of 1,2-disubstituted Z olefins in the presence of the corresponding E olefins. Reactions were performed in the presence of ...

Marinescu, Smaranda C.

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing, April 2013  

Broader source: Energy.gov [DOE]

Catalyst-Assisted Production of Olefins from Natural Gas Liquids: Prototype Development and Full-Scale Testing

62
63

Separation of Olefin/Paraffin Mixtures with Carrier Facilitated Membrane Final Report  

SciTech Connect (OSTI)

This document describes the results of a DOE funded joint effort of Membrane Technology and Research Inc. (MTR), SRI International (SRI), and ABB Lummus (ABB) to develop facilitated transport membranes for olefin/paraffin separations. Currently, olefin/paraffin separation is done by distillation—an extremely energy-intensive process because of the low relative volatilities of olefins and paraffins. If facilitated transport membranes could be successfully commercialized, the potential energy savings achievable with this membrane technology are estimated to be 48 trillion Btu per year by the year 2020. We discovered in this work that silver salt-based facilitated transport membranes are not stable even in the presence of ideal olefin/paraffin mixtures. This decline in membrane performance appears to be caused by a previously unrecognized phenomenon that we have named olefin conditioning. As the name implies, this mechanism of performance degradation becomes operative once a membrane starts permeating olefins. This project is the first study to identify olefin conditioning as a significant factor impacting the performance of facilitated olefin transport membranes. To date, we have not identified an effective strategy to mitigate the impact of olefin conditioning. other than running at low temperatures or with low olefin feed pressures. In our opinion, this issue must be addressed before further development of facilitated olefin transport membranes can proceed. In addition to olefin conditioning, traditional carrier poisoning challenges must also be overcome. Light, hydrogen, hydrogen sulfide, and acetylene exposure adversely affect membrane performance through unwanted reaction with silver ions. Harsh poisoning tests with these species showed useful membrane lifetimes of only one week. These tests demonstrate a need to improve the stability of the olefin complexing agent to develop membranes with lifetimes satisfactory for commercial application. A successful effort to improve membrane coating solution stability resulted in the finding that membrane performance loss could be reversed for all poisoning cases except hydrogen sulfide exposure. This discovery offers the potential to extend membrane lifetime through cyclic regeneration. We also found that certain mixed carriers exhibited greater stability in reducing environments than exhibited by silver salt alone. These results offer promise that solutions to deal with carrier poisoning are possible. The main achievement of this program was the progress made in gaining a more complete understanding of the membrane stability challenges faced in the use of facilitated olefin transport membranes. Our systematic study of facilitated olefin transport uncovered the full extent of the stability challenge, including the first known identification of olefin conditioning and its impact on membrane development. We believe that significant additional fundamental research is required before facilitated olefin transport membranes are ready for industrial implementation. The best-case scenario for further development of this technology would be identification of a novel carrier that is intrinsically more stable than silver ions. If the stability problems could be largely circumvented by development of a new carrier, it would provide a clear breakthrough toward finally recognizing the potential of facilitated olefin transport. However, even if such a carrier is identified, additional development will be required to insure that the membrane matrix is a benign host for the olefin-carrier complexation reaction and shows good long-term stability.

Merkel, T.C.; Blanc, R.; Zeid, J.; Suwarlim, A.; Firat, B.; Wijmans, H.; Asaro, M. (SRI); Greene, M. (Lummus)

2007-03-12T23:59:59.000Z

64

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible fuels comprising: (A) forming a hydrocarbosol using a surfactant package in a proportion of about 1:100 to about 1:20,000 by weight based on hydrocarbon, (1) the surfactant package comprising (a) at least one water-soluble surfactant, an effective amount of which surfactant promotes emulsification of a hydrocarbon with API gravity of about 20/sup 0//sup o/ API or less; and (b) at least one water-soluble bioemulsifier, being a microboally-derived substance which predominantly resides at hydrocarbon/water interfaces to substantially surround hydrocarbon droplets in hydrocarbon-in-water emulsions; (2) the hydrocarbosol (a) comprising a hydrocarbon characterized by an API gravity of about 20/sup 0//sup o/ API or less; (b) having a hydrocarbon:water ratio of about 70:30 by volume; and (B) burning the resultant hydrocarbosol.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III

1986-10-21T23:59:59.000Z

65

Calorimetric study of adsorption of aliphatic hydrocarbons on reduced cobalt catalyst  

SciTech Connect (OSTI)

A study has been made of the heats of adsorption and the adsorption isotherms of saturated and unsaturated hydrocarbons on Co at 298/sup 0/K; the content of organic matter in the catalyst has been determined after use in the Fischer-Tropsch synthesis. It is concluded that the Fischer-Tropsch process includes stages of diffusion of the original reactants and the products through a liquid film of hydrocarbons coating the catalyst; the hydrocarbon molecules are adsorbed on the surface in the ''lying down'' position; the adsorption of paraffins is reversible and is described by the BET theory; olefins form an irreversibly chemisorbed monolayer, above which reversible adsorption takes place; the ease of desorption of the paraffins explains their preferential formation in the Fischer-Tropsch synthesis.

Ostrovskii, V.E.; Medvedkova, E.A.

1986-06-01T23:59:59.000Z

66

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Goldberg, Robert I. (Selden, NY)

1987-01-01T23:59:59.000Z

67

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

1985-11-06T23:59:59.000Z

68

ACTION OF MICROÖRGANISMS ON HYDROCARBONS  

Science Journals Connector (OSTI)

...could account for the general absence of olefines...distillates (58). Diesel fuels and mineral oil...lubricating oil and diesel motor fuel from marine engines which had been out...water-contaminated engine oils. Similar circumstantial...

Claude E. Zobell

1946-03-01T23:59:59.000Z

69

Recovering Radioactive Materials with OSRP team  

ScienceCinema (OSTI)

The National Nuclear Security Administration sponsors a program, executed by Los Alamos National Laboratory, to recover radioisotopes used by industry and academia and no longer needed. Called the "Offsite Source Recovery Program (OSRP), it has recovered

None

2010-01-08T23:59:59.000Z

70

Process for recovering actinide values  

DOE Patents [OSTI]

A process for rendering actinide values recoverable from sodium carbonate scrub waste solutions containing these and other values along with organic compounds resulting from the radiolytic and hydrolytic degradation of neutral organophosphorous extractants such as tri-n butyl phosphate (TBP) and dihexyl-N,N-diethyl carbamylmethylene phosphonate (DHDECAMP) which have been used in the reprocessing of irradiated nuclear reactor fuels. The scrub waste solution is preferably made acidic with mineral acid, to form a feed solution which is then contacted with a water-immiscible, highly polar organic extractant which selectively extracts the degradation products from the feed solution. The feed solution can then be processed to recover the actinides for storage or recycled back into the high-level waste process stream. The extractant is recycled after stripping the degradation products with a neutral sodium carbonate solution.

Horwitz, E. Philip (Elmhurst, IL); Mason, George W. (Clarendon Hills, IL)

1980-01-01T23:59:59.000Z

71

Conversion of methanol to light olefins on SAPO-34: kinetic modeling and reactor design  

E-Print Network [OSTI]

design of an MTO reactor, accounting for the strong exothermicity of the process. Multi-bed adiabatic and fluidized bed technologies show good potential for the industrial process for the conversion of methanol into olefins....

Al Wahabi, Saeed M. H.

2005-02-17T23:59:59.000Z

72

Influence of the nature of FCC feed on the production of light olefins by catalytic cracking  

SciTech Connect (OSTI)

The 1990 Clean Air Act has act rules for gasoline reformulation, which requires major compositional changes, Including a higher contribution of oxygenated compounds to the gasoline pool. This explains why FCC units are expected to play a major role in the coming years as a producer of light olefins (propylene, butenes and amylenes) to be used as feedstock for oxygenate (MTBE/TAME) production. The impact of the nature of FCC feedstock on light olefins production (C3 to C5 olefins) has been studied using a MAT unit running at various operating conditions (C/O ratio, reactor temperature). Paraffinic feeds are potentially efficient to produce light olefins by catalytic cracking. Heavier paraffinic feeds like mixtures VGO + reside and pure reside have also been evaluated, and compared to naphthenic and aromatic feeds.

Chapus, Th.; Cauffriez, H.; Marcilly, Ch. [Institut Francais du Petrole, Rueil-Malmaison (France)

1996-10-01T23:59:59.000Z

73

Monolayer cuprous chloride dispersed on pillared clays for olefin-paraffin separations by ?-complexation  

Science Journals Connector (OSTI)

New adsorbents containing cuprous chloride dispersed on pillared interlayered clays (PILC) have been prepared and studied for olefin-paraffin separations. High surface-area PILC's were synthesized with different ...

Linda S. Cheng; Ralph T. Yang

1995-01-01T23:59:59.000Z

74

High-oxidation-state molybdenum and tungsten monoalkoxide pyrrolide alkylidenes as catalysts for olefin metathesis  

E-Print Network [OSTI]

Chapter 1 describes work toward solid-supported W olefin metathesis catalysts. Attempts to tether derivatives of the known Z-selective catalyst W(NAr)(C?H?)(pyr)(OHIPT) (Ar = 2,6- diisopropylphenyl, pyr = pyrrolide; HIPT ...

Townsend, Erik Matthew

2014-01-01T23:59:59.000Z

75

Direct production of light olefins from syngas over a carbon nanotube confined iron catalyst  

Science Journals Connector (OSTI)

Iron particles confined in carbon nanotube (CNT) channels have been used as a catalyst for the direct conversion of syngas to light olefins. Compared with iron catalysts supported on other materials such as Si...

ChuanFu Wang; XiuLian Pan; XinHe Bao

2010-04-01T23:59:59.000Z

76

Direct production of light olefins from syngas over potassium modified Fe–Mn catalyst  

Science Journals Connector (OSTI)

A series of potassium promoted Fe–Mn catalysts for light olefin synthesis from CO hydrogenation were prepared by the co-precipitation-calcination-impregnation method. The impact of potassium promoter on the te...

Jiang-Bing Li; Hong-Fang Ma; Hai-Tao Zhang…

2014-08-01T23:59:59.000Z

77

Nickel-catalyzed preparation of acrylamides from alpha olefins and isocyanates ; Synthetic studies toward ripostatin A  

E-Print Network [OSTI]

Chapter I. In the presence of the N-heterocyclic carbene ligand IPr, the nickel(0)-catalyzed coupling reaction of a-olefins and branched aliphatic isocyanates provides c,-unsaturated amides arising from preferential C-C ...

Schleicher, Kristin D. (Kristin Diann)

2010-01-01T23:59:59.000Z

78

Disassembly of Elastomers: Poly(olefin sulfone)-Silicones with Switchable Mechanical Properties  

E-Print Network [OSTI]

An elastomeric polymer composite that can be disassembled at will into its individual components when exposed to mild bases is presented. The composite is formed of a poly(olefin sulfone) and a silicone bound together using ...

Swager, Timothy Manning

79

Method for recovering power according to a cascaded rankine cycle by gasifying liquefied natural gas and utilizing the cold potential  

SciTech Connect (OSTI)

The present invention discloses a method for recovering effective energy as power between liquefied natural gas and a high temperature source by cascading two kinds of Rankine cycles when the liquefied natural gas is re-gasified. The method is characterized in that a first medium performs a first Rankine cycle with the liquefied natural gas as a low temperature source, the first medium being mainly a mixture of hydrocarbons having 1-6 carbon atoms or a mixture of halogenated hydrocarbons of boiling points close to those of said hydrocarbons, the first medium having compositions according to which the vapor curve of gasifying the liquefied natural gas substantially corresponds to the low pressure cooling curve of the first medium, the power generated thereby is recovered by a first turbine during the first Rankine cycle, a second medium having a higher boiling point than said first medium performs a second Rankine cycle with part of said first Rankine cycle as the low temperature source, the second medium, being a single hydrocarbon component having 1-6 carbon atoms or a mixture thereof, a single halogenated hydrocarbon whose boiling point is close to that of this hydrocarbon or a mixture thereof, or ammonia, whose low pressure cooling curve substantially corresponds to the vapor curve of the high pressure first medium, said first and second Rankine cycles are cascaded, and a second turbine is disposed to recover power during the second Rankine cycle.

Matsumoto, O.; Aoki, I.

1984-04-24T23:59:59.000Z

80

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible pre-atomized fuels, comprising: (A) forming a hydrocarbon-in-water emulsion using an effective amount of a surfactant package comprising at least one water-soluble surfactant, the hydrocarbon-in-water emulsion (1) comprising a hydrocarbon characterized by API gravity of about 20/sup 0/ API or less, viscosity of about 1000 centipoise or greater at 212/sup 0/F., a paraffin content of about 50% by weight or less and, an aromatic content of about 15% by weight or greater, and (2) having a hydrocarbon water ratio from about 60:40 to about 90:10 by volume; and (B) burning the resultant hydrocarbon-in-water emulsion.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III; Bolden, P.L. Jr.

1987-08-04T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids  

SciTech Connect (OSTI)

Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 ± 0.5) × 106 M?1 s?1) and with FeBr2+ (k = (3.0 ± 0.5) × 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

2012-03-14T23:59:59.000Z

82

Onsite Recovered Energy LP | Open Energy Information  

Open Energy Info (EERE)

Jump to: navigation, search Name: Onsite Recovered Energy LP Address: Centurion Region: South Africa Sector: Marine and Hydrokinetic Year Founded: 2009 Phone Number: +27 (0)83...

83

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons  

Science Journals Connector (OSTI)

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons ... (1, 3-6) Methanol and derived dimethyl ether (DME) are also excellent fuels in internal combustion engines (ICE) and in a new generation of direct oxidation methanol fuel cells (DMFC), as well as convenient starting materials for producing light olefins (ethylene and propylene) and subsequently practically any derived hydrocarbon product. ... Methanol produced this way was used in the 19th century for lighting, cooking, and heating purposes but was later replaced by cheaper fuels, especially kerosene. ...

George A. Olah; Alain Goeppert; G. K. Surya Prakash

2008-12-08T23:59:59.000Z

84

Hydrocarbon Potential of Deep Water  

Science Journals Connector (OSTI)

...research-article Hydrocarbon Potential of Deep Water H. R. Warman In...the geology and hydrocarbon potential of the Earth's deeper water areas, an attempt...United Kingdom 1981 Hydrocarbon potential of deep water Warman H. R. Author...

1978-01-01T23:59:59.000Z

85

Facilitated transport membrane hybrid systems for olefin purification  

SciTech Connect (OSTI)

A new membrane system has been developed by BP for refinery and chemical plant olefin purification and recovery. This facilitated transport system, coupled with distillation, offers lower capital and operating costs than conventional distillation alone. Initial results on lab scale hollow fiber devices indicate membrane flux ranging from 8.75 {times} 10{sup {minus}6} to 8 {times} 10{sup {minus}5} m{sup 3}/m{sup 2}/sec (2.5 to 23 scfd/ft{sub 2}) and selectivities from 150 to 300. Pilot plant experiments on propylene/propane and ethylene purge gas recovery over three to six months duration show membrane stability and product purity of 98.5% or greater using refinery grade propylene feed. Hybrid system optimization data for membranes and distillation indicate that using a side draw from the distillation tower provides advantages in terms of membrane area, purity of feed to the membrane, and low per-pass recovery coupled with high overall propylene recovery. Membrane performance data under various conditions are also presented. In addition to performance data, economic evaluation and energy savings are discussed.

Davis, J.C.; Valus, R.J.; Eshraghi, R.; Velikoff, A.E. [BP Research, Cleveland, OH (United States)

1993-01-01T23:59:59.000Z

86

Recovering Radioactive Materials with ORSP Team  

ScienceCinema (OSTI)

The National Nuclear Security Administration sponsors a program, executed by Los Alamos National Laboratory, to recover radioisotopes used by industry and academia and no longer needed. Called the "Offsite Source Recovery Program (OSRP), it has recovered more than 16,000 orphan sources as of 2008.

LANL

2009-09-01T23:59:59.000Z

87

Potential of producing various hydrocarbons from canola oil by catalytic treatment over Pt-ZSM-5  

SciTech Connect (OSTI)

Canola oil conversion was studied at atmospheric pressure over Pt-ZSM-5 catalyst (0.5 wt% Pt) in a fixed bed micro-reactor. The operating conditions were: temperature range of 400--500 C, weight hourly space velocity (WHSV) of 1.8 and 3.6 h{sup {minus}1} and steam/oil ratio of 4:1. The products were coke, gas, an organic liquid product (OLP) and residue. The gas and OLP consisted mainly of hydrocarbons. The objective of this study was to maximize the amount of gasoline range hydrocarbons in the OLP and the selectivity to isohydrocarbons in the gas. The gas yields varied between 22--65 wt% and were higher in the presence of steam compared to the operation without steam. Also, the gas fraction decreased with increase in space velocity. The olefin/paraffin ratio of C{sub 2}-C{sub 4} hydrocarbon gases varied between 0.31--0.79. The amount of isohydrocarbons relative to n-hydrocarbons were higher with Pt-ZSM-5 (1.6--4.8) compared to pure HZSM-5 catalyst (0.2--0.3). The OLP yields with Pt-ZSM-5 (20--55wt% of canola oil) were slightly lower compared to HZSM-5 (40--63wt% of canola oil) under similar conditions. The major components of OLP were aliphatic and aromatic hydrocarbons. The main aromatic hydrocarbons were benzene, toluene, xylenes and trimethylbenzenes. Alkylated pentane and hexane were the main aliphatic hydrocarbons. In the presence of steam, Pt-ZSM-5 gave higher yields of liquid hydrocarbons within the gasoline boiling range than HZSM-5.

Katikaneni, S.P.R.; Adjaye, J.D.; Bakhshi, N.N. [Univ. of Saskatchewan, Saskatoon (Canada)

1995-12-31T23:59:59.000Z

88

Plasma Processing Of Hydrocarbon  

SciTech Connect (OSTI)

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

89

Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615  

SciTech Connect (OSTI)

Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

Wayland, B.B.

2009-08-31T23:59:59.000Z

90

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

91

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

92

Separation and Characterization of Olefin/Paraffin in Coal Tar and Petroleum Coker Oil  

Science Journals Connector (OSTI)

Separation and Characterization of Olefin/Paraffin in Coal Tar and Petroleum Coker Oil ... This technique has been applied to shale oils, tar sands, and petroleum in both the mid-distillate (400-680°F) and gas oil boiling ranges (680-1000°F). ... enables anal. of petroleum high ends, i.e., heavy oils, residua and asphaltenes. ...

Hongxing Ni; Chang Samuel Hsu; Chao Ma; Quan Shi; Chunming Xu

2013-04-26T23:59:59.000Z

93

Catalytic conversion of methanol to low molecular weight olefins in a fluidized bed reactor  

E-Print Network [OSTI]

followed by a polimerization of the divalent carbenoid species to explain the olefinic formation. H-CH, -OH -----~ HaO + :CHa n:CH, -----~ (CH, )n n=2, 3, 4, 5 Swabb and Gates (1972), in their study of the dehydration of methanol over H...

Garza Tobias, Ricardo

1983-01-01T23:59:59.000Z

94

A Study of Cu(I)-Ethylene Complexation for OlefinParaffin Separation  

E-Print Network [OSTI]

. An alternative olefin­paraffin separation process with lower energy consumption would significantly decrease oper. Such an absorption method eliminates the need for refrigeration, thus increasing energy efficiency and reducing serves as a key process in the production of many industrial chemicals such as ethylene (95 million tons

Eldridge, R. Bruce

95

Final Report: Experimental and Theoretical Studies of Surface Oxametallacycles - Connections to Heterogeneous Olefin Epoxidation  

SciTech Connect (OSTI)

This project has aimed at the rational design of catalysts for direct epoxidation of olefins. This chemistry remains one of the most challenging problems in heterogeneous catalysis. Although the epoxidation of ethylene by silver catalysts to form ethylene oxide (EO) has been practiced for decades, little progress has been made in expanding this technology to other products and processes. We have made significant advances through the combination of surface science experiments, Density Functional Theory (DFT) calculations, and catalytic reactor experiments, toward understanding the mechanism of this reaction on silver catalysts, and to the rational improvement of selectivity. The key has been our demonstration of surface oxametallacycle intermediates as the species that control reaction selectivity. This discovery permits the influence of catalyst promoters on selectivity to be probed, and new catalyst formulations to be developed. It also guides the development of new chemistry with potential for direct epoxidation of more complex olefins. During the award period we have focused on 1. the formation and reaction selectivity of complex olefin epoxides on silver surfaces, and 2. the influence of co-adsorbed oxygen atoms on the reactions of surface oxametallacycles on silver, and 3. the computational prediction, synthesis, characterization and experimental evaluation of bimetallic catalysts for ethylene epoxidation. The significance of these research thrusts is as follows. Selective epoxidation of olefins more complex than ethylene requires suppression of not only side reactions available to the olefin such as C-H bond breaking, but it requires formation and selective ring closure of the corresponding oxametallacycle intermediates. The work carried out under this grant has significantly advanced the field of catalyst design from first principles. The combination of computational tools, surface science, and catalytic reactor experiments in a single laboratory has few other examples. We have successfully predicted and validated new bimetallic catalyst for ethylene epoxidation. In so doing, we have established one of the first examples of successful catalyst design from first principles to achieve improved reaction selectivity.

Mark A. Barteau

2009-09-15T23:59:59.000Z

96

The Analysis of Hydrocarbon Products Obtained From Methanol Conversion to Gasoline Using Open Tubular GC Columns and Selective Olefin Absorption  

Science Journals Connector (OSTI)

......SCOT column. Run conditions are...Table I. GC Run Conditions for Methanol Derived Gasolines Carrier Gas...minor amounts of straight-chain isomers...dependent upon process run conditions. These...methanol derived gasolines were similar in......

M.G. Bloch; R.B. Callen; J.H. Stockinger

1977-11-01T23:59:59.000Z

97

The Analysis of Hydrocarbon Types — Saturates, Aromatics and Olefins—by Selective Chemical Absorption and Flame Ionization Detection  

Science Journals Connector (OSTI)

......n-heptane calibration; (2).--Synthetic gasoline; (3).--Commercial gasoline; (4).--Propylene. ; 2 1 capacity packed...samples were prepared from a dearomatized straight run gasoline (S), a polymerization gasoline (0) containing......

Nestor L. Soulages; Antonio M. Brieva

1971-08-01T23:59:59.000Z

98

Recovering Energy From Ventilation and Process Airstreams  

E-Print Network [OSTI]

. Heat is transferred from the hot to the cold airstreams as the two move through the plate-type device. Heat can be recovered from exhaust air by using one of these three systems: process to-process, process-to-comfort, and comfort to... between surfaces. One excellent application for a high latent heat recovery device is used in the textile industry. Slide 5 shows air-to liquid plate-type heat exchangers used in a carpet mill to recover energy from hot, .moist exhaust air...

Cheney, W. A.

99

Mercury: Recovering Forgotten Passwords Using Personal Devices  

E-Print Network [OSTI]

Mercury: Recovering Forgotten Passwords Using Personal Devices Mohammad Mannan1 , David Barrera2, and to allow forgotten passwords to be securely restored, we present a scheme called Mercury. Its primary mode and revealed to the user. A prototype implementation of Mercury is available as an Android application. 1

Van Oorschot, Paul

100

A search for thermal isomerization of olefins to carbenes: Thermal generations of the silicon-nitrogen double bond  

SciTech Connect (OSTI)

The first part of this thesis will search for the thermal isomerization of olefins to carbenes which is predicted to be a high energy process by calculations and has only been observed in a few strained olefins. The possibility of thermal isomerization of simple olefins to carbenes will be explored. Substitution of a silyl group on the double bond of an olefin allows a potential intermediate which has a {beta}-radical to the silyl group during the cis-trans isomerization. The effects of a trimethylsilyl group on this isomerization are the subject of this study. The second part of this thesis will include the generation and chemistry of intermediates containing a silicon-nitrogen double bond. The isomerization of parent silanimine to the aminosilylene was calculated to be a high energy process. New approaches to the silicon-nitrogen double bond will also be presented. 92 refs., 12 figs., 11 tabs.

Zhang, Xianping.

1990-09-21T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Dispersant solutions for dispersing hydrocarbons  

DOE Patents [OSTI]

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, R.L.

1997-03-11T23:59:59.000Z

102

Carbon neutral hydrocarbons  

Science Journals Connector (OSTI)

...depends on a source of primary energy to drive the required chemical...synthetic hydrocarbons are an energy carrier produced from a primary energy source such as wind, nuclear...Gustavsson et al. 2007), using a conversion value of $1.00=0.72...

2008-01-01T23:59:59.000Z

103

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1987-01-01T23:59:59.000Z

104

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 5 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1988-09-13T23:59:59.000Z

105

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 6 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1987-05-19T23:59:59.000Z

106

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1988-01-01T23:59:59.000Z

107

Sequential pyrolysis of plastic to recover polystyrene HCL and terephthalic acid  

DOE Patents [OSTI]

A process of pyrolyzing plastic waste feed streams containing polyvinyl chloride, polyethylene terephthalate, polystyrene and polyethylene to recover polystyrene HCl and terephthalic acid comprising: heating the plastic waste feed stream to a first temperature; adding an acid or base catalyst on an oxide or carbonate support; heating the plastic waste feed stream to pyrolyze polyethylene terephthalate and polyvinyl chloride; separating terephthalic acid or HCl; heating to a second temperature to pyrolyze polystyrene; separating styrene; heating the waste feed stream to a third temperature to pyrolyze polyethylene; and separating hydrocarbons.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1995-01-01T23:59:59.000Z

108

Apparatus for separating and recovering hydrogen isotopes  

DOE Patents [OSTI]

An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

Heung, Leung K. (Aiken, SC)

1994-01-01T23:59:59.000Z

109

Ways to reduce the specific consumption of materials in the production of lower olefins  

SciTech Connect (OSTI)

The most common method of producing lower olefins, i.e., ethylene and propylene, is the thermal pyrolysis of straight-run gasoline in tube furnaces with subsequent low-temperature separation of the pyrolysis gas. The basic technology of reducing materials consumption in this petrochemical process is discussed. A long-term plan for conserving feedstock and material resources in the production of ethylene is described.

Chernykh, S.P.; Zizyukin, V.K.; Mukhina, T.N.; Zelentsova, N.I.; Avrekh, G.L.; Babash, S.E.; Shamrai, O.B.

1984-02-01T23:59:59.000Z

110

Method for recovering metals from waste  

DOE Patents [OSTI]

A method is described for recovering metals from metals-containing wastes, and vitrifying the remainder of the wastes for disposal. Metals-containing wastes such as circuit boards, cathode ray tubes, vacuum tubes, transistors and so forth, are broken up and placed in a suitable container. The container is heated by microwaves to a first temperature in the range of approximately 300--800 C to combust organic materials in the waste, then heated further to a second temperature in the range of approximately 1,000--1,550 C at which temperature glass formers present in the waste will cause it to melt and vitrify. Low-melting-point metals such as tin and aluminum can be recovered after organics combustion is substantially complete. Metals with higher melting points, such as gold, silver and copper, can be recovered from the solidified product or separated from the waste at their respective melting points. Network former-containing materials can be added at the start of the process to assist vitrification. 2 figs.

Wicks, G.G.; Clark, D.E.; Schulz, R.L.

1998-12-01T23:59:59.000Z

111

Method for recovering materials from waste  

DOE Patents [OSTI]

A method for recovering metals from metals-containing wastes, a vitrifying the remainder of the wastes for disposal. Metals-containing wastes such as circuit boards, cathode ray tubes, vacuum tubes, transistors and so forth, are broken up and placed in a suitable container. The container is heated by microwaves to a first temperature in the range of approximately 300--800{degrees}C to combust organic materials in the waste, then heated further to a second temperature in the range of approximately 1000--1550{degrees}C at which temperature glass formers present in the waste will cause it to melt and vitrify. Low-melting-point metals such as tin and aluminum can be recovered after organics combustion is substantially complete. Metals with higher melting points, such as gold, silver and copper, can be recovered from the solidified product or separated from the waste at their respective melting points. Network former-containing materials can be added at the start of the process to assist vitrification.

Wicks, G.G.; Clark, D.E.; Schulz, R.L.

1994-01-01T23:59:59.000Z

112

Hydrolysis and composition of recovered fibres fractionated from solid recovered fuel  

Science Journals Connector (OSTI)

Abstract Fibres fractionated from solid recovered fuel (SRF), a standardised market combustion fuel produced from sorted waste, were considered as a source of lignocellulosic fermentable sugars. The fibre yield from four samples of SRF was 25–45%, and the separated material consisted of 52–54% carbohydrates, mainly glucan, with a high content of ash (12–17%). The enzymatic digestibility of recovered fibres was studied at low and high solids loading and compared with model substrates containing only chemical and mechanical pulps. Above 80% hydrolysis yield was reached at 20% solids loading in 48 h, but variation was observed between different samples of recovered fibres. Surfactants were found to improve the hydrolysis yield of recovered fibres especially in tumbling-type of mixing at low solids loading, where hydrolysis was found to stagnate without surfactants. The results suggest that SRF is a potential source of easily digestible lignocellulosic carbohydrates for use in biorefineries.

K. Kemppainen; M. Siika-aho; A. Östman; E. Sipilä; T. Puranen; N. von Weymarn; K. Kruus

2014-01-01T23:59:59.000Z

113

Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts  

DOE Patents [OSTI]

A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n }.sup.+ {A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 -C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 -C.sub.20 hydrocarbyl, SiR".sub.3, NR".sub.2, OR", SR", GeR".sub.3, and SnR".sub.3 containing groups (R"=C.sub.1 -C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

Marks, Tobin J. (Evanston, IL); Luo, Lubin (Baton Rouge, LA); Yoon, Sung Cheol (Evanston, IL)

2003-04-08T23:59:59.000Z

114

Cyclopentadienyl-Containing Low-Valent Early Transition Metal Olefin Polymerization Catalysts  

DOE Patents [OSTI]

A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n }.sup.+ {A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 -C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 -C.sub.20 hydrocarbyl, SiR".sub.3, NR".sub.2, OR", SR", GeR".sub.3, SnR".sub.3, and C.dbd.C-containing groups (R"=C.sub.1 -C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

Marks, Tobin J. (Evanston, IL); Luo, Lubin (Baton Rouge, LA); Yoon, Sung Cheol (Evanston, IL)

2004-06-08T23:59:59.000Z

115

Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, April--June 1992  

SciTech Connect (OSTI)

Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

Curtis, C.W.

1992-07-27T23:59:59.000Z

116

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

SciTech Connect (OSTI)

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

117

Radical scavengers from heavy hydrocarbons  

SciTech Connect (OSTI)

The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

Kubo, Junichi [Nippon Oil Co. Ltd. (Japan)

1996-10-01T23:59:59.000Z

118

Hydrocarbon steam reforming using series steam superheaters  

SciTech Connect (OSTI)

In a process for steam reforming of a hydrocarbon gas feedstream wherein: the hydrocarbon gas feedstream is partially reformed at elevated temperatures in indirect heat exchange with hot combustion gases in a direct fired primary reforming furnace provided with a convection section for recovery of excess heat from said combustion gases; and the partially reformed feedstream is then further reformed in the presence of an oxygen-containing gas and steam in a secondary reformer to form a secondary reformer gaseous effluent; the improvement which comprises recovering waste heat from said secondary reformer effluent gas and from said primary reforming combustion products by heating a high pressure saturated steam in a first steam superheating zone by indirect heat exchange with at least a portion of said secondary reformer effluent gas to form a first superheated steam stream; and further heating said first superheated steam in a second steam superheating zone by indirect heat exchange with at least a portion of said primary reformer hot combustion gases for form a second superheated steam stream.

Osman, R. M.

1985-10-08T23:59:59.000Z

119

Recovering Flare Gas Energy - A Different Approach  

E-Print Network [OSTI]

Energy Technology Conference, Houston, TX, September 16-18, 1987 SLIDLIN CH81ICAL CX1'1PANY RARE GAS RECXNERY SYSID1 K.O, ~LM 19) PSIG STEAM F,D, FAN0'1 '" N Z N NAT~L GAS SEAL SEAL FU\\RE OIL PoT STACK TANK FLARE GAS I?T ~y ~LM ~LM ESL...RECOVERING FLARE GAS ENERGY - A DIFFERENT APPROACH \\ WALTER BRENNER Process Engineer SunOlin Chemical Co. Claymont, Delaware AUSTRACT Most petrochemical complexes and oil re fineries have systems to collect and dispose of waste gases...

Brenner, W.

120

The Utilization of Certain Hydrocarbons by Microorganisms  

Science Journals Connector (OSTI)

...UTILIZATION OF CERTAIN HYDROCARBONS BY MICROORGANISMS...1940 INTRODUCTION Hydrocarbons, as a class, represent...obtained by comparing the heat of combustion of some six carbon...biological utilization of hydrocarbons as sources of energy...

L. D. Bushnell; H. F. Haas

1941-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Interaction between Carcinogenic Hydrocarbons and Nucleosides  

Science Journals Connector (OSTI)

...addition, the findings that hydrocarbons inhibit DNA syn thesis...for these carcinogens. Hydrocarbon-nucleic acid interaction...and the interactions of water molecules. Indeed, carcinogenic hydrocarbons tend to form 1 This investigation...

Ronald G. Harvey and Marilyn Halonen

1968-11-01T23:59:59.000Z

122

Recovering Soaps and Greases from Wool-Scouring liquors  

Science Journals Connector (OSTI)

Recovering Soaps and Greases from Wool-Scouring liquors ... A NEW process, illustrated in the accompanying flowsheet, has been devised for recovering soaps and greases from waste wool-scouring liquors. ...

C.H.S. TUPHOLME

1939-12-20T23:59:59.000Z

123

Apparatus for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

124

Method for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

125

A Business Process Explorer: Recovering Business Processes from Business Applications  

E-Print Network [OSTI]

1 A Business Process Explorer: Recovering Business Processes from Business Applications Jin Guo and software developers. We present a business process explorer tool which automatically recovers business of business applications, we developed a business process explorer tool which recovers as-implemented business

Zou, Ying

126

Hydrocarbon sensors and materials therefor  

DOE Patents [OSTI]

An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

2000-01-01T23:59:59.000Z

127

Volatilization characteristics of solid recovered fuels (SRFs)  

Science Journals Connector (OSTI)

Abstract The volatilization characteristics of three MSW-derived materials (FO, RT and FL) produced by local waste-management companies were investigated as potential solid recovered fuels (SRFs). FL was prepared from sorted domestic waste and consisted of non-recyclable plastics, refuse paper and biomass. RT and FO were obtained through active hygienization of unsorted MSW and refuse materials from selective waste-collection streams. RT was rich in plastics and had low biomass, whereas FO was mainly biomass and refuse paper. The rate of energy release during volatilization depended on the content of biomass and plastic, especially at a low conversion. Major contaminants had different rates of volatilization. Nitrogen and sulfur tended to accumulate in the charred solid, and were released as SO2 and nitrous oxides during both the volatilization–combustion stage and the char burning stage. Chlorine release was faster for the fuels rich in plastic waste. According to their ash melting characteristics and slagging indexes (Fs: 1188 °C for FO, 1192 °C for RT and 1234 °C for FL) the three fuels were equivalent to commercial SRFs. The three fuels showed potential as standardized SRF, although it would be desirable to reduce their chlorine content and, in the case of FO, to increase it’s heating value.

Daniel Montané; Sònia Abelló; Xavier Farriol; César Berrueco

2013-01-01T23:59:59.000Z

128

Drag coefficient of Solid Recovered Fuels (SRF)  

Science Journals Connector (OSTI)

The numerical simulation of Solid Recovered Fuels (SRF) co-combustion in pulverised coal power plants requires a flexible particle model, which among other properties should be able to predict the aerodynamic behaviour of the irregular-shaped particles, especially their trajectories along the boiler axis. This will help to provide vital information on whether the SRF particles are entrained in the combustion gases or drop to the boiler bottom. One difficulty encountered in the process is the true value of the drag coefficient (CD) of the coarse SRF particles. Most of the numerical simulation codes calculate the particle trajectories by integrating the force balance of the particles in which the CD plays an important role. As a result, a true CD of SRF will definitely lead to more realistic results. In this short communication, the authors have taken a practical approach in determining the CD of the SRF. It was found that within the Newton’s law range the CD of the SRF lies between 0.6 and 2.0 with a mean value of 1.5. The results were further validated by correlating the calculated lift velocities of SRF using different CD values and that obtained through experiment.

Gregory Dunnu; Jörg Maier; Uwe Schnell; Günter Scheffknecht

2010-01-01T23:59:59.000Z

129

Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, January--March 1994  

SciTech Connect (OSTI)

Previous research has suggested that using a more effective hydrogen donor solvent in the low severity coal liquefaction reaction improves coal conversion. In order to understand the results of these methods, both independently and combined, a factorial experiment was designed. Pretreating coal with hydrochloric and sulfurous acid solutions in both water and methanol is compared with pretreating coal using only methanol and with no pretreatment. The effects of these pretreatments on coal liquefaction behavior are contrasted with the ammonium acetate pretreatment. Within each of these, individual reactions are performed with the hydroaromatic 1,2,3,4-tetrahydronaphthalene (tetralin, TET) and the cyclic olefin 1,4,5,8-tetrahydronaphthalene (isotetralin, ISO). The final aspect of the factorial experiment is the comparison of Wyodak subbituminous coal (WY) from the Argonne Premium Sample Bank and Black Thunder subbituminous coal (BT) provided by Amoco. Half of the reactions in the matrix have now been completed. In all but one case, Black Thunder-HCl/H{sub 2}O, the ISO proved to be more reactive than TET. After the other four reactions using this combination are complete, the average conversion may be greater with the cyclic olefin. The second part of this paper describes the current and future work with Fourier transform infrared spectroscopy. The objective of this work is to determine the kinetics of reaction of isotetralin at high temperatures and pressures. This quarter combinations of three products typically produced from isotetralin were used in spectral subtraction.

Curtis, C.W.

1994-06-01T23:59:59.000Z

130

FCC Tail Gas olefins conversion to gasoline via catalytic distillation with aromatics  

SciTech Connect (OSTI)

The goal of every refiner is to continually improve profitability by such means as increasing gasoline production, increasing gasoline octane pool and in cases where fuel balance becomes a problem, decreasing refinery fuel gas production. A new refinery process is currently being developed which accomplish these goals. Chemical Research and Licensing Company (CR and L) developed Catalytic Distillation technology in 1978 to produce MTBE. They have since used the Catalytic Distillation technique to produce cumene. CR and L has further developed this technology to convert olefin gases currently consumed as refinery fuel, to high octane gasoline components. The process, known as CATSTILL, alkylates olefin gases such as ethylene, propylene and butylene, present in FCC Tail Gas with light aromatics such as benzene, toluene and xylene, present in reformate, to produce additional quantities of high octane gasoline components. A portable CATSTILL demonstration plant has been constructed by Brown and Root U.S.A., under an agreement with CR and L, for placement in a refinery to further develop data necessary to design commercial plants. This paper presents current data relative to the CATSTILL development.

Partin, E.E. (Brown and Root U.S.A., Inc., Houston, TX (US))

1988-01-01T23:59:59.000Z

131

Metal catalyzed synthesis of hyperbranched ethylene and/or .alpha.-olefin polymers  

DOE Patents [OSTI]

Oily hyperbranched polymers derived from ethylene, propylene, butene and/or a C.sub.5 -C.sub.24 .alpha.-olefin, and a method for their synthesis, are disclosed. The polymers have non-regular microstructures and are characterized by a ratio ({character pullout})of methyl hydrogens centered around 0.85 ppm on the 1H-NMR spectra of the polymers relative to total aliphatic hydrogens of from about 0.40 to about 0.65 for polymers derived from ethylene or butene, and a ratio ({character pullout})of from greater than 0.50 to about 0.65 for polymers derived from propylene. A method for grafting hyperbranched polymers derived from ethylene, propylene, butene and/or a C.sub.5 -C.sub.24 .alpha.-olefin onto aromatic rings in organic molecules and polymers, and the resulting grafted materials, are also disclosed. The hyperbranched polymers and grafted materials are useful, for example, as lubricants and lubricant additives.

Sen, Ayusman (State College, PA); Kim, Jang Sub (State College, PA); Pawlow, James H. (Gainesville, FL); Murtuza, Shahid (State College, PA); Kacker, Smita (Annandale, NJ); Wojcinski, III, Louis M. (State College, PA)

2001-01-01T23:59:59.000Z

132

Mechanism of Efficient Anti-Markovnikov Olefin Hydroarylation Catalyzed by Homogeneous Ir(III) Complexes  

SciTech Connect (OSTI)

The mechanism of the hydroarylation reaction between unactivated olefins (ethylene, propylene, and styrene) and benzene catalyzed by [(R)Ir(?-acac-O,O,C{sup 3})-(acac-O,O){sub 2}]{sub 2} and [R-Ir(acac-O,O){sub 2}(L)] (R = acetylacetonato, CH{sub 3}, CH{sub 2}CH{sub 3}, Ph, or CH{sub 2}CH{sub 2}Ph, and L = H{sub 2}O or pyridine) Ir(III) complexes was studied by experimental methods. The system is selective for generating the anti-Markovnikov product of linear alkylarenes (61:39 for benzene + propylene and 98:2 for benzene + styrene). The reaction mechanism was found to follow a rate law with first-order dependence on benzene and catalyst, but a non-linear dependence on olefin. {sup 13}C-labelling studies with CH{sub 3}{sup 13}CH{sub 2}-Ir-Py showed that reversible ?-hydride elimination is facile, but unproductive, giving exclusively saturated alkylarene products. The migration of the {sup 13}C-label from the ? to ?-positions was found to be slower than the C–H activation of benzene (and thus formation of ethane and Ph-d{sub 5}-Ir-Py). Kinetic analysis under steady state conditions gave a ratio of the rate constants for CH activation and ?-hydride elimination (k{sub CH}: k{sub ?}) of ~0.5. The comparable magnitude of these rates suggests a common rate determining transition state/intermediate, which has been shown previously with B3LYP density functional theory (DFT) calculations. Overall, the mechanism of hydroarylation proceeds through a series of pre-equilibrium dissociative steps involving rupture of the dinuclear species or the loss of L from Ph-Ir-L to the solvento, 16-electron species, Ph-Ir(acac-O,O){sub 2}-Sol (where Sol refers to coordinated solvent). This species then undergoes trans to cisisomerization of the acetylacetonato ligand to yield the pseudo octahedral species cis-Ph-Ir-Sol, which is followed by olefin insertion (the regioselective and rate determining step), and then activation of the C–H bond of an incoming benzene to generate the product and regenerate the catalyst.

Bhalla, Gaurav; Bischof, Steven M; Ganesh, Somesh K; Liu, Xiang Y; Jones, C J; Borzenko, Andrey; Tenn, William J; Ess, Daniel H; Hashiguchi, Brian G; Lokare, Kapil S; Leung, Chin Hin; Oxgaard, Jonas; Goddard, William A; Periana, Roy A

2011-01-01T23:59:59.000Z

133

Thermal Behavior of As-Recovered (Unneutralized) Aspigel (Pressure Measurements)  

SciTech Connect (OSTI)

This brief report provides unreported pressures measured in accelerating rate calorimeter experiments performed to determine the thermal sensitivity of as-recovered and unneutralized Aspigel.

Scheele, Randall D.

2010-07-02T23:59:59.000Z

134

Use Vapor Recompression to Recover Low-Pressure Waste Steam  

Broader source: Energy.gov [DOE]

This tip sheet on recovering low-pressure waste steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

135

A new technology for producing synthetic liquid hydrocarbons from gaseous hydrocarbons  

Science Journals Connector (OSTI)

Conventional technologies of synthetic liquid fuels (SLF) production from gaseous hydrocarbons by producing synthesis ... liquid hydrocarbons are examined. A high-efficiency SLF production technology that allows ...

D. L. Astanovskii; L. Z. Astanovskii; A. L. Lapidus

2012-09-01T23:59:59.000Z

136

Low severity hydrocarbon steam reforming process  

SciTech Connect (OSTI)

A process is described for producing ammonia which comprises: (a) primary catalytically reforming at super atmospheric pressure in a direct-fired primary reforming zone, a hydrocarbon feedstock with steam to produce a gas containing carbon oxides, hydrogen and methane; (b) secondary catalytically reforming the gas from step (a) by introducing air and bringing the mixture towards equilibrium thereby producing a secondary reformer effluent gas containing nitrogen, carbon oxides, hydrogen and a decreased quantity of methane; (c) converting carbon monoxide catalytically with steam to carbon dioxide and hydrogen; (d) removing carbon oxides to give an ammonia synthesis gas comprising nitrogen and hydrogen and compressing the gas to ammonia synthesis pressure; (e) reacting the synthesis gas in an ammonia synthesis zone to produce ammonia and recovering ammonia from the reacted gas to produce an ammonia-depleted gas stream; (f) recycling at least a portion of the ammonia-depleted gas stream to the ammonia synthesis zone; and (g) treating a sidestream of the ammonia-depleted gas to separate a stream enriched in hydrogen and an inerts-enriched gas stream, and returning the enriched hydrogen stream to the ammonia synthesis zone.

Osman, R.M.; Byington, R.G.

1986-06-03T23:59:59.000Z

137

Modeling of the Phase behavior of light (C2 & C3) olefins in liquid phase epoxidation systems and experimental determination of gas/liquid mass transfer coefficients  

E-Print Network [OSTI]

). HYSYS® software was used to study the phase behavior and generate quantitative data on the solubility of gaseous olefins in the liquid phase which aided in the optimization of the reaction conditions. A detailed stirred tank reactor model was developed...

Ghanta, Madhav

2008-01-01T23:59:59.000Z

138

Olefin Metatheses in Metal Coordination Spheres: Development of Gyroscope-like trans-Spanning Bis(pyridine) Complexes and Organometallic pi-Adducts of Conjugated Polymers  

E-Print Network [OSTI]

Page 1.1 Single site olefin metathesis catalysts used in this dissertation; Grubbs? 1 (I), Grubbs? 2 (II), Grubbs? 3 (III), Schrock?s (IV), and Schrock?s tungsten (V... generation, Grubbs? third generation, Schrock?s catalyst, and a tungsten derivative of Schrock?s catalyst, I-V, respectively (Figure 1.1). Although a plethora of olefin metathesis catalysts exist, most are derivatives of these five. 3 3 Figure...

Zeits, Paul

2012-02-14T23:59:59.000Z

139

Enrichment of light hydrocarbon mixture  

DOE Patents [OSTI]

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

140

Fluorescence Detection of Hydrocarbons in Harbour Water  

Science Journals Connector (OSTI)

In harbor water, the hydrocarbons pollution identification represents an important issue. Hydrocarbon presence derives from oil spills, for instance in bilge water, or it may come from industrial discharge ... Fl...

A. Catini; F. Dini; D. Polese; S. Petrocco; M. De Luca…

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

142

Extracting hydrocarbons from water using a centrifuge  

Science Journals Connector (OSTI)

An original method for the solid-phase microextraction of hydrocarbons from water using a centrifuge is proposed. Comparative results...

A. Yu. Ryabov; A. A. Ilyina; A. V. Chuikin…

2014-09-01T23:59:59.000Z

143

Photo-oxides of Carcinogenic Hydrocarbons  

Science Journals Connector (OSTI)

... are involved in the biological action of carcinogenic hydrocarbons, we have attempted to isolate the photo-oxides of some of these hydrocarbons. Such ... -oxides of some of these hydrocarbons. Such photo-oxides would naturally be insoluble in water and hence would represent merely one stage in ...

J. W. COOK; R. MARTIN; E. M. F. ROE

1939-06-17T23:59:59.000Z

144

Catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

145

Oil and Gas- Leases to remove or recover (Pennsylvania)  

Broader source: Energy.gov [DOE]

This act states that a lease or agreement conveying the right to remove or recover oil, natural gas or gas of any other designation from lessor to lessee shall not be valid if such lease does not...

146

Use a Vent Condenser to Recover Flash Steam Energy  

Broader source: Energy.gov [DOE]

This tip sheet on using vent condensers to recover flash steam energy provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

147

Improving CO2 Efficiency for Recovering Oil in Heterogeneous Reservoirs  

SciTech Connect (OSTI)

The work strived to improve industry understanding of CO2 flooding mechanisms with the ultimate goal of economically recovering more of the U.S. oil reserves. The principle interests are in the related fields of mobility control and injectivity.

Grigg, Reid B.; Svec, Robert K.

2003-03-10T23:59:59.000Z

148

Use a Vent Condenser to Recover Flash Steam Energy (Revised)  

SciTech Connect (OSTI)

This revised ITP tip sheet on vent condenser to recover flash steam energy provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-05-01T23:59:59.000Z

149

Conversion of hydrocarbons for fuel-cell applications. Part I. Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids. Part II. Steam reforming of n-hexane on pellet and monolithic catalyst beds. Final report  

SciTech Connect (OSTI)

Experimental autothermal reforming (ATR) results obtained in the previous phase of this work with sulfur-free pure hydrocarbon liquids are summarized. Catalyst types and configuration used were the same as in earlier tests with No. 2 fuel oil to facilitate comparisons. Fuel oil has been found to form carbon in ATR at conditions much milder than those predicted by equilibrium. Reactive differences between paraffins and aromatics in ATR, and thus the formation of different carbon precursors, have been shown to be responsible for the observed carbon formation characteristics (fuel-specific). From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation in ATR. Effects of olefin (propylene) addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics (n-tetradecane and benzene) synergistic effects on conversion characteristics were identified. Comparisons of the No. 2 fuel oil data with the experimental results from this work with pure (and mixed) sulfur-free hydrocarbons indicate that the sulfur content of the fuel may be the limiting factor for efficient ATR operation. Steam reforming of hydrocarbons in conventional reformers is heat transfer limited. Steam reforming tasks performed have included performance comparisons between conventional pellet beds and honeycomb monolith catalysts. Metal-supported monoliths offer higher structural stability than ceramic supports, and have a higher thermal conductivity. Data from two metal monoliths of different catalyst (nickel) loading were compared to pellets under the same operating conditions.

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-10-01T23:59:59.000Z

150

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

151

Approach to Recover Hydrocarbons from Currently Off-Limit Areas of the Antrim Formation, MI Using Low-Impact Technologies  

SciTech Connect (OSTI)

The goal of this project was to develop and execute a novel drilling and completion program in the Antrim Shale near the western shoreline of Northern Michigan. The target was the gas in the Lower Antrim Formation (Upper Devonian). Another goal was to see if drilling permits could be obtained from the Michigan DNR that would allow exploitation of reserves currently off-limits to exploration. This project met both of these goals: the DNR (Michigan Department of Natural Resources) issued permits that allow drilling the shallow subsurface for exploration and production. This project obtained drilling permits for the original demonstration well AG-A-MING 4-12 HD (API: 21-009-58153-0000) and AG-A-MING 4-12 HD1 (API: 21-009-58153-0100) as well as for similar Antrim wells in Benzie County, MI, the Colfax 3-28 HD and nearby Colfax 2-28 HD which were substituted for the AG-A-MING well. This project also developed successful techniques and strategies for producing the shallow gas. In addition to the project demonstration well over 20 wells have been drilled to date into the shallow Antrim as a result of this project's findings. Further, fracture stimulation has proven to be a vital step in improving the deliverability of wells to deem them commercial. Our initial plan was very simple; the 'J-well' design. We proposed to drill a vertical or slant well 30.48 meters (100 feet) below the glacial drift, set required casing, then angle back up to tap the resource lying between the base to the drift and the conventional vertical well. The 'J'-well design was tested at Mancelona Township in Antrim County in February of 2007 with the St. Mancelona 2-12 HD 3.

James Wood; William Quinlan

2008-09-30T23:59:59.000Z

152

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

153

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for the recovery of liquid hydrocarbons from a subterranean hydrocarbon-bearing formation. It comprises injecting natural gas into the formation via a well in fluid communication with the formation, the natural gas being at a temperature which is insufficient to significantly mobilize light density oil in the formation and at a pressure such that the natural gas is immiscible with the light density oil in the formation, the natural gas being injected in a volume sufficient to contact light density oil in the formation within a radius from the well of about 50 meters; shutting in the well for a period of time of about 1 to about 100 days which is sufficient to render the contacted light density oil mobile; and producing the light density oil which has been mobilized by solution of the natural gas from the well.

Haines, H.K.; Monger, T.G.; Kenyon, D.E.; Galvin, L.J.

1991-06-25T23:59:59.000Z

154

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

155

Chapter 3 - Hydrocarbons from Petroleum  

Science Journals Connector (OSTI)

Publisher Summary Petroleum products (in contrast to petrochemicals) are those hydrocarbon fractions that are derived from petroleum and have commercial value as a bulk product. A major group of hydrocarbon products from petroleum (petrochemicals) are the basis of a major industry. They are, in the strictest sense, different to petroleum products insofar as the petrochemicals are the basic building blocks of the chemical industry. The specific gravity of product gases, including liquefied petroleum gas, may be determined conveniently by a number of methods and a variety of instruments. The heat value of gases is generally determined at constant pressure in a flow calorimeter in which the heat released by the combustion of a definite quantity of gas is absorbed by a measured quantity of water or air. A continuous recording calorimeter is available for measuring heat values of natural gases.

James G. Speight

2011-01-01T23:59:59.000Z

156

Discharge produces hydrocarbons from coal  

Science Journals Connector (OSTI)

Discharge produces hydrocarbons from coal ... Studies of the reactions of coal in electric discharges by two chemists at the U.S. Bureau of Mines' Pittsburgh Coal Research Center may lead to improved ways of producing acetylene and other useful chemicals from coal. ... Other workers have produced high yields of acetylene from coal by extremely rapid pyrolysis using energy sources such as plasma jets, laser beams, arc-image reactors, and flash heaters. ...

1968-01-22T23:59:59.000Z

157

Deep desulfurization of hydrocarbon fuels  

DOE Patents [OSTI]

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

158

A comprehensive detailed chemical kinetic reaction mechanism for combustion of nalkane  

E-Print Network [OSTI]

, olefins, naphthenes, and oxygenated hydrocarbons for gasoline [1], diesel fuel [2], and jet fuel [3

Paris-Sud XI, Université de

159

Working Together to Recover and Rebuild After Hurricane Sandy | Department  

Broader source: Energy.gov (indexed) [DOE]

Working Together to Recover and Rebuild After Hurricane Sandy Working Together to Recover and Rebuild After Hurricane Sandy Working Together to Recover and Rebuild After Hurricane Sandy November 5, 2012 - 6:30pm Addthis Supervising Engineer for Public Service Electric and Gas Company, Michael Vincent, right, Department of Energy Secretary Steven Chu, center, and FEMA Deputy Administrator Rich Serino review power restoration at the Hoboken electrical substation. Restoration of power to communities impacted by Hurricane Sandy remains a high priority. | Photo by Jocelyn Augustino/FEMA. Supervising Engineer for Public Service Electric and Gas Company, Michael Vincent, right, Department of Energy Secretary Steven Chu, center, and FEMA Deputy Administrator Rich Serino review power restoration at the Hoboken electrical substation. Restoration of power to communities impacted by

160

Working Together to Recover and Rebuild After Hurricane Sandy | Department  

Broader source: Energy.gov (indexed) [DOE]

Working Together to Recover and Rebuild After Hurricane Sandy Working Together to Recover and Rebuild After Hurricane Sandy Working Together to Recover and Rebuild After Hurricane Sandy November 5, 2012 - 6:30pm Addthis Supervising Engineer for Public Service Electric and Gas Company, Michael Vincent, right, Department of Energy Secretary Steven Chu, center, and FEMA Deputy Administrator Rich Serino review power restoration at the Hoboken electrical substation. Restoration of power to communities impacted by Hurricane Sandy remains a high priority. | Photo by Jocelyn Augustino/FEMA. Supervising Engineer for Public Service Electric and Gas Company, Michael Vincent, right, Department of Energy Secretary Steven Chu, center, and FEMA Deputy Administrator Rich Serino review power restoration at the Hoboken electrical substation. Restoration of power to communities impacted by

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Finding and Recovering SHGC Objects in an Edge Image  

Science Journals Connector (OSTI)

A set of modules to extract partial descriptions of SHGC objects in an edge image is presented. It consists of modules to find end edges, to find meridian edges, to find cross-section edges, and to recover 3D shapes. The first goal of the system is to extract geometrical edges derived from an SHGC object. From an input edge image, pairs of end edges are detected first by verifying strong geometrical constraints for the ends of an SHGC. Then, meridian edges are detected by using the constraint for tangent intersections and the ones related to the end edges. The second goal is to recover 3D information of the object. The axis of SHGC and the axes of skewed symmetry in cross-section edges are detected. Then, original cross section and the sweeping rule are recovered by utilizing these three orthogonal axes. Extracted geometrical edges and 3D information from real images are shown.

H. Sato; T.O. Binford

1993-01-01T23:59:59.000Z

162

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations  

Science Journals Connector (OSTI)

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations ... The environmental implications of offshore oil and gas activities ... The environmental implications of offshore oil and gas activities ...

Theodor C. Sauer

1981-08-01T23:59:59.000Z

163

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

164

Hydrocarbon Separations in Metal–Organic Frameworks  

Science Journals Connector (OSTI)

Given the large differences in the physical properties of methane and C2 hydrocarbons, both size selective effects and metal–hydrocarbon interactions can be tuned to achieve a high selectivity within a metal–organic framework. ... Polycyclic aromatic hydrocarbons, or PAHs, are carcinogenic byproducts of incomplete combustion of organic matter such as fossil fuels. ... data and the heats of adsorption were found to fit well to a small group of mol. ...

Zoey R. Herm; Eric D. Bloch; Jeffrey R. Long

2013-11-22T23:59:59.000Z

165

catalytic_upgrading_sugars_to_hydrocarbons  

Broader source: Energy.gov (indexed) [DOE]

phase reforming into hydrocarbons for fuels and co-product commodities. Process Block Diagram Next Steps Additional modeling is necessary to quantify baseline costs associated...

166

Application of advanced hydrocarbon characterization and its...  

Broader source: Energy.gov (indexed) [DOE]

advanced hydrocarbon characterization and its consequences on future fuel properties and advanced combustion research Rafal Gieleciak, Craig Fairbridge and Darcy Hager Poster...

167

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents [OSTI]

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

168

Synthesis of hydrocarbons from CO and H/sub 2/ in the presence of catalysts based on mononuclear iron complexes  

SciTech Connect (OSTI)

Iron catalysts for Fischer-Tropsch synthesis, activated by alkaline additives are active in the synthesis of hydrocarbons from CO and H/sub 2/. It is well known that catalysts obtained by applying K/sub 2/(Fe/sub 3/(CO)/sub 11/) complexes on ..gamma..-Al/sub 2/O/sub 3/ have increased selectivity in the formation of lower olefins from CO and H/sub 2/. IR spectroscopy using catalysts based on K/sub 2/(Fe/sub 3/(CO)/sub 11/) showed that during heat treatment in vacuum, CO, H/sub 2/, CO + H/sub 2/ atmosphere a transition is observed of polynuclear complexes found on a carrier surface, to a (Fe(CO)/sub 5/, Fe(acac)/sub 3/ and Fe(C/sub 5/H/sub 5/)/sub 2/, in Fischer-Tropsch synthesis. A study was made in this paper of the effect of the type of initial Fe-complex: iron pentacarbonyl Fe(CO)/sub 5/-I, iron acetylacetonate Fe(acac)/sub 3/-II, ferrocene Fe(C/sub 5/H/sub 5/)/sub 2/-III, on the activity and selectivity of Fe-K catalysts in the synthesis of lower olefins from CO and H/sub 2/. In these complexes Fe is oxidized from Fe/sup 0/ to Fe/sup 3 +/ (3). In order to prepare catalysts by the same method, Fe(acac)/sub 3/ was selected as Fe/sup 3 +/ compound, which is soluble in alkaline methanol solution.

Lapidus, A.L.; Savel'ev, M.M.; Tsapkina, M.V.; Solodov, S.N.; Sominskii, S.D.

1985-01-01T23:59:59.000Z

169

Biodegradation of Aromatic Hydrocarbons in an Extremely Acidic Environment  

Science Journals Connector (OSTI)

...biodegradation of aromatic hydrocarbons can occur in environments...Polycyclic aromatic hydrocarbons (PAHs) occur as common...formed by incomplete combustion of fossil fuels...enrichments with aromatic hydrocarbons, mineralization assays...lysis was initiated by heat and sodium dodecyl...

Raymond D. Stapleton; Dwayne C. Savage; Gary S. Sayler; Gary Stacey

1998-11-01T23:59:59.000Z

170

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons| Introduction Esophageal...polycyclic aromatic hydrocarbon (PAH) content. PAHs...usually exposed to combustion products from burning...SRM 2260a Aromatic Hydrocarbons in Toluene, SRM 2269...dichloromethane; heat: preheat cell at 100C...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

171

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...polycyclic aromatic hydrocarbons| Introduction...mechanism. However, data on the association...polycyclic aromatic hydrocarbon (PAH) content...usually exposed to combustion products from burning...dichloromethane; heat: preheat cell...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

172

MICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air  

E-Print Network [OSTI]

from Waters Associates. Water used was deionized, distilled, and hydrocarbon filtered (BarnsteadMICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air to extract polycyclic aromatic hydrocarbons (PAH) from air particulate sampleswas investigated. High

Canberra, University of

173

Metabolism of Polycyclic Aromatic Hydrocarbons in Cell Cultures  

Science Journals Connector (OSTI)

...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...cytotoxicity and conversion of hydrocarbons to water-soluble products (Chart...

Eliezer Huberman; James K. Selkirk; and Charles Heidelberger

1971-12-01T23:59:59.000Z

174

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...80C) or cold (5C) water. Measurements were...polycyclic aromatic hydrocarbons in mate drinks. | Drinking...polycyclic aromatic hydrocarbons (PAH), including...cold (5 degrees C) water. Measurements were...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

175

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...versus shallow-water environments...A (1999) Hydrocarbons in rift basins...Facies and hydrocarbon potential The...availability of water. This can either...form seals for hydrocarbons. The shallow-water environ- ments...

1999-01-01T23:59:59.000Z

176

Learning and discrimination of cuticular hydrocarbons in a social insect  

Science Journals Connector (OSTI)

...colony members. Cuticular hydrocarbons (CHCs) play a central...CHC profile with synthetic hydrocarbons [4-6] reveal that some hydrocarbons elicit aggression. However...non-volatile, insoluble in water and therefore difficult...

2012-01-01T23:59:59.000Z

177

Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO/Al2O3 and ZSM-5 Composite Catalyst System  

SciTech Connect (OSTI)

A composite Pd/ZnO/Al2O3-HZSM-5 (Si/Al=40) catalytic system was evaluated for the synthesis of gasoline-range hydrocarbons directly from synthesis gas. Bifunctional catalyst comprising PdZn metal and acid sites present the required catalytically active sites necessary for the methanol synthesis, methanol dehydration, and methanol-to-gasoline reactions. This system provides a unique catalytic pathway for the production of liquid hydrocarbons directly from syngas. However, selectivity control is difficult and poses many challenges. The composite catalytic system was evaluated under various process conditions. Investigated were the effects of temperature (310-375oC), pressure (300-1000 psig), time-on-stream (50 hrs), and gas-hour space velocity (740-2970 hr-1), using a H2/CO molar syngas ratio of 2.0. By operating at the lower end of the temperature range investigated, liquid hydrocarbon formation was favored, as was decreased amounts of undesirable light hydrocarbons. However, lower operating temperatures also facilitated undesirable CO2 formation via the water-gas shift reaction. Higher operating pressures slightly favored liquid synthesis. Operating at relatively low pressures (e.g. 300 psig) was made possible, whereas for methanol synthesis alone higher pressure are usually required to achieve similar conversion levels (e.g. 1000 psig). Thermodynamic constraints on methanol synthesis are eased by pushing the equilibrium through hydrocarbon formation. Catalytic performance was also evaluated by altering Pd and Zn composition of the Pd/ZnO/Al2O3 catalyst. Of the catalysts and conditions tested, selectivity toward liquid hydrocarbon was highest when using a 5% Pd metal loading and Pd/Zn molar ratio of 0.25 and mixed with HZMS-5, operating at 310oC and 300 psig, CO conversion was 43 % and selectivity (carbon weight basis) to hydrocarbons was 49 wt. %. Of the hydrocarbon fraction, 44wt. % was in the C5-C12 liquid product range and consisted primarily of aromatic polymethylbenzenes. However, as syngas conversion increases with increasing temperature, selectivity to liquid product diminished. This is attributed, in large part, to increased saturation of the olefinic intermediates over PdZn metal sites. Under all the conditions and catalysts evaluated in this study, generating liquid product in high yield was challenging (<10 wt. % C5+ yield).

Dagle, Robert A.; Lizarazo Adarme, Jair A.; Lebarbier, Vanessa MC; Gray, Michel J.; White, James F.; King, David L.; Palo, Daniel R.

2014-07-01T23:59:59.000Z

178

Tensile Effective Stresses in Hydrocarbon Storage Caverns  

E-Print Network [OSTI]

Tensile Effective Stresses in Hydrocarbon Storage Caverns Hippolyte Djizanne and Pierre Bérest LMS, Germany,1-2 October 2012 TENSILE EFFECTIVE STRESSES IN HYDROCARBON STORAGE CAVERNS Hippolyte Djizanne1 that effective tensile stresses can be generated at a cavern wall after a rapid increase or decrease in pressure

Paris-Sud XI, Université de

179

Conversion of organic solids to hydrocarbons  

DOE Patents [OSTI]

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

180

The Effects of Two Isomeric Benzoflavones on Aryl Hydrocarbon Hydroxylase and the Toxicity and Carcinogenicity of Polycyclic Hydrocarbons  

Science Journals Connector (OSTI)

...recrystallized from alcohol : water. For tissue culture experiments the hydrocarbons and benzoflavones...metabolism of the hydrocarbons to water-soluble derivatives...chloroform:methanol. Hydrocarbon-3 H metabolized to water-soluble derivatives...

Leila Diamond; Rosemary McFall; Joel Miller; and Harry V. Gelboin

1972-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Hydrocarbon fouling of SCR during Premixed Charge Compression...  

Broader source: Energy.gov (indexed) [DOE]

Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion...

182

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...  

Broader source: Energy.gov (indexed) [DOE]

and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Algal Lipid Extraction and Upgrading to Hydrocarbons...

183

DOE Perspectives on Advanced Hydrocarbon-based Biofuels | Department...  

Broader source: Energy.gov (indexed) [DOE]

DOE Perspectives on Advanced Hydrocarbon-based Biofuels DOE Perspectives on Advanced Hydrocarbon-based Biofuels Zia Haq, DPA Coordinator, presentation on DOE Perspectives on...

184

Commercialization of IH2® Biomass Direct-to-Hydrocarbon Fuel...  

Broader source: Energy.gov (indexed) [DOE]

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

185

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

186

Recovering oil by injecting ammoniated and nitrited seawater  

SciTech Connect (OSTI)

A waterflood process is described for recovering oil from a subterranean reservoir in a location in which seawater is economically available, comprising: incorporating within the seawater, at least prior to its injection into the reservoir, ammonia or ammonia-yielding material to raise the pH to near 9.5, plus enough nitrite ion-containing or ion-yielding material to increase the oil displacing capability of the ammoniated seawater without causing an undesirable increase of the rate of growth of sessile bacteria; and injecting the ammoniated and nitrited seawater into the reservoir to displace the reservoir fluid at substantially the natural reservoir temperature toward a production location from which oil is recovered.

Schutt, H.U.

1986-11-04T23:59:59.000Z

187

Method of recovering hazardous waste from phenolic resin filters  

DOE Patents [OSTI]

The invention is a process for the recovery of hazardous wastes such as heavy metals and radioactive elements from phenolic resin filter by a circulating a solution of 8 to 16 molar nitric acid at a temperature of 110 to 190 degrees F. through the filter. The hot solution dissolves the filter material and releases the hazardous material so that it can be recovered or treated for long term storage in an environmentally safe manner.

Meikrantz, David H. (Idaho Falls, ID); Bourne, Gary L. (Idaho Falls, ID); McFee, John N. (Albuquerque, NM); Burdge, Bradley G. (Idaho Falls, ID); McConnell, Jr., John W. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

188

Fractional distillation of C/sub 2//C/sub 3/ hydrocarbons at optimum pressures  

SciTech Connect (OSTI)

A method of recovering by distillation the separate components of a hydrocarbon gas mixture comprising ethylene, ethane, propylene and propane which comprises separating the ethylene and ethane as an overhead from a propylene and propane bottom in a first distillation tower at from about 400 to about 600 psia, separating ethylene and ethane as an ethylene overhead and an ethane bottom in a second distillation tower at from about 600 to about 700 psia, and separating propylene as an overhead from a propane bottom in a third distillation tower at from about 280 to about 300 psia is disclosed.

Tedder, D.W.

1984-08-07T23:59:59.000Z

189

The effect of acid strength on the MTO reaction : Conversion of methanol to hydrocarbons over H-SAPO-34 and high silica Chabazite (H-SSZ-13).  

E-Print Network [OSTI]

??The Methanol-to-Olefins (MTO) process for the production of polymer-grade olefins is a possible step in the upgrading of natural gas. The preferred MTO catalyst is… (more)

Bleken, Francesca

2007-01-01T23:59:59.000Z

190

A Comparison of Ten Different Methods for the Analysis of Saturates, Olefins, Benzene, Total Aromatics, and Oxygenates in Finished Gasolines  

Science Journals Connector (OSTI)

......overview of the changing European gasoline specifications with time...combined. These reformulated gasolines may now contain straight run naphtha, fluid catalytically...analysis of hydrocarbon types in gasoline is the fluorescent indi- cator......

Jan Beens; Hans Thomas Feuerhelm; Jörg-Christian Fröhling; Jerry Watt; Gertjan Schaatsbergen

191

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

192

Blocked and recovered memories of affective, distinctive, and neutral paragraphs  

E-Print Network [OSTI]

/know judgments. The question of retrieval blocking and recovery of strong negative memories comes to the forefront in the so-called recovered memory debate. Several authors (McNally et al., 2004a; Kihlstrom, 2004; Reisberg & Heuer, in press) have argued... negative stimuli are recalled later in life. McNally and colleagues (2004b) recruited participants who had suffered childhood sexual abuse and a control group who had not. They had all participants rate 2 lists, one of trauma-related and one of positively...

Corbisier, Barbara Lynn

2009-05-15T23:59:59.000Z

193

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the Fischer–Tropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

194

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network [OSTI]

Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble...

Kanga, Shahrukh

2012-06-07T23:59:59.000Z

195

Thermal acidization and recovery process for recovering viscous petroleum  

DOE Patents [OSTI]

A thermal acidization and recovery process for increasing production of heavy viscous petroleum crude oil and synthetic fuels from subterranean hydrocarbon formations containing clay particles creating adverse permeability effects is described. The method comprises injecting a thermal vapor stream through a well bore penetrating such formations to clean the formation face of hydrocarbonaceous materials which restrict the flow of fluids into the petroleum-bearing formation. Vaporized hydrogen chloride is then injected simultaneously to react with calcium and magnesium salts in the formation surrounding the bore hole to form water soluble chloride salts. Vaporized hydrogen fluoride is then injected simultaneously with its thermal vapor to dissolve water-sensitive clay particles thus increasing permeability. Thereafter, the thermal vapors are injected until the formation is sufficiently heated to permit increased recovery rates of the petroleum.

Poston, Robert S. (Winter Park, FL)

1984-01-01T23:59:59.000Z

196

Petrographic, Mineralogic, and Geochemical Studies of Hydrocarbon-derived Authigenic Carbonate Rock from Gas Venting, Seepage, Free Gas, and Gas Hydrate Sites in the Gulf of Mexico and offshore India  

E-Print Network [OSTI]

. ACR collected from the seafloor in the Gulf of Mexico (GOM) and ACR recovered from drilled cores in the Krishna-Godawari (KG) basin offshore India were used. All study sites are associated with hydrocarbon gas venting, seepage, free gas, or gas hydrate...

Jung, Woodong

2012-02-14T23:59:59.000Z

197

Experiences on Co-firing Solid Recovered Fuels in the Coal Power Sector  

Science Journals Connector (OSTI)

Solid Recovered Fuels (SRF) are solid fuels prepared from high calorific fractions of non- ... plants and industrial furnaces (CEN/TC 343, Solid Recovered Fuels, 2003). In other frameworks, these types of fuels a...

Jörg Maier; Alexander Gerhardt; Gregory Dunnu

2011-01-01T23:59:59.000Z

198

Innovative Elution Processes for Recovering Uranium from Seawater  

SciTech Connect (OSTI)

Utilizing amidoxime-based polymer sorbents for extraction of uranium from seawater has attracted considerable interest in recent years. Uranium collected in the sorbent is recovered typically by elution with an acid. One drawback of acid elution is deterioration of the sorbent which is a significant factor that limits the economic competitiveness of the amidoxime-based sorbent systems for sequestering uranium from seawater. Developing innovative elution processes to improve efficiency and to minimize loss of sorbent capacity become essential in order to make this technology economically feasible for large-scale industrial applications. This project has evaluated several elution processes including acid elution, carbonate elution, and supercritical fluid elution for recovering uranium from amidoxime-based polymer sorbents. The elution efficiency, durability and sorbent regeneration for repeated uranium adsorption- desorption cycles in simulated seawater have been studied. Spectroscopic techniques are used to evaluate chemical nature of the sorbent before and after elution. A sodium carbonate-hydrogen peroxide elution process for effective removal of uranium from amidoxime-based sorbent is developed. The cause of this sodium carbonate and hydrogen peroxide synergistic leaching of uranium from amidoxime-based sorbent is attributed to the formation of an extremely stable uranyl peroxo-carbonato complex. The efficiency of uranium elution by the carbonate-hydrogen peroxide method is comparable to that of the hydrochloric acid elution but damage to the sorbent material is much less for the former. The carbonate- hydrogen peroxide elution also does not need any elaborate step to regenerate the sorbent as those required for hydrochloric acid leaching. Several CO2-soluble ligands have been tested for extraction of uranium from the sorbent in supercritical fluid carbon dioxide. A mixture of hexafluoroacetylacetone and tri-n-butylphosphate shows the best result but uranium removal from the sorbent reaches only 80% after 10 hours of leaching. Some information regarding coordination of vanadium with amidoxime molecules and elution of vanadium from amidoxime- based sorbents is also given in the report.

Wai, Chien; Tian, Guoxin; Janke, Christopher

2014-05-29T23:59:59.000Z

199

Comparisons of hydrocarbon and nitrogen distributions in geologically diverse tar sand bitumen  

SciTech Connect (OSTI)

The characteristics of bitumens from different tar sand deposits are generally significantly different and affect the utilization of the resource. The chemical and physical properties of bitumen are a result of maturation reactions on the varied organic sediments. For example, saturated hydrocarbon distributions have been related to the geochemical history of organic matter. Very paraffinic or sometimes paraffinic-naphthenic distributions in organic matter are derived from a nonmarine depositional environment. More aromatic and paraffinic-naphthenic hydrocarbon distributions are derived from organic matter deposited in a marine environment. The characteristics of the bitumen also influence the potential for recovery and subsequent processing of the material. For example, saturated hydrocarbons contribute to the high pour points of recovered oils. The origin and composition of an oil influence its viscosity, API gravity, and coke formation during processing, particularly under low-temperature oxidation conditions. The objective of this work is to determine the chemical and physical properties of several samples of bitumen from geologically diverse tar sand deposits. The compound-type distributions and LTD properties of these bitumens are discussed relative to the depositional environment and processing potential of the organic matter.

Holmes, S.A.

1988-06-01T23:59:59.000Z

200

Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank  

Broader source: Energy.gov [DOE]

Case study covering Compact Membrane Systems, Inc. and its membrane vapor processor that recovers fuel vapors from gasoline refueling.

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

ANALYSIS OF SOLVENT RECOVERED FROM WRIGHT INDUSTRIES, INCORPORATED TESTING  

SciTech Connect (OSTI)

Washington Savannah River Company (WSRC) began designing and building a Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) at the Savannah River Site (SRS) to process liquid waste for an interim period. The MCU Project Team conducted testing of the contactors, coalescers, and decanters at Wright Industries, Incorporated (WII) in Nashville, Tennessee. That testing used MCU solvent and simulated SRS dissolved salt. Because of the value of the solvent, the MCU Project wishes to recover it for use in the MCU process in the H-Tank Farm. Following testing, WII recovered approximately 62 gallons of solvent (with entrained aqueous) and shipped it to SRS. The solvent arrived in two stainless steel drums. The MCU Project requested SRNL to analyze the solvent to determine whether it is suitable for use in the MCU Process. SRNL analyzed the solvent for Isopar{reg_sign} L by Gas Chromatography--Mass Spectroscopy (GC-MS), for Modifier and BOBCalixC6 by High Pressure Liquid Chromatography (HPLC), and for Isopar{reg_sign} L-to-Modifier ratio by Fourier-Transform Infrared (FTIR) spectroscopy. They also measured the solvent density gravimetrically and used that measurement to calculate the Isopar{reg_sign} L and Modifier concentration. The conclusions from this work are: (1) The constituents of the used WII solvent are collectively low in Isopar{reg_sign} L, most likely due to evaporation. This can be easily corrected through the addition of Isopar{reg_sign} L. (2) Compared to a sample of the WII Partial Solvent (without BOBCalixC6) archived before transfer to WII, the Reworked WII Solvent showed a significant improvement (i.e., nearly doubling) in the dispersion numbers for tests with simulated salt solution and with strip acid. Hence, the presence of the plasticizer impurity has no detrimental impact on phase separation. While there are no previous dispersion tests using the exact same materials, the results seem to indicate that the washing of the solvent gives a dispersion benefit. (3) WII Solvent that underwent a cleaning cycle provides an acceptable set of cesium distribution (i.e., D) values when used in a standard Extraction, Scrub, and Strip (ESS) test.

Poirier, M; Thomas Peters, T; Fernando Fondeur, F; Samuel Fink, S

2007-01-11T23:59:59.000Z

202

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Inc Hydrocarbon Inc Jump to: navigation, search Name Gulf Hydrocarbon Inc Address 2016 Main St Place Houston, Texas Zip 77002 Sector Biofuels Product Wholesale marketing of biodiesel and ethanol to refiners, blenders and petroleum distributors Website http://www.gulfhydrocarbon.com Coordinates 29.749227°, -95.371693° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.749227,"lon":-95.371693,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

203

George A. Olah, Carbocation and Hydrocarbon Chemistry  

Office of Scientific and Technical Information (OSTI)

George A. Olah, Carbocation and Hydrocarbon Chemistry George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information · Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations are stable and their physical properties ... can be observed, thus allowing details of their structures to be determined. Besides trivalent ions ... Olah demonstrated the existence of higher coordinate carbocations ... . These species do not violate the octet rule, but involve 2-electron 3-center bonding. '1

204

Using supercritical fluids to refine hydrocarbons  

DOE Patents [OSTI]

This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

Yarbro, Stephen Lee

2014-11-25T23:59:59.000Z

205

Removal of polycyclic aromatic hydrocarbons from surfactant solutions by selective sorption with organo-bentonite  

Science Journals Connector (OSTI)

Abstract Surfactant-enhanced soil washing is known to be an effective remediation approach for contaminated soils and groundwater. However, the recovery of surfactant solutions after soil washing is required for reducing the operation costs of the soil washing process. In this study, selective sorption with organo-bentonite was employed for the removal of polycyclic aromatic hydrocarbons (PAHs) from aqueous surfactant solution as a potential means of recovering surfactant solution after soil washing. The sorption of phenanthrene onto organo-bentonite from surfactant solution was well described by the pseudo-second-order kinetic model and the linear sorption isotherm model, respectively. \\{PAHs\\} can be effectively removed by organo-bentonite from surfactant solutions in a high proportion relative to the sorption loss of surfactant under all experimental conditions. The selectivity for PAH removal to surfactant sorption increased with increasing PAH hydrophobicity and surfactant hydrophilicity, but decreased with increasing surfactant concentration. However, increasing the organo-bentonite dose did not have obvious effect on the selectivity for surfactant recovery since it synchronously enhanced phenanthrene removal and surfactant sorption. The sorbent of organo-bentonite could be repeatedly used for recovering surfactant solution, which greatly reduced the sorption loss of surfactant and subsequently increased the selectivity for surfactant recovery considerably. The results suggest that selective sorption with organo-bentonite provides an alternative means of recovering surfactant solution after soil washing.

Wenjun Zhou; Xuehao Wang; Cuiping Chen; Lizhong Zhu

2013-01-01T23:59:59.000Z

206

E-Print Network 3.0 - aromatic hydrocarbons evaluated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

207

E-Print Network 3.0 - aromatic hydrocarbons part Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

208

Sexual selection on cuticular hydrocarbons of male sagebrush crickets in the wild  

Science Journals Connector (OSTI)

...association between cuticular hydrocarbon composition and desiccation...temperature on cuticular lipids and water balance in a desert Drosophila...interactions for cuticular hydrocarbon expression in Drosophila simulans...evolutionary roles of cuticular hydrocarbons in Diptera. In Insect hydrocarbons...

2013-01-01T23:59:59.000Z

209

Ash fusibility and compositional data of solid recovered fuels  

Science Journals Connector (OSTI)

Several approaches are established to analyse the fouling and slagging propensities of coal ashes, but the same cannot be said of solid recovered fuel (SRF) ashes. This work has been conducted by using some fouling and slagging indicators, which are commonly applicable to coal ashes, on SRF ashes to ascertain their applicability. In this work, laboratory prepared ashes derived from municipal solid waste (MSW), sewage sludge, demolition wood, shredded rubber tyres, and plastic/paper fluff are analysed for their fusibility leading to fouling and slagging using three approaches; the ash fusibility temperatures (AFT), ternary phase diagrams, and fouling/slagging indices. The results from each approach are examined to determine the inclination of the ashes toward fouling and slagging. A subsequent inter-comparison of the methods was conducted to validate the methods which are in agreement and are applicable to SRF ashes. The study showed that ternary equilibrium phase diagram SiO2–CaO–Al2O3, various fouling and slagging indices, and AFT can be used to complement each other to predict ash fusion properties, fouling and slagging propensities of SRF ashes.

Gregory Dunnu; Jörg Maier; Günter Scheffknecht

2010-01-01T23:59:59.000Z

210

Nuclear power fleets and uranium resources recovered from phosphates  

SciTech Connect (OSTI)

Current light water reactors (LWR) burn fissile uranium, whereas some future reactors, as Sodium fast reactors (SFR) will be capable of recycling their own plutonium and already-extracted depleted uranium. This makes them a feasible solution for the sustainable development of nuclear energy. Nonetheless, a sufficient quantity of plutonium is needed to start up an SFR, with the plutonium already being produced in light water reactors. The availability of natural uranium therefore has a direct impact on the capacity of the reactors (both LWR and SFR) that we can build. It is therefore important to have an accurate estimate of the available uranium resources in order to plan for the world's future nuclear reactor fleet. This paper discusses the correspondence between the resources (uranium and plutonium) and the nuclear power demand. Sodium fast reactors will be built in line with the availability of plutonium, including fast breeders when necessary. Different assumptions on the global uranium resources are taken into consideration. The largely quoted estimate of 22 Mt of uranium recovered for phosphate rocks can be seriously downscaled. Based on our current knowledge of phosphate resources, 4 Mt of recoverable uranium already seems to be an upper bound value. The impact of the downscaled estimate on the deployment of a nuclear fleet is assessed accordingly. (authors)

Gabriel, S.; Baschwitz, A.; Mathonniere, G. [CEA, DEN/DANS/I-tese, F-91191 Gif-sur-Yvette (France)

2013-07-01T23:59:59.000Z

211

Sustainable treatment of hydrocarbon-contaminated industrial land   

E-Print Network [OSTI]

Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

Cunningham, Colin John

2012-06-25T23:59:59.000Z

212

Chemical nature of high-molecular hydrocarbons of gaseous condensates  

SciTech Connect (OSTI)

Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

1987-01-01T23:59:59.000Z

213

Chapter 9 - Chemical and Physical Properties of Hydrocarbons  

Science Journals Connector (OSTI)

Publisher Summary Hydrocarbons are the simplest organic compounds and contain only carbon and hydrogen but they can be straight chain or branched chain with the same empirical formula but showing differences in properties. Chemical change results in the hydrocarbon yielding a product that may be entirely different in composition to the starting hydrocarbon—the exception is the isomerization reaction where a straight-chain hydrocarbon is converted to a branched-chain hydrocarbon. Chemical properties of hydrocarbons describe the potential of hydrocarbons to undergo chemical change or reaction by virtue of the hydrocarbon structure. Physical properties can be observed or measured without changing the composition of matter. Physical properties are used to observe and describe matter. Physical properties that are of interest in the current context include: boiling point, melting point, density, vapor density, flash point, ignition temperature, and dew point.

James G. Speight

2011-01-01T23:59:59.000Z

214

E-Print Network 3.0 - aromatic hydrocarbons methyl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Renewable Energy 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

215

E-Print Network 3.0 - aromatic hydrocarbons progress Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

216

E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

217

E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

218

E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

219

E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

220

E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

222

E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

223

E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

224

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enzymes Acid + Caustic Wastewater Treatment Process Heat and Power Integration Biogas + Sludge Fuel Finishing (hydroprocessing, as needed) Electricity Hydrogen Hydrocarbon...

225

THE ELECTRON MICROSCOPY OF HYDROCARBON PRODUCTION IN PARTHENIUM ARGENTATUM (GUAYULE)  

E-Print Network [OSTI]

conversion of solar energy is the production of hydrocarbonsproduction of hydrocarbons. Mankind's use of biologically converted solar energy

Bauer, T.E.

2010-01-01T23:59:59.000Z

226

aromatic hydrocarbons coated: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

227

Mineral Chemistry of Basalts Recovered from Hotspot Snake River Scientific Drilling Project, Idaho: Source and Crystallization Characteristics  

E-Print Network [OSTI]

Mineral Chemistry of Basalts Recovered from Hotspot Snake River Scientific Drilling Project, Idaho recovered by Hotspot: Snake River Scientific Drilling Project, Idaho establish crystallization conditions;ABSTRACT Mineral Chemistry of Basalts Recovered from Hotspot: Snake River Scientific Drilling Project

Seamons, Kent E.

228

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents [OSTI]

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

229

Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons  

Science Journals Connector (OSTI)

... in the flask's headspace. This procedure produced negligible amounts of contaminating hydrocarbons. The geothermal hydrocarbons were separated and combusted, and the carbon dioxide product purified and measured using ... of the pyrolysis and spark discharge experiments, b, Isotopic abundance of hydrocarbons from four geothermal localities as follows: D, Cerro Prieto, well M-5, sampled January 1979; ...

David J. Des Marais; Jason H. Donchin; Nancy L. Nehring; Alfred H. Truesdell

1981-08-27T23:59:59.000Z

230

Nonlinear dependence of the solubility of water in hydrocarbons on the molar volume of the hydrocarbon  

Science Journals Connector (OSTI)

The solubility of water in fifty hydrocarbon solvents at 20°C is estimated by ... in nonspecific cohesion forces, and assuming that water is primarily monomeric in solution, the prediction ... breaking of the H-b...

Paul Ruelle; Ulrich W. Kesselring

1996-07-01T23:59:59.000Z

231

Synthesis of Esters from Cage-Like Unsaturated Hydrocarbons, Carboxylic Acid Anhydrides, and Water  

Science Journals Connector (OSTI)

A convenient method for the preparation of esters was developed on the basis of reaction of cage-like polycyclic olefins with carboxylic acid anhydrides and water. Mixed anhydrides were found to give rise to t...

M. K. Mamedov; E. K. Nabieva; R. A. Rasulova

232

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network [OSTI]

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

233

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...WI 53706 The aryl hydrocarbon receptor (AHR) is...The mammalian aryl hydrocarbon receptor (AHR) is...complex with the 90-kDa heat shock protein (HSP90) and...polycyclic aromatic hydrocarbons such as {beta...cigarette smoking and other combustion processes, initiate...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

234

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...mammalian aryl hydrocarbon receptor...the 90-kDa heat shock protein (HSP90...polycyclic aromatic hydrocarbons such as {beta...smoking and other combustion processes...we searched data from the...Helminth HSP90 Heat-Shock Proteins...Molecular Sequence Data Protein Binding...Receptors, Aryl Hydrocarbon genetics metabolism...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

235

Hydrocarbon composition of crude oils near the Caspian depression  

SciTech Connect (OSTI)

The structural-group composition of hydrocarbons of Mesozoic crude oils near the Caspian depression was investigated by mass-spectrometry, followed by the analysis of the mass-spectra using a computer. The distribution of naphthenic hydrocarbons, according to the number of rings and of aromatic hydrocarbons, according to the degree of hydrogen unsaturation is similar for all the crude oils examined. The hydrocarbon composition of Mesozoic crude oils is characterized by a reduction in the content of aliphatic hydrocarbons and alkyl benzenes.

Botneva, T.A.; Khramova, E.V.; Nekhamkina, L.G.; Polyakova, A.A.

1983-01-01T23:59:59.000Z

236

Energy Recovered Light Source Technology at TJNAF | U.S. DOE...  

Office of Science (SC) Website

Energy Recovered Light Source Technology at TJNAF Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of Nuclear Science...

237

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents [OSTI]

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

238

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents [OSTI]

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

239

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

SciTech Connect (OSTI)

We have suggested that certain plants rich in hydrocarbon-like materials might be cultivated for renewable photosynthetic products. Two species were selected for experimental plantations: Euphorbia lathyris, an annual from seed and Euphorbia tirucalli, a perennial from cuttings, The yield from each species is over 10 barrels of oil/acre/year without genetic or agronomic improvement. In addition to plants, there are trees, such as species of Copaifera in Brazil and other tropical areas, which produce a diesel-like oil upon tapping. Each tree produces approximately 40 liters of hydrocarbon per year, and this material can be used directly by a diesel-powered car. Further efforts to develop plants as alternate energy sources are underway, as well as a continuing search for additional plant species throughout the world which have a similar capability.

Calvin, Melvin

1980-05-01T23:59:59.000Z

240

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents [OSTI]

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents [OSTI]

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

Hsu, Wen Ling

1987-10-14T23:59:59.000Z

242

Upgrading Recovered Paper With Enzyme Pretreat ment and Pressurized Peroxide Bleaching  

E-Print Network [OSTI]

tiveness of enzymes for toner removal was subsequently confirmed on an industrial scale (2,3). In addition to be effective for toner ink removal, can improve the bleachability of low quality recovered paper. When followed mixed recovered paper demonstrated that an enzymatic pretreatment improves the removal of residual inks

Abubakr, Said

243

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

244

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fractionation Hydrogen Acid, Caustic, Enzymes Wastewater Treatment Insoluble solids Biogas + Sludge Process Heat and Power Integration Corn Stover Hydrocarbon Biofuels (i.e....

245

Biological Conversion of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with...

246

CSIA of Petroleum Hydrocarbons: Forensic Fingerprinting and Oil Spill Characterisation.  

E-Print Network [OSTI]

??This thesis has identified a suite of hydrocarbon diagnostic indices to be applied in the forensic fingerprinting of diesel oil characterisation and source identification using… (more)

Muhammad, Syahidah Akmal binti

2012-01-01T23:59:59.000Z

247

The mobility of petroleum hydrocarbons in Athabasca oil sands tailings.  

E-Print Network [OSTI]

??Several oil sands tailings from Suncor Energy Inc. were analysed with respect to the mobility and solubility of the petroleum hydrocarbon (PHC) contaminants. At sites… (more)

Brickner, Heather

2014-01-01T23:59:59.000Z

248

Process for making unsaturated hydrocarbons using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

2011-04-12T23:59:59.000Z

249

Selective aerobic oxidation of hydrocarbons over supported gold catalysts.  

E-Print Network [OSTI]

??The selective oxidation of hydrocarbons is of vital importance for the production of valuable chemicals from crude oil and natural gas resources. Unfortunately, when using… (more)

Hereijgers, B.P.C.

2011-01-01T23:59:59.000Z

250

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

251

Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst  

Broader source: Energy.gov [DOE]

Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance

252

Electrical dispersion of water drops suspended in hydrocarbons  

Science Journals Connector (OSTI)

The effects of alternating (50 Hz) and direct current fields on drops of distilled water in a nonpolar hydrocarbon medium were examined.

G. M. Panchenkov; V. V. Papko; V. Ya. Baranov

1968-10-01T23:59:59.000Z

253

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents [OSTI]

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

254

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Broader source: Energy.gov (indexed) [DOE]

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

255

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect (OSTI)

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

256

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect (OSTI)

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

257

Transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates: Catalysts for asymmetric olefin hydroamination and acceptorless alcohol decarbonylation  

SciTech Connect (OSTI)

The research presented and discussed in this dissertation involves the synthesis of transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates, and their application in catalytic enantioselective olefin hydroamination and acceptorless alcohol decarbonylation. Neutral oxazolinylboranes are excellent synthetic intermediates for preparing new borate ligands and also developing organometallic complexes. Achiral and optically active bis(oxazolinyl)phenylboranes are synthesized by reaction of 2-lithio-2-oxazolide and 0.50 equiv of dichlorophenylborane. These bis(oxazolinyl)phenylboranes are oligomeric species in solid state resulting from the coordination of an oxazoline to the boron center of another borane monomer. The treatment of chiral bis(oxazolinyl)phenylboranes with sodium cyclopentadienide provide optically active cyclopentadienyl-bis(oxazolinyl)borates H[PhB(C{sub 5}H{sub 5})(Ox{sup R}){sub 2}] [Ox{sup R} = Ox{sup 4S-iPr,Me2}, Ox{sup 4R-iPr,Me2}, Ox{sup 4S-tBu]}. These optically active proligands react with an equivalent of M(NMe{sub 2}){sub 4} (M = Ti, Zr, Hf) to afford corresponding cyclopentadienyl-bis(oxazolinyl)borato group 4 complexes {PhB(C{sub 5}H{sub 4})(Ox{sup R}){sub 2}}M(NMe{sub 2}){sub 2} in high yields. These group 4 compounds catalyze cyclization of aminoalkenes at room temperature or below, providing pyrrolidine, piperidine, and azepane with enantiomeric excesses up to 99%. Our mechanistic investigations suggest a non-insertive mechanism involving concerted C?N/C?H bond formation in the turnover limiting step of the catalytic cycle. Among cyclopentadienyl-bis(oxazolinyl)borato group 4 catalysts, the zirconium complex {PhB(C{sub 5}H{sub 4})(Ox{sup 4S-iPr,Me2}){sub 2}}Zr(NMe{sub 2}){sub 2} ({S-2}Zr(NMe{sub 2}){sub 2}) displays highest activity and enantioselectivity. Interestingly, {S-2}Zr(NMe{sub 2}){sub 2} also desymmetrizes olefin moieties of achiral non-conjugated aminodienes and aminodiynes during cyclization. The cyclization of aminodienes catalyzed by {S-2}Zr(NMe{sub 2}){sub 2} affords diastereomeric mixture of cis and trans cylic amines with high diasteromeric ratios and excellent enantiomeric excesses. Similarly, the desymmetrization of alkyne moieties in {S-2}Zr(NMe{sub 2}){sub 2}-catalyzed cyclization of aminodiynes provides corresponding cyclic imines bearing quaternary stereocenters with enantiomeric excesses up to 93%. These stereoselective desymmetrization reactions are significantly affected by concentration of the substrate, temperature, and the presence of a noncyclizable primary amine. In addition, both the diastereomeric ratios and enantiomeric excesses of the products are markedly enhanced by N-deuteration of the substrates. Notably, the cationic zirconium-monoamide complex [{S-2}Zr(NMe{sub 2})][B(C{sub 6}F{sub 5}){sub 4}] obtained from neutral {S-2}Zr(NMe{sub 2}){sub 2} cyclizes primary aminopentenes providing pyrrolidines with S-configuration; whereas {S-2}Zr(NMe{sub 2}){sub 2} provides R-configured pyrrolidines. The yttrium complex {S-2}YCH{sub 2}SiMe{sub 3} also affords S-configured pyrrolidines by cyclization of aminopentenes, however the enantiomeric excesses of products are low. An alternative optically active yttrium complex {PhB(C{sub 5}H{sub 4})(Ox{sup 4S-tBu}){sub 2}}YCH{sub 2}SiMe{sub 3} ({S-3}YCH{sub 2}SiMe{sub 3}) is synthesized, which displays highly enantioselective in the cyclization of aminoalkenes at room temperature affording S-configured cyclic amines with enantiomeric excesses up to 96%. A noninsertive mechanism involving a six-membered transition state by a concerted C?N bond formation and N?H bond cleavage is proposed for {S-3}YCH{sub 2}SiMe{sub 3} system based on the kinetic, spectroscopic, and stereochemical features. In the end, a series of bis- and tris(oxazolinyl)borato iridium and rhodium complexes are synthesized with bis(oxazolinyl)phenylborane [PhB(Ox{sup Me2}){sub 2}]{sub n}, tris(oxazolinyl)borane [B(Ox{sup Me2}){sub 3}]n, and tris(4,4-dimethyl-2-oxazolinyl)phenylborate [To{sup M}]{sup ?}. All these new an

Manna, Kuntal [Ames Laboratory

2012-12-17T23:59:59.000Z

258

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons were quantitatively...polycyclic aromatic hydrocarbon constituent in a kerosene...polycyclic aromatic hydrocarbon fraction in terms of...formed by the incomplete combustion of organic material...and sediments (1), heat and power generation...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

259

E-Print Network 3.0 - aromatic hydrocarbon investigation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

260

E-Print Network 3.0 - aromatic hydrocarbons investigated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

E-Print Network 3.0 - aromatic hydrocarbon components Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

262

E-Print Network 3.0 - aromatic hydrocarbon molecules Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

263

E-Print Network 3.0 - aromatic hydrocarbons molecules Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

264

E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

265

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

...research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion...mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...Carcinogens 0 Epoxy Compounds 0 Fuel Oils 0 Hydrocarbons 0 Naphthalenes...

1975-01-01T23:59:59.000Z

266

Ozonation of Mutagenic and Carcinogenic Polyaromatic Amines and Polyaromatic Hydrocarbons in Water  

Science Journals Connector (OSTI)

...Amines and Polyaromatic Hydrocarbons in Water 1 1 Supported by a grant...amines and polyaromatic hydrocarbons in water. | The Salmonella-microsome...g., 13 halogenated hydrocarbons were identified in the drinking water of New Orleans (13...

Gary R. Burleson; Michael J. Caulfield; and Morris Pollard

1979-06-01T23:59:59.000Z

267

Determination of hydrocarbons in water – interlaboratory method validation before routine monitoring  

Science Journals Connector (OSTI)

The clarification of hydrocarbon input into the Baltic sea via rivers ... of a new method for the determination of hydrocarbons by solvent extraction and gas chromatography. Surrogate oil solutions with known hydrocarbon

P. Woitke; Reinhard Kreßner; Peter Lepom

2001-04-01T23:59:59.000Z

268

Energy Recovered Light Source Technology at TJNAF | U.S. DOE Office of  

Office of Science (SC) Website

Energy Recovered Light Source Energy Recovered Light Source Technology at TJNAF Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Spinoff Applications Spinoff Archives SBIR/STTR Applications of Nuclear Science and Technology Funding Opportunities Nuclear Science Advisory Committee (NSAC) News & Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: sc.np@science.doe.gov More Information » Spinoff Archives Energy Recovered Light Source Technology at TJNAF Print Text Size: A A A RSS Feeds FeedbackShare Page Application/instrumentation: Energy-recovered linac/TJNAF Free Electron Laser Developed at: Thomas Jefferson National Accelerator Facility, Brookhaven National

269

DOE Announces Three Projects to Help the Gulf Coast Recover and Rebuild |  

Broader source: Energy.gov (indexed) [DOE]

Three Projects to Help the Gulf Coast Recover and Three Projects to Help the Gulf Coast Recover and Rebuild DOE Announces Three Projects to Help the Gulf Coast Recover and Rebuild January 20, 2006 - 10:52am Addthis ROBINSONVILLE, MS - Energy Secretary Samuel W. Bodman today announced three Department of Energy (DOE) initiatives to help the people in the Gulf coast region recover from the hurricanes in 2005, as well as prevent loss of life and damage in the future. During his speech to the Energy Leadership Forum, the secretary announced that DOE will donate 400,000 hours of supercomputing time at its National Energy Research Scientific Computing Center (NERSC) to the U.S. Army Corps of Engineers to assist with the rebuilding of levees. DOE is also offering hurricane-affected residents free rebuilding workshops providing expert advice on the latest

270

NNSA Partners With Russia to Recover Material That Could Be Used in Dirty  

National Nuclear Security Administration (NNSA)

Partners With Russia to Recover Material That Could Be Used in Dirty Partners With Russia to Recover Material That Could Be Used in Dirty Bombs | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Home > Media Room > Press Releases > NNSA Partners With Russia to Recover Material ... Press Release NNSA Partners With Russia to Recover Material That Could Be Used in Dirty

271

DOE Announces Three Projects to Help the Gulf Coast Recover and Rebuild |  

Broader source: Energy.gov (indexed) [DOE]

Announces Three Projects to Help the Gulf Coast Recover and Announces Three Projects to Help the Gulf Coast Recover and Rebuild DOE Announces Three Projects to Help the Gulf Coast Recover and Rebuild January 20, 2006 - 10:52am Addthis ROBINSONVILLE, MS - Energy Secretary Samuel W. Bodman today announced three Department of Energy (DOE) initiatives to help the people in the Gulf coast region recover from the hurricanes in 2005, as well as prevent loss of life and damage in the future. During his speech to the Energy Leadership Forum, the secretary announced that DOE will donate 400,000 hours of supercomputing time at its National Energy Research Scientific Computing Center (NERSC) to the U.S. Army Corps of Engineers to assist with the rebuilding of levees. DOE is also offering hurricane-affected residents free rebuilding workshops providing expert advice on the latest

272

For Immediate Release --Tuesday, April 22, 2014 Touch therapy helps brains recover following stroke,  

E-Print Network [OSTI]

brains recover following stroke, University of Lethbridge research reveals Study from a stroke is harder for those who have been exposed to stress that then experienced a stroke in adulthood suffered more severe motor disabilities compared

Seldin, Jonathan P.

273

Improved Solubility and Emulsification of Wet-Milled Corn Germ Protein Recovered by Ultrafiltration–Diafiltration  

Science Journals Connector (OSTI)

This study evaluated Ultrafiltration–Diafiltration (UFDF) as a means to improve the extractability of wet-milled corn germ protein and determined its effects on ... functional properties of the recovered protein ...

Mila P. Hojilla-Evangelista

2014-09-01T23:59:59.000Z

274

Recovering and recycling Hg from chlor-alkali plant wastewater sludge  

Science Journals Connector (OSTI)

Montana Tech of the University of Montana and Universal Dynamics of British Columbia have developed a hydrometallurgical process for recovering and recycling mercury from chlorine plant wastewater sludge material...

L. G. Twidwell; R. J. Thompson

2001-01-01T23:59:59.000Z

275

Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford and P. Westerhoff  

E-Print Network [OSTI]

Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford to global warming. Biofuel from phototrophic microbes like algae and bacteria provides a viable substitute improves biofuel sustainability by refining phosphorus recycling. Biomass Production Residual Biomass

Hall, Sharon J.

276

Combined Total Amount of Oil and Gas Recovered Daily from the...  

Broader source: Energy.gov (indexed) [DOE]

XLS Combined Total Amount of Oil and Gas Recovered Daily from the Top Hat and Choke Line oil recovery systems - XLS Updated through 12:00 AM on July 16, 2010. 52Item84Recovery...

277

Combined Total Amount of Oil and Gas Recovered Daily from the...  

Broader source: Energy.gov (indexed) [DOE]

ODS format Combined Total Amount of Oil and Gas Recovered Daily from the Top Hat and Choke Line oil recovery systems - ODS format Updated through 12:00 AM on July 16, 2010....

278

A macrofossil analysis of materials recovered from Hovenweep National Monument, Cajon Mesa, Colorado and Utah  

E-Print Network [OSTI]

A MACROFOSSIL ANALYSIS OF MATERIALS RECOVERED FROM HOVENMEEP NATIONAL MONUMENT, CAJON MESA, COLORADO AND UTAH A Thesis by DONNA RUTH CHAPMAN Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1979 Major Subject: Botany A MACROFOSSIL ANALYSIS OF MATERIALS RECOVERED FROM HOVENWEEP NATIONAL MONUMENT, CATION MESA, COLORADO AND UTAH A Thesis by DONNA RUTH CHAPMAN Approved as to style and content by...

Chapman, Donna Ruth

2012-06-07T23:59:59.000Z

279

Advanced Size Measurements and Aerodynamic Classification of Solid Recovered Fuel Particles  

Science Journals Connector (OSTI)

Solid recovered fuels are highly heterogeneous mixtures generated from high calorific fractions of nonhazardous waste materials intended to be fired in existing coal power plants and industrial furnaces (CEN/TC 343 N 9rev3, Solid Recovered Fuel, 2003). ... There are numerous definitions for the term SRF, but the recent one put forth by CEN/TC 3431 defined it as “fuel prepared from non-hazardous waste to be used for energy recovery in waste incineration and co-incineration plants”. ...

Gregory Dunnu; Thomas Hilber; Uwe Schnell

2006-06-29T23:59:59.000Z

280

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants  

E-Print Network [OSTI]

1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

Paris-Sud XI, Université de

282

Contemplation on the heats of combustion of isomeric hydrocarbons  

Science Journals Connector (OSTI)

Within the Hückel molecular orbital theory, the heats of combustion of isomeric hydrocarbons are related to some topological factors. The standard heats of combustion values of alternant hydrocarbons, expressed as kcal/g, seem to be related to a4 coefficient of their secular polynomials.

Lemi Türker

2004-01-01T23:59:59.000Z

283

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network [OSTI]

aromatic hydrocarbons PAHs up to 788 amu (C64H20) were detected in the combustion gases. Only the most applications including heating systems and gas turbines for electric power generation.62­64 The combustionFormation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss

Sattler, Klaus

284

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

285

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

286

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

287

High levels of carcinogenic polycyclic aromatic hydrocarbons in mate drinks  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mate drinks Farin Kamangar...exposure to polycyclic aromatic hydrocarbons (PAHs), including known...80 oC) or cold (4 oC) water and two commonly used brands...Infusions were made by adding water to the leaves, steeping for...

Farin Kamangar; Michele Schantz; Christian Abnet; Renato Fagundes; and Sanford Dawsey

2008-05-01T23:59:59.000Z

288

Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids  

E-Print Network [OSTI]

O H H Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids O O t-BuO3C Br O O Br Br Ph PhPh Ph PhPh Ph Ph COOH HOOC Total Synthesis of Convex Polyhedral Hydrocarbons The Five Matter Icosahedron Water · Polyhedron: a closed surface made up of polygonal regions. · Regular

Stoltz, Brian M.

289

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings  

Science Journals Connector (OSTI)

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings ... Relation between Bioavailability and Fuel Oil Hydrocarbon Composition in Contaminated Soils ...

Claude-Henri. ChaIneau; Jean-Louis. Morel; Jean. Oudot

1995-06-01T23:59:59.000Z

290

E-Print Network 3.0 - aromatic hydrocarbons affect Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

291

E-Print Network 3.0 - aromatic hydrocarbons annual Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: releases about 5 billion kilograms of hydrocarbons...

292

E-Print Network 3.0 - aromatic hydrocarbons implications Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

293

E-Print Network 3.0 - aromatic hydrocarbon exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and...

294

E-Print Network 3.0 - aromatic hydrocarbon contamination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs). PAHs are...

295

E-Print Network 3.0 - aromatic hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aromatic hydrocarbons... the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

296

E-Print Network 3.0 - aromatic hydrocarbons extracted Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs)....

297

E-Print Network 3.0 - aromatic hydrocarbon metabolism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon is introduced into the ocean via oil spillage, offshore drilling leaks, industrial... hydrocarbons have been attributed to inhibition of ... Source: National...

298

E-Print Network 3.0 - aromatic hydrocarbon-degrading bacteria...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ydrocarbonDegradation It was hypothesized... aromatic hydrocarbon degradation. Hypothesis Test Result Groundwater stimulates Fe(lll) reduction Cell... Hydrocarbon Degradation At...

299

Chlorinated C$_{1}$ and C$_{2}$ Hydrocarbons in the Marine Environment [and Discussion  

Science Journals Connector (OSTI)

...the marine environment. | Journal Article | 0 Hydrocarbons, Chlorinated | Air Pollution analysis Animals Fresh Water Great Britain Hydrocarbons, Chlorinated analysis metabolism Seawater Water Pollution, Chemical analysis The Royal Society...

1975-01-01T23:59:59.000Z

300

Bioremediation of soil contaminated with hydrocarbons and heavy metals  

SciTech Connect (OSTI)

This investigation showed that a soil contaminated with petroleum hydrocarbons and heavy metals had sufficient indigenous microbial activity for hydrocarbon biodegradation under nonlimiting conditions. Nutrient supplementation with nitrogen and phosphate, together with aeration, seemed to be the most important factors for enhancing biodegradation. Hydrocarbon biodegradation occurred to a much greater extent under aerobic than under anaerobic conditions. Biodegradation did, however, induce low pH conditions and thus caused high heavy-metal concentrations in the leachate. Anaerobic conditions inhibited hydrocarbon biodegradation with no subsequent drop in pH and low heavy-metal concentrations in the leachate. Thus, anaerobic conditions were shown to facilitate less metal mobility than low pH conditions. Air sparging did not cause a significant increase in biodegradation. Adsorption of heavy-fraction hydrocarbons (> C{sub 20}) to microorganisms and colloidal material in the leachate was suspected of facilitating mobility of these fractions and thus their subsequent detection in the leachate.

Plessis, C.A. du; Phaal, C.B.; Senior, E. [Univ. of Natal, Scottsville (South Africa)

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Cogeneration systems and processes for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

302

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents [OSTI]

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

303

Olefin Autoxidation in Flow  

E-Print Network [OSTI]

Handling hazardous multiphase reactions in flow brings not only safety advantages but also significantly improved performance, due to better mass transfer characteristics. In this paper, we present a continuous microreactor ...

Neuenschwander, Ulrich

304

Bayer Material Science (TRL 1 2 3 System)- River Devices to Recover Energy with Advanced Materials(River DREAM)  

Broader source: Energy.gov [DOE]

Bayer Material Science (TRL 1 2 3 System) - River Devices to Recover Energy with Advanced Materials(River DREAM)

305

Interactions Between Energy Efficiecy Programs Funded Under Recover Act and Utility Customer-funded Energy Efficiency Programs  

Broader source: Energy.gov [DOE]

Interactions Between Energy Efficiecy Programs Funded Under Recover Act and Utility Customer-funded Energy Efficiency Programs Webinar.

306

Process for steam reforming of hydrocarbons  

SciTech Connect (OSTI)

A process is provided for the steam reforming of normally liquid hydrocarbons to produce carbon monoxide and hydrogen, which does not promote the deposition of carbonacious materials upon catalytic surfaces. The catalyst consists of nickel promoted with the oxides of iron and manganese within a specific manganese to iron ratio, said metal and metal oxides being supported upon a refractory support. The support is preferably aluminum oxide in its alpha phase having a surface area of more than 0.5 m2/gm but no more than 10 m2/gm. The metallic constituents are impregnated onto said refractory low surface area support as salts and are calcined at sufficiently high temperature to convert the salts to the oxide but at a sufficiently low temperature that they do not chemically react with the support.

Broughton, D.R.; Russ, K.J.

1980-11-11T23:59:59.000Z

307

Method and apparatus for detecting halogenated hydrocarbons  

DOE Patents [OSTI]

A halogenated hydrocarbon (HHC) detector is formed from a silent discharge (also called a dielectric barrier discharge) plasma generator. A silent discharge plasma device receives a gas sample that may contain one or more HHCs and produces free radicals and excited electrons for oxidizing the HHCs in the gas sample to produce water, carbon dioxide, and an acid including halogens in the HHCs. A detector is used to sensitively detect the presence of the acid. A conductivity cell detector combines the oxidation products with a solvent where dissociation of the acid increases the conductivity of the solvent. The conductivity cell output signal is then functionally related to the presence of HHCs in the gas sample. Other detectors include electrochemical cells, infrared spectrometers, and negative ion mobility spectrometers.

Monagle, Matthew (Los Alamos, NM); Coogan, John J. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

308

An investigation on recycling the recovered uranium from electro-refining process in a CANDU reactor  

Science Journals Connector (OSTI)

Feasibility studies for recycling the recovered uranium from electro-refining process of pyroprocessing into a Canada Deuterium Uranium (CANDU) reactor have been carried out with a source term analysis code ORIGEN-S, a reactor lattice analysis code WIMS-AECL, and a Monte Carlo analysis code MCNPX. The uranium metal can be recovered in a solid cathode during an electro-refining process and has a form of a dendrite phase with about 99.99% expecting recovery purity. Considering some impurities of transuranic (TRU) elements and fission products in the recovered uranium, sensitivity calculations were also performed for the compositions of impurities. For a typical spent PWR fuel of 3.0 wt.% of uranium enrichment, 30 GWD/tU burnup and 10 years cooling, the recovered uranium exhibited an extended burnup up to 14 GWD/tU. And among the several safety parameters, the void reactivity at the equilibrium state was estimated 15 mk. Additionally, a simple sphere model was constructed to analyze surface dose rates with the Monte Carlo calculations. It was found that the recovered uranium from the spent PWR fuel by electro-refining process has a significant radioactivity depending on the impurities such as fission products.

Chang Je Park; Kweon Ho Kang; Jung Won Lee; Ki Seog Seo

2011-01-01T23:59:59.000Z

309

Hydrocarbon concentrations at the Alpine mountain sites Jungfraujoch and Arosa  

Science Journals Connector (OSTI)

Volatile hydrocarbons have been measured for 1 yr at Arosa (2010 m asl) to determine the contribution of European emissions to the trace gas concentrations at this remote site. Results are compared to concurrent hydrocarbon concentrations at the high Alpine background site Jungfraujoch (3580 m asl). Hydrocarbon concentrations at Arosa are generally much higher than at Jungfraujoch. The influence of the Alpine boundary layer air was studied based on the diurnal variation of hydrocarbon concentrations, i.e. rising pollutant concentrations in the morning at Arosa and in the afternoon at Jungfraujoch. Different hydrocarbon emission sources of the uplifting air were found at the two sites. At Jungfraujoch, several transatlantic events were detected from October 2001 to January 2002 based on analysis of hydrocarbon ratios and air parcel trajectories. The OH concentration during the transatlantic transport was estimated to be around 5×105 cm?3, derived from simultaneous hydrocarbon oxidation and dilution in the free troposphere. These transatlantic transport events were tracked back to warm conveyor belts, characterized by uniform dynamics and relatively uniform surface sources. In addition, ozone production in the free tropospheric transport was also documented in these events.

Yingshi Li; Mike Campana; Stefan Reimann; Daniel Schaub; Konrad Stemmler; Johannes Staehelin; Thomas Peter

2005-01-01T23:59:59.000Z

310

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Broader source: Energy.gov (indexed) [DOE]

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

311

Iraq`s significant hydrocarbon potential remains relatively undeveloped  

SciTech Connect (OSTI)

Iraq is probably one of the least explored countries in the Middle East, despite the fact that it possesses one of the richest hydrocarbon basins in the world almost on a par to Saudi Arabia`s potential, if not more. The aim of this article is to state the facts about Iraq and focus on the huge but untapped and undeveloped hydrocarbon resources to the international oil community. Perhaps it is best to start by describing briefly the sedimentary and tectonic elements responsible for accumulating such large hydrocarbon resources. The paper describes the basin, tectonic elements, structural anomalies, deep drilling, source rocks, reservoir rocks, characteristics, and new reserves.

AL-Gailani, M. [GeoDesign Ltd., Kingston-upon-Thames (United Kingdom)

1996-07-29T23:59:59.000Z

312

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

1999-07-27T23:59:59.000Z

313

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

1999-01-01T23:59:59.000Z

314

Skid-mounted rotating thermal separator efficiently recovers NGL from associated gas  

SciTech Connect (OSTI)

A significant portion of the LPG fraction of the associated gas from a small field can be economically recovered even in remote locations. An example is the Breme field, for which Elf Gabon is the operator. Situated 50 miles from Port Gentil, the field is located on a narrow strip of land between the sea and a lagoon, with access only by plane or boat. A prefabricated, skid-mounted, turnkey plant is now efficiently recovering gas condensate from the field flare. At the full rated 14 MMscfd gas flow (55 psia), the recovered LPG can add as much as 650 b/d to the 12,000 b/d crude oil production rate, 6 vol %. The plant includes a compact plate heat exchanger and a rotating thermal separator (RTS) that requires little maintenance, minimal control, and no outside energy.

Marchal, P.; Malek, S.; Viltard, J.C.

1984-12-03T23:59:59.000Z

315

E-Print Network 3.0 - aromatic hydrocarbon emission Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic hydrocarbon emission...

316

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network [OSTI]

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

317

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

318

Method for production of hydrocarbons from hydrates  

DOE Patents [OSTI]

A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

McGuire, Patrick L. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

319

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Broader source: Energy.gov (indexed) [DOE]

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

320

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect (OSTI)

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN'  

E-Print Network [OSTI]

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN' OSpemnenr Of C%sITIkby. M k I. A biographyand photograph of Kenneth D. Jordan appear In previous paper in this issue. far outweighsthat

Simons, Jack

322

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

Desai, Anuradha M.

2007-04-25T23:59:59.000Z

323

Experiments on Hydrocarbon Gas Hydrates in Unconsolidated Sand  

Science Journals Connector (OSTI)

Experiments were carried out to observe the formation and decomposition of hydrocarbon gas hydrates in an unconsolidated sand pack 4.4 cm in diameter and ... 43 bars and 5 to 10°C; gas used was 90% methane and 10...

P. E. Baker

1974-01-01T23:59:59.000Z

324

Filtration Combustion in Hydrocarbon Desorption from a Porous Medium  

Science Journals Connector (OSTI)

We have investigated theoretically and experimentally the process of filtration combustion with hydrocarbon desorption from a porous skeleton realized, in particular, in heat cleaning of porous media out of resid...

S. I. Fut'ko; K. V. Dobrego; E. S. Shmelev…

2003-11-01T23:59:59.000Z

325

Fireball during combustion of hydrocarbon fueld releases II. Thermal radiation  

Science Journals Connector (OSTI)

The processes of radiative heat transfer in a fireball which develops upon ignition of a cloud of hydrocarbon fuel near the Earth’s surface are simulated numerically. The emissive characteristics of combustion pr...

G. M. Makhviladze; J. P. Roberts; S. E. Yakush

326

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network [OSTI]

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

327

Effect of the Composition of Hydrocarbon Streams on HCCI Performance  

Broader source: Energy.gov (indexed) [DOE]

of hydrocarbon samples and can be treated as compositional variables which could describe bulk properties of the samples Sample fingerprint STEP 1: Data receiving Q(2d)RPR How...

328

Hydrocarbon pollution control and remediation of groundwater: a brief review  

Science Journals Connector (OSTI)

...oil-contaminated sediments. There are two main remediation techniques: soil washing and bio- remediation. With soil washing, contaminated soil is leached with water containing a surfactant to assist in hydrocarbon removal. In situ washing is undertaken...

L. Clark

329

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE.  

Science Journals Connector (OSTI)

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE. ... Citation data is made available by participants in CrossRef's Cited-by Linking service. ... Experimental methods included adiabatic heat-capacity calorimetry (5 K to 420 K), comparative ... ...

Theodore W. Richards; Frederick Barry

1915-01-01T23:59:59.000Z

330

Measurements of dissolved nonmethane hydrocarbons in sea water  

Science Journals Connector (OSTI)

An automated stripping technique for the measurement of dissolved hydrocarbons in sea water is presented together with some results obtained ... cruise from Europe to Brazil. The sea water concentrations of NMHC ...

C. Plass; R. Koppmann; J. Rudolph

331

Hygienic rating of hydrocarbons in bottom deposits of water ecosystems  

Science Journals Connector (OSTI)

The authors of this article draw the reader’s attention to the topical problem of the contamination of bottom deposits of water ecosystems by hydrocarbons, such as oil and gas condensate,...

Rauf Valievich Galiulin…

2014-05-01T23:59:59.000Z

332

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents [OSTI]

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

333

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network [OSTI]

CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 2000 Major Subject: Chemical Engineering CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Alkhawaldeh, Ammar

2012-06-07T23:59:59.000Z

334

Recurrent Oil Sheens at the Deepwater Horizon Disaster Site Fingerprinted with Synthetic Hydrocarbon Drilling Fluids  

Science Journals Connector (OSTI)

We developed and patented a method using comprehensive two-dimensional gas chromatography (GC × GC) for accurate identification and quantification of drilling fluid olefins in crude oils. ... This scenario also explains the detection of drilling mud on oiled-DWH buoyancy module pieces, which would have been oiled from oil and drilling mud on the platform. ...

Christoph Aeppli; Christopher M. Reddy; Robert K. Nelson; Matthias Y. Kellermann; David L. Valentine

2013-06-25T23:59:59.000Z

335

Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank  

Broader source: Energy.gov (indexed) [DOE]

CMS to develop a membrane CMS to develop a membrane vapor processor that recovers fuel vapors from gasoline refueling with 99 percent efficiency. This membrane system enables gasoline stations to surpass environmental regulations while reducing fuel losses. Compact Membrane Systems, Inc. (CMS) was founded in 1993 in Wilmington, DE, with the acquisition of rights to certain DuPont polymer membrane patents. CMS focuses

336

Figure 1: Configuration of energy recovering system Modeling of an Electromechanical Energy Harvesting  

E-Print Network [OSTI]

of the system are integrated permanent magnets (PM) with the magnetic fields in opposition. This arrangement induction, v is the displacement's speed of permanent magnet, d is the displacement, pe is the coil position Fig.1, shows the detailed configuration of the proposed energy recovering system. In the central shaft

Paris-Sud XI, Université de

337

Biomass and Bioenergy 30 (2006) 316320 How to recover more value from small pine trees  

E-Print Network [OSTI]

Biomass and Bioenergy 30 (2006) 316­320 How to recover more value from small pine trees: Essential of residual biomass. To offset the cost of handling this low-value timber, additional marketing options States market for such products. However, less is known of the capability of essential oils extracted

338

Method to separate and recover oil and plastic from plastic contaminated with oil  

DOE Patents [OSTI]

The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in a liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic. 3 figs.

Smith, H.M.; Bohnert, G.W.; Olson, R.B.; Hand, T.E.

1998-01-27T23:59:59.000Z

339

Recovering lithium chloride from a geothermal brine. Report of investigations/1984  

SciTech Connect (OSTI)

The Bureau of Mines has devised techniques to recover lithium from geothermal brines as the chloride. More than 99 pct of the lithium was precipitated from a brine containing 170 mg/L Li by adding a solution of A1C13 and increasing the pH to 7.5 with lime slurry. The Li-Al precipitate was dissolved in HCl and sparged with gaseous HC1 to recover the A1C13; this resulted in a solution containing LiCl and CaC12. The solution was evaporated at 100C to obtain a mixture of the chlorides from which 97 pct of the lithium was recovered and 90 pct of the calcium was rejected by leaching with tetrahydrofuran. The LiC1 recovered by evaporation of the tetrahydrofuran was purified by dissolution in water and treatment with oxalic acid. The final LiC1 solution contained 89 pct of the lithium originally present in the brine and had a purity of 99.9 pct.

Schultze, L.E.; Bauer, D.J.

1984-01-01T23:59:59.000Z

340

INTRODUCTION Animals have long been known to store and recover energy in the  

E-Print Network [OSTI]

687 INTRODUCTION Animals have long been known to store and recover energy in the elastic structures substrates, the external environment represents another potentially useful energy store (see Alexander, 1995; Demes et al., 1995). Indeed, recent studies have shown that orangutans utilise the slow sway of tree

D'Août, Kristiaan

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A Business Process Explorer: Recovering and Visualizing E-Commerce Business Processes  

E-Print Network [OSTI]

A business process is composed of a set of interrelated tasks which are joined together by control flowA Business Process Explorer: Recovering and Visualizing E-Commerce Business Processes Jin Guo1 guojin@cs.queensu.ca 3kcdf@qlink.queensu.ca {4lb3, ying.zou}@queensu.ca ABSTRACT A business process

Zou, Ying

342

Recovering the 3D structure of tubular objects from stereo silhouettes  

Science Journals Connector (OSTI)

Although silhouette-based image understanding is attractive from an engineering viewpoint, recovering 3D shape from a single stereo pair of silhouette images of a generic multiple-object scene is a highly underconstrained problem. With respect to a gray-level-based ... Keywords: 3D reconstruction, Generalized cylinder, Model estimation, Silhouettes, Stereo

Aldo Cumani; Antonio Guiducci

1997-07-01T23:59:59.000Z

343

Reducing effluent discharge and recovering bioenergy in an osmotic microbial fuel cell treating domestic wastewater  

E-Print Network [OSTI]

domestic wastewater Zheng Ge, Qingyun Ping, Li Xiao, Zhen He Department of Civil Engineering and Mechanics cell is developed to treat domestic wastewater. Wastewater effluent can be greatly reduced due to osmotic water extraction. Bioenergy recovered from wastewater can potentially support pumping system

344

Wolf: A tool to recover dataflow oriented designs of software systems Arun Lakhotia  

E-Print Network [OSTI]

. It is developed using Reasoning System's Software Refinery and Mark V's Ob- jectMaker CASE-Tool Products and can recover designs for C programs. The dataflow designs are extracted using Software Refinery and displayed possible due to using Software Refinery's generic control flow graph abstractions for performing dataflow

Lakhotia, Arun

345

Method to separate and recover oil and plastic from plastic contaminated with oil  

DOE Patents [OSTI]

The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in as liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic.

Smith, Henry M. (Overland Park, KS); Bohnert, George W. (Harrisonville, MO); Olson, Ronald B. (Kansas City, MO); Hand, Thomas E. (Lee's Summit, MO)

1998-01-27T23:59:59.000Z

346

Emission of polycyclic aromatic hydrocarbons in China  

SciTech Connect (OSTI)

Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-02-01T23:59:59.000Z

347

Rock types, pore types, and hydrocarbon exploration  

SciTech Connect (OSTI)

A proposed exploration-oriented method of classifying porosity in sedimentary rocks is based on microscopic examination cores or cuttings. Factors include geometry, size, abundance, and connectivity of the pores. The porosity classification is predictive of key petrophysical characteristics: porosity-permeability relationships, capillary pressures, and (less certainly) relative permeabilities. For instance, intercrystalline macroporosity typically is associated with high permeability for a given porosity, low capillarity, and favorable relative permeabilities. This is found to be true whether this porosity type occurs in a sucrosic dolomite or in a sandstone with pervasive quartz overgrowths. This predictive method was applied in three Rocky Mountain oil plays. Subtle pore throat traps could be recognized in the J sandstone (Cretaceous) in the Denver basin of Colorado by means of porosity permeability plotting. Variations in hydrocarbon productivity from a Teapot Formation (Cretaceous) field in the Powder River basin of Wyoming were related to porosity types and microfacies; the relationships were applied to exploration. Rock and porosity typing in the Red River Formation (Ordovician) reconciled apparent inconsistencies between drill-stem test, log, and mud-log data from a Williston basin wildcat. The well was reevaluated and completed successfully, resulting in a new field discovery. In each of these three examples, petrophysics was fundamental for proper evaluation of wildcat wells and exploration plays.

Coalson, E.B.; Hartmann, D.J.; Thomas, J.B.

1985-05-01T23:59:59.000Z

348

A preliminary evaluation model for reservoir hydrocarbon-generating potential established based on dissolved hydrocarbons in oilfield water  

Science Journals Connector (OSTI)

A large number of oilfield water samples were analyzed in this work. Research ... relationship between the concentrations and distribution of dissolved hydrocarbons suggested that the contents and composition of ...

Hongjing Zhao; Weilin Sun; Baotian He; Bowen Mei…

2006-01-01T23:59:59.000Z

349

Solid Recovered Fuel: Materials Flow Analysis and Fuel Property Development during the Mechanical Processing of Biodried Waste  

Science Journals Connector (OSTI)

This diagram shows the flow of actual mass from which it is useful to recover energy. ... The utilization of solid recovered fuels (SRF) for energy recovery has been increasing steadily in recent years, and this development is set to continue. ... To date, Korea has used four species of solid recovered fuels (SRFs) which have been certified by the Environmental Ministry of Korea: refuse-derived fuel (RDF), refused plastic fuel (RPF), tyre-derived fuel (TDF), and wood chip fuel (WCF). ...

Costas A. Velis; Stuart Wagland; Phil Longhurst; Bryce Robson; Keith Sinfield; Stephen Wise; Simon Pollard

2013-02-11T23:59:59.000Z

350

Field evaluation of the availability for corn and soybean of phosphorus recovered as struvite from corn fiber processing for bioenergy.  

E-Print Network [OSTI]

??FIELD EVALUATION OF THE AVAILABILITY FOR CORN AND SOYBEAN OF PHOSPHORUS RECOVERED AS STRUVITE FROM CORN FIBER PROCESSING FOR BIOENERGY A paper to be submitted… (more)

Thompson, Louis Bernard

2013-01-01T23:59:59.000Z

351

Kidney cancer and hydrocarbon exposures among petroleum refinery workers  

SciTech Connect (OSTI)

To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

Poole, C.; Dreyer, N.A.; Satterfield, M.H. [Epidemiology Resources Inc., Newton Lower Falls, MA (United States); Levin, L. [Drexel Univ., Philadelphia, PA (United States)

1993-12-01T23:59:59.000Z

352

Design process of LNG heavy hydrocarbons fractionation: Low LNG temperature recovery  

Science Journals Connector (OSTI)

Abstract The liquefied natural gas (LNG) includes light hydrocarbons heavier than methane, such as ethane, propane and butane, which not only may increase the calorific values of the natural gas beyond specification limits, but also may have greater market values. During the gasification of the LNG, the energy invested in it during liquefaction process may be recovered and re-used. This paper relates to two regasification processes for separating natural gas liquids from liquefied natural gas using the low LNG temperature to produce natural gas meeting pipeline or other commercial specifications. From the two processes studied, the fractionated methane-rich stream is pressurized to pipeline pressure by pumps instead of compressors and the liquefied ethane, propane and butane are obtained directly at atmospheric pressure. Among the processes studied, the low pressure process sounds economically attractive with a saving in TAC of 4.6% over the high pressure process; however the high pressure process is more preferable for the cases where the space is limited.

Hosanna Uwitonze; Sangil Han; Choi Jangryeok; Kyu Suk Hwang

2014-01-01T23:59:59.000Z

353

In Situ Hydrocarbon Degradation by Indigenous Nearshore Bacterial Populations  

SciTech Connect (OSTI)

Potential episodic hydrocarbon inputs associated with oil mining and transportation together with chronic introduction of hydrocarbons via urban runoff into the relatively pristine coastal Florida waters poses a significant threat to Florida's fragile marine environment. It is therefore important to understand the extent to which indigenous bacterial populations are able to degrade hydrocarbon compounds and also determine factors that could potentially control and promote the rate at which these compounds are broken down in situ. Previous controlled laboratory experiments carried out by our research group demonstrated that separately both photo-oxidation and cometabolism stimulate bacterial hydrocarbon degradation by natural bacterial assemblages collected from a chronically petroleum contaminated site in Bayboro Bay, Florida. Additionally, we also demonstrated that stable carbon and radiocarbon abundances of respired CO{sub 2} could be used to trace in situ hydrocarbon degradation by indigenous bacterial populations at this same site. This current proposal had two main objectives: (a) to evaluate the cumulative impact of cometabolism and photo-oxidation on hydrocarbon degradation by natural bacterial assemblages collected the same site in Bayboro Bay, Florida and (b) to determine if in situ hydrocarbon degradation by indigenous bacterial populations this site could be traced using natural radiocarbon and stable carbon abundances of assimilated bacterial carbon. Funds were used for 2 years of full support for one ESI Ph.D. student, April Croxton. To address our first objective a series of closed system bacterial incubations were carried out using photo-oxidized petroleum and pinfish (i.e. cometabolite). Bacterial production of CO{sub 2} was used as the indicator of hydrocarbon degradation and {delta}{sup 13}C analysis of the resultant CO{sub 2} was used to evaluate the source of the respired CO{sub 2} (i.e. petroleum hydrocarbons or the pinfish cometabolite). Results from these time series experiments demonstrated that short-term exposure of petroleum to UV light enhanced hydrocarbon degradation by 48% over that observed for non-photo-oxidized petroleum. Despite the greater bio-availability of the photo-oxidized over the non-photo-oxidized petroleum, an initial lag in CO{sub 2} production was observed indicating potential phototoxicity of the photo- by-products. {delta}{sup 13}C analysis and mass balance calculations reveal that co-metabolism with pinfish resulted in increased hydrocarbon degradation for both photo-oxidized and non-photo-oxidized petroleum each by over 100%. These results demonstrate the cumulative effect of photo-oxidation and co-metabolism on petroleum hydrocarbon degradation by natural bacterial populations indigenous to systems chronically impacted by hydrocarbon input. To address the second objective of this proposal bacterial concentrates were collected from Bayboro Harbor in April 2001 for nucleic acid extraction and subsequent natural radiocarbon abundance analyses. Unfortunately, however, all of these samples were lost due to a faulty compressor in our -70 freezer. The freezer was subsequently repaired and samples were again collected from Bayboro Harbor in June 2002 and again December 2002. Several attempts were made to extract the nucleic acid samples--however, the student was not able to successfully extract and an adequate amount of uncontaminated nucleic acid samples for subsequent natural radiocarbon abundance measurements of the bacterial carbon by accelerator mass spectrometry (i.e. require at least 50 {micro}g carbon for AMS measurement). Consequently, we were not able to address the second objective of this proposed work.

Cherrier, J.

2005-05-16T23:59:59.000Z

354

NETL: News Release - New Projects to Study Ways to Recover Vast Quantities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

March 12, 2002 March 12, 2002 New Projects to Study Ways to Recover Vast Quantities of "Left Behind" Oil TULSA, OK - Nearly two out of every three barrels of oil discovered in the United States remain trapped underground after conventional recovery operations. This staggering amount of remaining oil - approximately 200 billion barrels - can be one of America's best hopes for greater energy security if new technologies can be developed to recover it. Often, however, the "left behind" oil is in regions of the reservoir that are difficult to access and the oil is held tightly in place within tiny rock pores by capillary pressures that resist many traditional oil production practices. Now, as part of its program to develop ways to free this unrecovered oil, the Department of Energy's Fossil Energy research program is adding three new projects to be carried out by three of the Nation's top petroleum engineering universities:

355

Industrial recovered-materials-utilization targets for the metals and metal-products industry  

SciTech Connect (OSTI)

The National Energy Conservation Policy Act of 1978 directs DOE to set targets for increased utilization of energy-saving recovered materials for certain industries. These targets are to be established at levels representing the maximum feasible increase in utilization of recovered materials that can be achieved progressively by January 1, 1987 and is consistent with technical and economic factors. A benefit to be derived from the increased use of recoverable materials is in energy savings, as state in the Act. Therefore, emhasis on different industries in the metals sector has been related to their energy consumption. The ferrous industry (iron and steel, ferrour foundries and ferralloys), as defined here, accounts for approximately 3%, and all others for the remaining 3%. Energy consumed in the lead and zinc segments is less than 1% each. Emphasis is placed on the ferrous scrap users, followed by the aluminum and copper industries. A bibliography with 209 citations is included.

None

1980-03-01T23:59:59.000Z

356

Preliminary assessment of hydrocarbon potential in southern Illinois  

SciTech Connect (OSTI)

Hydrocarbon exploration has been sparse south of the Cottage Grove fault system in southern Illinois. Over 240,000 ac in this area are within the Shawnee National Forest (SNF). Upcoming review of mineral exploration policy on SNF land and a recent amendment to the Mineral Leasing Act (1987) will result in release of portions of the SNF for competitive and potentially noncompetitive bidding for mineral exploration tracts in the near future. Preliminary assessment of hydrocarbon potential has been carried out in southern Illinois. Numerous oil shows occur in Paleozoic strata south of the Cottage Grove fault system, which, at present, describes the southern boundary of most oil production in Illinois. Only Mitchellsville oil field in southern Saline County lies south of the Cottage Grove fault system. The Upper Devonian New Albany Shale, though to be the primary source rock for Illinois basin hydrocarbons, underlies most of the area. Older potential source rocks may be present. Depositional trends of prolific oil-productive Mississippian strata in Illinois continue southward through the area. Few drill holes have tested strata older than Mississippian in the area. Complex faulting in the Rough Creek-Shawneetown fault system may have improved the potential for hydrocarbon emplacement and entrapment in this region. Preliminary assessment of hydrocarbon potential indicates that this wildcat region deserves further tests.

Crockett, J.E.; Oltz, D.F. (Illinois State Geological Survey, Champaign (USA))

1989-08-01T23:59:59.000Z

357

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect (OSTI)

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

358

Determination of Polycyclic Aromatic Hydrocarbons in Fresh Milk by Hollow Fiber Liquid-Phase Microextraction–Gas Chromatography Mass Spectrometry  

Science Journals Connector (OSTI)

......Polycyclic Aromatic Hydrocarbons in Fresh Milk by...polycyclic aromatic hydrocarbons (PAHs) in fresh...more volatile and heat sensitive. The...Polycyclic aromatic hydrocarbons (PAHs) are compounds...the incomplete combustion of carbon-containing...respectively. Data were collected......

Mohd Marsin Sanagi; Saw Hong Loh; Wan Aini Wan Ibrahim; Mohamed Noor Hasan; Hassan Y. Aboul Enein

2013-02-01T23:59:59.000Z

359

Hepatic coenzyme Q redox balance of fishes as a potential bioindicator of environmental contamination by polycyclic aromatic hydrocarbons  

Science Journals Connector (OSTI)

...at the land-water interface are...polycyclic aromatic hydrocarbon (PAH) contamination...Markers 0 Polycyclic Hydrocarbons, Aromatic 0 Water Pollutants, Chemical...metabolism Polycyclic Hydrocarbons, Aromatic toxicity...Ubiquinone metabolism Water Pollutants, Chemical...

2011-01-01T23:59:59.000Z

360

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents [OSTI]

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents [OSTI]

A chemical reactor for oxygenating hydrocarbons includes: (a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; (b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; (c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and (d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed. 4 figs.

Kong, P.C.; Lessing, P.A.

1995-06-27T23:59:59.000Z

362

Hydrocarbon composition of crude oil from Lam Bank  

SciTech Connect (OSTI)

The authors discuss the crude oil from a new offshore field called the Lam Bank in the Caspian Sea. A segregated commercial crude was distilled and the distillation data is shown. In order to determine the content of n-paraffins, the naphthenic-paraffinic part of the narrow cuts was subjected to adsorptive separation on CaA zeolite. Owing to the high contents of naphthenic and isoparaffinic hydrocarbons and the low content of aromatic hydrocarbons in the distillate part, this crude can be used to produce high-quality fuels and oils by the use of the dewaxing processes.

Samedova, F.I.; Agaeva, R.M.; Alieva, F.Z.; Valiev, M.A.

1987-07-01T23:59:59.000Z

363

Method for determining processability of a hydrocarbon containing feedstock  

SciTech Connect (OSTI)

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

Schabron, John F.; Rovani, Jr., Joseph F.

2013-09-10T23:59:59.000Z

364

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents [OSTI]

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

365

Isoconversional Kinetic Analysis of the Combustion of Heavy Hydrocarbons  

Science Journals Connector (OSTI)

One method to access unconventional, heavy-oil resources as well as waterflood residual oil is to apply in situ combustion (ISC) to oxidize in place a small fraction of the hydrocarbon, thereby providing heat to reduce oil viscosity and pressure that enhances recovery. ... As shown by Vyazovkin,(12) these deviations of temperature yield erroneous values of activation energy, when such a data set is used with a model that assumes linear heating. ... Estimates were made of the heat produced, and a formula was derived for computing the heat of combustion of hydrocarbons in the high-temp. ...

Murat Cinar; Louis M. Castanier; Anthony R. Kovscek

2009-07-06T23:59:59.000Z

366

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq  

E-Print Network [OSTI]

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon after the methane flames, respectively. Three-layer, feed- forward type artificial neural networks rights reserved. Keywords: Soot; Hydrocarbon flames; Artificial neural networks 1. Introduction

Senkan, Selim M.

367

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

20 May 1975 research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion] E...have been made of their fate in mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...

1975-01-01T23:59:59.000Z

368

Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels  

Broader source: Energy.gov [DOE]

Syngas upgrading to hydrocarbon fuels is one of eight priority pathways chosen to convert biomass into hydrocarbon fuels by the Bioenergy Technologies Office. These pathways were down-selected from an initial list of 18.

369

Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina*  

E-Print Network [OSTI]

1/28 Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina* , P of the heat transfer dynamics. Finally, the combustion mechanism is applied and validated experimentally for kerosene pyrolysis application. Keywords Regenerative cooling; Hydrocarbon pyrolysis; Supersonic Combustion

Boyer, Edmond

370

The Energies of the Atomic Linkages in the Normal Paraffin Hydrocarbons  

Science Journals Connector (OSTI)

...normal paraffin hydrocarbons, in the gaseous...values for the heats of combustion of these gases...values for the heats of combustion of the hydrocarbon gases,4'5...Jessup4 on the heats of combustion of normal heptane...

Frederick D. Rossini

1934-01-01T23:59:59.000Z

371

E-Print Network 3.0 - aromatic hydrocarbons molecular Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... ,b, Seong Gyu Seo,c and Sang-Chai Kim d a Department of Molecular Science and...

372

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

373

Vibration Spectra of Hydrocarbon Molecules. II. Skeletal Frequencies in Certain Branched Paraffins  

Science Journals Connector (OSTI)

25 October 1949 research-article Vibration Spectra of Hydrocarbon Molecules. II...characteristic frequencies should be assigned as vibrations of the carbon skeleton of these structural...problem of the interpretation of the vibration spectra of hydrocarbons is considered...

1949-01-01T23:59:59.000Z

374

Environmental and Transport Effects on Core Measurements of Water Saturation, Salinity, Wettability, and Hydrocarbon Composition  

E-Print Network [OSTI]

and core surfacing operations can significantly alter the water saturation, salinity, hydrocarbon measurements of water saturation, salinity, hydrocarbon composition, and wettability are critical for accurateSPE 166154 Environmental and Transport Effects on Core Measurements of Water Saturation, Salinity

Torres-Verdín, Carlos

375

Light hydrocarbons in the surface water of the mid-Atlantic  

Science Journals Connector (OSTI)

During a cruise of RV Polarstern over the Atlantic in September/October 1988, C2?C4 hydrocarbons were measured in surface sea water. The ship passed through three different ocean ... at 8° N and 3° S. Hydrocarbon

C. Plass; R. Koppmann; J. Rudolph

1992-11-01T23:59:59.000Z

376

The effect of alkaline additives on the performance of surfactant systems designed to recover light oils  

SciTech Connect (OSTI)

Surfactant flooding is flexible because of the ability to optimize formulations for a wide range of reservoir conditions and crude oil types. The objective for this work was to determine if the addition of alkaline additives will allow the design of surfactant formulations that are effective for the recovery of crude oil, while, at the same time, maintaining the surfactant concentration at a much lower level than has previously been used for micellar flooding. Specifically, the focus of the work was on light, midcontinent crudes that typically have very low acid contents. These oils are typical of much of the midcontinent resource. The positive effect of alkaline additives on the phase behavior of the surfactant formulations and acidic crude oils is well known. The extension to nonacidic and slightly acidic oils is not obvious. Three crude oils, a variety of commercial surfactants, and several alkaline additives were tested. The oils had acid numbers that ranged from 0.13, which is quite low, to less than 0.01 mg KOH/g of oil. Alkaline additives were found to be very effective in recovering Delaware-Childers (OK) oil at elevated temperatures, but much less effective at reservoir temperatures. Alkaline additives were very effective with Teapot Dome (WY) oil. With Teapot Dome oil, surfactant/alkali systems produced ultralow IFT values and recovered 60% of the residual oil that remained after waterflooding. The effect of alkaline additives on recovering Hepler (KS) oil was minimal. The results of this work indicate that alkaline additives do have merit for use in surfactant flooding of low acid crude oils; however, no universal statement about applicability can be made. Each oil behaves differently, with this treatment, and the effect of alkaline additives must be determined (at reservoir conditions) for each oil. 23 refs., 13 figs., 3 tabs.

French, T.R.; Josephson, C.B.; Evans, D.B.

1991-02-01T23:59:59.000Z

377

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS  

E-Print Network [OSTI]

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS ROBERT C. CLARK, JR., AND JOHN S. FINLEY' ABSTRACT Petroleum paraffin hydrocarbons (n-CI4H30 to n-C37H76 system that simulated tides. The mussels were exposed to levels of petroleum hydrocarbons from a surface

378

A 4D Synchrotron X-Ray-Tomography Study of the Formation of Hydrocarbon-  

E-Print Network [OSTI]

hydrocarbons and the growing production of hydrocarbons from low-permeability tight rocks. Quantitative models, University of Oslo, Idaho National Laboratory, and Institute for Energy Technology Summary Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes

Mazzini, Adriano

379

The Interaction of Carcinogenic Hydrocarbons with Tissues VII. Fractionation of Mouse Skin Proteins  

Science Journals Connector (OSTI)

...Inferaction of Hydrocarbons with Tissues. VII...separation of the water- soluble proteins...in Chart 1, and water-soluble proteins...Interaction of Hydrocarbons with Tissues. VII...noncarcinogenic hydrocarbons could be detected...electrophoretic separation of water-soluble proteins...

G. Rodman Davenport; C. W. Abell; and Charles Heidelberger

1961-06-01T23:59:59.000Z

380

Male-derived cuticular hydrocarbons signal sperm competition intensity and affect ejaculate expenditure in crickets  

Science Journals Connector (OSTI)

...taxa has shown that cuticular hydrocarbons (CHCs), contact pheromones...They were supplied with water and fed cat food ad libitum...between-family variation in male hydrocarbon profiles (Thomas Simmons...variation within the blends of hydrocarbons in this experiment, male...

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Heritable Genetic Changes in Cells Recovered From Irradiated 3D Tissue Constructs  

SciTech Connect (OSTI)

Combining contemporary cytogenetic methods with DNA CGH microarray technology and chromosome flow-sorting increases substantially the ability to resolve exchange breakpoints associated with interstitial deletions and translocations, allowing the consequences of radiation damage to be directly measured at low doses, while also providing valuable insights into molecular mechanisms of misrepair processes that, in turn, identify appropriate biophysical models of risk at low doses. Specific aims apply to cells recovered from 3D tissue constructs of human skin and, for the purpose of comparison, the same cells irradiated in traditional 2D cultures. The project includes research complementary to NASA/HRP space radiation project.

Michael Cornforth

2012-03-26T23:59:59.000Z

382

Recovering corn germ enriched in recombinant protein by wet-fractionation  

Science Journals Connector (OSTI)

Corn wet-fractionation processes (quick-germ fractionation and traditional wet milling) were evaluated as means of recovering fractions rich in recombinant collagen-related proteins that were targeted for expression in the germ (embryo) of transgenic corn. Transgenic corn lines accumulating a recombinant full-length human collagen type-I-alpha-1 (full-length rCI?1) or a 44-kDa rCI?1 fragment targeted for seed expression with an embryo-specific promoter were used. Factors to consider in efficient recovery processes are the distribution of the peptides among botanical parts and process recovery efficiency. Both recombinant proteins were distributed 62–64% in germ comprising about 8.6% of the dry grain mass; 34–38% in the endosperm comprising 84% of the dry grain mass; 1.7% in the pericarp comprising about 5% of the dry mass; and 1% in the tip-cap comprising 1.5–2% of the dry mass. The quick-germ method employed a short steeping period either in water or SO2–lactic acid solution followed by wet-milling degermination to recover a germ-rich fraction. Of the total recombinant protein expressed in germ, the quick-germ process recovered 40–43% of the total recombinant protein within 6–8% of the corn mass. The traditional corn wet-milling process produced higher purity germ but with lower recovery (24–26%) of the recombinant protein. The two quick-germ methods, using water alone or SO2–lactic acid steeping, did not substantially differ in rCI?1 recovery, and the quick-germ processes recovered germ with less leaching and proteolytic losses of the recombinant proteins than did traditional wet milling. Thus, grain fractionation enriched the recombinant proteins 6-fold higher than that of unfractionated kernels. Such enrichment may improve downstream processing efficiency and enable utilizing the protein-lean co-products to produce biofuels and biorenewable chemicals by fermenting the remaining starch-rich fractions.

Ilankovan Paraman; Steven R. Fox; Matthew T. Aspelund; Charles E. Glatz; Lawrence A. Johnson

2010-01-01T23:59:59.000Z

383

Message passing and moment closure for susceptible-infected-recovered epidemics on finite networks  

Science Journals Connector (OSTI)

The message passing approach of Karrer and Newman [Phys. Rev. E 82, 016101 (2010)] is an exact and practicable representation of susceptible-infected-recovered dynamics on finite trees. Here we show that, assuming Poisson contact processes, a pair-based moment-closure representation [Sharkey, J. Math. Biol. 57, 311 (2008)] can be derived from their equations. We extend the applicability of both representations and discuss their relative merits. On arbitrary time-independent networks, as was shown for the message passing formalism, the pair-based moment-closure equations also provide a rigorous lower bound on the expected number of susceptibles at all times.

Robert R. Wilkinson and Kieran J. Sharkey

2014-02-19T23:59:59.000Z

384

Speciation and Quantitation of Hydrocarbons in Gasoline Engine Exhaust  

Science Journals Connector (OSTI)

......laboratory engines or reactors. In this paper we...computer technology have advanced to the state where...2-1 m), and the heavy (C5 -C1 2 ) hydrocarbons...PLOT column with water or heavy hy drocarbons...technology to prevent water vapor from condensing...computer technology have advanced to the state where......

Keith L. Olson; Robert M. Sinkevitch; Thompson M. Sloane

1992-12-01T23:59:59.000Z

385

Hydrocarbon Condensation in Heavy-Duty Diesel Exhaust  

Science Journals Connector (OSTI)

Hydrocarbon Condensation in Heavy-Duty Diesel Exhaust ... The semivolatile mass fraction of diesel exhaust particles was studied using size-resolved on-line techniques (DMA-ELPI; TDMA-ELPI). ... The measured size resolved values of mass transfer imply that condensation, or diffusion-limited mass transfer, plays a major role in driving the volatile matter to the diesel exhaust particles. ...

Jyrki Ristimäki; Kati Vaaraslahti; Maija Lappi; Jorma Keskinen

2007-08-10T23:59:59.000Z

386

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...leaves and/or exposure to combustion products or formation of ash...analysis of the mainstream smoke chemistry of samples of the U.S. cigarette...comparison of the tumors induced by coal tar and benzo[a]pyrene...Spectrometry Ilex paraguariensis chemistry Polycyclic Hydrocarbons, Aromatic...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

387

Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection  

E-Print Network [OSTI]

data quality is good. This technique can be directly applied to the processed 2D and 3 D pre-stack/post-stack data sets (1) to detect hydrocarbon zones in both clastic and carbonate reservoirs by analyzing the low frequency signals in the decomposed...

Cai, Rui

2012-02-14T23:59:59.000Z

388

Chemical Kinetics of Hydrocarbon Ignition in Practical Combustion Systems  

SciTech Connect (OSTI)

Chemical kinetic factors of hydrocarbon oxidation are examined in a variety of ignition problems. Ignition is related to the presence of a dominant chain branching reaction mechanism that can drive a chemical system to completion in a very short period of time. Ignition in laboratory environments is studied for problems including shock tubes and rapid compression machines. Modeling of the laboratory systems are used to develop kinetic models that can be used to analyze ignition in practical systems. Two major chain branching regimes are identified, one consisting of high temperature ignition with a chain branching reaction mechanism based on the reaction between atomic hydrogen with molecular oxygen, and the second based on an intermediate temperature thermal decomposition of hydrogen peroxide. Kinetic models are then used to describe ignition in practical combustion environments, including detonations and pulse combustors for high temperature ignition, and engine knock and diesel ignition for intermediate temperature ignition. The final example of ignition in a practical environment is homogeneous charge, compression ignition (HCCI) which is shown to be a problem dominated by the kinetics intermediate temperature hydrocarbon ignition. Model results show why high hydrocarbon and CO emissions are inevitable in HCCI combustion. The conclusion of this study is that the kinetics of hydrocarbon ignition are actually quite simple, since only one or two elementary reactions are dominant. However, there are many combustion factors that can influence these two major reactions, and these are the features that vary from one practical system to another.

Westbrook, C.K.

2000-07-07T23:59:59.000Z

389

Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities  

E-Print Network [OSTI]

"The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant...

Ganji, A. R.; Hackett, B.; Chow, S.; Lonergan, R.; Wimer, J.

390

Fundamental spectroscopic studies of carbenes and hydrocarbon radicals  

SciTech Connect (OSTI)

Highly reactive carbenes and carbon-chain radicals are studied at millimeter wavelengths by observing their rotational spectra. The purpose is to provide definitive spectroscopic identification, accurate spectroscopic constants in the lowest vibrational states, and reliable structures of the key intermediates in reactions leading to aromatic hydrocarbons and soot particles in combustion.

Gottlieb, C.A.; Thaddeus, P. [Harvard Univ., Cambridge, MA (United States)

1993-12-01T23:59:59.000Z

391

Climatically driven emissions of hydrocarbons from marine sediments during deglaciation  

Science Journals Connector (OSTI)

...destabilizing hydrates shown in the lighter...destabilization of methane hydrates and release of...in SBC suggest gas emissions during...investigate the sand-sized fraction...the presence of sand layers (23...hydrocarbons and methane hydrate, which is widely...4) (24). Gas hydrates commonly...

T. M. Hill; J. P. Kennett; D. L. Valentine; Z. Yang; C. M. Reddy; R. K. Nelson; R. J. Behl; C. Robert; L. Beaufort

2006-01-01T23:59:59.000Z

392

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network [OSTI]

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

393

Hydrocarbon saturation determination using acoustic velocities obtained through casing  

DOE Patents [OSTI]

Compressional and shear velocities of earth formations are measured through casing. The determined compressional and shear velocities are used in a two component mixing model to provides improved quantitative values for the solid, the dry frame, and the pore compressibility. These are used in determination of hydrocarbon saturation.

Moos, Daniel (Houston, TX)

2010-03-09T23:59:59.000Z

394

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network [OSTI]

THERMOCATALYTIC CO2- FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS N. Muradov Florida Solar Energy Center 1679 Clearlake Road, Cocoa, Florida 32922 tel. 321-638-1448, fax. 321-638-1010, muradov (except for the start-up operation). This results in the following advantages: (1) no CO/CO2 byproducts

395

Biodegradation of total petroleum hydrocarbon (TPH) in Jordanian petroleum sludge  

Science Journals Connector (OSTI)

Bioremediation, or the use of micro-organisms to decontaminate soil or groundwater, is being increasingly seen as an effective, environment-friendly treatment for oil-contaminated sites. In this study, the results are presented concerning a laboratory screening of several natural bacterial consortia and laboratory tests to establish the performance in degradation of hydrocarbons contained in oily sludge from the Jordan Oil Refinery Plant. As a result of the laboratory screening, 18 isolates were selected and grouped into two main clusters; cluster 1 containing 12 isolates grown at 43°C, and cluster 2 containing six isolates grown at 37°C. Three natural bacterial consortia with ability to degrade total petroleum hydrocarbons (TPH) were prepared from these isolates. Experiments were conducted in Erlenmeyer flasks under aerobic conditions, with TPH removal percentage varying from 5.9% to 25.1%, depending upon consortia type and concentration. Consortia 7B and 13B exhibited the highest TPH removal percentages of 25% and 23%, respectively before nutrient addition. TPH removal rate was enhanced after addition of nutrients to incubated flasks. The highest TPH reduction (37%) was estimated after addition of a combination of nitrogen, phosphorus and sulphur to consortia 7B. This is the first report concerning biological treatment of total petroleum hydrocarbon by bacteria isolated from the oil refinery plant, where it lay the ground for full integrated studies recommended for hydrocarbon degradation that assist in solving sludge problems.

Bassam Mrayyan; Mohammad Battikhi

2004-01-01T23:59:59.000Z

396

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...succession that causes the shales to reach thermal maturity and generate hydrocarbons. Simple...T. J. 1988 Rift basins of interior Sudan--petroleum exploration and discovery...basins? Is that what we could call the thermal subsidence phase? J. J. Lambiase...

1999-01-01T23:59:59.000Z

397

Application of Resource-Ratio Theory to Hydrocarbon Biodegradation  

Science Journals Connector (OSTI)

Application of Resource-Ratio Theory to Hydrocarbon Biodegradation ... We suggest that the procedures outlined here can be used to help guide practical decisions about the nutrients that are most likely to be growth-limiting and help define the subsequent nutrient application rates. ...

Val H. Smith; David W. Graham; Dale D. Cleland

1998-09-12T23:59:59.000Z

398

Theoretical studies of hydrocarbon combustion chemistry. Annual progress report  

SciTech Connect (OSTI)

The author reports here the results of DZP CISD calculations for methylcarbene. Geometry, symmetry, and vibrational modes for the radical are reported for both the singlet and the triplet state. Future work will focus on the ethyl radical-oxygen interaction relevant to hydrocarbon combustion.

Schaefer, H.F. III

1994-08-01T23:59:59.000Z

399

FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY  

E-Print Network [OSTI]

photolysis of these ices produces a host of new compounds, some of which show intriguing prebiotic behavior1 FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY LOUIS J. ALLAMANDOLA, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon

400

Reclamation and groundwater remediation at a hydrocarbon site in Alaska  

SciTech Connect (OSTI)

As part of a joint hydrocarbon cleanup project between Unocal and Marathon, we have initiated the use of constructed wetlands for restoration of the 40-acre Poppy Lane gravel pit located near Kenai, Alaska. Gravel excavated from this site was used to construct roads and drilling pads in the 1960`-70`s. During this period it was also used as a refuse dump for waste from the Kenai gas field and from local residents. The bulk wastes were removed and pockets of oily sand were removed, treated and returned to a stockpile on the site. This left the site with residual pockets of hydrocarbon-impacted sand (<1000 TPH) plus traces of hydrocarbon contamination in the uppermost shallow groundwater flowing through the outwash gravels. The final part of the cleanup will be land restoration and bioremediation of the final traces of hydrocarbons, which are predominantly diesel-range. High resolution gas chromatography analysis indicated that common plants already growing on the site (willow, cottonwood, and alder) did not concentrate diesel-range petroleum hydrocarbons in their foliage when growing in soils containing these contaminants. As part of the planned restoration and shallow groundwater remediation, two 1/3 acre test plots were constructed to promote in-situ biodegradation processes. In spring 1995, the first test, a tree root-barrier plot, was planted with dormant cuttings of four native wetland tree and shrub species, which were planted to depths up to five feet. Alder and elderberry did not succeed under any conditions, nor did any species planted in standing water. For cottonwood and willow species, approximately one half of each rooted and survived. When the water table dropped the second year, the willow cuttings rooted deeper in the vadose zone, while cottonwood did not. As a result of these findings, a tree root-barrier wetland is not considered to be a viable option for groundwater treatment at Poppy Lane.

Ririe, G.T. [Unocal, Brea, CA (United States); Drake, L.D. [Univ. of Iowa, Iowa City, IA (United States); Olson, S.S. [Marathon Oil, Tyler, TX (United States)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Process for using alkyl substituted C8-C10 aromatic hydrocarbons as preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect (OSTI)

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream. The improvement consists of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent which provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100% which comprises: A. selectively extracting and stripping the hydrocarbon gas stream with the physical solvent to produce a residue hydrocarbon gas stream of pipeline specifications and a rich solvent stream containing ethane and heavier hydrocarbon components, the preferential physical solvent being: (1) rich in C/sub 8/-C/sub 10/ aromatic compounds having methyl, ethyl, or propyl aliphatic groups and (2) selective for ethane and heavier hydrocarbon components of the gas stream such that: (a) the relative volatility of methane over ethane is at least 5.0 and the hydrocarbon loading capacity, defined as solubility of ethane in solvent, is at least 0.25 standard cubic feet of ethane per gallon of solvent, or (b) the preferential factor determined by the multiplication of relative volatility of methane over ethane by the solubility of ethane in solvent, in standard cubic feet of ethane per gallon of solvent, of at least 1.25; and B. distilling the rich solvent to produce the hydrocarbon gas liquids and the physical solvent.

Mehra, Y.R.

1987-09-08T23:59:59.000Z

402

A study of the pyrolysis behaviors of pelletized recovered municipal solid waste fuels  

Science Journals Connector (OSTI)

Pelletized recovered solid waste fuel is often applied in gasification systems to provide feedstock with a stabilized quality and high heating value and to avoid the bridging behavior caused by high moisture content, low particle density, and irregular particle size. However, the swelling properties and the sticky material generated from pyrolysis of the plastic group components also tend to trigger bridging in the retorting zone. It is well known that the plastic group materials, which occupy a considerable proportion of municipal solid waste, can melt together easily even under low temperature. This study investigates the pyrolysis behaviors of typical recovered solid waste pellets, including the devolatilization rate, heat transfer properties, char properties, and swelling/shrinkage properties, in a small fixed-bed facility over a wide temperature range, from 900 °C to 450 °C. The results are also compared with those from wheat straw pellets, a typical cellulosic fuel. Moreover, the SEM images and BET analysis of the char structure are further analyzed to provide additional explanation for the mechanisms of swelling/shrinkage phenomena observed during heating.

Chunguang Zhou; Qinglin Zhang; Leonie Arnold; Weihong Yang; Wlodzimierz Blasiak

2013-01-01T23:59:59.000Z

403

Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust  

DOE Patents [OSTI]

A process for recovering zinc-rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered by distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10 C, separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream. 1 figure.

Zaromb, S.; Lawson, D.B.

1994-02-15T23:59:59.000Z

404

Interaction of Carcinogenic Hydrocarbons with Tissues: VIII. Binding of Tritium-labeled Hydrocarbons to the Soluble Proteins of Mouse Skin  

Science Journals Connector (OSTI)

...treated as described in "Materials and Methods." A demonstration...of the unbound radio active hydrocarbon was removed...migrated toward the cathode, a neutral in dicator...pro teins toward the cathode was affected by electro...dermis as described in "Materials and Methods." The...

C. W. Abell and Charles Heidelberger

1962-09-01T23:59:59.000Z

405

Cellulosic materials recovered from steam classified municipal solid wastes as feedstocks for conversion to fuels and chemicals  

Science Journals Connector (OSTI)

A process has been developed for the treatment of municipal solid waste to separate and recover the cellulosic biomass from the nonbiomass components. ... highly suitable as a feedstock for conversion to fuel, fe...

Michael H. Eley; Gerald R. Guinn; Joyita Bagchi

1995-09-01T23:59:59.000Z

406

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Natural Gas Plant Net Stocks Natural Gas Plant Net Stocks Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Butylene (C4H8) An olefinic hydrocarbon recovered from refinery processes. Ethane (C2H6) A normally gaseous straight-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of -127.48º F. It is extracted from natural gas and refinery gas streams. Isobutane (C4H10) A normally gaseous branch-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of 10.9º F. It is extracted from natural gas or refinery gas streams. Liquefied Petroleum Gases (LPG) A group of hydrocarbon-based gases derived from crude oil refining or nautral gas fractionation. They include: ethane, ethylene, propane, propylene, normal butane, butylene, isobutane, and isobutylene. For convenience of transportation, these gases are liquefied through pressurization.

407

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Plant Field Production Plant Field Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Butylene (C4H8) An olefinic hydrocarbon recovered from refinery processes. Ethane (C2H6) A normally gaseous straight-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of -127.48º F. It is extracted from natural gas and refinery gas streams. Field Production Represents crude oil production on leases, natural gas liquids production at natural gas processing plants, new supply of other hydrocarbons/oxygenates and motor gasoline blending components, and fuel ethanol blended into finished motor gasoline. Isobutane (C4H10) A normally gaseous branch-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of 10.9º F. It is extracted from natural gas or refinery gas streams.

408

CAPABILITY TO RECOVER PLUTONIUM-238 IN H-CANYON/HB-LINE  

SciTech Connect (OSTI)

Plutonium-238 is used in Radioisotope Thermoelectric Generators (RTGs) to generate electrical power and in Radioisotope Heater Units (RHUs) to produce heat for electronics and environmental control for deep space missions. The domestic supply of Pu-238 consists of scrap material from previous mission production or material purchased from Russia. Currently, the United States has no significant production scale operational capability to produce and separate new Pu-238 from irradiated neptunium-237 targets. The Department of Energy - Nuclear Energy is currently evaluating and developing plans to reconstitute the United States capability to produce Pu-238 from irradiated Np-237 targets. The Savannah River Site had previously produced and/or processed all the Pu-238 utilized in Radioisotope Thermoelectric Generators (RTGs) for deep space missions up to and including the majority of the plutonium for the Cassini Mission. The previous full production cycle capabilities included: Np-237 target fabrication, target irradiation, target dissolution and Np-237 and Pu-238 separation and purification, conversion of Np-237 and Pu-238 to oxide, scrap recovery, and Pu-238 encapsulation. The capability and equipment still exist and could be revitalized or put back into service to recover and purify Pu-238/Np-237 or broken General Purpose Heat Source (GPHS) pellets utilizing existing process equipment in HB-Line Scrap Recovery, and H-anyon Frame Waste Recovery processes. The conversion of Np-237 and Pu-238 to oxide can be performed in the existing HB-Line Phase-2 and Phase-3 Processes. Dissolution of irradiated Np-237 target material, and separation and purification of Np-237 and Pu-238 product streams would be possible at production rates of ~ 2 kg/month of Pu-238 if the existing H-Canyon Frames Process spare equipment were re-installed. Previously, the primary H-Canyon Frames equipment was removed to be replaced: however, the replacement project was stopped. The spare equipment is stored and still available for installation. Out of specification Pu-238 scrap material can be purified and recovered by utilizing the HB-Line Phase-1 Scrap Recovery Line and the Phase-3 Pu-238 Oxide Conversion Line along with H-Canyon Frame Waste Recovery process. In addition, it also covers and describes utilizing the Phase-2 Np-237 Oxide Conversion Line, in conjunction with the H-Canyon Frames Process to restore the H-Canyon capability to process and recover Np-237 and Pu-238 from irradiated Np-237 targets and address potential synergies with other programs like recovery of Pu-244 and heavy isotopes of curium from other target material.

Fuller, K.; Smith, Robert H. Jr.; Goergen, Charles R.

2013-01-09T23:59:59.000Z

409

Capability to Recover Plutonium-238 in H-Canyon/HB-Line - 13248  

SciTech Connect (OSTI)

Plutonium-238 is used in Radioisotope Thermoelectric Generators (RTGs) to generate electrical power and in Radioisotope Heater Units (RHUs) to produce heat for electronics and environmental control for deep space missions. The domestic supply of Pu-238 consists of scrap material from previous mission production or material purchased from Russia. Currently, the United States has no significant production scale operational capability to produce and separate new Pu-238 from irradiated neptunium-237 targets. The Department of Energy - Nuclear Energy is currently evaluating and developing plans to reconstitute the United States capability to produce Pu-238 from irradiated Np-237 targets. The Savannah River Site had previously produced and/or processed all the Pu-238 utilized in Radioisotope Thermoelectric Generators (RTGs) for deep space missions up to and including the majority of the plutonium for the Cassini Mission. The previous full production cycle capabilities included: Np- 237 target fabrication, target irradiation, target dissolution and Np-237 and Pu-238 separation and purification, conversion of Np-237 and Pu-238 to oxide, scrap recovery, and Pu-238 encapsulation. The capability and equipment still exist and could be revitalized or put back into service to recover and purify Pu-238/Np-237 or broken General Purpose Heat Source (GPHS) pellets utilizing existing process equipment in HB-Line Scrap Recovery, and H-Canyon Frame Waste Recovery processes. The conversion of Np-237 and Pu-238 to oxide can be performed in the existing HB-Line Phase-2 and Phase- 3 Processes. Dissolution of irradiated Np-237 target material, and separation and purification of Np-237 and Pu-238 product streams would be possible at production rates of ?2 kg/month of Pu-238 if the existing H-Canyon Frames Process spare equipment were re-installed. Previously, the primary H-Canyon Frames equipment was removed to be replaced: however, the replacement project was stopped. The spare equipment is stored and still available for installation. Out of specification Pu-238 scrap material can be purified and recovered by utilizing the HB-Line Phase- 1 Scrap Recovery Line and the Phase-3 Pu-238 Oxide Conversion Line along with H-Canyon Frame Waste Recovery process. In addition, it also covers and describes utilizing the Phase-2 Np-237 Oxide Conversion Line, in conjunction with the H-Canyon Frames Process to restore the H-Canyon capability to process and recover Np-237 and Pu-238 from irradiated Np-237 targets and address potential synergies with other programs like recovery of Pu-244 and heavy isotopes of curium from other target material. (authors)

Fuller, Kenneth S. Jr.; Smith, Robert H. Jr.; Goergen, Charles R. [Savannah River Nuclear Solutions, LLC, Savannah River Site, Aiken, SC 29802 (United States)] [Savannah River Nuclear Solutions, LLC, Savannah River Site, Aiken, SC 29802 (United States)

2013-07-01T23:59:59.000Z

410

NETL: News Release - Sonic Waves Help Recover Natural Gas from Clogged  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

19, 2002 19, 2002 Sonic Waves Help Recover Natural Gas from Clogged Storage Sites Could Mean More Gas for Consumers During Winter Sonic Tool The 10-pound sonic tool is intended to remove scale from gas storage wells. MORGANTOWN, WV - Natural gas companies looking for better ways to unclog the wells they use to withdraw gas from underground storage reservoirs may soon be getting "good vibes" from a low-cost sonic cleaning tool. A Department of Energy-sponsored team of companies led by Furness-Newburge Inc. of Versailles, KY, has produced a prototype of a system that uses sound waves to remove inorganic matter and other debris that clog the perforations of gas wells. The technology has the potential to increase significantly the efficiency at which natural gas is withdrawn from storage reservoirs, making a larger

411

Solid Recovered Fuel: Influence of Waste Stream Composition and Processing on Chlorine Content and Fuel Quality  

Science Journals Connector (OSTI)

Solid recovered fuel (SRF) produced by mechanical–biological treatment (MBT) of municipal waste can replace fossil fuels, being a CO2-neutral, affordable, and alternative energy source. ... (4) The concentration of chlorine in SRF is key to fuel quality due to concern that elevated concentrations could exacerbate ash deposition in the convective part of boilers;(8) cause high-temperature corrosion (>500 °C) of boiler steel due to alkali chlorides and lower temperature melt deposits (300–400 °C) in the presence of zinc and lead;(9) generate high acid gases emissions (hydrogen chloride (HCl));(10) and contribute to the formation of polychlorinated dibenzodioxins (PCDDs) (for [Cl] above 0.3% w/wd)(11) during thermal recovery. ... The overall moisture content MT, reported as % w/wd (d: dry solids), was measured in two steps. ...

Costas Velis; Stuart Wagland; Phil Longhurst; Bryce Robson; Keith Sinfield; Stephen Wise; Simon Pollard

2011-12-21T23:59:59.000Z

412

Laboratory directed research and development on disposal of plutonium recovered from weapons. FY1994 final report  

SciTech Connect (OSTI)

This research project was conceived as a multi-year plan to study the use of mixed plutonium oxide-uranium oxide (MOX) fuel in existing nuclear reactors. Four areas of investigation were originally proposed: (1) study reactor physics including evaluation of control rod worth and power distribution during normal operation and transients; (2) evaluate accidents focusing upon the reduced control rod worth and reduced physical properties of PuO{sub 2}; (3) assess the safeguards required during fabrication and use of plutonium bearing fuel assemblies; and (4) study public acceptance issues associated with using material recovered from weapons to fuel a nuclear reactor. First year accomplishments are described. Appendices contain 2 reports entitled: development and validation of advanced computational capability for MOX fueled ALWR assembly designs; and long-term criticality safety concerns associated with weapons plutonium disposition.

Pitts, J.H.; Choi, J.S.

1994-11-14T23:59:59.000Z

413

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents [OSTI]

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

414

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31T23:59:59.000Z

415

Faults as potential hydrocarbon barriers, Arroyo Grande, California  

E-Print Network [OSTI]

OPTICALMICROSCOPY. Composition. Grain Size Characteristics Deformation Fluorescence Observations . Microprobe Observations. CAPILLARY PRESSURE. Sample Preparation. Test Procedures. Interpretation of the Mercury Injection Capillary Pressure Curve... rim of hydrocarbons seen on the grains. 41 , , 42 25 Photomicrograph of one of the microcracks that contains oil, 43 26 Microprobe image of the zone of quartz cement seen in the quarry, 27 Mercury injection capillary pressure apparatus, 45 48...

Switek, Daniel Paul

2012-06-07T23:59:59.000Z

416

THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS  

SciTech Connect (OSTI)

The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

2013-10-10T23:59:59.000Z

417

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and expert riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1992-01-01T23:59:59.000Z

418

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and export riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1994-01-01T23:59:59.000Z

419

Petroleum hydrocarbon-degrading bacteria in the Galveston Bay system  

E-Print Network [OSTI]

PETROLEUM HYDRQCARBOiV-DEGRADING BACTERIA IN THE GALVESTON BAY SYSTEM A Thesis by STEVEN JAMES SCHROPP Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER OF SCIFNCE... December 1979 Major Subject: Biology PETROLEUM HYDROCARBON-DEGRADING BACTERIA IN THE GALVESTON BAY SYSTEM A Thesis by STEVEN JAMES SCHROPP Approved as to style and content by: (Co-Chairman of Committee) '( ~CA. ( -Chairman of Committee) (Head...

Schropp, Steven James

1979-01-01T23:59:59.000Z

420

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents [OSTI]

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Direct production of fractionated and upgraded hydrocarbon fuels from biomass  

SciTech Connect (OSTI)

Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

2014-08-26T23:59:59.000Z

422

Catalyst and process for steam-reforming of hydrocarbons  

SciTech Connect (OSTI)

An improved catalyst and an improved process for use of the catalyst in the steam-hydrocarbon reforming reaction are disclosed. The catalyst comprises a group VIII metal on a cylindrical ceramic support consisting essentially of alpha alumina and having a plurality of gas passages extending axially therethrough. These supported catalysts display a higher geometric surface area and a lower pressure drop than do standard rings.

Atwood, K.; Merriam, J.S.; Wright, J.H.

1980-11-11T23:59:59.000Z

423

Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments  

E-Print Network [OSTI]

. Sandberg, B. A. , University of Colorado Chairman of Advisory Committee: Dr. James M. Brooks Polycyclic aromatic hydrocarbon (PAH) distributions in Upper Pleistocene sediments of the Mississippi Fan and two intraslope basins in the Gulf of Mexico... chemistries is separate phase migration driven by hydrodynamic flow upward along fault planes. The same variables at intraslope basin sites are highly altered, possibly due to extensive gravity slump faulting. High- performance liquid chromatography...

Sandberg, William Allan

2012-06-07T23:59:59.000Z

424

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents [OSTI]

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

425

Irregular spacing of heat sources for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

2012-06-12T23:59:59.000Z

426

Federal Environmental Regulations Impacting Hydrocarbon Exploration, Drilling, and Production Operations  

SciTech Connect (OSTI)

Waste handling and disposal from hydrocarbon exploration, drilling, and production are regulated by the US Environmental Protection Agency (EPA) through federal and state regulations and/or through implementation of federal regulations. Some wastes generated in these operations are exempt under the Resource Conservation and Recovery Act (RCRA) but are not exempt under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act (SARA), and other federal environmental laws. Exempt wastes remain exempt only if they are not mixed with hazardous wastes or hazardous substances. Once mixture occurs, the waste must be disposed as a hazardous material in an approved hazardous waste disposal facility. Before the Clean Air Act as amended in 1990, air emissions from production, storage, steam generation, and compression facilities associated with hydrocarbon exploration, drilling, and production industry were not regulated. A critical proposed regulatory change which will significantly effect Class II injection wells for disposal of produced brine and injection for enhanced oil recovery is imminent. Federal regulations affecting hydrocarbon exploration, drilling and production, proposed EPA regulatory changes, and a recent significant US Court of Appeals decision are covered in this report. It appears that this industry will, in the future, fall under more stringent environmental regulations leading to increased costs for operators.

Carroll, Herbert B.; Johnson, William I.

1999-04-27T23:59:59.000Z

427

Paleotopography and hydrocarbon accumulation: Williston, Powder River, and Denver basins  

SciTech Connect (OSTI)

Recent geomorphic analyses of 1:24,000 scale topographic maps in the three major basins of the northern Great Plains have disclosed a persistent system of basement paleotopographic features that trend north-northeast throughout the region. Superimposed across this system and subtly influenced by it, are the northwesterly trending Laramide structural features. Paleozoic depositional patterns have been strongly influenced by the paleoridge and trough system formed by the north-northeast features. Mesozoic deposition has also been affected by the ancient subsurface system but in a more subtle manner. Many of the Paleozoic and Mezoxoic hydrocarbon locations in the three basins appear to be the results of paleotopographic control on hydrocarbon accumulation sites. This affect ranges from Paleozoic reef sites in the Williston basin through paleotrough localization of Pennsylvanian Minnelusa production in the Powder River basin to fractured Cretaceous Niobrara production at the Silo field in the Denver basin. Basement paleotopography is the underlying factor in all deposition and subsequent hydrocarbon migration in any basin. As such, it should be considered a major factor in the exploration for oil and gas.

Thomas, G.E. (Thomas and Associates, Denver, CO (United States))

1991-06-01T23:59:59.000Z

428

The effect of rhenium, sulfur and alumina on the conversion of hydrocarbons over platinum single crystals: Surface science and catalytic studies  

SciTech Connect (OSTI)

Conversion reactions of hydrocarbons over Pt-Re model catalyst surfaces modified by sulfur and alumina have been studied. A plasma deposition source has been developed to deposit Pt, Re, and Al on metal substrates variable coverage in ultrahigh vacuum without excessive heating. Conversion of n-hexane was performed over the Re-covered Pt and Pt-covered Re surfaces. The presence of the second metal increased hydrogenolysis activity of both Pt-Re surfaces. Addition of sulfur on the model Catalyst surfaces suppressed hydrogenolysis activity and increased the cyclization rate of n-hexane to methylcyclopentane over Pt-Re surfaces. Sulfiding also increased the dehydrogenation rate of cyclohexane to benzene Over Pt-Re surfaces. It has been proposed that the PtRe bimetallic catalysts show unique properties when combined with sulfur, and electronic interactions exist between platinum, rhenium and sulfur. Decomposition of hydrocarbons on the sulfur-covered Pt-Re surfaces supported that argument. For the conversion of 1-butene over the planar Pt/AlO{sub x}, the addition of Pt increased the selectivity of hydrogenation over isomerization.

Kim, C.

1992-04-01T23:59:59.000Z

429

The effect of rhenium, sulfur and alumina on the conversion of hydrocarbons over platinum single crystals: Surface science and catalytic studies  

SciTech Connect (OSTI)

Conversion reactions of hydrocarbons over Pt-Re model catalyst surfaces modified by sulfur and alumina have been studied. A plasma deposition source has been developed to deposit Pt, Re, and Al on metal substrates variable coverage in ultrahigh vacuum without excessive heating. Conversion of n-hexane was performed over the Re-covered Pt and Pt-covered Re surfaces. The presence of the second metal increased hydrogenolysis activity of both Pt-Re surfaces. Addition of sulfur on the model Catalyst surfaces suppressed hydrogenolysis activity and increased the cyclization rate of n-hexane to methylcyclopentane over Pt-Re surfaces. Sulfiding also increased the dehydrogenation rate of cyclohexane to benzene Over Pt-Re surfaces. It has been proposed that the PtRe bimetallic catalysts show unique properties when combined with sulfur, and electronic interactions exist between platinum, rhenium and sulfur. Decomposition of hydrocarbons on the sulfur-covered Pt-Re surfaces supported that argument. For the conversion of 1-butene over the planar Pt/AlO[sub x], the addition of Pt increased the selectivity of hydrogenation over isomerization.

Kim, C.

1992-04-01T23:59:59.000Z

430

Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device  

DOE Patents [OSTI]

A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

2014-05-06T23:59:59.000Z

431

Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream  

DOE Patents [OSTI]

An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

2013-01-22T23:59:59.000Z

432

A study of the structure of the hydrocarbons of primary hard-coal tar  

SciTech Connect (OSTI)

The hydrocarbons isolated from primary hard-coal (G/sub 6/ gas coal) tar have been investigated by a combination of physicochemical and chemical methods. It has been established that the hydrocarbons boiling up to 573 K are mainly aliphatic, hydroaromatic, and naphthenic and are aromatic only to a smaller degree. Molecular and presumable structural formulas of the oxygen compounds isolated from the 473-573 K hydrocarbon fraction have been derived.

Platonov, V.V.; Gerasimova, N.I.; Ivleva, L.N.; Klyavina, O.A.; Vishnyakov, S.N.

1985-01-01T23:59:59.000Z

433

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel  

Science Journals Connector (OSTI)

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel ... We found that the primary decomposition reactions involve either (1) dissociation of ethylene from JP-10, resulting in the formation of a C8 hydrocarbon intermediate, or (2) the production of two C5 hydrocarbons. ... Heats of combustion (kcal/mole) were measured via O bomb calorimetry; adamantane (I) (c), -1441.95 ...

Kimberly Chenoweth; Adri C. T. van Duin; Siddharth Dasgupta; William A. Goddard III

2009-02-11T23:59:59.000Z

434

An energy-saving oil drilling rig for recovering potential energy and decreasing motor power  

Science Journals Connector (OSTI)

An energy-saving oil drilling rig is researched. A large accumulator is adopted in this rig to store the energy of the motor during the auxiliary time of lifting the drill stem and the potential energy of the drill stem when lowered. The equipped power of this rig decreases remarkably compared with the conventional drilling rig, and this rig can also recover and reuse the potential energy of the drill stem. Therefore, this rig owns remarkable energy-saving effect compared with the conventional drilling rig, and the energy-saving effect of the energy-saving oil drilling rig is also verified by the field tests. The mathematical model of the energy-saving oil drilling rig lowering the drill stem was derived and simulation analysis was conducted. Through simulation the curves of the drill stem lowering velocity and lowering displacement with time were obtained, and some conclusions were reached: (1) the heavier the drill stem lowered, the higher the lowering velocity is, and the shorter the lowering time is; (2) the smaller the displacement of the variable pump-motor, the higher the lowering velocity is, and the shorter the lowering time is.

Lujun Zhang

2011-01-01T23:59:59.000Z

435

Geochemistry of Salado Formation brines recovered from the Waste Isolation Pilot Plant (WIPP) repository  

SciTech Connect (OSTI)

Intergranular brines recovered from the repository horizon of the Waste Isolation Pilot Plant (WIPP) have major- and trace-element compositions that reflect seawater evaporation and diagenetic processes. Brines obtained from repository drill holes are heterogenous with respect to composition, but their compositional fields are distinct from those obtained from fluid inclusions in WIPP halite. The heterogeneity of brine compositions within the drill-hole population indicates a lack of mixing and fluid homogenization within the salt at the repository level. Compositional differences between intergranular (drill hole) and intragranular (fluid inclusions) brines is attributed to isolation of the latter from diagenetic fluids that were produced from dehydration reactions involving gypsum and clay minerals. Modeling of brine-rock equilibria indicates that equilibration with evaporite minerals controls the concentrations of major elements in the brine. Drill-hole brines are in equilibrium with the observed repository minerals halite, anhydrite, magnesite, polyhalite and quartz. The equilibrium model supports the derivation of drill-hole brines from near-field fluid, rather than large-scale vertical migration of fluids from the overlying Rustler or underlying Castile Formations. 13 refs., 6 figs., 6 tabs.

Abitz, R.; Myers, J.; Drez, P.; Deal, D.

1990-01-01T23:59:59.000Z

436

Heritable Genetic Changes in Cells Recovered From Irradiated 3D Tissue Contracts. Final report  

SciTech Connect (OSTI)

Combining contemporary cytogenetic methods with DNA CGH microarray technology and chromosome flow-sorting increases substantially the ability to resolve exchange breakpoints associated with interstitial deletions and translocations, allowing the consequences of radiation damage to be directly measured at low doses, while also providing valuable insights into molecular mechanisms of misrepair processes that, in turn, identify appropriate biophysical models of risk at low doses. The aims of this work apply to cells recovered from 3D tissue constructs of human skin and, for the purpose of comparison, the same cells irradiated in traditional 2D cultures. These aims are: to analyze by multi-flour fluorescence in situ hybridization (mFISH) the chromosomes in clonal descendents of individual human fibroblasts that were previously irradiated; to examine irradiated clones from Aim 1 for submicroscopic deletions by subjecting their DNA to comparative genomic hybridization (CGH) microarray analysis; and to flow-sort aberrant chromosomes from clones containing stable radiation-induced translocations and map the breakpoints to within an average resolution of 100 kb using the technique of 'array painting'.

Cornforth, Michael N. [The University of Texas Medical Branch at Galveston, TX (United States)

2013-05-03T23:59:59.000Z

437

Trace element behavior in the fluidized bed gasification of solid recovered fuels – A thermodynamic study  

Science Journals Connector (OSTI)

Gasification of biomass and recycled fuels is of particular interest for the efficient production of power and heat. Trace elements present as impurities in the product gas should be removed very efficiently. The objective of this work has been to develop and test thermodynamic models for the reactions of trace elements with chlorine and sulfur in the gasification processes of recycled fuels. In particular, the chemical reactions of trace elements with main thermochemical conversion products, main ash components, and bed and sorbent material are implemented into the model. The possibilities of gas cleaning devices in condensing and removing the trace element compounds are studied by establishing the volatilization tendency of trace element compounds in reducing gases. The results obtained with the model are compared with the measured data of trace elements of gasification experiments using solid recovered fuel as feedstock. Some corresponding studies in the literature are also critically reviewed and compared. The observed discrepancies may be attributed to differences in thermodynamic databases applied and experimental arrangements. The method of removing gaseous trace elements by condensation is already in use in the 160 MWth waste gasification plant in Lahti, Finland.

Jukka Konttinen; Rainer Backman; M. Hupa; Antero Moilanen; Esa Kurkela

2013-01-01T23:59:59.000Z

438

Gasification of a solid recovered fuel in a pilot scale fluidized bed reactor  

Science Journals Connector (OSTI)

Abstract The paper investigates the technical feasibility of an air gasification process of a Solid Recovered Fuel (SRF) obtained from municipal solid waste. A pilot scale bubbling fluidized bed gasifier, having a feedstock capacity of about 70 kg/h and a maximum thermal output of about 400 kW, provided the experimental data: the complete composition of the syngas (including the tar, particulate and acid/basic gas contents), the chemical and physical characterization of the bed material and that of entrained fines collected at the cyclone. The experimental runs were carried out by reaching a condition of thermal and chemical steady state under values of equivalence ratio ranging from 0.25 to 0.33. The results indicate that the selected SRF can be conveniently gasified, yielding a syngas of valuable quality for energy applications. The rather high content of tar in the syngas indicates that the more appropriate plant configuration should be that of a “thermal gasifier”, with the direct combustion of the syngas in a burner ad hoc designed, coupled with an adequate energy-conversion device.

Umberto Arena; Fabrizio Di Gregorio

2014-01-01T23:59:59.000Z

439

Bromine as an ash forming element in a fluidised bed boiler combusting solid recovered fuel  

Science Journals Connector (OSTI)

Plastic materials are the main sources of chlorine in solid recovered fuels (SRF). Chlorine is attributed to be the main initiator of slagging, fouling and corrosion in biomass and waste combustion as it lowers the melting point of ash forming matter and reacts chemically with the heat transfer surface steels. SRF may also contain sources of bromine in the form of brominated flame retardants (BFRs) applied in many plastics and textiles. Results presented in this paper from an experimental campaign at an 80 MWth bubbling fluidised bed (BFB) boiler show that bromine is behaving in a similar manner as chlorine: bromine was found at the corrosion front in boiler membrane wall tubes, and as water soluble salts in aerosol samples collected from the furnace and electrostatic precipitator (ESP) ash. It is evident from these results and the data in the literature that most of the salts of bromine are, by both their fate and physical and chemical properties, similar to those of chlorine. It can be concluded that it if there is a source of bromine in the fuel corrosive high vapour pressure bromides can be formed analogously to chlorides.

Pasi Vainikka; Sonja Enestam; Jaani Silvennoinen; Raili Taipale; Patrik Yrjas; Ari Frantsi; Janne Hannula; Mikko Hupa

2011-01-01T23:59:59.000Z

440

A method to characterise the volatile release of solid recovered fuels (SRF)  

Science Journals Connector (OSTI)

A method was developed and successfully applied to characterise the de-volatilisation process of solid recovered fuels (SRF). Following the definitions of the European initiative on SRF standardisation CEN/TC 343, this kind of fuels have to be produced from non-hazardous bio-residues, mixed- and mono-waste streams, and they are designated to be used either in mono- or co-combustion processes. Consequently, SRF are – in most cases – heterogeneous fuel mixtures. The de-volatilisation process was identified as highly relevant due to the nature of fuel: most SRF components do not evolve a char comparable to coal. Furthermore, large particle sizes do not allow the application of common approaches to determine kinetic parameters. The method presented in this paper relies on thermo-gravimetric analysis (TGA). By successful combination with other well-established analytical procedures, the obtainable information towards the de-volatilisation process was largely improved. The method allows a quantification of energy and elemental distribution between volatiles and char during the de-volatilisation process in relation to the particle temperature. The data can be used to compare SRF or SRF components with other “known” fuels such as lignite and biomass. Moreover, the data is suitable as input data for combustion models. Focus of this paper is the analytical procedure including the required calculations. In addition, first results are presented and some ideas towards the use of the results are discussed.

Th. Hilber; M. Martensen; J. Maier; G. Scheffknecht

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Selective collection as a pretreatment for indirect solid recovered fuel generation  

Science Journals Connector (OSTI)

Abstract Effective selective collection (SC) has been increasing in many countries of the European Union. As a consequence the composition of residual municipal solid waste (RMSW) is changing not only because of economic development, but also due to the collection system. The input of RMSW treatment plants is thus not homogeneous. This paper analyses two case studies involving a total of five SC scenarios and their impact on the generation of solid recovered fuel (SRF) with/without bio-drying, post-treatment and packaging take back programs (TBPs). These case studies are based on two types of SC: kerbside and drop-off. The latest regulation on SRF classification is taken into account: energy content, Cl and Hg concentrations are assessed and discussed. The role of the respirometric index (RI) is also analyzed. Results show that when SC is highly efficient RMSW can be classified directly as SRF, but only if the introduction of RI does not set stringent respirometric targets. The role of packaging \\{TBPs\\} is important as the residual waste remaining after the packaging has been processed, can be valorized increasing the lower heating value (LHV) of the residual RMSW and minimizing the streams that should be landfilled. The source separation of food waste has a significant impact on the suitability of bio-drying: when the SC of food waste is very efficient, its percentage in the RMSW may be too low for effective bio-drying.

Elena Cristina Rada; Marco Ragazzi

2014-01-01T23:59:59.000Z

442

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust  

Science Journals Connector (OSTI)

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust ... Diesel and Gasoline Engine Exhausts and Some Nitroarenes; IARC:? Lyon, France 1989. ...

Wei Huang; Thomas J. Smith; Long Ngo; Tong Wang; Hongqiao Chen; Fanggu Wu; Robert F. Herrick; David C. Christiani; Hui Ding

2007-03-16T23:59:59.000Z

443

Naphthenic/paraffinic hydrocarbons of residual lube stock from West Siberian crudes  

SciTech Connect (OSTI)

The lube stocks from West Siberian crudes are characterized by high contents of aromatic hydrocarbons and by high viscosity indexes of the naphthenic/paraffinic and aromatic hydrocarbons. Mass spectrometric analysis showed that isoparaffins account for one-third of the total naphthenic/paraffinic hydrocarbons. The study showed that the naphthenic/paraffinic hydrocarbons of the residual lube stock from West Siberia crudes, even with a variation of molecular weight over broad limits, are relatively uniform in composition. They consist mainly of isoparaffinic and monocyclic and noncondensed naphthenic structures.

Detusheva, E.P.; Bogdanov, Sh.K.; Khramtsova, L.P.; Nekrasova, A.V.; Shkol'nikov, V.M.

1983-03-01T23:59:59.000Z

444

E-Print Network 3.0 - abundant accessible hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functionalization: An Energy Frontier Research... such as hydrocarbons, dioxygen, water, carbon dioxide and dihydrogen are central to new technologies for the use... of...

445

E-Print Network 3.0 - aromatic hydrocarbon exhaust Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: : Acetylenes: Aromatics: 57 15 2 26 A breakdown of 17...

446

Calculation of the heats of combustion of aromatic hydrocarbons contained in power-generating fuel  

Science Journals Connector (OSTI)

The additive method of group contributions is used for the calculation of the heats of combustion of aromatic hydrocarbons of different structures.

E. V. Sagadeev; V. V. Sagadeev

2006-07-01T23:59:59.000Z

447

Calculation of the Heats of Combustion of Saturated Hydrocarbons Contained in Power-Generating Fuels  

Science Journals Connector (OSTI)

An empirical method is suggested for the calculation of the heats of combustion of saturated hydrocarbons by the additive scheme proceeding from their...

E. V. Sagadeev; V. V. Sagadeev

2002-07-01T23:59:59.000Z

448

E-Print Network 3.0 - aromatic hydrocarbon diol-epoxide Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with a DNA... ), a polycyclic aromatic hydrocarbon. A residue of fuel and tobacco combustion and frequently ingested by humans... , BP is metabolized in mammals to...

449

Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control  

Broader source: Energy.gov [DOE]

Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions.

450

The Impact of Low Octane Hydrocarbon Blending Streams on "E85...  

Broader source: Energy.gov (indexed) [DOE]

Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12szybist.pdf More Documents &...

451

E-Print Network 3.0 - aromatic hydrocarbons adducted Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon... to its high reactivity toward DNA and cellular proteins. The major acrolein-DNA adduct, -hydrox- ypropano... -hy- droxynonenal, and acrolein, that readily form...

452

E-Print Network 3.0 - aromatic hydrocarbon pah-degrading Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

degradation Summary: Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N... , terminate in the sludge, and can be released to the...

453

E-Print Network 3.0 - aromatic hydrocarbons pahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

454

E-Print Network 3.0 - aromatic hydrocarbons pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

455

E-Print Network 3.0 - aromatic hydrocarbon pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

456

Polycyclic Aromatic Hydrocarbons Formation in Sludge Incineration by Fluidised Bed and Rotary Kiln Furnace  

Science Journals Connector (OSTI)

Polycyclic Aromatic Hydrocarbons (PAHs) are typical pollutants arising from incineration. They are produced in any incomplete combustion principally due to inhomogeneities in a combustion chamber. The effects ...

Giuseppe Mininni; Andrea Sbrilli; Ettore Guerriero…

2004-05-01T23:59:59.000Z

457

Polycyclic aromatic hydrocarbon (PAH) in four fish species from different trophic levels in the Persian Gulf  

Science Journals Connector (OSTI)

Concentration of ten polycyclic aromatic hydrocarbon (PAH) compounds were determined in liver of four fish species from different trophic levels (Aurigequula fasciata, omnivore; Alepes djedaba, carnivore; Liza ab...

Shirin Rahmanpour; Nasrin Farzaneh Ghorghani…

2014-11-01T23:59:59.000Z

458

E-Print Network 3.0 - active aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

459

E-Print Network 3.0 - aromatic hydrocarbon compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

460

E-Print Network 3.0 - aryl hydrocarbon receptor-dna Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - aromatic polycyclic hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

coal, oil, gas... called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called Source: Rock, Chris - Department of Biological Sciences,...

462

E-Print Network 3.0 - aromatic hydrocarbons modulate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

463

E-Print Network 3.0 - aromatic hydrocarbon aryl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

464

E-Print Network 3.0 - aryl hydrocarbon monooxygenase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

465

E-Print Network 3.0 - aromatic hydrocarbon tracers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

466

E-Print Network 3.0 - aryl hydrocarbon receptor-regulated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

classes of the aryl hydrocarbon receptor (AHR). A grander objective is to provide... pollutants is a direct consequence of their interactions with the aryl ... Source: Bradfield,...

467

E-Print Network 3.0 - aryl hydrocarbon receptor-1 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

468

E-Print Network 3.0 - aryl hydrocarbon nuclear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

469

E-Print Network 3.0 - ahr aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

470

E-Print Network 3.0 - aromatic hydrocarbon water-soluble Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... with their lipophilicity and water...

471

E-Print Network 3.0 - aromatic hydrocarbons phahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

WH, Caton JE. 1983. Extraction of polycyclic aromatic hydrocarbons for qualitative analysis. In... : Handbook of Polycyclic Aromatic ... Source: Rock, Chris - Department of...

472

E-Print Network 3.0 - aryl hydrocarbon receptor-independent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

473

E-Print Network 3.0 - aryl hydrocarbon receptor-mediated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 TOXICOLOGICAL SCIENCES 106(1), 8392 (2008) doi:10.1093toxscikfn149 Summary: ). Analysis of aryl hydrocarbon receptor-mediated signaling during physiological hypoxia reveals...

474

E-Print Network 3.0 - aryl hydrocarbon receptor-dependent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

475

E-Print Network 3.0 - aryl hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

476

E-Print Network 3.0 - aromatic hydrocarbon-contaminated soil...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

soil... hydrocarbon degraders, and polycyclic aromatic ... Source: Ma, Lena - Soil and Water Science Department, University of Florida Collection: Environmental Sciences and...

477

Examination of polycyclic aromatic hydrocarbons in an urban stormwater system and bioaccumulation in Odonata.  

E-Print Network [OSTI]

??Polycyclic aromatic hydrocarbons (PAHs) are toxic organic pollutants produced from combustion processes. Associated with urban runoff they have been detected worldwide in urban wetlands. PAH… (more)

Heintzman, Lucas

2013-01-01T23:59:59.000Z

478

Problems in Catalytic Oxidation of Hydrocarbons and Detailed Simulation of Combustion Processes.  

E-Print Network [OSTI]

??This dissertation research consists of two parts, with Part I on the kinetics of catalytic oxidation of hydrocarbons and Part II on aspects on the… (more)

Xin, Yuxuan

2014-01-01T23:59:59.000Z

479

New IR Fiber-Optic Chemical Sensor for in Situ Measurements of Chlorinated Hydrocarbons in Water  

Science Journals Connector (OSTI)

In this work the development and validation of a new MIR fiber-optic physicochemical sensor system for the continuous in situ analysis of chlorinated hydrocarbons (CHCs) in...

Krska, R; Taga, K; Kellner, R

1993-01-01T23:59:59.000Z

480

Detection of Hydrocarbons in Water by MIR Evanescent-Wave Spectroscopy with Flattened Silver Halide Fibers  

Science Journals Connector (OSTI)

IR transmitting AgClxBr1-x fibers were used as internal reflection elements for the spectroscopic detection of hydrocarbons that are dissolved in water in an...

Hahn, P; Tacke, M; Jakusch, M; Mizaikoff, B; Spector, O; Katzir, A

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "olefinic hydrocarbon recovered" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Characterization of hydrocarbons found in the arctic aquatic environment near the Ekati diamond mine.  

E-Print Network [OSTI]

??Polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment of the Ekati Diamond Mine were evaluated in snow, sediment, air and water (via passive membrane samplers).… (more)

Nabess, Stephanie Ann

2014-01-01T23:59:59.000Z

482

Hydrocarbon solubility and its migration processes: a look at the present status  

SciTech Connect (OSTI)

In this study we review the present status of knowledge of solubility of hydrocarbons and its implications on primary migration processes. The intent is to examine the solubility and the transportation mechanisms relevant to geopressured-geothermal reservoirs, although the discussion included here accommodates a wide range of related aspects. Influences of parameters associated with hydrocarbon (especially methane) solubility have been studied. We have sought to evaluate several primary hydrocarbon migration processes and to point out their attractive features as well as their limitations. A brief discussion of hydrocarbon generation processes is also included.

Mamun, C.K.; Ohkuma, H.; Sepehrnoori, K.

1985-12-01T23:59:59.000Z

483

Difficulties with Recovering the Masses of Supermassive Black Holes from Stellar Kinematical Data  

Science Journals Connector (OSTI)

We investigate the ability of three-integral, axisymmetric, orbit-based modeling algorithms to recover the parameters defining the gravitational potential (mass-to-light ratio and black hole mass M•) in spheroidal stellar systems using stellar kinematical data. We show that the potential estimation problem is generically underdetermined when applied to long-slit kinematical data of the kind used for most black hole mass determinations to date. A range of parameters (, M•) can provide equally good fits to the data, making it impossible to assign best-fit values. The indeterminacy arises from the large variety of orbital solutions that are consistent with a given mass model. We demonstrate the indeterminacy using a variety of data sets derived from realistic models, as well as published observations of the galaxy M32. The indeterminacy becomes apparent only when a sufficiently large number of distinct orbits are supplied to the modeling algorithm; if too few orbits are used, spurious minima appear in the ?2(,M•) contours, and these minima do not necessarily coincide with the parameters defining the gravitational potential. We show that the range of degeneracy in M• depends on the degree to which the data resolve the radius of influence rh of the black hole. For FWHM/2rh 0.5, where FWHM refers to the instrumental resolution, we find that only very weak constraints can be placed on M•. In the case of M32, our reanalysis demonstrates that when a large orbit library is used, data published prior to 2000 (FWHM/2rh ? 0.25) are equally consistent with black hole masses in the range 1.5 ? 106 M? M• 6 M?, with no preferred value in that range. Exactly the same data can reproduce previous published results with smaller orbit libraries. While the Hubble Space Telescope (HST) Space Telescope Imaging Spectrograph (STIS) data for this galaxy (FWHM/2rh ? 0.06) may overcome the degeneracy in M•, HST data for most galaxies do not resolve the black hole's sphere of influence and in these galaxies the degree of degeneracy allowed by the data may be greater than previously believed. We investigate the effect of regularization, or smoothness constraints, on the degree of degeneracy of the solutions. Enforcing smoothness reduces the range of acceptable models, but we find no indication that the true potential can be recovered simply by enforcing smoothing. For a given smoothing level, all solutions in the minimum ?2 valley exhibit similar levels of noise; as the smoothing is increased, there is a systematic shift in the midpoint of the ?2 valley, until at a high level of smoothing the solution is biased with respect to the true solution. These experiments suggest both that the indeterminacy is real (i.e., that it is not an artifact associated with nonsmooth solutions) and that there is no known empirical way to choose the smoothing parameter to ensure that the correct solution is selected.

Monica Valluri; David Merritt; Eric Emsellem

2004-01-01T23:59:59.000Z

484

Dear Parents, I hope this finds you well and recovering from the effects of Hurricane Sandy. During the coming  

E-Print Network [OSTI]

BULLETIN Dear Parents, I hope this finds you well and recovering from the effects of Hurricane of creative ways to make up the week of classes that we lost because of Hurricane Sandy. Depending for lost instructional time: 1. Use of available common hours as teaching slots, with the exception

485

Comment on “Solid Recovered Fuel: Materials Flow Analysis and Fuel Property Development during the Mechanical Processing of Biodried Waste”  

Science Journals Connector (OSTI)

Comment on “Solid Recovered Fuel: Materials Flow Analysis and Fuel Property Development during the Mechanical Processing of Biodried Waste” ... Validated material flow models of waste treatment systems form a sound basis to evaluate system performance in view of environmental pollution as well as with respect to resource recovery. ... characteristics of refuse-derived fuels (RDF) that are processed from residual household waste by mech. ...

David Laner; Oliver Cencic

2013-12-05T23:59:59.000Z

486

Mach 2 combustion characteristics of hydrogen/hydrocarbon fuel mixtures  

SciTech Connect (OSTI)

The combustion of H/sub 2//CH/sub 4/ and H/sub 2//C/sub 2/H/sub 4/ mixtures containing 10 to 70 vol pct hydrocarbon at combustor inlet Mach number 2 and temperatures 2000 to 4000 R is investigated experimentally, applying direct-connect test hardware and techniques similar to those described by Diskin and Northam (1987) in the facilities of the NASA Langley Hypersonic Propulsion Branch. The experimental setup, procedures, and data-reduction methods are described; and the results are presented in extensive tables and graphs and characterized in detail. Fuel type and mixture are found to have little effect on the wall heating rate measured near the combustor exit, but H/sub 2//C/sub 2/H/sub 4/ is shown to burn much more efficiently than H/sub 2//CH/sub 4/, with no pilot-off blowout equivalence ratios greater than 0.5. It is suggested that H/sub 2//hydrocarbon mixtures are feasible fuels (at least in terms of combustion efficiency) for scramjet SSTO vehicles operating at freestream Mach numbers above 4.

Diskin, G.S.; Jachimowski, C.J.; Northam, G.B.; Bell, R.A.

1987-01-01T23:59:59.000Z

487

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

1996-01-01T23:59:59.000Z

488

Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars  

SciTech Connect (OSTI)

Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

2014-05-18T23:59:59.000Z

489

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

Ruka, R.J.; Basel, R.A.

1996-03-12T23:59:59.000Z

490

Distillation sequence for the purification and recovery of hydrocarbons  

DOE Patents [OSTI]

This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

2007-12-25T23:59:59.000Z

491

Mutual solubilities of water and hydrocarbons from the Cubic plus Association equation of state: A new mixing rule for the correlation of observed minimum hydrocarbon solubilities  

Science Journals Connector (OSTI)

Abstract The cubic plus association (CPA) equation of state was employed to correlate the mutual solubilities of water and hydrocarbons (n-alkanes, cycloalkanes and aromatics). In order to reproduce the minimums observed in concentration vs. temperature curves, a new mixing rule is proposed based on Kabadi and Danner's idea, whereby the water–water dispersive term is corrected to include the hydrophobic hydration effect. With this correction, correlated hydrocarbon solubilities curves have observable curvature at low temperatures. Two binary interaction parameters are required for saturated hydrocarbons and three for aromatics, which is just one more than the original CPA formulation. Using parameters determined from binary data, this improved mixing rule was employed for multicomponent water–hydrocarbon systems, with no further regression, producing better predictions when compared to the conventional van der Waals’ rules.

Milton Medeiros

2014-01-01T23:59:59.000Z

492

Desiccant bed on hydrocarbon charged to and removed from underground (salt) cavern  

SciTech Connect (OSTI)

A hydrocarbon fluid storage system is described which consists of in operable conjunction: a cavern formed within an underground salt strata below a ground surface, the cavern comprises a lower liquid volume of saturated sodium chloride storage brine and an upper fluid volume of wet hydrocarbon storage fluid, surface fluid handling means; conduit connecting the lower storage brine and upper storage hydrocarbon fluid with the surface fluid handling means, of fluid transfer means enabling transfer of brine and hydrocarbon fluid from the surface to the cavern and from the cavern to the surface, such that brine can be added to or withdrawn from the lower brine volume and hydrocarbon fluids can be added to or withdrawn from the upper hydrocarbon fluid volume, and at least one desiccant drier means positioned at the surface in operable association with the surface fluid handling means whereby the wet hydrocarbon fluid upon withdrawal from the cavern passes through the desiccant drier means and thereby becomes dry, and dry hydrocarbon fluid intended for storage passes through the desiccant drier prior to entering the storage cavern and thereby becomes wet.

Washer, S.P.

1986-06-03T23:59:59.000Z

493

Adsorption and Desorption of Hydrocarbons on a Supported Nickel Cracking Catalyst  

Science Journals Connector (OSTI)

...Hydrocarbons on a Supported Nickel Cracking Catalyst A. K. Galwey A study has been made...a high area supported nickel cracking catalyst. Measurements have been made of (i...adsorbed, after standard preparation of the catalyst, when a known volume of each hydrocarbon...

1963-01-01T23:59:59.000Z

494

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing  

E-Print Network [OSTI]

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section hydrocarbons in surface sediment from the Coal Oil Point seep field, offshore Santa4 Barbara, California. After

Sessions, Alex L.

495

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California  

E-Print Network [OSTI]

area) are not well established, either globally or within strong source areas such as near Coal OilThe spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil hydrocarbon seepage from marine environments is an important source of methane and other gases

Washburn, Libe

496

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon fraction in terms...by the incomplete combustion of organic material...sediments (1), heat and power generation...PAH from fuel combustion found in the atmosphere...polycyclic aromatic hydrocarbons; PMS, postmitochondrial...amounts of mutation (data not presented...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

497

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus heteroclitus)  

E-Print Network [OSTI]

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus aromatic hydrocarbons (HAHs) such as 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) as well as polynuclear and that the frequencies of the major allele types differ between dioxin- sensitive and dioxin-resistant populations

Hahn, Mark E.

498

Assessment of natural and anthropogenic hydrocarbon inputs using PAHs as tracers.  

E-Print Network [OSTI]

to produce liquid hydrocarbons and water. -- Coal-to-liquids (CTLs) are derived either by pyrolysis of coal authors accept that conventional oil resources are at an advanced stage of depletion and that liquid fuels is a heterogeneous mix of hydrocarbons that remain in liquid phase when extracted to the surface. -- Condensate

499

QSPR models of boiling point, octanolwater partition coefficient and retention time index of polycyclic aromatic hydrocarbons  

E-Print Network [OSTI]

QSPR models of boiling point, octanol­water partition coefficient and retention time index of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Ma´rcia Miguel Castro Ferreira* Laborato Structure­Property Relationship (QSPR) analysis and study of polycyclic aromatic hydrocarbons (PAHs

Ferreira, Márcia M. C.

500

NEW MARINE DECAPOD CRUSTACEANS FROM WATERS INFLUENCED BY HYDROmERMAL DISCHARGE, BRINE, AND HYDROCARBON SEEPAGE  

E-Print Network [OSTI]

and waters influenced by brine and hydrocarbon seeps continue to yield species new to science. Such enNEW MARINE DECAPOD CRUSTACEANS FROM WATERS INFLUENCED BY HYDROmERMAL DISCHARGE, BRINE, AND HYDROCARBON SEEPAGE AUSTIN B. WILLIAMS} ABSTRACT Five species of decapod crustaceans new to science